Document Lwd3bzm2nMOzL1wXNamGyMZd

Shell MATERIAL 97367 (4-85) 24 HOUR EMERGENCY ASSISTANCE SAFETY DATA SHEET MSDS NUMBER 80,170-1 L : GENERAL MSDS ASSISTANCE PAGE 1 SHELL 713-473-9461 CHEMTREC: 800-424-9300 SHELL 713-241-4819 ACUTE HEALTH FIRE * 3 A' , REACTIVITY 5 L LEAST - 0 HAZARD RATING P HIGH - 3 SLIGHT - 1 EXTREME - 4 *For acute and chronic health effects refer to the discussion in Section MODERATE - 2 BE SAFE READ OUR PRODUCT SAFETY INFORMATION . . .AND rrpass on <**oouct imbrjty law AXOUIftf S IT] SECTION I PAINTED SCRAP METAL PRODUCT ^ NAME CHEMICALw MIXTURE (SEE SECTION II A) NAME CHEMICAL k FAMILY T SHELL CODE L MMMMM " SECTION II-A NO. PRODUCT/INGREDIENT COMPOSITION CAS NUMBER PERCENT P PAINTED SCRAP METAL MIXTURE 100 1 METAL ALLOYS 2 RESIDUAL PAINT/COATING WHICH MAY CONTAIN: 2A IRON OXIDE 2B TITAMIUM 01OXIDE 2C CALCIUM CARBONATE 2D SILICON DIOXIDE 2E LEAD 2F CHROMIUM 2G ASBESTOS FIBERS MIXTURE MIXTURE 1309-37-1 134S3-G7-7 1317-65-3 7631-86-9 7439-92-1 7440-47-3 1332-21-4 98->99 <1-2 THIS MSDS ADDRESSES COMPONENT 2 ONLY. THE EXACT COMPOSITION OF COMPONENT 2 IS UNKNOWN. THE LISTED COMPONENTS ARE OR HAVE BEEN USED IN INDUSTRIAL PAINTS AND COATINGS AND MAY BE PRESENT IN THE RESIDUAL FILM. COMPONENT 2 PROBABLY CONTAINS OTHER UNIDENTIFIED ORGANIC AND INORGANIC COMPOUNDS. THE IDENTITY OF COMPONENT 1 AND THE APPROPRIATE HEALTH AND SAFETY INFORMATION ARE UNKNOWN SINCE THE ITEM IS AN ARTICLE AND THE INFORMATION WAS NOT SUPPLIED BY THE MANUFACTURER. SECTION II-B NO. ACUTE ORAL LD50 P NOT AVAILABLE ACUTE TOXICITY DATA ACUTE DERMAL L050 ACUTE INHALATION LC50 SECTION III HEALTH INFORMATION THE HEALTH EFFECTS NOTED BELOW ARE CONSISTENT WITH REQUIREMENTS UNDER THE OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200). EYE CONTACT VAPORS. FUMES OR DUST FROM COMPONENT 2 MAY BE IRRITATING TO THE EYES. LAM 026439 ABS-044392 PRODUCT NAME: PAINTED SCRAP METAL MSDS 80,170-1 l. PAGE 2 SKIN CONTACT VAPORS, FUMES OR DUST FROM COMPONENT 2 MAY BE IRRITATING TO THE SKIN. INHALATION VAPORS, FUMES OR DUST FROM COMPONENT 2 MAY BE IRRITATING TO THE UPPER RESPIRATORY TRACT. INHALATION OF DUST CONTAINING SILICON DIOXIDE MAY CAUSE SILICOSIS. INHALATION OF DUST CONTAINING ASBESTOS FIBER MAY CAUSE ASBESTOSIS AND ASBESTOS AIRWAY DISEASE. (SEE OTHER HEALTH EFFECTS) INGESTION DUE TO THE PHYSICAL STATE OF THIS MATERIAL. INGESTION IS NOT A PROBABLE ROUTE OF EXPOSURE. SIGNS AND SYMPTOMS IRRITATION AS NOTED ABOVE. LUNG DAMAGE (SCARRING, BRONCHITIS. EMPHYSEMA) MAY BE EVIDENCED BY SHORTNESS OF BREATH, ESPECIALLY ON EXERTION, AND MAY BE ACCOMPANIED BY CHRONIC COUGH. AGGRAVATED MEDICAL CONDITIONS PREEXISTING EYE, SKIN, AND RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS MATERIAL. IMPAIRED RESPIRATORYFUNCTION(S) FROM PREEXISTING DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS MATERIAL. OTHER HEALTH EFFECTS IN REFERENCE TO COMPONENT 2D, THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER HAS DETERMINED THERE IS SUFFICIENT EVIDENCE FOR THE CARCINOGENICITY OF CRYSTALLINE SILICON DIOXIDE IN EXPERIMENTAL ANIMALS AND LIMITED EVIDENCE FOR THE CARCINOGENICITY OF CRYSTALLINE SILICON DIOXIDE IN HUMANS. IN REFERENCE TO COMPONENT 2E, EXPOSURE TO VAPORS,' FUMES, OR DUST MAY RESULT IN ABSORPTION OF LEAD INTO THE BLOODSTREAM, WHICH POTENTIALLY COULD RESULT IN LEAD TOXICITY OR ADVERSE REPRODUCTIVE EFFECTS. SUFFICIENT LEAD ABSORPTION IS KNOWN TO CAUSE DAMAGE TO BONE MARROW (ANEMIA), NERVOUS SYSTEM (BRAIN AND PERIPHERAL NERVE), KIDNEY AND TOXICITY OF BOWEL (COLIC). IN REFERENCE TO COMPONENT 2F, THE NATIONAL TOXICOLOGY PROGRAM AND THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER HAVE DETERMINED THERE IS SUFFICIENT EVIDENCE FOR THE CARCINOGENICITY OF CHROMIUM AND CERTAIN CHROMIUM COMPOUNDS BOTH IN HUMANS AND EXPERIMENTAL ANIMALS. IN REFERENCE TO COMPONENT 2G. THE OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION. THE NATIONAL TOXICOLOGY PROGRAM AND THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER HAVE DETERMINED THERE IS SUFFICIENT EVIDENCE FOR THE CARCINOGENICITY OF ASBESTOS IN BOTH HUMANS AND EXPERIMENTAL ANIMALS. THEREFORE, THE HANDLING PROCEDURES AND SAFETY PRECAUTIONS IN THIS MSDS SHOULD BE FOLLOWED TO MINIMIZE EMPLOYEE'S EXPOSURE. SEE SECTION VI FOR ADDITIONAL HEALTH INFORMATION. SECTION IV OCCUPATIONAL EXPOSURE LIMITS NO. PEL/TWA OSHA PEL/CEILING TLV/TWA ACGIH TLV/STEL OTHER 2A 10 MG/M3* 2B lO MG/M3TD 5 MG/M3RF 2C 15 MG/M3TD- 5 MG/M3RF 2D 0.05 MG/M3 2E 0.050 MG/M3 2F 2G 0.2 F/CC 0.1 PPM *5 if/cc m 5 MG/M3*2,,82 lO MG/M3TD 10 MG/M3TD 0.05 MG/M3 0.15 MG/M3 0.05 MG/M3 2F/CC, A1 3 4 6 DUST AND FUME. AS FE. *2-FUME, AS FE 3-CRYSTALLINE SILICA, CRISTOBALITE-RESPIRABLE DUST. 4-INORGANIC FUMES & DUSTS, AS LEAD. *5-CHR0MIC ACID & CHROMATES(AS CR03). *6-CHR0MIUM(VI), WATER SOLUBLE AND CERTAIN INSOLUBLE CMPDS. (A1) AS CR. *7-30 MIN EXCURSION LIMIT. SECTION V EMERGENCY AND FIRST AID PROCEDURES EYE CONTACT IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION. SKIN CONTACT IMMEDIATELY REMOVE CONTAMINATED CLOTHING OR SHOES, WIPE EXCESS FROM SKIN AND FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. USE SOAP IF AVAILABLE OR FOLLOW BY WASHING WITH SOAP AND WATER. DO NOT REUSE CLOTHING UNTIL THOROUGHLY CLEANED. GET MEDICAL ATTENTION. LAM 026440 ABS-044393 PRODUCT NAME: PAINTED SCRAP METAL MSDS 80,170-1 L PAGE 3 INHALATION REMOVE VICTIM TO FRESH AIR AND PROVIDE OXYGEN IF BREATHING IS DIFFICULT. RESPIRATION IF NOT BREATHING. GET MEDICAL ATTENTION. GIVE ARTIFICIAL INGESTION DO NOT INDUCE VOMITING. IN GENERAL, NO