Document LKGL0236r84okmwbK9NGdRdX
Ur,
INTERNAL CORRESPONDENCE
AIMING AND METALS DIVISION
> (Nans)
iviaiOA cation
Messrs. R. E. Byrne, Jr. J. V. Murray J. L. Myers W. C. Thurber*'
>pr * File
P. 0. BOX 579, NIAGARA FALLS, NEW YORK 14302
Do*. February 4, 1975
Originoting (>*.
"Calidria" Asbestos
Antwaring Uttar data
"Calidria" Asbestos Health and OSHA Information February 1, 1975
The final version of the above information package for f?G-?4d and RG-600 are attached. We expect to be revising this periodically as more information becomes available. Any comments or suggestions on how it may be improved will be welcome.
HBR:cjb Attachments
H. B. Rhodes
"CALIDRIA" ASBESTOS HEALTH AND OSHA INFORMATION
February 1, 1975
Union Carbide Corporation Mining and Metals Division
"Calidria" Asbestos Marketing and Technology Department
Niagara Falls, New York
INTRODUCTION
The Williams-Steiger Occupational Safety and Health Act was passed in 1970 with the stated objective of assuring every American worker a safe and healthy workplace. The first health standard promulgated under this act covered exposures to airborne asbestos and went into effect on June 7, 1972. This asbestos standard survived a broadside legal attack filed by the IUD and is now being revised by OSHA to clear up certain ambiguities. The revised version is expected about midyear 1975.
Asbestos has received a great deal of attention and publicity in the last several years. Unfortunately, much of the media treatment of the subject has been emotionally oriented and distorted and, in some cases, bordering on the sensational and untrue. Many users of asbestos and products containing asbestos have been mislead regarding the safety of asbestos and what is needed to comply with the OSHA requirements.
The information presented in this folder has been collected as a service to "Calidria" asbestos users. It is intended to help put both the health and OSHA compliance questions in a reasonable perspective. Included are:
1. A suimary of the main provisions of the OSHA Asbestos Standard and a copy of the regulations.
2. Airborne asbestos fiber count data obtained by Union Carbide at a variety of industrial locations during the blending of RG-244 into polyester resin, the spraying of the asbestos containing resin, and the sanding and grinding of the finished parts.
3. Two pamphlets, "What Every Employee Should Know About Asbestos" and "Asbestos and Health" published by the Asbestos Information Association/North America. The first is an employee oriented discussion of both health and OSHA while the second addresses the health question. Additional copies are available on request.
4. A Material Safety Data sheet and analytical data on "Calidria" asbestos.
OSHA REGULATIONS
Introduction
After extensive public hearings, a standard for Exposure to Asbestos Dust was published in the Federal Register, Volume 37, No. 110 on Wednesday, June 7, 1972. A copy of this standard is included with the literature at the back of this booklet.
Basically, the standard can be divided into the following five major categories:
1. Standards:
Defines the allowable airborne asbestos fiber content in the workplace.
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2. Monitoring:
Defines the method of collecting samples and measuring the airborne fiber concentration.
3. Methods of Compliance:
Defines acceptable procedures to met the allowable limits.
4. Medical:
Specifies frequency and type of medical examinations required.
5. Warning Signs and Labeling:
Specifies when warnings are necessary and the wording of such warnings.
The essential features of these categories are discussed in the remainder of this section. Before looking at these, however, it should be made clear that in the most basic sense the regulations require that every place of employment where asbestos is used must be monitored to determine the exposure level of airborne asbestos fibers, if the levels are well within the allowable limits, the only additional requirements are those relating to medical examina tions. If the levels are not clearly within compliance, all provisions of the regulations apply. There has been a great deal of confusion on this distinction, occasionally even with OSHA field inspectors.
Standards
The present OSHA standards set a maximum exposure to airborne asbestos fiber of length longer that 5y of:
1. An 8-hour, time-weighted average (TWA) of 5 fibers/cc.
2. A ceiling concentration of 10 fibers/cc.
On July 1, 1976, the allowable TWA is reduced to 2 fibers/cc. The ceiling concentration remains unchanged.
Note particularly the use of the time-weighted average over the 8hour shift. An operator performing one or two short additions of RG-244 per shift, as is typical of polyester producers, would have his exposure during the dumping time averaged with zero (or a very low background level) for the rest of the shift. This, obviously, tends to greatly reduce the 8-hour TWA.
Monitoring
The regulations require an initial monitoring to determine whether the workplace meets the required levels. Thus:
"Within six months of publication of the regulations (June 7, 1972), every employer shall cause every place of employment where asbestos fibers are released to be monitored in such a way as to determine where every employee's exposure to asbestos fibers is below the prescribed limits."
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Monitorying usually is done by the membrane filter/personal air sampler, which can be obtained from a number of manufacturers.
The personal air sampler draws workplace air onto a filter which collects the particulates and fibrous dust in the air. This filter is then placed under a microscope and the number of fibers counted. After the count is complete, the actual fiber concentrations, expressed as fibers per.cubic centimeter of air, are calculated by formula.
After the initial monitoring, the regulations state:
"...samples shall be of such frequency and pattern as to represent with reasonable accuracy the levels of exposure of employees. In no case shall the sampling be done at intervals greater than 6 months for employees whose exposure to asbestos may reasonably be foreseen to exceed the limits prescribed by paragraph (b) of this sectionT"
The section that has been underlined shows that if the initial monitoring give levels that are well below the allowable limits and no change is made in the method of operation which would increase dust levels, no further monitoring is required. It is a good and recommended practice, however, to monitor at regular intervals to make sure that the limits are being met.
It should also be understood that you cannot be cited legally for exceeding the allowable limits on the basis of your own monitoring. OSHA must base any citations issued on their own tests.
Methods of Compliance
If monitoring shows a^ plant or operation to be J_n excess of the limits, a number of ways are prescribed to bring it into compliance. These include, but are not limited to, engineering controls such as isolation, enclosure, exhaust ventilation, and dust collection. Certain work and housekeeping practices and waste disposal procedures are specified. Respirators, special clothing, and change rooms are also required under certain conditions.
It is most important to understand that these compliance procedures are required only if the allowable airborne asbestos fiber limits are being exceeded or can be expected to be exceeded under reasonably foreseeable circumstances. They are not automatic requirements that apply wherever asbestos is present.
Medical Examinations
Preplacement, annual, and termination medical examinations must be provided or made available by the employer for any employee "...engaged in occupations exposed to airborne concentrations of asbestos fibers." These medical records must be kept for 20 years and are available to the employee's physician.
This section has proved to be one of the most confusing in the regulations since it does not define any cutoff level below which examinations are not required. OSHA has declined to provide any official clarification but reports from plants that have been inspected indicate that they are generally taking the very reasonable approach of requiring examinations for employees who regularly handle asbestos, who are regularly in the area where
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asbestos is being handled, and for maintenance personnel who work on asbestos handling equipment. It is anticipated that the revised regulations will provide a more specific definition such as that originally proposed by NIOSH in the Criteria Document:
"For purposes of this requirement the term 'exposed to asbestos1 will be interpreted as referring to time-weighted average exposures above 1 fiber/cc or peak exposures above 5 fibers/cc."
