Document LKGdzrDJje6RK56egyXz5RB9g

. 1 J. m ' c. * * `w Shell MATERIAL SAFETY DATA SHEET MSDS NUMBER ^ 2,8l5`3 PAGE 1 24 HOUR EMERGENCY ASSISTANCE GENERAL MSDS ASSISTANCE SHELL: 713-473-9461 CHEMTREC: 800-424-9300 SHELL: 713-241-4819 C3 0 AACUTE HEALTH FIRE ' i REACTIVITY _ K LEAST - 0 HAZARD RATING HIGH 2 SLIGHT 1 EXTREME - 4 MODERATE * 2 /safe\ MAD OO" PRODUCT SAFETY MPOMUTON PASSHOM WWBWCTiMMTT lh For acute and chronic health effects refer to the discussion in 5eetion III SECTION I NAME KRATON(R) D1107 THERMOPLASTIC RUBBER PRODUCT ^ CHEMICAL a STYRENE-ISOPRENE-STYRENE BLOCK COPOLYMER NAME CHEMICAL k BLDCK COPOLYMER FAMILY r SHELL CODE k 46007 r 46798 SECTION 11-A NO. PRODUCT/INGREDIENT COMPOSITION P KRATON D1107 1 STYRENE-ISOPRENE-STYRENE BLOCK COPOLYMER 2 TALC* 3 ANTIOXIDANT/STABILIZER KRATON 01107-0 GRADE DOES NOT CONTAIN COMPONENT #2. CAS NUMBER PERCENT MIXTURE 25038-32-8 14807-96-6 100 >98 0-1.5 <1 SECTION II-B NO. ACUTE ORAL LD50 ACUTE TOXICITY DATA ACUTE DERMAL LD50 ACUTE INHALATION LC60 P NOT APPLICABLE BASED UPON DATA AVAILABLE TO SHELL. COMPONENTS 1 AND 3 IN THIS PRODUCT ARE NOT HAZARDOUS UNDER OSHA HAZARD COMMUNICATION (29 CFR 1910.1200). SECTION III HEALTH INFORMATION THE HEALTH EFFECTS NOTED BELOW ARE CONSISTENT WITH REQUIREMENTS UNDER THE OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200). EYE CONTACT BASED ON PRESENCE OF COMPONENT 2. PRODUCT MAY CAUSE MILD MECHANICAL IRRITATION TO THE EYES. SKIN CONTACT BASED ON PRESENCE OF COMPONENT 2, PRODUCT 1$ PRESUMED TO BE MINIMALLY IRRITATING TO THE 5KIN. INHALATION BASED .ON PRESENCE OF COMPONENT 2, PRODUCT MAY CAUSE MILD MECHANICAL IRRITATION TO THE NOSE. THROAT AND RESPIRATORY TRACT. INGESTION PRODUCT IS GENERALLY CONSIDERED TO HAVE A LOW ORDER OF ACUTE ORAL TOXICITY. DO 085455 CONFIDFNTIAL PRODUCT NAME: KRATON(R) D1107 THERMOPLASTIC RUBBER ---- MSDS PAGE *1 ^ < 2,815-3 ~ V* 2 SIGNS AND SYMPTOMS IRRITATION AS NOTED ABOVE. AGGRAVATED MEDICAL CONDITIONS PREEXISTING EYE. SKIN AND RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT. SECTION IV OCCUPATIONAL EXPOSURE LIMITS OSHA NO. PEL/TWA PEL/CEILING TLV/TWA ACGIH TLV/STEL P NONE ESTABLISHED 2 2 MG/M3* 20 MPPCF 2 MG/M3* TALC USED ON PRDDUCT IS NON-ASBESTOS FORM. "RESPIRABLE DUST. OTHER SECTION V EMERGENCY AND FIRST AID PROCEDURES EYE CONTACT FLUSH EYES WITH WATER. IF IRRITATION OCCURS, GET MEDICAL ATTENTION. SKIN CONTACT IF CONTACT WITH MOLTEN PRODUCT OCCURS, TREAT AS FOR ORDINARY BURNS. INHALATION NOT ORDINARILY REOUIRED; REMOVE AFFECTED PERSON FROM DUSTY ENVIRONMENT. INGESTION NOT ORDINARILY REOUIRED. SECTION VI SUPPLEMENTAL HEALTH INFORMATION ALL EVIDENCE INDICATES THAT LARGE POLYMER MOLECULES ARE NOT BIOLOGICALLY ACTIVE. SECTION VII PHYSICAL DATA BOILING POINT: NOT APPLICABLE (OEG F) SPECIFIC GRAVITY: 0.82 (H20-1) MELTING POINT: NOT APPLICABLE (DEG F) SOLUBILITY: (IN WATER) NEGLIGIBLE EVAPORATION RATE (N-BUTYL ACETATE - 1): NOT APPLICABLE VAPOR PRESSURE: NOT APPLICABLE (MM HG) VAPOR DENSITY: NOT APPLICABLE (AIR-1) Do 085456 conftdfnttal PRODUCT NAME: KRATON(R) 01107 THERMOPLASTIC RUBBER APPEARANCE AND ODOR: SOLID, ESSENTIALLY ODORLESS. USDS PAGE 2,BIS-3 3 SECTION VIII FIRE AND EXPLOSION HAZARDS FLASH POINT AND METHOD: NOT APPLICABLE FLAMMABLE LIMITS /% VOLUME IN AIR LOWER: N/APL UPPER: N/APL EXTINGUISHING MEDIA USE WATER FOG, FOAM. DRY CHEMICAL OR C02. SPECIAL FIRE FIGHTING PROCEDURES AND PRECAUTIONS MATERIAL WILL NOT BURN UNLESS PREHEATED. DO NOT ENTER CONFINED FIRE SPACE WITHOUT FULL BUNKER GEAR (HELMET WITH FACE SHIELD, BUNKER COATS, GLOVES AND RUBBER BOOTS), INCLUDING A POSITIVE PRESSURE NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS WITH WATER. SECTION IX REACTIVITY STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR CONDITIONS AND MATERIALS TO AVOID: MATERIALS: AVOID CONTACT WITH STRONG OXIDIZING AGENTS. CONDITIONS: PRODUCT CONTAINS RESIDUAL UNSATURATION WHICH CAN UNDERGO EXOTHERMIC OXIDATIVE DEGRADATION. ACCUMULATION OF PRODUCT IN AREAS EXPOSED TO ELEVATED TEMPERATURES FOR EXTENDED PERIODS IN AIR MAY RESULT IN SELF-HEATING AND AUTOIGNITION. SHELL'S INTERNAL GUIDELINE IS FIVE DAYS AT 200 DEG F. . ... HAZARDOUS DECOMPOSITION PRODUCTS AT PROCESSING TEMPERATURES, SOME DEGREE OF THERMAL DEGRADATION WILL OCCUR. ALTHOUGH HIGHLY DEPENDENT ON TEMPERATURE/ENVIRONMENTAL CONDITIONS. A VARIETY OF DECOMPOSITION PRODUCTS MAY BE PRESENT RANGING FROM SIMPLE HYDROCARBONS (SUCH AS METHANE/PROPANE) TO TOXIC/IRRITATING GASES (CARBON MONOXIDE/DIOXIDE, ACROLEIN. HALOGENATED COMPOUNDS, ACIDS, KETDNES, ALDEHYDES). SEE SPECIAL PRECAUTIONS. SECTION X EMPLOYEE PROTECTION RESPIRATORY PROTECTION IF EXPOSURE MAY OR DOES EXCEED OCCUPATIONAL EXPOSURE LIMITS (SEC. IV) USE A NIOSH-APPROVED RESPIRATOR TO PREVENT OVEREXPOSURE. IN ACCORD WITH 29 CFR 1910.134 USE EITHER AN ATMOSPHERE-SUPPLYING RESPIRATOR OR AN AIR-PURIFYING RESPIRATOR FOR PARTICULATES. OSHA HAS ESTABLISHED TRANSITIONAL OCCUPATIONAL EXPOSURE LIMITS FOR THIS