Document LJ3KR7Q97mBnXmOa6bQ0mJyX5

3 GLP10-01-02 Interim Report 15: Analysis for PFOS, PFHS and PFBS in Decatur, AL Avenue A Soils and Sediments Collected January 2011 Study Title 3M Environmental Laboratory Analytical Protocol GLP-10-01-02: Analysis of Perfluorooctane Sulfonate (PFOS), Perfluorohexane Sulfonate (PFHS) and Perfluorobutane Sulfonate (PFBS) in Groundwater, Soil and Sediment for the 3M Decatur Phase 3 Site-Related Monitoring Program Data Requirement EPA TSCA Good Laboratory Practice Standards 40 CFR Part 792 Study Director Jaisimha Kesari P.E., DEE Weston Solutions, Inc. 1400 Weston Way West Chester, PA 19380 Phone: 610-701-3761 Principal Analytical Investigator Cleston C. Lange, Ph.D. 3M Environmental Laboratory Interim Report Completion Date July 5, 2011 Performing Laboratory 3M Environmental Health and Safety Operations Environmental Laboratory 3M Center, Bldg 260-05-N-17 St. Paul, MN 55144 Project Identification GLP-10-01-02-15 Total Number of Pages 514 Study: GLP10-01-02, Interim Report 15 Analysis for PFOS, PFHS and PFBS in Avenue A Soils/Sediments Collected January 2011 This page has been reserved for specific country requirements. 3M Study GLP10-01-02-15 Page 2 of 514 Study: GLP10-01-02, Interim Report 15 Analysis for PFOS, PFHS and PFBS in Avenue A Soils/Sediments Collected January 2011 GLP Compliance Statement Report Title: GLP10-01-02 Interim Report 15. Analysis for PFOS, PFHS and PFBS in Decatur, AL Avenue A Soils and Sediments Collected January 2011. 3M Environmental Laboratory Analytical Protocol GLP-10-01-02: Analysis of Perfluorooctane Sulfonate (PFOS), Perfluorohexane Sulfonate (PFHS) and Perfluorobutane Sulfonate (PFBS) in Groundwater, Soil and Sediment for the 3M Decatur Phase 3 Site-Related Monitoring Program. This analytical phase was conducted in compliance with Toxic Substances Control Act (TSCA) Good Laboratory Practice (GLP) Standards, 40 CFR 792, with the exceptions listed below: Exceptionsto GLP compliance: Test, control and reference substances were not all characterized under GLPs. As these are real-life environmental samples, there was no dosing and no specific test substance for this study. 3M Study GLP10-01-02-15 Page 3 of 514 Study: GLP10-01-02, Interim Report 15 Analysis for PFOS, PFHS and PFBS in Avenue A Soils/Sediments Collected January 2011 Q uality A ssurance Statement Report Title: GLP10-01-02 Interim Report 15. Analysis for PFOS, PFHS and PFBS in Decatur, AL Avenue A Soils and Sediments Collected January 2011. 3M Environmental Laboratory Analytical Protocol GLP-10-01-02: Analysis of Perfluorooctane Sulfonate (PFOS), Perfluorohexane Sulfonate (PFHS) and Perfluorobutane Sulfonate (PFBS) in Groundwater, Soil and Sediment for the 3M Decatur Phase 3 Site-Related Monitoring Program. This report and the accompanying data were audited by the 3M Environmental Laboratory Quality Assurance Unit (QAU), as indicated below. The findings were reported to the principal investigator (P.I.), laboratory management and study director. Inspection Dates Phase 5/13/11,5/18/11-5/19/11 Data & Interim Report P.l. 5/31/11 Date Reported to Study Director Management 5/26/11 Study Director 5/23/11 Date 3M Study GLP10-01-02-15 Page 4 of 514 Study: GLP10-01-02, Interim Report 15 Analysis for PFOS, PFHS and PFBS in Avenue A Soils/Sediments Collected January 2011 Table of Contents GLP Compliance Statement............................................................................................................................3 Quality Assurance Statement..........................................................................................................................4 Table of Contents.............................................................................................................................................5 List of Tables.................................................................................................................................................... 6 1 Study Information......................................................................................................................................7 2 Summary................................................................................................................................................... 8 3 Introduction..............................................................................................................................................13 4 Test, Control and Reference Substances.............................................................................................. 13 5 Test System.............................................................................................................................................15 6 Method Summary....................................................................................................................................15 6.1 Methods...................................................................................................................................... 15 6.2 Sample Collection........................................................................................................................15 6.3 Sample Preparation.....................................................................................................................15 6.4 Percent Soil Moisture Determination...........................................................................................16 6.5 LC/MS/MS Analysis....................................................................................................................17 7 Analytical Results ....................................................................................................................................18 7.1 Calibration ................................................................................................................................... 18 7.2 Limits of Quantitation (LOQs)..................................................................................................... 20 7.3 Continuing Calibration Verification............................................................................................. 21 7.4 Blanks.......................................................................................................................................... 21 7.5 Laboratory Control Spikes (LCSs).............................................................................................. 21 7.6 Laboratory Matrix Spikes (LMSs)............................................................................................... 23 7.7 Percent Soil Moisture Determinations.........................................................................................23 Individual Sample Results.......................................................................................................................27 3M Study GLP10-01-02-15 Page 5 of 514 Study: GLP10-01-02, Interim Report 15 Analysis for PFOS, PFHS and PFBS in Avenue A Soils/Sediments Collected January 2011 8 Conclusion.............................................................................................................................................. 44 9 Data/Sample Retention...........................................................................................................................44 10 List of Attachments................................................................................................................................. 44 11 Signatures............................................................................................................................................... 45 List of Tables Table 1. Results for Decatur, AL Avenue A Soils and Sediment Collected January 2011...................................................................................................................................... 8 Table 2. LMS Recovery Results for Decatur, AL Avenue A Soils and Sediments Collected January 2011...................................................................................................... 10 Table 4. Instrument Information....................................................................................................................17 Table 5. Gradient Liquid Chromatography Conditions (ETS-8-053)........................................................... 18 Table 6. Mass Transitions............................................................................................................................ 18 Table 7. PFOS Calibration Summary.......................................................................................................... 19 Table 8. PFHSCalibration Summary............................................................................................................. 20 Table 9. PFBSCalibration Summary.............................................................................................................20 Table 10. LCS Results (PFOS).................................................................................................................. 22 Table 11. LCS Results (PFHS).................................................................................................................. 22 Table 12. LCS Results (PFBS)................................................................................................................... 23 Table 13. Percent Moistures for Decatur, AL Avenue A Soils & Sediments, January 2011.................................................................................................................................... 24 Table 14. Individual PFOS Results for Decatur, AL Avenue A Soils & Sediments, January 2011......................................................................................................................27 Table 15. Individual PFHS Results for Decatur, AL Avenue A Soils & Sediments, January 2011......................................................................................................................32 Table 16. Individual PFBS Results for Decatur, AL Avenue A Soils & Sediments, January 2011......................................................................................................................38 3M Study GLP10-01-02-15 Page 6 of 514 Study: GLP10-01-02, Interim Report 15 Analysis for PFOS, PFHS and PFBS in Avenue A Soils/Sediments Collected January 2011 1 Study Information Sponsor 3M Company Sponsor Representative Gary A. Hohenstein Environmental Manager Special Projects, EHS Operations Bldg 224-5W-03 St. Paul, MN 55144 Phone: (651) 737-3570 gahohenstein@mmm.com Study Director Jaisimha Kesari, P.E., DEE Weston Solutions, Inc. 1400 Weston Way West Chester, PA 19380 Study Analytical Testing Facility 3M EHS Operations Environmental Laboratory Building 260-5N-17 St. Paul, MN 55144 Study Personnel (3M Environmental Laboratory) William K. Reagen, Ph.D., Laboratory Manager Cleston C. Lange, Ph.D., Principal Analytical Investigator Marlene Heying Laboratory Technician (Pace Analytical, Professional Services) Gabriel P. McMurtry, Laboratory Technician (Pace Analytical, Professional Services) John Steege, Laboratory Technician (Pace Analytical, Professional Services) Kelly Ukes, Laboratory Technician (Pace Analytical, Professional Services) Study Dates Study Initiation: March 24, 2010 Interim Analytical Initiation: February 2, 2011 Interim Analytical Completion: April 15, 2011 Interim Report Completion: July 5, 2011 Location of Archives All original raw data and analytical reports have been archived at the 3M Environmental Laboratory according to 40 CFR Part 792. The test substance and analytical reference standard reserve samples are archived at the 3M Environmental Laboratory according to 40 CFR Part 79 3M Study GLP10-01-02-15 Page 7 of 514 Study: GLP10-01-02, Interim Report 15 Analysis for PFOS, PFHS and PFBS in Avenue A Soils/Sediments Collected January 2011 2 Summary This interim report 15 of study GLP10-01-02 provides the determined concentration results for perfluorooctane sulfonate (PFOS), perfluorohexane sulfonate (PFHS) and perfluorobutane sulfonate (PFBS) measured in soils and sediments collected in January 2011 from Avenue A locations at the 3M Decatur, AL facility. Samples were received into the laboratory electronic LIM system under related project GLP10-01-0115. Triplicate aliquots of soil from each sample bottle were accurately weighed. The third replicate of each was fortified with a known quantity of PFOS (linear), PFHS (linear) and PFBS as a laboratory matrix spike (LMS) sample, and then each was extracted for analysis. Quantitative analysis of soil/sediment extracts was performed by a sensitive LC/MS/MS method. The percent moisture of each soil was also determined for reporting results on a dry soil weight basis. The PFOS, PFHS and PFBS concentrations determined are summarized in Table 1. The LMS recoveries for each analyte are summarized in Table 2. Table 1. Results for Decatur, AL Avenue A Soils and Sediment Collected January 2011 31VI LIIV IS ID [d] GLP10-01-01-15-001 GLP10-01-01-15-002 GLP10-01-01-15-003 GLP10-01-01-15-004 GLP10-01-01-15-005 GLP10-01-01-15-006 GLP10-01-01-15-007 GLP10-01-01-15-008 GLP10-01-01-15-009 GLP10-01-01-15-010 GLP10-01-01-15-011 GLP10-01-01-15-012 GLP10-01-01-15-014 GLP10-01-01-15-015 GLP10-01-01-15-016 GLP10-01-01-15-018 GLP10-01-01-15-020 GLP10-01-01-15-021 GLP10-01-01-15-022 GLP10-01-01-15-023 GLP10-01-01-15-024 GLP10-01-01-15-025 GLP10-01-01-15-026 GLP10-01-01-15-027 GLP10-01-01-15-028 GLP10-01-01-15-029 GLP10-01-01-15-030 GLP10-01-01-15-031 GLP10-01-01-15-032 GLP10-01-01-15-033 GLP10-01-01-15-034 Sample ID DAL SS Trip1 0 0000 DAL SS SS12 0 0000 DAL SS SS12 0 0005 DAL SS SS13 0 0000 DAL SS SS16 0 0000 DAL SS SS16 DB 0000 DAL SS SS11 0 0000 DAL SS SS11 0 0005 DAL SS SS20 0 0000 DAL SS SS20 DB 0000 DAL SS SS19 0 0000 DAL SS SS19 0 0005 DAL SS SS15 0 0000 DAL SS SS17 0 0000 DAL SS SS14 0 0000 DAL SS SS18 0 0000 DAL SS SS10 0 0000 DAL SS SS30 0 0000 DAL SS SS30 0 0005 DAL SS SS30 0 0015 DAL SS SS25 0 0000 DAL SS SS25 0 0005 DAL SS SS25 0 0015 DAL SD SD22 0 0000 DAL SD SD22 0 0005 DAL SD SD22 DB 0005 DAL SD SD22 0 0015 DAL SD SD21 0 0000 DAL SD SD21 0 0005 DAL SD SD21 0 0015 DAL SS SS24 0 0000 Analyte Concentration (ng/g; dry) PFOS PFHS PFBS BLQ BLQ BLQ 2110 [a, b] 13.7 1.17 5830 186 [a] 4.89 123 1.93 1.01 [c] 312 6.74 7.24 300 6.48 7.54 57.4 0.918 0.696 [a] 98.9 [a, c] 4.30 [c] 0.627 [c] 102 2.68 0.309 107 [b] 2.27 [a] 0.247 [a] NR 2.22 0.224 397 14.6 1.30 272 3.49 [b] 0.283 61.2 2.13 0.228 324 4.18 0.494 78.9 [b] 2.33 0.814 [b] 3730 [a, b, c] 29.1 [a, b] 5.28 [c] 437 3.83 0.548 130 0.869 BLQ [a] 309 [a, b] 8.06 1.22 3320 607 [a, b, c] 19.7 2520 516 33.8 2020 295 35.0 4060 193 13.9 887 [a] 68.3 7.70 1120 69.1 [c] 6.49 [a] 473 62.8 8.19 2020 107 7.86 1650 148 10.4 [c] 562 57.7 5.46 [a] 1320 61.3 6.14 3M Study GLP10-01-02-15 Page 8 of 514 Study: GLP10-01-02, Interim Report 15 Analysis for PFOS, PFHS and PFBS in Avenue A Soils/Sediments Collected January 2011 Table 1. Results for Decatur, AL Avenue A Soils and Sediment Collected January 2011 3M LIMS ID [d] GLP10-01-01-15-035 GLP10-01-01-15-036 GLP10-01-01-15-037 GLP10-01-01-15-038 GLP10-01-01-15-039 GLP10-01-01-15-040 GLP10-01-01-15-041 GLP10-01-01-15-042 GLP10-01-01-15-043 GLP10-01-01-15-044 GLP10-01-01-15-045 GLP10-01-01-15-046 GLP10-01-01-15-047 GLP10-01-01-15-048 GLP10-01-01-15-049 GLP10-01-01-15-050 GLP10-01-01-15-051 GLP10-01-01-15-052 GLP10-01-01-15-053 GLP10-01-01-15-054 GLP10-01-01-15-055 GLP10-01-01-15-056 GLP10-01-01-15-057 GLP10-01-01-15-058 GLP10-01-01-15-059 GLP10-01-01-15-060 GLP10-01-01-15-061 GLP10-01-01-15-062 GLP10-01-01-15-063 GLP10-01-01-15-064 GLP10-01-01-15-065 GLP10-01-01-15-066 GLP10-01-01-15-067 GLP10-01-01-15-068 GLP10-01-01-15-069 GLP10-01-01-15-070 GLP10-01-01-15-071 GLP10-01-01-15-072 GLP10-01-01-15-073 GLP10-01-01-15-074 GLP10-01-01-15-075 GLP10-01-01-15-076 GLP10-01-01-15-077 GLP10-01-01-15-079 GLP10-01-01-15-080 Sample ID DAL SS SS24 0 0005 DAL SS SS24 0 0015 DAL SS SS29 0 0000 DAL SS SS29 0 0005 DAL SS SS29 0 0015 DAL SS SS20 0 0005 DAL SS SS13 0 0005 DAL SS SS13 DB 0005 DAL SS SS15 0 0005 DAL SS SS17 0 0005 DAL SS SS14 0 0005 DAL SS SS18 0 0005 DAL SS SS16 0 0005 DAL SS SS16 0 0015 DAL SS SS10 0 0005 DAL SS SS10 DB 0005 DAL SS SS10 0 0015 DAL SD SD20 0 0000 DAL SD SD20 0 0005 DAL SD SD20 0 0015 DAL SD SD23 0 0000 DAL SD SD23 0 0005 DAL SD SD23 0 0015 DAL SS SS28 0 0000 DAL SS SS28 0 0005 DAL SS SS28 DB 0005 DAL SS SS28 0 0015 DAL SS SS27 0 0000 DAL SS SS27 0 0005 DAL SS SS27 0 0015 DAL SS SS22 0 0000 DAL SS SS22 0 0005 DAL SS SS22 DB 0005 DAL SS SS22 0 0015 DAL SS SS21 0 0000 DAL SS SS21 0 0005 DAL SS SS21 0 0015 DAL SD SD18 0 0000 DAL SD SD18 0 0005 DAL SD SD18 0 0015 DAL SD SD19 0 0000 DAL SD SD19 0 0005 DAL SD SD19 0 0015 DAL SS SS26 0 0000 DAL SS SS26 DB 0000 Analyte Concentration (ng/g; dry) PFOS PFHS PFBS 974 61.0 8.80 1600 34.2 3.17 [a] 605 9.64 1.67 271 3.64 0.760 1070 43.3 6.30 29.4 [b] 1.70 [c] 0.299 559 2.17 0.988 552 2.23 0.906 170 [a] 1.26 [a] 0.154 [a, c] 220 [a] 3.06 0.226 271 3.12 BLQ [a] 30.8 0.597 BLQ 303 2.61 2.39 165 5.48 7.00 453 7.81 1.25 365 6.77 1.18 471 19.8 3.58 2800 160 10.3 1300 [a] 139 10.8 672 121 9.68 518 44.6 4.97 270 22.5 2.42 176 16.1 2.08 163 0.888 0.837 197 0.879 0.633 [a] 196 0.804 0.604 [a] 174 4.31 2.29 145 0.341 0.744 241 0.471 0.652 162 0.415 0.412 273 4.40 1.39 157 2.47 1.41 151 2.29 1.45 27.3 [b] 0.864 0.523 1130 14.0 0.823 325 13.4 0.367 121 [a] 13.0 1.95 1000 107 9.70 545 [a] 78.6 7.57 NR 47.8 5.77 873 119 12.9 1080 [a] 127 14.0 345 75.7 [a] 8.50 [a] 970 [a] 8.26 0.552 NR 9.95 [c] 0.666 [c] 3M Study GLP10-01-02-15 Page 9 of 514 Study: GLP10-01-02, Interim Report 15 Analysis for PFOS, PFHS and PFBS in Avenue A Soils/Sediments Collected January 2011 Table 1. Results for Decatur, AL Avenue A Soils and Sediment Collected January 2011 3M LIMS ID [d] Sample ID Analyte Concentration (ng/g; dry) PFOS PFHS PFBS GLP10-01-01-15-081 DAL SS SS26 0 0005 1140 17.7 1.03 GLP10-01-01-15-082 DAL SS SS26 0 0015 1040 62.4 2.87 GLP10-01-01-15-083 DAL SS Trip2 0 0000 BLQ BLQ BLQ GLP10-01-01-15-084 DAL SS SS12 0 0015 2520 294 10.7 GLP10-01-01-15-085 DAL SS SS19 0 0015 294 23.6 1.84 GLP10-01-01-15-086 DAL SS SS20 0 0015 206 2.38 0.483 GLP10-01-01-15-087 DAL SS SS14 0 0015 223 2.93 [a] BLQ [a] GLP10-01-01-15-088 DAL SS SS17 0 0015 221 1.97 0.886 GLP10-01-01-15-089 DAL SS SS13 0 0015 357 1.93 1.48 GLP10-01-01-15-090 DAL SS SS15 0 0015 109 [a, c] 3.85 0.269 [a] GLP10-01-01-15-091 DAL SS SS18 0 0015 156 1.63 0.246 GLP10-01-01-15-092 DAL SS SS11 0 0015 NR 0.515 BLQ [a] LMS results were within acceptance criteria of 100 + 30%, unless otherwise noted Values in table are shown at 3 significant figures, but more precise data was used for data calculations. [a] ; LMS recovery was outside of 100 + 30%, but within protocol defined reporting limits of 100 + 50% [b] RPD of duplicate results was greater than 50% [c] Result reported from a reassay result and original result which did not meet quality objectives was not used. [d] Samples were logged into 3M LIMS under study GLP10-01-01-15, and analyzed for this parallel study GLP10-01-02-15 n R; sample result did not meet protocol-defined reporting criteria and was not reported BLQ; LC/MS/MS analyte response was below the response for the nominal 0.200 ng/g standard that defined the LLOQ. Table 2. LMS Recovery Results for Decatur, AL Avenue A Soils and Sediments Collected January 2011 3o1rVaI Li IirMaSo iIrD\ [b] GLP10-01-01-15-001 GLP10-01-01-15-002 GLP10-01-01-15-003 GLP10-01-01-15-004 GLP10-01-01-15-005 GLP10-01-01-15-006 GLP10-01-01-15-007 GLP10-01-01-15-008 GLP10-01-01-15-009 GLP10-01-01-15-010 GLP10-01-01-15-011 GLP10-01-01-15-012 GLP10-01-01-15-014 GLP10-01-01-15-015 GLP10-01-01-15-016 GLP10-01-01-15-018 GLP10-01-01-15-020 GLP10-01-01-15-021 GLP10-01-01-15-022 Sample ID DAL SS Trip1 0 0000 DAL SS SS12 0 0000 DAL SS SS12 0 0005 DAL SS SS13 0 0000 DAL SS SS16 0 0000 DAL SS SS16 DB 0000 DAL SS SS11 0 0000 DAL SS SS11 0 0005 DAL SS SS20 0 0000 DAL SS SS20 DB 0000 DAL SS SS19 0 0000 DAL SS SS19 0 0005 DAL SS SS15 0 0000 DAL SS SS17 0 0000 DAL SS SS14 0 0000 DAL SS SS18 0 0000 DAL SS SS10 0 0000 DAL SS SS30 0 0000 DAL SS SS30 0 0005 PFOS 98.7% 64.4% 85.5% 109% 77.6% 99.2% 108% 147% [a] 120% 129% NR 85.3% 104% 109% 79.7% 117% 146% [a] 71.3% 130% L VS Recovery (%) PFHS 98.1% 100% 142% 98.0% 109% 115% 106% 125% [a] 97.4% 150% 82.5% 106% 129% 108% 103% 113% 137% 90.0% 120% PFBS 98.3% 125% 100% 105% [a] 110% 114% 134% 105% [a] 111% 150% 116% 114% 127% 129% 120% 89% 110% [a] 109% 148% 3M Study GLP10-01-02-15 Page 10 of 514 Study: GLP10-01-02, Interim Report 15 Analysis for PFOS, PFHS and PFBS in Avenue A Soils/Sediments Collected January 2011 Table 2. LMS Recovery Results for Decatur, AL Avenue A Soils and Sediments Collected January 2011 3M LIMS ID [b] GLP10-01-01-15-023 GLP10-01-01-15-024 GLP10-01-01-15-025 GLP10-01-01-15-026 GLP10-01-01-15-027 GLP10-01-01-15-028 GLP10-01-01-15-029 GLP10-01-01-15-030 GLP10-01-01-15-031 GLP10-01-01-15-032 GLP10-01-01-15-033 GLP10-01-01-15-034 GLP10-01-01-15-035 GLP10-01-01-15-036 GLP10-01-01-15-037 GLP10-01-01-15-038 GLP10-01-01-15-039 GLP10-01-01-15-040 GLP10-01-01-15-041 GLP10-01-01-15-042 GLP10-01-01-15-043 GLP10-01-01-15-044 GLP10-01-01-15-045 GLP10-01-01-15-046 GLP10-01-01-15-047 GLP10-01-01-15-048 GLP10-01-01-15-049 GLP10-01-01-15-050 GLP10-01-01-15-051 GLP10-01-01-15-052 GLP10-01-01-15-053 GLP10-01-01-15-054 GLP10-01-01-15-055 GLP10-01-01-15-056 GLP10-01-01-15-057 GLP10-01-01-15-058 GLP10-01-01-15-059 GLP10-01-01-15-060 GLP10-01-01-15-061 GLP10-01-01-15-062 GLP10-01-01-15-063 GLP10-01-01-15-064 GLP10-01-01-15-065 GLP10-01-01-15-066 GLP10-01-01-15-067 Sample ID DAL SS SS30 0 0015 DAL SS SS25 0 0000 DAL SS SS25 0 0005 DAL SS SS25 0 0015 DAL SD SD22 0 0000 DAL SD SD22 0 0005 DAL SD SD22 DB 0005 DAL SD SD22 0 0015 DAL SD SD21 0 0000 DAL SD SD21 0 0005 DAL SD SD21 0 0015 DAL SS SS24 0 0000 DAL SS SS24 0 0005 DAL SS SS24 0 0015 DAL SS SS29 0 0000 DAL SS SS29 0 0005 DAL SS SS29 0 0015 DAL SS SS20 0 0005 DAL SS SS13 0 0005 DAL SS SS13 DB 0005 DAL SS SS15 0 0005 DAL SS SS17 0 0005 DAL SS SS14 0 0005 DAL SS SS18 0 0005 DAL SS SS16 0 0005 DAL SS SS16 0 0015 DAL SS SS10 0 0005 DAL SS SS10 DB 0005 DAL SS SS10 0 0015 DAL SD SD20 0 0000 DAL SD SD20 0 0005 DAL SD SD20 0 0015 DAL SD SD23 0 0000 DAL SD SD23 0 0005 DAL SD SD23 0 0015 DAL SS SS28 0 0000 DAL SS SS28 0 0005 DAL SS SS28 DB 0005 DAL SS SS28 0 0015 DAL SS SS27 0 0000 DAL SS SS27 0 0005 DAL SS SS27 0 0015 DAL SS SS22 0 0000 DAL SS SS22 0 0005 DAL SS SS22 DB 0005 PFOS 64.2% 75.0% 99.0% 101% 113% 64.4% 91.2% 84.9% 104% 95.1% 101% 72.7% 88.0% 70.3% 98.0% 96.2% 109% 120% 92.2% 102% 149% 63.9% 98.3% 114% 80.4% 76.6% 118% 94.7% 101% 93.6% 65.1% 84.5% 97.3% 90.6% 116% 88.0% 114% 109% 123% 106% 74.5% 120% 106% 121% 108% L MS Recovery (%) PFHS 102% 66.0% [a] 96.1% 96.8% 104% 111% 114% [a] 101% 107% 128% 112% 97.6% 99.3% 107% 119% 105% 107% 110% [a] 112% 96.5% 132% 72.7% 114% 116% 98.8% 110% 97.9% 117% 95.3% 98.3% 94.8% 103% 104% 119% 107% 88.3% 116% 138% 104% 114% 108% 112% 107% 113% 102% PFBS 111% 101% 106% 121% 104% 108% 143% 114% 124% 105% [a] 141% 101% 107% 139% 110% 118% 115% 120% 120% 106% 137% 114% 145% 116% 114% 116% 115% 124% 106% 111% 106% 119% 114% 115% 103% 110% 132% 136% 115% 120% 109% 121% 112% 106% 112% 3M Study GLP10-01-02-15 Page 11 of 514 Study: GLP10-01-02, Interim Report 15 Analysis for PFOS, PFHS and PFBS in Avenue A Soils/Sediments Collected January 2011 Table 2. LMS Recovery Results for Decatur, AL Avenue A Soils and Sediments Collected January 2011 3M LIMS ID [b] Sample ID L MS Recovery (%) PFOS PFHS PFBS GLP10-01-01-15-068 DAL SS SS22 0 0015 119% 121% 116% GLP10-01-01-15-069 DAL SS SS21 0 0000 75.9% 92.0% 109% GLP10-01-01-15-070 DAL SS SS21 0 0005 116% 113% 125% GLP10-01-01-15-071 DAL SS SS21 0 0015 131% 103% 111% GLP10-01-01-15-072 DAL SD SD18 0 0000 79.4% 102% 114% GLP10-01-01-15-073 DAL SD SD18 0 0005 63.2% 113% 123% GLP10-01-01-15-074 DAL SD SD18 0 0015 NR 88.0% 86.3% GLP10-01-01-15-075 DAL SD SD19 0 0000 87.7% 112% 111% GLP10-01-01-15-076 DAL SD SD19 0 0005 134% 100% 99.8% GLP10-01-01-15-077 DAL SD SD19 0 0015 112% 139% 136% GLP10-01-01-15-079 DAL SS SS26 0 0000 66.9% 106% 117% GLP10-01-01-15-080 DAL SS SS26 DB 0000 NR 103% [a] 104% [a] GLP10-01-01-15-081 DAL SS SS26 0 0005 116% 111% 102% GLP10-01-01-15-082 DAL SS SS26 0 0015 71.2% 95.8% 123% GLP10-01-01-15-083 DAL SS Trip2 0 0000 109% 100% 98.5% GLP10-01-01-15-084 DAL SS SS12 0 0015 94.7% 104% 120% GLP10-01-01-15-085 DAL SS SS19 0 0015 96.1% 93.3% 107% GLP10-01-01-15-086 DAL SS SS20 0 0015 101% 101% 127% GLP10-01-01-15-087 DAL SS SS14 0 0015 108% 136% 141% GLP10-01-01-15-088 DAL SS SS17 0 0015 104% 104% 114% GLP10-01-01-15-089 DAL SS SS13 0 0015 89.0% 107% 108% GLP10-01-01-15-090 DAL SS SS15 0 0015 57.3% [a] 104% 145% GLP10-01-01-15-091 DAL SS SS18 0 0015 116% 113% 128% GLP10-01-01-15-092 DAL SS SS11 0 0015 NR 98.2% 138% LMS results were within acceptance criteria of 100 + 30%, unless otherwise noted Values in table are shown at 3 significant figures, but more precise data was used for data calculations. [a] Result reported from a reassay result and original result which did not meet quality objectives was not used. [b] Samples were logged into 3M LIMS under study GLP10-01-01-15, and analyzed for this parallel study GLP10-01-02-15 n R; sample result did not meet protocol-defined reporting criteria and was not reported BLQ; LC/MS/MS analyte response was below the response for the nominal 0.200 ng/g standard that defined the LLOQ. 3M Study GLP10-01-02-15 Page 12 of 514 Study: GLP10-01-02, Interim Report 15 Analysis for PFOS, PFHS and PFBS in Avenue A Soils/Sediments Collected January 2011 3 Introduction This analytical study was conducted to determine the PFOS, PFHS and PFBS concentrations in environmental media collected in the vicinity of the Decatur, AL 3M facility. Reported herein are the measured PFOS, PFHS and PFBS results for soils and sediments collected in January 2011 from Avenue A locations at the Decatur site. The samples were collected by Weston Solutions, Inc. personnel and shipped to the 3M Environmental Laboratory for quantitative analysis. Two travel blank samples (trip blanks) containing a control soil accompanied the sample bottle shipment to and from the field and were also analyzed and reported herein. Additionally, four aqueous equipment rinseate blanks were received with the soil samples and were analyzed separately with surface water and groundwater samples received from Decatur as part of the same program. The results for the rinseate blanks were reported elsewhere in GLP10-01-02 interim report 17. This interim report 15 for study GLP10-01-02 describes the sample shipping, receipt, extraction and quantitative liquid chromatography with triple quadrapole mass spectrometric detection (LC/MS/MS) analysis procedures conducted for the determination of PFOS, PFHS and PFBS concentrations in the Avenue A soils in February 2011. Additionally, included in this report are the assessment of the analytical precision and accuracy for the reported analyte concentration results, the recovery results for a stable isotope labeled surrogate (13C4-P FO S ) that was added to each soil aliquot prior to extraction, and the determined percent moisture (w/w) of each soil. 4 Test, Control and Reference Substances This study does not have a test or control substance in the classic sense of a GLP study because this study was purely analytical to measure specific target analytes in collected environmental samples. The analytical reference substances used are listed in Table 3. Table 3. Reference Substances R eference ID Chemical Name Chemical Formula Use CAS # Source Expiration Date Storage Conditions Chemical Lot Number TCR Number Physical Description Purity PFOS (linear) PFOS (linear + branched) PFHS (linear) n-Perfluorooctane-1Sulfonate Potassium Salt n-C8 F17SO3 K Reference Standard for Calibration and LMSs 2795-39-3 Wellington Laboratories 10/18/13 -20C LPFOSKBM06 TCR08-0001-1/1 Crystalline 98% Perfluorooctane Sulfonate Potassium Salt C8 F17SO3 K Reference Standard for LCSs 2795-39-3 3M 12/14/16 -20C 171 TCR-696 W hite Powder 86.4% n-Perfluorohexane-1-sulfonate Sodium Salt n-C6 F13SO3 Na Reference Standard for Calibration and LMSs 3871-99-6 Wellington Laboratories 3/25/18 -20C LPFHxSAM08 TCR08-0018-1/1 Crystalline >98% 3M Study GLP10-01-02-15 Page 13 of 514 Study: GLP10-01-02, Interim Report 15 Analysis for PFOS, PFHS and PFBS in Avenue A Soils/Sediments Collected January 2011 Table 3. Reference Substances R eference ID Chemical Name Chemical Formula Use CAS # Source Expiration Date Storage Conditions Chemical Lot Number TCR Number Physical Description Purity R eference ID Chemical Name Chemical Formula Use CAS # Source Expiration Date Storage Conditions Chemical Lot Number TCR Number Physical Description Purity PFHS (linear + branched) n-Perfluorohexane-1sulfonate Potassium Salt n-C6F13SO3 K Reference Standard for LCSs 3871-99-6 3M 2/12/17 -20C NB 120067-69 TCR-083 W hite Powder 98.6% [1,2,3,4,5,6,7,8-13C8]PFOS [13 C 8 ]-P e r flu o ro o c ta n e - 1 Sulfonate Sodium Salt 13C8F17SO3 Na Internal Standard for PFOS 2795-39-3 Wellington Laboratories 9/28/2013 -20C 092310 TCR10-0048-3/16, 4/16 M ixed IS m ethanol solution in sealed am poule >98% PFBS (predominantly linear) Perfluorobutane-1-sulfonate Potassium Salt n-C4 FgSC>3 K Reference Standard for All PFBS 29420-49-3 3M 1/10/17 -20C 101 TCR-121 W hite Powder 96.7% [1 3 C 3 ] -PFHS [13 C 3 ]-P e rflu o ro h e x a n e -1 Sulfonate Sodium Salt 13C312C3 F13SO3 Na Internal Standard for PFHS 3871-99-6 W ellington Laboratories 9/28/2013 -20C 092310 TCR10-0048-3/16, 4/16 M ixed IS m ethanol solution in sealed am poule >98% [1 ,2 ,3 ,4 - 1 3 C 4 ]-PFOS [1 ,2 ,3 ,4 -1 3 C 4 ]P e rflu o ro o c ta n e -1 -S u lfo n a te Sodium Salt 13C412C4 F17SO3 Na S u rro g a te 2795-39-3 W ellington Laboratories 9/8/2013 -20C MPFOS0910 T C R 1 0 -0 0 4 4 -2 /9 Methanol solution, sealed ampoule >98% [18O 2]-PFBS [18O 2 ]-P e rflu o ro b u ta n e -1 Sulfonate A m m onium Salt c 4 f 9 s 1 8 o 216o n h 4 Internal Standard for PFBS 29420-49-3 RTI International 3/9/15 -20C 11546-107-2 T C R -1 0 2 6 Methanol solution, sealed am poule >99% 3M Study GLP10-01-02-15 Page 14 of 514 Study: GLP10-01-02, Interim Report 15 Analysis for PFOS, PFHS and PFBS in Avenue A Soils/Sediments Collected January 2011 5 Test System There was not a test system for this study in the classic sense of a GLP study, nor was there a dosed test substance. This study was conducted for the determination of PFOS, PFHS and PFBS concentrations in "real world" environmental samples collected in January 2011 from Avenue A locations at the 3M Decatur, AL site. 6 Method Summary 6.1 Methods Soil extraction and quantitative LC/MS/MS analyses were performed using method ETS-8-053.0. Initially, a range finding (screening) preparation and analysis was conducted to approximate the concentrations of PFOS, PFHS and PFBS in the soils. The range finding results were not reported, but were used to establish the proper LMS fortification concentrations for the reported definitive analysis results. The definitive LC/MS/MS analyses were conducted between March and April of 2011. 6.2 Sample Collection On January 19, 2011 ninety-two (92) 250 -mL HDPE NalgeneTM sample bottles, five (5) 500-mL bottles of Milli-QTM water, and three travel blanks (trip blanks) containing approximately 25 grams of a control soil in each (in sealed 250 mL HDPE bottles), were sent from the 3M Environmental Laboratory to Weston Solutions, Inc. field personnel for collection of soils and sediments during drilling of three off-site wells near the 3M Decatur, AL facility, and nearby locations to the Decatur site. Following the soil sample collections, eighty-six (86) soil and sediment filled sample bottles, four (4) equipment rinseate blank samples and two (2) of the trip blanks were returned back to the laboratory for analysis. Samples were received at the laboratory with sample chains of custody numbers #14967 through #14976 on February 1,2011 and were logged into project GLP10-01-0115 in the 3M laboratory information management system (LIMS) on February 1,2011. Samples were stored refrigerated until they could be extracted and analyzed. Soil samples from Decatur, AL are regulated and were appropriately shipped in accordance with USDA/APHIS soil permit number P330-09-00125. Sample nomenclature followed the form DAL-SS-6xxR-xx-xxxx where the first string defines the Decatur Alabama (DAL) project area, the second string defines the sample media (i.e., SS = soil sample, SD = sediments sample, TRIP = trip blank), the third string defines the sampling location, the fourth string defines the sample type (0 = primary sample, DB = field duplicate, RB = equipment rinseate blank) and the fifth string indicates the sampling depth range (0015 indicates 1.5 ft to 2.0 ft interval soil sample). 6.3 Sample Preparation Once the samples were received at the laboratory, they were refrigerated until extraction could be performed. Each soil/sediment extraction involved removal of a 1 cubic centimeter (1 cc; 1 mL) of sample from each sample bottle using a fixed volume 1 cc spoon, followed by accurate weight determination of the aliquot on a 5-place balance. Then, a known quantity of internal standard (IS; 3M Study GLP10-01-02-15 Page 15 of 514 Study: GLP10-01-02, Interim Report 15 Analysis for PFOS, PFHS and PFBS in Avenue A Soils/Sediments Collected January 2011 nominal 3.0 ng for each) and surrogate (nominal 3.0 ng) were added to each soil aliquot. For laboratory matrix spike (LMS) preparations, an additional known quantity of PFOS (linear), PFHS (linear) and PFBS were also added. After fortification of LMSs were complete, the soil aliquots were each extracted by addition of 8 mL of a 4:1 acetonitrile:water solution followed by sonication for 1 to 2 hours and then centrifugation to remove solids. The supernatant from each extract was transferred to an autovial for analysis. An accurately measured volume of each supernatant was analyzed by LC/MS/MS. For this study, a range finding analysis was initially performed to approximate the concentrations of PFOS, PFHS and PFBS in each soil and sediment sample. The range finding analysis was performed on March 7, 2011 as analytical run 110307b. The range finding results were used to aid in the preparation of LMS samples for the definitive analysis. The range finding results are not reported herein. After the range finding analysis was completed, triplicate aliquots of each sample were taken from each bulk sample bottle and were extracted for definitive analysis. The third aliquot of each was prepared as a LMS and was fortified with a known quantity of PFOS (linear), PFHS (linear) and PFBS prior to extraction. Fortifications were performed at a level that was appropriate to the endogenous analyte level in the soils and were between 0.5- to 10-times the endogenous analyte levels determined from the range finding analysis. For those samples with PFOS levels above the range of the curve, a separate set of LMSs were fortified with PFOS only, in order to minimize interferences in quantifying PFBS and PFHS in those same samples. Definitive analyses were in March and April 2011 as analytical run s110317a,s110321a, s110325b, s110329a, a110325a, a110329a,a110401a and s110411a. Laboratory control spike (LCS) samples were prepared at two levels with each sample extraction batch prepared. Each of the two LCS level s were prepared at 3.0 and 30 ng fortifications, and each LCS level was prepared in triplicate. The LCSs were prepared using control soil TCR-842 and were fortified with PFOS (linear + branched), PFHS (linear + branched) and PFBS. For analytical batches prepared with dilutions, a 300 ng fortified LCS was prepared and was diluted similarly for analysis. A set of calibration standards were prepared by spiking known quantities of PFOS (linear), PFHS (linear) and PFBS, and surrogate (13C4-PFOS) into 1-cubic centimeter (1 cc; equivalent to 1 mL) aliquots of 3M Environmental Laboratory matrix soil TCR-842. The nominal mass of 1 cc of control soil TCR842 is 1.0 gram (dry). Therefore, the range of prepared calibration standards was nominal concentrations 0.200 ng/cc to 500 ng/cc (equivalent to 0.200 ng/mL to 500 ng/mL). When adjusted for the nominal mass of standard soil TCR-842 at nominal 1.0 g/mL (dry) the nominal calibration standard range was 0.200 ng/g to 500 ng/g (dry weight). 6.4 Percent Soil Moisture Determination The percent moisture of each soil and sediment was determined by gravimetric analysis. Dry weights were determined for separate sample weighings than the weighings performed for the LC/MS/M extract preparations. To determine the percent moisture, duplicate aliquots of each soil sample were removed and the accurate "wet" weight determined for each. Then the aliquots were dried at > 100C until no further significant mass loss occurred from water evaporation, at which time the accurate dried weights were determined. The difference in mass, attributed to water evaporation, was used to calculate the percent moisture in the original soil. The averaged percent moisture result for each was then used to calculate the soil PFOS, PFHS and PFBS concentrations on a dry weight basis. 3M Study GLP10-01-02-15 Page 16 of 514 Study: GLP10-01-02, Interim Report 15 Analysis for PFOS, PFHS and PFBS in Avenue A Soils/Sediments Collected January 2011 6.5 LC/MS/MS Analysis The definitive analysis of soil and sediment extracts for PFOS, PFHS and PFBS was performed by liquid chromatography with triple quadrapole mass spectrometric detection (LC/MS/MS) as described in method ETS-8-053.0. The relative percent difference (RPD) of duplicate sample results was used as a measure of analytical precision. The determined recovery of fortified PFOS (linear), PFHS (linear) and PFBS from LMS samples was used as a measure of analytical accuracy. Recovery of the surrogate (13C4-PFOS) is included within this report in Table 14, and is also part of an on-going method validation aspect in which surrogate recovery is being evaluated in real environmental samples. Details of the specific instrument parameters, the liquid chromatography gradient program, and the specific mass transitions analyzed are detailed in the raw data, and are briefly described below in Table 4, Table 5 and Table 6. Table 4. Instrument Information Instrument #1 Name A n a lytica l M ethod ID Liquid C hrom atograph Pre-sam pler column Analytical guard column Analytical column Injection Volum e Mass Spectrom eter Ion S ource P o la rity Software Instrument #2 Name A n a lytica l M ethod ID Liquid C hrom atograph Pre-sam pler column Analytical guard column Analytical column Injection Volum e Mass Spectrom eter Ion S ource P o la rity Software ETS-Stan E T S -8 -0 5 3 .0 A gilent 1100 with Binary Pump P rism RP (2.1 x 50 mm, 5 g) O asis HLB (3 x 20 mm, 25 g); 30C Betasil-C 18 (2.1 x 100 mm, 5 g); 30C 25 gL API 4000 TurboIon Spray N e g a tiv e A nalyst 1.4.2 ETS-Amelia E T S -8 -0 5 3 .0 A gilent 1100 with Binary Pump Prism RP (2.1 x 50 mm, 5 ) O asis HLB (3 x 20 mm, 25 ); 30C B etasil-C 18 (2.1 x 100 mm, 5 ); 30C 20 gL M icrom ass Q uattro II Z-spray N e g a tiv e M asslynx 3.5 3M Study GLP10-01-02-15 Page 17 of 514 Study: GLP10-01-02, Interim Report 15 Analysis for PFOS, PFHS and PFBS in Avenue A Soils/Sediments Collected January 2011 Table 5. Gradient Liquid Chromatography Conditions (ETS-8-053) Step Num ber Total Time [m in] 1 0.0 2 3.0 3 3.5 4 17.0 5 17.5 6 19.5 7 20.0 8 23.0 Flow Rate [m L/m in] 0.400 0.400 0.400 0.400 0.400 0.400 0.400 0.400 Percent A [2 m m Aqueous A m m onium Acetate] 97.0 97.0 70.0 40.0 10.0 10.0 97.0 97.0 Percent B [ A cetonitrile] 3.0 3.0 30.0 60.0 90.0 90.0 3.0 3.0 Table 6. Mass Transitions A n a ly te Mass Transitions M onitored PFBS 299>99, 299>80 18O 2-P F B S (IS) 303>84 PFHS 399>99, 399>80 13C 3-P F H S (IS) 402>80 PFOS 499>130, 499>99, 499>80 13C 8-P F O S (IS) 507>80 13C4-P F O S (S urrogate) 503>80 Note: Multiple mass transitions are summed to give the instrument response for that analyte. 7 Analytical Results Concentration results are rounded to three significant figures according to EPA rounding rules. Because of rounding some calculated values may vary slightly from those found in the raw data. Samples with RPDs for duplicate results of less than 50% and associated LMS results meeting the method acceptance criteria of 100 30% demonstrated that the method was appropriate for those samples and were reported without footnotes in results tables. Samples with LMS or RPD results outside of those criteria, but still reportable per protocol defined reporting criteria, were reported with exception footnotes in results tables. Those outside of reporting criteria were not reported (NR). The LMS spiked concentrations were adequate for the given matrix and their respective quantitative ranges of PFOS, PFHS and PFBS measured in the samples as determined during the range finding analysis. 7.1 Calibration A set of calibration standards were prepared by spiking varying known quantities of PFOS (linear), PFHS (linear), PFBS and surrogate (13C4-PFOS), and a fixed quantity of stable isotope labeled internal standards, into one cubic centimeter (1 cc, 1 mL) aliquots of 3M Environmental Laboratory control soil TCR-842 (nominal soil mass of 1.0 g/mL). A total of twelve (12) calibration standards were prepared as 3M Study GLP10-01-02-15 Page 18 of 514 Study: GLP10-01-02, Interim Report 15 Analysis for PFOS, PFHS and PFBS in Avenue A Soils/Sediments Collected January 2011 a set. The prepared standards ranged from nominal concentration 0.200 ng/mL to 500 ng/mL of soils, equivalent to nominal 0.200 ng/g to 500 ng/g for TCR-842. Following analysis of the calibration standards, the concentration of each standard was plotted against the measured analyte /IS peak area ratio. A quadratic equation with 1/x weighting was used to fit the data for each analyte. Calibration curves were not forced through zero. Determining the standard concentration using the resultant calibration curve and comparing to the known concentration confirmed accuracy of each curve point at within 100 30% (+ 35% at the LLOQ). The correlation coefficient (r) was greater than 0.999 for all calibration curves, and the coefficient of determination (r2) was greater than 0.990. Calibration results for PFOS, PFHS and PFBS are summarized in Table 7, Table 8 and Table 9, respectively. Because soil weights may vary significantly for a 1 cc (1 mL) field sample, depending on soil type and moisture content, the instrument response was calibrated for the known concentrations of target analytes based on the mass quantity of each pertinent reference substance added to a 1 cc soil (1 mL) calibration standard prior to extraction (e.g. calibrated in this study for a range of 0.200 ng/mL to 500 ng/mL PFOS, PFHS and PFBS). Because a 1cc aliquot of control soil TCR-842 weighs nominally 1.0 gram (dry weight) and has less than 5% moisture content, the nominal concentration range of the calibration was essentially 0.200 ng/g to 500 ng/g. However, because the sample soil aliquots typically weigh more than 1.0 gram and contain significant moisture, the determined concentrations during the analysis on an ng/mL basis from the calibration curve were adjusted for the accurate determined weight and percent moisture so they could be reported on a ng/g (dry weight) basis. Table 7. PFOS Calibration Summary A n a ly tic a l Run Actual s110317a s110321a s110325b s110329a a110325a a110329a a110401a s110411a Avg. Result Std.Dev. RSD Average Recovery n STD 1 0.200 0 .2 4 1 0 .1 9 1 0 .1 8 1 0 .2 2 5 0 .1 6 3 0 .2 0 6 0 .2 2 7 0 .2 3 4 0.209 0.028 13% 104% 8 PFOS (n g /m L ) STD 2 STD 3 STD 4 STD 5 STD 6 STD 7 STD 8 0.500 0 .4 2 7 0 .4 6 5 0 .4 5 1 0 .5 0 7 0 .5 5 1 0 .5 3 5 0 .5 4 4 0 .4 9 5 0.497 0.046 9.2% 99.4% 8 0.749 0 .7 5 1 0 .6 7 3 0 .7 8 8 0 .6 6 7 0 .7 9 0 0 .5 8 3 0 .6 8 5 0 .7 6 2 0.712 0.073 10% 95.1% 8 0.999 0 .9 4 5 1 .0 3 1 .0 5 1 .0 1 0 .9 2 1 1 .1 3 0 .8 9 0 .9 2 7 0.988 0.081 8.2% 98.9% 8 2.50 2 .5 2 .6 2 2 .5 1 2 .5 0 2 .6 7 2 .5 9 2 .3 7 2 .5 4 2.54 0.092 3.6% 102% 8 5.00 5 .0 5 5 .2 6 5 .0 6 4 .9 6 5 .3 6 4 .8 0 5 .0 1 5 .0 0 5.06 0.17 3.5% 101% 8 9.99 9 .7 9 1 0.5 1 0.4 9 .3 5 9 .8 8 9 .7 6 9 .8 2 9 .0 9 9.82 0.47 4.8% 98% 8 25.0 2 5.7 2 6.0 2 6.9 2 5.3 2 4.6 2 5.2 2 6.2 2 4.8 25.6 0.77 3.0% 102% 8 STD 9 50.0 4 9 .9 4 7 .9 4 9 .7 5 2.2 5 0.5 5 0.4 5 0.4 4 9.1 50.0 1.2 2.5% 100% 8 STD 10 99.9 9 5.4 9 9.2 9 4.1 9 6.4 9 7.6 9 9.6 9 7.5 9 5.4 96.9 1.9 2.0% 97.0% 8 STD 11 200 206 201 204 202 202 200 201 210 203 3.3 1.6% 102% 8 STD 12 500 498 500 499 500 499 500 500 496 499 1.4 0.28% 99.8% 8 r N/A 0.9998 0 .9 9 9 9 0.9997 0.9998 0.9999 0.9999 0.9999 0.9995 0.9998 0.00014 0.014% N/A 8 3M Study GLP10-01-02-15 Page 19 of 514 Study: GLP10-01-02, Interim Report 15 Analysis for PFOS, PFHS and PFBS in Avenue A Soils/Sediments Collected January 2011 Table 8. PFHS Calibration Summary A n a ly tic a l Run Actual s110317a s110321a s110325b a110325a a110329a s110411a Avg. Result Std.Dev. RSD Average Recovery n STD 1 0.199 0 .1 9 8 0 .1 6 5 0 .1 6 3 N/A 0 .1 9 7 0 .1 7 7 0.180 0.017 9.4% 90.5% 5 STD 2 STD 3 0.499 0 .4 4 4 0 .4 6 7 0 .4 7 7 0 .5 3 2 0 .4 1 7 0 .5 0 8 0.474 0.042 8.8% 95.0% 6 0.748 0 .7 8 1 0 .7 9 7 0 .7 5 3 0 .7 4 9 0 .7 6 8 0 .7 1 6 0.761 0.028 3.7% 102% 6 STD 4 0.997 0 .9 9 7 1 .0 7 1 .0 8 0 .9 3 8 1 .0 8 0 .9 9 1 1.03 0.059 5.8% 103% 6 PFHS (n g /m L ) STD 5 STD 6 STD 7 STD 8 2.49 2 .4 4 2 .5 1 2 .6 0 2 .3 0 2 .6 4 2 .7 0 2.53 0.15 5.8% 102% 6 4.99 5 .1 0 5 .1 4 5 .3 3 5 .0 2 4 .8 7 5 .1 9 5.11 0.16 3.1% 102% 6 9.97 9 .9 7 9 .9 8 9 .8 6 1 0.4 1 0.1 9 .6 2 9.99 0.26 2.6% 100% 6 24.9 2 6.5 2 6.6 2 5.6 2 6.2 2 5.9 2 6.2 26.2 0.37 1.4% 105% 6 STD 9 49.9 5 2.2 4 9 .9 5 1.3 4 9 .0 4 9 .6 5 0.6 50.4 1.2 2.3% 101% 6 STD 10 99.7 9 6.5 9 8.6 9 7.6 9 6.8 9 8.0 9 9.4 97.8 1.1 1.1% 98.1% 6 STD 11 199 197 197 198 202 200 196 198 2.3 1.1% 99.7% 6 STD 12 499 500 500 500 498 499 501 500 1.0 0.21% 100% 6 r N/A 0.9998 0 .9 9 9 9 0.9999 0.9999 0.9999 0.9999 0.9999 0.000041 0.0041% N/A 6 Table 9. PFBS Calibration Summary A n a ly tic a l Run Actual s110317a s110321a s110325b s110411a Avg. Result Std.Dev. RSD Average Recovery n STD 1 0.200 0 .1 8 9 0 .2 2 5 0 .1 8 3 0 .1 8 5 0.196 0.020 10% 97.8% 4 STD 2 0.500 0 .4 5 5 0 .4 3 2 0 .4 8 1 0 .4 9 6 0.466 0.028 6.1% 93.2% 4 STD 3 0.749 0 .7 8 9 0 .6 9 9 0 .6 9 2 0 .7 5 0.733 0.046 6.2% 97.8% 4 PFBS (n g /m L ) STD 4 STD 5 STD 6 STD 7 STD 8 0.999 0 .9 4 6 0 .9 9 3 1 .0 0 0 .9 4 5 0.971 0.030 3.0% 97.2% 4 2.50 2 .5 8 2 .5 4 2 .5 6 2 .6 8 2.59 0.062 2.4% 104% 4 5.00 5 .1 9 5 .1 7 5 .3 0 5 .1 4 5.20 0.070 1.3% 104% 4 9.99 1 0.1 1 0.2 1 0.5 9 .5 9 10.1 0.38 3.7% 101% 4 25.0 2 6.1 2 4.8 2 7.1 2 7.1 26.3 1.1 4.2% 105% 4 STD 9 50.0 5 2.4 5 1.8 5 0.8 5 1.2 51.6 0.70 1.4% 103% 4 STD 10 99.9 9 7.8 9 8.9 9 6.1 9 7.3 97.5 1.2 1.2% 97.6% 4 STD 11 200 196 198 199 198 198 1.3 0.64% 98.9% 4 STD 12 500 502 501 501 502 502 0.58 0.12% 100% 4 r N/A 0.9998 0 .9 9 9 9 0.9997 0.9998 0.9998 0.000082 0.0082% N/A 4 7.2 Limits of Quantitation (LOQs) The lower limit of quantitation (LLOQ) is considered to be the lowest non-zero calibration standard in the curve that meets linearity and accuracy requirements (100 + 35%) and for which the area counts are at least 2-times that of the average response determined from the method blanks. The LLOQ for this study was determined as nominal 0.200 ng/g for PFHS and PFOS. The LLOQ for PFBS was nominal 0.500 ng/g. Each sample that gave an analyte response less than the response of the LLOQ calibration standard was reported as BLQ (below the lower limit of quantitation). The upper limit of quantitation (ULOQ) was nominal concentration 200 ng/g for all analytes, and samples with endogenous analyte levels at greater than the ULOQ were appropriately diluted with extracts from method blanks to achieve analyte results within the curve range. The PFOS concentrations in most of 3M Study GLP10-01-02-15 Page 20 of 514 Study: GLP10-01-02, Interim Report 15 Analysis for PFOS, PFHS and PFBS in Avenue A Soils/Sediments Collected January 2011 the LMS samples exceeded the ULOQ and required dilution. Samples with an analyte/IS peak area response ratio that was less than the LLOQ analyte/IS response ratio were reported as below the limits of quantitation (BLQ). 7.3 Continuing Calibration Verification During the course of each analysis, continuing calibration verifications (CCVs) was performed by injection of a mid-level calibration standard to confirm that the instrument response and the initial calibration curve were still in control. All CCVs flanking reported data met the method criteria of 100% 30% (+ 35% at LLOQ). 7.4 Blanks Four types of blanks were analyzed during this analysis, and included the following: three method blanks were prepared with blank matrix soil TCR-842 and were spiked with IS, three method blanks without IS were prepared, two travel blanks (trip blanks) were prepared from aliquots of the travel blanks that accompanied the sample shipment, and solvent blanks contained extraction solvent. The different blanks results are reviewed to evaluate potential contamination during shipment and sampling, to evaluate method performance parameters such as injector carry over and also to establish the LLOQ. In addition to the aforementioned blanks, four aqueous equipment rinseate blanks were received with the soils/sediments and were analyzed by a sensitive water analysis LC/MS/MS method. The results for the equipment rinseate blank samples showed PFBS, PFHS and PFOS were less than the LLOQ of 0.0250 ng/mL for that analysis. 