Caution Signs and Labeling
The regulations require that:
"Caution signs shall be provided and displayed at each location where airborne concentrations of asbestos fibers may be in excess of the exposure limits prescribed in paragraph (b) of this section."
Wording for the signs is also specified.
There have been some cases where the OSHA inspectors have taken this to mean signs are required at any location where asbestos is present, regardless of whether or not the exposure limits are exceeded. Although this is clearly, incorrect, there has been a tendency to post the signs and not contest the * citation.
The regulations also require that:
"Caution labels shall be affixed to all raw materials, mixtures, scrap, waste, debris, and other products containing asbestos fibers, or to their containers, except that no label is required where asbestos fibers have been modified by a bonding agent, coating, binder, or other material so that during any reasonably foreseeable use, handling, storage, disposal, processing, or transportation, no airborne concentrations of asbestos 7ibers in excess of the exposure limits prescribed in paragraph (b) of this section will be released."
Wording for these labels is also specified.
AIRBORNE ASBESTOS FIBER COUNTS
Introduction
This section presents air sampling data obtained in a variety of situations, mostly for typical industrial operations. All samples were collected on Mi Hi pore filters and counted at 400X with phase contrast illumination in accordance with OSHA procedures. Particles which satisfied the L/D >3 criteria but which, in the judgment of an experienced counter, could not possibly be asbestos were not included in the counts.
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Presentation of Data
Table I shows "Calidria" asbestos RG-244 fiber counts obtained at 8 different polyester manufacturing plants. Typically, several hundred pounds of RG-244 are dumped into the thin tank in a 10-25 minute period. These samples obtained during the dumping operation thus represent ceiling concen trations. They would normally be averaged with considerably lower numbers for the remainder of the shift when asbestos is not being handled to arrive at the TWA. The highest fiber count found at these eight locations was 2.8 fibers/cc which is well below the allowable limit of 10 fibers/cc.
Table II shows the fiber counts at three of the same manufacturing locations at the empty bag collection point. These values are also quite low.
Table III shows airborne fiber counts for "small-scale" addition of RG-244 as occurs in a variety of compounding operations. The levels found ranged from 0.4 to 2 fibers/cc.
Table IV shows the airborne asbestos fiber count data obtained during the spraying of a variety of asbestos containing resins. Much of the data are for polyester resins, but epoxies and alkyds are also included. The asbestos content of the resins ranged from 0 to 12% by weight. The highest count obtained was 0.6 fiber/cc.
Polyester resin parts are often finished by sanding or grinding. Table V shows the airborne asbestos fiber counts obtained during a number of industrial finishing operations on resins with up to^X asbestos. The highest reading obtained here was 0.4 fiber/cc.
Table VI gives the results for a laboratory study where resin plaques containing a variety of fillers were abraided with an electric hand grinder in a small closed room. Even under these extreme conditions, the fiber counts were quite low with 1.2 fibers/cc, the highest observed.
TABLE 1 AIRBORNE ASBESTOS FIBER COUNTS(1*"LARGE-SCALE" DUMPING OF RG-244 KI00-450 1b./Batch)
Plant A B C
D E F G
H
Data Reference
--
1929-46-2 1929-30-2
1929-56-1 1929-50-3 1929-26-3 1929-24-2
1929-16-1
Description of Operation
Dump Sample
Bags Time
Time
Dunped (Min.) (Min.)
Special Ventilation(2)
10 10 10 None
14 9 9 None
15 21 21 Hood over thin tank opening
36 12 12 None
15 8 8 None
45 20 20 None
10 24 24 Hood over mixing area
28 15 15 None
CEILING Concentration Fiber Count
(Fibers/cc. >5^-) 0.7 1.2 0.7
2.4 0.5 1.6 0.8
2.8
^All samples collected in the breathing zone of the operator dumping the RG-244.
^Special ventilation refers to dust collection equipment at or near the dumping area that is specifically intended for dust control during the dumping operation. All plants had varying measures of overall building ventilation.
TABLE II
AIRBORNE ASBESTOS FIBER COUNTS EMPTY BAG REMOVAL
Plant A
B B
Data Reference
1929-40-3 1929-40-5
Description of Operation
Sample taken 3 feet above waste disposal drum for empty bags. (During dumping.)
Directly over empty bag stacking area. Taken during dump.
Empty bag storage area. Taken during dump as bags were put in.
Sample Time
(Min.) 10
23
24
Fiber Count (Fibers/cc.
0.4
0.6
0.4
TABLE III
AIRBORNE ASBESTOS FIBER COUNTS*1) "SMALL-SCALE" DUMPING OF RG-244 (1-12 lbs./Batch)
End Use
FurnHiture Molnding .11 II II II
Pounds Dumped
1 12
1 6
Dump Time (Min.)
10 2.5
11 8
Sample Time (Min.).
Special Ventilation'*'
10 2.5
11 8
None None None Good Hood
Ceiling Concentration Fiber Count
Fibers/cc >5u
1.5 1.1 2.0 0.9 -
GIeI l CIoI at MIIfg.
9 25 25 333
None None
0.7 1.2
ArtifiIIcial BrIiIck MIIfg.
5 1.5
4 10
4 10
Good Hood
0.9 0.4
Roof Coating Mfg.
12 13 13
None
1.1
^ All samples collected in the breathing zone of the operator dumping the RG-244.
(2)
Special ventilation refers to dust collection equipment at or near the dumping area that is specifically intended for dust control during the dumping operation. All plants had varying measures of overall building ventilation.
table nr
AIRBORNE ASBESTOS FIBER COUNTS SPRAYING Of RESIN BASEO SYSTEMS CONTAINING ASBESTOS
Suble
CownercUl
1 - POLYESTER RESINS A. General Puroose LMilnatlnq Resins
69 Boat nanufacture. 12/7/72
Binder
General purpose lanlnatlng resin.
1-13
10/31/74
N-28 N-30
N-34
M" 1-12
10/8/74 41
ft
Appro*-^
laate Ht. X Asbestos
Sorav Gun Type
Ooeratlon
Sanple Tine
(Hln.l
Airborne Asbestos
Fiber Concentration
IFlbers/ce >S^)
O.S Air-supported Operator spraying
chopper.
olds with resin
A chopped glass.
24
O.S 0.S 0.5
0.5 0.5 0.5
Operator spraying resin A chopped fiber glass. (Includes roll-out tine.)
Operator spraying resin A chopped fiber glass.
Operator spraying resin A chopped fiber glass.
Operator spraying old with resin. (No glass.)
16 S 4
55 53 35
0.6
0.1 0.4 0.4
0 0.03 0.1
B. Chemical Resistant Resins
J-21
Fiber-glass pipe nanufacture.
8/13/74
H-2S
Chenlcal resistant resin.
1.4 Airless. 1.4
Operator adjacent' to autonattc spray achlne coating 281 nandrels.