PRODUCT AND/OR COMPONENTS OF THIS PRODUCT. REFER TO 29 CFR 1910.1000 FOR THESE TRANSITIONAL LIMITS AND REQUIREMENTS FOR MEETING THESE LIMITS. PROTECTIVE CLOTHING SAFETY GLASSES AND PROTECTIVE CLOTHING SHOULD BE WORN WHEN PRODUCT IS HEATED IN PROCESSING. ADDITIONAL PROTECTIVE MEASURES VENTILATION AS REQUIRED TO CONTROL DUST CONCENTRATION IN AIR. ADEQUATE VENTILATION AND/OR ENGINEERING CONTROLS ARE REQUIRED WHEN PRODUCT IS HEATED IN PROCESSING. SECTION XI ENVIRONMENTAL PROTECTION SPILL OR LEAK PROCEDURES SHOVEL AND SWEEP UP OR USE INDUSTRIAL VACUUM CLEANER. CONTAINERS FOR RECLAIMING OR DISPOSAL. AVOID GENERATING DUST CLOUDS. PUT INTO DO 085457 CONFIDENTIAL 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PRODUCT NAME: KRATON(R) D1107 THERMOPLASTIC RUBBER MSDS PAGE 2,815-3 B THE INFORMATION CONTAINED HEREIN IS BASED ON THE DATA AVAILABLE TO US AND IS BELIEVED TD BE CORRECT. HOWEVER, SHELL MAKES ND WARRANTY. EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. SHELL ASSUMES NO RESPONSIBILITY FOR INJURY FROM THE USE OF THE PRODUCT DESCRIBED HEREIN. DATE PREPARED:JULY 07, 19B9 BE SAFE READ OUR PRODUCT SAFETY INFORMATION . . .AND PASS IT ON (PRODUCT LIABILITY LAW REQUIRES IT) Q. A. VAN GELDER SHELL OIL COMPANY PRODUCT SAFETY AND COMPLIANCE P. 0. BOX 4320 HOUSTON, TX 77210 DO 085459 CONFIDENT TAl Shell ENVIRONMENTAL DATA SHEET 97449 (9*671 EDS NUMBER 2.815-1 PAGE 1 PRODUCT ^KRATON(R) D1107 THERMOPLASTIC RUBBER PRODUCT t CODE f 46007 46798 SECTION I NO. PRODUCT/COMPOSITION COMPONENT P KRATON D1107 1 STYRENE-ISOPRENE-STYRENE BLOCK COPOLYMER 2 TALC* 3 ANTIOXIDANT/STABILIZER KRATON D1107-0 GRADE DOES NOT CONTAIN COMPONENT #2. CAS NUMBER PERCENT MIXTURE 25038-32-8 14807-96-6 100 >98 0-1.5 <1 SECTION II NO. EHS RQ (LBS) (*1) SARA TITLE III INFORMATION EHS TPQ (LBS) (*2) SEC 313 (*3) 313 CATEGORY ( *4 ) 311/312 CATEGORIES ( *5) BASED ON THE DATA AVAILABLE TO SHELL THIS PRODUCT CONTAINS NO SUBSTANCES SUBJECT TO REPORTING OR PLANNING REQUIREMENTS UNDER SARA TITLE III. ....................-.............................................................................................. FOOTNOTES.................... ............................... -............................................ -.................. *1 REPORTABLE QUANTITY OF EXTREMELY HAZARDOUS SUBSTANCE, SEC.302 *2 - THRESHOLD PLANNING QUANTITY. EXTREMELY HAZARDOUS SUBSTANCE. SEC 302 *3 * TOXIC CHEMICAL, SEC 313 *4 CATEGORY AS REQUIRED BY SEC 313 (40 CFR 372.65 C), MUST BE USED ON TOXIC RELEASE INVENTORY FORM *5 HAZARD CATEGORY FOR SARA SEC. 311/312 REPORTING HEALTH H-1 - IMMEDIATE (ACUTE) HEALTH HAZARD H-2 DELAYED (CHRONIC) HEALTH HAZARD PHYSICAL P-3 FIRE HAZARD P-4 SUDDEN RELEASE OF PRESSURE HAZARD P-5 * REACTIVE HAZARD SECTION III NOT APPLICABLE ENVIRONMENTAL RELEASE INFORMATION SECTION IV RCRA INFORMATION PLACE IN AN APPROPRIATE DISPOSAL FACILITY IN COMPLIANCE WITH LDCAL REGULATIONS. 00 COhjpr ^TTAi PRODUCT NAME: KRATON(R) D1107 THERMOPLASTIC RUBBER EDS PAGE ">r'-- a,bib-1 "2 ' THE INFORMATION CONTAINED HEREIN IS BASED DN THE DATA AVAILABLE TO US AND IS BELIEVED TO BE CORRECT. HOWEVER, SHELL MAKES NO WARRANTY, EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. SHELL ASSUMES NO RESPONSIBILITY FOR INJURY FROM THE USE OF THE PRODUCT DESCRIBED HEREIN. DATE PREPARED:OCTOBER 07, 1888 --........... ..........................- SHELL OIL COMPANY SAFETY, INDUSTRIAL HYGIENE ANO ENVIRONMENT P. 0. BOX 4320 HOUSTON, TX 77210 FOR ADDITIONAL INFORMATION ON THIS ENVIRONMENTAL DATA PLEASE CALL (713) 241-22S2 FOR EMERGENCY ASSISTANCE PLEASE CALL SHELL: (713) 473-94B1 CHEMTREC: (800) 424-8300 DO 085461 CONFIDENTIAL ^ PHONE-POULENC SURFACTANTS and SPECIALTIES __ Telephone (MS) 3BS-I300 CN 7500 Cnnbury. Nj 08512-7500 MATERIAL SAFETY DATA SHEET Emergency MmM*I Information. 1 600 228 563$ ToMportillon Emergency; CHEMTREC i 800 42* 9300 -SECTION 01 - IPEWTinCATKW --------------------------------------------- ---------------------------------------------------------------------- MSDS NO. 0160 REV. 4 DATE 03/67 AURAL CO-436 SURFACTANT DOMESTIC TRADE NAME. AURAL CO-436 SURFACTANT EXPORT TRADE NAME: FENOPON CO-436 SURFACTANT CAS REGISTRY NO- 00001051-17-4 CAS REGISTRY NAME: POLY<OXV-l,2-ETHANEDIVl). ALPHA-SULFO-OMEGA-(NONYLPHNOXY>-. AMMONIUM SALT SYNONYM: AMMONIUM SALT OF SULFATED NONYLPHENOXTPOlY(ETMYLENEOXY) ETHANOL MOLECULAR FORMULA: CH4JN06S MOLECULAR WEIGHT: 463 00 SECTION 03 - PHYSICAL A HEALTH HAZARD INGREDIENTS -- ------------ CAS REGISTRY NO. 00000064-17-5 CAS REGISTRY NAME. ETHANOL COMMON NAME: ETHYL ALCOHOL HAZARD % : 12.00 - 10.00 HAZARD REFERENCE: TLV:TWA 1000 PPM PELTWA 1000 PPM SECTION 03 - PHYSICAL 6 CHEMICAL CHARACTERISTICS______________ SOILING POINT: 65.00 DEG C Vapor PRESSURE '25 00 mm Hj VAPOR OENSITY <AIR*1)' DUE TO - 40% WATER AND ETHANOL WATER SOLUBILITY: COMPLETE MELTING/FREEZING POINT: < 0 DEG. C. APPEARANCE: CLEAR LIQUID SPECIFIC GRAV (WATER* 11 1.0650 PERCENTAGE VOLATILES' APPROX 15% ETHANOL: APPROX, 25% WATER EVAPORATION RATE. >1.00 (6UTYL ACETATE * 1) PH OF SOLUTION 6.50 - 7.50 10% SOLUTION ODOR: ALCOHOLIC -SECTION 04 - PHYSICAL HAZARD DATA FLASH POINT: 60-S3 DEG. F.. (CC/PM) AUTOIGNITION TEMP.: NO DATA FOUND FLAMMABLE LIMITS. 