Document Lg2Y7wRyRLKmK3qMYmyLmqqBX
STLS F, V F R N
T R ENT
STL Chicago ?417 Bond Street University Park, IL 60466
Tel: 708 534 5200 Fax: 70S 534 5211 www.stl-ific.com
Title; Project. M a n a g e r E - M a i l : r w r i y h t @ s t 1 i n c .c o m
T h i s Report. C o n t a i n s Lead ers in E n viro n m e n ta l Testing
U n i v e r s i t y Park, IL 60466 PHONE: (70S) 5 3 4 - 5 2 F A X . .: ( 7 0 S ) 5 3 4 - 5 2 1 1
P ages
Severn rrent Laboratories, inc.
WET CHEMISTRY DATA PACKAGE CONFIDENTIAL DECATUR - FC INVESTIGATION
JOB# 232679
Data Summary............................................................... 1 Chain of Custody..........................................................14 Case Narrative............................................................. 19 Raw Data...................................................................... 21
STL Chicago is part of Severn Trent Laboratories, Inc. SAM P L E "1 N F O R M A T I0 N
Job Number. 232679
Customer... Weston Solutions, Inc. Attn.T,. ,, . Jai Kesari
Project Number........ : 20004891 Customer Project ID.... : CONFIDENTIAL DECATUR Project Description___ : Confidential Decatur - FC Investigation
Laboratory ,5ampLe/T:\:\:/
.. customer sample ID
232679-1
DF06-SBC-133R-0-0000
232679-2
DF06-5B-133R--050
232679-3
DF06-SBC-133R-0-0055
232679-4
DF06-SEC-133R-0-0100
232679-5
DF06-SBC-133R-0-0150
232679-6
DF06-SB-133R-0-0180
232679-7
DF06-SBC -133R-0-0200
232679-8
DF6-SBC-133R-0-D250
Sample //"/.Date//:.
Matrix ;
Sampled
Soil
12/08/2004
Soi L
12/08/2004
Soi L
12/08/2004
Sai 1
12/08/2004
Soil
12/08/2004
Soi l
12/08/2004
Soi L
12/08/2004
Soil
12/08/2004
T ime Sampled
10:10
10:20 10:30 10:45 12:05 12:15 12:35 13:15
Date :Received 12/10/2004 12/10/2004 12/10/2004 12/10/2004 12/10/2004 12/10/2004 12/10/2004 12/10/2004
Received 10:00 10:00 10:00 10:00 10:00 10:00 10:00 10:00
Page 1
i
STL Chicago is part of Severn Trent Laboratories, [no.
Job Humber: 232679
; CUSTOMER: Weston Solutions , ine.
Customer Sample ID Date Sampled..... Time Sampled..... Sample Matrix....
D F06 -SBC-133 R-0-0000 12/QS/2004 10:10 Soi 1
TEST.METHOO Lloyd Kahn
:PARAMETER/TEST DESCRIPTIN.
Total Organic Carbon (Soils) TOC Average Duplicates, Solid
Qi
LABORATORY
TEST
RESULTS
PROJECT: CONFIDENTIAL DECATUR
Laboratory Sample ID 232679-1 Date Recei ved...... 12/10/2004 Tiine Recei ved...... 10:00
Date:12/27/2004 ATTN: Jai Kesari
SAMPLE RESULT- 0.FLAGS 1800
MDL 94
RE DILUTION UNITS EATON DT: DATE/TIME TECH
370 :1
mg/Ks 13723S
12/16/04 1349 cls
n Description = Dry Ugt.
Page 2
(O
* In Description = Dry Wgt.
Page 3
STL Chicago is part of Severn Trent Laboratories, Inc.
* In Description = Dry Wgt.
Page 4
STL Chicago is part of Severn Trent Laboratories, Inc.
Job Number: 232679
: LuS'iUMtK : weston :solutions, :m e .
Custodier Sample ID: DF06-SBC'133R-Q-0100 Date Sampled...... :T2/0S/2QD4 Time Sampled...... :10;45 Sample Matrix..... :Soi l
TEST METHOD Lloyd Hahn
PARAMETER/TEST DESCRIPTION
Total Organic Carbon iSoils) TOC Average Duplicates, Solid
LABORATORY
TEST
RESULTS
KK.UJ.cC1: LiUtU-JDfcNIIAL UtCAIUK
Laboratory Sample ID: 232679-4 Date Received....... :12/10/2004 Time Received....... :10:00
Date:12/27/2004
SAMPLE RESULT- ' flags ;: 960
HDL 110
-- - --s-1--- RL .DILUTION UNITS BATCH :0T PATE/TIME fECft
440 1
mg/Kg 137203
12/16/04 1442 cls
* In Description = Dry Ugt.
Page 5
STL Chicago is part of Severn Trent Laboratories, ]nc. Job Humber: 232679
LABORATORY
TEST
RESULTS
t Date:12/27/2004
* In Description = Dry Wgt.
Page 6
STL Chicago is pari of Severn Treni Laboratories, Ine.
3>
* [n Description = Dry Wgt.
Page 7
GO
* In Description = Dry Wgt.
Page B
STL Chicago is part of Severn Trent Laboratories, Inc.
In Description = Dry Wgt.
Page 9
STL Chicago is part of Severn Trent Laboratories, Inc.
Job Number: 232679
LABORATORY
CHRONICLE
Date: 12/27/2004
CUSTOMER: Weston Solutions, Ire.
; . . .