Operator wiping nandrels. In area near spraying.
23 0.1 14 0.4
J-5
Ship coating.
10/3/74
Chenlcal
0.7 Air-supported Roll-out nan. In
65 0.4
resistant
wand.
spraying area about
resin + chopped
1/4 of tine.
fiber glass.
J-7
ft
0.7 ft
Operator spraying
41 0.4
ship hull in dry
dock.
N-23
-
0.7 ft
ft 23 0
(1) Based on toUl fornilatlon *s sprayed.
TABU IV (continued!
AIRBORNE ASBESTOS FIBER COUNTS SPRAYING OP RESIN BASED SYSTEMS CONTAINING ASBESTOS
Saa*>lt )*sianat1on
Coanerclal Application
: - EPOtY RESIAS
A. Filled Epoxy
K-8 Ship coating.
Date 10/2/74
K-10 H-10
1-27 J-l
0
B. Eooxy - Coal Tar
M-4S
Coating dry dock. 10/1/74
N-l
K-3
Coating pipe
Interiors.
II - ALKYD RESIN PAINT
H-7 Painting 10/6/74 building exterloc
N-35
Binder
Approx-^
(MU Ht. S Asbestos
Sorav Cun Type
Epoxy prlwr.
High build epoxy.
l.s Airless. 1.5
0 Air supported. 0 0
Epoxy Coal-tar, solvent.
1 1 1
Airless.
Air-supported uand.
Alkyd resin.
12 12
Airless gun.
Operation
Operator spraying outside t under a ship.
Operator spraying side of ship froa scaffold.
m
m
Operator spraying side of dry dock froa suspended platfona. Operator spraying side of dry dock froa fixed scaffold. Operator spraying Interior of 3", 6* and 12* dlaaeter pipe.
Operator spraying building exterior tall.
Saeple Tint
fMln.l
Airborne
Asbestos Fiber
Concentration
IFIbers/cc >5^.'
33 0.2 8 0.2 31 0.1 14 0.3 60 0.03
* 11
0.2
38 0 37 0.1
90 S 0.06
1) Btscd on total foraulatlon as sprayed.
TABLE
AIRBORNE ASBESTOS FIBER COUNTS CRINOINC AND SAHOIHC Of RE51V6ASEP SYSTEMS CONTAINING ASBESTOS
Saxple Designation
Connerclal Application
I. THERWSET RESIN (Polyester)
-- Holding furniture parts
Data
3/1S/72
Resin
Polyester
1929-40-4
12/6/72
1929-82-3 1929-82-4 1929-82-S 1-13 1-6
Fabrication of reinforced fiber glass pipe.
2/27/73
Polyester
8/13/74
1-26 G-8 1-39
Fabrication of FRP tanks and pipe.
8/13/74
Polyester
1929-84-4 1929-84-S
Production of artificial bricks.
N-20 N-25
Production of fiber glass boats.
3/8/73 m
Polyester
11/26/74
Polyester
Asbestos
Approx.
Type
Wt. X
Ooeratlon
SeMple Time
(Hln.)
Airborne Astestos Fiber Concentration
(Flbers/cc >5*)
RG-244
0.05 0.05
0.3
RG-144
2-3
RG-244
2-3 2-3 1.4
1.4
RG-244 m m
1.5 1.5 1.5
RG-244
2.0 2.0
Operator hand sanding small parts.
Operator running paver sender with Integral hood.
Operator sanding and grinding molded parts. Good hood 1 ventilating systea on grinder.
45 45
23
Operator pulls pipe along line. Saws off end with circular saw.
19
Same operation as 192982-3.
49
Operator removing end of 45 pipe with scarfing machine.
Operator shaping end of pipe with bell 6 spigot aachlne.
16
Operator cutting off pipe end and light grinding
on extertor surface.
17
Operator grinding Inside of 13' 1.0. x 26' tank.
Continuation of same operation as 1-26.
Operator grinding edges of Miscellaneous saall parts.
16 5 25
Operator cutting with sabre saw.
Operator trieming with sabre saw.
44 39
RG-244
0.5 0.5
Operator grinding Inside of boat hull.
Operator grinding.
11 4
0.002 0.002 0.3
0.1 0.1 0.04 0.3 0.2
0.4 0.3 0.3
0.1 0.2
0.0 0.0
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J
RULES AND REGULATIONS
Title 29--LABOR
Chapter XVII--Occupational Safety and Health Administration, Depart*
ment of Labor
PART 1910--OCCUPATIONAL SAFETY
AND HEALTH STANDARDS
Standard for Exposure to Asbestos
Dust
On December 7. 1971, an emergency temporary standard concerning exposure to asbestos fibers was published in the Federal Register (36 F.R. 23207). In ac cordance with section 6(c) (3) of the Williams-Steiger Occuptaional Safety and Health Act of 1970, a notice of proposed rulemaking regarding a permanent standard for exposure to asbestos fibers was published in the Federal Register on January 12. 1972 (37 Fit. 466). The no tice Invited interested persons to submit both orally and in writing, data, views, and arguments concerning the proposal.
On or about January 24,1972, the Ad visory Committee on Asbestos Dust was established and requested to make writ ten recommendations with regard to the proposed standard on asbestos. On or about February 1. 1972, the Department of Health, Education, and Welfare trans mitted to the Secretary of Labor a cri teria document containing Recommenda
tions for an Occupational Exposure exposure to asbestos fibers and the ap
Standard for Asbestos by the National pearance of adverse biological manifes
Institute for Occupational Safety and tations, such as asbestosis, lung cancers,
Health (NIOSH). Public notice was given and mesothelioma, have given rise to
of the receipt of the recommendations controversy as to the validity of the
and their availability for inspection and measuring techniques used and the relia
copying. On or about February 25, 1972, bility of the relations attempted to be
the Advisory Committee on Asbestos Dust established. Because of the long lapse
submitted its written recommendations of time between onset of exposure and
to the Assistant Secretary of Labor for biological manifestations, we have now
Occupational Safety and Health.
evidence of the consequences of exposure,
Pursuant to the notice of rule making, but we do not have, in general, accurate
a hearing was held on March 14 through measures of the levels of exposure oc
17.1972, for the purpose of receiving oral curring 20 or 30 years ago. which have
data, views, and arguments concerning given rise to these consequences. There
the proposed standard. On or about are also controversies concerning the
March 31,1972, the presiding hearing ex relative toxicity of the various kinds of
aminer certified to the Assistant Secre asbestos, and varying hazards in dif
tary of Labor for Occupational Safety ferent workplaces.
and Health the record of the proceeding. It is fair to say that the controversy
The record includes prehearing written has centered in the area between a two-
comments, a transcript of the oral pres fiber TWA concentration and five-fiber
entations made at the hearing, and nu TWA concentration, with variations on
merous exhibits received during the the time needed for compliance. Many
course of the hearing or within the pe employers support a five-fiber TWA.
riod allowed after the close of the Most medical opinion is divided between
hearing.
a two-fiber standard and a five-fiber
The proposed standard dealt with (1) standard.