3.30 % 16.00 % ETHANOL FIRE FIGHTING MEDIA WATER / ORY CHEMICAL / CARSON C OXIDE SPECIAL FIRE FIGHTING PROCEDURES. NONE KNOWN FIRE/EXPLOSION HAZARDS NONE KNOWN NFPA HAZARD CODES - HEALTH/FIAMMABILITY/REACTIVITY 2 3 0 HMIS HAZAR0 COOES - HEALTH/FLAMMABJLITY/RlACTIVITY 2 3 0 SECTION OS - REACTIVITY OATA_____________ STABILITY: STABLE HAZARDOUS POLYMERIZATION WILL NOT OCCUR CONDITIONS TO AVOI0 NONE KNOWN INCOMPATIBLE MATERIALS: STRONG OXIDIZING OR REDUCING AGENTS. HAZAROOUS DECOMPOSITION PROOUCT$: NONE KNOWN SECTION 06 - HEALTH HAZARD DATA - ACUTE TOXICITY - ORAL TOXICITY. RAT LDSO 6000 MG/KG DERMAL TOXICITY, NO OATA FOUNO DO 0854^-p ooNFroFNrrAi. Please see reverse side for additional information Form 2732-1-PP 5'90 JP P.HONE-POULENC SURFACTANTS and SPECIALTIES Telephone (609) 395-1300 CN 7500 Cnnbury, NJ 08512-7500 Emergency Medical Information: 1 600 226 5635 Transportation Emergency. CHEMTREC l 800 424 9300 MSDS NO. 0260 RtV. 4 DATE 03/67 AL1PAL CO-436 SURFACTANT _________ SECTION 06 - MFAI TU HA7ARO DATA tCPWTJ-------------------------------------------------------------------------------------- .-----------------------INHALATION TOXICITY: NO OATA FOUND. SKIN IRRITATION: AA0BIT; TESTED AS 15% ACTIVE SOLUTION; PRIMARY IRRITATION INDEX: 2 39. MILD IRRITANT. EYE IRRITATION: RABBIT: SEVERE IRRITANT WITHOUT A WASHOUT, MOOERATE IRRITANT WITH A WASHOUT 30-SECONDS AFTER INSTILLATION. SENSITIZER: NO DOT CORROSIVE: NO PRIMARY ROUTE(S) OF ENTRY: INHALATION / CONTACT - SIGNS 4 SYMPTOMS OF EXPOSURE - SYMPTOMS OF INGESTION: NO EFFECTS QF EXPOSURE EXPECTED. SYMPTOMS OF INHALATION. WILL CAUSE IRRITATION OF MUCOUS MEMBRANES. NOSE. EYES AND THROAT. COUGHING. DIFFICULTY IN BREATHING. SYMPTOMS OF SKIN CONTACT CONTACT MAY CAUSE IRRITATION. REDNESS. SWELLING OR DERMATITIS. SYMPTOMS OF EYE CONTACT VAPORS SLIGHTLY UNCOMFORTABLE. SPLASHES IRRITATING WILL CAUSE PAINFUL BURNING QR STINGING OF EYES AND LiOS. WATERING OF EYES AND INFLAMMATION OF CONJUNCTIVA. - EMERGENCY FIRST AID PROCEDURES - FIRST AID FOR INGESTION GENERAL PRECAUTIONARY MEASURES SUGGEST INDUCING VOMITING IMMEDIATELY BY GIVING TWO GLASSES OF WATER AND STICKING FINGER DOWN THROAT. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON CALL A PHYSICIAN FIRST AID FOR INHALATION REMOVE TO FRESH AIR IF NOT BREATHING. GIVE ARTIFICIAL RESPIRATION, PREFERABLY MOUTH-TO 'MOUTH IF BREATHING IS DIFFICULT. GIVE OXYGEN. CALL A PHYSICIAN. FIRST AID FOR SKIN CONTACT FLUSH SKIN WITH WATER. FIRST AID FQR EYE CONTACT: IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES CALL A PHYSICIAN. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE. NO DATA FOUND EXPOSURE LIMITS. SEE SECTION 02 FOR PHYSICAL A HEALTH HAZARD INGREDIENTS - OTHER TOXJCTfY - OTHER ACUTE TOXIOTY NO DATA FOUND SUB CHRONIC ORAL TOXICITY: 90 DAY SUBCHRONIC ORAL - RAT AND OOG. 0 5 1 AND 2% OF DIET. DATA SHOWED NO SIGNIFICANT CHANGES INDICATIVE OF PHARMACOTOXC EFFECTS. ALTHOUGH GROWTH DEPRESSION WAS OBSERVED N THE RAT AT THE HIGH DOSE LEVEL AND IN THE OOG AT THE MiO AND HIGH DOSE LEVELS SUB CHRONIC INHALATION TOXICITY: NO DATA FOUND SUB CHRONIC MISCELLANEOUS TOXICITY: NO DATA FOUND AQUATIC TOXICITY- NO DATA FOUND TUMORIGENICITY: NO DATA FOUND MUTAGENICITY NO DATA FOUND REPRODUCTIVE TOXICITY NO OATA FOUND Please see reverse side for additional information DO 085463 CONFTDENTTAl Fe'm 2732-1-RP 5*90 fP RHONE-POULENC SURFACTANTS and SPECIALTIES Telephone <*D9) 39543&0 CN 7500 C: anbury, NJ 00512*7500 Em*rgof>cy Mudicjl InlormMion: 'l BOO 228 5635 Treneportetion Emergency. OtEMTRCC 1 800424 9300 M50S NO. 0260 REV. 4 DATE 03/17 ALtPAL CO-436 SURFACTANT SgCIfTOW DC - HEALTH flATA ICOHTA MISCELLANEOUS TOXICITY; NO 0ATA FOUND ----------------07 - IlmiFATIftMAL CONTROL WtflCEPUBES -------------- VENTILATION: USE WITH A0CQUATE VENTILATION. RESPIRATORY PROTECTION: NJOSH-APPROVED RESPIRATOR. WHERE TlV OR PEL MAY 66 EXCEEDED. EYE PROTECTION: CHEMICAL GOGGLES. SKIN PROTECTION: IMPERVIOUS GLOVES. PERSONAL HYGIENE: WASH THOROUGHLY AFTER HANDLING. PROTECTIVE MEASURES DURING REPAIR/MAINTENANCE OF EQUIPMENT: WASH EQUIPMENT THOROUGHLY WITH STEAM OR WARM WATER UNTIL CLEAN. CHECK FOR FLAMMA0LE5 WITH AN "EXPLOSION METER" AND ALSO CHECK THE OXYGEN LEVEL WITH AN OXYGEN METER. IN ALL CASES, FOLLOW GOOO INDUSTRIAL SAFETY PRACTICES BEFORE ENTERING EQUIPMENT. __________ SECTION M - PHECALfTlONS FOR SAFE HANOUNfi STORA/J AMO USE_________ , PRECAUTIONARY MEASURES: AVOID CONTACT WITH EYES AND SKIN. WASH THOROUGHLY AFTER HANDLING, AVOID BREATHING VAPOR. USE ADEQUATE VENTILATION. KEEP THIS CONTAINER AND VAPORS FROM THIS CONTAINER AWAY FROM HEAT, SPARKS AND FLAME KEEP CONTAINER CLOSED SPHL/LCAK CLEAN-UP PROCEDURES: ELIMINATE SOURCES OF IGNITION. ABSORB WITH EARTH. SAND OR SIMILAR INERT MATERIAL AND DISPOSE OF WITH SQUD WASTE ACCORDING TO FEDERAL STATE AND LOCAL REGULATIONS. FLUSH SP'LL AREA WITH WATER DISPOSAL METHOD OISPOSE OF WITH LIQUID WASTE ACCORDING TO FEDERAL STATE AND LOCAL REGULATIONS EPA HAZARDOUS SUBSTANCE REPORTABLE QUANTITY.NOT LISTED RCRA CLASS 'GNITIBLE D001 _______ section na - transportation data - DOMESTIC DATA DOT SHIPPING NAME FLAMMABLE LIQUID. NOS DOT HAZARD CLASS FLAMMABLE LIQUID HAZARDOUS INGREDIENT(S): ETHANOL UN NUMBER. 