Lab ID: 232679"1 METHOD
EDD Lloyd Kahn
Client ID: DF06-SBC-133R-0-0000 DESCRIPTION Electronic Data Deliverable Total Organic Carbon (Soils)
Lab ID: 232679"2 Client ID: DF6-SB-133R-D-0050
METHOD
DESCRIPTION
Lloyd Kahn
Total Organic Carbon (Soils)
Lab ID: 232679-3 Client ID: DF06"SBC-133R"0"0055
METHOD
DESCRIPTION
Lloyd Kahn
Total Organic Carbon (Soils)
Lab ID: 232679-4 Client ID: DF06-SBC-133R-0-0100
METHOD
DESCRIPTION
Llayd Kahn
Total Organic Carbon (Soils)
Lab ID: 232679'5 Client ID: DF06-SBC-133R-0-0150
METHOD
DESCRIPTION
Lloyd Kahn
Total Organic Carbon (Soils)
Lab ID: 232679-6 Client ID: DF06-SB-133R"0'0180
METHOD
DESCRIPTION
Lloyd Kahn
Total Organic Carbon (Soils)
Lab ID: 232679-7 Client ID: DF06-SBC-133R-0-0200
METHOD
DESCRIPTION
Lloyd Kahn
Total Organic Carbon (Soils)
Lab ID: 232679-8 Client ID: DF06-SBC-133R--Q250
METHOD
DESCRIPTION
Lloyd Kahn
TotaL Organic Carbon (Soils)
PROJECT: CONFIDENTIAL DECATUR
ATTN: Jai Kesari
Date Recvd; 12/10/2004 Sample Date: 12/05/2004
RUN# BATCH# PREP BT #(S)
DATE/TlME ANALYZED
1
1 137288 137258
12/16/2004 1349
DILUTION
Date Recvd: 12/10/2004 Sample Date: 12/05/2004
RUN# BATCH# PREP BT #(S)
DATE/TlME ANALYZED DILUTION
1 137288 1372SS
12/16/2004 1412
Date Recvd: 12/10/2004 Sample Date: 12/03/2004
RUN# BATCH# PREP BT #(S)
DATE/TlME ANALYZED
1 137288 137288
12/16/2004 1428
DILUTION
Date Recvd: 12/10/2004 Sample Date: 12/08/2004
RUN# BATCH# PREP BT #(S)
DATE/TlME ANALYZED DILUTION
1 137288 137288
12/16/2004 1442
Date Recvd: 12/10/2004 Sample Date; 12/08/2004
RUN# BATCH# PREP BT #<SJ
DATE/TlME ANALYZED DILUTION
1 137288 137288
12/16/2004 1505
Date Recvd: 12/10/2004 Sample Date: 12/08/2004
RUN# BATCH# PREP BT #(S)
DATE/TlME ANALYZED DILUTION
1 137288 137288
12/16/2004 1517
Date Recvd: 12/10/2004 Sample Date; 12/08/2004
RUN# BATCH# PREP BT #(S)
DATE/TlME ANALYZED DILUTION
1 137288 137288
12/16/2004 1533
Date Recvd: 12/10/2004 Sample Date: 12/08/2004
RUN# BATCH# PREP BT #(S)
DATE/TlME ANALYZED
1 137288 137288
12/16/2004 1547
DILUTION
Page 10
iO
'/Q U A L T T Y A S S U R A N C E M E T H O D S .R E F E R E N 'C.'E S A N D N T E S : .... ;br t Date: 12/27/2004
REPORT COMMENTS 1) ALL pagcis of this report are integral parts of the analytical data. Therefore, this report should
be reproduced only in its entirety. 2) Soil, sediment and sludge sample results are reported on a "dry weight" basis except when analyzed for
Landfill disposal or incineration parameters. All other solid matrix samples are reported on an "as received" basis unless noted differently3) Reporting limits are adjusted for sample size used, dilutions and moisture content if applicable. A) The test results for the noted analytical method(s) meet the requirements of NELAC. Lab Cert. ID# 100201 5) According to 40CFR Part 136.3, pH, Chlorine Residual and Dissolved Oxygen analyses are to be performed immediately after aqueous sample collection. When these parameters are not indicated as field (c.g. pH Field) they were not analyzed immediately, but as soon as possible on Laboratory receipt.
Glossary of flags, qualifiers and abbreviations (any number of which may appear in the report) Inorganic Qualifiers (Q-Column) U Analyte was not detected at or above the statedlimit. < Not detected at or above the reporting Limit. J Result is less than the RL, but greater than or equal to the method detection limit. B Result is less than the CRDL/RL, but greater than or equal to the 1DL/MDL. S Result was determined by the Method of Standard Additions, F AFCEE: Result is less than the RL, but greater than or equal to the methoddetection limit, inorganic Flags (Flag Column)
ICV,CCV,ICB,CCB,ISA,I SB,CR1,CRA,MRL: Instrument related QC exceed the upper or lower control limits. * LCS, LCD, MD: Batch QC exceeds the upper or lower control Limits. + MSA correlation coefficient is less than 0.995. A MS, MSD: The analyte present in the original sample is A times greater than the matrix spike concentration; therefore, control limits are not applicable. E SD: Serial dilution exceeds the control limits, H MB, EB1, EB, EB3: Batch QC is greater than reporting Limit or had a negative instrument reading Lower than the absolute value of the reporting Limit. N MS, MSD: Spike recovery exceeds the upper or Lower control Limits. W AS(GFAA) Post^digestion spike was outside S5-115% control Limits. Organic Qualifiers (Q - Column) U Analyte was not detected at or above the stated limit. NO Compound not detected. J Result is an estimated value below the reporting Limit or a tentatively identified compound (TIC). Q Result was qualitatively confirmed, but not quantified. C Pesticide identification was confirmed by GC/MS. Y The chromatographic response resembles a typical fuel pattern. Z The chromatographic response does not resembLe a typical fuel pattern. E ResuLt exceeded calibration range, secondary dilution required. F AFCEE:Result is an estimated value below the reporting Limit or a tentativelyidentified compound (TIC) Organic Flags (Flags column) B MB: Batch QC is greater than reporting Limit. * LCS, LCD, ELC, ELD, CV, MS, MSD, Surrogate: Batch QC exceeds the upper or Lowercontrol limits. EB1, EB2, EE3, MLE: Batch QC is greater than reporting Limit A Concentration exceeds the instrument calibration range a Concentration is below the method Reporting Limit (RL) B Compound was found in the blank and sample. D Surrogate or matrix spike recoveries were not obtained because the extract was diluted for analysis; also compounds analyzed at a dilution will be flagged with a D. H Alternate peak selection upon analytical review I Indicates the presence of an interfence, recovery is not calculated. M Manually integrated compound. P The lower of the two values Is reported when the % difference between the results of two GC columns is
Page 12
11
QUA L IT A $
CE ME T H 0
R e F e f' E N C'
P N0TES
.Report P t e : 12/27/2004.
