Document MGJ7DeJ51qakZzZ2mLdqryeKk
UOW CONFIDENTIAL INFORMATION
CRI NUMBER
R&D REPORT
THE DOW CHEMICAL COMPANY
LABORATORY REPORT CODE
LAD-AR 94.11
'ARTMENT
ntSEARCH AND DEVELOPMENT
GEOGRAPHIC LOCATION
LOUISIANA
DATE ISSUED
July 15, 1994
REPORT TITLE
Update of the Reactive Chemicals Testing of the Compatibility of Leak
Repair Sealants with Process Chemicals Used in the Louisiana Division
PAGES IN .53___ FULL REPORT
LAB NO. PROBLEM NO.
274 0000
AUTHOR'S LAST NAME AND INITIALS/MASTER NUMBER
J. G. Schell (432167), G. P. Wagener (431616), G. J. Barrilleaux (430781)
AUTHHORRJS SIGNATURE
,,
On
RE'/ftiWER'S AND/OR SUPERVISOR'S NAME
R. D. Summers
DESCRIPTIVE SUMMARY WITH CONCLUSIONS:
PERVISOR'S SIGNATURE ^71
The purpose of this report is to update the tables presented in CRI report LAD-AR 92.05 (February, 1992) summarizing the Reactive Chemicals testing of the compatibility of leak repair sealants with process chemicals in the Louisiana Division (LAD). The tables in the first report, containing over 300 entries collected over an 8 year period, were printed from an Excel spreadsheet which is kept in the LAD Reactive Chemicals lab. The spreadsheet is continually being updated and currently has over 650 entries. In addition to leak repair sealants, the tables also list the reactivities of valve packings, gaskets, thread sealants, O-rings, coatings, and adhesives with process chemicals. The tests were performed using Differential Thermal Analysis (DTA), Differential Scanning Calorimetry (DSC), Heat
fixing Calorimetry (HOM), and Accelerating Rate Calorimetry (ARC).
According to the Dow Reactive Chemicals Program, it is the responsibility of the owner of the chemical or process to obtain sufficient data to assure safe operation. LAD Safety & Loss Prevention Standard S-317, Leak Repair to Operating Lines or Equipment, states that "the leak-stop compound must be compatible with the operating line or equipment contents by Dow Reactive Chemicals testing." Reactive Chemicals testing of the compatibility of leak repair sealant and process chemical is necessary to prevent a reaction that could cause a fire, explosion, and/or spill resulting in injury and/or property loss. Not only could the reaction between the sealant and th process chemical be a problem, but the heat of this reaction could initiate another reaction of the process chemical itself, or a reaction between the process chemical and the line or equipment material of construction. If plant personnel want to use a sealant on a process chemical line that is not in the sealant compatibility table, they must contact the Reactive Chemicals group.
This sealant compatibility table has been added to the Reactive Chemicals Program option of the Safety menu on the LARNDC and LACSDC VAX computers in LAD so that all Dow personnel in the Division can have access to this information.
KEY WORDS
Leak Repair, Sealant, Valve Packing, Gasket, O-ring, Coating, Adhesive, Compatibility, Reactivity, Differential Thermal Analysis. DTA, Differential Scanning Calorimetry, DSC, Heat of Mixing, HOM, Accelerating Rate Calorimetry, ARC
PATENT STATUS:
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WILL THIS PRODUCT BE SOLD/USED IN OTHER COUNTRIES? YES* EfVlO
'CONTACT YOUR LOCAL REGULATORY COMPLIANCE PERSON AND/OR CHIEF PflOOUCT STEWARD.
DISTRIBUTION:
FORM NO C4301 (REV 03/82]
CRI - S66 MIDLAND. Ml CRI - FREEPORT.TX
CRI PLAQUEMINE, LA DEPARTMENT FILES
DISTRIBUTION LIST IS CONTINUED ON ATTACHED PAGE.
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According to LAD Safety & Loss Prevention Standard S-317, leak repair sealants may be used to temporarily stop leaks on operating lines or equipment. The leak repair is not a substitute for routine preventative maintenance and scheduled equipment repair. The line or equipment must be permanently repaired within 6 months, or with manager's approval, no later than the next scheduled shutdown. If the leak was caused by internal corrosion, or erosion, permanent repair must be made within 3 months.
The standard also states that "the leak-stop compound must be compatible with the operating line or equipment contents by Dow Reactive Chemicals testing." Reactive Chemicals testing of the compatibility of leak repair sealant and process chemical is necessary to prevent a reaction that could cause a fire, explosion, and/or spill resulting in injury and/or property loss. Not only could the reaction between the sealant and the process chemical be a problem, but the heat of this reaction could initiate another reaction of the process chemical itself, or a reaction between the process chemical and the line or equipment material of construction.
The purpose of this report is to update the tables presented in CRI report LADAR 92.05 (February, 1992) summarizing the Reactive Chemicals testing of the compatibility of leak repair sealants with process chemicals in the Louisiana Division (LAD). The tables in the first report, containing over 300 entries collected over an 8 year period, were printed from an Excel spreadsheet which is kept in the LAD Reactive Chemicals lab. The spreadsheet is continually being updated and currently has over 650 entries. In addition to leak repair sealants, the tables also list the reactivities of valve packings, gaskets, thread sealants, O-rings, coatings, and adhesives with process chemicals.
(
EXPERIMENTAL
The reactivities of the sealants with process chemicals summarized in Tables Mil were tested using Differential Thermal Analysis (DTA), Differential Scanning Calorimetry (DSC), Heat of Mixing Calorimetry (HOM), and Accelerating Rate Calorimetry (ARC).
Differential Thermal Analysis (DTA)
DTA was used prior to 1987 to detect exothermic or endothermic reactions and the reaction onset temperatures as the temperature of the sample was increased at a set rate . DTA measures the difference in temperature between the sample and reference, and not the heat flow; therefore, an accurate determination of the heat of reaction cannot be made.
r \
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Differential Scanning Calorimetry (DSC)
DSC is currently used as a screening tool to determine the exothermic or endothermic heat of reaction at elevated temperatures and the reaction onset temperature. The DSC method is similar to the DTA method except that the sample and reference material are maintained at the exact same temperature as the temperature is increased at a set rate. If the sealant and process chemical sample exothermically react at a certain temperature, the sample heater requires less energy input than the reference heater to maintain the same temperature. This energy input difference is precisely equivalent to the exothermic heat evolved and is a direct calorimetric measure of the heat of reaction. Thus DSC is considered to be more quantitative than DTA.
2-Drop Heat of Mixing Calorimetry
The LAD Reactive Chemicals lab uses a 2-Drop Heat of Mixing Calorimeter to measure heat of mixing at ambient temperature. A 50 microliter sample of liquid process chemical is injected by syringe into a 2 milliliter vial containing approximately 50 milligrams of a sealant sample. If the process chemical is a gas, a 10 milliliter sample is purged through the vial containing the sealant sample. The heat of mixing of the samples is calculated by dividing the sample peak area by the peak area of a one calorie standard.
Together, the DSC and heat of mixing tests are screening tools used to determine if there are any signs of reactivity between a sealant and a process chemical at ambient and elevated temperatures.
Accelerating Rate Calorimetry (ARC1
If more accurate and detailed thermal data are deemed necessary after the DSC and heat of mixing tests, then an ARC test is performed. Larger samples of the sealant and process chemical are loaded into an ARC sphere and a wait-searchheat sequence with a heat step usually of 10 degrees C is repeated from ambient temperature to the desired end temperature. If the self heat rate of an exothermic reaction between the sealant and the process chemical exceeds 0.02 degrees C per minute, the reaction is allowed to proceed on its own under nearadiabatic conditions. This method gives an accurate measure of the heat of reaction after corrections are made for the thermal inertia of the sample container, and also a fairly conservative estimate of the conditions for a runaway reaction. The ARC onset-of-reaction temperature is more accurate than the DSC onset temperature. Also, pressure data is collected during the ARC run.
RESULTS AND DISCUSSION
Table I (pp. 6-21) lists the reactivity of sealants with process chemicals and is sorted by process chemical. The table includes the process chemical, sealant,
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plant, reference number (corresponding to the Reactive Chemicals test number), test (DTA, DSC, HOM, or ARC), and reactivity and onset temperature. Table II (pp. 22-37) is sorted by sealant and Table III (pp. 38-53) is sorted by plant. If no thermal reactivity was observed between the sealant and the process chemical, and the test was run, for example, to 200 degrees C, the remark under the Reactivity heading would read "No exo to 200 C." If an exothermic reaction was observed with an onset temperature of 100 degrees C, the remark would read "Exo at 100 C."
If HOM and DSC or ARC test results indicate no reactivity between a sealant and a process chemical at ambient and elevated temperatures, then they can be considered compatible.
If only DTA, DSC, or ARC tests were run and indicated no reactivity at elevated temperatures, then a HOM test should be performed to check for reactivity at ambient temperature before a sealant and process chemical are considered compatible.
If HOM and/or DSC or ARC test results indicate an exothermic reaction between a sealant and a process chemical, then the Reactive Chemicals group should be consulted to help interpret the results to decide if the sealant should or should not be used.
It is important to remember that according to the Reactive Chemicals Program, it is the responsibility of the owner of the chemical or process (plant personnel) to obtain sufficient data to assure safe operation. LAD Safety & Loss Prevention Standard S-317, Leak Repair to Operating Lines or Equipment, states that "the leak-stop compound must be compatible with the operating line or equipment contents by Dow Reactive Chemicals testing." Reactive Chemicals testing of the compatibility of leak repair sealant and process chemical is necessary to prevent a reaction that could cause a fire, explosion, and/or spill resulting in injury and/or property loss. Not only could the reaction between the sealant and the proc ss chemical be a problem, but the heat of this reaction could initiate another reaction of the process chemical itself, or a reaction between the process chemical and the line or equipment material of construction. If plant personnel want to use a sealant on a process chemical line that is not in the sealant compatibility table, they must contact the Reactive Chemicals group to have the sealant and process chemical tested.
Vendors sometimes give assurances that their sealants are compatible with certain process chemicals based on prior field usage, experience, consultation, chemical theory, or testing by their company. It is important to remember that these assurances are not adequate and that LAD Safety & Loss Prevention Standard S-317 requires Dow reactive chemical testing of the sealant with the line or equipment contents. Therefore, vendor literature is not accepted as proper documentation.
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Reactivity testing only addresses chemical compatibility and in no way does it address or imply anything about a sealant's performance. It should not be assumed that because the reactivity of a sealant has been tested that it will adequately perform as a sealant in the process.
The sealant Excel spreadsheet is continually being updated as new tests are run. These include re-checks, new sealants, and sealants used with new process chemicals. Therefore, if a sealant is not in the table, the Reactive Chemicals group should be contacted to see if it was run since the last report was issued. The sealant compatibility table has also been added to the Reactive Chemicals Program option of the Safety menu on the LARNDC and LACSDC VAX computers in LAD so that all Dow personnel in the division can have access to this information.
CONCLUSIONS
1. In accordance with LAD Safety & Loss Prevention Standard S-317, Reactive Chemical testing should be performed to determine if a sealant is compatible with a process chemical before it is used.
2. An Excel spreadsheet with over 650 entries collected during the past 11 years resides in the LAD Reactive Chemicals lab and is continually being updated.
3. In addition to leak repair sealants, the spreadsheet also lists the reactivities of valve packings, gaskets, thread sealants, O-rings, coatings, and adhesives with process chemicals.
4. This sealant compatibility table has been added to the Reactive Chemicals Program option of the Safety menu on the LARNDC and LACSDC VAX computers in LAD so that all Dow personnel in the division can have access to this information.
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TABLE I. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PROCESS CHEMICAL)
PROCESS CHEMICAL
SEALANT
PLANT
REF. NO. TEST
ACETYLENE
ACID GAS BLEND ACID GAS BLEND
ACID GAS BLEND
AIR
AIR
AIR AIR AIR
AIR
AIR AIR (INSTRUMENT) AIR (INSTRUMENT) AMMONIA (15%) - D-270
AMMONIA (15%) - D-271 AMMONIA (20% IN H20) AMMONIA (AQUEOUS) AMMONIUM HYDROXIDE ANHYDROUS AMMONIA ANHYDROUS AMMONIA ANHYDROUS AMMONIA ANHYDROUS AMMONIA ANHYDROUS AMMONIA
ANHYDROUS AMMONIA ANHYDROUS AMMONIA AT-200 SCRUBBER EFFLUENT AT-200 SCRUBBER EFFLUENT
BENZENE BENZENE BENZENE(CRUDE) BENZENE(CRUDE) BENZENE PLANT PYROLYSIS GAS BENZENE-TOLUENE-XYLENE (T-1602)
BENZENE-TOLUENE-XYLENE (T-1602)
BENZENE-TOLUENE-XYLENE (T-1602) BETA-TRICHLOROETHANE BETA-TRICHLOROETHANE o BETA-TRICHLOROETHANE g BETA-TRICHLOROETHANE ^
BETA-TRICHLOROETHANE ^ ^
BETA-TRICHLOROETHANE BETA-TRICHLOROETHANE
ti O ^^
-i O 00
TEAM LEAK REPAIRS VALVEPACK B STEAM 4 PROCESS SP-1011 STEAM 4 PROCESS SP-60 STEAM 4 PROCESS SP-CM SP-1011 (30 MIN CURE 1 ST RUN) SP-1011 (30 MIN CURE 2ND RUN) SP-1011 (30 MIN CURE 3RD RUN) SP-1011 (UNCURED SAMPLE) SP-102 (CURED @ 300 C / 48 HOURS) TEAM LEAK REPAIRS SEALANT 2W TEAM LEAK REPAIRS SEALANT 2X STEAM 4 PROCESS SP-102 STEAM 4 PROCESS SP-60 STEAM 4 PROCESS SP-60 STEAM 4 PROCESS SP-102 TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS PTFE SEALANT TEAM LEAK REPAIRS SEALANT IX DOW CORNING 44 LUBRICANT FEL-PRO HI-TEMP NICKEL EASE STEAM 4 PROCESS SP-1015 TEAM LEAK REPAIRS PTFE SEALANT TEAM LEAK REPAIRS SEALANT #16 TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS VALVEPACK B STEAM 4 PROCESS SP-2000 STEAM 4 PROCESS SP-CM ROYAL PURPLE BARRIER FLUID 22 ROYAL PURPLE BARRIER FLUID 22 STEAM 4 PROCESS SP-1011 STEAM 4 PROCESS SP-103 TEAM LEAK REPAIRS VALVEPACK B FURMANITE FSC-5B FURMANITE FSC-6B TEAM LEAK REPAIRS SEALANT #6 4 F-14 FIBERS FURMANITE FSC-44D FURMANITE FSC-44D FURMANITE FSC-5B FURMANITE FSC-5B STEAM 4 PROCESS SP-289 STEAM 4 PROCESS SP-289 STEAM 4 PROCESS SP-3100
LHC 2 LGTI LGTI LGTI CHLOR-ALKALI 2 CHLOR-ALKALI 2 CHLOR-ALKALI 2 CHLOR ALKALI 2 POWER 2 POWER 2 POWER 2 LGTI LGTI LGTI LGTI LGTI DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS CAUSTIC CAUSTIC CAUSTIC CHLORINE CHLORINE LHC 3 LHC 3 BENZENE BENZENE BENZENE LHC 3 LHC 3 LHC 3 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2
Dow Confidential
86223C 4791-42A 4791-42A 4791-42A 4791-35A 4791-35A 4791-35A 4791-35A 4791-43B 92320 92320 4791-42A 4791-42A 4791-5A 4791-5A 89336 RCL 1039 91239 93121 93121 RCL 1232 RCL 1038 RCL 1010 RCL 1007 RCL 1181 91296 91296 92169 92169 84E031 84E030 85053A 92199 92199 92199 93154 93154 93154 93154 93154 93154 93154
DTA DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DTA DSC DSC DSC DTA DTA DTA DTA DTA DSC DSC DSC HOM DTA DTA DTA DSC DSC DSC DSC HOM DSC HOM DSC HOM DSC
REACTIVITY
NO EXO TO 210 C EXO AT 45 C NO EXO TO 300 C EXO AT 50 C EXOAT 160 C EXO AT 60 C EXO AT 273 C EXOAT 178 C EXO AT 420 C NO EXO TO 500 C NO EXO TO 500 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 235 C NO EXO TO 300 C NO EXO TO 175C NO EXO TO 130 C NO EXO TO 155 C NO EXO TO 250 C NO EXO TO 320 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 300 C EXO AT 40 C NO EXO TO 250 C NO EXO TO 200 C NO EXO AT 22 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 300 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 250 C EXO AT 269 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C EXO AT 253 C
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TABLE t. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PROCESS CHEMICAL)
PROCESS CHEMICAL
BETA-TRICHLOROETHANE BETA-TRICHLOROETHANE BETA-TRICHLOROETHANE BETA-TRICHLOROETHANE BETA-TRICHLOROETHANE BETA-TRICHLOROETHANE BETZ BALANCED POLYMER 68701 BETZ BALANCED POLYMER 68701 BETZ BP-P-1B (50%) + COR-TROL 778P (50%) BETZ BP-P-1B (50%) + COR-TROL 778P (50%) BOILER WATER WITH COR-TROL, EDTA, & PIB BOILER WATER WITH COR-TROL, EDTA, & PIB BRINE BRINE BRINE INTO AT-260 BRINE OUT AT-260 1.3-BUTADIENE 1,3-BUTADIENE 1,3-BUTADIENE 1,3-BUTADIENE BUTYL ETHYL MAGNESIUM (15%) IN HEXANE C-2 RECYCLE GAS C-2 RECYCLE GAS C-450 FEED TO C5S LITES C-450 FEED TO C5S + LITES C-500 FEED PYGAS + LITES C-500 FEED PYGAS LITES CALCIUM STEARATE CARBON STEEL CONCRETE WATER CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE
SEALANT
PLANT
STEAM & PROCESS SP-3100
VINYL 2
TEAM LEAK REPAIRS SEALANT #2X
VINYL 2
TEAM LEAK REPAIRS SEALANT K2X
VINYL 2
TEAM LEAK REPAIRS SEALANT #6
VINYL 2
TEAM LEAK REPAIRS SEALANT #6
VINYL 2
TEAM LEAK REPAIRS VALVEPACK A
VINYL 1
FURMANITE FSC-6B
LHC 3
FURMANITE FSC-6B
LHC 3
TEAM LEAK REPAIRS SEALANT #6 & F-14 FIBERS POWER 1
TEAM LEAK REPAIRS SEALANT #6 & F-14 FIBERS POWER 1
TEAM LEAK REPAIRS SEALANT DB-22 & F-10 FIBERS POWER 1
TEAM LEAK REPAIRS SEALANT DB-22 & F-10 FIBERS POWER 1
TEAM LEAK REPAIRS VALVEPACK AX
BRINE
TEAM LEAK REPAIRS VALVEPACK AX
BRINE
PROTECTO COAT 800 G
CHLORINE
PROTECTO-COAT 800 G
CHLORINE
ROYAL PURPLE BARRIER FLUID 22
LHC 3
ROYAL PURPLE BARRIER FLUID 22
LHC 3
TEAM LEAK REPAIRS VALVEPACK B
LHC 2
TEAM LEAK REPAIRS VALVEPACK B-EC
VECTOR
SEMSTONE 805 LINING MATERIAL
POLY B
TEAM LEAK REPAIRS SEALANT 16X
GLYCOL 2
TEAM LEAK REPAIRS SEALANT X-36
GLYCOL 2
TEAM LEAK REPAIRS SEALANT #6
LHC 3
TEAM LEAK REPAIRS SEALANT 2X
LHC 3
TEAM LEAK REPAIRS SEALANT #6
LHC 3
TEAM LEAK REPAIRS SEALANT 2X
LHC 3
STEAM & PROCESS SP-3100
POLY C
STEAM A PROCESS SP-520
POWER 2
FURMANITE FSC-44D
VINYL 2
FURMANITE FSC-44D
VINYL 2
FURMANITE FSC-5B
VINYL 2
FURMANITE FSC-5B
VINYL 2
SAFE SEAL - CHEMOLA TEFLON
METHANES
SAFE SEAL - CHEMOLA TEFLON
METHANES
SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) METHANES
SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) METHANES
SAFE SEAL MULTIPAK (JOHN CRANE 6KB)
METHANES
SAFE SEAL MULTIPAK (JOHN CRANE 6KB)
METHANES
STEAM & PROCESS SP-325
VINYL 2
STEAM & PROCESS SP-325 STEAM & PROCESS SP-CM
VINYL 2 VINYL 2
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REF. NO.
93154 93154 93154 93154 93154 84E189 94092 94092 92175 92175 92163 92183 94052 94052 4792-20A 4792-20A 92169 92169 86223D 93062 910B2 91117 91115 90385 90385 90385 90385 93194 92327 93154 93154 93154 93154 94060 94060 94060 94060 94060 94060 93154 93154 93154
TEST
HOM DSC HOM DSC HOM DTA HOM DSC DSC HOM DSC HOM HOM DSC DSC DSC DSC HOM DTA DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC HOM DSC HOM HOM DSC HOM DSC HOM DSC DSC HOM DSC
REACTIVITY
NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C EXO AT 284 C NO EXO AT 22 C EXO AT 275 C SL. EXO AT 22 C NO EXO TO 200 C NO EXO TO 335 C NO EXO AT 22 C NO EXO TO 250 C NO EXO AT 22 C NO EXO AT 22 C NO EXO TO 225 C EXOAT 155 C EXO AT 58 C NO EXO TO 200 C NO EXO AT 22 C NO EXO TO 210 C EXOAT 105 C EXO AT 40 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 300 C NO EXO TO 180 C EXO AT 225 C NO EXO AT 22 C EXO AT 223 C NO EXO AT 22 C NO EXO AT 22 C EXO AT 297 C NO EXO AT 22 C EXO AT 325 C NO EXO AT 22 C EXOAT 185 C EXO AT 252 C NO EXO AT 22 C EXO AT 247 C
TABLE I. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PROCESS CHEMICAL)
PROCESS CHEMICAL
SEALANT
PLANT
REF. NO. TEST
CARBON TETRACHLORIDE
CARBON TETRACHLORIDE
CARBON TETRACHLORIDE
CARBON TETRACHLORIDE
CARBON TETRACHLORIDE
CARBON TETRACHLORIDE (CRUDE, 93%)
CARBON TETRACHLORIDE (CRUDE, 93%)
CARBON TETRACHLORIDE (CRUDE, 93%)
CARBON TETRACHLORIDE (CRUDE, 93%)
CAUSTIC (25%)
CELL EFFLUENT (10% SODIUM HYDROXIDE)
CELL EFFLUENT (10% SODIUM HYDROXIDE)
CELL EFFLUENT (10% SODIUM HYDROXIDE)
CELL EFFLUENT (10% SODIUM HYOROXIDE)
CHLORINE
CHLORINE
CHLORINE
CHLORINE
CHLORINE
CHLORINE
CHLORINE
CHLORINE
CHLORINE
CHLORINE
CHLORINE
CHLORINE
CHLORINE
CHLORINE
CHLORINE
CHLORINE
CHLORINE
CHLORINE
CHLORINE
CHLORINE
CHLORINE
CHLORINE CHLORINE
D
CHLORINE CHLORINE
"n q^
CHLORINE CHLORINE CHLORINE
Z! g \>
^g
- oo
STEAM & PROCESS SP-CM TEAM LEAK REPAIRS SEALANT #11 TEAM LEAK REPAIRS SEALANT #11 TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS SEALANT #6 CHESTERTON 810 STEEL PUTTY (CURED) CHESTERTON 810 STEEL PUTTY (CURED) CHESTERTON 858 STEEL PUTTY (CURED) CHESTERTON 858 STEEL PUTTY (CURED) TEAM LEAK REPAIRS PRI-102C (THREADS) TEAM LEAK REPAIRS F-14 FIBER STEAM & PROCESS SP-1011 STEAM & PROCESS SP-2000 STEAM & PROCESS SP-60 ANCHOR VALVE PACKING 375 ANCHOR VALVE PACKING 4205 BELZONA CERAMIC-R METAL BELZONA E-METAL BELZONA SUPER METAL CELL PUTTY CHRYSOTILE ASBESTOS FIBER GSKT CONLEY TEFLON PASTE FELPOXY STEEL OARLOCK VALVE PACKING 6130 GARLOCK VALVE PACKING 7130 GORE PACKING PTFE W/ GRAPHITE GORTEX PTFE GORTEX SEALANT (TEFLON) JOHN CRANE VALVE PKG C-1050 JOHN CRANE VALVE PKG C-60 JOHN CRANE VALVE PKG C-7762 JOHN MANSVILLE VALVE PKG AF-5331 LOCTITE #56747 PST LOCTITE #59231 (WITH TEFLON) LOCTITE 271 ADHESIVE/SEALANT PARKER HANNIFIN VALVE PKG 2287-BR PARKER HANNIFIN VALVE PKG 2287-GL PTFE/KEVLAR SEAL-ITT #34 SILASTIC 732-RTV SILICONE RUBBER STEAM & PROCESS SP-1011 TEAM LEAK REPAIRS SEALANT #11
Dow Confidential
VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 SOLVENTS/E DC SOLVENTS/EDC SOLVENTS/E DC SOLVENTS/EDC CAUSTIC VINYL 2 CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLOR-ALKALI 2 CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE SOLVENTS/EDC CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLOR-ALKALI 2 CHLOR-ALKALI 2 CHLOR-ALKALI 2 CHLORINE CHLORINE CHLOR-ALKALI 2 CHLORINE CHLOR-ALKALI 2 CHLOR-ALKALI 2 VINYL 1
93154 93154 93154 93154 93154 92298 92298 92298 92298 91098 93129 92180 92180 92180 84E138 84E005 85172D 84E1B4 85172A ARC 91-647 90022 RCL 83-004 84E183 84E007 84E008 86206A 85136A ARC 91-616 84E141 84E140 B4E003 84E144 90282 90282 89071 84E142 84E143 89322 90277 B4E100 69322 RCL 83-093
HOM DSC HOM DSC HOM DSC HOM DSC HOM DSC DSC DSC DSC DSC DSC DTA DTA DTA DTA ARC DSC DTA DTA DTA DTA DTA DTA ARC DSC DSC DTA DTA DSC ARC DSC 0SC DSC DSC DSC DTA DSC DTA
REACTIVITY
NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 150 C NO EXO AT 22 C NO EXO TO 150 C NO EXO AT 22 C NO EXO TO 200 C NO EXO TO 200 C SL EXOAT 180 C SL EXOAT 170C SL EXOAT 194 C EXO < 30 C EXOAT 136 C EXO AT 35 C EXO < 25 C EXO AT 30 C EXO AT 86 C NO EXO TO 250 C EXOAT 100 C EXO < 25 C EXO AT -83 C EXO AT -76 C NO EXO TO 200 C NO EXO TO 250 C NO EXO TO 200 C EXO AT 36 C EXO AT 46 C EXO AT 102 C EXO < 30 C EXOAT 115C EXO AT 33 C EXO AT -5 C EXO < 30 C EXO AT 38 C EXO AT 48 C EXO AT 90 C EXOAT 160 C EXO AT 40 C EXO AT 90 C
9
TABLE I. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PROCESS CHEMICAL)
PROCESS CHEMICAL
SEALANT
PLANT
REF. NO. TEST
CHLORINE CHLORINE CHLORINE (LIQUID) CHLORINE (LIQUID) CHLORINE (LIQUID) CHLORINE (LIQUID) CHLORINE (LIQUID) CHLORINE (LIQUID) CHLORINE (LIQUID) CHLORINE (LIQUID) CHLORINE (LIQUID) CHLORINE (LIQUID) CHLORINE (LIQUID) CHLORINE (LIQUID) CHLORINE (LIQUID) CHLORINE (LIQUID) CHLORINE (LIQUID) CHLORINE (LIQUID) CHLORINE (LIQUID) CHLORINE (LIQUID) CHLORINE (LIQUID) CHLORINE (TRACE WATER. HCBD) CHLORINE VENT GAS CHLORINE VENT GAS CHLORINE VENT GAS CHLORINE VENT GAS CHLOROFORM CHLOROFORM CHLOROFORM CHLOROFORM CHLOROFORM CHLOROFORM CHLOROFORM CHLOROFORM CITRIKLEEN DEGREASER CITRIKLEEN DEGREASER COAL (LOC 33A) COAL (LOC 33A) COAL CHAR SLURRY (LOC 35C) COAL CHAR SLURRY (LOC 35C) CONDENSATE (C-16) CP-1000 OIL SATURATED WITH HCL
D 3O Z3 T1 --i x> 3 TJ Q
z \> -1 \) --f o T> 30
TEAM LEAK REPAIRS SEALANT #6 + F-14 FIBER
VINYL 1
UNCURED EPDM RUBBER
CHLOR-ALKALI 2
CASTROL BRAYCOTE 1728
CHLORINE
COPALTITE HIGH TEMPERATURE SEALANT
CHLORINE
DOW CORNING 3120 RTV SEALANT
CHLORINE
GARLOCK 900 GASKET
CHLORINE
GOR-TEX GR GASKET
CHLORINE
GRAFOIL GHE
CHLORINE
KADEL SN N-75 SEALANT
CHLORINE
KLINGER K-61 GASKET
CHLORINE
PERMATEX FORM-A-GASKET 2 (CURED)
CHLORINE
SAFE SEAL - CHEMOLA TEFLON
METHANES
STEAM & PROCESS SP-2026
CHLORINE
STEAM & PROCESS SP-292
CHLOR-ALKALI 2
STEAM & PROCESS SP-300D
CHLORINE
STEAM & PROCESS SP-375
CHLORINE
STEAM & PROCESS SP-CM
CHLORINE
STEAM & PROCESS SP-TFLO
CHLORINE
TEAM LEAK REPAIRS VALVEPACK OX (TEFLON)
CHLOR-ALKALI 2
TORLON SN T210 SEALANT
CHLORINE
USADURIAN SBR RUBBER
CHLORINE
CPE-TAC
CHLORINE
DERAKANE 470 (CURED 6/14/88)
CHLORINE
IPI EPOXY (CURED)
CHLORINE
RED PRIMER (CURED)
CHLORINE
WHITE DURDICK 800 G
CHLORINE
SAFE SEAL - CHEMOLA TEFLON
METHANES
SAFE SEAL - CHEMOLA TEFLON
METHANES
SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) METHANES
SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) METHANES
SAFE SEAL MULTIPAK (JOHN CRANE 6KB)
METHANES
SAFE SEAL MULTIPAK (JOHN CRANE 6KB)
METHANES
STEAM & PROCESS SP-CM
METHANES
TEAM.LEAK REPAIRS SEALANT DB-2
METHANES
C5A PEL PRO
POWER 1
NO. 725 NICKEL ANTISEIZE
POWER 1
STEAM & PROCESS SP-102
LGTI
STEAM A PROCESS SP-60
LGTI
STEAM & PROCESS SP-102
LGTI
STEAM & PROCESS SP-60
LGTI
TEAM LEAK REPAIRS SEALANT 18X
GLYCOL 1
TEAM LEAK REPAIRS SEALANT 6
METHANES
Dow Confidential
RCL 83-095 DTA
ARC 91-648 ARC
ARC 91-585 ARC
ARC 94-851 ARC
ARC 94-848 ARC
ARC 92-737 ARC
ARC 93-771 ARC
ARC 91-586 ARC
RCL-93-9809 ARC
ARC 92-738 ARC
ARC 94-855 ARC
94060
ARC
ARC 92-692 ARC
RCL-93-9831 ARC
ARC 92-711 ARC
RCL-93-9830 ARC
ARC 92-708 ARC
ARC 92-715 ARC
RCL-92-9764 ARC
RCL-93-9799 ARC
ARC 94-853 ARC
84E211
DTA
4792-21A DSC
4792-21A DSC
4792-20A DSC
4792-20A DSC
94060
HOM
94060
DSC
94060
HOM
94060
DSC
94060
HOM
94060
DSC
85133D
DTA
RCL 82-039 DTA
89050
DSC
89050
DSC
4791-6A
DSC
4791-6A
DSC
4791-6A
DSC
4791-6A
DSC
90266
DSC
92288
DSC
REACTIVITY
EXOAT 130 C EXO AT 98 C EXOAT 167 C EXOAT 113 C EXO AT 36 C EXO AT 26 C NO EXO TO 175 C EXO AT 104 C EXOAT 182 C EXO AT 27 C EXO AT 22 C EXO AT 8 C EXO AT 20 C NO EXO TO 250 C EXO AT 20 C NO EXO TO 250 C EXO AT 20 C NO EXO TO 175 C NO EXO TO 250 C EXOAT 109 C EXO AT 59 C EXO AT 135 C EXO AT 30 C NO EXO TO 250 C EXO AT 40 C EXO AT 35 C NO EXO AT 22 C EXO AT 310 C NO EXO AT 22 C EXO AT 200 C NO EXO AT 22 C EXO AT 224 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 300 C EXO AT 78 C NO EXO TO 235 C NO EXO TO 235 C EXOAT 165 C NO EXO TO 235 C NO EXO TO 300 C NO EXO TO 200 C
10
TABLE I. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PROCESS CHEMICAL)
PROCESS CHEMICAL
SEALANT
PLANT
REF. NO. TEST
CRACKED QAS
CRACKED QAS
CRACKED QAS
CRACKED QAS
CRACKED QAS
CRACKED QAS (2C-50)
CRACKED QAS (2C-50)
CRACKED QAS (2C-50)
CRACKED QAS (2C-50B)
CRACKED QAS (H2.C1,C2,C3.C4.HIGHERS)
D-102 QUENCH LIQUOR
D-1220 BOILER BLOWDOWN
D-13 HEXES
D-13 HEXES
D-270 LIQUID
DIMETHYL ETHER
DIMETHYL SULFIDE
DITCHWATER (LHC 2 * LQTI)
DITCHWATER (LHC2 & LQTI)
DNDA CATALYST (BATCH 886)
DNDA CATALYST (BATCH 886)
OOWANOLDB
DOWANOL DF 250
DOWANOL DF 250
DOWANOL DPM
DOWANOL DPM
DOWANOLEB
DOWANOLEB
DOWANOL EB
DOWANOL EB
DOWANOL EB
DOWANOL EB
DOWANOL EB
DOWANOL EB
DOWANOL EB SERIES (EB.DB.TBH)
DOWANOLPM
DOWANOL PM
DOWANOL PM
DOWANOL PM
O
DOWANOL PM
ZO
DOWANOL PM
i>
DOWANOL PM
O -n o ~Z.
