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RESEARCH PrecPirsoevRenesReaerscuhlt.s.
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05 APR? MU: 11
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Analytical Report
3M Company Analysis of PFOA and PFOS in Water Samples from Oakdale Municipality
E05-0184 Exygen Report No. L0004708
Testing Laboratory
Exygen Research 3058 Research Drive State College, PA 16801
S e quester
Gary A. Hohenstein Manager. Environmental Operations
EHS Oprations 3M Company
Building 42-2E-27 S t Paul, MN 55106
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.1058 Research Drive
X -E m s tSatalte Coiste, PA 16801, USA
T: 800.281.3219
\ F: 814.272.1019 exygen.com
1 Introduction
Results are reported for the analysis of perfluorooctanoate (PFOA) and perftuorooctanesutlonate {PFOS) in water samples received at Exygen as requested by Gary Hoherwtein of 3M Company. The Exygen project number assigned to the samples is LOOO47O0. Table I lists tha target analytes quantitated for the samples.
Tablet. Target Analytes for Quantitation
Parameter
Acronym
Formula
Perfluorooctanoate
PFOA or C8 add
CrFuCOO'
Perfluorooctanesutfonate
PFOS or C8 sulfonate
CFt7S03*
2 Sample Receipt
Thirty-one samples were received at Exygen in 500 mL white plastic narrow-mouth bottles. At the request of 3M, all samples were analyzed. A copy of all sample log-in information is presented in AttachmentA.
The samples were received on 05/01/05. The samples were shipped ambient via UPS. The samples were stored refrigerated from time of receipt until analysis.
3 Method* - Analytical and Preparatory
The Exygen method entitled, "Method of Analysis for the Determination of Perfluorooctane sulfonate (PFOS), Perfluorooctane eulfonytamide (PFOSA), and Perfluorooctanoate (POAA) in Water,*1modified for isomer separation, was used to prepare and analyze the samples. A summary of the sample preparation can be found In Section 3.1 and the modified analysis conditions for isomer separation can be found in Section 3 2.
3.1 Water Sample Preparation
Solid phase extraction (SPE) was used to prepare the water samples for LC/MS/MS analysis. Forty milliters of the water sample was transferred to a 0 SPE cartridge. The cartridge was washed with 5 mL of a 40% methanol: 60% water wash. The cartridge was eluted with 5 mL of 100% methanol. A portion of the extract was transferred to autosampler vials and analyzed using electrospray LC/MS/MS.
PAG* 2OF5
3.2 Sample Analysis by LC/MS/MS
In High Pressure Liquid Chromatography (HPLC), an aliquot of extract is injected and passed through a liquid-phase chromatographic column. Based on the affinity of the analyte for the stationary phase in the column relative to the liquid mobie phase, the analyte is retained for a characteristic amount of time. Following HPLC separation, mass spectrometry provides a rapid and accurate means for analyzing a wide range of organic compounds. Molecules are ionized, fragmented, and detected. The ions characteristic of the compounds are observed and quantitated against extracted standards.
An HP1100 system interfaced to an Applad Biosystems API 4000 was used to analyze the sample extracts for quantitation.
Isomer separation was obtained using a gradient elution through a Thermo Ftuophase RP. 50 x 2.1 mm x 5pm column. The sum of the isomers is reported as a single value tor each of the analytes.
The folowirg gradient was performed:
Mobile Phase (A): Mobie Phase (B):
2mM Ammonavn Acetate in Water Methanol
Time 0.0
1.0 6.0 10.0 11.0 18.0
65 05
25 25 65 65
35 35 75 75 35 35
The fblcwfng parameters wars used tor operation of the mass spectrometer
Parameter Ionization Mode Polarity Transitions Monitored
Gas Temperatire Dryino Gas (N2)
Settlna Electrospray Negative 413->369 (PFOA), 499->60 (PFOS), 415->370 f ' C-PFOA, surrogate spite) 350C 7.0 L/min
4 Analysts
4.1 Calibration
A 7-point calibration curve was analyzed tartialy and throughout the analytical sequence for PFOA, PFOS and UC PFOA. The calibration points were prepared at 0,25,50,100,250,500, and 1000 ng/L (ppt) tor LC/MSMS analysis. Calibration standards are prepared using the same SPE procedure used tor samples. The instrument response versus the concentration was plotted for each point Using inear regression with 1/x weighting, the slope, /-intercept
PAQC3 O Ffl
and coefficient of determination (r2) were determined. A calibration curve Is acceptable If r2 > 0.965.
