Document M41gNe9o6a9w94QyMvDY80apM

4 * Willi Budoat Btitmtu No. 44-RI3S7 Approval Etpirat April 30. 1971 V.S. DEPARTMENT OF LABOR ,, j-j' : ^ 7 : J' s' . J . rom "O. LSb-UD!>- May 1969 WAGE AND LABOR STANDARDS ADMINISTRATION Bureau of Labor Standards MATERIAL SAFETY DATA SHEET manufacturer's name PFO ADDRESS fNumber, Street, City, Slate, and ZIP Code) SECTION 1 EMERGENCY telephone NO. f216) 753-4561 CHEMICAL NAME AND SYNONYMS 25% Di-sec-butvl Perorvdicarbonate in OMS TRADE NAME AND SYNONYMS <75% SliBP ' Payoxide, Solution F0BMULA CloHls06 (pure SBP) PAINTS.PRESERVATIVIS, l SOLVENTS PIGMENTS tCATALVSf Vehicle Solvents additives tr - v. - r -- * > `.V. jLii- **# - > OTHERS % TLV (Unlit) ALLOYS AND METALLIC COATMOS BASE METAL ALLOYS METALLIC COATINGS FILLER METAL PLUS COATING OR CORE FLUX OTHERS 4 J ^"'^?''-:-'^S'ijirt^OS MIXTURES OR OTHER LIQUIDS, SOLIDS, OR OASES '^tll-sec-butyl peroxydicarbonate 11 odorless mineral spirits (ppm) A --` .- % TLV (IMHt) % JTLT (OrIk) 75 NA 25 5oo -J r'oiling point f ^ecpnpoaes on hes ting SPECIFIC GRAVITY IHaO=l) VAPOR PRESSURE Imm Hp.) VAPOR DENSITY 1AIR-1 i 1 SOLUBILITY IN MATER l NA NA ne Eligible "voL^ru (decomposes) EVAPORATION RATE APPEARANCE AND 00OR clear liquid, unpleacuit. TTRWEK-%a>i--''V' ' "r" 0.971 NA NA j FLASH POINT IMath04 ua*4l 51*0 (OPPSD Micro) FLAMMABLE LIMITS OMS Lol I EXTINGUISHING MEDIA water I SPECIAL FIRE fighting procedures Don't fight a peroxydicarbonate fire. It will burn out auieklv. Uol I Limit fire by water spray from a safe distance. | unusual reieases gases which spray flammable liquids and 1 1 Si 074549 threshold limit value jjot established: solvent OMS TLV = 500 ppm, SBP has very low vapor EFFECTS OF OVEREXPOSURE , --- . ID<n 9.3 g/kg, non-toxic. Moderately irritating to the eye. pres suite. Extremely irritating to the akin. Solvent causes narcoBis. EMERGENCY AND FIRST AID PROCEDURES Sirin Contact; Flush with water, clean with soap and water and then with alcohol. t Eye Contact: Flush with water for at least 15 minutes, call a physician. Swallowing: Do not induce vomiting, consult a physician immediately. -ITS "Lrrr mm STASIUTY UNSTABLE STABLE CONDITIONS TO AVOID Tfefrigerate at -18*0 (0*F) Contamination I INCOMPATABILITY filauriolM to avoid) accelerators, amines, acids, alkaline materials HA2ARDOUS DECOMPOSITION PRODUCTS Some decomposition products flammable ! HAZARDOUS ! POLYMERIZATION MAY OCCUR WILL NOT OCCUR CONDITIONS TO AVOID , , , ., Contact with Dolvmerizable materials X (monomers) Product is a polymerization initiator. -Wr ' " 4IPW STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED xii Snill; Flood with water and waBh up with soap and water. Alternate Method: Cover with sand and clean up. Spread solid with adsorbed peroxide in a safe disposal area immediately. a. Add waste cautiously to $% alcoholic potassium hydroxide. Alternate Procedure: Scatter material on ground in a well ventilated disposal are andlallow to decompose gradually. uu .k-V'V'B!1 iTWBKinanayp .T respiratory protect.on (Spooifr against mists and vapors local exhaust Provide adequate ventilatior SPECIAL MECHANICAL (General) OTHER PROTECTIVE GLOVES Rubfcel.j pyC EYE PROTECTION Splash Goggles OTHER protective equipment shoes, plastic aprons. bl.' MraBtfiu |,v. n.; i >1* .''