SAFE SEAL - CHEMOLA TEFLON
LHC 2
SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) LHC 2
SAFE SEAL MULTIPAK (JOHN CRANE 6KB)
LHC 2
TEAM LEAK REPAIRS SEALANT DB-22
LHC 3
TEAM LEAK REPAIRS VALVEPACK BEC
LHC 2
FURMANITE FSC-46D (TEFLON 300)
LHC 2
STEAM & PROCESS SP-102
LHC 2
STEAM & PROCESS SP-CM
LHC 2
CHESTERTON 858 PUTTY - PARTS A & B
LHC 2
TEAM LEAK REPAIRS SEALANT #6
LHC 2
FURMANITE FSC-6B
VINYL 2
TEAM LEAK REPAIRS SEALANT #18
LHC 3
FURMANITE FSC-6C
SOLVENTS/EDC
FURMANITE FSC-6B
SOLVENTS/EDC
TEAM LEAK REPAIRS F14 FIBERS
GLYCOL 1
TEAM LEAK REPAIRS SEALANT DB-2
METHANES
FURMANITE FSC-6B
LHC 2
CURED AVANTI AV-202 MULTIGROUT
LHC 3
CURED AVANTI AV-220 MULTIGROUT
LHC 3
SEMSTONE 145-S
POLY B
SEMSTONE 245
POLY B
TEAM LEAK REPAIRS VALVEPACK E
DOWANOLS
TEAM LEAK REPAIRS SEALANT #6
DOWANOLS
TEAM LEAK REPAIRS SEALANT #6
DOWANOLS
TEAM LEAK REPAIRS SEALANT #6
DOWANOLS
TEAM LEAK REPAIRS SEALANT #6
DOWANOLS
EPR EO 962 "O'-RING
DOWANOLS
EPR RED DOT 'O'-RING
DOWANOLS
STEAM A PROCESS SP-1011
DOWANOLS
STEAM & PROCESS SP-102
DOWANOLS
STEAM & PROCESS SP-3100
DOWANOLS
STEAM & PROCESS SP-60
DOWANOLS
STEAM & PROCESS SP-CM
DOWANOLS
VITON YELLOW DOT `O'-RINQ
DOWANOLS
STEAMA PROCESS SP-1015
DOWANOLS
EPR EO 962 "O'-RING
DOWANOLS
EPR RED DOT *0*-RING
DOWANOLS
STEAM A PROCESS SP-1011
DOWANOLS
STEAM A PROCESS SP-102
DOWANOLS
STEAM A PROCESS SP-3100
DOWANOLS
STEAM A PROCESS SP-60
DOWANOLS
STEAM A PROCESS SP-CM
DOWANOLS
Dow Confidential
94033 94033 94033 90243 90236 93135 92065 92065 92104 RCL 736 89208 89151 92198 92196 91169 RCL 82-043 91221 871171 871172 90146 90146 RCL 1491 92016 92016 92016 92016 92339 92339 93014 93014 93014 93014 93014 92339 84E104 92339 92339 93014 93014 93014 93014 93014
DSC DSC DSC DSC DSC DSC DSC DSC DSC DTA DSC DSC DSC DSC DSC DTA DSC DSC DSC DSC DSC DTA HOM DSC HOM DSC DSC DSC DSC DSC DSC DSC OSC DSC DTA DSC DSC DSC DSC DSC DSC DSC
-o
REACTIVITY
NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 200 C NO EXO TO 250 C NO EXO TO 200 C NO EXO TO 400 C EXO AT 338 C NO EXO TO 150 C NO EXO TO 400 C NO EXO TO 200 C NO EXO TO 250 C EXO AT 344 C EXO AT 270 C NO EXO TO 250 C NO EXO TO 200 C NO EXO TO 180 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 250 C EXO AT 223 C NO EXO TO 350 C NO EXO AT 25 C NO EXO TO 200 C SL EXO AT 25 C NO EXO TO 200 C NO EXO TO 210 C NO EXO TO 250 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 250 C EXO AT 275 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 300 C
n
TABLE I. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PROCESS CHEMICAL)
PROCESS CHEMICAL
SEALANT
PLANT
REF. NO. TEST
DOWANOL PM
DOWANOL PM
DOWANOL PM
DOWANOL PM SERIES (PM.DPM.TPM)
DOWANOL PM. DPM, TPM. KOH MIX (DV-114)
DOWANOL TBH AND HIGHERS (T-130)
DOWANOL TPM
DOWANOL TPM
DOWANOL TPM & HIGHERS
DOWTHERM A
DOWTHERM A
DOWTHERM A
DOWTHERM A
DOWTHERM A
DOWTHERM A
DOWTHERM G
DOWTHERM G
DOWTHERM G
DOWTHERM G
DOWTHERM G
DOWTHERM G
DOWTHERM G
DOWTHERM G
DOWTHERM G
DOWTHERM G
DOWTHERM G
DOWTHERM G DOWTHERM G
o r-
DOWTHERM G
Zc
DOWTHERM G
DOWTHERM G DOWTHERM G DOWTHERM G DOWTHERM G DOWTHERM G
z> nc ~Z_ * j -t V
--vj
&
DOWTHERM G
DOWTHERM G
ETHANE
ETHANE
ETHANE/ETHYLENE (2C-52 OVERHEAD GAS)
ETHANOLAMINES (MEA.DEA.TEA)
ETHANOLAMINES (MEA.DEA.TEA)
TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS SEALANT #6 VITON YELLOW DOT '0*-RING STEAM & PROCESS SP-2000 TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS SEALANT *6 TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS SEALANT 16X TEAM LEAK REPAIRS SEALANT 2X TEAM LEAK REPAIRS SEALANT 2X TEAM LEAK REPAIRS SEALANT 5G TEAM LEAK REPAIRS SEALANT X-36 TEAM LEAK REPAIRS VALVEPACK AX FURMANITE FSC-5C FURMANITE FSC-5C FURMANITE FSC-6B FURMANITE FSC-6B STEAM & PROCESS SP-1011 STEAM & PROCESS SP-1011 STEAM & PROCESS SP-102 STEAM & PROCESS SP-102 STEAM & PROCESS SP-109 TEAM LEAK REPAIRS 16X & FURMANITE FSC-6B TEAM LEAK REPAIRS SEALANT #16X TEAM LEAK REPAIRS SEALANT 16X TEAM LEAK REPAIRS SEALANT #2XH TEAM LEAK REPAIRS SEALANT #2XH TEAM LEAK REPAIRS SEALANT 16X TEAM LEAK REPAIRS SEALANT 16X TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK B-EC TEAM LEAK REPAIRS VALVEPACK ER TEAM LEAK REPAIRS VALVEPACK OX TEAM LEAK REPAIRS VALVEPACK OX TEAM LEAK REPAIRS SEALANT *6 TEAM LEAK REPAIRS VALVEPACK B TEAM LEAK REPAIRS SEALANT #6 STEAM & PROCESS SP-1012 STEAM & PROCESS SP-2007
DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS POLY C POLY C POLY C POLY C POLY C POLY C VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 METHANES VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 PROMIX LHC 2 LHC 2 DOWANOLS DOWANOLS
92016 92016 92339 84E105 92251 92251 92016 92016 92251 87033B 93080 93080 87033A 87033C 87063A 89186 93154 92100 93154 93154 93154 93154 93154 RCL 1458 92100 92100 93154 93154 93154 92100 92100 92100 93154 92100 92100 92100 93154 94071 86223G RCL 1015 84E106 84E107
HOM DSC DSC DTA DSC DSC HOM DSC DSC DTA DSC HOM DTA DTA DSC DSC HOM DSC HOM DSC HOM DSC HOM DTA DSC DSC HOM DSC HOM DSC DSC DSC HOM DSC DSC DSC HOM DSC DTA DTA DTA DTA
Dow Confidential
REACTIVITY
SL EXO AT 25 C NO EXO TO 200 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 300 C NO EXO TO 300 C SL EXO AT 25 C NO EXO TO 200 C NO EXO TO 300 C NO EXO TO 350 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C NO EXO TO 350 C NO EXO TO 350 C NO EXO TO 400 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 290 C NO EXO TO 350 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C NO EXO TO 350 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C NO EXO TO 350 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 200 C NO EXO TO 300 C NO EXO TO 200 C NO EXO TO 250 C NO EXO TO 250 C
on A 0??09?
f-O NFTDFNTTAl
12
TABLE I. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PROCESS CHEMICAL)
PROCESS CHEMICAL
SEALANT
PLANT
ETHANOLAMINES (MEA.DEA.TEA)
TEAM LEAK REPAIRS SEALANT #6
ETHYL CHLORIDE
GRAFOIL GHE
ETHYL CHLORIDE
GRAFOIL GHR
ETHYL CHLORIDE
TEAM LEAK REPAIRS SEALANT #6
ETHYLENE
FURMANITE FSC-6B
ETHYLENE
STEAM & PROCESS SP-2000
ETHYLENE
STEAM & PROCESS SP-2026
ETHYLENE
TEAM LEAK REPAIRS SEALANT DB-20
ETHYLENE
TEAM LEAK REPAIRS VALVEPACK A
ETHYLENE
TEAM LEAK REPAIRS VALVEPACK AW W/ FIBERS
ETHYLENE
TEAM LEAK REPAIRS VALVEPACK AX
ETHYLENE
TEAM LEAK REPAIRS VALVEPACK AX
ETHYLENE
TEAM LEAK REPAIRS VALVEPACK B
ETHYLENE
TEAM LEAK REPAIRS VALVEPACK B + G FIBERS
ETHYLENE
TEAM LEAK REPAIRS VALVEPACK GX
ETHYLENE DICHLORIDE
COOPER OIL TOOL DIVISION WKM NO. 114
ETHYLENE DICHLORIDE
FURMANITE FSC-5B
ETHYLENE DICHLORIDE
FURMANITE FSC-5B
ETHYLENE DICHLORIDE
FURMANITE FSC-6B
ETHYLENE DICHLORIDE
FURMANITE FSC-6B
ETHYLENE DICHLORIDE
STEAM & PROCESS SP-289
ETHYLENE DICHLORIDE
STEAM & PROCESS SP-289
ETHYLENE DICHLORIDE
STEAM & PROCESS SP-325
ETHYLENE DICHLORIDE
STEAM & PROCESS SP-325
ETHYLENE DICHLORIDE
TEAM LEAK REPAIRS SEALANT #2X
ETHYLENE DICHLORIDE
TEAM LEAK REPAIRS SEALANT #2X
ETHYLENE DICHLORIDE
TEAM LEAK REPAIRS SEALANT #2XH
ETHYLENE DICHLORIDE
TEAM LEAK REPAIRS SEALANT #2XH
ETHYLENE DICHLORIDE
TEAM LEAK REPAIRS SEALANT #6
ETHYLENE DICHLORIDE
TEAM LEAK REPAIRS SEALANT #6
ETHYLENE DICHLORIDE
TEAM LEAK REPAIRS SEALANT *6
ETHYLENE DICHLORIDE
TEAM LEAK REPAIRS VALVEPACK A
ETHYLENE DICHLORIDE
TEAM LEAK REPAIRS VALVEPACK AX
ETHYLENE DICHLORIDE
TEAM LEAK REPAIRS VALVEPACK AX
ETHYLENE DICHLORIDE (C-250 REFLUX)
FURMANITE FSC-5C
ETHYLENE DICHLORIDE (C-250 REFLUX)
FURMANITE FSC-6B
ETHYLENE DICHLORIDE (CRUDE - EDC VCM + HCL) WKM VALVEPACK 114 & 'STP* LUBRICANT
ETHYLENE DICHLORIDE (D-15 VESSEL SAMPLE)
STEAM & PROCESS SP-325
ETHYLENE DICHLORIDE BETA-TRICHLOROETHANE TEAM LEAK REPAIRS SEALANT 6
ETHYLENE DICHLORIDE BETA-TRICHLOROETHANE TEAM LEAK REPAIRS VALVEPACK A
ETHYLENE GLYCOL
FURMANITE FSC-6B
ETHYLENE GLYCOL
MOLYKOTE 44 LUBRICANT
DOWANOLS GLYCOL 2 GLYCOL 2 SOLVENTS/EDC LHC 3 VINYL 1 VINYL 1 VINYL 1 VINYL 1 POLY C BRINE BRINE LHC 3 POLY C LHC 3 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 1 VINYL 2 VINYL 2 VINYL 1 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 SOLVENTS/EDC VINYL 1 VINYL 1 GLYCOL 2 GLYCOL 2
Dow Confidential
REF. NO. TEST
84E108 90311 90311 90024 92306 RCL 83-111 RCL 83-112 84E194 84E186 86183A 94052 94052 86223F B6183B 93207 93042 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 3108-46 93154 93154 84E188 93154 93154 4791-29A 4791-29A 93066 93144 84E193 84E190 92143 94030
DTA DSC DSC DSC DSC DTA DTA DTA DTA DTA HOM DSC DTA DTA DSC DSC DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM DTA DSC HOM DTA DSC HOM DSC DSC DSC DSC DTA DTA DSC DSC
REACTIVITY
NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 200 C NO EXO TO 300 C NO EXO TO 225 C NO EXO TO 130 C NO EXO TO 250 C NO EXO TO 375 C NO EXO AT 22 C NO EXO TO 108 C NO EXO TO 350 C NO EXO TO 325 C NO EXO TO 200 C NO EXO TO 310 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 250 C NO EXO AT 22 C NO EXO TO 325 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 200 C NO EXO TO 350 C NO EXO AT 22 C EXO AT 300 C NO EXO TO 250 C NO EXO AT 22 C NO EXO TO 150 C EXO AT 40 C EXOAT 130 C NO EXO TO 300 C NO EXO TO 400 C EXO AT 276 C NO EXO TO 200 C EXOAT265 C
IJU A 0 P P 0 9 3
CONF TOFNT TA(
'3
TABLE I. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PROCESS CHEMICAL)
PROCESS CHEMICAL
SEALANT
PLANT
REF. NO. TEST
ETHYLENE GLYCOL ETHYLENE GLYCOL ETHYLENE GLYCOL (1%) IN CONDENSATE ETHYLENE GLYCOL (1%) IN WATER ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE REACTOR OUTLET GAS FLARE DRUM LIQUID FLIGHTGARD 2000 FREON 12 FREON 12 FUEL OIL FUEL OIL HO (15%) METHYL CHLORIDE (05%) HQ (15%) METHYL CHLORIDE (85%) HO (50%) + CHLORINE (50%) HO (50%) CHLORINE (50%) HO (50%) CHLORINE (50%) HO, Ml, M2. M3, M4 (T-851) HO, Ml, M2. M3, M4 (T-851) Ha,M 1 ,M2,M3,M4 (K-350 SUCTION) HYDROGEN HYDROGEN HYDROGEN HYDROGEN CHLORIDE
STEAM & PROCESS SP-1011 STEAM & PROCESS SP-2000 STEAM & PROCESS SP-1011 FURMANITE FSC-6B 3M NEOPRENE 80 CONTACT ADHESIVE 3M NEOPRENE 80 CONTACT ADHESIVE CHEMRA2 O-RING MATERIAL 0962 O-RING MATERIAL EPR EO 962 "O'-RING EPR RED DOT 'O- RING FURMANITE FSC-5B GRAFOIL GHE GRAPHONICS GASKET GRAPHONICS GASKET (ADHESIVE STRIP) STEAM & PROCESS SP-1011 STEAM & PROCESS SP-1012 STEAM & PROCESS SP-106 STEAM & PROCESS SP-109 STEAM & PROCESS SP-2000 STEAM & PROCESS SP-60 TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK B VITON YELLOW DOT 'O'-RING LAMONS SPIROSEAL GSKT (GRAPHITE) TEAM LEAK REPAIRS VALVEPACK OX D.E.R. 331 EPOXY RESIN STEAM & PROCESS SP-2007 STEAM & PROCESS SP 2026 ROYAL PURPLE BARRIER FLUID 22 ROYAL PURPLE BARRIER FLUID 22 STEAM & PROCESS SP-1011 STEAM & PROCESS SP-103 CURED DB 22 SILASTIC 732 RTV TEAM LEAK REPAIRS SEALANT #6 STEAM 4 PROCESS SP-2600 STEAM 4 PROCESS SP-CM STEAM 4 PROCESS SP-2000 STEAM 4 PROCESS SP-2000 TEAM LEAK REPAIRS VALVEPACK AW 4 FIBERS TEAM LEAK REPAIRS VALVEPACK B FURMANITE FSC-5B
Dow Confidential
GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 DOWANOLS DOWANOLS GLYCOL 2 GLYCOL 2 GLYCOL 1 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 DOWANOLS GLYCOL 2 LHC 2 GLYCOL 2 METHANES CHLORINE LHC 3 LHC 3 METHANES METHANES SOLVENTS/E DC SOLVENTS/E DC SOLVENTS/EDC METHANES METHANES METHANES CHLOR-ALKALI 2 POLY C LHC 2 GLYCOL 2
94030 94030 92194 92143 93034 93034 8914/ 89147 92339 92339 90318 90165 92050 93077 94030 85197D RCL 1230 85197B 94030 85197A 90003 90003 92339 90131 91058 90270 RCL 82-037 90051 92169 92169 RCL 1145 RCL 1147 4791-9A 4791-9A 4791-9A RCL 82-014 RCL 1400 RCL 82-119 93199 86191A 86223B 92143
DSC DSC DSC DSC DSC HOM DSC DSC DSC DSC DSC DSC DSC DSC DSC DTA DTA DTA DSC DTA DSC DSC DSC DSC DSC DSC DTA DSC DSC HOM DTA DTA DSC DSC DSC DTA DTA DTA HOM DTA DTA DSC
REACTIVITY
NO EXO TO 350 C NO EXO TO 350 C NO EXO TO 250 C NO EXO TO 165 C EXOAT 190 C EXO AT 22 C NO EXO TO 250 C NO EXO TO 250 C EXOAT 195 C EXOAT 195 C NO EXO TO 200 C NO EXO TO 300 C NO EXO TO 194 C NO EXO TO 250 C EXOAT 120 C EXO AT 255 C NO EXO TO 250 C EXO AT 250 C EXO AT 320 C NO EXO TO 350 C EXO AT 125 C NO EXO TO 250 C EXOAT 186 C EXO AT 360 C NO EXO TO 150 C NO EXO TO 100 C NO EXO TO 100 C NO EXO TO 250 C NO EXO TO 200 C NO EXO AT 22 C NO EXO TO 350 C EXO AT 145 C EXO AT 25 C EXOAT 170C EXOAT 125 C NO EXO TO 500 C NO EXO TO 300 C NO EXO TO 200 C NO EXO TO 25 C NO EXO TO 375 C NO EXO TO 210 C NO EXO TO 250 C
14
TABLE I. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PROCESS CHEMICAL)
PROCESS CHEMICAL
SEALANT
PLANT
REF. NO. TEST
HYDROGEN CHLORIDE
HYDROGEN CHLORIDE
HYDROGEN CHLORIDE
HYDROGEN CHLORIDE
HYDROGEN CHLORIDE
HYDROGEN CHLORIDE
HYDROGEN CHLORIDE
HYDROGEN CHLORIDE (ANHYDROUS)
HYDROGEN CHLORIDE (ANHYDROUS)
HYDROGEN CHLORIDE (ANHYDROUS)
HYDROGEN CHLORIDE (ANHYDROUS)
HYDROGEN CHLORIDE (ANHYDROUS)
HYDROGEN CHLORIDE (ANHYDROUS)
HYDROGEN CHLORIDE (ANHYDROUS)
HYDROGEN CHLORIDE (ANHYDROUS)
HYDROGEN CHLORIDE (ANHYDROUS)
HYDROGEN CHLORIDE (ANHYDROUS)
HYDROGEN CHLORIDE (ANHYDROUS)
HYDROGEN CHLORIDE (ANHYDROUS)
HYDROGEN CHLORIDE (ANHYDROUS)
HYDROGEN CHLORIDE (ANHYDROUS)
HYDROGEN CHLORIDE (ANHYDROUS)
HYDROGEN CHLORIDE (ANHYDROUS)
HYDROGEN CHLORIDE (ANHYDROUS)
HYDROGEN CHLORIDE (ANHYDROUS)
HYDROGEN CHLORIDE (ANHYDROUS)
HYDROGEN CHLORIDE (ANHYDROUS)
HYDROGEN SULFIDE GAS
HYDROGEN SULFIDE GAS
HYDROGEN SULFIDE GAS
HYDROLYZER BOTTOMS
ISOPAR E
ISOPAR E
ISOPAR E
ISOPAR E
ISOPAR E
ISOPAR E
ISOPAR E
g
ISOPAR E
ZO
ISOPAR E
ISOPRENE
a
Ml, M2, M3.M4. + HCI
^
-t '-) r-4 O
FURMANITE FSC-6B
GLYCOL 2
SAFE SEAL CHEMOLA TEFLON
METHANES
SAFE SEAL - CHEMOLA TEFLON
METHANES
SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) METHANES
SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) METHANES
SAFE SEAL MULTIPAK (JOHN CRANE 6KB)
METHANES
SAFE SEAL MULTIPAK (JOHN CRANE 6KB)
METHANES
COOPER OIL TOOL DIVISION WKM NO. 114
VINYL 2
FURMANITE FSC-5B
VINYL 2
FURMANITE FSC-5B
VINYL 2
FURMANITE FSC-5C
VINYL 2
FURMANITE FSC-6B
VINYL 2
FURMANITE FSC-6B
VINYL 2
STEAM & PROCESS SP-1011
VINYL 2
STEAM & PROCESS SP-1011
VINYL 2
STEAM & PROCESS SP-102
VINYL 2
STEAM & PROCESS SP-102
VINYL 2
STEAM & PROCESS SP-2000
VINYL 1
STEAM & PROCESS SP-2007
VINYL 1
STEAM & PROCESS SP-CM
METHANES
TEAM LEAK REPAIRS SEALANT #1X
VINYL 2
TEAM LEAK REPAIRS SEALANT #1X
VINYL 2
TEAM LEAK REPAIRS SEALANT 2X
VINYL 2
TEAM LEAK REPAIRS SEALANT #2X
VINYL 2
TEAM LEAK REPAIRS SEALANT #6
VINYL 1
TEAM LEAK REPAIRS SEALANT DB-2
METHANES
TEAM LEAK REPAIRS VALVEPACK A
VINYL 1
STEAM & PROCESS SP-3100
LGTI
STEAM & PROCESS SP-770
LGTI
TEAM LEAK REPAIRS SEALANT 16X
LGTI
SYNTHO-GLASS NEPTUNE RESEARCH
GLYCOL 1
STEAM & PROCESS SP-325
POLY C
STEAM & PROCESS SP-325
POLY C
TEAM LEAK REPAIRS SEALANT #6
POLY C
TEAM LEAK REPAIRS SEALANT IX
POLY C
TEAM LEAK REPAIRS SEALANT 2X
POLY C
TEAM LEAK REPAIRS SEALANT 5G
POLY C
TEAM LEAK REPAIRS SEALANT DB 20
POLY C
TEAM LEAK REPAIRS SEALANT X-36
POLY C
TEAM LEAK REPAIRS VALVEPACK AX
POLY C
TEAM LEAK REPAIRS VALVEPACK AX
VECTOR
STEAM & PROCESS SP-325
METHANES
Dow Confidential
92143 94060 94060 94060 94060 94060 94060 93042 92146 93154 4791-29A 92146 93154 93154 93154 93154 93154 RCL 84-007 RCL 84-006 85133F 93154 93154 93154 93154 RCL 84-009 RCL 82-042 RCL 84-008 93022 93022 93032
91175 93215 93215 B7033G 87033D 87033E 87033F 87033H 870331 87033J 93069 93093
DSC HOM DSC HOM DSC HOM DSC DSC DSC HOM DSC DSC HOM DSC HOM DSC HOM DTA DTA DTA DSC HOM DSC HOM DTA DTA DTA DSC DSC DSC DSC DSC HOM DTA DTA DTA DTA DTA DTA DTA DSC DSC
REACTIVITY
NO EXO TO 250 C SL. EXO AT 22 C NO EXO TO 450 C SL. EXO AT 22 C EXO AT 360 C EXO AT 22 C NO EXO TO 325 C EXO AT 225 C NO EXO TO 250 C NO EXO AT 22 C NO EXO TO 70 C NO EXO TO 250 C SL. EXO AT 22 C NO EXO TO 200 C SL. EXO AT 22 C NO EXO TO 400 C SL. EXO AT 22 C NO EXO TO 200 C NO EXO TO 185 C NO EXO TO 250 C EXO AT 80 C SL. EXO AT 22 C EXOAT 117 C SL. EXO AT 22 C NO EXO TO 165 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 300 C NO EXO TO 300 C EXO AT 316 C NO EXO TO 150 C EXOAT 170 C NO EXO AT 22 C NO EXO TO 260 C NO EXO TO 260 C NO EXO TO 260 C NO EXO TO 260 C NO EXO TO 260 C NO EXO TO 260 C NO EXO TO 260 C NO EXO TO 200 C NO EXO TO 300 C
'5
TABLE I. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORT ED BY PROCESS CHEMICAL)
PROCESS CHEMICAL
SEALANT
PLANT
REF. NO. TEST
Ml, M2, M3, M4.+ HCI MEA.DEA.TEA.KOH (REACTOR EFFLUENT) METHANE METHANES E-259 VENT (HCI.M1.M2.M3) METHANES R-300 OUTLET (M1,M2,M3,M4,HCI) METHANOL METHANOL METHYL CHLORIDE METHYL CHLORIDE METHYL CHLORIDE METHYL CHLORIDE METHYL CHLORIDE METHYL CHLORIDE METHYL CHLORIDE METHYL CHLORIDE METHYL CHLORIDE METHYL CHLORIDE METHYL CHLORIDE METHYL CHLORIDE METHYL CHLORIDE + DIMETHYL ETHER METHYL CHLORIDE + DIMETHYL ETHER METHYL DIETHANOLAMINE METHYL DIETHANOLAMINE METHYL DIETHANOLAMINE METHYL DIETHANOLAMINE (LOC48) METHYLENE CHLORIDE METHYLENE CHLORIDE METHYLENE CHLORIDE METHYLENE CHLORIDE METHYLENE CHLORIDE METHYLENE CHLORIDE METHYLENE CHLORIDE METHYLENE CHLORIDE METHYLENE CHLORIDE METHYLENE CHLORIDE METHYLENE CHLORIDE METHYLENE CHLORIDE MONOETHYLENE GLYCOL MONOPROPYLENE GLYCOL + WATER MONOPROPYLENE GLYCOL WATER N-PROPANOL (50%) WATER (50%) NITROGEN
STEAM & PROCESS SP-325
METHANES
TEAM LEAK REPAIRS SEALANT #6
DOWANOLS
TEAM LEAK REPAIRS VALVEPACK B
LHC 2
SILASTIC 732-RTV SILICONE RUBBER
METHANES
STEAM & PROCESS SP-2600
METHANES
STEAM & PROCESS SP-1015
METHANES.
