Document LK45N1BRV4nG1V5zoqXDKMo6X
Injuries Guarded Against by 1968 Recommended Threshold Limit Values
(Likely effect at a small multiple of the TLV; not maximum injury expected at a large multiple. Based on interpretation of ACGIH documentation and personal judgment.)
H. F. Snyth, Jr. - April 1969
Summary 1
Guard against trivial effect
List A. Cosmetic
1 TLV's
B. Inert dust load
1
F. Good housekeeping
6
G* Trivial narcosis
19
B. Odor, EOT irritation 106
153
Guard against severe effect List C. Lung fibrosis
D. Chronic toxicity E. Cancer I. EOT bronchial J. Metal fume fever K. Allergy L. Bronchial, alveolar M. Acute or subacute N. Chemical asphyxia 0. Simple asphyxia
8 TLV's 72
9 76
3 9 lk
5k
3 10
25B
gurnmary 2
Time-weighted-average appropriate
List A. Cosmetic
B, Inert dust load C, Lung fibrosis D. Chronic toxicity
1 TLV's 21
8 72
E. Cancer
9 nr
Ceiling appropriate List F. Good housekeeping
G. Trivial narcosis H. Odor, EOT irritation I. EOT bronchial J. Metal fume fever K. Allergy L. Bronchial, alveolar M. Acute or subacute N. Chemical asphyxia
0. Simple asphyxia
6 TLV's
19 106
76 3 9
lk
5k
3 10
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2.
list A. Cosmetic Effect Silver metal, and salts
1 TLV
B. Minor Nose, Throat, Bronchial Irritation and Inert Dust Load in Lung
21 TLV's
Alumina
Graphite
Tin, inorganic
Boron oxide
Limestone
Tin oxide
Carbon black
Rouge
Titanium dioxide
Cellulose
Silicon carbide
Tungsten, insoluble
Perrovanadium
Starch
Tungsten, soluble
Fibrous glass
Sucrose
Vegetable oils
Glycerine
Tantalum
Zirconium
C. Lung Fibrosis Cristobalite Diatamaceous earth Mica
Portland cement
Quartz Soapstone Talc Tremolite
8 TLV's
D. Chronic Toxicity Acrylamide Aldrin 2-Amino pyridine Antimony ANTU Arsenic Barium, soluble Benzene Cadmium, soluble and dust Cadmium fume Calcium arsenate Carbon disulfide Carbon tetrachloride Chlordane Chlorinated camphene Chlorodiphenyl 42$ Cl Chlorodiphenyl 54$ Cl Chlorodiphenyl oxide
Chloroform Chromium, metal and soluble
chrcmous, chromic salts Cobalt Copper, dust, mist Copper fume Crag herbicide 2,4-D DDT 1.1-Di chioroethane 1.2-Dichloroethane Dieldrln Dimethyl acetamide Dimethyl formamide Dicxane Endrin Hafnium Heptachlor
72 TLV's Hexachloroethane Hexachloronaphthalene Hydrogen selenide Hydroquinone
Lead Lead arsenate Lindane Manganese Mercury Mercury, organic Methoxychlor Methyl bromide Molybdenum, insoluble Molybdenum, soluble Nickel, metal and soluble Octachloronaphthalene Pentachloronaphthalene Phenyl hydrazine Phosphorous, yellow Propylene dichloride Pyridine Quinone Selenium 2,4,5-T Tellurium Tet rachloroethane Tet rachloronaphthalene
Tetraethyl lead
Tetramethyl lead Thallium Tin, organic 1,1,2-Trichloroethane Trichloronaphthalene
Trichloropropane Triorthocresyl phosphate
Uranium Yttrium
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List E* Cancer - Asbestos Benzidine Be ryIlium Coal tar pitch volatiles Chromates, insoluble 2-Naphthylaraine Nickel carbonyl Nit ros odimethylamine beta-Propiolact one
F. Nothing, "Good Housekeeping" Dichlorodifluoromethane Dichloramonofluoromethane Dichlorotetrafluoroethane FLuorotrichloromethane
G. Trivial Narcosis Butadiene Cyclohexane Qyclohexene Cy clopentadiene 1,2-Dichloroethylene Ethyl chloride Hexane LPG Methyl chloride Methyl cyclohexane
H. Odor, Eye, Nose, Throat Irritation Acetic acid Acetone Allyl alcohol Allyl glycidyl ether Allyl propyl disulfide n-Anyl acetate sec-Anyl acetate Benzyl chloride 2-Butanone 2-But axyethanol n-Butyl acetate sec-Butyl acetate t-Butyl acetate n-Butyl alcohol sec-Butyl alcohol t-Butyl alcohol Butyl amine n-Butyl glycidyl ether Butyl mercaptan Camphor alpha-Chloroacetophenone Chlorobenzene Chloropicrin Chloroprene Cresol Qyclohexanol Cumene Cyclohexanone
(Continued)
3.
9 TLV's
6 TLV's
Sulfur hexafluoride Trifluoromonobramomethane
Methylene chloride
19 TLV's
Pentane Perchloroethylene
Propane 1,1,1-Trichloroethane
Trichloroethylene Trichlorotrifluoroethane
Toluene Vinyl chloride
106 TLV's
Diacetone alcohol o-Dichlorobenzene p-Dichlorobenzene Diethyl amine Diisobutyl ketone Diisopropyl amine Dimethylamine Dipropylene glycol methyl ether Epichlorohydrin 2-Ethoxyethanol 2-Ethoxyethanol acetate Ethyl acetate Ethyl acrylate Ethyl alcohol Ethyl amine Ethyl sec-amyl ketone Ethyl benzene Ethyl butyl ketone Ethyl ether Ethyl formate Ethyl mercaptan Formic acid Glycidol Heptane 2-Hexanone Hexone sec-Hexyl acetate Hydrogen sulfide
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k.