greater than 25%. Abbreviations AS Post Digestion Spike (GFAA Samples - See Note 1 below) Batch Designation given to identify a specific extraction, digestion, preparation set, or analysis set CAP Capillary Column CCB Continuing Calibration Blank ccv Continuing calibration Verification CF Confirmation analysis of original C1 Confirmation analysis of A1 or DI C2 Confirmation analysis of A2 or D2 C3 Confirmation analysis of A3 or 03 CRA Low Level standard Check - GFAA; Mercury CRI Low Level standard Check - ICP CV Calibration Verification Standard Oil Fac Dilution Factor - Secondary dilution analysis D1 Dilution 1 02 Dilution 2 03 Dilution 3 DLFac Detection Limit Factor DSH Distilled Standard - High Level DSL Distilled standard - Low Level OsM Distilled Standard - Medium Level EB1 Extraction Blank 1 EB2 Extraction Blank 2 EB3 01 Blank ELC Method Extracted LCS ELD Method Extracted LCD ICAL Initial calibration ICB Initial Calibration Blank ICV Initial Calibration Verification IDL Instrument Detection Limit ISA Interference Check Sample A - ICAP ISB Interference Check Sample B - ICAP Job No. The first six digits of the sample ID which refers to a specific client, project and sample group
Lab 10 An S number unique laboratory identification LCD Laboratory Control Standard Duplicate LCS Laboratory control Standard with reagent grade water or a matrix free from the analyte of interest MB Method Blank or (PB) Preparation Blank MD Method Duplicate MDL Method Detection Limit MLE Medium Level Extraction Blank MRL Method Reporting Limit Standard MSA Method of Standard Additions MS Matrix Spike MSD Matrix Spike Duplicate ND Not Detected PREPF Preparation factor used by the Laboratory's Information Management System CLIMSJ PDS Post Digestion Spike (ICAP) RA Re-ana lysis of original Al Re-analysis of Di A2 Re-ana lysis of D2 A3 Re-ana Lysis of D3 RD Re-extraction of dilution RE Re-oxtraction of original Rc Re-extraction Confirmation RL Reporting Limit RPD Relative Percent Difference of duplicate (unrounded) analyses RRF Relative Response Factor RT Retention Time
Page 13
2
Q U A LM' T &
A S''5 U R A N C E
E T HDDS
E N C E AN N 0
Report Date: 12/27/ZD04
RTW Retention Time Window Sample ID A 9 digit number uhique for each sample, the first
six digits are referred as the job number
SCB Seeded Control Blank
$D Serial Dilution (Calculated when sample concentration exceeds 50 times the MDL)
UCB Unseeded Control Blank
SSV Second Source Verification Standard
StCS
Solid Laboratory Control Standard(LCS)
PHC pH Calibration Check LCSP pH Laboratory Control sanple
LCDP
pH Laboratory control Sample Duplicate
MDPH
pH Sample Duplicate
MDFP Flashpoint Sample Duplicate
LCFP
Flashpoint LCS
G1 Gelex Check Standard Range C M
G2 Gelex Check Standard Rahge 1-10
G3 Gelex Check Standard Range 10-100
G4 Gelex Check Standard Range 100-1000
Note 1: The Post spike Designation on Batch QC for GFAA is designated with an "5" added to the current
abbreviation used. EX. LCS S=LCS Post Spike (GFAA); MSS=MS Post Spike (GFAA)
Note 2: The HD calculates an absolute difference (A) when the sample concentration is less than 5 times the
reporting limit. The control limit is represented as +/- the RL.
Page 14
CHAIN OF CUSTODY
3 lT>3. 4 ) 1 ^
CHAIN OF CUSTODY/ANALYSIS REQUEST FORM
Severn Trent Laboratories
T: 703-534-5200
F: 708-534-5211
2417 Bond Street
University Park, IL 60466
PAGE ___ Of
PROJECT INFORMATION Client: Weston Solutions, Inc.
1400 Weston Way, Bldg. 5-2 West Chester, PA 19380 T: 610-701-3761 F: 610-701-7401
Project Manager: Jai Kesari email: j.ke sariio)westo nsol uti ons. co m
Project Name: Reference No:
Decatur, Alabama 02181-129-081-0001
ANALYSES REQUESTED
Sampler:
T Frinak, A Murphy
P.O. #: Quotation #:
SAMPLE ANALYSIS
ExyLIMS # \
A
Client Sample Identification
DF06 SBC 133R
0000
DF06 SB 133R
0050
DF06 SBC 133R
0055
DF06 SBC 133R
0100
DF06 SBC 133R
0150
DF06 SB 133R
0160
DF06 SBC 133R
0200
DF06 SBC 133R
0250
Collection
Date
8-Dec-04 8-Dec-04 8-Dec-04 8-Dec-04 8-Dec-04 8-Dec-04 8-Dec-04 8-Dec-04
Collection
Time 10:10 10:20
10:30 10:45 12:05 12:15 12:35 13:15
a. mEm e
o
Cl
Eo
4eC) oo. 2oc
a o 2U
X X
Sample
Matrix
SOIL SOIL SOIL SOIL SOIL SOIL SOIL SOIL
Comments
U O
X X. X X
_x
X X X
CHAIN OF CUSTODY
Relu)tuisj
Date
fi' /
7y
Cooler ID No.:
Time
Received By:
Fed Ex
Q
Cooler Temp. (C}: Date Time
n, 1ot POT)
PROJECT REQUIREMENTS
Results Deadline:
Laboratory Report Options: Sample Results Only Add Case Narrative Add Quality Control Summary Add Calibration Summary Add Raw Data Other:
Sample Lot#:
Sample No.
Analysis
`- i i
tL A "
L I L -
STL Chicago Internal Sample Custody Transfer Record
Client: G j c
Relinquished by: n
Received by: 1 r.
0^
Date
Time
Comments
i-W'vi 'ijO -tW l'u
vt
CH1*22*11-0Q1/C-1/99
rpjsckl
Job Sample Receipt Checklist Report
Job Number.: 232679
Location.: 57222 Check List Number.: 1
Description.:
Customer Job ID.... :
Job Check List Date.: 12/10/2004
Project Number.: 20004391 Project Description.: Confidential Decatur - FC Investigation
Customer...... : Weston Solutions, Inc.