TEAM LEAK REPAIRS SEALANT DB-2
METHANES
755 STICK SEALANT
METHANES
SAFE SEAL - CHEMOLA TEFLON
METHANES
SAFE SEAL - CHEMOLA TEFLON
METHANES
SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) METHANES
SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) METHANES
SAFE SEAL MULTIPAK (JOHN CRANE 6KB)
METHANES
SAFE SEAL MULTIPAK (JOHN CRANE 6KB)
METHANES
STEAM & PROCESS SP-1360
METHANES
STEAM & PROCESS SP-2007
METHANES
STEAM & PROCESS SP-2026
METHANES
STEAM & PROCESS SP-CM
METHANES
TEAM LEAK REPAIRS SEALANT DB-2
METHANES
TEAM LEAK REPAIRS SEALANT #6
METHOCEL
TEAM LEAK REPAIRS SEALANT #6
METHOCEL
NICKEL ANTISEIZE
LGTI
NICKEL ANTISEIZE & PERMATEX
LGTI
PERMATEX
LGTI
STEAM & PROCESS SP-CM
LGTI
SAFE SEAL - CHEMOLA TEFLON
METHANES
SAFE SEAL - CHEMOLA TEFLON
METHANES
SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) METHANES
SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) METHANES
SAFE SEAL MULTIPAK (JOHN CRANE 6KB)
METHANES
SAFE SEAL MULTIPAK (JOHN CRANE 6KB)
METHANES
STEAM & PROCESS SP-103
METHANES
STEAM & PROCESS SP-1300
METHANES
STEAM & PROGESS SP-1360
METHANES
STEAM & PROCESS SP-2026
METHANES
STEAM & PROCESS SP-CM
METHANES
TEAM LEAK REPAIRS SEALANT DB-2
METHANES
FURMANITE FSC-6B
GLYCOL 2
TEAM LEAK REPAIRS SEALANT 1BX
GLYCOL 1
TEAM LEAK REPAIRS SEALANT 2X
GLYCOL 1
SEMSTONE 145-S
POLY B
STEAM & PROCESS SP-60
LGTI
Dow Confidential
93093 RCL 1270,71 86223E RCL 83-092 RCL 82-045 85173A RCL 82-041 91126 94060 94060 94060 94060 94060 94060 RCL 1578 84E156 85132A 85133B RCL 82-040 93196 93196 93098 93098 93098 4791-5A 94060 94060 94060 94060 94060 94060 RCL 1584 RCL 1582 RCL 1577 85132B 85133C RCL 82-038 92143 91146 91146 90146 4791-43A
HOM DTA DTA DTA DTA DTA DTA DSC HOM DSC HOM DSC HOM DSC DTA DTA DTA DTA DTA DSC HOM DSC DSC DSC DSC HOM DSC HOM DSC HOM DSC DTA DTA DTA DTA DTA DTA DSC DSC DSC DSC DSC
REACTIVITY
NO EXO AT 22 C NO EXO TO 300 C NO EXO TO 250 C NO EXO TO 200 C NO EXO TO 310 C NO EXO TO 225 C NO EXO TO 175 C NO EXO TO 175 C NO EXO AT 22 C EXO AT 375 C SL. EXO AT 22 C NO EXO TO 250 C SL. EXO AT 22 C NO EXO TO 250 C NO EXO TO 140 C NO EXO TO 150 C NO EXO TO 200 C NO EXO TO 250 C NO EXO TO 190 C NO EXO TO 190 C SL. EXO AT 22 C EXOAT 125 C EXOAT 160 C NO EXO TO 200 C NO EXO TO 250 C NO EXO AT 22 C EXO AT 228 C NO EXO AT 22 C EXO AT 335 C NO EXO AT 22 C EXOAT 120 C NO EXO TO 150 C NO EXO TO 150 C NO EXO TO 150 C NO EXO TO 200 C NO EXO TO 250 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 250 C EXO AT 350 C
On A 0 7 7 0 9 5
OONFTDFNTTAI
'-v.
16
TABLE I. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PROCESS CHEMICAL)
PROCESS CHEMICAL
SEALANT
PLANT
REF. NO. TEST
OIL BOTTOMS (T-102C TOWER)
TEAM LEAK REPAIRS SEALANT #6
PER/TET (CRUDE)
FURMANITE GASKET COATING (CL2)
PEIVTET (CRUDE)
TEAM LEAK REPAIRS SEALANT *10 + F-45 FIBER
PER/TET (CRUDE)
TEAM LEAK REPAIRS SEALANT #11
PER/TET (CRUDE)
TEAM LEAK REPAIRS VALVEPACK OX
POTASSIUM CARBONATE (22%) IN WATER
TEAM LEAK REPAIRS SEALANT #6
PROPANE
TEAM LEAK REPAIRS SEALANT #6
PROPANE
TEAM LEAK REPAIRS SEALANT X-36 A&B
PROPANE
TEAM LEAK REPAIRS VALVEPACK B
PROPYLENE
FURMANITE FSC-5B
PROPYLENE
FURMANITE FSC-5B
PROPYLENE
FURMANITE FSC-6B
PROPYLENE
FURMANITE FSC-6B
PROPYLENE
LOCTITE 290
PROPYLENE PROPYLENE
STEAM & PROCESS SP-1011 STEAM & PROCESS SP-1011
PROPYLENE PROPYLENE PROPYLENE PROPYLENE PROPYLENE PROPYLENE PROPYLENE PROPYLENE PROPYLENE PROPYLENE
STEAM & PROCESS SP-2000 STEAM & PROCESS SP-2000 TEAM LEAK REPAIRS SEALANT #2X TEAM LEAK REPAIRS SEALANT 2X TEAM LEAK REPAIRS SEALANT #2XH TEAM LEAK REPAIRS SEALANT #2XH TEAM LEAK REPAIRS SEALANT OB-20 TEAM LEAK REPAIRS VALVEPACK A TEAM LEAK REPAIRS VALVEPACK B TEAM LEAK REPAIRS VALVEPACK GX
PROPYLENE (2C-54 OVERHEAD)
LOCTITE 290
PROPYLENE + REGAL 32 OIL
FURMANITE FSC-46D
PROPYLENE REGAL 32 OIL
FURMANITE FSC-46D
PROPYLENE DICHLORIDE, 02, AIR. HCI, WATER (E-IB STEAM & PROCESS SP-1360
PROPYLENE DICHLORIDE. 02, AIR. HCI. WATER (E-IB STEAM & PROCESS SP-2026
PROPYLENE DICHLORIDE. CI2, AIR. HCI, WATER (E-IB TEAM LEAK REPAIRS SEALANT #11
PROPYLENE DICHLORIDE, 02. AIR. HCI. WATER (E-IB TEAM LEAK REPAIRS SEALANT D8-2
PROPYLENE GLYCOL PROPYLENE GLYCOL (2%) IN WATER PROPYLENE GLYCOL (2%) IN WATER PROPYLENE GLYCOL (2%) IN WATER PROPYLENE GLYCOL (2%) IN WATER
TEAM LEAK REPAIRS SEALANT #6 FURMANITE FSC-1/2A FURMANITE FSC-1/2A FURMANITE FSC-3A FURMANITE FSC-3A
PROPYLENE OXIDE
GRAFOIL VALVE PACKING
PROPYLENE OXIDE
TEAM LEAK REPAIRS SEALANT #6
PROPYLENE OXIDE DIMETHYL ETHER/ METHYL CL TEAM LEAK REPAIRS TC-4 (CURED)
PYGAS
FURMANITE FSC-6B
Dow Confidential
GLYCOL 1 SOLVENTS/EDC SOLVENTS/EDC SOLVENTS/EDC SOLVENTS/EDC GLYCOL 2 PROMIX LHC 3 LHC 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 LHC 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 1 VINYL 1 LHC 2 LHC 3 LHC 2 LHC 3 LHC 3 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1 METHOCEL LHC 3
4791-36B 91064 69228 89141 89141 91092 94071 92124 86223H 93154 93154 93154 93154 92148 93154 93154 93154 93154 93154 93154 93154 93154 84E195 B4E187 86223A 93207 92148 93164 93164 RCL 1561 RCL 1560 RCL 1558 RCL 1559 91199 92026 92026 92026 92026 84E068 88285 90324 91100
DSC DSC DSC DSC DSC DSC DSC DSC DTA DSC HOM DSC HOM DSC DSC HOM DSC HOM DSC HOM DSC HOM DTA DTA DTA DSC DSC DSC HOM DTA DTA DTA DTA DSC DSC HOM DSC HOM DTA DSC DSC DSC
REACTIVITY
NO EXO TO 190 C NO EXO TO 250 C EXO AT 245 C EXO AT 80 C EXOAT 145 C NO EXO TO 200 C NO EXO TO 178 C NO EXO TO 160 C NO EXO TO 300 C NO EXO TO 250 C NO EXO AT 22 C NO EXO TO 225 C NO EXO AT 22 C NO EXO TO 200 C NO EXO TO 250 C NO EXO AT 22 C NO EXO TO 250 C NO EXO AT 22 C NO EXO TO 250 C NO EXO AT 22 C NO EXO TO 250 C NO EXO AT 22 C NO EXO TO 250 C NO EXO TO 400 C NO EXO TO 210 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 210 C SL. EXO AT 22 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 190 C NO EXO TO 250 C NO EXO TO 200 C NO EXO AT 22 C NO EXO TO 200 C NO EXO AT 22 C NO EXO TO 235 C EXO AT 200 C EXOAT 120 C NO EXO TO 200 C
DO A 0 D 7 0 9 6
OONF TDFNT TAt
no A 0??097
rO NFTO FNTTAI
7
TABLE I. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PROCESS CHEMICAL)
PROCESS CHEMICAL
PYROLYSIS GAS PYROLYSIS GAS PYROLYSIS GASOLINE & RESIN OIL PYROLYSIS GASOLINE & RESIN OIL QUENCH LIQUOR QUENCH LIQUOR QUENCH LIQUOR QUENCH LIQUOR QUENCH LIQUOR QUENCH LIQUOR QUENCH LIQUOR QUENCH LIQUOR QUENCH LIQUOR QUENCH LIQUOR QUENCH OIL (C-10 BOTTOMS) QUENCH OIL (C-10 BOTTOMS) R-2 & R-102 HYDROLYZER BTMS RANDO 66 OIL RANDO 6B OIL RANDO 68 OIL REGAL 32 OIL REGAL OIL 32 RESIN OIL RESIN OIL SHELL THERMIA C CHL WITH DISSOLVED HCL SHELL THERMIA OIL C SHELL THERMIA OIL C SILICONE SWS-101 SILICONE SWS-101 SILICONE SWS-101 SIMULATED VENT GAS SIMULATED VENT GAS SLAG (LOC 37B) SLAG(LOC37B) SLAG WATER (LOC 37) SLAG WATER (LOC 37) SODIUM HYDROXIDE (10%) SODIUM HYDROXIDE (10%) SODIUM HYDROXIDE (10%) SODIUM HYDROXIDE (10%) SODIUM HYDROXIDE (10%) SODIUM HYDROXIDE (10%)
SEALANT
PLANT
ROYAL PURPLE BARRIER FLUID 22
LHC 3
ROYAL PURPLE BARRIER FLUID 22
LHC 3
TEAM LEAK REPAIRS SEALANT #6
LHC 3
TEAM LEAK REPAIRS SEALANT X36 A&B
LHC 3
FURMANITE FSC-6B
VINYL 2
FURMANITE FSC-6B
VINYL 2
STEAM 4 PROCESS SP-1011
VINYL 2
STEAM & PROCESS SP-1011
VINYL 2
STEAM & PROCESS SP-325
VINYL 2
STEAM & PROCESS SP-325
VINYL 2
TEAM LEAK REPAIRS SEALANT #2X
VINYL 2
TEAM LEAK REPAIRS SEALANT #2X
VINYL 2
TEAM LEAK REPAIRS SEALANT #6
VINYL 2
TEAM LEAK REPAIRS SEALANT *6
VINYL 2
FURMANITE FSC-5B
LHC 3
FURMANITE FSC-6B
LHC 3
STEAM & PROCESS SP-2000
GLYCOL 1
STEAM & PROCESS SP-2000
POLY A
STEAM & PROCESS SP-2021
POLYA
STEAM & PROCESS SP-325
POLYA
TEAM LEAK REPAIRS SEALANT #6
LHC 3
SEAL-ITT +34
CHLORINE
ROYAL PURPLE BARRIER FLUID 22
LHC 3
ROYAL PURPLE BARRIER FLUID 22
LHC 3
ULTRAMETAL LIQUID METAL (CURED)
METHANES
STEAM A PROCESS SP-1011
METHANES
STEAM & PROCESS SP-109
METHANES
SAFE SEAL - CHEMOLA TEFLON
LHC 2
SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) LHC 2
SAFE SEAL MULTIPAK (JOHN CRANE 6KB)
LHC 2
TEAM LEAK REPAIRS SEALANT DB-22
VINYL 2
TEAM LEAK REPAIRS SEALANT DB-22
VINYL 2
STEAM & PROCESS SP-102
LGTI
STEAM & PROCESS SP-60
LGTI
TEAM LEAK REPAIRS VALVEPACK AX
LGTI
TEAM LEAK REPAIRS VALVEPACK AX
LGTI
FURMANITE FSC-1/2A
LHC 3
FURMANITE FSC-1/2A
LHC 3
FURMANITE FSC-1/2A
LHC 3
FURMANITE FSC-6B
LHC 3
FURMANITE FSC-6B
LHC 3
FURMANITE FSC-6B
LHC 3
Dow Confidential
REF. NO.
92169 92169 92124 92124 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 91363 91363 89378 93210 93210 93210 90034 90277 92169 92169 93028 90400 90400 94038 94038 94038 92302 92302 4791-6A 4791-6A 94065 94065 92093 92093 92093 92093 92093 92093
TEST
DSC HOM DSC DSC DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM DSC DSC DSC DSC DSC DSC DSC DSC DSC HOM DSC DSC DSC DSC DSC DSC DSC HOM DSC DSC DSC HOM HOM DSC HOM HOM DSC HOM
REACTIVITY
NO EXO TO 200 C NO EXO AT 22 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 250 C NO EXO TO 200 C EXO AT 36 C NO EXO TO 200 C NO EXO TO 250 C EXOAT 165 C NO EXO TO 200 C NO EXO AT 22 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 250 C EXOAT 126 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 120 C NO EXO AT 22 C NO EXO TO 235 C NO EXO TO 235 C NO EXO TO 250 C NO EXO AT 22 C NO EXO AT 25 C EXOAT 165 C NO EXO AT 22 C NO EXO AT 25 C NO EXO TO 200 C NO EXO AT 22 C
18
TABLE I. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PROCESS CHEMICAL)
PROCESS CHEMICAL
SEALANT
PLANT
REF. NO. TEST
SODIUM HYDROXIDE (10%)
SODIUM HYDROXIDE (10%)
SODIUM HYDROXIDE (10%)
SODIUM HYDROXIDE (10%)
SODIUM HYDROXIDE (10%)
SODIUM HYDROXIDE (10%)
SODIUM HYDROXIDE (3%)
SODIUM HYDROXIDE (40%) - HE-201
SODIUM HYDROXIDE (50%)
SODIUM HYDROXIDE (50%)
SODIUM HYDROXIDE (50%)
SODIUM HYDROXIDE (50%)
SODIUM HYDROXIDE (50%)
SODIUM HYDROXIDE (50%)
SODIUM HYDROXIDE (50%)
SODIUM HYDROXIDE (50%)
SODIUM HYDROXIDE (50%)
SODIUM HYDROXIDE (50%)
SODIUM HYOROXIDE (50%) + AMMONIA
SODIUM HYOROXIDE (50%) * AMMONIA
SODIUM HYDROXIDE (50%) NH40H
SOUR CONDENSATE
SS. CAST FE, CU. HAST, GRAPHITE, H20
STYRENE
SULFUR (LOC 24)
SULFUR (LOC 24)
SULFUR (LOC 24)
SULFURIC ACID
SULFURIC ACID (96%)
SULFURIC ACID (96%)
SULFURIC ACID (96%)
SULFURIC ACID (96%)
SULFURIC ACID (96%)
SULFURIC ACID SOLUTION (10N)
SULFURIC ACID SOLUTION (10 N)
SULFURIC ACID SOLUTION (10N)
SULFURIC ACID SOLUTION (10N)
SYNGAS
0
SYNGAS SYNGAS
b3 ^
SYNGAS SYNGAS
-t T> ^0
Z -O --( \)
o
PIG REPAIR PUTTY EPOXY STICK PIG REPAIR PUTTY EPOXY STICK SEAL-ITT #34 STEAM & PROCESS SP-1011 STEAM & PROCESS SP-2000 STEAM & PROCESS SP-60 SEMSTONE 145-S STEAM & PROCESS SP-5000 BELZONA CERAMIC-R METAL BELZONA E-METAL BELZONA SUPER METAL SERVICE GROUP INC 107 A&B BONDER STEAM & PROCESS SP-1011 STEAM & PROCESS SP-1015 STEAM & PROCESS SP-60 TEAM LEAK REPAIRS SEALANT #16 TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS SEALANT 2X TEAM LEAK REPAIRS SEALANT #16 TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS TC-4 EPOXY BONDER TEAM LEAK REPAIRS SEALANT #6 DOW CORNING 111 LUB/SEALANT TEAM LEAK REPAIRS VALVEPACK AX STEAM & PROCESS SP-1011 STEAM & PROCESS SP-102 STEAM & PROCESS SP-60 TEAM LEAK REPAIRS SEALANT DB-2 BELZONA CERAMIC-R METAL BELZONA E-METAL BELZONA SUPER METAL STEAM & PROCESS SP-2007 STEAM & PROCESS SP-2026 GRAFOIL GHE GASKET GRAPHITE MAT'L GRAFOIL GHE GASKET GRAPHITE MAT'L GRAFOIL GHE GASKET METAL MAT! GRAFOIL GHE GASKET METAL MAT'L NEPTUNE RESEARCH SYNTHO-GLASS STEAM & PROCESS SP-3000 STEAM & PROCESS SP-429 TEAM LEAK REPAIRS SEALANT 18X TEAM LEAK REPAIRS SEALANT 19X
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CAUSTIC CAUSTIC CHLORINE CHLORINE CHLORINE CHLORINE POLY B CAUSTIC CHLORINE CHLORINE CHLORINE CAUSTIC METHANES DOWANOLS CHLOR-ALKALI 2 CAUSTIC CAUSTIC CAUSTIC CAUSTIC CAUSTIC CAUSTIC LGTI LHC 3 VECTOR LGTI LGTI LGTI METHANES CHLORINE CHLORINE CHLORINE CHLOR-ALKALI 2 CHLOR-ALKALI 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 LGTI LGTI LGTI LGTI LGTI
92137 92137 90277 92180 92180 92180 90146 4791-30B 85172F 84E180 85172C 89223 RCL 1146 RCL 1233 92326 RCL 1008 RCL1005 871121 RCL 1009 RCL 1006 RCL 1368 870901 89271 93069 4791-5A 4791-5A 4791-5A RCL 82-044 85172E 84E213 85172B 851018 85101A 93011 93011 93011 93011 93036 93125 93125 92318 92316
DSC HOM DSC DSC DSC DSC DSC DSC DTA DTA DTA DSC DTA DTA DSC DTA DTA DSC DTA DTA DTA 0SC DSC DSC DSC DSC DSC DTA DTA DTA DTA DTA DTA DSC HOM DSC HOM DSC DSC DSC DSC DSC
REACTIVITY
EXOAT 150 C NO EXO AT 25 C EXO AT 166 C EXOAT 180 C EXOAT 170 C EXOAT 194 C EXOAT 155 C EXO AT 90 C NO EXO TO 250 C EXOAT 150 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 295 C NO EXO TO 250 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 230 C NO EXO TO 190 C NO EXO TO 200 C NO EXO TO 200 C EXO AT 85C NO EXO TO 250 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 200 C EXO AT 45 C NO EXO TO 250 C EXO < 30 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 250 C NO EXO AT 22 C EXOAT 137 C NO EXO TO 250 C NO EXO TO 500 C NO EXO TO 500 C NO EXO TO 285 C NO EXO TO 400 C NO EXO TO 400 C
'9
TABLE I. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PROCESS CHEMICAL)
PROCESS CHEMICAL
SEALANT
PLANT
REF. NO. TEST
SYNGAS SYNGAS SYNGAS SYNGAS SYNGAS SYNGAS BLEND SYNGAS BLEND SYNGAS BLEND T-52 BTMS T-8-2 BOTTOMS TET, PER. HCE, HCI, CHLORINE 1,1,1 -TRICHLOROETHANE 1,1,1 -TRICHLOROETHANE TRIETHANOLAMINE TRIETHANOLAMINE TRIETHANOLAMINE VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIDE (80%) ANHYDROUS HCI (20%) VINYL CHLORIDE (80%) + ANHYDROUS HCI (20%) VINYL CHLORIDE (80%) + ANHYDROUS HCI (20%) VINYL CHLORIDE (80%) + ANHYDROUS HCI (20%)
TEAM LEAK REPAIRS SEALANT 2X TEAM LEAK REPAIRS SEALANT 2XH TEAM LEAK REPAIRS SEALANT RF 300 TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK EPX STEAM & PROCESS SP-1011 STEAM & PROCESS SP-102 STEAM & PROCESS SP-60 TEAM LEAK REPAIRS SEALANT #6 & F-14 FIBERS FURMANITE FSC-5B TEAM LEAK REPAIRS CURED HI-PRO C5A FEL PRO NO. 725 NICKEL ANTISEIZE MOLYKOTE 44 LUBRICANT STEAM & PROCESS SP-1011 STEAM & PROCESS SP-2000 FURMANITE FSC-46D FURMANITE FSC-46D FURMANITE FSC-5C FURMANITE FSC-5C FURMANITE FSC-6B FURMANITE FSC-6B STEAM & PROCESS SP-1011 STEAM S PROCESS SP-1011 STEAM & PROCESS SP-2000 STEAM & PROCESS SP-2000 STEAM & PROCESS SP-2007 STEAM & PROCESS SP-325 STEAM & PROCESS SP-325 STEAM & PROCESS SP-429 TEAM LEAK REPAIRS SEALANT #11 TEAM LEAK REPAIRS SEALANT #2X TEAM LEAK REPAIRS SEALANT #2X TEAM LEAK REPAIRS SEALANT #2XH TEAM LEAK REPAIRS SEALANT #2XH TEAM LEAK REPAIRS SEALANT DB-20 TEAM LEAK REPAIRS VALVEPACK A TEAM LEAK REPAIRS VALVEPACK B FURMANITE FSC-46D FURMANITE FSC-46D FURMANITE FSC-5C FURMANITE FSC-5C
LGTI LGTI LGTI LGTI LGTI LGTI LGTI LGTI GLYCOL 2 GLYCOL 2 SOLVENTS/EDC POWER 1 POWER 1 GLYCOL 2 GLYCOL 2 GLYCOL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 1 VINYL 2 VINYL 2 METHANES VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 1 VINYL 1 VINYL 1 VINYL 2 VINYL 2 VINYL 2 VINYL 2
93123 93123 93072 92318 92318 4791-42A 4791-43A 4791-43A 92160 93131 91050 89050 89050 94030 94030 94030 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 3108-46 93154 93154 93179 93147 93154 93154 93154 93154 84E196 3108-46 3108-46 93154 93154 93154 93154
DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM DTA DSC HOM DSC DSC DSC HOM DSC HOM DTA DTA DTA DSC HOM DSC HOM
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REACTIVITY
EXO AT 362 C NO EXO TO 500 C NO EXO TO 500 C NO EXO TO 400 C NO EXO TO 400 C EXO AT 47 C EXOAT 160 C EXO AT 365 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 250 C EXOAT 125 C EXOAT 133 C EXO AT 240 C EXO AT 320 C EXO AT 319 C NO EXO TO 300 C NO EXO AT 22 C NO EXO TO 300 C NO EXO AT 22 C EXOAT 149 C SL. EXO AT 22 C NO EXO TO 350 C SL. EXO AT 22 C NO EXO TO 200 C SL. EXO AT 22 C NONE NO EXO TO 220 C NO EXO AT 22 C EXOAT 114 C EXOAT 135 C EXO AT 336 C NO EXO AT 22 C EXO AT 264 C NO EXO AT 22 C NO EXO TO 225 C NONE NONE NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 250 C NO EXO AT 22 C
DO A 0 ? ? 0 9 9
OONFTDFNT TAl
TABLE I. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PROCESS CHEMICAL)
PROCESS CHEMICAL
SEALANT
PLANT
REF. NO. TEST
VINYL CHLORIDE (80%) + ANHYDROUS HCI (20%)
VINYL CHLORIDE (80%) + ANHYDROUS HCI (20%)
VINYL CHLORIDE (80%) + ANHYDROUS HCI (20%)
VINYL CHLORIDE (80%) + ANHYDROUS HCI (20%)
VINYL CHLORIDE (80%) ANHYDROUS HCI (20%)
VINYL CHLORIDE (80%) ANHYDROUS HCI (20%)
VINYL CHLORIDE (80%) + ANHYDROUS HCI (20%)
VINYL CHLORIDE (80%) + ANHYDROUS HCI (20%)
VINYL CHLORIDE (80%) + ANHYDROUS HQ (20%)
VINYL CHLORIDE (80%) + ANHYDROUS HCI (20%)
VINYL CHLORIDE (80%) + ANHYDROUS HQ (20%)
WASTE WATER EFFLUENT (P-5)
WATER (COOLING TOWER)
WATER (E7F)
WATER (E7F)
WATER (LOCT-144)
WATER (LOCT-144)
WATER WITH <1% GLYCOLS
WATER/STEAM
WATER/STEAM
WATER/STEAM
WATER/STEAM
WATER/STEAM
WATER/STEAM
WATER/STEAM
WATER/STEAM
WATER/STEAM
WATER/STEAM
WATER/STEAM
WATER/STEAM
WATER/STEAM
WATER/STEAM
WATER/STEAM
WATER/STEAM WATER/STEAM
0 b5
WATER/STEAM
WATER/STEAM WATER/STEAM
rj ^ ^0
WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM
Z^ ^
Eg
STEAM & PROCESS SP-1011 STEAM & PROCESS SP-1011 STEAM & PROCESS SP-325 STEAM & PROCESS SP-325 TEAM LEAK REPAIRS SEALANT 18X TEAM LEAK REPAIRS SEALANT K18X TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS SEALANT #6 + F-14 FIBER TEAM LEAK REPAIRS SEALANT D8-20 TEAM LEAK REPAIRS VALVEPACK A TEAM LEAK REPAIRS SEALANT 18X STERLING STUFFING BOX SEALANT #1 TEAM LEAK REPAIRS 16X 4 F-10 4 F-14 FIBERS TEAM LEAK REPAIRS SEALANT 16X 4 F-10 FIBERS STEAM 4 PROCESS SP-102 STEAM 4 PROCESS SP-60 STEAM 4 PROCESS SP-1011 COPALTITE CEMENT SEALANT FURMANITE FSC-1/2A FURMANITE FSC-1/2A FURMANITE FSC-11C FURMANITE FSC-3A FURMANITE FSC-6B FURMANITE FSC-6B FURMANITE FSC-7C PLIDCO S.P. SEALANT (J-STICK) SERVICE GROUP INC SG-101 LIQUID SERVICE GROUP INC SG-101 SOLID SERVICE GROUP INC SG-101HT SERVICE GROUP INC SG-102 SOLID SERVICE GROUP INC SG-106 LIQUID SERVICE GROUP INC SG-108 A4B SERVICE GROUP INC SG-109 SERVICE GROUP INC SG-110 SOLID SERVICE GROUP INC SG-113 SERVICE GROUP INC SG-201 SERVICE GROUP INC SG-201HT SERVICE GROUP INC SG-250 SERVICE GROUP INC SG-302 SERVICE GROUP INC SG-303 SERVICE GROUP INC SG-304
VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 1 VINYL 1 VINYL 1 GLYCOL 1 LHC 3 GLYCOL 2 GLYCOL 2 LGTI LGTI GLYCOL 2 LHC 3 VINYL 2 VINYL 2 LHC 3 LHC 3 LHC 3 VINYL 2 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3
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93154 93154 93154 93154 93154 93154 93154 93154 RCL 83-096 RCL 83-097 B4E191 90264 91135 92160 92160 4791-5A 4791-5A 92194 4792-25A 93154 93154 93020 90312 91052 93154 90312 4792-25A 89272 89272 89272 89272 89272 89272 89272 89272 89272 89272 89272 89272 89272 89272 89272
DSC HOM DSC HOM DSC HOM DSC HOM DTA DTA DTA DSC DSC DSC DSC DSC DSC DSC DSC DSC HOM DSC DSC DSC HOM DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC
REACTIVITY
EXOAT 178 C NO EXO AT 22 C NO EXO TO 250 C SL. EXO AT 22 C NO EXO TO 250 C SL. EXO AT 22 C NO EXO TO 250 C SL. EXO AT 22 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 400 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 260 C NO EXO TO 250 C NO EXO TO 250 C EXOAT 130 C NO EXO TO 300 C NO EXO AT 22 C NO EXO TO 285 C NO EXO TO 360 C NO EXO TO 400 C NO EXO AT 22 C NO EXO TO 320 C EXO AT 339 C NO EXO TO 320 C EXOAT 117 C NO EXO TO 350 C NO EXO TO 330 C NO EXO TO 340 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 275 C EXO AT 185 C EXO AT 75 C EXO AT 125 C NO EXO TO 325 C NO EXO TO 350 C EXO AT 260 C NO EXO TO 325 C
PROCESS CHEMICAL
WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM ZEROL 300 OIL
Q -D ZO n -4 X> o T| O Z v>
-t \)
--I -* >O
1
TABLE I. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PROCESS CHEMICAL)
SEALANT
PLANT
REF. NO. TEST