1993 - EXPORT DATA EXPORT SHIPPING NAME FLAMMABLE LIQUID. NOS EXPORT HAZARD CLASS FLAMMABLE LIQUID HAZARDOUS INGREDIENT(S) ETHANOL UN NUMBER 1993 Please see reverse side for additional information 0 085464 Conf^ofnttal form 2732-i-RP 5/90 Shell MATERIAL 17387 !>: 24 HOUR EMERGENCY ASSISTANCE SAFETY DATA SHEE1 MSDS NUMBER > 2,388-6 GENERAL MSDS ASSISTANCE PAGE SHELL: 713-473-9461 CHEMTREC: 800-424-9300 ACUTe HAi TH *0 tmt ^1 I , RfACTIVITY ' 0 | HAZARD RATING SHELL: 713-241-4819 *ucmt * EXTREME 4 MODERATE * t BE SAFE MADOUantOOVCT AAFfTY MTOMIAtlON MS* IT ON for cute m6 chrome heelth effect* refer to the discuseion in Section III SECTION 1 NAME KRATON(R) 01184 THERMOPLASTIC RUBBER PRODUCT ^ CHEMICAL l STYRENE-BUTADIENE-STYRENE BLOCK COPOLYMER NAME V VCHEMICAL l BLOCK COPOLYMER FAMILY SHELL CODE rf 46223 46117 46B97 46977 46269 46972 SECTION II- A NO. PRODUCT/INOREOI ENT COMPOSITION CAS NUMBER PERCENT P KRATON D1184X THERMOPLASTIC RUBBER MIXTURE 100 1 STYRENE-BUTADIENE-STYRENE BLOCK COPOLYMER 2 TALC 3 CALCIUM CARBONATE IM A ANTIOXIDANT/STABILIZER 9003-SB-6 14807-96-6 1317-85-3 >94 0-1 0-5 <1 KRATON 011B4X-0 DOES NOT CONTAIN COMPONENT 2 OR 3. KRATON D1184X-2 CONTAINS COMPONENT 2. KRATON D1184G-6 AND D1184G-6 CONTAINS COMPONENT 3. SECTION II-B NO. ACUTE ORAL LDSO ACUTE TOXICITY DATA ACUTE DERMAL LDSO ACUTE IM4ALATI0N LCSO P NOT AVAILABLE BASED UPON DATA AVAILABLE TO SHELL, COMPONENTS 1 AND 4 IN THIS PROOUCT ARE NOT HAZARDOUS UNDER OSH/ HAZARD COMMUNICATION (29 CFR 1910.1200). SECTION III HEALTH INFORMATION THE HEALTH EFFECTS NOTED BELOW ARE CONSISTENT WITH REQUIREMENTS UNDER THE OSHA HAZARD COMMUNICATIOf STANDARD (29 CFR 1910.1200). EYE CONTACT BASED ON PRESENCE OF COMPONENT 2 OR 3, PROOUCT MAY CAUSE MILD MECHANICAL IRRITATION TO THE EYES. SKIN CONTACT BASED ON PRESENCE OF COMPONENT 2 OR 3. PRODUCT IS PRESUMED TO BE MINIMALLY IRRITATING TO THE SKIN. IM1ALATI0N BASED ON PRESENCE OF COMPONENT 2 OR 3. PRODUCT MAY CAUSE MILD MECHANICAL IRRITATION TO THE NOSE THROAT AS RESPIRATORY TRACT. DO CONF Td*httal PRODUCT NAME: KRATON(R) D11S4 THERMOPLASTIC RURBER USDS PAGE 2,311-6 2 INGESTION PRODUCT IS GENERALLY CONSIDERED TO HAVE A LOW ORDER OF ACUTE ORAL TOXICITY. SIGNS ANO SYMPTOMS TRRITATION AS NOTED ABOVE. AGGRAVATED MEDICAL CONDITIONS PREEXISTING EYE. SKIN. AND RE5PIRAT0RY 0IS0R0ER5 MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT. SECTION IV OCCUPATIONAL EXPOSURE.LIMITS NO. PEL/TWA QSHA PEL/CEILING TLV/TVA ACQ1H TLV/STEL 2 2 MG/M33 15 MG/M3-3 S MG/M3* 20 MPPCF 2 MG/M3* 10 M6/M3-- TALC USED ON PRODUCT IS NON-ASBESTOS FORM. * RESPIRABLE DUST. * TOTAL DUST. OTHER SECTION V EMERGENCY AND FIRST AID PROCEDURES EYE CONTACT FLUSH EYES WITH WATER. IF IRRITATION OCCURS. GET MEDICAL ATTENTION. SKIN CONTACT IF CONTACT WITH MOLTEN PRODUCT OCCURS. TREAT AS FOR ORDINARY BURNS. INHALATION NOT ORDINARILY REQUIRED: REMOVE AFFECTED PERSON FROM DUSTY ENVIRONMENT. INGESTION NOT ORDINARILY REQUIRED. SECTION VI SUPPLEMENTAL HEALTH INFORMATION ALL EVIDENCE INDICATES THAT LARGE POLYMER MOLECULES ARE NOT BIOLOGICALLY ACTIVE. SECTION VII PHYSICAL DATA BOILING POINT: NOT APPLICABLE (DEG F) SPECIFIC GRAVITY: O.B4 (H20-1) MELTING POINT: NOT APPLICABLE (DEG F) SOLUBILITY: (IN WATER) NEGLIGIBLE EVAPORATION RATE (N-BUTYL ACETATE 1): NOT APPLICABLE VAPOR PRESSURE: NOT APPLICABLE (MM HG) VAPOR DENSITY: NOT APPLICABLE (AIR-1) DO 08546ft CONFTOHNTIAl PRODUCT NAME: KRATON(R) D11B* THERMOPLASTIC RUBBER APPEARANCE AND ODOR: SOLID. ESSENTIALLY ODORLESS SECTION VIII EIRE AND EXPLOSION HAZARDS MSOS 2,BBS'S PAGE 3 ( PLASH POINT ANO METHOD: NOT APPLICABLE FLAMMABLE LIMITS /% VOLUME IN AIR LOWER: N/AP UPPER: N/AP EXTINGUISHING MEDIA USE WATER FOG. FOAM, DRY CHEMICAL OR C02, SPECIAL FIRE FIGHTING PROCEDURES AND PRECAUTIONS MATERIAL WILL NOT BURN UNLESS PREHEATED. DO NOT ENTER CONFINED FIRE SPACE WITHOUT FULL BUNKER GEA (HELMET WITH FACE SHIELD, BUNKER COATS. GLOVES ANO RUBBER BOOTS). INCLUDING A POSITIVE PRESSURE NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS WITH WATER. SECTION IX REACTIVITY STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR CONDITIONS AND MATERIALS TO AVOID: MATERIALS: AVOID CONTACT WITH STRONG OXIDIZING AGENTS. CONDITIONS: PRODUCT CONTAINS RESIDUAL UNSATURATION WHICH CAN UNDERGO EXOTHERMIC OXIDATIVE DEGRADATION. ACCUMULATION OF PRODUCT IN AREAS EXPOSED TO ELEVATED TEMPERATURES FOR -EXTENDED PERIODS IN AIR MAY RESULT IN SELF-HEATING