7.5 Laboratory Control Spikes (LCSs) Laboratory control spikes were prepared by spiking know quantities of PFOS (linear + branched), PFHS (linear + branched) and PFBS into 1 cc aliquots of soil TCR-842, fortified with nominal 3.0 ng, 30 ng and 300 ng, with each level prepared in triplicate. The analysis of LCSs was split between runs when the samples from one preparation batch, prepared with the set of LCSs, were analyzed in more than one analytical run. The results of the LCS analyses and calculation of analyte measurement accuracies (percent recovery) for PFOS, PFHS and PFBS are shown in Table 10, Table 11 and Table 12, respectively. The LCS recoveries were calculated using the following equation: (Determined Concentration of LCS) LCS Recovery * 100% Spike Concentration 3M Study GLP10-01-02-15 Page 21 of 514 Study: GLP10-01-02, Interim Report 15 Analysis for PFOS, PFHS and PFBS in Avenue A Soils/Sediments Collected January 2011 Table 10. LCS Results (PFOS) S a m p le ID Actual Conc. (ng/g) LCS 1 (ru n s 1 1 0 3 1 7 a ) LCS 2 (ru n s 1 1 0 3 1 7 a ) LCS 3 (ru n s 1 1 0 3 1 7 a ) LCS 1 (ru n s 1 1 0 3 2 1 a ) LCS 2 (ru n s 1 1 0 3 2 1 a ) LCS 3 (ru n s 1 1 0 3 2 1 a ) LCS 1 (ru n s 1 1 0 3 2 5 b ) LCS 2 (ru n s 1 1 0 3 2 5 b ) LCS 3 (ru n s 1 1 0 3 2 5 b ) LCS 1 (ru n a 1 1 0 3 2 5 a ) LCS 2 (ru n a 1 1 0 3 2 5 a ) LCS 3 (ru n a 1 1 0 3 2 5 a ) LCS 1 (ru n s 1 1 0 4 1 1 a ) LCS 2 (ru n s 1 1 0 4 1 1 a ) LCS 3 (ru n s 1 1 0 4 1 1 a ) A verage S ta n d a rd D ev ia tio n RSD A v e ra g e LCS R e c o v e ry Table 11. LCS Results (PFHS) S a m p le ID Actual Conc. (ng/g) LCS 1 (ru n s 1 1 0 3 1 7 a ) LCS 2 (ru n s 1 1 0 3 1 7 a ) LCS 3 (ru n s 1 1 0 3 1 7 a ) LCS 1 (ru n s 1 1 0 3 2 1 a ) LCS 2 (ru n s 1 1 0 3 2 1 a ) LCS 3 (ru n s 1 1 0 3 2 1 a ) LCS 1 (ru n s 1 1 0 3 2 5 b ) LCS 2 (ru n s 1 1 0 3 2 5 b ) LCS 3 (ru n s 1 1 0 3 2 5 b ) LCS 1 (ru n a 1 1 0 3 2 5 a ) LCS 2 (ru n a 1 1 0 3 2 5 a ) LCS 3 (ru n a 1 1 0 3 2 5 a ) LCS 1 (ru n s 1 1 0 4 1 1 a ) LCS 2 (ru n s 1 1 0 4 1 1 a ) LCS 3 (ru n s 1 1 0 4 1 1 a ) A verage S ta n d a rd D ev ia tio n RSD A v e ra g e LCS R e c o v e ry 3 .0 n g LCS 2.99 3 .2 2 3 .1 7 3 .1 8 N /A N /A N /A N /A N /A N /A N /A N /A N /A 2 .9 5 3 .0 3 2 .9 2 3 .0 8 0 .1 3 4 .2 % 103% M e a s u re d PFOS (ng) 3 0 n g LCS 29.9 N /A N /A N /A 3 0 .4 3 3 .9 3 4.3 N /A N /A N /A N /A N /A N /A 3 1 .6 31 2 9 .9 3 1 .9 1 .8 5 .8 % 107% 3 .0 n g LCS 2.99 3 .2 1 3 .4 2 3 .3 2 N /A N /A N /A N /A N /A N /A N /A N /A N /A 3 .3 4 3 .2 4 3 .3 6 3 .3 2 0 .0 7 8 2 .4 % 111% M e a s u re d PFHS (ng ) 3 0 n g LCS 29.9 N /A N /A N /A 3 3.3 3 5 .9 3 3 .7 N /A N /A N /A N /A N /A N /A 3 3 .8 3 4 .7 3 5.5 3 4.5 1 .1 3 .1 % 115% 3 0 0 n g LCS 299 N /A N /A N /A N /A N /A N /A 369 340 356 310 314 289 N /A N /A N /A 330 30 9 .2 % 110% 3 0 0 n g LCS 299 N /A N /A N /A N /A N /A N /A 346 324 350 334 337 308 N /A N /A N /A 333 15 4 .6 % 111% 3M Study GLP10-01-02-15 Page 22 of 514 Study: GLP10-01-02, Interim Report 15 Analysis for PFOS, PFHS and PFBS in Avenue A Soils/Sediments Collected January 2011 Table 12. LCS Results (PFBS) S a m p le ID Actual Conc. (ng/g) LCS 1 (ru n s 1 1 0 3 1 7 a ) LCS 2 (ru n s 1 1 0 3 1 7 a ) LCS 3 (ru n s 1 1 0 3 1 7 a ) LCS 1 (ru n s 1 1 0 3 2 1 a ) LCS 2 (ru n s 1 1 0 3 2 1 a ) LCS 3 (ru n s 1 1 0 3 2 1 a ) LCS 1 (ru n s 1 1 0 3 2 5 b ) LCS 2 (ru n s 1 1 0 3 2 5 b ) LCS 3 (ru n s 1 1 0 3 2 5 b ) LCS 1 (ru n s 1 1 0 4 1 1 a ) LCS 2 (ru n s 1 1 0 4 1 1 a ) LCS 3 (ru n s 1 1 0 4 1 1 a ) A verage S ta n d a rd D ev ia tio n RSD A v e ra g e LCS R e c o v e ry 3 .0 n g LCS 3.00 2 .9 8 3 .1 2 3 .2 8 N /A N /A N /A N /A N /A N /A 3 .3 1 3 .1 4 3 .1 5 3 .1 6 0 .1 2 3 .8 % 105% M e a s u re d PFBS (ng) 3 0 n g LCS 30.0 N /A N /A N /A 3 0.2 3 0 .8 3 3.5 N /A N /A N /A 3 1.3 3 1 .9 3 1.2 3 1.5 1 .1 4 3 .6 % 105% 3 0 0 n g LCS 300 N /A N /A N /A N /A N /A N /A 314 309 317 N /A N /A N /A 313 4 .0 4 1 .3 % 104% 7.6 Laboratory Matrix Spikes (LMSs) Laboratory matrix spikes (LMSs) were generated by adding a known quantity of PFOS (linear), PFHS (linear) and PFBS to an aliquot of soil collected from the field, and then preparing the sample the same as non-spiked samples. Spikes for this study, LMSs were spiked at levels that were appropriate for the endogenous analyte levels in the soils, determined from screening analysis and fortified with the target analytes from 0.5-times to 10-times the endogenous analyte levels determined in the soil/sediment samples during the range finding analysis. The LMS method acceptance criterion of within 100 30% were met for all reported results. The LMS recovery results are summarized in Table 2, and individual sample results for PFOS, PFHS and PFBS are shown in Table 14, Table 15 and Table 16, respectively. The PFOS, PFHS and PFBS recovery calculations for LMSs used the following equation: TL,,M,,S ,,Recovery = -(-D--e-t-e-r--m--i-n--e-d---C--o-n--c-e--n-t-r--a-t-i-o-n---o-f---L--M--S------D--e--t-e-r-m---i-n--e-d--C---o-n--c-e-n--t-r-a--t-i-o-n---o-f--F--i-e-l-d---S-a--m- --ple) *. .100%. Spike Concentration 7.7 Percent Soil Moisture Determinations The percent moisture was determined for each soil and sediment sample. Duplicate aliquots of each were taken and accurately weighed to determine the "wet"weight. Then each aliquot was dried at > 100C until no further loss in mass occurred due to water evaporation, then the dry weight was accurately determined. The average percent moisture and RPD of the duplicate determinations for each soil are reported in Table 13. The percent moisture was calculated by the following equation: 3M Study GLP10-01-02-15 Page 23 of 514 Study: GLP10-01-02, Interim Report 15 Analysis for PFOS, PFHS and PFBS in Avenue A Soils/Sediments Collected January 2011 ,, ,,, . (Original Soil Wet Mass - Dried Soil Mass) . Percent Moisture = --- ------------------------------------------------ - * 100% Original Soil Wet Mass Table 13. Percent Moistures for Decatur, AL Avenue A Soils & Sediments, January 2011. LIMS ID GLP10-01-01-15-001 GLP10-01-01-15-002 GLP10-01-01-15-003 GLP10-01-01-15-004 GLP10-01-01-15-005 GLP10-01-01-15-006 GLP10-01-01-15-007 GLP10-01-01-15-008 GLP10-01-01-15-009 GLP10-01-01-15-010 GLP10-01-01-15-011 GLP10-01-01-15-012 GLP10-01-01-15-014 GLP10-01-01-15-015 GLP10-01-01-15-016 GLP10-01-01-15-018 GLP10-01-01-15-020 GLP10-01-01-15-021 GLP10-01-01-15-022 GLP10-01-01-15-023 GLP10-01-01-15-024 GLP10-01-01-15-025 GLP10-01-01-15-026 GLP10-01-01-15-027 GLP10-01-01-15-028 GLP10-01-01-15-029 GLP10-01-01-15-030 GLP10-01-01-15-031 GLP10-01-01-15-032 Sample ID DAL SS Trip1 0 0000 DAL SS SS12 0 0000 DAL SS SS12 0 0005 DAL SS SS13 0 0000 DAL SS SS16 0 0000 DAL SS SS16 DB 0000 DAL SS SS11 0 0000 DAL SS SS11 0 0005 DAL SS SS20 0 0000 DAL SS SS20 DB 0000 DAL SS SS19 0 0000 DAL SS SS19 0 0005 DAL SS SS15 0 0000 DAL SS SS17 0 0000 DAL SS SS14 0 0000 DAL SS SS18 0 0000 DAL SS SS10 0 0000 DAL SS SS30 0 0000 DAL SS SS30 0 0005 DAL SS SS30 0 0015 DAL SS SS25 0 0000 DAL SS SS25 0 0005 DAL SS SS25 0 0015 DAL SD SD22 0 0000 DAL SD SD22 0 0005 DAL SD SD22 DB 0005 DAL SD SD22 0 0015 DAL SD SD21 0 0000 DAL SD SD21 0 0005 Moisture Content (%, w/w) [a] 3.29 17.6 8.32 16.4 17.7 19.3 15.3 11.2 [c] 7.20 8.16 9.63 16.5 7.05 [b, c] 4.46 14.1 9.67 23.7 19.7 17.5 20.0 26.2 14.1 16.6 25.6 17.7 17.6 16.3 33.7 25.2 Relative Percent Difference [a] 1.2 6.9 1.6 4.2 2.2 12 8.6 0.15 8.5 4.6 6.6 2.3 22 6.1 7.4 8.7 3.5 12 1.2 3.5 2.8 1.3 0.026 6.3 3.4 3.7 0.47 0.31 5.1 3M Study GLP10-01-02-15 Page 24 of 514 Study: GLP10-01-02, Interim Report 15 Analysis for PFOS, PFHS and PFBS in Avenue A Soils/Sediments Collected January 2011 Table 13. Percent Moistures for Decatur, AL Avenue A Soils & Sediments, January 2011. LIMS ID GLP10-01-01-15-033 GLP10-01-01-15-034 GLP10-01-01-15-035 GLP10-01-01-15-036 GLP10-01-01-15-037 GLP10-01-01-15-038 GLP10-01-01-15-039 GLP10-01-01-15-040 GLP10-01-01-15-041 GLP10-01-01-15-042 GLP10-01-01-15-043 GLP10-01-01-15-044 GLP10-01-01-15-045 GLP10-01-01-15-046 GLP10-01-01-15-047 GLP10-01-01-15-048 GLP10-01-01-15-049 GLP10-01-01-15-050 GLP10-01-01-15-051 GLP10-01-01-15-052 GLP10-01-01-15-053 GLP10-01-01-15-054 GLP10-01-01-15-055 GLP10-01-01-15-056 GLP10-01-01-15-057 GLP10-01-01-15-058 GLP10-01-01-15-059 GLP10-01-01-15-060 GLP10-01-01-15-061 GLP10-01-01-15-062 GLP10-01-01-15-063 GLP10-01-01-15-064 Sample ID DAL SD SD21 0 0015 DAL SS SS24 0 0000 DAL SS SS24 0 0005 DAL SS SS24 0 0015 DAL SS SS29 0 0000 DAL SS SS29 0 0005 DAL SS SS29 0 0015 DAL SS SS20 0 0005 DAL SS SS13 0 0005 DAL SS SS13 DB 0005 DAL SS SS15 0 0005 DAL SS SS17 0 0005 DAL SS SS14 0 0005 DAL SS SS18 0 0005 DAL SS SS16 0 0005 DAL SS SS16 0 0015 DAL SS SS10 0 0005 DAL SS SS10 DB 0005 DAL SS SS10 0 0015 DAL SD SD20 0 0000 DAL SD SD20 0 0005 DAL SD SD20 0 0015 DAL SD SD23 0 0000 DAL SD SD23 0 0005 DAL SD SD23 0 0015 DAL SS SS28 0 0000 DAL SS SS28 0 0005 DAL SS SS28 DB 0005 DAL SS SS28 0 0015 DAL SS SS27 0 0000 DAL SS SS27 0 0005 DAL SS SS27 0 0015 Moisture Content (%, w/w) [a] 16.9 18.7 25.4 18.1 20.7 14.1 19.2 19.7 17.9 18.6 15.5 18.7 11.4 [b] 16.6 15.7 16.4 13.7 13.8 23.1 32.5 27.2 25.2 22.4 16.9 15.5 15.7 14.6 14.8 21.5 15.6 13.9 16.4 Relative Percent Difference [a] 3.1 1.2 2.5 0.068 5.3 4.1 2.1 7.4 5.2 1.1 11 7.6 29 1.9 2.5 3.7 1.7 2.6 3.0 7.6 2.4 3.7 3.3 2.9 2.2 0.88 2.3 4.1 4.0 3.1 3.2 1.0 3M Study GLP10-01-02-15 Page 25 of 514 Study: GLP10-01-02, Interim Report 15 Analysis for PFOS, PFHS and PFBS in Avenue A Soils/Sediments Collected January 2011 Table 13. Percent Moistures for Decatur, AL Avenue A Soils & Sediments, January 2011. LIMS ID GLP10-01-01-15-065 Sample ID DAL SS SS22 0 0000 Moisture Content (%, w/w) [a] 20.1 Relative Percent Difference [a] 2.6 GLP10-01-01-15-066 DAL SS SS22 0 0005 18.9 1.1 GLP10-01-01-15-067 DAL SS SS22 DB 0005 17.9 6.6 GLP10-01-01-15-068 DAL SS SS22 0 0015 16.9 1.5 GLP10-01-01-15-069 DAL SS SS21 0 0000 19.7 15 GLP10-01-01-15-070 DAL SS SS21 0 0005 14.9 4.5 GLP10-01-01-15-071 DAL SS SS21 0 0015 18.3 1.6 GLP10-01-01-15-072 DAL SD SD18 0 0000 24.3 12 GLP10-01-01-15-073 DAL SD SD18 0 0005 21.5 1.1 GLP10-01-01-15-074 DAL SD SD18 0 0015 26.5 2.4 GLP10-01-01-15-075 DAL SD SD19 0 0000 24.9 0.48 GLP10-01-01-15-076 DAL SD SD19 0 0005 21.8 0.41 GLP10-01-01-15-077 DAL SD SD19 0 0015 24.7 8.3 GLP10-01-01-15-079 DAL SS SS26 0 0000 18.5 1.5 GLP10-01-01-15-080 DAL SS SS26 DB 0000 18.9 1.1 GLP10-01-01-15-081 DAL SS SS26 0 0005 12.7 6.4 GLP10-01-01-15-082 DAL SS SS26 0 0015 12.4 4.5 GLP10-01-01-15-083 DAL SS Trip2 0 0000 2.9 4.6 GLP10-01-01-15-084 DAL SS SS12 0 0015 14.2 2.7 GLP10-01-01-15-085 DAL SS SS19 0 0015 19.5 4.9 GLP10-01-01-15-086 DAL SS SS20 0 0015 21.4 4.4 GLP10-01-01-15-087 DAL SS SS14 0 0015 16.8 11 GLP10-01-01-15-088 DAL SS SS17 0 0015 19.3 2.2 GLP10-01-01-15-089 DAL SS SS13 0 0015 19.7 2.6 GLP10-01-01-15-090 DAL SS SS15 0 0015 18.5 2.6 GLP10-01-01-15-091 DAL SS SS18 0 0015 15.9 1.8 GLP10-01-01-15-092 DAL SS SS11 0 0015 15.9 4.1 [a] R esult determ ined as the average result for duplicate soil aliquots rem oved from each sam ple bottle. [b] RPD of duplicate results was greater than 20% [c] Value was determ ined from a second dry w eight determ ination when first determ ination had a high RPD 3M Study GLP10-01-02-15 Page 26 of 514 Study: GLP10-01-02, Interim Report 15 Analysis for PFOS, PFHS and PFBS in Avenue A Soils/Sediments Collected January 2011 Individual Sample Results Table 14. Individual PFOS Results for Decatur, AL Avenue A Soils & Sediments, January 2011 LIMS Sample ID Sample Description GLP10-01-01-15-001 GLP10-01-01-15-001 Dup GLP10-01-01-15-001 LMS GLP10-01-01-15-002 GLP10-01-01-15-002 Dup GLP10-01-01-15-002 LMS GLP10-01-01-15-003 GLP10-01-01-15-003 Dup GLP10-01-01-15-003 LMS GLP10-01-01-15-004 GLP10-01-01-15-004 Dup GLP10-01-01-15-004 LMS GLP10-01-01-15-005 GLP10-01-01-15-005 Dup GLP10-01-01-15-005 LMS GLP10-01-01-15-006 GLP10-01-01-15-006 Dup GLP10-01-01-15-006 LMS GLP10-01-01-15-007 GLP10-01-01-15-007 Dup GLP10-01-01-15-007 LMS GLP10-01-01-15-008 GLP10-01-01-15-008 Dup GLP10-01-01-15-008 LMS GLP10-01-01-15-009 GLP10-01-01-15-009 Dup GLP10-01-01-15-009 LMS GLP10-01-01-15-010 GLP10-01-01-15-010 Dup GLP10-01-01-15-010 LMS GLP10-01-01-15-011 GLP10-01-01-15-011 Dup GLP10-01-01-15-011 LMS GLP10-01-01-15-012 GLP10-01-01-15-012 Dup GLP10-01-01-15-012 LMS GLP10-01-01-15-014 GLP10-01-01-15-014 Dup GLP10-01-01-15-014 LMS GLP10-01-01-15-015 GLP10-01-01-15-015 Dup GLP10-01-01-15-015 LMS GLP10-01-01-15-016 GLP10-01-01-15-016 Dup GLP10-01-01-15-016 LMS DAL SS Trip1 0 0000 DAL SS Trip1 0 0000 Lab Duplicate DAL SS Trip1 0 0000 Lab Matrix Spike DAL SS SS12 0 0000 DAL SS SS12 0 0000 Lab Duplicate DAL SS SS12 0 0000 Lab Matrix Spike DAL SS SS12 0 0005 DAL SS SS12 0 0005 Lab Duplicate DAL SS SS12 0 0005 Lab Matrix Spike DAL SS SS13 0 0000 DAL SS SS13 0 0000 Lab Duplicate DAL SS SS13 0 0000 Lab Matrix Spike DAL SS SS16 0 0000 DAL SS SS16 0 0000 Lab Duplicate DAL SS SS16 0 0000 Lab Matrix Spike DAL SS SS16 DB 0000 DAL SS SS16 DB 0000 Lab Duplicate DAL SS SS16 DB 0000 Lab Matrix Spike DAL SS SS11 0 0000 DAL SS SS11 0 0000 Lab Duplicate DAL SS SS11 0 0000 Lab Matrix Spike DAL SS SS11 0 0005 DAL SS SS11 0 0005 Lab Duplicate DAL SS SS11 0 0005 Lab Matrix Spike DAL SS SS20 0 0000 DAL SS SS20 0 0000 Lab Duplicate DAL SS SS20 0 0000 Lab Matrix Spike DAL SS SS20 DB 0000 DAL SS SS20 DB 0000 Lab Duplicate DAL SS SS20 DB 0000 Lab Matrix Spike DAL SS SS19 0 0000 DAL SS SS19 0 0000 Lab Duplicate DAL SS SS19 0 0000 Lab Matrix Spike DAL SS SS19 0 0005 DAL SS SS19 0 0005 Lab Duplicate DAL SS SS19 0 0005 Lab Matrix Spike DAL SS SS15 0 0000 DAL SS SS15 0 0000 Lab Duplicate DAL SS SS15 0 0000 Lab Matrix Spike DAL SS SS17 0 0000 DAL SS SS17 0 0000 Lab Duplicate DAL SS SS17 0 0000 Lab Matrix Spike DAL SS SS14 0 0000 DAL SS SS14 0 0000 Lab Duplicate DAL SS SS14 0 0000 Lab Matrix Spike Surrogate (13C4-PFOS) Recovery [a] 102% 108% 110% 123% 115% 155% 133% 130% 155% 109% 119% 110% 98.3% 106% 111% 108% 109% 109% 108% 100% 102% 135% 110% 97.2% 109% 115% 112% 107% 99.7% 113% 108% 108% 104% 103% 108% 115% 107% 106% 98.6% 107% 103% 102% 99.0% 122% 122% Actual LMS Spike Conc. (ng/g; dry weight) N/A 0.8 8 8 N/A 2660 N/A 3020 N/A 214 N/A 430 N/A 397 N/A 90.9 N/A 65.2 N/A 172 N/A 179 N/A NR N/A 485 N/A 180 N/A 79.3 N/A 439 Measured PFOS Concentration (ng/g; dry weight) BLQ BLQ 0.876 2740 1480 3830 5760 5900 8410 119 127 356 324 301 646 302 298 693 63.1 51.7 156 97.6 100 207 98.7 106 309 80 134 338 NR NR NR 371 424 811 107 437 459 62.3 60.1 148 302 347 675 RPD / LMS Recover y (%) N/A 98.7% 60% 64.4% 2.4% 85.5% 6.5% 109% 7.2% 77.6% 1 .2 % 99.2% 20% 108% 2 .6 % 147% 7.1% 120% 51% 129% NR NR 13.1% 85.3% 121% 104% 3.6% 109% 14% 79.7% Average PFOS Conc. (ng/g; dry wt.) BLQ N/A 2 1 1 0 [a. b] N/A 5830 N/A 123 N/A 312 N/A 300 N/A 57.4 N/A 98.9 [b, c] N/A 102 N/A 107 [a] N/A NR N/A 397 N/A 272 N/A 61.2 N/A 324 N/A 3M Study GLP10-01-02-15 Page 27 of 514 Study: GLP10-01-02, Interim Report 15 Analysis for PFOS, PFHS and PFBS in Avenue A Soils/Sediments Collected January 2011 Table 14. Individual PFOS Results for Decatur, AL Avenue A Soils & Sediments, January 2011 LIMS Sample ID Sample Description GLP10-01-01-15-018 GLP10-01-01-15-018 Dup GLP10-01-01-15-018 LMS GLP10-01-01-15-020 GLP10-01-01-15-020 Dup GLP10-01-01-15-020 LMS GLP10-01-01-15-021 GLP10-01-01-15-021 Dup GLP10-01-01-15-021 LMS GLP10-01-01-15-022 GLP10-01-01-15-022 Dup GLP10-01-01-15-022 LMS GLP10-01-01-15-023 GLP10-01-01-15-023 Dup GLP10-01-01-15-023 LMS GLP10-01-01-15-024 GLP10-01-01-15-024 Dup GLP10-01-01-15-024 LMS GLP10-01-01-15-025 GLP10-01-01-15-025 Dup GLP10-01-01-15-025 LMS GLP10-01-01-15-026 GLP10-01-01-15-026 Dup GLP10-01-01-15-026 LMS GLP10-01-01-15-027 GLP10-01-01-15-027 Dup GLP10-01-01-15-027 LMS GLP10-01-01-15-028 GLP10-01-01-15-028 Dup GLP10-01-01-15-028 LMS GLP10-01-01-15-029 GLP10-01-01-15-029 Dup GLP10-01-01-15-029 LMS GLP10-01-01-15-030 GLP10-01-01-15-030 Dup GLP10-01-01-15-030 LMS GLP10-01-01-15-031 GLP10-01-01-15-031 Dup GLP10-01-01-15-031 LMS GLP10-01-01-15-032 GLP10-01-01-15-032 Dup GLP10-01-01-15-032 LMS GLP10-01-01-15-033 GLP10-01-01-15-033 Dup GLP10-01-01-15-033 LMS GLP10-01-01-15-034 GLP10-01-01-15-034 Dup GLP10-01-01-15-034 LMS DAL SS SS18 0 0000 DAL SS SS18 0 0000 Lab Duplicate DAL SS SS18 0 0000 Lab Matrix Spike DAL SS SS10 0 0000 DAL SS SS10 0 0000 Lab Duplicate DAL SS SS10 0 0000 Lab Matrix Spike DAL SS SS30 0 0000 DAL SS SS30 0 0000 Lab Duplicate DAL SS SS30 0 0000 Lab Matrix Spike DAL SS SS30 0 0005 DAL SS SS30 0 0005 Lab Duplicate DAL SS SS30 0 0005 Lab Matrix Spike DAL SS SS30 0 0015 DAL SS SS30 0 0015 Lab Duplicate DAL SS SS30 0 0015 Lab Matrix Spike DAL SS SS25 0 0000 DAL SS SS25 0 0000 Lab Duplicate DAL SS SS25 0 0000 Lab Matrix Spike DAL SS SS25 0 0005 DAL SS SS25 0 0005 Lab Duplicate DAL SS SS25 0 0005 Lab Matrix Spike DAL SS SS25 0 0015 DAL SS SS25 0 0015 Lab Duplicate DAL SS SS25 0 0015 Lab Matrix Spike DAL SD SD22 0 0000 DAL SD SD22 0 0000 Lab Duplicate DAL SD SD22 0 0000 Lab Matrix Spike DAL SD SD22 0 0005 DAL SD SD22 0 0005 Lab Duplicate DAL SD SD22 0 0005 Lab Matrix Spike DAL SD SD22 DB 0005 DAL SD SD22 DB 0005 Lab Duplicate DAL SD SD22 DB 0005 Lab Matrix Spike DAL SD SD22 0 0015 DAL SD SD22 0 0015 Lab Duplicate DAL SD SD22 0 0015 Lab Matrix Spike DAL SD SD21 0 0000 DAL SD SD21 0 0000 Lab Duplicate DAL SD SD21 0 0000 Lab Matrix Spike DAL SD SD21 0 0005 DAL SD SD21 0 0005 Lab Duplicate DAL SD SD21 0 0005 Lab Matrix Spike DAL SD SD21 0 0015 DAL SD SD21 0 0015 Lab Duplicate DAL SD SD21 0 0015 Lab Matrix Spike DAL SS SS24 0 0000 DAL SS SS24 0 0000 Lab Duplicate DAL SS SS24 0 0000 Lab Matrix Spike Surrogate (13C4-PFOS) Recovery [a] 107% 104% 104% 117% 108% 134% 106% 107% 125% 109% 113% 116% 106% 109% 110% 119% 119% 129% 118% 113% 142% 130% 115% 128% 121% 116% 137% 112% 102% 103% 115% 102% 106% 113% 109% 104% 110% 130% 151% 116% 118% 119% 105% 109% 109% 109% 117% 110% Actual LMS Spike Conc. (ng/g; dry weight) N/A 160 N/A 5180 N/A 536 N/A 263 N/A 305 N/A 2630 N/A 4200 N/A 4070 N/A 4110 N/A 727 N/A 757 N/A 536 N/A 4290 N/A 937 N/A 414 N/A 922 Measured PFOS Concentration (ng/g; dry weight) 108 50 267 2900 4560 11300 463 412 819 118 143 471 176 442 505 2750 3890 5290 2490 2550 6680 2050 1990 6140 4750 3370 8700 682 1090 1360 1380 870 1810 544 402 929 2100 1930 6470 1690 1610 2540 673 450 979 1240 1410 1990 RPD / LMS Recover y (%) 73% 117% 45% 146% 12% 71.3% 19% 130% 86% 64.2% 34% 75.0% 2.5% 99.0% 3.0% 101% 34% 113% 46% 64.4% 45% 91.2% 30% 84.9% 8.3% 104% 4.8% 95.1% 40% 101% 13% 72.7% Average PFOS Conc. (ng/g; dry wt.) 78.9 [a] N/A 3730 [b, c] N/A 437 N/A 130 N/A 309 [a, b] N/A 3320 N/A 2520 N/A 2020 N/A 4060 N/A 887 [b] N/A 1120 N/A 473 N/A 2020 N/A 1650 N/A 562 N/A 1320 N/A 3M Study GLP10-01-02-15 Page 28 of 514 Study: GLP10-01-02, Interim Report 15 Analysis for PFOS, PFHS and PFBS in Avenue A Soils/Sediments Collected January 2011 Table 14. Individual PFOS Results for Decatur, AL Avenue A Soils & Sediments, January 2011 LIMS Sample ID Sample Description GLP10-01-01-15-035 GLP10-01-01-15-035 Dup GLP10-01-01-15-035 LMS GLP10-01-01-15-036 GLP10-01-01-15-036 Dup GLP10-01-01-15-036 LMS GLP10-01-01-15-037 GLP10-01-01-15-037 Dup GLP10-01-01-15-037 LMS GLP10-01-01-15-038 GLP10-01-01-15-038 Dup GLP10-01-01-15-038 LMS GLP10-01-01-15-039 GLP10-01-01-15-039 Dup GLP10-01-01-15-039 LMS GLP10-01-01-15-040 GLP10-01-01-15-040 Dup GLP10-01-01-15-040 LMS GLP10-01-01-15-041 GLP10-01-01-15-041 Dup GLP10-01-01-15-041 LMS GLP10-01-01-15-042 GLP10-01-01-15-042 Dup GLP10-01-01-15-042 LMS GLP10-01-01-15-043 GLP10-01-01-15-043 Dup GLP10-01-01-15-043 LMS GLP10-01-01-15-044 GLP10-01-01-15-044 Dup GLP10-01-01-15-044 LMS GLP10-01-01-15-045 GLP10-01-01-15-045 Dup GLP10-01-01-15-045 LMS GLP10-01-01-15-046 GLP10-01-01-15-046 Dup GLP10-01-01-15-046 LMS GLP10-01-01-15-047 GLP10-01-01-15-047 Dup GLP10-01-01-15-047 LMS GLP10-01-01-15-048 GLP10-01-01-15-048 Dup GLP10-01-01-15-048 LMS GLP10-01-01-15-049 GLP10-01-01-15-049 Dup GLP10-01-01-15-049 LMS GLP10-01-01-15-050 GLP10-01-01-15-050 Dup GLP10-01-01-15-050 LMS DAL SS SS24 0 0005 DAL SS SS24 0 0005 Lab Duplicate DAL SS SS24 0 0005 Lab Matrix Spike DAL SS SS24 0 0015 DAL SS SS24 0 0015 Lab Duplicate DAL SS SS24 0 0015 Lab Matrix Spike DAL SS SS29 0 0000 DAL SS SS29 0 0000 Lab Duplicate DAL SS SS29 0 0000 Lab Matrix Spike DAL SS SS29 0 0005 DAL SS SS29 0 0005 Lab Duplicate DAL SS SS29 0 0005 Lab Matrix Spike DAL SS SS29 0 0015 DAL SS SS29 0 0015 Lab Duplicate DAL SS SS29 0 0015 Lab Matrix Spike DAL SS SS20 0 0005 DAL SS SS20 0 0005 Lab Duplicate DAL SS SS20 0 0005 Lab Matrix Spike DAL SS SS13 0 0005 DAL SS SS13 0 0005 Lab Duplicate DAL SS SS13 0 0005 Lab Matrix Spike DAL SS SS13 DB 0005 DAL SS SS13 DB 0005 Lab Duplicate DAL SS SS13 DB 0005 Lab Matrix Spike DAL SS SS15 0 0005 DAL SS SS15 0 0005 Lab Duplicate DAL SS SS15 0 0005 Lab Matrix Spike DAL SS SS17 0 0005 DAL SS SS17 0 0005 Lab Duplicate DAL SS SS17 0 0005 Lab Matrix Spike DAL SS SS14 0 0005 DAL SS SS14 0 0005 Lab Duplicate DAL SS SS14 0 0005 Lab Matrix Spike DAL SS SS18 0 0005 DAL SS SS18 0 0005 Lab Duplicate DAL SS SS18 0 0005 Lab Matrix Spike DAL SS SS16 0 0005 DAL SS SS16 0 0005 Lab Duplicate DAL SS SS16 0 0005 Lab Matrix Spike DAL SS SS16 0 0015 DAL SS SS16 0 0015 Lab Duplicate DAL SS SS16 0 0015 Lab Matrix Spike DAL SS SS10 0 0005 DAL SS SS10 0 0005 Lab Duplicate DAL SS SS10 0 0005 Lab Matrix Spike DAL SS SS10 DB 0005 DAL SS SS10 DB 0005 Lab Duplicate DAL SS SS10 DB 0005 Lab Matrix Spike Surrogate (13C4-PFOS) Recovery [a] 118% 120% 136% 125% 121% 110% 113% 111% 118% 111% 106% 106% 109% 113% 115% 115% 114% 100% 113% 104% 116% 104% 102% 111% 111% 108% 108% 113% 111% 101% 116% 103% 113% 109% 114% 110% 112% 111% 108% 104% 105% 116% 121% 113% 109% 113% 115% 118% Actual LMS Spike Conc. (ng/g; dry weight) N/A 2550 N/A 870 N/A 570 N/A 222 N/A 671 N/A 108 N/A 577 N/A 478 N/A 190 n/a 228 N/A 223 N/A 83.4 N/A 211 N/A 193 N/A 327 N/A 636 Measured PFOS Concentration (ng/g; dry weight) 1020 932 3210 1430 1770 2210 602 607 1160 273 268 484 1070 1080 1810 17.8 40.9 159 578 540 1090 562 542 1040 181 159 453 238 202 365 237 304 490 26.9 34.7 126 262 344 472 174 156 313 346 559 838 396 335 967 RPD / LMS Recover y (%) 8 .8 % 8 8 .0 % 21% 70.3% 0.84% 98.0% 1.9% 96.2% 0.56% 109% 79% 120% 6.9% 92.2% 3.6% 102% 13% 149% 16% 63.9% 25% 98.3% 25% 114% 27% 80.4% 11% 76.6% 47% 118% 17% 94.7% Average PFOS Conc. (ng/g; dry wt.) 974 N/A 1600 N/A 605 N/A 271 N/A 1070 N/A 29.4 [a] N/A 559 N/A 552 N/A 170 [b] N/A 2 2 0 [b] N/A 271 N/A 30.8 N/A 303 N/A 165 N/A 453 N/A 365 N/A 3M Study GLP10-01-02-15 Page 29 of 514 Study: GLP10-01-02, Interim Report 15 Analysis for PFOS, PFHS and PFBS in Avenue A Soils/Sediments Collected January 2011 Table 14. Individual PFOS Results for Decatur, AL Avenue A Soils & Sediments, January 2011 LIMS Sample ID Sample Description GLP10-01-01-15-051 GLP10-01-01-15-051 Dup GLP10-01-01-15-051 LMS GLP10-01-01-15-052 GLP10-01-01-15-052 Dup GLP10-01-01-15-052 LMS GLP10-01-01-15-053 GLP10-01-01-15-053 Dup GLP10-01-01-15-053 LMS GLP10-01-01-15-054 GLP10-01-01-15-054 Dup GLP10-01-01-15-054 LMS GLP10-01-01-15-055 GLP10-01-01-15-055 Dup GLP10-01-01-15-055 LMS GLP10-01-01-15-056 GLP10-01-01-15-056 Dup GLP10-01-01-15-056 LMS GLP10-01-01-15-057 GLP10-01-01-15-057 Dup GLP10-01-01-15-057 LMS GLP10-01-01-15-058 GLP10-01-01-15-058 Dup GLP10-01-01-15-058 LMS GLP10-01-01-15-059 GLP10-01-01-15-059 Dup GLP10-01-01-15-059 LMS GLP10-01-01-15-060 GLP10-01-01-15-060 Dup GLP10-01-01-15-060 LMS GLP10-01-01-15-061 GLP10-01-01-15-061 Dup GLP10-01-01-15-061 LMS GLP10-01-01-15-062 GLP10-01-01-15-062 Dup GLP10-01-01-15-062 LMS GLP10-01-01-15-063 GLP10-01-01-15-063 Dup GLP10-01-01-15-063 LMS GLP10-01-01-15-064 GLP10-01-01-15-064 Dup GLP10-01-01-15-064 LMS GLP10-01-01-15-065 GLP10-01-01-15-065 Dup GLP10-01-01-15-065 LMS GLP10-01-01-15-066 GLP10-01-01-15-066 Dup GLP10-01-01-15-066 LMS DAL SS SS10 0 0015 DAL SS SS10 0 0015 Lab Duplicate DAL SS SS10 0 0015 Lab Matrix Spike DAL SD SD20 0 0000 DAL SD SD20 0 0000 Lab Duplicate DAL SD SD20 0 0000 Lab Matrix Spike DAL SD SD20 0 0005 DAL SD SD20 0 0005 Lab Duplicate DAL SD SD20 0 0005 Lab Matrix Spike DAL SD SD20 0 0015 DAL SD SD20 0 0015 Lab Duplicate DAL SD SD20 0 0015 Lab Matrix Spike DAL SD SD23 0 0000 DAL SD SD23 0 0000 Lab Duplicate DAL SD SD23 0 0000 Lab Matrix Spike DAL SD SD23 0 0005 DAL SD SD23 0 0005 Lab Duplicate DAL SD SD23 0 0005 Lab Matrix Spike DAL SD SD23 0 0015 DAL SD SD23 0 0015 Lab Duplicate DAL SD SD23 0 0015 Lab Matrix Spike DAL SS SS28 0 0000 DAL SS SS28 0 0000 Lab Duplicate DAL SS SS28 0 0000 Lab Matrix Spike DAL SS SS28 0 0005 DAL SS SS28 0 0005 Lab Duplicate DAL SS SS28 0 0005 Lab Matrix Spike DAL SS SS28 DB 0005 DAL SS SS28 DB 0005 Lab Duplicate DAL SS SS28 DB 0005 Lab Matrix Spike DAL SS SS28 0 0015 DAL SS SS28 0 0015 Lab Duplicate DAL SS SS28 0 0015 Lab Matrix Spike DAL SS SS27 0 0000 DAL SS SS27 0 0000 Lab Duplicate DAL SS SS27 0 0000 Lab Matrix Spike DAL SS SS27 0 0005 DAL SS SS27 0 0005 Lab Duplicate DAL SS SS27 0 0005 Lab Matrix Spike DAL SS SS27 0 0015 DAL SS SS27 0 0015 Lab Duplicate DAL SS SS27 0 0015 Lab Matrix Spike DAL SS SS22 0 0000 DAL SS SS22 0 0000 Lab Duplicate DAL SS SS22 0 0000 Lab Matrix Spike DAL SS SS22 0 0005 DAL SS SS22 0 0005 Lab Duplicate DAL SS SS22 0 0005 Lab Matrix Spike Surrogate (13C4-PFOS) Recovery [a] 108% 104% 114% 114% 110% 141% 106% 113% 121% 103% 109% 120% 105% 105% 108% 108% 112% 114% 112% 108% 110% 113% 106% 117% 109% 101% 107% 105% 113% 116% 108% 107% 113% 111% 104% 114% 121% 108% 106% 99.0% 120% 115% 119% 113% 125% 102% 105% 114% Actual LMS Spike Conc. (ng/g; dry weight) N/A 587 N/A 4890 N/A 968 N/A 860 N/A 405 N/A 258 N/A 226 N/A 189 N/A 261 N/A 210 N/A 241 N/A 226 N/A 223 N/A 246 N/A 275 N/A 228 Measured PFOS Concentration (ng/g; dry weight) 458 484 1070 2130 3480 7380 1290 1320 1930 659 686 1400 525 510 912 265 274 503 180 172 437 166 160 329 215 179 495 197 195 425 181 166 470 168 122 385 240 241 406 157 167 458 273 273 563 161 153 433 RPD / LMS Recover y (%) 5.5% 101% 48% 93.6% 2.4% 65.1% 4.0% 84.5% 2.9% 97.3% 3.7% 90.6% 4.6% 116% 3.7% 8 8 .0 % 19% 114% 0.74% 109% 8.9% 123% 32% 106% 0.72% 74.5% 6 .0 % 120% 0.15% 106% 5.3% 121% Average PFOS Conc. (ng/g; dry wt.) 471 N/A 2800 N/A 1300 [b] N/A 672 N/A 518 N/A 270 N/A 176 N/A 163 N/A 197 N/A 196 N/A 174 N/A 145 N/A 241 N/A 162 N/A 273 N/A 157 N/A 3M Study GLP10-01-02-15 Page 30 of 514 Study: GLP10-01-02, Interim Report 15 Analysis for PFOS, PFHS and PFBS in Avenue A Soils/Sediments Collected January 2011 Table 14. Individual PFOS Results for Decatur, AL Avenue A Soils & Sediments, January 2011 LIMS Sample ID Sample Description GLP10-01-01-15-067 GLP10-01-01-15-067 Dup GLP10-01-01-15-067 LMS GLP10-01-01-15-068 GLP10-01-01-15-068 Dup GLP10-01-01-15-068 LMS GLP10-01-01-15-069 GLP10-01-01-15-069 Dup GLP10-01-01-15-069 LMS GLP10-01-01-15-070 GLP10-01-01-15-070 Dup GLP10-01-01-15-070 LMS GLP10-01-01-15-071 GLP10-01-01-15-071 Dup GLP10-01-01-15-071 LMS GLP10-01-01-15-072 GLP10-01-01-15-072 Dup GLP10-01-01-15-072 LMS GLP10-01-01-15-073 GLP10-01-01-15-073 Dup GLP10-01-01-15-073 LMS GLP10-01-01-15-074 GLP10-01-01-15-074 Dup GLP10-01-01-15-074 LMS GLP10-01-01-15-075 GLP10-01-01-15-075 Dup GLP10-01-01-15-075 LMS GLP10-01-01-15-076 GLP10-01-01-15-076 Dup GLP10-01-01-15-076 LMS GLP10-01-01-15-077 GLP10-01-01-15-077 Dup GLP10-01-01-15-077 LMS GLP10-01-01-15-079 GLP10-01-01-15-079 Dup GLP10-01-01-15-079 LMS GLP10-01-01-15-080 GLP10-01-01-15-080 Dup GLP10-01-01-15-080 LMS GLP10-01-01-15-081 GLP10-01-01-15-081 Dup GLP10-01-01-15-081 LMS GLP10-01-01-15-082 GLP10-01-01-15-082 Dup GLP10-01-01-15-082 LMS GLP10-01-01-15-083 GLP10-01-01-15-083 Dup GLP10-01-01-15-083 LMS DAL SS SS22 DB 0005 DAL SS SS22 DB 0005 Lab Duplicate DAL SS SS22 DB 0005 Lab Matrix Spike DAL SS SS22 0 0015 DAL SS SS22 0 0015 Lab Duplicate DAL SS SS22 0 0015 Lab Matrix Spike DAL SS SS21 0 0000 DAL SS SS21 0 0000 Lab Duplicate DAL SS SS21 0 0000 Lab Matrix Spike DAL SS SS21 0 0005 DAL SS SS21 0 0005 Lab Duplicate DAL SS SS21 0 0005 Lab Matrix Spike DAL SS SS21 0 0015 DAL SS SS21 0 0015 Lab Duplicate DAL SS SS21 0 0015 Lab Matrix Spike DAL SD SD18 0 0000 DAL SD SD18 0 0000 Lab Duplicate DAL SD SD18 0 0000 Lab Matrix Spike DAL SD SD18 0 0005 DAL SD SD18 0 0005 Lab Duplicate DAL SD SD18 0 0005 Lab Matrix Spike DAL SD SD18 0 0015 DAL SD SD18 0 0015 Lab Duplicate DAL SD SD18 0 0015 Lab Matrix Spike DAL SD SD19 0 0000 DAL SD SD19 0 0000 Lab Duplicate DAL SD SD19 0 0000 Lab Matrix Spike DAL SD SD19 0 0005 DAL SD SD19 0 0005 Lab Duplicate DAL SD SD19 0 0005 Lab Matrix Spike DAL SD SD19 0 0015 DAL SD SD19 0 0015 Lab Duplicate DAL SD SD19 0 0015 Lab Matrix Spike DAL SS SS26 0 0000 DAL SS SS26 0 0000 Lab Duplicate DAL SS SS26 0 0000 Lab Matrix Spike DAL SS SS26 DB 0000 DAL SS SS26 DB 0000 Lab Duplicate DAL SS SS26 DB 0000 Lab Matrix Spike DAL SS SS26 0 0005 DAL SS SS26 0 0005 Lab Duplicate DAL SS SS26 0 0005 Lab Matrix Spike DAL SS SS26 0 0015 DAL SS SS26 0 0015 Lab Duplicate DAL SS SS26 0 0015 Lab Matrix Spike DAL SS Trip2 0 0000 DAL SS Trip2 0 0000 Lab Duplicate DAL SS Trip2 0 0000 Lab Matrix Spike Surrogate (13C4-PFOS) Recovery [a] 107% 111% 113% 109% 106% 116% 110% 110% 110% 115% 104% 115% 103% 107% 117% 110% 110% 110% 115% 113% 117% 108% 120% 115% 122% 113% 102% 111% 115% 116% 117% 109% 116% 105% 107% 120% 111% 107% 113% 108% 109% 117% 122% 127% 107% 110% 106% 108% Actual LMS Spike Conc. (ng/g; dry weight) N/A 196 N/A 75.1 N/A 647 N/A 291 N/A 103 N/A 858 N/A 362 N/A NR N/A 662 N/A 935 N/A 539 N/A 918 N/A NR N/A 827 N/A 465 N/A 0.843 Measured PFOS Concentration (ng/g; dry weight) 130 172 364 18.8 35.8 116 1310 948 1620 323 327 663 132 110 256 1060 947 1680 567 522 773 NR NR NR 910 837 1450 1280 873 2330 285 405 951 1020 919 1580 NR NR NR 1030 1250 2100 1230 843 1370 BLQ BLQ 0.919 RPD / LMS Recover y (%) 28% 108% 62% 119% 32% 75.9% 1.3% 116% 18% 131% 11% 79.4% 8.3% 63.2% NR NR 8.4% 87.7% 38% 134% 35% 112% 10% 66.9% NR NR 19% 116% 38% 71.2% N/A 109% Average PFOS Conc. (ng/g; dry wt.) 151 N/A 27.3 [a] N/A 1130 N/A 325 N/A 1 2 1 [b] N/A 1000 N/A 545 [b] N/A NR N/A 873 N/A 1080 [b] N/A 345 N/A 970 [b] N/A NR NR 1140 N/A 1040 N/A BLQ N/A 3M Study GLP10-01-02-15 Page 31 of 514 Study: GLP10-01-02, Interim Report 15 Analysis for PFOS, PFHS and PFBS in Avenue A Soils/Sediments Collected January 2011 Table 14. Individual PFOS Results for Decatur, AL Avenue A Soils & Sediments, January 2011 LIMS Sample ID Sample Description Surrogate (13C4-PFOS) Recovery [a] Actual LMS Spike Conc. (ng/g; dry weight) Measured PFOS Concentration (ng/g; dry weight) RPD / LMS Recover y (%) Average PFOS Conc. (ng/g; dry wt.) GLP10-01-01-15-084 GLP10-01-01-15-084 Dup GLP10-01-01-15-084 LMS GLP10-01-01-15-085 GLP10-01-01-15-085 Dup GLP10-01-01-15-085 LMS DAL SS SS12 0 0015 DAL SS SS12 0 0015 Lab Duplicate DAL SS SS12 0 0015 Lab Matrix Spike DAL SS SS19 0 0015 DAL SS SS19 0 0015 Lab Duplicate DAL SS SS19 0 0015 Lab Matrix Spike 127% 110% 147% 115% 114% 108% N/A 4270 N/A 486 2630 2420 6560 282 306 761 8.6% 94.7% 8.2% 96.1% 2520 N/A 294 N/A GLP10-01-01-15-086 GLP10-01-01-15-086 Dup GLP10-01-01-15-086 LMS DAL SS SS20 0 0015 DAL SS SS20 0 0015 Lab Duplicate DAL SS SS20 0 0015 Lab Matrix Spike 104% 103% 119% N/A 263 244 36% 206 169 472 101% N/A GLP10-01-01-15-087 GLP10-01-01-15-087 Dup DAL SS SS14 0 0015 DAL SS SS14 0 0015 Lab Duplicate 113% 115% N/A 240 15% 223 206 GLP10-01-01-15-087 LMS GLP10-01-01-15-088 GLP10-01-01-15-088 Dup GLP10-01-01-15-088 LMS GLP10-01-01-15-089 GLP10-01-01-15-089 Dup GLP10-01-01-15-089 LMS GLP10-01-01-15-090 GLP10-01-01-15-090 Dup GLP10-01-01-15-090 LMS DAL SS SS14 0 0015 Lab Matrix Spike DAL SS SS17 0 0015 DAL SS SS17 0 0015 Lab Duplicate DAL SS SS17 0 0015 Lab Matrix Spike DAL SS SS13 0 0015 DAL SS SS13 0 0015 Lab Duplicate DAL SS SS13 0 0015 Lab Matrix Spike DAL SS SS15 0 0015 DAL SS SS15 0 0015 Lab Duplicate DAL SS SS15 0 0015 Lab Matrix Spike 106% 110% 113% 112% 113% 106% 107% 107% 97.9% 110% 298 N/A 288 N/A 336 N/A 109 544 108% N/A 217 3.3% 221 224 520 104% N/A 350 3.8% 357 364 657 89.0% N/A 118 17% 109 [b, c] 99.5 159 57.3% N/A GLP10-01-01-15-091 GLP10-01-01-15-091 Dup GLP10-01-01-15-091 LMS GLP10-01-01-15-092 GLP10-01-01-15-092 Dup DAL SS SS18 0 0015 DAL SS SS18 0 0015 Lab Duplicate DAL SS SS18 0 0015 Lab Matrix Spike DAL SS SS11 0 0015 DAL SS SS11 0 0015 Lab Duplicate 105% 113% 108% 112% 101% N/A 244 N/A 158 2.4% 156 154 439 116% N/A NR NR NR NR GLP10-01-01-15-092 LMS DAL SS SS11 0 0015 Lab Matrix Spike 112% NR NR NR NR BLQ; Analyte/IS peak area response ratio was less than that of the lowest acceptable standard in the curve and was nominal 0.200 ng/g Values are shown at 3 significant figures, but more precise data was used for data calculations. All results were reported from the least diluted sample that fell within the range of the calibration curve. NR; not reportable due to QC failure [a] RPD for duplicate results was greater than 50% [b] LMS recovery was outside of 100 + 30%, but within reporting limits of 100 + 50% [c] Result determined from a reassay result when original results were NR, surrogate recovery result is shown from original result.______ Table 15. Individual PFHS Results for Decatur, AL Avenue A Soils & Sediments, January 2011 LIMS Sample ID Sample Description GLP10-01-01-15-001 GLP10-01-01-15-001 Dup GLP10-01-01-15-001 LMS GLP10-01-01-15-002 GLP10-01-01-15-002 Dup GLP10-01-01-15-002 LMS DAL SS Tripl 0 0000 DAL SS Tripl 0 0000 Lab Duplicate DAL SS Tripl 0 0000 Lab Matrix Spike DAL SS SS12 0 0000 DAL SS SS12 0 0000 Lab Duplicate DAL SS SS12 0 0000 Lab Matrix Spike Surrogate (13C4-PFOS) Recovery [a] 98.3% 104% 106% 118% 110% 149% Actual LMS Spike Conc. (ng/g; dry weight) N/A 0.886 N/A 53.2 Measured PFHS Concentration (ng/g; dry weight) BLQ BLQ 0.869 15.4 12.0 67.1 RPD / LMS Recover y (%) N/A 98.1% 25% 100% Average PFHS Conc. (ng/g; dry wt.) BLQ N/A 13.7 N/A 3M Study GLP10-01-02-15 Page 32 of 514 Study: GLP10-01-02, Interim Report 15 Analysis for PFOS, PFHS and PFBS in Avenue A Soils/Sediments Collected January 2011 Table 15. Individual PFHS Results for Decatur, AL Avenue A Soils & Sediments, January 2011 LIMS Sample ID Sample Description GLP10-01-01-15-003 GLP10-01-01-15-003 Dup GLP10-01-01-15-003 LMS GLP10-01-01-15-004 GLP10-01-01-15-004 Dup GLP10-01-01-15-004 LMS GLP10-01-01-15-005 GLP10-01-01-15-005 Dup GLP10-01-01-15-005 LMS GLP10-01-01-15-006 GLP10-01-01-15-006 Dup GLP10-01-01-15-006 LMS GLP10-01-01-15-007 GLP10-01-01-15-007 Dup GLP10-01-01-15-007 LMS GLP10-01-01-15-008 GLP10-01-01-15-008 Dup GLP10-01-01-15-008 LMS GLP10-01-01-15-009 GLP10-01-01-15-009 Dup GLP10-01-01-15-009 LMS GLP10-01-01-15-010 GLP10-01-01-15-010 Dup GLP10-01-01-15-010 LMS GLP10-01-01-15-011 GLP10-01-01-15-011 Dup GLP10-01-01-15-011 LMS GLP10-01-01-15-012 GLP10-01-01-15-012 Dup GLP10-01-01-15-012 LMS GLP10-01-01-15-014 GLP10-01-01-15-014 Dup GLP10-01-01-15-014 LMS GLP10-01-01-15-015 GLP10-01-01-15-015 Dup GLP10-01-01-15-015 LMS GLP10-01-01-15-016 GLP10-01-01-15-016 Dup GLP10-01-01-15-016 LMS GLP10-01-01-15-018 GLP10-01-01-15-018 Dup GLP10-01-01-15-018 LMS GLP10-01-01-15-020 GLP10-01-01-15-020 Dup GLP10-01-01-15-020 LMS GLP10-01-01-15-021 GLP10-01-01-15-021 Dup GLP10-01-01-15-021 LMS DAL SS SS12 0 0005 DAL SS SS12 0 0005 Lab Duplicate DAL SS SS12 0 0005 Lab Matrix Spike DAL SS SS13 0 0000 DAL SS SS13 0 0000 Lab Duplicate DAL SS SS13 0 0000 Lab Matrix Spike DAL SS SS16 0 0000 DAL SS SS16 0 0000 Lab Duplicate DAL SS SS16 0 0000 Lab Matrix Spike DAL SS SS16 DB 0000 DAL SS SS16 DB 0000 Lab Duplicate DAL SS SS16 DB 0000 Lab Matrix Spike DAL SS SS11 0 0000 DAL SS SS11 0 0000 Lab Duplicate DAL SS SS11 0 0000 Lab Matrix Spike DAL SS SS11 0 0005 DAL SS SS11 0 0005 Lab Duplicate DAL SS SS11 0 0005 Lab Matrix Spike DAL SS SS20 0 0000 DAL SS SS20 0 0000 Lab Duplicate DAL SS SS20 0 0000 Lab Matrix Spike DAL SS SS20 DB 0000 DAL SS SS20 DB 0000 Lab Duplicate DAL SS SS20 DB 0000 Lab Matrix Spike DAL SS SS19 0 0000 DAL SS SS19 0 0000 Lab Duplicate DAL SS SS19 0 0000 Lab Matrix Spike DAL SS SS19 0 0005 DAL SS SS19 0 0005 Lab Duplicate DAL SS SS19 0 0005 Lab Matrix Spike DAL SS SS15 0 0000 DAL SS SS15 0 0000 Lab Duplicate DAL SS SS15 0 0000 Lab Matrix Spike DAL SS SS17 0 0000 DAL SS SS17 0 0000 Lab Duplicate DAL SS SS17 0 0000 Lab Matrix Spike DAL SS SS14 0 0000 DAL SS SS14 0 0000 Lab Duplicate DAL SS SS14 0 0000 Lab Matrix Spike DAL SS SS18 0 0000 DAL SS SS18 0 0000 Lab Duplicate DAL SS SS18 0 0000 Lab Matrix Spike DAL SS SS10 0 0000 DAL SS SS10 0 0000 Lab Duplicate DAL SS SS10 0 0000 Lab Matrix Spike DAL SS SS30 0 0000 DAL SS SS30 0 0000 Lab Duplicate DAL SS SS30 0 0000 Lab Matrix Spike Surrogate (13C4-PFOS) Recovery [a] 129% 125% 149% 105% 114% 106% 94.6% 102% 107% 104% 105% 105% 104% 96.6% 98.3% 130% 106% 93.6% 105% 111% 108% 103% 96.0% 108% 104% 104% 100% 100% 104% 110% 103% 102% 95.0% 103% 99.0% 98.0% 95.3% 118% 117% 103% 100% 100% 112% 104% 130% 102% 103% 120% Actual LMS Spike Conc. (ng/g; dry weight) N/A 303 N/A 4.27 N/A 21.5 N/A 19.8 N/A 4.55 N/A 18.3 N/A 3.43 N/A 3.58 N/A 2.82 N/A 24.2 N/A 3.59 N/A 3.97 N/A 2 2 .0 N/A 16.0 N/A 80.8 N/A 5.36 Measured PFHS Concentration (ng/g; dry weight) 197 176 617 1.73 2.13 6 .1 2 6.50 6.98 30.2 6.59 6.37 29.3 0.825 1.01 5.73 3.72 4.87 27.2 2.63 2.72 6 .0 2 2.15 2.40 7.66 2.38 2.07 4.55 13.6 15.7 40.4 1.80 5.18 8 .1 2 2.07 2.19 6.40 3.87 4.50 26.8 2 .8 6 1.79 20.5 18.4 39.9 140 4.04 3.61 8.65 RPD / LMS Recover y (%) 11% 142% 21% 98.0% 7.1% 109% 3.5% 115% 20% 106% 27% 125% 3.3% 97.4% 11% 150% 14% 82.5% 14% 106% 97.0% 129% 5.6% 108% 15% 103% 46% 113% 74% 137% 11% 90.0% Average PFHS Conc. (ng/g; dry wt.) 186 [b] N/A 1.93 N/A 6.74 N/A 6.48 N/A 0.918 N/A 4.30 [c] N/A 2 .6 8 N/A 2.27 N/A 2 .2 2 N/A 14.6 N/A 3.49 [a] N/A 2.13 N/A 4.18 N/A 2.33 N/A 29.1 [a, b] N/A 3.83 N/A 3M Study GLP10-01-02-15 Page 33 of 514 Study: GLP10-01-02, Interim Report 15 Analysis for PFOS, PFHS and PFBS in Avenue A Soils/Sediments Collected January 2011 Table 15. Individual PFHS Results for Decatur, AL Avenue A Soils & Sediments, January 2011 LIMS Sample ID Sample Description GLP10-01-01-15-022 GLP10-01-01-15-022 Dup GLP10-01-01-15-022 LMS GLP10-01-01-15-023 GLP10-01-01-15-023 Dup GLP10-01-01-15-023 LMS GLP10-01-01-15-024 GLP10-01-01-15-024 Dup GLP10-01-01-15-024 LMS GLP10-01-01-15-025 GLP10-01-01-15-025 Dup GLP10-01-01-15-025 LMS GLP10-01-01-15-026 GLP10-01-01-15-026 Dup GLP10-01-01-15-026 LMS GLP10-01-01-15-027 GLP10-01-01-15-027 Dup GLP10-01-01-15-027 LMS GLP10-01-01-15-028 GLP10-01-01-15-028 Dup GLP10-01-01-15-028 LMS GLP10-01-01-15-029 GLP10-01-01-15-029 Dup GLP10-01-01-15-029 LMS GLP10-01-01-15-030 GLP10-01-01-15-030 Dup GLP10-01-01-15-030 LMS GLP10-01-01-15-031 GLP10-01-01-15-031 Dup GLP10-01-01-15-031 LMS GLP10-01-01-15-032 GLP10-01-01-15-032 Dup GLP10-01-01-15-032 LMS GLP10-01-01-15-033 GLP10-01-01-15-033 Dup GLP10-01-01-15-033 LMS GLP10-01-01-15-034 GLP10-01-01-15-034 Dup GLP10-01-01-15-034 LMS GLP10-01-01-15-035 GLP10-01-01-15-035 Dup GLP10-01-01-15-035 LMS GLP10-01-01-15-036 GLP10-01-01-15-036 Dup GLP10-01-01-15-036 LMS GLP10-01-01-15-037 GLP10-01-01-15-037 Dup GLP10-01-01-15-037 LMS DAL SS SS30 0 0005 DAL SS SS30 0 0005 Lab Duplicate DAL SS SS30 0 0005 Lab Matrix Spike DAL SS SS30 0 0015 DAL SS SS30 0 0015 Lab Duplicate DAL SS SS30 0 0015 Lab Matrix Spike DAL SS SS25 0 0000 DAL SS SS25 0 0000 Lab Duplicate DAL SS SS25 0 0000 Lab Matrix Spike DAL SS SS25 0 0005 DAL SS SS25 0 0005 Lab Duplicate DAL SS SS25 0 0005 Lab Matrix Spike DAL SS SS25 0 0015 DAL SS SS25 0 0015 Lab Duplicate DAL SS SS25 0 0015 Lab Matrix Spike DAL SD SD22 0 0000 DAL SD SD22 0 0000 Lab Duplicate DAL SD SD22 0 0000 Lab Matrix Spike DAL SD SD22 0 0005 DAL SD SD22 0 0005 Lab Duplicate DAL SD SD22 0 0005 Lab Matrix Spike DAL SD SD22 DB 0005 DAL SD SD22 DB 0005 Lab Duplicate DAL SD SD22 DB 0005 Lab Matrix Spike DAL SD SD22 0 0015 DAL SD SD22 0 0015 Lab Duplicate DAL SD SD22 0 0015 Lab Matrix Spike DAL SD SD21 0 0000 DAL SD SD21 0 0000 Lab Duplicate DAL SD SD21 0 0000 Lab Matrix Spike DAL SD SD21 0 0005 DAL SD SD21 0 0005 Lab Duplicate DAL SD SD21 0 0005 Lab Matrix Spike DAL SD SD21 0 0015 DAL SD SD21 0 0015 Lab Duplicate DAL SD SD21 0 0015 Lab Matrix Spike DAL SS SS24 0 0000 DAL SS SS24 0 0000 Lab Duplicate DAL SS SS24 0 0000 Lab Matrix Spike DAL SS SS24 0 0005 DAL SS SS24 0 0005 Lab Duplicate DAL SS SS24 0 0005 Lab Matrix Spike DAL SS SS24 0 0015 DAL SS SS24 0 0015 Lab Duplicate DAL SS SS24 0 0015 Lab Matrix Spike DAL SS SS29 0 0000 DAL SS SS29 0 0000 Lab Duplicate DAL SS SS29 0 0000 Lab Matrix Spike Surrogate (13C4-PFOS) Recovery [a] 105% 109% 112% 102% 105% 106% 115% 115% 124% 114% 108% 137% 125% 111% 123% 117% 112% 132% 108% 98.0% 99.3% 110% 98.3% 102% 109% 105% 100% 106% 125% 145% 112% 114% 114% 101% 105% 105% 105% 112% 106% 114% 116% 131% 121% 116% 106% 109% 107% 114% Actual LMS Spike Conc. (ng/g; dry weight) N/A 1.05 N/A 30.5 N/A 844 N/A 840 N/A 407 N/A 206 N/A 72.8 N/A 220 N/A 107 N/A 215 N/A 234 N/A 82.7 N/A 92.3 N/A 127 N/A 87.1 N/A 28.5 Measured PFHS Concentration (ng/g; dry weight) 0.820 0.918 2.13 6.31 9.82 39.3 411 804 1160 524 508 1320 286 305 690 230 156 406 65.3 71.3 149 71.5 66.7 320 60.6 65.0 172 111 104 337 151 146 447 61.5 54.0 151 50.3 72.3 151 67.7 54.2 187 28.6 39.8 127 9.09 1 0 .2 43.6 RPD / LMS Recover y (%) 11% 120% 43% 102% 66% 6 6 .0 % 3.1% 96.1% 6.7% 96.8% 38% 104% 8 .8 % 111% 6.9% 114% 7.0% 101% 6 .6 % 107% 3.0% 128% 13% 112% 36% 97.6% 22% 99.3% 33% 107% 11% 119% Average PFHS Conc. (ng/g; dry wt.) 0.869 N/A 8.06 N/A 607 [a, b, c] N/A 516 N/A 295 N/A 193 N/A 68.3 N/A 69.1 [c] N/A 62.8 N/A 107 N/A 148 N/A 57.7 N/A 61.3 N/A 61.0 N/A 34.2 N/A 9.64 N/A 3M Study GLP10-01-02-15 Page 34 of 514 Study: GLP10-01-02, Interim Report 15 Analysis for PFOS, PFHS and PFBS in Avenue A Soils/Sediments Collected January 2011 Table 15. Individual PFHS Results for Decatur, AL Avenue A Soils & Sediments, January 2011 LIMS Sample ID Sample Description GLP10-01-01-15-038 GLP10-01-01-15-038 Dup GLP10-01-01-15-038 LMS GLP10-01-01-15-039 GLP10-01-01-15-039 Dup GLP10-01-01-15-039 LMS GLP10-01-01-15-040 GLP10-01-01-15-040 Dup GLP10-01-01-15-040 LMS GLP10-01-01-15-041 GLP10-01-01-15-041 Dup GLP10-01-01-15-041 LMS GLP10-01-01-15-042 GLP10-01-01-15-042 Dup GLP10-01-01-15-042 LMS GLP10-01-01-15-043 GLP10-01-01-15-043 Dup GLP10-01-01-15-043 LMS GLP10-01-01-15-044 GLP10-01-01-15-044 Dup GLP10-01-01-15-044 LMS GLP10-01-01-15-045 GLP10-01-01-15-045 Dup GLP10-01-01-15-045 LMS GLP10-01-01-15-046 GLP10-01-01-15-046 Dup GLP10-01-01-15-046 LMS GLP10-01-01-15-047 GLP10-01-01-15-047 Dup GLP10-01-01-15-047 LMS GLP10-01-01-15-048 GLP10-01-01-15-048 Dup GLP10-01-01-15-048 LMS GLP10-01-01-15-049 GLP10-01-01-15-049 Dup GLP10-01-01-15-049 LMS GLP10-01-01-15-050 GLP10-01-01-15-050 Dup GLP10-01-01-15-050 LMS GLP10-01-01-15-051 GLP10-01-01-15-051 Dup GLP10-01-01-15-051 LMS GLP10-01-01-15-052 GLP10-01-01-15-052 Dup GLP10-01-01-15-052 LMS GLP10-01-01-15-053 GLP10-01-01-15-053 Dup GLP10-01-01-15-053 LMS DAL SS SS29 0 0005 DAL SS SS29 0 0005 Lab Duplicate DAL SS SS29 0 0005 Lab Matrix Spike DAL SS SS29 0 0015 DAL SS SS29 0 0015 Lab Duplicate DAL SS SS29 0 0015 Lab Matrix Spike DAL SS SS20 0 0005 DAL SS SS20 0 0005 Lab Duplicate DAL SS SS20 0 0005 Lab Matrix Spike DAL SS SS13 0 0005 DAL SS SS13 0 0005 Lab Duplicate DAL SS SS13 0 0005 Lab Matrix Spike DAL SS SS13 DB 0005 DAL SS SS13 DB 0005 Lab Duplicate DAL SS SS13 DB 0005 Lab Matrix Spike DAL SS SS15 0 0005 DAL SS SS15 0 0005 Lab Duplicate DAL SS SS15 0 0005 Lab Matrix Spike DAL SS SS17 0 0005 DAL SS SS17 0 0005 Lab Duplicate DAL SS SS17 0 0005 Lab Matrix Spike DAL SS SS14 0 0005 DAL SS SS14 0 0005 Lab Duplicate DAL SS SS14 0 0005 Lab Matrix Spike DAL SS SS18 0 0005 DAL SS SS18 0 0005 Lab Duplicate DAL SS SS18 0 0005 Lab Matrix Spike DAL SS SS16 0 0005 DAL SS SS16 0 0005 Lab Duplicate DAL SS SS16 0 0005 Lab Matrix Spike DAL SS SS16 0 0015 DAL SS SS16 0 0015 Lab Duplicate DAL SS SS16 0 0015 Lab Matrix Spike DAL SS SS10 0 0005 DAL SS SS10 0 0005 Lab Duplicate DAL SS SS10 0 0005 Lab Matrix Spike DAL SS SS10 DB 0005 DAL SS SS10 DB 0005 Lab Duplicate DAL SS SS10 DB 0005 Lab Matrix Spike DAL SS SS10 0 0015 DAL SS SS10 0 0015 Lab Duplicate DAL SS SS10 0 0015 Lab Matrix Spike DAL SD SD20 0 0000 DAL SD SD20 0 0000 Lab Duplicate DAL SD SD20 0 0000 Lab Matrix Spike DAL SD SD20 0 0005 DAL SD SD20 0 0005 Lab Duplicate DAL SD SD20 0 0005 Lab Matrix Spike Surrogate (13C4-PFOS) Recovery [a] 107% 102% 102% 105% 109% 111% 110% 110% 96.6% 109% 100% 112% 100% 98.0% 107% 107% 104% 104% 109% 107% 97.3% 111% 99.3% 109% 105% 110% 106% 108% 107% 104% 100% 101% 112% 116% 108% 105% 109% 111% 113% 104% 100% 110% 109% 106% 136% 102% 109% 116% Actual LMS Spike Conc. (ng/g; dry weight) N/A 4.44 N/A 67.2 N/A 0.940 N/A 5.77 N/A 4.78 N/A 3.81 N/A 4.55 N/A 4.45 N/A 0.835 N/A 4.22 N/A 19.3 N/A 16.4 N/A 15.9 N/A 58.7 N/A 244 N/A 242 Measured PFHS Concentration (ng/g; dry weight) 3.93 3.35 8.30 46.1 40.4 115 1.67 1.72 2.73 2.29 2.05 8.61 2.34 2 .1 2 6.84 1.43 1.08 6.27 3.17 2.96 6.37 2.62 3.61 8 .2 0 0.567 0.626 1.56 1.97 3.25 6.78 5.40 5.56 26.8 6.63 8.99 23.8 6.53 7.01 25.4 18.9 2 0 .6 75.8 141 178 400 138 139 368 RPD / LMS Recover y (%) 16% 105% 13% 107% 3.4% 110% 11% 112% 10% 96.5% 28% 132% 6 .6 % 72.7% 32% 114% 10% 116% 49% 98.8% 2.9% 110% 30% 97.9% 7.1% 117% 8 .8 % 95.3% 23% 98.3% 1 .1 % 94.8% Average PFHS Conc. (ng/g; dry wt.) 3.64 N/A 43.3 N/A 1.70 [c] N/A 2.17 N/A 2.23 N/A 1.26 N/A 3.06 N/A 3.12 N/A 0.597 N/A 2.61 N/A 5.48 N/A 7.81 N/A 6.77 N/A 19.8 N/A 160 N/A 139 N/A 3M Study GLP10-01-02-15 Page 35 of 514 Study: GLP10-01-02, Interim Report 15 Analysis for PFOS, PFHS and PFBS in Avenue A Soils/Sediments Collected January 2011 Table 15. Individual PFHS Results for Decatur, AL Avenue A Soils & Sediments, January 2011 LIMS Sample ID Sample Description GLP10-01-01-15-054 GLP10-01-01-15-054 Dup GLP10-01-01-15-054 LMS GLP10-01-01-15-055 GLP10-01-01-15-055 Dup GLP10-01-01-15-055 LMS GLP10-01-01-15-056 GLP10-01-01-15-056 Dup GLP10-01-01-15-056 LMS GLP10-01-01-15-057 GLP10-01-01-15-057 Dup GLP10-01-01-15-057 LMS GLP10-01-01-15-058 GLP10-01-01-15-058 Dup GLP10-01-01-15-058 LMS GLP10-01-01-15-059 GLP10-01-01-15-059 Dup GLP10-01-01-15-059 LMS GLP10-01-01-15-060 GLP10-01-01-15-060 Dup GLP10-01-01-15-060 LMS GLP10-01-01-15-061 GLP10-01-01-15-061 Dup GLP10-01-01-15-061 LMS GLP10-01-01-15-062 GLP10-01-01-15-062 Dup GLP10-01-01-15-062 LMS GLP10-01-01-15-063 GLP10-01-01-15-063 Dup GLP10-01-01-15-063 LMS GLP10-01-01-15-064 GLP10-01-01-15-064 Dup GLP10-01-01-15-064 LMS GLP10-01-01-15-065 GLP10-01-01-15-065 Dup GLP10-01-01-15-065 LMS GLP10-01-01-15-066 GLP10-01-01-15-066 Dup GLP10-01-01-15-066 LMS GLP10-01-01-15-067 GLP10-01-01-15-067 Dup GLP10-01-01-15-067 LMS GLP10-01-01-15-068 GLP10-01-01-15-068 Dup GLP10-01-01-15-068 LMS GLP10-01-01-15-069 GLP10-01-01-15-069 Dup GLP10-01-01-15-069 LMS DAL SD SD20 0 0015 DAL SD SD20 0 0015 Lab Duplicate DAL SD SD20 0 0015 Lab Matrix Spike DAL SD SD23 0 0000 DAL SD SD23 0 0000 Lab Duplicate DAL SD SD23 0 0000 Lab Matrix Spike DAL SD SD23 0 0005 DAL SD SD23 0 0005 Lab Duplicate DAL SD SD23 0 0005 Lab Matrix Spike DAL SD SD23 0 0015 DAL SD SD23 0 0015 Lab Duplicate DAL SD SD23 0 0015 Lab Matrix Spike DAL SS SS28 0 0000 DAL SS SS28 0 0000 Lab Duplicate DAL SS SS28 0 0000 Lab Matrix Spike DAL SS SS28 0 0005 DAL SS SS28 0 0005 Lab Duplicate DAL SS SS28 0 0005 Lab Matrix Spike DAL SS SS28 DB 0005 DAL SS SS28 DB 0005 Lab Duplicate DAL SS SS28 DB 0005 Lab Matrix Spike DAL SS SS28 0 0015 DAL SS SS28 0 0015 Lab Duplicate DAL SS SS28 0 0015 Lab Matrix Spike DAL SS SS27 0 0000 DAL SS SS27 0 0000 Lab Duplicate DAL SS SS27 0 0000 Lab Matrix Spike DAL SS SS27 0 0005 DAL SS SS27 0 0005 Lab Duplicate DAL SS SS27 0 0005 Lab Matrix Spike DAL SS SS27 0 0015 DAL SS SS27 0 0015 Lab Duplicate DAL SS SS27 0 0015 Lab Matrix Spike DAL SS SS22 0 0000 DAL SS SS22 0 0000 Lab Duplicate DAL SS SS22 0 0000 Lab Matrix Spike DAL SS SS22 0 0005 DAL SS SS22 0 0005 Lab Duplicate DAL SS SS22 0 0005 Lab Matrix Spike DAL SS SS22 DB 0005 DAL SS SS22 DB 0005 Lab Duplicate DAL SS SS22 DB 0005 Lab Matrix Spike DAL SS SS22 0 0015 DAL SS SS22 0 0015 Lab Duplicate DAL SS SS22 0 0015 Lab Matrix Spike DAL SS SS21 0 0000 DAL SS SS21 0 0000 Lab Duplicate DAL SS SS21 0 0000 Lab Matrix Spike Surrogate (13C4-PFOS) Recovery [a] 100% 105% 116% 101% 101% 104% 104% 108% 109% 108% 104% 106% 108% 102% 113% 105% 97.0% 103% 101% 108% 111% 104% 103% 109% 107% 100% 109% 116% 104% 102% 95.3% 115% 111% 115% 108% 120% 98.3% 101% 110% 103% 107% 109% 105% 102% 111% 106% 106% 106% Actual LMS Spike Conc. (ng/g; dry weight) N/A 215 N/A 81.1 N/A 25.8 N/A 2 2 .6 N/A 0.755 N/A 1.04 N/A 0.841 N/A 4.83 N/A 0.903 N/A 0.891 N/A 0.985 N/A 5.49 N/A 4.56 N/A 3.93 N/A 0.752 N/A 32.3 Measured PFHS Concentration (ng/g; dry weight) 125 118 344 44.6 44.6 129 22.9 2 2 .2 53.1 16.3 15.8 40.3 0.875 0.901 1.55 0.919 0.838 2.09 0.835 0.773 1.97 4.53 4.10 9.32 0.360 0.322 1.37 0.512 0.431 1.43 0.403 0.427 1.52 4.13 4.68 10.3 2.35 2.59 7.60 2 .1 1 2.48 6.31 0.728 1 .0 0 1.77 16.8 11.1 43.7 RPD / LMS Recover y (%) 5.6% 103% 0 .1 0 % 104% 3.4% 119% 3.1% 107% 2.9% 88.3% 9.1% 116% 7.7% 138% 10% 104% 11% 114% 17% 108% 5.9% 112% 13% 107% 9.6% 113% 16% 102% 32% 121% 41% 92.0% Average PFHS Conc. (ng/g; dry wt.) 121 N/A 44.6 N/A 22.5 N/A 16.1 N/A 0 .8 8 8 N/A 0.879 N/A 0.804 [b] N/A 4.31 N/A 0.341 N/A 0.471 N/A 0.415 N/A 4.40 N/A 2.47 N/A 2.29 N/A 0.864 N/A 14.0 N/A 3M Study GLP10-01-02-15 Page 36 of 514 Study: GLP10-01-02, Interim Report 15 Analysis for PFOS, PFHS and PFBS in Avenue A Soils/Sediments Collected January 2011 Table 15. Individual PFHS Results for Decatur, AL Avenue A Soils & Sediments, January 2011 LIMS Sample ID Sample Description GLP10-01-01-15-070 GLP10-01-01-15-070 Dup GLP10-01-01-15-070 LMS GLP10-01-01-15-071 GLP10-01-01-15-071 Dup GLP10-01-01-15-071 LMS GLP10-01-01-15-072 GLP10-01-01-15-072 Dup GLP10-01-01-15-072 LMS GLP10-01-01-15-073 GLP10-01-01-15-073 Dup GLP10-01-01-15-073 LMS GLP10-01-01-15-074 GLP10-01-01-15-074 Dup GLP10-01-01-15-074 LMS GLP10-01-01-15-075 GLP10-01-01-15-075 Dup GLP10-01-01-15-075 LMS GLP10-01-01-15-076 GLP10-01-01-15-076 Dup GLP10-01-01-15-076 LMS GLP10-01-01-15-077 GLP10-01-01-15-077 Dup GLP10-01-01-15-077 LMS GLP10-01-01-15-079 GLP10-01-01-15-079 Dup GLP10-01-01-15-079 LMS GLP10-01-01-15-080 GLP10-01-01-15-080 Dup GLP10-01-01-15-080 LMS GLP10-01-01-15-081 GLP10-01-01-15-081 Dup GLP10-01-01-15-081 LMS GLP10-01-01-15-082 GLP10-01-01-15-082 Dup GLP10-01-01-15-082 LMS GLP10-01-01-15-083 GLP10-01-01-15-083 Dup GLP10-01-01-15-083 LMS GLP10-01-01-15-084 GLP10-01-01-15-084 Dup GLP10-01-01-15-084 LMS GLP10-01-01-15-085 GLP10-01-01-15-085 Dup GLP10-01-01-15-085 LMS GLP10-01-01-15-086 GLP10-01-01-15-086 Dup GLP10-01-01-15-086 LMS DAL SS SS21 0 0005 DAL SS SS21 0 0005 Lab Duplicate DAL SS SS21 0 0005 Lab Matrix Spike DAL SS SS21 0 0015 DAL SS SS21 0 0015 Lab Duplicate DAL SS SS21 0 0015 Lab Matrix Spike DAL SD SD18 0 0000 DAL SD SD18 0 0000 Lab Duplicate DAL SD SD18 0 0000 Lab Matrix Spike DAL SD SD18 0 0005 DAL SD SD18 0 0005 Lab Duplicate DAL SD SD18 0 0005 Lab Matrix Spike DAL SD SD18 0 0015 DAL SD SD18 0 0015 Lab Duplicate DAL SD SD18 0 0015 Lab Matrix Spike DAL SD SD19 0 0000 DAL SD SD19 0 0000 Lab Duplicate DAL SD SD19 0 0000 Lab Matrix Spike DAL SD SD19 0 0005 DAL SD SD19 0 0005 Lab Duplicate DAL SD SD19 0 0005 Lab Matrix Spike DAL SD SD19 0 0015 DAL SD SD19 0 0015 Lab Duplicate DAL SD SD19 0 0015 Lab Matrix Spike DAL SS SS26 0 0000 DAL SS SS26 0 0000 Lab Duplicate DAL SS SS26 0 0000 Lab Matrix Spike DAL SS SS26 DB 0000 DAL SS SS26 DB 0000 Lab Duplicate DAL SS SS26 DB 0000 Lab Matrix Spike DAL SS SS26 0 0005 DAL SS SS26 0 0005 Lab Duplicate DAL SS SS26 0 0005 Lab Matrix Spike DAL SS SS26 0 0015 DAL SS SS26 0 0015 Lab Duplicate DAL SS SS26 0 0015 Lab Matrix Spike DAL SS Trip2 0 0000 DAL SS Trip2 0 0000 Lab Duplicate DAL SS Trip2 0 0000 Lab Matrix Spike DAL SS SS12 0 0015 DAL SS SS12 0 0015 Lab Duplicate DAL SS SS12 0 0015 Lab Matrix Spike DAL SS SS19 0 0015 DAL SS SS19 0 0015 Lab Duplicate DAL SS SS19 0 0015 Lab Matrix Spike DAL SS SS20 0 0015 DAL SS SS20 0 0015 Lab Duplicate DAL SS SS20 0 0015 Lab Matrix Spike Surrogate (13C4-PFOS) Recovery [a] 111% 100% 111% 99.0% 103% 113% 106% 106% 106% 111% 109% 113% 104% 115% 111% 117% 109% 98.3% 107% 110% 112% 112% 105% 112% 101% 103% 115% 107% 103% 109% 104% 105% 113% 118% 122% 103% 106% 102% 104% 122% 106% 142% 111% 110% 104% 100% 99.0% 115% Actual LMS Spike Conc. (ng/g; dry weight) N/A 29.1 N/A 25.7 N/A 215 N/A 72.4 N/A 106 N/A 166 N/A 234 N/A 108 N/A 23.0 N/A 46.9 N/A 20.7 N/A 92.9 N/A 0.841 N/A 426 N/A 24.3 N/A 5.26 Measured PFHS Concentration (ng/g; dry weight) 13.6 13.2 46.2 14.0 1 2 .0 39.4 112 102 326 77.7 79.4 161 53.3 42.3 141 129 110 305 129 126 360 63.7 87.8 225 8.58 7.93 32.6 9.00 10.9 58.1 17.3 18.1 40.7 70.6 54.3 151 BLQ BLQ 0.844 297 291 737 2 2 .8 24.4 46.2 2.60 2.16 7.70 RPD / LMS Recover y (%) 2 .6 % 113% 16% 103% 10% 102% 2 .2 % 113% 23% 8 8 .0 % 15% 112% 2 .0 % 100% 32% 139% 7.8% 106% 19% 103% 4.2% 111% 26% 95.8% N/A 100% 2 .2 % 104% 6.9% 93.3% 19% 101% Average PFHS Conc. (ng/g; dry wt.) 13.4 N/A 13.0 N/A 107 N/A 78.6 N/A 47.8 N/A 119 N/A 127 N/A 75.7 [b] N/A 8.26 N/A 9.95 [c] N/A 17.7 N/A 62.4 N/A BLQ N/A 294 N/A 23.6 N/A 2.38 N/A 3M Study GLP10-01-02-15 Page 37 of 514 Study: GLP10-01-02, Interim Report 15 Analysis for PFOS, PFHS and PFBS in Avenue A Soils/Sediments Collected January 2011 Table 15. Individual PFHS Results for Decatur, AL Avenue A Soils & Sediments, January 2011 LIMS Sample ID Sample Description Surrogate (13C4-PFOS) Recovery [a] Actual LMS Spike Conc. (ng/g; dry weight) Measured PFHS Concentration (ng/g; dry weight) RPD / LMS Recover y (%) Average PFHS Conc. (ng/g; dry wt.) GLP10-01-01-15-087 GLP10-01-01-15-087 Dup DAL SS SS14 0 0015 DAL SS SS14 0 0015 Lab Duplicate 109% 110% N/A 3.19 2 .6 8 17% 2.93 [b] GLP10-01-01-15-087 LMS DAL SS SS14 0 0015 Lab Matrix Spike 102% 5.96 1 1 .0 136% N/A GLP10-01-01-15-088 GLP10-01-01-15-088 Dup DAL SS SS17 0 0015 DAL SS SS17 0 0015 Lab Duplicate 106% 108% N/A 1.93 2.01 3.9% 1.97 GLP10-01-01-15-088 LMS DAL SS SS17 0 0015 Lab Matrix Spike 108% 5.77 7.97 104% N/A GLP10-01-01-15-089 GLP10-01-01-15-089 Dup DAL SS SS13 0 0015 DAL SS SS13 0 0015 Lab Duplicate 109% 102% N/A 1.82 2.04 11% 1.93 GLP10-01-01-15-089 LMS DAL SS SS13 0 0015 Lab Matrix Spike 103% 6.73 9.12 107% N/A GLP10-01-01-15-090 GLP10-01-01-15-090 Dup DAL SS SS15 0 0015 DAL SS SS15 0 0015 Lab Duplicate 103% 94.3% N/A 3.78 3.92 3.6% 3.85 GLP10-01-01-15-090 LMS DAL SS SS15 0 0015 Lab Matrix Spike 106% 5.45 9.52 104% N/A GLP10-01-01-15-091 GLP10-01-01-15-091 Dup DAL SS SS18 0 0015 DAL SS SS18 0 0015 Lab Duplicate 101% 109% N/A 1.84 26% 1.63 1.42 GLP10-01-01-15-091 LMS DAL SS SS18 0 0015 Lab Matrix Spike 104% 4.88 7.15 113% N/A GLP10-01-01-15-092 GLP10-01-01-15-092 Dup DAL SS SS11 0 0015 DAL SS SS11 0 0015 Lab Duplicate 108% 97.7% N/A 0.419 0.612 38% 0.515 GLP10-01-01-15-092 LMS DAL SS SS11 0 0015 Lab Matrix Spike 108% 1.06 1.55 98.2% N/A BLQ; Analyte/IS peak area response ratio was less than that of the lowest acceptable standard in the curve and was nominal 0.200 ng/g Values are shown at 3 significant figures, but more precise data was used for data calculations. All results were reported from the least diluted sample that fell within the range of the calibration curve. NR; not reportable due to QC failure [a] RPD for duplicate results was greater than 50% [b] LMS recovery was outside of 100 + 30%, but within reporting limits of 100 + 50% [c] Result determined from a reassay result when original results were NR, surrogate recovery result is shown from original result.______ Table 16. Individual PFBS Results for Decatur, AL Avenue A Soils & Sediments, January 2011 LIMS Sample ID Sample Description GLP10-01-01-15-001 GLP10-01-01-15-001 Dup GLP10-01-01-15-001 LMS GLP10-01-01-15-002 GLP10-01-01-15-002 Dup GLP10-01-01-15-002 LMS GLP10-01-01-15-003 GLP10-01-01-15-003 Dup GLP10-01-01-15-003 LMS GLP10-01-01-15-004 GLP10-01-01-15-004 Dup GLP10-01-01-15-004 LMS GLP10-01-01-15-005 GLP10-01-01-15-005 Dup GLP10-01-01-15-005 LMS DAL SS Tripl 0 0000 DAL SS Tripl 0 0000 Lab Duplicate DAL SS Tripl 0 0000 Lab Matrix Spike DAL SS SS12 0 0000 DAL SS SS12 0 0000 Lab Duplicate DAL SS SS12 0 0000 Lab Matrix Spike DAL SS SS12 0 0005 DAL SS SS12 0 0005 Lab Duplicate DAL SS SS12 0 0005 Lab Matrix Spike DAL SS SS13 0 0000 DAL SS SS13 0 0000 Lab Duplicate DAL SS SS13 0 0000 Lab Matrix Spike DAL SS SS16 0 0000 DAL SS SS16 0 0000 Lab Duplicate DAL SS SS16 0 0000 Lab Matrix Spike Surrogate (13C4-PFOS) Recovery [a] 98.3% 104% 106% 118% 110% 149% 129% 125% 149% 105% 114% 106% 94.6% 102% 107% Actual LMS Spike Conc. (ng/g; dry weight) N/A 0.8 8 8 N/A 2 .6 6 N/A 15.1 N/A 3.69 N/A 21.5 Measured PFBS Concentration (ng/g; dry weight) BLQ BLQ 0.872 1.35 1 .0 0 4.50 5.79 4.00 2 0 .0 0.907 1 .1 0 4.86 6.93 7.54 30.8 RPD / LMS Recover y (%) N/A 98.3% 29% 125% 37% 100% 20% 105% 8.4% 110% Average PFBS Conc. (ng/g; dry wt.) BLQ N/A 1.17 N/A 4.89 N/A 1 . 