Document MG81XZpQ11wRxyk3Q3dogNDd9

-----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------IDate Printed: 03-25-1996 Page 1 LA-MAR-KA MSDS for AMMONIUM HYDROXIDE, 1% TO 30% AQUEOUS + ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- --- 1 -PRODUCT IDENTIFICATION PRODUCT NAME: COMMON SYNONYMS: CHEMICAL FAMILY: FORMULA: FORMULA WT.: CAS NO.: NIOSH/RTECS NO. : PRODUCT USE: AMMONIUM HYDROXIDE, 1% TO 30%, AQUEOUS AMMONIUM HYDROXIDE, IN TO 8N VOLUMETRIC SOLUTIONS AND CONCENTRATES NH40H IN H20 N/E N/E N/E LABORATORY REAGENT CHEMTREC # (800) 424-9300 LA-MAR-KA, INC. 10272 SOUTH PERDUE STREET BATON ROUGE, LA. 70814 EFFECTIVE: 03/24/95 REVISION #01 ISSUED: 03/24/95 PRECAUTIONARY LABELING LA-MAR-KA LABELING SYSTEM HEALTH 3 SEVERE (POISON) FLAMMABILITY 1 SLIGHT REACTIVITY 2 MODERATE CONTACT 3 SEVERE (CORROSIVE) LABORATORY PROTECTIVE EQUIPMENT GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD; PROPER GLOVES U.S. PRECAUTIONARY LABELING POISON DANGER CAUSES BURNS. HARMFUL IF INHALED. MAY BE FATAL IF SWALLOWED. EXCEPTIONAL HEALTH AND CONTACT HAZARDS: READ MATERIAL SAFETY DATA SHEET. DO NOT GET IN EYES, ON SKIN, ON CLOTHING. DO NOT BREATHE VAPOR. KEEP IN TIGHTLY CLOSED CONTAINER. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. KEEP CONTAINER OUT OF SUN AND AWAY FROM HEAT. IN CASE OF FIRE, USE WATER SPRAY. IN CASE OF SPILL, CAREFULLY NEUTRALIZE SPILL WITH DILUTE HCL. FLUSH SPILL AREA WITH WATER. INTERNATIONAL LABELING IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN. PRECAUTIONARY LABELING (CONTINUED) KEEP OUT OF REACH OF CHILDREN. IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY DO A 060549 CONFIDENTIAL + --------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- + Date Printed: 03-25-1996 Page 2 LA-MAR-KA MSDS for AMMONIUM HYDROXIDE, 1% TO 30% AQUEOUS +--------------------------------------------------------------------------------------------------------------------------------------------------------------------+ 1 -PRODUCT IDENTIFICATION (continued) WITH PLENTY OF WATER AND SEEK MEDICAL ADVICE. 2 -COMPONENTS COMPONENT AMMONIUM HYDROXIDE WATER CAS NO. 1336-21-6 7732-18-5 WEIGHT % 1- 26 99-64 OSHA/PEL 35 PPM N/E ACGIH/TLV 25 PPM N/E 3 -PHYSICAL DATA BOILING POINT: N/A VAPOR PRESSURE (MMHG): N/A MELTING POINT: N/A VAPOR DENSITY (AIR=1): N/A SPECIFIC GRAVITY: N/A (H20=l) EVAPORATION RATE: N/A SOLUBILITY(H20): COMPLETE (100%) % VOLATILES BY VOLUME: 100 (21 C) PH: 14.0 ODOR THRESHOLD (P.P.M.): N/A PHYSICAL STATE: LIQUID COEFFICIENT WATER/OIL DISTRIBUTION: N/A APPEARANCE & ODOR: CLEAR, COLORLESS LIQUID. PUNGENT ODOR. 4 -FIRE AND EXPLOSION HAZARD DATA FLASH POINT (CLOSED CUP): N/A NFPA 704M RATING: 3-1-0 AUTOIGNITION TEMPERATURE: N/A FLAMMABLE LIMITS: UPPER - N/A LOWER - N/A FIRE EXTINGUISHING MEDIA USE WATER SPRAY. SPECIAL FIRE-FIGHTING PROCEDURES FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE. MOVE EXPOSED CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK. USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL; DO NOT GET WATER A 0605^0 cNFTDFNTI4L -4------ --------------- ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------ Date Printed: 03-25-1996 Page 3 LA-MAR-KA MSDS for AMMONIUM HYDROXIDE, 1% TO 30% AQUEOUS + ------------------------------------------------------------------------------------------------------------------------------------------------------------------+ f 4 -FIRE AND EXPLOSION HAZARD DATA (continued) INSIDE CONTAINERS. UNUSUAL FIRE & EXPLOSION HAZARDS GIVES OFF FLAMMABLE VAPORS. VAPORS MAY FORM EXPLOSIVE MIXTURE WITH AIR. CLOSED CONTAINERS EXPOSED TO HEAT MAY EXPLODE. ANHYDROUS AMMONIA HAS THE FOLLOWING FLAMMABLE LIMITS: UPPER - 25% AND LOWER - 16%. THE AUTOIGNITION TEMPERATURE FOR AMMONIA GAS IS 1204 F. TOXIC GASES PRODUCED AMMONIA, OXIDES OF NITROGEN EXPLOSION DATA-SENSITIVITY TO MECHANICAL IMPACT NONE IDENTIFIED. EXPLOSION DATA-SENSITIVITY TO STATIC DISCHARGE NONE IDENTIFIED. 5 -HEALTH HAZARD DATA THRESHOLD LIMIT VALUE (TLV/TWA): 18 MG/M3 (25 PPM) * /IS FOR AMMONIA. SHORT-TERM EXPOSURE LIMIT (STEL): 27 MG/M3 (35 PPM) STEL IS FOR AMMONIA. PERMISSIBLE EXPOSURE LIMIT (PEL): 27 MG/M3 (35 PPM) PEL IS FOR AMMONIA. TOXICITY OF COMPONENTS ORAL RAT LD50 FOR AMMONIUM HYDROXIDE INTRAPERITONEAL MOUSE LD50 FOR WATER INTRAVENOUS MOUSE LD50 FOR WATER CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO 350 190 25 OSHA REG: NO CARCINOGENICITY NONE IDENTIFIED. REPRODUCTIVE EFFECTS NONE IDENTIFIED. EFFECTS OF OVEREXPOSURE INHALATION: SEVERE IRRITATION OR BURNS OF RESPIRATORY SYSTEM, PULMONARY EDEMA, LUNG INFLAMMATION MG/KG G/KG G/KG DO A 060551 OO NFT DFNTJal ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------ 1- Date Printed: 03-25-1996 Page 4 LA-MAR-KA MSDS for AMMONIUM HYDROXIDE, 1% TO 30% AQUEOUS --------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- + 5 -HEALTH HAZARD DATA (continued) SKIN CONTACT: SEVERE IRRITATION OR BURNS EYE CONTACT: SEVERE IRRITATION OR BURNS, PROLONGED CONTACT MAY CAUSE PERMANENT CORNEAL DAMAGE, BLINDNESS SKIN ABSORPTION: NONE IDENTIFIED INGESTION: IS HARMFUL AND MAY BE FATAL, SEVERE BURNS TO MOUTH, THROAT, AND STOMACH, NAUSEA, VOMITING, DIARRHEA CHRONIC EFFECTS: NONE IDENTIFIED TARGET ORGANS RESPIRATORY SYSTEM, LUNGS, EYES, SKIN, MUCOUS MEMBRANES MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE SKIN DISORDERS, RESPIRATORY SYSTEM DISEASE PRIMARY ROUTES OF ENTRY INHALATION, INGESTION, EYE CONTACT, SKIN CONTACT URGENCY AND FIRST AID PROCEDURES INGESTION: CALL A PHYSICIAN. IF SWALLOWED, DO NOT INDUCE VOMITING. IF CONSCIOUS, GIVE LARGE AMOUNTS OF WATER. FOLLOW WITH DILUTED VINEGAR, FRUIT JUICE OR WHITES OF EGGS, BEATEN WITH WATER. INHALATION: IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. SKIN CONTACT: IN CASE OF CONTACT, IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. WASH CLOTHING BEFORE RE-USE. EYE CONTACT: IN CASE OF EYE CONTACT, IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. SARA/TITLE III HAZARD CATEGORIES AND LISTS ACUTE: YES CHRONIC: YES FLAMMABILITY: NO PRESSURE: NO REACTIVITY: NO EXTREMELY HAZARDOUS SUBSTANCE: YES CERCLA HAZARDOUS SUBSTANCE: YES SARA 313 TOXIC CHEMICALS: GENERIC CLASS: YES CONTAINS AMMONIA (RQ = 100 LBS, TPQ = 500 LBS) CONTAINS AMMONIUM HYDROXIDE (RQ = 1000 LBS) CONTAINS AMMONIA C16 DO A 06.0552 CONFIDENTIAL 4----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- H Date Printed: 03-25-1996 Page 5 LA-MAR-KA MSDS for AMMONIUM HYDROXIDE, 1% TO 30% AQUEOUS 4- -------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- ----- 5 -HEALTH HAZARD DATA (continued) TSCA INVENTORY: YES 6 -REACTIVITY DATA STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR CONDITIONS TO AVOID: HEAT, SUNLIGHT INCOMPATIBLES: STRONG ACIDS, MOST COMMON