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000168
Var-24-2003 05:Sirm From-CUSTOER SERVICE
.
'ALGOFLON D0 27
sts
1+328 P-001/006. F-033
SOLVAY SOLEXIS, Inc. 10 Leonards Lane `Thorofare, NJ 08086. 856-853-8119
Section 1 - Chemical product and Company information
Date Revised: December 26, 2002 `CPhreomdiucctalNaNmaem:e:ALAqGuOeFouLsOdNisDpe6r0si2o7nof12tsaflucroethylene homopolymer `and surfactant
Chemical Family: Fluoropolymer dispersion
`ESmyenrogneynmcs:y MTeilxetpuhroene: 800-424-9300 (CHEMTREC2,4 haus)
856-853-8119
Emergency Overview: `White aqueous dispersion. Surfaces can be extremely slippery in the ease: ofa spill
Section 2 - Compositional information
Nome
oar
homopolymer
Japproumae wegncow)
59-61
i
War oenxio0 __
press
[sss
Jooodst-------- Je
pPil Cilla Gel Co Phe Btn
!
[Ammon Perfluorocionowte __Jpoas-261 --~ _ > AeoJns0sDark \sere oc boncale
Section 3 - Potential Health Effects
Effects of Overexposure:
`Eye Contact Bye contact can cause irritation.
SSkkiinn Ccoonnttaaccttcan cause iritation.
Inhalation
inhalationof
vapors
or
mist
may
cause
imitationofthe
respiratory
act
and
mucous
Breathing fumes generated during processingof the polymer a: tempererurea abot:
men ranes. 31% 1707 F)
cn
case "polymer fume fever".
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ssessan1
TE P00 Fam
Ingestion
Not an expected
exposure
route.
Ingestion
can
cause
gastoinestinal
Iract
initation,
nausea,
and
vomiting.
Section 4 - First Aid Measures
Eye Contact: Flush eyes for
15
minutes
with
copious
amounts
ofwater,
revacting
eyelids
often.
Seek
medical
anention.
Skin Contact: `Wash skin thoroughly with mild soap and water.
Flush with lukewarm water for
15 mutes. If
iriration persists, consult a physician.
IIFnohaplmamtpioonm:sofinitation of discomfort axe experienced, or Weim i OVEIOME by ExPOSUTE move:
`affected person to fresh air. Give oxygen or arificial sespiration as needed.
Tngestion:
If conscious,
drink three
to
four
8
ounce
glassesofwater
or milk.
Calla
physician.
If unconscious,
pjemrmseodni.ately take affected person fo & hospital. Do nof give anythingb| ymouth to an unconscious.
Section 5 - Fire Fighting Measures
`Flash Point: Not
`Lower Explosive
Flammable
Limit: Not
Applicable
Upper Explosive Limit: Not Applicable Autoignition Temperature: Not Applicable
Extinguishing Media: Water (spray or fog), foam, dry chemical or carbon dioxide (C02).
Unusual Fire Hazards:
Flucropolymers will degrade upon prolonged heating or in a fire, liberating carbonyl fluoride and fluoride (HF). Decomposition products are Toxic if inhaled or they come into contact with
`hydrogen `moist skin. HF
has
an
ACGIH
TLV
ceiling
limit
of3
ppm
(2.6
mg/m3)andan
OSHA
PEL
TWA
f3
ppm. Carbonyl fluoride has an ACGIH TLV TWA and OSHA PEL TWAof 2 ppm ($ mg/m3).
Fire Fighting Procedures:
eUnsteesreflifrecaornetaaiwnietdhoburteaptrhoipnegrapprpoatreactruison(.SFCigBhAt)fiarnedfsrkoimn sparfoetedcitsitaonncfeo.rIafcpiodssgiabslee,xpaoisumroen.itDoroinsgo.t
`should be performed.