SERVICE GROUP INC SG-306 SERVICE GROUP INC SG-312 SERVICE GROUP INC SGC FIBER SERVICE GROUP INC SGK FIBER STEAM & PROCESS SP-1011 STEAM & PROCESS SP-1011 STEAM & PROCESS SP-102 STEAM & PROCESS SP-102 STEAM & PROCESS SP-2000 STEAM & PROCESS SP-2000 STEAM & PROCESS SP-2015 STEAM & PROCESS SP-2511 TEAM LEAK REPAIRS SEALANT #1 TEAM LEAK REPAIRS SEALANT #18X TEAM LEAK REPAIRS SEALANT #10X TEAM LEAK REPAIRS SEALANT K2X TEAM LEAK REPAIRS SEALANT 2X TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS SEALANT 18X TEAM LEAK REPAIRS SEALANT 2X TEAM LEAK REPAIRS SEALANT 2XH TEAM LEAK REPAIRS SEALANT PRI-102C TEAM LEAK REPAIRS SEALANT SW TEAM LEAK REPAIRS VALVEPACK A TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK EPX WHITE BAKERSEAL SEALANT TEAM LEAK REPAIRS PRI-102C (THREADS)
LHC 3 LHC 3 LHC 3 LHC 3 METHANES VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 CHLOR-ALKALI 2 METHANES METHANES VINYL 2 VINYL 2 VINYL 2 VINYL 2 GLYCOL 1 VINYL 2 GLYCOL 1 CAUSTIC GLYCOL 1 LGTI VINYL 2 VINYL 1 DOWANOLS POWER 2 LHC 3 POLYA
89272
DSC
09272
DSC
89272
DSC
89272
DSC
90037
DSC
93154
HOM
93154
DSC
93154
HOM
93154
DSC
93154
HOM
84E134
DTA
86060A
DTA
RCL 83-017 DTA
93154
DSC
93154
HOM
93154
DSC
93154
HOM
90041
DSC
93154
HOM
RCL-90-2661 DSC
871122
DSC
91159
DSC
93088
DSC
93075
DSC
RCL 83-018 DTA
94015
DSC
91152
DSC
4792-25A DSC
91028
DSC
REACTIVITY
NO EXO TO 290 C NO EXO TO 350 C NO EXO TO 325 C NO EXO TO 325 C NO EXO TO 300 C NO EXO AT 22 C NO EXO TO 300 C NO EXO AT 22 C NO EXO TO 325 C NO EXO AT 22 C NO EXO TO 250 C NO EXO TO 275 C NO EXO TO 150 C NO EXO TO 300 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 335 C NO EXO AT 22 C NO EXO TO 308 C NO EXO TO 285 C NO EXO TO 300 C NO EXO TO 230 C NO EXO TO 275 C NO EXO TO 150 C NO EXO TO 315 C NO EXO TO 350 C EXO AT 360 C NO EXO TO 250 C
Dow Confldential
TABLE II. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY SEALANT)
SEALANT
PROCESS CHEMICAL
PLANT
REF. NO. TEST
3M NEOPRENE 80 CONTACT ADHESIVE
3M NEOPRENE 80 CONTACT ADHESIVE
755 STICK SEALANT
ANCHOR VALVE PACKING 375
ANCHOR VALVE PACKING 4205
BELZONA CERAMIC-R METAL
BELZONA CERAMIC-R METAL
BELZONA CERAMIC-R METAL
BELZONA E-METAL
BELZONA E-METAL
BELZONA E-METAL
BELZONA SUPER METAL
BELZONA SUPER METAL
BELZONA SUPER METAL
C5A FEL PRO
C5A FEL PRO
CASTROL BRAYCOTE 1728
CELL PUTTY
CHEMRAZ O-RING MATERIAL
CHESTERTON 810 STEEL PUTTY (CURED)
CHESTERTON 810 STEEL PUTTY (CURED)
CHESTERTON 858 PUTTY - PARTS A A B
CHESTERTON 858 STEEL PUTTY (CURED)
CHESTERTON 858 STEEL PUTTY (CURED)
CHRYSOTILE ASBESTOS FIBER GSKT
CONLEY TEFLON PASTE
COOPER OIL TOOL DIVISION WKM NO. 114
COOPER OIL TOOL DIVISION WKM NO. 114
COPALTITE CEMENT SEALANT
COPALTITE HIGH TEMPERATURE SEALANT
CPE-TAC
CUREO AVANTIAV-202 MULTIGROUT
CURED AVANTI AV-220 MULTIGROUT
CURED DB 22
D.E.fl. 331 EPOXY RESIN
DERAKANE 470 (CURED 6/14/88)
DOW CORNING 111 LUB/SEALANT O DOW CORNING 3120 RTV SEALANT ^ ^
DOW CORNING 44 LUBRICANT EO062 O-RING MATERIAL
^^
EPR EO 862 *0*-RING EPR EO 962 -O'-RING
^O 5 "O
T> O " \)
ETHYLENE OXIDE ETHYLENE OXIDE METHYL CHLORIDE CHLORINE CHLORINE CHLORINE SODIUM HYDROXIDE (50%) SULFURIC ACID (96%) CHLORINE SODIUM HYDROXIDE (50%) SULFURIC ACID (96%) CHLORINE SODIUM HYDROXIDE (50%) SULFURIC ACID (96%) 1,1,1 -TRICHLOROETHANE CITRIKLEEN DEGREASER CHLORINE (LIQUID) CHLORINE ETHYLENE OXIDE CARBON TETRACHLORIDE (CRUDE. 93%) CARBON TETRACHLORIDE (CRUDE. 93%) CRACKED GAS (2C-50B) CARBON TETRACHLORIDE (CRUDE. 93%) CARBON TETRACHLORIDE (CRUDE. 93%) CHLORINE CHLORINE ETHYLENE DICHLORIDE HYDROGEN CHLORIDE (ANHYDROUS) WATER/STEAM CHLORINE (LIQUID) CHLORINE (TRACE WATER. HCBD) DITCHWATER (LHC 2 & LGTI) DITCHWATER (LHC2 & LGTI) HO (50%) + CHLORINE (50%) FLIGHTGARD 2006 CHLORINE VENT GAS SS, CAST FE. CU. HAST. GRAPHITE. H20 CHLORINE (LIQUID) ANHYDROUS AMMONIA ETHYLENE OXIDE DOWANOLEB DOWANOL PM
Dow ConlkJanUal
GLYCOL 2 GLYCOL 2 METHANES CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE POWER 1 POWER 1 CHLORINE CHLOR-ALKALI 2 GLYCOL 2 SOLVENTS/EDC SOLVENTS/EDC LHC 2 SOLVENTS/EDC SOLVENTS/EDC CHLORINE CHLORINE VINYL 2 VINYL 2 LHC 3 CHLORINE CHLORINE LHC 3 LHC 3 SOLVENTS/EDC GLYCOL 2 CHLORINE LHC 3 CHLORINE OOWANOLS GLYCOL 2 DOWANOLS DOWANOLS
93034 93034 91126 84E138 B4E005 85172D 85172F 85172E 84E184 84E180 84E213 85172A 85172C 85172B 89050 89050 ARC 91-585 ARC 91-647 89147 92298 92298 92104 92298 92298 90022 RCL 83-004 93042 93042 4792-25A ARC 94-851 84E211 871171 871172 4791-9A 90270 4792-21A 89271 ARC 94-848 93121 89147 92339 92339
DSC HOM DSC DSC DTA DTA DTA DTA DTA DTA DTA DTA DTA DTA DSC DSC ARC ARC DSC DSC HOM DSC DSC HOM DSC DTA DSC DSC DSC ARC DTA DSC DSC DSC DSC DSC DSC ARC DSC DSC DSC DSC
REACTIVITY
EXOAT 190 C EXO AT 22 C NO EXO TO 175 C EXO < 30 C EXO AT 136 C EXO AT 35 C NO EXO TO 250 C NO EXO TO 250 C EXO < 25 C EXOAT 150 C EXO < 30 C EXO AT 30 C NO EXO TO 250 C NO EXO TO 250 C EXOAT 125 C NO EXO TO 300 C EXOAT 167 C EXO AT 86 C NO EXO TO 250 C NO EXO TO 150 C NO EXO AT 22 C NO EXO TO 150 C NO EXO TO 150 C NO EXO AT 22 C NO EXO TO 250 C EXOAT 100 C NO EXO TO 310 C EXO AT 225 C EXO AT 130 C EXO AT113 C EXOAT 135 C NO EXO TO 200 C NO EXO TO 200 C EXO AT 25 C NO EXO TO 100 C EXO AT 30 C NO EXO TO 250 C EXO AT 36 C NO EXO TO 130 C NO EXO TO 250 C NO EXO TO 210 C NO EXO TO 250 C
5
SEALANT
FURMANITE GASKET COATING (CL2) GARLOCK 900 GASKET GARLOCK VALVE PACKING 6130 GARLOCK VALVE PACKING 7130 GORTEX GR GASKET GORE PACKING PTFE W/ GRAPHITE GORTEX PTFE GORTEX SEALANT (TEFLON) GRAFOIL GHE GRAFOIL GHE GRAFOIL GHE GRAFOIL GHE GASKET GRAPHITE MATL GRAFOIL GHE GASKET GRAPHITE MAT'L GRAFOIL GHE GASKET METAL MAT L GRAFOIL GHE GASKET METAL MATL GRAFOIL QHR GRAFOIL VALVE PACKING GRAPHONICS GASKET GRAPHONICS GASKET (ADHESIVE STRIP) IPI EPOXY (CURED) JOHN CRANE VALVE PKG C-1050 JOHN CRANE VALVE PKG C-60 JOHN CRANE VALVE PKG C-7762 JOHN MANSVILLE VALVE PKG AF-5331 KADEL SN N-75 SEALANT KLINGER K-61 GASKET LAMONS SPIROSEAL GSKT (GRAPHITE) LOCTITE #58747 PST LOCTITE #59231 (WITH TEFLON) LOCTITE 271 ADHESIVE/SEALANT LOCTITE 290 LOCTITE 290 MOLYKOTE 44 LUBRICANT MOLYKOTE 44 LUBRICANT NEPTUNE RESEARCH SYNTHO-GLASS NICKEL ANTISEIZE NICKEL ANTISEIZE & PERMATEX NICKEL ANTISEIZE (NO. 725) NICKEL ANTISEIZE (NO. 725) PARKER HANNIFIN VALVE PKG 2287-BR PARKER HANNIFIN VALVE PKG 22B7-GL PERMATEX
TABLE II. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY SEALANT)
PROCESS CHEMICAL
PLANT
REF. NO. TEST
PEFVTET (CRUDE) CHLORINE (LIQUID) CHLORINE CHLORINE CHLORINE (LIQUID) CHLORINE CHLORINE CHLORINE CHLORINE (LIQUID) ETHYL CHLORIDE ETHYLENE OXIDE SULFURIC ACID SOLUTION (10 N) SULFURIC ACID SOLUTION (10N) SULFURIC ACID SOLUTION (10 N) SULFURIC ACID SOLUTION (10N) ETHYL CHLORIDE PROPYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE CHLORINE VENT GAS CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE (LIQUID) CHLORINE (LIQUID) ETHYLENE OXIDE REACTOR OUTLET GAS CHLORINE CHLORINE CHLORINE PROPYLENE PROPYLENE (2C-54 OVERHEAD) ETHYLENE GLYCOL TRIETHANOLAMINE SYNGAS METHYL DIETHANOLAMINE METHYL DIETHANOLAMINE 1,1,1 -TRICHLOROETHANE CITRIKLEEN DEGREASER CHLORINE CHLORINE METHYL DIETHANOLAMINE
SOLVENTS/EDC CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE SOLVENTS/EDC CHLORINE CHLORINE GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 1 GLYCOL 1 GLYCOL 2 CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE GLYCOL 2 CHLOR-ALKALI 2 CHLOR-ALKALI 2 CHLOR-ALKALI 2 LHC 2 LHC 2 GLYCOL 2 GLYCOL 2 LGTI LGTI LGTI POWER 1 POWER 1 CHLORINE CHLORINE LGTI
91064
DSC
ARC 92-737 ARC
84E007
DTA
84E008
DTA
ARC 93-771 ARC
86206A
DTA
85136A
DTA
ARC 91-616 ARC
ARC 91-586 ARC
90311
DSC
90165
DSC
93011
DSC
93011
HOM
93011
DSC
93011
HOM
90311
DSC
84E068
DTA
92050
DSC
93077
DSC
4792-21A DSC
84E141
DSC
B4E140
DSC
84E003
DTA
84E144
DTA
RCL-93-9809 ARC
ARC 92-736 ARC
90131
DSC
90282
DSC
90282
ARC
89071
DSC
92148
DSC
92148
DSC
94030
DSC
94030
DSC
93036
DSC
93098
DSC
93098
DSC
89050
DSC
89050
DSC
84E142
DSC
84E143
DSC
93098
DSC
Dow Confidential
REACTIVITY
NO EXO TO 250 C EXO AT 26 C EXO AT -83 C EXO AT -76 C NO EXO TO 175 C NO EXO TO 200 C NO EXO TO 250 C NO EXO TO 200 C EXOAT 104 C NO EXO TO 250 C NO EXO TO 300 C NO EXO TO 250 C NO EXO AT 22 C EXOAT 137 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 235 C NO EXO TO 194 C NO EXO TO 250 C NO EXO TO 250 C EXO AT 36 C EXO AT 46 C EXOAT 102 C EXO < 30 C EXOAT 182 C EXO AT 27 C EXO AT 360 C EXOAT 115 C EXOAT 33 C EXO AT -5 C NO EXO TO 200 C NO EXO TO 200 C EXO AT 265 C EXO AT 240 C NO EXO TO 500 C EXOAT 125 C EXOAT 160 C EXOAT 133 C EXO AT 78 C EXO < 30 C EXO AT 38 C NO EXO TO 200 C
DO A 0 ? ? 1 0 3
CONFTDFNTTAl
26
TABLE II. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY SEALANT)
SEALANT
PROCESS CHEMICAL
PLANT
REF. NO. TEST
PERMATEX FORM-A-GASKET 2 (CURED)
CHLORINE (LIQUID)
PIG REPAIR PUTTY EPOXY STICK
SODIUM HYDROXIDE (10%)
PIG REPAIR PUTTY EPOXY STICK
SODIUM HYDROXIDE (10%)
PLIDCO S.P. SEALANT (J-STICK)
WATER/STEAM
PROTECTO-COAT BOO G
BRINE INTO AT-260
PROTECTO-COAT 800 G
BRINE OUT AT-260
PTFE/KEVLAR
CHLORINE
RED PRIMER (CURED)
CHLORINE VENT GAS
ROYAL PURPLE BARRIER FLUID 22
1,3-BUTADIENE
ROYAL PURPLE BARRIER FLUID 22
1,3-BUTADIENE
ROYAL PURPLE BARRIER FLUID 22
BENZENE
ROYAL PURPLE BARRIER FLUID 22
BENZENE
ROYAL PURPLE BARRIER FLUID 22
FUEL OIL
ROYAL PURPLE BARRIER FLUID 22
FUEL OIL
ROYAL PURPLE BARRIER FLUID 22
PYROLYSIS GAS
ROYAL PURPLE BARRIER FLUID 22
PYROLYSIS GAS
ROYAL PURPLE BARRIER FLUID 22
RESIN OIL
ROYAL PURPLE BARRIER FLUID 22
RESIN OIL
SAFE SEAL - CHEMOLA TEFLON
CARBON TETRACHLORIDE
SAFE SEAL - CHEMOLA TEFLON
CARBON TETRACHLORIDE
SAFE SEAL CHEMOLA TEFLON
CHLORINE (LIQUID)
SAFE SEAL - CHEMOLA TEFLON SAFE SEAL - CHEMOLA TEFLON
CHLOROFORM CHLOROFORM
SAFE SEAL - CHEMOLA TEFLON
CRACKED GAS
SAFE SEAL - CHEMOLA TEFLON SAFE SEAL - CHEMOLA TEFLON SAFE SEAL - CHEMOLA TEFLON
HYDROGEN CHLORIDE HYDROGEN CHLORIDE METHYL CHLORIDE
SAFE SEAL - CHEMOLA TEFLON
METHYL CHLORIDE
SAFE SEAL - CHEMOLA TEFLON
METHYLENE CHLORIDE
SAFE SEAL - CHEMOLA TEFLON
METHYLENE CHLORIDE
SAFE SEAL - CHEMOLA TEFLON
SILICONE SWS-101
SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) CARBON TETRACHLORIDE
SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) CARBON TETRACHLORIDE
SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) CHLOROFORM
SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) CHLOROFORM
SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) CRACKED GAS
SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) HYDROGEN CHLORIDE
SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) HYDROGEN CHLORIDE
SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) METHYL CHLORIDE
SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) METHYL CHLORIDE
SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) METHYLENE CHLORIDE
SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) METHYLENE CHLORIDE
CHLORINE CAUSTIC CAUSTIC LHC 3 CHLORINE CHLORINE CHLOR-ALKALI 2 CHLORINE LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 METHANES METHANES METHANES METHANES METHANES LHC 2 METHANES METHANES METHANES METHANES METHANES METHANES LHC 2 METHANES METHANES METHANES METHANES LHC 2 METHANES METHANES METHANES METHANES METHANES METHANES
ARC 94-855 92137 92137 4792-25A 4792-20A 4792-20A 89322 4792-20A 92169 92169 92169 92169 92169 92169 92169 92169 92169 92169 94060 94060 94060 94060 94060 94033 94060 94060 94060 94060 94060 94060 94038 94060 94060 94060 94060 94033 94060 94060 94060 94060 94060 94060
ARC DSC HOM DSC DSC DSC DSC DSC DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM HOM DSC ARC HOM DSC DSC HOM DSC HOM DSC HOM DSC DSC HOM DSC HOM DSC DSC HOM DSC HOM DSC HOM DSC
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REACTIVITY
EXO AT 22 C EXOAT 150 C NO EXO AT 25 C EXO AT 339 C EXO AT 155 C EXO AT 58 C EXO AT 48 C EXO AT 40 C NO EXO TO 200 C NO EXO AT 22 C NO EXO TO 200 C NO EXO AT 22 C NO EXO TO 200 C NO EXO AT 22 C NO EXO TO 200 C NO EXO AT 22 C NO EXO TO 200 C NO EXO AT 22 C NO EXO AT 22 C EXO AT 297 C EXO AT 8 C NO EXO AT 22 C EXO AT 310 C NO EXO TO 300 C SL. EXO AT 22 C NO EXO TO 450 C NO EXO AT 22 C EXO AT 375 C NO EXO AT 22 C EXO AT 228 C EXO AT 126 C NO EXO AT 22 C EXO AT 325 C NO EXO AT 22 C EXO AT 200 C NO EXO TO 300 C SL. EXO AT 22 C EXO AT 360 C SL. EXO AT 22 C NO EXO TO 250 C NO EXO AT 22 C EXO AT 335 C
DO A 0 2 7 1 0 4
OONFTDFNTTAl
SEALANT
SILASTIC 732-RTV SILICONE RUBBER SILASTIC 732-RTV SILICONE RUBBER SP-1011 {30 MIN CURE 1ST RUN) SP-1011 (30 MIN CURE 2ND RUN) SP-1011 (30 MIN CURE 3RD RUN) SP-1011 (UNCURED SAMPLE) SP-102 (CURED 300 C / 48 HOURS) STEAM & PROCESS SP-1011 STEAM & PROCESS SP-1011 STEAM & PROCESS SP-1011 STEAM & PROCESS SP-1011 STEAM & PROCESS SP-1011 STEAM & PROCESS SP-1011 STEAM & PROCESS SP-1011 STEAM & PROCESS SP-1011 STEAM & PROCESS SP-1011 STEAM & PROCESS SP-1011 STEAM & PROCESS SP-1011 STEAM & PROCESS SP-1011 STEAM & PROCESS SP-1011 STEAM & PROCESS SP-1011 STEAM & PROCESS SP-1011 STEAM & PROCESS SP-1011 STEAM & PROCESS SP-1011 STEAM & PROCESS SP-1011 STEAM & PROCESS SP-1011 STEAM & PROCESS SP-1011 STEAM & PROCESS SP-1011 STEAM & PROCESS SP-1011 STEAM & PROCESS SP-1011 STEAM & PROCESS SP-1011 STEAM & PROCESS SP-1011 STEAM & PROCESS SP-1011 STEAM & PROCESS SP-1011 STEAM & PROCESS SP-1011 STEAM & PROCESS SP-1011 STEAM & PROCESS SP-1011 5TEAM ft PROCESS SP-1011
TEAM ft PROCESS SP-1012 TEAM ft PROCESS SP-1012
EAM ft PROCESS SP-1015 EAM ft PROCESS SP-1015
O o
T-Ln
Vo
%o
28
TABLE II. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY SEALANT)
PROCESS CHEMICAL
CHLORINE METHANES E-259 VENT (HCI.M1.M2.M3) AIR AIR AIR AIR AIR ACID GAS BLEND BENZENE (CRUDE) CELL EFFLUENT (10% SODIUM HYDROXIDE) CHLORINE DOWANOL EB DOWANOL PM DOWTHERM G DOWTHERMG ETHYLENEGLYCOL ETHYLENE GLYCOL (1%) IN CONDENSATE ETHYLENE OXIDE HCI (15%) + METHYL CHLORIDE (85%) HYDROGEN CHLORIDE (ANHYDROUS) HYDROGEN CHLORIDE (ANHYDROUS) PROPYLENE PROPYLENE QUENCH LIQUOR QUENCH LIQUOR SHELL THERMIA OIL C SODIUM HYDROXIDE (10%) SODIUM HYDROXIDE (50%) SULFUR (LOC 24) SYNGAS BLEND TRIETHANOLAMINE VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIDE (80%) + ANHYDROUS HCI (20%) VINYL CHLORIDE (80%) + ANHYDROUS HCI (20%) WATER WITH <1% GLYCOLS WATER/STEAM ' WATER/STEAM ETHANOLAMINES (MEA.DEA.TEA) ETHYLENE OXIDE ANHYDROUS AMMONIA DOWANOL EB SERIES (EB.DB.TBH)
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PLANT
CHLOR-ALKALI 2 METHANES CHLOR-ALKALI 2 CHLOR-ALKALI 2 CHLOR-ALKALI 2 CHLOR ALKALI 2 POWER 2 LGTI BENZENE CHLORINE CHLOR-ALKALI 2 DOWANOLS DOWANOL S VINYL 2 VINYL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 METHANES VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 METHANES CHLORINE METHANES LGTI LGTI GLYCOL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 GLYCOL 2 METHANES VINYL 2 DOWANOLS GLYCOL 2 DOWANOLS DOWANOLS
REF. NO. TEST
84E100 RCL 83-092 4791-35A 4791-35A 4791-35A 4791-35A 4791-43B 4791-42A 84E031 92180 89322 93014 93014 93154 93154 94030 92194 94030 RCL 1145 93154 93154 93154 93154 93154 93154 90400 92180 RCL 1146 4791-5A 4791-42A 94030 93154 93154 93154 93154 92194 90037 93154 84E106 85197D RCL 1232 84E104
DTA OTA DSC DSC DSC DSC DSC DSC DTA DSC DSC DSC DSC DSC HOM DSC DSC DSC DTA DSC HOM DSC HOM DSC HOM DSC DSC DTA DSC DSC DSC DSC HOM DSC HOM DSC DSC HOM DTA DTA DTA DTA
REACTIVITY
EXOAT 160 C NO EXO TO 200 C EXOAT 160 C EXO AT 60 C EXO AT 273 C EXOAT 178 C EXO AT 420 C EXO AT 45 C NO EXO TO 250 C SLEXOAT 180 C EXO AT 40 C NO EXO TO 300 C EXO AT 275 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C NO EXO TO 250 C EXOAT 120 C NO EXO TO 350 C NO EXO TO 200 C SL. EXO AT 22 C NO EXO TO 250 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 250 C EXOAT 180 C NO EXO TO 295 C NO EXO TO 200 C EXO AT 47 C EXO AT 320 C NO EXO TO 350 C SL. EXO AT 22 C EXOAT 178 C NO EXO AT 22 C NO EXO TO 250 C NO EXO TO 300 C NO EXO AT 22 C NO EXO TO 250 C EXO AT 255 C NO EXO TO 250 C NO EXO TO 250 C
V
TABLE II. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY SEALANT)
SEALANT
PROCESS CHEMICAL
SAFE SEAL QRAFPAK (UCAR CARBON CO GRAFOIL) SILICONE SWS-101
SAFE SEAL MULTIPAK (JOHN CRANE 6KB)
CARBON TETRACHLORIDE
SAFE SEAL MULTIPAK (JOHN CRANE 6KB)
CARBON TETRACHLORIDE
SAFE SEAL MULTIPAK (JOHN CRANE 6KB)
CHLOROFORM
SAFE SEAL MULTIPAK (JOHN CRANE 6KB)
CHLOROFORM
SAFE SEAL MULTIPAK (JOHN CRANE 6KB)
CRACKED GAS
SAFE SEAL MULTIPAK (JOHN CRANE 6KB)
HYDROGEN CHLORIDE
SAFE SEAL MULTIPAK (JOHN CRANE 6KB)
HYDROGEN CHLORIDE
SAFE SEAL MULTIPAK (JOHN CRANE 6KB)
METHYL CHLORIDE
SAFE SEAL MULTIPAK (JOHN CRANE 6KB)
METHYL CHLORIDE
SAFE SEAL MULTIPAK (JOHN CRANE 6KB)
METHYLENE CHLORIDE
SAFE SEAL MULTIPAK (JOHN CRANE 6KB)
METHYLENE CHLORIDE
SAFE SEAL MULTIPAK (JOHN CRANE 6KB)
SILICONE SWS-101
SEAL-ITT #34
CHLORINE
SEAL-ITT #34
SODIUM HYDROXIDE (10%)
SEAL-ITT *34
REGAL OIL 32
SEMSTONE 145-S SEMSTONE 145-S
N-PROPANOL (50%) + WATER (50%) SODIUM HYDROXIDE (3%)
SEMSTONE 145-S
DNDA CATALYST (BATCH 886)
SEMSTONE 245
DNDA CATALYST (BATCH 886)
SEMSTONE 805 LINING MATERIAL
BUTYL ETHYL MAGNESIUM (15%) IN HEXANE
SERVICE GROUP INC 107 A&B BONDER
SODIUM HYDROXIDE (50%)
SERVICE GROUP INC SG-101 LIQUID
WATER/STEAM
SERVICE GROUP INC SG-101 SOLID
WATER/STEAM
SERVICE GROUP INC SG-101HT
WATER/STEAM
SERVICE GROUP INC SG-102 SOLID SERVICE GROUP INC SG-106 LIQUID
WATER/STEAM WATER/STEAM
SERVICE GROUP INC SG-106 A&B SERVICE GROUP INC SG-109
WATER/STEAM WATER/STEAM
SERVICE GROUP INC SG-110 SOLID
WATER/STEAM
SERVICE GROUP INC SG-113
WATER/STEAM
SERVICE GROUP INC SG-201
VtfATER/STEAM
SERVICE GROUP INC SG-201 HT
WATER/STEAM
SERVICE GROUP INC SG-250
WATER/STEAM
SERVICE GROUP INC SG-302
WATER/STEAM
SERVICE GROUP INC SG-303
WATER/STEAM
SERVICE GROUP INC SG-304 SERVICE GROUP INC SG-306
WATER/STEAM WATER/STEAM
SERVICE GROUP INC SG-312
WATER/STEAM
SERVICE GROUP INC SGC FIBER
WATER/STEAM
-- *.r.e GROUP INC SGK FIBER
WATER/STEAM
HO (50%) CHLORINE (50%)
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PLANT
LHC 2 METHANES METHANES METHANES METHANES LHC 2 METHANES METHANES METHANES METHANES METHANES METHANES LHC 2 CHLORINE CHLORINE CHLORINE POLY B POLY B POLY B POLY B POLY B CAUSTIC LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 SOLVENTS/E DC
REF. NO.
94038 94060 94060 94060 94060 94033 94060 94060 94060 94060 94060 94060 94038 90277 90277 90277 90146 90146 90146 90146 91082 89223 89272 89272 89272 89272 89272 89272 89272 89272 89272 89272 89272 89272 89272 89272 89272 89272 89272 89272 89272 479 0
TEST
DSC HOM DSC HOM DSC DSC HOM DSC HOM DSC HOM DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC r*'
REACTIVITY
NO EXO TO 300 C NO EXO AT 22 C EXO AT 185 C NO EXO AT 22 C EXO AT 224 C NO EXO TO 300 C EXO AT 22 C NO EXO TO 325 C SL. EXO AT 22 C NO EXO TO 250 C NO EXO AT 22 C EXOAT 120 C NO EXO TO 300 C EXO AT 90 C EXOAT 166 C EXOAT 165 C NO EXO TO 250 C EXOAT 155 C NO EXO TO 250 C EXO AT 223 C EXO AT 40 C NO EXO TO 250 C NO EXO TO 320 C EXO AT117 C NO EXO TO 350 C NO EXO TO 330 C NO EXO TO 340 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 275 C EXOAT 185 C EXOAT 75 C EXO AT 125 C NO EXO TO 325 C NO EXO TO 350 C EXO AT 260 C NO EXO TO 325 C NO EXO TO NOF'"'
no A 0??107
C O N FID FN TTAl
SEALANT
STEAM & PROCESS SP-1015 STEAM PROCESS SP-1015 STEAM & PROCESS SP-102 STEAM & PROCESS SP-102 STEAM & PROCESS SP-102 STEAM & PROCESS SP-102 STEAM & PROCESS SP-102 STEAM & PROCESS SP-102 STEAM & PROCESS SP-102 STEAM & PROCESS SP-102 STEAM A PROCESS SP-102 STEAM & PROCESS SP-102 STEAM A PROCESS SP-102 STEAM A PROCESS SP-102 STEAM A PROCESS SP-102 STEAM A PROCESS SP-102 STEAM A PROCESS SP-102 STEAM A PROCESS SP-102 STEAM A PROCESS SP-102 STEAM A PROCESS SP-103 STEAM A PROCESS SP-103 STEAM A PROCESS SP-103 STEAM A PROCESS SP-106 STEAM A PROCESS SP-109 STEAM A PROCESS SP-109 STEAM A PROCESS SP-109 STEAM A PROCESS SP-1300 STEAM A PROCESS SP-1360 STEAM A PROCESS SP-1360 STEAM A PROCESS SP-1360 STEAM A PROCESS SP-2000 STEAM A PROCESS SP-2000 8TEAM A PROCESS SP-2000 STEAM A PROCESS SP-2000 STEAM A PROCESS SP-2000 STEAM A PROCESS SP-2000 STEAM A PROCESS SP-2000 STEAM A PROCESS SP-2000 STEAM A PROCESS SP-2000 STEAM A PROCESS SP-2000 STEAM A PROCESS SP-2000 STEAM A PROCESS SP-2000
9
TABLE II. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY SEALANT)
PROCESS CHEMICAL
PLANT
REF. NO. TEST
METHANOL
METHANES
SODIUM HYDROXIDE (50%)
DOWANOLS
AIR (INSTRUMENT)
LGTI
AMMONIA (15%) - D-271
LGTI
COAL (LOC 33A)
LGTI
COAL CHAR SLURRY (LOC 35C)
LGTI
CRACKED GAS (2C-50)
LHC 2
DOWANOL EB
DOWANOLS
DOWANOL PM
DOWANOLS .