0 1 [c] N/A 7.24 N/A 3M Study GLP10-01-02-15 Page 38 of 514 Study: GLP10-01-02, Interim Report 15 Analysis for PFOS, PFHS and PFBS in Avenue A Soils/Sediments Collected January 2011 Table 16. Individual PFBS Results for Decatur, AL Avenue A Soils & Sediments, January 2011 LIMS Sample ID Sample Description GLP10-01-01-15-006 GLP10-01-01-15-006 Dup GLP10-01-01-15-006 LMS GLP10-01-01-15-007 GLP10-01-01-15-007 Dup GLP10-01-01-15-007 LMS GLP10-01-01-15-008 GLP10-01-01-15-008 Dup GLP10-01-01-15-008 LMS GLP10-01-01-15-009 GLP10-01-01-15-009 Dup GLP10-01-01-15-009 LMS GLP10-01-01-15-010 GLP10-01-01-15-010 Dup GLP10-01-01-15-010 LMS GLP10-01-01-15-011 GLP10-01-01-15-011 Dup GLP10-01-01-15-011 LMS GLP10-01-01-15-012 GLP10-01-01-15-012 Dup GLP10-01-01-15-012 LMS GLP10-01-01-15-014 GLP10-01-01-15-014 Dup GLP10-01-01-15-014 LMS GLP10-01-01-15-015 GLP10-01-01-15-015 Dup GLP10-01-01-15-015 LMS GLP10-01-01-15-016 GLP10-01-01-15-016 Dup GLP10-01-01-15-016 LMS GLP10-01-01-15-018 GLP10-01-01-15-018 Dup GLP10-01-01-15-018 LMS GLP10-01-01-15-020 GLP10-01-01-15-020 Dup GLP10-01-01-15-020 LMS GLP10-01-01-15-021 GLP10-01-01-15-021 Dup GLP10-01-01-15-021 LMS GLP10-01-01-15-022 GLP10-01-01-15-022 Dup GLP10-01-01-15-022 LMS GLP10-01-01-15-023 GLP10-01-01-15-023 Dup GLP10-01-01-15-023 LMS GLP10-01-01-15-024 GLP10-01-01-15-024 Dup GLP10-01-01-15-024 LMS DAL SS SS16 DB 0000 DAL SS SS16 DB 0000 Lab Duplicate DAL SS SS16 DB 0000 Lab Matrix Spike DAL SS SS11 0 0000 DAL SS SS11 0 0000 Lab Duplicate DAL SS SS11 0 0000 Lab Matrix Spike DAL SS SS11 0 0005 DAL SS SS11 0 0005 Lab Duplicate DAL SS SS11 0 0005 Lab Matrix Spike DAL SS SS20 0 0000 DAL SS SS20 0 0000 Lab Duplicate DAL SS SS20 0 0000 Lab Matrix Spike DAL SS SS20 DB 0000 DAL SS SS20 DB 0000 Lab Duplicate DAL SS SS20 DB 0000 Lab Matrix Spike DAL SS SS19 0 0000 DAL SS SS19 0 0000 Lab Duplicate DAL SS SS19 0 0000 Lab Matrix Spike DAL SS SS19 0 0005 DAL SS SS19 0 0005 Lab Duplicate DAL SS SS19 0 0005 Lab Matrix Spike DAL SS SS15 0 0000 DAL SS SS15 0 0000 Lab Duplicate DAL SS SS15 0 0000 Lab Matrix Spike DAL SS SS17 0 0000 DAL SS SS17 0 0000 Lab Duplicate DAL SS SS17 0 0000 Lab Matrix Spike DAL SS SS14 0 0000 DAL SS SS14 0 0000 Lab Duplicate DAL SS SS14 0 0000 Lab Matrix Spike DAL SS SS18 0 0000 DAL SS SS18 0 0000 Lab Duplicate DAL SS SS18 0 0000 Lab Matrix Spike DAL SS SS10 0 0000 DAL SS SS10 0 0000 Lab Duplicate DAL SS SS10 0 0000 Lab Matrix Spike DAL SS SS30 0 0000 DAL SS SS30 0 0000 Lab Duplicate DAL SS SS30 0 0000 Lab Matrix Spike DAL SS SS30 0 0005 DAL SS SS30 0 0005 Lab Duplicate DAL SS SS30 0 0005 Lab Matrix Spike DAL SS SS30 0 0015 DAL SS SS30 0 0015 Lab Duplicate DAL SS SS30 0 0015 Lab Matrix Spike DAL SS SS25 0 0000 DAL SS SS25 0 0000 Lab Duplicate DAL SS SS25 0 0000 Lab Matrix Spike Surrogate (13C4-PFOS) Recovery [a] 104% 105% 105% 104% 96.6% 98.3% 130% 106% 93.6% 105% 111% 108% 103% 96.0% 108% 104% 104% 100% 100% 104% 110% 103% 102% 95.0% 103% 99.0% 98.0% 95.3% 118% 117% 103% 100% 100% 112% 104% 130% 102% 103% 120% 105% 109% 112% 102% 105% 106% 115% 115% 124% Actual LMS Spike Conc. (ng/g; dry weight) N/A 19.8 N/A 0.909 N/A 3.26 N/A 0.6 8 6 N/A 0.716 N/A 0.564 N/A 4.85 N/A 0.718 N/A 0.793 N/A 0.878 N/A 0.641 N/A 4.04 N/A 1.07 N/A 1.05 N/A 1 .2 2 N/A 52.5 Measured PFBS Concentration (ng/g; dry weight) 8.61 6.48 30.2 0.765 0.627 1.91 0.664 0.590 4.48 0.308 0.309 1.07 0.246 0.248 1.32 0 .2 1 1 0.237 0.881 1.32 1.28 6.84 0.227 0.338 1.19 0.247 0.209 1.25 0.473 0.515 1.55 0.596 1.03 1.39 5.08 5.48 1 1 .0 0.544 0.552 1.71 BLQ BLQ 1.56 1.17 1.28 2.58 16.3 23.1 72.5 RPD / LMS Recover y (%) 28% 114% 20% 134% 12% 105% 0.38% 111% 1 .1 % 150% 12% 116% 3.2% 114% 39% 127% 17% 129% 8 .6 % 120% 54% 89.2% 7.4% 110% 1.4% 109% N/A 148% 9.1% 111% 34% 101% Average PFBS Conc. (ng/g; dry wt.) 7.54 N/A 0.696 [b] N/A 0.627 [c] N/A 0.309 N/A 0.247 [b] N/A 0.224 N/A 1.30 N/A 0.283 N/A 0.228 N/A 0.494 N/A 0.814 5.28 [c] N/A 0.548 N/A BLQ [b] N/A 1 .2 2 N/A 19.7 N/A 3M Study GLP10-01-02-15 Page 39 of 514 Study: GLP10-01-02, Interim Report 15 Analysis for PFOS, PFHS and PFBS in Avenue A Soils/Sediments Collected January 2011 Table 16. Individual PFBS Results for Decatur, AL Avenue A Soils & Sediments, January 2011 LIMS Sample ID Sample Description GLP10-01-01-15-025 GLP10-01-01-15-025 Dup GLP10-01-01-15-025 LMS GLP10-01-01-15-026 GLP10-01-01-15-026 Dup GLP10-01-01-15-026 LMS GLP10-01-01-15-027 GLP10-01-01-15-027 Dup GLP10-01-01-15-027 LMS GLP10-01-01-15-028 GLP10-01-01-15-028 Dup GLP10-01-01-15-028 LMS GLP10-01-01-15-029 GLP10-01-01-15-029 Dup GLP10-01-01-15-029 LMS GLP10-01-01-15-030 GLP10-01-01-15-030 Dup GLP10-01-01-15-030 LMS GLP10-01-01-15-031 GLP10-01-01-15-031 Dup GLP10-01-01-15-031 LMS GLP10-01-01-15-032 GLP10-01-01-15-032 Dup GLP10-01-01-15-032 LMS GLP10-01-01-15-033 GLP10-01-01-15-033 Dup GLP10-01-01-15-033 LMS GLP10-01-01-15-034 GLP10-01-01-15-034 Dup GLP10-01-01-15-034 LMS GLP10-01-01-15-035 GLP10-01-01-15-035 Dup GLP10-01-01-15-035 LMS GLP10-01-01-15-036 GLP10-01-01-15-036 Dup GLP10-01-01-15-036 LMS GLP10-01-01-15-037 GLP10-01-01-15-037 Dup GLP10-01-01-15-037 LMS GLP10-01-01-15-038 GLP10-01-01-15-038 Dup GLP10-01-01-15-038 LMS GLP10-01-01-15-039 GLP10-01-01-15-039 Dup GLP10-01-01-15-039 LMS GLP10-01-01-15-040 GLP10-01-01-15-040 Dup GLP10-01-01-15-040 LMS DAL SS SS25 0 0005 DAL SS SS25 0 0005 Lab Duplicate DAL SS SS25 0 0005 Lab Matrix Spike DAL SS SS25 0 0015 DAL SS SS25 0 0015 Lab Duplicate DAL SS SS25 0 0015 Lab Matrix Spike DAL SD SD22 0 0000 DAL SD SD22 0 0000 Lab Duplicate DAL SD SD22 0 0000 Lab Matrix Spike DAL SD SD22 0 0005 DAL SD SD22 0 0005 Lab Duplicate DAL SD SD22 0 0005 Lab Matrix Spike DAL SD SD22 DB 0005 DAL SD SD22 DB 0005 Lab Duplicate DAL SD SD22 DB 0005 Lab Matrix Spike DAL SD SD22 0 0015 DAL SD SD22 0 0015 Lab Duplicate DAL SD SD22 0 0015 Lab Matrix Spike DAL SD SD21 0 0000 DAL SD SD21 0 0000 Lab Duplicate DAL SD SD21 0 0000 Lab Matrix Spike DAL SD SD21 0 0005 DAL SD SD21 0 0005 Lab Duplicate DAL SD SD21 0 0005 Lab Matrix Spike DAL SD SD21 0 0015 DAL SD SD21 0 0015 Lab Duplicate DAL SD SD21 0 0015 Lab Matrix Spike DAL SS SS24 0 0000 DAL SS SS24 0 0000 Lab Duplicate DAL SS SS24 0 0000 Lab Matrix Spike DAL SS SS24 0 0005 DAL SS SS24 0 0005 Lab Duplicate DAL SS SS24 0 0005 Lab Matrix Spike DAL SS SS24 0 0015 DAL SS SS24 0 0015 Lab Duplicate DAL SS SS24 0 0015 Lab Matrix Spike DAL SS SS29 0 0000 DAL SS SS29 0 0000 Lab Duplicate DAL SS SS29 0 0000 Lab Matrix Spike DAL SS SS29 0 0005 DAL SS SS29 0 0005 Lab Duplicate DAL SS SS29 0 0005 Lab Matrix Spike DAL SS SS29 0 0015 DAL SS SS29 0 0015 Lab Duplicate DAL SS SS29 0 0015 Lab Matrix Spike DAL SS SS20 0 0005 DAL SS SS20 0 0005 Lab Duplicate DAL SS SS20 0 0005 Lab Matrix Spike Surrogate (13C4-PFOS) Recovery [a] 114% 108% 137% 125% 111% 123% 117% 112% 132% 108% 98.0% 99.3% 110% 98.3% 102% 109% 105% 100% 106% 125% 145% 112% 114% 114% 101% 105% 105% 105% 112% 106% 114% 116% 131% 121% 116% 106% 109% 107% 114% 107% 102% 102% 105% 109% 111% 110% 110% 96.6% Actual LMS Spike Conc. (ng/g; dry weight) N/A 83.9 N/A 81.4 N/A 20.6 N/A 18.2 N/A 18.9 N/A 26.8 N/A 21.5 N/A 23.4 N/A 20.7 N/A 4.61 N/A 12.7 N/A 4.35 N/A 5.70 N/A 4.44 N/A 16.8 N/A 1.08 Measured PFBS Concentration (ng/g; dry weight) 36.0 31.7 123 32.9 37.2 134 16.6 11.3 35.3 7.54 7.87 27.4 7.28 5.71 33.6 7.45 8.93 38.7 7.83 7.89 34.5 10.3 10.5 36.1 5.92 5.01 29.1 5.69 6.60 10.8 9.17 8.43 22.4 2.68 3.65 9.23 1.68 1.66 7.96 0.810 0.711 5.99 7.12 5.48 25.6 0.278 0.320 1.59 RPD / LMS Recover y (%) 13% 106% 12% 121% 38% 104% 4.3% 108% 24% 143% 18% 114% 0.79% 124% 1.7% 105% 17% 141% 15% 101% 8.4% 107% 31% 139% 0.78% 110% 13% 118% 26% 115% 14% 120% Average PFBS Conc. (ng/g; dry wt.) 33.8 N/A 35.0 N/A 13.9 N/A 7.70 N/A 6.49 [b] N/A 8.19 N/A 7.86 N/A 10.4 [c] N/A 5.46 [b] N/A 6.14 N/A 8.80 N/A 3.17 [b] N/A 1.67 N/A 0.760 N/A 6.30 N/A 0.299 N/A 3M Study GLP10-01-02-15 Page 40 of 514 Study: GLP10-01-02, Interim Report 15 Analysis for PFOS, PFHS and PFBS in Avenue A Soils/Sediments Collected January 2011 Table 16. Individual PFBS Results for Decatur, AL Avenue A Soils & Sediments, January 2011 LIMS Sample ID Sample Description GLP10-01-01-15-041 GLP10-01-01-15-041 Dup GLP10-01-01-15-041 LMS GLP10-01-01-15-042 GLP10-01-01-15-042 Dup GLP10-01-01-15-042 LMS GLP10-01-01-15-043 GLP10-01-01-15-043 Dup GLP10-01-01-15-043 LMS GLP10-01-01-15-044 GLP10-01-01-15-044 Dup GLP10-01-01-15-044 LMS GLP10-01-01-15-045 GLP10-01-01-15-045 Dup GLP10-01-01-15-045 LMS GLP10-01-01-15-046 GLP10-01-01-15-046 Dup GLP10-01-01-15-046 LMS GLP10-01-01-15-047 GLP10-01-01-15-047 Dup GLP10-01-01-15-047 LMS GLP10-01-01-15-048 GLP10-01-01-15-048 Dup GLP10-01-01-15-048 LMS GLP10-01-01-15-049 GLP10-01-01-15-049 Dup GLP10-01-01-15-049 LMS GLP10-01-01-15-050 GLP10-01-01-15-050 Dup GLP10-01-01-15-050 LMS GLP10-01-01-15-051 GLP10-01-01-15-051 Dup GLP10-01-01-15-051 LMS GLP10-01-01-15-052 GLP10-01-01-15-052 Dup GLP10-01-01-15-052 LMS GLP10-01-01-15-053 GLP10-01-01-15-053 Dup GLP10-01-01-15-053 LMS GLP10-01-01-15-054 GLP10-01-01-15-054 Dup GLP10-01-01-15-054 LMS GLP10-01-01-15-055 GLP10-01-01-15-055 Dup GLP10-01-01-15-055 LMS GLP10-01-01-15-056 GLP10-01-01-15-056 Dup GLP10-01-01-15-056 LMS DAL SS SS13 0 0005 DAL SS SS13 0 0005 Lab Duplicate DAL SS SS13 0 0005 Lab Matrix Spike DAL SS SS13 DB 0005 DAL SS SS13 DB 0005 Lab Duplicate DAL SS SS13 DB 0005 Lab Matrix Spike DAL SS SS15 0 0005 DAL SS SS15 0 0005 Lab Duplicate DAL SS SS15 0 0005 Lab Matrix Spike DAL SS SS17 0 0005 DAL SS SS17 0 0005 Lab Duplicate DAL SS SS17 0 0005 Lab Matrix Spike DAL SS SS14 0 0005 DAL SS SS14 0 0005 Lab Duplicate DAL SS SS14 0 0005 Lab Matrix Spike DAL SS SS18 0 0005 DAL SS SS18 0 0005 Lab Duplicate DAL SS SS18 0 0005 Lab Matrix Spike DAL SS SS16 0 0005 DAL SS SS16 0 0005 Lab Duplicate DAL SS SS16 0 0005 Lab Matrix Spike DAL SS SS16 0 0015 DAL SS SS16 0 0015 Lab Duplicate DAL SS SS16 0 0015 Lab Matrix Spike DAL SS SS10 0 0005 DAL SS SS10 0 0005 Lab Duplicate DAL SS SS10 0 0005 Lab Matrix Spike DAL SS SS10 DB 0005 DAL SS SS10 DB 0005 Lab Duplicate DAL SS SS10 DB 0005 Lab Matrix Spike DAL SS SS10 0 0015 DAL SS SS10 0 0015 Lab Duplicate DAL SS SS10 0 0015 Lab Matrix Spike DAL SD SD20 0 0000 DAL SD SD20 0 0000 Lab Duplicate DAL SD SD20 0 0000 Lab Matrix Spike DAL SD SD20 0 0005 DAL SD SD20 0 0005 Lab Duplicate DAL SD SD20 0 0005 Lab Matrix Spike DAL SD SD20 0 0015 DAL SD SD20 0 0015 Lab Duplicate DAL SD SD20 0 0015 Lab Matrix Spike DAL SD SD23 0 0000 DAL SD SD23 0 0000 Lab Duplicate DAL SD SD23 0 0000 Lab Matrix Spike DAL SD SD23 0 0005 DAL SD SD23 0 0005 Lab Duplicate DAL SD SD23 0 0005 Lab Matrix Spike Surrogate (13C4-PFOS) Recovery [a] 109% 100% 112% 100% 98.0% 107% 107% 104% 104% 109% 107% 97.3% 111% 99.3% 109% 105% 110% 106% 108% 107% 104% 100% 101% 112% 116% 108% 105% 109% 111% 113% 104% 100% 110% 109% 106% 136% 102% 109% 116% 100% 105% 116% 101% 101% 104% 104% 108% 109% Actual LMS Spike Conc. (ng/g; dry weight) N/A 1.15 N/A 0.954 N/A 0.761 N/A 0.910 N/A 0.889 N/A 0.834 N/A 4.22 N/A 19.3 N/A 3.27 N/A 3.18 N/A 14.7 N/A 24.4 N/A 24.2 N/A 21.5 N/A 20.3 N/A 5.15 Measured PFBS Concentration (ng/g; dry weight) 0.939 1.04 2.38 0.979 0.833 1.92 BLQ 0.154 1.04 0.275 0.177 1.27 BLQ BLQ 1.29 BLQ BLQ 0.968 2.06 2.71 7.21 6 .1 2 7.89 29.5 1.15 1.36 5.03 1.07 1.29 5.12 3.49 3.67 19.1 8.71 1 1 .8 37.4 10.5 11.1 36.4 9.95 9.41 35.2 5.08 4.85 28.1 2.49 2.34 8.37 RPD / LMS Recover y (%) 9.9% 120% 16% 106% N/A 137% 44% 114% N/A 145% N/A 116% 27% 114% 25% 116% 17% 115% 18% 124% 4.8% 106% 30% 111% 5.5% 106% 5.5% 119% 4.6% 114% 6 .1 % 115% Average PFBS Conc. (ng/g; dry wt.) 0.988 N/A 0.906 N/A 0.154 [b. d] N/A 0.226 N/A BLQ [b] N/A BLQ N/A 2.39 N/A 7.00 N/A 1.25 N/A 1.18 N/A 3.58 N/A 10.3 N/A 1 0 .8 N/A 9.68 N/A 4.97 N/A 2.42 N/A 3M Study GLP10-01-02-15 Page 41 of 514 Study: GLP10-01-02, Interim Report 15 Analysis for PFOS, PFHS and PFBS in Avenue A Soils/Sediments Collected January 2011 Table 16. Individual PFBS Results for Decatur, AL Avenue A Soils & Sediments, January 2011 LIMS Sample ID Sample Description GLP10-01-01-15-057 GLP10-01-01-15-057 Dup GLP10-01-01-15-057 LMS GLP10-01-01-15-058 GLP10-01-01-15-058 Dup GLP10-01-01-15-058 LMS GLP10-01-01-15-059 GLP10-01-01-15-059 Dup GLP10-01-01-15-059 LMS GLP10-01-01-15-060 GLP10-01-01-15-060 Dup GLP10-01-01-15-060 LMS GLP10-01-01-15-061 GLP10-01-01-15-061 Dup GLP10-01-01-15-061 LMS GLP10-01-01-15-062 GLP10-01-01-15-062 Dup GLP10-01-01-15-062 LMS GLP10-01-01-15-063 GLP10-01-01-15-063 Dup GLP10-01-01-15-063 LMS GLP10-01-01-15-064 GLP10-01-01-15-064 Dup GLP10-01-01-15-064 LMS GLP10-01-01-15-065 GLP10-01-01-15-065 Dup GLP10-01-01-15-065 LMS GLP10-01-01-15-066 GLP10-01-01-15-066 Dup GLP10-01-01-15-066 LMS GLP10-01-01-15-067 GLP10-01-01-15-067 Dup GLP10-01-01-15-067 LMS GLP10-01-01-15-068 GLP10-01-01-15-068 Dup GLP10-01-01-15-068 LMS GLP10-01-01-15-069 GLP10-01-01-15-069 Dup GLP10-01-01-15-069 LMS GLP10-01-01-15-070 GLP10-01-01-15-070 Dup GLP10-01-01-15-070 LMS GLP10-01-01-15-071 GLP10-01-01-15-071 Dup GLP10-01-01-15-071 LMS GLP10-01-01-15-072 GLP10-01-01-15-072 Dup GLP10-01-01-15-072 LMS DAL SD SD23 0 0015 DAL SD SD23 0 0015 Lab Duplicate DAL SD SD23 0 0015 Lab Matrix Spike DAL SS SS28 0 0000 DAL SS SS28 0 0000 Lab Duplicate DAL SS SS28 0 0000 Lab Matrix Spike DAL SS SS28 0 0005 DAL SS SS28 0 0005 Lab Duplicate DAL SS SS28 0 0005 Lab Matrix Spike DAL SS SS28 DB 0005 DAL SS SS28 DB 0005 Lab Duplicate DAL SS SS28 DB 0005 Lab Matrix Spike DAL SS SS28 0 0015 DAL SS SS28 0 0015 Lab Duplicate DAL SS SS28 0 0015 Lab Matrix Spike DAL SS SS27 0 0000 DAL SS SS27 0 0000 Lab Duplicate DAL SS SS27 0 0000 Lab Matrix Spike DAL SS SS27 0 0005 DAL SS SS27 0 0005 Lab Duplicate DAL SS SS27 0 0005 Lab Matrix Spike DAL SS SS27 0 0015 DAL SS SS27 0 0015 Lab Duplicate DAL SS SS27 0 0015 Lab Matrix Spike DAL SS SS22 0 0000 DAL SS SS22 0 0000 Lab Duplicate DAL SS SS22 0 0000 Lab Matrix Spike DAL SS SS22 0 0005 DAL SS SS22 0 0005 Lab Duplicate DAL SS SS22 0 0005 Lab Matrix Spike DAL SS SS22 DB 0005 DAL SS SS22 DB 0005 Lab Duplicate DAL SS SS22 DB 0005 Lab Matrix Spike DAL SS SS22 0 0015 DAL SS SS22 0 0015 Lab Duplicate DAL SS SS22 0 0015 Lab Matrix Spike DAL SS SS21 0 0000 DAL SS SS21 0 0000 Lab Duplicate DAL SS SS21 0 0000 Lab Matrix Spike DAL SS SS21 0 0005 DAL SS SS21 0 0005 Lab Duplicate DAL SS SS21 0 0005 Lab Matrix Spike DAL SS SS21 0 0015 DAL SS SS21 0 0015 Lab Duplicate DAL SS SS21 0 0015 Lab Matrix Spike DAL SD SD18 0 0000 DAL SD SD18 0 0000 Lab Duplicate DAL SD SD18 0 0000 Lab Matrix Spike Surrogate (13C4-PFOS) Recovery [a] 108% 104% 106% 108% 102% 113% 105% 97.0% 103% 101% 108% 111% 104% 103% 109% 107% 100% 109% 116% 104% 102% 95.3% 115% 111% 115% 108% 120% 98.3% 101% 110% 103% 107% 109% 105% 102% 111% 106% 106% 106% 111% 100% 111% 99.0% 103% 113% 106% 106% 106% Actual LMS Spike Conc. (ng/g; dry weight) N/A 4.51 N/A 3.77 N/A 1.04 N/A 0.840 N/A 4.83 N/A 0.902 N/A 0.890 N/A 0.984 N/A 5.49 N/A 4.56 N/A 3.93 N/A 0.751 N/A 1.29 N/A 1.16 N/A 5.14 N/A 21.5 Measured PFBS Concentration (ng/g; dry weight) 2.09 2.06 6.74 0.830 0.844 5.00 0.689 0.576 2 .0 1 0.630 0.577 1.75 2.48 2 .1 0 7.82 0.694 0.794 1.82 0.6 8 6 0.619 1.62 0.432 0.392 1.61 1.28 1.50 7.56 1.46 1.36 6.26 1.37 1.53 5.86 0.495 0.551 1.39 0.971 0.674 2.23 0.352 0.383 1.81 2.06 1.85 7.65 10.31 9.10 34.1 RPD / LMS Recover y (%) 1.5% 103% 1.7% 110% 18% 132% 8 .8 % 136% 17% 115% 13% 120% 10% 109% 9.7% 121% 15% 112% 7.0% 106% 11% 112% 11% 116% 36% 109% 8 .6 % 125% 11% 111% 12% 114% Average PFBS Conc. (ng/g; dry wt.) 2.08 N/A 0.837 N/A 0.633 [b] N/A 0.604 N/A 2.29 N/A 0.744 N/A 0.652 N/A 0.412 N/A 1.39 N/A 1.41 N/A 1.45 N/A 0.523 N/A 0.823 N/A 0.367 N/A 1.95 N/A 9.70 N/A 3M Study GLP10-01-02-15 Page 42 of 514 Study: GLP10-01-02, Interim Report 15 Analysis for PFOS, PFHS and PFBS in Avenue A Soils/Sediments Collected January 2011 Table 16. Individual PFBS Results for Decatur, AL Avenue A Soils & Sediments, January 2011 LIMS Sample ID Sample Description GLP10-01-01-15-073 GLP10-01-01-15-073 Dup GLP10-01-01-15-073 LMS GLP10-01-01-15-074 GLP10-01-01-15-074 Dup GLP10-01-01-15-074 LMS GLP10-01-01-15-075 GLP10-01-01-15-075 Dup GLP10-01-01-15-075 LMS GLP10-01-01-15-076 GLP10-01-01-15-076 Dup GLP10-01-01-15-076 LMS GLP10-01-01-15-077 GLP10-01-01-15-077 Dup GLP10-01-01-15-077 LMS GLP10-01-01-15-079 GLP10-01-01-15-079 Dup GLP10-01-01-15-079 LMS GLP10-01-01-15-080 GLP10-01-01-15-080 Dup GLP10-01-01-15-080 LMS GLP10-01-01-15-081 GLP10-01-01-15-081 Dup GLP10-01-01-15-081 LMS GLP10-01-01-15-082 GLP10-01-01-15-082 Dup GLP10-01-01-15-082 LMS GLP10-01-01-15-083 GLP10-01-01-15-083 Dup GLP10-01-01-15-083 LMS GLP10-01-01-15-084 GLP10-01-01-15-084 Dup GLP10-01-01-15-084 LMS GLP10-01-01-15-085 GLP10-01-01-15-085 Dup GLP10-01-01-15-085 LMS GLP10-01-01-15-086 GLP10-01-01-15-086 Dup GLP10-01-01-15-086 LMS GLP10-01-01-15-087 GLP10-01-01-15-087 Dup GLP10-01-01-15-087 LMS GLP10-01-01-15-088 GLP10-01-01-15-088 Dup GLP10-01-01-15-088 LMS GLP10-01-01-15-089 GLP10-01-01-15-089 Dup GLP10-01-01-15-089 LMS DAL SD SD18 0 0005 DAL SD SD18 0 0005 Lab Duplicate DAL SD SD18 0 0005 Lab Matrix Spike DAL SD SD18 0 0015 DAL SD SD18 0 0015 Lab Duplicate DAL SD SD18 0 0015 Lab Matrix Spike DAL SD SD19 0 0000 DAL SD SD19 0 0000 Lab Duplicate DAL SD SD19 0 0000 Lab Matrix Spike DAL SD SD19 0 0005 DAL SD SD19 0 0005 Lab Duplicate DAL SD SD19 0 0005 Lab Matrix Spike DAL SD SD19 0 0015 DAL SD SD19 0 0015 Lab Duplicate DAL SD SD19 0 0015 Lab Matrix Spike DAL SS SS26 0 0000 DAL SS SS26 0 0000 Lab Duplicate DAL SS SS26 0 0000 Lab Matrix Spike DAL SS SS26 DB 0000 DAL SS SS26 DB 0000 Lab Duplicate DAL SS SS26 DB 0000 Lab Matrix Spike DAL SS SS26 0 0005 DAL SS SS26 0 0005 Lab Duplicate DAL SS SS26 0 0005 Lab Matrix Spike DAL SS SS26 0 0015 DAL SS SS26 0 0015 Lab Duplicate DAL SS SS26 0 0015 Lab Matrix Spike DAL SS Trip2 0 0000 DAL SS Trip2 0 0000 Lab Duplicate DAL SS Trip2 0 0000 Lab Matrix Spike DAL SS SS12 0 0015 DAL SS SS12 0 0015 Lab Duplicate DAL SS SS12 0 0015 Lab Matrix Spike DAL SS SS19 0 0015 DAL SS SS19 0 0015 Lab Duplicate DAL SS SS19 0 0015 Lab Matrix Spike DAL SS SS20 0 0015 DAL SS SS20 0 0015 Lab Duplicate DAL SS SS20 0 0015 Lab Matrix Spike DAL SS SS14 0 0015 DAL SS SS14 0 0015 Lab Duplicate DAL SS SS14 0 0015 Lab Matrix Spike DAL SS SS17 0 0015 DAL SS SS17 0 0015 Lab Duplicate DAL SS SS17 0 0015 Lab Matrix Spike DAL SS SS13 0 0015 DAL SS SS13 0 0015 Lab Duplicate DAL SS SS13 0 0015 Lab Matrix Spike Surrogate (13C4-PFOS) Recovery [a] 111% 109% 113% 104% 115% 111% 117% 109% 98.3% 107% 110% 112% 112% 105% 112% 101% 103% 115% 107% 103% 109% 104% 105% 113% 118% 122% 103% 106% 102% 104% 122% 106% 142% 111% 110% 104% 100% 99.0% 115% 109% 110% 102% 106% 108% 108% 109% 102% 103% Actual LMS Spike Conc. (ng/g; dry weight) N/A 18.1 N/A 5.3 N/A 16.6 N/A 23.4 N/A 26.9 N/A 0.918 N/A 4.69 N/A 4.14 N/A 4.65 N/A 0.843 N/A 21.3 N/A 4.86 N/A 1.05 N/A 1.19 N/A 1.15 N/A 6.73 Measured PFBS Concentration (ng/g; dry weight) 7.02 8.11 29.8 6.27 5.27 10.3 13.1 12.7 31.2 13.7 14.3 37.3 7.60 9.41 45.0 0.585 0.519 1.63 0.593 0.739 5.54 1 .0 2 1.04 5.27 2.99 2.75 8.57 BLQ BLQ 0.830 10.7 1 0 .6 36.2 1.82 1.85 7.01 0.481 0.486 1.82 BLQ BLQ 1 .6 8 0.872 0.901 2 .2 0 1.46 1.50 8.72 RPD / LMS Recover y (%) 14% 123% 17% 86.3% 3.5% 111% 4.5% 99.8% 21% 136% 12% 117% 22% 104% 1.7% 102% 8.4% 123% N/A 98.5% 1 .0 % 120% 1.4% 107% 1 .0 % 127% N/A 141% 3.2% 114% 2.5% 108% Average PFBS Conc. (ng/g; dry wt.) 7.57 N/A 5.77 N/A 12.9 N/A 14.0 N/A 8.50 [b] N/A 0.552 N/A 0 . 6 6 6 [c] N/A 1.03 N/A 2.87 N/A BLQ N/A 10.7 N/A 1.84 N/A 0.483 N/A BLQ [b] N/A 0 .8 8 6 N/A 1.48 N/A 3M Study GLP10-01-02-15 Page 43 of 514 Study: GLP10-01-02, Interim Report 15 Analysis for PFOS, PFHS and PFBS in Avenue A Soils/Sediments Collected January 2011 Table 16. Individual PFBS Results for Decatur, AL Avenue A Soils & Sediments, January 2011 LIMS Sample ID Sample Description Surrogate (13C4-PFOS) Recovery [a] Actual LMS Spike Conc. (ng/g; dry weight) Measured PFBS Concentration (ng/g; dry weight) RPD / LMS Recover y (%) Average PFBS Conc. (ng/g; dry wt.) GLP10-01-01-15-090 GLP10-01-01-15-090 Dup DAL SS SS15 0 0015 DAL SS SS15 0 0015 Lab Duplicate 103% 94.3% N/A 0.269 BLQ N/A 0.269 [b. d] GLP10-01-01-15-090 LMS DAL SS SS15 0 0015 Lab Matrix Spike 106% 1.09 1.58 145% N/A GLP10-01-01-15-091 GLP10-01-01-15-091 Dup DAL SS SS18 0 0015 DAL SS SS18 0 0015 Lab Duplicate 101% 109% N/A 0.235 0.257 9.0% 0.246 GLP10-01-01-15-091 LMS DAL SS SS18 0 0015 Lab Matrix Spike 104% 0.975 1.49 128% N/A GLP10-01-01-15-092 GLP10-01-01-15-092 Dup DAL SS SS11 0 0015 DAL SS SS11 0 0015 Lab Duplicate 108% 97.7% N/A BLQ BLQ N/A BLQ [b] GLP10-01-01-15-092 LMS DAL SS SS11 0 0015 Lab Matrix Spike 108% 1.06 1.46 138% BLQ; Analyte/IS peak area response ratio was less than that of the lowest acceptable standard in the curve and was nominal 0.200 ng/g Values are shown at 3 significant figures, but more precise data was used for data calculations. All results were reported from the least diluted sample that fell within the range of the calibration curve. NR; not reportable due to QC failure [a] RPD for duplicate results was greater than 50% [b] LMS recovery was outside of 100 + 30%, but within reporting limits of 100 + 50% [c] Result determined from a reassay result when original results were NR, surrogate recovery result is shown from original result. [d] Result reported from one value when duplicate value was BLQ.___________________________________________________________ N/A 8 Conclusion Quantitative analysis for PFOS, PFHS and FPBS in the Avenue A soils and sediments collected at the Decatur, AL site in January 2011 was successfully completed following 3M Environmental Laboratory method ETS-8-053.0. The average PFOS, PFHS and PFBS concentration results are summarized in Table 1 and the LMS recoveries are summarized in Table 2. The PFOS, PFHS and PFBS results for the individual sample replicates that were analyzed are shown in Table 14, Table 15 and Table 16, respectively. The overall results showed that PFOS was the dominant analyte measured in each of the environmental samples, typically followed by PFHS and then PFBS 9 Data/Sample Retention All samples and associated project data (hardcopy and electronic) will be archived according to 3M Environmental Laboratory standard operating procedures. 10 List of Attachments Attachment A: Raw Data; Chromatograms and Preparation Forms 3M Study GLP10-01-02-15 Page 44 of 514 Study: GLP10-01-02, Interim Report 15 Analysis for PFOS, PFHS and PFBS in Avenue A Soils/Sediments Collected January 2011 11 Signatures Report Approval: Cleston C. Lange, Ph.D., Principal Analytical Investigator '/z -l/z a / Date William K. Reagen, Ph.D., 3M Environmental Laboratory Management Date 3M Study GLP10-01-02-15 Page 45 of 514 Study: GLP10-01-02, Interim Report 15 Analysis for PFOS, PFHS and PFBS in Avenue A Soils/Sediments Collected January 2011 Attachment A Raw Data, Chromatograms (Partial Set), Preparation Forms and Correspondence 3M Study GLP10-01-02-15 Page 46 of 514 3M Environmental Laboratory Note to File Project or Study Number: GLP10-01-02-15 L IM S N u m b er: GLP10-01-02-15 A ffe c te d D ata: All data Sample Name s ll0 3 1 7 a 0 0 1 s ll0 3 1 7 a 0 0 2 s ll0 3 1 7 a 0 0 3 sll0317a004 sll0317a005 s ll0 3 1 7 a 0 0 6 s ll0 3 1 7 a 0 0 7 sl!0317a008 s ll0 3 1 7 a 0 0 9 s ll0 3 1 7 a 0 1 0 s ll0 3 1 7 a 0 1 1 Sll0317a012 s ll0 3 1 7 a 0 1 3 sll0317a014 sll0317a015 s ll0 3 1 7 a 0 1 6 s ll0 3 1 7 a 0 1 7 sll0317a018 s!10317a019 s ll0 3 1 7 a 0 2 0 sll0317a021 sll0317a022 s ll0 3 1 7 a 0 2 3 s ll0 3 1 7 a 0 2 4 sll0317a02S s ll0 3 1 7 a 0 2 6 s ll0 3 1 7 a 0 2 7 s ll0 3 1 7 a 0 2 8 $110317a029 s ll0 3 1 7 a 0 3 0 sll0317a031 sll0317a032 sll0317a033 sll0317a034 sll0317a035 s ll0 3 1 7 a 0 3 6 s ll0 3 1 7 a 0 3 7 s ll0 3 1 7 a 0 3 8 s ll0 3 1 7 a 0 3 9 s ll0 3 1 7 a 0 4 0 s ll0 3 1 7 a 0 4 1 s ll0 3 1 7 a 0 4 2 sll0317a043 sll0317a044 sll0317a045 sll0317a046 sll0317a047 s ll0 3 1 7 a 0 4 8 sll0317a049 sll0317a050 sll0317a051 sll0317a052 s ll0 3 1 7 a 0 5 3 $110317a054 sll0317a055 s ll0 3 1 7 a 0 5 6 sll0317a057 sll0317a058 sll0 3 1 7 a 0 S 9 S ll0 31 7 a0 60 sll0317a061 sll0317a062 sll0317a063 sll0317a064 s ll0 3 1 7 a 0 6 5 sll0317a066 $110317a067 sll0317a068 sll0317a069 s ll0 3 1 7 a 0 7 0 sl!0317a071 s ll0 3 1 7 a 0 7 2 $110317a073 sll0317a074 sll0317a075 s ll0 3 1 7 a 0 7 6 sll0317a077 sll0317a078 sll0317a079 sll0317a080 sll0317a081 sll0317a082 s ll0 3 1 7 a 0 8 3 sll0317a084 sll0317a08S s ll0 3 1 7 a 0 8 6 sll0317a087 Sample ID 10 006*80 solvent blank 10 006-80 solvent blank EC-110316*09 SO ng W arm up standard EC-110316-09 50 ng W arm up standard 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank EC-110316-010.2 ng Extracted Curve Point EC-110316-02 0.5 ng Extracted Curve Point EC-110316-03 0.75 ng Extracted Curve Point EC-110316-04 1 ng Extracted Curve Point EC-110316-05 2.5 ng Extracted Curve Point EC-110316-06 5 ng Extracted Curve Point EC-110316-07 10 ng Extracted Curve Point EC-110316-08 25 ng Extracted Curve Point EC-110316-09 50 ng Extracted Curve Point EC-110316-10 100 ng Extracted Curve Point EC-110316-11 200 ng Extracted Curve Point EC-110316-12 500 ng Extracted Curve Point 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank MB-110316-01 M ethod Blank w /o IS MB-110316-02 M ethod Blank w /o IS MB-110316-03 M ethod Blank w /o IS MB-110316-04 M ethod Blank w / IS MB-110316-05 M ethod Blank w / IS MB-110316-06 M ethod Blank w / IS MB-110316-07 M ethod Blank w / IS fo r dilutions MB-110316-08 M ethod Blank w / IS fo r dilutions MB-110316-09 M ethod Blank w / IS fo r dilutions MB-110316-10 M ethod Blank w / IS fo r dilutions MB-110316-11 Method Blank w / IS fo r dilutions MB-110316-12 M ethod Blank w / IS fo r dilutions ICS-110316-013 ng LCS in TCR-842 LCS-110316-02 3 ng LCS in TCR-842 LCS-110316-03 3 ng LCS in TCR-842 10 006-80 solvent blank EC-110316-05 2.5 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-001 DAL SS SS T rlp l 0 0000 GLP10-01-01-15-001 Dup DAL SS SS T rip l 0 0000 Lab Duplicate GLP10-01-01-15-001LMS DAL SS SS T rip l 0 0000 Lab M a trix Spike GLP10-01-01-15-083 DAL SS Trip2 0 0000 GLP10-01-01-15-083 Dup DAL SS Trip2 0 0000 Lab Duplicate GLP10-01-01-15-083 LMS DAL SS Trip2 0 0000 Lab M a trix Spike GLP10-01-01-15-002 DAL SS SS12 0 0000 GLP10-01-01-15-002 Dup DAL SS SS12 0 0000 Lab Duplicate GLP10-01-01-15-002 LMS DAL SS SS12 0 0000 Lab M a trix Spike GLP10-01-01-15-003 DAL SS SS12 0 0005 GLP10-01-01-15-003 Dup DAL SS SS12 0 0005 Lab Duplicate GLP10-01-01-15-003 LMS DAL SS SS12 0 0005 Lab M a trix Spike GLP10-01-01-15-004 DAL SS SS13 0 0000 GLP10-01-01-15-004 Dup DAL SS SS13 0 0000 Lab Duplicate GLP10-01-01-15-004 LMS DAL SS SS13 0 0000 Lab M a trix Spike 10 006-80 solvent blank EC-110316-06 5 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-005 DAL SS SS16 0 0000 GLP10-01-01-1S-005 Dup DAL SS SS16 0 0000 Lab Duplicate GLP10-01-01-1S-005 LMS DAL SS SS16 0 0000 Lab M a trix Spike GLP10-01-01-15-006 DAL SS SS16 DB 0000 GLP10-01-01-15-006 Dup DAL SS SS16 DB 0000 Lab Duplicate GLP10-01-01-15-006 LMS DAL SS SS16 DB 0000 Lab M a trix Spike GLP10-01-01-15-007 DAL SS SS110 0000 GLP10-01-01-15-007 Dup DAL SS SS110 0000 Lab Duplicate GLP10-01-01-15-007 LMS DAL SS SS110 0000 Lab M a trix Spike GLP10-01-01-15-008 DAL SS SS110 0005 GLP10-01-01-15-008 Dup DAL SS SS110 0005 Lab Duplicate GLP10-01-01-15-008 LMS DAL SS SS110 0005 Lab M a trix Spike GLP10-01-01-15-009 DAL SS SS20 0 0000 GLP10-01-01-15-009 Dup DAL SS SS20 0 0000 Lab Duplicate GLP10-01-01-15-009 LMS DAL SS SS20 0 0000 Lab M a trix Spike 10 006-80 solvent blank EC-110316-07 10 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-010 DAL SS SS20 DB 0000 GLP10-01-01-15-010 Dup DAL SS SS20 DB 0000 Lab Duplicate GLP10-01-01-15-010 LMS DAL SS SS20 DB 0000 Lab M a trix Spike GLP10-01-01-15-011 DAL SS SS19 0 0000 GLP10-01-01-15-011 Dup DAL SS SS19 0 0000 Lab Duplicate GLP10-01-01-15-011 LMS DAL SS SS19 0 0000 Lab M a trix Spike GLP10-01-01-15-012 DAL SS SS19 0 0005 GLP10-01-01-15-012 Dup DAL SS SS19 0 0005 Lab Duplicate 3M Study GLP10-01-02-15 s110317a Analyte Peak Name MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS Calculated Concentration Accuracy Record (n g /m L) (%) M odified File Name N/A N/A N/A N/A 0 sll0317a.w iff 0 sll0317a.w iff N/A N/A 0 sll0317a.w iff N/A N/A N/A N/A 0 sll0317a.w iff 0 sll0317a.w iff N/A N/A 0 sll0317a.w !ff N/A N/A N/A N/A N/A N/A 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0.153 79.9 0 sll0317a.w iff 0.477 99.8 0 sll0317a.w iff 0.682 0.988 2.58 95.1 103 108 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 4.95 103 0 sll0317a.w iff 9.54 26.2 49.6 99.8 109 104 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 97.8 102 0 sll0317a.w iff 181 94.6 0 sll0317a.w (ff 482 101 0 sll0317a.w iff N/A N/A 0 sll0317a.w iff N/A N/A 0 sll0317a.w iff N/A N/A 0 sll0317a.w iff N/A N/A N/A N/A N/A N/A 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff N/A N/A 0 sll0317a.w iff 3.36 N/A 0 sll0317a.w iff 3.06 N/A 3.23 N/A 0 sll0317a.w iff 0 sll0317a.w iff 3 N/A 2.82 N/A 0 sll0317a.w iff 0 sll0317a.w iff 3.31 N/A 2.89 N/A 0 sll0317a.w iff 0 sll0317a.w iff 2.96 N/A 2.96 N/A 0 sll0317a.w iff 0 sll0317a.w iff 3.19 N/A 3.1 N/A 0 sll0317a.w iff 0 sll0317a.w iff 2.97 N/A 0 sll0317a.w iff N/A N/A 0 sll0317a.w iff 2.37 99 0 sll0317a.w iff N/A N/A 0 sll0317a.w iff 2.93 N/A 0 sll0317a.w iff 3.09 N/A 0 sll0317a.w iff 3.17 N/A 0 sll0317a.w iff 3.15 N/A 0 sll0317a.w iff 3.04 N/A 0 sll0317a.w iff 3.1 N/A 3.53 N/A 3.29 N/A 4.44 N/A 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 3.83 N/A 0 sll0317a.w iff 3.72 N/A 0 sll0317a.w iff 4.44 N/A 3.13 N/A 3.41 N/A 0 sll0317a.w iff 0 $110317a.wiff 0 sll0317a.w iff 3.15 N/A 0 sll0317a.w iff N/A N/A 5.06 106 N/A N/A 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 2.82 N/A 0 sll0317a.w iff 3.03 N/A 3.2 N/A 0 sll0317a.w lff 0 sll0317a.w iff 3.1 N/A 0 sll0317a.w iff 3.14 N/A 0 sll0317a.w iff 3.13 N/A 0 sll0317a.w iff 3.11 N/A 2.88 N/A 0 sll0317a.w iff 0 sll0317a.w iff 2.93 N/A 3.87 N/A 0 sll0317a.w iff 0 sll0317a.w iff 3.17 N/A 2.79 N/A 3.12 N/A 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 3.3 N/A 0 sll0317a.w iff 3.21 N/A N/A N/A 10 105 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff N/A N/A 0 sll0317a.w iff 3.06 N/A 2.86 N/A 0 sll0317a.w iff 0 sll0317a.w iff 3.23 N/A 3.09 N/A 3.09 N/A 2.99 N/A 2.97 N/A 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 3.1 N/A 0 sll0317a.w iff Page 1 of 8 sll0317a088 sll0317a089 sll0317a090 sll0317a091 sll0317a092 sll0317a093 sll0317a094 s ll0 3 1 7 a 0 9 5 sll0317a096 sll0317a097 sll0317a098 sll0317a099 s ll0 3 1 7 a l0 0 s ll0 3 1 7 a l0 1 s ll0 3 1 7 a l0 2 s ll0 3 1 7 a l0 3 sX10317al04 sll0 3 17 a l05 s ll0 3 1 7 a l0 6 s ll0 3 1 7 a l0 7 s ll0 3 1 7 a l0 8 s ll0 3 1 7 a l0 9 s ll0 3 1 7 a ll0 s ll0 3 1 7 a lll s ll0 3 1 7 a ll2 s ll0 3 1 7 a ll3 sll0 3 1 7 a ll4 sll0 3 1 7 a ll5 s ll0 3 1 7 a ll6 sll0 3 1 7 a ll7 sll0 3 1 7 a ll8 sll0 3 1 7 a ll9 sll0 3 17 a l20 s l!0 3 1 7 a l2 1 s ll0 3 1 7 a !2 2 s ll0 3 1 7 a l2 3 sll0 3 17 a l24 sll0 3 17 a l25 s ll0 3 1 7 a l2 6 s ll0 3 1 7 a l2 7 s l!0 3 1 7 a l2 8 s ll0 3 1 7 a l2 9 s ll0 3 1 7 a l3 0 s!10317al31 sll0 3 17 a l32 sll0 3 17 a l33 s ll0 3 1 7 a !3 4 s ll0 3 1 7 a l3 5 s ll0 3 1 7 a l3 6 s l!0 3 1 7 a l3 7 sll0 3 17 a l38 sll0 3 17 a l39 sll0 3 17 a l40 sll0 3 17 a l41 sll0 3 17 a l42 sll0 3 17 a l43 sll0 3 17 a l44 s ll0 3 1 7 a l4 5 sll0 3 17 a l46 sll0 3 17 a l47 s ll0 3 1 7 a l4 8 $ 1 1 0 3 1 7 a l4 9 s ll0 3 1 7 a l5 0 s ll0 3 1 7 a l5 1 s ll0 3 1 7 a l5 2 sll0317alS 3 s!10317al54 s ll0 3 1 7 a l5 5 sll0317alS 6 sll0317alS 7 s ll0 3 1 7 a l5 8 sll0317alS 9 s ll0 3 1 7 a l6 0 s ll0 3 1 7 a l6 1 s ll0 3 1 7 a l6 2 s ll0 3 1 7 a l6 3 sll0317a001 sll0317a002 sll0317a003 sll0317a004 sll0317aO0S s ll0 3 1 7 a 0 0 6 sll0317a007 sll0317a008 sll0317a009 sll0317a010 sll0317a011 s ll0 3 1 7 a 0 1 2 s ll0 3 1 7 a 0 1 3 sl!0317a014 s!10317a015 GLP10-01-01-15-012 LMS DAL SS SS19 0 0005 Lab M a trix Spike GLP10-01-01-15-014 DAL SS SS15 0 0000 GLP10-01-01-15-014 Dup DAL SS SS15 0 0000 Lab Duplicate GLP10-01-01-15-014 LMS DAL SS SS15 0 0000 Lab M a trix Spike GLP10-01-01-15-015 DAL SS SS17 0 0000 GLP10-01-01-15-015 Dup DAL SS SS17 0 0000 Lab Duplicate GLP10-01-01-15-015 LMS DAL SS SS17 0 0000 Lab M a trix Spike 10 006-80 solvent blank EC-110316-05 2,5 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-016 DAL SS SS14 0 0000 GLP10-01-01-15-016 Dup DAL SS SS14 0 0000 Lab Duplicate GLP10-01-01-15-016 LMS DAL SS SS14 0 0000 Lab M a trix Spike GLP10-01-01-15-018 DAL SS SS18 0 0000 GLP10-01-01-15-018 Dup DAL SS SS18 0 0000 Lab Duplicate GLP10-01-01-15-018 LMS DAL SS SS18 0 0000 Lab M a trix Spike GLP10-01-01-15-020 DAL SS SS10 0 0000 GLP10-01-01-15-020 Dup DAL SS SS10 0 0000 Lab Duplicate GLP 10-01-01-15-020 LMS DAL SS SS10 0 0000 Lab M a trix Spike GLP10-01-01-15-021 DAL SS SS30 0 0000 GLP10-01-01-15-021 Dup DAL SS SS30 0 0000 Lab Duplicate GLP10-01-01-15-021 LMS DAL SS SS30 0 0000 Lab M a trix Spike GLP10-01-01-15-022 DAL SS SS30 0 0005 GLP10-01-01-15-022 Dup DAL SS SS30 0 0005 Lab Duplicate GLP10-01-01-15-022 LMS DAL SS SS30 0 000S Lab M a trix Spike 10 006-80 solvent blank EC-110316-06 5 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-023 DAL SS SS30 0 0015 GLP10-01-01-1S-023 Dup DAL SS SS30 0 0015 Lab Duplicate GLP10-01-01-15-023 LMS DAL SS SS30 0 0015 Lab M a trix Spike GLP10-01-01-15-024 DAL SS SS25 0 0000 GLP10-01-01-15-024 Dup DAL SS SS25 0 0000 Lab Duplicate GLP10-01-01-1S-024 LMS DAL SS SS25 0 0000 Lab M a trix Spike GLP10-01-OMS-025 DAL SS SS25 0 0005 GLP10-01-01-15-025 Dup DAL SS SS25 0 0005 Lab Duplicate GLP10-01-01-15-02S LMS DAL SS SS25 0 0005 Lab M a trix Spike GLP10-01-01-15-026 DAL SS SS25 0 0015 GLP10-01-01-15-026 Dup DAL SS SS25 0 0015 Lab Duplicate GLP10-01-01-15-026 LMS DAL SS SS25 0 0015 Lab M a trix Spike GLP10-01-01-15-027 DAL SD SD22 0 0000 GLP10-01-01-15-027 Dup DAL SD SD22 0 0000 Lab Duplicate GLP10-01-01-15-027 LMS DAL SD SD22 0 0000 Lab M a trix Spike 10 006-80 solvent blank EC-110316-07 10 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-028 DAL SD SD22 0 0005 GLP 10-01-01-15-028 Dup DAL SD SD22 0 0005 Lab Duplicate GLP10-01-01-15-028 LMS DAL SD 5D22 0 0005 Lab M a trix Spike GLP10-01-01-15-029 DAL SD SD22 DB 0005 GLP10-01-01-15-029 Dup DAL SD SD22 DB 000S Lab Duplicate GLP10-01-01-15-029 LMS DAL SD SD22 DB 0005 Lab M a trix Spike GLP10-01-01-15-030 DAL SO SD22 0 0015 GLP10-01-01-15-030 Dup DAL SD SD22 0 0015 Lab Duplicate GLP10-01-01-15-030 LMS DAL SD SD22 0 0015 Lab M a trix Spike GLP10-01-01-15-031 DAL SD SD21 0 0000 GLP10-01-01-15-031 Dup DAL SD SD210 0000 Lab Duplicate GLP10-01-01-15-031 LMS DAL SD SD210 0000 Lab M a trix Spike GLP10-01-01-15-032 DAL SD SD210 0005 GLP10-01-01-15-032 Dup DAL SD SD210 0005 Lab Duplicate GLP10-01-01-15-032 LMS DAL SD SD210 0005 Lab M a trix Spike 10 006-80 solvent blank EC-110316-05 2.5 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-033 DAL SD SD210 0015 GLP10-01-01-15-033 Dup DAL SD SD210 0015 Lab Duplicate GLP10-01-01-15-033 LMS DAL SD SD210 0015 Lab M a trix Spike GLP10-01-01-15-034 DAL SS SS24 0 0000 GLP10-01-01-15-034 Dup DAL SS SS24 0 0000 Lab Duplicate GLP10-01-01-15-034 LMS DAL SS SS24 0 0000 Lab M a trix Spike GLP10-Q1-01-15-035 DAL SS SS24 0 0005 GLP10-01-01-15-035 Dup DAL SS SS24 0 0005 Lab Duplicate GLP10-01-01-1S-035 LMS DAL SS SS24 0 0005 Lab M a trix Spike 10 006-80 solvent blank EC-110316-06 5 ng Extracted Curve Point 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank EC-110316-09 50 ng W arm up standard EC-110316-09 50 ng W arm up standard 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank EC-110316-010.2 ng Extracted Curve Point EC-110316-02 0.5 ng Extracted Curve Point EC-110316-03 0.7S ng Extracted Curve Point EC-110316-04 1 ng Extracted Curve Point EC-110316-05 2.5 ng Extracted Curve Point EC-110316-06 5 ng Extracted Curve Point 3M Study GLP10-01-02-15 s110317a MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 3.29 N/A 3.07 N/A 3.03 N/A 2.83 N/A 3.07 N/A 2.95 N/A 2.92 N/A N/A 2.63 110 N/A 2.84 N/A 3.51 N/A 3.49 N/A 3.08 N/A 2.98 N/A 2.99 N/A 3.35 N/A 3.11 N/A 3.86 N/A 3.05 N/A 3.07 N/A 3.59 N/A 3.12 N/A 3.2S N/A 3.34 N/A N/A 4.86 102 N/A 3.04 N/A 3.13 N/A 3.17 N/A 3.42 N/A 3.42 N/A 3.71 N/A 3.39 N/A 3.23 N/A 4.08 N/A 3.72 N/A 3.3 N/A 3.67 N/A 3.48 N/A 3.34 N/A 3.92 N/A N/A 9.56 100 N/A 3.22 N/A 2.92 N/A 2.96 N/A 3.29 N/A 2.93 N/A 3.04 N/A 3.24 N/A 3.14 N/A 2.98 N/A 3.15 N/A 3.73 N/A 4.32 N/A 3.34 N/A 3.39 N/A 3.41 N/A N/A 2.67 112 N/A 3.01 N/A 3.12 N/A 3.14 N/A 3.12 N/A 3.35 N/A 3.15 N/A 3.4 N/A 3.45 N/A 3.89 N/A N/A 5.17 108 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 0.189 94.7 0.455 91 0.789 105 0.946 94.7 2.58 103 5.19 104 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w lff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 5110317a.wiff 0 sll0317a.w iff 1 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w lff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w fff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 5110317a.wiff 0 5110317a.wiff 0 5110317a.wiff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sl!0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff Page 2 of 8 Page 49 of 514 s l!0 3 1 7 a 0 1 6 sll0317a017 sll0317a018 sll0317a019 sll0317a020 $110317a021 sll0317a022 sll0317a023 sll0317a024 sll0317a025 s ll0 3 1 7 a 0 2 6 sll0317a027 sll0317a028 sll0317a029 sll0317a030 sll0317a031 sll0317a032 sll0317a033 sll0317a034 sll0317a035 s ll0 3 1 7 a 0 3 6 sll0317a037 sll0317a038 sll0317a039 sll0317a040 sll0317a041 s ll0 3 1 7 a 0 4 2 s ll0 3 1 7 a 0 4 3 s ll0 3 1 7 a 0 4 4 sll0317a045 s ll0 3 1 7 a 0 4 6 s ll0 3 1 7 a 0 4 7 Sll0317a048 s!10317a049 s ll0 3 1 7 a 0 5 0 sll0317a051 sll0317a052 sll0317a053 sll0317a054 sll0317a055 s ll0 3 1 7 a 0 5 6 sll0317a057 sll0317a058 sll0317a059 sll0317a060 s ll0 3 1 7 a 0 6 1 s ll0 3 1 7 a 0 6 2 sll0317a063 sll0317a064 sll0317a065 s ll0 3 1 7 a 0 6 6 sll0317a067 sll0317a068 sll0317a069 sll0317a070 sll0317a071 sll0317a072 sll0317a073 s ll0 3 1 7 a 0 7 4 sll0317a075 sll0317a076 s ll0 3 1 7 a 0 7 7 sll0317a078 sll0317a079 sll0317a080 sll0317a081 sll0317a082 s ll0 3 1 7 a 0 8 3 sll0317a084 sll0317a085 s ll0 3 1 7 a 0 8 6 sll0317a087 s ll0 3 1 7 a 0 8 8 s ll0 3 1 7 a 0 8 9 s ll0 3 1 7 a 0 9 0 sll0317a091 sll0317a092 s ll0 3 1 7 a 0 9 3 sll0317a094 sll0317a095 s ll0 3 1 7 a 0 9 6 s!10317a097 sll0317a098 sll0317a099 s ll0 3 1 7 a l0 0 s ll0 3 1 7 a l0 1 s ll0 3 1 7 a l0 2 s ll0 3 1 7 a l0 3 s ll0 3 1 7 a l0 4 s ll0 3 1 7 a l0 5 s ll0 3 1 7 a l0 6 EC-110316-07 10 ng Extracted Curve Point EC-110316-08 25 ng Extracted Curve Point EC-110316-09 50 ng Extracted Curve Point EC-110316-10 100 ng Extracted Curve Point EC-110316-11 200 ng Extracted Curve Point EC-110316-12 500 ng Extracted Curve Point 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank M 8-110316-01 M ethod Blank w /o IS M8-110316-02 M ethod Blank w /o IS MB-110316-03 M ethod Blank w /o IS MB-110316-04 M ethod Blank w / IS MB-110316-05 M ethod Blank w / IS MB-110316-06 M ethod Blank w / IS MB-110316-07 M ethod Blank w / IS fo r dilutions MB-110316-08 M ethod Blank w / IS fo r dilutions MB-110316-09 M ethod Blank w / IS fo r dilutions MB-110316-10 M ethod Blank w / IS fo r dilutions MB-110316-11 M ethod Blank w / IS fo r dilutions MB-110316-12 M ethod Blank w / IS fo r dilutions LCS-110316-01 3 ng LCS in TCR-842 LCS-110316-02 3 ng LCS in TCR-842 LCS-110316-03 3 ng LCS in TCR-842 10 006-80 solvent blank EC-110316-05 2.5 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-001 DAL SS SS T rip l 0 0000 GLP10-01-01-15-001 Dup DAL SS SS T rip l 0 0000 Lab Duplicate GLP10-01-01-15-001 LMS DAL SS SS T rip l 0 0000 Lab M a trix Spike GLP10-01-01-15-083 DAL SS Trip2 0 0000 GLP10-01-01-15-083 Dup DAL SS Trip2 0 0000 Lab Duplicate GLP10-01-01-15-083 LMS DAL SS Trip2 0 0000 Lab M a trix Spike GLP10-01-01-15-002 DAL SS SS12 0 0000 GLP10-01-01-15-002 Dup DAL SS SS12 0 0000 Lab Duplicate GLP10-01-Q1-15-002 LMS DAL SS SS12 0 0000 Lab M atrix Spike GLP10-01-01-15-003 DAL SS SS12 0 0005 GLP10-01-01-15-003 Dup DAL SS SS12 0 O00S Lab Duplicate GLP10-01-01-15-003 LMS DAL SS SS12 0 0005 Lab M a trix Spike GLP10-01-01-15-004 DAL SS SS13 0 0000 GLP10-01-01-15-004 Dup DAL SS SS13 0 0000 Lab Duplicate GLP10-01-01-15-004 LMS DAL SS SS13 0 0000 Lab M atrix Spike 10 006-80 solvent blank EC-110316-06 5 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-005 DAL SS SS16 0 0000 GLP10-01-01-15-005 Dup DAL SS SS16 0 0000 Lab Duplicate GLP10-01-01-15-005 LMS DAL SS SS16 0 0000 Lab M a trix Spike GLP10-01-01-15-006 DAL SS SS16 DB 0000 GLP10-01-01-15-006 Dup DAL SS SS16 DB 0000 Lab Duplicate GLP10-01-01-15-006 LMS DAL SS SS16 DB 0000 Lab M a trix Spike GLP10-01-01-15-007 DAL SS SS110 0000 GLP10-01-01-15-007 Dup DAL SS SS110 0000 Lab Duplicate GLP10-01-01-15-007 LMS DAL SS SS110 0000 Lab M a trix Spike GLP10-01-01-15-008 DAL SS SS110 0005 GLP10-01-01-15-008 Dup DAL SS SS110 0005 Lab Duplicate GLP10-01-01-15-008 LMS DAL SS SS110 0005 Lab M a trix Spike GLP10-01-01-15-009 DAL SS SS20 0 0000 GLP10-01-01-15-009 Dup DAL SS SS20 0 0000 Lab Duplicate GLP10-01-01-15-009 LMS DAL SS SS20 0 0000 Lab M a trix Spike 10 006-80 solvent blank EC-110316-07 10 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-010 DAL SS SS20 DB 0000 GLP10-01-01-15-010 Dup DAL SS SS20 DB 0000 Lab Duplicate GLP10-01-01-15-010 LMS DAL SS SS20 DB 0000 Lab M atrix Spike GLP10-01-01-15-011 DAL SS SS19 0 0000 GLP10-01-01-15-011 Dup DAL SS SS19 0 0000 Lab Duplicate GLP10-01-01-15-011 LMS DAL SS SS19 0 0000 Lab M a trix Spike GLP10-01-01-15-012 DAL SS SS19 0 0005 GLP10-01-01-15-012 Dup DAL SS SS19 0 0005 Lab Duplicate GLP10-01-01-15-012 LMS DAL SS SS19 0 0005 Lab M atrix Spike GLP10-01-01-15-014 DAL SS SS15 0 0000 GLP10-01-01-15-014 Dup DAL SS SS15 0 0000 Lab Duplicate GLP10-01-01-15-014 LMS DAL SS SS15 0 0000 Lab M a trix Spike GLP10-01-01-15-015 DAL SS SS17 0 0000 GLP10-01-01-15-015 Dup DAL SS SS17 0 0000 Lab Duplicate GLP10-01-01-15-015 LMS DAL SS SS17 0 0000 Lab M a trix Spike 10 006-80 solvent blank EC-110316-05 2.5 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-016 DAL SS SS14 0 0000 GLP10-01-01-15-016 Dup DAL SS SS14 0 0000 Lab Duplicate GLP10-01-01-15-016 LMS DAL SS SS14 0 0000 Lab M a trix Spike GLP10-01-01-15-018 DAL SS SS18 0 0000 GLP10-01-01-15-018 Dup DAL SS SS18 0 0000 Lab Duplicate GLP10-01-01-15-018 LMS DAL SS SS18 0 0000 Lab M a trix Spike GLP10-01-01-15-020 DAL SS SS10 0 0000 GLP10-01-01-15-020 Dup DAL SS SS10 0 0000 Lab Duplicate GLP10-01-01-15-020 LMS DAL SS SS10 0 0000 Lab M a trix Spike 3M Study GLP10-01-02-15 s110317a PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS N/A N/A N/A N/A N/A N/A N/A <0 <0 <0 <0 <0 <0 <0 <0 <0 N/A N/A <0 <0 <0 <0 N/A N/A N/A N/A N/A N/A 10.1 102 26.1 104 52.4 105 97.8 97.9 196 98.1 502 100 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 2.98 N/A 3.12 N/A 3.28 N/A N/A 2.45 97.9 N/A N/A N/A 0.982 N/A N/A N/A 0.984 N/A 2.41 N/A 1.79 N/A 8,45 N/A 9.18 N/A 6 N/A 33.1 N/A 0.86 N/A 1.07 N/A 3.59 N/A N/A 5.42 108 N/A 8.18 N/A 8.04 N/A 35.8 N/A 10.3 N/A 7.84 N/A 38.1 N/A 1.02 N/A 0.813 N/A 2.1 N/A 25.9 N/A 0.719 N/A 6.23 N/A 0.425 N/A 0.374 N/A 1.56 N/A N/A 9.69 97 N/A 0.358 N/A 0.354 N/A 1.84 N/A 0.347 N/A 0.369 N/A 1.56 N/A 1.53 N/A 1,42 N/A 7.06 N/A 0.276 N/A 0.37 N/A 1.66 N/A 0.311 N/A 0.269 N/A 1.58 N/A N/A 2.57 103 N/A 0.604 N/A 0.705 N/A 1.76 N/A 0.846 N/A 1.71 N/A 2.16 N/A 2.49 N/A 3.49 N/A 11.9 N/A 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 1 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 1 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 1 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 1 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 1 sll0317a.w iff 1 sl!0317a.w iff 1 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 1 sll0317a.w lff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 5110317a.wiff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sl!0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 1 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a,w iff 0 sll0317a.w iff 1 sll0317a.w iff 0 sll0317a.w iff 0 5110317a.wiff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 1 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 1 5110317a.wiff 1 sll0317a.w iff 0 sll0317a.w iff 1 sll0317a.w iff 0 sll0317a.w iff 1 sll0317a.w iff 0 sll0317a.w iff 0 5110317a,wiff 0 sll0317a.w iff 0 sll0317a.w iff 0 5110317a.wiff 1 sll0317a.w iff 1 sll0317a.w iff 0 5110317a.wiff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 1 5110317a.wiff Page 3 of 6 Page 50 of 514 s ll0 3 1 7 a l0 7 s ll0 3 1 7 a l0 8 s ll0 3 1 7 a l0 9 s ll0 3 1 7 a ll0 s ll0 3 1 7 a lll s ll0 3 1 7 a ll2 s ll0 3 1 7 a ll3 s ll0 3 1 7 a ll4 s ll0 3 1 7 a ll5 s ll0 3 1 7 a ll6 sl!0 3 1 7 a ll7 s ll0 3 1 7 a ll8 s ll0 3 1 7 a ll9 s ll0 3 1 7 a l2 0 sll0 3 17 a l21 sll0 3 17 a l22 s ll0 3 1 7 a l2 3 s ll0 3 1 7 a l2 4 sll0 3 17 a l25 s ll0 3 1 7 a l2 6 s ll0 3 1 7 a l2 7 s ll0 3 1 7 a l2 8 s ll0 3 1 7 a l2 9 s U 0 31 7 al30 sll0 3 17 a l31 $ 1 1 0 3 1 7 a l3 2 s ll0 3 1 7 a l3 3 s ll0 3 1 7 a l3 4 s ll0 3 1 7 a l3 5 s ll0 3 1 7 a l3 6 s ll0 3 1 7 a l3 7 s ll0 3 1 7 a l3 8 s ll0 3 1 7 a l3 9 s ll0 3 1 7 a l4 0 s ll0 3 1 7 a l4 1 s ll0 3 1 7 a l4 2 s ll0 3 1 7 a l4 3 s ll0 3 1 7 a l4 4 sU 0 3 1 7 a l4 5 s ll0 3 1 7 a l4 6 sll0 3 17 a l47 sll0 3 17 a l48 sll0 3 17 a l49 sll0 3 17 a l50 s l!0 3 1 7 a l5 1 sll0 3 17 a l52 sll0 3 17 a l53 sll0 3 17 a l54 sll0 3 17 a l55 sll0317alS 6 sll0 3 17 a l57 sll0 3 17 a l58 sll0 3 17 a l59 s ll0 3 1 7 a l6 0 s ll0 3 1 7 a l6 1 s ll0 3 1 7 a l6 2 sll0 3 17 a l63 s ll0 3 1 7 a 0 0 1 sll0317a002 sll0317a003 sll0317a004 sll0317a00S s ll0 3 1 7 a 0 0 6 sll0317a007 sll0317a008 sll0317a009 sll0317a010 s ll0 3 1 7 a 0 1 1 sll0317a012 sll0317a013 sll0317a014 sll0317a015 s ll0 3 1 7 a 0 1 6 sll0317a017 sll0317a018 sll0317a019 sll0317a020 sll0317a021 sll0317a022 s ll0 3 1 7 a 0 2 3 sll0317a024 s ll0 3 1 7 a 0 2 5 sll0317a026 sll0317a027 sll0317a028 sll0317a029 sll0317a030 sll0317a031 sll0317a032 sll0317a033 sll0317a034 GLP10-01-01-15-021OAL SS SS30 0 0000 GLP10-01-01-15-021 Dup DAL SS SS30 0 0000 Lab Duplicate GLP10-01-01-15-021LMS DAL SS SS30 0 0000 Lab M a trix Spike GLP10-01-01-15-022 DAL SS SS30 0 0005 GLP10-01-01-15-022 Dup DAL SS SS30 0 0005 Lab Duplicate GLP10-01-01-15-022 LMS DAL SS SS30 0 000S Lab M atrix Spike 10 006-80 solvent blank EC-110316-06 5 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-023 DAL SS SS30 0 0015 GLP10-01-01-15-023 Dup DAL SS SS30 0 0015 Lab Duplicate GLP10-01-01-15-023 LMS DAL SS SS30 0 0015 Lab M a trix Spike GLP10-01-01-15-024 DAL SS SS25 0 0000 GLP10-01-01-15-024 Dup DAL SS SS25 0 0000 Lab Duplicate GLP10-01-01-15-024 LMS DAL SS SS25 0 0000 Lab M a trix Spike GLP10-01-01-15-025 DAL SS SS25 0 0005 GLP10-01-01-15-025 Dup DAL SS SS25 0 0005 Lab Duplicate GLP10-01-01-15-025 LMS DAL SS SS2S 0 0005 Lab M a trix Spike GLP10-01-01-15-026 DAL SS SS25 0 0015 GLP10-01-01-15-026 Dup DAL SS SS25 0 0015 Lab Duplicate GLP10-01-01-15-026 LMS DAL SS SS25 0 0015 Lab M a trix Spike GLP10-01-01-15-027 DAL SD SD22 0 0000 GLP10-01-01-15-027 Dup DAL SD SD22 0 0000 Lab Duplicate GLP10-01-01-15-027 LMS DAL SD SD22 0 0000 Lab M a trix Spike 10 006-80 solvent blank EC-110316-07 10 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-1S-028 DAL SD SD22 0 0005 GLP10-01-01-1S-028 Dup DAL SD SD22 0 0005 Lab Duplicate GLP10-01-01-1S-028 LMS DAL SD SD22 0 0005 Lab M a trix Spike GLP10-01-01-1S-029 DAL SD SD22 OB OOOS GLP10-01-01-1S-029 Dup DAL SD SD22 DB 0005 Lab Duplicate GLP10-01-01-15-029 LMS DAL SD SD22 D8 0005 Lab M a trix Spike GLP10-01-01-15-030 DAL SD SD22 0 OOIS GLP10-01-01-15-030 Dup DAL SD SD22 0 0015 Lab Duplicate GLP10-01-01-15-030 LMS DAL SD SD22 0 0015 Lab M a trix Spike GLP10-01-01-15-031 DAL SD SD21 0 0000 GLP10-01-01-15-031 Dup DAL SD SD210 0000 Lab Duplicate GLP10-01-01-15-031 LMS DAL SD SD210 0000 Lab M a trix Spike GLP10-01-01-15-032 DAL SD SD210 0005 GLP10-01-01-15-032 Dup DAL SD SD210 0005 Lab Duplicate GLP10-01-01-15-032 LMS DAL SD SD210 0005 Lab M a trix Spike 10 006-80 solvent blank EC-110316-05 2.5 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-033 DAL SD SD210 0015 GLP10-01-01-15-033 Dup DAL SD SD210 0015 Lab Duplicate GLP10-01-01-15-033 LMS DAL SD SD210 0015 Lab M a trix Spike GLP10-01-01-15-034 DAL SS SS24 0 0000 GLP10-01-01-15-034 Dup DAL SS SS24 0 0000 Lab Duplicate GLP10-01-01-15-034 LMS DAL SS SS24 0 0000 Lab M a trix Spike GLP10-01-01-15-035 DAL SS SS24 0 0005 GLP10-01-01-15-03S Dup DAL SS SS24 0 0005 Lab Duplicate GLP10-01-01-15-035 LMS DAL SS SS24 0 0005 Lab M a trix Spike 10 006-80 solvent blank EC-110316-06 5 ng Extracted Curve Point 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank EC-110316-09 50 ng W arm up standard EC-110316-09 50 ng Warm up standard 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank EC-110316-010.2 ng Extracted Curve Point EC-110316-02 0.5 ng Extracted Curve Point EC-110316-03 0.75 ng Extracted Curve Point EC-110316-04 1 ng Extracted Curve Point EC-110316-05 2.5 ng Extracted Curve Point EC-110316-06 5 ng Extracted Curve Point EC-110316-07 10 ng Extracted Curve Point EC-110316-08 25 ng Extracted Curve Point EC-110316-09 50 ng Extracted Curve Point EC-110316-10 100 ng Extracted Curve Point EC-110316-11200 ng Extracted Curve Point EC-110316-12 500 ng Extracted Curve Point 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank MB-110316-01 M ethod Blank w /o IS MB-110316-02 M ethod Blank w /o IS MB-110316-03 M ethod Blank w /o IS MB-110316-04 M ethod Blank w / IS MB-110316-05 M ethod Blank w / IS MB-110316-06 M ethod Blank w / IS MB-110316-07 M ethod Blank w / IS fo r dilutions MB-110316-08 M ethod Blank w /IS fo r dilutions MB-110316-09 M ethod Blank w / IS fo r dilutions 3M Study GLP10-01-02-15 s110317a PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A <0 <0 <0 0.431 N/A 0.449 N/A 1.6 N/A 0.171 N/A 0.179 N/A 1.48 N/A N/A 5.39 108 N/A 1.03 N/A 1.08 N/A 2.11 N/A 26.2 N/A 39.7 N/A 138 N/A 39.3 N/A 36.2 N/A 146 N/A 47.1 N/A 48.1 N/A 164 N/A 16 N/A 11.7 N/A 42.9 N/A N/A 10.5 105 N/A 11.1 N/A 12.8 N/A 37.6 N/A 11.6 N/A 9.4 N/A 44.4 N/A 7.46 N/A 8.46 N/A 36.1 N/A 7.01 N/A 9.27 N/A 40.2 N/A 12.1 N/A 11.3 N/A 42.3 N/A N/A 2.51 100 N/A 6.67 N/A S.85 N/A 35,2 N/A 5.63 N/A 6.92 N/A 11.7 N/A 19.5 N/A 19.6 N/A 44.1 N/A N/A 5.57 111 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 0.198 99.2 0.444 89 0.781 104 0.997 100 2.44 98 5.1 102 9.97 100 26.5 106 52.2 105 96.5 96.8 197 98.9 500 100 N/A N/A N/A N/A N/A N/A N/A 0.00135 N/A N/A 0.01 N/A N/A 0.00445 N/A N/A 0 sll0317a.w iff 0 sll0317a.w lff 0 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 1 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a,w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w lff 0 sl!0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a,w iff 0 sll0317a.w lff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 $110317a.wiff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 1 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff Page 4 of 8 Page 51 of 514 s ll0 3 1 7 a 0 3 5 sll0317a036 sll0317a037 sll0317a038 sll0317a039 sll0317a040 sll0317a041 sll0317a042 Sll0317a043 s ll0 3 1 7 a 0 4 4 sll0317a04S s l!0 3 1 7 a 0 4 6 s ll0 3 1 7 a 0 4 7 s ll0 3 1 7 a 0 4 8 $110317a049 $110317a050 s ll0 3 1 7 a 0 5 1 s ll0 3 1 7 a 0 5 2 s ll0 3 1 7 a 0 5 3 sll0317a054 sll0317a055 s ll0 3 1 7 a 0 5 6 s ll0 3 1 7 a 0 5 7 sll0317a058 sll0317a059 sll0317a060 s ll0 3 1 7 a 0 6 1 s ll0 3 1 7 a 0 6 2 s ll0 3 1 7 a 0 6 3 s ll0 3 1 7 a 0 6 4 sll0317a065 s ll0 3 1 7 a 0 6 6 sll0317a067 sll0317a068 s ll0 3 1 7 a 0 6 9 sll0317a070 sll0317a071 S ll0 3 1 7 a 0 7 2 sll0317a073 sll0317a074 S ll 0 3 1 7 a 0 7 5 s ll0 3 1 7 a 0 7 6 s ll0 3 1 7 a 0 7 7 sll0317a078 s ll0 3 1 7 a 0 7 9 sll0317a080 sll0317a081 sll0317a082 sll0317a083 sll0317a084 sll0317a085 s ll0 3 1 7 a 0 8 6 s ll0 3 1 7 a 0 8 7 s ll0 3 1 7 a 0 8 8 s ll0 3 1 7 a 0 8 9 s ll0 3 1 7 a 0 9 0 sll0317a091 sll0317a092 sll0317a093 sll0317a094 S ll0 31 7 a0 95 $110317a096 s ll0 3 1 7 a 0 9 7 sll0317a098 s ll0 3 1 7 a 0 9 9 s ll0 3 1 7 a l0 0 s ll0 3 1 7 a l0 1 s ll0 3 1 7 a l0 2 s ll0 3 1 7 a l0 3 s ll0 3 1 7 a !0 4 s ll0 3 1 7 a l0 5 s ll0 3 1 7 a l0 6 s ll0 3 1 7 a l0 7 s ll0 3 1 7 a l0 8 s ll0 3 1 7 a l0 9 s ll0 3 1 7 a ll0 s ll0 3 1 7 a lll s ll0 3 1 7 a ll2 s ll0 3 1 7 a ll3 sll0 3 1 7 a ll4 s ll0 3 1 7 a ll5 s ll0 3 1 7 a ll6 sll0 3 1 7 a ll7 $110317all8 sll0 3 1 7 a l!9 sll0 3 17 a l20 sll0 3 17 a l21 sll0 3 17 a l22 sll0 3 17 a l23 sll0 3 17 a l24 sU 0 3 1 7 a l2 5 MB-110316-10 M ethod Blank w / IS fo r dilutions MB-110316-11 M ethod Blank w / IS fo r dilutions MB-110316-12 M ethod Blank w / IS fo r dilutions LCS-110316-013 ng LCS in TCR-842 LCS-110315-02 3 ng LCS in TCR-842 tCS-110316-03 3 ng LCS in TCR-842 10 006-80 solvent blank EC-110316-05 2.5 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-001 DAL SS SS T rip l 0 0000 GLP10-01-01-15-001 Dup DAL SS SS T rip l 0 0000 Lab Duplicate GLP10-01-01-15-001 LMS DAL SS SS T rip l 0 0000 Lab M a trix Spike GLP10-01-01-15-083 DAL SS Trip2 0 0000 GLP10-01-01-15-083 Dup DAL SS Trip2 0 0000 Lab Duplicate GLP10-01-01-15-083 LMS DAL SS Trip2 0 0000 Lab M a trix Spike GLP10-01-01-15-002 DAL SS SS12 0 0000 GLPIO-Ol-Ol-15-002 Dup DAL SS SS12 0 0000 Lab Duplicate GLP10-01-01-15-002 LMS DAL SS SS12 0 0000 Lab M a trix Spike GLP10-01-01-15-003 DAL SS SS12 0 0005 GLP10-01-01-15-003 Dup DAL SS SS12 0 0005 Lab Duplicate GLP10-01-01-15-003 LMS DAL SS SS12 0 0005 Lab M a trix