~w---, . *a . 'jOr--X'MQ'. -2**"w PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Store at -18C (0*F) or below. Check storage temperatures at least once a shift. See manufacturer's literature. %xxlTiajyTlreSfrigeration can be provided by dry ice placed above the peroxy- dicarbonate. SL 074550 Form Approved ftudpat 6wr*pu Mo. 44-91387 Approval lupirot April 30. 1971 .$. DEPARTMEKI OF LMOR w O V* ` * /. (> t "7 ^ WAGE AND LABOR STANDARDS ADMINISTRATION Buraau of Labor Standards MATERIAL SAFETY DATA SHEET Form No. L$9005*4 May 1969 MANUFACTURER'S name :i ____ PPG ' ADDRESS (NamStr, Strttt, City. Stair, and ZIP Coda) SECTION 1 CH^MIpAL NAME AMD SYMNVMS ? 50%-0i.-Bee-butyl Iteroxydicarbonate In Toluene f"MOLA EMERGENCY TELEPHONE NO, SVNONVMS CloHle0s (pun*,) V ,PAINTS,PRESERVATIVIS, a SOLVENTS PIGMENTS _ " .(CATALYST ^>HICiti ''SOLVENTS ijoomyw j.,- _ % TLV (ltoi*) ALLOYS AND METALLIC COATINGS BASE METAL ALLOYS METALLIC COATINGS FILLER METAL PLUS COATING ON CORE FLUX OTHERS SSL ?.!s \1 h. wlRgj.1-,jteF-r?^feAii*. - * ^^^i^.fc..ssJFTA''3^j^Aj^u>J|||*XTUltej 0f 0THCR LI#UIDSt solids, or oases F' r dl*Heobutyl peroxydicarbonate V #twlnen^ppm) - -- - -- -- r'a?3r*: ...... ` -t-" - ' ... .... * TLV (UrIt.) ft (UTrLIVm) $0 NA 50 200 ,, decomposes on he ating SPECIFIC GRAVITY <MjO=1> VAPOR PRESJ1(RI iTM> M#,) VAPOR OENSITY IAIR=1) 1 90LU9ILITY IN WATER NA NA ne eligible PERCENT VOLATILE BY VOLUME l%> EVAPORATION RATE 1-- =U APPEARANCE AND ODOR clear liquid, toluene odor I >. H - . o.?5i _ _ FLASH POINT |M.ttiod UMdl EXTINGUISHING MEDIA Water FLAMMASLE LIMITS Toluene . ui UrI 1 1 SPECIAL FIRE FIGHTING PROCEDURES 1- Do^t fight a TwrmnrrHp.arhnnat^ fim.____It will burn ant, miifJrlv, ___T.imit. r-l-rp________1 | by water spray from a safe distance. | 1 UNUSUAL FIRE AND EXPLOSION.HAZARDS ... gr1 1 Thermal decomposition releases gases which sprav flamnahlp U I into the air where they mix with oxyj;en and burn very vigorous!HpL- 1 SL 074551 THRE UoctDeLs>1^^iii^hed: solvent, toluene TLV - 200 ppm; SBP has very low vapor pressure! EFFECTS OF OVEREXPOSURE Not estaolisned. Product i3 expected to be moderately Irritating to eyes and extremely irritating to the skin. Solvent is an irritant. EMERGENCY AND FIRST AID PROCEDURES , ,, Skin Contact: Flash with water, clean with soap and water and then with alcohol. Swallowing: if Do not induce vomiting, consult a physician immediately. -,----------- , ... tl- i*. -u1. . m.*'" . rnT Ml-- 7.-' ' .b'1* ' ;* ' v' Vjt-t .................. 'V*" | '"y stability UNITASLE X '-7*c w?) STASH Contamination incompatability (Mattriai. to avoid) accelerators} f^gg acids, alkaline materials 1 I HAZARDOUS DECOMPOSITION PRODUCTS Some decomposition products flammable II .......... 