For the results reported here, calibration criteria were met. The caibration curves are included in the raw data in Attachment C.
4.2 Surrogates
13C PFQA (CbF^^CJFJwC|OOH) Is used as a surrogate for the water samples. 13c PFOA was added to the empty sample containers before the bottles were sent to the field for sampling. In the field, a l sample and quality control bottles were filed to a volumetric fill line with the sample.
,3C PFOA recoveries can be found InAttachment B.
4.3 Laboratory Control Spikes
Laboratory control spices in the analytical set were prepared by adding a known concentration of PFOA, ,3C PFOA, and PFOS to laboratory reagents. Laboratory control spikes are used to assess method accuracy. The laboratory control spikes must show recoveries between 70130% or the data is rejected. For the results reported here, the laboratory control spikes were within the acceptable range.
4.4 Field Matrix Spikes
A law and a high matrix spike were prepared for every water sample in the field. Compounds were added to the empty sample containers before the bottles were sent to the field for sampling. Matrix spikes are used to assess method accuracy in the matrix. The matrix sptos should show recoveries between 70-130%. For the results reported here, the matrix spices were within the acceptable range, exceptas noted in Section 6 of this report
4.5 Sample Related Comments
All water samples were collected in duplicate. Duplicate sample results are reported along with the sample resutts InAttachment B.
5 Date Summary
Please see Attachment B for a detaled listing of the analytical results. The results are reported in parts per billon (n^mL) for PFOA and PFOS.
6 Statement o fAccuracy
Based on results of laboratory control spikes, field matrix spikes, and surrogate spikes, the analytical accuracy for PFOS and PFOA results for al samples Is 1 30%, Laboratory control spikes, surrogate spikes and field matrix spikes showed recoveries within these ranges, with the following exceptions:
P A Q td O F S
The PFOA and PFOS recovery In O-W8-572608 Low Spike, O-Publc Works Lunch Rm Sink Low Spike, and 0-W5-1272B7 Low Spike could not be calculated because the Inherent sample concentration in this sample was over 3 times greater than (he spiking concentration.
The PFOS recovery for sample O-Public Works Lunch Pm Sink High Spike was 135%.
Specific sample recoveries are given in Attachment B. 7 Data/Sample Retantion
Samples wfll be returned to 3M 80 days after final reporting. ASelectronic data is archived on retrievable media and hard copy reports are stored In data folders maintained by Exygen. Hardcopy data Is stored fore minimum of five years. The client wift be notified 30 days prior to the disposal of hardcopy data. 8 Attachments 7.1 Attachment A; Analytical Results 72 Attachment B: Spike Recovery Data 7.3 Attachment C: Chain of Custody Forms 7.4 Attachment 0: RawAnalytical Data
PAX3OP5
6
SECTION A
7
en
Proven Kesull
1
Summary of PFOA and PFOS in Water Samples E05-0184
Exygan ID
L4708-1 L4708-2 L4708-5 L4708-6 L47Q8-9 L4708-10 L4708-13 L4708-14 L4708-17
L4708-18 L4708-21
L4708-22 L4708-25 L4708-26 L4708-29
Sampla ID
0-W 5-127i87 O-WS-127287 Dup
O-WI -208462 0*W 1-206462 Dup
Q-W2-2Q8463
0-W2-208463 Dup
0-W7-463534 0-W7-463534 Dup
O-W8M572608 O-W8-572808 Dup
O-W3-20S454 O-W3-208454 Dup O-Pubtic Works Lunch Rm Sink O-Public Works Lunch Rm Sink Dup Trip Blank E05-0184
Analyte Found (rtg/mL)
C8 Add PFOA
C8 Sulfonate PFOS
Psrfluorooetsnoata
Prfluorooctanesulfonat*
0.714
0.t
0.781
0.968
0.0892
0.0516
0.0852
0.0541
0.0807
NQ
0.0871
NQ
0.274
0.238
0.305
0.273
0.523
0.687
0.503
0.662
ND ND
ND ND
0.687 0.709
ND
0.872 0.949 ND
ND = Not detected at or above 0.025 ng/mL. NQ = Not quantrflabte Maasurad concantratfon between D.025 ng/mL and the Limit of
Quantitation (LOQ) which is 0.050 ng/mL.