TREATMENT IS NECESSARY UNLESS LARGE QUANTITIES OF MATERIAL ARE INGESTED. HOWEVER, GET MEDICAL ADVICE. SECTION VI SUPPLEMENTAL HEALTH INFORMATION IN REFERENCE TO COMPONENT 2F, SEVERAL EPIDEMIOLOGIC STUDIES OF CHROMATE PRODUCTION WORKERS HAVE DEMONSTRATED AN ASSOCIATION OF EXPOSURE TO CHROMIUM COMPOUNDS WITH RESPIRATORY CANCER. WHETHER THE ASSOCIATION IMPLICATES HEXAVALENT CHROMIUM (CRVI) ALONE, OR TRIVALENT (CRIII) AS WELL, IS NOT DEFINITIVELY ADDRESSED BY THESE STUDIES. SEVERAL HEXAVALENT CHROMIUM COMPOUNDS HAVE BEEN SHOWN TO BE CARCINOGENIC IN EARLIER BIOASSAY STUDIES. ONLY CALCIUM CHROMATE HAS CONSISTENTLY PRODUCED LUNG TUMORS IN RATS, BY SEVERAL ROUTES OF ADMINISTRATION. OTHER CHROMIUM COMPOUNDS -- STRONTIUM CHROMATE, ZINC CHROMATE, SODIUM DICHROMATE, LEAD CHROMATE, LEAD CHROMATE OXIDE, AND SINTERED CHROMIUM TRIOXIDE -- HAVE PRODUCED LOCAL SARCOMAS OR LUNG TUMORS IN RATS AT THE SITE OF INTRABRONCHIAL, INTRATRACHEAL. INTERMUSCULAR, SUBCUTANEOUS AND INTRAPERITONEAL APPLICATION. HEXAVALENT CHROMIUM COMPOUNDS HAVE NOT INDUCED LUNG TUMORS BY INHALATION. TRIVALENT CHROMIUM COMPOUNDS HAVE NOT BEEN REPORTED TO BE CARCINOGENIC BY ANY ROUTE OF ADMINISTRATION. IN REFERENCE TO COMPONENT 2G, THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER HAS CONCLUDED THE FOLLOWING: "CIGARETTE SMOKING AND OCCUPATIONAL EXPOSURE TO ASBESTOS FIBRES INCREASES LUNG CANCER INCIDENCE INDEPENDENTLY; WHEN THEY OCCUR TOGETHER, THEY ACT MULTIPLICATIVELY." THE HANDLING PROCEDURES AND SAFETY PRECAUTIONS IN THIS MSDS SHOULO BE FOLLOWED TO MINIMIZE EMPLOYEE EXPOSURE. SECTION VII PHYSICAL DATA BOILING POINT: N/A (DEG F) SPECIFIC GRAVITY: N/A (H20*1 ) MELTING^POINT: N/A (DEG F) SOLUBILITY: (IN WATER) INSOLUBLE EVAPORATION RATE (N-BUTYL ACETATE - 1): N/A APPEARANCE AND ODOR: SOLID VAPOR PRESSURE: N/A (MM HG) VAPOR DENSITY: N/A (AIR-1) N/A-AVAILABLE SECTION VIII FIRE AND EXPLOSION HAZARDS FLASH POINT AND METHOD: >200 DEG. F FLAMMABLE LIMITS /% VOLUME IN AIR LOWER: N/A UPPER: N/A EXTINGUISHING MEDIA USE WATER FOG, FOAM, DRY CHEMICAL OR C02. LAM 026441 SPECIAL FIRE FIGHTING PROCEDURES AND PRECAUTIONS MATERIAL WILL NOT BURN UNLESS PREHEATED. DO NOT ENTER CONFINED FIRE SPACE WITHOUT FULL BUNKER GEAR (HELMET WITH FACE SHIELD. BUNKER COATS. GLOVES AND RUBBER BOOTS). INCLUDING A POSITIVE PRESSURE NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS WITH WATER. ABS-044394 PRODUCT NAME: PAINTED SCRAP METAL MSDS 80,170-1 L PAGE 4 SECTION IX REACTIVITY STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR CONDITIONS AND MATERIALS TO AVOID: NONE KNOWN HAZARDOUS DECOMPOSITION PRODUCTS CARBON MONOXIDE AND UNIDENTIFIED ORGANIC AND INORGANIC COMPOUNDS MAY BE FORMED DURING COMBUSTION. SECTION X EMPLOYEE PROTECTION RESPIRATORY PROTECTION AVOID