permissible concentrations of asbestos In view of the undisputed grave con
fibers; (2) methods of compliance; (3) sequences from exposure to asbestos
warning signs; (4) monitoring; (5) med fibers, it is essential that the exposure be
ical examinations; and (6) recordkeep regulated now, on the basis of the best
ing. Each of these major proposals elic evidence available now. even though it
ited comments, arguments, objections, may not be as good as scientifically de
and counterproposals. They all have been sirable. An asbestos standard carr be re
examined and considered.
evaluated in the light of the results of
1. Acceptable concentrations of asbes ongoing studies, and future studies, but
tos dust. The proposed standard would cannot wait for them. Lives of employees
limit occupational exposure to 6-hour are at stake.
time-weighted average (TWA) airborne It is concluded that there should be concentrations of asbestos dust not ex one minimum standard of exposure to ceeding five fibers longer than five asbestos applicable to all workplaces ex
micrometers per milliliter. Concentra posed to any kind, or mixture of kinds, tions above five fibers but not to exceed of asbestos. Reasons of practical ad
10 fibers (ceiling concentration) would ministration preclude a variety of stand
be permitted up to 15 minutes in an hour, ards for different kinds of asbestos and
but for not more than 5 hours in any one of workplaces. Also, while the evidence
8-hour day.
tends to show that crocidolite, for in
NIOSH in effect has recommended stance. is more harmful than chrysotile,
that the five-fiber TWA and 10-flber the evidence is not sufficient to establish peak concentrations be permitted only separate standards for varieties of for 2 years; thereafter, TWA concentra asbestos.
tions should be not more than 2 fibers Because there must be one standard
per cubic centimeter (cm.*) of air, and governing exposure to all varieties of peak concentrations should not exceed 10 asbestos, and in workplaces apparently
fibers/cm.*, with no time restriction. more hazardous than others; because Numerous objections and counterpro some present employees with regular ex
posals have been made, with regard to both the limits of asbestos fiber concen trations and the time periods to comply with them. Some, for example, have rec ommended return to a 12-flber standard of an earlier day; l.e., a level adopted under the Walsh-Healey Public Con tracts Act in 1969. Others have recom mended a two-fiber standard to become effective in 6 months, then a one-fiber
standard for 2 years, and finally a zerofiber standard after 3 years. These rec ommendations give a fair indication of the wide spread of the counterproposals.
posure to asbestos have probably al ready accumulated great doses of asbes tos fibers, due to higher levels of ex posure in the past; because it appears that levels of exposure which may be safe with regard to asbestosis are not safe with regard to mesothelioma; be cause the statute requires the protection of every employee, even of one who may have regular exposure to asbestos during a working life which may reach, or even exceed, 40 years: and because of several other considerations which have been urged and are reflected in the record of
No one has disputed that exposure to the proceeding, the conflict in the medi
asbestos of high enough Intensity and cal evidence is resolved in favor of the
long enough duration is causally related health of employees. As of July 1, 1976,
to asbestosis and cancers. The dispute is TWA concentrations of asbestos fibers
as to the determination of a specific level longer than 5 micrometers will not be
below which exposure is safe. Various allowed to exceed two flbers/cc., with a
studies attempting to establish quantita ceiling value of 10 flbers/cc. The current
tive relations between specific levels of TWA concentrations of five fibers, and
FEOERAl REGISTER, VOL 37, NO. 110--WEDNESDAY, JUNE 7, 1972
RULES AND REGULATIONS
11319
celling concentrations of 10 flbers/ce. fibers, so that these would not be released 8. Records. The standard, as proposed
will be permitted until July 1, 1976, dur- in the normal use of the products, should and as adopted, requires maintenance of
ing what will be a transitional period not be required to be labeled; and (2) records of monitoring and of medical
deemed necessary to allow employers to words such as "danger" and "cancer" are examinations. Most of the controversy In
make the needed changes for coming unwarrantedly alarming.
this area has revolved around the ques
Into compliance with the more stringent Both contentions have merit, and the tion whether an employer should be al
standard.
standard has been changed accordingly. lowed to have access to the results of
The record shows that the many work 4. Monitoring. The proposed standard the required medical examinations. The
operations subject to the single asbestos would have required personal monitor apprehension of those who have argued
standard (textile, manufacturing, indus ing and environmental monitoring. against employer access is based on the
trial. and marine Installation, etc.) will Many issues have been raised concerning expectation that some employers will use
meet varying degrees of difficulty in the availability and reliability of meas the medical examinations as a means of
complying with the standard. In some uring instruments, frequency of moni screening employment applicants, and
plants, extensive redesign and reloca toring, and conditions In which monitor worse, as grounds for discharging current
tion of equipment may be needed. It ap ing should be required. The adopted employees, who show signs of being af
pears. however, the delay In the effective standard takes the objections Into con fected by exposure to asbestos. Since the
date of the two-fiber standard will pro sideration. It requires periodic monitor purpose of the medical examinations is
vide all employers a reasonable time to ing at intervals no longer than 6 months, to monitor the health of employees ex
comply. At the same time, so long as the thus allowing considerable time and dis posed to the hazards of abestos, em
ceiling limit Is complied with, no harm cretion, and prescribes the use of the ployees cannot in reason be granted the
Is reasonably expected to result from ex membrane filter method, which Is an ac privilege of refusing to disclose to their
posures during the transitional period. ceptable method for determination of employers results of occupational expo
2. Methods of compliance. It has been asbestos libera.
sure. It does not make sense to require
pointed out by many persons, that pro It has also been recommended that employers to provide medical examina
tection against asbestos fibers Is best employees or their representatives should tions if they cannot know and use the
obtained by controlling the generation of have an opportunity to observe the results of the examinations. For these
fibers first, and secondly, by controlling monitoring. The recommendation has reasons the standard provides that em
the dispersion of released fibers Into the been accepted.
ployers may have a restricted access to
ambient air of the workplaces. Therefore, S. Medical examinations. The pro some medical information.
the standard requires feasible techno logical controls and appropriate work
posed standard would only require an appropriate medical examination on a
On the other hand, there Is no Inten tion to allow employers to abuse medical
practices as the primary means of com pliance. Rotation of employees as a way of meeting the TWA concentration re
periodic basis. The generality of the pro posal has attracted many objections and also many helpful comments. The recom
Information obtained pursuant to the Act, to the detriment of employees. Therefore, the administration of the
quirement is allowed only In stated ex mendations of NIOSH and of the Advi medical records requirement will be
ceptional circumstances, because, as a general rule, it would be difficult to Im
sory Committee on Asbestos Dust were much more specific with respect to both
closely watched, and. in cases of abuse, appropriate action will be considered.
plement. Personal protective equipment, such as respirators, cannot be relied upon because, among other reasons, they may be so uncomfortable as to be bur densome. except for short periods of time. Therefore, it Is expected that res pirators and shift rotation will be used during the period necessary to install en gineering controls and to train employ ees in sound work practices, but, after technological compliance has been achieved, their use must be limited to special work situations and emergencies. Where both are practicable, shift rota tion is required.