ooo
Drive R4 16801, USA
J ; 814372.1039
F:e8xy1g4W.23M1i.m1580
SECTION B
en RESEARCH Precise Research.
\ Proven Results.
Field Matrix Spika Recovery Summary for PFOA and PFOS In Water E05-0164
Semple OeecrtoMon
0 -W5-1272$7 Low Spike (147B0.3, 0.1pp* SpSur)
C8 Acid PFOA_____________ C8 Sulfonate PFOS
Amount Amt Found Amount
Amt Found Amount
Spited In Semple Recovered Recovery In Sample Recovered Recovery tntftnu (na/mL) (no/mU <%> (neftnu tna/mU (%)
0.1
0.714
0.589
0.669
1.16
0 -W5-127287 High Spike (ureee, vppk **>*)
1
0.714
1.57
96
0.869
1.60
91
O-W1-208482 Low Spike (WTtfrT 0A ppVSpika)
0.1 0.0862 0.166
99
0.0516
0.153
101
0 -W1*208462 High Spike (M7404,1 ppbtpliM)
1
0.0892
1.06
99
0.0516 1.10 105
0-W2<206462 Low Spike (LreM i,e.ippbepito) .
0.1
0.0807
0.195
114
0.0295 0.159
129
0 -W2-208443 High Spike {L470e-13, 1paha*)
1 0.0807 1.16 106 0.0296 1.23 120
0-W7-483534 Low Spike (bt704-14, 0.1 ppbeplka)
0.1
0.274
0.363
109
0238
0.366
128
0 -W7-4S3534 High Spike (L470e*ie, 1ppbpke)
1\ 0.274 1.29 102 0.236 1.27 103
0 -W8-5726Q8 Low Spike (Lsroe-is.e.i ppaepaw)
0.1 0.523 0.620
% 0.687 0.801
O-W8-S72608 High Spike (uroM M spetetke)
1 0.523 1.64 112 0,687 1.90 121
O-W3-20S454 Low Spike <1470444.4.1 ppbSpllw)
O-W3-20S4S4 High Spike 0X70444,1 ppbfplte)
0.1
Nb\
0.107
107
ND
0.114
114
1 ND 1.12 112 ND 1.20 120
O-PuMcWorks Lunch km Sink LawSpika
0470447.0.1 ppbSpiks)
0.1
0.667
6,708
0.872
0.961
O-Publk Wort Loach Rmlin k Hightpika tures4e.ippeipik*)
1
0.667
1,9 5 , 126 0.872 2.22 135
Trip Blank 05-0184 Low Spk
!
(L4T04-40,0.1 ppkBpea)
0.1
ND
0.123
123
ND
0.119
119
Trip Blank E05-0154 High Spk
(L47QI41,1 ppbOpfkc)
1
ND
0.940
94
ND
1.03 103
` Sample residue exceeds the spiking lewd sJonfficanfly: therefore, an accurate recovery value cannot be caicutated
NO - Not detected at or above 0.02$ nglmL.