Contact.: Jai Kesari
Questiohs ?
(Y/N) Comments
V2
Date of the Report.. : 12/27/2004 Project Manager.... : row
Chain-of-Custody Present?....................... . Y
Were samples dropped off at or picked up by STL7 ,. N
Custody seal on shipping container?............. . Y
...If "yes", custody seal intact?............... . Y
Custody seals on sample containers?............. . N
...If "yes", custody seal intact?...............
Samples iced?................ ...... ........
Y
Temperature of cooler acceptable? <4 deg C +/- 2) . Y 3.3
Samples received intact (good condition)?....... . Y
Volatile samples acceptable? (no headspace).....
Correct containers used?........................ . Y
Adequate sample volume provided?................ . Y
Samples preserved correctly?.................... . Y
Samples received within holding-time?........... . Y
Agreement between COC and sampLe labels?........ . Y
Radioactivity at or below background levels?.... . Y
A Sample Discrepancy Report (SDR) was needed?___ . N
If samples were shipped was there an air bill #?. . Y
Sample Custodian Signature/Date........ ......... . Y
Page 1
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CASE NARRATIVE
Client; Job #:
STL Chicago Wet Chemistry Case Narrative
Weston Solutions, lncT 232679
Date Rec'd: 12/10/04
1. This narrative covers the analysis o f the samples in the above Job # for TOC by the Lloyd Kahn Method.
The samples were analyzed for TOC in duplicate by furnace combustion and nondispersive infrared detection on a Dohrmann Phoenix 8000 TOC analyzer, after acidification to remove inorganic carbon, and drying. No correction was made, therefore, for moisture content.. The average o f the sample bums is reported.
2. The method-recommended holding time o f 2 weeks was met. Refer to the Laboratory Chronicle Page for dates of sampling, receipt, and analysis.
3. The TOC calibration curve and the initial and continuing verification standards and blanks met acceptance criteria.
4. The method blank was less than the reporting limit.
5. The LCSs were within acceptance limits.
6. The matrix QC in this analytical batch was done on a sample from Job #.
7. The first analysis of sample 232679-5 was not reported, but repeated using more sample weight. See the raw data.
-risi
..
Diane L, Harper
Wet Chemistry Section Manager
-- j j -n-%
Date
RAW DATA
*** RUN LOG
***
(V2 )
Total Organic Carbon [Soils) Method Code..; TOCS Batch Code...; 137288
Status...... : RVWD
User Name..... els
Batch Date...: 12/16/04 QC Code....... TOCS
Batch Time...: 1516
CaLe Code..... TOCS
3 3 /f
Location Code.*: 57222 Equipment Code.: T0C4 Import Code___ :
TEST CODE
TT TT TT T T TT TT T
O0O0000CCC I11
Cc C C C ccS ss CCc
23 4AAA 2A SSs
VVV
V 2A
234 2 2
SAMPLE: Grp PdS Sample ID
Dilution
TEST POS Date / Time
123 456 7 111222 7890 12
1 1 __ ICAL_104LSTTC1_
0
12
___1CV_I04LSTTC2_
12/16/04 0813 0
13
__ MB__
12/16/04 0820 0
14
LCS IO0FSTLK5 3
12/16/04 0839 0
15
__ LCD_IO0FSTLK3_3
12/16/04 0849 0
16
232577J 1_S__
12/16/04 0914
17 18
232577J1_SJIS_I04LSTTC2_6 2325 77_11_S_MSDJ04LSTTC2_6
12/16/04 0938 12/16/04 0949
1
19
232677_7_S__
12/16/04 1007
0
1 10 232677_8_S__
12/16/04 1042
0
1 11 232677_9J__
12/16/04 1056
0
1 12 232677J O S ___
12/16/04 1119
0
1 13 232677_11_S__ r
12/16/04 1134
0
1 14 1 15
232677J 2J __ 232677_13_S___
12/16/04 1157
0
....
12/16/04 1218
0
1 16 __ CCV_I04LSTTC2_
12/16/04 1246 0
1 17
CCS
12/16/04 1254 0
1 18 232677_14_S__
12/16/04 1329
0
1 19 2 3 2 6 7 9 J J ___
12/16/04 1349
0
1 20 232679_2_S___
12/16/04 1412
0
1 21 232679_3_S__
12/16/04 1428
0
1 22 232679J J ___
12/16/04 1442
0
1 23 232679_5_S___
12/16/04 1505
0
1 24 232679_6_S__
12/16/04 1517
0
1 25 232679 7 S
12/16/04 1533
0
1 26 232679_8_S___
12/16/04 1547
0
1 27 232746 9 $
12/16/04 1602
0
1 28 ___ccv_iQ 4Lsrrc2_
12/16/04 1624 0
Page 1
--
=35
*** RUN LOG
#**
CV2 ) 12/20/04 13:35
Page 2
*** OC $uTvriBry
*+*
<V2 >
Total Organic Carbon (Soils)
Method Code..: TOCS Batch Code.,.: 137286
Status..... .: RVUD
Grp Srnp Sample ID
12
1CV 104LSTTC2
1 3 ___MB_
1 4 __ LCS_I00FSTLK3_3
15
___ LCD_I00FSTIK3_3
1 16 ___ CCV_I04LSTTC2_
1 17 __ C CB_
1 2S ___ CCV_I04LSTTC2_
1 29 ___ CCB__
Batch Date__ : 12/16/04 Batch Time...: 1516
User Name....: els
QC Code....... : TOCS Cate Code..... : TOCS
Location Code,,; 57222
Pos Test Result
Known
Original
1 TDC
1990.99
2000
1 TOC 12.09
1 TOC
4550,SB
4780
12.89
1 TOC
4690.69
4700
12.89
1 TOC
2054.40
2000
1 TOC `1.84
1 TOC
2000.34
2000
1 TOC
-2.40
Report Date: 12/20/04 13:35
Equipment Code.: TOC4 Import Code___ :
Alternate QC Res 100
F QC Res
F
4550.88
95 102 103
7
100
Page 1
4
* * * RAU TEST DATA
***
CV2 )
TotaL Organic Carbon (Soils)
Method Code.,: TOCS Batch Code...: 137288 Status.,.,.,,: RVWD
Batch Date...: 12/16/04 Batch Time.,.: 1516
User Rame.... : cls
SAMPLE;
rp Pos Sample ID
11
1CAL I4LSTTC1
12
1CV 104LSTTC2
13
KB
14
LCS I0FSTLK3 3
15
LCD I00FSTLK3 3
1 6 232577 11 S
1 7 232577 11 S MS IQ4LSTTC2 6
1 8 232577 11 S MSD 104LSTTC2 6-
1 9 232677 7 S
1 10 232677 8 S
1 11 232677 9 S
1 12 232677 10 S
1 13 232677 11 S
1 14 232677 12 S
1 15 232677 13 S
1 16
CCV I04LSTTC2
1 17
cce
1 18 232677 14 S
1 19 232679 1 S
1 20 232679 2 $
1 21 232679 3 S
1 22 232679 4 S
1 23 232679 5 S
1 24 232679 6 S
1 25 232679 7 S
1 26 232679 S
1 27 232746 9 S
1 28
CCV ID4LSTTC2
1 29
CCB
QC Code..