Spike GLP10-01-01-15-004 DAL SS SS13 0 0000 GLP10-01-01-15-004 Dup DAL SS SS13 0 0000 Lab Duplicate GLP10-01-01-15-004 LMS DAL SS SS13 0 0000 Lab M a trix Spike 10 006-80 solvent blank EC-110316-06 5 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-005 DAL SS SS16 0 0000 GLP10-01-01-15-005 Dup DAL SS SS16 0 0000 Lab Duplicate GLP10-01-01-15-005 LMS DAL SS SS16 0 0000 Lab M a trix Spike GLP10-01-01-15-006 DAL SS SS16 DB 0000 GLPIO-Ol-Ol-15-006 Dup DAL SS SS16 DB 0000 Lab Duplicate GLP10-01-01-15-006 LMS DAL SS SS16 DB 0000 Lab M a trix Spike GLP10-01-01-15-007 DAL SS SS110 0000 GLP10-01-01-15-007 Dup DAL SS SS110 0000 Lab Duplicate GLP10-01-01-15-007 LMS DAL SS SS110 0000 Lab M a trix Spike GLP10-01-01-15-008 DAL SS SS110 0005 GLP10-01-01-15-008 Dup DAL SS SS110 0005 Lab Duplicate GLP10-01-01-15-008 LMS DAL SS SS110 0005 Lab M a trix Spike GLP10-01-01-15-009 DAL SS SS20 0 0000 GLP10-01-01-15-009 Dup DAL SS SS20 0 0000 Lab Duplicate GLP10-01-01-15-009 LMS DAL SS SS20 0 0000 Lab M atrix Spike 10 006-80 solvent blank EC-110316-07 10 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-010 DAL SS SS20 DB 0000 GLPlO-01-01-15-010 Dup DAL SS SS20 DB 0000 Lab Duplicate GLP10-01-01-15-010 LMS DAL SS SS20 DB 0000 Lab M a trix Spike GLP10-01-01-15-011 DAL SS SS19 0 0000 GLP10-01-01-15-011 Dup DAL SS SS19 0 0000 Lab Duplicate GLP10-01-01-15-011 LMS DAL SS SS19 0 0000 Lab M a trix Spike GLP10-01-01-15-012 DAL SS SS19 0 0005 GLP10-01-01-15-012 Dup DAL SS SS19 0 0005 Lab Duplicate GLP10-01-01-15-012 LMS DAL SS SS19 0 0005 Lab M a trix Spike GLP10-01-01-15-014 DAL SS SS1S 0 0000 GLP10-01-01-15-014 Dup DAL SS SS15 0 0000 Lab Duplicate GLP10-01-01-15-014 LMS DAL SS SS15 0 0000 Lab M a trix Spike GLP10-01-01-15-015 DAL SS SS17 0 0000 GLP10-01-01-15-015 Dup DAL SS SS17 0 0000 Lab Duplicate GLP10-01-01-15-015 LMS DAL SS SS17 0 0000 Lab M a trix Spike 10 006-80 solvent blank EC-110316-05 2.5 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-016 DAL SS SS14 0 0000 GLP10-01-01-15-016 Dup DAL SS SS14 0 0000 Lab Duplicate GLP10-01-01-15-016 LMS DAL SS SS14 0 0000 Lab M a trix Spike GLP10-01-01-15-018 DAL SS SS18 0 0000 GLP10-01-01-15-018 Dup DAL SS SS18 0 0000 Lab Duplicate GLP10-01-01-15-018 LMS DAL SS SS18 0 0000 Lab M a trix Spike GLP10-01-01-15-020 DAL SS SS10 0 0000 GLP10-01-01-15-020 Dup DAL SS SS10 0 0000 Lab Duplicate GLP10-01-01-15-020 LMS DAL SS SS10 0 0000 Lab M a trix Spike GLP10-01-01-15-021 DAL SS SS30 0 0000 GLP10-01-01-15-021 Dup DAL SS SS30 0 0000 Lab Duplicate GLP10-01-01-15-021 LMS DAL SS SS30 0 0000 Lab M a trix Spike GLP10-01-01-15-022 DAL SS SS30 0 0005 GLP10-01-01-15-022 Dup DAL SS SS30 0 0005 Lab Duplicate GLP10-01-01-15-022 LMS DAL SS SS30 0 0005 Lab M a trix Spike 10 006-80 solvent blank EC-110316-06 5 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-023 DAL SS SS30 0 0015 GLP10-01-01-15-023 Dup DAL SS SS30 0 0015 Lab Duplicate GLP10-01-01-15-023 LMS DAL SS SS30 0 0015 Lab M a trix Spike GLP10-01-01-15-024 DAL SS SS25 0 0000 GLP10-01-01-15-024 Dup DAL SS SS25 0 0000 Lab Duplicate GLP10-01-01-15-024 LMS DAL SS SS25 0 0000 Lab M a trix Spike GLP10-01-01-15-025 DAL SS SS25 0 0005 GLP10-01-01-15-025 Dup DAL SS SS25 0 0005 Lab Duplicate GLP10-01-01-15-025 LMS DAL SS SS25 0 0005 Lab M a trix Spike GLP10-01-01-15-026 DAL SS SS25 0 0015 3M Study GLP10-01-02-15 s110317a PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS <0 N/A <0 N/A <0 N/A 3.21 N/A 3.42 N/A 3.32 N/A N/A N/A 2.5 100 N/A N/A 0.0176 N/A 0.028 N/A 0.978 N/A 0.0173 N/A 0.0167 N/A 1 N/A 27.S N/A 21.4 N/A 126 N/A 312 N/A 264 N/A 1020 N/A 2.13 N/A 2,84 N/A 7.16 N/A N/A N/A 5.47 110 N/A N/A 7.67 N/A 7.44 N/A 35.1 N/A 7.89 N/A 7.71 N/A 36.9 N/A 1.1 N/A 1.31 N/A 6.3 N/A 794 N/A 7.34 N/A 31.7 N/A 3.63 N/A 3.29 N/A 8.77 N/A N/A N/A 9.98 100 N/A N/A 3.13 N/A 3.42 N/A 10.7 N/A 3.9 N/A 3.22 N/A 8.06 N/A 15.7 N/A 17.4 N/A 41.7 N/A 2.18 N/A 5.67 N/A 11.3 N/A 2.61 N/A 2.82 N/A 8.07 N/A N/A N/A 2.37 95.2 N/A N/A 4.94 N/A 6.15 N/A 30.5 N/A 4.06 N/A 2.97 N/A 31.9 N/A 19.8 N/A 36 N/A 173 N/A 3.2 N/A 2.94 N/A 8.07 N/A 0.807 N/A 0.778 N/A 2.03 N/A N/A N/A 5.53 111 N/A N/A 5.56 N/A 8.28 N/A jillp 32.2 N/A 55 | N/A M i 13701 N/A No intercept N/A -- $ ^ & 6 4 9 jjN /A mm . S4|rtN/A N olnt S u p t " ] N / A 409 N/A 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a,w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 1 sll0317a.w iff 0 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 0 sll0317a.w iff 1 sll0317a.w iff 0 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a,w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a,w iff 1 sll0317a.w iff 1 sll0317a.w iff 0 sll0317a.w ff 0 sll0317a.w iff 0 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a,w iff 1 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a,w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff Page 5 of 8 Page 52 of 514 s ll0 3 1 7 a l2 6 sll0 3 17 a l27 sll0 3 17 a l28 sll0 3 17 a l29 sll0 3 17 a l30 sll0 3 17 a l31 sll0 3 17 a l32 sll0 3 17 a l33 sll0 3 17 a l34 s ll0 3 1 7 a l3 5 $ 1 1 0 3 1 7 a l3 6 s ll0 3 1 7 a l3 7 sll0 3 17 a l38 sll0 3 17 a l39 s ll0 3 1 7 a l4 0 s ll0 3 1 7 a l4 1 s ll0 3 1 7 a l4 2 s ll0 3 1 7 a l4 3 s ll0 3 1 7 a l4 4 sll0 3 17 a l45 s ll0 3 1 7 a l4 6 sll0 3 17 a l47 s ll0 3 1 7 a l4 8 s ll0 3 1 7 a l4 9 s ll0 3 1 7 a l5 0 s ll0 3 1 7 a l5 1 s ll0 3 1 7 a l5 2 s ll0 3 1 7 a l5 3 sll0 3 17 a l54 sll0 3 17 a l55 s ll0 3 1 7 a l5 6 s ll0 3 1 7 a lS 7 s ll0 3 1 7 a l5 8 s ll0 3 1 7 a l5 9 s ll0 3 1 7 a l6 0 sll0 3 17 a l61 sll0 3 17 a l62 sll0 3 17 a l63 sU0317a001 sll0317a002 sll0317a003 s ll0 3 1 7 a 0 0 4 sll0317a005 s ll0 3 1 7 a 0 0 6 $110317a007 s ll0 3 1 7 a 0 0 8 s ll0 3 1 7 a 0 0 9 sll0317a010 sll0317a011 sll0317a012 sll0317a013 s ll0 3 1 7 a 0 1 4 sll0317a015 s ll0 3 1 7 a 0 1 6 sll0317a017 s ll0 3 1 7 a 0 1 8 s ll0 3 1 7 a 0 1 9 s ll0 3 1 7 a 0 2 0 s ll0 3 1 7 a 0 2 1 sll0317a022 $110317a023 sll0317a024 sll0317a025 s ll0 3 1 7 a 0 2 6 sll0317a027 sll0317a028 sll0317a029 sll0317a030 sll0317a031 sll0317a032 sll0317a033 sll0317a034 sll0317a035 s ll0 3 1 7 a 0 3 6 sll0317a037 sll0317a038 sll0317a039 sll0317a040 sll0317a041 s ll0 3 1 7 a 0 4 2 sll0317a043 s ll0 3 1 7 a 0 4 4 sll0317a045 s ll0 3 1 7 a 0 4 6 sll0317a047 sll0317a048 sll0317a049 sll0317a050 sll0317a051 sll0317a052 sll0317a053 GLP10-01-01-15-026 Dup DAL SS SS25 0 0015 Lab Duplicate GLP10-01-01-15-026 LMS DAL SS SS25 0 0015 Lab M a trix Spike GLP10-01-01-15-027 OAL SD SD22 0 0000 GLP10-01-01-15-027 Dup DAL SD SD22 0 0000 Lab Duplicate GLP10-01-01-15-027 LMS DAL SD SD22 0 0000 Lab M a trix Spike 10 006-80 solvent blank EC-110316-07 10 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-028 DAL SD SD22 0 0005 GLP1Q-01-01-15-028 Dup DAL SD SD22 0 0005 Lab Duplicate GLP10-01-01-15-028 LMS DAL SD SD22 0 0005 Lab M a trix Spike GLP10-01-01-15-029 OAL SD SD22 DB 000S GLP10-01-01-15-029 Dup DAL SD SD22 DB 0005 Lab Duplicate GLP10-01-01-15-029 LMS DAL SD SD22 DB 0005 Lab M a trix Spike GLP10-01-01-15-030 DAL SD SD22 0 0015 GLP10-01-01-15-030 Dup DAL SD SD22 0 0015 Lab Duplicate GLP10-01-01-15-030 LMS DAL SD SD22 0 0015 Lab M a trix Spike GLP10-01-01-15-031 DAL SD SD210 0000 GLP10-Q1-01-15-031 Dup DAL SD SD210 0000 Lab Duplicate GLP10-01-01-15-031 LMS DAL SD SD210 0000 Lab M a trix Spike GLP10-01-01-15-032 DAL SD SD210 0005 GLP10-01-01-15-032 Dup DAL SD SD210 0005 Lab Duplicate GLP10-01-01-15-032 LMS DAL SD SD210 0005 Lab M a trix Spike 10 006-80 solvent blank EC-110316-05 2.5 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-033 DAL SD SD21 0 0015 GLP10-01-01-15-033 Dup DAL SD SD210 0015 Lab Duplicate GLP10-01-01-15*033 LMS DAL SD SD210 0015 Lab M a trix Spike GLP10-01-01-15-034 DAL SS SS24 0 0000 GLP10-01-01-15-034 Dup DAL SS SS24 0 0000 Lab Duplicate GLP10-01-01-15-034 LMS DAL SS SS24 0 0000 Lab M a trix Spike GLP10-01-01-15-035 DAL SS SS24 0 0005 GLP10-01-01-15-035 Dup DAL SS SS24 0 0005 Lab Duplicate GLP10-01-01-15-035 LMS DAL SS SS24 0 0005 Lab M a trix Spike 10 006-80 solvent blank EC-110316-06 5 ng Extracted Curve Point 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank EC-110316-09 50 ng W arm up standard EC-110316-09 50 ng W arm up standard 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank EC-110316-010.2 ng Extracted Curve Point EC-110316-02 0.5 ng Extracted Curve Point EC-110316-03 0.75 ng Extracted Curve Point EC-110316-04 1 ng Extracted Curve Point EC-110316-05 2.5 ng Extracted Curve Point EC-110316-06 5 ng Extracted Curve Point EC-110316-07 10 ng Extracted Curve Point EC-110316-08 25 ng Extracted Curve Point EC-110316-09 50 ng Extracted Curve Point EC-110316-10 100 ng Extracted Curve Point EC-110316-11 200 ng Extracted Curve Point EC-110316-12 500 ng Extracted Curve Point 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank MB-110316-01 M ethod Blank w /o IS MB-110316-02 M ethod Blank w /o IS MB-110316-03 M ethod Blank w /o IS MB-110316-04 M ethod Blank w / IS MB-110316-0S M ethod Blank w / IS MB-110316-06 M ethod Blank w / IS MB-110316-07 M ethod Blank w / IS fo r dilutions MB-110316-08 M ethod Blank w / IS fo r dilutions MB-110316-09 M ethod Blank w / IS fo r dilutions MB-110316-10 M ethod Blank w / IS fo r dilutions MB-110316-11 M ethod Blank w / IS fo r dilutions MB-110316-12 M ethod Blank w / IS fo r dilutions LCS-110316-01 3 ng LCS in TCR-842 LCS-110316-02 3 ng LCS in TCR-842 LCS-110316-03 3 ng LCS in TCR-842 10 006-80 solvent blank EC-110316-05 2.5 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-1S-001 DAL SS SS T rlp l 0 0000 GLP10-01-01-15-001 Dup DAL SS SS T rip l 0 0000 Lab Duplicate GLP10-01-01-15-001 LMS DAL SS SS T rip l 0 0000 Lab M a trix Spike GLP10-01-01-15-083 OAL SS Trip2 0 0000 GLP10-01-01-15-083 Dup DAL SS Trip2 0 0000 Lab Duplicate GLP10-01-01-15-083 LMS DAL SS Trip2 0 0000 Lab M a trix Spike GLP10-01-01-15-002 DAL SS SS12 0 0000 GLP10-01-01-15-002 Dup DAL SS SS12 0 0000 Lab Duplicate GLP10-01-01-15-002 LMS DAL SS SS12 0 0000 Lab M a trix Spike GLP10-01-01-15-003 DAL SS SS12 0 0005 3M Study GLP10-01-02-15 s110317a PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS 395 N/A ,,'\,,,i2 5 N /A 222 N/A 162 N/A ill N/A n i l N/A N/A 9.9 99.3 N/A N/A 96.2 N/A 116 N/A 205 N/A 130 N/A 91.3 N/A 261 N/A 60.7 N/A 61.6 N/A 160 N/A 99.3 N/A 122 N/A 393 N/A 175 N/A 160 N/A 477 N/A N/A N/A 2.78 112 N/A N/A 69.3 N/A 63.1 N/A 182 N/A 49.7 N/A 75.9 N/A 164 N/A 144 N/A 126 N/A 368 N/A N/A N/A 5.29 106 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 0.241 120 0.427 85.3 0.751 100 0.945 94.6 2.5 100 5.05 101 9.79 98 25.7 103 49.9 99.7 95.4 95.5 206 103 498 99.7 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 0.0743 N/A 0.0696 N/A 0.0613 N/A 0.0997 N/A 0.0567 N/A 0.0512 N/A 0.0906 N/A 0.0423 N/A 0.0488 N/A 3.22 N/A 3.17 N/A 3.18 N/A N/A N/A 2.42 96.7 N/A N/A 0.118 N/A 0,0981 N/A 0.986 N/A 0.424 N/A 0.131 N/A 1.09 N/A No Intercept N/A `No In te re e p tv - N/A jN o l h t e r ^ ^ t | ^ : 4N/A jN o in te rM E rti^ j N/A 1 sll0317a.w iff 1 Sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 0 sll0317a.w iff 1 sll0317a.w iff 0 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sl!0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 0 sll0317a.w iff 1 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 s!10317a.wiff 0 sll0317a,w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 s!10317a.wiff 1 sll0317a.w iff 1 s!10317a.wiff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a,w iff 1 sll0317a.w iff 1 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w lff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff Page 6 of 8 Page 53 of 514 sll0317a054 sll0317a055 s ll0 3 1 7 a 0 5 6 sll0317a057 sll0317a058 sll0317a059 sll0317a060 sll0317a061 sll0317a062 sll0317a063 sll0317a064 sll0317a065 s ll0 3 1 7 a 0 6 6 sll0317a067 sll0317a068 sll0317a069 sll0317a070 sll0317a071 sll0317a072 s ll0 3 1 7 a 0 7 3 s ll0 3 1 7 a 0 7 4 sll0317a075 s ll0 3 1 7 a 0 7 6 s ll0 3 1 7 a 0 7 7 sll0317a078 sll0317a079 sll0317a080 s ll0 3 1 7 a 0 8 1 s ll0 3 1 7 a 0 8 2 s ll0 3 1 7 a 0 8 3 sll0317a084 sll0317a085 s ll0 3 1 7 a 0 8 6 s ll0 3 1 7 a 0 8 7 sll0317a088 sll0317a089 sll0317a090 sll0317a091 s ll0 3 1 7 a 0 9 2 s ll0 3 1 7 a 0 9 3 s ll0 3 1 7 a 0 9 4 sll0317a095 s ll0 3 1 7 a 0 9 6 sll0317a097 sll0317a098 s ll0 3 1 7 a 0 9 9 s ll0 3 1 7 a l0 0 s ll0 3 1 7 a l0 1 s ll0 3 1 7 a l0 2 s ll0 3 1 7 a l0 3 s ll0 3 1 7 a l0 4 s ll0 3 1 7 a l0 5 s ll0 3 1 7 a l0 6 s ll0 3 1 7 a l0 7 s ll0 3 1 7 a l0 8 s ll0 3 1 7 a l0 9 s ll0 3 1 7 a ll0 s ll0 3 1 7 a lll sll0 3 1 7 a ll2 s ll0 3 1 7 a ll3 sll0 3 1 7 a ll4 sll0 3 1 7 a ll5 sll0 3 1 7 a ll6 s ll0 3 1 7 a !1 7 s ll0 3 1 7 a ll8 sll0 3 1 7 a ll9 s ll0 3 1 7 a l2 0 sll0 3 17 a l21 sll0 3 17 a l22 sll0 3 17 a l23 sll0 3 17 a l24 sll0 3 17 a l25 s ll0 3 1 7 a l2 6 sll0 3 17 a l27 sll0 3 17 a l28 sll0 3 17 a l29 sll0 3 17 a l30 sll0 3 17 a l31 sll0 3 17 a l32 sll0 3 17 a l33 s ll0 3 1 7 a l3 4 sll0 3 17 a l35 s ll0 3 1 7 a l3 6 sll0 3 17 a l37 sll0 3 17 a l38 sll0 3 17 a l39 sll0 3 17 a l40 sll0 3 17 a l41 sll0 3 17 a l42 sll0 3 17 a l43 sll0 3 17 a l44 GLP10-01-01-15-003 Dup DAL SS SS12 0 0005 Lab Duplicate GLP10-01-01-15-003 LMS DAL SS SS12 0 0005 Lab M a trix Spike GLP10-01-01-15-004 DAL SS SS13 0 0000 GLP10-01-01-15-004 Dup DAL SS SS13 0 0000 Lab Duplicate GLP10-01-01-15-004 LMS DAL SS SS13 0 0000 Lab M a trix Spike 10 006-80 solvent blank EC-110316-06 5 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-005 DAL SS SS16 0 0000 GLP10-01-01-15-005 Dup DAL SS SS16 0 0000 Lab Duplicate GLP10-01-01-15-005 LMS DAL SS SS16 0 0000 Lab M atrix Spike GLP10-01-01-15-006 DAL SS SS16 DB 0000 GLPlO-Ol-Ol-lS-006 Dup DAL SS SS16 DB 0000 Lab Duplicate GLP10-01-01-1S-006 LMS DAL SS SS16 DB 0000 Lab M a trix Spike GLP10-01-01-15-007 DAL SS SS110 0000 GLP10-01-01-15-007 Dup DAL SS SS110 0000 Lab Duplicate GLP10-01-01-1S-007 LMS DAL SS SS110 0000 Lab M a trix Spike GLP10-01-01-1S-008 DAL SS SS11 0 0005 GLP10-01-01-15-008 Dup DAL SS SS110 0005 Lab Duplicate GLP10-01-01-15-008 LMS DAL SS SS110 0005 Lab M a trix Spike GLP10-01-01-15-009 DAL SS SS20 0 0000 GLP10-01-01-15-009 Dup DAL SS SS20 0 0000 Lab Duplicate GLP10-01-01-15-009 LMS DAL SS SS20 0 0000 Lab M a trix Spike 10 006-80 solvent blank EC-110316-07 10 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-1S-010 DAL SS SS20 DB 0000 GLPlO-01-01-15-010 Dup DAL SS SS20 DB 0000 Lab Duplicate GLP10-01-01-1S-010 LMS DAL SS SS20 DB 0000 Lab M a trix Spike GLP10-01-01-1S-011 DAL SS SS19 0 0000 GLP10-01-01-15-011 Dup DAL SS SS19 0 0000 Lab Duplicate GLP10-01-01-15-011 LMS DAL SS SS19 0 0000 Lab M a trix Spike GLP10-01-01-15-012 DAL SS SS19 0 0005 GLP10-01-01-15-012 Dup DAL SS SS19 0 0005 Lab Duplicate GLP10-01-01-15-012 LMS DAL SS SS19 0 0005 Lab M a trix Spike GLP10-01-01-15-014 DAL SS SS15 0 0000 GLP10-01-01-15-014 Dup DAL SS SS15 0 0000 Lab Duplicate GLP10-01-01-15-014 LMS DAL SS SS15 0 0000 Lab M a trix Spike GLP10-01-01-15-015 DAL SS SS17 0 0000 GLP10-01-01-15-015 Dup DAL SS SS17 0 0000 Lab Duplicate GLP10-01-01-15-015 LMS DAL SS SS17 0 0000 Lab M a trix Spike 10 006-80 solvent blank EC-110316-05 2.5 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-016 DAL SS SS14 0 0000 GLP10-01-01-15-016 Dup DAL SS SS14 0 0000 Lab Duplicate GLP10-01-01-15-016 LMS DAL SS SS14 0 0000 Lab M a trix Spike GLP10-01-01-15-018 DAL SS SS18 0 0000 GLP10-01-01-15-018 Dup DAL SS SS18 0 0000 Lab Duplicate GLP10-01-01-15-018 LMS DAL SS SS18 0 0000 Lab M a trix Spike GLP10-01-01-15-020 DAL SS SS10 0 0000 GLP10-01-01-15-020 Dup DAL SS SS10 0 0000 Lab Duplicate GLP10-01-01-15-020 LMS DAL SS SS10 0 0000 Lab M a trix Spike GLP10-01-01-15-021 DAL SS SS30 0 0000 GLP10-01-01-15-021 Dup DAL SS SS30 0 0000 Lab Duplicate GLP10-01-01-15-021 LMS DAL SS SS30 0 0000 Lab M a trix Spike GLP10-01-01-1S-022 DAL SS SS30 0 0005 GLP10-01-01-15-022 Dup DAL SS SS30 0 0005 Lab Duplicate GLP 10-01-01-15-022 LMS DAL SS SS30 0 0005 Lab M a trix Spike 10 006-80 solvent blank EC-110316-06 5 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-023 DAL SS SS30 0 0015 GLP10-01-01-15-023 Dup DAL SS SS30 0 0015 Lab Duplicate GLP10-01-01-15-023 LMS DAL SS SS30 0 0015 Lab M a trix Spike GLP10-01-01-15-024 DAL SS SS25 0 0000 GLP10-01-01-15-024 Dup DAL SS SS25 0 0000 Lab Duplicate GLP10-01-01-15-024 LMS DAL SS SS25 0 0000 Lab M a trix Spike GLP10-01-01-1S-025 DAL SS SS25 0 0005 GLP10-01-01-15-025 Dup DAL SS SS25 0 0005 Lab Duplicate GLP10-01-01-15-025 LMS DAL SS SS25 0 0005 Lab M a trix Spike GLP10-01-01-15-026 DAL SS SS25 0 0015 GLP10-01-01-15-026 Dup DAL SS SS25 0 0015 Lab Duplicate GLP10-01-01-15-026 LMS DAL SS SS25 0 0015 Lab M a trix Spike GLP10-01-01-15-027 DAL SD SD22 0 0000 GLP10-01-01-15-027 Dup DAL SD SD22 0 0000 Lab Duplicate GLP10-01-01-15-027 LMS DAL SD SD22 0 0000 Lab M a trix Spike 10 006-80 solvent blank EC-110316-07 10 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-028 DAL SO SD22 0 0005 GLP10-01-01-15-028 Dup DAL SD SD22 0 0005 Lab Duplicate GLP10-01-01-15-028 LMS DAL SD SD22 0 0005 Lab M a trix Spike GLP10-01-01-15-029 DAL SD SD22 DB 0005 GLP10-01-01-15-029 Dup DAL SD SD22 DB 0005 Lab Duplicate GLP10-01-01-1S-029 LMS DAL SD SD22 DB 0005 Lab M a trix Spike GLP10-01-01-15-030 DAL SD SD22 0 0015 GLP10-01-01-15-030 Dup DAL SD SD22 0 0015 Lab Duplicate GLP10-01-01-15-030 LMS DAL SD SD22 0 0015 Lab M a trix Spike GLP10-01-01-15-031 DAL SD SD210 0000 GLP10-01-01-15-031 Dup DAL SO SD210 0000 Lab Duplicate 3M Study GLP10-01-02-15 $110317a PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS N/A No intertapvfellll N/A 146 N/A 169 N/A 417 N/A N/A N/A 5.46 N/A N/A 382 N/A 321 N/A p i p i N/A *~361 N/A 361 N/A IjN /A 84 N/A 67 N/A 171 N/A NoTntercept S B N/A 322 N/A 239 N/A 136 N/A 128 N/A 450 N/A N/A N/A 10.2 N/A N/A 116 N/A 191 N/A 514 N/A N/A 422 N/A SKjN/A 430 N/A 470 N/A 1250 N/A 130 N/A ' - I N/A ftliitefc.e^S No Intercept iN o.InterM pt . ?N o i n t ^ e ^ ^ ||i j , ,v ,, N/A !Nolritercegt&^` \N/A 'No Intercept* ^ N/A No In te rc e p ? ^ ><N/A No Intercept N/A Page 7 of 8 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 0 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a,w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 0 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a,w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 0 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 5110317a.wiff 1 sll0317a.w iff 1 sl!0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 s!10317a.wiff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sl!0317a.w iff 1 sll0317a.w iff 1 5110317a.wiff 1 sll0317a.w iff 1 5110317a.wiff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff Page 54 of 514 s ll0 3 1 7 a l4 5 sll0 3 17 a l46 sll0 3 17 a l47 sll0 3 17 a l48 s ll0 3 1 7 a l4 9 s ll0 3 1 7 a l5 0 sll0 3 17 a l51 sll0 3 17 a l52 sll0 3 17 a l53 sU 0 3 1 7 a l5 4 sll0 3 17 a l55 s ll0 3 1 7 a l5 6 sll0 3 17 a l57 sll0 3 17 a l58 sll0 3 17 a l59 sll0 3 17 a l60 s!10317al61 sll0 3 17 a l62 sll0 3 17 a l63 GLPIO-Ol-Ol-15-031LMS DAL SD SD210 0000 Lab M a trix Spike GLP10-01-01-15-032 DAL SD SD210 0005 GLPIO-Ol-Ol-15-032 Dup DAL SD SD210 0005 Lab Duplicate GLPlO-01-01-15-032 LMS DAL SD SD210 0005 Lab M a trix Spike 10 006-80 solvent blank EC-110316-05 2.5 ng Extracted Curve Point 10 006-80 solvent blank GLP10-O1-OM5-O33 DAL SD SD210 0015 GLPlO-01-01-15-033 Dup DAL SD SD210 0015 Lab Duplicate GLPlO-01-01-15-033 LMS DAL SD SD210 0015 Lab M atrix Spike GLP10-01-OM5-034 DAL SS SS24 0 0000 GLPlO-Ol-Ol-15-034 Dup DAL SS SS24 0 0000 Lab Duplicate GLPlO-01-01-15-034 LMS DAL SS SS24 0 0000 Lab M a trix Spike GLP10-01-01-1S-035 DAL SS SS24 0 0005 GLPlO-01-01-15-035 Dup DAL SS SS24 0 0005 Lab Duplicate GLPlO-01-01-15-035 LMS DAL SS SS24 0 0005 Lab M a trix Spike 10 006-80 solvent blank EC-110316-06 5 ng Extracted Curve Point 10 006-80 solvent blank s110317a PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS JSIo Ipteroe^ g g N/A `N o ^inte ree pt^^'' N/A N o ln te rc e ^^'^N /A [No Intercept y v j N/A N/A N/A 2.72 N/A N/A <)80 N/A . N/A No Intercept N/A No l n t e r M | | | | p N/A N o'lnte nce^^-lN /A N/A N Intercept ^ *N/A No J n te r c a p t^ y N/A ;Np Interat t i v i N/A N/ " ' N/A 5.69 N/A N/A 109 114 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a,w iff 1 sll0317a.w iff 1 sll0317a.w iff 0 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 1 sll0317a.w iff 0 sll0317a.w iff 1 sll0317a.w iff 3M Study GLP10-01-02-15 Page 8 of 8 Page 55 of 514 s110321a Sample Name Sample ID sll0 3 21 a 00 1 10 006-80 solvent blank s!10321a002 10 006-80 solvent blank sU0321a003 EC-110316-09 50 ng W arm up standard sll0 3 21 a 00 4 EC-110316-09 50 ng W arm up standard sll0 3 21 a 00 5 10 006-80 solvent blank sll0 3 21 a 00 6 10 006-80 solvent blank sll0 3 21 a 00 7 10 006-80 solvent blank sll0 3 21 a 00 8 10 006-80 solvent blank sll0 3 21 a 00 9 10 006-80 solvent blank sll0 3 21 a 01 0 EC-110316-010.2 ng Extracted Curve Point sll0 3 21 a 01 1 EC-110316*02 0.5 ng Extracted Curve Point S ll0321a012 EC-110316-03 0.75 ng Extracted Curve Point sll0 3 21 a 01 3 EC-110316-04 1 ng Extracted Curve Point sll0 3 21 a 01 4 EC-110316-05 2.5 ng Extracted Curve Point sll0 3 21 a 01 5 EC-110316-06 5 ng Extracted Curve Point sll0 3 21 a 01 6 EC-110316-07 10 ng Extracted Curve Point sll0 3 21 a 01 7 EC-110316-08 25 ng Extracted Curve Point sll0 3 21 a 01 8 EC-110316-09 50 ng Extracted Curve Point sll0 3 21 a 01 9 EC-110316-10 100 ng Extracted Curve Point sll0 3 21 a 02 0 EC-110316-11 200 ng Extracted Curve Point sU 0321a021 EC-110316-12 S00 ng Extracted Curve Point sll0 3 21 a 02 2 10 006-80 solvent blank sll0 3 21 a 02 3 10 006-80 solvent blank sll0 3 21 a 02 4 10 006-80 solvent blank sll0 3 2 1 a 0 2 5 10 006-80 solvent blank sl!0 32 1a 0 26 MB-110316-01 M ethod Blank w /o IS sll0 3 2 1 a 0 2 7 MB-110316-04 M ethod Blank w / IS sll0 3 2 1 a 0 2 8 LCS-110316-04 30 ng LCS in TCR-842 sll0 3 2 1 a 0 2 9 ICS-110316-05 30 ng LCS in TCR-842 sll0 3 2 1 a 0 3 0 LCS-110316-06 30 ng LCS in TCR-842 sll0 3 21 a 03 1 GLP10-01-01-15-036 DAL SS SS24 0 0015 sll0 3 2 1 a 0 3 2 GLP10-01-01-15-036 Dup DAL SS SS24 0 0015 Lab Duplicate sll0 3 21 a 03 3 GLP10-01-01-1S-036 LMS DAL SS SS24 0 0015 Lab M a trix Spike sll0 3 21 a 03 4 GLP10-01-01-15-037 DAL SS SS29 0 0000 sll0 3 21 a 03 5 GLP10-01-01-15-037 Dup DAL SS SS29 0 0000 Lab Duplicate sll0 3 2 1 a 0 3 6 GLP10-01-01-15-037 LMS DAL SS SS29 0 0000 Lab M a trix Spike sll0 3 21 a 03 7 GLP10-01-01-15-038 DAL SS SS29 0 0005 sll0 3 21 a 03 8 GLP10-01-01-15-038 Dup DAL SS SS29 0 0005 Lab Duplicate sll0 3 21 a 03 9 GLP10-01-01-15-038 LMS DAL SS SS29 0 0005 Lab M a trix Spike sll0 3 21 a 04 0 GLP10-01-01-15-039 DAL SS SS29 0 0015 sll0 3 21 a 04 1 10 006-80 solvent blank sll0 3 21 a 04 2 EC-110316-05 2.5 ng Extracted Curve Point sll0 3 21 a 04 3 10 006-80 solvent blank sll0 3 21 a 04 4 GLP10-01-01-15-039 Dup DAL SS SS29 0 0015 Lab Duplicate sll0 3 21 a 04 5 GLP10-01-01-15-039 LMS DAL SS SS29 0 0015 Lab M a trix Spike sll0 3 21 a 04 6 GLP10-01-01-15-040 DAL SS SS20 0 0005 sll0 3 21 a 04 7 GLP10-01-01-15-040 Dup DAL SS SS20 0 0005 Lab Duplicate sU0321a048 GLP10-01-01-15-040 LMS DAL SS SS20 0 0005 Lab M a trix Spike s!10321a049 GLP10-01-01-15-041 DAL SS SS13 0 0005 sll0 3 21 a 05 0 GLP10-01-01-15-041 Dup DAL SS SS13 0 0005 Lab Duplicate s ll0 3 2 1 a 0 S l GLP10-01-01-15-041 LMS DAL SS SS13 0 0005 Lab M a trix Spike sll0 3 21 a 05 2 GLP10-01-01-15-042 DAL SS SS13 DB 0005 sll0 3 21 a 05 3 GLP10-01-01-15-042 Dup DAL SS SS13 DB 0005 Lab Duplicate sll0 3 21 a 05 4 GLP10-01-01-15-042 LMS DAL SS SS13 DB 0005 Lab M a trix Spike sll0321a0S 5 GLP10-01-01-15-043 DAL SS SS1S 0 0005 sl!0321a0S6 GLP10-01-01-15-043 Dup DAL SS SS15 0 0005 Lab Duplicate sll0 3 21 a 05 7 GLP10-01-01-15-043 LMS DAL SS SS15 0 0005 Lab M a trix Spike sl!0321a0S8 GLP10-01-01-15*044 DAL SS SS17 0 0005 sll0 3 21 a 05 9 10 006-80 solvent blank sll0 3 21 a 06 0 EC-110316-06 5 ng Extracted Curve Point sll0 3 21 a 06 1 10 006-80 solvent blank S ll0321a062 GLP10-01-01-15-044 Dup DAL SS SS17 0 0005 Lab Duplicate sll0 3 21 a 06 3 GLP10-01-01-15-044 LMS DAL SS SS17 0 0005 Lab M a trix Spike sll0 3 21 a 06 4 GLP10-01-01-15-045 DAL SS SS14 0 0005 sll0321a06S GLP10-01-01-15-045 Dup DAL SS SS14 0 0005 Lab Duplicate sll0 3 21 a 06 6 GLP10-01-01-1S-045 LMS DAL SS SS14 0 0005 Lab M a trix Spike sll0 3 21 a 06 7 GLP10-01-01-15-046 DAL SS SS18 0 0005 sll0 3 21 a 06 8 GLP10-01-01-15-046 Dup DAL SS SS18 0 O00S Lab Duplicate sll0 3 21 a 06 9 GLP10-01-01-15-046 LMS DAL SS SS18 0 0005 Lab M a trix Spike sll0 3 21 a 07 0 GLP10-01-01-15-047 DAL SS SS16 0 0005 sll0 3 21 a 07 1 GLP10-01-01-15-047 Dup DAL SS SS16 0 0005 Lab Duplicate sll0 3 21 a 07 2 GLP10-01-01-15-047 LMS DAL SS SS16 0 0005 Lab M a trix Spike sll0 3 21 a 07 3 GLP10-01-01-15-048 DAL SS SS16 0 0015 sll0 3 21 a 07 4 GLP10-01-01-15-048 Dup DAL SS SS16 0 0015 Lab Duplicate sll0 3 21 a 07 5 GLP10-01-01-15-048 LMS DAL SS SS16 0 0015 Lab M a trix Spike sll0 3 21 a 07 6 GLP10-01-01-15-049 DAL SS SS10 0 0005 sl!0 32 1a 0 77 10 006-80 solvent blank sll0 3 21 a 07 8 EC-110316-07 10 ng Extracted Curve Point sll0 3 21 a 07 9 10 006-80 solvent blank sll032X a080 GLP10-01-01-15-049 Dup DAL SS SS10 0 0005 Lab Duplicate sll0 3 21 a 08 1 GLP10-01-01-15-049 LMS OAL SS SS10 0 0005 Lab M a trix Spike sll0 3 21 a 08 2 GLP10-01-01-15-050 DAL SS SS10 DB 0005 sll0 3 21 a 08 3 GLP10-01-01-15-050 Dup DAL SS SS10 DB 0005 Lab Duplicate s!10321a084 GLP10-01-01-15-050 LMS DAL SS SS10 DB 0005 Lab M atrix Spike 3M Study GLP10-01-02-15 Analyte Peak Name MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS Calculated Concentration Accuracy Record {n g /m L) <%) M odified File Name N/A N/A 0 sll0321a.w iff N/A N/A 0 sll0321a.w iff N/A N/A 0 sll0321a.w iff N/A N/A 0 sll0321a.w iff N/A N/A 0 s!10321a.wiff N/A N/A 0 sll0321a.w iff N/A N/A 0 sll0321a.w iff N/A N/A 0 sll0321a.w iff N/A N/A 0 sll0321a.w iff 0.053 27.7 0 sll0321a.w iff 0.416 86.9 0 sll0321a.w iff 0.638 88.9 0 sll0321a,w iff 0.939 2.48 98.2 104 0 sll0321a.w iff 0 sll0321a.w iff 5.08 106 0 sll0321a.w iff 10.2 107 0 sll0321a.w iff 25.3 106 0 sll0321a.w iff 50.4 105 0 sll0321a.w iff 98.3 103 0 sll0321a.w iff 180 94.2 0 sll0321a.w iff 481 101 0 sll0321a.w iff N/A N/A 0 sll0321a.w iff N/A N/A 0 sll0321a.w iff N/A N/A 0 sll0321a.w iff N/A N/A N/A N/A 0 sll0321a.w iff 0 sll0321a.w iff 3.15 N/A 0 $110321a.wiff 2.85 N/A 0 sll0321a.w iff 3.05 N/A 0 sll0321a.w iff 3.11 N/A 3.6 N/A 0 sll0321a.w iff 0 sll0321a.w iff 3.46 N/A 0 sll0321a,w iff 3.17 N/A 0 sll0321a.w iff 3.24 N/A 0 sll0321a.w iff 3.18 N/A 0 sll0321a.w iff 3.4 N/A 0 sll0321a.w iff 3.18 N/A 0 sll0321a.w iff 3.03 N/A 3.05 N/A 0 sll0321a.w iff 0 sll0321a.w iff 3.14 N/A 0 sll0321a.w iff N/A N/A 0 sll0321a.w iff 2.4 100 N/A N/A 0 s!10321a.wiff 0 sll0321a.w iff 3.25 N/A 0 sll0321a.w iff 3.3 N/A 0 sll0321a.w iff 3.29 N/A 0 sll0321a.w iff 3.28 N/A 0 sll0321a.w iff 2.88 N/A 0 sll0321a.w iff 3.25 N/A 0 sll0321a.w iff 2.99 N/A 0 5110321a.wiff 3.34 N/A 1 sll0321a.w iff 2.98 N/A 0 sll0321a.w iff 2.92 N/A 0 sll0321a.w iff 3.19 N/A 0 sll0321a.w iff 3.2 N/A 3.1 N/A 0 sll0321a.w iff 0 sll0321a.w iff 3.11 N/A 0 sll0321a.w iff 3.24 N/A 0 sll0321a.w iff N/A N/A 0 sll0321a.w iff 4.71 98.6 0 sll0321a.w iff N/A N/A 0 sll0321a.w iff 3.19 N/A 0 5110321a.wiff 2.9 N/A 3.32 N/A 0 sll0321a.w iff 0 sll0321a.w iff 2.96 N/A 0 sll0321a.w iff 3.24 N/A 0 sll0321a.w iff 3.12 N/A 0 sll0321a.w iff 3.28 N/A 3.17 N/A 0 sll0321a.w iff 0 sll0321a.w lff 3.22 N/A 0 sll0321a.w iff 3.18 N/A 0 sll0321a.w iff 3.09 N/A 0 sll0321a.w iff 2.99 N/A 0 sll0321a.w iff 3.01 N/A 0 sll0321a.w iff 3.33 N/A 0 sll0321a.w iff 3.47 N/A 0 sll0321a.w iff N/A N/A 0 sll0321a.w iff 10.3 108 0 sll0321a.w iff N/A N/A 0 sll0321a.w iff 3.23 N/A 3.13 N/A 0 sll0321a.w iff 0 sll0321a.w iff 3.24 N/A 0 sll0321a.w iff 3.3 N/A 0 sll0321a.w iff 3.38 N/A 0 s!10321a.wiff Page 1 of 6 Page 56 of1 s110321a Sample Name Sam plelD sll0 3 2 1 a 0 8 5 GLPlO-01-01-15-051 DAL SS SS10 0 0015 s ll0 3 2 1 a 0 8 6 GLPlO-01-01-15-051 Dup DAL SS SS10 0 0015 Lab Duplicate sll0 3 2 1 a 0 8 7 GLPlO-01-01-15-051 LMS DAL SS SS10 0 0015 Lab M a trix Spike sll0 3 2 1 a 0 8 8 GLPlO-01-01-15-052 DAL SD SD20 0 0000 sll0 3 2 1 a 0 8 9 GLP10-01-01-15-0S2 Dup DAL SD SD20 0 0000 Lab Duplicate sll0 3 2 1 a 0 9 0 GLP10-01-01-15-052 LMS DAL SD SD20 0 0000 Lab M a trix Spike sll0 3 2 1 a 0 9 1 GLPlO-01-01-15-053 DAL SD SD20 0 0005 s!10321a092 GLPlO-01-01-15-053 Dup DAL SD SD20 0 0005 Lab Duplicate sll0 3 2 1 a 0 9 3 GLPlO-01-01-15-053 LMS DAL SD SD20 0 0005 Lab M atrix Spike S ll0321a094 GLPlO-01-01-15-054 DAL SD SD20 0 0015 sll0 3 2 1 a 0 9 5 10 006-80 solvent blank s ll0 3 2 1 a 0 9 6 EC-110316-05 2.5 ng Extracted Curve Point sll0 3 2 1 a 0 9 7 10 006-80 solvent blank sll0 3 2 1 a 0 9 8 GLPlO-01-01-15-054 Dup DAL SD SD20 0 0015 Lab Duplicate sll0 3 2 1 a 0 9 9 GLPlO-01-01-15-054 LMS DAL SD SD20 0 0015 Lab M a trix Spike s ll0 3 2 1 a l0 0 GLP10-01-01-15-055 DAL SD SD23 0 0000 s ll0 3 2 1 a l0 1 GLP10-01-01-15-0S5 Dup DAL SD SD23 0 0000 Lab Duplicate s ll0 3 2 1 a l0 2 GLP10-01-01-15-05S LMS DAL SD SD23 0 0000 Lab M a trix Spike S ll0 3 2 1 a l0 3 GLPlO-01-01-15-056 DAL SD SD23 0 0005 s ll0 3 2 1 a l0 4 GLPlO-01-01-15-056 Dup DAL SD SD23 0 0005 Lab Duplicate s ll0 3 2 1 a l0 5 GLPlO-01-01-15-056 LMS DAL SD SD23 0 0005 Lab M a trix Spike s ll0 3 2 1 a l0 6 GLPlO-01-01-15-057 DAL SD SD23 0 0015 s ll0 3 2 1 a l0 7 GLP10-01-01-15-057 Dup DAL SD SD23 0 001S Lab Duplicate s ll0 3 2 1 a l0 8 GLPlO-01-01-15-057 LMS DAL SD SD23 0 001S Lab M a trix Spike S ll0 3 2 1 a l0 9 GLPlO-01-01-15-058 DAL SS SS28 0 0000 s ll0 3 2 1 a ll0 GLPlO-01-01-15-058 Dup DAL SS SS28 0 0000 Lab Duplicate s l l0 3 2 1 a lll GLPlO-01-01-15-058 LMS DAL SS SS28 0 0000 Lab M a trix Spike S ll0 3 2 1 a ll2 GLP10-01-01-15-0S9 DAL SS SS28 0 0005 s ll0 3 2 1 a ll3 10 006-80 solvent blank s ll0 3 2 1 a ll4 EC-110316-06 5 ng Extracted Curve Point s ll0 3 2 1 a ll5 10 006-80 solvent blank s ll0 3 2 1 a ll6 GLP10-01-01-1S-OS9 Dup DAL SS SS28 0 0005 Lab Duplicate s ll0 3 2 1 a ll7 GLP10-01-01-15-059 LMS DAL SS SS28 0 0005 Lab M a trix Spike s ll0 3 2 1 a ll8 GLPlO-01-01-15-060 DAL SS SS28 DB 0005 s !1 0 3 2 1 a ll9 GLPlO-01-01-15-060 Dup DAL SS SS28 DB 0005 Lab Duplicate s ll0 3 2 1 a l2 0 GLPlO-01-01-15-060 LMS DAL SS SS28 DB 0005 Lab M a trix Spike s ll0 3 2 1 a l2 1 GLPlO-01-01-15-061 DAL SS SS28 0 0015 s ll0 3 2 1 a l2 2 GLP10-01-01-1S-061 Dup DAL SS SS28 0 0015 Lab Duplicate s ll0 3 2 1 a l2 3 GLPlO-01-01-15-061 LMS DAL SS SS28 0 0015 Lab M a trix Spike s ll0 3 2 1 a l2 4 GLP10-01-01-1S-062 DAL SS SS27 0 0000 s ll0 3 2 1 a l2 S GLPlO-01-01-15-062 Dup DAL SS SS27 0 0000 Lab Duplicate s ll0 3 2 1 a l2 6 GLP10-01-01-15-062 LMS DAL SS SS27 0 0000 Lab M a trix Spike s ll0 3 2 1 a l2 7 GLP10-01-01-1S-063 DAL SS SS27 0 0005 $110321al28 GLPlO-01-01-15-063 Dup DAL SS SS27 0 0005 Lab Duplicate s ll0 3 2 1 a l2 9 GLPlO-01-01-15-063 LMS DAL SS SS27 0 000S Lab M a trix Spike s ll0 3 2 1 a l3 0 GLPlO-01-01-15-064 DAL SS SS27 0 0015 s ll0 3 2 1 a l3 1 10 006-80 solvent blank s ll0 3 2 1 a l3 2 EC-110316-07 10 ng Extracted Curve Point s ll0 3 2 1 a l3 3 10 006-80 solvent blank s ll0 3 2 1 a l3 4 GLPlO-01-01-15-064 Dup DAL SS SS27 0 0015 Lab Duplicate s ll0 3 2 1 a l3 5 GLPlO-01-01-15-064 LMS DAL SS SS27 0 0015 Lab M a trix Spike S ll0 3 2 1 a l3 6 GLP10-01-01-1S-065 DAL SS SS22 0 0000 s ll0 3 2 1 a l3 7 GLPlO-01-01-15-065 Dup DAL SS SS22 0 0000 Lab Duplicate s ll0 3 2 1 a !3 8 GLPlO-01-01-15-065 LMS DAL SS SS22 0 0000 Lab M a trix Spike s ll0 3 2 1 a l3 9 GLPlO-01-01-15-066 DAL SS SS22 0 0005 s ll0 3 2 1 a l4 0 GLP10-01-01-15-066 Dup DAL SS SS22 0 0005 Lab Duplicate s ll0 3 2 1 a l4 1 GLPlO-01-01-15-066 LMS DAL SS SS22 0 0005 Lab M a trix Spike s ll0 3 2 1 a l4 2 GLPlO-01-01-15-067 DAL SS SS22 DB 0005 s ll0 3 2 1 a l4 3 GLPlO-01-01-15-067 Dup DAL SS SS22 DB 0005 Lab Duplicate S ll0 3 2 1 a l4 4 GLPlO-01-01-15-067 LMS DAL SS SS22 DB 0005 Lab M a trix Spike S ll0 3 2 1 a l4 5 GLP10-01-01-15-068 DAL SS SS22 0 0015 s ll0 3 2 1 a l4 6 GLPlO-01-01-15-068 Dup DAL SS SS22 0 0015 Lab Duplicate s ll0 3 2 1 a l4 7 GLPlO-01-01-15-068 LMS DAL SS SS22 0 0015 Lab M a trix Spike S ll0 3 2 1 a l4 8 GLPlO-01-01-15-069 DAL SS SS210 0000 s ll0 3 2 1 a l4 9 10 006-80 solvent blank s ll0 3 2 1 a lS 0 EC-110316-05 2.5 ng Extracted Curve Point s ll0 3 2 1 a l5 1 IO 006-80 solvent blank s ll0 3 2 1 a l5 2 GLPlO-01-01-15-069 Dup DAL SS SS210 0000 Lab Duplicate s ll0 3 2 1 a l5 3 GLPlO-01-01-15-069 LMS DAL SS SS210 0000 Lab M a trix Spike s ll0 3 2 1 a lS 4 GLPlO-01-01-15-070 DAL SS SS210 0005 s ll0 3 2 1 a l5 5 GLPlO-01-01-15-070 Dup DAL SS SS210 0005 Lab Duplicate s ll0 3 2 1 a l5 6 GLPlO-01-01-15-070 LMS DAL SS SS210 0005 Lab M a trix Spike S ll0 3 2 1 a l5 7 GLPlO-01-01-15-071 DAL SS SS21 0 0015 s ll0 3 2 1 a l5 8 GLPlO-01-01-15-071 Dup DAL SS SS210 0015 Lab Duplicate s ll0 3 2 1 a l5 9 GLPlO-01-01-15-071 LMS DAL SS SS210 0015 Lab M a trix Spike s ll0 3 2 1 a l6 0 GLPlO-01-01-15-072 DAL SD SD18 0 0000 s ll0 3 2 1 a l6 1 GLPIO-Ol-Ol-15-072 Dup DAL SD SD18 0 0000 Lab Duplicate s ll0 3 2 1 a l6 2 GLPlO-01-01-15-072 LMS DAL SD SD18 0 0000 Lab M a trix Spike s ll0 3 2 1 a l6 3 GLPlO-01-01-15-073 DAL SD SD18 0 0005 s ll0 3 2 1 a l6 4 GLPlO-01-01-15-073 Dup DAL SD SD18 0 0005 Lab Duplicate s ll0 3 2 1 a l6 S GLPlO-01-01-15-073 LMS DAL SD SD18 0 0005 Lab M a trix Spike s ll0 3 2 1 a l6 6 10 006-80 solvent blank s ll0 3 2 1 a l6 7 EC-110316-06 5 ng Extracted Curve Point s ll0 3 2 1 a l6 8 10 006-80 solvent blank s!10321a001 10 006-80 solvent blank sl!0 32 1a 0 02 10 006-80 solvent blank 3M Study GLP10-01-02-15 Analyte Peak Name MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS PF8S PFBS Calculated Concentration Accuracy Record (n g /m L) <%) 3.1 N/A M odified File Name 0 sll0321a.w iff 2.98 N/A 0 sll0321a.w iff 3.27 N/A 0 sll0321a.w iff 3.26 N/A 0 sll0321a.w iff 3.17 N/A 0 sll0321a.w iff 4.05 N/A 0 sll0321a.w iff 3.03 N/A 0 sll0321a.w iff 3.24 N/A 0 sll0321a.w iff 3.46 N/A 0 sll0321a.w iff 2.97 N/A 0 sll0321a.w iff N/A N/A 0 sll0321a.w iff 2.49 104 0 sll0321a.w iff N/A N/A 0 sll0321a.w iff 3.13 N/A 0 sll0321a.w iff 3.45 N/A 0 sll0321a.w iff 3 N/A 3.02 N/A 0 sll0321a.w iff 0 sll0321a.w iff 3.11 N/A 0 sll0321a.w iff 3.11 N/A 0 sll0321a.w lff 3.21 N/A 0 sll0321a.w iff 3.26 N/A 0 sll0321a.w iff 3.22 N/A 0 sll0321a.w iff 3.11 N/A 0 sll0321a.w iff 3.16 N/A 0 sll0321a.w iff 3.23 N/A 0 sll0321a.w iff 3.03 N/A 0 sll0321a.w iff 3.37 N/A 0 sll0321a.w iff 3.12 N/A 0 sll0321a.w iff N/A N/A 0 sll0321a.w iff 5.01 105 0 sll0321a.w iff N/A N/A 0 $110321a.wiff 2.89 N/A 0 sll0321a.w iff 3.08 N/A 3.02 N/A 0 sll0321a.w iff 0 sll0321a.w iff 3.23 N/A 0 sll0321a.w iff 3.32 N/A 0 sll0321a,w iff 3.11 N/A 0 sll0321a.w iff 3.07 N/A 0 sll0321a.w iff 3.24 N/A 0 sll0321a.w iff 3.2 N/A 0 sll0321a.w iff 2.98 N/A 0 $110321a.wiff 3.26 N/A 0 sll0321a.w iff 3.47 N/A 0 sll0321a.w iff 3.11 N/A 0 sll0321a.w iff 3.04 N/A 0 sll0321a.w iff 2.84 N/A 0 sll0321a.w iff N/A N/A 0 sll0321a.w iff 10.5 110 0 sll0321a.w iff N/A N/A 0 sll0321a,w iff 3.43 N/A 3.31 N/A 0 sll0321a.w lff 0 sll0321a.w iff 3.42 N/A 0 sll0321a.w iff 3.23 N/A 0 sll0321a.w iff 3.58 N/A 0 sll0321a.w iff 2.93 N/A 0 sll0321a.w iff 3.02 N/A 0 sll0321a.w iff 3.27 N/A 0 sll0321a.w iff 3.08 N/A 3.18 N/A 3.24 N/A 0 sll0321a.w iff 0 sll0321a.w iff 0 sll0321a.w iff 3.14 N/A 0 sll0321a.w iff 3.03 N/A 0 sll0321a.w iff 3.32 N/A 0 sll0321a.w iff 3.15 N/A 0 sll0321a.w iff N/A N/A 0 sll0321a.w iff 2.61 109 0 sll0321a.w iff N/A N/A 0 sll0321a.w iff 3.15 N/A 0 sll0321a.w iff 3.17 N/A 0 sll0321a.w iff 3.31 N/A 0 sll0321a.w iff 2.99 N/A 3.3 N/A 0 sll0321a.w iff 0 sll0321a.w iff 2.95 N/A 0 sll0321a.w iff 3.07 N/A 0 sll0321a.w iff 3.36 N/A 0 sll0321a.w iff 3.17 N/A 0 sll0321a.w iff 3.17 N/A 0 sll0321a.w iff 3.16 N/A 0 sll0321a.w iff 3.31 N/A 0 sll0321a.w iff 3.25 N/A 0 sll0321a.w iff 3.37 N/A 0 sll0321a.w iff N/A N/A 0 sll0321a.w iff 5.08 106 0 sll0321a.w iff N/A N/A 0 sll0321a.w iff N/A N/A 0 sll0321a.w iff N/A N/A 0 sll0321a.w iff Page 2 of 8 Page 57 of 514 s110321a Sample Name Sample ID sll0 3 21 a 00 3 EC-110316-09 50 ng W arm up standard Sll0321a004 EC-110316-09 50 ng W arm up standard sll0 3 21 a 00 5 10 006-80 solvent blank sll0 3 21 a 00 6 10 006-80 solvent blank sll0 3 21 a 00 7 10 006-80 solvent blank s ll0 3 2 1 a 0 0 8 10 006-80 solvent blank sll0 3 21 a 00 9 10 006-80 solvent blank sll0 3 21 a 01 0 EC-110316-010.2 ng Extracted Curve Point s ll0 3 2 1 a 0 1 1 EC-110316-02 0.S ng Extracted Curve Point s ll0 3 2 1 a 0 1 2 EC-110316-03 0.75 ng Extracted Curve Point sl!0 32 1a 0 13 EC-110316-04 1 ng Extracted Curve Point s ll0 3 2 1 a 0 1 4 EC-110316-05 2.5 ng Extracted Curve Point sll0 3 21 a 01 5 EC-110316-06 5 ng Extracted Curve Point s ll0 3 2 1 a 0 1 6 EC-110316-07 10 ng Extracted Curve Point s ll0 3 2 1 a 0 1 7 EC-110316-08 25 ng Extracted Curve Point sll0 3 21 a 01 8 EC-110316-09 50 ng Extracted Curve Point sll0 3 21 a 01 9 EC-110316-10 100 ng Extracted Curve Point sll0 3 21 a 02 0 EC-110316-11 200 ng Extracted Curve Point s ll0 3 2 1 a 0 2 1 EC-110316-12 500 ng Extracted Curve Point sl!0 32 1a 0 22 10 006-80 solvent blank sl!0 32 1a 0 23 10 006-80 solvent blank s ll0 3 2 1 a 0 2 4 10 006-80 solvent blank sll0 3 21 a 02 5 10 006-80 solvent blank s ll0 3 2 1 a 0 2 6 M8-110316-01 M ethod Blank w /o IS sll0 3 21 a 02 7 MB-110316-04 M ethod Blank w / IS s ll0 3 2 1 a 0 2 8 LCS-110316-04 30 ng LCS in TCR-842 s ll0 3 2 1 a 0 2 9 LCS-110316-05 30 ng LCS in TCR-842 s ll0 3 2 1 a 0 3 0 LCS-110316-06 30 ng LCS in TCR-842 s ll0 3 2 1 a 0 3 1 GLP10-01-01-15-036 DAL SS SS24 0 0015 s ll0 3 2 1 a 0 3 2 GLP10-01-01-15-036 Dup DAL SS SS24 0 0015 Lab Duplicate s ll0 3 2 1 a 0 3 3 GLP10-01-01-15-036 LMS DAL SS SS24 0 0015 Lab M a trix Spike S ll0321a034 GLP10-01-01-15-037 DAL SS SS29 0 0000 sll0 3 21 a 03 5 GLP10-01-01-15-037 Dup DAL SS SS29 0 0000 Lab Duplicate s ll0 3 2 1 a 0 3 6 GLP10-01-01-15-037 LMS DAL SS SS29 0 0000 Lab M a trix Spike sll0 3 21 a 03 7 GLP10-01-01-15-038 DAL SS SS29 0 0005 sll0 3 21 a 03 8 GLP10-01-01-15-038 Dup DAL SS SS29 0 0005 Lab Duplicate sll0 3 21 a 03 9 GLP10-01-01-15-038 LMS DAL SS SS29 0 0005 Lab M a trix Spike sll0 3 21 a 04 0 GLP10-01-01-15-039 DAL SS SS29 0 0015 s ll0 3 2 1 a 0 4 1 10 006-80 solvent blank sll0 3 21 a 04 2 EC-110316-05 2.5 ng Extracted Curve Point sll0 3 21 a 04 3 10 006-80 solvent blank sll0 3 21 a 04 4 GLP10-01-01-15-039 Dup DAL SS SS29 0 0015 Lab Duplicate sll0 3 21 a 04 5 GLP10-01-01-15-039 LMS DAL SS SS29 0 0015 Lab M a trix Spike sll0 3 21 a 04 6 GLP10-01-01-1S-040 DAL SS SS20 0 0005 sl!0 32 1a 0 47 GLP10-01-01-15-040 Dup DAL SS SS20 0 0005 Lab Duplicate s ll0 3 2 1 a 0 4 8 GLP10-01-01-15-040 LMS DAL SS SS20 0 0005 Lab M a trix Spike s ll0 3 2 1 a 0 4 9 GLP10-01-01-15-041 DAL SS SS13 0 O00S sll0 3 2 1 a 0 5 0 GLP10-01-01-15-041 Dup DAL SS SS13 0 000S Lab Duplicate sll0 3 2 1 a 0 5 1 GLP10-01-01-1S-041 LMS DAL SS SS13 0 0005 Lab M a trix Spike $110321a052 GLP10-01-01-15-042 DAL SS SS13 DB 0005 sll0 3 2 1 a 0 5 3 GLP10-01-01-15-042 Dup DAL SS SS13 DB 0005 Lab Duplicate sll0321a0S 4 GLP10-01-01-15-042 LMS DAL SS SS13 DB 0005 Lab M a trix Spike sll0 3 2 1 a 0 5 5 GLP10-01-01-1S-043 DAL SS SS15 0 0005 s ll0 3 2 1 a 0 5 6 GLP10-01-01-15-043 Dup DAL SS SS15 0 0005 Lab Duplicate sll0 3 2 1 a 0 5 7 GLP10-01-01-15-043 LMS DAL SS SS15 0 0005 Lab M a trix Spike sll0 3 2 1 a 0 5 8 GLP10-01-01-15-044 DAL SS SS17 0 0005 sll0 3 2 1 a 0 5 9 10 006-80 solvent blank s ll0 3 2 1 a 0 6 0 EC-110316-06 5 ng Extracted Curve Point sl!0 32 1a 0 61 10 006-80 solvent blank sl!0 32 1a 0 62 GLP10-01-01-15-044 Dup DAL SS SS17 0 0005 Lab Duplicate sll0 3 21 a 06 3 GLP10-01-01-15-044 LMS DAL SS SS17 0 0005 Lab M a trix Spike Sll0321a064 GLP10-01-01-1S-045 DAL SS SS14 0 0005 Sll0321a065 GLP10-01-01-15-045 Dup DAL SS SS14 0 0005 Lab Duplicate s ll0 3 2 1 a 0 6 6 GLP10-01-01-15-045 LMS DAL SS SS14 0 0005 Lab M a trix Spike Sll0321a067 GLP10-01-01-15-046 DAL SS SS18 0 0005 sll0 3 21 a 06 8 GLP10-01-01-15-046 Dup DAL SS SS18 0 0005 Lab Duplicate sll0 3 21 a 06 9 GLP10-01-01-15-046 LMS DAL SS SS18 0 000S Lab M a trix Spike sll0 3 21 a 07 0 GLP10-01-01-15-047 DAL SS SS16 0 0005 sll0 3 21 a 07 1 GLP10-01-01-15-047 Dup DAL SS SS16 0 OOOS Lab Duplicate s!10321a072 GLP10-01-01-15-047 LMS DAL SS SS16 0 0005 Lab M a trix Spike sll0 3 21 a 07 3 GLP10-01-01-15-048 DAL SS SS16 0 0015 sll0 3 21 a 07 4 GLP10-01-01-15-048 Dup DAL SS SS16 0 0015 Lab Duplicate sll0 3 21 a 07 5 GLP10-01-01-15-048 LMS DAL SS SS16 0 0015 Lab M a trix Spike s ll0 3 2 1 a 0 7 6 GLP10-01-01-15-049 DAL SS SS10 0 0005 sll0 3 21 a 07 7 10 006-80 solvent blank sll0 3 21 a 07 8 EC-110316-07 10 ng Extracted Curve Point sll0 3 21 a 07 9 10 006-80 solvent blank sll0 3 21 a 08 0 GLP10-01-01-15-049 Dup DAL SS SS10 0 0005 Lab Duplicate sl!0 32 1a 0 81 GLP10-01-01-15-049 LMS DAL SS SS10 0 0005 Lab M a trix Spike s ll0 3 2 1 a 0 8 2 GLP10-01-01-15-050 DAL SS SS10 DB 0005 sl!0 32 1a 0 83 GLP10-01-01-15-050 Dup DAL SS SS10 DB 0005 Lab Duplicate s ll0 3 2 1 a 0 8 4 GLP10-01-01-15-050 LMS DAL SS SS10 DB 0005 Lab M a trix Spike Sll0321a085 GLP10-01-01-15-051 DAL SS SS10 0 0015 s ll0 3 2 1 a 0 8 6 GLP10-01-01-15-051 Dup DAL SS SS10 0 0015 Lab Duplicate s ll0 3 2 1 a 0 8 7 GLP10-01-01-15-051 LMS DAL SS SS10 0 0015 Lab M a trix Spike sll0 3 21 a 08 8 GLP10-01-01-1S-052 DAL SD SD20 0 0000 3M Study GLP10-01-02-15 Analyte Peak Name PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PF8S PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS Calculated Concentration Accuracy Record (n g /m L) (%) M odified File Name N/A N/A 0 sll0321a.w iff N/A N/A 0 sll0321a.w iff N/A N/A 0 sll0321a.w iff N/A N/A 0 sll0321a.w iff N/A N/A 0 sll0321a.w iff N/A N/A 0 sll0321a.w iff N/A N/A 0 sll0321a.w iff 0.225 112 0 sll0321a.w iff 0.432 86.4 0 sll0321a.w iff 0.699 93.4 0 sll0321a.w iff 0.993 2.54 99.4 102 1 sll0321a.w iff 0 sll0321a.w iff 5.17 103 0 sll0321a.w iff 10.2 102 0 sll0321a.w iff 24.8 51.8 99.4 104 0 sll0321a.w iff 0 sll0321a.w iff 98.9 99 0 sll0321a.w iff 198 98.9 0 sll0321a.w iff 501 100 0 sll0321a.w iff N/A N/A 0 sll0321a.w iff N/A N/A 0 sll0321a.w iff N/A N/A 0 sll0321a.w iff N/A N/A 0 sll0321a.w iff N/A N/A 0 sll0321a.w iff <0 N/A 0 $110321a.wiff 30.2 N/A 0 sll0321a.w iff 30.8 N/A 0 sll0321a.w iff 33.5 N/A 0 sll0321a.w iff 3.42 N/A 0 sll0321a.w iff 4.17 N/A 0 sll0321a.w iff 10.6 N/A 0 sll0321a.w iff 1.42 N/A 1.63 N/A 0 sll0321a.w iff 1 sll0321a.w iff 6.98 N/A 0 sll0321a.w iff 1.16 N/A 0 sll0321a.w iff 0.843 N/A 0 sll0321a.w iff 6.74 N/A 1 $110321a.wiff 9.05 N/A 0 sll0321a.w iff N/A N/A 0 sll0321a.w iff 2.6 104 0 sll0321a.w iff N/A N/A 0 sll0321a.w iff 7.68 N/A 0 sll0321a.w iff 38.1 N/A 0 sll0321a.w iff 0.234 N/A 1 sll0321a.w iff 0.343 N/A 0 sll0321a.w iff 1.47 N/A 1 sll0321a.w lff 0.793 N/A 0 sll0321a,w iff 0.948 N/A 1 sll0321a.w iff 2.06 N/A 1 sll0321a.w iff 1.14 N/A 0 sll0321a.w iff 0,937 N/A 1 sll0321a.w iff 2.01 N/A 0 sll0321a.w iff 0.154 N/A 0 sll0321a.w iff 0.212 N/A 0 sll0321a.w iff 1.37 N/A 1 sll0321a.w iff 0.318 N/A 0 s!10321a.wiff N/A N/A 0 sll0321a.w iff 5.36 107 N/A N/A 0 sll0321a.w iff 0 sll0321a.w iff 0.205 N/A 0 sll0321a,w iff 1.39 N/A 1 sll0321a.w iff 0.143 N/A 1 sll0321a.w iff 0.158 N/A 0 sll0321a.w iff 1.45 N/A 0 sll0321a.w iff 0.0323 N/A 0 sll0321a.w iff 0.0335 N/A 0 sll0321a.w iff 1.16 N/A 1 sll0321a.w iff 2.58 N/A 0 sll0321a.w iff 3.12 N/A 0 sll0321a.w iff 8.5S N/A 0 sll0321a.w iff 7.55 N/A 0 sll0321a.w iff 9.7 N/A 0 sll0321a.w iff 38.1 N/A 0 sll0321a.w iff 1.65 N/A 1 sll0321a.w iff N/A N/A 0 sll0321a.w iff 9.87 98.8 0 sll0321a.w iff N/A N/A 0 s!10321a.wiff 1.92 N/A 1 sll0321a,w iff 7.68 N/A 0 5110321a.wiff 1.71 N/A 1 sll0321a.w iff 1.74 N/A 1 sll0321a.w iff 8.04 N/A 0 sll0321a.w lff 6.21 N/A 0 sll0321a.w iff 6.66 N/A 0 sll0321a.w iff 32.6 N/A 0 sll0321a.w lff 8.97 N/A 0 sl!0321a.w iff Page 3 of 8 Page 58 of 514 s110321a Sample Name Sample ID sll0 3 21 a 08 9 GLP10-01-01-15-052 Dup DAL SD SD20 0 0000 Lab Duplicate sll0 3 21 a 09 0 GLPlO-01-01-15-052 LMS DAL SD SD20 0 0000 Lab M a trix Spike sll0 3 21 a 09 1 GLPlO-01-01-15-053 DAL SD SD20 0 0005 sll0 3 21 a 09 2 GLPlO-01-01-15-053 Dup DAL SD SD20 0 0005 Lab Duplicate sll0 3 21 a 09 3 GLPlO-01-01-15-053 LMS DAL SD SD20 0 0005 Lab M a trix Spike sll0 3 21 a 09 4 GLPlO-01-01-15-054 DAL SD SD20 0 0015 sll0 3 21 a 09 5 10 006-80 solvent blank sll0 3 21 a 09 6 EC-110316-05 2.5 ng Extracted Curve Point sll0 3 21 a 09 7 10 006-80 solvent blank sll0 3 21 a 09 8 GLPlO-01-01-15-054 Dup DAL SD SD20 0 0015 Lab Duplicate sll0 3 21 a 09 9 GLPlO-01-01-15-054 LMS DAL SD SD20 0 0015 Lab M a trix Spike s ll0 3 2 1 a l0 0 GLPlO-01-01-15-055 DAL SD SD23 0 0000 s ll0 3 2 1 a l0 1 GLPlO-01-01-15-055 Dup DAL SD SD23 0 0000 Lab Duplicate s ll0 3 2 1 a l0 2 GLPlO-01-01-15-055 LMS DAL SD SD23 0 0000 Lab M a trix Spike s ll0 3 2 1 a l0 3 GLPlO-01-01-15-056 DAL SD SD23 0 0005 s ll0 3 2 1 a l0 4 GLP10-01-01-1S-056 Dup DAL SD SD23 0 0005 Lab Duplicate s ll0 3 2 1 a l0 5 GLPlO-01-01-15-056 LMS DAL SD SD23 0 0005 Lab M a trix Spike s ll0 3 2 1 a l0 6 GLP10-01-01-15-057 DAL SD SD23 0 0015 s ll0 3 2 1 a l0 7 GLPlO-01-01-15-057 Dup DAL SD SD23 0 0015 Lab Duplicate s ll0 3 2 1 a l0 8 GLPlO-01-01-15-057 LMS DAL SD SD23 0 0015 Lab M a trix Spike s ll0 3 2 1 a l0 9 GLP10-01-01-15-058 DAL SS SS28 0 0000 s ll0 3 2 1 a ll0 GLPlO-01-01-15-058 Dup DAL SS SS28 0 0000 Lab Duplicate s ll0 3 2 1 a lll GLP10-01-01-15-058 LMS DAL SS SS28 0 0000 Lab M a trix Spike s ll0 3 2 1 a ll2 GLPlO-01-01-15-059 DAL SS SS28 0 0005 s !1 0 3 2 1 a ll3 10 006-80 solvent blank s ll0 3 2 1 a ll4 EC-110316-06 5 ng Extracted Curve Point s ll0 3 2 1 a llS 10 006-80 solvent blank s ll0 3 2 1 a l! 6 GLPlO-01-01-15-059 Dup DAL SS SS28 0 0005 Lab Duplicate s ll0 3 2 1 a ll7 GLP10-01-01-15-OS9 LMS DAL SS SS28 0 000S Lab M a trix Spike s ll0 3 2 1 a ll8 GLPlO-01-01-15-060 DAL SS SS28 DB 0005 s ll0 3 2 1 a ll9 GLPlO-01-01-15-060 Dup DAL SS SS28 DB 0005 Lab Duplicate s ll0 3 2 1 a l2 0 GLPlO-01-01-15-060 LMS DAL SS SS28 DB 0005 Lab M a trix Spike s ll0 3 2 1 a 121 GLPlO-01-01-15-061 DAL SS SS28 0 0015 5110321a122 GLPlO-01-01-15-061 Dup DAL SS SS28 0 0015 Lab Duplicate 5110321a123 GLP10-01-01-15-061 LMS DAL SS SS28 0 0015 Lab M a trix Spike s ll0 3 2 1 a l2 4 GLPlO-01-01-15-062 DAL SS SS27 0 0000 s ll0 3 2 1 a l2 5 GLPlO-01-01-15-062 Dup DAL SS SS27 0 0000 Lab Duplicate s ll0 3 2 1 a l2 6 GLPlO-01-01-15-062 LMS DAL SS SS27 0 0000 Lab M a trix Spike s!10 3 21 al27 GLP10-01-01-15-063 DAL SS SS27 0 0005 s ll0 3 2 1 a l2 8 GLPlO-01-01-15-063 Dup DAL SS SS27 0 0005 Lab Duplicate s ll0 3 2 1 a l2 9 GLPlO-01-01-15-063 LMS DAL SS SS27 0 0005 Lab M a trix Spike s ll0 3 2 1 a l3 0 GLPlO-01-01-15-064 DAL SS SS27 0 001S s ll0 3 2 1 a l3 1 10 006-80 solvent blank s ll0 3 2 1 a l3 2 EC-110316-07 10 ng Extracted Curve Point s ll0 3 2 1 a l3 3 10 006-80 solvent blank s ll0 3 2 1 a l3 4 GLPlO-01-01-15-064 Dup DAL SS SS27 0 0015 Lab Duplicate s ll0 3 2 1 a l3 5 GLP10-01-01-15-064 LMS DAL SS SS27 0 0015 Lab M a trix Spike s ll0 3 2 1 a l3 6 GLP10-01-01-1S-065 DAL SS SS22 0 0000 5110321a137 GLPlO-01-01-15-065 Dup DAL SS SS22 0 0000 Lab Duplicate s ll0 3 2 1 a l3 8 GLPlO-01-01-15-065 LMS DAL SS SS22 0 0000 Lab M a trix Spike s ll0 3 2 1 a l3 9 GLPlO-01-01-15-066 DAL SS SS22 0 0005 s ll0 3 2 1 a l4 0 GLP10-01-01-15-066 Dup DAL SS SS22 0 0005 Lab Duplicate s ll0 3 2 1 a l4 1 GLPlO-01-01-15-066 LMS DAL SS SS22 0 0005 Lab M a trix Spike s ll0 3 2 1 a l4 2 GLPlO-01-01-15-067 DAL SS SS22 DB 0005 s!10 3 21 al43 GLPlO-01-01-15-067 Dup DAL SS SS22 DB 0005 Lab Duplicate s ll0 3 2 1 a l4 4 GLPlO-01-01-15-067 LMS DAL SS SS22 DB 0005 Lab M a trix Spike s ll0 3 2 1 a l4 5 GLPlO-01-01-15-068 DAL SS SS22 0 0015 s ll0 3 2 1 a l4 6 GLPlO-01-01-15-068 Dup DAL SS SS22 0 0015 Lab Duplicate s ll0 3 2 1 a l4 7 GLPlO-01-01-15-068 LMS DAL SS SS22 0 0015 Lab M a trix Spike s ll0 3 2 1 a l4 8 GLP10-01-01-15-069 DAL SS SS210 0000 s ll0 3 2 1 a l4 9 10 006-80 solvent blank s ll0 3 2 1 a l5 0 EC-110316-05 2.5 ng Extracted Curve Point s ll0 3 2 1 a l5 1 10 006-80 solvent blank s!10 3 21 al52 GLPlO-01-01-15-069 Dup DAL SS SS210 0000 Lab Duplicate s ll0 3 2 1 a l5 3 GLPlO-01-01-15-069 LMS DAL SS SS210 0000 Lab M a trix Spike s ll0 3 2 1 a lS 4 GLPlO-01-01-15-070 DAL SS SS21 0 0005 s ll0 3 2 1 a l5 5 GLPlO-01-01-15-070 Dup DAL SS SS210 0005 Lab Duplicate s ll0 3 2 1 a !5 6 GLPlO-01-01-15-070 LMS DAL SS SS210 0005 Lab M a trix Spike s ll0 3 2 1 a lS 7 GLP10-01-01-1S-071 DAL SS SS210 0015 s ll0 3 2 1 a l5 8 GLP10-01-01-15-071 Dup DAL SS SS210 0015 Lab Duplicate s ll0 3 2 1 a lS 9 GLPlO-01-01-15-071 LMS DAL SS SS210 0015 Lab M a trix Spike s ll0 3 2 1 a l6 0 GLPlO-01-01-15-072 DAL SD SD18 0 0000 s ll0 3 2 1 a l6 1 GLP10-01-01-15-072 Dup DAL SD SD18 0 0000 Lab Duplicate s ll0 3 2 1 a l6 2 GLPlO-01-01-15-072 LMS DAL SD SO18 0 0000 Lab M a trix Spike s ll0 3 2 1 a l6 3 GLP10-01-01-15-073 DAL SD SD18 0 0005 $110321al64 GLPlO-01-01-15-073 Dup DAL SD SD18 0 0005 Lab Duplicate s ll0 3 2 1 a l6 5 GLPlO-01-01-15-073 LMS DAL SD SD18 0 0005 Lab M a trix Spike s ll0 3 2 1 a l6 6 10 006-80 solvent blank s ll0 3 2 1 a l6 7 EC-110316-06 5 ng Extracted Curve Point s ll0 3 2 1 a l6 8 10 006-80 solvent blank sll0 3 21 a 00 1 10 006-80 solvent blank sll0 3 2 1 a 0 0 2 10 006-80 solvent blank sll0 3 21 a 00 3 EC-110316-09 50 ng W arm up standard sll0 3 21 a 00 4 EC-110316-09 50 ng W arm up standard sll0321a00S 10 006-80 solvent blank sll0 3 21 a 00 6 10 006-80 solvent blank 3M Study GLP10-01-02-15 A n a ly te Peak Name PF8S PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFHS PFHS PFHS PFHS PFHS PFHS Calculated Concentration Accuracy Record (n g /m L) (%) M odified File Name 12.4 N/A 38.3 N/A 0 sll0321a.w iff 0 sll0321a.w iff 9.25 N/A 10.3 N/A 0 sll0321a.w iff 0 sll0321a.w iff 37.6 N/A 11.4 N/A 0 sll0321a.w iff 0 sll0321a.w iff N/A N/A 2.72 109 0 sll0321a.w iff 0 sll0321a.w iff N/A N/A 0 sll0321a.w iff 10.3 N/A 0 sll0321a.w iff 40.9 N/A 6.43 N/A 0 sll0321a.w iff 0 sll0321a.w iff 6.8 N/A 0 sll0321a.w iff 34.6 N/A 2.75 N/A 2.75 N/A 8.12 N/A 2.42 N/A 0 sll0321a.w iff 0 s!10321a.wiff 0 sll0321a.w iff 0 sll0321a.w iff 0 sll0321a.w iff 2.46 N/A 0 s!10321a.wiff 7.46 N/A 0.73 N/A 0.839 N/A 0 sll0321a.w iff 1 sll0321a.w iff 0 sll0321a,w iff 6.62 N/A 0 sll0321a.w iff 0.615 N/A N/A N/A 1 sll0321a.w iff 0 sll0321a.w iff 5.59 112 0 sll0321a.w iff N/A N/A 0 sll0321a.w iff 0.558 N/A 1.92 N/A 0.846 N/A 0 sll0321a.w iff 0 sll0321a.w iff 0 sll0321a.w iff 0.692 N/A 2.08 N/A 2.58 N/A 1 sll0321a.w iff 0 sll0321a.w iff 0 sll0321a.w iff 2.16 N/A 0 sll0321a.w iff 8.1 N/A 0.606 N/A 0 sll0321a.w iff 0 sll0321a.w iff 0.739 N/A 2.02 N/A 0 sll0321a.w iff 0 sll0321a.w iff 0.821 N/A 0 sll0321a.w iff 0.646 N/A 0 sll0321a.w iff 1.82 N/A 0.445 N/A 0 sll0321a.w iff 0 sll0321a.w iff N/A N/A 10.7 107 N/A N/A 0.336 N/A 0 sll0321a.w iff 0 sl!0321a.w iff 0 $110321a.wiff 1 sll0321a.w iff 1.63 N/A 0 sll0321a.w iff 1.13 N/A 1.26 N/A 6.88 N/A 1 sll0321a.w iff 0 sll0321a.w iff 0 sll0321a.w iff 1.62 N/A 0 sll0321a.w iff 1.45 N/A 0 sll0321a.w iff 6.86 N/A 0 sll0321a.w iff 1.72 N/A 1.58 N/A 7.46 N/A 0.609 N/A 0 sll0321a.w iff 0 sll0321a.w iff 0 sll0321a.w iff 1 sll0321a.w iff 0.7 N/A 1.85 N/A 0 sll0321a.w iff 1 sll0321a.w iff 0.819 N/A 0 $110321a.wiff N/A N/A 0 sll0321a.w iff 2.48 99.2 N/A N/A 1 sll0321a.w iff 0 sll0321a.w iff 0.544 N/A 0 sll0321a.w lff 1.72 N/A 0.319 N/A 0.322 N/A 1.56 N/A 1.73 N/A 2.16 N/A 7.44 N/A 0 sll0321a,w iff 0 sll0321a.w iff 1 sll0321a.w iff 0 sll0321a.w iff 1 sll0321a.w iff 0 sll0321a.w iff 0 sll0321a.w iff 10.1 N/A 8.94 N/A 0 sll0321a.w iff 0 sll0321a.w iff 39.7 N/A 9.4 N/A 8.94 N/A 0 sll0321a.w iff 0 sll0321a.w iff 0 sll0321a.w iff 41.2 N/A 0 s!10321a.wiff N/A N/A 4.97 99.4 N/A N/A N/A N/A 0 sll0321a.w iff 1 sll0321a.w iff 0 sll0321a,w iff 0 sll0321a.w iff N/A N/A 0 sll0321a.w iff N/A N/A N/A N/A N/A N/A N/A N/A 0 sll0321a.w iff 0 sll0321a.w iff 0 sll0321a.w iff 0 sll0321a.w iff Page 4 of 8 Page 59 of 514 s110321 a Sample Name Sample ID sll0 3 21 a 00 7 10 006*80 solvent blank sll0 3 21 a 00 8 10 006-80 solvent blank sll0 3 21 a 00 9 10 006*80 solvent blank sll0 3 21 a 01 0 EC*110316*010.2 ng Extracted Curve Point sll0 3 21 a 01 1 EC-110316-02 0.5 ng Extracted Curve Point sll0 3 21 a 01 2 EC-110316-03 0.7S ng Extracted Curve Point sll0 3 21 a 01 3 EC-110316-04 1 ng Extracted Curve Point sll0 3 21 a 01 4 EC-110316-05 2.5 ng Extracted Curve Point sll0 3 21 a 01 5 EC-110316-06 5 ng Extracted Curve Point sll0 3 21 a 01 6 EC-110316-07 10 ng Extracted Curve Point sll0 3 21 a 01 7 EC-110316-08 25 ng Extracted Curve Point sll0 3 21 a 01 8 EC-110316-09 50 ng Extracted Curve Point sll0 3 21 a 01 9 EC-110316-10 100 ng Extracted Curve Point sll0 3 21 a 02 0 EC-110316-11200 ng Extracted Curve Point sll0 3 21 a 02 1 EC-110316-12 500 ng Extracted Curve Point sll0 3 21 a 02 2 10 006-80 solvent blank sll0 3 21 a 02 3 10 006-80 solvent blank sll0 3 21 a 02 4 10 006-80 solvent blank sll0321a02S 10 006-80 solvent blank sU 0321a026 MB-110316-01 Method Blank w /o IS sll0 3 21 a 02 7 MB-110316-04 Method Blank w / IS sll0 3 21 a 02 8 LCS-110316-04 30 ng LCS in TCR-842 sll0 3 21 a 02 9 LCS-110316-05 30 ng LCS in TCR-842 sll0 3 21 a 03 0 ICS-110316-06 30 ng LCS in TCR-842 sll0 3 21 a 03 1 GLP10-01-01-15-036 DAL SS SS24 0 0015 sll0 3 2 1 a 0 3 2 GLP10-01-01-15-036 Dup DAL SS SS24 0 0015 Lab Duplicate sll0 3 21 a 03 3 GLP10-01-01-15-036 LMS DAL SS SS24 0 0015 Lab M a trix Spike sll0 3 2 1 a 0 3 4 GLP10-01-01-15-037 DAL SS SS29 0 0000 sll0 3 21 a 03 5 GLP10-01-01-15-037 Dup DAL SS SS29 0 0000 Lab Duplicate sll0 3 2 1 a 0 3 6 GLP10-01-01-1S-037 LMS DAL SS SS29 0 0000 Lab M a trix Spike sll0 3 2 1 a 0 3 7 