DOWTHERM G
VINYL 2
DOWTHERM G
VINYL 2
HYDROGEN CHLORIDE (ANHYDROUS)
VINYL 2
HYDROGEN CHLORIDE (ANHYDROUS)
VINYL 2
SLAG (LOC 37B)
LGTI
SULFUR (LOC 24)
LGTI
SYNGAS BLEND
LGTI
WATER (LOC T-144)
LGTI
WATER/STEAM
VINYL 2
WATER/STEAM
VINYL 2
BENZENE (CRUDE)
BENZENE
HO (15%) + METHYL CHLORIDE (85%)
METHANES
METHYLENE CHLORIDE
METHANES
ETHYLENE OXIDE
GLYCOL 2
DOWTHERM G
METHANES
ETHYLENE OXIDE
GLYCOL 2
SHELL THERMIA OILC
METHANES
METHYLENE CHLORIDE
METHANES
METHYL CHLORIDE
METHANES
METHYLENE CHLORIDE
METHANES
PROPYLENE DICHLORIDE, CI2, AIR, HCI, WATER (E-IB GLYCOL 1
AT-200 SCRUBBER EFFLUENT
CHLORINE
CELL EFFLUENT (10% SODIUM HYDROXIDE)
CHLORINE
DOWANOL PM SERIES (PM,DPM,TPM)
DOWANOLS
ETHYLENE
VINYL 1
ETHYLENE GLYCOL
GLYCOL 2
ETHYLENE OXIDE
GLYCOL 2
Ha.M1.M2,M3,M4 (K-350 SUCTION)
METHANES
HYDROGEN
CHLOR-ALKALI 2
HYDROGEN CHLORIDE (ANHYDROUS)
VINYL 1
PROPYLENE
VINYL 2
PROPYLENE
VINYL 2
R-2 A R-102 HYDROLYZER BTMS
GLYCOL 1
85173A RCL 1233 4791-42A 4791-5A 4791-6A 4791-6A 92065 93014 93014 93154 93154 93154 93154 4791-6A 4791-5A 4791-43A 4791-5A 93154 93154 84E030 RCL 1147 RCL 1584 RCL 1230 RCL 1458 85197B 90400 RCL 1582 RCL 1578 RCL 1577 RCL 1561 91296 92180 84E105 RCL 83-111 94030 94030 RCL 82-119 93199 RCL 84-007 93154 93154 89378
DTA DTA DSC DSC DSC DSC DSC DSC DSC DSC HOM DSC HOM DSC DSC DSC DSC DSC HOM DTA DTA DTA DTA DTA DTA DSC DTA DTA DTA DTA DSC DSC DTA DTA DSC DSC DTA HOM DTA DSC HOM DSC
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REACTIVITY
NO EXO TO 225 C NO EXO TO 250 C NO EXO TO 300 C NO EXO TO 200 C NO EXO TO 235 C EXOAT 165 C NO EXO TO 400 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 400 C SL. EXO AT 22 C NO EXO TO 235 C NO EXO TO 200 C EXOAT 160 C NO EXO TO 260 C NO EXO TO 300 C NO EXO AT 22 C NO EXO TO 250 C EXOAT 145 C NO EXO TO 150 C NO EXO TO 250 C NO EXO TO 290 C EXO AT 250 C NO EXO TO 250 C NO EXO TO 150 C NO EXO TO 140 C NO EXO TO 150 C NO EXO TO 200 C EXO AT 40 C SL EXOAT 170 C NO EXO TO 250 C NO EXO TO 300 C NO EXO TO 350 C EXO AT 320 C NO EXO TO 200 C NO EXO TO 25 C NO EXO TO 200 C NO EXO TO 250 C NO EXO AT 22 C NO EXO TO 250 C
SEALANT
STEAM & PROCESS SP-2000 STEAM & PROCESS SP-2000 STEAM & PROCESS SP-2000 STEAM & PROCESS SP-2000 STEAM & PROCESS SP-2000 STEAM & PROCESS SP-2000 STEAM & PROCESS SP-2000 STEAM & PROCESS SP-2007 STEAM & PROCESS SP-2007 STEAM & PROCESS SP-2007 STEAM & PROCESS SP-2007 STEAM & PROCESS SP-2007 STEAM & PROCESS SP-2007 STEAM & PROCESS SP-2015 STEAM & PROCESS SP-2021 STEAM ft PROCESS SP-2028 STEAM & PROCESS SP-2026 STEAM ft PROCESS SP-2026 STEAM ft PROCESS SP-2026 STEAM ft PROCESS SP-2026 STEAM ft PROCESS SP-2026 STEAM ft PROCESS SP-2026 STEAM ft PROCESS SP-2511 STEAM ft PROCESS SP-2600 STEAM ft PROCESS SP-2600 STEAM ft PROCESS SP-289 STEAM ft PROCESS SP-289 STEAM ft PROCESS SP-289 STEAM ft PROCESS SP-289 STEAM ft PROCESS SP-292 STEAM ft PROCESS SP-3000 STEAM ft PROCESS SP-3000 STEAM ft PROCESS SP-3100 STEAM ft PROCESS SP-3100 STEAM ft PROCESS SP-3100 STEAM ft PROCESS SP-3100 STEAM ft PROCESS SP-3100 STEAM ft PROCESS SP-3100 STEAM ft PROCESS SP-325 STEAM ft PROCESS SP-325 STEAM ft PROCESS SP-325 STEAM ft PROCESS SP-325
o oo Z-n O
T>
O T\ O
zj \\>T
X> O " 3D
30
TABLE II. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY SEALANT)
PROCESS CHEMICAL
PLANT
REF. NO. TEST
RANDO68 OIL
POLYA
SODIUM HYDROXIDE (10%)
CHLORINE
TRIETHANOLAMINE
GLYCOL 2
VINYL CHLORIDE
VINYL 2
VINYL CHLORIDE
VINYL 2
WATER/STEAM
VINYL 2
WATER/STEAM
VINYL 2
ETHANOLAMINES (MEA.DEAJEA)
DOWANOLS
FREON 12
METHANES
HYDROGEN CHLORIDE (ANHYDROUS)
VINYL 1
METHYL CHLORIDE
METHANES
SULFURIC ACID (96%)
CHLOR-ALKALI 2
VINYL CHLORIOE
VINYL 1
WATER/STEAM
CHLOR-ALKALI 2
RANDO 68 OIL
POLYA
CHLORINE (LIQUID)
CHLORINE
ETHYLENE
VINYL 1
FREON 12
CHLORINE
METHYL CHLORIDE
METHANES
METHYLENE CHLORIDE
METHANES
PROPYLENE DICHLORIDE. CI2. AIR. HCI. WATER (E-IB GLYCOL 1
SULFURIC ACID (96%)
CHLOR-ALKALI 2
WATER/STEAM
METHANES
HO. Ml. M2. M3, M4 (T-851)
METHANES
METHANES R-300 OUTLET (Ml .M2.M3.M4.HCI)
METHANES
BETA-TRICHLOROETHANE
VINYL 2
BETA-TRICHLOROETHANE
VINYL 2
ETHYLENE DICHLORIDE
VINYL 2
ETHYLENE DICHLORIDE
VINYL 2
CHLORINE (LIQUID)
CHLOR-ALKALI 2
SYNGAS
LGTI
CHLORINE (LIQUID)
CHLORINE
BETA-TRICHLOROETHANE
VINYL 2
BETA-TRICHLOROETHANE
VINYL 2
CALCIUM STEARATE
POLY C
DOWANOL EB
DOWANOLS
DOWANOL PM
DOWANOLS
HYDROGEN SULFIDE GAS
LGTI
CARBON TETRACHLORIDE
VINYL 2
CARBON TETRACHLORIDE
VINYL 2
ETHYLENE DICHLORIDE
VINYL 2
ETHYLENE BICHLORIDE
VINYL 2
93210
DSC
92180
DSC
94030
DSC
93154
DSC
93154
HOM
93154
DSC
93154
HOM
84E107
DTA
RCL 82-037 DTA
RCL 84-006 DTA
84E156
DTA
85101B
DTA
3108-46
DTA
84E134
DTA
93210
DSC
ARC 92-692 ARC
RCL 83-112 DTA
90051
DSC
85132A
DTA
85132B
DTA
RCL 1560 DTA
85101A
DTA
86060A
DTA
RCL 82-014 DTA
RCL 82-045 DTA
93154
DSC
93154
HOM
93154
DSC
93154
HOM
RCL-93-9831 ARC
93125
DSC
ARC 92-711 ARC
93154
DSC
93154
HOM
93194
DSC
93014
DSC
93014
DSC
93022
DSC
93154
DSC
93154
HOM
93154
DSC
93154
HOM
Dow Confidential
REACTIVITY
NO EXO TO 200 C EXOAT 170 C EXO AT 319 C NO EXO TO 200 C SL. EXO AT 22 C NO EXO TO 325 C NO EXO AT 22 C NO EXO TO 250 C NO EXO TO 100 C NO EXO TO 185 C NO EXO TO 150 C NO EXO TO 250 C NONE NO EXO TO 250 C EXO AT 36 C EXO AT 20 C NO EXO TO 225 C NO EXO TO 250 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 250 C NO EXO TO 275 C NO EXO TO 500 C NO EXO TO 310 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 250 C NO EXO TO 500 C EXO AT 20 C EXO AT 253 C NO EXO AT 22 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 300 C EXO AT 252 C NO EXO AT 22 C NO EXO TO 250 C NO EXO AT 22 C
1)0 A 0 ? ? 1 0 9
CONF TDFNT TAi
SEALANT
STEAM A PROCESS SP-325 STEAM & PROCESS SP-325 STEAM & PROCESS SP-325 STEAM A PROCESS SP-325 STEAM A PROCESS SP-325 STEAM A PROCESS SP-325 STEAM A PROCESS SP-325 STEAM A PROCESS SP-325 STEAM A PROCESS SP-325 STEAM a PROCESS SP-325 STEAM a PROCESS SP-325 STEAM a PROCESS SP-325 STEAM A PROCESS SP-375 STEAM a PROCESS SP-429 STEAM a PROCESS SP-429 STEAM a PROCESS SP-5000 STEAM a PROCESS SP-520 STEAM A PROCESS SP-60 STEAM a PROCESS SP-60 STEAM a PROCESS SP-60 STEAM a PROCESS SP-60 STEAM a PROCESS SP-60 STEAM a PROCESS SP-60 STEAM a PROCESS SP-60 STEAM a PROCESS SP-60 STEAM a PROCESS SP-60 STEAM a PROCESS SP-60 STEAM a PROCESS SP-60 STEAM a PROCESS SP-60 STEAM a PROCESS SP-60 STEAM a PROCESS SP-60 STEAM a PROCESS SP-60 STEAM a PROCESS SP-60 STEAM a PROCESS SP-770 STEAM a PROCESS SP-CM STEAM a PROCESS SP-CM STEAM a PROCESS SP-CM STEAM a PROCESS SP-CM STEAM a PROCESS SP-CM STEAM a PROCESS SP-CM STEAM a PROCESS SP-CM STEAM a PROCESS SP-CM
11
TABLE II. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTEO BY SEALANT)
PROCESS CHEMICAL
PLANT
REF. NO. TEST
ETHYLENE DICHLORIDE (D-15 VESSEL SAMPLE) ISOPAR E ISOPAR E Ml. M2. M3. M4, HCI Ml. M2. M3. M4, + HCI QUENCH LIOUOR QUENCH LIQUOR RANDO 68 OIL VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIDE (80%) + ANHYDROUS HCI (20%) VINYL CHLORIDE (80%) + ANHYDROUS HCI (20%) CHLORINE (LIQUID) SYNGAS VINYL CHLORIDE SODIUM HYDROXIDE (40%) - HE-201 CARBON STEEL + CONCRETE + WATER ACID QAS BLEND AIR (INSTRUMENT) AMMONIA (15%) - D-270 CELL EFFLUENT (10% SODIUM HYDROXIDE) COAL (LOC 33A) COAL CHAR SLURRY (LOC 35C) DOWANOL EB DOWANOL PM ETHYLENE OXIDE NITROGEN SLAG (LOC 37B) SODIUM HYDROXIDE (10%) SODIUM HYDROXIDE (50%) SULFUR (LOC 24) SYNGAS BLEND WATER (LOCT-144) HYDROGEN SULFIDE GAS
ACID GAS BLEND AT-200 SCRUBBER EFFLUENT CARBON TETRACHLORIDE CARBON TETRACHLORIDE CHLORINE (LIQUID) CHLOROFORM CRACKED GAS (2C-50) DOWANOL EB
SOLVENTS/EDC POLY C POLY C METHANES METHANES VINYL 2 VINYL 2 POLYA VINYL 2 VINYL 2 VINYL 2 VINYL 2 CHLORINE LGTI METHANES CAUSTIC POWER 2 LGTI LGTI LGTI CHLORINE LGTI LGTI DOWANOLS DOWANOLS GLYCOL 2 LGTI ' LGTI CHLORINE CHLOR-ALKALI 2 LGTI LGTI LGTI LGTI LGTI CHLORINE VINYL 2 VINYL 2 CHLORINE METHANES LHC 2 DOWANOLS
93144
DSC
93215
DSC
93215
HOM
93093
DSC
93093
HOM
93154
DSC
93154
HOM
93210
DSC
93154
DSC
93154
HOM
93154
DSC
93154
HOM
RCL-93-9830 ARC
93125
DSC
93179
DSC
4791-SOB DSC
92327
DSC
4791-42A DSC
4791-42A DSC
4791-5A
DSC
92180
DSC
4791-6A
DSC
4791-6A
DSC
93014
DSC
93014
DSC
85197A
DTA
4791-43A DSC
4791-6A
DSC
92180
DSC
92326
DSC
4791-5A
DSC
4791-43A DSC
4791-5A
DSC
93022
DSC
4791-42A DSC
91296
DSC
93154
DSC
93154
HOM
ARC 92-708 ARC
85133D
OTA
92065
DSC
93014
DSC
Dow Confidential
REACTIVITY
NO EXO TO 300 C EXOAT 170 C NO EXO AT 22 C NO EXO TO 300 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 200 C NO EXO TO 220 C NO EXO AT 22 C NO EXO TO 250 C SL. EXO AT 22 C NO EXO TO 250 C NO EXO TO 285 C EXOAT 114 C EXO AT 90 C NO EXO TO 180 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 200 C SL EXO AT 194 C NO EXO TO 235 C NO EXO TO 235 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 350 C EXO AT 350 C NO EXO TO 235 C EXOAT 194 C NO EXO TO 200 C NO EXO TO 200 C EXO AT 365 C NO EXO TO 250 C NO EXO TO 300 C EXO AT 50 C NO EXO TO 250 C EXO AT 247 C NO EXO AT 22 C EXO AT 20 C NO EXO TO 250 C EXO AT 338 C NO EXO TO 300 C
32
TABLE II. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY SEALANT)
SEALANT
PROCESS CHEMICAL
PLANT
REF. NO. TEST
STEAM & PROCESS SP-CM
STEAM & PROCESS SP-CM
STEAM & PROCESS SP-CM
STEAM & PROCESS SP-CM
STEAM & PROCESS SP-CM
STEAM & PROCESS SP-CM
STEAM & PROCESS SP-TFLO
STERLING STUFFING BOX SEALANT #1
SYNTHO-GLASS NEPTUNE RESEARCH
TEAM LEAK REPAIRS 16X & F-10 & F-14 FIBERS
TEAM LEAK REPAIRS 16X & FURMANITE FSC-6B
TEAM LEAK REPAIRS CURED HI-PRO
TEAM LEAK REPAIRS F-14 FIBER
TEAM LEAK REPAIRS F14 FIBERS
TEAM LEAK REPAIRS PRI-102C (THREADS)
TEAM LEAK REPAIRS PRI-102C (THREADS)
TEAM LEAK REPAIRS PTFE SEALANT
TEAM LEAK REPAIRS PTFE SEALANT
TEAM LEAK REPAIRS SEALANT #1
TEAM LEAK REPAIRS SEALANT #10 + F-45 FIBER
TEAM LEAK REPAIRS SEALANT #11
TEAM LEAK REPAIRS SEALANT #11
TEAM LEAK REPAIRS SEALANT #11
TEAM LEAK REPAIRS SEALANT #11
TEAM LEAK REPAIRS SEALANT #11
TEAM LEAK REPAIRS SEALANT #11
TEAM LEAK REPAIRS SEALANT #16
TEAM LEAK REPAIRS SEALANT #16
TEAM LEAK REPAIRS SEALANT #16
TEAM LEAK REPAIRS SEALANT #16X
TEAM LEAK REPAIRS SEALANT 16X
TEAM LEAK REPAIRS SEALANT #18
TEAM LEAK REPAIRS SEALANT #18X
TEAM LEAK REPAIRS SEALANT #18X
TEAM LEAK REPAIRS SEALANT 18X
TEAM LEAK REPAIRS SEALANT #1BX
TEAM LEAK REPAIRS SEALANT #1X TEAM LEAK REPAIRS SEALANT #1X TEAM LEAK REPAIRS SEALANT #2X TEAM LEAK REPAIRS SEALANT #2X TEAM LEAK REPAIRS SEALANT #2X TEAM LEAK REPAIRS SEALANT #2X
n da zo TJ
x> ry mo Z \)
DOWANOL PM
DOWANOLS
HCI, Ml, M2, M3, M4 (T-851)
METHANES
HYDROGEN CHLORIDE (ANHYDROUS)
METHANES
METHYL CHLORIDE
METHANES
METHYL DIETHANOLAMINE (LOC4B)
LGTI
METHYLENE CHLORIDE
METHANES
CHLORINE (LIQUID)
CHLORINE
WATER (COOLING TOWER)
LHC 3
HYDROLYZER BOTTOMS
GLYCOL 1
WATER (E7F)
GLYCOL 2
DOWTHERM G
VINYL 2
TET, PER, HCE, HCI, CHLORINE
SOLVENTS/E DC
CELL EFFLUENT ( SODIUM HYDROXIDE)
VINYL 2
D-270 LIQUID
GLYCOL 1
CAUSTIC (25%)
CAUSTIC
ZEROL 300 OIL
POLYA
AMMONIA (AQUEOUS)
DOWANOLS
ANHYDROUS AMMONIA
DOWANOLS
WATER/STEAM
METHANES
PER/TET (CRUDE)
SOLVENTS/EDC
CARBON TETRACHLORIDE
VINYL 2
CARBON TETRACHLORIDE
VINYL 2
CHLORINE
VINYL 1
PER/TET (CRUDE)
SOLVENTS/EDC
PROPYLENE DICHLORIDE, CI2, AIR. HCI. WATER (E-IB GLYCOL 1
VINYL CHLORIDE
VINYL 2
ANHYDROUS AMMONIA
CAUSTIC
SODIUM HYDROXIDE (50%)
CAUSTIC
SODIUM HYDROXIDE (50%) + AMMONIA
CAUSTIC
DOWTHERM G
VINYL 2
DOWTHERM G
VINYL 2
D-1220 BOILER BLOWDOWN
LHC 3
VINYL CHLORIDE (80%) + ANHYDROUS HCI (20%)
VINYL 2
VINYL CHLORIDE (80%) + ANHYDROUS HCI (20%)
VINYL 2
WATER/STEAM
VINYL 2
WATER/STEAM
VINYL 2
HYDROGEN CHLORIDE (ANHYDROUS)
VINYL 2
HYDROGEN CHLORIDE (ANHYDROUS)
VINYL 2
BETA-TRICHLOROETHANE
VINYL 2
BETA-TRICHLOROETHANE
VINYL 2
ETHYLENE BICHLORIDE
VINYL 2
ETHYLENE DICHLORIDE
VINYL 2
93014 RCL 1400 85133F 85133B 4791-5A 85133C ARC 92-715 91135 91175 92160 92100 91050 93129 91169 91098 91028 RCL 1039 RCL 1038 RCL 83-017 89228 93154 93154 RCL 83-093 89141 RCL 1558 93147 RCL 1010 RCL 1008 RCL 1009 92100 93154 89151 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154
DSC DTA DTA DTA DSC DTA ARC DSC DSC DSC DSC DSC DSC DSC DSC DSC DTA DTA DTA DSC DSC HOM DTA DSC DTA DSC DTA DTA DTA DSC HOM DSC DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM
Dow Confidential
REACTIVITY
NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 175 C NO EXO TO 250 C NO EXO TO 150 C NO EXO TO 200 C NO EXO TO 350 C NO EXO TO 250 C NO EXO TO 200 C NO EXO TO 250 C NO EXO TO 200 C NO EXO TO 250 C NO EXO TO 300 C NO EXO TO 320 C NO EXO TO 150 C EXO AT 245 C NO EXO TO 350 C NO EXO AT 22 C EXO AT 90 C EXO AT 80 C NO EXO TO 200 C EXO AT 135 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 190 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 250 C NO EXO TO 250 C SL. EXO AT 22 C NO EXO TO 300 C NO EXO AT 22 C EXO AT 80 C SL. EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 325 C NO EXO AT 22 C
DO A 0 ? ? 1 1 1
CONFTDFNTTAl
SEALANT
TEAM LEAK REPAIRS SEALANT #2X TEAM LEAK REPAIRS SEALANT #2X TEAM LEAK REPAIRS SEALANT *2X TEAM LEAK REPAIRS SEALANT 2X TEAM LEAK REPAIRS SEALANT #2X TEAM LEAK REPAIRS SEALANT 2X TEAM LEAK REPAIRS SEALANT #2X TEAM LEAK REPAIRS SEALANT #2X TEAM LEAK REPAIRS SEALANT #2X TEAM LEAK REPAIRS SEALANT #2X TEAM LEAK REPAIRS SEALANT #2XH TEAM LEAK REPAIRS SEALANT #2XH TEAM LEAK REPAIRS SEALANT #2XH TEAM LEAK REPAIRS SEALANT #2XH TEAM LEAK REPAIRS SEALANT #2XH TEAM LEAK REPAIRS SEALANT #2XH TEAM LEAK REPAIRS SEALANT 2XH TEAM LEAK REPAIRS SEALANT #2XH TEAM LEAK REPAIRS SEALANT 6 TEAM LEAK REPAIRS SEALANT 16 TEAM LEAK REPAIRS SEALANT 16 TEAM LEAK REPAIRS SEALANT 6 TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS SEALANT 6 TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS SEALANT 6 TEAM LEAK REPAIRS SEALANT *6 TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS SEALANT 6 TEAM LEAK REPAIRS SEALANT 6 TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS SEALANT 6 TEAM LEAK REPAIRS SEALANT 6 TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS SEALANT 6 TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS SEALANT 8 TEAM LEAK REPAIRS SEALANT 6 TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS SEALANT #6
'3
TABLE II. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY SEALANT)
PROCESS CHEMICAL
PLANT
REF. NO.
TEST
HYDROGEN CHLORIDE (ANHYDROUS) HYDROGEN CHLORIDE (ANHYDROUS) PROPYLENE PROPYLENE QUENCH LIQUOR QUENCH LIQUOR VINYL CHLORIDE VINYL CHLORIDE WATER/STEAM WATER/STEAM DOWTHERM G DOWTHERM G ETHYLENE DICHLORIDE ETHYLENE DICHLORIDE PROPYLENE PROPYLENE VINYL CHLORIDE VINYL CHLORIDE AMMONIA (20% IN H20) ANHYDROUS AMMONIA BETA-TRICHLOROETHANE BETA-TRICHLOROETHANE C-450 FEED TO C5S + LITES C-500 FEED PYGAS + LITES CARBON TETRACHLORIDE CARBON TETRACHLORIDE CP-1000 OIL SATURATED WITH HCL CRACKED GAS (H2,C1.C2,C3.C4,HIGHERS) DOWANOL DF 250 DOWANOL DF 250 DOWANOL DPM DOWANOL DPM DOWANOL PM DOWANOL PM . DOWANOL TPM DOWANOL TPM ETHANE ETHANE/ETHYLENE (2C-52 OVERHEAD GAS) ETHANOLAMINES (MEA.DEA.TEA) ETHYL CHLORIDE ETHYLENE DICHLORIDE ETHYLENE DICHLORIDE
Dow Confidential
VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 LGTI CAUSTIC VINYL 2 VINYL 2 LHC 3 LHC 3 VINYL 2 VINYL 2 METHANES LHC 2 DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS PROMIX LHC 2
DOWANOLS SOLVENTS/EDC VINYL 1 VINYL 2
93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 69336 RCL 1007 93154 93154 90365 90385 93154 93154 92288 RCL 738 92016 92016 92016 92016 92016 92016 92016 92016 94071 RCL 1015 84E108 90024 3108-46 93154
DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM DSC DTA DSC HOM DSC DSC DSC HOM DSC DTA HOM DSC HOM DSC HOM DSC HOM DSC DSC DTA DTA DSC DTA DSC
REACTIVITY
EXOAT 117 C SL. EXO AT 22 C NO EXO TO 250 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C EXO AT 336 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 250 C NO EXO AT 22 C EXO AT 264 C NO EXO AT 22 C NO EXO TO 235 C NO EXO TO 200 C EXO AT 284 C NO EXO AT 22 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 200 C NO EXO TO 400 C NO EXO AT 25 C NO EXO TO 200 C SL EXO AT 25 C NO EXO TO 200 C SL EXO AT 25 C NO EXO TO 200 C SL EXO AT 25 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 200 C NQ EXO TO 250 C NO EXO TO 250 C NO EXO TO 200 C NO EXO TO 350 C
34
TABLE II. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY SEALANT)
SEALANT
PROCESS CHEMICAL
PLANT
REF. NO. TEST
TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS SEALANT 6 TEAM LEAK REPAIRS SEALANT 6 TEAM LEAK REPAIRS SEALANT 6 TEAM LEAK REPAIRS SEALANT 6 TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS SEALANT 6 TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS SEALANT #8 TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS SEALANT 6 TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS SEALANT *8 TEAM LEAK REPAIRS SEALANT *8 TEAM LEAK REPAIRS SEALANT *6 TEAM LEAK REPAIRS SEALANT #8 & F-14 FIBERS TEAM LEAK REPAIRS SEALANT #8 4 F-14 FIBERS TEAM LEAK REPAIRS SEALANT #6 4 F-14 FIBERS TEAM LEAK REPAIRS SEALANT #8 4 F-14 FIBERS TEAM LEAK REPAIRS SEALANT #8 F-14 FIBER TEAM LEAK REPAIRS SEALANT 18 F-14 FIBER TEAM LEAK REPAIRS SEALANT 16X TEAM LEAK REPAIRS SEALANT 16X TEAM LEAK REPAIRS SEALANT 18X TEAM LEAK REPAIRS SEALANT 16X TEAM LEAK REPAIRS SEALANT 16X TEAM LEAK REPAIRS SEALANT 16X 4 F-10 FIBERS TEAM LEAK REPAIRS SEALANT 18X TEAM LEAK REPAIRS SEALANT 18X TEAM LEAK REPAIRS SEALANT 1BX TEAM LEAK REPAIRS SEALANT 18X TEAM LEAK REPAIRS SEALANT 18X TEAM LEAK REPAIRS SEALANT 19X
ETHYLENE DICHLORIDE
VINYL 2
ETHYLENE DICHLORIDE + BETA-TRICHLOROETHANE VINYL 1
HCI (50%) CHLORINE (50%)
SOLVENTS/E DC
HYDROGEN CHLORIDE (ANHYDROUS)
VINYL 1
ISOPAR E
POLY C
MEA.OEA.TEA.KOH (REACTOR EFFLUENT)
DOWANOLS
METHYL CHLORIDE DIMETHYL ETHER
METHOCEL
METHYL CHLORIDE + DIMETHYL ETHER
METHOCEL
OIL BOTTOMS (T-102C TOWER)
GLYCOL 1
POTASSIUM CARBONATE (22%) IN WATER
GLYCOL 2
PROPANE
PROMIX
PROPYLENE GLYCOL
GLYCOL 1
PROPYLENE OXIDE
GLYCOL 1
PYROLYSIS GASOLINE 4 RESIN OIL
LHC 3
QUENCH LIQUOR
VINYL 2
QUENCH LIQUOR
VINYL 2
REGAL 32 OIL
LHC 3
SODIUM HYDROXIDE (50%)
CAUSTIC
SODIUM HYDROXIDE (50%) + AMMONIA
CAUSTIC
SOUR CONDENSATE
LGTI
VINYL CHLORIDE (80%) + ANHYDROUS HCI (20%)
VINYL 2
VINYL CHLORIDE (80%) + ANHYDROUS HCI (20%)
VINYL 2
WATER/STEAM
GLYCOL 1
WATER/STEAM
VINYL 2
BENZENE-TOLUENE-XYLENE (T-1602)
LHC 3
BETZ BP-P-1B (50%) + COR-TROL 778P (50%)
POWER 1
BETZ BP-P-1B (50%) + COR-TROL 778P (50%)
POWER 1
T-52 BTMS
GLYCOL 2
CHLORINE
VINYL 1
VINYL CHLORIDE (80%) + ANHYDROUS HCI (20%)
VINYL 1
C-2 RECYCLE GAS
GLYCOL 2
DOWTHERM A
POLY C
DOWTHERM G
VINYL 2
DOWTHERM G
VINYL 2
HYDROGEN SULFIDE GAS
LGTI
WATER (E7F)
GLYCOL 2
CONDENSATE (C-16)
GLYCOL 1
MONOPROPYLENE GLYCOL + WATER
GLYCOL 1
SYNGAS
LGTI
WASTE WATER EFFLUENT (P-5)
GLYCOL 1
WATER/STEAM
GLYCOL 1
SYNGAS
LGTI
93154
HOM
84E193
DTA
4791-9A
DSC
RCL 84-009 DTA
87033G
DTA
RCL1270,71 DTA
93196
DSC
93196
HOM
4791-36B DSC
91092
DSC
94071
DSC
91199
DSC
88285
DSC
92124
DSC
93154
DSC
93154
HOM
90034
DSC
RCL 1005 DTA
RCL 1006 DTA
870901
DSC
93154
DSC
93154
HOM
90041
DSC
93154
HOM
92199
DSC
92175
DSC
92175
HOM
92160
DSC
RCL 83-095 DTA
RCL 83-096 DTA
91117
DSC
87033B
DTA
92100
DSC
92100
DSC
93032
DSC
92160
DSC
90266
DSC
91146
DSC
92318
DSC
90264
DSC
RCL-90-2661 DSC
92316
DSC
Dow Confidential
REACTIVITY
NO EXO AT 22 C NO EXO TO 400 C EXOAT 125 C NO EXO TO 165 C NO EXO TO 260 C NO EXO TO 300 C NO EXO TO 190 C SL. EXO AT 22 C NO EXO TO 190 C NO EXO TO 200 C NO EXO TO 178 C NO EXO TO 250 C EXO AT 200 C NO EXO TO 200 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 250 C NO EXO TO 200 C NO EXO TO 200 C EXO AT 85C NO EXO TO 250 C SL. EXO AT 22 C NO EXO TO 335 C NO EXO AT 22 C NO EXO TO 250 C NO EXO TO 335 C NO EXO AT 22 C NO EXO TO 200 C EXOAT 130 C NO EXO TO 250 C NO EXO TO 300 C NO EXO TO 350 C NO EXO TO 350 C NO EXO TO 350 C EXO AT 316 C NO EXO TO 200 C NO EXO TO 300 C NO EXO TO 250 C NO EXO TO 400 C NO EXO TO 250 C NO EXO TO 308 C NO EXO TO 400 C
00 A 0 7 7 \Y ?
OONFTDFNTTAl
i .
