Document LpdQBvYQO3arJ60ZOBxJOw265
FILE NAME: Westinghouse (WH)
DATE: 1943 Jan
DOC#: WH508
DOCUMENT DESCRIPTION: Journal Article - Safety in Handling Aluminum Powders
*
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II
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. fatidiifiuute.
s. d. fcBtfuKicfc........... ra#
JAMES Jt. EES................ Mnno^iu? Ctfiior
TO20QO8S *. 0UYBoo,.JIorfate Sdlter irony k baxhs..... ...WarkaiMifor JOHNB* cmULKAK .... 4cfctttMEdifo*
NORMfitf G. FAHQDHAA .Asstoiutl &btar
IfefiTEA b. POMS............ Jufrteal falter
JNURYx 1343
Nliukir,
Our Tear II of World War II.................................................... 75
EPMOMM rOBEWCU
EDI7HU1 &B*SENTAnVE9
& SXTlTESEB., t *r < t . W ebt
* . 6 . M eB B ID C ...
,, ,W * iil* g to 0
EASTS M b tiU H lt..................... .Altaota
Waste Disposal Problems In Wartime.....................................
Sy f . W . M OKLKKN
Safety ln Handling Aluminum Powders................... . I r G . K , BftBOOCK 4 r. i . KEtH W lCCH
78 ' 82
Progress Report l the Rubber Director................................... 88
M. A. ' WnXWMSON , . fribifetinr
d is t r ic t m a n a g e s *
'
E. W. JBEDElt ............ ................New YerX
Selection ol Pomps for Oleum and Strong Sulphuric A cid.. .. 86
Br WXilD E. PSKT
'
B . G fX E D C U C C ................. J fP ir Tarfe FRED G R A N T ......................... C Jrw tom l . U A* COM JNGHAM ................. Cbictrpn
Effect of the Kinetic Energy Term In Gas Flow Calculations.. SO
Hr- BEHJRMH MULBB
`
W . P rB O Y D , , Tr. ............ . . t , . .to te n
J. &. VAN BSDAEE.. . , PAfladefchia
Nylon Research Wins Its War Wings...................................... 4
E s tro s m . s u i t ti& O fti
I
I
Manufacture of Butadiene From Ethyl Alcohol--H -............... 94
Pufelisbetl wwtfbly* Pik 53 nnts p*r npr
ir J. A. sums at t. moves
'
Adilrui canHAmlnHo
*tA>M?}p*
tlem La D ire ct ad Cbcuhxtliiifa O m n . i
M ftU 3SD VfmH 4 t S lH
Y<nk* V . Y.
Labor Relations and Collective Bargaining in Chemical
B o b fln ip ita c ratest RTpillod Stete*, M*t6C*, C*n\l (Md SoufH. AnuLatutn eMuittiei $3
Industry ......... ...................................................>.................. 99
a esc. * Mcr. jo o o b t
'
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o yitt, $i (bt tb y*tm, D Ua thrn
I -yatut. ConoAtf, 53,50 o yatfr. & I lWfl
y N a r 9< fo r I b w rM m Ipajrabte lt Ca* trte* le n tis), G rM l B itto l ad f rtlW
Chrome Tanning Leather.............
I P o H M itn w , Sft ihlU tepa tt yen r, SC ib S U iy i
a c h e m . * p m . m c ru a s o rooW EH CET
lor ym All tftei WwHH. 45 a
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yocov 19 iB r lk iM y n n . E aieted laufend Int Milet 9Ptenb*r 4, )btl at Ptni
Chen. & W*t VJral Notebook . . 81 PAtBCttBAtteo. . ............................>137
1I
O M W UL A fe a oy, N . ff. 5. A W w kr ri
PracKnt Equljmwml Horn . . . IB7 Mc4ittg tm d C o o fe a lta u 14A
I N w H 9/ J4?4 C fe ltM ls o n iif t o lr
|M3,*r Kaflxnr-aUl PnbOahlof Cwxpttey. '
Cbtinlad EqglMBriag Nows LI8 Wewe Fla Airwd . . * 158
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ins 5 t M b Oll]**l Q 9 X M lh I C d lV n A v ra w . Chicago; N > l 3 lm lt Ban Eren*
Nvwr Frcim Wasbingutn . , 121 C boia 6 Ml.