Section 6 - Accidental Release Measures
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Releases: Imnarcearsiealofinatore&lecaosveeorredspciolln,taaibnseorrbfomratdiesrpioaslalo.ntDo viermsicoupfliatcoecoosrrdsiienmgiltaoraipnpelrticaabbsloerbleoncta.l, Psltaatcee asnpdilled federal regulations.
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Section 7 - Handling and Storage Wash handsafteruse and before handling food or applying cosmetics. Do not use tobacco products in
tnheeairmcmoemdbiuasttieblareesm.atKeerieaplsc.ontainers closed. Keep awayfromheat, sparks and flames. Do not store:
Section 8 - Exposure Controls/Personal Protection
ACGIH Threshold Limit Value (8br. fime weighted average) `Ammonium Perfluorooctonoate TLV/TWA-8hr 0.01 mg/m3 air, A3 skin notation OSHA Permissible Exposure Limit Value (8br. time weighted average) None established
Engineering Coatrols:
Ventilation Requivements:
Local Exhaust: Vent vapors
from
melt
processing
away
from
operating
personnel.
Local
exhaust
ventilation at arate of 50 feet per minute.
Personal Protective Equipment:
Respiratory Prorection:
No occupational exposure
standards
have
been
developed
for
this
material.
In
situations
where
eRexsppoisruarteortouvsaeploirmsitoartimoinsstms aisdelikbeylyN, INOISOES/HM/SMHSAHAoarptphre omvaendufraescptiurraetrormsuasrebreeocbosmemrevnedde.d.
Respiratory protection pragrams must be in accordance with 29 CFR 1910.134.
EEyyee/FPraocteePcrtoitoenc:tion: ANS] 287.1 approved safety gasses with side shields or equivaleat. Safety
`goggles where there is a potential for splashingor contact with liquid material.
Skin Protection:
Nitrile gloves where
there
is
a
potential
for
splashing
or
contact
with
liquid
material.
Section 9 - Physical and Chemical Properties
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Appearance: Liquid
Color: Grayish-white
OVdaopro:rEPsrseesnstuirael:lyNoodtoarvlaeislsable
Vapor Density (Air=1): Not available
Boiling Point: 100 C1212 F (estimate, water)
Melting
Specific
PGorianvti:ty0:C1/.3425
F
(estimate,
wates)
pSoHl:ubGirleiattyeirntWhaatner8: Dispersion
MMoolleeccuullaarrWFeoirgmuhlta::NMoitxatpuprleicable
% Volatile by Volume: 35-38
Section 10 - Stability and Reactivity
Stability:
This product is stable.
Reactivity:
`This product is not reactive.
Conditions to Avoid: Hear, sparks, flames, and other ignition sous. Hazardous Decomposition Products:
Thermal decomposition ofthe polymer (af temperamres above 350 C/662 F) will generate hydrogen
fuoride (HF), which is corrosive, causing burs on contact with skin and other tissue.
Incompatibility (Materials to Avoid):
Alkali metals and halogenated compounds.
Section 11 - Toxicological Information
`Health injuries are not known or expected under normal use. Component surfactants may be absorbed by the skin and may be harmful byingestion. Ammonium Perfluorocionoate: LDS0 ora-l rar 536 mg/kg Carcinogenicit--y ACGIH A3
Non ionic surfactant
1PDol5y0meorraplyr--orlaytsi1s8p00rmog/dkug(.act t62s5 C1157 By:
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Rat 5 minute LCSO: 2700 mp/m3 Rat 30 minute LCS0: 3500 mg/m3
Breathing fumes generatedduringprocessing of the polymeric substance at temperatures ranging
From 315 10 375 C Symptoms include
(599 10 707 F) can cause chills, headache, nausea,
an influenza-like. disorder called `breathing discomfort, weakness,
"polymer fame fever". cough, sore throat, and
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fumefeveris smoking tobacco contaminated with minute amountsofpolytetrafluoroethylene
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damage (inflamorationofthe lungs) may occur in sevese cases, but recovery is normally complete.