1 HAZARDOUS POLYMERIZATION MAY OCCUR WILL NOT OCCUR C8ontactTwf^fiIIpolyinerlzable materials X (monomers) 1 Product is a polymerization initiator. ... ' ...... ............. ... r... .'aW^-7^. STEPS TO ME TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Small Spill; Flood with water and wash up with soap and water. T*PT . S'. Alternate Method; Cover with sand and clean up. Spread solid with adsorbed peroxide in a safe disposal area immediately. ^aiy^ian^lTfes: Add waste cautiously to 5% alcoholic potassium hydroxide. Alternate Procedure: Scatter material on ground in a well ventilated disposal aduall: respiratory protection fSppei/y iyp; protect against mists and vapors ventilation local exhaust adeqUate ventilatior SPECIAL MECHANICAL (Crntml) OTHER vn..iwtoSij*F* protective gloves Rubber( EYE protection Splash Goggles OTHER PROTECTIVE EQUIPMENT R,, ubber sih. oes, pilastic a__p__ro__n_ s agawujriikL.jj.wu. f--------------r--vr-ir 'y ' ebb* *.?* "t*..'.- PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Store at -7*0 (20"F) or below. Check storage temperatures at least once a shift. See manufacturers literature. Auxiliary refrigeration can be provided by dry ice placed above the peroxy- dicarbonate. Snergency refrigeration can be provided by direct contact with wet Ij It f SL 074552 U.b. UfcPAH l IVlfcNl Of- LABOR Occupational Safety and Health Administration MATERIAL SAFETY DATA SHEE7 /I* -/ <*m * . I dint /\ppfr>vCCl OMB NO. 44-RUB7 Required under USDL Safety and Health Regulations for Ship Repairing, Shipbuilding, and Shipbreaking (l!!) CFR 1915, 1916, 19171 manufacturer's nami SECTION I gme netr/cr TCtLimoNt: no. PPG Industries ,,.... .... ....... ....... (2161 753-4561___ aijohess liViimirr Strrtt. City. Stair. CuJri *. O .*** ~LIIE KtrSxiffRsVlE AND SVNOriVMi I TMAOt NAMt ANB SYNONYMS --30%~Di-Sec-Butvl Peroxvdlcarbonate In xvlene I tHTTliCALTAiaO--------- ' rO R MU LA 30% 3BP in xylene ~ ,f pwr*. 9RP) o -PAINTS, PRESERVATIVES. b SOLVENTS PfOMINTS----- - - " ` ' ' X TLV (Unit*) ALLOYS AND METALLIC COATINGS BASE METAL CATALYST ......" ALLOYS Vehicle "--"-- SULVENfS ' ~~........................ AOOUiVES ~ METALLIC COATINGS filler METAL PLUS COATING OR CORE FLUX OTHERS OTHERS HAZARDOUS MIXTURES OF OTHER LIOUID5. SOLIOS. OR CASES Diraac-butryl oeroxvdicarbonate M-xylene (PHI) , "~y/''**" 1 . "x TLV (Unlttl TLV X (Unitli 30 NA 70 100 ----- SECTION III - PHYSICAL DATA aoiLino 'N3^c,yBBOafta on heatIns VAROR PRESSURE VAPOR DENSITY (AIR-. 1) 3 GO Cl . 10. No Data SPECIFIC GRAVITY PERCENT, VOLATILE BY VOLUME (X| EVAPORATION RATE t----------------- !) Decotrooses _0.930 70 _ NA _ solubility it* water Jlggligibl ----------------------------------------------------- APPEARANCE AND ODOR clear liquid, xvlene odor SECTION IV FIRE AND EXPLOSION HAZARD DATA FLASH POINT (MvinoO UNOM! _ FLAMMABLC LIMITS 87? (Seta-Flash Close CupOM-xylene uL r._ ;A --TrOS-- cxtihguishino mcoia Jfeter srccini f.re fighting pporeoi-'PES Don't fight a peroxydjearbonate fire; It will burn out quickly: Unit fire by w^ter ___ spray, from a safe distance. unusual pine-and exPLOVcn hazards _ ..TheriOAL decomposition releases gases _v?lich_spray 1 jquid,,gnd_yapor,,into_S;lig.Jl- where they mix with oxygen and burn very vigorously. .. RAGE (l) (Continued on reverse side! Form OSHA-20 AM. My 71 SL 074553 SECTION V HEALTH HAZARD DATA tllltlT.I IOLO LIMI l VALUE "" Not established; solvent, xylene