TOCS
Cale Code..... TOCS
Location Code.. 57222
Dilution
TOC mg/Kg
T0C2 mg/Kg
Report Date: 12/20/04 13:35
Equipment Code.: T0C4 Import Code___ :
TDC3 mg/Kg
T0C4 mg/Kg
T0CAV2 mg/Kg
1990.99 12.89
4550.88 4890.69
1379.46
28S2.69
3007.39 9275.47
2939.25 1794.66
1199.75 5027.33
3665.60
2640.71 2054.40
-1.84 1440.55
1589.83
7100.85 1054.59
1021.71
401.47
402.46
631.27 631,42
133019.80
2000.34
-2.40
1230.22
4707.10 2675.00 1544.31 638.83 5665.06 3168.78 2087.93
1501.31 2008.47 7999.75 614.39 888.92 348.14 336.02 613.67 452.44 145772.70
1304.84 2882.69 3007.39 6991.28 2807.12 1669.48 919.29 5346,19 3417.19 2364.32
1470.93 1799.15 7550.3 834.49 955.32 374.81 369.24 622.47 541.93 139396.25
Page 1
*< 3
*** RAW TEST DATA
***
<VZ )
Total Organic Carbon (Soils)
Method Code ..: TOCS Batch Code. 137288 Status..... RVWD
Batch Date.. : 12/16/04 Batch Time.. : 1516
User Name__ : els
SAMPLE:
Grp Pds Sample ID
11
ICAL I04LSTTC1
12
ICV I04LSTTC2
13
MB
14
LCS I00FSTUC3 3
15
LCD I00FSTLK3 3
1 6 232577 11 S
1 7 232577 11 S MS I04LSTTC2 6
1 8 232577 11 S MSD I04LSTTC2 6-
1 9 232677 7 S
1 10 232677 8 S
1 11 232677 9 S
1 12 232677 10 S
1 13 232677 11 S
1 14 232677 12 S
1 15 232677 13 S
1 16
CCV I04LSTTC2
1 17
CCS
1 18 232677 14 S
1 19 232679 1 S
1 20 232679 2 S
1 21 232679 3 S
1 22 232679 4 S
1 23 232679 5 S
1 24 232679 6 S
1 25 232679 7 S
1 26 232679 8 S
1 27 232746 9 S
1 28
CCV I041STTC2
1 29
CCB
QC Code....... 1 TQCS Calc Code..... : TOCS Location Code*.: 57222
Dilution
T0CAV3 mg/Kg
TDCAV4 mg/Kg
Report Date: 12/20/04 13:35
Equipment Code.; TOC4 Import Code___ :
TOCRl ug
TOCR2 ug
T0CR3 ug
99.5494 2.0625
116.5025
146,2316 95.8727
174.9791
190.0672 213.3358 85.2383 58.5059
55.1886
278.0111
140.7590 108.2690
102.7198 -0.2950
60.7911 80.2864 291.8449
43.5546
47.1010 36.6142 33.1221 52.9636
55.8174
133.0198
100.0171 -0.3848
77.5036
118.6188 104.3250 60.8457 36.2218 262.2923 109.0061 74.9566
75.2155 118.2986 319.1901 35.5731 39.8237 32.3418 26.0417 46.7615 41.6243 145.7727
Page 2
*** RAU TEST DATA
***
(V2 )
Total Organic Carbon (Soils)
Method Code..: TOCS Batch C o d e , , , : 137288 Status.......: RVWD
Batch Date...: 12/16/04 Batch Time :1516
User Name :cls
SAMPLE:
Grp Pos Sample ID
11
ICAL I04LSTTC1
12
1CV I04LSTTC2
13
MB
14
LCS IO0FSTLK3 3
15
LCD IQ0FSTLK3 3
1 6 232577 11 S
1 7 232577 11 S HS I04LSTTC2 6
1 8 2325/7 11 S MSD I04LSTTC2 6-
1 9 232677 7 S
1 10 232677 8 S
1 11 232677 9 S
1 12 232677 10 S
1 13 232677 11 S
1 14 232677 12 S
1 15 232677 13 S
1 16
CCV I04LSTTC2
1 17
CCB
1 18 232677 14 S
1 19 232679 1 S
1 20 232679 2 S
1 21 232679 3 S
1 22 232679 4 S
1 23 232679 5 S
1 24 232679 6 S
1 25 232679 7 S
1 26 232679 8 S
1 27 232746 9 S
1 28
CCV IQ4LSTTC2
1 29
CCB
QC Code.-......: TOCS Cale Code......: TOCS
Location Code..: 57222
Dilution
T0CR4 ug
WT1 g
Report Date: 12/20/04 13:35
Equipment coda.: TQC4 Import Code.___:
UT2 UT3 UT4 ggg
0.05 0.16
0.0256 0.0299
0.0695
0.0607 0.0632
0.0230 0.0290
0.0326 0,0460 0.0553
0.0384 0.0410
0.05 0.16
0.0422 0.0505
0.0411
0.0413
0.0461 0.0912
0.0823 0.0839
0.0884
0.0010 0.05
0.16
0.0630
0.0252 0.0390 0.0394 0.0567 0.0463 0.0344 0.0359
0.0501 0.0589 0.0399 0.0579 0.0448 0.0929 0.0775 0.0762 0.0920 0.0010
