Document La7q8r9yXzoo77rRV6oYOMRz

Fotm Approved Bvdost Bufiiu No* 44-R1387 Approval tapir** April 30* 1871 U.S. DEPARTMENT OF LABOR t "r> rp f v ^ - * o t v* ` *> WAGE AND LABOR STANDARDS ADMINISTRATION Bureau of Labor Standards MATERIAL SAFETY DATA SHEET Form No. L$8-O0S*4 May 1969 SECTION 1 MANUFACTURER'S NAME PPG Industries, Inc. emergency telephone no. (216) 753-4561 ADDRESS {Nmmter, Sttttt, City, Suit, and ZIP Cod*) ,0n Gateway Center, Pittsburgh, Pa. 15222 CHEMICAL NAME AND SYNONYMS TRADE NAME AND SYNONYMS di-normal propyl peroxydicarbonate (Normal propy L percarbonate) RV CHEMICAL FAMILY _. . . Organic Peroxide FORMULA p ti rt C8H146 PAINTS, PRESERVATIVES. A SOLVENTS PIGMENTS CATALYST VEHICLE SOLVENTS ADDITIVES OTHERS A TLV % (Units) ALLOYS AND METALLIC COATINGS BASE METAL 100 Listei ALLOYS METALLIC COATINGS FILLER METAL PLUS COATING OR CORE FLUX OTHERS HAZARDOUS MIXTURES OP OTHER LIQUIDS, SOLIDS, OR GASES % TLV (Unit*) TLV . % (ORIM) . vv boiling point i*f.) Decomposes on heat .ng 1 VAPOR PRESSURE lTM> He.) NA 1 VAPOR DENSITY IAIR=1> NA SOLUBILITY IN WATER ^ rligible SPECIFIC GRAVITY IH20=1) PERCENT VOLATILE BY VOLUME (%l EVAPORATION RATE APPEARANCE AND OOOR Clear liquid, disagreeable odor VWHlUPII 1.1161 1 NA | NA I FLASH POINT (Method u.*dl NA FLAMMABLE LIMITS L*l EXTINGUISHING MEDIA Generates own oxygen, difficult to extinguish. SPECIAL FIRE FIGHTING PROCEDURREES Protect surrounding areas by cooling with water. U*l Let fire run its course. UNUSUAL FIRE AND EXPLOSION HOAZnARcDfSergos autoacc lerative decomposition and mav self icmite on decomposition. Confinement may lead to a detonation. ..w, sm ...... SL 074537 THRESHOLD LIMIT VALUE Not established effects OF OVEREXPOSURE _______________________Inhalation overexposure is not likely. NPP is extremely i4rritating to ^tVh<ek fstlrkRin a>Hn|Rd BetyfAefsl . EMERGENCY AND FIRST AID PROCEDURES I Provide adequate ventilation. In case of contact, immediately flush eyes with water for 15 minutes. Call a physician. Flush skin with large amounts of water. : stability UNSTABLE X CONDITIONS TO AVOID ^ rafri9arated at all tim6S. STABLE Avoid cross contamination. INCOMPATABILITY /Hot*rials to avoid) Accelerators, amines, caustic, acids HAZARDOUS DECOMPOSITION PRODUCTS Most all decomposition products are flaimnable. HAZARDOUS POLYMERIZATION MAY OCCUR WILL NOT OCCUR CONDITIONS TO AVOID Excess concentration in monomer mav X cause rapid polymerizations. respiratory protection fSpteifr typt) provide vantilation. j ventilation LOCAL EXHAUST Provide adequate ventilation. MECHANICAL (Gtntral) PROTECTIVE GLOVES Rubber gloves OTHER PROTECTIVE EQUIPMENT EYE PROTECTION SPECIAL other Splash goggles k fi Q PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Store at 0F or below. See manufacturer's literature for description of storage precautions. OTHER PRECAUTIONS Form Approved Oudgot fturoou No* 44**1387 Approval Enpiraft April 30* 1971 U.S. DEPARTMENT OF LABOR ^ WAGE AND LABOR STANDARDS ADMINISTRATION Bureau of Labor Standard* MATERIAL SAFETY DATA SHEET 'T Form No, lB*00S*4 May 1969 MANUFACTURER'S name PPG ADDRESS (Number, Street, City, State, *#iW ZIP Cede) SECTION 1 EMERGENCY TELEPHONE NO. (216) 753-4561 