GLP10-01-01-15-038 DAL SS SS29 0 0005 sll0 3 21 a 03 8 GLP10-01-01-15-038 Dup DAL SS SS29 0 0005 Lab Duplicate sll0 3 21 a 03 9 GLP10-01-01-15-038 LMS DAL SS SS29 0 0005 Lab M a trix Spike sll0 3 2 1 a 0 4 0 GLP10-01-01-15-039 DAL SS SS29 0 0015 sll0 3 21 a 04 1 10 006*80 solvent blank sll0 3 21 a 04 2 EC-110316-05 2.5 ng Extracted Curve Point sll0 3 21 a 04 3 10 006-80 solvent blank sll0 3 21 a 04 4 GLP10-01-01-15-039 Dup DAL SS SS29 0 0015 Lab Duplicate sll0 3 21 a 04 5 GLP10-01-01-15-039 LMS DAL SS SS29 0 0015 Lab M a trix Spike sll0 3 2 1 a 0 4 6 GLP10-01-01-15-040 DAL SS SS20 0 0005 sll0 3 21 a 04 7 GLP10-01-01-1S-040 Dup DAL SS SS20 0 0O0S Lab Duplicate sll0 3 21 a 04 8 GLP10-01-01-1S-040 LMS DAL SS SS20 0 0005 Lab M a trix Spike $110321a049 GLP10-01-01-15-041 DAL SS SS13 0 0005 sllO321aOS0 GLP10-01-01-15-041 Dup DAL SS SS13 0 0005 Lab Duplicate s ll0 3 2 1 a 0 S l GLP10-01-01-15-041 LMS DAL SS SS13 0 0005 Lab M a trix Spike sll0 3 21 a 05 2 GLP10-01-01-15-042 DAL SS SS13 DB 0005 s!10321a0S3 GLP10-01-01-15-042 Dup DAL SS SS13 DB 0005 Lab Duplicate sll0 3 21 a 05 4 GLP10-01-01-15-042 LMS DAL SS SS13 DB 0005 Lab M a trix Spike sll0 3 21 a 05 5 GLP10-01-01-15-043 DAL SS SS15 0 0005 sll0 3 21 a 05 6 GLP10-01-01-15-043 Dup DAL SS SS15 0 0005 Lab Duplicate sllO 321a0S7 GLP10-01-01-15-043 LMS DAL SS SS15 0 0005 Lab M a trix Spike sll0 3 21 a 05 8 GLP10-01-01-15-044 DAL SS SS17 0 0005 sll0 3 21 a 05 9 10 006-80 solvent blank sll0 3 21 a 06 0 EC-110316-06 S ng Extracted Curve Point sll0 3 21 a 06 1 10 006-80 solvent blank sll0 3 21 a 06 2 GLP10-01-01-15-044 Dup DAL SS SS17 0 0005 Lab Duplicate sll0 3 21 a 06 3 GLP10-01-01-15-044 LMS DAL SS SS17 0 0005 Lab M a trix Spike sll0 3 21 a 06 4 GLP10-01-01-15-045 DAL SS SS14 0 0005 sll0321a06S GLP10-01-01-15-045 Dup DAL SS SS14 0 0005 Lab Duplicate sll0 3 21 a 06 6 GLP10-01-01-15-045 LMS DAL SS SS14 0 0005 Lab M a trix Spike sll0 3 21 a 06 7 GLP10-01-01-15-046 DAL SS SS18 0 0005 s!10321a068 GLP10-01-01-15-046 Dup DAL SS SS18 0 0005 Lab Duplicate sll0 3 21 a 06 9 GLP10-01-01-15-046 LMS DAL SS SS18 0 0005 Lab M a trix Spike sll0 3 21 a 07 0 GLP10-01-01-15-047 DAL SS SS16 0 0005 sll0 3 21 a 07 1 GLP10-01-01-15-047 Dup DAL SS SS16 0 000S Lab Duplicate sll0 3 21 a 07 2 GLP10-01-01-15-047 LMS DAL SS SS16 0 0005 Lab M a trix Spike sll0 3 21 a 07 3 GLP10-01-01-15-048 DAL SS SS16 0 0015 sll0 3 21 a 07 4 GLP10-01-01-15-048 Dup DAL SS SS16 0 0015 Lab Duplicate sll0 3 21 a 07 5 GLP10-01-01-15-048 LMS DAL SS SS16 0 001S Lab M a trix Spike sll0 3 21 a 07 6 GLP10-01*01-15-049 DAL SS SS10 0 0005 sll0 3 21 a 07 7 10 006-80 solvent blank sll0 3 21 a 07 8 EC-110316-07 10 ng Extracted Curve Point sll0 3 21 a 07 9 10 006-80 solvent blank sll0 3 21 a 08 0 GLP10-01-01-15-049 Dup DAL SS SS10 0 0005 Lab Duplicate sll0 3 21 a 08 1 GLP10-01*01-15-049 LMS DAL SS SS10 0 0005 Lab M a trix Spike sll0 3 21 a 08 2 GLP10-01-01-15-050 DAL SS SS10 DB 0005 sll0 3 21 a 08 3 GLP10-01-01-15-050 Dup DAL SS SS10 DB 0005 Lab Duplicate sll0 3 21 a 08 4 GLP10-01-01-15-050 LMS DAL SS SS10 DB 0005 Lab M a trix Spike sll0 3 21 a 08 5 GLP10-01-01-15-051 DAL SS SS10 0 0015 sll0 3 21 a 08 6 GLP10-01-01-15-051 Dup DAL SS SS10 0 0015 Lab Duplicate sll0 3 21 a 08 7 GLP10-01-01-15-051 LMS DAL SS SS10 0 0015 Lab M a trix Spike sll0 3 21 a 08 8 GLP10-01-01-15-0S2 DAL SD SD20 0 0000 sll0 3 21 a 08 9 GLP10-01-01-15-052 Dup DAL SD SD20 0 0000 Lab Duplicate sll0 3 21 a 09 0 GLP10-01-01-15-052 LMS DAL SD SD20 0 0000 Lab M a trix Spike sll0 3 21 a 09 1 GLP10-01-01-15-053 DAL SD SD20 0 0005 sll0 3 21 a 09 2 GLP10-01-01-15-053 Dup DAL SD SD20 0 0005 Lab Duplicate 3M Study GLP10-01-02-15 Analyte Peak Name PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS Calculated Concentration Accuracy Record (n g /m L) N/A (%) M odified File Name N/A 0 sll0 3 21 a .w iff N/A N/A 0 sll0321a.w iff N/A N/A 0 sll0321a.w iff 0.165 83 0 sll0321a.w iff 0.467 93.6 0 sll0321a.w iff 0.797 107 0 sll0321a.w iff 1.07 108 2.51 101 0 sll0321a.w iff 0 sll0321a.w iff 5.14 103 0 sll0321a.w iff 9.98 100 0 sll0321a.w iff 26.6 107 0 sll0321a.w iff 49.9 100 0 sll0321a.w iff 98.6 98.9 0 sll0321a.w iff 197 99.1 500 100 0 sll0321a.w iff 0 sll0321a.w iff N/A N/A 0 sl!0321a.w iff N/A N/A 0 sll0321a.w iff N/A N/A 0 sll0321a.w iff N/A N/A 0 sll0321a.w iff N/A N/A 0 sll0321a.w iff <0 N/A 0 sll0321a.w iff 33,3 N/A 1 sll0321a.w iff 35.9 N/A 1 sll0321a.w iff 33.7 N/A 1 sll0321a.w iff 36.4 N/A 1 sll0321a.w iff 45.5 N/A 1 sll0321a.w iff 146 N/A 1 sll0321a.w iff 7.7 N/A 1 sll0321a.w iff 9.99 N/A 1 sll0321a.w iff 38.2 N/A 1 sll0321a.w iff S.63 N/A 1 sll0321a.w iff 3.98 N/A 1 sll0321a.w iff 9.34 N/A 1 sll0321a.w iff 58.6 N/A 1 sll0321a.w iff N/A N/A 0 sll0321a.w iff 2.45 98.4 0 sll0321a.w iff N/A N/A 0 sll0321a.w iff 56.7 N/A 1 sll0321a.w iff 171 N/A 1 sll0321a.w iff 0.559 N/A 1 sll0321a.w iff 1.35 N/A 1 sll0321a.w iff 2.54 N/A 1 sll0321a.w iff 1.93 N/A 1 sll0321a.w iff 1.87 N/A 1 sll0321a.w iff 7.46 N/A 1 sll0321a.w iff 2.73 N/A 1 sll0321a.w iff 2.38 N/A 1 sll0321a.w iff 7.16 N/A 1 sll0321a.w iff 1.72 N/A 1 sll0321a.w iff 1.49 N/A 8.23 N/A 1 sll0321a.w iff 1 sll0321a.w iff 3.66 N/A 1 sll0321a.w iff N/A N/A 0 sll0321a.w iff 5.23 105 0 sll0321a.w iff N/A N/A 0 sll0321a.w iff 3,44 N/A 1 sll0321a.w iff 7 N/A 1 sll0321a.w iff 3.23 N/A 4.25 N/A 1 sll0321a.w iff 1 sll0321a.w iff 9.21 N/A 1 sll0321a.w iff 0.794 N/A 1 sll0321a.w iff 0.77 N/A 1 sll0321a.w iff 1.87 N/A 1 sll0321a.w iff 2.47 N/A 0 sll0321a.w iff 3.74 N/A 1 sll0321a.w iff 8.04 N/A 1 sll0321a.w iff 6.67 N/A 1 sll0321a.w iff 6.84 N/A 1 sll0321a.w iff 34.7 N/A 1 sll0321a.w iff 9.55 N/A 1 sll0321a.w iff N/A N/A 0 sll0321a.w iff 10.1 101 0 sll0321a.w iff N/A N/A 0 sll0321a.w iff 12.7 N/A 1 sll0321a.w iff 36.4 N/A 1 sll0321a.w iff 10.4 N/A 1 sll0321a,w iff 9.45 N/A 1 sll0321a.w iff 40 N/A 1 sll0321a.w iff 33.6 N/A 1 sll0321a.w iff 37.5 N/A 1 sll0321a,w iff 129 N/A 1 sll0321a.w iff 145 N/A 1 sll0321a.w iff 187 N/A 1 sll0321a.w iff 409 N/A 121 N/A 1 sll0321a.w iff 1 sll0321a.w iff 129 N/A 1 sll0321a.w iff Page 5 of 8 Page 60 of 514 s110321a Sam pleName Sample IO s ll0 3 2 1 a 0 9 3 GLP10-01-01-15-053 LMS DAL SD SD20 0 0005 Lab M a trix Spike sll0 3 21 a 09 4 GLPlO-01-01-15-054 DAL SD SD20 0 0015 sll0 3 21 a 09 5 10 006-80 solvent blank s ll0 3 2 1 a 0 9 6 EC-U0316-05 2.5 ng Extracted Curve Point sll0 3 21 a 09 7 10 006-80 solvent blank sll0 3 21 a 09 8 GLPlO-01-01-15-054 Dup DAL SD SD20 0 0015 Lab Duplicate sll0 3 21 a 09 9 GLPlO-01-01-15-054 LMS DAL SD SD20 0 0015 Lab M a trix Spike S ll0 3 2 1 a l0 0 GLPIO-Ol-Ol-15-055 DAL SD SD23 0 0000 s ll0 3 2 1 a l0 1 GLPIO-Ol-Ol-15-055 Dup DAL SD SD23 0 0000 Lab Duplicate s ll0 3 2 1 a !0 2 GLP10-01-01-15-05S LMS DAL SD SD23 0 0000 Lab M a trix Spike $110321al03 GLPIO-Ol-Ol-15-056 DAL SD SD23 0 0005 s ll0 3 2 1 a l0 4 GLP10-01-01-1S-056 Dup DAL SD SD23 0 0005 Lab Duplicate s ll0 3 2 1 a !0 5 GLPlO-01-01-15-056 LMS DAL SD SD23 0 0005 Lab M a trix Spike s ll0 3 2 1 a l0 6 GLPIO-Ol-Ol-15-057 DAL SD SD23 0 0015 s ll0 3 2 1 a l0 7 GLP10-01-01-15-057 Dup DAL SD SD23 0 0015 Lab Duplicate s ll0 3 2 1 a l0 8 GLPlO-01-01-15-057 LMS DAL SD SD23 0 0015 Lab M a trix Spike s l!0 3 2 1 a l0 9 GLPlO-01-01-15-058 DAL SS SS28 0 0000 s ll0 3 2 1 a ll0 GLPlO-01-01-15-058 Dup DAL SS SS28 0 0000 Lab Duplicate s ll0 3 2 1 a lll GLP10-01-01-15-OS8 LMS DAL SS SS28 0 0000 Lab M a trix Spike s ll0 3 2 1 a ll2 GLP10-01-01-15-0S9 DAL SS SS28 0 0005 s ll0 3 2 1 a ll3 10 006-80 solvent blank s ll0 3 2 1 a ll4 EC-110316-06 5 ng Extracted Curve Point s ll0 3 2 1 a ll5 10 006-80 solvent blank s ll0 3 2 1 a ll6 GLPlO-01-01-15-059 Dup DAL SS SS28 0 0005 Lab Duplicate s ll0 3 2 1 a ll7 GLPlO-01-01-15-059 LMS DAL SS SS28 0 0005 Lab M a trix Spike S ll0 3 2 1 a ll8 GLPlO-01-01-15-060 DAL SS SS28 DB 0005 s ll0 3 2 1 a l! 9 GLPlO-01-01-15-060 Dup DAL SS SS28 DB 0005 Lab Duplicate s ll0 3 2 1 a l2 0 GLP10-01-01-1S-060 LMS DAL SS SS28 DB 0005 Lab M a trix Spike s ll0 3 2 1 a l2 1 GLPlO-01-01-15-061 DAL SS SS28 0 0015 s l!0 3 2 1 a l2 2 GLP10-01-01-15-061 Dup DAL SS SS28 0 0015 Lab Duplicate s l!0 3 2 1 a l2 3 GLP10-01-01-15-061 LMS DAL SS SS28 0 0015 Lab M a trix Spike s l!0 3 2 1 a l2 4 GLPlO-01-01-15-062 DAL SS SS27 0 0000 s ll0 3 2 1 a l2 5 GLPlO-01-01-15-062 Dup DAL SS SS27 0 0000 Lab Duplicate s ll0 3 2 1 a l2 6 GLPlO-01-01-15-062 LMS OAL SS SS27 0 0000 Lab M a trix Spike S ll0 3 2 1 a l2 7 GLPlO-01-01-15-063 DAL SS SS27 0 0005 s ll0 3 2 1 a l2 8 GLPlO-01-01-15-063 Dup DAL SS SS27 0 0005 Lab Duplicate s ll0 3 2 1 a l2 9 GLPlO-01-01-15-063 LMS DAL SS SS27 0 0005 Lab M a trix Spike s ll0 3 2 1 a l3 0 GLPlO-01-01-15-064 DAL SS SS27 0 001S s ll0 3 2 1 a l3 1 10 006-80 solvent blank s ll0 3 2 1 a l3 2 EC-110316-07 10 ng Extracted Curve Point s ll0 3 2 1 a l3 3 10 006-80 solvent blank s ll0 3 2 1 a l3 4 GLPlO-01-01-15-064 Dup DAL SS SS27 0 001S Lab Duplicate s ll0 3 2 1 a l3 5 GLPlO-01-01-15-064 LMS DAL SS SS27 0 0015 Lab M a trix Spike s ll0 3 2 1 a l3 6 GLP10-01-01-1S-065 DAL SS SS22 0 0000 s ll0 3 2 1 a l3 7 GLPlO-01-01-15-065 Dup DAL SS SS22 0 0000 Lab Duplicate $110321al38 GLPlO-01-01-15-065 LMS DAL SS SS22 0 0000 Lab M a trix Spike s ll0 3 2 1 a l3 9 GLP10-01-01-15-066 DAL SS SS22 0 0005 s ll0 3 2 1 a l4 0 GLPlO-01-01-15-066 Dup DAL SS SS22 0 OOOS Lab Duplicate s ll0 3 2 1 a l4 1 GLPIO-Ol-Ol-15-066 LMS DAL SS SS22 0 0005 Lab M a trix Spike s ll0 3 2 1 a l4 2 GLPlO-01-01-15-067 DAL SS SS22 DB 0005 $110321al43 GLPlO-01-01-15-067 Dup DAL SS SS22 DB 0005 Lab Duplicate s ll0 3 2 1 a l4 4 GLPlO-01-01-15-067 LMS DAL SS SS22 DB 0005 Lab M a trix Spike s ll0 3 2 1 a l4 5 GLPlO-01-01-15-068 DAL SS SS22 0 0015 s ll0 3 2 1 a l4 6 GLPlO-01-01-15-068 Dup DAL SS SS22 0 0015 Lab Duplicate s ll0 3 2 1 a l4 7 GLP10-01-01-1S-068 LMS DAL SS SS22 0 0015 Lab M a trix Spike s ll0 3 2 1 a l4 8 GLP10-01-01-1S-069 DAL SS SS210 0000 s ll0 3 2 1 a l4 9 10 006-80 solvent blank s ll0 3 2 1 a l5 0 EC-110316-05 2.5 ng Extracted Curve Point s ll0 3 2 1 a l5 1 10 006-80 solvent blank s ll0 3 2 1 a l5 2 GLPlO-01-01-15-069 Dup DAL SS SS210 0000 Lab Duplicate s ll0 3 2 1 a l5 3 GLPlO-01-01-15-069 LMS DAL SS SS210 0000 Lab M a trix Spike S ll0 3 2 1 a l5 4 GLPlO-01-01-15-070 DAL SS SS210 0005 s ll0 3 2 1 a l5 5 GLP10-01-01-15-070 Dup DAL SS SS210 0005 Lab Duplicate s ll0 3 2 1 a l5 6 GLPlO-01-01-15-070 LMS DAL SS SS210 0005 Lab M a trix Spike s ll0 3 2 1 a l5 7 GLPlO-01-01-15-071 DAL SS SS210 0015 s ll0 3 2 1 a l5 8 GLP10-01-01-15-071 Dup DAL SS SS210 0015 Lab Duplicate s ll0 3 2 1 a lS 9 GLP10-01-01-15-071 LMS DAL SS SS210 0015 Lab M a trix Spike s ll0 3 2 1 a l6 0 GLPlO-01-01-15-072 DAL SD SD18 0 0000 s!10 3 21 al61 GLPlO-01-01-15-072 Dup DAL SD SD18 0 0000 Lab Duplicate s ll0 3 2 1 a l6 2 GLPlO-01-01-15-072 LMS DAL SD SD18 0 0000 Lab M a trix Spike s ll0 3 2 1 a l6 3 GLPlO-01-01-15-073 DAL SD SD18 0 0005 s ll0 3 2 1 a l6 4 GLP10-01-01-15-073 Dup DAL SD SD18 0 OOOS Lab Duplicate s ll0 3 2 1 a l6 5 GLP10-01-01-1S-073 LMS DAL SD SD18 0 0005 Lab M a trix Spike s ll0 3 2 1 a l6 6 10 006-80 solvent blank s ll0 3 2 1 a l6 7 EC-110316-06 5 ng Extracted Curve Point s ll0 3 2 1 a l6 8 10 006-80 solvent blank sll0 3 2 1 a 0 0 1 IO 006-80 solvent blank sll0 3 2 1 a 0 0 2 10 006-80 solvent blank sll0 3 2 1 a 0 0 3 EC-110316-09 50 ng W arm up standard sll0 3 2 1 a 0 0 4 EC-110316-09 50 ng W arm up standard sll0 3 21 a 00 5 10 006-80 solvent blank $110321a006 10 006-80 solvent blank sll0 3 2 1 a 0 0 7 10 006-80 solvent blank sll0 3 2 1 a 0 0 8 10 006-80 solvent blank sll0 3 2 1 a 0 0 9 10 006-80 solvent blank s!10321a010 EC-110316-010.2 ng Extracted Curve Point 3M Study GLP10-01-02-15 Analyte Peak Name PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS Calculated Concentration Accuracy Record (n g /m L) N/A N/A (%) 380 N/A 143 N/A N/A 2.55 N/A M odified File Name 1 sll0321a.w iff 1 sll0321a.w iff 0 sll0321a.w iff 102 0 s ll0 3 2 1 a .w iff 0 sll0321a.w iff 129 N/A 399 N/A 56.5 N/A 62.5 N/A 159 N/A 25.3 N/A 26 N/A 1 sll0321a.w iff 1 sll0321a,w iff 1 sll0321a.w iff 1 sll0321a.w iff 1 sll0321a.w iff 1 sll0321a.w iff 1 sll0321a.w iff 51.5 N/A 1 sll0321a.w iff 18.9 N/A 18.9 N/A 44.6 N/A 0.77 N/A 1 sll0321a.w iff 1 sll0321a.w iff 1 sll0321a.w iff 1 sll0321a.w iff 0.896 N/A 1 sll0321a.w iff 2.06 N/A 0 sll0321a.w iff 0.82 N/A N/A N/A 4.92 98.6 N/A N/A 0 sll0321a.w iff 0 sll0321a.w iff 0 sll0321a.w iff 0 sll0321a.w iff 0.812 N/A 2 N/A 1 sll0321a.w iff 1 sll0321a.w iff 1.12 N/A 1 sll0321a.w iff 0.926 N/A 1 sll0321a.w iff 2.34 N/A 4.72 N/A 1 sll0321a.w iff 1 sll0321a.w iff 4.22 N/A 1 sll0321a.w iff 9.66 N/A 1 sll0321a.w iff 0.314 N/A 0.3 N/A 1 sll0321a.w iff 1 sll0321a.w iff 1.52 N/A 0.613 N/A 0.45 N/A 1.61 N/A 1 sll0321a.w iff 1 sll0321a.w iff 1 sll0321a.w iff 1 sll0321a.w iff 0.415 N/A 0 5110321a.wiff N/A N/A 9.78 98.1 N/A N/A 0.366 N/A 1.54 N/A 0 sll0321a.w iff 1 5110321a.wiff 0 5110321a.wiff 1 sll0321a.w iff 0 sll0321a.w iff 3.63 N/A 1 s!10321a.wiff 3.94 N/A 9.37 N/A 2.61 N/A 2.76 N/A 1 sll0321a.w iff 1 s!10321a.wiff 1 sll0321a.w iff 1 5110321a.wiff 8.33 N/A 2.65 N/A 1 sll0321a.w iff 1 sll0321a.w iff 2.56 N/A 1 sll0321a.w iff 8.03 N/A 1 sll0321a.w iff 0.896 N/A 1.27 N/A 2.36 N/A 1 sll0321a.w iff 1 sll0321a.w iff 1 sll0321a.w iff 14.2 N/A 1 S ll0321a.w iff N/A N/A 2.56 103 N/A N/A 0 sll0321a.w iff 0 sll0321a.w iff 0 s!10321a.wiff 8.97 N/A 1 s!10321a.wiff 33.8 N/A 1 s!10321a.wiff 12.3 N/A 11.1 N/A 39.8 N/A 11.8 N/A 1 sll0321a.w iff 1 sll0321a.w iff 1 sll0321a.w iff 1 sll0321a.w iff 14 N/A 38.3 N/A 110 N/A 1 5110321a.wiff 1 5110321a.wiff 1 sll0321a.w iff 99.8 N/A 379 N/A 1 sll0321a.w iff 1 sll0321a.w iff 104 N/A 1 sll0321a.w iff 87.6 N/A 222 N/A 1 S ll0321a.w iff 1 sll0321a.w iff N/A N/A 0 sll0321a.w iff 5.48 110 N/A N/A N/A N/A 0 sll0321a.w iff 0 sll0321a.w iff 0 sll0321a.w iff N/A N/A 0 sll0321a.w iff N/A N/A N/A N/A N/A N/A 0 sll0321a.w iff 0 sll0321a.w iff 0 sll0321a.w iff N/A N/A 0 sll0321a.w iff N/A N/A N/A N/A 0 sll0321a.w iff 1 sll0321a.w iff N/A N/A 1 sll0321a.w iff 0.191 95.6 0 sll0321a.w iff Page 6 of 8 Page 61 of 514 Page 62 of 514 Page 7 of 8 s i 10321a li sa; m il w " If^ g s Ws m asg 5 s s | g s s s t | i , . TM -.= :i .> 'f c '- . W BBm hlmmmmmmmmmmmmmmmmmmmmmmmmtmmmim iliiiill! 11111111111 * ss! s s j ii i! il 33 33 J I SS i ,f ci il ci I il il l il 33 33 33 ih liliiil illh lilil 33 33 33 33 33 33 33 S5 iljl.il. , . i i J M I m m its tK it * , i t m m m m s ,, S55i:;5S55,, B * I J = ix2 2 ix2 2 s 2 s I d 2 s o i s 2 s 2 o S o d s 2 s x S 3S S s 2 s s 2 s2 2 s S 2 8 2 2 S jj 3M Study GLP10-01 -02-15 m m m m n m m m m m m m v 3 |S S ||S S S |S ||||||||| 'S 'S 'S ' S 'S ' S ' S S ' ili iS ii liiS iiiillii iiliiiliiiiiiiiiliiiili ;883333939393988i39ii3i88888i399993393399338 : s s -a -a s s s Page 63 of 514 111111111111111111111111111111111111111111111111111111111111111111111111 lili l ii i I 1-t iH o O - WWW 1-10 0 I I ....................... | a s ss lilllllllllllllllll llllllllllllllfll flflSIIIIIIIIIIII flllllflllllllll Is- ^ I f S - a S ^ I S i S S S S S 3 5 S 3 l S S S S 3 3 S S $ S 5 2 S ^ S S 5 3 S 8 s3sI a F p s i l s s i ai - '! f - II ii b it S * ! ____ * *I ........ ...... 2 f llllllllllllllllllllllllllllilllllllllllllllllllllllllllllllllllllllllll i Page 8 of 8 s110321a lili lilil lili lilil lili lilil lili lilil I I 55 33 I I 33 33 33 33 33 I I 35 35 33 33 53 33 - 11,11 I l J i J I . II 11 i M l I . il Ii i U M ! . lllll 1 i l i ! I l i l l i l l l l i filil!!! 1 1 ssssssgssggsuss 1 sBSssassgssRssP! 3 ssS saa sa S ssS sss u a sa ssS ssssS isss J g1132I2I3121g3g13S3sIIs3i h 3l 3atgi2sSlsilsSIsIS31<1<iS{ I1{121a32I2I32121a3121a3I2Ia3 | I5| 2123a32121a3132aSlai2l il *3 I' llllilllillllllllllllllllliiiillliiiilllll 3M Study GLP10-01 -02-15 si10325b Sample Name s ll0 3 2 5 b 0 0 1 s ll0 3 2 5 b 0 0 2 s ll0 3 2 5 b 0 0 3 s ll0 3 2 S b 0 0 4 sll0325b005 s ll0 3 2 S b 0 0 6 s ll0 3 2 S b 0 0 7 s ll0 3 2 5 b 0 0 8 s ll0 3 2 S b 0 0 9 s ll0 3 2 5 b 0 1 0 s ll0 3 2 5 b 0 1 1 s ll0 3 2 5 b 0 1 2 s ll0 3 2 5 b 0 1 3 s ll0 3 2 5 b 0 1 4 s ll0 3 2 5 b 0 1 5 s ll0 3 2 5 b 0 1 6 s ll0 3 2 5 b 0 1 7 s ll0 3 2 S b 0 1 8 s ll0 3 2 5 b 0 1 9 s ll0 3 2 S b 0 2 0 s ll0 3 2 5 b 0 2 1 Sll0325b022 s ll0 3 2 5 b 0 2 3 s ll0 3 2 5 b 0 2 4 s ll0 3 2 5 b 0 2 5 s ll0 3 2 S b 0 2 6 s ll0 3 2 5 b 0 2 7 s ll0 3 2 5 b 0 2 8 s ll0 3 2 5 b 0 2 9 s ll0 3 2 5 b 0 3 0 s ll0 3 2 S b 0 3 1 s ll0 3 2 5 b 0 3 2 s ll0 3 2 5 b 0 3 3 s ll0 3 2 5 b 0 3 4 s ll0 3 2 5 b 0 3 5 s ll0 3 2 5 b 0 3 6 s ll0 3 2 5 b 0 3 7 s!10325b038 s ll0 3 2 S b 0 3 9 s ll0 3 2 5 b 0 4 0 s ll0 3 2 5 b 0 4 1 s ll0 3 2 5 b 0 4 2 s ll0 3 2 5 b 0 4 3 s l!0 3 2 S b 0 4 4 s ll0 3 2 S b 0 4 5 s ll0 3 2 5 b 0 4 6 s ll0 3 2 5 b 0 4 7 s ll0 3 2 5 b 0 4 8 s ll0 3 2 5 b 0 4 9 s ll0 3 2 S b 0 5 0 s ll0 3 2 5 b 0 5 1 s ll0 3 2 S b 0 S 2 s ll0 3 2 5 b 0 5 3 s ll0 3 2 5 b 0 S 4 sll0 3 2 5 b 0 S 5 s ll0 3 2 5 b 0 S 6 sU0325b057 s ll0 3 2 5 b 0 5 8 sll032Sb059 S ll0 3 2 5 b 0 6 0 sll032Sb061 s ll0 3 2 5 b 0 6 2 s ll0 3 2 5 b 0 6 3 S ll0 3 2 5 b 0 6 4 sll0325b065 sl!0 3 2 S b 0 6 6 $11032Sb067 s ll0 3 2 S b 0 6 8 s ll0 3 2 5 b 0 6 9 s ll0 3 2 5 b 0 7 0 s ll0 3 2 5 b 0 7 1 sll0325b072 s ll0 3 2 5 b 0 7 3 sll032Sb074 s!1032Sb075 s!10325b076 s ll0 3 2 5 b 0 7 7 sll032Sb078 s ll0 3 2 5 b 0 7 9 sll032Sb080 s ll0 3 2 5 b 0 8 1 sl!0325b082 s ll0 3 2 S b 0 8 3 s!10325b084 Sample ID 10 006-80 solvent blank 10 006-80 solvent blank EC-110316-09 50 ng W arm up standard EC-110316-09 50 ng W arm up standard 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank EC-110316-010.2 ng Extracted Curve Point EC-110316-02 0.5 ng Extracted Curve Point EC-110316-03 0.75 ng Extracted Curve Point EC-110316-04 1 ng Extracted Curve Point EC-110316-05 2.5 ng Extracted Curve Point EC-110316-06 5 ng Extracted Curve Point EC-110316-07 10 ng Extracted Curve Point EC-110316-08 25 ng Extracted Curve Point EC-110316-09 50 ng Extracted Curve Point EC-110316-10 100 ng Extracted Curve Point EC-110316-11 200 ng Extracted Curve Point EC-110316-12 500 ng Extracted Curve Point 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank MB-110316-01 M ethod Blank w /o IS MB-110316-04 M ethod Blank w / IS LCS-110316-07 300ng LCS in TCR-842 LCS-110316-08 300ng LCS in TCR-842 LCS-110316-09 300ng LCS in TCR-842 GLP10-01-01-15-074 DAL SD SD18 0 0015 GLP10-01-01-15-074 Dup DAL SD SD18 0 0015 Lab Duplicate GLP10-01-01-15-074 LMS DAL SD SD18 0 001S Lab M a trix Spike GLP10-01-01-15-075 DAL SD SD19 0 0000 GLP10-01-01-15-075 Dup DAL SD SD19 0 0000 Lab Duplicate GLP10-01-01-15-075 LMS DAL SD SD19 0 0000 Lab M a trix Spike GLP10-01-01-15-076 DAL SO SD19 0 0005 GLP10-01-01-15-076 Dup DAL SD SD19 0 0005 Lab Duplicate GLP10-01-01-15-076 LMS DAL SD SD19 0 0005 Lab M a trix Spike GLP10-01-01-15-077 DAL SD SD19 0 0015 10 006-80 solvent blank EC-110316-05 2.5 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-077 Dup DAL SD SD19 0 0015 Lab Duplicate GLP10-01-01-15-077 LMS DAL SD SD19 0 0015 Lab M atrix Spike GLP10-01-01-15-079 DAL SS SS26 0 0000 GLP10-01-01-15-079 Dup DAL SS SS26 0 0000 Lab Duplicate GLP10-01-01-15-079 LMS DAL SS SS26 0 0000 Lab M a trix Spike GLP10-01-01-15-080 DAL SS SS26 DB 0000 GLPlO-01-01-15-080 Dup DAL SS SS26 DB 0000 Lab Duplicate GLP10-01-01-15-080 LMS DAL SS SS26 DB 0000 Lab M a trix Spike GLP10-01-01-15-081 DAL SS SS26 0 0005 GLP10-01-01-15-081 Dup DAL SS SS26 0 0005 Lab Duplicate GLP10-01-01-15-081 LMS DAL SS SS26 0 000S Lab M a trix Spike GLP10-01-01-15-082 DAL SS SS26 0 0015 GLP10-01-01-15-082 Dup DAL SS SS26 0 0015 Lab Duplicate GLP10-01-01-15-082 LMS DAL SS SS26 0 0015 Lab M a trix Spike GLP10-01-01-15-084 DAL SS SS12 0 0015 10 006-80 solvent blank EC-110316-06 5 ng Extracted Curve Point 10 0 0 6 -8 0 solvent blank GLP10-01-01-1S-084 Dup DAL SS SS12 0 0015 Lab Duplicate GLP10-01-01-1S-084 LMS DAL SS SS12 0 0015 Lab M a trix Spike GLP10-01-01-15-085 DAL SS SS19 0 0015 GLPlO-01-01-15-085 Dup DAL SS SS19 0 001S Lab Duplicate GLP10-01-01-15-08S LMS DAL SS SS19 0 0015 Lab M a trix Spike GLP10-01-01-15-086 DAL SS SS20 0 0015 GLP10-01-01-15-086 Dup DAL SS SS20 0 0015 Lab Duplicate GLP10-01-01-15-086 LMS DAL SS SS20 0 0015 Lab M a trix Spike GLP10-01-01-15-087 DAL SS SS14 0 0015 GLP10-01-01-15-087 Dup DAL SS SS14 0 0015 Lab Duplicate GLP10-01-01-15-087 LMS DAL SS SS14 0 0015 Lab M a trix Spike GLP10-01-01-15-088 DAL SS SS17 0 0015 GLP10-01-01-15-088 Dup DAL SS SS17 0 0015 Lab Duplicate GLP10-01-01-15-088 LMS DAL SS SS17 0 0015 Lab M a trix Spike GLP10-01-01-15-089 DAL SS SS13 0 001S 10 006-80 solvent blank EC-110316-07 10 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-089 Dup DAL SS SS13 0 0015 Lab Duplicate GLP10-01-01-15-089 LMS DAL SS SS13 0 0015 Lab M a trix Spike GLP10-01-01-15-090 DAL SS SS15 0 0015 GLP10-01-01-15-090 Dup DAL SS SS15 0 0015 Lab Duplicate GLP10-01-01-15-090 LMS DAL SS SS15 0 0015 Lab M a trix Spike Analyte Peak Name MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS Calculated Concentration Accuracy Record (n g /m L) N/A (%) M odified File Name N/A 0 s!10325b.wiff N/A N/A 0 sll0325b.w iff N/A N/A 0 sll0325b.w iff N/A N/A 0 sll0325b.w iff N/A N/A N/A N/A 0 sll0325b.w iff 0 sll0325b.w iff N/A N/A 0 sll0325b.w iff N/A N/A 0 sll0325b.w iff N/A N/A 0.0309 16.2 0 sll0325b.w iff 0 sll0325b.w iff 0.367 76.8 0 sll0325b.w iff 0.635 1.09 2.29 88.5 114 95.7 0 sll0325b.w iff 0 sll032S b.w iff 0 sll0325b.w iff 5.03 105 1 sll0325b.w iff 10.4 108 0 sll0325b.w iff 26.4 50.5 94.1 110 106 98.4 0 sll0325b.w iff 0 sll0325b.w iff 0 sll0325b.w iff 184 96.3 0 sll0325b.w iff 480 101 0 sll0325b.w iff N/A N/A N/A N/A 0 sll0325b.w iff 0 sll0325b.w iff N/A N/A N/A N/A N/A N/A 3.21 N/A 0 sll0325b.w iff 0 sll0325b.w iff 0 sll0325b.w iff 0 sll0325b.w iff 3.41 N/A 0 sll0325b.w iff 3.47 N/A 0 sll0325b.w iff 3.54 N/A 3.11 N/A 0 sll0325b.w iff 0 sll0325b.w iff 3.44 N/A 0 sll0325b.w iff 3.3 N/A 1 sll0325b.w iff 3.49 N/A 3.25 N/A 0 sll0325b.w iff 0 sll0325b.w iff 2.93 N/A 1 sll0325b.w iff 3.2 N/A 3.29 N/A 3.33 N/A 3.35 N/A 0 sll0325b.w iff 0 sll0325b.w iff 0 sll0325b.w iff 0 sll0325b.w iff N/A N/A 0 sll0325b.w iff 2.42 101 N/A N/A 3.13 N/A 0 sll0325b.w iff 0 S ll0325b,w iff 0 sll0325b.w iff 3.34 N/A 0 sll0325b.w iff 3.01 N/A 0 sll0325b.w iff 3.06 N/A 3.43 N/A 3.18 N/A 0 sll0325b.w iff 0 sll0325b.w iff 0 sll0325b.w iff 3.08 N/A 0 sll0325b.w iff 3.25 N/A 3.09 N/A 0 sll0325b.w iff 0 sll0325b.w iff 3.13 N/A 0 sll0325b.w iff 3.36 N/A 0 sll0325b.w iff 3.51 N/A 3.64 N/A 0 sll0325b.w iff 0 sll0325b.w iff 3.08 N/A 0 sll0325b.w iff 3.65 N/A 0 sll0325b.w iff N/A N/A 5.17 108 N/A N/A 3.16 N/A 0 sll0325b.w iff 0 sll0325b.w iff 0 sll032S b.w iff 0 sll0325b.w iff 4.23 N/A 0 sll0325b.w iff 3.3 N/A 0 sll0325b.w iff 3.27 N/A 0 sll0325b.w iff 3.1 N/A 0 sll0325b.w iff 2.98 N/A 0 sll0325b.w iff 2.95 N/A 3.42 N/A 0 sll0325b.w iff 0 sll0325b.w iff 3.24 N/A 0 sll0325b.w tff 3.29 N/A 1 sll0325b.w iff 3.04 N/A 3.17 N/A 3.23 N/A 3.22 N/A 0 sll0325b.w iff 0 sll0325b.w iff 0 sll0325b.w iff 0 sll0325b.w iff 3.25 N/A 0 sll0325b.w iff N/A N/A 0 sll0325b.w iff 10.1 106 N/A N/A 3.03 N/A 0 sll0325b.w iff 0 sll0325b.w iff 0 sll0325b.w iff 3.08 N/A 3.07 N/A 0 sll032S b.w iff 0 sll032S b.w iff 2.81 N/A 0 S ll0325b.w iff 3.15 N/A 0 sll0325b.w iff 3M Study GLP10-01-02-15 Page 1 of 5 Page s110325b Sample Name s ll0 3 2 5 b 0 8 5 s ll0 3 2 5 b 0 8 6 s ll0 3 2 5 b 0 8 7 s ll0 3 2 5 b 8 8 sll032Sb089 s ll0 3 2 5 b 0 9 0 sll032Sb091 sll032Sb092 s ll0 3 2 S b 0 9 3 s ll0 3 2 5 b 0 9 4 sll0 3 25 b 0 l s ll0 3 2 5 b 0 0 2 s ll0 3 2 5 b 0 0 3 s ll0 3 2 5 b 0 0 4 s ll0 3 2 5 b 0 0 5 s ll0 3 2 S b 0 0 6 s ll0 3 2 5 b 0 0 7 s ll0 3 2 5 b 0 0 8 s!10325b009 s ll0 3 2 5 b 0 1 0 s ll0 3 2 5 b 0 1 1 s ll0 3 2 5 b 1 2 s ll0 3 2 S b 0 1 3 s ll0 3 2 5 b 0 1 4 s ll0 3 2 S b 0 1 5 s ll0 3 2 5 b 0 1 6 S ll0 3 2 5 b 0 1 7 s ll0 3 2 5 b 0 1 8 Sll0325b019 s ll0 3 2 S b 0 2 0 s ll0 3 2 S b 0 2 1 s ll0 3 2 S b 0 2 2 s ll0 3 2 5 b 0 2 3 s ll0 3 2 5 b 0 2 4 s ll0 3 2 S b 0 2 5 s ll0 3 2 S b 0 2 6 s ll0 3 2 5 b 0 2 7 s ll0 3 2 5 b 0 2 8 s ll0 3 2 5 b 0 2 9 S ll0 3 2 5 b 0 3 0 s ll0 3 2 5 b 0 3 1 s!10325b032 s ll0 3 2 5 b 0 3 3 s ll0 3 2 5 b 0 3 4 s ll0 3 2 5 b 0 3 5 s ll0 3 2 S b 0 3 6 s ll0 3 2 5 b 0 3 7 s ll0 3 2 5 b 0 3 8 s ll0 3 2 5 b 0 3 9 S ll0 3 2 5 b 0 4 0 s ll0 3 2 5 b 0 4 1 s ll0 3 2 5 b 0 4 2 s ll0 3 2 5 b 0 4 3 s ll0 3 2 5 b 0 4 4 s ll0 3 2 5 b 0 4 5 s ll0 3 2 5 b 0 4 6 s ll0 3 2 5 b 0 4 7 s ll0 3 2 S b 0 4 8 $110325b049 s ll0 3 2 5 b 0 5 0 s ll0 3 2 5 b 0 5 1 s ll0 3 2 5 b 0 5 2 s ll0 3 2 5 b 0 5 3 s ll0 3 2 5 b 0 5 4 s ll0 3 2 S b 0 5 S s ll0 3 2 5 b 0 S 6 s ll0 3 2 5 b 0 5 7 s ll0 3 2 5 b 0 5 8 $110325b059 Sll0325b060 s ll0 3 2 5 b 0 6 1 s ll0 3 2 5 b 0 6 2 s ll0 3 2 5 b 0 6 3 s ll0 3 2 5 b 0 6 4 s ll0 3 2 5 b 0 6 5 s ll0 3 2 5 b 0 6 6 s ll0 3 2 5 b 0 6 7 $110325b068 s ll0 3 2 5 b 0 6 9 s ll0 3 2 5 b 0 7 0 s ll0 3 2 S b 0 7 1 $110325b072 s ll0 3 2 5 b 0 7 3 Sll0325b074 s ll0 3 2 5 b 0 7 5 s!10325b076 Sample ID GLPlO-Ol-Ol-lS-091 DAL SS SS18 0 0015 GLPlO-Ol-Ol-lS-091 Dup DAL SS SS18 0 0015 Lab Duplicate GLP10-01-01-1S-091LMS DAL SS SS18 0 0015 Lab M atrix Spike GLP10-01-01-15-092 DAL SS SS110 0015 GLP10-01-01-15-092 Dup DAL SS SS110 0015 Lab Duplicate GLP10-01-01-15-092 LMS DAL SS SS110 0015 Lab M a trix Spike 10 0 0 6 -8 0 solvent blank EC-110316-05 2,5 ng Extracted Curve Point 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank EC-110316-09 50 ng W arm up standard EC-110316-09 50 ng W arm up standard 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank EC-110316-010.2 ng Extracted Curve Point EC-110316-02 0.5 ng Extracted Curve Point EC-110316-03 0.75 ng Extracted Curve Point EC-110316-04 1 ng Extracted Curve Point EC-110316-05 2.5 ng Extracted Curve Point EC-110316-06 5 ng Extracted Curve Point EC-110316-07 10 ng Extracted Curve Point EC-110316-08 25 ng Extracted Curve Point EC-110316-09 50 ng Extracted Curve Point EC-110316-10 100 ng Extracted Curve Point EC-110316-11 200 ng Extracted Curve Point EC-110316-12 500 ng Extracted Curve Point 10 006-80 solvent blank 10 0 0 6 -8 0 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank MB-110316-01 M ethod Blank w /o IS MB-110316-04 M ethod Blank w / IS LCS-110316-07 300ng LCS in TCR-842 LCS-110316-08 300ng LCS in TCR-842 LCS-110316-09 300ng LCS in TCR-842 GLP10-01-01-15-074 DAL SD SD18 0 0015 GLP10-01-01-15-074 Dup DAL SD SD18 0 001S Lab Duplicate GLP10-01-01-15-074 LMS DAL SD SD18 0 0015 Lab M a trix Spike GLP10-01-01-15-07S DAL SD SD19 0 0000 GLP10-01-01-15-075 Dup DAL SD SD19 0 0000 Lab Duplicate GLP10-01-01-1S-075 LMS DAL SD SD19 0 0000 Lab M a trix Spike GLP10-01-01-15-076 DAL SD SD19 0 0005 GLP10-01-01-15-076 Dup DAL SD SD19 0 0005 Lab Dupiicate GLP10-01-01-15-076 LMS DAL SD SD19 0 000S Lab M a trix Spike GLP10-01-01-15-077 DAL SD SD19 0 0015 10 006-80 solvent blank EC-110316-05 2.5 ng Extracted Curve Point 10 006*80 solvent blank GLP10-01-01-15-077 Dup DAL SD SD19 0 0015 Lab Duplicate GLP10-01-01-15-077 LMS DAL SD SD19 0 0015 Lab M a trix Spike GLP10-01-01-15-079 DAL SS SS26 0 0000 GLP10-01-01-15-079 Dup DAL SS SS26 0 0000 Lab Duplicate GLP10-01-01-15-079 LMS DAL SS SS26 0 0000 Lab M a trix Spike GLP10-01-01-15-080 DAL SS SS26 DB 0000 GLPlO-01-01-15-080 Dup DAL SS SS26 DB 0000 Lab Duplicate GLP10-01-01-15-080 LMS DAL SS SS26 DB 0000 Lab M a trix Spike GLP10-01-01-15-081 DAL SS SS26 0 0005 GLP10-01-01-15-081 Dup DAL SS SS26 0 0005 Lab Duplicate GLP10-01-01-15-081 LMS DAL SS SS26 0 0005 Lab M a trix Spike GLP10-01-01-15-082 DAL SS SS26 0 001S GLP10-01-01-15-082 Dup DAL SS SS26 0 0015 Lab Duplicate GLP10-01-01-15-082 LMS DAL SS SS26 0 0015 Lab M a trix Spike GLP10-01-01-1S-084 DAL SS SS12 0 0015 10 006-80 solvent blank EC-110316-06 5 ng Extracted Curve Point 10 0 0 6 -8 0 solvent blank GLP10-01-01-1S-084 Dup DAL SS SS12 0 0015 Lab Duplicate GLP10-01-01-15-084 LMS DAL SS SS12 0 0015 Lab M a trix Spike GLP10-01-01-15-085 DAL SS SS19 0 0015 GLP10-01-01-15-08S Dup DAL SS SS19 0 0015 Lab Dupiicate GLP10-01-01-15-085 LMS DAL SS SS19 0 0015 Lab M a trix Spike GLP10-01-01-15-086 DAL SS SS20 0 0015 GLP10-01-01-15-086 Dup DAL SS SS20 0 0015 Lab Duplicate GLP10-01-01-15-086 LMS DAL SS SS20 0 001S Lab M atrix Spike GLP10-01-01-15-087 DAL SS SS14 0 0015 GLP10-01-01-15-087 Dup DAL SS SS14 0 0015 Lab Duplicate GLP10-01-01-15-087 LMS DAL SS SS14 0 0015 Lab M a trix Spike GLP10-01-01-15-088 DAL SS SS17 0 0015 GLP10-01-01-15-088 Dup DAL SS SS17 0 0015 Lab Duplicate GLP10-01-01-15-088 LMS DAL SS SS17 0 0015 Lab M a trix Spike GLP10-01-01-15-089 DAL SS SS13 0 001S Analyte Peak Name MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS Calculated Concentration Accuracy Record (n g /m L) (%) M odified File Name 3 N/A 0 sll0325b.w iff 3.24 N/A 0 sll0325b.w iff 3.09 N/A 0 sll0325b.w iff 3.21 N/A 0 sll0325b.w iff 2.91 N/A 0 sll0325b.w iff 3.22 N/A 0 sll0325b.w iff N/A N/A 0 sll032S b.w iff 2.77 116 0 sll032S b.w iff N/A N/A 0 sll032S b.w iff N/A N/A 0 sll0325b.w iff N/A N/A 0 sll0325b.w iff N/A N/A 0 sll0325b.w iff N/A N/A 0 sll0325b.w iff N/A N/A 0 sl!0325b.w iff N/A N/A 0 sll0325b.w iff N/A N/A 0 sll0325b.w iff N/A N/A 0 sll0325b.w iff N/A N/A 0 sll0325b.w iff N/A N/A 0 sll0325b.w iff 0.183 91.3 0 sll0325b.w iff 0.481 96.3 0 sll0325b.w iff 0.692 92.4 0 sll0325b.w iff 1 101 0 S ll0325b.w iff 2.56 102 0 sll0325b,w iff 5.3 106 0 sll032S b.w iff 10.5 105 0 sll0325b.w iff 27.1 109 0 sll032S b.w iff 50.8 102 0 sll0325b.w iff 96.1 96.2 0 sll0325b.w iff 199 99.5 0 sll0325b.w iff 501 100 0 sll032S b.w iff N/A N/A 0 sll0325b.w iff N/A N/A 0 sll0325b.w iff N/A N/A 0 sll0325b.w iff N/A N/A 1 sll032S b.w iff N/A N/A 0 S ll0325b.w iff <0 N/A 0 sll0325b.w iff 314 N/A 0 sll0325b.w iff 309 N/A 0 sll032S b.w iff 317 N/A 0 sll0325b.w iff 5.46 N/A 0 sll0325b.w iff 4.86 N/A 0 sll0325b.w iff 9.75 N/A 0 sll0325b.w iff 15.8 N/A 0 sll0325b.w iff 14.6 N/A 0 sll0325b.w iff 47.1 N/A 0 sll0325b.w iff 11.8 N/A 0 sll0325b.w iff 12.7 N/A 0 sll0325b.w iff 39.9 N/A 0 sll0325b,w iff 9.5 N/A 0 sll032S b.w iff N/A N/A 0 sll0325b.w iff 2.75 110 0 sll0325b.w iff N/A N/A 0 sll0325b.w iff 8.68 N/A 0 $110325b.wiff 41.8 N/A 0 sll0325b.w iff 0.627 N/A 0 sll0325b.w iff 0.6 N/A 0 sll0325b.w iff 1.77 N/A 0 sll0325b.w iff 3.1 N/A 0 sll0325b.w iff 0.653 N/A 0 sll0325b.w iff 2 N/A 0 sll0325b.w iff 1.38 N/A 1.18 N/A 0 sll0325b.w iff 0 sll0325b.w iff 6.36 N/A 0 S ll0325b.w iff 2.75 N/A 0 sll0325b.w iff 3.08 N/A 0 sll0325b.w iff 9.22 N/A 0 S ll0325b.w iff 9.19 N/A 0 sll0325b.w iff N/A N/A 0 sll0325b.w iff 5.36 107 0 sll0325b.w iff N/A N/A 0 sll0325b.w iff 10.5 N/A 0 sll0325b.w iff 42.4 N/A 0 S ll0325b.w iff 1.89 N/A 0 sll0325b.w iff 1.5 N/A 0 sll032S b.w iff 7.22 N/A 0 sll0325b.w iff 0.41 N/A 0 S ll0325b.w iff 0.492 N/A 0 sll0325b.w iff 1.73 N/A 0 sll0325b.w iff 0.154 N/A 0 sll0325b.w iff 0.149 N/A 0 sll0325b.w iff 1.41 N/A 0 sll0325b.w iff 0.912 N/A 0 sll0325b.w iff 0.843 N/A 0 S ll0325b.w iff 1.91 N/A 0 sll0325b.w iff 1.13 N/A 0 sll0325b.w iff 3M Study GLP10-01-02-15 Page 2 of S s110325b Sample Name s ll0 3 2 5 b 0 7 7 s ll0 3 2 5 b 0 7 8 s ll0 3 2 5 b 0 7 9 s ll0 3 2 5 b 0 8 0 s ll0 3 2 5 b 0 8 1 s ll0 3 2 5 b 0 8 2 s ll0 3 2 5 b 0 8 3 s ll0 3 2 5 b 0 8 4 sll0325b085 s ll0 3 2 S b 0 8 6 s ll0 3 2 S b 0 8 7 s ll0 3 2 5 b 0 8 8 s ll0 3 2 5 b 0 8 9 S ll0 3 2 5 b 0 9 0 s ll0 3 2 5 b 0 9 1 s ll0 3 2 5 b 0 9 2 s ll0 3 2 5 b 0 9 3 S ll0 3 2 5 b 0 9 4 s ll0 3 2 5 b 0 0 1 s ll0 3 2 5 b 0 0 2 s ll0 3 2 S b 0 0 3 s ll0 3 2 S b 0 0 4 s ll0 3 2 5 b 0 0 5 s ll0 3 2 5 b 0 0 6 s ll0 3 2 5 b 0 0 7 $110325b008 S ll0 3 2 5 b 0 0 9 s ll0 3 2 5 b 0 1 0 s ll0 3 2 5 b 0 1 1 s ll0 3 2 5 b 0 1 2 $110325b013 $110325b014 s ll0 3 2 5 b 0 1 5 s ll0 3 2 5 b 0 1 6 s ll0 3 2 5 b 0 1 7 s ll0 3 2 5 b 0 1 8 s ll0 3 2 5 b 0 1 9 s ll0 3 2 5 b 0 2 0 Sll0325b021 s ll0 3 2 5 b 0 2 2 s ll0 3 2 5 b 0 2 3 s ll0 3 2 S b 0 2 4 s ll0 3 2 5 b 0 2 5 s ll0 3 2 5 b 0 2 6 s ll0 3 2 5 b 0 2 7 s ll0 3 2 5 b 0 2 8 s ll0 3 2 5 b 0 2 9 s ll0 3 2 5 b 0 3 0 $11032Sb031 s ll0 3 2 5 b 0 3 2 s ll0 3 2 5 b 0 3 3 s ll0 3 2 S b 0 3 4 sl!0325b035 s ll0 3 2 5 b 0 3 6 s!10325b037 s ll0 3 2 5 b 0 3 8 s ll0 3 2 S b 0 3 9 $110325b040 s ll0 3 2 5 b 0 4 1 $110325b042 S ll0 3 2 5 b 0 4 3 s ll0 3 2 5 b 0 4 4 s ll0 3 2 5 b 0 4 5 s ll0 3 2 5 b 0 4 6 $110325b047 $110325b048 s ll0 3 2 S b 0 4 9 $110325b050 s ll0 3 2 5 b 0 5 1 s ll0 3 2 5 b 0 5 2 $110325b053 s ll0 3 2 5 b 0 5 4 s ll0 3 2 5 b 0 5 5 s ll0 3 2 5 b 0 5 6 s ll0 3 2 5 b 0 5 7 s ll0 3 2 5 b 0 5 8 s ll0 3 2 S b 0 5 9 s ll0 3 2 5 b 0 6 0 s ll0 3 2 5 b 0 6 1 s ll0 3 2 5 b 0 6 2 s ll0 3 2 5 b 0 6 3 s ll0 3 2 5 b 0 6 4 s ll0 3 2 5 b 0 6 5 s ll0 3 2 5 b 0 6 6 s ll0 3 2 5 b 0 6 7 s ll0 3 2 5 b 0 6 8 Sample 10 10 006-80 solvent blank EC-110316-07 10 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-089 Dup DAL SS SS13 0 0015 Lab Duplicate GLP10-01-01-15-089 IM S DAL SS SS13 0 001S Lab M a trix Spike GLP10-01-01-15-090 DAL SS SS15 0 0015 GLP10-01-01-15-090 Dup DAL SS SS15 0 001S Lab Duplicate GLP10-01-01-1S-090 LMS DAL SS SS15 0 0015 Lab M a trix Spike GLP10-01-01-15-091 DAL SS SS18 0 0015 GLP10-01-01-15-091 Dup DAL SS SS18 0 0015 Lab Duplicate GLP10-01-01-15-091 LMS DAL SS SS18 0 0015 Lab M a trix Spike GLPlO-01-01-15-092 DAL SS SS110 0015 GLP10-01-01-15-092 Dup DAL SS SS110 0015 Lab Duplicate GLP10-01-01-15-092 LMS DAL SS SS110 0015 Lab M a trix Spike 10 006-80 solvent blank EC-110316-05 2.5 ng Extracted Curve Point 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank EC-110316-09 50 ng W arm up standard EC-110316-09 50 ng W arm up standard 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank EC-110316-010.2 ng Extracted Curve Point EC-110316-02 0.S ng Extracted Curve Point EC-110316-03 0.75 ng Extracted Curve Point EC-110316-04 1 ng Extracted Curve Point EC-110316-05 2.5 ng Extracted Curve Point EC-110316-06 5 ng Extracted Curve Point EC-110316-07 10 ng Extracted Curve Point EC-110316-08 25 ng Extracted Curve Point EC-110316-09 50 ng Extracted Curve Point EC-110316-10 100 ng Extracted Curve Point EC-110316-11 200 ng Extracted Curve Point EC-110316-12 500 ng Extracted Curve Point 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank MB-110316-01 M ethod Blank w /o IS MB-110316-04 M ethod Blank w / IS LCS-110316-07 300ng LCS in TCR-842 LCS-110316-08 300ng LCS in TCR-842 LCS-110316-09 300ng LCS in TCR-842 GLP10-01-01-15-074 DAL SD SD18 0 0015 GLP10-01-01-15-074 Dup DAL SD SD18 0 0015 Lab Duplicate GLP10-01-01-15-074 LMS DAL SD SD18 0 001S Lab M a trix Spike GLP10-01-01-15-075 DAL SD SD19 0 0000 GLP10-01-01-15-075 Dup DAL SD SD19 0 0000 Lab Duplicate GLP10-01-01-15-075 LMS DAL SD SD19 0 0000 Lab M a trix Spike GLP10-01-01-15-076 DAL SD SD19 0 0005 GLP10-01-01-1S-076 Dup DAL SD SD19 0 0005 Lab Duplicate GLP10-01-01-15-076 LMS DAL SD SD19 0 0005 Lab M a trix Spike GLP10-01-01-15-077 DAL SD SD19 0 0015 10 006-80 solvent blank EC-110316-05 2.5 ng Extracted Curve Point 10 006-80 solvent blank GLPlO-01-01-15-077 Dup DAL SD SD19 0 0015 Lab Duplicate GLPlO-01-01-15-077 LMS DAL SD SD19 0 0015 Lab M a trix Spike GLPlO-01-01-15-079 DAL SS SS26 0 0000 GLPlO-01-01-15-079 Dup DAL SS SS26 0 0000 Lab Duplicate GLPlO-01-01-15-079 LMS DAL SS SS26 0 0000 Lab M a trix Spike GLPlO-01-01-15-080 DAL SS SS26 DB 0000 GLPlO-01-01-15-080 Dup DAL SS SS26 DB 0000 Lab Duplicate GLPlO-01-01-15-080 LMS DAL SS SS26 DB 0000 Lab M a trix Spike GLPlO-01-01-15-081 DAL SS SS26 0 0005 GLPIO-Ol-Ol-15-081 Dup DAL SS SS26 0 0005 Lab Duplicate GLPlO-01-01-15-081 LMS DAL SS SS26 0 000S Lab M a trix Spike GLPIO-Ol-Ol-15-082 DAL SS SS26 0 0015 GLPIO-Ol-Ol-15-082 Dup DAL SS SS26 0 0015 Lab Duplicate GLPlO-Ol-Ol-15-082 LMS DAL SS SS26 0 0015 Lab M a trix Spike GLPlO-01-01-15-084 DAL SS SS12 0 0015 10 006-80 solvent blank EC-110316-06 5 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-084 Dup DAL SS SS12 0 0015 Lab Duplicate GLP10-01-01-15-084 LMS DAL SS SS12 0 0015 Lab M a trix Spike GLPlO-01-01-15-085 DAL SS SS19 0 0015 GLP10-01-01-1S-085 Dup DAL SS SS19 0 0015 Lab Duplicate GLPlO-01-01-15-085 LMS DAL SS SS19 0 0015 Lab M a trix Spike GLP10-01-01-1S-086 DAL SS SS20 0 0015 GLPIO-Ol-Ol-15-086 Dup DAL SS SS20 0 0015 Lab Duplicate Analyte Peak Name PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS Calculated Concentration Accuracy Record (n g /m L) N/A <%) M odified File Name N/A 0 sll0 3 25 b .w iff 10.4 104 0 sll0325b.w iff N/A N/A 0 sll0325b.w iff 1.16 N/A 0 sll0325b.w iff 6.48 N/A 0 sll0325b.w lff 0.211 N/A 0 sll0325b.w iff 0.196 N/A 0 sll0325b.w iff 1.45 N/A 0 sll0325b.w iff 0.248 N/A 0 sll0325b.w iff 0.323 N/A 0 sll0325b.w iff 1.53 N/A 0 sll0325b.w iff 0.115 N/A 0 sll0325b.w iff 0.147 N/A 0 sll0325b.w iff 1.38 N/A 0 sll0325b.w iff N/A N/A 0 sll0325b.w iff 2.57 103 0 sll0325b.w iff N/A N/A 0 sll0325b.w iff N/A N/A 0 sll0325b.w iff N/A N/A 1 sll0325b.w iff N/A N/A 1 sll0325b.w iff N/A N/A 1 sll0325b.w iff N/A N/A 1 sll032S b.w lff N/A N/A 1 sll0325b.w iff N/A N/A N/A N/A N/A N/A 1 sll0325b.w iff 1 sll0325b.w iff 1 sll0325b.w iff N/A N/A 0.163 82.1 0.477 95.6 0.753 101 1 sll0325b.w iff 1 sll0325b.w iff 1 sll0325b.w iff 1 sll0325b.w iff 1.08 2.6 5.33 9.86 25.6 51.3 97.6 198 108 104 107 98.9 103 103 97.9 99.4 1 sll0325b.w iff 1 sll0325b.w iff 1 sll0325b.w iff 1 sll0325b.w iff 1 sll0325b.w iff 1 sll0325b.w iff 1 sll0325b.w iff 1 sll0325b.w iff 500 100 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A <0 N/A 346 N/A 324 N/A 1 sll0325b.w iff 1 sll0325b.w iff 1 sll0325b.w iff 1 sll032S b.w iff 1 sll0325b.w iff 1 sll0325b.w iff 1 sll0325b.w iff 1 sll0325b.w iff 1 sll0325b.w iff 350 N/A 1 sll0325b.w iff 46.4 N/A 1 sll0325b.w iff 39 N/A 133 N/A 155 N/A 127 N/A 460 N/A 1 sll0325b.w iff 1 sll0325b.w iff 1 sll032S b.w lff 1 sll0325b.w iff 1 sll0325b.w iff 111 N/A 1 sll0325b.w iff 112 N/A 1 sll0325b.w iff 385 N/A 1 sll0325b.w iff 79.6 N/A N/A N/A 1 sll0325b.w iff 1 sll0325b.w iff 2.59 104 1 sll0325b.w iff N/A N/A 1 sll0325b.w iff 81 N/A 209 N/A 9.2 N/A 9.18 N/A 35.5 N/A 65 N/A 8.65 N/A 1 sll0325b.w iff 1 sll0325b.w iff 1 sl!0325b.w iff 1 sll0325b.w iff 1 sll0325b.w iff 1 sll0325b.w iff 1 sll0325b.w iff 37.1 N/A 23.4 N/A 20.5 N/A 49.2 N/A 64.8 N/A 1 sll0325b.w iff 1 sll0325b.w iff 1 sll0325b.w iff 1 sll032S b.w iff 1 sll0325b.w iff 60.7 N/A 1 sll0325b.w lff 163 N/A 255 N/A N/A N/A 5.07 102 1 sll0325b.w iff 1 sll0325b.w iff 1 sll0325b.w iff 1 sll0325b.w iff N/A N/A 288 N/A 1 sll0325b.w iff 1 sll0325b.w iff 943 N/A 23.6 N/A 19.8 N/A 47.6 N/A 2.22 N/A 1 sll0325b,w iff 1 sll0325b.w iff 1 sll0325b.w iff 1 sll0325b.w iff 1 s!10325b.wiff 2.19 N/A 1 sll0325b.w iff 3M Study1GLP10-01-02-15 Page 3 of 5 Page 66 of 514 a s110325b Sample Name s ll0 3 2 5 b 0 6 9 s ll0 3 2 5 b 0 7 0 sll0325b071 s ll0 3 2 5 b 0 7 2 s ll0 3 2 5 b 0 7 3 s ll0 3 2 5 b 0 7 4 sll0325b075 s ll0 3 2 5 b 0 7 6 s ll0 3 2 5 b 0 7 7 s ll0 3 2 5 b 0 7 8 s ll0 3 2 5 b 0 7 9 s ll0 3 2 5 b 0 8 0 s ll0 3 2 5 b 0 8 1 s ll0 3 2 5 b 0 8 2 s ll0 3 2 5 b 0 8 3 s ll0 3 2 S b 0 8 4 sll0325b085 s ll0 3 2 5 b 0 8 6 s ll0 3 2 5 b 0 8 7 s ll0 3 2 5 b 0 8 8 s ll0 3 2 S b 0 8 9 s!1032Sb090 S ll0 3 2 5 b 0 9 1 s ll0 3 2 5 b 0 9 2 s ll0 3 2 5 b 0 9 3 s ll0 3 2 S b 0 9 4 s ll0 3 2 S b 0 0 1 s ll0 3 2 5 b 0 0 2 s ll0 3 2 S b 0 0 3 s ll0 3 2 5 b 0 0 4 s ll0 3 2 5 b 0 0 5 s ll0 3 2 5 b 0 0 6 s ll0 3 2 S b 0 0 7 s ll0 3 2 5 b 0 0 8 s ll0 3 2 5 b 0 0 9 s ll0 3 2 5 b 0 1 0 s ll0 3 2 S b 0 1 1 s ll0 3 2 S b 0 1 2 s ll0 3 2 S b 0 1 3 s ll0 3 2 5 b 0 1 4 s ll0 3 2 5 b 0 1 5 s ll0 3 2 S b 0 1 6 s ll0 3 2 5 b 0 1 7 s ll0 3 2 5 b 0 1 8 s ll0 3 2 S b 0 1 9 s ll0 3 2 5 b 0 2 0 s ll0 3 2 5 b 0 2 1 sU0325b022 s ll0 3 2 S b 0 2 3 s ll0 3 2 5 b 0 2 4 s ll0 3 2 5 b 0 2 5 s ll0 3 2 5 b 0 2 6 s ll0 3 2 5 b 0 2 7 s ll0 3 2 S b 0 2 8 s ll0 3 2 5 b 0 2 9 s ll0 3 2 5 b 0 3 0 s ll0 3 2 5 b 0 3 1 s ll0 3 2 5 b 0 3 2 s ll0 3 2 S b 0 3 3 s ll0 3 2 S b 0 3 4 s ll0 3 2 5 b 0 3 5 s l!0 3 2 S b 0 3 6 s ll0 3 2 5 b 0 3 7 s ll0 3 2 5 b 0 3 8 s ll0 3 2 5 b 0 3 9 s ll0 3 2 5 b 0 4 0 s ll0 3 2 S b 0 4 1 s ll0 3 2 5 b 0 4 2 s ll0 3 2 5 b 0 4 3 s ll0 3 2 S b 0 4 4 s ll0 3 2 5 b 0 4 5 s ll0 3 2 5 b 0 4 6 s ll0 3 2 5 b 0 4 7 s ll0 3 2 5 b 0 4 8 s ll0 3 2 5 b 0 4 9 s ll0 3 2 5 b 0 5 0 s ll0 3 2 5 b 0 5 1 s ll0 3 2 5 b 0 5 2 s ll0 3 2 5 b 0 5 3 s ll0 3 2 5 b 0 5 4 s ll0 3 2 S b 0 5 S s ll0 3 2 S b 0 5 6 s ll0 3 2 5 b 0 5 7 s ll0 3 2 S b 0 5 8 s!1032Sb059 sl!0325b060 Sample ID GLP10-01-01-15-086 LMS DAL SS SS20 0 0015 Lab M a trix Spike GLP10-01-01-15-087 DAL SS SS14 0 0015 GLP10-01-01-15-087 Dup DAL SS SS14 0 0015 Lab Duplicate GLP10-01-01-15-087 LMS DAL SS SS14 0 0015 Lab M a trix Spike GLP10-01-01-15-088 DAL SS SS17 0 0015 GLP10-01-01-15-088 Dup DAL SS SS17 0 0015 Lab Duplicate GLP10-01-01-15-088 LMS DAL SS SS17 0 0015 Lab M a trix Spike GLP10-01-01-15-089 DAL SS SS13 0 0015 10 006-80 solvent blank EC-110316-07 10 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-089 Dup DAL SS SS13 0 0015 Lab Duplicate GLP10-01-01-15-089 LMS DAL SS SS13 0 0015 Lab M a trix Spike GLP10-01-01-15-090 DAL SS SS1S 0 0015 GLP10-01-01-15-090 Dup DAL SS SS1S 0 0015 Lab Duplicate GLP10-01-01-15-090 LMS DAL SS SS15 0 0015 Lab M a trix Spike GLP10-01-01-15-091 DAL SS SS18 0 0015 GLP10-01-01-15-091 Dup DAL SS SS18 0 0015 Lab Duplicate GLP10-01-01-15-091 LMS DAL SS SS18 0 0015 Lab M a trix Spike GLP10-01-01-15-092 DAL SS SS11 0 0015 GLP10-01-01-15-092 Dup DAL SS SS110 0015 Lab Duplicate GLP10-01-01-15-092 LMS DAL SS SS110 0015 Lab M a trix Spike 10 006-80 solvent blank EC-110316-05 2.5 ng Extracted Curve Point 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank EC-110316-09 50 ng W arm up standard EC-110316-09 50 ng W arm up standard 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank EC-110316-010.2 ng Extracted Curve Point EC-110316-02 0.S ng Extracted Curve Point EC-110316-03 0.75 ng Extracted Curve Point EC-110316-04 1 ng Extracted Curve Point EC-110316-05 2.5 ng Extracted Curve Point EC-110316-06 5 ng Extracted Curve Point EC-110316-07 10 ng Extracted Curve Point EC-110316-08 25 ng Extracted Curve Point EC-110316-09 50 ng Extracted Curve Point EC-110316-10 100 ng Extracted Curve Point EC-110316-11 200 ng Extracted Curve Point EC-110316-12 500 ng Extracted Curve Point 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank MB-110316-01 M ethod Blank w /o IS MB-110316-04 M ethod Blank w / IS LCS-110316-07 300ng LCS In TCR-842 LCS-110316-08 300ng LCS In TCR-842 LCS-110316-09 300ng LCS In TCR-842 GLP10-01-01-15-074 DAL SD SD18 0 0015 GLP10-01-01-15-074 Dup DAL SD SD18 0 0015 Lab Duplicate GLP10-01-01-1S-074 LMS DAL SD SD18 0 0015 Lab M a trix Spike GLP10-01-01-1S-075 DAL SD SD19 0 0000 GLP10-01-01-15-075 Dup DAL SD SD19 0 0000 Lab Duplicate GLP10-01-01-15-075 LMS DAL SD SD19 0 0000 Lab M a trix Spike GLPIO-Ol-Ol-15-076 DAL SD SD19 0 0005 GLP10-01-01-15-076 Dup DAL SD SD19 0 OOOS Lab Duplicate GLP10-01-01-15-076 LMS DAL SD SD19 0 0005 Lab M a trix Spike GLP10-01-01-15-077 DAL SD SD19 0 0015 10 006-80 solvent blank EC-110316-05 2.5 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-077 Dup DAL SD SD19 0 0015 Lab Duplicate GLP10-01-01-15-077 LMS DAL SD SD19 0 001S Lab M a trix Spike GLP10-01-01-15-079 DAL SS SS26 0 0000 GLP10-01-01-15-079 Dup DAL SS SS26 0 0000 Lab Duplicate GLP10-01-01-15-079 LMS DAL SS SS26 0 0000 Lab M a trix Spike GLP10-01-01-15-080 DAL SS SS26 DB 0000 GLPlO-01-01-15-080 Dup DAL SS SS26 DB 0000 Lab Duplicate GLP10-01-01-15-080 LMS DAL SS SS26 DB 0000 Lab M a trix Spike GLP10-Q1-01-15-081 DAL SS SS26 0 0005 GLP10-01-01-15-081 Dup DAL SS SS26 0 0005 Lab Duplicate GLP10-01-01-15-081 LMS DAL SS SS26 0 0005 Lab M a trix Spike GLP10-01-01-15-082 DAL SS SS26 0 0015 GLP10-01-01-15-082 Dup DAL SS SS26 0 0015 Lab Duplicate GLP10-01-01-15-082 LMS DAL SS SS26 0 0015 Lab M a trix Spike GLP10-01-01-15-084 DAL SS SS12 0 0015 10 006-80 solvent blank EC-110316-06 5 ng Extracted Curve Point Analyte Peak Name PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS Calculated Concentration Accuracy Record (n g /m L) <%) M odified File Name 7.32 N/A 1 sll032S b.w iff 2.68 N/A 1 sll032S b.w iff 2.92 N/A 1 sll0325b.w iff 9.26 N/A 1 sll0325b.w iff 2.02 N/A 1 sll0325b.w iff 1.88 N/A 1 sll0325b.w iff 6.91 N/A 1,41 N/A 1 sll032S b.w iff 1 $110325b.wiff N/A N/A 1 sll0325b.w iff 10.1 101 1 sll0325b.w iff N/A N/A 1 sll0325b.w iff 1.58 N/A 1 sl!0325b.w iff 6.78 N/A 1 sll0325b.w iff 2,96 N/A 1 sll0325b.w iff 3,27 N/A 1 sll0325b.w iff 8.73 N/A 1 sll0325b.w iff 1.95 N/A 1 sll0325b.w iff 1.79 N/A 1 sll0325b.w iff 7.32 N/A 1 sll0325b.w iff 0.431 N/A 1 sll032S b.w iff 0.658 N/A 1 sll0325b.w iff 1.47 N/A 1 sll0325b.w iff N/A N/A 1 sll0325b.w iff 2.46 99 1 sll0325b.w iff N/A N/A 1 sll0325b.w iff N/A N/A 1 sll0325b.w iff N/A N/A 1 sll0325b.w iff N/A N/A 0 sll0325b.w iff N/A N/A 0 sll0325b.w iff N/A N/A 0 sll0325b.w lff N/A N/A 0 sll0325b.w iff N/A N/A 0 sll0325b.w iff N/A N/A 0 sll0325b.w iff N/A N/A 0 sll0325b.w iff N/A N/A 0 sll0325b.w lff 0.181 90.3 0 sll0325b.w iff 0.451 90.2 0 sll0325b.w iff 0.788 105 0 sll0325b.w iff 1.05 105 1 sll0325b,w lff 2.51 100 0 sll0325b.w iff 5.06 101 1 sll0325b,w iff 10.4 104 0 sll0 3 25 b .w tff 26.9 108 0 sll0325b,w iff 49.7 99.4 0 sll0325b.w iff 94.1 94.2 0 sll0325b.w iff 204 102 0 sll0325b.w iff 499 99.9 0 sll0325b.w iff N/A N/A 0 sl!0325b.w iff N/A N/A N/A N/A 0 sll0325b.w iff 0 sll0325b.w iff N/A N/A 0 sll0325b.w iff N/A N/A 1 sll0325b.w iff 0.0989 N/A 1 sll0325b.w lff 369 N/A 1 sll0325b.w lff 340 N/A 1 sll0325b.w iff 356 N/A 1 sll0325b.w iff 292 N/A 1 sll0325b.w iff 232 N/A 1 sll0325b.w lff 395 N/A 1 sll0325b.w lff M l "1 1 4 0 > /A 1 sll0325b.w lff i S **9931 N/A 1 sll0325b.w lff >' 1730s: N/A 1 sll0325b.w iff mm i) ' 'ipso*- N/A -817 N/A 2 0 3 0 ]N/A 1 sll0325b.w iff 1 sll0325b,w iff 1 sll0325b.w lff 357 N/A 1 sll0325b.w iff N/A N/A 1 sll0325b,w iff 2.54 102 0 sll0325b.w iff N/A N/A 1 sll032S b.w iff 374 N/A 1 sll0325b.w iff g i g l i 938^ N/A 1 sll0325b,w iff . 900| N/A S ^ 9 0 9 ) N/A ,a 6 5 N /A 1 sll032S b.w iff 1 sll0325b.w iff 1 sll0325b.w iff 1870JN/A 1 sll032S b.w iff S IP S !. ^'9 2 0 j N/A `PSm ' 150!N/A .12 N/A f'Sil ll *12001 N/A 1 sll0325b.w iff 1 sll0325b.w iff 1 sll0325b.w iff 1 sll0325b.w iff , 207o!N/A KrmMm 'fb f N/A M '*99'3 N/A 8 8 | p 1430 !N/A 2905N/A 1 sll0325b.w iff 1 sll0325b.w iff 1 sll0325b.w iff 1 sll0325b.w lff 1 sll0325b.w iff N/A ~ N/A 1 sll0325b.w iff 5.51 110 0 sll0325b.w iff 3M Study GLP10-01-02-15 Page 4 of 5 Page 67 of 514 s110325b Sample Name s ll0 3 2 5 b 0 6 1 s ll0 3 2 5 b 0 6 2 s ll0 3 2 S b 0 6 3 s ll0 3 2 5 b 0 6 4 s ll0 3 2 5 b 0 6 5 s ll0 3 2 S b 0 6 6 s ll0 3 2 5 b 0 6 7 s ll0 3 2 S b 0 6 8 s ll0 3 2 S b 0 6 9 s ll0 3 2 5 b 0 7 0 s ll0 3 2 5 b 0 7 1 s ll0 3 2 5 b 0 7 2 s ll0 3 2 5 b 0 7 3 s ll0 3 2 5 b 0 7 4 s ll0 3 2 5 b 0 7 5 s ll0 3 2 5 b 0 7 6 s ll0 3 2 5 b 0 7 7 s ll0 3 2 5 b 0 7 8 s ll0 3 2 5 b 0 7 9 s ll0 3 2 5 b 0 8 0 s ll0 3 2 5 b 0 8 1 s ll0 3 2 5 b 0 8 2 s ll0 3 2 S b 0 8 3 sll032Sb084 s ll0 3 2 5 b 0 8 5 s ll0 3 2 5 b 0 8 6 s ll0 3 2 5 b 0 8 7 s!10325b088 sll032Sb089 s ll0 3 2 5 b 0 9 0 s ll0 3 2 S b 0 9 1 s ll0 3 2 5 b 0 9 2 s ll0 3 2 5 b 0 9 3 s ll0 3 2 5 b 0 9 4 Sample ID 10 006-80 solvent blank GLPlO-01-01-15-084 Dup DAL SS SS12 0 0015 Lab Duplicate GLP10-01-01-15-084 IM S DAL SS SS12 0 0015 Lab M a trix Spike GLP10-01-01-15-085 DAL SS SS19 0 0015 GLPlO-01-01-15-085 Dup DAL SS SS19 0 0015 Lab Duplicate GLP10-01-01-15-085 LMS DAL SS SS19 0 0015 Lab M a trix Spike GLPIO-Ol-Ol-15-086 DAL SS SS20 0 0015 GLPlO-01-01-15-086 Dup DAL SS SS20 0 0015 Lab Duplicate GLPIO-Ol-Ol-15-086 LMS DAL SS SS20 0 0015 Lab M a trix Spike GLPlO-01-01-15-087 DAL SS SS14 0 0015 GLPlO-01-01-15-087 Dup DAL SS SS14 0 0015 Lab Duplicate GLPlO-01-01-15-087 LMS DAL SS SS14 0 0015 Lab M a trix Spike GLPlO-01-01-15-088 DAL SS SS17 0 0015 GLP10-01-01-1S-088 Dup DAL SS SS17 0 0015 Lab Duplicate GLPlO-01-01-15-088 LMS DAL SS SS17 0 0015 Lab M a trix Spike GLPlO-Ol-Ol-15-089 DAL SS SS13 0 0015 10 006-80 solvent blank EC-110316-07 10 ng Extracted Curve Point 10 006-80 solvent blank GLPlO-01-01-15-089 Dup DAL SS SS13 0 0015 Lab Duplicate GLPlO-01-01-15-089 LMS DAL SS SS13 0 0015 Lab M a trix Spike GLPlO-01-01-15-090 DAL SS SS15 0 0015 GLP10-01-01-15-090 Dup DAL SS SS15 0 0015 Lab Duplicate GLPIO-Ol-Ol-15-090 LMS DAL SS SS15 0 0015 Lab M a trix Spike GLPlO-01-01-15-091 DAL SS SS18 0 0015 GLPIO-Ol-Ol-15-091 Dup DAL SS SS18 0 0015 Lab Duplicate GLPlO-01-01-15-091 LMS DAL SS SS18 0 0015 Lab M a trix Spike GLPlO-01-01-15-092 DAL SS SS110 0015 GLPlO-01-01-15-092 Dup DAL SS SS110 0015 Lab Duplicate GLPlO-01-01-15-092 LMS DAL SS SS110 0015 Lab M atrix Spike 10 006-80 solvent blank EC-110316-05 2.5 ng Extracted Curve Point 10 006-80 solvent blank 10 006-80 solvent blank Data no* used outside ca'ibra* on range dilu* on needed Analyte Peak Name PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS Calculated Concentration Accuracy Record (ng/m l) (%) M odified File Name N/A N/A ftlPi 21301 N/A \4770* N/A 1 sll0325b.w iff 1 sll0325b.w iff 1 sll0325b,w iff 292 N/A 1 sll0325b.w iff 248 N/A 1 sll0325b.w iff 7 N/A 1 sll0325b.w iff 208 N/A 171 N/A 1 sll0325b.w iff 1 sll0325b.w iff 449 N/A 1 sll032S b.w iff 202 N/A 1 sll0325b.w iff 224 N/A 456 N/A 1 sll0325b.w iff 1 sll0325b.w iff 227 N/A 1 sll0325b.w iff 210 N/A 1 sll0325b.w iff 451 N/A 1 sll0325b.w iff 271 N/A 1 sll0325b.w iff N/A N/A 1 sll0325b.w iff 10.4 105 0 sll032S b.w iff N/A N/A 1 sll0325b.w iff 282 N/A 1 S ll0325b.w iff 488 N/A 1 sll0325b.w iff 120 N/A 1 sll0325b.w iff 96.8 N/A 1 sll0325b.w iff 297 N/A 1 sll0325b.w iff 167 N/A 1 sl!0325b.w iff 194 N/A 1 sll0325b.w iff 450 N/A 1 sll0325b.w iff 107 N/A 1 sll0325b.w iff 18.4 N/A 1 s!10325b,wiff 42.9 N/A 1 sll0325b.w iff N/A N/A 1 sll0325b.w iff 2.98 119 0 sll0325b.w iff N/A N/A 1 sll032S b.w iff N/A N/A 1 sll0325b.w iff H m aasm ,BUSg g ; ! 