15
TABLE II. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY SEALANT)
SEALANT
PROCESS CHEMICAL
PLANT
REF. NO. TEST
TEAM LEAK REPAIRS SEALANT IX
AMMONIUM HYDROXIDE
DOWANOLS
TEAM LEAK REPAIRS SEALANT IX
ISOPAR E
POLY C
TEAM LEAK REPAIRS SEALANT 2W
AIR
POWER 2
TEAM LEAK REPAIRS SEALANT 2X
AIR
POWER 2
TEAM LEAK REPAIRS SEALANT 2X
C-450 FEED TO C5S + LITES
LHC 3
TEAM LEAK REPAIRS SEALANT 2X
C-500 FEED PYGAS + LITES
LHC 3
TEAM LEAK REPAIRS SEALANT 2X
DOWTHERM A
POLY C
TEAM LEAK REPAIRS SEALANT 2X
DOWTHERM A
POLY C
TEAM LEAK REPAIRS SEALANT 2X
ISOPAR E
POLY C
TEAM LEAK REPAIRS SEALANT 2X
MONOPROPYLENE GLYCOL + WATER
GLYCOL 1
TEAM LEAK REPAIRS SEALANT 2X
SODIUM HYDROXIDE (50%)
CAUSTIC
TEAM LEAK REPAIRS SEALANT 2X
SYNGAS
LGTI
TEAM LEAK REPAIRS SEALANT 2X
WATER/STEAM
CAUSTIC
TEAM LEAK REPAIRS SEALANT 2XH
SYNGAS
LGTI
TEAM LEAK REPAIRS SEALANT 2XH
WATER/STEAM
GLYCOL 1
TEAM LEAK REPAIRS SEALANT 5Q
DOWTHERM A
POLY C
TEAM LEAK REPAIRS SEALANT SO
ISOPAR E
POLY C
TEAM LEAK REPAIRS SEALANT DB 20
ISOPAR E
POLY C
TEAM LEAK REPAIRS SEALANT DB-2
CHLOROFORM
METHANES
TEAM LEAK REPAIRS SEALANT DB-2
DIMETHYL ETHER
METHANES
TEAM LEAK REPAIRS SEALANT DB-2
HYDROGEN CHLORIDE (ANHYDROUS)
METHANES
TEAM LEAK REPAIRS SEALANT DB-2
METHANOL
METHANES
TEAM LEAK REPAIRS SEALANT DB-2
METHYL CHLORIDE
METHANES
TEAM LEAK REPAIRS SEALANT DB-2
METHYLENE CHLORIDE
METHANES
TEAM LEAK REPAIRS SEALANT DB-2
PROPYLENE DICHLORIDE, CI2, AIR, HCI, WATER (E-IB GLYCOL 1
TEAM LEAK REPAIRS SEALANT DB-2
SULFURIC ACID
METHANES
TEAM LEAK REPAIRS SEALANT DB-20
ETHYLENE
VINYL 1
TEAM LEAK REPAIRS SEALANT DB-20
PROPYLENE
VINYL 1
TEAM LEAK REPAIRS SEALANT DB-20
VINYL CHLORIDE
VINYL 1
TEAM LEAK REPAIRS SEALANT DB-20
VINYL CHLORIDE (80%) + ANHYDROUS HCI (20%)
VINYL t
TEAM LEAK REPAIRS SEALANT DB-22
CRACKED GAS
LHC 3
TEAM LEAK REPAIRS SEALANT DB-22
SIMULATED VENT GAS
VINYL 2
TEAM LEAK REPAIRS SEALANT DB-22
SIMULATED VENT GAS
VINYL 2
TEAM LEAK REPAIRS SEALANT DB-22 & F-10 FIBERS BOILER WATER WITH COR-TROL, EDTA. & PIB
POWER 1
TEAM LEAK REPAIRS SEALANT DB-22 & F-10 FIBERS BOILER WATER WITH COR-TROL, EDTA. & PIB
POWER 1
TEAM LEAK REPAIRS SEALANT PRI-102C
WATER/STEAM
LGTI
TEAM LEAK REPAIRS SEALANT RF 300
SYNGAS
LGTI
TEAM LEAK REPAIRS SEALANT SW
WATER/STEAM
VINYL 2
TEAM LEAK REPAIRS SEALANT X-36
C-2 RECYCLE GAS
GLYCOL 2
TEAM LEAK REPAIRS SEALANT X-36 TEAM LEAK REPAIRS SEALANT X-36
DOWTHERM A ISOPAR E
POLY C POLY C
TEAM LEAK REPAIRS SEALANT X-36 A&B
PROPANE
LHC 3
91239 87033D 92320 92320 90385 90385 93080 93080 87033E 91146 871121 93123 871122 93123 91159 87033A 87033F 87033H RCL 82-039 RCL 82-043 RCL 82-042 RCL 82-041 RCL 82-040 RCL 82-038 RCL 1559 RCL 82-044 B4E194 84E195 84E196 RCL 83-097 90243 92302 92302 92183 92183 93088 93072 93075 91115 87033C 870331 92124
DSC DTA DSC DSC DSC DSC DSC HOM DTA DSC DSC DSC DSC DSC DSC DTA DTA DTA DTA DTA DTA DTA DTA DTA DTA DTA DTA DTA DTA DTA DSC DSC HOM DSC HOM DSC DSC DSC DSC DTA DTA DSC
Dow Confidential
REACTIVITY
NO EXO TO 175 C NO EXO TO 260 C NO EXO TO 500 C NO EXO TO 500 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 260 C NO EXO TO 250 C NO EXO TO 230 C EXO AT 362 C NO EXO TO 285 C NO EXO TO 500 C NO EXO TO 300 C NO EXO TO 350 C NO EXO TO 260 C NO EXO TO 260 C NO EXO TO 250 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 175 C NO EXO TO 190 C NO EXO TO 200 C NO EXO TO 190 C EXO AT 45 C NO EXO TO 130 C NO EXO TO 250 C NO EXO TO 225 C NO EXO TO 250 C NO EXO TO 200 C NO EXO TO 120 C NO EXO AT 22 C NO EXO TO 250 C NO EXO AT 22 C NO EXO TO 230 C NO EXO TO 500 C NO EXO TO 275 C NO EXO TO 300 C NO EXO TO 350 C NO EXO TO 260 C NO EXO TO 160 C
OO A 0 P P 1 1 3
C O N FTD FN TIAl
DO A O?? T-1 4
C.ONF t D F N T T At
36
TABLE II. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY SEALANT)
SEALANT
PROCESS CHEMICAL
PLANT
REF. NO. TEST
TEAM LEAK REPAIRS SEALANT X36 A&B TEAM LEAK REPAIRS TC-4 (CURED) TEAM LEAK REPAIRS TC-4 EPOXY BONDER TEAM LEAK REPAIRS VALVEPACK A TEAM LEAK REPAIRS VALVEPACK A TEAM LEAK REPAIRS VALVEPACK A TEAM LEAK REPAIRS VALVEPACK A TEAM LEAK REPAIRS VALVEPACK A TEAM LEAK REPAIRS VALVEPACK A TEAM LEAK REPAIRS VALVEPACK A TEAM LEAK REPAIRS VALVEPACK A TEAM LEAK REPAIRS VALVEPACK A TEAM LEAK REPAIRS VALVEPACK AW & FIBERS TEAM LEAK REPAIRS VALVEPACK AW W/ FIBERS TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK B TEAM LEAK REPAIRS VALVEPACK B TEAM LEAK REPAIRS VALVEPACK B TEAM LEAK REPAIRS VALVEPACK B TEAM LEAK REPAIRS VALVEPACK B TEAM LEAK REPAIRS VALVEPACK B TEAM LEAK REPAIRS VALVEPACK B TEAM LEAK REPAIRS VALVEPACK B
PYROLYSIS GASOLINE & RESIN OIL
LHC 3
PROPYLENE OXIDE + DIMETHYL ETHER/ METHYL CL METHOCEL
SODIUM HYDROXIDE (50%) + NH40H
CAUSTIC
BETA-TRICHLOROETHANE
VINYL 1
ETHYLENE
VINYL 1
ETHYLENE DICHLORIDE
VINYL 1
ETHYLENE DICHLORIDE + BETA-TRICHLOROETHANE VINYL .1
HYDROGEN CHLORIDE (ANHYDROUS)
VINYL 1
PROPYLENE
VINYL 1
VINYL CHLORIDE
VINYL 1
VINYL CHLORIDE (80%) + ANHYDROUS HCI (20%)
VINYL 1
WATER/STEAM
VINYL 1
HYDROGEN
POLY C
ETHYLENE
POLY C
BRINE
BRINE
BRINE
BRINE
DOWANOL PM, DPM, TPM, KOH MIX (DV-114)
DOWANOLS
DOWANOL TBH AND HIGHERS (T-130)
DOWANOLS
DOWANOL TPM A HIGHERS
DOWANOLS
DOWTHERM A
POLY C
DOWTHERM G
VINYL 2
DOWTHERM G
VINYL 2
ETHYLENE
BRINE
ETHYLENE
BRINE
ETHYLENE DICHLORIDE
VINYL 2
ETHYLENE DICHLORIDE
VINYL 2
ETHYLENE OXIDE
GLYCOL 2
ISOPAR E
POLY C
ISOPRENE
VECTOR
SLAG WATER (LOC 37)
LGTI
SLAG WATER (LOC 37)
LGTI
STYRENE
VECTOR
SYNGAS
LGTI
WATER/STEAM
DOWANOLS
1,3-BUTADIENE
LHC 2
ACETYLENE
LHC 2
ANHYDROUS AMMONIA
CAUSTIC
BENZENE PLANT PYROLYSIS GAS
BENZENE
ETHANE
LHC 2
ETHYLENE
LHC 3
ETHYLENE OXIDE
GLYCOL 2
HYDROGEN
LHC 2
Dow Confidential
92124 90324 RCL 1368 84E189 84E186 84E188 84E190 RCL 84-008 B4E1B7 3108-46 84E191 RCL 83-018 86191A 86183A 94052 94052 92251 92251 92251 87063A 92100 93154 94052 94052 93154 93154 90003 87033J 93069 94065 94065 93069 92318 94015 86223D 86223C RCL 1181 85053A B6223G B6223F 90003 86223B
DSC DSC DTA DTA DTA DTA DTA DTA DTA DTA DTA DTA DTA DTA HOM DSC DSC DSC DSC DSC DSC HOM HOM DSC DSC HOM DSC DTA DSC DSC HOM DSC DSC DSC DTA DTA DTA DTA DTA DTA DSC DTA
REACTIVITY
NO EXO TO 200 C EXOAT 120 C NO EXO TO 200 C EXO AT 275 C NO EXO TO 250 C EXO AT 300 C EXO AT 276 C NO EXO TO 200 C NO EXO TO 400 C NONE NO EXO TO 400 C NO EXO TO 150 C NO EXO TO 375 C NO EXO TO 375 C NO EXO AT 22 C NO EXO TO 225 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 350 C NO EXO TO 350 C NO EXO AT 22 C NO EXO AT 22 C NO EXO TO 108 C NO EXO TO 250 C NO EXO AT 22 C EXOAT 125 C NO EXO TO 260 C NO EXO TO 200 C NO EXO TO 250 C NO EXO AT 22 C NO EXO TO 200 C NO EXO TO 400 C NO EXO TO 315 C NO EXO TO 210 C NO EXO TO 210 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 350 C NO EXO TO 250 C NO EXO TO 210 C
17
TABLE II. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY SEALANT)
SEALANT
TEAM LEAK REPAIRS VALVEPACK B TEAM LEAK REPAIRS VALVEPACK B TEAM LEAK REPAIRS VALVEPACK B TEAM LEAK REPAIRS VALVEPACK B TEAM LEAK REPAIRS VALVEPACK B + Q FIBERS TEAM LEAK REPAIRS VALVEPACK B-EC TEAM LEAK REPAIRS VALVEPACK B-EC TEAM LEAK REPAIRS VALVEPACK BEC TEAM LEAK REPAIRS VALVEPACK E TEAM LEAK REPAIRS VALVEPACK EPX TEAM LEAK REPAIRS VALVEPACK EPX TEAM LEAK REPAIRS VALVEPACK ER TEAM LEAK REPAIRS VALVEPACK QX TEAM LEAK REPAIRS VALVEPACK QX TEAM LEAK REPAIRS VALVEPACK OX TEAM LEAK REPAIRS VALVEPACK OX TEAM LEAK REPAIRS VALVEPACK OX TEAM LEAK REPAIRS VALVEPACK OX TEAM LEAK REPAIRS VALVEPACK OX (TEFLON) TORLON SN T210 SEALANT ULTRAMETAL LIQUID METAL (CURED) UNCURED EPDM RUBBER USADURIAN SBR RUBBER VITON YELLOW DOT "O'-RING VITON YELLOW DOT *0*-RINQ VITON YELLOW DOT `O'-RING WHITE BAKERSEAL SEALANT WHITE DURDICK 800 Q WKM VALVEPACK 114 4 *STP* LUBRICANT
PROCESS CHEMICAL
PLANT
METHANE
LHC 2
PROPANE
LHC 2
PROPYLENE
LHC 2
VINYL CHLORIDE
VINYL 1
ETHYLENE
POLY C
1.3-BUTADIENE
VECTOR
DOWTHERM G
VINYL 2
CRACKED GAS
LHC 2
DOWANOLOB
DOWANOLS
SYNGAS
LGTI
WATER/STEAM
POWER 2
DOWTHERM G
VINYL 2
ETHYLENE
LHC 3
PROPYLENE
LHC 3
DOWTHERM G
VINYL 2
DOWTHERM G
VINYL 2
FLARE DRUM LIQUID
LHC 2
PER/TET (CRUDE)
SOLVENTS/E DC
CHLORINE (LIQUID)
CHLOR-ALKALI 2
CHLORINE (LIQUID)
CHLORINE
SHELL THERMIA C OIL WITH DISSOLVED HCL
METHANES
CHLORINE
CHLOR-ALKALI 2
CHLORINE (LIQUID)
CHLORINE
DOWANOL EB
DOWANOLS
DOWANOL PM
DOWANOLS
ETHYLENE OXIDE
DOWANOLS
WATER/STEAM
LHC 3
CHLORINE VENT GAS
CHLORINE
ETHYLENE DICHLORIDE (CRUDE - EDC + VCM + HCL) VINYL 2
REF. NO. TEST
86223E
DTA
B6223H
DTA
B6223A
DTA
3108-46
DTA
B6183B
DTA
93062
DSC
92100
DSC
90236
DSC
RCL 1491 DTA
92318
DSC
91152
DSC
92100
DSC
93207
DSC
93207
DSC
92100
DSC
93154
HOM
91058
DSC
89141
DSC
RCL-92-9764 ARC
RCL-93-9799 ARC
93028
DSC
ARC 91-648 ARC
ARC 94-853 ARC
92339
DSC
92339
DSC
92339
DSC
4792-25A DSC
4792-20A DSC
93066
DSC
REACTIVITY
NO EXO TO 250 C NO EXO TO 300 C NO EXO TO 210 C NONE NO EXO TO 325 C EXOAT 105 C NO EXO TO 350 C NO EXO TO 250 C NO EXO TO 350 C NO EXO TO 400 C NO EXO TO 350 C NO EXO TO 350 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 150 C EXOAT 145 C NO EXO TO 250 C EXOAT 109 C NO EXO TO 250 C EXO AT 98 C EXO AT 59 C NO EXO TO 250 C NO EXO TO 250 C EXOAT 186C EXO AT 360 C EXO AT 35 C EXOAT 130 C
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Dow Confidential
CONFTDFNT TAl
PLANT
BENZENE BENZENE BENZENE BRINE BRINE BRINE BRINE CAUSTIC CAUSTIC CAUSTIC CAUSTIC CAUSTIC CAUSTIC CAUSTIC CAUSTIC CAUSTIC CAUSTIC CAUSTIC CAUSTIC CAUSTIC CAUSTIC CAUSTIC CHLOR-ALKALI 2 CHLOR-ALKALI 2 CHLOR-ALKALI 2 CHLOR-ALKALI 2 CHLOR-ALKALI 2 CHLOR-ALKALI 2 CHLOR-ALKALI 2 CHLOR-ALKALI 2 CHLOR-ALKALI 2 CHLOR-ALKALI 2 CHLOR-ALKALI 2 CHLOR-ALKALI 2 CHLOR-ALKALI 2 CHLOR-ALKALI 2 CHLOR-ALKALI 2 CHLOR-ALKALI 2 CHLOR-ALKALI 2 CHLOR-ALKALI 2 CHLOR-ALKALI 2 CHLORINE
38
TABLE 111. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PLANT)
PROCESS CHEMICAL
SEALANT
REF. NO. TEST
BENZENE (CRUDE) BENZENE (CRUDE) BENZENE PLANT PYROLYSIS GAS BRINE BRINE ETHYLENE ETHYLENE ANHYDROUS AMMONIA ANHYDROUS AMMONIA ANHYDROUS AMMONIA CAUSTIC (25%) SODIUM HYDROXIDE (10%) SODIUM HYDROXIDE (10%) SODIUM HYDROXIDE (40%) - HE-201 SODIUM HYDROXIDE (50%) SODIUM HYDROXIDE (50%) SODIUM HYDROXIDE (50%) SODIUM HYDROXIDE (50%) SODIUM HYOROXIDE (50%) + AMMONIA SODIUM HYDROXIDE (50%) + AMMONIA SODIUM HYDROXIDE (50%) NH40H WATER/STEAM AIR AIR AIR AIR CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE (LIQUID) CHLORINE (LIQUID) HYDROGEN SODIUM HYOROXIDE (50%) SULFURIC ACID (96%) SULFURIC ACID (96%) WATER/STEAM CHLORINE AT-200 SCRUBBER EFFLUENT
STEAM & PROCESS SP-1011 STEAM & PROCESS SP-103 TEAM LEAK REPAIRS VALVEPACK B TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS SEALANT 416 TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS VALVEPACK B TEAM LEAK REPAIRS PRI-102C (THREADS) PIG REPAIR PUTTY EPOXY STICK PIG REPAIR PUTTY EPOXY STICK STEAM & PROCESS SP-5000 SERVICE GROUP INC 107 A&B BONDER TEAM LEAK REPAIRS SEALANT #16 TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS SEALANT 2X TEAM LEAK REPAIRS SEALANT #16 TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS TC-4 EPOXY BONOER TEAM LEAK REPAIRS SEALANT 2X SP-1011 (30 MIN CURE 1ST RUN) SP-1011 (30 MIN CURE 2ND RUN) SP-1011 (30 MIN CURE 3RD RUN) SP-1011 (UNCURED SAMPLE) LOCTITE #56747 PST LOCTITE #59231 (WITH TEFLON) LOCTITE 271 ADHESIVE/SEALANT PTFE/KEVLAR SILASTIC 732-RTV SILICONE RUBBER STEAM & PROCESS SP-1011 UNCURED EPOM RUBBER STEAM & PROCESS SP-292 TEAM LEAK REPAIRS VALVEPACK OX (TEFLON) STEAM & PROCESS SP-2000 STEAM & PROCESS SP-60 STEAM & PROCESS SP-2007 STEAM & PROCESS SP-2026 STEAM & PROCESS SP-2015 CELL PUTTY STEAM & PROCESS SP-2000
84E031
DTA
84E030
DTA
85053A
DTA
94052
HOM
94052
DSC
94052
HOM
94052
DSC
RCL 1010 DTA
RCL 1007 DTA
RCL 1181 DTA
91098
DSC
92137
DSC
92137
HOM
4791-30B DSC
89223
DSC
RCL 1008 DTA
RCL 1005 DTA
871121
DSC
RCL 1009 DTA
RCL 1006 DTA
RCL 1368 DTA
871122
DSC
4791-35A DSC
4791-35A DSC
4791-35A DSC
4791-35A DSC
90282
DSC
90282
ARC
89071
DSC
89322
DSC
B4E100
DTA
89322
DSC
ARC 91-648 ARC
RCL-93-9831 ARC
RCL-92-9764 ARC
93199
HOM
92326
DSC
85101B
DTA
85101A
DTA
84E134
DTA
ARC 91-647 ARC
91296
DSC
Dow Confidential
REACTIVITY
NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 300 C NO EXO AT 22 C NO EXO TO 225 C NO EXO AT 22 C NO EXO TO 108 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 300 C NO EXO TO 200 C EXOAT 150 C NO EXO AT 25 C EXO AT 90 C NO EXO TO 250 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 230 C NO EXO TO 190 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 285 C EXOAT 160 C EXO AT 60 C EXO AT 273 C EXOAT 178 C EXOAT 115C EXO AT 33 C EXO AT -5 C EXO AT 48 C EXOAT 160 C EXO AT 40 C EXO AT 98 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 25 C NO EXO TO 200 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 250 C EXO AT 86 C EXO AT 40 C
DO A 0 ? ? 1 1 7
CONFTDFNTTAl
PLANT
CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE
39
TABLE III. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PLANT)
PROCESS CHEMICAL
AT-200 SCRUBBER EFFLUENT BRINE INTO AT-260 BRINE OUT AT-260 CELL EFFLUENT (10% SODIUM HYDROXIDE) CELL EFFLUENT (10% SODIUM HYDROXIDE) CELL EFFLUENT (10% SODIUM HYDROXIDE) CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE (LIQUID) CHLORINE (LIQUID) CHLORINE (LIQUID) CHLORINE (LIQUID) CHLORINE (LIQUID) CHLORINE (LIQUID) CHLORINE (LIQUID) CHLORINE (LIQUID) CHLORINE (LIQUID) CHLORINE (LIQUID) CHLORINE (LIQUID) CHLORINE (LIQUID) CHLORINE (LIQUID) CHLORINE (LIQUID) CHLORINE (LIQUID) CHLORINE (LIQUID) CHLORINE (TRACE WATER, HCBD)
SEALANT
STEAM & PROCESS SP-CM PROTECTO-COAT 800 G PROTECTO-COAT 800 G STEAM & PROCESS SP-1011 STEAM & PROCESS SP-2000 STEAM & PROCESS SP-60 ANCHOR VALVE PACKING 375 ANCHOR VALVE PACKING 4205 BEL20NA CERAMIC-R METAL BELZONA E-METAL BELZONA SUPER METAL CHRYSOTILE ASBESTOS FIBER GSKT CONLEY TEFLON PASTE FELPOXY STEEL GARLOCK VALVE PACKING 6130 GARLOCK VALVE PACKING 7130 GORE PACKING PTFE W/ GRAPHITE GORTEX SEALANT (TEFLON) JOHN CRANE VALVE PKG C-1050 JOHN CRANE VALVE PKG C-60 JOHN CRANE VALVE PKG C-7762 JOHN MANSVILLE VALVE PKG AF-5331 PARKER HANNIFIN VALVE PKG 2287-BR PARKER HANNIFIN VALVE PKG 2287-GL SEAL-ITT #34 CASTROL BRAYCOTE 1728 COPALTITE HIGH TEMPERATURE SEALANT DOW CORNING 3120 RTV SEALANT GARLOCK 900 GASKET GOR-TEX GR GASKET GRAFOIL GHE KADEL SN N-75 SEALANT KLINGER K-61 GASKET PERMATEX FORM-A-GASKET 2 (CURED) STEAM & PROCESS SP-2026 STEAM & PROCESS SP-300D STEAM & PROCESS SP-375 STEAM & PROCESS SP-CM STEAM & PROCESS SP-TFLO TORLON SN T210 SEALANT USADURIAN SBR RUBBER CPE-TAC
Dow Confidential
REF. NO TEST
91296
DSC
4792-20A DSC
4792-20A DSC
92180
DSC
92180
DSC
92160
DSC
B4E138
DSC
84E005
DTA
85172D
DTA
84E184
DTA
85172A
DTA
90022
DSC
RCL 83-004 DTA
84E183
DTA
84E007
DTA
84E008
DTA
86206A
DTA
ARC 91-616 ARC
84E141
DSC
84E140
DSC
B4E003
DTA
84E144
DTA
84E142
DSC
84E143
DSC
90277
DSC
ARC 91-585 ARC
ARC 94-851 ARC
ARC 94-848 ARC
ARC 92-737 ARC
ARC 93-771 ARC
ARC 91-586 ARC
RCL-93-9809 ARC
ARC 92-738 ARC
ARC 94-855 ARC
ARC 92-692 ARC
ARC 92-711 ARC
RCL-93-9830 ARC
ARC 92-708 ARC
ARC 92-715 ARC
RCL-93-9799 ARC
ARC 94-853 ARC
84E211
DTA
REACTIVITY
NO EXO TO 250 C EXOAT 155 C EXO AT 58 C SL EXOAT 180 C SL EXOAT 170 C SL EXOAT 194 C EXO < 30 C EXOAT 136 C EXO AT 35 C EXO < 25 C EXO AT 30 C NO EXO TO 250 C EXOAT 100 C EXO < 25 C EXO AT -83 C EXO AT -76 C NO EXO TO 200 C NO EXO TO 200 C EXO AT 36 C EXO AT 46 C EXO AT 102 C EXO < 30 C EXO < 30 C EXO AT 38 C EXO AT 90 C EXO AT 167 C EXOAT 113 C EXO AT 36 C EXO AT 26 C NO EXO TO 175 C EXO AT 104 C EXO AT 182 C EXO AT 27 C EXO AT 22 C EXO AT 20 C EXO AT 20 C NO EXO TO 250 C EXO AT 20 C NO. EXO TO 175 C EXO AT 109 C EXO AT 59 C EXOAT 135 C
CONFTOFNTTAl
PLANT
CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE CHLORINE DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS
40
TABLE III. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PLANT)
PROCESS CHEMICAL
CHLORINE VENT GAS CHLORINE VENT GAS CHLORINE VENT GAS CHLORINE VENT GAS FREON 12 REGAL OIL 32 SODIUM HYDROXIDE (10%) SODIUM HYDROXIDE (10%) SODIUM HYDROXIDE (10%) SODIUM HYDROXIDE (10%) SODIUM HYDROXIDE (50%) SODIUM HYDROXIDE (50%) SODIUM HYDROXIDE (50%) SULFURIC ACID (96%) SULFURIC ACID (96%) SULFURIC ACID (96%) AMMONIA (AQUEOUS) AMMONIUM HYDROXIDE ANHYDROUS AMMONIA ANHYDROUS AMMONIA ANHYDROUS AMMONIA ANHYDROUS AMMONIA DOWANOL DB DOWANOL DF 250 DOWANOL DF 250 DOWANOL DPM DOWANOL DPM DOWANOL EB DOWANOL EB DOWANOL EB DOWANOL EB DOWANOL EB DOWANOL EB DOWANOL EB DOWANOL EB DOWANOL EB SERIES (EB.DB.TBH) DOWANOL PM DOWANOL PM DOWANOL PM DOWANOL PM DOWANOL PM DOWANOL PM
SEALANT
DERAKANE 470 (CURED 6/14/88) IPI EPOXY (CURED) RED PRIMER (CURED) WHITE DURDICK 800 G STEAM & PROCESS SP-2026 SEAL-ITT +34 SEAL-ITT #34 STEAM & PROCESS SP-1011 STEAM & PROCESS SP-2000 STEAM & PROCESS SP-60 BELZONA CERAMIC-R METAL BELZONA E-METAL BELZONA SUPER METAL BELZONA CERAMIC-R METAL BELZONA E-METAL BELZONA SUPER METAL TEAM LEAK REPAIRS PTFE SEALANT TEAM LEAK REPAIRS SEALANT IX DOW CORNING 44 LUBRICANT FEL-PRO HI-TEMP NICKEL EASE STEAM & PROCESS SP-1015 TEAM LEAK REPAIRS PTFE SEALANT TEAM LEAK REPAIRS VALVEPACK E TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS SEALANT #6 EPR EO 962 `O'-RING EPR RED DOT `O'-RING STEAM & PROCESS SP-1011 STEAM & PROCESS SP-102 STEAM & PROCESS SP-3100 STEAM & PROCESS SP-60 STEAM & PROCESS SP-CM VITON YELLOW DOT `0`RING STEAM & PROCESS SP-1015 EPR EO 962 `O'-RING EPR RED DOT `O'-RING STEAM & PROCESS SP-1011 STEAM & PROCESS SP-102 STEAM & PROCESS SP-3100 STEAM & PROCESS SP-60
Dow Confidential
REF. NO. TEST
4792-21A 4792-21A 4792-20A 4792-20A 90051 90277 90277 92180 92180 92180 85172F 84E180 85172C 85172E 84E213 85172B RCL 1039 91239 93121 93121 RCL 1232 RCL 1038 RCL 1491 92016 92016 92016 92016 92339 92339 93014 93014 93014 93014 93014 92339 84E104 92339 92339 93014 93014 93014 93014
DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DTA DTA DTA DTA DTA DTA DTA DSC DSC DSC DTA DTA DTA HOM DSC HOM DSC DSC DSC DSC DSC DSC DSC DSC DSC DTA DSC DSC DSC DSC DSC DSC
REACTIVITY
EXO AT 30 C NO EXO TO 250 C EXO AT 40 C EXO AT 35 C NO EXO TO 250 C EXOAT 165 C EXOAT 166 C EXOAT 180 C EXOAT 170 C EXO AT 194 C NO EXO TO 250 C EXOAT 150 C NO EXO TO 250 C NO EXO TO 250 C EXO < 30 C NO EXO TO 250 C NO EXO TO 300 C NO EXO TO 175 C NO EXO TO 130 C NO EXO TO 155 C NO EXO TO 250 C NO EXO TO 320 C NO EXO TO 350 C NO EXO AT 25 C NO EXO TO 200 C SL EXO AT 25 C NO EXO TO 200 C NO EXO TO 210 C NO EXO TO 250 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 250 C EXO AT 275 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 300 C
DO A 0 ? ? 1 1 9
CONFTDFNTTA1
PLANT
DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS DOWANOLS GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL f GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1
11
TABLE III. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PLANT)
PROCESS CHEMICAL
SEALANT
REF. NO. TEST
DOWANOL PM
STEAM & PROCESS SP-CM
DOWANOL PM
TEAM LEAK REPAIRS SEALANT #6
DOWANOL PM
TEAM LEAK REPAIRS SEALANT #6
DOWANOL PM
VITON YELLOW DOT `O'-RING
DOWANOL PM SERIES (PM.DPM.TPM)
STEAM & PROCESS SP-2000
DOWANOL PM, DPM, TPM, KOH MIX (DV-114)
TEAM LEAK REPAIRS VALVEPACK AX
DOWANOL TBH AND HIGHERS (T-130)
TEAM LEAK REPAIRS VALVEPACK AX
DOWANOL TPM
TEAM LEAK REPAIRS SEALANT #6
DOWANOL TPM
TEAM LEAK REPAIRS SEALANT #6
DOWANOL TPM & HIGHERS
TEAM LEAK REPAIRS VALVEPACK AX
ETHANOLAMINES (MEA.DEA.TEA)
STEAM & PROCESS SP-1012
ETHANOLAMINES (MEA.DEA.TEA)
STEAM & PROCESS SP-2007
ETHANOLAMINES (MEA.DEA.TEA)
TEAM LEAK REPAIRS SEALANT #6
ETHYLENE OXIDE
EPR EO 962 'O'-RING
ETHYLENE OXIDE
EPR RED DOT `O'-RING
ETHYLENE OXIDE
VITON YELLOW DOT `O'-RING
MEA.DEA.TEA.KOH (REACTOR EFFLUENT)
TEAM LEAK REPAIRS SEALANT 6
SODIUM HYDROXIDE (50%)
STEAM & PROCESS SP-1015
WATER/STEAM
TEAM LEAK REPAIRS VALVEPACK AX
CONDENSATE (C-16)
TEAM LEAK REPAIRS SEALANT 1BX
D-270 LIQUIO
TEAM LEAK REPAIRS F14 FIBERS
ETHYLENE OXIDE
GRAPHONICS GASKET
HYDROLYZER BOTTOMS
SYNTHO-GLASS NEPTUNE RESEARCH
MONOPROPYLENE GLYCOL WATER
TEAM LEAK REPAIRS SEALANT 18X
MONOPROPYLENE GLYCOL WATER
TEAM LEAK REPAIRS SEALANT 2X
OIL BOTTOMS (T-102C TOWER)
TEAM LEAK REPAIRS SEALANT #6
PROPYLENE DICHLORIDE. CI2. AIR. HCI, WATER (E-IBi STEAM & PROCESS SP-1360
PROPYLENE DICHLORIDE, CI2, AIR. HCI. WATER (E-IB STEAM & PROCESS SP-2026
PROPYLENE DICHLORIDE, CI2, AIR. HCI. WATER (E-IB TEAM LEAK REPAIRS SEALANT #11
PROPYLENE DICHLORIDE. 02, AIR, HCI, WATER (E-IB TEAM LEAK REPAIRS SEALANT DB-2
PROPYLENE GLYCOL
TEAM LEAK REPAIRS SEALANT #6
PROPYLENE GLYCOL (2%) IN WATER
FURMANITE FSC-1/2A
PROPYLENE GLYCOL (2%) IN WATER
FURMANITE FSC-1/2A
PROPYLENE GLYCOL (2%) IN WATER
FURMANITE FSC-3A
PROPYLENE GLYCOL (2%) IN WATER
FURMANITE FSC-3A
PROPYLENE OXIDE
GRAFOIL VALVE PACKING