No faralities from inhalationof PTFE fumes have been reported; 10 casesof polymer fume fever
`from overheatingof finished PTFE products have been reported.
This product
relented duri
may contain s
ng processing.
mTaFllEahmaosubnetesonfshroeswindutaol
temat
cause
lluivoerroeatnhdylkeinden
(T
ey
FcEan)cmeor ninomIsebro
that can
ratory
b
e
`animals in
California
a test
under
cPoronpdouscitteidonby65thaesNaatciaorncailnoTgoexn.icology
Program
(NTP).
Itis
also
listed
by
the
state
of
`Exposures to TFE can occur in handling newly opened drums and in siwuations where processing
temperatures
in processiag
eoxrcbeuemdimnagnouffSacurourroepro=slyrmeceormcmoenntdaaitniionngsp.arAtsv.oiTdo
breathing
minimize
fumes and
exposures
gases produced
10 trace levels of
TFE, follow the handling instructions in Section 8 ofthe MSDS. For additional information, consul:
the current editionofthe guide to the Safe Handling ofFluoropolymers published by the Society of
Plastics Industry, Inc. (SPI) Fluoropolymer Division.
Section 12 - Ecotoxicological Information
`No ecotoxicological information is available for this material.
Section 13 - Disposal Considerations
a`WcacsotrediDnigsptooscaulr:rMeanttefreidaelr,ala,ssstuaprpelainedd,lioscanlorreaguhlaaztairondso,usorwiansctienearcactoeridninaghtioghR-CteRmApe.raLnainrdef:ill
incinerator designed 10 burn fluorine-containing|`materials. Processing, use or contamination may `make this information inaccurate or incomplete.
Section 14 - Transportation information
Shipping Class: Not regulated by DOT.
Section 15 - Regulatory information
CAlhlemciocmaplonIennvtenstoafrtyhaisndprtohdeuCcatnaardeilainstEendvoinrotnhmeeTnotxailcPSruobtsecttainocnesAcCton(tCraElPAA)ctpr(oTvSisCiAo)naSledcotmieosnti8c(:3)
hup/10.80.196.45/msds/AlgoflowD60h_t2m7l
000173 32472003
+
Var-2etn 058 "ALGOFLON
DouF/ron-CUTONE
SERGE
rr
Te Ras Fei
`substances
list
(DSL). This praduct Standard (29 CFR
1s not a "hazardous substance" as 1910.1200). "This product is not a
defined by "controlled
OSHA Hazard product" asdefined
Communication by the Canadian
Workplace
Hazardous
Materials
Information
System
(WHMIS).
SARA 313 Toxic Chemicals: Componeats not listed
S`AAcuRteA: N31o1/312: CFihrre:onNico: Na
Reactivity: No Sudden ReleaseofPressure: No
SARA 302 Extremely Hazardous Substances: Components notlisted
`Polytemafluoroethylene is listed on the Pennsylvania Hazardous Substance List.
Section 16 - Additional Iiformation
NFPA Ratings (Scale of0-4): HFierael=t0h=1
Reactivity=0
To our knowledge, the information contained However, neither Solvay Solexis Inc. nor any
herein is accurate as of the of its affiliates makes any
dateofthis document. warranty, expressed or
implied, or accepts any liability in connection with this information or its use. This information is fur
upsreodbuyctteicnhcnoicmablilnyasskiiolnlewdiptehrasnoynsoarthtehreisruobswinancdeisocrreatniyonoiahnedrrpirsokcaesnsd.dToheissniostorfelaateli1c0entshee uunsdeoerfatihiiys
`patent or other `ormaterial for
proprietary right. The any contemplated use,
user alone must finally determine suitability of the mannofeusre andwhetherany patents are
any informaticn infringed. This
information givestypical properties only and is not to be used for specification purposes.
Copyright 2002, Solvay Solexis, Inc. All Rights Reserved.
L
hp://10.80.196.45/msds/Algoflon/D60_27. hrm
000174
3/24/2003