3M Study GLP10-01-02-15 Page 5 of 5 Page 68 of 514 s110329a Sample Name s ll0 3 2 9 a 0 0 1 s ll0 3 2 9 a 0 0 2 sll0329a003 s ll0 3 2 9 a 0 0 4 sll0329a005 s ll0 3 2 9 a 0 0 6 sll0329a007 sll0329a008 sll0329a009 sll0329a010 sll0329a011 sll0329a012 sll0329a013 sll0329a014 sll0329a015 s ll0 3 2 9 a 0 1 6 sll0329a017 sll0329a018 sll0329a019 S ll0 3 2 9 a 0 2 0 sll0329a021 s ll0 3 2 9 a 0 2 2 s ll0 3 2 9 a 0 2 3 sll0329a024 sll0329a025 s ll0 3 2 9 a 0 2 6 sll0329a027 sll0329a028 sll0329a029 sll0329a030 s ll0 3 2 9 a 0 3 1 s ll0 3 2 9 a 0 3 2 s ll0 3 2 9 a 0 3 3 sll0329a034 s!10329a03S s ll0 3 2 9 a 0 3 6 sll0329a037 sll0329a038 sll0329a039 sll0329a040 sll0329a041 sll0329a042 sll0329a043 sll0329a044 s ll0 3 2 9 a 0 4 5 $110329a046 sll0329a047 sll0329a048 sll0329a049 sll0329a050 sll0329a0S l sll0 3 2 9 a 0 S 2 sll0 3 2 9 a 0 S 3 sll0329a054 s ll0 3 2 9 a 0 5 5 s ll0 3 2 9 a 0 5 6 sll0329a057 sll0329a058 sll0 3 2 9 a 0 S 9 sll0329a060 sll0329a061 sll0329a062 s ll0 3 2 9 a 0 6 3 s ll0 3 2 9 a 0 6 4 sll0329a065 sll0329a066 s ll0 3 2 9 a 0 6 7 sU0329a068 sll0329a069 sll0329a070 sll0329a071 sll0329a072 sll0329a073 sll0329a074 sll0329a075 s ll0 3 2 9 a 0 7 6 S ll0 32 9 a0 77 sll0329a078 sll0329a079 sll0329a001 sll0329a002 sll0329a003 s ll0 3 2 9 a 0 0 4 s ll0 3 2 9 a 0 0 5 Sample ID 10 006-80 solvent blank 10 006-80 solvent blank EC-110316-09 50 ng W arm up standard EC-110316-09 50 ng W arm up standard 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank EC-110316-010.2 ng Extracted Curve Point EC-110316-02 0.5 ng Extracted Curve Point EC-110316-03 0.75 ng Extracted Curve Point EC-110316-04 1 ng Extracted Curve Point EC-110316-05 2.5 ng Extracted Curve Point EC-110316-06 5 ng Extracted Curve Point EC-110316-07 10 ng Extracted Curve Point EC-110316-08 25 ng Extracted Curve Point EC-110316-09 50 ng Extracted Curve Point EC-110316-10 100 ng Extracted Curve Point EC-110316-11 200 ng Extracted Curve Point EC-110316-12 S00 ng Extracted Curve Point 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank MB-110316-01 M ethod Blank w /o IS MB-110316-04 M ethod Blank w / IS GLP10-01-01-15-036 DAL SS SS24 0 0015 df:50 GLP10-01-01-15-036 Dup D A I SS SS24 0 0015 Lab Duplicate df:50 GLP10-01-01-15-036 LMS DAL SS SS24 0 0015 Lab M a trix Spike df:50 GLP10-01-01-15-037 DAL SS SS29 0 0000 df:S0 GLP10-01-01-15-037 Dup DAL SS SS29 0 0000 Lab Duplicate df:50 GLP10-01-01-15-037 LMS DAL SS SS29 0 0000 Lab M a trix Spike df:50 GLP10-01-01-15-038 LMS DAL SS SS29 0 0005 Lab M atrix Spike df:50 GLP10-01-01-15-039 DAL SS SS29 0 0015 df:50 GLP10-01-01-15-039 Dup DAL SS SS29 0 0015 Lab Duplicate df:50 GLP10-01-01-15-039 LMS DAL SS SS29 0 0015 Lab M a trix Spike df:50 GLP10-01-01-15-041 DAL SS SS13 0 0005 df:S0 GLP10-01-01-15-041 LMS DAL SS SS13 0 0005 Lab M a trix Spike df:S0 GLP10-01-01-15-042 DAL SS SS13 DB 0005 df:50 10 006-80 solvent blank EC-110316-05 2.5 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-042 Dup DAL SS SS13 OB 0005 Lab Duplicate df:50 GLP10-01-01-15-042 LMS DAL SS SS13 DB 0005 Lab M atrix Spike df:S0 GLP10-01-01-15-043 LMS DAL SS SS15 0 0005 Lab M a trix Spike df:50 GLP10-01-01-1S-04S LMS DAL SS SS14 0 0005 Lab M a trix Spike df:50 GLP10-01-01-15-047 LMS DAL SS SS16 0 0005 Lab M a trix Spike df:50 GLP10-01-01-15-048 LMS DAL SS SS16 0 0015 Lab M atrix Spike df:50 GLP10-01-01-15-049 DAL SS SS10 0 0005 df:S0 GLP10-01-01-15-049 Dup DAL SS SS10 0 0005 Lab Duplicate df:50 GLP10-01-01-15-049 LMS DAL SS SS10 0 0005 Lab M a trix Spike df:50 GLP10-01-01-15-050 DAL SS SS10 DB 0005 df:50 GLP10-01-01-15-050 Dup DAL SS SS10 DB 0005 Lab Duplicate df:50 GLPlO-Ol-Ol-15-OSO LMS DAL SS SS10 OB 0005 Lab M a trix Spike df:50 GLP10-01-01-15-051 DAL SS SS10 0 0015 df:50 GLP10-01-01-15-051 Dup DAL SS SS10 0 0015 Lab Duplicate df:S0 GLP10-01-01-1S-051 LMS DAL SS SS10 0 0015 Lab M a trix Spike df:50 10 006-80 solvent blank EC-110316-06 5 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-052 DAL SD SD20 0 0000 df:50 GLP10-01-01-15-052 Dup DAL SD SD20 0 0000 Lab Duplicate df:50 GLP10-01-01-1S-052 LMS DAL SD SD20 0 0000 Lab M a trix Spike df:S0 GLP10-01-01-15-053 DAL SD SD20 0 0005 df:50 GLP10-01-01-15-053 Dup DAL SD SD20 0 0005 Lab Duplicate df:50 GLP10-01-01-15-053 LMS DAL SD SD20 0 0005 Lab M a trix Spike df:50 GLP10-01-01-15-054 DAL SD SD20 0 0015 df:50 GLP10-01-01-15-054 Dup DAL SD SD20 0 0015 Lab Duplicate df:50 GLP10-01-01-15-054 LMS DAL SD SD20 0 0015 Lab M a trix Spike df:50 GLP10-01-01-15-055 DAL SD SD23 0 0000 df:50 GLP10-01-01-15-055 Dup DAL SD SD23 0 0000 Lab Duplicate df:50 GLP10-01-01-1S-0SS LMS DAL SD SD23 0 0000 Lab M a trix Spike df:50 GLP10-01-01-15-056 LMS DAL SD SD23 0 0005 Lab M atrix Spike df:50 GLP10-01-01-15-058 LMS DAL SS SS28 0 0000 Lab M atrix Spike df:50 GLP10-01-01-15-060 LMS DAL SS SS28 DB 0005 Lab M a trix Spike df:50 10 0 0 6 8 0 solvent blank EC-110316-07 10 ng Extracted Curve Point 10 0 0 6 8 0 solvent blank 10 0 0 6 8 0 solvent blank 10 006-80 solvent blank EC-110316-09 50 ng W arm up standard EC-110316-09 50 ng W arm up standard 10 0 0 6 8 0 solvent blank Analyte Peak Name MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS PFOS PFOS PFOS PFOS PFOS Calculated Concentration Accuracy Record (n g /m L) N/A N/A ( * ) M odified File Name N/A 0 sll0 3 2 9 a .w iff N/A 0 sll0 3 2 9 a .w iff N/A N/A 0 sll0329a.w iff N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 0.186 97.5 0 sll0329a.w iff 0 sll0329a.w iff 0 sll0329a.w iff 0 sll0329a.w iff 0 sll0329a.w iff 0 sll0329a.w iff 0 sll0329a.w iff 0.47 98.3 0 sll0329a.w iff 0.645 0.899 90 94.1 0 sll0329a.w iff 0 sll0329a.w iff 2.53 4.94 106 103 0 sll0329a.w iff 0 sll0329a.w iff 9.28 97.1 0 sl!0329a.w iff 25.7 107 0 sll0329a.w iff 52.7 97 110 101 0 sll0329a.w iff 0 sll0329a.w iff 179 93.6 0 sll0329a.w iff 482 101 0 sll0329a.w iff N/A N/A N/A N/A 0 sll0329a.w iff 0 sll0329a.w iff N/A N/A 0 sll0329a.w iff N/A N/A 0 sll0329a.w iff N/A N/A 3.07 N/A 0 sll0329a,w iff 0 sll0329a.w iff 3.02 N/A 0 sll0329a.w iff 3.07 N/A 0 sll0329a.w iff 3.13 N/A 0 sll0329a.w iff 2.98 N/A 0 sll0329a.w iff 3.2 N/A 0 sl!0329a.w iff 3.03 N/A 0 sll0329a.w iff 2,99 N/A 3.04 N/A 3.08 N/A 0 sll0329a.w iff 0 sll0329a.w iff 0 sll0329a.w iff 3.08 N/A 0 sll0329a.w iff 3.03 N/A 0 sll0329a.w iff 3.14 N/A 0 sll0329a.w iff 3.13 N/A 0 sll0329a.w iff N/A N/A 0 sll0329a.w iff 2.63 110 N/A N/A 3.06 N/A 0 sll0329a.w iff 0 sll0329a.w iff 0 sll0329a.w iff 3.35 N/A 0 sll0329a.w iff 3.27 N/A 0 sll0329a.w iff 3.12 N/A 0 sll0329a.w iff 3.32 N/A 0 sll0329a.w iff 3.11 N/A 0 sll0329a.w lff 3.19 N/A 0 sll0329a.w iff 3.18 N/A 0 sll0329a.w iff 3.24 N/A 0 sll0329a.w iff 3.19 N/A 0 sll0329a.w iff 3.02 N/A 0 sll0329a.w iff 3.18 N/A 0 sll0329a.w iff 3.37 N/A 3.17 N/A 0 sll0329a.w iff 0 sll0329a.w iff 3.23 N/A 0 sll0329a.w iff N/A N/A 0 sll0329a.w iff 4.97 104 N/A N/A 0 sll0329a.w iff 0 sll0329a.w iff 3.28 N/A 0 sll0329a.w iff 3.14 N/A 0 sll0329a.w iff 3.27 N/A 0 sll0329a.w iff 3.07 N/A 0 sll0329a.w iff 3.22 N/A 0 sll0329a.w iff 3.09 N/A 3.07 N/A 0 sll0329a.w iff 0 sll0329a.w iff 3.16 N/A 3.16 N/A 0 sll0329a.w iff 0 sll0329a.w iff 3,21 N/A 0 sll0329a.w iff 2.95 N/A 0 sll0329a.w iff 3.34 N/A 3.03 N/A 3.1 N/A 0 sll0329a.w iff 0 sll0329a.w iff 0 sll0329a.w iff 3.24 N/A 0 sll0329a.w iff N/A N/A 9.79 102 0 sll0329a.w iff 0 sll0329a.w iff N/A N/A 0 sll0329a.w iff N/A N/A 1 sll0329a.w iff N/A N/A N/A N/A 0 sll0329a.w iff 0 sll0329a.w iff N/A N/A 0 sll0329a.w iff N/A N/A 0 sll0329a.w iff 3M Study GLP10-01-02-15 Pag 1 of 2 Page 69 of s110329a Sample Name s ll0 3 2 9 a 0 0 6 sll0329a007 sll0329a008 sll0329a009 sll0329a010 sll0329a011 sll0329a012 sll0329a013 sll0329a014 sll0329a015 s ll0 3 2 9 a 0 1 6 sll0329a017 sll0329a018 sll0329a019 s ll0 3 2 9 a 0 2 0 sll0329a021 sll0329a022 s ll0 3 2 9 a 0 2 3 sll0329a024 sll0329a025 s ll0 3 2 9 a 0 2 6 s ll0 3 2 9 a 0 2 7 sll0329a028 s ll0 3 2 9 a 0 2 9 s ll0 3 2 9 a 0 3 0 sll0329a031 sll0329a032 sll0329a033 s ll0 3 2 9 a 0 3 4 s ll0 3 2 9 a 0 3 5 s ll0 3 2 9 a 0 3 6 s ll0 3 2 9 a 0 3 7 s ll0 3 2 9 a 0 3 8 s ll0 3 2 9 a 0 3 9 s ll0 3 2 9 a 0 4 0 sll0329a041 sll0329a042 sll0329a043 sll0329a044 s ll0 3 2 9 a 0 4 5 sll0329a046 sll0329a047 sll0329a048 sll0329a049 sll0329a050 sll0329a051 sll0329a052 sll0329a053 sll0329a0S4 s ll0 3 2 9 a 0 S S s ll0 3 2 9 a 0 5 6 sll0329a057 sll0329a058 s!10329a059 sll0329a060 sll0329a061 sll0329a062 sll0329a063 sll0329a064 s ll0 3 2 9 a 0 6 5 sll0329a066 s ll0 3 2 9 a 0 6 7 sll0329a068 sll0329a069 sll0329a070 sll0329a071 sll0329a072 S ll0 3 2 9 a 0 7 3 sll0329a074 sll0329a07S s ll0 3 2 9 a 0 7 6 sll0329a077 s ll0 3 2 9 a 0 7 8 sll0329a079 Sample ID 10 006*80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank 10 006*80 solvent blank EC-110316-010.2 ng Extracted Curve Point EC-110316-02 0.5 ng Extracted Curve Point EC-110316-03 0.75 ng Extracted Curve Point EC-110316-04 1 ng Extracted Curve Point EC-110316-05 2.5 ng Extracted Curve Point EC-110316-06 5 ng Extracted Curve Point EC-110316-07 10 ng Extracted Curve Point EC-110316-08 25 ng Extracted Curve Point EC-110316-09 50 ng Extracted Curve Point EC-110316-10 100 ng Extracted Curve Point EC-110316-11 200 ng Extracted Curve Point EC-110316-12 500 ng Extracted Curve Point 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank MB-110316-01 M ethod Blank w /o IS MB-110316-04 M ethod Blank w / IS GLP10-01-01-15-036 DAL SS SS24 0 0015 df:50 GLP10-01-01-15-036 Dup DAL SS SS24 0 0015 Lab Duplicate df:50 GLP10-01-01-15-036 IM S DAL SS SS24 0 0015 Lab M a trix Spike df:50 GLP10-01-01-15-037 DAL SS SS29 0 0000 df:50 GLP10-01-01-15-037 Dup DAL SS SS29 0 0000 Lab Duplicate df:50 GLP10-01-01-15-037 LMS DAL SS SS29 0 0000 Lab M a trix Spike df:50 GLP10-01-01-15-038 LMS DAL SS SS29 0 0005 Lab M a trix Spike df:S0 GLP10-01-01-15-039 DAL SS SS29 0 0015 df:50 GLP10-01-01-15-039 Dup DAL SS SS29 0 0015 Lab Duplicate df:S0 GLP10-01-01-15-039 LMS DAL SS SS29 0 0015 Lab M a trix Spike df:50 GLP10-01-01-15-041 DAL SS SS13 0 0005 df:S0 GLP10-01-01-15-041 LMS DAL SS SS13 0 0005 Lab M a trix Spike df:50 GLP10-01-01-15-042 DAL SS SS13 DB 0005 df:50 10 006-80 solvent blank EC-110316-05 2.5 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-042 Dup DAL SS SS13 DB 0005 Lab Duplicate df:50 GLP10-01-01-15-042 LMS DAL SS SS13 DB 0005 Lab M a trix Spike df:50 GLP10-01-01-15-043 LMS DAL SS SS15 0 0005 Lab M a trix Spike df:50 GLP10-01-01-15-045 LMS DAL SS SS14 0 0005 Lab M a trix Spike df:50 GLP10-01-01-15-047 LMS DAL SS SS16 0 0005 Lab M a trix Spike df:50 GLP10-01-01-15-048 LMS DAL SS SS16 0 0015 Lab M a trix Spike df:S0 GLP10-01-01-15-049 DAL SS SS10 0 0005 df:50 GLP10-01-01-15-049 Dup DAL SS SS10 0 0005 Lab Duplicate df:50 GLP10-01-01-1S-049 LMS DAL SS SS10 0 0005 Lab M a trix Spike df:S0 GLP10-01-01-15-050 DAL SS SS10 DB 0005 df:S0 GLP10-01-01-15-050 Dup DAL SS SS10 DB 0005 Lab Duplicate df:50 GLP10-01-01-15-050 LMS DAL SS SS10 DB 0005 Lab M a trix Spike df:50 GLP10-01-01-15-051 DAL SS SS10 0 0015 df:50 GLP10-01-01-15-051 Dup DAL SS SS10 0 0015 Lab Duplicate df:50 GLP10-01-01-15-051 LMS DAL SS SS10 0 0015 Lab M a trix Spike df:50 10 006-80 solvent blank EC-110316-06 S ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-052 DAL SD SD20 0 0000 df:S0 GLP10-01-01-15-052 Dup DAL SD SD20 0 0000 Lab Duplicate df:50 GLP10-01-01-15-052 LMS DAL SO SD20 0 0000 Lab M a trix Spike df:50 GLP10-01-01-15-053 DAL SD SD20 0 0005 df:50 GLP10-01-01-15-053 Dup DAL SD SD20 0 0005 Lab Duplicate df:50 GLP10-01-01-15-053 LMS DAL SD SD20 0 0005 Lab M a trix Spike df:50 GLP10-01-01-15-054 DAL SD S020 0 0015 df:50 GLP10-01-01-1S-054 Dup DAL SD SD20 0 0015 Lab Duplicate df:50 GLP10-01-01-15-054 LMS DAL SD SD20 0 0015 Lab M a trix Spike df:50 GLP10-01-01-1S-0SS DAL SD SD23 0 0000 df;50 GLP10-01-01-15-055 Dup DAL SD SD23 0 0000 Lab Duplicate df:50 GLP10-01-01-15-055 LMS DAL SD SD23 0 0000 Lab M a trix Spike df:50 GLP10-01-01-15-056 LMS DAL SD SD23 0 0005 Lab M a trix Spike df:50 GLP10-01-01-1S-0S8 LMS DAL SS SS28 0 0000 Lab M a trix Spike df:50 GLP10-01-01-15-060 LMS DAL SS SS28 DB 0005 Lab M a trix Spike df:S0 10 006-80 solvent blank EC-110316-07 10 ng Extracted Curve Point 10 006-80 solvent blank All PFOS data reported A n a ly te Peak Name PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS Calculated Concentration Accuracy Record (n g /m L) N/A (%) M odified File Name N/A 0 sll0 3 2 9 a .w iff N/A N/A 0 sll0329a.w iff N/A N/A 0 sll0329a.w iff N/A N/A 0 sll0329a.w iff 0.225 113 1 sll0329a.w iff 0.507 101 0 sll0329a.w iff 0.667 89 0 sll0329a.w iff 1.01 101 0 sll0329a.w iff 2.5 99.8 0 sll0329a.w iff 4.96 99.2 0 sll0329a.w iff 9.35 93.6 0 sll0329a.w iff 25.3 101 0 sll0329a.w iff 52.2 104 0 sll0329a.w iff 96.4 96.5 0 sll0329a.w iff 202 101 0 sll0329a.w iff 500 99.9 0 sll0329a.w iff N/A N/A 0 sll0329a.w iff N/A N/A 0 sll0329a.w iff N/A N/A 0 sll0329a.w iff N/A N/A 0 sll0329a.w iff N/A N/A 1 sll0329a.w iff 0.0944 N/A 1 sll0329a.w iff 36.5 N/A 1 sll0329a.w iff 40.4 N/A 1 sll0329a.w iff 50.8 N/A 1 sll0329a.w iff 10.2 N/A 1 sll0329a.w iff 11.9 N/A 1 sll0329a.w iff 20.4 N/A 1 sll0329a.w iff 10.9 N/A 1 sll0329a.w iff 27.2 N/A 1 sll0329a.w iff 30.2 N/A 1 sll0329a.w iff 53.7 N/A 1 sll0329a.w iff 9.76 N/A 1 sll0329a.w iff 18.9 N/A 1 sll0329a.w iff 13.1 N/A 1 sll0329a.w iff N/A N/A 0 sll0329a.w iff 2.66 107 0 sll0329a.w iff N/A N/A 1 sll0329a.w iff 12.2 N/A 1 sll0329a.w iff 21.8 N/A 1 sll0329a,w iff 11.9 N/A 1 sll0329a.w iff 11 N/A 1 sll0329a,w iff 11.2 N/A 1 sll0329a.w iff 8.1 N/A 1 sll0329a.w iff 9.96 N/A 1 sll0329a.w iff 15.8 N/A 1 sll0329a.w iff 25.6 N/A 1 sll0329a.w iff 12.6 N/A 1 sll0329a.w iff 9.03 N/A 1 sll0329a.w iff 30.4 N/A 1 sll0329a.w iff 16.3 N/A 1 sll0329a.w iff 17.6 N/A 1 sll0329a.w iff 36.3 N/A 1 sll0329a.w iff N/A N/A 1 Sll0329a.w iff 5.11 102 0 sll0329a.w iff N/A N/A 1 sll0329a.w iff 43.8 N/A 1 sll0329a.w iff 73 N/A 1 sll0329a.w iff 151 N/A 1 sll0329a.w iff 22.6 N/A 1 sll0329a.w iff 24.4 N/A 1 sll0329a.w iff 39.9 N/A 1 $110329a.wiff 15.1 N/A 1 sll0329a.w iff IS N/A 1 sll0329a.w iff 32.5 N/A 1 sll0329a.w iff 13.3 N/A 1 sll0329a.w iff 14.3 N/A 1 S ll0329a.w iff 22.S N/A 1 $110329a.wiff 9.76 N/A 1 s!10329a.wiff 8.72 N/A 1 $110329a.wiff 10.1 N/A 1 sll0329a.w iff N/A N/A 1 $1103293.w iff 9.8 98.1 0 sll0329a.w iff N/A N/A 1 $1103293.w iff 3M Study GLP10-01-02-15 Page 2 of 2 Page 70 of 514 a110325a Quantify Compound Summary Report Sample List: Last modified: Method: Last modified: Job Code: D:\Masslynx\Amelia2009.pro\SAMPLEDB\a110325a Thu Mar 31 15:28:57 2011 D:\Masslynx\Amelia2009.pro\METHDB\a110325a Thu Mar 31 15:25:52 2011 Printed: Thu Mar 31 16:44:172011 Compound 1: PFOS # Name 1 a110325a001 2 a110325a002 3 a110325a003 4 a110325a004 5 a110325a005 6 a110325a006 7 a110325a007 6 a110325a008 9 a110325a009 10 a110325a010 11 a110325a011 12 a110325a012 13 a110325a013 14 a110325a014 15 a110325a015 16 a110325a016 17 a110325a017 16 a110325a016 19 a110325a019 20 a110325a020 21 a110325a021 22 a110325a022 23 a110325a023 24 a110325a024 25 a110325a025 26 a110325a026 27 a110325a027 28 a110325a028 29 a110325a029 30 a110325a030 31 a110325a031 32 a110325a032 33 a110325a033 34 a110325a034 35 a110325a035 36 a110325a036 37 a110325a037 38 a110325a038 39 a110325a039 40 a110325a040 41 a110325a041 42 a110325a042 43 a110325a043 44 a110325a044 45 a110325a045 46 a110325a046 47 a110325a047 48 a110325a048 49 a110325a049 50 a110325a050 51 a110325a051 52 a110325a052 53 a110325a053 54 a110325a054 55 a110325a055 56 a110325a056 57 a110325a057 58 a110325a058 59 a110325a059 60 a110325a060 61 a110325a061 62 a110325a062 63 a110325a063 64 a110325a064 65 a110325a065 66 a110325a066 67 a110325a067 68 a110325a068 69 a110325a069 70 a110325a070 71 a110325a071 72 a110325a072 73 a110325a073 74 a110325a074 75 a110325a075 76 a110325a076 77 a110325a077 78 a110325a078 79 a110325a079 80 a110325a080 81 a110325a081 82 a110325a082 83 a110325a083 Samplelist Text 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 Warm-up: EC-110316-09 50 ng extracted curve point Warm-up: EC-110316-09 50 ng extracted curve point 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 EC-110316-01 0.2 ng Extracted Curve Point EC-110316-02 0.5 ng Extracted Curve Point EC-110316-03 0.75 ng Extracted Curve Point EC-110316-04 1 ng Extracted Curve Point EC-110316-05 2.5 ng Extracted Curve Point EC-110316-06 5 ng Extracted Curve Point EC-110316-07 10 ng Extracted Curve Point EC-110316-08 25 ng Extracted Curve Point EC-110316-09 50 ng Extracted Curve Point EC-110316-10 100 ng Extracted Curve Point EC-110316-11 200 ng Extracted Curve Point EC-110316-12 500 ng Extracted Curve Point 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 MB-110316-01 Method Blank w/o IS MB-110316-04 Method Blank w/IS LCS-110316-07 300ng LCS in TCR-842 df:10 LCS-110316-08 300ng LCS in TCR-842 df:10 LCS-110316-09 300ng LCS in TCR-842 df:10 GLP10-01-01-15-002 DAL SS SS12 0 0000 df:50 GLP10-01-01-15-002 Dup DAL SS SS12 0 0000 Lab Duplicate df:50 GLP10-01-01-15-002 LMS DAL SS SS12 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-003 OAL SS SS12 0 0005 df:50 GLP10-01-01-15-003 Dup DAL SS SS12 0 0005 Lab Duplicate df:50 GLP10-01-01-15-003 LMS DAL SS SS12 0 0005 Lab Matrix Spike df:50 GLP10-01-01-15-006 LMS DAL SS SS16 DB 0000 Lab Matrix Spike df:50 GLP10-01-01-15-008 DAL SS SS11 0 0005 df:50 GLP10-01-01-15-010 LMS DAL SS SS20 DB 0000 Lab Matrix Spike df:50 GLP10-01-01-15-011 DAL SS SS19 0 0000 df:50 10 006-80 solvent blank EC-110316-05 2.5 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-011 LMS DAL SS SS19 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-012 LMS DAL SS SS19 0 0005 Lab Matrix Spike df:50 GLP10-01-01-15-014 Dup DAL SS SS15 0 0000 Lab Duplicate df:50 GLP10-01-01-15-014 LMS DAL SS SS15 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-016 Dup DAL SS SS14 0 0000 Lab Duplicate df:50 GLP10-01-01-15-016 LMS DAL SS SS14 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-020 DAL SS SS10 0 0000 df:50 GLP10-01-01-15-020 Dup DAL SS SS10 0 0000 Lab Duplicate df:50 GLP10-01-01-15-020 LMS DAL SS SS10 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-021 LMS DAL SS SS30 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-023 LMS DAL SS SS30 0 0015 Lab Matrix Spike df:50 GLP10-01-01-15-024 DAL SS SS25 0 0000 df:50 GLP10-01-01-15-024 Dup DAL SS SS25 0 0000 Lab Duplicate df:50 GLP10-01-01-15-024 LMS DAL SS SS25 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-025 DAL SS SS25 0 0005 df:50 10 006-80 solvent blank EC-110316-06 5 ng Extracted Curve Point 10 006-60 solvent blank GLP 10-01-01-15-025 Dup DAL SS SS25 0 0005 Lab Duplicate df:50 GLP10-01-01-15-025 LMS DAL SS SS25 0 0005 Lab Matrix Spike df:50 GLP10-01-01-15-026 DAL SS SS25 0 0015 df: 50 GLP10-01-01-15-026 Dup DAL SS SS25 0 0015 Lab Duplicate df:50 GLP 10-01-01-15-026 LMS DAL SS SS25 0 0015 Lab Matrix Spike df:50 GLP10-01-01-15-027 DAL SD SD22 0 0000 df:50 GLP10-01-01-15-027 Dup DAL SD SD22 0 0000 Lab Duplicate df:50 GLP 10-01-01*15-027 LMS DAL SD SD22 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-028 DAL SD SD22 0 0005 df:50 GLP10-01-01-15-028 Dup DAL SD SD22 0 0005 Lab Duplicate df:50 GLP10-01-01-15-028 LMS DAL SD SD22 0 0005 Lab Matrix Spike df:50 GLP10-01-01-15-029 DAL SD SD22 DB 0005 df:50 GLP10-01-01-15-029 Dup DAL SD SD22 DB 0005 Lab Duplicate df:50 GLP10-01-01-15-029 LMS DAL SD SD22 DB 0005 Lab Matrix Spike df:50 GLP10-01-01-15-030 DAL SD SD22 0 0015 df:50 10 006-80 solvent blank EC-110316-07 10 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-030 Dup DAL SD SD22 0 0015 Lab Duplicate df:50 GLP10-01-01-15-030 LMS DAL SD SD22 0 0015 Lab Matrix Spike df:50 GLP10-01-01-15-031 DAL SD SD21 0 0000 df:50 Type Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte QC Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte QC Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte QC Analyte Analyte Analyte Analyte Cone. 0 0.066 0 0 55.89 56.669 0.035 0 0.017 0 0.163 0.551 0.79 0.921 2.668 5.357 9.877 24.601 50.52 97.558 202.457 499.351 0.157 0 0 0 0.174 0.064 31.033 31.445 28.922 98.203 53.058 143.804 182.661 176.936 277.986 17.484 124.549 9.443 8.254 0 2.787 0 9.993 16.735 9.564 12.763 9.487 15.359 30.586 69.042 239.918 15.291 8.274 68.346 133.619 201.322 54.356 0 4.756 0 58.208 158.982 58.76 51.536 150.641 91.745 70.045 211.669 20.086 35.531 37.26 43.895 28.671 47.894 10.895 0 9.175 0 7.621 17.315 37.639 3M Study GLP10-01-02-15 Page 1 of 6 Pag a110325a Compound 2: PFHS # 84 a110325a084 85 a110325a085 86 a110325a086 87 a110325a087 86 a110325a088 89 a110325a089 90 a110325a090 91 a110325a091 92 a110325a092 93 a110325a093 94 a110325a094 95 a110325a095 96 a110325a096 97 a110325a097 98 a110325a098 99 a110325a099 100 a110325a100 101 a110325a101 102 a110325a102 103 a110325a103 104 a110325a104 105 a110325a105 G LP 10-01-01-15-031 Dup DAL SD SD21 0 0000 Lab Duplicate df:50 G LP 10-01-01-15-031 LMS DAL SD SD21 0 0000 Lab Matrix Spike df:50 G LP 10-01-01-15-032 DAL SD SD21 0 0005 df:50 G LP10-01-01-15-032 Dup DAL SD SD21 0 0005 Lab Duplicate df:50 G LP10-01-01-15-032 LMS DAL SD SD21 0 0005 Lab Matrix Spike df:50 GLP10-01-01-15-033 DAL SD SD21 0 0015 df:50 G LP 10-01 -01 -15-033 Dup DAL SD SD21 0 0015 Lab Duplicate df:50 G LP10-01-01-15-033 LMS DAL SD SD21 0 0015 Lab Matrix Spike df:50 GLP10-01-01-15-034 DAL SS SS24 0 0000 df:50 G LP10-01-01-15-034 Dup DAL SS SS24 0 0000 Lab Duplicate df:50 G LP 10-01 -01 -15-034 LMS DAL SS SS24 0 0000 Lab Matrix Spike df:50 G LP10-01-01-15-035 DAL SS SS24 0 0005 df:50 10 006-80 solvent blank EC-110316-05 2.5 ng Extracted Curve Point 10 006-80 solvent blank G LP10-01-01-15-035 Dup DAL SS SS24 0 0005 Lab Duplicate df:50 G LP 10-01-01-15-035 LMS DAL SS SS24 0 0005 Lab Matrix Spike df:50 10 006-80 solvent blank EC-110316-06 5 ng Extracted Curve Point 10 006-80 solvent blank 10 006-60 solvent blank 10 006-60 solvent blank A n a ly te A n a ly te A n a ly te A n a ly te A n a ly te A n a ly te A n a ly te A n a ly te A n a ly te A n a ly te A n a ly te A n a ly te A n a ly te QC A n a ly te A n a ly te A n a ly te A n a ly te QC A n a ly te A n a ly te A n a ly te 45.437 150.797 39.201 35.179 54.132 15.187 10.523 23.673 24.507 29.488 43.184 43.254 0 2.66 0 43.299 126.275 0.031 5.1 0.012 0 0 Name 1 a110325a001 2 a110325a002 3 a110325a003 4 a110325a004 5 a110325a005 6 a110325a006 7 a110325a007 8 a110325a008 9 a110325a009 10 a110325a010 11 a110325a011 12 a110325a012 13 a110325a013 14 a110325a014 15 a110325a015 16 a110325a016 17 a110325a017 18 a110325a018 19 a110325a019 20 a110325a020 21 a110325a021 22 a110325a022 23 a110325a023 24 a110325a024 25 a110325a025 26 a110325a026 27 a110325a027 26 a110325a028 29 a110325a029 30 a110325a030 31 a110325a031 32 a110325a032 33 a110325a033 34 a110325a034 35 a110325a035 36 a110325a036 37 a110325a037 38 a110325a038 39 a110325a039 40 a110325a040 41 a110325a041 42 a110325a042 43 a110325a043 44 a110325a044 45 a110325a045 46 a110325a046 47 a110325a047 48 a110325a048 49 a110325a049 50 a110325a050 51 a110325a051 52 a110325a052 53 a110325a053 54 a110325a054 55 a110325a055 56 a110325a056 57 a110325a057 58 a110325a058 59 a110325a059 60 a110325a060 61 a110325a061 62 a110325a062 63 a110325a063 64 a110325a064 65 a110325a065 66 a110325a066 67 a110325a067 68 a110325a068 69 a110325a069 70 a110325a070 71 a110325a071 72 a110325a072 73 a110325a073 Samplelist Text 10 006-80 80:20 A C N ;H 20 10 006-80 80:20 A C N :H 20 10 006-80 80:20 A C N ;H 20 10 006-80 80:20 A C N .H 20 Warm-up: EC-110316-09 50 ng extracted curve point Warm-up: EC-110316-09 50 ng extracted curve point 10 006-80 80:20 A C N :H 20 10 006-80 80:20 A C N :H 20 10 006-80 80:20 A C N :H 20 10 006-80 80:20 A C N :H 20 EC-110316-01 0.2 ng Extracted Curve Point EC-110316-02 0.5 ng Extracted Curve Point EC-110316-03 0.75 ng Extracted Curve Point EC-110316-04 1 ng Extracted Curve Point EC-110316-05 2.5 ng Extracted Curve Point EC-110316-06 5 ng Extracted Curve Point EC-110316-07 10 ng Extracted Curve Point EC-110316-08 25 ng Extracted Curve Point EC-110316-09 50 ng Extracted Curve Point EC-110316-10 100 ng Extracted Curve Point EC-110316-11 200 ng Extracted Curve Point EC-110316-12 500 ng Extracted Curve Point 10 006-80 80:20 A C N :H 20 10 006-80 80:20 A C N :H 20 10 006-80 80:20 A C N :H 20 10 006-80 80:20 ACN:H20 M B -110316-01 Method Blank w/o IS M B -110316-04 Method Blank w/ IS LCS-110316-07 300ng LCS in TCR-842 df:10 LCS-110316-08 300ng LCS in TCR-842 df:10 LC S -110316-09 300ng LCS in TCR-842 df:10 G LP10-01-01-15-002 DAL SS SS12 0 0000 df:50 GLP10-01-01-15-002 Dup DAL SS SS12 0 0000 Lab Duplicate df:50 G LP 10-01-01-15-002 LMS DAL SS SS12 0 0000 Lab Matrix Spike df:50 G LP 10-01-01-15-003 DAL SS SS12 0 0005 df:50 G LP 10-01-01-15-003 Dup DAL SS SS12 0 0005 Lab Duplicate df:50 G LP10-01-01-15-003 LMS DAL SS SS12 0 0005 Lab Matrix Spike df:50 G LP 10-01-01-15-006 LMS DAL SS SS16 DB 0000 Lab Matrix Spike df:50 G LP 10-01-01-15-008 DAL SS SS11 0 0005 df:50 G LP10-01-01-15-010 LMS DAL SS SS20 DB 0000 Lab Matrix Spike df:50 GLP10-01-01-15-011 DAL SS SS19 0 0000 df:50 10 006-60 solvent blank EC-110316-05 2.5 ng Extracted Curve Point 10 006-60 solvent blank G LP10-01-01-15-011 LMS DAL SS SS19 0 0000 Lab Matrix Spike df:50 G LP10-01-01-15-012 LMS DAL SS SS19 0 0005 Lab Matrix Spike df:50 G LP10-01-01-15-014 Dup DAL SS SS15 0 0000 Lab Duplicate df:50 G LP10-01-01-15-014 LMS DAL SS SS15 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-016 Dup DAL SS SS14 0 0000 Lab Duplicate df:50 G LP10-01-01-15-016 LMS DAL SS SS14 0 0000 Lab Matrix Spike df:50 G LP 10-01-01-15-020 DAL SS SS10 0 0000 df:50 G LP10-01-01-15-020 Dup DAL SS SS10 0 0000 Lab Duplicate df:50 GLP 10-01 -01-15-020 LMS DAL SS SS10 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-021 LMS DAL SS SS30 0 0000 Lab Matrix Spike df:50 G LP10-01-01-15-023 LMS DAL SS SS30 0 0015 Lab Matrix Spike df:50 GLP10-01-01-15-024 DAL SS SS25 0 0000 df:50 GLP10-01-01-15-024 Dup DAL SS SS25 0 0000 Lab Duplicate df:50 GLP10-01-01-15-024 LMS DAL SS SS25 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-025 DAL SS SS25 0 0005 df:50 10 006-80 solvent blank EC-110316-06 5 ng Extracted Curve Point 10 006-80 solvent blank G LP 10-01-01-15-025 Dup DAL SS SS25 0 0005 Lab Duplicate df:50 GLP10-01-01-15-025 LMS DAL SS SS25 0 0005 Lab Matrix Spike df:50 G LP 10-01-01-15-026 DAL SS SS25 0 0015 df:50 GLP10-01-01-15-026 Dup DAL SS SS25 0 0015 Lab Duplicate df:50 GLP10-01-01-15-026 LMS DAL SS SS25 0 0015 Lab Matrix Spike df:50 G LP10-01-01-15-027 DAL SD SD22 0 0000 df:50 G LP10-01-01-15-027 Dup DAL SD SD22 0 0000 Lab Duplicate df:50 GLP10-01-01-15-027 LMS DAL SD SD22 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-028 DAL SD SD22 0 0005 df:50 GLP 10-01-01-15-028 Dup DAL SD SD22 0 0005 Lab Duplicate df:50 G LP10-01-01-15-028 LMS DAL SD SD22 0 0005 Lab Matrix Spike df:50 Type A n a ly te A n a ly te A n a ly te A n a ly te A n a ly te A n a ly te A n a ly te A n a ly te A n a ly te A n a ly te S ta n d a rd S ta n d a rd S ta n d a rd Standard Standard Standard S ta n d a rd S ta n d a rd S ta n d a rd Standard S ta n d a rd S ta n d a rd A n a ly te Analyte A n a ly te A n a ly te A n a ly te Analyte A n a ly te A n a ly te A n a ly te A n a ly te A n a ly te A n a ly te A n a ly te A n a ly te A n a ly te A n a ly te A n a ly te A n a ly te A n a ly te A n a ly te QC A n a ly te Analyte Analyte Analyte A n a ly te Analyte Analyte Analyte A n a ly te A n a ly te A n a ly te A n a ly te A n a ly te A n a ly te A n a ly te A n a ly te A n a ly te QC A n a ly te A n a ly te A n a ly te A n a ly te A n a ly te A n a ly te A n a ly te A n a ly te A n a ly te A n a ly te A n a ly te A n a ly te Cone. 0.976 0 1.493 1.432 55.063 51.441 1.116 1.621 1.44 0.25 0.399 0.532 0.749 0.938 2.298 5.024 10.418 26.153 48.974 96.772 201.893 498.444 0.29 0,301 0.381 0.34 0.111 0.066 33.416 33.722 30.785 1.12 0.592 2.732 6.432 5.546 15.21 0.833 14.831 0.243 0.287 0.194 2.604 0.048 0.348 0.996 0.333 0.356 0.602 0.832 0.791 1.062 4.227 0.4 0.933 12.948 25.764 31.479 11.446 0.214 5.338 0.116 11.594 31.488 8.016 7.253 16.935 5.226 3.989 9.88 2.59 2.748 3.991 3M Study GLP10-01-02-15 Page 2 of 6 Page 72 of 514 a110325a Compound 3: MPFHxS # 74 a110325a074 75 a110325a075 76 a110325a076 77 a110325a077 78 a110325a078 79 a110325a079 80 a110325a060 81 a110325a081 82 a110325a062 83 a110325a083 84 a110325a084 85 a110325a085 86 a110325a086 87 a110325a087 88 a110325a088 89 a110325a089 90 a110325a090 91 a110325a091 92 a110325a092 93 a1103258093 94 a110325a094 95 a110325a095 96 a110325a096 97 a110325a097 98 a110325a098 99 a1103253099 100 a110325a100 101 a110325a101 102 a110325a102 103 a110325a103 104 a110325a104 105 a110325a105 GLP10-01-01-15-029 DAL SD SD22 DB 0005 df:50 GLP10-01-01-15-029 Dup DAL SD SD22 DB 0005 Lab Duplicate df:50 GLP10-01-01-15-029 LMS DAL SD SD22 DB 0005 Lab Matrix Spike df:50 GLP10-01-01-15-030 DAL SD SD22 0 0015 df:50 10 006-80 solvent blank EC-110316-07 10 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-030 Dup DAL SD SD22 0 0015 Lab Duplicate df:50 GLP10-01-01-15-030 LMS DAL SD SD22 0 0015 Lab Matrix Spike df:50 GLP10-01-01-15-031 DAL SD SD21 0 0000 df:50 GLP10-01-01-15-031 Dup DAL SD SD21 0 0000 Lab Duplicate df:50 GLP10-01-01-15-031 LMS DAL SD SD21 0 0000 Lab Matrix Spike df:50 GLP1Q-01-01-15-032 DAL SD SD21 0 0005 df:50 GLP10-01-01-15-032 Dup DAL SD SD21 0 0005 Lab Duplicate df:50 GLP10-01-01-15-032 LMS DAL SD SD21 0 0005 Lab Matrix Spike df:50 GLP10-01-01-15-033 DAL SD SD21 0 0015 df:50 GLP10-01-01-15-033 Dup DAL SD SD21 0 0015 Lab Duplicate df:50 GLP10-01 -01-15-033 LMS DAL SD SD21 0 0015 Lab Matrix Spike df:50 GLP10-01-01-15-034 DAL SS SS24 0 0000 df:50 GLP10-01-01-15-034 Dup DAL SS SS24 0 0000 Lab Duplicate df:50 GLP10-01-01-15-034 LMS DAL SS SS24 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-035 DAL SS SS24 0 0005 df:50 10 006-80 solvent blank EC-110316-05 2.5 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-035 Dup DAL SS SS24 0 0005 Lab Duplicate df:50 GLP10-01-01-15-035 LMS DAL SS SS24 0 0005 Lab Matrix Spike df:50 10 006-80 solvent blank EC-110316-06 5 ng Extracted Curve Point 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank Analyte Analyte Analyte Analyte Analyte QC Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte QC Analyte Analyte Analyte Analyte QC Analyte Analyte Analyte 3.348 2.784 5.628 1.679 0.122 10,177 0.321 1.415 3.331 2.528 3.347 7.601 3.826 3.505 9.036 1.807 1.812 5.096 1.901 1.724 3.334 2.859 0.111 2.996 0.277 2.905 6.905 0.253 5.202 0.128 0.24 0.115 Name 1 a110325a001 2 a110325a002 3 a110325a003 4 a110325a004 5 a110325a005 6 a110325a006 7 a110325a007 8 a110325a008 9 a110325a009 10 a110325a010 11 a110325a011 12 a110325a012 13 a110325a013 14 a110325a014 15 a110325a015 16 a110325a016 17 a110325a017 18 a110325a018 19 a1103258019 20 a110325a020 21 a110325a021 22 a110325a022 23 a110325a023 24 a110325a024 25 a110325a025 26 a110325a026 27 a110325a027 28 a110325a028 29 a110325a029 30 a110325a030 31 a110325a031 32 a110325a032 33 a110325a033 34 a110325a034 35 a110325a035 36 a110325a036 37 a110325a037 38 a110325a038 39 a110325a039 40 a110325a040 41 a110325a041 42 a110325a042 43 a110325a043 44 a110325a044 45 a110325a045 46 a110325a046 47 a110325a047 48 a110325a048 49 a110325a049 50 a110325a050 51 a110325a051 52 a110325a052 53 a110325a053 54 a110325a054 55 a110325a055 56 a110325a056 57 a110325a057 58 a110325a058 59 a110325a059 60 a110325a060 61 a110325a061 62 a110325a062 63 a110325a063 Samplelist Text 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 Warm-up: EC-110316-09 50 ng extracted curve point Warm-up: EC-110316-09 50 ng extracted curve point 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 EC-110316-01 0.2 ng Extracted Curve Point EC-110316-02 0.5 ng Extracted Curve Point EC-110316-03 0.75 ng Extracted Curve Point EC-110316-04 1 ng Extracted Curve Point EC-110316-05 2.5 ng Extracted Curve Point EC-110316-06 5 ng Extracted Curve Point EC-110316-07 10 ng Extracted Curve Point EC-110316-08 25 ng Extracted Curve Point EC-110316-09 50 ng Extracted Curve Point EC-110316-10 100 ng Extracted Curve Point EC-110316-11 200 ng Extracted Curve Point EC-110316-12 500 ng Extracted Curve Point 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 MB-110316-01 Method Blank w/o IS MB-110316-04 Method Blank w/ IS LCS-110316-07 300ng LCS in TCR-842 df:10 LCS-110316-08 300ng LCS in TCR-842 df:10 LCS-110316-09 300ng LCS in TCR-842 df:10 GLP10-01-01-15-002 DAL SS SS12 0 0000 df:50 GLP10-01-01-15-002 Dup DAL SS SS12 0 0000 Lab Duplicate df:50 GLP10-01-01-15-002 LMS DAL SS SS12 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-003 DAL SS SS12 0 0005 df:50 GLP10-01-01-15-003 Dup DAL SS SS12 0 0005 Lab Duplicate df:50 GLP10-01-01-15-003 LMS DAL SS SS12 0 0005 Lab Matrix Spike df:50 GLP10-01-01-15-006 LMS DAL SS SS16 DB 0000 Lab Matrix Spike df:50 GLP10-01-01-15-008 DAL SS SS11 0 0005 df:50 GLP10-01-01-15-010 LMS DAL SS SS20 DB 0000 Lab Matrix Spike df:50 GLP10-01-01-15-011 DAL SS SS19 0 0000 df:50 10 006-80 solvent blank EC-110316-05 2.5 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-011 LMS DAL SS SS19 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-012 LMS DAL SS SS19 0 0005 Lab Matrix Spike df:50 GLP10-01-01-15-014 Dup DAL SS SS15 0 0000 Lab Duplicate df:50 GLP10-01-01-15-014 LMS DAL SS SS15 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-016 Dup DAL SS SS14 0 0000 Lab Duplicate df:50 GLP10-01-01-15-016 LMS DAL SS SS14 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-020 DAL SS SS10 0 0000 df:50 GLP10-01-01-15-020 Dup DAL SS SS10 0 0000 Lab Duplicate df:50 GLP10-01-01-15-020 LMS DAL SS SS10 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-021 LMS DAL SS SS30 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-023 LMS DAL SS SS30 0 0015 Lab Matrix Spike df:50 GLP10-01-01-15-024 DAL SS SS25 0 0000 df:50 GLP10-01-01-15-024 Dup DAL SS SS25 0 0000 Lab Duplicate df:50 GLP10-01-01-15-024 LMS DAL SS SS25 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-025 DAL SS SS25 0 0005 df:50 10 006-80 solvent blank EC-110316-06 5 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-025 Dup DAL SS SS25 0 0005 Lab Duplicate df:50 Type Cone. Analyte 0.008 Analyte 0.013 Analyte 0.007 Analyte 0.006 Analyte 1.031 Analyte 1.056 Analyte 0.009 Analyte 0.02 Analyte 0.015 Analyte 0.015 Standard 1.004 Standard 0.943 Standard 0.914 Standard 0.972 Standard 1.023 Standard 0.915 Standard 0.938 Standard 0.963 Standard 1.014 Standard 1.131 Standard 1.063 Standard 1.121 Analyte 0.002 Analyte 0.011 Analyte 0.027 Analyte 0.011 Analyte 0.011 Analyte 0.946 Analyte 1.095 Analyte 0.998 Analyte 1.005 Analyte 1.031 Analyte 1.06 Analyte 0.982 Analyte 1.083 Analyte 0.958 Analyte 1.045 Analyte 0.88 Analyte 1.031 Analyte 0.858 Analyte 1.138 Analyte 0.003 QC 0.869 Analyte 0.009 Analyte 0.996 Analyte 1.045 Analyte 1.175 Analyte 1.049 Analyte 0.954 Analyte 1.054 Analyte 0.998 Analyte 0.833 Analyte 1.049 Analyte 0.797 Analyte 1.043 Analyte 1.073 Analyte 1.081 Analyte 1.011 Analyte 0.989 Analyte 0.021 QC 1.021 Analyte 0.025 Analyte 1.076 3M Study GLP10-01-02-15 Page 3 of 6 Page 73 of 514 a i 10325a Compound 4: M8PFOS # 64 a110325a064 65 a110325a065 66 a110325a066 67 a110325a067 68 a110325a068 69 a110325a069 70 a110325a070 71 a110325a071 72 a110325a072 73 a110325a073 74 a110325a074 75 a110325a075 76 a110325a076 77 a110325a077 78 a110325a078 79 a110325a079 80 a110325a080 81 a110325a081 82 a110325a082 83 a110325a083 84 a110325a084 85 a110325a085 86 a110325a086 87 a110325a087 88 a110325a088 89 a110325a089 90 a110325a090 91 a110325a091 92 a11032Sa092 93 a110325a093 94 a110325a094 95 a110325a095 96 a110325a096 97 a110325a097 98 a110325a098 99 a110325a099 100 a110325a100 101 a110325a101 102 a110325a102 103 a110325a103 104 a110325a104 105 a110325a105 GLP10-01-01-15-025 LMS DAL SS SS25 0 0005 Lab Matrix Spike df:50 GLP10-01-01-15-026 DAL SS SS25 0 0015 df:50 GLP10-01-01-15-026 Dup DAL SS SS25 0 0015 Lab Duplicate df:50 GLP10-01-01-15-026 LMS DAL SS SS25 0 0015 Lab Matrix Spike df:50 GLP10-01-01-15-027 DAL SD SD22 0 0000 df:50 GLP10-01-01-15-027 Dup DAL SD SD22 0 0000 Lab Duplicate df:50 GLP10-01-01-15-027 LMS DAL SD SD22 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-028 DAL SD SD22 0 0005 df:50 GLP10-01-01-15-028 Dup DAL SD SD22 0 0005 Lab Duplicate df:50 GLP10-01-01-15-028 LMS DAL SD SD22 0 0005 Lab Matrix Spike df:50 GLP10-01-01-15-029 DAL SD SD22 DB 0005 df:50 GLP10-01-01-15-029 Dup DAL SD SD22 DB 0005 Lab Duplicate df:50 GLP10-01-01-15-029 LMS DAL SD SD22 OB 0005 Lab Matrix Spike df:50 GLP10-01-01-15-030 DAL SD SD22 0 0015 df:50 10 006-80 solvent blank EC-110316-07 10 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01 -01-15-030 Dup DAL SD SD22 0 0015 Lab Duplicate df:50 GLP10-01-01 -15-030 LMS DAL SD SD22 0 0015 Lab Matrix Spike df:50 GLP 10-01-01-15-031 DAL SD SD21 00000 df:50 GLP 10-01-01-15-031 Dup DAL SD SD21 0 0000 Lab Duplicate df:50 GLP10-01-01-15-031 LMS DAL SD SD21 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-032 DAL SD SD21 0 0005 df:50 GLP10-01-01-15-032 Dup DAL SD SD21 0 0005 Lab Duplicate df:50 GLP10-01-01-15-032 LMS DAL SD SD21 0 0005 Lab Matrix Spike df:50 GLP10-01-01-15-033 DAL SD SD21 0 0015 df:50 GLP10-01-01-15-033 Dup DAL SD SD21 0 0015 Lab Duplicate df:50 GLP10-01-01-15-033 LMS DALSDSD21 0 0015 Lab Matrix Spike df:50 GLP10-01-01-15-034 DAL SS SS24 0 0000 df:50 GLP 10-01-01-15-034 Dup DAL SS SS24 0 0000 Lab Duplicate df:50 GLP10-01-01-15-034 LMS DAL SS SS24 0 0000 Lab Matrix Spike df:50 GLP 10-01-01-15-035 DAL SS SS24 0 0005 df:50 10 006-60 solvent blank EC-110316-05 2.5 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-035 Dup DAL SS SS24 0 0005 Lab Duplicate df:50 GLP10-01-01-15-035 LMS DAL SS SS24 0 0005 Lab Matrix Spike df:50 10 006-80 solvent blank EC-110316-06 5 ng Extracted Curve Point 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte QC Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte QC Analyte Analyte Analyte Analyte QC Analyte Analyte Analyte 0.99 0.993 0.907 1.035 1.071 1.069 0.904 0.949 0.95 0.852 0.929 0.966 0.914 1.013 0.007 0.901 0.025 0.942 0.985 0.919 0.93 1.008 0.967 1.066 0.895 0.956 0.974 0.937 0.973 0.988 1.044 0.871 0.01 0.936 0.003 1.017 0.808 0.007 0.935 0.026 0.006 0.01 Name 1 a110325a001 2 a110325a002 3 a110325a003 4 a110325a004 5 a110325a005 6 a110325a006 7 a110325a007 8 a110325a008 9 a110325a009 10 a110325a010 11 a110325a011 12 a110325a012 13 a110325a013 14 a110325a014 15 a110325a015 16 a110325a016 17 a110325a017 18 a110325a018 19 a110325a019 20 a110325a020 21 a110325a021 22 a11Q325a022 23 a110325a023 24 a110325a024 25 a110325a025 26 a110325a026 27 a110325a027 28 a110325a028 29 a110325a029 30 a110325a030 31 a110325a031 32 a110325a032 33 a110325a033 34 a110325a034 35 a110325a035 36 a110325a036 37 a110325a037 38 a110325a038 39 a110325a039 40 a110325a040 41 a110325a041 42 a110325a042 43 a110325a043 44 a110325a044 45 a110325a045 46 a110325a046 47 a110325a047 48 a110325a048 49 a110325a049 50 a110325a050 51 a110325a051 52 a110325a052 53 a110325a053 Samplelist Text 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 Warm-up: EC-110316-09 50 ng extracted curve point Warm-up: EC-110316-09 50 ng extracted curve point 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 EC-110316-01 0.2 ng Extracted Curve Point EC-110316-02 0.5 ng Extracted Curve Point EC-110316-03 0.75 ng Extracted Curve Point EC-110316-04 1 ng Extracted Curve Point EC-110316-05 2.5 ng Extracted Curve Point EC-110316-06 5 ng Extracted Curve Point EC-110316-07 10 ng Extracted Curve Point EC-110316-08 25 ng Extracted Curve Point EC-110316-09 50 ng Extracted Curve Point EC-110316-10 100 ng Extracted Curve Point EC-110316-11 200 ng Extracted Curve Point EC-110316-12 500 ng Extracted Curve Point 10 006-80 80:20 ACN:H2Q 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 MB-110316-01 Method Blank w/o IS MB-110316-04 Method Blank w/ IS LCS-110316-07 300ng LCS in TCR-842 df:10 LCS-110316-08 300ng LCS in TCR-842 df:10 LCS-110316-09 300ng LCS in TCR-842 df:10 GLP10-01-01-15-002 DAL SS SS12 0 0000 df:50 GLP10-01-01-15-002 Dup DAL SS SS12 0 0000 Lab Duplicate df:50 GLP10-01 -01-15-002 LMS DAL SS SS12 0 0000 Lab Matrix Spike df:50 GLP10-01 -01-15-003 DAL SS SS12 0 0005 df:50 GLP10-01-01-15-003 Dup DAL SS SS12 0 0005 Lab Duplicate df:50 GLP10-01-01-15-003 LMS DAL SS SS12 0 0005 Lab Matrix Spike df:50 GLP10-01-01-15-006 LMS DAL SS SS16 DB 0000 Lab Matrix Spike df:50 GLP10-01-01-15-008 DAL SS SS11 0 0005 df:50 GLP10-01-01-15-010 LMS DAL SS SS20 DB 0000 Lab Matrix Spike df:50 GLP10-01-01-15-011 DAL SS SS19 0 0000 df:50 10 006-80 solvent blank EC-110316-05 2.5 ng Extracted Curve Point 10 006-60 solvent blank GLP 10-01-01-15-011 LMS DAL SS SS19 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-012 LMS DAL SS SS19 0 0005 Lab Matrix Spike df:50 GLP 10-01-01-15-014 Dup DAL SS SS15 0 0000 Lab Duplicate df:50 GLP10-01-01-15-014 LMS DAL SS SS15 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-016 Dup DAL SS SS14 0 0000 Lab Duplicate df:50 GLP10-01-01-15-016 LMS DAL SS SS14 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-020 DAL SS SS10 0 0000 df:50 GLP10-01-01-15-020 Dup DAL SS SS10 0 0000 Lab Duplicate df:50 GLP10-01-01-15-020 LMS DAL SS SS10 0 0000 Lab Matrix Spike df:50 Type Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte QC Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Cone. 0.015 0.012 0.02 0.036 1.098 1.14 0.018 0.008 0.004 0.006 1.128 1.131 1.116 1.019 0.958 0.992 0.971 1.035 0.865 0.993 0.857 0.916 0.011 0.02 0.008 0.009 0.016 1.042 1.119 1.058 1.123 1.013 1.09 1.043 1.194 1.08 1.161 1.143 0.995 0.989 1.075 0.014 1.017 0.007 0.979 1.018 1.129 1.105 0.903 1.016 1.008 1.154 1.003 3M Study GLP10-01-02-15 Page 4 of 6 Page 74 of 514 a110325a Compound 5: MPFOS # 54 a110325a054 55 a110325a055 56 a110325a056 57 a110325a057 58 a110325a058 59 a110325a059 60 a110325a060 61 a110325a061 62 a110325a062 63 a110325a063 64 a110325a064 65 a110325a065 66 a110325a066 67 a110325a067 66 a110325a068 69 a110325a069 70 a110325a070 71 a110325a071 72 a110325a072 73 a110325a073 74 a110325a074 75 a110325a075 76 a110325a076 77 a110325a077 78 a110325a078 79 a110325a079 80 a110325a080 81 a110325a081 82 a110325a082 83 a110325a083 84 a110325a084 85 a110325a085 86 a110325a066 87 a110325a087 88 a110325a088 89 a110325a089 90 a110325a090 91 a110325a091 92 a110325a092 93 a110325a093 94 a110325a094 95 a110325a095 96 a110325a096 97 a110325a097 98 a110325a098 99 a110325a099 100 a110325a100 101 a110325a101 102 a110325a102 103 a110325a103 104 a110325a104 105 a110325a105 GLP10-01-01-15-021 LMS DAL SS SS30 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-023 LMS DAL SS SS30 0 0015 Lab Matrix Spike df:50 GLP10-01-01-15-024 DAL SS SS25 0 0000 df:50 GLP10-01-01-15-024 Dup DAL SS SS25 0 0000 Lab Duplicate df:50 GLP10-01-01-15-024 LMS DAL SS SS25 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-025 DAL SS SS25 0 0005 df:50 10 006-80 solvent blank EC-110316-06 5 ng Extracted Curve Point 10 006-80 solvent blank GLP 10-01-01-15-025 Dup DAL SS SS25 0 0005 Lab Duplicate df:50 GLP10-01-01-15-025 LMS DAL SS SS25 0 0005 Lab Matrix Spike df:50 GLP 10-01-01-15-026 DAL SS SS25 0 0015 df:50 GLP10*01-01-15-026 Dup DAL SS SS25 0 0015 Lab Duplicate df:50 GLP10-01-01-15-026 LMS DAL SS SS25 0 0015 Lab Matrix Spike df:50 GLP10-01-01-15-027 DAL SD SD22 0 0000 df:50 GLP10-01-01-15-027 Dup DAL SD SD22 0 0000 Lab Duplicate df:50 GLP10-01-01-15-027 LMS DAL SD SD22 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-028 DAL SD SD22 0 0005 df:50 GLP10-01-01-15-028 Dup DAL SD SD22 0 0005 Lab Duplicate df:50 GLP10-01-01-15-028 LMS DAL SD SD22 0 0005 Lab Matrix Spike df:50 GLP10-01-01-15-029 DAL SD SD22 DB 0005 df:50 GLP10-01-01-15-029 Dup DAL SD SD22 DB 0005 Lab Duplicate df:50 GLP10-01-01-15-029 LMS DAL SD SD22 DB 0005 Lab Matrix Spike df:50 GLP10-01-01-15-030 DAL SD SD22 0 0015 df:50 10 006-80 solvent blank EC-110316-07 10 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-030 Dup DAL SD SD22 0 0015 Lab Duplicate df:50 GLP10-01-01-15-030 LMS DAL SD SD22 0 0015 Lab Matrix Spike df:50 GLP10-01-01-15-031 DAL SD SD21 0 0000 df:50 GLP10-01-01-15-031 Dup DAL SD SD21 0 0000 Lab Duplicate df:50 GLP10-01-01-15-031 LMS DAL SD SD21 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-032 DAL SD SD21 0 0005 df:50 GLP10-01 -01-15-032 Dup DAL SD SD21 0 0005 Lab Duplicate df:50 GLP10-01-01-15-032 LMS DAL SD SD21 0 0005 Lab Matrix Spike df:50 GLP10-01-01-15-033 DAL SD SD21 0 0015 df:50 GLP10-01 -01-15-033 Dup DAL SD SD21 0 0015 Lab Duplicate df:50 GLP10-01-01-15-033 LMS DAL SD SD21 0 0015 Lab Matrix Spike df:50 GLP10-01-01-15-034 DAL SS SS24 0 0000 df:50 GLP10-01-01-15-034 Dup DAL SS SS24 0 0000 Lab Duplicate df:50 GLP10-01-01-15-034 LMS DAL SS SS24 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-035 DAL SS SS24 0 0005 df:50 10 006-60 solvent blank EC-110316-05 2.5 ng Extracted Curve Point 10 006-60 solvent blank GLP10-01-01-15-035 Dup DAL SS SS24 0 0005 Lab Duplicate df:50 GLP10-01-01-15-035 LMS DAL SS SS24 0 0005 Lab Matrix Spike df:50 10 006-60 solvent blank EC-110316-06 5 ng Extracted Curve Point 10 006-60 solvent blank 10 006-60 solvent blank 10 006-60 solvent blank Analyte Analyte Analyte Analyte Analyte Analyte Analyte QC Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte QC Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte QC Analyte Analyte Analyte Analyte QC Analyte Analyte Analyte 1.017 1.041 0.942 1.079 0.968 0.981 0.026 1.028 0.001 1.121 1.025 1.039 1.041 1.055 0.932 1.098 0.975 1.113 1.142 0.937 0.942 1.15 1.004 1.083 0.03 0.971 0.027 1.012 0.995 1.056 1.006 1.02 1.093 0.994 1.061 1.07 1.089 1.067 1.055 1.034 0.98 1.063 0.019 0.932 0.016 0.989 0.993 0.003 0.913 0.009 0.014 0.013 Name 1 a110325a001 2 a110325a002 3 a110325a003 4 a110325a004 5 a110325a005 6 a110325a006 7 a110325a007 6 a110325a008 9 a110325a009 10 a110325a010 11 a110325a011 12 a110325a012 13 a110325a013 14 a110325a014 15 a110325a015 16 a110325a016 17 a110325a017 18 a110325a018 19 a110325a019 20 a110325a020 21 a110325a021 22 a110325a022 23 a110325a023 24 a110325a024 25 a110325a025 26 a110325a026 27 a110325a027 28 a110325a028 29 a110325a029 30 a110325a030 31 a110325a031 32 a110325a032 33 a110325a033 34 a110325a034 35 a110325a035 36 a110325a036 37 a110325a037 38 a110325a038 39 a110325a039 40 a110325a040 41 a110325a041 42 a110325a042 43 a110325a043 Sampletist Text 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 Warm-up: EC-110316-09 50 ng extracted curve point Warm-up: EC-110316-09 50 ng extracted curve point 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H2Q 10 006-80 80:20 ACN:H20 EC-110316-01 0.2 ng Extracted Curve Point EC-110316-02 0.5 ng Extracted Curve Point EC-110316-03 0.75 ng Extracted Curve Point EC-110316-04 1 ng Extracted Curve Point EC-110316-05 2.5 ng Extracted Curve Point EC-110316-06 5 ng Extracted Curve Point EC-110316-07 10 ng Extracted Curve Point EC-110316-08 25 ng Extracted Curve Point EC-110316-09 50 ng Extracted Curve Point EC-110316-10 100 ng Extracted Curve Point EC-110316-11 200 ng Extracted Curve Point EC-110316-12 500 ng Extracted Curve Point 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 MB-110316-01 Method Blank w/o IS MB-110316-04 Method Blank w/ IS LCS-110316-07 300ng LCS in TCR-842 df:10 LCS-110316-08 300ng LCS in TCR-842 df:10 LCS-110316-09 300ng LCS in TCR-842 df:10 GLP10-01-01-15-002 DAL SS SS12 0 0000 df:50 GLP10-01-01-15-002 Dup DAL SS SS12 0 0000 Lab Duplicate df:50 GLP10-01-01-15-002 LMS DAL SS SS12 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-003 DAL SS SS12 0 0005 df:50 GLP10-01-01-15-003 Dup DAL SS SS12 0 0005 Lab Duplicate df:50 GLP10-01-01-15-003 LMS DAL SS SS12 0 0005 Lab Matrix Spike df:50 GLP10-01-01-15-006 LMS DAL SS SS16 DB 0000 Lab Matrix Spike df:50 GLP10-01-01-15-008 DAL SS SS11 0 0005 df:50 GLP10-01-01-15-010 LMS DAL SS SS20 DB 0000 Lab Matrix Spike df:50 GLP10-01-01-15-011 DAL SS SS19 0 0000 df:50 10 006-80 solvent blank EC-110316-05 2.5 ng Extracted Curve Point Type Cone. Analyte 0 Analyte 0 Analyte 0 Analyte 0 Analyte 56.71 Analyte 56.167 Analyte 0 Analyte 0 Analyte 0 Anafyte 0 Standard 0.163 Standard 0.552 Standard 0.579 Standard 0.977 Standard 2.4 Standard 4.718 Standard 10.061 Standard 26.459 Standard 50.047 Standard 95.48 Standard 182.504 Standard 481.568 Analyte 0.101 Analyte 0 Analyte 0 Analyte 0 Analyte 0 Analyte 3.364 Analyte 3.294 Analyte 2.914 Analyte 3.024 Analyte 3.125 Analyte 3.191 Analyte 3.097 Analyte 2.926 Analyte 2.781 Analyte 2.696 Analyte 2.946 Analyte 2.91 Analyte 3.353 Analyte 2.846 Analyte 0 QC 2.376 3M Study GLP10-01-02-15 Page 5 of 6 Page 75 of 514 a110325a 44 a110325a044 45 a110325a045 46 a110325a046 47 a110325a047 48 a110325a048 49 a110325a049 50 a110325a050 51 a110325a051 52 a110325a052 53 a110325a053 54 a110325a054 55 a110325a055 56 a110325a056 57 a110325a057 58 a110325a058 59 a110325a059 60 a110325a060 61 a110325a061 62 a110325a062 63 a110325a063 64 a110325a064 65 a110325a065 66 a110325a066 67 a110325a067 68 a110325a068 69 a110325a069 70 a110325a070 71 a110325a071 72 a110325a072 73 a110325a073 74 a110325a074 75 a110325a075 76 a110325a076 77 a110325a077 78 a110325a078 79 a110325a079 60 a110325a080 61 a110325a081 62 a110325a082 63 a110325a083 84 a110325a084 85 a110325a085 86 a110325a066 87 a110325a087 88 a110325a088 89 a110325a089 90 a110325a090 91 a110325a091 92 a110325a092 93 a110325a093 94 a110325a094 95 a110325a095 96 a110325a096 97 a110325a097 98 a110325a098 99 a110325a099 100 a110325a100 101 a110325a101 102 a110325a102 103 a110325a103 104 a110325a104 105 a110325a105 data reported data not highlighted was not reported 10 006-80 solvent blank GLP10-01-01-15-011 LMS DAL SS SS19 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-012 LMS DAL SS SS19 0 0005 Lab Matrix Spike df:50 GLP10-01-01-15-014 Dup DAL SS SS15 0 0000 Lab Duplicate df:50 GLP10-01-01-15-014 LMS DAL SS SS15 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-016 Dup DAL SS SS14 0 0000 Lab Duplicate df:50 GLP10-01-01-15-016 LMS DAL SS SS14 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-020 DAL SS SS10 0 0000 df:50 GLP10-01-01-15-020 Dup DAL SS SS10 0 0000 Lab Duplicate df:50 GLP10-01-01-15-020 LMS DAL SS SS10 0 0000 Lab Matrix Spike df:50 GLP 10-01-01-15-021 LMS DAL SS SS30 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-023 LMS DAL SS SS30 0 0015 Lab Matrix Spike df:50 GLP10-01-01-15-024 DAL SS SS25 0 0000 df:50 GLP10-01-01-15-024 Dup DAL SS SS25 0 0000 Lab Duplicate df:50 GLP10-01-01-15-024 LMS DAL SS SS25 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-025 DAL SS SS25 0 0005 df:50 10 006-80 solvent blank EC-110316-06 5 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-025 Dup DAL SS SS25 0 0005 Lab Duplicate df:50 GLP10-01-01-15-025 LMS DAL SS SS25 0 0005 Lab Matrix Spike df:50 GLP10-01-01-15-026 DAL SS SS25 0 0015 df:50 GLP10-01-01-15-026 Dup DAL SS SS25 0 0015 Lab Duplicate df:50 GLP10-01-01-15-026 LMS DAL SS SS25 0 0015 Lab Matrix Spike df:50 GLP10-01 -01-15-027 DAL SD SD22 0 0000 df:50 GLP10-01-01-15-027 Dup DAL SD SD22 0 0000 Lab Duplicate df:50 GLP10-01-01-15-027 LMS DAL SD SD22 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-028 DAL SD SD22 0 0005 df:50 GLP10-01-01-15-028 Dup DAL SD SD22 0 0005 Lab Duplicate df:50 GLP10-01-01-15-028 LMS DAL SD SD22 0 0005 Lab Matrix Spike df:50 GLP10-01-01-15-029 DAL SD SD22 DB 0005 df:50 GLP10-01-01-15-029 Dup DAL SD SD22 DB 0005 Lab Duplicate df:50 GLP 10-01-01-15-029 LMS DAL SD SD22 DB 0005 Lab Matrix Spike df:50 GLP 10-01-01-15-030 DAL SD SD22 0 0015 df:50 10 006-80 solvent blank EC-110316-07 10 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-030 Dup DAL SD SD22 0 0015 Lab Duplicate df:50 GLP10-01-01-15-030 LMS DAL SD SD22 0 0015 Lab Matrix Spike df:50 GLP10-01-01-15-031 DAL SD SD21 0 0000 df:50 GLP10-01-01-15-031 Dup DAL SD SD21 0 0000 Lab Duplicate df:50 GLP10-01-01-15-031 LMS DAL SD SD21 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-032 DAL SD SD21 0 0005 df:50 GLP10-01-01-15-032 Dup DAL SD SD21 0 0005 Lab Duplicate df:50 GLP10-01-01-15-032 LMS DAL SD SD21 0 0005 Lab Matrix Spike df:50 GLP10-01-01-15-033 DAL SD SD21 0 0015 df:50 GLP10-01-01-15-033 Dup DAL SD SD21 0 0015 Lab Duplicate df:50 GLP10-01-01-15-033 LMS DAL SD SD21 0 0015 Lab Matrix Spike df:50 GLP10-01-01-15-034 DAL SS SS24 0 0000 df:50 GLP10-01-01-15-034 Dup DAL SS SS24 0 0000 Lab Duplicate df:50 GLP10-01-01-15-034 LMS DAL SS SS24 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-035 DAL SS SS24 0 0005 df;50 10 006-80 solvent blank EC-110316-05 2.5 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-035 Dup DAL SS SS24 0 0005 Lab Duplicate df:50 GLP10-01-01-15-035 LMS DAL SS SS24 0 0005 Lab Matrix Spike df:50 10 006-80 solvent blank EC-110316-06 5 ng Extracted Curve Point 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte QC Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte QC Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte QC Analyte Analyte Analyte Analyte QC Analyte Analyte Analyte 0 3.212 3.067 3.185 2.763 2.956 3.063 3.007 3.122 2.746 2.958 3.181 3.231 2.802 2.975 3.019 0 4.812 0 3.07 2.776 3.341 2.791 2.838 3.187 3.108 3.083 3.362 3.309 2.662 2.841 3.039 2.964 3.223 0 10.093 0 3.015 3.001 2.792 3.02 3.217 2.794 3.173 3.202 2.741 3.036 3.073 2.932 2.952 3.269 2.799 0 2.357 0 2.842 2.778 0 5.162 0 0 0 3M Study GLP10-01-02-15 Page 6 of 6 Page 76 of 514 a110329a Quantify Compound Summary Report Sample List: Last modified: Method: Last modified: Job Code: D:\Massiynx\Amelia2009.pro\SAMPLEDB\a110329a Fri Apr 01 09:00:30 2011 D:\Masslynx\Amelia2009.pro\METHDB\a110329a Thu Mar 31 16:50:26 2011 Printed: Fri Apr 01 10:19:25 2011 Compound 1: PFOS Name 1 a110329a001 2 a110329a002 3 a110329a003 4 a110329a004 5 a110329a005 6 a110329a006 7 a110329a007 8 a110329a008 9 a110329a009 10 a110329a010 11 a110329a011 12 a110329a012 13 a110329a013 14 a110329a014 15 a110329a015 16 a110329a016 17 a110329a017 18 a110329a018 19 a110329a019 20 a110329a020 21 a110329a021 22 a110329a022 23 a110329a023 24 a110329a024 25 a110329a025 26 a110329a026 27 a110329a027 28 a110329a028 29 a110329a029 30 a110329a030 31 a110329a031 32 a110329a032 33 a110329a033 34 a110329a034 35 a110329a035 36 a110329a036 37 a110329a037 38 a110329a038 39 a110329a039 40 a110329a040 41 a110329a041 42 a110329a042 43 a110329a043 44 a110329a044 45 a110329a045 46 a110329a046 47 a110329a047 48 a110329a048 49 a110329a049 50 a110329a050 51 a110329a051 52 a110329a052 53 a110329a053 54 a110329a054 55 a110329a055 56 a110329a056 57 a110329a057 58 a110329a058 59 a110329a059 60 a110329a060 61 a110329a061 62 a110329a062 63 a110329a063 64 a110329a064 65 a110329a065 66 a110329a066 67 a110329a067 68 a110329a068 69 a110329a069 70 a110329a070 71 a110329a071 72 a110329a072 73 a110329a073 74 a110329a074 Samplelist Text 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 Warm-up: EC-110316-09 50 ng extracted curve point Warm-up: EC-110316-09 50 ng extracted curve point 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 EC-110316-01 0.2 ng Extracted Curve Point EC-110316-02 0.5 ng Extracted Curve Point EC-110316-03 0.75 ng Extracted Curve Point EC-110316-04 1 ng Extracted Curve Point EC-110316-05 2.5 ng Extracted Curve Point EC-110316-06 5 ng Extracted Curve Point EC-110316-07 10 ng Extracted Curve Point EC-110316-08 25 ng Extracted Curve Point EC-110316-09 50 ng Extracted Curve Point EC-110316-10 100 ng Extracted Curve Point EC-110316-11 200 ng Extracted Curve Point EC-110316-12 500 ng Extracted Curve Point 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 MB-110316-01 Method Blank w/o IS MB-110316-04 Method Blank w/ IS GLP10-01-01-15-063 LMS DAL SS SS27 0 0005 Lab Matrix Spike df:50 GLP10-01-01-15-065 LMS DAL SS SS22 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-067 LMS DAL SS SS22 DB 0005 Lab Matrix Spike df:50 GLP10-01-01-15-069 DAL SS SS21 0 0000 df:50 GLP10-01-01-15-069 Dup DAL SS SS21 0 0000 Lab Duplicate df:50 GLP10-01-01-15-069 LMS DAL SS SS21 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-070 LMS DAL SS SS21 0 0005 Lab Matrix Spike df:50 GLP10-01 -01-15-072 DAL SD SD18 0 0000 df:50 GLP10-01-01-15-072 Dup DAL SD SD18 0 0000 Lab Duplicate df:50 GLP10-01 -01-15-072 LMS DAL SD SD18 0 0000 Lab Matrix Spike df:50 GLP 10-01-01-15-073 DAL SD SD18 0 0005 df:50 GLP10-01-01-15-073 Dup DAL SD SD18 0 0005 Lab Duplicate df:50 GLP10-01-01-15-073 LMS DAL SD SD18 0 0005 Lab Matrix Spike df:50 10 006-80 solvent blank EC-110316-05 2.5 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-075 DAL SD SD19 0 0000 df:50 GLP10-01-01-15-075 Dup DAL SD SD19 0 0000 Lab Duplicate df:50 GLP10-01-01-15-075 LMS DAL SD SD19 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-076 DAL SD SD19 0 0005 df:50 GLP10-01-01-15-076 Dup DAL SD SD19 0 0005 Lab Duplicate df:50 GLP10-01-01-15-076 LMS DAL SD SD19 0 0005 Lab Matrix Spike df:50 GLP10-01-01-15-077 LMS DAL SD SD19 0 0015 Lab Matrix Spike df:50 GLP10-01-01-15-079 DAL SS SS26 0 0000 df:50 GLP10-01-0115-079 Dup DAL SS SS26 0 0000 Lab Duplicate df:50 GLP10-01-01-15-079 LMS DAL SS SS26 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-080 DAL SS SS26 DB 0000 df:50 GLP10-01-01-15-080 Dup DAL SS SS26 DB 0000 Lab Duplicate df:50 GLP10-01-01-15-080 LMS DAL SS SS26 DB 0000 Lab Matrix Spike df:50 GLP10-01-01-15-081 DAL SS SS26 0 0005 df:50 GLP 10-01-01-15-081 Dup DAL SS SS26 0 0005 Lab Duplicate df:50 10 006-80 solvent blank EC-110316-06 5 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-081 LMS DAL SS SS26 0 0005 Lab Matrix Spike df:50 GLP10-01-01-15-082 DAL SS SS26 0 0015 df:50 GLP10-01-01-15-082 Dup DAL SS SS26 0 0015 Lab Duplicate df:50 GLP10-01-01-15-082 LMS DAL SS SS26 0 0015 Lab Matrix