Document LgkbdJV4d1ywrD0K2aZY0qdjq

( \ m r O M lj BIODEGRADATION (BOD) TEST SUBSTANCE Identity: Perfluorooctanoic acid; may also be referred to as PFOA, FC- 26, or FX-1001. (Octanoic acid, pentadecafluoro-, CAS # 33567-1) Remarks: The 3M production lot number was not noted. The test sample is FX-1001. It's purity was not sufficiently characterized, though current information indicates it is a mixture of 95 - 98% test substance and 1 - 5% perfluorochemical inerts. METHOD: Method: Not noted. Type: Aerobic GLP: No Year completed: 1985 Contact time: 20 days Inoculum: Sewage/3M Chemolite industrial wastewater treatment plant, Cottage Grove, MN RESULTS Chemical Oxygen Demand (COD): 2650 mg/kg* Biochemical Oxygen Demand (carbonaceous BOD): 5-Day: <1800 mg/kg 10-Day: <19,000 mg/kg 20-Day: <19,300 mg/kg * Average of two values. This piece of data comes from a summary only. No raw data was found. It was noted that this value was determined by dichromate reflux. CONCLUSIONS No reliable conclusions can be derived from this study. Submitter: 3M Company, Environmental Laboratory, P.O. Box 33331, St. Paul, Minnesota, 55133 DATA QUALITY Reliability: Klimisch ranking 3. There is no information on the purity of the substance. There is no analytical to confirm test substance 003694 concentration. pH was not noted. Seed does not appear to be sufficiently active. The study indicates a neutralization step was used, but no description of that activity is noted on the data sheets. This step is requested on the computer-generated Archived Final Report for Lab Request No. C1006. REFERENCES The COD and BOD studies were conducted by 3M Company, Environmental Laboratory, St. Paul, Minnesota, Lab Request number C1006, 2/14/85. OTHER Last changed: 5/24/00 003695 05/22/2000 ENVIRONMENTAL LABORATORY ARCHIVED FINAL REPORT 1 LAB REQUEST NO. C1006 REQUESTOR NAME: EAR/MTE DEPARTMENT: 0535 PROJECT NO: 9970012600 DATE RECEIVED: 01/03/1985 DESC: ENVIROMENTAL SCREENS ON FX-1001(FC-26) CONTRACT LAB(S): EXP COMP DATE: 02/18/1985 DATE COMPLETED: 02/14/1985 PROJECT LEAD: ST WOLF PHONE NO: 651-778-4048 3M FAX NO: 651-778-6176 NEUTRALIZE PRODUCT WITH NAOH PRIOR TO BOD + FISH TEST. DILUTE IN WATER PRIOR TO NEUTRALIZING CAREFULLY. SAMPLE DATE CODE DESCRIPTION RESULT MDL or (95% O.I.) ACID FX-1001 96-HR-LC50 C-BOD-05 C-BOD-10 C-BOD-20 COD-RFX FISH ACUTE TEST - 96 HOUR BOD-05 (CARBONACEOUS) BOD-10 (CARBONACEOUS) BOD-20 (CARBONACEOUS) COD (DICHROMATE REFLUX) DUP 1 COD-RFX COD (DICHROMATE REFLUX) COMPLETE - SEE ATTACHED REPORT SEE ATTACHED REPORT SEE ATTACHED REPORT 2700 MG/KG 2600 MG/KG Enter Carriage Return to continue: 003696 *ital Laboratory BOD Work Shaat >01111010, and Standards Man m d i d Dilution W ater Blank Bottle Mo. Initial 0.0. (A,) 1C X / o __ x J h . _ __ SJ6______ % . / c > Praaant 0.0. (A.) y- c?0 8 -0 S' ? - r . ____ 0.0. Oaplatlon lAi *Ai) /o . o ' O f0 Avenge 0 .0. Depletion (A<-X*) \0 '0 # Baadod Dilution W ater Blank (optional) Bottle No. m ... u s ?i Saod Cont/oia BottlaNo. Initial 0.0. <C.) f -t Sample8tao Praaant 0.0. (C.) t- Oa t-OS~ 0.0. Dapiation (C.C.) Of o 0 i0 Average D.O. D^ouoeieaot^teoan "N |yt C 4 ___ _______________ ______CL.2J?.