T!,V100_FPM; SBP has very low vapor pressure II I KlSOf OVKULKMOSURE Acute Toxicity - Oral LD^q* 6.8 g/kg Dermal LDjq- 3.0 g/kg practically non- toxlc. Moderately Irritating to the skip. Mildlv Irritating to the eve. SoT emergency and nasi AiopHoccooers vent produces narcosis. ____ .Skill..Cant*At:. Xlusb with. wa.ttr.,.tlftan_Hi.th_Aoap and water and then with ___ alcohol. Eye Contact;__Flush with water for at least IS minutes, call physlcip Swallowing: Do not Induce vomiting, consult a physician Immediately. STABILITY unstable stable SECTION VI - REACTIVITY DATA LUNOITIONS TO AVUIO jc._ Sefriferate t 00 C n20pi Contamination accelerators, amines, acida, alkaline material* hazaroous decomposition products Some decomposition products flamnabla hazardous POLYMERIZATION may occur WILL NOT OCCUR CONDITIONS TO AVOID Contact with polymer!*ah!e materials (monomers) Product la a polymerization initiator. SECTION VII SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED ______ Small Solll: Flood with water and wash up with soap and water. Alternate method: Cover with sand and clean uo. Spread solid with absorbed peroxide in a safe disposal area Immediately. WASTE DISPOSAL METHOD Snail Quantities: Add waste cautiously to 57. alcoholic potassium hydroxide. Alternate PrftgpHnrw Rcettei- materiel rm ground in A well vtnM1atad_diappeal ares and allow to decompose gradually. SECTION VIII SPECIAL PROTECTION INFORMATION PEiklRATORV PROTECTION (SpCtjfV t\IK) Protect against mists and vapors VENTILATION LOCAL EXHAUST Provide edeouefe ventilJtion MECHANICAL {General) SPECIAL OTHER PBOTCCTIVE CLOVES EVE PROTECTION Rubber. PVC __Solesh Goggles_____________________________ OTHER PROTECTIVE EQUIPMENT Rubber rtwea. bImUf iptwi----------------------------------------------------------------------------------------------- SECTION IX SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANOLINC AND STORING . _Store at 0 C (32 F) or below. Check storage temperatures at least once a shi t_.__________ SesjMnufastvuerrJLa_ literature, i;*tcautions .........Auxiliary refrigeration cn be provided bv drv ice placed above the oeroxv ______ dlcarbonate. PAGE 121 *. : t*o Emergency refrigeration can be provided by dlrece contact with wet icc. Form OSHA-20 Rtv. May 11 SL 074554 #-- f r ' V <- U.S, DEPARTMENT OF LABOR Occupational Safety and Health Administration MATERIAL SAFETY DATA SHEET Form Aoorovtd OMt N. 44-RlJS? Required under USDL Safety and Health Regulations for Ship Repairing, Shipbuilding, and Shipbreaking (29 CFR 1915. 1916. 1917) June, 1978 SECTION 1 MANUFACTURER'S NAME EMERGENCY TELEPHONE NO. PPG Industries, Inc. (216) 753-4561 AOOACSS-Wfui**i. Strrtt. aty.Stttt. end ZlfCodtl -------- One Gateway Center. Pittsburgh, PA 1S222 CHEMICAL NAME AMO SYNONYMS TRAOC N/^^ANO SYNONYMS 01-sec-outvl Peroxvdlcarbonate CHEMiCALFAm1ly! I ~ FORMULA~ Organic Peroxide ____________ ciomsoa^______________________ ~ - SECTION II HAZARDOUS INGREDIENTS PAINTS.PRESERVATIVES.