NQ * Not quantifiable = Man ured ooncenlwtlon between 0.028 ngftnL end the lim it of
Quantitation (LOO) which la 0.060 hg/lmL
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Surrogate Splka Recovery Summary for 13C*PFOA in Water E05-0184
Exygan ID
Sample ascription
Amount Spikad (nfl/mL)
n C-PFOA
Amount Racovarad
fngSmL)
Racovery !%)
L4708-1 ' L4708-2 U 708-3 L4708-4
0-W 5-127287 O-W5-127287 Dup
0-W5-127287 Low Spk 0-W5-127287 High Spk
0.5 0.487 0.5 0.520 0.5 0.546 0.5 0.465
97 104 109 93
L4706-5 L4708-6 U706-7 U708-8
O-W1-208462 O-W1-208462 Dup O-W1-208462 Low Spk OrW1-208462 High Spk
0.5 0.545 0.5 0.497 0.5 0.517
0.5 0.508
109 99 103 102
L4708-9 L4708-10 L4708-11 L4708-12
O-W2-208463 0-W2-2084B3 Dup O-W2-208403 Low Spk O-W2-208463 High Spk
0.5 0.536 0.5 0.603 0.5 0.563 0.5 0.552
107
121 117 110
L4708-13 14708-14
L4708-15 L4708-16
0-W7-463534 0-W7-463534 Dup 0-W7-463534 Low Spk 0-W7-463534 High Spk
0.5 0.540 0.5 0.606 0.5 0.571 0.5 0.529
108 122 114 106
L4708-17 L4708-18 L4708-19 L4708-20
O-W8-572608. 0-W8-5726G8 Dup O-W8-572608 Low Spk 0-W8-572608 High Spk
0.5 0.566 0.5 0.529 0.5 0.617 0.5 0.561
117 106 123 110
L4708-21 L4708-22
L4708-23 L4708-24
O-W3-208454 O-W3-208454 Dup
O-W3-208454 Low Spk
O-W3-208454 High Spk
0.5 0.596 0.5 0.581
0.5 0.537 0.5 0.635
119 116
107
127
L47Q8-25 L4708-26 L4708-27 L4708-28
O-Public Work Lunch Rm Sink O-Publlc Works Lunch Rm Sink Dup O-Pubtic Works Lunch Rm Sink Low Spk O-Public Works Lunch Rm Sink High Spk
0.5 0.5 0.5 0.5
0.487 0.488 0.483 0.575
97 98 97 115
L4708-29
L4708-30 L4708-31
Trip Blank E05-0184 Trip Blank E05-0184 Low Spk Trip Blank E05-0184 High Spk
0.5 0.5 , 0.5 ,
0.524 0.522 0.504
105 104 101
000 R //
MJ ^ 3 0 5 8 Research Drive State CoegeV, PA 16801, USA ^ T :,, 8^00.2811.3219 m FF:: 814.277.2,1019 exyj$en,com
SECTION C
/2>
3058 Research Drive State Coliege, PA 16801
Phone: 814-272-1039 Fax: 814-231-1580
T
Loam
Login Group: L04708
Login #:
4818
Project:
P0001275
Company Name: 3M
Submitted By: KENT LINDSTROM
Conform COC Sample; Conform COC: Conform Sample:
Conform Request:
Login Type. Started:
Immediate Receipt of Samples True
Date Start:
03/01/2005
Due Date:
03/11/2005
Received Date: 03/01/2005
Received By: Ammerman, Mark Spread Sample:
Label: Exygen SD/PI: Risha, Karen Project TKIe/Type; Cottage Grove Residential Water Sampling / ROUTINE Login Notes: Conform Notes:
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t-
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Tamp. C ontrol/Temo.