Spike df:50 GLP10-01-01-15-084 DAL SS SS12 0 0015 df:50 GLP10-01-01-15-084 Dup DAL SS SS12 0 0015 Lab Duplicate df:50 GLP10-01-01-15-084 LMS DAL SS SS12 0 0015 Lab Matrix Spike df:50 GLP10-01-01-15-085 LMS DAL SS SS19 0 0015 Lab Matrix Spike df:50 10 006-60 solvent blank EC-110316-07 10 ng Extracted Curve Point 10 006-60 solvent blank 10 006-60 solvent blank Type Cone. Analyte Analyte Analyte Analyte Analyte 48.859 Analyte 52.035 Analyte Analyte Analyte Analyte Standard 0.206 Standard 0.535 Standard 0.583 Standard 1.131 Standard 2.592 Standard 4.795 Standard 9.761 Standard 25.24 Standard 50.408 Standard 99.603 Standard 199.943 Standard 500.042 Analyte 0.091 Analyte Analyte Analyte Analyte Analyte Analyte 9.121 Analyte , 10.255 Analyte 9.275 Analyte 22.099 Analyte 15.299 Analyte 25.045 Analyte 11.418 Analyte 20.67 Analyte 18.811 Analyte 39.154 Analyte 15.179 Analyte 11.512 Analyte 21.365 Analyte QC 2.424 Analyte Analyte 21.939 Analyte 19.296 Analyte 43.666 Analyte 22.126 Analyte 15.513 Analyte 49.603 Analyte 17.852 Analyte 21.887 Analyte 21.261 Analyte 34.47 Analyte 94.842 Analyte 21.648; Analyte 34.11 Analyte 27.849 Analyte 28.357 Analyte QC 4.895 Analyte Analyte 50.634 Analyte 22.635< Analyte 18.853 Analyte 29.45 Analyte 45.151 Analyte 47.818 Analyte 153.898 Analyte 15.66 Analyte QC 9.632 Analyte 0.084 Analyte : PFHS Name 1 a110329a001 2 a110329a002 3 a110329a003 4 a110329a004 5 a110329a005 6 a110329a006 7 a110329a007 8 a110329a008 Samplelist Text 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 Warm-up: EC-110316-09 50 ng extracted curve point Warm-up: EC-110316-09 50 ng extracted curve point 10 006-80 80:20 ACN.H20 10 006-80 80:20 ACN:H20 Type Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Cone. 1.259 1.321 0.946 1.361 51.153 46.8 1.409 1.091 3M Study GLP10-01-02-15 Page 1 of 5 Page a i 10329a 9 a110329a009 10 a110329a010 11 a110329a011 12 a110329a012 13 a110329a013 14 a110329a014 15 a110329a015 16 a110329a016 17 a110329a017 18 a110329a018 19 a110329a019 20 a110329a020 21 a110329a021 22 a110329a022 23 a110329a023 24 a110329a024 25 a110329a025 26 a110329a026 27 a110329a027 28 a110329a028 29 a110329a029 30 a110329a030 31 a110329a031 32 a110329a032 33 a110329a033 34 a110329a034 35 a110329a035 36 a110329a036 37 a110329a037 38 a110329a038 39 a110329a039 40 a110329a040 41 a110329a041 42 a110329a042 43 a110329a043 44 a110329a044 45 a110329a045 46 a110329a046 47 a110329a047 48 a110329a048 49 a110329a049 50 a110329a050 51 a110329a051 52 a110329a052 53 a110329a053 54 a110329a054 55 a110329a055 56 a110329a056 57 a110329a057 58 a110329a058 59 a110329a059 60 a110329a060 61 a110329a061 62 a110329a062 63 a110329a063 64 a110329a064 65 a110329a065 66 a110329a066 67 a110329a067 68 a110329a068 69 a110329a069 70 a110329a070 71 a110329a071 72 a110329a072 73 a110329a073 74 a110329a074 Compound 3: MPFHxS # Name 1 a110329a001 2 a110329a002 3 a110329a003 4 a110329a004 5 a110329a005 6 a110329a006 7 a110329a007 8 a110329a008 9 a110329a009 10 a110329a010 11 a110329a011 12 a110329a012 13 a110329a013 14 a110329a014 15 a110329a015 16 a110329a016 17 a110329a017 18 a110329a018 19 a110329a019 20 a110329a020 21 a110329a021 22 a110329a022 23 a110329a023 24 a110329a024 25 a110329a025 26 a110329a026 27 a110329a027 28 a110329a028 29 a110329a029 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 EC-110316-01 0.2 ng Extracted Curve Point EC-110316-02 0.5 ng Extracted Curve Point EC-110316-03 0.75 ng Extracted Curve Point EC-110316-04 1 ng Extracted Curve Point EC-110316-05 2.5 ng Extracted Curve Point EC-110316-06 5 ng Extracted Curve Point EC-110316-07 10 ng Extracted Curve Point EC-110316-08 25 ng Extracted Curve Point EC-110316-09 50 ng Extracted Curve Point EC-110316-10 100 ng Extracted Curve Point EC-110316-11 200 ng Extracted Curve Point EC-110316-12 500 ng Extracted Curve Point 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 MB-110316-01 Method Blank w/o IS MB-110316-04 Method Blank w/ IS GLP10-01-01-15-063 LMS DAL SS SS27 0 0005 Lab Matrix Spike df:50 GLP10-01-01-15-065 LMS DAL SS SS22 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-067 LMS DAL SS SS22 D8 0005 Lab Matrix Spike df:50 GLP10-01-01-15-069 DAL SS SS21 0 0000 df:50 GLP10-01-01-15-069 Dup DAL SS SS21 0 0000 Lab Duplicate df:50 GLP10-01 -01-15-069 LMS DAL SS SS21 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-070 LMS DAL SS SS21 0 0005 Lab Matrix Spike df:50 GLP10-01-01-15-072 DAL SD SD18 0 0000 df:50 GLP 10-01-01-15-072 Dup DAL SD SD18 0 0000 Lab Duplicate df:50 GLP 10-01-01-15-072 LMS DAL SD SD18 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-073 DAL SD SD18 0 0005 df:50 GLP10-01-01-15-073 Dup DAL SD $D18 0 0005 Lab Duplicate df:50 GLP 10-01-01-15-073 LMS DAL SD SD18 0 0005 Lab Matrix Spike df:50 10 006-80 solvent blank EC-110316-05 2.5 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-075 DAL SD SD19 0 0000 df:50 GLP10-01-01-15-075 Dup DAL SD SD19 0 0000 Lab Duplicate df:50 GLP10-01-01-15-075 LMS DAL SD SD19 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-076 DAL SD SD19 0 0005 df:50 GLP10-01-01-15-076 Dup DAL SD SD19 0 0005 Lab Duplicate df:50 GLP10-01-01-15-076 LMS DAL SD SD19 0 0005 Lab Matrix Spike df:50 GLP10-01-01-15-077 LMS DAL SD SD19 0 0015 Lab Matrix Spike df:50 GLP10-01-01-15-079 DAL SS SS26 0 0000 df:50 GLP10-01-01-15-079 Dup DAL SS SS26 0 0000 Lab Duplicate df:50 GLP10-01-01-15-079 LMS DAL SS SS26 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-080 DAL SS SS26 DB 0000 df:50 GLP 10-01-01-15-080 Dup DAL SS SS26 DB 0000 Lab Duplicate df:50 GLP10-01-01-15-080 LMS DAL SS SS26 DB 0000 Lab Matrix Spike df:50 GLP10-01-01-15-081 DAL SS SS26 0 0005 df:50 GLP10-01-01-15-081 Dup DAL SS SS26 0 0005 Lab Duplicate df:50 10 006-80 solvent blank EC-110316-06 5 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-081 LMS DAL SS SS26 0 0005 Lab Matrix Spike df:50 GLP10-01-01-15-082 DAL SS SS26 0 0015 df:50 GLP10-01-01-15-082 Dup DAL SS SS26 0 0015 Lab Duplicate df:50 GLP10-01-01-15-082 LMS DAL SS SS26 0 0015 Lab Matrix Spike df:50 GLP10-01-01-15-084 DAL SS SS12 0 0015 df:50 GLP10-01-01-15-084 Dup DAL SS SS12 0 0015 Lab Duplicate df:50 GLP10-01-01-15-084 LMS DAL SS SS12 0 0015 Lab Matrix Spike df:50 GLP 10-01-01-15-085 LMS DAL SS SS19 0 0015 Lab Matrix Spike df:50 10 006-80 solvent blank EC-110316-07 10 ng Extracted Curve Point 10 006-80 solvent blank 10 006-80 solvent blank Analyte Analyte Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte QC Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte QC Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte QC Analyte Analyte 1.047 0.046 0.197 0.417 0.768 1.08 2.638 4.869 10.062 25.9 49.649 97.979 199.86 498.975 0.326 0.392 0.405 0.413 0.16 0.036 0.269 0.27 0.206 0.259 0.367 0.841 1.871 2.686 2.26 7.323 2.428 2.368 4.865 0.216 2.538 0.042 3.595 6.153 10.514 3.933 4.268 8.88 4.66 0.74 5.96 0.771 5.523 0.231 1.992 1.657 0.672 4.944 0.008 1.234 1.518 2.276 3.801 5.367 6.582 17.271 1.616 8.681 0 Samplelist Text 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 Warm-up: EC-110316-09 50 ng extracted curve point Warm-up: EC-110316-09 50 ng extracted curve point 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 ' 10 006-80 80:20 ACN:H20 EC-110316-01 0.2 ng Extracted Curve Point EC-110316-02 0.5 ng Extracted Curve Point EC-110316-03 0.75 ng Extracted Curve Point EC-110316-04 1 ng Extracted Curve Point EC-110316-05 2.5 ng Extracted Curve Point EC-110316-06 5 ng Extracted Curve Point EC-110316-07 10 ng Extracted Curve Point EC-110316-08 25 ng Extracted Curve Point EC-110316-09 50 ng Extracted Curve Point EC-110316-10 100 ng Extracted Curve Point EC-110316-11 200 ng Extracted Curve Point EC-110316-12 500 ng Extracted Curve Point 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 MB-110316-01 Method Blank w/o IS MB-110316-04 Method Blank w/ IS GLP10-01-01-15-063 LMS DAL SS SS27 0 0005 Lab Matrix Spike df:50 Type Cone. Analyte Analyte Analyte Analyte Analyte 0.891 Analyte 0.955 Analyte Analyte Anafyte Analyte Standard 1.014 Standard 0.941 Standard 0.98 Standard 0.925 Standard 1,013 Standard 0.953 Standard Standard 1.041 1.065 Standard 1.096 Standard 0.858 Standard 0.972 Standard 1.142 Analyte Analyte Analyte Analyte Analyte Analyte 1.019 Analyte 0.957 3M Study GLP10-01-02-15 Page 2 of 5 Page 78 of 514 a110329a 30 a110329a030 31 a110329a031 32 a110329a032 33 a110329a033 34 a110329a034 35 a110329a035 36 a110329a036 37 a110329a037 38 a110329a038 39 a110329a039 40 a110329a040 41 a110329a041 42 a110329a042 43 a110329a043 44 a110329a044 45 a110329a045 46 a110329a046 47 a110329a047 48 a110329a048 49 a110329a049 50 a110329a050 51 a110329a051 52 a110329a052 53 a110329a053 54 a110329a054 55 a110329a055 56 a110329a056 57 a110329a057 58 a110329a058 59 a110329a059 60 a110329a060 61 a110329a061 62 a110329a062 63 a110329a063 64 a110329a064 65 a110329a065 66 a110329a066 67 a110329a067 68 a110329a068 69 a110329a069 70 a110329a070 71 a110329a071 72 a110329a072 73 a110329a073 74 a110329a074 Compound 4: M8PFOS # Name 1 a110329a001 2 a110329a002 3 a110329a003 4 a110329a004 5 a110329a005 6 a110329a006 7 a110329a007 8 a110329a008 9 a110329a009 10 a110329a010 11 a110329a011 12 a110329a012 13 a110329a013 14 a110329a014 15 a110329a015 16 a110329a016 17 a110329a017 18 a110329a018 19 a110329a019 20 a110329a020 21 a110329a021 22 a110329a022 23 a110329a023 24 a110329a024 25 a110329a025 26 a110329a026 27 a110329a027 28 a110329a028 29 a110329a029 30 a110329a030 31 a110329a031 32 a110329a032 33 a110329a033 34 a110329a034 35 a110329a035 36 a110329a036 37 a110329a037 38 a110329a038 39 a110329a039 40 a110329a040 41 a110329a041 42 a110329a042 43 a110329a043 44 a110329a044 45 a110329a045 46 a110329a046 47 a110329a047 48 a110329a048 49 a110329a049 50 a110329a050 GLP10-01-01-15-065 LMS DAL SS SS22 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-067 LMS DAL SS SS22 DB 0005 Lab Matrix Spike df:50 GLP10-01-01-15-069 DAL SS SS21 0 0000 df:50 GLP10-01-01-15-069 Dup DAL SS SS21 0 0000 Lab Duplicate df:50 GLP 10-01-01-15-069 LMS DAL SS SS21 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-070 LMS DAL SS SS21 0 0005 Lab Matrix Spike df:50 GLP10-01-01-15-072 DAL SD SD18 0 0000 df:50 GLP10-01-01 -15-072 Dup DAL SD SD18 0 0000 Lab Duplicate df:50 GLP10-01-01-15-072 LMS DAL SD SD18 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-073 DAL SD SD18 0 0005 df:50 GLP10-01-01-15-073 Dup DAL SD SD18 0 0005 Lab Duplicate df:50 GLP10-01-01-15-073 LMS DAL SD SD18 0 0005 Lab Matrix Spike df:50 10 006-80 solvent blank EC-110316-05 2.5 ng Extracted Curve Point 10 006-60 solvent blank GLP 10-01-01-15-075 DAL SD SD19 0 0000 df:50 GLP 10-01-01-15-075 Dup DAL SD SD19 0 0000 Lab Duplicate df:50 GLP10-01-01-15-075 LMS DAL SD SD19 0 0000 Lab Matrix Spike df:50 GLP 10-01-01-15-076 DAL SD SD19 0 0005 df:50 GLP 10-01-01-15-076 Dup DAL SD SD19 0 0005 Lab Duplicate df:50 GLP 10-01-01-15-076 LMS DAL SD SD19 0 0005 Lab Matrix Spike df:50 GLP10-01-01-15-077 LMS DAL SD SD19 0 0015 Lab Matrix Spike df:50 GLP 10-01-01-15-079 DAL SS SS26 0 0000 df:50 GLP 10-01-01-15-079 Dup DAL SS SS26 0 0000 Lab Duplicate df:50 GLP10-01-01-15-079 LMS DAL SS SS26 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-080 DAL SS SS26 DB 0000 df:50 GLP10-01-01-15-080 Dup DAL SS SS26 DB 0000 Lab Duplicate df:50 GLP10-01-01-15-080 LMS DAL SS SS26 DB 0000 Lab Matrix Spike df:50 GLP10-01-01-15-081 DAL SS SS26 0 0005 df:50 GLP10-01-01-15-091 Dup DAL SS SS26 0 0005 Lab Duplicate df:50 10 006-80 solvent blank EC-110316-06 5 ng Extracted Curve Point 10 006-80 solvent blank GLP 10-01-01-15-081 LMS DAL SS SS26 0 0005 Lab Matrix Spike df:50 GLP10-01-01-15-082 DAL SS SS26 0 0015 df:50 GLP10-01-01-15-082 Dup DAL SS SS26 0 0015 Lab Duplicate df:50 GLP10-01-01-15-082 LMS DAL SS SS26 00015 Lab Matrix Spike df:50 GLP 10-01-01-15-084 DAL SS SS12 0 0015 df:50 GLP 10-01-01-15-084 Dup DAL SS SS12 0 0015 Lab Duplicate df:50 GLP10-01-01-15-084 LMS DAL SS SS12 0 0015 Lab Matrix Spike df:50 GLP10-01-01-15-085 LMS DAL SS SS19 0 0015 Lab Matrix Spike df:50 10 006-80 solvent blank EC-110316-07 10 ng Extracted Curve Point 10 006-80 solvent blank 10 006-80 solvent blank Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte QC Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte QC Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte QC Analyte Analyte 1.043 1.01 0.904 0.92 1.058 1.06 0.999 1.065 1.041 0.903 1.091 0.958 0.925 0.922 1.075 0.877 1.044 0.88 0.938 0.92 0.892 1.057 0.863 1.051 0.958 0.907 0.907 0.888 0.861 0.978 0.871 0.927 0.974 0.944 0.86 0.903 0.96 0.787 Samplelist Text 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 Warm-up: EC-110316-09 50 ng extracted curve point Warm-up: EC-110316-09 50 ng extracted curve point 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 EC-110316-01 0.2 ng Extracted Curve Point EC-110316-02 0.5 ng Extracted Curve Point EC-110316-03 0.75 ng Extracted Curve Point EC-110316-04 1 ng Extracted Curve Point EC-110316-05 2.5 ng Extracted Curve Point EC-110316-06 5 ng Extracted Curve Point EC-110316-07 10 ng Extracted Curve Point EC-110316-08 25 ng Extracted Curve Point EC-110316-09 50 ng Extracted Curve Point EC-110316-10 100 ng Extracted Curve Point EC-110316-11 200 ng Extracted Curve Point EC-110316-12 500 ng Extracted Curve Point 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN;H20 MB-110316-01 Method Blank w/o IS MB-110316-04 Method Blank w/ IS GLP10-01-01-15-063 LMS DAL SS SS27 0 0005 Lab Matrix Spike df:50 GLP 10-01-01-15-065 LMS DAL SS SS22 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-067 LMS DAL SS SS22 DB 0005 Lab Matrix Spike df:50 GLP10-01-01-15-069 DAL SS SS21 0 0000 df:50 GLP10-01-01-15-069 Dup DAL SS SS21 0 0000 Lab Duplicate df:50 GLP10-01-01-15-069 LMS DAL SS SS21 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-070 LMS DAL SS SS21 0 0005 Lab Matrix Spike df:50 GLP10-01-01-15-072 DAL SD SD18 0 0000 df:50 GLP10-01-01-15-072 Dup DAL SD SD18 0 0000 Lab Duplicate df:50 GLP10-01-01-15-072 LMS DAL SD SD18 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-073 DAL SD SD18 0 0005 df:50 GLP10-01-01-15-073 Dup DAL SD SD18 0 0005 Lab Duplicate df:50 GLP10-01-01-15-073 LMS DAL SD SD18 0 0005 Lab Matrix Spike df:50 10 006-80 solvent blank EC-110316-05 2.5 ng Extracted Curve Point 10 006-60 solvent blank GLP10-01-01-15-075 DAL SD SD19 0 0000 df:50 GLP10-01-01-15-075 Dup DAL SD SD19 0 0000 Lab Duplicate df:50 GLP10-01-01-15-075 LMS DAL SD SD19 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-076 DAL SD SD19 0 0005 df:50 GLP 10-01-01-15-076 Dup DAL SD SD19 0 0005 Lab Duplicate df:50 GLP10-01-01-15-076 LMS DAL SD SD19 0 0005 Lab Matrix Spike df:50 Type Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte QC Analyte Analyte Analyte Analyte Analyte Analyte Analyte Cone. 1.065 1.052 0.936 1.023 1.075 0.999 1.086 1.094 1.015 1.112 0.957 0.921 0.927 0.851 0.952 1.045 1.046 1.008 1.055 1.132 1.072 1.013 1.078 1.003 0.956 1.072 1.15 1.027 1.066 0.97 1.08 1.112 1.01 0.984 1.028 3M Study GLP10-01-02-15 Page 3 of 5 Page 79 of 514 a110329a 51 a110329a051 52 a110329a052 53 a110329a053 54 a110329a054 55 a110329a055 56 a110329a056 57 a110329a057 58 a110329a058 59 a110329a059 60 a110329a06Q 61 a110329a061 62 a110329a062 63 a110329a063 64 a110329a064 65 a110329a065 66 a110329a066 67 a110329a067 68 a110329a066 69 a110329a069 70 a110329a070 71 a110329a071 72 a110329a072 73 a110329a073 74 a110329a074 Compound 5: MPFOS # Name 1 a110329a001 2 a110329a002 3 a110329a003 4 a110329a004 5 a110329a005 6 a110329a006 7 a110329a007 8 a110329a008 9 a110329a009 10 a110329a010 11 a110329a011 12 a110329a012 13 a110329a013 14 a110329a014 15 a110329a015 16 a110329a016 17 a110329a017 18 a110329a018 19 a110329a019 20 a110329a020 21 a110329a021 22 a110329a022 23 a110329a023 24 a110329a024 25 a110329a025 26 a110329a026 27 a110329a027 28 a110329a028 29 a110329a029 30 a110329a030 31 a110329a031 32 a110329a032 33 a110329a033 34 a110329a034 35 a110329a035 36 a110329a036 37 a110329a037 38 a110329a038 39 a110329a039 40 a110329a040 41 a110329a041 42 a110329a042 43 a110329a043 44 a110329a044 45 a110329a045 46 a110329a046 47 a110329a047 48 a110329a048 49 a110329a049 50 a110329a050 51 a110329a051 52 a110329a052 53 a110329a053 54 a110329a054 55 a110329a055 56 a110329a056 57 a110329a057 58 a110329a056 59 a110329a059 60 a110329a060 61 a110329a061 62 a110329a062 63 a110329a063 64 a110329a064 65 a110329a065 66 a110329a066 67 a110329a067 68 a110329a068 69 a110329a069 70 a110329a070 71 a110329a071 GLP10-01-01-15-077 LMS DAL SD SD19 0 0015 Lab Matrix Spike df:50 GLP10-01-01-15-079 DAL SS SS26 0 0000 df:50 GLP10-01-01-15-079 Dup DAL SS SS26 0 0000 Lab Duplicate df:50 GLP 10-01-01-15-079 LMS DAL SS SS26 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-080 DAL SS SS26 DB 0000 df:50 GLP10-01-01-15-080 Dup DAL SS SS26 OB 0000 Lab Duplicate df:50 GLP10-01-01-15-080 LMS DAL SS SS26 DB 0000 Lab Matrix Spike df:50 GLP 10-01-01-15-081 DAL SS SS26 0 0005 df:50 GLP 10-01-01-15-081 Dup DAL SS SS26 0 0005 Lab Duplicate df:50 10 006-80 solvent blank EC-110316-06 5 ng Extracted Cun/e Point 10 006-80 solvent blank GLP10-01-01-15-081 LMS DAL SS SS26 0 0005 Lab Matrix Spike df:50 GLP10-01-01-15-082 DAL SS SS26 0 0015 df:50 GLP10-01-01-15-082 Dup DAL SS SS26 0 0015 Lab Duplicate df:50 GLP10-01-01-15-082 LMS DAL SS SS26 0 0015 Lab Matrix Spike df:50 GLP10-01-01-15-084 DAL SS SS12 0 0015 df:50 GLP10-01-01-15-084 Dup DAL SS SS12 0 0015 Lab Duplicate df:50 GLP10-01-01-15-084 LMS DAL SS SS12 0 0015 Lab Matrix Spike df:50 GLP10-01-01-15-085 LMS DAL SS SS19 0 0015 Lab Matrix Spike df:50 10 006-80 solvent blank EC-110316-07 10 ng Extracted Curve Point 10 006-60 solvent blank 10 006-80 solvent blank Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte QC Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte Analyte QC Analyte Analyte 1.018 1.023 1.004 1.155 1.046 1.078 0.892 1.051 1.06 0.969 1.134 1.036 1.001 0.998 1.072 0.99 1.08 1.099 0.88 Samplelist Text 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 Warm-up: EC-110316-09 50 ng extracted curve point Warm-up: EC-110316-09 50 ng extracted curve point 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 EC-110316-01 0.2 ng Extracted Curve Point EC-110316-02 0.5 ng Extracted Curve Point EC-110316-03 0.75 ng Extracted Curve Point EC-110316-04 1 ng Extracted Curve Point EC-110316-05 2.5 ng Extracted Curve Point EC-110316-06 5 ng Extracted Curve Point EC-110316-07 10 ng Extracted Curve Point EC-110316-08 25 ng Extracted Curve Point EC-110316-09 50 ng Extracted Curve Point EC-110316-10 100 ng Extracted Curve Point EC-110316-11 200 ng Extracted Curve Point EC-110316-12 500 ng Extracted Curve Point 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 10 006-80 80:20 ACN:H20 MB-110316-01 Method Blank w/o IS MB-110316-04 Method Blank w/ IS GLP10-01-01-15-063 LMS DAL SS SS27 0 0005 Lab Matrix Spike df:50 GLP10-01-01-15-065 LMS DAL SS SS22 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-067 LMS DAL SS SS22 DB 0005 Lab Matrix Spike df:50 GLP10-01-01-15-069 DAL SS SS21 0 0000 df:50 GLP 10-01-01-15-069 Dup DAL SS SS21 0 0000 Lab Duplicate df:50 GLP10-01-01-15-069 LMS DAL SS SS21 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-070 LMS DAL SS SS21 0 0005 Lab Matrix Spike df:50 GLP10-01-01-15-072 DAL SD SD18 0 0000 df:50 GLP10-01-01-15-072 Dup DAL SD SD18 0 0000 Lab Duplicate df:50 GLP10-01 -01-15-072 LMS DAL SD SD18 0 0000 Lab Matrix Spike df:50 GLP 10-01-01-15-073 DAL SD SD18 0 0005 df:50 GLP10-01 -01-15-073 Dup DAL SD SD18 0 0005 Lab Duplicate df:50 GLP10-01-01-15-073 LMS DAL SD SD18 0 0005 Lab Matrix Spike df:50 10 006-80 solvent blank EC-110316-05 2.5 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-075 DAL SD SD19 0 0000 df:50 GLP10-01-01-15-075 Dup DAL SD SD19 0 0000 Lab Duplicate df:50 GLP10-01-01-15-075 LMS DAL SD SD19 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-076 DAL SD SD19 0 0005 df:50 GLP10-01-01-15-076 Dup DAL SD SD19 0 0005 Lab Duplicate df:50 GLP 10-01-01-15-076 LMS DAL SD SD19 0 0005 Lab Matrix Spike df:50 GLP 10-01-01-15-077 LMS DAL SD SD19 0 0015 Lab Matrix Spike df:50 GLP10-01-01-15-079 DAL SS SS26 0 0000 df:50 GLP 10-01-01-15-079 Dup DAL SS SS26 0 0000 Lab Duplicate df:50 GLP10-01-01-15-079 LMS DAL SS SS26 0 0000 Lab Matrix Spike df:50 GLP10-01-01-15-080 DAL SS SS26 DB 0000 df:50 GLP10-01-01-15-080 Dup DAL SS SS26 DB 0000 Lab Duplicate df:50 GLP10-01-01-15-080 LMS DAL SS SS26 DB 0000 Lab Matrix Spike df:50 GLP 10-01-01-15-081 DAL SS SS26 0 0005 df:50 GLP10-01-01-15-081 Dup DAL SS SS26 0 0005 Lab Duplicate df:50 10 006-80 solvent blank EC-110316-06 5 ng Extracted Curve Point 10 006-80 solvent blank GLP 10-01-01-15-081 LMS DAL SS SS26 0 0005 Lab Matrix Spike df:50 GLP10-01-01-15-082 DAL SS SS26 0 0015 df:50 GLP10-01-01-15-082 Dup DAL SS SS26 0 0015 Lab Duplicate df:50 GLP10-01-01-15-082 LMS DAL SS SS26 0 0015 Lab Matrix Spike df:50 GLP10-01-01-15-084 DAL SS SS12 0 0015 df:50 GLP10-01-01-15-084 Dup DAL SS SS12 0 0015 Lab Duplicate df:50 GLP10-01 -01-15-084 LMS DAL SS SS12 0 0015 Lab Matrix Spike df:50 GLP10-01-01-15-085 LMS DAL SS SS19 0 0015 Lab Matrix Spike df:50 10 006-80 solvent blank Type Cone. Analyte Analyte Analyte Analyte Analyte 49.789 Analyte 49.274 Analyte Analyte Analyte Analyte Standard 0.192 Standard 0.41 Standard 0.741 Standard 0.936 Standard 2.356 Standard 4.907 Standard 9.423 Standard 26.311 Standard 49,762 Standard 99.906 Standard 177.915 Standard 482,716 Analyte Analyte Analyte Analyte Analyte 0.071 Analyte 3.042 Analyte 2.876 Analyte 3.101 Analyte 3.025 Analyte 3.001 Analyte 3.1 Analyte 3.353 Analyte 3.12 Analyte 2.904 Analyte 2.801 Analyte 2.984 Analyte 2.957 Analyte 2.856 Analyte 3.029 Analyte QC 2.093 Analyte Analyte 3.285 Analyte 2.961 Analyte 2.888 Analyte 3.021 Analyte 3.062 Analyte 3.229 Analyte 3.147 Analyte 3.102 Analyte 2.966 Analyte 2.844 Analyte 2.915 Analyte 2.87 Analyte 2.673 Analyte 2.834 Analyte 2.847 Analyte QC 4.602 Analyte Analyte 2.73 Analyte 2.877 Analyte 3.015 Analyte 3.3 Analyte 2.79 Analyte 3.027 Analyte 2.671 Analyte 2.939 Analyte 3M Study GLP10-01-02-15 Page 4 of 5 Page 80 of 514 72 a110329a072 73 a110329a073 74 a110329a074 EC-110316*07 10 ng Extracted Curve Point 10 006-80 solvent blank 10 006-80 solvent blank data reported a110329a QC A n a ly te A n a ly te 9.269 3M Study GLP10-01-02-15 Page 5 of 5 Page 81 of 514 a110401a Quantify Compound Summary Report Sample Li: D:\Masslynx\Amelia2009.pro\SAMPLEDB\a110401a Last modi! Fri Apr 01 16:28:58 2011 Method: D:\Masslynx\Amelia2009.pro\METHDB\a110401a Last modit Mon A pr 04 08:58:45 2011 Job Code: Printed: Mon A pr 04 09:05:15 2011 Compound 1: PFOS # Name Samplelist Text Type Cone. 1 a110401a001 10 006-80 80:20 A C N :H 20 A n a ly te 2 a110401a002 10 006-80 80:20 A C N :H 20 A n a ly te 3 a110401a003 10 006-80 80:20 A C N :H 20 A n a ly te 4 a110401a004 10 006-80 80:20 A C N :H 2 0 A n a ly te 5 a110401a005 Warm-up: EC-110316-09 50 ng extracted curve point Analyte 46.933 6 a110401a006 Warm-up: EC-110316-09 50 ng extracted curve point Analyte 49.615 7 a110401a007 10 006-80 80:20 A C N :H 2 0 A n a ly te 8 a110401a008 10 006-80 80:20 A C N :H 2 0 Analyte 9 a110401a009 10 006-80 80:20 A C N :H 2 0 Analyte 10 a110401a010 10 006-80 80:20 A C N :H 2 0 Analyte 11 a110401a011 EC-110316-01 0.2 ng Extracted Curve Point Standard 0.227 12 a110401a012 EC-110316-02 0.5 ng Extracted Curve Point Standard 0.544 13 a110401a013 EC-110316-03 0.75 ng Extracted Curve Point Standard 0.685 14 a110401a014 EC-110316-04 1 ng Extracted Curve Point Standard 0.89 15 a110401a015 EC-110316-05 2.5 ng Extracted Curve Point Standard 2.373 16 a110401a016 EC-110316-06 5 ng Extracted Curve Point Standard 5.01 17 a110401a017 EC-110316-07 10 ng Extracted Curve Point Standard 9.816 18 a110401a018 EC-110316-08 25 ng Extracted Curve Point Standard 26.216 19 a110401a019 EC-110316-09 50 ng Extracted Curve Point Standard 50.353 20 a110401a020 EC-110316-10 100 ng Extracted Curve Point Standard 97.473 21 a110401a021 EC-110316-11 200 ng Extracted Curve Point Standard 201.456 22 a110401a022 EC-110316-12 500 ng Extracted Curve Point Standard 499.792 23 a110401a023 10 006-80 80:20 A C N :H 2 0 Analyte 0.224 24 a110401a024 10 006-80 80:20 A C N :H 2 0 Analyte 25 a110401a025 10 006-80 80:20 A C N :H 2 0 A n a ly te 26 a110401a026 10 006-80 80:20 A C N :H 2 0 Analyte 27 a110401a027 MB-110316-01 Method Blank w/o IS A n a ly te 28 a110401a028 MB-110316-04 Method Blank w / IS A n a ly te 29 a110401a029 GLP10-01-01-15-005 LMS Lab Matrix Spike df:50 A n a ly te 15.018 30 a110401a030 10 006-80 solvent blank A n a ly te 31 a110401a031 EC-110316-05 2.5 ng Extracted Curve Point QC 2.618 32 a110401a032 10 006-80 solvent blank A n a ly te Compound 2: M8PFOS # Name Samplelist Text Type Cone. 1 a110401a001 10 006-80 80:20 ACN:H20 A n a ly te 2 a110401a002 10 006-80 80:20 ACN:H20 A n a ly te 3 a110401a003 10 006-80 80:20 ACN:H20 A n a ly te 4 a110401a004 10 006-80 80:20 ACN:H20 A n a ly te 5 a110401a005 W arm -up: EC-110316-09 50 ng extracted curve point Analyte 1.042 6 a110401a006 W arm -up: EC-110316-09 50 ng extracted curve point Analyte 1.081 7 a110401a007 10 006-80 80:20 ACN:H20 Analyte 8 a110401a008 10 006-80 80:20 A C N :H 2 0 Analyte 9 a110401a009 10 006-80 80:20 ACN:H20 Analyte 10 a110401a010 10 006-80 80:20 ACN:H20 Analyte 11 a110401a011 EC-110316-01 0.2 ng Extracted Curve Point S ta n d a rd 1.071 12 a110401a012 EC-110316-02 0.5 ng Extracted Curve Point S ta n d a rd 1.083 13 a110401a013 EC-110316-03 0.75 ng Extracted Curve Point S ta n d a rd 0.97 14 a110401a014 EC-110316-04 1 ng Extracted Curve Point Standard 0.965 15 a110401a015 EC-110316-05 2.5 ng Extracted Curve Point S ta n d a rd 1.098 16 a110401a016 EC-110316-06 5 ng Extracted Curve Point S ta n d a rd 1.028 17 a110401a017 EC-110316-07 10 ng Extracted Curve Point S ta n d a rd 1.096 18 a110401a018 EC-110316-08 25 ng Extracted Curve Point Standard 1.009 19 a110401a019 EC-110316-09 50 ng Extracted Curve Point S ta n d a rd 1.041 20 a110401a020 EC-110316-10 100 ng Extracted Curve Point Standard 0.958 21 a110401a021 EC-110316-11 200 ng Extracted Curve Point Standard 0.833 22 a110401a022 EC-110316-12 500 ng Extracted Curve Point Standard 0.846 23 a110401a023 10 006-80 80:20 A C N :H 20 A n a ly te 24 a110401a024 10 006-80 80:20 A C N :H 20 A n a ly te 25 a110401a025 10 006-80 80:20 A C N :H 20 A n a ly te 26 a110401a026 10 006-80 80:20 A C N :N 20 A n a ly te 27 a110401a027 MB-110316-01 Method Blank w/o IS Analyte 28 a110401a026 MB-110316-04 Method Blank w / IS A n a ly te 1.036 29 a110401a029 GLP10-01-01-15-005 LMS Lab Matrix Spike df:50 Analyte 1.039 30 a110401a030 10 006-80 solvent blank Analyte 31 a110401a031 EC-110316-05 2.5 ng Extracted Curve Point QC 1.045 32 a110401a032 10 006-60 solvent blank Analyte Compound 3: MPFOS # Name Samplelist Text Type Cone. 1 a110401a001 10 006-80 80:20 A C N :H 20 A n a ly te 2 a110401a002 10 006-80 80:20 A C N :H 20 A n a ly te 3 a110401a003 10 006-80 80:20 A C N :H 20 A n a ly te 4 a110401a004 10 006-80 80:20 A C N :H 20 A n a ly te 5 a110401a005 Warm-up: EC-110316-09 50 ng extracted curve point Analyte 48.607 6 a110401a006 Warm-up: EC-110316-09 50 ng extracted curve point Analyte 51.871 7 a110401a007 10 006-80 80:20 A C N :H 20 A n a ly te 8 a110401a008 10 006-80 80:20 A C N :H 20 A n a ly te 9 a110401a009 10 006-80 80:20 A C N :H 20 A n a ly te 10 a110401a010 10 006-80 80:20 A C N :H 20 A n a ly te 11 a110401a011 EC-110316-01 0.2 ng Extracted Curve Point Standard 0.198 12 a110401a012 EC-110316-02 0.5 ng Extracted Curve Point Standard 0.437 13 a110401a013 EC-110316-03 0.75 ng Extracted Curve Point Standard 0.578 14 a110401a014 EC-110316-04 1 ng Extracted Curve Point Standard 0.902 3M Study GLP10-01-02-15 Page 1 of 2 a110401a 15 a110401a015 16 a110401a016 17 a110401a017 18 a110401a016 19 a110401a019 20 a110401a020 21 a110401a021 22 a110401a022 23 a110401a023 24 a110401a024 25 a110401a025 26 a110401a026 27 a110401a027 26 a110401a028 29 a110401a029 30 a110401a030 31 a110401a031 32 a110401a032 EC-110316-05 2.5 ng Extracted Curve Point EC-110316-06 5 ng Extracted Curve Point EC-110316-07 10 ng Extracted Curve Point EC-110316-08 25 ng Extracted Curve Point EC-110316-09 50 ng Extracted Curve Point EC-110316-10 100 ng Extracted Curve Point EC-110316-11 200 ng Extracted Curve Point EC-110316-12 500 ng Extracted Curve Point 10 006-80 80:20 A C N :H 20 10 006-80 80:20 A C N :H 20 10 006-80 80:20 A C N :H 20 10 006-80 80:20 A C N :H 20 M B-110316-01 Method Blank w/o IS M B-110316-04 Method Blank w/ 1S G LP 10-01-01-15-005 LMS Lab Matrix Spike df:50 10 006-80 solvent blank EC-110316-05 2.5 ng Extracted Curve Point 10 006-80 solvent blank Standard Standard S ta n d a rd S ta n d a rd S ta n d a rd S ta n d a rd S ta n d a rd S ta n d a rd A n a ly te A n a ly te A n a ly te A n a ly te A n a ly te A n a ly te A n a ly te A n a ly te QC A n a ly te 2.602 4.687 10.591 26.356 49.548 100.266 176.025 483.356 2.85 3.028 2.659 3M Study GLP10-01-02-15 Page 2 of 2 Page 83 of 514 s lH M lla Sample Name sll0411a001 sll0411a002 sll0411a003 sll0411a004 sll0411a005 s ll0 4 1 1 a 0 0 6 sll0411a007 sll0411a008 sll0411a009 sll0411a010 sll0411a011 sll0411a012 sll0411a013 S ll0 41 1 a0 14 sll0411a015 sll0 4 U a0 1 6 sll0411a017 sll0411a018 sll0411a019 s ll0 4 1 1 a 0 2 0 s ll0 4 1 1 a 0 2 1 s ll0 4 1 1 a 0 2 2 s ll0 4 1 1 a 0 2 3 s ll0 4 1 1 a 0 2 4 sll0411a025 $110411a026 sll0411a027 sll0411a028 sll0411a029 sll0411a030 s ll0 4 1 1 a 0 3 1 sll0411a032 sll0411a033 sll0411a034 sll0411a035 s ll0 4 1 1 a 0 3 6 sll0411a037 sll0411a038 sll0411a039 sll0411a040 sll0411a041 sll0411a042 S ll0 41 1 a0 43 sll0411a044 s ll0 4 1 1 a 0 4 5 sll0411a046 sll0411a047 $U0411a048 s ll0 4 1 1 a 0 4 9 s ll0 4 1 1 a 0 5 0 sll0411a051 sll0411a052 sll0411a053 sll0411a054 sll04U a055 sll0 4 1 1 a 0 S 6 sll0411a057 S ll0 4 1 1 a 0 5 8 sll0411a059 s ll0 4 1 1 a 0 6 0 sll0411a061 sll0411a062 sll0411a063 $U0411a064 sll0411a065 s ll0 4 1 1 a 0 6 6 sll0411a067 sll0411a068 sll0411a069 sll0411a070 sll0411a071 S ll0 4 1 1 a 0 7 2 sll0411a073 sll0411a074 s ll0 4 1 1 a 0 7 5 sll0411a076 sll0411a077 sll04U a078 Sample ID 10 006-96 solvent blank 10 006-96 solvent blank EC-110407-09 SO ng W arm up standard EC-110407-09 50 ng W arm up standard 10 006-96 solvent blank 10 006-96 solvent blank 10 006-96 solvent blank 10 006-96 solvent blank 10 006-96 solvent blank EC-110407-010.2 ng Extracted Curve Point EC-110407-02 0.5 ng Extracted Curve Point EC-110407-03 0.75 ng Extracted Curve Point EC-110407-04 1 ng Extracted Curve Point EC-110407-05 2.5 ng Extracted Curve Point EC-110407-06 5 ng Extracted Curve Point EC-110407-07 10 ng Extracted Curve Point EC-110407-08 25 ng Extracted Curve Point EC-110407-09 50 ng Extracted Curve Point EC-110407-10 100 ng Extracted Curve Point EC-110407-11 200 ng Extracted Curve Point EC-110407-12 500 ng Extracted Curve Point 10 006-96 solvent blank 10 006-96 solvent blank 10 006-96 solvent blank 10 006-96 solvent blank MB-110407-01 M ethod Blank w /o IS MB-110407-02 M ethod Blank w /o IS MB-110407-03 M ethod Blank w /o IS MB-110407-04 M ethod Blank w / IS MB-110407-05 M ethod Blank w / IS MB-110407-06 M ethod Blank w / IS LCS-110407-013 ng LCS in TCR-842 LCS-110407-02 3 ng LCS in TCR-842 LCS-110407-03 3 ng LCS in TCR-842 LCS-110407-04 30 ng LCS in TCR-842 LCS-110407-05 30 ng LCS in TCR-842 LCS-110407-06 30 ng LCS in TCR-842 GLP10-01-01-1S-004 DAL SS SS13 0 0000 GLP10-01-01-15-004 Dup DAL SS SS13 0 0000 Lab Duplicate GLP10-01-01-15-004 LMS DAL SS SS13 0 0000 Lab M a trix Spike 10 006-96 solvent blank EC-110407-05 2.5 ng Extracted Curve Point 10 006-96 solvent blank GLP10-01-01-15-008 DAL SS SS110 0005 GLP10-01-01-15-008 Dup DAL SS SS110 0005 Lab Duplicate GLP10-01-01-15-008 LMS DAL SS SS110 0005 Lab M a trix Spike GLP10-01-01-15-020 DAL SS SS10 0 0000 GLP10-01-01-15-020 Dup DAL SS SS10 0 0000 Lab Duplicate GLP10-01-01-15-020 LMS DAL SS SS10 0 0000 Lab M a trix Spike GLP10-01-01-15-029 DAL SD SD22 DB 0005 GLP10-01-01-15-029 Dup DAL SD SD22 DB 0005 Lab Duplicate GLP10-01-01-15-029 LMS DAL SD SD22 DB 0005 Lab M a trix Spike GLP10-01-01-15-032 DAL SD SD210 0005 GLP10-01-01-15-032 Dup DAL SD SD210 000S Lab Duplicate GLP10-01-01-15-032 LMS DAL SD SD210 0005 Lab M a trix Spike GLP10-01-01-15-040 DAL SS SS20 0 0005 GLP10-01-01-15-040 Dup DAL SS SS20 0 0005 Lab Duplicate GLP10-01-01-15-040 LMS DAL SS SS20 0 0005 Lab M a trix Spike 10 006-96 solvent blank EC-110407-06 5 ng Extracted Curve Point 10 006-96 solvent blank GLP10-01-01-15-080 DAL SS SS26 DB 0000 GLP10-01-01-1S-080 Dup DAL SS SS26 DB 0000 Lab Duplicate GLP10-01-01-15-080 LMS DAL SS SS26 DB 0000 Lab M a trix Spike GLP10-01-01-15-090 DAL SS SS15 0 0015 GLP10-01-01-15-090 Dup DAL SS SS15 0 0015 Lab Duplicate GLP10-01-01-15-090 LMS DAL SS SS15 0 0015 Lab M a trix Spike GLP10-01-01-15-092 DAL SS SS110 0015 GLP10-01-01-15-092 Dup DAL SS SS110 0015 Lab Duplicate GLP10-01-01-15-092 LMS DAL SS SS110 0015 Lab M a trix Spike GLP10-01-01-15-020 DAL SS SS10 0 0000 DF:50 GLP10-01-01-15-020 Dup DAL SS SS10 0 0000 Lab Duplicate DF:50 GLP10-01-01-15-020 LMS DAL SS SS10 0 0000 Lab M a trix Spike DF:S0 GLP10-01-01-15-024 DAL SS SS2S 0 0000 DF:50 GLP10-01-01-15-024 Dup DAL SS SS25 0 0000 Lab Duplicate DF:50 GLP10-01-01-15-024 LMS DAL SS SS25 0 0000 Lab M a trix Spike DF:50 10 006-96 solvent blank EC-110407-07 10 ng Extracted Curve Point Analvte Peak Name MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS Sample Use Type Record Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Q uality Co Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Q uality Co Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Q uality Co Calculated Concentratio Accuracy Record n (ng/mL) (%) M odified File Name N/A N/A 0 sll0411a.w iff N/A N/A 0 sll0411a.w iff N/A N/A 1 sll0411a.w iff N/A N/A 0 sll0411a.w iff N/A N/A 0 sll0411a.w iff N/A N/A 0 sll0411a.w iff N/A N/A 0 sll0411a.w iff N/A N/A 0 sll0411a.w iff N/A N/A 0 sll0411a.w iff 1 0.198 104 0 sll0411a.w lff 1 0.479 100 0 sll0411a.w lff 1 0.74 103 0 sll0411a.w iff 1 0.89 93.1 0 sll0411a.w iff 1 2.41 101 0 sll0411a.w iff 1 4.89 102 0 sll0411a.w iff 1 9.05 94.6 0 sll0411a.w iff 1 24.3 102 0 s ll0 4 1 1 a .w iff 1 48.3 101 0 sll0411a.w iff 1 94.9 99.3 0 sll0411a.w iff 1 195 102 0 sll0411a.w iff 1 187 98 0 sll0411a.w iff N/A N/A 0 sll0411a.w iff N/A N/A 0 sll0411a.w iff N/A N/A 0 sll0411a.w iff N/A N/A 0 sll0411a.w iff N/A N/A 0 sll0411a.w iff N/A N/A 0 sll0411a.w iff N/A N/A 0 sll0411a.w iff 3,11 N/A 0 sll0411a.w iff 2.91 N/A 0 sll0411a.w iff 5.32 N/A 0 5110411a.wiff 2.69 N/A 0 sll0411a.w iff 2.87 N/A 0 slH M lla .w iff 2.77 N/A 0 s lH M lla ,w iff 2.91 N/A 0 s lH M lla .w iff 2.93 N/A 0 s lH M lla .w iff 2.74 N/A 0 slH M lla .w iff 3.02 N/A 0 slH M lla .w iff 2.99 N/A 0 slH M lla .w iff 2.99 N/A 0 slH M lla .w iff N/A N/A 0 slH M lla .w iff 1 2.32 97 0 slH M lla .w iff N/A N/A 0 slH M lla .w iff 2.88 N/A 0 slH M lla .w iff 2.93 N/A 0 slH M lla .w iff 2.88 N/A 0 slH M lla .w iff 3.49 N/A 0 slH M lla .w iff 4.36 N/A 0 s lH M lla .w iff 6.2 N/A 0 s lH M lla .w iff 3.33 N/A 0 s lH M lla .w iff 3.04 N/A 0 s lH M lla .w iff 3.18 N/A 0 slH M lla .w iff 3.08 N/A 0 s lH M lla .w iff 3.08 N/A 0 S lH M lla.w iff 2.89 N/A 0 slH M lla .w iff 2.93 N/A 0 slH M lla .w iff 2.84 N/A 0 slH M lla .w iff 2.76 N/A 0 slH M lla .w iff N/A N/A 0 slH M lla .w iff 1 4.69 98.1 0 slH M lla .w iff N/A N/A 0 slH M lla .w iff 2.95 N/A 0 slH M lla .w iff 3.28 N/A 0 s lH M lla .w iff 3.73 N/A 0 s lH M lla .w iff 2.96 N/A 0 s lH M lla .w iff 2.87 N/A 0 s lH M lla .w iff 2.93 N/A 0 s lH M lla .w iff 3.1 N/A 0 s lH M lla .w iff 2.92 N/A 0 s lH M lla .w iff 2.76 N/A 0 slH M lla .w iff 2.8 N/A 0 slH M lla .w iff 2.9 N/A 0 s lH M lla .w iff 2.97 N/A 0 s i 10411a.wiff 3.09 N/A 0 slH M lla .w iff 2.82 N/A 0 slH M lla .w iff 2.91 N/A 0 slH M lla .w iff N/A N/A 0 slH M lla .w iff 1 9.09 95.1 0 slH M lla .w iff 3M Study GLP10-01-02-15 Page 1 of 5 Page 8' s i 10411a Sample Name sl!0411a079 s ll0 4 1 1 a 0 8 0 sll0411a081 s ll0 4 1 1 a 0 8 2 sll0411a083 sll0411a084 sll0411a085 s ll0 4 1 1 a 0 8 6 s ll0 4 1 1 a 0 0 1 s ll0 4 1 1 a 0 0 2 s ll0 4 1 1 a 0 0 3 sll0411a004 s i 10411a005 s ll0 4 1 1 a 0 0 6 s ll0 4 1 1 a 0 0 7 s ll0 4 1 1 a 0 0 8 s ll0 4 1 1 a 0 0 9 s ll0 4 1 1 a 0 1 0 sll0411a011 sll0411a012 s ll0 4 1 1 a 0 1 3 sll0411a014 S ll0 41 1 a0 15 s ll0 4 1 1 a 0 1 6 sll0411a017 sll0411a018 sll0411a019 sll0411a020 sll0411a021 sll0411a022 sll0411a023 sll0411a024 sl!0411a025 s ll0 4 1 1 a 0 2 6 sll0411a027 sll0411a028 sll0411a029 sll0411a030 sll0411a031 $110411a032 s ll0 4 1 1 a 0 3 3 s ll0 4 1 1 a 0 3 4 s ll0 4 1 1 a 0 3 5 $110411a036 sll0411a037 s ll0 4 1 1 a 0 3 8 sll0411a039 sll0411a040 s ll0 4 1 1 a 0 4 1 sll0411a042 sll0411a043 sll0411a044 sll0411a045 s ll0 4 1 1 a 0 4 6 sll0411a047 s ll0 4 1 1 a 0 4 8 sll0411a049 sll0411a050 s ll0 4 1 1 a 0 5 1 sll0411a052 s ll0 4 1 1 a 0 5 3 s ll0 4 1 1 a 0 5 4 s ll0 4 1 1 a 0 5 5 sll0411a056 s ll0 4 1 1 a 0 5 7 Sll0411a058 s ll0 4 1 1 a 0 5 9 sll0411a060 sll0411a061 sll0411a062 sll0411a063 sll0411a064 s ll0 4 1 1 a 0 6 5 sll0411a066 sll0411a067 sll0411a068 sll0411a069 sll0411a070 sll0411a071 sll0411a072 Sample ID 10 006-96 solvent blank GLPlO-01-01-15-080 DAL SS SS26 DB 0000 DF:50 GLP10-01-01-15-080 Dup DAL SS SS26 DB 0000 Lab Duplicate DF:50 GLP10-01-01-15-080 LMS DAL SS SS26 DB 0000 Lab M a trix Spike DF:50 10 006-96 solvent blank EC-110407-05 2.5 ng Extracted Curve Point 10 006-96 solvent blank 10 006-96 solvent blank 10 006-96 solvent blank 10 006-96 solvent blank EC-110407-09 50 ng W arm up standard EC-110407-09 50 ng Warm up standard 10 006-96 solvent blank 10 006-96 solvent blank 10 006-96 solvent blank 10 006-96 solvent blank 10 006-96 solvent blank EC-110407-010.2 ng Extracted Curve Point EC-110407-02 0,5 ng Extracted Curve Point EC-110407-03 0.75 ng Extracted Curve Point EC-110407-04 1 ng Extracted Curve Point EC-110407-05 2.5 ng Extracted Curve Point EC-110407-06 5 ng Extracted Curve Point EC-110407-07 10 ng Extracted Curve Point EC-110407-08 25 ng Extracted Curve Point EC-110407-09 50 ng Extracted Curve Point EC-110407-10 100 ng Extracted Curve Point EC-110407-11 200 ng Extracted Curve Point EC-110407-12 500 ng Extracted Curve Point 10 006-96 solvent blank 10 006-96 solvent blank 10 006-96 solvent blank 10 006-96 solvent blank MB-110407-01 Method Blank w /o IS MB-110407-02 M ethod Blank w /o IS MB-110407-03 M ethod Blank w /o IS MB-110407-04 M ethod Blank w / IS MB-110407-05 M ethod Blank w / IS MB-110407-06 M ethod Blank w / IS LCS-110407-01 3 ng LCS in TCR-842 LCS-110407-02 3 ng LCS in TCR-842 LCS-110407-03 3 ng LCS in TCR-842 LCS-110407-04 30 ng LCS In TCR-842 LCS-110407-05 30 ng LCS in TCR-842 LCS-110407-06 30 ng LCS in TCR-842 GLP10-01-01-15-004 DAL SS SS13 0 0000 GLP10-01-01-15-004 Dup DAL SS SS13 0 0000 Lab Duplicate GLP10-01-01-15-004 LMS DAL SS SS13 0 0000 Lab M a trix Spike 10 006-96 solvent blank EC-110407-05 2.5 ng Extracted Curve Point 10 006-96 solvent blank GLP10-01-01-15-008 DAL SS SS110 0005 GLP10-01-01-15-008 Dup DAL SS SS110 0005 Lab Duplicate GLP10-01-01-15-008 LMS DAL SS SS110 0005 Lab M a trix Spike GLP10-01-01-15-020 DAL SS SS10 0 0000 GLP10-01-01-15-020 Dup DAL SS SS10 0 0000 Lab Duplicate GLP1Q-01-01-15-020 LMS DAL SS SS10 0 0000 Lab M a trix Spike GLP10-01-01-15-029 DAL SD SD22 DB 0005 GLP10-01-01-15-029 Dup DAL SD SD22 DB 0005 Lab Duplicate GLP10-01-01-15-029 LMS DAL SD SD22 DB 0005 Lab M a trix Spike GLP10-01-01-15-032 DAL SD SD210 0005 GLP10-01-01-15-032 Dup DAL SD SD210 0005 Lab Duplicate GLP10-01-01-15-032 LMS DAL SD SD210 0005 Lab M a trix Spike GLP10-01-01-15-040 DAL SS SS20 0 0005 GLP10-01-01-15-040 Dup DAL SS SS20 0 0005 Lab Duplicate GLP10-01-01-15-040 LMS DAL SS SS20 0 0005 Lab M a trix Spike 10 006-96 solvent blank EC-110407-06 5 ng Extracted Curve Point 10 006-96 solvent blank GLP10-01-01-15-080 DAL SS SS26 DB 0000 GLP10-01-01-15-080 Dup DAL SS SS26 DB 0000 Lab Duplicate GLP10-01-01-15-080 LMS DAL SS SS26 DB 0000 Lab M a trix Spike GLP10-01-01-15-090 DAL SS SS15 0 0015 GLP10-01-01-15-090 Dup DAL SS SS15 0 0015 Lab Duplicate GLP10-01-01-15-090 LMS DAL SS SS15 0 0015 Lab M a trix Spike GLP10-01-01-15-092 DAL SS SS11 0 0015 GLP10-01-01-15-092 Dup DAL SS SS110 0015 Lab Duplicate GLP10-01-01-15-092 LMS DAL SS SS110 0015 Lab M a trix Spike GLP10-01-01-15-020 DAL SS SS10 0 0000 DF:50 GLP10-01-01-15-020 Dup DAL SS SS10 0 0000 Lab Duplicate DF:S0 Analyte Peak Name MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS Sample Use Type Record Double Blank Unknown Unknown Unknown Double Blank Q uality Co Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Q uality Co Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Q uality Co Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Calculated Concentratio Accuracy Record n (ng/mL) (%| M odified File Name N/A N/A 0 sll0411a,w iff 2.86 N/A 0 sll0411a,w iff 2.82 N/A 1 sll0411a.w iff 2.83 N/A 0 sl!0411a.w iff N/A N/A 0 sll0411a.w iff 1 2.35 98.4 0 sll0411a.w iff N/A N/A 0 sll0411a.w iff N/A N/A 0 sll0411a.w iff N/A N/A 0 sll0411a.w iff N/A N/A 0 sll0411a.w iff N/A N/A 0 sll0411a.w iff N/A N/A 0 sll0411a.w iff N/A N/A 0 sll0411a.w iff N/A N/A 0 sll0411a.w iff N/A N/A 1 sll0411a.w iff N/A N/A 0 sll0411a.w iff N/A N/A 0 $110411a.wiff 1 0.185 92.3 0 sll0411a.w iff 1 0.496 99.2 0 s!10411a.wiff 1 0.75 100 0 sll0411a.w iff 1 0.945 94.6 0 sll0411a.w iff 1 2.68 107 0 sll0411a.w iff 1 5.14 103 0 sll0411a.w iff 1 9.59 96 0 sll0411a.w iff 1 27.1 108 0 sll0411a.w iff 1 51.2 102 0 sll0411a.w iff 1 97.3 97.4 0 s ll0 4 1 1 a ,w iff 1 198 99 0 sll0411a.w iff 1 502 100 0 sll0411a.w iff N/A N/A 0 sll0411a.w iff N/A N/A 1 sll0411a.w iff N/A N/A 0 sll0411a.w iff N/A N/A 0 sll0411a.w iff N/A N/A 0 s11041 la .w iff N/A N/A 1 sll0411a.w iff N/A N/A 0 sll0411a.w iff 0.066 N/A 1 sll0411a.w iff <0 N/A 0 sll0411a.w iff 15.6 N/A 0 sll0411a.w iff 3.31 N/A 0 sll0411a.w iff 3.14 N/A 0 sll0411a.w iff 3.15 N/A 0 sll0411a.w iff 31.3 N/A 0 sll0411a.w iff 31.9 N/A 0 sll0411a.w iff 31.2 N/A 0 s!10411a.wiff 1.18 N/A 1 sll0411a.w iff 1.57 N/A 0 sll0411a.w iff 6.59 N/A 0 sll0411a.w iff N/A N/A 0 sll0411a.w iff 1 2.67 107 0 sll0411a.w fff N/A N/A 0 sll0411a.w iff 0.918 N/A 0 s i 10411a.wiff 0.754 N/A 0 sll0411a.w iff 6.11 N/A 0 sll0411a.w iff 4.52 N/A 0 sll0411a.w iff 5.32 N/A 0 sll0411a.w iff 10.6 N/A 0 sll0411a.w iff 11.4 N/A 0 sll0411a.w iff 8.59 N/A 0 sll0411a.w iff 9.42 N/A 0 sll0411a.w iff 8.61 N/A 0 sll0411a.w iff 10.5 N/A 0 sll0411a.w iff 36.7 N/A 0 sll0411a.w iff 0.465 N/A 0 sll0411a.w iff 0.473 N/A 0 sll0411a.w iff 0.381 N/A 0 sll0411a.w iff N/A N/A 0 sll0411a.w iff 1 5.44 109 0 sll0411a.w iff N/A N/A 1 sll0411a.w iff 0.705 N/A 0 sll0411a.w iff 0.793 N/A 0 sll0411a.w iff 5.9 N/A 0 sll0411a.w iff 0.291 N/A 0 sll0411a.w iff 0.331 N/A 0 sll0411a.w iff 0.353 N/A 0 sll0411a.w iff 0.394 N/A 0 5110411a.wiff 0.412 N/A 0 sll0411a.w iff 0.275 N/A 0 sll0411a.w iff 0.0653 N/A 1 sll0411a.w iff 0.112 N/A 0 s!10411a.wiff 3M Study GLP10-01-02-15 Page 2 of S Page 85 of 514 $110411a Sample Name s ll0 4 1 1 a 0 7 3 s ll0 4 1 1 a 0 7 4 s ll0 4 1 1 a 0 7 5 sll0411a076 sll0411a077 sll0411a078 sll0411a079 sll0411a080 sll0411a081 sll0411a082 sll0411a083 sll0411a084 sll0411a085 sll0411a086 s ll0 4 1 1 a 0 0 1 s ll0 4 1 1 a 0 0 2 s ll0 4 1 1 a 0 0 3 sll0411a004 sll0411a005 s ll0 4 1 1 a 0 0 6 sll0411a007 sll0411a008 sll0411a009 sll0411a010 s ll0 4 1 1 a 0 1 1 sll0411a012 sll0411a013 sl!0411a014 sll0411a015 s ll0 4 1 1 a 0 1 6 s ll0 4 1 1 a 0 1 7 sl!0411a018 s ll0 4 1 1 a 0 1 9 s ll0 4 1 1 a 0 2 0 sll0411a021 sll0411a022 sll0411a023 sll0411a024 sll0411a025 s ll0 4 1 1 a 0 2 6 sll0411a027 sll04H a028 sll0411a029 sll0411a030 sll0411a031 sll0411a032 $110411a033 sll0411a034 sll0411a035 s ll0 4 1 1 a 0 3 6 sll0411a037 s!10411a038 sll0411a039 sll0411a040 sll0411a041 sll0411a042 sll0411a043 sll0411a044 sll0411a045 s ll0 4 1 1 a 0 4 6 s ll0 4 1 1 a 0 4 7 s ll0 4 1 1 a 0 4 8 sll04U a049 sll0411a050 s ll0 4 1 1 a 0 5 1 sll0411a052 sll0411a053 s ll0 4 1 1 a 0 5 4 sll0411a0SS s ll0 4 1 1 a 0 5 6 sll0411a057 sll0411a058 sll0411a059 sll0411a060 sll0411a061 sll0411a062 sll04U a063 sll0411a064 sll0411a065 sll0411a066 Sample ID GLP10-01-01-15-020 IM S DAL SS SS10 0 0000 Lab M a trix Spike DF:50 GLP10-01-01-15-024 DAL SS SS25 0 0000 DF:50 GLP10-01-01-15-024 Dup DAL SS SS25 0 0000 Lab Duplicate DF:50 GLP10-01-01-15-024 LMS DAL SS SS25 0 0000 Lab M a trix Spike DF;50 10 006-96 solvent blank EC-110407-07 10 ng Extracted Curve Point 10 006-96 solvent blank GLP10-01-01-15-080 DAL SS SS26 DB 0000 DF:50 GLP10-01-01-15-080 Dup DAL SS SS26 DB 0000 Lab Duplicate DF.50 GLP10-01-01-15-080 LMS DAL SS SS26 DB 0000 Lab M atrix Spike DF:50 10 006-96 solvent blank EC-110407-05 2.5 ng Extracted Curve Point 10 006-96 solvent blank 10 006-96 solvent blank 10 006-96 solvent blank 10 006-96 solvent blank EC-110407-09 50 ng Warm up standard EC-110407-09 50 ng W arm up standard 10 006-96 solvent blank 10 006-96 solvent blank 10 006-96 solvent blank 10 006-96 solvent blank 10 006-96 solvent blank EC-110407-010.2 ng Extracted Curve Point EC-110407-02 0.5 ng Extracted Curve Point EC-110407-03 0.75 ng Extracted Curve Point EC-110407-04 1 ng Extracted Curve Point EC-110407-05 2.5 ng Extracted Curve Point EC-110407-06 5 ng Extracted Curve Point EC-110407-07 10 ng Extracted Curve Point EC-110407-08 25 ng Extracted Curve Point EC-110407-09 SO ng Extracted Curve Point EC-110407-10 100 ng Extracted Curve Point EC-110407-11 200 ng Extracted Curve Point EC-110407-12 500 ng Extracted Curve Point 10 006-96 solvent blank 10 006-96 solvent blank 10 006-96 solvent blank 10 006-96 solvent blank MB-110407-01 M ethod Blank w /o IS MB-110407-02 M ethod Blank w /o IS MB-110407-03 M ethod Blank w /o IS MB-110407-04 M ethod Blank w / IS MB-110407-05 M ethod Blank w / IS MB-110407-06 M ethod Blank w / IS LCS-110407-01 3 ng LCS in TCR-842 LCS-110407-02 3 ng LCS in TCR-842 LCS-110407-03 3 ng LCS in TCR-842 LCS-110407-O4 30 ng LCS in TCR-842 LCS-110407-05 30 ng LCS in TCR-842 LCS-110407-06 30 ng LCS in TCR-842 GLP10-01-01-15-004 DAL SS SS13 0 0000 GLP10-01-01-15-004 Dup DAL SS SS13 0 0000 Lab Duplicate GLP10-01-01-15-004 LMS DAL SS SS13 0 0000 Lab M a trix Spike 10 006-96 solvent blank EC-110407-05 2.5 ng Extracted Curve Point 10 006-96 solvent blank GLP10-01-01-15-008 DAL SS SS110 0005 GLP10-01-01-15-008 Dup DAL SS SS110 0005 Lab Duplicate GLP10-01-01-15-008 LMS DAL SS SS110 0005 Lab M a trix Spike GLP10-01-01-15-020 DAL SS SS10 0 0000 GLP10-01-01-15-020 Dup DAL SS SS10 0 0000 Lab Duplicate GLP10-01-01-15-020 LMS DAL SS SS10 0 0000 Lab M a trix Spike GLP10-01-01-15-029 DAL SD SD22 DB 0005 GLP10-01-01-15-029 Dup DAL SD SD22 DB 0005 Lab Duplicate GLP10-01-01-15-029 LMS DAL SD SD22 DB 0005 Lab M a trix Spike GLP10-01-01-1S-032 DAL SD SD210 0005 GLP10-01-01-15-032 Dup DAL SD SD210 0005 Lab Duplicate GLP10-01-01-15-032 LMS DAL SD SD210 0005 Lab M a trix Spike GLP10-01-01-15-040 DAL SS SS20 0 0005 GLP10-01-01-15-040 Dup DAL SS SS20 0 OOOS Lab Duplicate GLP10-01-01-15-040 LMS DAL SS SS20 0 0005 Lab M a trix Spike 10 006-96 solvent blank EC-110407-06 5 ng Extracted Curve Point 10 006-96 solvent blank GLP10-01-01-15-080 DAL SS SS26 DB 0000 GLPlO-01-01-15-080 Dup DAL SS SS26 DB 0000 Lab Duplicate GLP10-01-01-1S-080 LMS DAL SS SS26 DB 0000 Lab M a trix Spike GLP10-01-01-15-090 DAL SS SS15 0 0015 GLP10-01-01-15-090 Dup DAL SS SS15 O0015 Lab Duplicate Analyte Peak Name PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS Calculated Sample Use Concentratio Accuracy Record Type Record n (ng/m L) (%) M odified File Name Unknown 0.196 N/A 0 sll0411a.w iff Unknown 0.48 N/A 0 sll0411a.w iff Unknown 0.643 N/A 0 sll0411a.w iff Unknown 0.49 N/A 0 sll0411a.w iff Double Blank N/A N/A 0 sll0411a.w iff Q uality Co 1 9.5 95.1 0 sll0411a,w iff Double Blank N/A N/A 1 sll0411a,w iff Unknown 0.0162 N/A 0 sll0411a.w iff Unknown 0.346 N/A 0 sll0411a.w iff Unknown 0.0978 N/A 0 sll0411a,w iff Double Blank N/A N/A 0 s11041 la .w iff Q uality Co 1 2.51 101 0 sll0411a.w iff Double Blank N/A N/A 0 sll0411a.w iff Double Blank N/A N/A 0 s i 10411a.wiff Double Blank N/A N/A 0 s i 10411a.wiff Double Blank N/A N/A 0 sll0411a.w iff Double Blank N/A N/A 0 sll0411a.w iff Double Blank N/A N/A 0 sll0411a.w iff Double Blank N/A N/A 1 sll0411a.w iff Double Blank N/A N/A 0 sll0411a.w iff Double Blank N/A N/A 0 sll0411a.w iff Double Blank N/A N/A 1 sll0411a.w iff Double Blank N/A N/A 0 sll0411a.w iff Standard 1 0.177 89 0 sll0411a.w iff Standard 1 0.508 102 0 sll0411a.w iff Standard 1 0.716 9S.7 0 sll0411a.w iff Standard 1 0.991 99.4 0 sll0411a.w iff Standard 1 2.7 109 0 sll0411a.w iff Standard 1 5.19 104 0 sll0411a.w iff Standard 1 9.62 96.5 0 sll0411a.w iff Standard 1 26.2 105 0 s ll0 4 1 1 a .w iff Standard 1 50.6 101 0 sll0411a.w iff Standard 1 99.4 99.7 0 s ll0 4 1 1 a .w iff Standard 1 196 98.4 0 sll0411a.w iff Standard 1 501 100 0 s i 10411a.wiff Double Blank N/A N/A 1 sll0411a.w iff Double Blank N/A N/A 0 sll0411a.w iff Double Blank N/A N/A 0 sll0411a.w lff Double Blank N/A N/A 1 sll0411a.w iff Double Blank N/A N/A 0 sll0411a.w iff Double Blank N/A N/A 1 s!10411a.wiff Double Blank N/A N/A 1 sll0411a.w iff Unknown <0 N/A 1 sll0411a.w iff Unknown <0 N/A 0 sll0411a.w iff Unknown 152 N/A 1 sll0411a.w iff Unknown 3.34 N/A 1 sll0411a.w iff Unknown 3,24 N/A 1 sll0411a.w iff Unknown 3.36 N/A 1 sll0411a.w iff Unknown 33.8 N/A 1 sll0411a.w iff Unknown 34.7 N/A 1 sll0411a.w iff Unknown 35.5 N/A 1 sll0411a.w iff Unknown 3.31 N/A 1 s i 10411a.w iff Unknown 2.89 N/A 1 s i 10411a.w iff Unknown 2.54 N/A 1 sll0411a.w iff Double Blank N/A N/A 0 s i 10411a.wiff Q uality Co 1 2.66 107 0 sll0411a.w iff Double Blank N/A N/A 0 sll0411a.w iff Unknown 5.15 N/A 1 sll0411a.w iff Unknown 6.23 N/A 1 sll0411a.w iff Unknown 37.1 N/A 1 sll0411a.w iff Unknown 45.9 N/A 1 sll0411a.w iff Unknown 61.8 N/A 1 sll0411a.w iff Unknown 73 N/A 1 sll0411a.w iff Unknown 105 N/A 1 sll0411a.w iff Unknown 78.8 N/A 1 sll0411a.w lff Unknown 364 N/A 1 s i 10411a.w iff Unknown 118 N/A 1 sll0411a.w iff Unknown 147 N/A 1 sll0411a.w iff Unknown 124 N/A 1 sll0411a.w iff Unknown 1.89 N/A 1 sll0411a.w iff Unknown 2.16 N/A 1 sll0411a.w iff Unknown 2.9 N/A 1 sll0411a.w iff Double Blank N/A N/A 0 sll0411a.w iff Q uality Co 1 5.25 105 0 sll0411a.w iff Double Blank N/A N/A 0 sll0411a.w iff Unknown 10.7 N/A 1 sll0411a.w iff Unknown 11.7 N/A 1 s!10411a.wiff Unknown 61.9 N/A 1 sll0411a.w iff Unknown 4.24 N/A 1 sll0411a.w iff Unknown 3.75 N/A 1 s!10411a.wiff 3M Study GLP10-01-02-15 Page 3 of 5 Page 86 of 514 s ll0 4 1 1 a Sample Name s ll0 4 1 1 a 0 6 7 s ll0 4 1 1 a 0 6 8 s ll0 4 1 1 a 0 6 9 s ll0 4 1 1 a 0 7 0 sll0411a071 $110411a072 s ll0 4 1 1 a 0 7 3 s l!0 4 1 1 a 0 7 4 s l!0 4 1 1 a 0 7 5 s ll0 4 1 1 a 0 7 6 sl!0411a077 sll0411a078 s ll0 4 1 1 a 0 7 9 s ll0 4 1 1 a 0 8 0 s ll0 4 1 1 a 0 8 1 s ll0 4 1 1 a 0 8 2 s ll0 4 1 1 a 0 8 3 sll0411a084 sll0411a085 s ll0 4 1 1 a 0 8 6 s ll0 4 1 1 a 0 0 1 sll0411a002 sll0411a003 sll0411a004 sll0411a00S s ll0 4 1 1 a 0 0 6 s ll0 4 1 1 a 0 0 7 s ll0 4 1 1 a 0 0 8 s ll0 4 1 1 a 0 0 9 s ll0 4 1 1 a 0 1 0 s ll0 4 1 1 a 0 1 1 s ll0 4 1 1 a 0 1 2 sll0411a013 sll0411a014 sll0411a01S sll0411a016 sll0411a017 sll0411a018 s ll0 4 1 1 a 0 1 9 sl!0411a020 sll0411a021 s ll0 4 1 1 a 0 2 2 s ll0 4 1 1 a 0 2 3 s ll0 4 1 1 a 0 2 4 sll0411a02S s ll0 4 1 1 a 0 2 6 sll0411a027 s ll0 4 1 1 a 0 2 8 sll0411a029 sll0411a030 sll04U a031 sll0411a032 sll0411a033 sll04U a034 s ll0 4 1 1 a 0 3 5 sll0411a036 s ll0 4 1 1 a 0 3 7 s ll0 4 1 1 a 0 3 8 s ll0 4 1 1 a 0 3 9 s ll0 4 1 1 a 0 4 0 sll0411a041 sll0411a042 sll0411a043 sll0411a044 sll0411a045 s ll0 4 1 1 a 0 4 6 sll0411a047 sll0411a048 $110411a049 sll0411a050 sl!0411a051 sll0 4 1 1 a 0 S 2 sll0411a053 sll0411a054 sll0411a055 s ll0 4 1 1 a 0 5 6 s ll0 4 1 1 a 0 5 7 sll0411a058 sll0411a059 s!10411a060 Sample 10 GLP10-01-01-15-090 LMS DAL SS SS15 0 0015 Lab M a trix Spike GLP10-01-01-15-092 DAL SS SS110 0015 GLP10-01-01-15-092 Dup DAL SS SS110 0015 Lab Duplicate GLP10-01-01-15-092 LMS DAL SS SS110 0015 Lab M a trix Spike GLP10-01-01-15-020 DAL SS SS10 0 0000 DF:50 GLP10-01-01-15-020 Dup DAL SS SS10 0 0000 Lab Duplicate DF:50 GLP10-01-01-15-020 LMS DAL SS SS10 0 0000 Lab M a trix Spike DF:50 GLP10-01-01-15-024 DAL SS SS25 0 0000 DF:50 GLP10-01-01-15-024 Dup DAL SS SS25 0 0000 Lab Duplicate DF:50 GLP10-01-01-1S-024 LMS DAL SS SS25 0 0000 Lab M a trix Spike DF:50 10 006*96 solvent blank EC-110407-07 10 ng Extracted Curve Point 10 006-96 solvent blank GLP10-01-01-15-080 DAL SS SS26 DB 0000 DF:50 GLP10-01-01-1S-080 Dup DAL SS SS26 DB 0000 Lab Duplicate DF:50 GLP10-01-01-15-080 LMS DAL SS SS26 DB 0000 Lab M a trix Spike DF:50 10 006-96 solvent blank EC-110407-05 2.5 ng Extracted Curve Point 10 006-96 solvent blank 10 006-96 solvent blank 10 006-96 solvent blank 10 006-96 solvent blank EC-110407-09 50 ng W arm up standard EC-110407-09 50 ng W arm up standard 10 006-96 solvent blank 10 006-96 solvent blank 10 006-96 solvent blank 10 006-96 solvent blank 10 006-96 solvent blank EC-110407-010.2 ng Extracted Curve Point EC-110407-02 0.5 ng Extracted Curve Point EC-110407-03 0.75 ng Extracted Curve Point EC-110407-04 1 ng Extracted Curve Point EC-110407-05 2.5 ng Extracted Curve Point EC-110407-06 5 ng Extracted Curve Point EC-110407-07 10 ng Extracted Curve Point EC-110407-08 25 ng Extracted Curve Point EC-110407-09 50 ng Extracted Curve Point EC-110407-10 100 ng Extracted Curve Point EC-110407-11200 ng Extracted Curve Point EC-110407'12 500 ng Extracted Curve Point 10 006-96 solvent blank 10 006-96 solvent blank 10 006-96 solvent blank 10 006-96 solvent blank MB-110407-01 M ethod Blank w /o IS MB-110407-02 M ethod Blank w /o IS MB-110407-03 M ethod Blank w /o IS MB-110407-04 M ethod Blank w / IS MB-110407-05 M ethod Blank w / IS MB-110407-06 M ethod Blank w / IS LCS-110407-01 3 ng LCS in TCR-842 LCS-110407-02 3 ng LCS in TCR-842 LCS-110407-03 3 ng LCS in TCR-842 LCS-110407-04 30 ng LCS in TCR-842 LCS-110407-05 30 ng LCS in TCR-842 LCS-110407-06 30 ng LCS in TCR-842 GLP10-01-01-15-004 DAL SS SS13 0 0000 GLP10-01-01-1S-004 Dup DAL SS SS13 0 0000 Lab Duplicate GLP10-01-01-15-004 LMS DAL SS SS13 0 0000 Lab M a trix Spike 10 006-96 solvent blank EC-110407-05 2.5 ng Extracted Curve Point 10 006-96 solvent blank GLP10-01-01-15-008 DAL SS SS110 0005 GLP10-01-01-15-008 Dup DAL SS SS110 0005 Lab Duplicate GLP10-01-01-15-008 LMS DAL SS SS110 0005 Lab M a trix Spike GLP10-01-01-15-020 DAL SS SS10 0 0000 GLP10-01-01-15-020 Dup DAL SS SS10 0 0000 Lab Duplicate GLP10-01-01-15-020 LMS DAL SS SS10 0 0000 Lab M a trix Spike GLP10-01-01-15-029 DAL SD SD22 DB 0005 GLP10-01-01-15-029 Dup DAL SD SD22 DB 0005 Lab Duplicate GLP10-01-01-15-029 LMS DAL SD SD22 DB 0005 Lab M a trix Spike GLP10-01-01-15-032 DAL SD SD210 0005 GLP10-01-01-15-032 Dup DAL SD SD210 0005 Lab Duplicate GLP10-01-01-1S-032 LMS DAL SD SD210 0005 Lab M a trix Spike GLP10-01-01-15-040 DAL SS SS20 0 0005 GLP10-01-01-15-040 Dup DAL SS SS20 0 0005 Lab Duplicate GLP10-01-01-15-040 LMS DAL SS SS20 0 0005 Lab M a trix Spike 10 006-96 solvent blank EC-110407-06 5 ng Extracted Curve Point Analyte Peak Name PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS Sample Use Type Record Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Q uality Co Double Blank Unknown Unknown Unknown Double Blank Q uality Co Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Q uality Co Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Q uality Co Calculated Concentratio Accuracy Record n (ng/mL) (%) 3.42 N/A M odified File Name 1 s!10411a.wiff 3.36 N/A 1 sll0411a.w iff 1.65 N/A 1 sll0411a.w iff 1.4 N/A 1 sll0411a.w iff 1.05 N/A 1 sll0411a.w iff 1.5 N/A 1 sll0411a.w iff 1.64 N/A 1 sll0411a.w iff 9.08 N/A 1 sll0411a.w iff 16 N/A 1 sll0411a.w iff 27.6 N/A 1 sll0411a.w iff N/A N/A 0 sll0411a.w iff 1 9.48 95.1 0 sll0411a.w iff N/A N/A 1 sll0411a.w iff 0.17 N/A 1 sll0411a,w iff 1.38 N/A 1 sll0411a.w iff 1.15 N/A 1 sll0411a.w iff N/A N/A 0 sll0411a.w iff 1 2.63 106 0 sll0411a.w iff N/A N/A 0 sll0411a.w iff N/A N/A 0 sll0411a.w iff N/A N/A 0 sll0411a.w iff N/A N/A 0 sll0411a.w iff N/A N/A 1 sll0411a.w iff N/A N/A 0 sll0411a.w iff N/A N/A 0 sll0411a.w iff N/A N/A 0 sll0411a.w iff N/A N/A 0 sll0411a.w iff N/A N/A 0 sll0411a.w iff N/A N/A 0 sll0411a.w iff 1 0.234 117 0 sll0411a.w iff 1 0.49S 98.9 0 sll0411a.w iff 1 0.762 102 0 sll0411a.w iff 1 0.927 92.8 0 sll0411a.w iff 1 2.54 101 0 s11041 la . w iff 1 5 99.9 0 sll0411a.w iff 1 9.09 91 0 sll0411a.w iff 1 24.8 99,3 0 sll0411a.w iff 1 49.1 98.2 0 sll0411a.w lff 1 95.4 95.5 0 sll0411a.w iff 1 210 105 0 $110411a.wiff 1 496 99.3 0 s!10411a.wiff N/A N/A 1 sll0411a.w iff N/A N/A 0 sll0411a.w iff N/A N/A 1 sll0411a.w iff N/A N/A 1 sll0411a.w iff N/A N/A 1 sll0411a.w iff N/A N/A 1 sll0411a.w iff N/A N/A 1 sll0411a.w iff 0.0918 N/A 1 sll0411a.w iff 0.0566 N/A 1 sll0411a.w iff 120 N/A 1 sll0411a.w iff 2.95 N/A 1 sll0411a.w iff 3.03 N/A 1 sll0411a.w iff 2.92 N/A 1 sll0411a.w iff 31.6 N/A 1 s!10411a.wiff 31 N/A 1 sll0411a.w iff 29.9 N/A 1 sll0411a.w iff 148 N/A 1 sll0411a.w iff 209 N/A 1 sll0411a.w iff 156 N/A 1 $110411a.wiff N/A N/A 1 sll0411a.w iff 1 2.56 102 0 sll0411a.w iff N/A N/A 1 sll0411a.w iff 135 N/A 1 sll0411a.w iff 128 N/A 1 sll0411a.w iff 282 N/A 1 sll0411a.w iff No Intercept N/A 1 sll0411a.w iff No Intercept N/A 1 sll0411a.w iff No Intercept N/A 1 sll0411a.w iff No Intercept N/A 1 sll0411a.w iff No Intercept N/A 1 sll0411a.w iff No Intercept N/A 1 sll0411a.w iff No Intercept N/A 1 sll0411a.w iff No Intercept N/A 1 sll0411a.w iff No Intercept N/A 1 sll0411a.w iff 82.8 N/A 1 sll0411a.w iff 71.2 N/A 1 sll0411a.w iff 51.8 N/A 1 $110411a.wiff N/A N/A 1 sll0411a.w iff 1 4.9 98 0 sll0411a.w iff 3M Study GLP10-01-02-15 Page 4 of 5 Page 87 of 514 sll0 4 1 1 a Sample Name s ll0 4 1 1 a 0 6 1 sll0411a062 s ll0 4 1 1 a 0 6 3 sll0411a064 sll0411a065 s ll0 4 1 1 a 0 6 6 sll0411a067 sll0411a068 s ll0 4 1 1 a 0 6 9 s ll0 4 1 1 a 0 7 0 sll0411a071 sll0411a072 sll0411a073 S ll0 4 1 1 a 0 7 4 sll0411a075 sll0 4 U a0 7 6 sll0411a077 s ll0 4 1 1 a 0 7 8 s ll0 4 1 1 a 0 7 9 s ll0 4 1 1 a 0 8 0 sll0411a081 s ll0 4 1 1 a 0 8 2 $110411a083 sll0411a084 sll0411a085 s ll0 4 1 1 a 0 8 6 Sample 10 10 006-96 solvent blank GLPlO-01-01-15-080 DAL SS SS26 DB 0000 GLPlO-01-01-15-080 Oup DAL SS SS26 DB 0000 Lab Duplicate GLPlO-01-01-15-080 LMS DAL SS SS26 DB 0000 Lab M a trix Spike GLP10-01-01-1S-090 DAL SS SS15 0 0015 GLPlO-01-01-15-090 Dup DAL SS SS15 0 0015 Lab Duplicate GLPlO-01-01-15-090 LMS DAL SS SS15 0 0015 Lab M a trix Spike GLPlO-01-01-15-092 DAL SS SS110 0015 GLPlO-01-01-15-092 Dup DAL SS SS110 0015 Lab Duplicate GLP10-01-01-15-092 LMS DAL SS SS110 0015 Lab M a trix Spike GLP10-01-01-15-020 DAL SS SS10 0 0000 DF:S0 GLP10-01-01-15-020 Dup DAL SS SS10 0 0000 Lab Duplicate DF:50 GLP10-01-01-15-020 LMS DAL SS SS10 0 0000 Lab M a trix Spike DF:50 GLPlO-01-01-15-024 DAL SS SS25 0 0000 DF:50 GLP10-01-01-15-024 Dup DAL SS SS25 0 0000 Lab Duplicate DF:50 GLPlO-01-01-15-024 LMS DAL SS SS25 0 0000 Lab M a trix Spike DF:50 10 006-96 solvent blank EC-110407-07 10 ng Extracted Curve Point 10 006-96 solvent blank GLPlO-01-01-15-080 DAL SS SS26 DB 0000 DF:50 GLPlO-01-01-15-080 Oup DAL SS SS26 DB 0000 Lab Duplicate DF:50 GLPlO-01-01-15-080 LMS DAL SS SS26 DB 0000 Lab M a trix Spike DF:S0 10 006-96 solvent blank EC-110407-05 2.5 ng Extracted Curve Point 10 006-96 solvent blank 10 006-96 solvent blank Analyte Peak Name PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS Sample Use Type Record Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Q uality Co Double Blank Unknown Unknown Unknown Double Blank Q uality Co Double Blank Double Blank Calculated Concentratio Accuracy Record n (ng/mL) {%) M odified File Name N/A N/A 1 sll0411a.w iff No Intercept N/A 1 sll0411a.w iff No Intercept N/A 1 sll0411a.w iff No Intercept N/A 1 sll0411a.w iff 120 N/A 1 sll0411a.w iff 108 N/A 1 sll0411a.w iff 182 N/A 1 sll0411a.w iff 147 N/A 1 sll0411a.w iff 47.8 N/A 1 sll0411a.w iff 74.8 N/A 1 sll0411a.w iff 51.5 N/A 1 s!10411a.wiff 88.7 N/A 1 sll0411a.w iff 218 N/A 1 sll0411a.w iff 68.4 N/A 1 sll0411a.w iff 78.7 N/A 1 sll0411a.w iff 55.1 N/A 1 sll0411a.w tff N/A N/A 1 sll0411a.w iff 1 9.35 93.5 0 sll0411a.w iff N/A N/A 1 sll0411a.w iff 21.6 N/A 1 sll0411a.w iff 46.3 N/A 1 sll0411a.w iff 25.1 N/A 1 sll0411a,w iff N/A N/A 1 sll0411a.w iff 1 2.4 96.1 0 sll0411a.w iff N/A N/A 0 s!10411a.wiff N/A N/A 0 sll0411a.w iff only highlighted data reported fro m this run, ail o th e r data reported fro m previous analysis 3M Study GLP10-01-02-15 Page 5 of 5 Page 88 of 514 Project or Study D escrip tio n : LIM S Number: A ffected Data: Note To File D ecatur Soil Sam pling G L P 10-01 None On 1/19/11 a bottle order for soil sampling was prepared as follows: Three soil trip blanks in 250 mL Nalgene bottle, closed and sealed with tape, and labeled as Soil Trip Blank 1, Soil Trip Blank 2, and Soil Trip Blank 3. Soil Trip Blank 1 contains 23.46g of 10 010-125 (10 010-125 is an aliquot of TCR-842), Soil Trip Blank 2 contains 24.14g of 10 010-125, and Soil Trip Blank 3 contains 22.08g of 10 010-125. The trip blanks were weighed on balance 1629700 on 1/19/11. Five 500 mL bottles containing Milli-Q Element water (TNI 1-0023) for rinseate samples. 