CHEMICAL NAME AND SYNONYMS 8556 Di-n-propyl peroxydicarbonate in MCH TRADE NAME AND SYNONYMS CHEMICAL FAMILYO- rgan.ic _Per_o__x_i,d,e FORMULA - n 4U6 w PAINTS, PRESERVATIVE!, A SOLVENTS PIGMENTS CATALYST VEHICLE SOLVENTS AOOITIVES OTHERS % TLV (Unix) ALLOTS AND METALLIC COATINGS BASE METAL ALLOYS METALLIC COATINGS FILLER METAL PLUS COATING OR CORE FLUX OTHERS HAZARDOUS MIXTURES OP OTHER LIQUIDS, SOLIDS, OR CASES di-n-propyl peroxydicarbonate methyl cyclohexane (ppm) TLV % (Unit*) TLV % (Unit*) 8? NA _ 1? 500 HgOILING POINT CF.) Decompose3 Qn fc^t SPECIFIC GRAVITY (H20=l| VAPOR PRESSURE Iwn Hs.| VAPOR DENSITY IAIR=II NA t%>PERCENT VOLATILE by volume (aecoinposes)\ NA 1 _EVAPORATION RA=T1E1 SOLUSILITY IN WATER Megligibl s appearance and odor dear liquid 1.0S2 1 NA NA FLAA!SH POINT (M(Hod UMdl re (0PP5D Micro Test on 75% NPP) EXTINGUISHING MEDIA I FLAMMAJLiE LIMITS | Li Ifetbyl cyclohexane I--TTT Utl special fire fighting procedures Don't fight a peroxydicarbonate fire. It will burn out quickly. T.imlt fire by water spray from a safe distance. Wertte^^ecoTOQaU^on Releases gases which spray flammable and vapor into the air where they mix with oxygen and burn very vigorous^. SL 074539  a .f. r 4 'i ^esVa^sfeghi- solvent methyl cyclohexane TLV=5QO ppm, NFP has very lew vapor prfssm- ^tsof overexposure lDb0=^.6 g/kg, non-toxic. Extremely Irritating to the eye. Extremely irritating to the skin. Solvent causes narcosis. EMERGENCY AND FIRST AID PROCEDURES Skin contact: flush with water, clean with soap and water and then with alcohol. Eye contact: flush with water for at least 15 minutes, call a physician Swallowing: do not induce . '-I l HUffTU1 ' L\.- Tl'r* rrr^' * V' - ' STABILITY UNSTABLE vomiting, consult a physician immediately -I - 'I' 1 - -"V J -JTF > i+r X CONDITIONS TO AVOID Ref^e^ at _l8-Q (0"F) STABLE Contamination INCOMPATABILITY (Materiali to avoid) Accelerators, amines, acids, alkaline materials HAZARDOUS DECOMPOSITION PRODUCTS Some decomposition products flammable HAZARDOUS POLYMERIZATION MAY OCCUR WILL NOT OCCUR CONDITIONS TO AVOID Contact with X polymerizable materials (monomers) Product is a polymerization initiator sot STEPS TO SE TAKEN IN CASE MATERIAL 4$ RELEASED OR SPILLED Small snill: Flood with water and wash up with soap and water. |.Alternate method: Cover with sand and clean up. Spread solid with adsorbed peroxide in a safe disposal area immediately._______________ | ^SSi^ou^^^es: Add waste continuously to $% alcoholic potassium hydroxide. Alternate Procedure: Scatter material on ground in a well ventilated disposal area and allow to decompose gradually. r:?T. m--.muanai1 ::*a- RESPIRATORY PROTECTION (Sptelfy typo) Protect against mists and vapors ventilation 'f'rovude adequate ventilation SPECIAL MECHANICAL (General) other ___ protective gloves Rubber) p7C EYE PROTECTION Splash Goggles other protective eouipment j^ber Gloves, Plastic Aprons ...... t.'.t? StorePRECAUTIONS TO BE TAKEN IN HANDLING AND STORING at -18C (0aF) or below. Check storage |temperatures at least once a shift. See manufacturer's literature. OTHER PRECAUTIONS ,Auxiliary refrigeration can be provided by dry ice placed above the peroxydicarbonate. SL 074540