Page 3
.I
7
*** RAW TEST DATA
(V2 )
Total Organic Carbon (Soils)
Method Code..: TOCS Batch Code...: 137288 Status...... : RVWD
Batch Date...: 12/16/04 Batch Time.,.: 1516
User Name____: d s
SAMPLE:
Grp Pos Sample ID
11
ICAL I04LSTTC1
12
ICV IQ4LSTTC2
13
MB
14
LCS I00FSTLK3 3
15
LCD I00FSTLK3 3
1 6 232577 11 S
1 7 232577~11 S MS IQ4LSTTC2 6
1 8 232577 11 S MSD IQ4LSTTC2 6
1 9 232677 7 S
1 10 232677 8 S
1 11 232677 9 S
1 12 232677 10 S
1 13 232677 11 S
1 14 232677^12 S
1 15 232677J3 S__
1 16
CCV~I04LSTTC2
1 17
CCB
1 18 232677 14 S
1 19 232679 1 S
1 20 232679 2 S
1 21 232679 3 S
1 22 232679 4 S
1 23 232679 5 S
1 24 232679 6^S
1 25 232679 7^S
1 26 232679 8 S
1 27 232746 9 S
1 28 __ CCVJ4LSTTC2
1 29
c c b "~
QC Code.**.____: TOCS Calc Code.....TOCS
Location Code..: 57222
Dilution
DIFAC N/A
TCS mg/Kg
Report Date: 12/20/04 13:35
Equipment Code.: TOC4 import Code____:
TCS2 mg/Kg
TCSAV2 mg/Kg
TICS mg/Kg
Page 4
AI S
Calibration Report Print Date/Time: 2004/12/20 8:20:27
Cal. Curve ID:
SOILCURVE
Created:
12/13/2004 13:36
Calibration Factor (m): 9.841 e+04
Y Intercept (b): -250134
r-squared:
0.99935
Standard ID Y X Expected Measured Message Date &
Raw Data ug C ug C
Time
0 ugram C
-8891 0.000 2.451 No Sample Det 12/13/2004 11:24
10ugramC
911065 10.000 11.800
12/13/2004 11:42
20 ugram C 1653385 20.000 21375
12/13/2004 11:48
40 ugram C 3745719 40.000 40.605
12/13/2004 12:04
120 ugram C 11194916 120.000 116,302 Endpoint Time 12/13/2004 12:28
200 ugram C 18654032 200,000 192.099
12/13/2004 12:46
300 ugram C 29462156 300,000 301,928
12/13/2004 12:59
400 ugram C 39451668 400.000 403,439 Endpoint Time 12/13/200413:19
Multiple Analysis Report Print Data/Time. 2004/12/16 16:35:47
Sample ID
Result Std. Dev. RSD Mode ALT
ICV
99.5494
TC
ICB-MB
2.0625
TC
LCS
116.5025
TC
LCD....................... .......146.2316............. ...TC ..
232572-11
22.8143
TC
232572-11
95.8727
TC
232572-11.........................77.5036...
.......... TC
232572-11 ms
174.9791
TC
232572-11msd
190.0672
TC
232677-7..........................213.3368... .......... TC
232677-7
118.6188
TC
232677-8
85.2383
TC
232677-8..........................104.3250... .......... TC
232677-9
58.5059
TC
232677-9
60.8457
TC
232677-10.........................55.1886...
.......... TC
232677-10
36.2218
TC
232677-11
278.0111
TC
232677-11............. ...........262.2923... .......... TC
232677-12
140.7590
TC
232677-12
109.0061
TC
232677-13............. ...........108.2690... .......... TC
232677-13
74.9566
TC
CCV
102.7198
TC
CCB....................... ....... -0.2950............. ...TC ..
232677-14
60.7911
TC
232677-14
75.2155
TC
232677-15............. ...........80.2864...
.......... TC
232677-15
118.2986
TC
232679-2
291.8449
TC
232679-2............... .......... 319.1901... .......... TC
232679-3
43.5546
TC
232679-3
35.5731
TC
232679-4............... .......... 47.1010...
..........TC .
232679-4
39.8237
TC
232679-5
15.6963
TC
232679-5............... ..........36.6142...
..........TC .
232679-5
32.3418
TC
232679-6
33.1221
TC
232679-6.............. .......... 26.0417...
..........TC .
232679-7
52.9636
TC
232679-7
46.7615
TC
232679-8............... .......... 55.8179...
..........TC .