BREATHING DUST, VAPOR AND FUMES. IF EXPOSURE MAY OR DOES EXCEED OCCUPATIONAL EXPOSURE LIMITS (SEC. IV) USE A NIOSH-APPROVED RESPIRATOR TO PREVENT OVEREXPOSURE. IN ACCORD WITH 29 CFR 1910.134 USE EITHER A FULL-FACE, ATMOSPHERE-SUPPLYING RESPIRATOR OR AIR-PURIFYING HIGH EFFICIENCY RESPIRATOR FOR PARTICULATES. OSHA HAS ESTABLISHED TRANSITIONAL OCCUPATIONAL EXPOSURE LIMITS FOR THIS PRODUCT AND/OR COMPONENTS OF THIS PRODUCT. REFER TO 29 CFR 1910.1000 FOR THESE TRANSITIONAL LIMITS AND REQUIREMENTS FOR MEETING THESE LIMITS. PROTECTIVE CLOTHING AVOID CONTACT OF DUST, VAPORS AND CONTACT WITH EYES. AVOID CONTACT PROTECTIVE CLOTHING. FUMES WITH EYES. WEAR CHEMICAL GOGGLES IF THERE OF DUST. VAPOR AND FUMES WITH SKIN AND CLOTHING. IS LIKELIHOOD OF WEAR GLOVES AND ADDITIONAL PROTECTIVE MEASURES USE EXPLOSION-PROOF VENTILATION AS REQUIRED TO CONTROL PARTICULATE CONCENTRATIONS. SECTION XI ENVIRONMENTAL PROTECTION SPILL OR LEAK PROCEDURES MAY BURN. ALTHOUGH NOT READILY ** SHOVEL AND SWEEP UP OR USE INTO CONTAINERS FOR RECLAIMING IGNITABLE. USE CAUTIOUS JUDGEMENT WHEN CLEANING UP LARGE INDUSTRIAL VACUUM CLEANER. AVOID GENERATING DUST CLOUDS. OR DISPOSAL. SPILLS. ** PUT SECTION XII SPECIAL PRECAUTIONS AVOID EXPOSURE TO FUMES. DUSTS AND VAPORS WHICH MAY BE GENERATED IF THIS MATERIAL IS CUT, WELDED, GRINDED. SANDED. ETC. FOLLOW NECESSARY PRECAUTIONS AS DESCRIBED IN THIS MSDS. SECTION XIII TRANSPORTATION REQUIREMENTS DEPARTMENT OF TRANSPORTATION CLASSIFICATION: NOT HAZARDOUS BY D.O.T. REGULATIONS LAM 026442 SECTION XIV OTHER REGULATORY CONTROLS THE COMPONENTS OF THIS PRODUCT ARE LISTED ON THE EPA/TSCA INVENTORY OF CHEMICAL SUBSTANCES. IN ACCORDANCE WITH SARA TITLE III, SECTION 313, THE EDS SHOULD ALWAYS BE COPIED AND SENT WITH THE MSDS. ABS-044395 PRODUCT NAME: PAINTED SCRAP METAL MSDS 80,170-1 L PAGE 5 SECTION XV SPECIAL NOTES SEE ENVIRONMENTAL SAFETY DATA SHEET FOR WASTE DISPOSAL AND OTHER ENVIRONMENTAL INFORMATION. THE OCCUPATIONAL EXPOSURE LIMITS (SECTION IV) AND/OR THE RESPIRATORY PROTECTION PRECAUTIONS (SECTION X) HAVE BEEN REVISED. THE INFORMATION CONTAINED HEREIN IS BASED ON THE DATA AVAILABLE TO US AND IS BELIEVED TO BE CORRECT. HOWEVER, SHELL MAKES NO WARRANTY, EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. SHELL ASSUMES NO RESPONSIBILITY FOR INJURY FROM THE USE OF THE PRODUCT DESCRIBED HEREIN. DATE PREPARED:AUGUST 09, 1989 BE SAFE READ OUR PRODUCT SAFETY INFORMATION ...AND PASS IT ON (PRODUCT LIABILITY LAW REQUIRES IT) J. C. WILLETT SHELL OIL COMPANY PRODUCT SAFETY AND COMPLIANCE P. 0. BOX 4320 HOUSTON, TX 77210 LAM 026443 ABS-044396 Shell ENVIRONMENTAL DATA SHEET 97449 (9-87) EDS NUMBER 80. 