PROPYLENE OXIDE
TEAM LEAK REPAIRS SEALANT 6
R-2 & R-102 HYDROLYZER BTMS
STEAM & PROCESS SP-2000
WASTE WATER EFFLUENT (P-5)
TEAM LEAK REPAIRS SEALANT 18X
WATER/STEAM
TEAM LEAK REPAIRS SEALANT #6
WATER/STEAM
TEAM LEAK REPAIRS SEALANT 18X
WATER/STEAM
TEAM LEAK REPAIRS SEALANT 2XH
Dow Confidential
93014
DSC
92016
HOM
92016
DSC
92339
DSC
84E105
DTA
92251
DSC
92251
DSC
92016
HOM
92016
DSC
92251
DSC
84E106
DTA
84E107
DTA
84E108
DTA
92339
DSC
92339
DSC
92339
DSC
RCL1270.71 DTA
RCL 1233 DTA
94015
DSC
90266
DSC
91169
DSC
92050
DSC
91175
DSC
91146
DSC
91146
DSC
4791-36B DSC
RCL 1561 DTA
RCL 1560 DTA
RCL 1558 DTA
RCL 1559 DTA
91199
DSC
92026
DSC
92026
HOM
92026
DSC
92026
HOM
B4E068
DTA
88285
DSC
89378
DSC
90264
DSC
90041
DSC
RCL-90-2661 DSC
91159
DSC
REACTIVITY
NO EXO TO 300 C SL EXO AT 25 C NO EXO TO 200 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 300 C NO EXO TO 300 C SL EXO AT 25 C NO EXO TO 200 C NO EXO TO 300 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 250 C EXO ATI 95 C EXOAT 195 C EXOAT 186 C NO EXO TO 300 C NO EXO TO 250 C NO EXO TO 315 C NO EXO TO 300 C NO EXO TO 250 C NO EXO TO 194 C NO EXO TO 150 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 190 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 190 C NO EXO TO 250 C NO EXO TO 200 C NO EXO AT 22 C NO EXO TO 200 C NO EXO AT 22 C NO EXO TO 235 C EXO AT 200 C NO EXO TO 250 C NO EXO TO 250 C NO EXO 70 335 C NO EXO TO 308 C NO EXO TO 300 C
42
TABLE III. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PLANT)
PLANT
PROCESS CHEMICAL
SEALANT
REF. NO. TEST
GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2 GLYCOL 2
n oo Zo "H --( V -T\ O
z \> H \) -f
C-2 RECYCLE GAS C-2 RECYCLE GAS ETHYL CHLORIDE ETHYL CHLORIDE ETHYLENE GLYCOL ETHYLENE GLYCOL ETHYLENE GLYCOL ETHYLENE GLYCOL ETHYLENE GLYCOL (1%) IN CONDENSATE ETHYLENE GLYCOL (1%) IN WATER ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE ETHYLENE OXIDE REACTOR OUTLET GAS FLIGHTGARD 2000 HYDROGEN CHLORIDE HYDROGEN CHLORIDE MONOETHYLENE GLYCOL POTASSIUM CARBONATE (22%) IN WATER SULFURIC ACID SOLUTION (10 N) SULFURIC ACID SOLUTION (10 N) SULFURIC ACID SOLUTION (10 N) SULFURIC ACID SOLUTION (10 N) T-52 BTMS T-8-2 BOTTOMS TRIETHANOLAMINE TRIETHANOLAMINE TRIETHANOLAMINE WATER (E7F) WATER (E7F)
TEAM LEAK REPAIRS SEALANT 16X TEAM LEAK REPAIRS SEALANT X-36 GRAFOIL GHE GRAFOIL GHR FURMANITE FSC-6B MOLYKOTE 44 LUBRICANT STEAM & PROCESS SP-1011 STEAM & PROCESS SP-2000 STEAM & PROCESS SP-1011 FURMANITE FSC-6B 3M NEOPRENE 80 CONTACT ADHESIVE 3M NEOPRENE 80 CONTACT ADHESIVE CHEMRA2 O-RING MATERIAL E0962 O-RING MATERIAL FURMANITE FSC-5B GRAFOIL GHE GRAPHONICS GASKET (ADHESIVE STRIP) STEAM & PROCESS SP-1011 STEAM & PROCESS SP-1012 STEAM & PROCESS SP-106 STEAM & PROCESS SP-109 STEAM & PROCESS SP-2000 STEAM & PROCESS SP-60 TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK B LAMONS SPIROSEAL GSKT (GRAPHITE) D.E.R. 331 EPOXY RESIN FURMANITE FSC-5B FURMANITE FSC-6B FURMANITE FSC-6B TEAM LEAK REPAIRS SEALANT #6 GRAFOIL GHE GASKET GRAPHITE MAT! GRAFOIL GHE GASKET GRAPHITE MAT L GRAFOIL GHE GASKET METAL MAT'L GRAFOIL GHE GASKET METAL MATTTEAM LEAK REPAIRS SEALANT #6 & F-14 FIBERS FURMANITE FSC-5B MOLYKOTE 44 LUBRICANT STEAM & PROCESS SP-1011 STEAM & PROCESS SP-2000 TEAM LEAK REPAIRS 16X & F-10 & F-14 FIBERS TEAM LEAK REPAIRS SEALANT 16X & F-10 FIBERS
91117 91115 90311 90311 92143 94030 94030 94030 92194 92143 93034 93034 89147 89147 90318 90165 93077 94030 85197D RCL 1230 85197B 94030 85197A 90003 90003 90131 90270 92143 92143 92143 91092 93011 93011 93011 93011 92160 93131 94030 94030 94030 92160 92160
Dow Confidential
DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC HOM DSC DSC DSC DSC DSC DSC DTA DTA DTA DSC DTA DSC DSC DSC DSC DSC DSC DSC DSC DSC HOM DSC HOM DSC DSC DSC DSC DSC DSC DSC
REACTIVITY
NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 200 C EXO AT 265 C NO EXO TO 350 C NO EXO TO 350 C NO EXO TO 250 C NO EXO TO 165 C EXO AT 190 C EXO AT 22 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 200 C NO EXO TO 300 C NO EXO TO 250 C EXO AT 120 C EXO AT 255 C NO EXO TO 250 C EXO AT 250 C EXO AT 320 C NO EXO TO 350 C EXO AT 125 C NO EXO TO 250 C EXO AT 360 C NO EXO TO 100 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 250 C NO EXO AT 22 C EXOAT 137 C NO EXO TO 250 C NO EXO TO 200 C NO EXO TO 200 C EXO AT 240 C EXO AT 320 C EXO AT 319 C NO EXO TO 200 C NO EXO TO 200 C
PLANT
GLYCOL 2
LGTI
LGTI
LGTI
LGTI
LGTI
LGTI
LGTI
LGTI
LGTI
LGTI
LGTI
LGTI
LGTI
LGTI
LGTI
LGTI
LGTI
LGTI
LGTI
LGTI
LGTI
LGTI
LGTI
LGTI
LGTI
LGTI
LGTI
LGTI
LGTI
LGTI
LGTI
LGTI
LGTI
LGTI LGTI LGTI LGTI LGTI LGTI LGTI LGTI
D OO Z3 *n
i> 3 33
v
H \> --1 --'1 x> \>
>3
TABLE III. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PLANT)
PROCESS CHEMICAL
SEALANT
REF. NO. TEST
WATER WITH <1% GLYCOLS ACID GAS BLEND ACID GAS BLEND ACID GAS BLEND AIR (INSTRUMENT) AIR (INSTRUMENT) AMMONIA (15%) - D-270 AMMONIA (15%) - D-271 AMMONIA (20% IN H20) COAL (LOC 33A) COAL (LOC 33A) COAL CHAR SLURRY (LOC 35C) COAL CHAR SLURRY (LOC 35C) HYDROGEN SULFIDE GAS HYDROGEN SULFIDE GAS HYDROGEN SULFIDE GAS METHYL DIETHANOLAMINE METHYL DIETHANOLAMINE METHYL DIETHANOLAMINE METHYL DIETHANOLAMINE (LOC48)
NITROGEN SLAG (LOC 37B) SLAG (LOC 37B) SLAG WATER (LOC 37) SLAG WATER (LOC 37) SOUR CONDENSATE SULFUR (LOC 24) SULFUR (LOC 24) SULFUR (LOC 24) SYNGAS SYNGAS SYNGAS SYNGAS SYNGAS SYNGAS SYNGAS SYNGAS SYNGAS SYNGAS SYNGAS BLEND SYNGAS BLEND SYNGAS BLEND
STEAM & PROCESS SP-1011 STEAM & PROCESS SP-1011 STEAM & PROCESS SP-60 STEAM & PROCESS SP-CM STEAM & PROCESS SP-102 STEAM & PROCESS SP-60 STEAM & PROCESS SP-60 STEAM & PROCESS SP-102 TEAM LEAK REPAIRS SEALANT #6 STEAM & PROCESS SP-102 STEAM & PROCESS SP-60 STEAM & PROCESS SP-102 STEAM & PROCESS SP-60 STEAM & PROCESS SP-3100 STEAM & PROCESS SP-770 TEAM LEAK REPAIRS SEALANT 16X NICKEL ANTISEIZE NICKEL ANTISEIZE & PERMATEX PERMATEX STEAM & PROCESS SP-CM STEAM & PROCESS SP-60 STEAM & PROCESS SP-102 STEAM & PROCESS SP-60 TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS SEALANT *6 STEAM & PROCESS SP-1011 STEAM & PROCESS SP-102 STEAM & PROCESS SP-60 NEPTUNE RESEARCH SYNTHO-GLASS STEAM & PROCESS SP-3000 1 STEAM & PROCESS SP-429 TEAM LEAK REPAIRS SEALANT 18X TEAM LEAK REPAIRS SEALANT 19X TEAM LEAK REPAIRS SEALANT 2X TEAM LEAK REPAIRS SEALANT 2XH TEAM LEAK REPAIRS SEALANT RF 300 TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK EPX STEAM & PROCESS SP-1011 STEAM & PROCESS SP-102 STEAM & PROCESS SP-60
Dow Confidential
92194 4791-42A 4791-42A 4791-42A 4791-42A 4791-42A 4791-5A 4791-5A 89336 4791-6A 4791-6A 4791-6A 4791-6A 93022 93022 93032 93098 93098 93098 4791-5A 4791-43A 4791-6A 4791-6A 94065 94065 870901 4791-5A 4791-5A 4791-5A 93036 93125 93125 92318 92316 93123 93123 93072 92318 92318 4791-42A 4791-43A 4791-43A
DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC HOM DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC
REACTIVITY
NO EXO TO 250 C EXO AT 45 C NO EXO TO 300 C EXO AT 50 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 235 C NO EXO TO 235 C NO EXO TO 235 C EXOAT 165 C NO EXO TO 235 C NO EXO TO 300 C NO EXO TO 300 C EXO AT 316 C EXOAT 125 C EXOAT 160 C NO EXO TO 200 C NO EXO TO 250 C EXO AT 350 C NO EXO TO 235 C NO EXO TO 235 C NO EXO TO 250 C NO EXO AT 22 C EXO AT 85C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 500 C NO EXO TO 500 C NO EXO TO 285 C NO EXO TO 400 C NO EXO TO 400 C EXO AT 362 C NO EXO TO 500 C NO EXO TO 500 C NO EXO TO 400 C NO EXO TO 400 C EXO AT 47 C EXOAT 160 C EXO AT 365 C
nn a 02p ip :
CONFTDFNTTAI
PLANT
LGTI LQTI LQTI LHC 2 LHC 2 LHC 2 LHC 2 LHC 2 LHC 2 LHC 2 LHC 2 LHC 2 LHC 2 LHC 2 LHC 2 LHC 2 LHC 2 LHC 2 LHC 2 LHC 2 LHC 2 LHC 2 LHC 2 LHC 2 LHC 2 LHC 2 LHC 2 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3
44
TABLE III. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PLANT)
PROCESS CHEMICAL
SEALANT
REF. NO. TEST
WATER (LOC T-144) WATER (LOCT-144) WATER/STEAM 1,3-BUTADIENE ACETYLENE CRACKED GAS CRACKED GAS CRACKED GAS CRACKED GAS CRACKED GAS (2C-50) CRACKED GAS (2C-50) CRACKED GAS (2C-50) CRACKED GAS (2C-50B) CRACKED GAS (H2,C1,C2,C3,C4 .HIGHERS) DIMETHYL SULFIDE ETHANE ETHANE/ETHYLENE (2C-52 OVERHEAD GAS) FLARE DRUM LIQUID HYDROGEN METHANE PROPANE PROPYLENE PROPYLENE PROPYLENE (2C-54 OVERHEAD) SILICONE SWS-101 SILICONE SWS-101 SILICONE SWS-101 1,3-BUTADIENE 1.3-BUTADIENE BENZENE BENZENE BENZENE-TOLUENE-XYLENE (T-1602) BENZENE-TOLUENE-XYLENE (T-1602) BENZENE-TOLUENE-XYLENE (T-1602) BETZ BALANCED POLYMER 68701 BETZ BALANCED POLYMER 68701 C-450 FEED TO C5S + LITES C-450 FEED TO C5S LITES C-500 FEED PYGAS + LITES C-500 FEED PYGAS + LITES CRACKED GAS D-1220 BOILER BLOWDOWN
STEAM & PROCESS SP-102
4791-5A
STEAM & PROCESS SP-60
4791-5A
TEAM LEAK REPAIRS SEALANT PRI-102C
93088
TEAM LEAK REPAIRS VALVEPACK B
86223D
TEAM LEAK REPAIRS VALVEPACK B
86223C
SAFE SEAL - CHEMOLA TEFLON
94033
SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) 94033
SAFE SEAL MULTIPAK (JOHN CRANE 6KB)
94033
TEAM LEAK REPAIRS VALVEPACK BEC
90236
FURMANITE FSC-46D (TEFLON 300)
93135
STEAM & PROCESS SP-102
92065
STEAM & PROCESS SP-CM
92065
CHESTERTON 858 PUTTY - PARTS A & B
92104
TEAM LEAK REPAIRS SEALANT #6
RCL736
FURMANITE FSC-6B
91221
TEAM LEAK REPAIRS VALVEPACK B
86223G
TEAM LEAK REPAIRS SEALANT *6
RCL 1015
TEAM LEAK REPAIRS VALVEPACK OX
91058
TEAM LEAK REPAIRS VALVEPACK B
86223B
TEAM LEAK REPAIRS VALVEPACK B
86223E
TEAM LEAK REPAIRS VALVEPACK B
86223H
LOCTITE 290
92148
TEAM LEAK REPAIRS VALVEPACK B
86223A
LOCTITE 290
92148
SAFE SEAL - CHEMOLA TEFLON
94038
SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) 94038
SAFE SEAL MULTIPAK (JOHN CRANE 6KB)
94038
ROYAL PURPLE BARRIER FLUID 22
92169
ROYAL PURPLE BARRIER FLUID 22
92169
ROYAL PURPLE BARRIER FLUID 22
92169
ROYAL PURPLE BARRIER FLUID 22
92169
FURMANITE FSC-5B
92199
FURMANITE FSC-6B
92199
TEAM LEAK REPAIRS SEALANT #6 & F-14 FIBERS 92199
FURMANITE FSC-6B
94092
FURMANITE FSC-6B
94092
TEAM LEAK REPAIRS SEALANT #6
90385
TEAM LEAK REPAIRS SEALANT 2X
90385
TEAM LEAK REPAIRS SEALANT #6
90385
TEAM LEAK REPAIRS SEALANT 2X
90385
TEAM LEAK REPAIRS SEALANT DB-22
90243
TEAM LEAK REPAIRS SEALANT *18
89151
DSC DSC DSC OTA DTA DSC DSC DSC DSC DSC DSC DSC DSC DTA DSC DTA DTA DSC DTA DTA DTA DSC DTA DSC DSC DSC DSC DSC HOM DSC HOM DSC DSC DSC HOM DSC DSC DSC DSC DSC DSC DSC
Dow Confidential
REACTIVITY
NO EXO TO 260 C NO EXO TO 250 C NO EXO TO 230 C NO EXO TO 210 C NO EXO TO 210 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 250 C NO EXO TO 200 C NO EXO TO 400 C EXO AT 338 C NO EXO TO 150 C NO EXO TO 400 C NO EXO TO 180 C NO EXO TO 300 C NO EXO TO 200 C NO EXO TO 150 C NO EXO TO 210 C NO EXO TO 250 C NO EXO TO 300 C NO EXO TO 200 C NO EXO TO 210 C NO EXO TO 200 C EXOAT 126 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 200 C NO EXO AT 22 C NO EXO TO 200 C NO EXO AT 22 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 250 C SL. EXO AT 22 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 250 C
PLANT
LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3
n oo zo "n --i* i>
T| O
Z \) H \) -- --1k J> \>
CO
'5
TABLE III. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PLANT)
PROCESS CHEMICAL
SEALANT
REF. NO. TEST
DITCHWATER (LHC 2 & LGTI) DITCHWATER (LHC2 & LGTI) ETHYLENE ETHYLENE ETHYLENE FUELOIL FUEL OIL PROPANE PROPYLENE PROPYLENE REGAL 32 OIL PROPYLENE + REGAL 32 OIL PYGAS PYROLYSIS GAS PYROLYSIS GAS PYROLYSIS GASOLINE & RESIN OIL PYROLYSIS GASOLINE & RESIN OIL QUENCH OIL (C-10 BOTTOMS) QUENCH OIL (C-10 BOTTOMS) REGAL 32 OIL RESIN OIL RESIN OIL SODIUM HYDROXIDE (10%) SODIUM HYDROXIDE (10%) SODIUM HYDROXIDE (10%) SODIUM HYDROXIDE (10%) SODIUM HYDROXIDE (10%) SODIUM HYDROXIDE (10%) SS, CAST FE, CU. HAST. GRAPHITE. H20 WATER (COOLING TOWER) WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM
CURED AVANTI AV-202 MULTIGROUT CURED AVANTI AV-220 MULTIGROUT FURMANITE FSC-6B TEAM LEAK REPAIRS VALVEPACK B TEAM LEAK REPAIRS VALVEPACK GX ROYAL PURPLE BARRIER FLUID 22 ROYAL PURPLE BARRIER FLUID 22 TEAM LEAK REPAIRS SEALANT X-36 A&B TEAM LEAK REPAIRS VALVEPACK GX FURMANITE FSC-46D FURMANITE FSC-46D FURMANITE FSC-6B ROYAL PURPLE BARRIER FLUID 22 ROYAL PURPLE BARRIER FLUID 22 TEAM LEAK REPAIRS SEALANT 6 TEAM LEAK REPAIRS SEALANT X36 A&B FURMANITE FSC-5B FURMANITE FSC-6B TEAM LEAK REPAIRS SEALANT *6 ROYAL PURPLE BARRIER FLUID 22 ROYAL PURPLE BARRIER FLUID 22 FURMANITE FSC-1/2A FURMANITE FSC-1/2A FURMANITE FSC-1/2A FURMANITE FSC-6B FURMANITE FSC-6B FURMANITE FSC-6B DOW CORNING 111 LUB/SEALANT STERLING STUFFING BOX SEALANT #1 COPALTITE CEMENT SEALANT FURMANITE FSC-11C FURMANITE FSC-3A FURMANITE FSC-6B FURMANITE FSC-7C PLIDCO S.P. SEALANT (J-STICK) SERVICE GROUP INC SG-101 LIQUID SERVICE GROUP INC SG-101 SOLID SERVICE GROUP INC SG-101HT SERVICE GROUP INC SG-102 SOLID SERVICE GROUP INC SG-106 LIQUID SERVICE GROUP INC SG-108 A&B SERVICE GROUP INC SG-109
Dow Confidential
871171 871172 92306 86223F 93207 92169 92169 92124 93207 93164 93164 91100 92169 92169 92124 92124 91363 91363 90034 92169 92169 92093 92093 92093 92093 92093 92093 89271 91135 4792-25A 93020 90312 91052 90312 4792-25A 89272 89272 89272 89272 89272 89272 89272
DSC DSC DSC DTA DSC DSC HOM DSC DSC DSC HOM DSC DSC HOM DSC DSC DSC DSC DSC DSC HOM HOM DSC HOM HOM DSC HOM DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC
REACTIVITY
NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 350 C NO EXO TO 200 C NO EXO TO 200 C NO EXO AT 22 C NO EXO TO 160 C NO EXO TO 200 C NO EXO TO 210 C SL. EXO AT 22 C NO EXO TO 200 C NO EXO TO 200 C NO EXO AT 22 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 300 C NO EXO TO 300 C NO EXO TO 250 C NO EXO TO 200 C NO EXO AT 22 C NO EXO AT 25 C EXOAT 165 C NO EXO AT 22 C NO EXO AT 25 C NO EXO TO 200 C NO EXO AT 22 C NO EXO TO 250 C NO EXO TO 250 C EXOAT 130 C NO EXO TO 285 C NO EXO TO 360 C NO EXO TO 400 C NO EXO TO 320 C EXO AT 339 C NO EXO TO 320 C EXOAT 117 C NO EXO TO 350 C NO EXO TO 330 C NO EXO TO 340 C NO EXO TO 300 C NO EXO TO 300 C
46
TABLE III. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PLANT)
PLANT
PROCESS CHEMICAL
SEALANT
REF. NO. TEST
LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES
n oo ZO "n -4 >
o "n o z \> -i \)
WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CHLORINE (LIQUID) CHLOROFORM CHLOROFORM CHLOROFORM CHLOROFORM CHLOROFORM CHLOROFORM CHLOROFORM CHLOROFORM CP-1000 OIL SATURATED WITH HCL DIMETHYL ETHER DOWTHERM Q FREON 12 HO (15%) METHYL CHLORIDE (85%) HCI (15%) + METHYL CHLORIDE (85%) HO, Ml, M2, M3, M4 (T-851) HO, Ml. M2, M3, M4 (T-851) HO,Ml,M2,M3,M4 (K-350 SUCTION)
HYDROGEN CHLORIDE HYDROGEN CHLORIDE HYDROGEN CHLORIDE HYDROGEN CHLORIDE HYDROGEN CHLORIDE
T> \> --^
SERVICE GROUP INC SG-110 SOLID
89272
SERVICE GROUP INC SG-113
89272
SERVICE GROUP INC SG-201
89272
SERVICE GROUP INC SG-201HT
89272
SERVICE GROUP INC SG-250
89272
SERVICE GROUP INC SG-302
89272
SERVICE GROUP INC SG-303
89272
SERVICE GROUP INC SG-304
89272
SERVICE GROUP INC SG-306
89272
SERVICE GROUP INC SG-312
89272
SERVICE GROUP INC SGC FIBER
89272
SERVICE GROUP INC SGK FIBER
89272
WHITE BAKERSEAL SEALANT
4792-25A
SAFE SEAL - CHEMOLA TEFLON
94060
SAFE SEAL - CHEMOLA TEFLON
94060
SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) 94060
SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) 94060
SAFE SEAL MULTIPAK (JOHN CRANE 6KB)
94060
SAFE SEAL MULTIPAK (JOHN CRANE 6KB)
94060
SAFE SEAL - CHEMOLA TEFLON
94060
SAFE SEAL - CHEMOLA TEFLON
94060
SAFE SEAL - CHEMOLA TEFLON
94060
SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) 94060
SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) 94060
SAFE SEAL MULTIPAK (JOHN CRANE 6KB)
94060
SAFE SEAL MULTIPAK (JOHN CRANE 6KB)
94060
STEAM & PROCESS SP-CM
85133D
TEAM LEAK REPAIRS SEALANT DB-2
RCL 82-039
TEAM LEAK REPAIRS SEALANT #6
92288
TEAM LEAK REPAIRS SEALANT DB-2
RCL 82-043
STEAM & PROCESS SP-109
RCL 1458
STEAM & PROCESS SP-2007
RCL 82-037
STEAM & PROCESS SP-1011
RCL 1145
STEAM & PROCESS SP-103
RCL 1147
STEAM & PROCESS SP-2600
RCL 82-014
STEAM A PROCESS SP-CM
RCL 1400
STEAM & PROCESS SP-2000
RCL 82-119
SAFE SEAL - CHEMOLA TEFLON
94060
SAFE SEAL - CHEMOLA TEFLON
94060
SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) 94060
SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) 94060
SAFE SEAL MULTIPAK (JOHN CRANE 6KB)
94060
DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC HOM DSC HOM DSC HOM DSC ARC HOM DSC HOM DSC HOM DSC DTA DTA DSC DTA DTA DTA DTA DTA DTA DTA DTA HOM DSC HOM DSC HOM
Dow Confidential
REACTIVITY
NO EXO TO 275 C EXOAT 185 C EXO AT 75 C EXOAT 125 C NO EXO TO 325 C NO EXO TO 350 C EXO AT 260 C NO EXO TO 325 C NO EXO TO 290 C NO EXO TO 350 C NO EXO TO 325 C NO EXO TO 325 C EXO AT 360 C NO EXO AT 22 C EXO AT 297 C NO EXO AT 22 C EXO AT 325 C NO EXO AT 22 C EXOAT 185 C EXO AT 8 C NO EXO AT 22 C EXO AT 310 C NO EXO AT 22 C EXO AT 200 C NO EXO AT 22 C EXO AT 224 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 290 C NO EXO TO 100 C NO EXO TO 350 C EXO AT 145 C NO EXO TO 500 C NO EXO TO 300 C NO EXO TO 200 C SL. EXO AT 22 C NO EXO TO 450 C SL. EXO AT 22 C EXO AT 360 C EXO AT 22 C
no A
CONF TDFNT TAl
PLANT
METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES
17
TABLE III. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORT ED BY PLANT)
PROCESS CHEMICAL
SEALANT
REF. NO. TEST
HYDROGEN CHLORIDE HYDROGEN CHLORIDE (ANHYDROUS) HYDROGEN CHLORIDE (ANHYDROUS) Ml, M2, M3. M4, + HCI Ml, M2, M3, M4, + HD METHANES E-259 VENT (HCI,Ml,M2,M3) METHANES R-300 OUTLET (M1,M2,M3,M4,HCI) METHANOL METHANOL METHYL CHLORIDE METHYL CHLORIDE METHYL CHLORIDE METHYL CHLORIDE METHYL CHLORIDE METHYL CHLORIDE METHYL CHLORIDE METHYL CHLORIDE METHYL CHLORIDE METHYL CHLORIDE METHYL CHLORIDE METHYL CHLORIDE METHYLENE CHLORIDE METHYLENE CHLORIDE METHYLENE CHLORIDE METHYLENE CHLORIDE METHYLENE CHLORIDE METHYLENE CHLORIDE METHYLENE CHLORIDE METHYLENE CHLORIDE METHYLENE CHLORIDE METHYLENE CHLORIDE METHYLENE CHLORIDE METHYLENE CHLORIDE SHELL THERMIA C OIL WITH DISSOLVED HCL
SHELL THERMIA OIL C SHELL THERMIA OIL C SODIUM HYDROXIDE (50%) SULFURIC ACID VINYL CHLORIDE WATER/STEAM WATER/STEAM WATER/STEAM
SAFE SEAL MULTIPAK (JOHN CRANE 6KB)
94060
STEAM & PROCESS SP-CM
85133F
TEAM LEAK REPAIRS SEALANT DB-2
RCL 82-042
STEAM & PROCESS SP-325
93093
STEAM & PROCESS SP-325
93093
SILASTIC 732-RTV SILICONE RUBBER
RCL 83-092
STEAM & PROCESS SP-2600
RCL 82-045
STEAM & PROCESS SP-1015
85173A
TEAM LEAK REPAIRS SEALANT DB-2
RCL 82-041
755 STICK SEALANT
91126
SAFE SEAL - CHEMOLA TEFLON
94060
SAFE SEAL - CHEMOLA TEFLON
94060
SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) 94060
SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) 94060
SAFE SEAL MULTIPAK (JOHN CRANE 6KB)
94060
SAFE SEAL MULTIPAK (JOHN CRANE 6KB)
94060
STEAM & PROCESS SP-1360
RCL 1578
STEAM & PROCESS SP-2007
84E1S6
STEAM & PROCESS SP-2026
85132A
STEAM & PROCESS SP-CM
85133B
TEAM LEAK REPAIRS SEALANT DB-2
RCL 82-040
SAFE SEAL - CHEMOLA TEFLON
94060
SAFE SEAL - CHEMOLA TEFLON
94060
SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) 94060
SAFE SEAL GRAFPAK (UCAR CARBON CO GRAFOIL) 94060
SAFE SEAL MULTIPAK (JOHN CRANE 6KB)
94060
SAFE SEAL MULTIPAK (JOHN CRANE 6KB)
94060
STEAM & PROCESS SP-103
RCL 1584
STEAM & PROCESS SP-1300
RCL 1582
STEAM & PROCESS SP-1360
RCL 1577
STEAM & PROCESS SP-2026
8S132B
STEAM & PROCESS SP-CM
85133C
TEAM LEAK REPAIRS SEALANT DB-2
RCL 82-038
ULTRAMETAL LIQUID METAL (CURED)
93028
STEAM & PROCESS SP-1011
90400
STEAM & PROCESS SP-109
90400
STEAM & PROCESS SP-1011
RCL 1146
TEAM LEAK REPAIRS SEALANT DB-2
RCL 82-044
STEAM & PROCESS SP-429
93179
STEAM & PROCESS SP-1011
90037
STEAM & PROCESS SP-2511
86060A
TEAM LEAK REPAIRS SEALANT HI
RCL 83-017
DSC DTA DTA DSC HOM DTA DTA DTA DTA DSC HOM DSC HOM DSC HOM DSC DTA DTA DTA DTA DTA HOM DSC HOM DSC HOM DSC DTA DTA DTA DTA DTA DTA DSC DSC DSC DTA DTA DSC DSC DTA DTA
Dow Confidential
REACTIVITY
NO EXO TO 325 C NO EXO TO 250 C NO EXO TO 200 C NO EXO TO 300 C NO EXO AT 22 C NO EXO TO 200 C NO EXO TO 310 C NO EXO TO 225 C NO EXO TO 175 C NO EXO TO 175 C NO EXO AT 22 C EXO AT 375 C SL. EXO AT 22 C NO EXO TO 250 C SL. EXO AT 22 C NO EXO TO 250 C NO EXO TO 140 C NO EXO TO 150 C NO EXO TO 200 C NO EXO TO 250 C NO EXO TO 190 C NO EXO AT 22 C EXO AT 228 C NO EXO AT 22 C EXO AT 335 C NO EXO AT 22 C EXOAT 120 C NO EXO TO 150 C NO EXO TO 150 C NO EXO TO 150 C NO EXO TO 200 C NO EXO TO 250 C NO EXO TO 200 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 295 C EXO AT 45 C EXOAT 114 C NO EXO TO 300 C NO EXO TO 275 C NO EXO TO 150C
48
TABLE III. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PLANT)
PLANT
PROCESS CHEMICAL
SEALANT
REF. NO.