- . . . 167
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duDi JUiwrA Mosa, ASdwrthj ) m4ba
bsrjnatiBg WoritbjllfHl > IN C b^u^cal Ecouomlctt an d Moricete 17S
w . a I y t u M avkfet t t W u t e lt o trr* .
Nw Pfodual* and Idotoitfil * 12S C u n r o t Frttfe* , * . . s . 187
lm d | ftM ta lii S|i la iA ir I w t it f )9 JUw
qlSl JUtata
From tho Log I Expulotttti t * 199 Bi\r 'Cob&tnwBon
196
A Index to adTt(l*r wUl 1 found om
2
McGRAW*mtt mVSHTNG O,, INC* '
JAM ES 7L McORAW / F oundv and Souo to ff CfaAlMU)
t^ ibU0aUi-O Sko
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t i l t f M otA D xm dw nr, A U em r. St. Y*
f^ nrlat and
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599 W *vl B trn l nvr Yocfc, R . Y .
MME5 Ht MtGfcJW, Jr ...........,PMundmt
KO W A & D ER !U .T C B.& irii!iTV to.Frt*l*aB i
M ACON SR lT iO W .... .w ...V lw F# w t6 * * t
6 A. P V lS A K t.. .................... Y f a u iro i
j. A . GE8ANDI.OO ... ............ foM AU t/j
I H. bUhCCKTSN, T Dfeeutor ot ChtculaHon '
MasnbBI JU6.P. MmbC AJLG>
CuVfo address M tGttAW iD M s, JTow York
i
M oGHAW -HILL PUBU8H1NG CO M PAHT
830 Weal 4W 6tb New Yorft , Y.
plkSQta) M rawnl*6 ftBf
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P le a t e b a stf* fe y o d dffrfe 8 CtuBHCfll d
Engfoeeitno
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F f e . . . . . . ............... ..V . , , > . . . . . . 0 . 0 W ................
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S 0 i e S f i i M a iid Im fT M S M m s s m P o w d e r s
Gr. M. BABCOCK a n d F. B. R EtH W ISC H Reynoidi Metals Co,, UulsrJJIe. Ey.
................... --- Chem. & Met. tH T E B m rT A T T O M " - ;....
"
Except iw -those people who work constapfly with alnnvmum powders, sufficient respect for the explosibillfy .of tiiis material does pot appear to .exist. With tire present widespread, -use cl aluminum powders for the manufacture of military pyrotechnics, need has developed for (he mors widespread dissemination of information an sa le practices in their handling and in manufacturing pyrotechnics. The article which follows ts based on the experience gained by the Reynolds Meted* Co. in many years of producing and handling mdaille powders and is offered as a starting point in the develop ment of safety programs for concerns engaged in Dr beginning opera tions fa pyrotechnic w ort. Certain fundamental precautions are dis cussed by the authors a s a sendee, to the Industry, hut neither they nor their company assume liability of any kind in presenting this information.--Ediiws.
F IukKlv ATjUMIHTM POW ER, BOHH'- should he stored unopened in n sep wirat similar to the ra&tertsl arate urea whsiever possible, stow etinunonly used in ulummum paintif they are stored along with such
tinder the mthei' misleading name of
felnminun brnnue powde^ 1 is a
valuable component of pyroteohnto
cheuunla ` qs sulphur, nitrate* and others of similar character, a Are
from any eause would present a most
mixtures used for flares Mid signalsTlitr- high surface $* of a given
serious problem, Whatever s drum of alunununt powder is opened for
weight of aluminum flake powder lauding or inspeetion, it should ha
makes it easily tgnitible When in the presence of oxygen or air.- Burning,
it evolves v tremendous luiumnt of beat and light. Owing .to Us low uppnrenl drasily, .fine particles of
(nosed und re-snnlefl us suon as pos sible. This not only insures greater safety against Are from extern!
causes hut el limits the likelihood ot tramp material getting into the
the material tend to float in air with . powder, ot of the powder absorbing Urn Attendant danger of violent ex water from the air. In one in*tones plosion nponIgnition, when a proper a sealed drum of fluke alumismui
ratio of nhramiun to oxygen is -withstood an alunununt dust explo
reached,
sion and eubaeipient fire without
' A. somewhat different nlummum ignition of the drum contents,
powder, the grained variety, consists Thuro ant tew practical -means of
o f spheres, iaosege nhapw nr irre exttaguiabtog firm involving alumi
gular grains of nJomimim. vtnoh are num powder or mixtures containing
relatively hard to ignite. When ruined ' this powder. Anything which tends
with exygoB.prailnisng compounds, too grained powder -ill lnc.11 vltli the evolution of maoh heat sad light.