232679-8
41.6243
TC
232746-9
133.0198
TC
232746-9............... ..........145.7727... .......... TC
CCV
100.0171
TC
CCB
-0.3848
TC
A
Detailed Analysis Report Print Date/Time: 2004/12/1616:35:53
Sample ID: ICV Method: boat CaL Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12160805
_
/
Timestamp: 12/16/2004 08:1&
Sample Type: Cal. Verificakign^
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 99.5494 99.5494 9546364 1.160 2.159 316
Sample ID: ICB-MB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC
_
Filename: 12160814
^
Timestamp: 12/16/2004 08:20
Sample Type: Cal. Verification^"
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 2.0625 2.0625 -47164 1.656 1.249 120
Last Message: Out oTCali^ration q
^ ^ Jyy (c
Sample ID: LCS Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12160833
Timestamp: 12/16/2064 08:39 Sample Type: Sample V _ __
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 116.5025 116.5025 11490585
1.744 2.743 275
Sample ID: LCD Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12160843
Timestamp: 12/16/20 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 146.2316 146.2316 14416174
1.900 2.898 287
Sample ID: 232 Method: boat Cal. Curve: SOILCU VE Operator ID: CAROL
Mode: TC Filename: 12160859
Timestamp: 12/16/2004 09:04 Sample Type: Sample
Rep # ppm C ug C aw Data Beginning Ending Integration seline Baseline Time
V-
(ii X
Sample ID: 23267M \ Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12161158
Timestamp: 12/16/2004 12:03 Sample Type: Sample
Rep# ppm C ug C Rawvata Beginning Ending Integration Baseline Baseline Time
1 109.0061 109.0061 10752874 2.016 3.013 277
Sample ID: 232677-13 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
)de: TC
Filename: 12161212
Tirtiestamp: 12/16/2004 12:18
Sampre Type: Sample
....x
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline VTime
1 108.2690 108.2690 10680344 1.682 \ 2.680 293
Sample ID: 232677-13 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12161221
Timestamp: 12/16/2004 12:27 Sample Type: Samp)
Rep # ppm C ug C Raw Data Beginning Ending ^Integration Baseline Baseline Time
1 74.9566 74.9566 7402125 2.298 3.295 302
Sample ID: CCV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC
^
Filename: 12161240
Timestamp: 12/16/20(^412:46 i
Sample Type: Cal. V erification ^/
Rep# ppmC ugC Raw Data Beginning Ending Integration Baseline Baseline Time
1 102.7198 102.7196 9858350 1.368 2.368 323
Sample ID: CCB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC
Filename: 12161252
/
Timestamp: 12/16/2004 12:54
Sample Type: Sample l ^
Rep# ppmC ugC Raw Data Beginning Ending Integration
Baseline Baseline Time
1 -0.2950 -0.2950 -3264
1.535 1.501 120
Last Message: No Sample Detected
"\
Sample ID: 232677-14 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC
Filename: 12161325
/
Timestamp: 12/16/200413:29
Sample Type: Sample y
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 60.7911 607911 6008115 4.037 6.031 198
Sample ID: 232677-14 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12161337
Timestamp: 12/16/200413:43 Sample Type: Sample
Rep# ppmC ugC Raw Data Beginning Ending Integration Baseline Baseline Time
1 75.2155 75.2155 7427599 1.603 2.602 294
Sample ID: 2 3 2 6 7 7 u Method: boat Cal. Curve: SOILCURVE: Operator ID: CAROL
Mode: TC
Filename: 12161344
X
Timestamp: 12/16/2004 13:49
Sample Type: Sample y
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 80.2864 80.2864 7926619 2.227 3.226 249
Sample ID: 2 3 2 6 7 7 ^ ,0 ''
Method: boat
^
Cal. Curve: SOILCURVE
Operator ID: CAROL
Mode: TC Filename: 12161358
Timestamp: 12/16/2004 14:03 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 118.2986 118.2986 11667337 1.529 2.529 310
Sample ID: 232679-2 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC
Filename: 12161406
X"
Timestamp: 12/16/2004 14:12
Sample Type: Sample y ___ _
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 291.8449 291.8449 28745744 2.108 3.106 324
;]S?==E==^
Sample ID; 232679-2 Method; boat Cal, Curve; SOILCURVE Operator ID: CAROL
Mode; TC Filename: 12161416
Timestamp: 12/16/2004 14:23 Sample Type: Sample
Rep# ppmC ugC Raw Data Beginning Ending Integration
Baseline Baseline Time
1 319.1901 319,1901 31436744
1.978 2.977 353
sample ID: 232679-3 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12161423
Timestamp: 12/16/20p414:28 Sample Type: Sample V
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 43.5546 43.5546 4311899 2.399 3.398 242
Sample ID: 232679-3 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12161430
Timestamp: 12/16/2004 14:35 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 35.5731 35.5731 3526451
3.877 4.874 228
Sample ID: 23267^ - {
79-4 Mode: Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
TC Filename: 12161437 Timestamp: 12/16/2004 14:42 Sample Type: Sample \
>
Rep# ppmC ugC Raw Data Beginning Ending Integration Baseline Baseline Time
1 47,1010 47.1010 4660893 2.663 3.663 262
Sample ID: 232679-4 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12161443
Timestamp: 12/16/2004 14:47 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 39.8237 39.8237 3944754 2.827 3.826 228
:S5=5!S
sample 10: 232679-5 \
Method: boat
\
Cal, Curve: SOILCURVE
Operator ID: CAROL
Mode: TC r Filename: 12161453
^ Timestamp: 12/16/2004 14:57 Sample Type: Sample
Rep # ppm C ug C RaurData Beginning Ending Integration Baseline Baseline Time
1 15.6963 15.6963 1570406 2.965 3.960 185
Sample ID: 232679-5 Method: boat Cal. Curve: SOILCURVE Operator ID; CAROL
Mode: TC Filename: 12161500
Timestamp: 12/16/200*15:05 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration
Baseline Baseline Time
1 36.6142 36.6142 3628912
1.848 2.847 264
Sample ID: 232679-5 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12161506
Timestamp: 12/16/200415:10 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 32.3418 32.3418 3208471 2.106 3.104 228
Sample ID: 232679-6 Method: boat
Cal, Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12161512
Timestamp: 12/16/2604 15:17 Sample Type: Sample V.
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 33.1221 33.1221 3285255 1.990 2.989 230
Sample ID: 232679-6 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12161622
Timestamp: 12/16/2004 15:26 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 26.0417 26.0417 2688487 2.364 3.360 206
Sample ID: 232679-7 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC
Filename: 12161628
Timestamp: 12/16/200415:
Sample Type: Semple \ /
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 52.9636 52.9636 5237827 1.988 2.986 255
Sample ID: 232679-7 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12161535
Timestamp: 12/16/200415:40 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 46.7615 467615 4627489 1.940 2.939 259
Sample ID: 232679-8 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12161542
Timestamp: 12/16/2 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 55.8179 55.8179 5518714 1.910 2.906 268
Sample ID: 232679-8 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12161550
Timestamp: 12/16/2004 15:54 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 41.6243 41.6243 4121944 1.903 2.903 240
Sample ID: 232746-9 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC
Filename: 12161556
X
Timestamp: 12/16/2004 16:02
Sample Type: Sample V.
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 133.0198 133.0198 13116030 176&, 2764 286
Sample ID; 232746-9 Method; boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12161603 \ Timestamp: 12/16/2004 16:09 \ Sample Type: Sample
Rep# ppmC ug C Raw Data beginning Ending Integration Baseline BaseKne Time
1 145.7727 145.7727 14371019 2.Q59 3.056 346
Sample ID: CCV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename: 12161618
f
Timestamp: 12/16/2004'16:24
Sample Type: Cal. Verification .