METHOCEL
METHOCEL
METHOCEL
POLYA
POLYA
POLYA
POLYA
POLY B
POLY B
POLY B
POLY B
POLY B
POLY C
POLY C
POLY C
POLY C
POLY C
POLY C
POLY C
POLY C
POLY C
POLY C
POLY C
POLY C
POLY C
POLY C
POLY C
POLY C
POLY C
POLY C
POLY C
POWER 1
POWER 1
POWER 1
POWER 1
POWER 1
POWER 1 POWER 1 POWER 1 POWER 2 POWER 2 POWER 2
r> o^ zo T--\4, T1>/ V TT O z o
-I \)
METHYL CHLORIDE + DIMETHYL ETHER
TEAM LEAK REPAIRS SEALANT #6
93196
METHYL CHLORIDE + DIMETHYL ETHER
TEAM LEAK REPAIRS SEALANT #6
93196
PROPYLENE OXIDE + DIMETHYL ETHER/ METHYL CL TEAM LEAK REPAIRS TC-4 (CURED)
90324
RANDO 68 OIL
STEAM & PROCESS SP-2000
93210
RANDO 68 OIL
STEAM & PROCESS SP-2021
93210
RANDO 68 OIL
STEAM & PROCESS SP-325
93210
ZEROL 300 OIL
TEAM LEAK REPAIRS PRI-102C (THREADS)
91028
BUTYL ETHYL MAGNESIUM (15%) IN HEXANE
SEMSTONE 805 LINING MATERIAL
91082
DNDA CATALYST (BATCH 886)
SEMSTONE 145-S
90146
ONDA CATALYST (BATCH 886)
SEMSTONE 245
90146
N-PROPANOL (50%) + WATER (50%)
SEMSTONE 145-S
90146
SODIUM HYDROXIDE (3%)
SEMSTONE 145-S
90146
CALCIUM STEARATE
STEAM & PROCESS SP-3100
93194
DOWTHERM A
TEAM LEAK REPAIRS SEALANT 16X
87033B
DOWTHERM A
TEAM LEAK REPAIRS SEALANT 2X
93080
DOWTHERM A
TEAM LEAK REPAIRS SEALANT 2X
93080
DOWTHERM A
TEAM LEAK REPAIRS SEALANT 5G
87033A
DOWTHERM A
TEAM LEAK REPAIRS SEALANT X-36
87033C
DOWTHERM A
TEAM LEAK REPAIRS VALVEPACK AX
87063A
ETHYLENE
TEAM LEAK REPAIRS VALVEPACK AW W/ FIBERS 86183A
ETHYLENE
TEAM LEAK REPAIRS VALVEPACK B + G FIBERS 86183B
HYDROGEN
TEAM LEAK REPAIRS VALVEPACK AW & FIBERS 86191A
ISOPAR E
STEAM & PROCESS SP-325
93215
ISOPAR E
STEAM & PROCESS SP-325
93215
ISOPAR E
TEAM LEAK REPAIRS SEALANT *6
87033G
ISOPAR E
TEAM LEAK REPAIRS SEALANT IX
87033D
ISOPAR E
TEAM LEAK REPAIRS SEALANT 2X
87033E
ISOPAR E
TEAM LEAK REPAIRS SEALANT 5G
87033F
ISOPAR E
TEAM LEAK REPAIRS SEALANT DB 20
87033H
ISOPAR E
TEAM LEAK REPAIRS SEALANT X-36
870331
ISOPAR E
TEAM LEAK REPAIRS VALVEPACK AX
87033J
1,1,1 -TRICHLOROETHANE
C5A FEL PRO
89050
1,1,1 -TRICHLOROETHANE
NO. 725 NICKEL ANTISEIZE
89050
BETZ BP-P-1B (50%) + COR-TROL 77BP (50%)
TEAM LEAK REPAIRS SEALANT #6 & F-14 FIBERS 92175
BETZ BP-P-1B (50%) COR-TROL 778P (50%)
TEAM LEAK REPAIRS SEALANT *6 & F-14 FIBERS 92175
BOILER WATER WITH COR-TROL, EDTA, & PIB
TEAM LEAK REPAIRS SEALANT DB 22 A F 10 FIBERS 92183
BOILER WATER WITH COR-TROL, EDTA, & PIB
TEAM LEAK REPAIRS SEALANT DB 22 & F-10 FIBERS 92183
CITRIKLEEN DEGREASER
C5A FEL PRO
89050
CITRIKLEEN DEGREASER
NO. 725 NICKEL ANTISEIZE
89050
AIR
SP-102 (CURED 0300 C / 48 HOURS)
4791-43B
AIR
TEAM LEAK REPAIRS SEALANT 2W
92320
AIR
TEAM LEAK REPAIRS SEALANT 2X
92320
Dow Confidential
TEST
DSC HOM DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DTA DSC HOM DTA DTA DSC DTA DTA DTA DSC HOM DTA DTA DTA DTA DTA DTA DTA DSC DSC DSC HOM DSC HOM DSC DSC DSC DSC DSC
REACTIVITY
NO EXOTO 190 C SL. EXO AT 22 C EXOAT 120 C NO EXO TO 200 C EXO AT 36 C NO EXO TO 200 C NO EXO TO 250 C EXO AT 40 C NO EXO TO 250 C EXO AT 223 C NO EXO TO 250 C EXOAT 155 C NO EXO TO 300 C NO EXO TO 350 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C NO EXO TO 350 C NO EXO TO 350 C NO EXO TO 375 C NO EXO TO 325 C NO EXO TO 375 C EXO AT 170 C NO EXO AT 22 C NO EXO TO 260 C NO EXO TO 260 C NO EXO TO 260 C NO EXO TO 260 C NO EXO TO 260 C NO EXO TO 260 C NO EXO TO 260 C EXOAT 125 C EXOAT 133 C NO EXO TO 335 C NO EXO AT 22 C NO EXO TO 250 C NO EXO AT 22 C NO EXO TO 300 C EXO AT 78 C EXO AT 420 C NO EXO TO 500 C NO EXO TO 500 C
19
TABLE III. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PLANT)
PLANT
PROCESS CHEMICAL
SEALANT
REF. NO. TEST
POWER 2
POWER 2 PROMIX PROMIX SOLVENTS/EDC SOLVENTS/EDC SOLVENTS/EDC SOLVENTS/EDC SOLVENTS/EDC SOLVENTS/EDC SOLVENTS/EDC SOLVENTS/EDC SOLVENTS/EDC SOLVENTS/EDC SOLVENTS/EDC SOLVENTS/EDC SOLVENTS/EDC SOLVENTS/EDC SOLVENTS/EDC SOLVENTS/EDC SOLVENTS/EDC
VECTOR VECTOR VECTOR VINYL 1 VINYL 1 VINYL 1 VINYL 1 VINYL 1
VINYL 1 VINYL 1 VINYL 1 VINYL 1 VINYL 1 VINYL 1
33
VINYL 1 VINYL 1
Z3 U>
VINYL 1 VINYL 1
3_ 23
VINYL 1 VINYL 1
VINYL 1
^^ \>
~^
CARBON STEEL + CONCRETE + WATER
STEAM & PROCESS SP-520
WATER/STEAM
TEAM LEAK REPAIRS VALVEPACK EPX
ETHANE
TEAM LEAK REPAIRS SEALANT #6
PROPANE
TEAM LEAK REPAIRS SEALANT #6
CARBON TETRACHLORIDE (CRUDE, 93%)
CHESTERTON 010 STEEL PUTTY (CURED)
CARBON TETRACHLORIDE (CRUDE, 93%)
CHESTERTON 810 STEEL PUTTY (CURED)
CARBON TETRACHLORIDE (CRUDE, 93%)
CHESTERTON 858 STEEL PUTTY (CURED)
CARBON TETRACHLORIDE (CRUDE, 93%)
CHESTERTON 858 STEEL PUTTY (CURED)
CHLORINE
GORTEX PTFE
D-13 HEXES
FURMANITE FSC-5C
D-13 HEXES
FURMANITE FSC-6B
ETHYL CHLORIDE
TEAM LEAK REPAIRS SEALANT #6
ETHYLENE DICHLORIDE (D-15 VESSEL SAMPLE)
STEAM & PROCESS SP-325
HCI (50%) + CHLORINE (50%)
CURED DB 22
H (50%) + CHLORINE (50%)
SILASTIC 732 RTV
HO (50%) + CHLORINE (50%)
TEAM LEAK REPAIRS SEALANT #6
PER/TET (CRUDE)
FURMANITE GASKET COATING (CL2)
PER/TET (CRUDE)
TEAM LEAK REPAIRS SEALANT #10 + F-45 FIBER
PER/TET (CRUDE) PER/TET (CRUDE)
TEAM LEAK REPAIRS SEALANT #11 TEAM LEAK REPAIRS VALVEPACK OX
TET, PER, HCE, HO. CHLORINE
TEAM LEAK REPAIRS CURED HI-PRO
1,3-BUTADIENE
TEAM LEAK REPAIRS VALVEPACK B-EC
ISOPRENE
TEAM LEAK REPAIRS VALVEPACK AX
STYRENE BETA-TRICHLOROETHANE
TEAM LEAK REPAIRS VALVEPACK AX TEAM LEAK REPAIRS VALVEPACK A
CHLORINE CHLORINE
TEAM LEAK REPAIRS SEALANT #11 TEAM LEAK REPAIRS SEALANT #6 + F-14 FIBER
ETHYLENE ETHYLENE
STEAM & PROCESS SP-2000 STEAM & PROCESS SP-2026
ETHYLENE ETHYLENE
TEAM LEAK REPAIRS SEALANT DB-20 TEAM LEAK REPAIRS VALVEPACK A
ETHYLENE DICHLORIDE
>' TEAM LEAK REPAIRS SEALANT #6
ETHYLENE DICHLORIDE
TEAM LEAK REPAIRS VALVEPACK A
ETHYLENE DICHLORIDE + BETA-TRICHLOROETHANE TEAM LEAK REPAIRS SEALANT #6
ETHYLENE DICHLORIDE BETA-TRICHLOROETHANE TEAM LEAK REPAIRS VALVEPACK A
HYDROGEN CHLORIDE (ANHYDROUS)
STEAM & PROCESS SP-2000
HYDROGEN CHLORIDE (ANHYDROUS)
STEAM & PROCESS SP-2007
HYDROGEN CHLORIDE (ANHYDROUS)
TEAM LEAK REPAIRS SEALANT #6
HYDROGEN CHLORIDE (ANHYDROUS)
TEAM LEAK REPAIRS VALVEPACK A
PROPYLENE
TEAM LEAK REPAIRS SEALANT DB-20
PROPYLENE
TEAM LEAK REPAIRS VALVEPACK A
VINYL CHLORIDE
STEAM & PROCESS SP-2007
Dow Confidential
92327 91152 94071 94071 92298 92298 92298 92298 85136A 92196 92196 90024 93144 4791-9A 4791-9A 4791-9A 91064 89228 89141 89141 91050 93062 93069 93069 84E189 RCL 83-093 RCL 03-095 RCL 83-111 RCL 83-112 84E194 84E186 3108-46 84E188 84E193 84E190 RCL 84-007 RCL 84-006 RCL 84-009 RCL 84-008 84E195 84E187 3108-46
DSC DSC DSC DSC DSC HOM DSC HOM DTA DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DSC DTA DTA DTA DTA DTA DTA DTA DTA DTA DTA DTA DTA DTA DTA DTA DTA DTA DTA
REACTIVITY
NO EXO TO 180 C NO EXO TO 350 C NO EXO TO 200 C NO EXO TO 178 C NO EXO TO 150 C NO EXO AT 22 C NO EXO TO 150 C NO EXO AT 22 C NO EXO TO 250 C EXO AT 344 C EXO AT 270 C NO EXO TO 250 C NO EXO TO 300 C EXO AT 25 C EXOAT 170 C EXOAT 125 C NO EXO TO 250 C EXO AT 245 C EXO AT 80 C EXOAT 145 C NO EXO TO 250 C EXOAT 105 C NO EXO TO 200 C NO EXO TO 200 C EXO AT 275 C EXO AT 90 C EXOAT 130 C NO EXO TO 300 C NO EXO TO 225 C NO EXO TO 130 C NO EXO TO 250 C NO EXO TO 200 C EXO AT 300 C NO EXO TO 400 C EXO AT 276 C NO EXO TO 200 C NO EXO TO 185 C NO EXO TO 165 C NO EXO TO 200 C NO EXO TO 250 C NO EXO TO 400 C NONE
PLANT
VINYL 1 VINYL 1 VINYL 1 VINYL 1 VINYL 1 VINYL 1 VINYL 1 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2
50
TABLE III. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PLANT)
PROCESS CHEMICAL
SEALANT
REF. NO. TEST
r>
33
-n
-n o z_* M\j -4 T> N)
VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIDE (80%) + ANHYDROUS HCI (20%) VINYL CHLORIDE (80%) + ANHYDROUS HCI (20%) VINYL CHLORIDE (80%) + ANHYDROUS HCI (20%) WATER/STEAM BETA-TRICHLOROETHANE BETA-TRICHLOROETHANE BETA-TRICHLOROETHANE BETA-TRICHLOROETHANE BETA-TRICHLOROETHANE BETA-TRICHLOROETHANE BETA-TRICHLOROETHANE BETA-TRICHLOROETHANE BETA-TRICHLOROETHANE BETA-TRICHLOROETHANE BETA-TRICHLOROETHANE BETA-TRICHLOROETHANE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CARBON TETRACHLORIDE CELL EFFLUENT ( SODIUM HYDROXIDE) D-102 QUENCH LIQUOR DOWTHERM G DOWTHERM Q DOWTHERM Q DOWTHERM G DOWTHERM G DOWTHERM G DOWTHERM G DOWTHERM G DOWTHERM G
TEAM LEAK REPAIRS SEALANT DB-20 TEAM LEAK REPAIRS VALVEPACK A TEAM LEAK REPAIRS VALVEPACK B TEAM LEAK REPAIRS SEALANT #6 + F-14 FIBER TEAM LEAK REPAIRS SEALANT DB-20 TEAM LEAK REPAIRS VALVEPACK A TEAM LEAK REPAIRS VALVEPACK A FURMANITE FSC-44D FURMANITE FSC-44D FURMANITE FSC-5B FURMANITE FSC-5B STEAM & PROCESS SP-289 STEAM & PROCESS SP-289 STEAM & PROCESS SP-3100 STEAM & PROCESS SP-3100 TEAM LEAK REPAIRS SEALANT #2X TEAM LEAK REPAIRS SEALANT #2X TEAM LEAK REPAIRS SEALANT *6 TEAM LEAK REPAIRS SEALANT #6 FURMANITE FSC-44D FURMANITE FSC-44D FURMANITE FSC-5B FURMANITE FSC-5B STEAM & PROCESS SP-325 STEAM & PROCESS SP-325 STEAM & PROCESS SP-CM STEAM & PROCESS SP-CM TEAM LEAK REPAIRS SEALANT #11 TEAM LEAK REPAIRS SEALANT #11 TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS F-14 FIBER FURMANITE FSC-6B FURMANITE FSC-5C FURMANITE FSC-5C FURMANITE FSC-6B FURMANITE FSC-6B STEAM & PROCESS SP-1011 STEAM & PROCESS SP-1011 STEAM & PROCESS SP-102 STEAM & PROCESS SP-102 TEAM LEAK REPAIRS 16X & FURMANITE FSC-6B
Dow Confidential
84E196 3108-46 3108-46 RCL 83-096 RCL 83-097 84E191 RCL 83-018 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93129 89208 89186 93154 92100 93154 93154 93154 93154 93154 92100
DTA DTA DTA DTA DTA DTA DTA DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM DSC DSC DSC HOM DSC HOM DSC HOM DSC HOM DSC
REACTIVITY
NO EXO TO 225 C NONE NONE NO EXO TO 250 C NO EXO TO 250 C NO EXO TO 400 C NO EXO TO 150 C EXO AT 269 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C EXO AT 253 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C EXO AT 284 C NO EXO AT 22 C EXO AT 225 C NO EXO AT 22 C EXO AT 223 C NO EXO AT 22 C EXO AT 252 C NO EXO AT 22 C EXO AT 247 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 200 C NO EXO TO 200 C NO EXO TO 400 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C
SI
PLANT
VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2
n ov Z -3 -tl -t T> O T\ O
Z_( N)
-1
T--> '-0i
TABLE III. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTEO BY PLANT)
PROCESS CHEMICAL
SEALANT
REF. NO.
DOWTHERM Q
TEAM LEAK REPAIRS SEALANT 16X
DOWTHERM Q
TEAM LEAK REPAIRS SEALANT T6X
DOWTHERM Q
TEAM LEAK REPAIRS SEALANT K2XH
DOWTHERM G
TEAM LEAK REPAIRS SEALANT #2XH
DOWTHERM G
TEAM LEAK REPAIRS SEALANT 16X
DOWTHERM G
TEAM LEAK REPAIRS SEALANT 16X
DOWTHERM G
TEAM LEAK REPAIRS VALVEPACK AX
DOWTHERM G
TEAM LEAK REPAIRS VALVEPACK AX
DOWTHERM G
TEAM LEAK REPAIRS VALVEPACK B EC
DOWTHERM G
TEAM LEAK REPAIRS VALVEPACK ER
DOWTHERM G
TEAM LEAK REPAIRS VALVEPACK OX
DOWTHERM G
TEAM LEAK REPAIRS VALVEPACK OX
ETHYLENE DICHLORIDE
COOPER OIL TOOL DIVISION WKM NO. 114
ETHYLENE DICHLORIDE
FURMANITE FSC-5B
ETHYLENE DICHLORIDE
FURMANITE FSC-5B
ETHYLENE DICHLORIDE
FURMANITE FSC-6B
ETHYLENE DICHLORIDE
FURMANITE FSC-6B
ETHYLENE DICHLORIDE
STEAM & PROCESS SP-289
ETHYLENE DICHLORIDE
STEAM & PROCESS SP-289
ETHYLENE DICHLORIDE
STEAM & PROCESS SP-325
ETHYLENE DICHLORIDE
STEAM & PROCESS SP-325
ETHYLENE DICHLORIDE
TEAM LEAK REPAIRS SEALANT K2X
ETHYLENE DICHLORIDE
TEAM LEAK REPAIRS SEALANT #2X
ETHYLENE DICHLORIDE
TEAM LEAK REPAIRS SEALANT 2XH
ETHYLENE DICHLORIDE
TEAM LEAK REPAIRS SEALANT #2XH
ETHYLENE DICHLORIDE
TEAM LEAK REPAIRS SEALANT #6
ETHYLENE DICHLORIDE
TEAM LEAK REPAIRS SEALANT #6
ETHYLENE DICHLORIDE
TEAM LEAK REPAIRS VALVEPACK AX
ETHYLENE DICHLORIDE
TEAM LEAK REPAIRS VALVEPACK AX
ETHYLENE DICHLORIDE (C-250 REFLUX)
FURMANITE FSC-5C
ETHYLENE DICHLORIDE (C-250 REFLUX)
FURMANITE FSC-6B
ETHYLENE DICHLORIDE (CRUDE - EDC VCM HCL) WKM VALVEPACK 114 & *STP* LUBRICANT
HYDROGEN CHLORIDE (ANHYDROUS)
COOPER OIL TOOL DIVISION WKM NO. 114
HYDROGEN CHLORIDE (ANHYDROUS)
FURMANITE FSC-5B
HYDROGEN CHLORIDE (ANHYDROUS)
FURMANITE FSC-5B
HYDROGEN CHLORIDE (ANHYDROUS)
FURMANITE FSC-5C
HYDROGEN CHLORIDE (ANHYDROUS)
FURMANITE FSC-6B
HYDROGEN CHLORIDE (ANHYDROUS)
FURMANITE FSC-6B
HYDROGEN CHLORIDE (ANHYDROUS)
STEAM & PROCESS SP-1011
HYDROGEN CHLORIDE (ANHYDROUS)
STEAM & PROCESS SP-1011
HYDROGEN CHLORIDE (ANHYDROUS)
STEAM & PROCESS SP-102
HYDROGEN CHLORIDE (ANHYDROUS)
STEAM & PROCESS SP-102
Dow Confidential
92100 93154 93154 93154 92100 92100 92100 93154 92100 92100 92100 93154 93042 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 4791-29A 4791-29A 93066 93042 92146 93154 4791-29A 92146 93154 93154 93154 93154 93154
TEST
DSC HOM DSC HOM DSC DSC DSC HOM DSC DSC DSC HOM DSC DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM DSC DSC DSC DSC DSC HOM DSC DSC HOM DSC HOM DSC HOM
REACTIVITY
NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C NO EXO TO 350 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C NO EXO TO 350 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 310 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 250 C NO EXO AT 22 C NO EXO TO 325 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 250 C NO EXO AT 22 C NO EXO TO 150 C EXO AT 40 C EXOAT 130 C EXO AT 225 C NO EXO TO 250 C NO EXO AT 22 C NO EXO TO 70 C NO EXO TO 250 C SL. EXO AT 22 C NO EXO TO 200 C SL. EXO AT 22 C NO EXO TO 400 C SL. EXO AT 22 C
PLANT
VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2
52
TABLE III. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PLANT)
PROCESS CHEMICAL
N-)
zo n
__, Tv
o 'Tl O
"7 \)
-H \)
1 --1
^O
HYDROGEN CHLORIDE (ANHYDROUS) HYDROGEN CHLORIDE (ANHYDROUS) HYDROGEN CHLORIDE (ANHYDROUS) HYDROGEN CHLORIDE (ANHYDROUS) PROPYLENE PROPYLENE PROPYLENE PROPYLENE PROPYLENE PROPYLENE PROPYLENE PROPYLENE PROPYLENE PROPYLENE PROPYLENE PROPYLENE QUENCH LIQUOR QUENCH LIQUOR QUENCH LIQUOR QUENCH LIQUOR QUENCH LIQUOR QUENCH LIQUOR QUENCH LIQUOR QUENCH LIQUOR QUENCH LIQUOR QUENCH LIQUOR SIMULATED VENT GAS SIMULATED VENT GAS VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIDE
SEALANT
TEAM LEAK REPAIRS SEALANT #IX TEAM LEAK REPAIRS SEALANT (MX TEAM LEAK REPAIRS SEALANT #2X TEAM LEAK REPAIRS SEALANT #2X FURMAN1TE FSC-5B FURMANITE FSC-5B FURMANITE FSC-6B FURMANITE FSC-6B STEAM & PROCESS SP-1011 STEAM & PROCESS SP-1011 STEAM & PROCESS SP-2000 STEAM & PROCESS SP-2000 TEAM LEAK REPAIRS SEALANT 2X TEAM LEAK REPAIRS SEALANT K2X TEAM LEAK REPAIRS SEALANT #2XH TEAM LEAK REPAIRS SEALANT #2XH FURMANITE FSC-6B FURMANITE FSC-6B STEAM & PROCESS SP-1011 STEAM & PROCESS SP-1011 STEAM & PROCESS SP-325 STEAM & PROCESS SP-325 TEAM LEAK REPAIRS SEALANT 2X TEAM LEAK REPAIRS SEALANT #2X TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS SEALANT #6 TEAM LEAK REPAIRS SEALANT DB-22 TEAM LEAK REPAIRS SEALANT DB-22 FURMANITE FSC-46D FURMANITE FSC-46D FURMANITE FSC-5C FURMANITE FSC-5C FURMANITE FSC-6B FURMANITE FSC-6B STEAM & PROCESS SP-1011 STEAM & PROCESS SP-1011 STEAM & PROCESS SP-2000 STEAM & PROCESS SP-2000 STEAM & PROCESS SP-325 STEAM & PROCESS SP-325 TEAM LEAK REPAIRS SEALANT 11 TEAM LEAK REPAIRS SEALANT *2X
Dow Confidential
REF. NO.
93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 92302 92302 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93147 93154
TEST
DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM DSC DSC
REACTIVITY
EXO AT 80 C SL. EXO AT 22 C EXOAT 117 C SL. EXO AT 22 C NO EXO TO 250 C NO EXO AT 22 C NO EXO TO 225 C NO EXO AT 22 C NO EXO TO 250 C NO EXO AT 22 C NO EXO TO 250 C NO EXO AT 22 C NO EXO TO 250 C NO EXO AT 22 C NO EXO TO 250 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 120 C NO EXO AT 22 C NO EXO TO 300 C NO EXO AT 22 C NO EXO TO 300 C NO EXO AT 22 C EXOAT 149 C SL. EXO AT 22 C NO EXO TO 350 C SL. EXO AT 22 C NO EXO TO 200 C SL. EXO AT 22 C NO EXO TO 220 C NO EXO AT 22 C EXOAT 135 C EXO AT 336 C
PUNT
VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2 VINYL 2
3
TABLE III. REACTIVITY OF SEALANT WITH PROCESS CHEMICAL (SORTED BY PLANT)
PROCESS CHEMICAL
SEALANT
REF. NO.
VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIDE VINYL CHLORIDE (80%) ANHYDROUS HCI (20%) VINYL CHLORIDE (80%) + ANHYDROUS HCI (20%) VINYL CHLORIDE (80%) + ANHYDROUS HCI (20%) VINYL CHLORIDE (80%) + ANHYDROUS HCI (20%) VINYL CHLORIDE (80%) + ANHYDROUS HCI (20%) VINYL CHLORIDE (80%) + ANHYDROUS HCI (20%) VINYL CHLORIDE (80%) + ANHYDROUS HCI (20%) VINYL CHLORIDE (80%) ANHYDROUS HCI (20%) VINYL CHLORIDE (80%) + ANHYDROUS HCI (20%) VINYL CHLORIDE (80%) + ANHYDROUS HCI (20%) VINYL CHLORIDE (80%) ANHYDROUS HCI (20%) VINYL CHLORIDE (80%) + ANHYDROUS HCI (20%) WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM WATER/STEAM
TEAM LEAK REPAIRS SEALANT #2X TEAM LEAK REPAIRS SEALANT 2XH TEAM LEAK REPAIRS SEALANT #2XH FURMANITE FSC-46D FURMANITE FSC-46D FURMANITE FSC-5C FURMANITE FSC-5C STEAM & PROCESS SP-1011 STEAM & PROCESS SP-1011 STEAM & PROCESS SP-325 STEAM & PROCESS SP-325 TEAM LEAK REPAIRS SEALANT #18X TEAM LEAK REPAIRS SEALANT K18X TEAM LEAK REPAIRS SEALANT #8 TEAM LEAK REPAIRS SEALANT 6 FURMANITE FSC-1/2A FURMANITE FSC-1/2A FURMANITE FSC-6B STEAM & PROCESS SP-1011 STEAM & PROCESS SP-102 STEAM & PROCESS SP-102 STEAM & PROCESS SP-2000 STEAM & PROCESS SP-2000 TEAM LEAK REPAIRS SEAUNT 10X TEAM LEAK REPAIRS SEALANT *18X TEAM LEAK REPAIRS SEALANT #2X TEAM LEAK REPAIRS SEAUNT #2X TEAM LEAK REPAIRS SEALANT *6 TEAM LEAK REPAIRS SEALANT SW
93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93154 93075
TEST
HOM DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM DSC HOM HOM HOM DSC HOM DSC HOM DSC HOM DSC HOM HOM DSC
REACTIVITY
NO EXO AT 22 C EXO AT 264 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO TO 250 C NO EXO AT 22 C EXOAT 178 C NO EXO AT 22 C NO EXO TO 250 C SL. EXO AT 22 C NO EXO TO 250 C SL. EXO AT 22 C NO EXO TO 250 C SL. EXO AT 22 C NO EXO TO 300 C NO EXO AT 22 C NO EXO AT 22 C NO EXO AT 22 C NO EXO TO 300 C NO EXO AT 22 C NO EXO TO 325 C NO EXO AT 22 C NO EXO TO 300 C NO EXO AT 22 C NO EXO TO 350 C NO EXO AT 22 C NO EXO AT 22 C NO EXO TO 275 C
n oa zo ~n -I >
z>
T| 3 Z \> -4 X' --t -> T> OJ
Dow Confidential
LOUISIANA
Distribution List
B.W. Bailey C. A. Barrios C.B. Carpenter
w. w. Chew
B. Cisneros S. R. Cole S. Corbino K. D. Diamond R. S. Fitzgerald T. F. Grant N. L. Grissom J. W. Gross T. M. Gunn S. F. Hanrahan C. R. Holmes R. D. Hudson C. E. Jackson W. L. Jackson K. L. Johnson D. S. Jones G. C. LeBlanc V. E. McMurray C. D. Mercer
- 3301W - 807 - 807 - 6650 - 2510 - 6601 - 3801 - 1901 - 8601 - 5501 - 4801 - 2511 - 1701 - 3305 - 3302P - 2801 - 1501 - 6801 - 5701 - 3502W - 3601 - 8601 - 5301
C. D. Messelt W. S. Milligan S. H. Mims M.T. Mitchell C. D. Modtland J. C. Monroe M. Oubre R. L. Peebles B. G. Pope S. L. Serpas J.W. Shively R. B. Speed R. L. Stevens R. D. Summers E. T. Supple D.W. Taylor R. D. Thornhill G. P. Townsend W. A. Turner P. L. Usie M. L. Williams B. G. Witt Patent Department CRI (5)
FREEPORT
MIDLAND
*W. W. Henslee D. J. Leggett *D. C. Schulz W. E. Shewbart *S. F. Spangenberg CRI(l)
- B-2020 - B-1216 - B-101 - B-101 - B-1225 - B-1210
A. Chakrabarti *C. A. Dudley J. S. Kelyman J. B. Powers CRI (1)
FORT SASKATCHEWAN
SARNIA
*R. A. Wagner
- 91A
*J. R. MacLauchlan
PITTSBURG
STADE
*T. W. Regulski
- 463
*E. L. Dreher
- 3502W - 4801 - 3801 - 807 - 6801 - 3305 - 1601 - 1601 - 2509 - 4101 - 6650 - 901 - 4350 - 2510 - 3801 - 4601 - 2601 - 6650 - 4501 - 4109 - 807 - 2502 - 2506 - 2507
- 1897C - 1897F - 566 '- 1897C - 566
- 115
- C4-1
* Summary Only
00 A C.DNF J DFNT TAI