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C ontainer # COO63056 C0063057 C0063058 C0063059 C0063060 C00S3081 CO063062 C0063063 C0063064 C0063065 C0063066 C0053067 C006308B C0063069
G ro a t W eia ht 260.50 g
H
C ontainer T ype
500 ml Clear Plastic Narrow
267.30 Q
500 ml Clear Ptaatic Narrow
256.90 g
500 ml Clear Plastic Narrow
257.70 g 256.60 g
500 ml Clear Plaatic Narrow
500 ml Clear Plastic Narrow
266.80 g
500 ml d e a r Plastic Narrow
252.900
500 ml Clear Plastic Narrow
259.90 g
500 ml Clear Plastic Narrow
254.10 g
500 ml Clear Plastic Narrow
245.90 g
500 ml Clear Plaatic Narrow
246.40 fl
500 ml Clear Plaatic Narrow
240.90 g
500 m l Clear Plastic Narrow
249.30 g
500 ml Clear Plaatic Narrow
251.10 0
600 ml Clear Plastic Narrow
P reservative NONE NONE NONE NONE NONE NONE NONE NONE NONE NONE NONE NONE NONE NONE
M fot, .,L9t
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500 ml Clear Plastic Narrow
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500 ml Clear Plastic Narrow
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500 ml Clear Plastic Narrow
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500 ml Clear PIm Hc Narrow
253.00 g
500 ml Clear Plastic Narrow
248.90 g
500 ml Clear Plastic Narrow
265.30 g
500 ml Clear Plastic Narrow
259.40 g
500 ml Clear Plastic Narrow
256.90 g
600 ml Clear Plastic Narrow
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3/1/2005 Login .rpt
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Report VersionP:agFeeb32o2f 52005 6:53AM
)&
Instance:
R0149332
m iiiiR iiu
t
Sample,,tB
L0004708-0001 L0004706-0002 LD00478-0003 L0004708-0004 L0004708-0005 L0004708-0006 L0004708-0007 L0004708-OQ08 L0004708-0009 L0004708-0010 L0004708-0011 L0004708-0012 L0004708-0013 LOO04708-0014 LOO04708-0015 10004708-0016 L0004708-0017 L0004708-0018 L0004708-0019 L0004708-D020 L0004708-0021 L0004708-0022 L0004708-0023
gonwn+t C0063056 C0063057 CQ063058 C0063059 C0063060 C0063061 CO063062 C0063063 C0063064 C0063065 C0063066 C0063067 C0063068 C0063069 00003070 COO63071 C0063072 00063073 00063074 C0063075 C0063076 C0063077
Matrix LIQUID LIQUID LIQUID LIQUID LIQUID LIQUID LIQUID LIQUID LIQUID LIQUID LIQUID LIQUID LIQUID LIQUID LIQUID LIQUID LIQUID LIOUiD LIQUID LIQUID LIQUID LIQUID LIQUID
3/1/2005 Login,rpt
Login
E a s fe to Water
Samples
Sample 0-W 5-127287
W ater
O-WS-Oup (127287)
W ater
O-WS-127287-Low Spite
W ater
O-WS-127287-High Spike
W ater
0-W1 -208462
Date Sampled Date Loaned In Pete Due 02/28/2005 03/01/2005 03/11/2005
02/28/2005 03/01/2005 03/11/2005
| 1
VrIi
02/28/2005 02/28/2005 02/28/2005
03/01/2005 03/01/2005 03/01/2005
03/11/2005 03/11/2005 03/11/2005
ll Jj T
H:
W ater
O -W l -208462-Dup
W ater
O-WI-208462-Low Spike
02/28/2005 02/28/2005
03/01/2005 03/01/2005
03/11/2005 03/11/2005
V* |
W ater
0-W1-208462-Hlgh S pite
Q2/28/200S 03/01/2005 03/11/2005
W ater
O-W2-206463
W ater
O*W2-208463-Dup
W ater
0-W2-208463-LOW Spike
W ater
O-W2-208463-Hieh Spite
W ater
0-W 7-463534
W ater
0-W 7-463634-D up
02/28/2005 02/28/2005 02/28/2005 02/28/2005 02/26/2005 02/28/2005
03/01/2005 03/01/2005 03/01/2005 03/01/2005 03/01/2005 03/01/2005
03/11/2005
111
03/11/2005 03/11/2005 03/11/2005
| !
?