AND AUTOIGNITION. SHELL'S INTERNAL GUIDELINE IS FIVE DAYS AT 200 DEG F. HAZARDOUS DECOMPOSITION PRODUCTS AT PROCESSING TEMPERATURES. SOME DEGREE OF THERMAL DEGRADATION WILL OCCUR. ALTHOUGH HIGHLY DEPENDENT On TEMPERATURE/ENVIRONMENTAL CONDITIONS. A VARIETY OF DECOMPOSITION PRODUCTS MAY BE i* PRESENT RANGING FROM SIMPLE HYDROCARBONS (SUCH AS METHANE/PROPANE) TO TOXIC/IRRITATING GASES (CARBON MONOXIDE/DIOXIDE. ACROLEIN, HALOGENATED COMPOUNDS. ACIDS. KETONES. ALDEHYDES). SEE SPECIA PRECAUTIONS. SECTION X EMPLOYEE PROTECTION RESPIRATORY PROTECTION IF EXPOSURE MAY OR DOES EXCEED OCCUPATIONAL EXPOSURE LIMITS (SEC. IV) USE A NIOSH-APPROVED RESPIRATOR TO PREVENT OVEREXPOSURE. IN ACCORD WITH 2B CFR 1810.134 USE EITHER AN ATMOSPHERE-SUPPLYING RESPIRATOR OR AN AIR-PURIFYING RESPIRATOR FOR PARTICULATES. OSHA HAS ESTABLISHED TRANSITIONAL OCCUPATIONAL EXPOSURE LIMITS FOR THIS PRODUCT AND/OR COMPONENTS OF THIS PRODUCT. REFER TO 28 CFR 1810.1000 FOR THESE TRANSITIONAL LIMITS AND REQUIREMENTS FOR MEETING THESE LIMITS. PROTECTIVE CLOTHING SAFETY GLAS5ES AM) PROTECTIVE CLOTHING SHOULD BE WORN WHEN PRODUCT IS HEATED IN PROCESSING. ADDITIONAL PROTECTIVE MEASURES VENTILATION AS REQUIRED TO CONTROL DUST CONCENTRATION IN AIR. ADEQUATE VENTILATION AND/OR ENGINEERING CONTROLS ARE REQUIRED WHEN PRODUCT IS HEATED IN PROCESSING. SECTION XI ENVIRONMENTAL PROTECTION SPILL OR LEAK PROCEDURES SHOVEL AND SWEEP UP OR USE INDUSTRIAL VACUUM. CLEANER. CONTAINERS FOR RECLAIMING OR DISPOSAL. AVOID GENERATING DUST CLOUDS. PUT INTO DO 085467 CONFIDENTIAL. . PRODUCT NAME: KRATON(R) 011*4 THERMOPLASTIC RUBBER MSDS PAGE 2.3SB-6 4 SECTION XII SPECIAL PRECAUTIONS JUJATON RUBBER HAS A TENDENCY TO ACCUMULATE STATIC CHARGE CURING TRANSPORT. HANDLING AND PROCESSING. REDUCING THE VELOCITY OF TRANSPORT WILL REDUCE CHARGING STATIC CHARGE BUILDUP CAN BE A POTENTIAL FIRE HAZARC WHEN USED IN PRESENCE OF VOLATILE OR FLAMMABLE MIXTURES. PRACTICE GOOD HOUSEKEEPING. DO NOT ALLOW PRODUCT TO ACCUMULATE IN PROCESSING AREA. IN PROCESSING. DO NOT ALLOW THE TEMPERATURE TO EXCEEC-450 OEG. F. MAINTAIN A FIRE WATCH IF 45C OEG. F IS REACHED. AVOID VAPORS FROM HEATED PRODUCTS. ADEQUATE VENTILATION AND/OR ENGINEERING CONTROLS MUST BE EMFLOYED IN HIGH TEMPERATURE PROCESSING TO PREVENT EXPOSURE TO POTENTIALLY TOXIC/IRRITATING FUMES SECTION XIII TRANSPORTATION REQUIREMENTS DEPARTMENT OF TRANSPORTATION CLASSIFICATION: NOT HAZARDOUS BY D.O.T. REGULATIONS SECTION XIV OTHER REGULATORY CONTROLS THE COMPONENTS OF THIS PRODUCT ARE LISTED ON THE EPA/TSCA INVENTORY OF CHEMICAL SUBSTANCES. IN ACCORDANCE WITH SARA TITLE III. SECTION 313. THE EOS SHOULD ALWAYS BE COPIED AND SENT WITH THE MSDS. SECTION XV SPECIAL NOTES THE OCCUPATIONAL EXPOSURE LIMITS (SECTION IV) ANO/OR THE RESPIRATORY PROTECTION PRECAUTIONS (SECTION X) HAVE BEEN REVISED. THE INFORMATION CONTAINED HEREIN IS BASED ON THE DATA AVAILABLE TO US AND IS BELIEVED TO BE CORRECT. HOWEVER. SHELL MAKES NO WARRANTY, EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. SHELL ASSUMES NO RESPONSIBILITY FOR INJURY FROM THE USE OF THE PRODUCT DESCRIBED HEREIN. DATE PREPARED:JULY 18, 198* BE SAFE READ OUR PRODUCT SAFETY INFORMATION ...AM) PASS IT ON (PRODUCT LIABILITY LAW REQUIRES IT) J. C. WILLETT SHELL OIL COMPANY PRODUCT SAFETY ANO COMPLIANCE P. 0. BOX 4320 HOUSTON, TX 77210 00 085468 CONFIDENTIAL PRINLiN B7138A ' KRATON. G1657 WATER BASE DISPERSION m GENERAL DESCRIPTION PRINLIN B7138A is a resin modified v/ater base dis persion of Kraton G1657. B7138A is an attractive alternative to solvent based rubber solutions because it contains less than 0.5% retained organic solvent while maintaining many of the properties typical of the base elastomer such as; low temperature flexibility, improved tensile strength, increased impact resistance, higher elasticity and added cohesive strength. POSSIBLE END USES: STORAGE AND HANDLING (SEE REVERSE) FREEZABLE / METAL REACTIVE Storage of this product for periods exceeding 6 to 8 months should be avoided. FREEZING Renders P&S dispersions unusable. Carefully inspect all cold weather shipments. REDUCTION/CLEAN-UP Tap water is normally suitable for dilution and cleaning of wet coating, if coating has 'dried on'; removal with toluol or chlorin ated solvents may be necessary. Sealants Coatings' Caulks Pressure Sensitive Adhesives STABILITY Slow agglomeration can occur as dis persions age. Such agglomerates and any dried particles should be filtered out before using. Or gandy. cheesecloth or 60-30 mesh screen (stainless) TYPICAL PHYSICALS Viscosity <% 77 F Nor.