3. Labeling. The proposed standard stopped short of requiring labeling as
frequency and type of medical examina
tions to be required. The comments vary
as to the class of employees to be ex
amined and as to the frequency of the
examinations.
The adopted standard requires medical
examinations both at the beginning and
the termination of employments exposed
to concentrations of asbestos fibers, and
also requires
medical examina
tions of every employee exposed to air
borne concentrations of asbestos. It has
been pointed out that in certiO indus
tries, such as construction, an employee
may work for several employers during
the same year. Accordingly, the standard
does not require either preemployment,
The Issues discussed above are believed to be the major ones. Numerous other is sues have been raised in the rulemaking proceedings. Some have been referred to incidentally. Many recommendations, for instance, about work practices, are so obviously meritorious that their adop tion needs no exposition here, other recommendations and many objections have not been adopted for a variety of reasons which should be manifest. Sev eral, for Instance, have recommended the use of respirators only pursuant to a variance, or in cases of emergency and
occasional short-term exposures. The
recommendation with respect to vari
bestos and asbestos-containing products. or termination, or periodic examinaton ances undoubtedly has many merits,
The proposed standard would have re of any employee who has been examined but is considered administratively im
quired only warning signs at locations in accordance with the standard within practical.
where asbestos hazards are present. However, labeling, rather than warning signs, has proved to be a point of con troversy. Both NIOSH and the Advisory Committee on Asbestos Dust recom mended labels for asbestos products and containers, and these recommendations became very controversial in the course of the proceeding. Many counterproproposals have been made as to the lan guage of the warning as well as to the
products to be subject to the labeling requirements. Employers. In general,
the past year.
One question which has been raised goes to whether the employer or the em ployee should be allowed to choose the examining physician. The standard gives the option to the employer. Bince some employers already have a medical examination program in operation, and, also, have medical departments with some expertise In the diagnosis of abestoe-related diseases. It seems more reasonable to permit them to utilize the present programs and expertise, than to
Accordingly, after consideration of the whole record of the proceeding, and pursuant to sections 6 (b) and (c) and 8(c) of the Willlams-Steiger Occupa tional Safety and Health Act of 1970 (84
Stat 1S93, 1596, 1599; 29 UB.C. 655, 657), 29 CFR 1910.4, and to Secretary of Labor's Order No. 12-71 (36 FJL 8754). Part 1910 of Title 29 of the Code of Fed eral Regulations is amended as set forth below.
strongly contend that (1) finished prod permit an employee to choose a private (1) Section 1910.93 is amended by re
ucts which effectively entrap asbestos general practitioner.
vising Table G-3 to read as follows:
FEDEIAL tEGISTEK, VOL 37, NO. 110--WEDNESDAY, JUNE 7, 1972
11320
RULES AND REGULATIONS
1910.93 Air contaminant*.
to which any employee may be exposed <d) Personal protective equipment--
shall not exceed two fibers, longer than (I) Compliance with the exposure limits
Tabu G---Itoraoi Dim
S micrometers, per cubic centimeter of prescribed by paragraph (b) of this sec air. as determined by the method pre tion may not be achieved by the use of
Subetonee
Mppe(
VeltP
scribed in paragraph (e) of this section. respirators or shift rotation of em (3) Ceiling concentration. No em ployees, except:
Blllco:
ployee shall be exposed at any time to (1) During the time period necessary
Crystalline: Quart! (raplrublt)
280' tOnsg/K*
airborne concentrations of asbestos fibers in excess of 10 fibers, longer than
to Install the engineering controls and to institute the work practices required
Quart! (total dual) CristobalH: U H the
value calculated from the count or mam lotxaulee tor quarla. Trldymlle: Ute K the value calculated (ran the for mulae tor quaru. Amorphous, Including natural diatomaceour earth...............
5 micrometers, per cubic centimeter of by paragraph (e) of this section;
20
%OH-2
SOrng/M* %S10i
air, as determined by the method pre scribed in paragraph (e) of this section.
to) Methods of compliance--(1) En gineering methods. (1) Engineering con trols. Engineering controls, such as, but not limited to. isolation, enclosure, ex haust ventilation, and dust collection, shall be used to meet the exposure limits prescribed in paragraph (b) of this
section.
(li) In work situations in which the methods prescribed in paragraph (c) of this section are either technically not feasible or feasible to an extent insuffi cient to reduce the airborne concentra tions of asbestos fibers below the limits prescribed by paragraph (b) of this section: or
(ill) In emergencies.
ftav thin 1% err lullinc silica):
Mica...................................... Ponpstone............................. T*lc....................................... Portland cement.................. Graphite (natural).................. Coot dost (respirable fraction
SO SO 80 18
(11) Local exhaust ventilation, (a) Local exhaust ventilation and dust col
lection systems shall be designed, con structed. installed, and maintained in accordance with the American National Standard Fundamentals Governing the
(iv) Where both respirators and per sonnel rotation are allowed by subdivi sions (1), (11), or (ill) of this subpara graph, and both are practicable, person nel rotation shall be preferred and used.
(2) When a respirator is permitted by
lea than 6% 8iOj)................................... For more than 5^ 610*....................
2.4m*/M or
I0mg/ll*
Design and Operation of Local Exhaust Systems, ANSI 29.2-1971, which is in
subparagr&ph (1) of this paragraph, it shall be selected from among those ap
Jnrrl or Nuisance Oust: Kivpirttble fraction.............. ToliU dust............................
%B10r+S
18 Bibr/M1 80 IBmg/M*
Note: Conversion factor*-- p>ppcfXA5.3-million ptrUeles per cubic Deter
- particles per c.c. i Millions oi particles per cubic- foot of air, baaed on liiifiinffr samples counted by light-field technics. < The percentage of crystalline tUtaa In the fontrala L the amount determined from alr*borne aamptes, except In those Instances in which other methods nave been shown to be applicable. As determined by the membrane Alter method at 430 x plttac contrast magnification. both concentration and percent quarts for the appitenifann of this limit are to be determined from Die fraction passing a size-selector with the following
characteristics:
At-ruilynarntc diameter vumt density sphere)
2 J.S 3.6 &.0 1U
Percent pairing elector
00 78 80 28 0
The measurements under this note refer to the use of an A EC instrument. If the respirable fraction of eoa! dust is determined with a MRE the figure corresponding to that of 2.4 Mg/M4 in the table for coal dust Is 44 Mg/M*.
2. A new S 1910.93a is added to Part 1910, reading as follows:
1910.93a Asbestos.
(a) Definitions. For the purpose of this section. (1) "Asbestos" includes chrysotlle. amoslte, croddolite, tremollte, anthophyllite, and actinollte.
(2) "Asbestos fibers" means asbestos fibers longer than 5 micrometers.
(b) Permissible exposure to airborne concentrations of asbestos fibers--(1) Standard effective July 7, 1972. Hie 8-hour time-weighted average airborne concentrations of asbestos fibers to which any employee may be exposed shall not exceed five fibers, longer than 5 micrometers, per cubic centimeter of air, as determined by the method pre scribed in paragraph <e) of this section.
corporated by reference herein.