14
ft
|i
03/11/2005 03/11/2005
f ifc
|*
W ater
0-W7-483634-Low Spike
02/28/2005 03/01/2005 03/11/2005
Water
0-W7-483534-High Spike
W ater
O-W6-572608
02/28/2005 02/28/2005
03/01/2005 03/01/2005
03/11/2005 |
1
03/11/2005
W rier
O-WIW72606-Dup
02/25/2005 03/01/2005 03/11/2005
W ater
O-W6-5726Q8-L0W Spike
02/28/2005 03/01/2005 03/11/2005 &i
W ater
0-W8*572608*Hiflh SpKe
W rier
O-W3-20S4S4
02/28/2005 02/28/2005
W rier
O-W3-20B454-Dup
02/28/2005
W ater
O-W3-208454-Low Spike
O Q i.'i
R eport V ersion: Feb 22 2005 9;53AM
02/28/2005 In s ta n c e :
03/01/2005 03/01/2005 03/01/2005 03/01/2005
03/11/2005 03/11/2005 03/11/2005 03/11/2005
p
1
R014332
10004706*0024 L0O4708-025 L0004706-0020 L004708-0027 L0004708-0028 LOOO47Q0-OO29 LOO04708-0030 L0004708-0031
C0063078 C0063079 C0063083 C0063064 C0063065 C0063086 C0630S0 C0063061 C0063082
L i QUID LIQUID LIQUID LIQUID LIQUID LIQUID LIQUID Q U ID
Loain
Water
O-W3*208454*High Spike
Ii t
02/28/2005 03/01/2005 03/11/2005
W ater
O-Pubfic Works Lunch Rm Sink
02/28/2008 03/01/2005 03/11/2005
W ater
O-Publlc Works Lunch Rm Sink Dup
02/28/2005 03/01/2005 03/11/2005 ft
Water W ater
O-Publie Works Lunch Rm Sink Low Spike O-Publlc Works Lunch Rm Sink High Spike
02/28/2005 02/28/2005
03/01/2005 03/01/2005
03/11/2005 03/11/2005
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W ater
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W ater
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03/01/2005 03/01/2005 03/01/2005
03/11/2005 03/11/2005 03/11/2005
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Project: E05-0184
CONTRA3CMT ELNAVBIORROANTMOERNYTWALORLAKBOORRDAETROBRYYSAMPLE Contract Ub(s): EXYGEN
Page 1 o f3
Requester Hohenstein, Gary A (0042-2E-27) DPDPrraeootpjjeeeaccRrtttemDNceeeunisvmcter5bdip3e:t0r2i7o0/12n015:2/O2260a70k45d4a4le9Municipal Well PCs III
Completion Date: PPEhrmooajneielctANld^uedmardeb:sesrK:: ek6nr5lti1nL-d7ins7td8rso-t5mm3@m52mmm.com
Ship Date: < ? / * ?/<>$
Comments: Pace field samling.
Trip blanks filled by Exygen & transported w/bottle order. BGJ, 2/28/05.