-Vciatilos Weight per Gallon @ 77 F Residual Hydrocarbons Dilution Resin Modifier 400 cps 43.0 % 8.1 lbs 0.5% Water as Required Wood Rosin Hydrogen ated Rosin are effective for this purpose. Volume operations usualiy require continous filtration. FOAMING If encountered, can be effectively con trolled by addition of V,ounce per gallon of Neocryl AP2650 (Polyvinyl Chemicai. Wilmington, MA 01887). Neocryl AP2650 or the addition of 1 to 2 ounces per gallon of Antifoam A6138A (Pierce & Stevens), a 50/50 mix of Foamkill 649 (Crucible Chemical, Green ville. SC 29606) Coalescing Temp. Ester 72 F PUMPS Avoid the use of positive displacement (gear) pumps and iron or common steel piping. pH 9.0 Diaphragm pumps are recommended. Piping and CAUTION other equipment should be of stainless or aluminum construction. ^ This product depends on consistent control of all materials and methods to insure proper performance. Factors of variability connected with coated or imping ing substrate, application methods, viscosity control, etc., require that the user subject the adhesive and all elements of the composite structure to careful prelimi METAL REACTIVITY. Most dispersions are alkaline and contact with brass, copper, iron etc. should be avoided. Stainless steel, aluminum and some plastics have been useful for piping, sumps, etc. nary testing, end-use qualification, field evaluation PRINLIN is 4 registered tradename of Pierce A Stevens Cor|>. and effective and continuous production - quality EXPERIMENTAL PRODUCT DEVELOPMENT DATA Kraton is *. registered trademark of the Shell Chemical Co. EPDD VT# 05m This information has been secured during the course of product development. The product is subject to modification and its properties are thus tentative. While currently offered for field and/or lab evaluation, future commercial availability cannot be assured at this time. Careful evaluation is of critical importance. Coatings and adhesives are developed using laboratory tests of limited duretion, scope and applicability. Such tests, while indicative of commercial utility, are by no means infallible. Accordingly, the user is obligated to determine whether the product is suitable for the purpose intended and to carefully qualify its performance during an phases of research, develop ment, field trial and commercialization. AVAILABILITY1 Samples for lab testing (qts.. gals.) are readily available. Allow 3-4 weeks for auantities sufficient to permit pilot or plant trial. DO 0 8 5 4 6 9 CONFIDENT TAl GENERAL INFORMATION NOTE -- This product is intended for industrial use only. SPECIFICATIONS ' ,, The d4ta provided herein, whether tentative or established, represent the typical condition for this product. Such information is not intended to be used for specification limits, certification standards, or other finite acceptance criteria. To qualify as the basis for acceptance, customer specifications and test methods must be reviewed and appr ved by P&S. STORAGE AND HANDLING This form indicates whether the product described is flammable, freezable, reactive, or of a composition known to be reactive with metals. In general, products of such nature are treated as follows: FLAMMABLES (Red Label Assumed) ' Store and handle in accordance with acceptable industry practice and comply with regulations as defined by the National Fire Codes, OSHA and local authorities having, jurisdiction. FREEZABLES (No Freeze-Thaw Stability Assumed) Store at temperatures above 40* F. (4*C.). Storage below this temperature may cause damage. Best storage tempera tures are between 60* F. (16* C.) and 80* F. (20* C.). Lower temperatures can cause increased viscosity of a temporary nature. After storage at low temperatures, allow product to warm to room temperature before agitating or using. REACTIVE (Heat and Ught Sensitivity) Prolong storage life and protect from spontaneous polymerization bystoring at temperatures below 77* F. (25* C.). Where noted as UV reactive, the material requires shielding from sunlight and other UV sources (e.g..f!uoresoent lamps). METAL REACTIVITY Many products (esp. hot melts, aqueous and reactive systems) degrade rapidly if exposed to copper, brass, black iron, or aluminum. Utilize stainless steel application and storage equipment where such sensitivity is n ted as a product characteristic. ' Rotate coating and adhesive stock on a first-in-first-out basis. Request your P&S representative to advise you of the anti cipated shelf life of specific products under the storage conditions in your plant. NOTE -- Before commercializing this orany P&S product secure documentation (e.g., MSDS) to insure yourend-product and operational compliance with federal, state and municipal regulations (OSHA, EPA, FDA, etc.). Consult the indicated P&S Marketing Division for service of your specific needs in this regard. PACKAGING Product packaging is specified by P&S. Non-standard packaging is discouraged and can be considered only in cases where warranted by volume and frequency of shipments. P&S can assist in developing bulk packaging-shipping methods (portable tanks, bins, tank wagons, tankcars, etc.) to facilitate the needs of customers whose requirements justify such handling. Most bulk supply methods require contractual commitments and involve scale-up from