to disturb die burning mass may threw the aluminum into the aiv usd
result in a violent explosion of we--
This material, however, has a high mondbns destructive power. It is
apparent density end low sarfuoe tone tout dry sand, carefully placed
area which wads to keep it from over a pDe of burning aluuusrmn,
Hutpenilna in air so that die danger will smother toe flume, but in toe
of explosion or tiro from ahuntotra excitement attending such a fire,
fog" is almost niL
there is danger that too sand will
Both flake and grained aluinfotmi he thrown cur shoveled on to toe
are shipped in led drums with mass, and that toe powder will be
felly removable heads, Those, drums thrown into the air. There have been
several cases where relatively harm
less fives have been hanged to seri
ous and fatal explosions from this
cause.
-
Consequently, the enter And more
prudent rule in to instruct employees
to walk out of the building in the
case of on aluminum tire, shutting
toe dour securely but us gently as
possible to avoid disturbing the
burning mass. AD employee should he instructed
in procedures to avoid. They should
understand thoroughly tout water,
carbon tetrachloride, fin foam, ear-
bon dioxide and oimllzir extinguish- '
tog agents should not he used on nhuutovsn fires. Hue of eneh materi
als wilt causa explosions. Bight
watchmen should he tostruetod to
convey title information to any regu
lar or volunteer group which at
tempts to extinguish an aluminum
fire, purfhemovft toe we of a fine
pray n water from a stirrup pomp,
cuoh as is used hy civilian defense
workers on mntmlioty bombs, should
news- he wed on otomtonm (ns'der
fires.
It is of utmost importance Hint
local fire department- be in I'ui Hid
of these precautions, 'The depart
ment should he provided with com
plete information and ehurts regard
ing those warehouses which contaiu
aluminum, us well es these contain
ing ofiler chemicola. These rimrts
should also be readily available to
the watchmen and to the pluut'c own
protection (Uvirion at all tones.
AVOm&ta HAZARDS
'
A enure of groat danger to toe bundling of ahnniuniu powder la die presence ui foreign subitancea, piirtiunlurly bard or metallic materials Cure should bo token to see flint doting bolts, mute and similar bits of motel cannot eoriurawaic slumijinm powder or pyrotechnic mlslnrss,
Jtioad plant I10115eheepin.tr ie nue of too most effective methods in aehieviug plant safety and eare must lie taken particularly to toe weigh ing, miring and pressing rooms. As little material ns ts practical should be kept to one place at one time. Stoops for handling powders should
he of non-sparking material arid toe
handling should be slow end dcll-
at
. JM f A E T IM S CHEMICAL k METALLtUtGICAL EHsmUCjUllG
berate, to reduce duoting to a mini mum. Rooms in which powder is bandied should be oleehctl at irequant intervals, but never during
lighioj eiecirju lighliiig tutti pimer equijmienl corrying Uhoruriteie' jjproval for use iu explosive erras and wliere explnmve. vpora (ire n-
PoriienUrly io die ease of fiah<.
rnuuini powder, coniidarable time is required ro dissipate this' oherge.
Several types of ram-eparking,
wedgUngi mixing or pressing opera euutuered >bould lu) ued.
