Document MEkKnOe22eMJ4B6e3vpovRa9
M & a .G - O l Z
BIODEGRADATION (BOD/COD)
TEST SUBSTANCE________________________________________________
Identity: A mixture containing perfluorooctanesulfonate, which may also be referred to as PFOS, FC-95, or as a component of FC-603F. (1Octanesulfonic acid) (CAS # 2795-39-3).
Rem arks: The 3M production lot number was 501. The test sample is FC603F. Current information indicates it is a mixture of 0.5% PFOS, 7% diethylene glycol butyl ether, 82.95% water, 2% acrylic foamer, 4% Alkylether sulfate, 1.45% Xanthan gum, 1.4% calcium acetate, 0.07% N-(3Chloroallyl)hexaminium chloride, 0.5% triethanolamine, 0.05% sodium hydroxide, 0.03% cis-1-(3-Chloroallyl)-3,5,7-triaza-1-azoniaadamantane chloride, and 0.05% tolytriazole.
The following summary applies to a mixture with incompletely characterized concentrations o f impurities. Data may not accurately reflect the biodegradability o f the fluorochemical component o f die test sample.
METHOD:_________________________________________________________
Method: Not noted. Type: Aerobic GLP: No Year completed: 1994 Contact time: 28 days Inoculum: Not given.
RESULTS_________________________________________________________
Chemical Oxygen Demand (COD):
276,000 mg/kg
Biochemical Oxygen Demand (BOD): 5-Day:
20-Day: 28-Day:
47,700 mg/kg 230.000 mg/kg 296.000 mg/kg
C O N C L U S IO N S ___________________________________________________
No conclusions given.
Submitter: 3M Company, Environmental Laboratory, P.O. Box 33331, St. Paul, Minnesota, 55133
002441
DATA QUALITY R eliability: Klimisch ranking 3. Study lacks description and records of the method followed. The inoculum was not properly characterized. Sample purity was not properly characterized and the study lacks analytical confirmation of the amount of fluorochemical proportion in the solution. REFERENCES____________________________________________________ This study was conducted by Pace, Inc., of Minneapolis, MN at the request of the 3M Company, Lab Request number M 1 6 5 5 ,1994. OTHER_____________ ________________________ _____________________ Last changed: 6/26/00
002442
BEST COPY AVAILABLE
DATE: 0 3 / 3 1 / 1 9 5 4
3K ENVIRONMENTAll LABORATORE CONTRACT LABORATORI WORK ORDER BY PARAMETER
LAB REQUEST NO. M1655
CONTRACT LAB : p a c e PROJECT NUMBER ; BILTWENVIR SKIP DATE
Com puter Code
T e s t Name
PROJECT LEAD: 5A BEACH TELEPHONE : 6 1 2 - 7 7 8 - 7 4 5 2 fAX : 6 1 2 -7 7 8 -6 1 7 6
Sam ple N um bers
Sam ple A v ailab le D ate
R esu lt Due D ate
COD COD P-C BOD-05 BOD-05 1CARBONACEOUS i P-CBOD-20 BOD-20 (CARBONACEOUS) P-CBOD-2 3 BOD-2 3 (CARBONACEOUS)
1
t Jk
1
1
0 3 /2 1 /1 9 3 3 0 3 /3 1 /1 3 9 4 0 3 /2 1 /1 3 3 4 0 3 /3 1 /1 3 3 4
0 4 /1 3 /1 9 9 4 0 4 /2 2 /1 9 9 4 0 5 /0 3 /1 3 3 4 0 5 /1 5 /1 9 3 4
"B io chem ical Oxygen Demand
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cbod-oS ------
Oate/Time Out M j 13.(ff-/
B EST CO PY AVAILABLE
m** H^ /JbS
Reviewed
Samples BOO and
C800
Analysis Results Units
Comments pH
Seec Samp Add Bottle Vd Vd Inhto. # (mL) (ml) (CBOD)
01
02 0 0 DROP (D1-D2)
BOO
Blank Blank
OPt
Seed Control Seed Control
^.H S-
Seed Control
mg/L Inhibited
0 NA 0 NA 25 25 25 25 25 25
No > . y
No - h - > $
No h
7 -7
No U S 7 - 4
Yes 'IC L
7 .1 7, 3 . *7
3 .3 v5,
,7 0 .7 -
V, 5 7 -6 < 7 .7 -
Seed Control
Inhibited
25 25 Yes S 6
5 . a -2 .7
LCS
TV198 31
26
No OqP
/( I
LCS
TV198 31
26
No W
V * . 2 .3 .0
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Seed Correction % ( - - g - ) [ S - l f e ) - j 9 ^ S < /
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---------
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Correction)
x
300
mL
.'or vol.
D2 must be >1.0
0 0 DROP must be >2.0
Seed Lot Na ^ ? 7 ? 7 !5
, .....i Incubator
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002444
Biochemical Oxygen Demand
Oala/TimeIn V / f / f *-/ / A > / )
BOD-__ ___
BEST COPY AVAILABS^1" 0*- ^ ^ ^ C/Analyst r A. -E2
Roviiiew C ^ 2 Z l
Samples BOD and
CBOD Blank
Blank
Seed Control
Analysis Results Units
mgrt.
Comments pH
Seec Samp Add Bottle Vd Vd Inhib. # (mL) (mL) (CBOD)
0 NA No
D1
0 NA 25 25
No No
7*
D2 TJ
DO DROP (01-D2)
BOD
Seed Control Seed Control Seed Control LCS
Inhibited Inhibited TV19831
25 25 25 25 25 25 26
No V Yes
Yes X I - i . y b No
3 .y 04
(ri 3 6 ,y
m
LCS
TV198 31
2 6 No
2 0D 2 VeS 3 7 7 - f
1
2 COiS-
1 ? *
2 o a st
7Y ? - 4
2 5 .COS' 2 (JDJ
<
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1 12 3 o t o& 1
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Seed Correction
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2 >-C0^ 2 0.00?
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37f
13
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1
V. 1 S'./ */
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: ' - w i t e i W
D2 mustbe > 1.0
Inhibited Seed Correction = ( SiroSop) InrrtSMd
CCftredl&VSoSl(fm-'i)A7.i
/Ktf = - 7 ^ ,.-rr--:------
DO DROP mustbe >20 k 4 )
`lUTWiBS'fe,
/ Biochemical Oxygen Demand
Dataffimeln V / f A W
BOO-___
C800-
-
Oatertime Out
BEST COPY AVAILABLE Analyst m .
lbi6
Samples BOO and
CBOO
Blank
Analysis
Comments
Results Units
pH
mg/L
Seec Samp Add Bottle
Vd Vd Indb. #
M O M L (CBOD)
NA No
Dl
02 0 0 DROP
P1-D2)
6 fl Q P i
Blank Seed Control
NA No m
25 No
** .0
BOD
Seed Control
25 No
Seed Control Seed Control LCS
Inhibited Inhibited TV198 31
25 25 25 25
2
Yes 4 U Yes
No
A 6 .? > L i-A
LCS TV198 31
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f~ ( ^ T ) t a s ^ r ) ( a * s i ^
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Inhibited Seed Corocfcn = ( c Sto^ p)
XOrrt.
InMxSeaJ
.Cortrol Vd (rrt)
. ^ O .b S ' -V.'.V
D2mustbe>
DO DROP mustbe > 0
- SeedLot Na s ( q H
r > S* * -. *
002446