<b) See 5 1910.8 concerning the avail ability of ANSI Z9.2-1971, and the maintenance of a historic file in connec tion therewith. Hie address of the Amer ican National Standards Institute is given in 11910.100.
(ill) Particular tools. All hand-op erated and power-operated tools which may produce or release asbestos fibers In excess of the exposure limits pre scribed in paragraph (b) of this section, such as. but not limited to. saws, scorers, abrasive wheels, and drills, shall be pro vided with local exhaust ventilation sys tems in accordance with subdivision (U) ol this subparagraph.
(2) Work practices--(1) Wet methods. Insofar as practicable, asbestos shall be
handled, mixed, applied, removed, cut, scored, or otherwise worked in a wet state sufficient to prevent the emission of airborne fibers in excess of the ex posure limits prescribed in paragraph (b) of this section, unless the usefulness of the product would be diminished thereby.
(U) Particular products and opera tions. No asbestos cement, mortar, coat ing, grout, plaster, or similar material containing asbestos shall be removed from bags, cartons, or other containers in which they are shipped, without being either wetted, or enclosed, or ventilated so as to prevent effectively the release of airborne asbestos fibers in excess of the limits prescribed in paragraph <b) of this section.
(ill) Spraying, demolition, or removal. Employees engaged in the spraying of asbestos, the removal, or demolition of pipes, structures, or equipment covered or insulated with asbestos, and in the removal or demolition of asbestos in sulation or coverings shall be provided with respiratory equipment in accord ance with paragraph (d)(2) (ill) of this
proved by the Bureau of Mines, Depart ment of the Interior, or the National In stitute for Occunatlonal Safety and Health, Department of Health. Educa tion. and Welfare, und-r the provisions of 30 CFR Part 11 <37 F.R. 6244, Mar. 25. 1972), and shall be used in accordance with subdivisions (D. (11), (ill), and (lv) of this subparagraph.
(i) Air purifying respirators. A reusa ble or single use air purifying respirator, or a respirator described in subdivision (il) or (ill) of this subparagraph, shall be used to reduce the concentrations of airborne asbestos fibers in the respirator below the exposure limits prescribed In paragraph (b) of this section, when the ceiling or the 8-hour time-weighted aver age airborne concentrations of asbestos fibers are reasonably exnected to exceed no more than 10 times those limits.
(U) Powered air purifying respirators. A full facepiece powered air purifying respirator, or a powered air purifying respirator, or a respirator described in subdivision (ill) of this subparagraph, shall be used to reduce the concentra tions of airborne asbestos fibers In the respirator below the exposure limits pre scribed In paragraph (b) of this section, when the ceiling or the 8-hour timeweighted average concentrations of asbestos fibers are reasonably expected to exceed 10 times, but not 100 times, those limits.
(ill) Type "C" supplied-air respirators, continuous flow or pressure-demand class. A type "C" continuous flow or pres sure-demand. supplied-air respirator shall be used to reduce the concentra tions of airborne asbestos fibers in the respirator below the exposure limits pre scribed in paragraph (b) of this section, when the ceiling or the 8-hour timeweighted average airborne concentra tions of asbestos fibers are reasonably
expected to exceed 100 times those limits.
(2) Standard effective July 1, 1976. section and with special clothing In ac (iv) Establishment of a respirator pro
Hie 8-hour time-weighted average air cordance with paragraph (d) (3) of this gram. (a) Hie employer shall establish
borne concentrations of asbestos fibers section.
a respirator program In accordance with
FEDERAL REGISTER, VOL 37, NO. 110--WEDNESDAY, JUNE 7. 1972
RULES AND REGULATIONS
11321
the requirements of the American Na where asbestos fibers are released to be subparagraph shall conform to the re
tional Standards Practices for Respira monitored In such a way as to determine quirements of 20" x 14" vertical format
tory Protection. ANSI Z88.2-1969. which whether every employee's exposure to signs specified in 11910.145(d)(4), and
is incorporated by reference herein.
asbestos fibers Is below the limits pre to this subdivision. The signs shall dis
b. See 11910.6 concerning the avail scribed in paragraph (b) of this sec play the following legend In the lower
ability of ANSI Z88.2-1969 and the main tion. If the limits are exceeded, the em panel, with letter sizes and styles of a
tenance of an historic file in connection ployer shall immediately undertake a visibility at least equal to that specified
therewith. The address of the American compliance program in accordance with In this subdivision.
National Standards Institute is given In paragraph <c> of this section.
Legend
{ 1910.100. (c) No employee shall be assigned to
(2) Personal monitoring--(1) Sam ples shall be collected from within the
Asbestos___________
tasks requiring the use of respirators If, breathing zone of the employees, on
Notation
1" Sans Serif. Oothlc or Block.
based upon his most recent examination, membrane filters of 0.8 micrometer po- Dust Hazard
4i" Sans Serif.
an examining physician determines that rosslty mounted in an open-face filter
Gothic or
the employee will be unable to function normally wearing a respirator, or that the safety or health of the employee or other employees will be impaired by his use of a respirator. Such employee shall
holder. Samples shall be taken for the determination of the 8-hour timeweighted average airborne concentra tions and of the ceiling concentrations of asbestos fibers.
Avoid Breathing Dust-- Wear Assigned Protective
Equipment. Do Not Remain In Area
Unless Tour Work Re
Block. V" Gothic. Vi" Gothic.
Vi" Gothic.
be routed to another job or given the (11) Sampling frequency and patterns. quires It.
opportunity to transfer to a different po After the initial determinations required Breathing Asbestos Dust 14 point Gothic.
sition whose duties he is able to perform by subparagraph (1) of this paragraph, May Be Hazardous To
with the same employer. In the same geo samples shall be of such frequency and Tour Health.
graphical area and with the same senior pattern as to represent with reasonable Spacing between lines shall be at least
ity. sUtus. and rate of pay he had Just prior to such transfer, if such a different
position is available. <3> Special clothing: The employer
shall provide, and require the use of, spe cial clothing, such as coveralls or similar whole body clothing, head coverings, gloves, and foot coverings for any em ployee exposed to airborne concentra tions of asbestos fibers, which exceed the ceiling level prescribed in paragraph <b> of this section.
(4) Change rooms: (i) At any fixed place of employment exposed to airborne concentrations of asbestos fibers in ex cess of the exposure limits prescribed In paragraph (b) of this section, the em ployer shall provide change rooms for employees working regularly at the place.
iii> Clothes lockers: The employer shall provide two separate lockers or containers for each employee, so separated or isolated as to prevent contamination of the employee's street clothes from his work clothes.
accuracy the levels of exposure of em ployees. In no case shall the sampling be done at Intervals greater than 6 months for employees whose exposure to asbestos may reasonably be foreseen to exceed the limits prescribed by paragraph <b> of this section.