conductive doors hare been employed
tions. AD materiel should be kept in i-lnscd -eenlainera white denning
Wlu-jstrer pnsshdr, buili (be shoes of worlters nd the floore ebonld bo
mwessfully.' three types may be dascribed briefly lore, including (1)
is in progress. I f oil is used m the et coud neuve but imn-spaking Magnetite flooring installed over e
pyrotechnic mixture, spwual ease tyi'e. IflJeririeal dia&hargr* predneed wood or ctwerrie busn, with eondtie-
must be taken to insure that all Oily rags or waste are dcpoMM 1 .oloaed safety cans say from Uie
liy niatte or ligbtoing are Hic ntoti dilDettU rnitey hutirds to ctmtrL The dangre Erom ststie barges pto-
liie metal grids planed beneath tlu surface at thn floor and properly groindeA; (2) emtilsifirO asphalt
I storage or loading areas. These rags duced by frie lion 1* gm itetl a i coU, etiinpo$it]on flooring mlh a comhie-
' it imngu,stcboeredimspuosstebdeotfodkaeinlyp, uriininndleanrnly edrreylewoerelobmeirt.poaiivl otonn wIkomlkruinigg oinn ntunn). gHrwounagdgedregrantceiuwl hgircihdsa,Uxuibd laCnll)oviner-
to keep nil nuns, window ledges ciiiiductug aboie, uuiy prndnre dntii-ial graphite tile mud of a
beams, building steel and. other rest sparks capable of iguling pyvoft-rii- voHilnctlve mastir, the i-ilgce of the
ing planes free from dust.
' nie mixtures or fine lumimim par tile betug melted toeetlier w-ilh
i- TOUTING protection ttihfetlesfrsiucstipoenndecduumiuuI tinhjtr ainrt.iuoiIiOmvhmi hsortOD(rtabniuinnu. siunr.-ftaacllea.1i.iWn ittho Ipbrims fiudset
4
Tim buildings used for weighing, potnlvr potn-ttil frtmi * M-uop lit a nmutinned type no laetiil grid is
' miring and loading operations contamer an ensile bigb talio neoesMiry, Ihe tils lUolf bring
should) wherever possible, be so plinrgea on fhc nlitmiiuni) jnirtii-les. gnmndeil at TfuiunA poinls.
spaced and. proteoted that fires or
isxplotions iu one unit cannot be eom-
muniootsd to other units. Construc The viliWS, Irom nhotos by th. D. S. Army Sunti Cape, show a lh.rm.ll bomh
tion should be adapted to the Tent dnmonslratton ot I b Arnty Vfai Calice., Washington, C. C.; ihs topo r n toni
ing of implosions, using either a ih tonb h.gtnnlbo t d ritto , v tlk Ih. lowur nhown Un cltmctx vi Ohi skpisIdq
"soft" n'ai] or roof, or e blow-out wbu di botoli, bovine teadud e Itaipatohuc ot ebani *J)GD da, ts mnlllnv
panel. ATI equipment should bu
thteoob (ho slob at rie) n whtch II insto
Ineatod so that the operator has h
free patli to eu outside door, with
out a mixing boneh, prass or mixer
betweea him and the dour, -
All nietnl in the buildings should
be grounded. This not only Innludeh
the equipment ifadf, but also ididol
window and door frames and nOrnr
bnilding idemwits. Clips oonnwitfA to
flexible grounded lends should bo
placed on all metal drums nr oiber
raovable equipment, Only nrplnsion-
preof motors rhimld bo pernutlwl.
and for these the* controls should bp
fully inclosed and. non-iireiug, loonted
outside the lViu-kmuni no that no
wor-hor need lie in the mixing or
pressing room from the time of
starting these operation* until they
are completed.
All lights should lit of a ivpe
appro red for explosive oporab'tins
end conditions. Piirtlcnlar rare
Tnnt bo token when anhamolso nr
manual tools are to be used In build
ings for repairs or ehengas,' When
each, work is te be earned nut, the
rooms must first be emptied of all
ipniflbjc moterifil and fliorongbly
rimmed. Fatal explosions hew* .bran
enured in dnst-filled rooms by on
Ore fttnn the switch of an ordinary
fhi(blight. Therefore, only fln-dt
* Vsuihu btfarteatlen oit Ike* noms idra Monind nwa Artum nf 4*rk vp ( Amidi
h ilt YVatactoJEM r.* b a n r e g i a i , 3>t. ; tl* F JlH ilittle lha, l u e tiln t S b iu lih ilu D U1, 20 U orftatcU er-iH aso . Xehr T w k i K . ) u t l V- U m o itiiliU C o . 1X1 OIt M t ttmofcUrn,
X f.