T2/r2ip8/b0l5a.nks for E05-Q184 also used for EOS-0186 per direction from Kent Lindstrom. Samples traveled together. AC, PI ,F,
3M Sample Number Sampled Date Sample Description
EO5-0184-79849 Analysis Code PFOA
2/28/2005 Analytical
Method O-W I-2084C62pmannwH
PFOA . PFOA
3A/1M5/y20il0i5Pw Paft
PFOS
PFOSbyESMS
PFOS
3/15/2005
E05-0184-79850 Analysis Code PFOA PFOS E05-0184-79851 Anatyfia Cod PFOA PFOS
2/28/2005 Analytical
Method
O-W
1-208462 Dun CiOPRfart
PFOA PFOA
PFOS by ESMS
PFOS
2/28/2005 Analytical
Method 0 -W
2-208463 Qmiponanb
PFOA PFOA
PFOSbyESMS
PFOS
3A/o1f5f/t2vi0t0i P5 in Pale 3/15/2005 3A/1n5a/t2o0l0i 5Pu* Pule 3/15/2005
E05-0184-79852 Analysis Code PFOA PFOS E05-01 84-79853 Analysis Code PFOA PFOS
2/28/2005 Analytical
Method
O-W2-208463 Dud ConMKfflttttt
PFOA PFOA
PFOS by ESMS
PFOS
38/2005 O-W3-208454
Am IyIm I Method
CgmiMwciti
PFOA PFOA
PFOSbyESMS
PFOS
AnalysisDue Pate 3/15/2005 3/15/2005 Aaalvil Due Date 3/15/2005 3/15/2005
E5-0184-79854
2/28/2005 1O-W3-208454 Dud
00 8
22
2/28/2005
CONTRA3CMT ELNAVBOIRROANTMOERNYTWAOLRLKABOORRDAETROBRYYSAMPLE
Page 2 of 3
Project: E05-0184 (cont)
Contract Lab(s): EXYGEN
3M Semple Number Sampled Date Sample Description
E05-0184-79854 (cont) Analysis Code PFOA PFOS
2/28/2005 O-W3-208454 Dup
Analytic! Methodl
Component
PFOA PFOA
PFOSbyESMS
PFOS
AnahnhLpMf Pate 3/15/2005 3/15/2005
E05-0184-79855 Anelvail Code PFOA PFOS
/2 28/2005
0-W5-127287
Analytical Method
PFOA PFOA
PFOSbyESMS
PFOS
AntfaiiiPvy Putt 3/15/2005 3/15/2005
E05-0184-79856 AntjyiU Code PFOA PFOS
2/28/2005 0-W5-127287 Duo
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ammamti
PFOA PFOA
PFOS by ESMS
PFOS
3A/1n5il/T2i0to05Pm P itt 3/15/2005
E05-0184-79857 Analnli C rtt PFOA PFOS
2/28/2005 0-W7463534
AnelytKild Mittcd
CWIMBWlft
PFOA PFOA
PFOSbyESMS
PFOS
3A/M15l/y2r0tf0J5BuePutff 3/15/2005
E05-0184-79858 AeetYAii^pdt PFOA PFOS
2/28/2005 0-W7-463534 Dup
Analytical
CaniBttqwtt
PFOA PFOA
PFOS by ESMS
PFOS
AnafvswDue Pete 3/15/2005 3/15/2005
E05-0184-79859 Analvsli Code
PFOA
PFOS
2/28/2005 O-W8-572608
Analytical Method
Compunteti
PFOA PFOA
PFOSbyESMS
PFOS
3A/1as5l/Y20ia05Dus Pitc 3/15/2005
E05-0184-79860 PFOA PFOS
2/28/2005 0-W8-5 72608 Duo
Analytical Method PFOA
CPbFfOflBAlIBBBtl
PFOS by ESMS
PFOS
Anihraii Put PMs 3/15/2005 3/15/2005
E05-0184-79865 Analysts Code PFOA PFOS
2/28/2005 1Public Works Bide
Analytical Method
Components
PFOA PFOA
PFOS by ESMS
PFOS
Analvili Due Date 3/15/2005 3/15/2005
E05-0184-79866
A n tiv id i Code
PFOA PFOS
2/28/2U5 Public Works Bids Duo
Analytical Method
ttmBtUIMrtl
PFOA PFOA
PFOS by ESMS
PFOS
Analysis Due Date 3/15/2005 3/15/2005
00., 8
2/28/2005
CONTRA3CMT ELNAVBOIRROANTMOERNYTWAOLRLKABOORRDAETROBRYYSAMPLE
Page 3 of 3
Project: E05-01M (cont)
Contract Lab(s):EXYGEN
3M Sample Number Sampled Date Sample Description
E05-0184-79867 Apalyaii Code PFOA PFOS
2/28/2005 Trip Blank
PFOA PFOS by ESMS
PFOA PFOS
Analyst Due Pate 3/15/2005 3/15/2005
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