(3) Environmental monitoring--(1) samples shall be collected from areas of a work environment which are represent ative of the airborne concentrations of asbestos fibers which may reach the breathing zone of employees. Samples shall be collected on a membrane filter of 0.8 micrometer porosity mounted in an open-face filter holder. Samples shall be taken for the determination of the 8hour time-weighted average airborne concentrations and of the ceiling con centrations of asbestos fibers.
(11) Sampling frequency and patterns. After the initial determinations required
by subparagraph (1) of this paragraph, samples shall be of such frequency and pattern as to represent with reasonable
equal to the height of the upper of any two lines.
(2) Caution labels--(1) Labeling. Cau tion labels shall be affixed to all raw materials, mixtures, scrap, waste, debris, and other products containing asbestos fibers, or to their containers, except that no label is required where asbestos fibers have been modified by a bonding agent, coating, binder, or other material so that during any reasonably foreseeable use, handling, storage, disposal, processing, or transportation, no airborne concentra tions of asbestos fibers in excess of the exposure limits prescribed in paragraph (b) of this section will be released.
(ii) Label specifications. The caution labels required by subdivision (i) of this subparagraph shall be printed in letters of sufficient size and contrast as to be readily visible and legible. The label shall state:
Caution
Contains Asbestos Fibers
<iii> Laundering: (a) Laundering of accuracy the levels of exposure of the
Avoid Creating Dust
asbestos contaminated clothing shall be employees. In no case shall sampling be
Breathing Asbestos Dust May Cause
done so as to prevent the release of air at intervals greater than 6 months for
Serious Bodily Harm
borne asbestos fibers in excess of the ex posure limits prescribed in paragraph (b) of this section.
(b> Any employer who gives asbestoscontaminated clothing to another person for laundering shall inform such person of the requirement in (a) of this subdi vision to effectively prevent the release of airborne asbestos fibers In excess of the exposure limits prescribed In para graph <b) of this section.
(c) Contaminated clothing shall be transported in sealed impermeable bags, or other closed, impermeable containers, and labeled In accordance with para graph (g) of this section.
(e) Method of measurement. All de terminations of airborne concentrations of asbestos fibers shall be made by the
membrane filter method at-400-450 X
employees whose exposures to asbestos may reasonably be foreseen to exceed the exposure limits prescribed in para graph (b> of this section.
(4) Employee observation of monitor ing. Affected employees, or their rep resentatives. shall be given a reasonable opportunity to observe any monitoring required by this paragraph and shall have access to the records thereof.
(g> Caution signs and labels. (1) Cau tion signs. (1) Posting. Caution signs
shall be provided and displayed at each location where airborne concentrations of asbestos fibers-may be in excess of the exposure limits prescribed in paragraph (b) of this section. Signs shall be posted at such a distance from such a location so that an employee may read the signs and take necessary protective steps be
(h) Housekeeping--(1) Cleaning. All external surfaces in any place of employ ment shall be maintained free of accu mulations of asbestos fibers if. with their dispersion, there would be an excessive concentration.
(2) Waste disposal. Asbestos waste, scrap, debris, bags, containers, equip ment. and asbestos-contaminated cloth ing. consigned for disposal, which may produce in any reasonably foreseeable use. handling, storage, processing, dis posal. or transportation airborne concen trations of asbestos fibers in excess of the exposure limits prescribed iff'paragraph (b) of this section shall be collected and disposed of in sealed impermeable bags, or other closed, impermeable containers.
(1) Recordkeeping--(1) Exposure rec ords. Every employer shall maintain rec
(magnification) (4 millimeter objective) with phase contrast illumination.
(f) Monitoring--(1) Initial determi nations. Within 6 months of the publi cation of this section, every employer shall cause every place of employment
fore entering the area marked by the signs. Signs shall be posted at all ap proaches to areas containing excessive concentrations of airborne asbestos fibers.
(11) Sign specifications. The warning signs required by subdivision (i) of this
ords of any personal or environmental monitoring required by this section. Rec ords shall be maintained for a period of at least 3 years and shall be made avail able upon request to the Assistant Secre tary of Labor for Occupational Safety and Health, the Director of the National
FEDEEAl REGISTEI, VOL 37, NO. 110--WEDNESDAY, JUNE 1, 1972
11322
RULES AND REGULATIONS
Institute for Occupational Safety and tions. Records shall be retained by
Health, and to authorized representa employers for at least 20 years.
tives of either.
(11) Access. The contents of the rec
(2> Employee access. Every employee ords of the medical examinations
and former employee shall have reason required by this paragraph shall be made
able access to any record required to be available, for inspection and copying,
maintained by subparagraph (1) of this to the Assistant Secretary of Labor for
paragraph, which Indicates the em Occupational Safety and Health, the
ployee's own exposure to asbestos fibers. Director of NIOSH, to authorized physi
(3) Employee notification. Any em cians and medical consultants of either
ployee found to have been exposed at any of them, and, upon the request of an em
time to airborne concentrations of asbes ployee or former employee, to his physi
tos fibers in excess of the limits pre cian. Any physician who conducts a
scribed in paragraph (b> of this section medical examination required by this
shall be notified in writing of the expo paragraph shall furnish to the employer
sure as soon as practicable but not later of the examined employee all the infor
than 5 days of the finding. The employee mation specifically required by this
shall also be timely notified of the cor paragraph, and any other medical in
rective action being taken.
formation related to occupational ex
(j) Medical examinations--(1) Gen posure to asbestos fibers. eral. The employer shall provide or make
available at his cost, medical examina 3. A new f 1910.19 is added to Subpart
tions relative to exposure to asbestos re B of Part 1910, reading as follows:
quired by this paragraph. (2) Preplacement. The employer shall
1910.19
Aabcdot dud.
provide or make available to each of his Section 1910.93a shall apply to the ex
employees, within 30 calendar days fol posure of every employee to asbestos
lowing his first employment in an dust in every employment and place
occupation exposed to airborne con of employment covered by i 1910.12,
centrations of asbestos fibers, a compre 11910.13. } 1910.14, } 1910.15, or 11910.16,
hensive medical examination, which shall in lieu of any different standard on ex
include, as a minimum, a chest roent posure to asbestos dust which would
genogram ( posterior-anterior 14 x 17 otherwise be applicable by virtue of any
inches), a history to elicit symptom of those sections.
atology of respiratory disease, and Effective date. Paragraph (b)(2) of
pulmonary function tests to Include ( 1910.93a shall become effective July 1.
forced vital capacity (FVC) and forced 1976. All other provisions of |{ 1919.93a,
expiratory volume at 1 second (FEV,.). 1910.93. and 1910.19 shall become effec
<3) Annual examinations. On or be tive July 7.1972. The current emergency
fore January 31. 1973, and at least an temporary standard remains in effect
nually thereafter, every employer shall until July 7, 1972.
provide, or make available, comprehen sive medical examinations to each of his
(Secs. 6. 8. 84 Stat. 1593. 1898; 29 U.S.C. 655. 657: 29 CFR 1910.4; Secretary of Labor's
employees engaged in occupations ex Order No. 12-71, 38 F-R. 8764)
posed to airborne concentrations of as bestos fibers. Such annual examination shall Include, as a minimum, a chest
Signed at Washington, D.C., this 2d day of June 1972.
roentgenogram (posterior-anterior 14 x
G. C. Guenther,
17 inches), a history to elicit symptom
Assistant Secretary of Labor.
atology of respiratory disease, and pulmonary function tests to include
|FR Doc.72-8574 Filed 6-6-72:8:48 am]
forced vital capacity (FVC) and forced
expiratory volume at 1 second (FEV. .).
