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| AR226-1399 ; | . . :: " ARy R&6- 1399 ti T. A. Foster August 29, 1984 PERSONAL AND CONFIDENTIAL T0: J. A. SCHMID PhRb FROM: J. Fa hh SUMMARY OF C-8 IN WATER SAMPLING PROGRAM This letter summarizes the sampling procedure and the results of the pro- gram to obtain C-8 concentration data for drinking the plant. The original set of samples were taken water down river `from on March 15, 1984. A second set of samples was taken at selected locations on June 4, 1984. The samples were taken by going to gas stations or small grocery stores in communities down stream of the plant and asking to have a plastic jug filled with drinking water. The sample obtained was then transferred to 8 oz. glass bottles. Two bottles were obtained. One bottle was analysis and the second was used as a retainer for future use if used for needed. Tporocfendsuurrea. that the samples were not being contaminated in the sampling Samples were also obtained up river to check for a background or blank and mTohdei ofriicgaitniaoln polfanthweasprtoocedhuarvee tusheed satmopldeesteramnianleyzeC-d8 heirne aiorn. plaTnot gebyt asensitthievitryivberelofwlotw,hea cosnacmeplnetrastiizoenofcal1c0u0lamltedwasforfrdeielzeutidorniedo.f C-T8heemsiusbssieoqnusentby analysis produced high and inconsistent blanks and data. When the analytical problems could not be resolved on plant, the samples were sent to the Experimental Station for analysis by a modification of the C-8 in blood procedure. The details of the analytical procedure are given in the attached letter from S. R. Laas to J. F. Doughty. The table below shows the locations of the samples taken on 3/15/84, the sample designation, and any comments. sai OESIGNATION COMMENTS Parkersburg Mashington Yorks Distribution Center of Parkersburg P Thoaskee.n from my w Tfaokuenntaifnr.on drinking 0 private well back 000189 from river. 5 - ~ EID079096 = . . J. A. SCHMID N - -2- AUGUST 29, 1984 supe Powell's Store Washington, WV DESIGNATION COMMENTS. WB Thought to represent ' Lubeck water. Mason's Village Mkt Lt Little Hocking, Ohio Oiler Exon Belleville, WW B Private well Reeds Country Store RD Reedsville, Ohio Randy's Amoco RH RRaovuetnesw6o8od, WW Gulf Station Racine, Ohio R Known to be city water. GPRuooliunftteStP2alteiaosnant, Ww PP Sohio Station sit bridge to WW allipolis, Ohio 6 First community to take water directly from the river. The table below shows the locations of the samples taken on 6/4/84, the sample designation, and any comments. SAMPLE ou Pont DESIGNATION TM TPoswheilnlg'tsonGseneWrWal Store Ws LLuibbeecckk, pWeWmzof1 ws MLaistotnl'esHoVciklilnagg,e MOkhito, L COMMENTS TTaokuenntaifnr.om drinking . In aide of Lubeck. iTnhde tahtetacThoecdatliaentteorf ttoheJ.saAm.pleSschaiindrferlaantiJo.n Ft.o Dtohueshptlyants;ummaNroitzeesthtahtetdhaeta original value for the Little Hocking sample should be changed to 0.6 in- = stead of 0.8. This change is made by hand in the letter attached. 3Ss JFRDeocaucghhmteyn:t0s072, - . 10079097 2 : 000190. PERSONAL AND CONFIDENTIAL - cc: T. A. Foster June 14,1986 T0: J. A. Schmid FROM: J. F Joushty UPDATE on C-8 IN WATER SAMPLES Trheeceantttadcathae.d taIblceonschlouudse tthhee Cn-e8w idnatwaatceornfdiartmatihneclourdiignignalthedamtoa.st a1.ndThteheDusaPmopnltingdatsaystsehmowsdoetshatnottheconttesatmindaoetse ntohte sseaemplCe-.8 up river 2c.onTtheentsaescontdheHafsihristn.gton sample had essentially the same C-8 33.% Tthhee Lubeck nWaeswhLiuntgetcokn ssaommppllee. shTohwsusestsheenHtaisahlilyngttohen ssaammepleconiscenftrroamtitohne Hater System as I suspect or at least the Lubeck system has the same concentration. d4.etTehcetioonrigliinmailt LfiotrtlteheHotceskti.ng Tshaemplceonwcaesntvreartyionclnosoew atpopetahres to be below the detection limit. Iisdoncendoetd.planThetocdooncaedndtirtaitoinoanls ascaemplvienrgy ulnolwesasndfuirnthmeyc jiundfgoermemnattion are not cause for concern. EID079098 - - 2 000191 . Co LocaTION \ C-8 IN VATER (3/15/84) and (6/4/88) D(IMSITLAESN)CE SIDE ppb C-Bk% PARKERSBURG DU PO(N3T/15/84) (6/4784) DICSETNTREIRBUOTFION PARKERSBURG HASHIN(G3T/O1N5/84) (6/2/84) LUBECK(674/88) LITTLE(3H/O15C/K8I4N)G (6/8788) PELLEVILLE RESDSVILLE RAVENSHOOD RACINE POINT PLEASANT 4 GALLIPOLIS 7.5 up stream w 0.5 up stream w 0.25 down streams HV 0.25 down stream. WV 0.25 down stream HV 3 down stream OHIO 12 dorm stream WW 14 down stream OHIO 29 dom stream WV 50 down stream OHIO 78 down stream WW 79 down stream OHIO up wxmD mo . 1.2I,%v] : 10 1.5. oe 339 ohyo ged 1m IE mw no up ju wall is back from the river Arfirst community to take water directly from the river stAvcaolnuveesrtobttoaiCn-8edvsfrFomcEoinpteenrtimeonrtiaglinaSltlaytiornepmourltteidplied by 1.5 to ND = below the detection limit of 0.6 as C-8 (0.4 as F) : 10019048.01 3 - - 000192 . PERFLUOROOCTANOATE (C8) IN WATER The results are given in the attached table. If you have any i =. : . EID079099 000193 oo. . metxe - RerfluorooctianoWaatteer Pral No. ai-3401 84-3402 84-3403 84-3404 84-3405 Designation L c ng F/g Water (opm) nde nde 04 ad. ad 84-3406 WB 81-3464 5 84-2465 w 81-3466 84-3067 wi 84-3468 ee 84-3979 w 84-3980 L 84-3981 w 84-3982 wn 0.8 ) nd. nd nd. nd nd. oard. ~ nde Ln - (2) nd. = none detected; detection Heit = 0.4 ppb. = 000194 Z I. ~ po