* SOLVENTS % TLV (Units) ALLOYS AND METALLIC COATINOS PIGMENTS BASE METAL 'catalyST ALLOYS VEHICLE.......... SOLVENTS ADDITIVES METALLIC COATINGS filler metal PLUS COATING OR CORE FLUX others ' THEM , , HAZAROOUS MIXTURES OP OTHER LIOUIOS, SOLIDS. OR CASES Di-sec-butyl peroxydlcarbonate % TLV (Unit.) TLV % IlMol 100 N/A oo SECTION III PHYSICAL DATA ingBOiUNa point t'F.yec0mp0ses on heat VAPOR PRESSURE (mm Hf.) N/A VAPOR DENSITY (AIR.1I N/A SPECIFIC GRAVITY PERCENT, VOLATILE BY VOLUME (%> EVAPORATION RATE I .11 solubility in water negligible appearance and odor Clear liquid , unpleasant odor 1.067 nil SECTION IV FIRE AND EXPLOSION HAZARD DATA flash foinT (Mctnee ueei 1180F tSETA flash) FLAMMABLE LIMITS EXTINOUISMINQ MEDIA Mater - difficult to extinguish special fife fiohtino procedures Don't fioht a oeroxydicarbonate fire.__It will bum out ouicklv. Limit fine bv water spray from a safe t UNUSUAL Fine AND EXPLOSION HAZARDS , .. . . __________________ Thermal decomposition releases oases which.* flamnabl* liquids and vapors into air where they mix with oxvoen^'nd burn very vigorously. PAGE (1) (Continued on reverse side) Form OSHA-20 Rtv. May 71 `A- ' -- A.` SL 074555 SECTION V HEALTH HAZARD DATA THRESHOLD Limit VALUE Not established by OSHA EFFECTS or overexposure , "I ;\ LP^n >.o g7kg, non-toxic (PPG). Moderately irritating to the eye. Extremely irricating to skin. EMERGENCY AND FIRST AIO PROCEDURES Skin Contact: Flush with water, clean with soap and water and then with alcohol. Eve Contact: Flush with water for at least 15 minutes, call a physician. Swallowing: Do not induce vomiting, consult a physician SECTION VI * PSACTIVITY DATA STASIUTV UNSTABLE stable INCOMRATABILITV IMcltntlt to trotd) Avoid contamination X with 1 CONDITIONS TO AVOID .. ! Thermally unscable-refnserate at 1 1 accelerators, amines, acids, alkaline -18C (0F) materials HAZAROOUS OCCOMPOSI tion products Some decomijosition Droducts HAZARDOUS POLVMERIZATION MAY OCCUR WILL NOT OCCUR flammable conditions to avoio Contact with polymerizable X materials (monomers) SECTION VII SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASES OR.SPILLEO . ... Provide ventilation. Aosorb on vermiculite or sand--carefully sweep into open metal container for disposal. Wash area with soap and water. WASTE DISPOSAL METHOD Small quantities: Carefully scatter material on ground in a well ventilated disposal area and allow to decompose gradually. SECTION VIII SPECIAL PROTECTION INFORMATION RESPIRATORY PROTEC+ION /Specify type) VENTILATION Local Exhaust SPECIAL mechanical (Central) other Provide adeauate ventilation PROTECTIVE OLOVES CVC PROTECTION Rubber . PVC Splash aozgles other protective eouirment Rubber shoes, plastic aprons, eve wash fountain SECTION IX - SPECIAL PRECAUTIONS RECAUTIONS TO BE TAKEN IN HANDLING AND STORING StOtfi at.Or PelQW "L80C ^O preserve assay, wear protective gloves when handling. Keep container covered with original closure. Protect iron sunlight and pther sources of heat, Auxiliary refrigeration gan be provided by placinz dry ice above the peroxydicaroonate. OTHER PRECAUTIONS Check storage temperature at lease once a shift. See manufacturer's literature. PAGE 12) SFJ IS.IN Industrial Bio-Test Laboratories, Inc., August 24, 1976, No. AS768 Form OSHA-20 May 72 SL 074556