fllRAUCJtJL L ilETALIXFlGlCAD ENGIKEERTSC JATU 'AST'
........ . - .* # ! & * * * ' ------
The tuttet of slulSo ebcuH he ex plained to employees, Banff liwple illustraUonB sudli as the rnblringof
silk in bo5)1 weather, ox the comhjng o f tom-. Bolt driws should not lie
utoil im uuSunci i n the mixing, p n s a n g or loading rooms. Spfcdal m e &cmLd be taken in tpc rooms,
iim the friction of 0) parlidas passim; orci- the screw* n o d , thtir temporei? unpenmon and separa tion in sir can build ap hit'll static
t`bai$c.-. All metal So priexsbig and storage warns slionlO be gromid. cd ami every ptetjhility o r a spark from loaehiiifry, from bnohan defc-
ti-k- litrill bulbs, or from the drop ping of steal lnk should be guard ed n"olnst I'roptirly fcHMttded
metal rmitniitcw on upark-proof eoudut'uvv flooring will permit more rapid di-Kix>etion of static charges time wooden eoutainers. Mix.1
should he Unwed to nnm in * t rest fo r a short; time W o re the mixture is iTOOwft, thus permitting any sta tic i>hurR inihitsed in- Bit metal pnr-
ld is in tbc mix lo l)o sondneted.to gnauli Suuple aleotrOJWipia'eiui bc
tnnd tu ilctermine vrhai a iW i'`
ia Irne ol stallo dinega.
_ _.
Adoinal %btinff PTM1* '1'011 " i n importuni requiremenl f o t th
piani hiuidling niu>numM piemie.
'Cht groiuulinjr of ali mvUl windffw
imi! doox frames ami approvo! Tight-
itimi prleetimi uf all wtrUiff will lurgaly dminnte Ilio poseihility of
high targes iQw.tmg before of
J iir in g a th u n d o rs ta rm n n .il p e rh n p s
dlsfluiJTing: te th ground with ou
iicemnpnnyng ha#k or spade Prottidiun BOinfit stillai lighluing
yt r o te 8 beai lei le nutlmrjUes on .fbu Mibjeet'1' W.uiy to iu m is hut
down oli mixing ami )oding opaxa-
`lioas durisff ncrore, nearhy lightajnff
stunuSi th npU>.WM lonvinff th
piweswiff roani* dnrinff limi pcriort. ({aditi aste are good indicatola of
lippruatlng elcctrieid ululine, bui
i f they are uscii, thoy (houli net 1
inainoci in Ihe tauffing urea owinj!
-lo th hanini llity ietrodnoe.
MHXBS AND PBEERES '
Mnobinory nactl in wirbt,' and
prembff oparittiijns should be etjuipped with unfboMd dust-proof bearings, which ->honlil I kapt well . liibrieuLed. Bswcaive lumpvralnre
rh.e m any pari shmild tnll for an immcdiaW shuKtown. It a shaft nr ftlhw {art ehoill'l ffeeD'. an n bear Ing snrfdoe, dd iUtiupl olnmld be made to Imism ihn pert by fume, such ue by a hRimaer blow on the
dinft, es kniff ni any iffulbble n` lerial is 1 flic room, lrpoand ring uis or bevel genro ahnuld I Troludnd from nluiulnuai-puvvilt't-eon-
fnininff mutonak. bhnral applicatiunB if n heavy ffniahv uiinimirioff this
/langer.
.
The rlotllinff worn hy plsnl b-
pioynos should he Vvpl. ulftnn nail
fruB from oluinnuum r.ust by fre-
(juoat rnishinff. Many loneerBa sup
ply. shirts end slhnlnt id both male
and female on|ilttjiH`S, ihr sW is be
ing made without niffo. Thcrr is n
pdoJbiUty of domrer when mplajiK^
wuar flwir work lotHrs to tboir
i,, AvoSSg A lum lm im Pourder ExplosSans
hntnos hefora clurnginff. Ktir exam ple, a porlt from n vniaroUv umy
1, All machlemy ani all molti do and wtoiow tram stortili h wril wtawioi.
Z All
ani cnnvoylnq .qulpotom Acuiti ho ewrttuclct! ot> a . lo lntoill
0 nattosa ot inai Silo n m a .
'
__ ,
x spelulas. coni*, y o r, oni <U* hit. hnuM he ot uon-JPmtonS uialeriata.
' i. Moiors, as ter oc Ptoflbl, .houli b
c'" TM1" K"Bna' " ?*" *
OS. Who>. SI lo W nr lo h a rt In Ih. w ko-a.