Odor, Eye, Nose, Throat Irritation (continued)
Isoamyl acetate Isoamyl alcohol Isobutyl acetate Isobutyl alcohol Isophorone Isopropyl acetate Isopropyl alcohol Isopropyl amine Isopropyl ether Isopropyl glycidyl ether Maleic anhydride Mesityl oxide Methyl acrylate Methylal Methyl alcohol Methyl amine Methyl n-amyl ketone Methyl cellosolve Methyl cellosolve acetate Methyl cyclohexanol Methyl cyclohexanone Methyl isobutyl carbinol Methyl mercaptan alpha-Methyl styrene
103 TLV's Naphtha, coal tar Naphthalene Nitroethane Nitromethane 1-Nitropropane 2-Nitropropane Octane Oxalic acid Pentachlorophenol 2-Pentanone Perchloromethylmercaptan Petroleum distillate naphtha Phenyl ether Phenyl glycidyl ether Phenol Propargyl alcohol n-Propyl acetate n-Propyl alcohol Tet rahydrofuran Tetryl Triethyl amine Turpentine Stoddard solvent Styrene Vinyl toluene Xylene
Eye, Nose, Throat, Bronchial Irritation
Acetaldehyde
Diphenyl
Acetic anhydride
Ethanolamine
Acrolein
Ethylene lmlne
Allyl chloride
Ethylene oxide
Ammonia
N-Ethyl morpholine
Ammonium sulfamate
Ethyl silicate
Benzcyl peroxide
Ferban
Boron pentafluoride
Fluorine
Boron tribromide
Formaldehyde
Boron trifluoride
Furfural
Bromine
Hydrazine
t-Butyl chromate
Hydrogen bromide
Calcium oxide
Hydrogen chloride
Chlorine
Hydrogen fluoride
Chlorine dioxide
Hydrogen peroxide 90f>
Chlorine trifluoride
Iodine
Chromic acid
Iron, soluble salts
Crotonaldehyde Dibutyl phosphate Dibutyl phthalate Dichloroethyl ether
Ketene Lithium hydride Methyl acetate Methyl acetylene
Dlethylaminoethanol Di-2-ethylhexyl phthalate Higlycidyl ether
1,1-Dimethyl hydrazine
Methyl formate
Methyl silicate Monomethyl hydrazinei Morpholine
Dimethyl phthalate
Nitric acid
Metal Fume Fever Iron oxide fume
Magnesium oxide fumes
76 TLV's Nitrogen trifluoride Osmium tetroxide Oxygen difluoride Perchloryl fluoride Phthalic anhydride Phosphoric acid Phosphorous pentachloride Phosphorous trichloride Picric acid Propylene imine Propylene oxide Selenium hexafluoride Sodium hydroxide Sulfur dioxide Sulfuric acid Sulfur monochloride Sulfur pentachloride Sulfuiyl fluoride Tellurium hexafluoride Teiphenyls Tetranitro methane Triphenyl phosphate Vanadium pentoxide Zinc chloride fume
3 TLV's Zinc oxide fume
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'Xis.t K. Allergy
V Diethylene triamine Ethylene diamine Maleic anhydride
L. Bronchial, Alveolar Injury Acrolein Chloroacetaldehyde l-Chloro-2-nitropropane Diazomethane Dihorane 1,1-Dichloronitroethane DifluorodAbromamethane
M. Acute or Subacute Toxicity Abate Acetonitrile Aczylonitrile Aniline Anisidine Arsine Braraofom p-t-Butyl toluene Carbaiyl Carbon dioxide o-Chlorobenzy1 malonitrile Decaborane Demetron BDVP Dibrom 1,2-Dibromoethane Dimethylaniline Dinitrobenzene
N. Chemical Asphyxia Carbon monoxide Cyanogen Hydrogen cyanide
0- Simple Asphyxia Acetylene Argon Ethane Ethylene Helium
5-
Methylene bis-isocyanate Methyl isocyanate p-Phenylene diamine
9 TLV's Platinum, soluble salts
Rhodium, metal or salts Tolylene diisocyanate
14 TLV's Dimethyl sulfate Ethylene chlorohydrin ' Nitric oxide Nitrogen dioxide Ozone Phosgene Tributyl phosphate
Dinitro-o-cresol Diphenyl amine EPN Ethyl bromide Ethylene glycol
dinitrate Indium Malathion
Methyl azinophos Methyl iodide Mononethyl aniline Nicotine Nitrobenzene Nitroglycerine Nitrotoluene
Parathion Parquat Pentaborane Phosdrin
54 TLV's Phosphine Fival n-Propyl nitrate Pyrethrum RIK Ronnel Rotenone Sodium fluoroacetate Stibine Strychnine TEDP TEPP Tetrachlorodifluoroethane Tetramethyl
Buccinonitrile Thiram o-Toluidine Trinitrot oluene Xylidene
3 TLV's
Ifydrogen Methane Neon Nitrogen Nitrous oxide
10 TLV's
i
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