truckload intakes. AVAILABILITY -- Commercial Products (U.S. Destinations) Many standard products are available from factory and warehouse stocks (allow up to 10 days delivery). Various other products are made to order from ingredient materials on hand (allow up to 25 days). Certain special order products require up to 45 days for processing. Consult your P&S sales representative regarding the normal availability and shipping points for special products. : LOCATION HEADQUARTERS: BUFFALO BRANCHES: CAROL STREAM. IL DALLAS, TX KIMBERTON. PA CONTACT PIERCE & STEVENS CORP. DEPARTMENT TECHNICAL. MANUFACTURING. GENERAL ADMINISTRATIVE, CENTRAL ORDER ENTRY MARKETING & SALES OFFICES MAIUZIP BOX 1092/14240 BOX 1092/14240 ORDER-ENTRY - SALES & TECH SERVICE * ORDER-ENTRY -- SALES ORDER-ENTRY -- SALES & TECH SERVICE 245 E KEHOE/60188 4525 JOSEPH HARDIN DR775236 BOX 218/19442 MILPITAS. CA ORDER-ENTRY - SALES & TECH SERVICE 805 SINCLAIR FRONTAGE/95035 PHONE --- 716/858-4910 FAX 716/B56-971B 708/653-3800 FAX 708/5104927 214/330-9205 FAX 214/330-8129 215/933-8857 FAX 215/933-0201 408/262-7331 FAX 408/942-1569 CANADA: FT. ERIE. ONTARIO ORDER-ENTRY -- SALES & TECH SERVICE BOX 249/L2A5M9 416/871-2724 DISCLAIMER Neither Pierce & Stevens (P&S) nor its marketing agents shall be responsible for the use of this information, or of any product, method or apparatus mentioned. You must make your own determination of product suitability and thoroughly qualify it for serviceability, for environmental acceptability, and for impact on the health and safety of youremployees and purchasers of your products. P&S warrants that the materials themselves do not infringe the claims of any United States patent, but no license is implied nor. is any further patent warranty made. P&S* only obligation shall be to replace such quantity of the product which is proven to have been defective. No person is authorized to make any statement or recommendation not contained herein, and any such statement or recommendation so made shall not bind P&S. A MtATT A LAMBERT COMPANY Do 08547c CO/VF r^r.rA( VARUECH DIVISION PRINLll^f B7138A- TECHNICAL SHEET Polymer.. Kra|onG1657 Polymer Type S - EE - S (Styrene - Ethylene Butylene - Styrene) saturated tnblock copolymer, soft rubbery midblock. % Styrene in Polymer 14% by weight Surfactant Type Anionic at 5.75% weight level of solids Resin Modification FDA Status '' Hydrogenated rosin ester in the .dispersion phase. Meets FDA approval under. #175.105 Other properties PRINLIN B7138A forms a film at 72F. This film exhibits ex cellent flexibility at low temperatures and high elongation. A major difference between PRINLIN 87.l38Aanddispersicns bn other G series polymers is ihe resin modification and low styrene content. As a result B7138A is iow in modulus, exhibiting high elasticity. Typical Physicals pH Viscosity Weight per Gallon % Non-Volatile Particle Size Freeze Thaw Stability Antifoam 9.0 400 cps 8.1 43 1 - 3 microns None Foamkill 649 from Crucible Chemical Handling High levels of shear may C3use PRINLIN dispersions to form agglomerates . To minimize shear we recommend the use.. of diaphram pumps and low shear mixers when used. During storage avoid exposure to excessive heat. Possible End Uses Sealants Coatings Asphalts Caulks Pressure Sensitive Adhesives Skippable Coatings '1 FDA status should te confirmed prior to evaluation. Status will be supplied in writing upon request. Kraion is a registered tradename of Shell Chemical Co. PRINLIN is a registered tradename of Pierce & Stevens Corp. 00 085471 CONFTDFNTTAL MATERIAL SAFETY DATA SHEET Sigma-Aldrich Corporation 1001 West Saint Paul Ave, Milwauke , WI * 1990 version 53233 USA For Emergency Contact USA/Canada Outside USA/Canada Sigma 800-325-5832 314-771-5765 Aldrich 800-231-8327 414-273-3850 PRODUCT #: CAS #: 75-15-0 NAME: CARBON DISULFIDE REAGENT SYNONYMS CARBON BISULFIDE * CARBON BISULFIDE (DOT) * CARBON BISULPHIDE * CARBON DISULFIDE (ACGIH,DOT,OSHA) * CARBON DISULPHIDE *' CARBONE (SUFURE DE) (FRENCH) * CARBONIO (SOLFURO DI) (ITALIAN) * CARBON SULFIDE * CARBON SULPHIDE (DOT) * DITHIOCARBONIC ANHYDRIDE * KOHLENDISULFID (SCHWEFELKOHLENSTOFF) (GERMAN) * KOOLSTOFDISULFIDE (ZWAVELKOOLSTOF) (DUTCH) * NCI-C04591 * RCRA WASTE NUMBER P022 * SCHWEFELKOHLENSTOFF (GERMAN) * SOLFURO DI CARBONIO (ITALIAN) * SULPHOCARBONIC ANHYDRIDE * UN 1131 (DOT) * WEEVILTOX * WEGLA DWUSIARCZEK (POLISH) * -------------------------------------- TOXICITY HAZARDS ---------------------------------------- RTECS NO: FF6650000 CARBON DISULFIDE TOXICITY DATA IHL-HMN LCLO:4000 PPM/30M IHL-HMN LCLO:2000 PPM/5M UNR-MAN LDLO:186 MG/KG ORL-RAT LD50:3188 MG/KG IHL-RAT LC50:25 GM/M3/2H 29ZWAE -,118,68 TABIA2 3,231,33 85DCAI 2,73,70 GISAAA 31(1),13,66 85GMAT -,32,82 DO 08547? CONFIDENTIAL h i ORL-MUS LD50:2780 MG/KG 61SAAA 31(1),13,66 IHL-MUS LC50:10 GM/M3/2H 85GMAT -,32,82 ORL-RBT LD50:2550 MG/KG GISAAA 31(1),13,66 ORL-GPG LD50:2125 