(4) Termination of employment. The employer shall provide, or make avail able. within 30 calendar days before or after the termination of employment of any employee engaged in an occupation exposed-to airborne concentrations of asbestos fibers, a comprehensive medical examination which shall include, as a minimum, a chest roentgenogram (pos terior-anterior 14 x 17 inches), a history to elicit'symptomatology of respiratory disease, and pulmonary function tests to include forced vital capacity (FVC)
and forced expiratory volume at 1 second (FEV, ,,).
(5> Recent examinations. Ho medical examination .is required of any em ployee. if adequate records show that the employee has been examined in ac cordance with this paragraph within the past 1-year period.
(6) Medical records--(l) Mainte
nance. Employers of employees examined pursuant to this paragraph shall cause to be maintained complete and accurate records of all such medical examina
UNION
MaterialCARBIDE
September 1, 1972
UNION CARBIDE CORPORATION 4625 ROYAL AVENUE NIAGARA FALLS, NEW YORK 14302
TELEPHONE:
278-3376
PRODUCT: Chrysotile Asbestos TRADE NAMES: "Calidria" Asbestos
CHEMICAL FORMULA: MgglOHJgS^O,,,
I. PHYSICAL DATA
BOILING POINT AND MELTING POINT: Not Pertinent
SPECIFIC GRAVITY <H20=1): 2.45
VOLATILE CONTENT: Absorbed Water 1 -- 4% By Weight Structural Water Approximately 13% by Weight
APPEARANCE: Pellets or Fine White Powder. No odor. Very Slight Solubility in Water.
II. HAZARDOUS INGREDIENTS
Not Applicable.
III. FIRE AND EXPLOSION HAZARD DATA
Material is not Combustible. No Fire or Explosion Hazard.
IV. REACTIVITY DATA
INERT MATERIAL: No Decomposition or Polymerization Conditions.
V. HEALTH HAZARD DATA
PERMISSIBLE EXPOSURE TO AIRBORNE CONCENTRATION: The current standard of the Occupational Safety and Health Act of 1970 contains the following exposure limits: "The 8-hour time-weighted average airborne concentration of asbestos fibers to which employees are exposed shall not exceed 5 fibers per milliliter greater than 5 microns in length, as determined by the membrane filter method at 400-450X magnification (4 millimeter objective) phase contrast illumination. No employee shall be exposed at any time to airborne concentrations of asbestos fibers in excess of 10 fibers per milliliter, longer than 5 microns." (Federal Register -- Vol. 37, June 7, 1972, page 11320).
EFFECTS OF OVER EXPOSURE: Prolonged over exposure may result in lung damage.
EMERGENCY AND FIRST AID PROCEDURES: Not applicable. Material has no acute toxicity.
VI. SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Avoid inhalation of dust Remove spilled material by vacuum cleaner or by water wash.
WASTE DISPOSAL METHOD: If reasonably foreseeable handling will not produce airborne concentrations in excess of exposure limits, no special procedures are required. When limits are likely to be exceeded, waste and scrap shall be collected and disposed of in impermeable sealed bags or other closed, impermeable containers, suitably labelled.
Union Carbide Corporation assumes no responsibility and makes no warranty, expressed or implied, repre sentation, promise, or statement as to completeness, accuracy, or currency of any data provided.
CALIDRIA ASBESTOS RG-244
TYPICAL CHEMICAL ANALYSIS
Component
Weight %
MgO
Si02
A1203 Fe Ca Co Cr Cu Mn Ni Se
Loss on Ignition (C02 & H2O)
38.2
46.1
0.2
1.4 0.025 0.004 0.13 0.005 0.05 0.16
<0.001
12.7
Component
Ag A1 As Au B Ba Be Bi Ca Cb Cd Co Cr Cs Cu Fe Ga Ge Hf Hg In Ir
K
La Li Mg Mn Mo Na
TYPICAL SPECTROGRAPHIC ANALYSIS
Detection Limit, Wt. %
0.001 0.003 0.01 0.002 0.006 0.003 0.001 0.005 0.002 0.006 0.01 0.01 0.003 N.A.(1) 0.001 0.006 0.01 0.005 0.03 0.02 0.03 0.03 N.A. 0.01 0.1 0.001 0.003 0.003 0.03
Analysis, Wt. %
n.dJ2)
0.08-0.8 N.D. N.D. N.D. N.D. N.D. N.D.
0.008-0.08 N.D. N.D.
0.004-0.04 0.02-0.2
---
N.D. 0.4-4.0
N.D. N.D. N.D. N.D. N.D. N.D.
--
N.D. N.D. Major 0.008-0.08 N.D. 0.08-0.8
Component
Ni Os P Pb Pd Pt Rb Re Rh Ra Sb Sc Se Si Sn Sr Ta Te Th Ti T1 U V W Y Yb Zn Zr
Detection Limit, Analysis,
Wt. %
Wt. %
0.003 0.03 0.08 0.003 0.005 0.005 N.A. 0.03 0.02 0.03 0.01 0.01
-----
0.001 0.002 0.01 0.01 0.05 0.03 0.003 0.2 0.1 0.003 0.01 0.01 0.01 0.02 0.006
0.08-0.8 N.D. N.D. N.D. N.D. N.D.
--
N.D. N.D. N.D. N.D. N.D.
<o.oorj;
Major N.D. N.D. N.D. N.D. N.D.
0.0008-0.008 N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D.
^ N.A. - Not analyzed. ^ N.D. - Not detected. ^ By chemical analysis
PLEASE TYPE AND BE CONCISE
ADDRESS SECTION MESSAGE ADDRESSEE
F W T ATJPTCnV
MESSAGE SECTION (------------ ------------------
MESSAGE ENTRY FORM
B I&.
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MESSAGE BILLING CODE^>> (INDICATE A DIGIT NUMERIC CODE)
6
DIVISION/DEPARTMENT
CITY/STATE
DESTINATION ADDRESSEE CODE
UNION CARBIDE
KING CITY
CALIFORNIA
METALS
*
- - - i)
l
[
PLEASE ADVISE BY TWX ON SEPTEMBER 8. TOTAL TONS AND TONS, MEETING SPECS OF RG-244 AND SX-24 PRODUCED SEPTEMBER 1 THROUGH 7. THANKS.
W. C. THURBER NYC - 38th floor
DATE
ORIGINATOR
9/4/75
W. C. THURBER
DIVISION/DEPARTMENT
METALS
CITY LOCATION
NYC - 38th floor
UC 149-28B
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