-ho he
ai Ut uiplattanumol,. dito-prtu). dadt-aiool imi walotr-rool >|W. ol snulir.Vcaoo
easily amine flllul burns I# a person whoso clothing i* OM wllh the dost of a pyrotechnic jnix-Lm. Owing I
the pinslbilit.v uf static disrersi ailh and Ik-irke nviteriitls tlkoald wk tm
worn lit work by employee. The ideal amusement in liiekcr
rooms ter rmploycea u. Ui n*i> a
T D u V s W in n . b ptimillid lo cobert la wwhronm Ihor houli ho dtm ed double looker njatein with -an intrr
aerer! lime* o day. If n*ss<ny, ahbi?h noi while optiolio om ?ohw on.
veiling shower or wnBliroom. With
. Ond to Ih. houli ho topi al mini. M*i PJ)o **
Oil* method, a Im te is provided
couahnulr wilh otototoo owd.r do nel lobi a . Ih OClbUUr MW*r for eavb employee at ond) side of
mrnoilal. Ti.al.1 Osi rcvort' .tot <tal * lowm apl>ln
lor
lie ohower nr wasbrorinu The em
powiei suBpenit U fc Vndts orilh Ih. n w tid 1 SgoIKon. Wllh un dtsbUaUy ployee removes hin work clothes anil
buttici alcwtoe -li*. ttilh a . me, th InWH 0>h>!* * 1TM **> * " plows tlieiii in the work flnthm loefcv
a --^-nU^llco 1 7,0 mg. A l .per Uh* i rf, mi al " ctonUdUort Si 13J m|. Wi er, Iben takas Ids show and con
tot Indndlon spmk,
, . .. ' tinues lo his scrond Irckrr on the
7, tlohllna ol e t Acidi U wntriiod by iuHitnol. euplotlonittonl bull _ other side of the shower room where
I.
11 paeenory k) uas Uastlsbl. 7 shouii tdway bs ot o Uni.twrllilpMiseoaren Ids street elalhing. Thus
treptovei Irptt, ior w . lo toiplcd aioiMphUM.
* his work dothra Inokrr is always
8, All hoadoo ani ** ah" b . kepi wH lubnatacd i *Mw)1.a twaa dut. available for '.paction by eiimpanr .
1D. Ab nmplayem riioaM weer eppmvtd sn> otattiitii, urtlhout poAt. or nife, oOlolol or for the remoml of died
il 6Diftlb6o
*
clotting for rcplnceaiBul with ulcsn
1 U OpauHm enomre te matoy .houli vwur rocplratn. to a h.Hltti ptoemitU. oiolking.' A* prrviotody enlioued,'
17. Stdoly A sta t n lyy. MA no both ndudlv. ond nMt-tptuWno Aoold U eparlt-proof and conductive shoes
Vrfifll by t^ftNftDt
' should always be worn by eraplovers
13, CuincriTc Bccnna chnuH ho oojplcyod U pCMlbtc.
'
in the lcntling and inUttMt area.
II, Opotoicn .houli he InstretHod A ni Hi tfe'.ol riTM, boy h*oW wUt oo! n.
doso Ih. dp.T .1 tho o d tot . 0)*0irt to oMhonly arllv.S So lato ohS*'
befekewce
-
li. AlomJnom pondo AosiH be .to rti tody * acatod ira a n i Bpart 1M 0 muleir.nl. o.at*dly oMildna oonU or toaBy Oddlrablo subilBoOra.
H. Ooly i l i ood or On4.rewr-opp.i)*d erttngulcher houli bo sud o
smattonai pender Orti. 17. Caie Aould be lutoa io piova! lutei0n aubalonw troni oeMm telo alarine
[A1u.liOta'rrnaltaOl otMiElf!-nllr-d'rtowvne rl'.ut` axplotlons
r D u u ts t o A i r , OCT i h a t . **, * ^ r.
' 'j?' "Niitouoi'Wirt CoCe inr tlir Jvsv*:
^Tt^Bulldl))? tulrouUoa ohould tollon fi ecomomndoUons ol * 0 Nfctonul rito
Piolbcllon AuoclctllBl."
`
l e lo generai. Il la eirlsable lo lolle* mocl ol Ihe preeootons suolly A r i
Ms" `-t-ine tor m tectw n .\eiunei Uelit-
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