___________ \ 0 Initi(aBl.0).0. Praa(aBn.t)0.0. 0.0.Oaplattoo n c 7-8 o HP ? - r o -- u ----- Cn Olueooa Qlutamlc A dd Standard BottleNou SampleBiaa Initi(a0l.)D.O. 0P.r0a.aa(Dnit> TDoe(tpDallTet0oi.oo0n. ~ lf~ C In >* __U .__I._/*''v? *8-c o <-00 f. * 5" V- C.o -__nc 3 / ^ Q /r 3 yo V-t* 7. ? o 6 -C o 3.7c> DTepolSettaionndaDrudo 2- o 1 Z. 3 f o-i o 0 cl O 3 /O BOO Bbo 72 o 3 2o? * ~l-0O BottlaNo. SanorioSfa. T > r Initi(aDl.0).0. Praaa(n0.t)DA. TCoatpatlat0i.o0n. DTapoiSattainodnaQruda BOO.^Day AvBaOraOga*Day 003697 Laboratory orkShaat " jt-A-pm L d > n ,.N < > Anaiymt . ^ C le o i aainB M m m oovom i ( V N 10 1 6 ^ / / ^ Oal* Start** BOD Run No. ^ ^ '5 Day BOD Raadlngs Oat* Implo PnoripSoii /C / o o C Initial Dilution ___________ / ' ^ 0 % ______of Sampla diluted to ____ / , f S J L ______ ml w ith 01 water Initial Dilution Factor (Dilution factor * 1 if undilutad) BNeotl.ia rt>i fe e 7*&c ,<K Cju Consol #aSS*# 3- '3 <c 1 /3 a? i3 __ yoC / ? 7 n /* 3J- 0I0n.it(i0al.) F >0 7 -^ c J.?o 0P.V09.N(DMa) TQo|pta||l^0|p.0g. OL-Dd OfaoplllaoatiooMnsOhrne ---2BO1ODay _o. a-/ y,a,v ./1 ~ oyo BVOTDL , Note; 1. Cone, = Concanjrationof tampia<ml/lor/ngff}Jn BOObotttos. 2. SompteSlzo Vrm of 0 of aompteordllutachfcMnpla addad to BOOBottt*. 3. Samplaewith QT21 and 0 0 6 2 2 used to calculate enrage BOO. Commanta 003698 ,rantoJ Laboratory BOO Work Sliaat ,4 Contrete, and Standante fT^rTkas L a b R n q .N o . ciooc d e i - ) ' O sla Btartad _____ ____________________a_o d__O_on_o_an_tr>etto-ni * ifJt S M M taM M InM M arCano. /("*- Oimiiif~ld w*m r / < I d - l \ i / h < -_____ G fi - *r Noaooodod OMuttoA- Water Btank BODRunNo. ^ 5 ' 3 - Day BOD Raadlngt | Data Dato ___________ t -n * * T*n. Oau T. t - n - i r _________ lotHiNo. u tifa ____ i i __________ lulllilOlOl (A.) X/o /r ti.to PlMMIt 0.0. (A.) y. r * 0.0 .OaptoUon 0. 2 0 Amaga D.O. Piptetloa 1 IZ-M y. o o o . i - jo-/* _____ t e _______ _____ a j k _______ ln ^ id DiluitoB Wotaf nianMopMonal) n**Mf Mo. m l? 3 ______7 / WtlalOXX (C.) f./e i/r ________ PlMMll 1X0. <c.) 7**0 7 ?" 7 ?r 0.0 .DaplaMan (C-Ct) O-ye Oi j. ANapOiA Qm ||||ob TTcJ j 0 -Y 3 t M d Contrata |g|H|ffo ()Inttial p.0. <>)Ptaaant 0.0. (rncD.O. Daptation J?/3 -- n -------------- 20 XiH o 7-S O 7. j o C-jO Otaoooo * Q lu tan ta A d d S tandort -- 7 c ft: ,9 /#! - _ .. 3 >- i 7__..._. _ / * * *l t 5 InMIal 0 .0. (0 .) Praaont 00.(0 ) ___ 2. 6 oSr._6^_ i.fo ,y*' * 7 ^ (ii #/#<!< /_ Total o .a fUaMlQift (o T o ) a .** Y to ?.>o /c S-.5 ----------------- O ' 3 / i 3. r OaptaUon Oua ____L? Oey To Standard BOO Am afio / . IW BOO 2 -i7 ^ Cf * > . % 'A i 2 2 0 2n - 7_1'7 V J 2 2 o > ~ 2 ./c B M to N o . O M p latiM J > } M tw a a (0 .) p fM M ita a (0*) Total D.O. OaplooR (A *04 DVOAPaIOlaHMOIMI QVuW to nanoara __ Ota BOO Am afia.Boy BOO 003699 <#nUI Laboratory LabBoq. No.te AMUM , C/ooit OMattwM ' T $ mmZ e~ /<? i u //1 < ~ BOD Bun No. . . .. L ... Day BOO Roodlng AMWM llM * ____________________________________\ /z ziZ i.r . C fO O C ,-/ InitialOKotton taitiildhuMm PmIdv oNtott.e CmmI l' i>Y fa>c l% c 1? I^c H0 33 I3 x? f3 lot #58, .. i 2 H $ i L ofSampladllutadta ! &Q_0 ....mlwithMwfltOf (Dilutionfactor 1Mundiluted) b> 0h0M.