MG/KG GISAAA 31(1),13,66 RF"r.EWS, STANDARDS, AND REGULATIONS ACGIH TLV-TWA 10 PPM (SKIN) 85INA8 5,104,86 MSHA STANDARD-AIR:TWA 20 PPM (60 MG/M3) (SKIN) DTLVS* 3,39,71 OSHA PEL:8H TWA 20 PPM;CL 30 PPM;PK 100 PPM/30M/8H FEREAC 54,2923,89 OSHA PEL FINAL:8H TWA 4 PPM (12 MG/M3);STEL 12 PPM (36 MG/M3)(SKIN) FEREAC 54,2923,89 NIOSH REL TO CARBON DISULFIDE-AIR:10H TWA 1 PPM;CL 10 PPM/15M MMWR** 37(S-7),7,88 NOHS 1974: HZD 17370; NIS 24; TNF 1074; NOS 27; TNE 24200 NOES 1983: HZD 17370; NIS 18; TNF 689; NOS 41; TNE 44438; TFE 4881 EPA GENETOX PROGRAM 1988, POSITIVE: SPERM MORPHOLOGY-HUMAN EPA TSCA CHEMICAL INVENTORY, 1989 EPA TSCA TEST SUBMISSION (TSCATS) DATA BASE, APRIL 1990 NIOSH ANALYTICAL METHODS: SEE CARBON DISULFIDE, 1600 TARGET ORGAN DATA LIVER (FATTY LIVER DEGENERATION) PATERNAL EFFECTS (SPERMATOGENESIS) PATERNAL EFFECTS (PROSTATE, SEMINAL VESICLE, CQWPER'S, ACCESSORY GLANDS EFFECTS ON FERTILITY (POST-IMPLANTATION MORTALITY) EFFECTS ON EMBRYO OR FETUS (FETOTOXICITY) EFFECTS ON NEWBORN (BEHAVIORAL) ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES (RTECS) DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN RTECS FOR COMPLETE INFORMATION. -------------------------------------- HEALTH HAZARD DATA ------------- A :E EFFECTS HARMFUL IF SWALLOWED, INHALED, OR ABSORBED THROUGH SKIN. VAPOR OR MIST IS IRRITATING TO THE EYES, MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT. CAUSES SKIN IRRITATION. EXPOSURE CAN CAUSE: DAMAGE TO THE KIDNEYS DAMAGE TO THE LIVER DAMAGE TO THE HEART MAY CAUSE NERVOUS SYSTEM DISTURBANCES. MAY CAUSE CONVULSIONS. CHRONIC EFFECTS OVEREXPOSURE MAY CAUSE REPRODUCTIVE DISORDER(S) BASED ON TESTS WITH LABORATORY ANIMALS. LABORATORY EXPERIMENTS HAVE SHOWN MUTAGENIC EFFECTS. FIRST AID IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS. CALL A PHYSICIAN. REMOVE AND WASH CONTAMINATED CLOTHING PROMPTLY. ------------------------------------------ PHYSICAL DATA ------------------------------------------- BOILING PT: 46 C DO 085473 CONFTDFNTIAL ft MELTING PT: -112 C SPECIFIC GRAVITY: 1.266 VAPOR DENSITY: 2.67 VAPOR PRESSURE: 400 MM 28 C 200 MM 10.6 C AI ARANCE AND ODOR COLORLESS LIQUID ------------------------- FIRE AND EXPLOSION HAZARD DATA ----------------------- FLASHPOINT: -29 F BY: AUTOIGNITION TEMPERATURE: 212 F LOWER EXPLOSION LEVEL: 1.3% UPPER EXPLOSION LEVEL: 50% EXTINGUISHING MEDIA WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER, ALCOHOL OR POLYMER FOAM. SPECIAL FIREFIGHTING PROCEDURES WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO PREVENT CONTACT WITH SKIN AND EYES. UNUSUAL FIRE AND EXPLOSIONS HAZARDS DANGER: EXTREMELY FLAMMABLE. VAPOR MAY TRAVEL CONSIDERABLE DISTANCE TO SOURCE OF IGNITION AND FLASH BACK. EMITS TOXIC FUMES UNDER FIRE CONDITIONS. ---------------------------------------- REACTIVITY DATA------------------------- ----------------INCOMPATIBILITIES OXIDIZING AGENTS AMINES HAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCTS CARBON MONOXIDE, CARBON DIOXIDE ' SULFUR OXIDES -------------------------------- SPILL OR LEAK PROCEDURES -----------------------------STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED EVACUATE AREA. SHUT OFF ALL SOURCES OF IGNITION. WEAR SELF-CONTAINED BREATHING APPARATUS, RUBBER BOOTS AND HEAVY RUBBER GLOVES. ABSORB ON SAND OR VERMICULITE AND PLACE IN CLOSED CONTAINERS FOR DISPOSAL. VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE. WASTE DISPOSAL METHOD BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER BUT EXERT EXTRA CARE IN IGNITING AS THIS MATERIAL IS HIGHLY FLAMMABLE. OBSERVE ALL FEDERAL, STATE, AND LOCAL LAWS. ------ PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE -----WEAR APPROPRIATE NIOSH/MSHA-APPROVED RESPIRATOR, CHEMICAL-RESISTANT GLOVES, SAFETY GOGGLES, OTHER PROTECTIVE CLOTHING. SAFETY SHOWER AND EYE BATH. USE ONLY IN A CHEMICAL FUME HOOD. DO NOT BREATHE VAPOR. DO NOT GET IN EYES, ON SKIN, ON CLOTHING. AVOID PROLONGED OR REPEATED EXPOSURE. READILY ABSORBED THROUGH SKIN. WASH THOROUGHLY AFTER HANDLING. , TOXIC. 00 85474 CONF Jr)F'NTTAl. IRRITANT. POSSIBLE MUTAGEN/TERATOGEN. REPRODUCTIVE HAZARD. NEUROLOGICAL HAZARD. KEEP TIGHTLY CLOSED. ( KEEP AWAY FROM HEAT, SPARKS, AND OPEN FLAME. MAY EXPLODE WHEN HEATED. MAY DEVELOP PRESSURE. STENCH. REFRIGERATE. REGULATORY INFORMATION THIS PRODUCT IS SUBJECT TO SARA SECTION 313 REPORTING REQUIREMENTS. ------------------- ADDITIONAL PRECAUTIONS AND COMMENTS ------------------SECTION 9 FOOTNOTES CAUTION: CONTACT WITH AZIDES OR ACTIVE METALS SUCH AS SODIUM, POTASSIUM, ZINC, ETC., MAY CAUSE FIRES AND EXPLOSIONS. THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT BUT DOES NOT PURPORT TO BE ALL INCLUSIVE AND SHALL BE USED ONLY AS A GUIDE. SIGMA-ALDRICH SHALL NOT BE HELD LIABLE FOR ANY DAMAGE RESULTING FROM HANDLING OR FROM CONTACT WITH THE ABOVE PRODUCT. SEE REVERSE SIDE OF INVOICE OR PACKING SLIP FOR ADDITIONAL TERMS AND CONDITIONS OF SALE { DO 085475 C0NFTD5NTIAI