170 L PAGE 1 PRODUCT ^ PAINTED SCRAP METAL PRODUCT k CODE P MMMM SECTION I NO. PRODUCT/COMPOSITION COMPONENT CAS NUMBER PERCENT P PAINTED SCRAP METAL MIXTURE 100 1 METAL ALLOYS 2 RESIDUAL PAINT/COATING WHICH MAY CONTAIN: 2A IRON OXIDE 2B TITAMIUM DIOXIDE 2C CALCIUM CARBONATE 2D SILICON DIOXIDE 2E LEAD 2F CHROMIUM 2G ASBESTOS FIBERS MIXTURE MIXTURE 1309-37-1 13463-67-7 1317-65-3 7631-86-9 7439-92-1 7440-47-3 1332-21-4 98->99 <1-2 THIS MSDS ADDRESSES COMPONENT 2 ONLY. THE EXACT COMPOSITION OF COMPONENT 2 IS UNKNOWN. THE LISTED COMPONENTS ARE OR HAVE BEEN USED IN INDUSTRIAL PAINTSAND COATINGS AND MAY BE PRESENT IN THE RESIDUAL FILM. COMPONENT 2 PROBABLY CONTAINS OTHER UNIDENTIFIED ORGANIC AND INORGANIC COMPOUNDS. THE IDENTITY OF COMPONENT 1 AND THE APPROPRIATE HEALTH AND SAFETY INFORMATION ARE UNKNOWN SINCE THE ITEM IS AN ARTICLE AND THE INFORMATION WAS NOT SUPPLIED BY THE MANUFACTURER. SECTION II NO. EHS RQ (LBS) (*1) SARA TITLE III INFORMATION EHS TPQ (LBS) (*2 ) SEC 313 (*3 ) 313 CATEGORY (*4) 311/312 CATEGORIES (*5 ) BASED UPON THE VARIABILITY OF THE COMPOSITION AND END USE OF THIS MATERIAL, SARA TITLE III INFORMATION MUST BE DETERMINED ON A CASE BY CASE BASIS. ................ .............. .............. ................................................ -............FOOTNOTES......................................... ...................... .......................... -................... *1 = REPORTABLE OUANTITY OF EXTREMELY HAZARDOUS SUBSTANCE, SEC.302 2 THRESHOLD PLANNING QUANTITY, EXTREMELY HAZARDOUS SUBSTANCE, SEC 302 *3 * TOXIC CHEMICAL, SEC 313 *4 = CATEGORY AS REQUIRED BY SEC 313 (40 CFR 372.65 C), MUST BE USED ON TOXIC RELEASE INVENTORY FORM *5 - HAZARD CATEGORY FOR SARA SEC. 311/312 REPORTING HEALTH H-1 - IMMEDIATE (ACUTE) HEALTH HAZARD H-2 DELAYED (CHRONIC) HEALTH HAZARD PHYSICAL P-3 FIRE HAZARD P-4 * SUDDEN RELEASE OF PRESSURE HAZARD P-5 - REACTIVE HAZARD SECTION III ENVIRONMENTAL RELEASE INFORMATION LAM 026444 ABS-044397 PRODUCT NAME: PAINTED SCRAP METAL EDS 80,170 PAGE 2 L, SECTION IV RCRA INFORMATION IF THIS MATERIAL BECOMES A WASTE. IT WOULD NOT BE A HAZARDOUS WASTE BY RCRA CRITERIA (40 CFR 261). PLACE IN AN APPROPRIATE DISPOSAL FACILITY IN COMPLIANCE WITH LOCAL REGULATIONS. THE INFORMATION CONTAINED HEREIN IS BASED ON THE DATA AVAILABLE TO US AND IS BELIEVED TO BE CORRECT. HOWEVER, SHELL MAKES NO WARRANTY, EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. SHELL ASSUMES NO RESPONSIBILITY FOR INJURY FROM THE USE OF THE PRODUCT DESCRIBED HEREIN. DATE PREPARED:MARCH 13, 1989 ........... -.............. .............. SHELL OIL COMPANY ENVIRONMENTAL AFFAIRS P. 0. BOX 4320 HOUSTON, TX 77210 FOR ADDITIONAL INFORMATION ON THIS ENVIRONMENTAL DATA PLEASE CALL (713) 241-2252 FOR EMERGENCY ASSISTANCE PLEASE CALL SHELL: (713) 473-9461 CHEMTREC: (800) 424-9300 LAM 02S44S ABS-044398 5QS W lam 26438 ABS 044391.1