(0al) 0fi0ilV.(0R4I Z - l ' f 7- 3<> TO<omt0aM,l00I4m.0. - JSrPO & / & 7 -1 ro o T -'O o ? -ro ?-<j[o _ (.`'S f*' - / 1 / V J .*o y o-Ho OmTMbIsBiHaMoaaii)tDem ...If?0..0-Pay la0_0 Day r 0 `0| (l2c) <f ) ( 60 O ? 4 S*c * i U . / Note: 1. Cone. Concwjjratlono!umptofmMor/ngAln BOObottlM. 2. 8ampte8l w a @ W 0OfaaiiiptewdUutaalNiinpteaddadtoBOOBottla. 3. 8empteewHhieioiid006S2i*edtooaloloteevwgoBOOL 003700 iiw n lal Laboratory BOD Work Shoot j, Controlo, and Standards j a -mm .a b R a q .N o . Amrivot o3. C t o o G C tc if Duo Untad ji J L S t-- A */ e t ' * ' - - MMatttoji taWMiofCono. ~ i~ * /< OtaBHod Stator B O D R unN o. g J ' ' 3 ^ AnalyM HiMMlorTMp. - - Day BOD RaadJnga Ih n D M ' Tamp. Dala Tm m J e - J h M v - __________ _____ L - _______________ ______________ u i ' i i . _____ .................. ....... ...................... NqmmnmIm I OHuHon Btank Botila No. M tialD .O . (A,) PraOOMD.0. (A4 3C io 7.%o Xi3 2 if ... h 9 f __ &L..... __ L-____ ? S o 0.0.Captation *( A .-A 4 5. 3O AwaragoOA. s. Captation / __ >.? 3*_____ J- andad Dilution-WatorBianfc (optional) attiaN o. m U _______? / initiai a o . (C.) f 1 i- r f ___ _________________ Pm ant 0.0. (C.) ?- & o 0 .0. Oapiation <CV^C4 0 - fO Avana 0.0. OaatoUon a fx . "s. (C* M 7 < *f O. S ' -S 2 . 7 - i f ________ ____ Q __________ 1taHIsNo, InMtol 0.0. (-) Praaant 0.0. (B.) DaO0pM ifi (-4 h 0.0 *0 -- U --------------- Sluoaaa* Stufante A dd Standud BattiaNo. , _ Initi(a0l.0).0. ?7 C 3 h: f .U (ridurti.. 0 /**,7*./ Y-oo <6-0 0 .% ' ( __ m nc 7-B O ?-ro . 8 0 0P0m.(a0n4t TO(oatpa.il.aD0tio.40n. if 3. C o 3.6 r V Ho Ito . I O f ***/ **- 7:2>r $ -9 o OSO >< .to .l..___________ CTaopBtattaionndaOnuia **00*Oay A2w00ar0ao.aDw 2.f V 2/ ^ . -.hi 2 33 y. io 2 Ht La#-* A . BatilaHa ampiaMm Initi(a0l.O)O. Plana(0n4tOO. TO(oaKtpail*a00tio4.0n. QTieplflu^ngdilaOratM .BOOOay Am t m ItM. BOO * 3 > ? 03701 jnontal Laboratory oifcShMt- " ft-A-MHC UbRpQ.No.- t t 0 0 ( p BOO Run No. $ 5 '3 d jJ .. 2 <J> AMipt . ____ ________________________________ /7 m . . Day BOO Rpadingp |Ort* CiooC, -f Inna^wHo^I^n^nolDan^U^^u^nwHw^wm^^ro IhIUjI onnyQHHuty - h co % ----- ofSampledllutodto / 0 oc> _ mlwithDlwater -(Dilutionfactor 11fundiluted) BMoeM.i Cmd } 3 fii 3-3 & C 7 7&C _ 13 1? a? __?3. <j<? /ot *82? .r 9 U 3* ahaiiiDn^l) afom.i<dm Tdo(mtfamtl-inbood. r./^ ? ,y o 7 /o ft _ o.io 7-f* l / o 0'1 . 7 fo 6- ? 0 i./o aA. ^ M -- l.% 0 6 -7 1.10 Q^pIqIIqH m Bf 6 .2 3 ^0 0Dny ofoo) too 0 - 2 c1 O 0 ?c> ^2 200) }C 2 2 o o o C>K 0 ) <!V> o> 67 ' A ^ - ^ f *> Mote: 21.. CSaomnpel, eaSCtaonnWcemnotrartigonofofaaommpipnlaor(mdUl/luotre/nogltmyptnIoBaOdOdbedolttoloBi.OOBottio. 3. Si mplonwHhO TglondP O tS aunodtonaleulote amraQoBOO. 003702