METALS, STRONG OXIDIZING AGENTS, BROMINE, CHLORINE, ALUMINUM, COPPER, BRASS, BRONZE, MERCURY, DIMETHYL SULFATE DECOMPOSITION PRODUCTS: AMMONIA, OXIDES OF NITROGEN 7 -SPILL & DISPOSAL PROCEDURES STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING. STOP LEAK IF YOU CAN DO SO WITHOUT RISK. VENTILATE AREA. CAREFULLY NEUTRALIZE SPILL WITH DILUTE HCL. FLUSH AREA WITH FLOODING AMOUNTS OF WATER. (USE CAUTION.) DISPOSAL PROCEDURE DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL ENVIRONMENTAL REGULATIONS. 8 -INDUSTRIAL PROTECTIVE EQUIPMENT VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV REQUIREMENTS. RESPIRATORY PROTECTION: RESPIRATORY PROTECTION REQUIRED IF AIRBORNE CONCENTRATION EXCEEDS TLV. AT CONCENTRATIONS UP TO 300 PPM, A CHEMICAL CARTRIDGE RESPIRATOR WITH AMMONIA/AMINE CARTRIDGE AND DUST/MIST FILTER IS RECOMMENDED. ABOVE THIS LEVEL, A SELF-CONTAINED BREATHING APPARATUS IS ADVISED. EYE/SKIN PROTECTION: SAFETY GOGGLES AND FACE SHIELD, UNIFORM, PROTECTIVE SUIT, RUBBER GLOVES ARE RECOMMENDED. DO A 60553 co/n/f r^NTlA[ +--------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------+ Date Printed: 03-25-1996 Page 6 LA-MAR-KA MSDS for AMMONIUM HYDROXIDE, 1% TO 30% AQUEOUS +----------------------------------------------------------------------- '--------------------------------------------------------------------------------------------+ 9 -STORAGE AND HANDLING PRECAUTIONS STORAGE REQUIREMENTS KEEP CONTAINER TIGHTLY CLOSED. STORE IN CORROSION-PROOF AREA. STORE BELOW 25 C. DO NOT STORE IN DIRECT SUNLIGHT. ISOLATE FROM INCOMPATIBLE MATERIALS. 10 -TRANSPORTATION DATA AND ADDITIONAL INFORMATION DOMESTIC (D.O.T.) N/A = NOT APPLICABLE OR NOT AVAILABLE N/E = NOT ESTABLISHED THE INFORMATION IN THIS MATERIAL SAFETY DATA SHEET MEETS THE REQUIREMENTS OF THE UNITED STATES OCCUPATIONAL SAFETY AND HEALTH ACT AND REGULATIONS PROMULGATED THEREUNDER (29 CFR 1910.1200 ET. SEQ.) AND THE CANADIAN WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM. THIS DOCUMENT IS INTENDED ONLY AS A GUIDE TO THE APPROPRIATE PRECAUTIONARY HANDLING OF THE MATERIAL BY A PERSON TRAINED IN, OR SUPERVISED BY A PERSON TRAINED IN, CHEMICAL HANDLING. THE USER Tq RESPONSIBLE FOR DETERMINING THE PRECAUTIONS AND DANGERS OF THIS CHEMICAL * HIS OR HER PARTICULAR APPLICATION. DEPENDING ON USAGE, PROTECTIVE CLOTHING ^CLUDING EYE AND FACE GUARDS AND RESPIRATORS MUST BE USED TO AVOID CONTACT WITH MATERIAL OR BREATHING CHEMICAL VAPORS/FUMES. EXPOSURE TO THIS PRODUCT MAY HAVE SERIOUS ADVERSE HEALTH'EFFECTS. THIS CHEMICAL MAY INTERACT WITH OTHER SUBSTANCES. SINCE THE POTENTIAL USES ARE SO VARIED, LA-MAR-KA CANNOT WARN OF ALL OF THE POTENTIAL DANGERS OF USE OR INTERACTION WITH OTHER CHEMICALS OR MATERIALS. LA-MAR-KA WARRANTS THAT THE CHEMICAL MEETS THE SPECIFICATIONS SET FORTH ON THE LABEL. LA-MAR-KA DISCLAIMS ANY OTHER WARRANTIES, EXPRESSED OR IMPLIED, WITH REGARD TO THE PRODUCT SUPPLIED HEREUNDER, ITS MERCHANTABILITY OR ITS FITNESS FOR A PARTICULAR PURPOSE. THE USER SHOULD RECOGNIZE THAT THIS PRODUCT CAN CAUSE SEVERE INJURY AND EVEN DEATH, ESPECIALLY IF IMPROPERLY HANDLED OR THE KNOWN DANGERS OF USE ARE NOT HEEDED. READ ALL PRECAUTIONARY INFORMATION. AS NEW DOCUMENTED GENERAL SAFETY INFORMATION BECOMES AVAILABLE, LA-MAR-KA WILL PERIODICALLY REVISE THIS MATERIAL SAFETY DATA SHEET. APPROVED BY LA-MAR-KA, INC. DO A 060554 CONFTDFNTIAl