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 100.0171 100.0171 9592382 1.422 2.421 291
Sample ID: CCB Method: boat CaL Curve: SOILCURVE Operator ID: CAROL
Mode: TC Filename; 12161626
Timestamp: 12/16/20 Sample Type: Sample
Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time
1 -0.3848 -0.3848 -12100 1.660 1.514 120
Last Message: No Sample Detected
STL Chicago
Page No;,
107
TOC in Soils
Book No. -57V 7
Method: Lloyd Kahn
Instrument Phoenix 8000 fTQC4i
LabNet Batch: / 3 47^--
folculatlone: TOC (mg/kg) =* ug C / grams sample
Date of Standard Curve:
Book # 4?79 7 Page # f d f
MS, MSD Known Cone, (mg/kg) * 100 ug C / grama sample MS, MSD Observed (mg/kg) * ug C / grams sample
,
^ / \ftQ J 2 --
MS, MSD Rec. fobeerved ma/ka - avo, sample result fmo/koll x 100
known concentration in mg/kg
standard Traceability: (Note: Working Standards are prepared daily from the noted Stock Solutions.)
Stock I (Curve) r ^ i r ? c ( _ Stock II (ICV/CCV) J-OYS~fTC_^
LOS Source ID 7 ~ ^ T 7^ '> LCS True Value V r /Af Acceptance Range
________
Sample ID: id ./
Sample Weight (g) ____ g e
<y . >
77, < W
zi? 7 . r
Comments:
b?S '
ft-c s t,
/ / 0. x n r
2 .3 7 5 7 2 - _ / o __
/ / J b /V - ^ 2,
- 11
p .O Q ,^
7 C 727
- /< ^ ! )h
v ii O -S X C ll- 7
-- 1
~7 -t - to
n .o io .C c l
< 7 . 2 ' /3 7 . 6 ' 2-3 2 <7 , (2 2-'C 7 O O 2 90
O. O
. 0 7 2- 6, 0 3 ? Y 7 . c Y C? 0 O O S' 7
1 1 , 1C3 C / _
n^
/ 9 OE- 7 ? i'? 5
ft? . M r . .
( t o w S ? '> 3/1 7 y*- 7 \7 2 ,u r y / o u .
v: ^
< rf. 23 r J
>V. V2X - 0
2 Y , S7 T ?
Y~f, / r t O 0 ^ , 2 2 /P
l _ _ - '/ _ O . c k ^ 7
P -//
7 . <7
sr, 0 3 f-y
a n Y .O tt J G tlfZ l /W .^ & r r ir 's
J ^ r z - . o ' } y y
V . Z T (7
V
/77 (oe, ( / O P. 2- t f ^ 1
Prep Analyst Analyst
Reviewed by:.
hu^.
r
VJ. "c^/.
Date: Data: Date:
r'*f
/ . ' //<
^/YnY
8
CHf*23*12*098/8 -05/01
STL Chicago
Page No
108
TOC in Soils
Book No,;.
Method: Lloyd Kahn
Instrument Phoenix 8000 (TOC4
LabNet Batch: / 3 7
Calculation:
Date of Standard Curve: ^
:
TOC (mg/kg) * ug C / grams sample
Book #
MS, MSD Known Cona (mg/kg) 100 ug C / grams sample
yf
Page #
MS, MSD Observed (mg/kg) = ug C / grams sample
'^
MS, MSD Rec. fobserved mg/kg - avo. sample result (mq/Ro)l x 1J
known concentration in mi
Standard Traceabllttv:
Stock I (Curve)
ICS Source ID
Sample ID:
Sample Weight (g)
ug C
n r t i i ' / y .o 3rf C.W , r 5.
M m r? '
^ 7 ~ /t/ <7 0 , O' \
--/vs 7 ? . r e r
o. 7?//
7n i/r r ft? 29^9-
<3. r If?. 2if?C
<?,<? Y f( - a (T,c $ T f 3 /?. /?cy
I -^ ___/ - 3 ?. O 0 7 ^
- y P O <YO ( r?. /<#^
I
<?. o Y Y ^
O---(V7 T7e
. P03? - // ^f*/?` ^
I - V ^ /}?/*^ - 7 7, o ^ a . ?
3y 3 ^ f 32.3W?
/7r
- 0 r>.n o
37 /2 a /
a,w7 ? '7, 76-X
___ -*Vy
-
7y
-V-
0. c) ~i 0 1 .
-0-0 y Y
7776 f T
) 0 - 0 T l-o '/7, V2V7
-
Comments;
Prep Analyst:. w /? ) Analyst:. Reviewed by:. ( lb ,*1 ^
'O dui
M
Date: D ate:. Date:
/3 CHI-22>12-C4tsm-ovoi
STL Chicago TOC in Soils
Page No.;
109
Book No.; *->7 Y Z
Method: Lloyd Kahn
Instrument Phoenix 8000 (T0C4j
LabNet Batch: / 3
galculiflpne:
Date of Standard Curve;__ ------------------ *
TOC(mg/kg) = ug C / grams sample
Book#
MS, MSD Known Cone, (mg/kg) * 100 ug C / grama sample
MS, MSD Observed (mg/kg) * ug C / grams sample
MS. MSD Rec. = fobserved mg/kg - avo. sample result (ma/kaj| ^rlQQ
known concentration in mg/kg
^
standard Traceability; (Note: Worldrt^Standards are prepared daily from the noted Stock Solutions.)
Stock I (Curv*)________ .
Stock II (ICV/CCV)
l_CS Source ID
LCS True Value
Acceptance Range
m Sample ID:
OD U
" WT? \ X^ _
Sample Weight (g) L. _UflC_ ...
O ,00(0
w lf iF
_ a id 0 .n <
m_________
i _________________
m r n ? z)
/D. n n r
-
f
'
r~ ---
X x
,x
'
x ^X__________________________________
X
- -- X ^
X________________________________
\\
X
X
_
.x
X X
Comments:
Prep Analyst:
Analyst
Reviewed by:
----- -------
\
: / J - //f v /c/ 1*? kiqc DDaattee: / - V ry - 7 --
Date: t?7,?W.LL