92 empty 250 mL Nalgene bottles (for collecting soil, sediment, and rinseate samples). Recorded By: G abriel P. M cM urtry 3M Study GLP10-01-02-15 Date: 1/19/11 / ' If- 1 ( Page 89 of 514 GLPlO-01-02-15 ETS-8-053 Soils Weighed 10-Mar-2011 Sample ID Sample Description 1 GLP10-01-01-15-001 GLP10-01-01-15-001 Duo GLP10-01-01-15-001 LMS GLP10-01-01-15-002 GLP10-01-01-15-002 Dup GLP10-01-01-15-002 LMS GLP10-01-01-15-003 GLP10-01-01-15-003 Dup GLP10-01-01-15-003 LMS GLP10-01-01-15-004 GLP10-01-01-15-004 Dup GLP10-01-01-15-004 LMS GLP10-01-01-15-005 GLP10-01-01-15-005 Dup GLP10-01-01-15-005 LMS GLP10-01-01-15-006 GLP10-01-01-15-006 Dup GLP10-01-01-15-006 LMS GLP10-01-01-15-007 GLP10-01-01-15-007 Dup GLP10-01-01-15-007 LMS GLP10-01-01-15-008 GLP10-01-01-15-008 Dup GLP10-01-01-15-008 LMS GLP10-01-01-15-009 GLP10-01-01-15-009 Dup GLP10-01-01-15-009 LMS GLP10-01-01-15-010 GLP10-01-01-15-010 Dup GLP10-01-01-15-010 LMS GLP10-01-01-15-011 GLP10-01-01-15-011 Dup GLP10-01-01-15-011 LMS GLP10-01 -01 -15-012 GLP10-01-01-15-012 Dup GLP10-01-01-15-012 LMS GLP10-01-01-15-014 GLP10-01-01-15-014 Dup GLP10-01 -01-15-014 LMS GLP10-01-01-1S-015 GLP10-01-01-15-015 Dup GLP10-01-01-15-015 LMS GLP10-01-01-15-016 GLP10-01-01-15-016 Dup GLP10-01-01-15-016 LMS GLP10-01-01-15-018 GLP10-01-01-15-018 Dup GLP10-01-01-15-018 LMS GLP10-01-01-15-020 GLP10-01-01-15-020 Dup GLP10-01-01-15-020 LMS GLP 10-01-01-15-021 GLP10-01-01-15-021 Dup GLP10-01-01-15-021 LMS GLP10-01-01-15-022 GLP10-01-01-15-022 Dup GLP10-01-01-15-022 LMS GLP10-01-01-15-023 GLP10-01-01-15-023 Dup GLP10-01-01-15-023 LMS GLP10-01-01-15-024 GLP10-01 -01 -15-024 Dup GLP10-01-01-15-024 LMS GLP10-01-01-15-025 GLP10-01-01-15-025 Dup GLP10-01-01-15-025 LMS GLP10-01-01-15-026 GLP10-01-01-15-026 Dup GLP10-01-01-15-026 LMS 2 DAL SS SS Tripl 0 0000 DAL SS SS Tripl 0 0000 Lab Duplicate DAL SS SS Tripl 0 0000 Lab Matrix Spike DAL SS SS12 0 0000 DAL SS SS12 0 0000 Lab Duplicate DAL SS SS12 0 0000 Lab Matrix Spike DAL SS SS12 0 0005 DAL SS SS12 0 0005 Lab Duplicate DAL SS SS12 0 0005 Lab Matrix Spike DAL SS SS13 0 0000 DAL SS SS13 0 0000 Lab Duplicate DAL SS SS13 0 0000 Lab Matrix Spike DAL SS SS16 0 0000 DAL SS SS16 0 0000 Lab Duplicate DAL SS SS16 0 0000 Lab Matrix Spike DAL SS SS16 DB 0000 DAL SS SS16 DB 0000 Lab Duplicate DAL SS SS16 DB 0000 Lab Matrix Spike DAL SS SS11 0 0000 DAL SS SS11 0 0000 Lab Duplicate DAL SS SS11 0 0000 Lab Matrix Spike DAL SS SS11 0 0005 DAL SS SS11 0 0005 Lab Duplicate DAL SS SS11 0 0005 Lab Matrix Spike DAL SS SS20 0 0000 DAL SS SS20 0 0000 Lab Duplicate DAL SS SS20 0 0000 Lab Matrix Spike DAL SS SS20 DB 0000 DAL SS SS20 DB 0000 Lab Duplicate DAL SS SS20 DB 0000 Lab Matrix Spike DAL SS SS19 0 0000 DAL SS SS19 0 0000 Lab Duplicate DAL SS SS19 0 0000 Lab Matrix Spike DAL SS SS19 0 0005 DAL SS SS19 0 0005 Lab Duplicate DAL SS SS19 0 0005 Lab Matrix Spike DAL SS SS15 0 0000 DAL SS SS15 0 0000 Lab Duplicate DAL SS SS15 0 0000 Lab Matrix Spike DAL SS SS17 0 0000 DAL SS SS17 0 0000 Lab Duplicate DAL SS SS17 0 0000 Lab Matrix Spike DAL SS SS14 0 0000 DAL SS SS14 0 0000 Lab Duplicate DAL SS SS14 0 0000 Lab Matrix Spike DAL SS SS18 0 0000 DAL SS SS18 0 0000 Lab Duplicate DAL SS SS18 0 0000 Lab Matrix Spike DAL SS SS10 0 0000 DAL SS SS10 0 0000 Lab Duplicate DAL SS SS10 0 0000 Lab Matrix Spike DAL SS SS30 0 0000 DAL SS SS30 0 0000 Lab Duplicate DAL SS SS30 0 0000 Lab Matrix Spike DAL SS SS30 0 0005 DAL SS SS30 0 0005 Lab Duplicate DAL SS SS30 0 0005 Lab Matrix Spike DAL SS SS30 0 0015 DAL SS SS30 0 0015 Lab Duplicate DAL SS SS30 0 0015 Lab Matrix Spike DAL SS SS25 0 0000 DAL SS SS25 0 0000 Lab Duplicate DAL SS SS25 0 0000 Lab Matrix Spike DAL SS SS25 0 0005 DAL SS SS25 0 0005 Lab Duplicate DAL SS SS25 0 0005 Lab Matrix Spike DAL SS SS25 0 0015 DAL SS SS25 0 0015 Lab Duplicate DAL SS SS25 0 0015 Lab Matrix Spike Soil Matrix ID Soil Weight Used (g) 34 1.0969 1.1041 1.1639 2.1713 2.1685 2.2792 1.7306 1.6369 1.8023 1.4718 1.5972 1.4002 1.4346 1.2958 1.4129 1.4828 1.5002 1.5622 1.5738 1.5306 1.2980 1.8322 1.6269 1.7266 1.4855 1.3023 1.5702 1.5863 1.5513 1.5200 1.8169 1.7215 1.9596 1.3867 1.3293 1.2357 1.3064 1.1784 1.4972 1.3188 1.3474 1.3190 1.4883 1.5932 1.3255 1.5709 1.8341 1.7257 1.4118 1.1844 1.6224 0.9862 1.0133 1.1617 1.1939 1.0273 1.1540 1.1015 1.0546 1.0244 2.1757 2.3313 2.5810 1.2722 1.3291 1.3854 1.7182 1.5521 1.4726 Printed 3/10/2011 3M Study GLP10-01-02-15 Page 1 o f 4 Page 90 of 514 GLPlO-01-02-15 ETS-8-053 Soils Weighed 10-Mar-2011 Sample ID Sample Description 1 GLP10-01 -01-15-027 GLP10-01-01-15-027 Dud GLP10-01-01-15-027 LMS GLP10-01-01-15-028 GLP10-01-01-15-028 Duo GLP10-01-01-15-028 LMS GLP10-01-01-15-029 GLP10-01-01-15-029 Dup GLP10-01-01-15-029 LMS GLP10-01 -01-15-030 GLP10-01-01-15-030 Dup GLP10-01-01-15-030 LMS GLP10-01-01-15-031 GLP10-01-01-15-031 Dup GLP10-01-01-15-031 LMS GLP10-01-01-15-032 GLP10-01-01-15-032 Dup GLP10-01-01-15-032 LMS GLP10-01 -01-15-033 GLP10-01-01-15-033 Dup GLP10-01-01-15-033 LMS GLP10-01-01-15-034 GLP10-01-01-15-034 Dup GLP10-01-01-15-034 LMS GLP10-01-01-15-035 GLP10-01-01-15-035 Dup GLP10-01-01-15-035 LMS GLP10-01-01-15-036 GLP10-01-01-15-036 Dup GLP10-01-01-15-036 LMS GLP10-01-01-15-037 GLP10-01-01-15-037 Dup GLP10-01-01-15-037 LMS GLP10-01-01-15-038 GLP10-01-01-15-038 Dup GLP10-01-01 -15-038 LMS GLP10-01-01-15-039 GLP10-01-01-15-039 Dup GLP10-01-01-15-039 LMS GLP10-01-01-15-040 GLP10-01 -01 -15-040 Dup GLP10-01-01-15-040 LMS GLP10-01-01-15-041 GLP10-01-01-15-041 Dup GLP10-01-01-15-041 LMS GLP10-01-01-15-042 GLP10-01-01-15-042 Dup GLP10-01-01-15-042 LMS GLP10-01 -01 -15-043 GLP10-01-01-15-043 Dup GLP10-01-01-15-043 LMS GLP10-01-01-15-044 GLP10-01-01-15-044 Dup GLP10-01-01-15-044 LMS GLP10-01-01-15-045 GLP10-01-01-15-045 Dup GLP10-01-01-15-045 LMS GLP10-01-01-15-046 GLP10-01-01-15-046 Dup GLP10-01-01-15-046 LMS GLP10-01-01-15-047 GLP10-01-01-15-047 Dup GLP10-01-01-15-047 LMS GLP10-01-01-15-048 GLP10-01-01-15-048 Dup GLP10-01 -01-15-048 LMS GLP10-01-01-15-049 GLP10-01-01-15-049 Dud GLP10-01-01-15-049 LMS 2 DAL SD SD22 0 0000 DAL SD SD22 0 0000 Lab Duplicate DAL SD SD22 0 0000 Lab Matrix Spike DAL SD SD22 0 0005 DAL SD SD22 0 0005 Lab Duplicate DAL SD SD22 0 0005 Lab Matrix Spike DAL SD SD22 DB 0005 DAL SD SD22 DB 0005 Lab Duplicate DAL SD SD22 DB 0005 Lab Matrix Spike DAL SD SD22 0 0015 DAL SD SD22 0 0015 Lab Duplicate DAL SD SD22 0 0015 Lab Matrix Spike DAL SD SD21 0 0000 DAL SD SD21 0 0000 Lab Duplicate DAL SD SD21 0 0000 Lab Matrix Spike DAL SD SD21 0 0005 DAL SD SD21 0 0005 Lab Duplicate DAL SD SD21 0 0005 Lab Matrix Spike DAL SD SD21 0 0015 DAL SD SD21 0 0015 Lab Duplicate DAL SD SD21 0 0015 Lab Matrix Spike DAL SS SS24 0 0000 DAL SS SS24 0 0000 Lab Duplicate DAL SS SS24 0 0000 Lab Matrix Spike DAL SS SS24 0 0005 DAL SS SS24 0 0005 Lab Duplicate DAL SS SS24 0 0005 Lab Matrix Spike DAL SS SS24 0 0015 DAL SS SS24 o 0015 Lab Duplicate DAL SS SS24 0 0015 Lab Matrix Spike DAL SS SS29 0 0000 DAL SS SS29 0 0000 Lab Duplicate DAL SS SS29 0 0000 Lab Matrix Spike DAL SS SS29 0 0005 DAL SS SS29 0 0005 Lab Duplicate DAL SS SS29 0 0005 Lab Matrix Spike DAL SS SS29 0 0015 DAL SS SS29 0 0015 Lab Duplicate DAL SS SS29 0 0015 Lab Matrix Spike DAL SS SS20 0 0005 DAL SS SS20 0 0005 Lab Duplicate DAL SS SS20 0 0005 Lab Matrix Spike DAL SS SS13 0 0005 DAL SS SS13 0 0005 Lab Duplicate DAL SS SS13 0 0005 Lab Matrix Spike DAL SS SS13DB 0005 DAL SS SS13 DB 0005 Lab Duplicate DAL SS SS13 DB 0005 Lab Matrix Spike DAL SS SS15 0 0005 DAL SS SS15 0 0005 Lab Duplicate DAL SS SS15 0 0005 Lab Matrix Spike DAL SS SS17 0 0005 DAL SS SS17 0 0005 Lab Duplicate DAL SS SS17 0 0005 Lab Matrix Spike DAL SS SS14 0 0005 DAL SS SS14 0 0005 Lab Duplicate DAL SS SS14 0 0005 Lab Matrix Spike DAL SS SS18 0 0005 DAL SS SS18 0 0005 Lab Duplicate DAL SS SS18 0 0005 Lab Matrix Spike DAL SS SS16 0 0005 DAL SS SS16 0 0005 Lab Duplicate DAL SS SS16 0 0005 Lab Matrix Spike DAL SS SS16 0 0015 DAL SS SS16 0 0015 Lab Duplicate DAL SS SS16 0 0015 Lab Matrix Spike DAL SS SS10 0 0005 DAL SS SS10 0 0005 Lab Duplicate DAL SS SS10 0 0005 Lab Matrix Spike Soil Matrix ID Soil Weight Used (g) 34 1.2988 1.3968 1.6349 1.7902 1.9765 1.6704 1.9346 1.9990 1.6023 1.1968 1.1321 1.1141 1.3499 1.7710 1.7567 1.5533 1.4631 1.4255 1.3571 1.4063 1.4551 1.2169 1.2909 1.3334 2.8500 3.1143 2.6325 1.5557 1.3947 1.4021 Printed 3/10/2011 3M Study GLP10-01-02-15 Page 2 o f 4 Page 91 of 514 GLPlO-01-02-15 ETS-8-053 Soils Weighed 10-Mar-2011 Sample ID Sample Description 1 GLP10-01-01-15-050 GLP10-01-01-15-050 Dup GLP10-01-01-15-050 LMS GLP10-01-01-15-051 ' GLP10-01-01-15-051 Dud GLP10-01 -01-15-051 LMS GLP10-01-01-15-052 GLP10-01-01-15-052 Dud GLP10-01-01-15-052 LMS GLP10-01-01-15-053 GLP10-01-01-15-053 Dud GLP10-01-01-15-053 LMS GLP10-01 -01 -15-054 GLP10-01-01-15-054 Dud GLP10-01-01-15-054 LMS GLP10-01-01-15-055 GLP10-01-01-15-055 Dud GLP10-01-01-15-055 LMS GLP10-01 -01-15-056 GLP10-01-01-15-056 Dud GLP10-01-01-15-056 LMS GLP10-01-01-15-057 GLP10-01-01-15-057 Dud GLP10-01-01-15-057 LMS GLP10-01-01-15-058 GLP10-01-01-15-058 Dup GLP10-01-01-15-058 LMS GLP10-01-01-15-059 GLP10-01-01-15-059 Dud GLP10-01-01-15-059 LMS GLP10-01-01-15-060 GLP10-01-01-15-060 Dud GLP10-01-01-15-060 LMS GLP10-01-01-15-061 GLP10-01-01-15-061 Dud GLP10-01-01-15-061 LMS GLP10-01-01-15-062 GLP10-01-01-15-062 Dud GLP10-01-01-15-062 LMS GLP10-01 -01-15-063 GLP10-01-01-15-063 Dup GLP10-01-01-15-063 LMS GLP10-01-01-15-064 GLP10-01-01-15-064 Dup GLP10-01-01-15-064 LMS GLP10-01-01-15-065 GLP10-01-01-15-065 Dup GLP10-01-01-15-065 LMS GLP10-01-01-15-066 GLP10-01-01-15-066 Dud GLP10-01-01-15-066 LMS GLP10-01-01-15-067 GLP10-01-01-15-067 Dud GLP10-01-01-15-067 LMS GLP10-01-01-15-068 GLP10-01-01-15-068 Dud GLP10-01-01-15-068 LMS GLP10-01 -01 -15-069 GLP10-01-01-15-069 Dud GLP10-01-01 -15-069 LMS GLP10-01-01-15-070 GLP10-01-01-15-070 Dup GLP10-01-01-15-070 LMS GLP10-01-01-15-071 GLP10-01-01-15-071 Dud GLP10-01-01-15-071 LMS GLP10-01-01-15-072 GLP10-01-01-15-072 Dud GLP10-01-01-15-072 LMS 2 DAL SS SS10DB 0005 DAL SS SS10 DB 0005 Lab Duplicate DAL SS SS10 DB 0005 Lab Matrix Spike DAL SS SS10 0 0015 DAL SS SS10 0 0015 Lab Duplicate DAL SS SS10 0 0015 Lab Matrix Spike DAL SD SD20 0 0000 DAL SD SD20 0 0000 Lab Duplicate DAL SD SD20 0 0000 Lab Matrix Spike DAL SD SD20 0 0005 DAL SD SD20 0 0005 Lab Duplicate DAL SD SD20 0 0005 Lab Matrix Spike DAL SD SD20 0 0015 DAL SD SD20 0 0015 Lab Duplicate DAL SD SD20 0 0015 Lab Matrix Spike DAL SD SD23 0 0000 DAL SD SD23 0 0000 Lab Duplicate DAL SD SD23 0 0000 Lab Matrix Spike DAL SD SD23 0 0005 DAL SD SD23 0 0005 Lab Duplicate DAL SD SD23 0 0005 Lab Matrix Spike DAL SD SD23 0 0015 DAL SD SD23 0 0015 Lab Duplicate DAL SD SD23 0 0015 Lab Matrix Spike DAL SS SS28 0 0000 DAL SS SS28 0 0000 Lab Duplicate DAL SS SS28 0 0000 Lab Matrix Spike DAL SS SS28 0 0005 DAL SS SS28 0 0005 Lab Duplicate DAL SS SS28 0 0005 Lab Matrix Spike DAL SS SS28 DB 0005 DAL SS SS28 DB 0005 Lab Duplicate DAL SS SS28 DB 0005 Lab Matrix Spike DAL SS SS28 0 0015 DAL SS SS28 0 0015 Lab Duplicate DAL SS SS28 0 0015 Lab Matrix Spike DAL SS SS27 0 0000 DAL SS SS27 0 0000 Lab Duplicate DAL SS SS27 0 0000 Lab Matrix Spike DAL SS SS27 0 0005 DAL SS SS27 0 0005 Lab Duplicate DAL SS SS27 0 0005 Lab Matrix Spike DAL SS SS27 0 0015 DAL SS SS27 0 0015 Lab Duplicate DAL SS SS27 0 0015 Lab Matrix Spike DAL SS SS22 0 0000 DAL SS SS22 0 0000 Lab Duplicate DAL SS SS22 0 0000 Lab Matrix Spike DAL SS SS22 0 0005 DAL SS SS22 0 0005 Lab Duplicate DAL SS SS22 0 0005 Lab Matrix Spike DAL SS SS22 DB 0005 DAL SS SS22 DB 0005 Lab Duplicate DAL SS SS22 DB 0005 Lab Matrix Spike DAL SS SS22 0 0015 DAL SS SS22 0 0015 Lab Duplicate DAL SS SS22 0 0015 Lab Matrix Spike DAL SS SS21 0 0000 DAL SS SS21 0 0000 Lab Duplicate DAL SS SS21 0 0000 Lab Matrix Spike DAL SS SS21 0 0005 DAL SS SS21 0 0005 Lab Duplicate DAL SS SS21 0 0005 Lab Matrix Spike DAL SS SS21 0 0015 DAL SS SS21 0 0015 Lab Duplicate DAL SS SS21 0 0015 Lab Matrix Spike DAL SD SD18 0 0000 DAL SD SD18 0 0000 Lab Duplicate DAL SD SD18 0 0000 Lab Matrix Spike Soil Matrix ID Soil Weight Used (g) 34 Printed 3/10/2011 3M Study GLP10-01-02-15 Page 3 o f 4 Page 92 of 514 GLP10-01-02-15 ETS-8-053 Soils Weighed 10-Mar-2011 Sample ID Sample Description 1 GLP10-01-01-15-073 GLP10-01-01-15-073 Dup GLP10-01-01-15-073 LMS GLP10-01-01-15-074 GLP10-01 -01-15-074 Duo GLP10-01-01-15-074 LMS GLP10-01-01-15-075 GLP10-01-01-15-075 Dud GLP10-01-01-15-075 LMS GLP10-01-01-15-076 GLP10-01-01-15-076 DUD GLP10-01-01-15-076 LMS GLP10-01 -01-15-077 GLP10-01-01-15-077 Dud GLP10-01-01 -15-077 LMS GLP10-01-01-15-079 GLP10-01-01-15-079 Dud GLP10-01-01-15-079 LMS GLP10-01-01-15-080 GLP10-01-01-15-080 Dud GLP10-01-01-15-080 LMS GLP10-01-01-15-081 GLP10-01-01-15-081 Dud GLP10-01-01-15-081 LMS GLP10-01-01-15-082 GLP10-01-01-15-082 Dud GLP10-01-01-15-082 LMS GLP10-01-01-15-083 GLP10-01-01-15-083 Dup GLP10-01-01-15-083 LMS GLP10-01 -01-15-084 GLP10-01-01-15-084 Dud GLP10-01-01-15-084 LMS GLP10-01-01-15-085 GLP10-01-01-15-085 Dud GLP10-01-01-15-085 LMS GLP10-01-01-15-086 GLP10-01-01-15-086 Dup GLP10-01-01-15-086 LMS GLP10-01-01-15-087 GLP10-01-01-15-087 Dup GLP10-01-01-15-087 LMS GLP10-01 -01-15-088 GLP10-01-01-15-088 Dup GLP10-01-01-15-088 LMS GLP10-01 -01 -15-089 GLP10-01-01-15-089 Dup GLP10-01-01-15-089 LMS GLP10-01 -01 -15-090 GLP10-01-01-15-090 Dud GLP10-01-01-15-090 LMS GLP10-01-01-15-091 GLP10-01-01-15-091 Dud GLP10-01-01-15-091 LMS GLP 10-01-01-15-092 GLP10-01-01-15-092 Dup GLP10-01-01-15-092 LMS 2 DAL SD SD18 0 0005 DAL SD SD18 0 0005 Lab Duplicate DAL SD SD18 0 0005 Lab Matrix Spike DAL SD SD18 0 0015 DAL SD SD18 0 0015 Lab Duplicate DAL SD SD18 0 0015 Lab Matrix Spike DAL SD SD19 0 0000 DAL SD SD19 0 0000 Lab Duplicate DAL SD SD19 0 0000 Lab Matrix Spike DAL SD SD19 0 0005 DAL SD SD19 0 0005 Lab Duplicate DAL SD SD19 0 0005 Lab Matrix Spike DAL SD SD19 0 0015 DAL SD SD19 0 0015 Lab Duplicate DAL SD SD19 0 0015 Lab Matrix Spike DAL SS SS26 0 0000 DAL SS SS26 0 0000 Lab Duplicate DAL SS SS26 0 0000 Lab Matrix Spike DAL SS SS26 DB 0000 DAL SS SS26 DB 0000 Lab Duplicate DAL SS SS26 DB 0000 Lab Matrix Spike DAL SS SS26 0 0005 DAL SS SS26 0 0005 Lab Duplicate DAL SS SS26 0 0005 Lab Matrix Spike DAL SS SS26 0 0015 DAL SS SS26 0 0015 Lab Duplicate DAL SS SS26 0 0015 Lab Matrix Spike DAL SS Trip2 0 0000 DAL SS Trip2 0 0000 Lab Duplicate DAL SS Trip2 0 0000 Lab Matrix Spike DAL SS SS12 0 0015 DAL SS SS12 0 0015 Lab Duplicate DAL SS SS12 0 0015 Lab Matrix Spike DAL SS SS19 0 0015 DAL SS SS19 0 0015 Lab Duplicate DAL SS SS19 0 0015 Lab Matrix Spike DAL SS SS20 0 0015 DAL SS SS20 0 0015 Lab Duplicate DAL SS SS20 0 0015 Lab Matrix Spike DAL SS SS14 0 0015 DAL SS SS14 0 0015 Lab Duplicate DAL SS SS14 0 0015 Lab Matrix Spike DAL SS SS17 0 0015 DAL SS SS17 0 0015 Lab Duplicate DAL SS SS17 0 0015 Lab Matrix Spike DAL SS SS13 0 0015 DAL SSSS13 0 0015 Lab Duplicate DAL SS SS13 0 0015 Lab Matrix Spike DAL SSSS15 0 0015 DAL SS SS15 0 0015 Lab Duplicate DAL SS SS15 0 0015 Lab Matrix Spike DAL SS SS18 0 0015 DAL SS SS18 0 0015 Lab Duplicate DAL SS SS18 0 0015 Lab Matrix Spike DAL SS SS11 0 0015 DAL SS SS11 0 0015 Lab Duplicate DAL SS SS11 0 0015 Lab Matrix Spike Note: Soils were weighed then stored in WR01 until extraction. Col 3 & 4: Balance ID: 900 Soil Matrix ID Soil Weight Used (g) 34 Printed 3/10/2011 3M Study GLP10-01-02-15 Page 4 o f 4 Page 93 of 514 GLPlO-01-02-15 ETS-8-053 Soils Weighed 14-Mar-2011 I1 to;I 1 Sample ID Sample Description 1 GLP10-01-01-15-001 GLP10-01-01-15-001 Dup GLP10-01 -01 -15-001 LMS GLP10-01-01-15-002 GLP10-01-01-15-002 Dup GLP10-01-01-15-002 LMS GLP10-01 -01 -15-003 GLP10-01-01-15-003 Dup GLP10-01-01-15-003 LMS GLP10-01 -01 -15-004 GLP10-01-01-15-004 Dup GLP10-01-01-15-004 LMS GLP10-01-01-15-005 GLP10-01-01-15-005 Dup GLP10-01-01-15-005 LMS GLP10-01-01-15-006 GLP10-01-01-15-006 Dup GLP10-01-01-15-006 LMS GLP10-01-01-15-007 GLP10-01-01-15-007 Dup GLP10-01-01-15-007 LMS GLP10-01-01-15-008 GLP10-01 -01-15-008 Dup GLP10-01 -01 -15-008 LMS GLP10-01-01-15-009 GLP10-01-01-15-009 Dup GLP10-01-01-15-009 LMS GLP10-01-01-15-010 GLP10-01-01-15-010 Dup GLP10-01-01-15-010 LMS GLP10-01-01-15-011 GLP10-01-01-15-011 Dup GLP10-01-01-15-011 LMS GLP10-01-01-15-012 GLP10-01-01-15-012 Dup GLP10-01-01-15-012 LMS GLP10-01-01-15-014 GLP10-01-01-15-014 Dup GLP10-01-01-15-014 LMS GLP10-01 -01 -15-015 GLP10-01-01-15-015 Dup GLP10-01-01-15-015 LMS GLP10-01-01-15-016 GLP10-01-01-15-016 Dup GLP10-01-01-15-016 LMS GLP10-01-01-15-018 GLP10-01-01-15-018 Dup GLP10-01-01-15-018 LMS GLP10-01-01-15-020 GLP10-01-01-15-020 Dup GLP10-01-01-15-020 LMS GLP10-01-01-15-021 GLP10-01-01-15-021 Dup GLP10-01-01-15-021 LMS GLP10-01-01-15-022 GLP10-01-01-15-022 Dup GLP10-01-01-15-022 LMS GLP10-01-01 -15-023 GLP10-01-01-15-023 Dup GLP10-01-01-15-023 LMS GLP10-01 -01-15-024 GLP10-01-01-15-024 Dup GLP10-01-01-15-024 LMS GLP10-01-01-15-025 GLP10-01-01-15-025 Dup GLP10-01-01-15-025 LMS GLP10-01-01-15-026 GLP10-01-01-15-026 Dup GLP10-01-01-15-026 LMS 2 DAL SS SS Tripl 0 0000 DAL SS SS Tripl 0 0000 Lab Duplicate DAL SS SS Tripl 0 0000 Lab Matrix Spike DAL SS SS12 0 0000 DAL SS SS12 0 0000 Lab Duplicate DAL SS SS12 0 0000 Lab Matrix Spike DAL SS SS12 0 0005 DAL SS SS12 0 0005 Lab Duplicate DAL SS SS12 0 0005 Lab Matrix Spike DAL SS SS13 0 0000 DAL SS SS13 0 0000 Lab Duplicate DAL SS SS13 0 0000 Lab Matrix Spike DAL SS SS16 0 0000 DAL SS SS16 0 0000 Lab Duplicate DAL SS SS16 0 0000 Lab Matrix Spike DAL SS SS16 DB 0000 DAL SS SS16 DB 0000 Lab Duplicate DAL SS SS16 DB 0000 Lab Matrix Spike DAL SS SS11 0 0000 DAL SS SS11 0 0000 Lab Duplicate DAL SS SS11 0 0000 Lab Matrix Spike DAL SS SS11 0 0005 DAL SS SS11 0 0005 Lab Duplicate DAL SS SS11 0 0005 Lab Matrix Spike DAL SS SS20 0 0000 DAL SS SS20 0 0000 Lab Duplicate DAL SS SS20 0 0000 Lab Matrix Spike DAL SS SS20 DB 0000 DAL SS SS20 DB 0000 Lab Duplicate DAL SS SS20 DB 0000 Lab Matrix Spike DAL SS SS19 0 0000 DAL SS SS19 0 0000 Lab Duplicate DAL SS SS19 0 0000 Lab Matrix Spike DAL SS SS19 0 0005 DAL SS SS19 0 0005 Lab Duplicate DAL SS SS19 0 0005 Lab Matrix Spike DAL SS SS15 0 0000 DAL SS SS15 0 0000 Lab Duplicate DAL SS SS15 0 0000 Lab Matrix Spike DAL SS SS17 0 0000 DAL SSSS17 0 0000 Lab Duplicate DAL SS SS17 0 0000 Lab Matrix Spike DAL SS SS14 0 0000 DAL SS SS14 0 0000 Lab Duplicate DAL SS SS14 0 0000 Lab Matrix Spike DAL SS SS18 0 0000 DAL SS SS18 0 0000 Lab Duplicate DAL SS SS18 0 0000 Lab Matrix Spike DAL SS SS10 0 0000 DAL SS SS10 0 0000 Lab Duplicate DAL SS SS10 0 0000 Lab Matrix Spike DAL SS SS30 0 0000 DAL SS SS30 0 0000 Lab Duplicate DAL SS SS30 0 0000 Lab Matrix Spike DAL SS SS30 0 0005 DAL SS SS30 0 0005 Lab Duplicate DAL SS SS30 0 0005 Lab Matrix Spike DAL SS SS30 0 0015 DAL SS SS30 0 0015 Lab Duplicate DAL SS SS30 0 0015 Lab Matrix Spike DAL SS SS25 0 0000 DAL SS SS25 0 0000 Lab Duplicate DAL SS SS25 0 0000 Lab Matrix Spike DAL SS SS25 0 0005 DAL SS SS25 0 0005 Lab Duplicate DAL SS SS25 0 0005 Lab Matrix Spike DAL SS SS25 0 0015 DAL SS SS25 0 0015 Lab Duplicate DAL SS SS25 0 0015 Lab Matrix Spike Soil Matrix ID Soil Weight Used (g) 1 34 HK1?09!69HH -- 1IB39-- H11M 3H M E M w m m m &am ^B f6369H K -- nra^g-- H H H 74002 HH1R2958IHH mmmszmi 1 1 5 00'2^H 1^H115&38^H woemmm H K lf8 3 2 2 M i mmmmsmi W 766H R K ljr4 8 '5 ;5H H K lf3 2 3 H i H K 1!T5863m IH S 1 f5 2 0 0 H mmmeasma am m ssm a ^M R 3293H B I wmoe&amm mmmmma mmmwMWB mmmmam H 3 M 8 S M wmsismsmk H H -- HB83-- mmmssmm H I32 S E 9 B H R 5109H I am trm m m m n iM H m am m m m m m sm am ^ 0 I9 8 6 2 flM T " ''-- -- BKRIB-- i n S M g iH B M1I02%9HI H M H I1M 5W H H f O '5 3 S H l Wsmsmm m am am a aamassmm -- KE>iiB>taM m m m m wm 1f7482W - mmmssmm a/am m m a Printed 3/14/2011 3M Study GLP10-01-02-15 Page 1 o f 4 Page 94 of 514 GLPlO-01'02-15 ETS-8-053 Soils Weighed 14-Mar-2011 I to toB Sample ID Sample Description 1 GLP10-01-01-15-027 GLP10-01-01-15-027 Duo GLP10-01-01-15-027 LMS GLP10-01-01-15-028 GLP10-01-01-15-028 Duo GLP10-01-01-15-028 LMS GLP10-01-01-15-029 GLP10-01-01-15-029 Duo GLP10-01-01-15-029 LMS GLP10-01 -01-15-030 GLP10-01-01-15-030 Dup GLP10-01-01-15-030 LMS GLP10-01-01-15-031 GLP10-01-01-15-031 Dup GLP10-01-01-15-031 LMS GLP10-01-01-15-032 GLP10-01-01-15-032 Dud GLP10-01-01-15-032 LMS GLP10-01-01-15-033 GLP10-01-01-15-033 Dud GLP10-01-01-15-033 LMS GLP10-01-01-15-034 GLP10-01-01-15-034 Dud GLP10-01-01-15-034 LMS GLP10-01-01-15-035 GLP10-01-01-15-035 DUD GLP10-01-01-15-035 LMS GLP10-01-01-15-036 GLP10-01-01-15-036 Dud GLP10-01-01-15-036 LMS GLP10-01-01-15-037 GLP10-01-01-15-037 Dud GLP10-01-01-15-037 LMS GLP10-01-01-15-038 GLP10-01-01-15-038 Dup GLP10-01-01-15-038 LMS GLP10-01-01-15-039 GLP10-01-01-15-039 Dup GLP10-01-01-15-039 LMS GLP10-01-01-15-040 GLP10-01-01-15-040 Dud GLP10-01-01-15-040 LMS GLP10-01-01-15-041 GLP10-01-01-15-041 DUD GLP10-01-01-15-041 LMS GLP10-01-01-15-042 GLP10-01-01-15-042 Dud GLP10-01-01-15-042 LMS GLP10-01-01-15-043 GLP10-01-01-15-043 Dud GLP10-01-01-15-043 LMS GLP10-01-01-15-044 GLP10-01-01-15-044 Dup GLP10-01-01-15-044 LMS GLP10-01-01-15-045 GLP10-01-01-15-045 Dud GLP10-01 -01-15-045 LMS GLP10-01-01-15-046 GLP10-01-01-15-046 DUD GLP10-01 -01 -15-046 LMS GLP10-01-01-15-047 GLP10-01-01-15-047 Dud GLP10-01 -01-15-047 LMS GLP10-01-01-15-048 GLP10-01-01-15-048 Dud GLP10-01-01-15-048 LMS GLP10-01-01-15-049 GLP10-01-01-15-049 Dud GLP10-01-01-15-049 LMS 2 DAL SD SD22 0 0000 DAL SD SD22 0 0000 Lab Duplicate DAL SD SD22 0 0000 Lab Matrix Spike DAL SD SD22 0 0005 DAL SD SD22 0 0005 Lab Duplicate DAL SD SD22 0 0005 Lab Matrix Spike DAL SD SD22 DB 0005 DAL SD SD22 DB 0005 Lab Duplicate DAL SD SD22 DB 0005 Lab Matrix Spike DAL SDSD22 0 0015 DAL SD SD22 0 0015 Lab Duplicate DAL SD SD22 0 0015 Lab Matrix Spike DAL SD SD21 0 0000 DAL SD SD21 0 0000 Lab Duplicate DAL SD SD21 0 0000 Lab Matrix Spike DAL SD SD21 0 0005 DAL SD SD21 0 0005 Lab Duplicate DAL SD SD21 0 0005 Lab Matrix Spike DAL SD SD21 0 0015 DAL SD SD21 0 0015 Lab Duplicate DAL SD SD21 0 0015 Lab Matrix Spike DAL SS SS24 0 0000 DAL SS SS24 0 0000 Lab Duplicate DAL SS SS24 0 0000 Lab Matrix Spike DAL SS SS24 0 0005 DAL SS SS24 0 0005 Lab Duplicate DAL SS SS24 0 0005 Lab Matrix Spike DAL SS SS24 0 0015 DAL SS SS24 0 0015 Lab Duplicate DAL SS SS24 0 0015 Lab Matrix Spike DAL SS SS29 0 0000 DAL SS SS29 0 0000 Lab Duplicate DAL SS SS29 0 0000 Lab Matrix Spike DAL SS SS29 0 0005 DAL SS SS29 0 0005 Lab Duplicate DAL SS SS29 0 0005 Lab Matrix Spike DAL SS SS29 0 0015 DAL SS SS29 0 0015 Lab Duplicate DAL SS SS29 0 0015 Lab Matrix Spike DAL SS SS20 0 0005 DAL SS SS20 0 0005 Lab Duplicate DAL SS SS20 0 0005 Lab Matrix Spike DAL SS SS13 0 0005 DAL SS SS 13 0 0005 Lab Duplicate DAL SS SS13 0 0005 Lab Matrix Spike DAL SS SS13 DB 0005 DAL SS SS13 DB 0005 Lab Duplicate DAL SS SS13 DB 0005 Lab Matrix Spike DAL SS SS15 0 0005 DAL SS SS15 0 0005 Lab Duplicate DAL SS SS15 0 0005 Lab Matrix Spike DAL SS SS17 0 0005 DAL SS SS17 0 0005 Lab Duplicate DAL SS SS17 0 0005 Lab Matrix Spike DAL SS SS14 0 0005 DAL SS SS14 0 0005 Lab Duplicate DAL SS SS14 0 0005 Lab Matrix Spike DAL SS SS18 0 0005 DAL SS SS18 0 0005 Lab Duplicate DAL SS SS18 0 0005 Lab Matrix Spike DAL SS SS16 0 0005 DAL SS SS16 0 0005 Lab Duplicate DAL SS SS16 0 0005 Lab Matrix Spike DAL SS SS16 0 0015 DAL SS SS16 0 0015 Lab Duplicate DAL SS SS16 0 0015 Lab Matrix Spike DAL SS SS10 0 0005 DAL SS SS10 0 0005 Lab Duplicate DAL SS SS10 0 0005 Lab Matrix Spike Soil Matrix ID Soil Weight Used (g) 34 m m im m em m m m m m eam H R IM 9 3 2 H m am m sm EBffi93!4SH m K6023m HHR1968BH am m M M M im eom m am m N M a m m srn rn m flB llS W S H K h irita H K 4255S K H B 1 f3 5 a iH IH 1 3 S 5 M m m msBssa^i m m m s rn m hm sm sm m m ssm w m B K 3K 49m H & 2 6 3 2 5 H B m ta ssim m ^ H 1 F 3 9 3 .7 ^H Mumw402iimm 1.0683 1.2359 1.1055 1.6665 1.3811 1.3100 1.5722 1.7359 1.8415 1.0491 1.3354 1.1483 1.0287 1.1133 1.0559 1.4305 1.3816 1.2858 1.4217 1.6350 1.5553 1.4228 1.4283 1.3513 1.3901 1.3273 1.2679 1.6793 1.4735 1.4360 1.4857 1.3636 1.4069 1.4755 1.4705 1.5459 1.6689 1.6383 1.7717 Printed 3/14/2011 3M Study GLP10-01-02-15 Page 2 o f 4 Page 95 of 514 GLPlO-01-02-15 ETS-8-053 Soils Weighed 14-Mar-2011 Sample ID Sample Description 1 GLP10-01-01-15-050 GLP10-01-01-15-050 Dud GLP10-01-01-15-050 LMS GLP10-01-01-15-051 GLP10-01-01-15-051 Dud GLP10-01-01-15-051 LMS GLP10-01-01-15-052 GLP10-01-01-15-052 Dud GLP10-01-01-15-052 LMS GLP10-01-01-15-053 GLP10-01-01-15-053 Dud GLP10-01-01-15-053 LMS GLP10-01 -01-15-054 GLP10-01-01-15-054 Dud GLP10-01-01-15-054 LMS GLP10-01-01-15-055 GLP10-01-01-15-055 Dud GLP10-01-01-15-055 LMS GLP10-01-01-15-056 GLP10-01-01-15-056 Dud GLP10-01-01-15-056 LMS GLP10-01-01-15-057 GLP10-01-01-15-057 Dud GLP10-01-01-15-057 LMS GLP10-01-01-15-058 GLP10-01-01-15-058 Dud GLP10-01-01-15-058 LMS GLP10-01-01-15-059 GLP10-01-01-15-059 Dud GLP10-01-01-15-059 LMS GLP10-01-01-15-060 GLP10-01-01-15-060 Dud GLP10-01-01-15-060 LMS GLP10-01-01-15-061 GLP10-01-01-15-061 Dud GLP10-01-01-15-061 LMS GLP10-01-01-15-062 GLP10-01-01-15-062 Dud GLP10-01-01-15-062 LMS GLP10-01-01-15-063 GLP10-01-01-15-063 Dud GLP10-01-01-15-063 LMS GLP10-01-01-15-064 GLP10-01-01-15-064 Dud GLP10-01 -01 -15-064 LMS GLP10-01-01-15-065 GLP10-01 -01 -15-065 Dud GLP10-01-01-15-065 LMS GLP10-01-01-15-066 GLP10-01-01-15-066 Dud GLP10-01-01-15-066 LMS GLP10-01-01-15-067 GLP10-01-01-15-067 Dud GLP10-01-01-15-067 LMS GLP 10-01-01-15-068 GLP10-01-01-15-068 Dud GLP10-01-01-15-068 LMS GLP10-01-01-15-069 Dud GLP10-01-01-15-069 LMS GLP10-01-01-15-070 GLP10-01-01-15-070 Dud GLP10-01-01-15-070 LMS GLP10-01-01-15-071 GLP10-01-01-15-071 Dud GLP10-01-01-15-071 LMS GLP10-01-01-15-072 GLP10-01-01-15-072 Dud GLP10-01-01-15-072 LMS 2 DAL SS SS10 DB 0005 DAL SS SS10 DB 0005 Lab Duplicate DAL SS SS10 DB 0005 Lab Matrix Spike DAL SS SS10 0 0015 DAL SS SS10 0 0015 Lab Duplicate DAL SS SS10 0 0015 Lab Matrix Spike DAL SD SD20 0 0000 DAL SD SD20 0 0000 Lab Duplicate DAL SD SD20 0 0000 Lab Matrix Spike DAL SD SD20 0 0005 DAL SD SD20 0 0005 Lab Duplicate DAL SD SD20 0 0005 Lab Matrix Spike DAL SD SD20 0 0015 DAL SD SD20 0 0015 Lab Duplicate DAL SD SD20 0 0015 Lab Matrix Spike DAL SD SD23 0 0000 DAL SD SD23 0 0000 Lab Duplicate DAL SD SD23 0 0000 Lab Matrix Spike DAL SD SD23 0 0005 DAL SD SD23 0 0005 Lab Duplicate DAL SD SD23 0 0005 Lab Matrix Spike DAL SD SD23 0 0015 DAL SD SD23 0 0015 Lab Duplicate DAL SD SD23 0 0015 Lab Matrix Spike DAL SS SS28 0 0000 DAL SS SS28 0 0000 Lab Duplicate DAL SS SS28 0 0000 Lab Matrix Spike DAL SS SS28 0 0005 DAL SS SS28 0 0005 Lab Duplicate DAL SS SS28 0 0005 Lab Matrix Spike DAL SS SS28 DB 0005 DAL SS SS28 DB 0005 Lab Duplicate DAL SS SS28 DB 0005 Lab Matrix Spike DAL SS SS28 0 0015 DAL SS SS28 0 0015 Lab Duplicate DAL SS SS28 0 0015 Lab Matrix Spike DAL SS SS27 0 0000 DAL SS SS27 0 0000 Lab Duplicate DAL SS SS27 0 0000 Lab Matrix Spike DAL SS SS27 0 0005 DAL SS SS27 0 0005 Lab Duplicate DAL SS SS27 0 0005 Lab Matrix Spike DAL SS SS27 0 0015 DAL SS SS27 0 0015 Lab Duplicate DAL SS SS27 0 0015 Lab Matrix Spike DAL SS SS22 0 0000 DAL SS SS22 0 0000 Lab Duplicate DAL SS SS22 0 0000 Lab Matrix Spike DAL SS SS22 0 0005 DAL SS SS22 0 0005 Lab Duplicate DAL SS SS22 0 0005 Lab Matrix Spike DAL SS SS22 DB 0005 DAL SS SS22 DB 0005 Lab Duplicate DAL SS SS22 DB 0005 Lab Matrix Spike DAL SS SS22 0 0015 DAL SS SS22 0 0015 Lab Duplicate DAL SS SS22 0 0015 Lab Matrix Spike U M L O O O O ^ 1 U UUUU DAL SS SS21 0 0000 Lab Duplicate DAL SS SS21 0 0000 Lab Matrix Spike DAL SS SS21 0 0005 DAL SS SS21 0 0005 Lab Duplicate DAL SS SS21 0 0005 Lab Matrix Spike DAL SS SS21 0 0015 DAL SS SS21 0 0015 Lab Duplicate DAL SS SS21 0 0015 Lab Matrix Spike DAL SD SD18 0 0000 DAL SD SD18 0 0000 Lab Duplicate DAL SD SD18 0 0000 Lab Matrix Spike Soil Matrix ID Soil Weight Used (g) 34 1.8480 1.5647 1.8236 2.3117 2.3619 2.2142 1.5251 1.5534 1.5162 1.2051 1.2705 1.4174 1.5316 1.4619 1.5515 1.6304 1.8054 1.5886 1.3277 1.4115 1.1674 1.3684 1.4116 1.3105 1.0441 1.1800 1.5726 1.0451 1.1338 1.1206 1.5755 1.4069 1.3963 1.3283 1.3133 1.3205 1.0337 1.1024 1.3121 1.3914 1.2129 1.3036 1.2317 1.0243 1.2141 1.1009 1.0535 1.1390 1.3700 1.3156 1.3506 1.5326 1.2590 1.5503 1.4807 1.5275 1.6011 m m a a rn g m WBBBUBBKi HM HHH H H I EBSBBKB f iilf f i H nan H H Printed 3/14/2011 3M Study GLP10-01-02-15 Page 3 o f 4 Page 96 of 514 GLPlO-01-02-15 ETS-8-053 Soils Weighed 14-Mar-2011 Sample ID Sample Description 1 GLP10-01-01-15-073 GLP10-01-01-15-073 DUO GLP10-01-01-15-073 LMS GLP10-01-01-15-074 GLP10-01-01-15-074 Dup GLP10-01-01-15-074 LMS GLP10-01-01-15-075 GLP10-01-01-15-075 Dup GLP10-01-01-15-075 LMS GLP10-01-01-15-076 GLP10-01-01-15-076 Dup GLP10-01-01-15-076 LMS GLP10-01-01-15-077 GLP10-01-01-15-077 Dup GLP10-01-01-15-077 LMS GLP10-01-01-15-079 GLP10-01-01-15-079 Dup GLP10-01-01-15-079 LMS GLP10-01-01-15-080 GLP10-01-01-15-080 Dup GLP10-01-01-15-080 LMS GLP10-01-01-15-081 GLP10-01-01-15-081 Dup GLP 10-01-01-15-082 GLP10-01-01-15-082 LMS GLP10-01-01-15-083 GLP10-01-01-15-083 Dup GLP10-01-01-15-083 LMS GLP10-01 -01 -15-084 GLP10-01-01-15-084 Dup GLP10-01-01-15-084 LMS GLP10-01-01-15-085 GLP10-01-01-15-085 Dup GLP10-01-01-15-085 LMS GLP10-01-01-15-086 GLP10-01-01-15-086 Dup GLP10-01-01-15-086 LMS GLP 10-01-01-15-087 GLP10-01-01-15-087 Dup GLP10-01-01 -15-087 LMS GLP10-01-01-15-088 GLP10-01-01-15-088 Dup GLP10-01-01-15-088 LMS GLP10-01-01-15-089 GLP10-01-01-15-089 Dup GLP10-01-01-15-089 LMS GLP10-01-01-15-090 GLP10-01-01-15-090 Dup GLP10-01-01-15-090 LMS GLP10-01-01-15-091 2 DAL SD SD18 0 0005 DAL SD SD18 0 0005 Lab Duplicate DAL SD SD18 0 0005 Lab Matrix Spike DAL SD SD18 0 0015 DAL SD SD18 0 0015 Lab Duplicate DAL SD SD18 0 0015 Lab Matrix Spike DAL SD SD19 0 0000 DAL SD SD19 0 0000 Lab Duplicate DAL SD SD19 0 0000 Lab Matrix Spike DAL SD SD19 0 0005 DAL SD SD19 0 0005 Lab Duplicate DAL SD SD19 0 0005 Lab Matrix Spike DAL SD SD19 0 0015 DAL SD SD19 0 0015 Lab Duplicate DAL SD SD19 0 0015 Lab Matrix Spike DAL SS SS26 0 0000 DAL SS SS26 0 0000 Lab Duplicate DAL SS SS26 0 0000 Lab Matrix Spike DAL SS SS26 DB 0000 DAL SS SS26 DB 0000 Lab Duplicate DAL SS SS26 DB 0000 Lab Matrix Spike DAL SS SS26 0 0005 DAL SS SS26 0 0005 Lab Duplicate L //A L O O O O ^ U U U U U J L d U IVIcIll IA O p iA t? DAL SS SS26 0 0015 U n L u o o O fc v U UU 1J L a U U u u lIv ctL c DAL SS SS26 0 0015 Lab Matrix Spike DAL SS Trip2 0 0000 DAL SS Trip2 0 0000 Lab Duplicate DAL SS Trip2 0 0000 Lab Matrix Spike DAL SS SS12 0 0015 DAL SS SS12 0 0015 Lab Duplicate DAL SS SS12 0 0015 Lab Matrix Spike DAL SS SS19 0 0015 DAL SS SS19 0 0015 Lab Duplicate DAL SS SS19 0 0015 Lab Matrix Spike DAL SSSS20 0 0015 DAL SS SS20 0 0015 Lab Duplicate DAL SS SS20 0 0015 Lab Matrix Spike DAL SS SS14 0 0015 DAL SS SS14 0 0015 Lab Duplicate DAL SS SS14 0 0015 Lab Matrix Spike DAL SS SS17 0 0015 DAL SS SS17 0 0015 Lab Duplicate DAL SS SS17 0 0015 Lab Matrix Spike DAL SS SS13 0 0015 DAL SS SS13 0 0015 Lab Duplicate DAL SS SS13 0 0015 Lab Matrix Spike DAL SS SS15 0 0015 DAL SS SS15 0 0015 Lab Duplicate DAL SS SS15 0 0015 Lab Matrix Spike DAL SS SS18 0 0015 GLP10-01-01-15-091 LMS GLP10-01-01 -15-092 GLP10-01-01-15-092 Dup GLP10-01-01-15-092 LMS DAL SS SS18 0 0015 Lab Matrix Spike DAL SS SS11 0 0015 DAL SS SS11 0 0015 Lab Duplicate DAL SS SS11 0 0015 Lab Matrix Spike Note: Soils were weighed then stored in WR01 until extraction. Col 3 & 4: Q f H Balance ID: 900 ' Soil Matrix ID Soil Weight Used (g) 34 H B H IH nm nam HUSHBI BHH m H iwiMiniHiniiiiffi ....... ... HHHUH & 3R H B 1H K aB H ffiH H i nnm H ! - 1-- HH ........................ mil H H H S B fli aKaMTM aTM TM S i H H H H ffii lllBMIllHBMIrt HI flUilHIiilil-- HI UHHHH H H RH I H BHBi un g h lilllMiPiM-- in HHHi mmmmmam BBHM HHHI BB1 m H nu mw-- a m g i m SH H l nm nn rnmmmmm B-- s m ia B M BB --B B Pr,n3M S u d y G tp i0 -0 1 -0 2 -1 5 Page 4 o f 4 Page 97 of 514 GLPlO-01-02-15 ETS-8-053 Soils Weighed 15-Mar-2011 Sample ID Sample Description 1 GLP10-01-01-15-001 GLP10-01-01-15-001 Dup GLP10-01-01-15-001 LMS GLP10-01-01-15-002 GLP10-01-01-15-002 Dup GLP10-01-01-15-002 LMS GLP10-01-01-15-003 GLP10-01-01-15-003 Dud GLP10-01-01-15-003 LMS GLP10-01-01-15-004 GLP10-01-01-15-004 Dud GLP10-01-01-15-004 LMS GLP10-01-01-15-005 GLP10-01-01-15-005 Dud GLP10-01-01-15-005 LMS GLP10-01-01-15-006 GLP10-01-01-15-006 Dup GLP10-01-01-15-006 LMS GLP10-01-01-15-007 GLP10-01-01-15-007 Dud GLP10-01-01-15-007 LMS GLP10-01-01-15-008 GLP10-01-01-15-008 Dup GLP10-01 -01-15-008 LMS GLP10-01-01-15-009 GLP10-01-01-15-009 Dud GLP10-01-01-15-009 LMS GLP10-01-01-15-010 GLP10-01-01-15-010 Dud GLP10-01-01-15-010 LMS GLP10-01-01-15-011 GLP10-01-01-15-011 Dup GLP10-01-01-15-011 LMS GLP10-01-01-15-012 GLP10-01-01-15-012 Dup GLP10-01-01-15-012 LMS GLP10-01-01-15-014 GLP10-01-01-15-014 Dud GLP10-01-01-15-014 LMS GLP10-01-01-15-015 GLP10-01-01-15-015 Dud GLP10-01-01-15-015 LMS GLP10-01-01-15-016 GLP10-01-01-15-016 Dup GLP10-01-01-15-016 LMS GLP10-01-01-15-018 GLP10-01-01-15-018 Dud GLP10-01-01-15-018 LMS GLP10-01-01-15-020 GLP10-01-01-15-020 Dud GLP10-01-01-15-020 LMS GLP10-01-01-15-021 GLP10-01-01-15-021 Dud GLP10-01-01-15-021 LMS GLP10-01-01-15-022 GLP10-01-01-15-022 Dup GLP10-01-01-15-022 LMS GLP10-01-01-15-023 GLP10-01-01-15-023 Dud GLP10-01-01-15-023 LMS GLP10-01-01-15-024 GLP10-01-01-15-024 Dud GLP10-01-01-15-024 LMS GLP10-01-01-15-025 GLP10-01-01-15-025 Dud GLP10-01-01-15-025 LMS GLP10-01-01-15-026 GLP10-01-01-15-026 Dud GLP10-01-01-15-026 LMS 2 DAL SS SS Triol 0 0000 DAL SS SS Tripl 0 0000 Lab Duplicate DAL SS SS Triol 0 0000 Lab Matrix Spike DAL SS SS12 0 0000 DAL SS SS12 0 0000 Lab Duplicate DAL SS SS12 0 0000 Lab Matrix Spike DAL SS SS12 0 0005 DAL SS SS12 0 0005 Lab Duplicate DAL SS SS12 0 0005 Lab Matrix Spike DAL SS SS13 0 0000 DAL SS SS13 0 0000 Lab Duplicate DAL SS SS13 0 0000 Lab Matrix Spike DAL SS SS16 0 0000 DAL SS SS16 0 0000 Lab Duplicate DAL SS SS16 0 0000 Lab Matrix Spike DAL SS SS16 DB 0000 DAL SS SS16 DB 0000 Lab Duplicate DAL SS SS16 DB 0000 Lab Matrix Spike DAL SS SS11 0 0000 DAL SS SS11 0 0000 Lab Duplicate DAL SS SS11 0 0000 Lab Matrix Spike DAL SS SS11 0 0005 DAL SS SS11 0 0005 Lab Duplicate DAL SS SS11 0 0005 Lab Matrix Spike DAL SS SS20 0 0000 DAL SS SS20 0 0000 Lab Duplicate DAL SS SS20 0 0000 Lab Matrix Spike DAL SS SS20 DB 0000 DAL SS SS20 DB 0000 Lab Duplicate DAL SS SS20 DB 0000 Lab Matrix Spike DAL SS SS19 0 0000 DAL SS SS19 0 0000 Lab Duplicate DAL SS SS19 0 0000 Lab Matrix Spike DAL SS SS19 0 0005 DAL SS SS19 0 0005 Lab Duplicate DAL SS SS19 0 0005 Lab Matrix Spike DAL SS SS15 0 0000 DAL SS SS15 0 0000 Lab Duplicate DAL SS SS15 0 0000 Lab Matrix Spike DAL SS SS17 0 0000 DAL SS SS17 0 0000 Lab Duplicate DAL SS SS17 0 0000 Lab Matrix Spike DAL SS SS14 0 0000 DAL SS SS14 0 0000 Lab Duplicate DAL SS SS14 0 0000 Lab Matrix Spike DAL SS SS18 0 0000 DAL SS SS18 0 0000 Lab Duplicate DAL SS SS18 0 0000 Lab Matrix Spike DAL SS SS10 0 0000 DAL SS SS10 0 0000 Lab Duplicate DAL SS SS10 0 0000 Lab Matrix Spike DAL SS SS30 0 0000 DAL SS SS30 0 0000 Lab Duplicate DAL SS SS30 0 0000 Lab Matrix Spike DAL SS SS30 0 0005 DAL SS SS30 0 0005 Lab Duplicate DAL SS SS30 0 0005 Lab Matrix Spike DAL SS SS30 0 0015 DAL SS SS30 0 0015 Lab Duplicate DAL SS SS30 0 0015 Lab Matrix Spike DAL SS SS25 0 0000 DAL SS SS25 0 0000 Lab Duplicate DAL SS SS25 0 0000 Lab Matrix Spike DAL SS SS25 0 0005 DAL SS SS25 0 0005 Lab Duplicate DAL SS SS25 0 0005 Lab Matrix Spike DAL SS SS25 0 0015 DAL SS SS25 0 0015 Lab Duplicate DAL SS SS25 0 0015 Lab Matrix Spike Soil Matrix ID Soil Weight Used (g) 34 1.0969 1.1041 1,1639 2.1713 2.1685 2.2792 1.7306 1.6369 1.8023 1.4718 1.5972 1.4002 1.4346 1.2958 1.4129 1.4828 1.5002 1.5622 1.5738 1.5306 1.2980 1.8322 1.6269 1.7266 1.4855 1.3023 1.5702 1.5863 1.5513 1.5200 1.8169 1.7215 T.9596 1.3867 1.3293 1.2357 1.3064 1.1784 1.4972 1.3188 1.3474 1.3190 1.4883 1.5932 1.3255 1.5709 1.8341 1.7257 1.4118 1.1844 1.6224 0.9862 1.0133 1.1617 1.1939 1.0273 1.1540 1.1015 1.0546 1.0244 2.1757 2.3313 2.5810 1.2722 1.3291 1.3854 1.7182 1.5521 1.4726 Printed 3/15/2011 3M Study GLP10-01-02-15 Page 1 o f 5 Page 98 of 514 GLPlO-01-02-15 ETS-8-053 Soils Weighed 15-Mar-2011 Sample ID Sample Description 1 GLP10-01-01-15-027 GLP10-01-01-15-027 Dup GLP10-01-01-15-027 LMS GLP10-01-01-15-028 GLP10-01-01-15-028 Dup GLP10-01-01-15-028 LMS GLP10-01-01-15-029 GLP10-01 -01 -15-029 Dup GLP10-01-01-15-029 LMS GLP10-01-01-15-030 GLP10-01-01-15-030 Dup GLP10-01-01-15-030 LMS GLP10-01-01-15-031 GLP10-01-01-15-031 Dup GLP10-01-01-15-031 LMS GLP10-01-01-15-032 GLP10-01-01-15-032 Dup GLP10-01-01-15-032 LMS GLP10-01-01-15-033 GLP10-01-01-15-033 Dup GLP10-01-01-15-033 LMS GLP10-01-01-15-034 GLP10-01-01-15-034 Dup GLP10-01-01-15-034 LMS GLP10-01-01-15-035 GLP10-01 -01-15-035 Dup GLP10-01-01-15-035 LMS GLP10-01-01-15-036 GLP10-01-01-15-036 Dup GLP10-01-01-15-036 LMS GLP10-01-01-15-037 GLP10-01-01-15-037 Dup GLP10-01-01-15-037 LMS GLP10-01-01-15-038 GLP10-01-01-15-038 Dup GLP10-01-01-15-038 LMS GLP10-01-01-15-039 GLP10-01-01-15-039 Dup GLP10-01-01-15-039 LMS GLP10-01-01-15-040 GLP10-01-01-15-040 Dup GLP10-01-01-15-040 LMS GLP10-01-01-15-041 GLP10-01-01-15-041 Dup GLP10-01-01-15-041 LMS GLP10-01-01-15-042 GLP10-01-01-15-042 Dup GLP10-01-01-15-042 LMS GLP10-01-01-15-043 GLP10-01 -01-15-043 Dup GLP10-01-01-15-043 LMS GLP10-01-01-15-044 GLP10-01-01-15-044 Dup GLP10-01-01-15-044 LMS GLP10-01-01-15-045 GLP10-01-01-15-045 Dup GLP10-01-01-15-045 LMS GLP10-01-01-15-046 GLP10-01-01-15-046 Dup GLP10-01-01-15-046 LMS GLP10-01-01-15-047 GLP10-01 -01 -15-047 Dup GLP10-01-01-15-047 LMS GLP10-01-01-15-048 GLP10-01-01-15-048 Dup GLP10-01-01-15-048 LMS GLP10-01-01-15-049 GLP10-01-01 -15-049 Dup GLP10-01-01-15-049 LMS 2 DAL SD SD22 0 0000 DAL SD SD22 0 0000 Lab Duplicate DAL SD SD22 0 0000 Lab Matrix Spike DAL SD SD22 0 0005 DAL SD SD22 0 0005 Lab Duplicate DAL SD SD22 0 0005 Lab Matrix Spike DAL SD SD22 DB 0005 DAL SD SD22 DB 0005 Lab Duplicate DAL SD SD22 DB 0005 Lab Matrix Spike DAL SD SD22 0 0015 DAL SD SD22 0 0015 Lab Duplicate DAL SD SD22 0 0015 Lab Matrix Spike DAL SD SD21 0 0000 DAL SD SD21 0 0000 Lab Duplicate DAL SD SD21 0 0000 Lab Matrix Spike DAL SD SD21 0 0005 DAL SD SD21 0 0005 Lab Duplicate DAL SD SD21 0 0005 Lab Matrix Spike DAL SD SD21 0 0015 DAL SD SD21 0 0015 Lab Duplicate DAL SD SD21 0 0015 Lab Matrix Spike DAL SS SS24 0 0000 DAL SS SS24 0 0000 Lab Duplicate DAL SS SS24 0 0000 Lab Matrix Spike DAL SS SS24 0 0005 DAL SS SS24 0 0005 Lab Duplicate DAL SS SS24 0 0005 Lab Matrix Spike DAL SS SS24 0 0015 DAL SS SS24 0 0015 Lab Duplicate DAL SS SS24 0 0015 Lab Matrix Spike DAL SS SS29 0 0000 DAL SS SS29 0 0000 Lab Duplicate DAL SS SS29 0 0000 Lab Matrix Spike DAL SS SS29 0 0005 DAL SS SS29 0 0005 Lab Duplicate DAL SS SS29 0 0005 Lab Matrix Spike DAL SS SS29 0 0015 DAL SS SS29 0 0015 Lab Duplicate DAL SS SS29 0 0015 Lab Matrix Spike DAL SS SS20 0 0005 DAL SS SS20 0 0005 Lab Duplicate DAL SS SS20 0 0005 Lab Matrix Spike DAL SS SS13 0 0005 DAL SS SS13 0 0005 Lab Duplicate DAL SS SS13 0 0005 Lab Matrix Spike DAL SS SS13 DB 0005 DAL SS SS13 DB 0005 Lab Duplicate DAL SS SS13 DB 0005 Lab Matrix Spike DAL SS SS15 0 0005 DAL SS SS15 0 0005 Lab Duplicate DAL SS SS15 0 0005 Lab Matrix Spike DAL SS SS17 0 0005 DAL SS SS17 0 0005 Lab Duplicate DAL SS SS17 0 0005 Lab Matrix Spike DAL SS SS14 0 0005 DAL SS SS14 0 0005 Lab Duplicate DAL SS SS14 0 0005 Lab Matrix Spike DAL SS S S I8 0 0005 DAL SS SS18 0 0005 Lab Duplicate DAL SS SS18 0 0005 Lab Matrix Spike DAL SS SS16 0 0005 DAL SS SS16 0 0005 Lab Duplicate DAL SS SS16 0 0005 Lab Matrix Spike DAL SSSS16 0 0015 DAL SS SS16 0 0015 Lab Duplicate DAL SS SS16 0 0015 Lab Matrix Spike DAL SS SS10 0 0005 DAL SS SS10 0 0005 Lab Duplicate DAL SS SS10 0 0005 Lab Matrix Spike Soil Matrix ID Soil Weight Used (g) 34 1.2988 1.3968 1.6349 1 7902 1.9765 1.6704 1.9346 1.9990 1.6023 1.1968 1.1321 1.1141 1.3499 1.7710 1.7567 1.5533 1.4631 1.4255 1.3571 1.4063 1.4551 1.2169 1.2909 1.3334 2.8500 3.1143 2.6325 1.5557 1.3947 1.4021 1.0683 1.2359 1.1055 1.6665 1.3811 1.3100 1.5722 1.7359 1.8415 1.0491 1.3354 1.1483 1.0287 1.1133 1.0559 1.4305 1.3816 1.2858 1.4217 1.6350 1.5553 1.4228 1.4283 1.3513 1.3901 1.3273 1.2679 1.6793 1.4735 1.4360 1.4857 1.3636 1.4069 1.4755 1,4705 1.5459 1.6689 1.6383 1.7717 Printed 3/15/2011 3M Study GLP10-01-02-15 Page 2 o f 5 Page 99 of 514 GLPlO-01-02-15 ETS-8-053 Soils Weighed 15-Mar-2011 Sample ID 1 GLP10-01-01-15-050 GLP10-01-01-15-050 Dup GLP10-01-01-15-050 LMS GLP10-01-01-15-051 GLP10-01-01-15-051 Dup GLP10-01-01-15-051 LMS GLP10-01-01-15-052 GLP10-01-01-15-052 Dup GLP10-01-01-15-052 LMS GLP10-01-01-15-053 GLP10-01-01-15-053 Dup GLP10-01-01-15-053 LMS GLP10-01-01-15-054 GLP10-01-01-15-054 Dup GLP10-01-01-15-054 LMS GLP10-01-01-15-055 GLP10-01 -01-15-055 Dup GLP10-01-01-15-055 LMS GLP 10-01-01-15-056 GLP10-01-01-15-056 Dup GLP10-01-01-15-056 LMS GLP10-01-01-15-057 GLP10-01-01-15-057 Dup GLP10-01-01-15-057 LMS GLP10-01-01-15-058 GLP10-01-01-15-058 Dup GLP10-01-01-15-058 LMS GLP10-01-01-15-059 GLP10-01-01-15-059 Dup GLP10-01-01-15-059 LMS GLP10-01-01-15-060 GLP10-01-01-15-060 Dup GLP10-01-01-15-060 LMS GLP10-01-01-15-061 GLP10-01-01-15-061 Dup GLP10-01-01-15-061 LMS GLP10-01-01-15-062 GLP10-01-01-15-062 Dup GLP10-01-01-15-062 LMS GLP10-01-01-15-063 GLP10-01-01-15-063 Dup GLP10-01-01-15-063 LMS GLP10-01-01-15-064 GLP10-01-01-15-064 Dup GLP10-01-01-15-064 LMS GLP10-01-01-15-065 GLP10-01-01-15-065 Dup GLP10-01-01-15-065 LMS GLP10-01 -01-15-066 GLP10-01-01-15-066 Dup GLP10-01-01-15-066 LMS GLP 10-01-01-15-067 GLP10-01-01-15-067 Dup GLP10-01-01-15-067 LMS GLP10-01-01-15-068 GLP10-01-01-15-068 Dup GLP10-01-01-15-068 LMS GLP10-01-01-15-069 GLP10-01-01-15-069 Dup GLP10-01-01-15-069 LMS GLP10-01-01-15-070 GLP10-01-01-15-070 Dup GLP10-01-01-15-070 LMS GLP10-01-01-15-071 GLP10-01-01-15-071 Dup GLP10-01-01-15-071 LMS GLP10-01-01-15-072 GLP10-01 -01-15-072 Dup GLP10-01-01-15-072 LMS Sample Description Soil Matrix ID Soil Weight Used (g) 2 DAL SS SS10DB 0005 DAL SS SS10 DB 0005 Lab Duplicate DAL SS SS10 DB 0005 Lab Matrix Spike DAL SS SS10 0 0015 DAL SS SS10 0 0015 Lab Duplicate DAL SS SS10 0 0015 Lab Matrix Spike DAL SD SD20 0 0000 DAL SD SD20 0 0000 Lab Duplicate DAL SD SD20 0 0000 Lab Matrix Spike DAL SD SD20 0 0005 DAL SD SD20 0 0005 Lab Duplicate DAL SD SD20 0 0005 Lab Malrix Spike DAL SD SD20 0 0015 DAL SD SD20 0 0015 Lab Duplicate DAL SD SD20 0 0015 Lab Matrix Spike DAL SD SD23 0 0000 DAL SD SD23 0 0000 Lab Duplicate DAL SD SD23 0 0000 Lab Matrix Spike DAL SD SD23 0 0005 DAL SD SD23 0 0005 Lab Duplicate DAL SD SD23 0 0005 Lab Matrix Spike DAL SD SD23 0 0015 DAL SD SD23 0 0015 Lab Duplicate DAL SD SD23 0 0015 Lab Matrix Spike DAL SS SS28 0 0000 DAL SS SS28 0 0000 Lab Duplicate DAL SS SS28 0 0000 Lab Matrix Spike DAL SS SS28 0 0005 DAL SS SS28 0 0005 Lab Duplicate DAL SS SS28 0 0005 Lab Matrix Spike DAL SS SS28 DB 0005 DAL SS SS28 DB 0005 Lab Duplicate DAL SS SS28 DB 0005 Lab Matrix Spike DAL SS SS28 0 0015 DAL SS SS28 0 0015 Lab Duplicate DAL SS SS28 0 0015 Lab Matrix Spike DAL SS SS27 0 0000 DAL SS SS27 0 0000 Lab Duplicate DAL SS SS27 0 0000 Lab Matrix Spike DAL SS SS27 0 0005 DAL SS SS27 0 0005 Lab Duplicate DAL SS SS27 0 0005 Lab Matrix Spike DAL SS SS27 0 0015 DAL SS SS27 0 0015 Lab Duplicate DAL SS SS27 0 0015 Lab Matrix Spike DAL SS SS22 0 0000 DAL SS SS22 0 0000 Lab Duplicate DAL SS SS22 0 0000 Lab Matrix Spike DAL SS SS22 0 0005 DAL SS SS22 0 0005 Lab Duplicate DAL SS SS22 0 0005 Lab Matrix Spike DAL SS SS22 DB 0005 DAL SS SS22 DB 0005 Lab Duplicate DAL SS SS22 DB 0005 Lab Matrix Spike DAL SS SS22 0 0015 DAL SS SS22 0 0015 Lab Duplicate DAL SS SS22 0 0015 Lab Matrix Spike DAL SS SS21 0 0000 DAL SS SS21 0 0000 Lab Duplicate DAL SS SS21 0 0000 Lab Matrix Spike DAL SS SS21 0 0005 DAL SS SS21 0 0005 Lab Duplicate DAL SS SS21 0 0005 Lab Matrix Spike DAL SS SS21 0 0015 DAL SS SS21 0 0015 Lab Duplicate DAL SS SS21 0 0015 Lab Matrix Spike DAL SD SD18 0 0000 DAL SD SD18 0 0000 Lab Duplicate DAL SD SD18 0 0000 Lab Matrix Spike . 3 4 1.8480 1.5647 1.8236 2.3117 2.3619 2.2142 1.5251 1.5534 1.5162 1.2051 1.2705 1.4174 1.5316 1.4619 1.5515 1.6304 1.8054 1.5886 1.3277 1.4115 1.1674 1.3684 1.4116 1.3105 1.0441 1.1800 1.5726 1.0451 1.1338 1.1206 1.5755 1.4069 1.3963 1.3283 1.3133 1.3205 1.0337 1.1024 1.3121 1.3914 1.2129 1.3036 1.2317 1.0243 1.2141 1.1009 1.0535 1.1390 1.3700 1.3156 1.3506 1.5326 1.2590 1.5503 1.4807 1.5275 1.6011 1.0504 1.0050 0.9628 1.0656 0.9871 1.0108 1.0302 1.4321 1.1910 1.2936 1.2975 1.5367 Printed 3/15/2011 3M Study GLP10-01-02-15 Page 3 o f 5 Page 100 of 514 GLPlO-01-02-15 ETS-8-053 Soils Weighed 15-Mar-2011 Sample ID Sample Description Soil Matrix ID Soil Weight Used (g) 1 2 34 GLP10-01-01-15-073 DAL SD SD18 0 0005 1.7040 GLP10-01-01-15-073 Duo DAL SD SD18 0 0005 Lab Duplicate 1.4038 GLP10-01-01-15-073 LMS DAL SD SD18 0 0005 Lab Matrix SDike 1.7588 GLP10-01-01-15-074 DAL SD SD18 0 0015 1.1855 GLP10-01-01-15-074 Duo DAL SD SD18 0 0015 Lab Duplicate 1.2552 GLP10-01-01-15-074 LMS DAL SD SD18 0 0015 Lab Matrix Spike 1.2823 GLP10-01-01-15-075 DAL SD SD19 0 0000 1.6058 GLP10-01-01-15-075 Duo DAL SD SD19 0 0000 Lab Duplicate 1.5361 GLP10-01-01-15-075 LMS DAL SD SD19 0 0000 Lab Matrix Spike 2.0090 GLP10-01-01-15-076 DAL SD SD19 0 0005 1.1033 GLP10-01-01-15-076 Dud DAL SD SD19 0 0005 Lab Duplicate 1.1352 GLP10-01-01-15-076 LMS DAL SD SD19 0 0005 Lab Matrix Spike 1.3660 GLP10-01-01-15-077 DAL SD SD19 0 0015 1.6597 GLP10-01-01-15-077 Dup DAL SD SD19 0 0015 Lab Duplicate 1.2242 GLP10-01 -01-15-077 LMS DAL SD SD19 0 0015 Lab Matrix Spike 1.2317 GLP10-01-01-15-079 DAL SS SS26 0 0000 1.3164 GLP10-01-01 -15-079 Dud DAL SS SS26 0 0000 Lab Duplicate 1.4204 GLP10-01-01-15-079 LMS DAL SS SS26 0 0000 Lab Matrix Spike 1.3365 GLP10-01-01-15-080 DAL SS SS26 DB 0000 1.4661 GLP10-01-01-15-080 Dud DAL SS SS26 DB 0000 Lab Duplicate 1.4776 GLP10-01-01-15-080 LMS DAL SS SS26 DB 0000 Lab Matrix Spike 1.6660 GLP10-01-01-15-081 DAL SS SS26 0 0005 1.5471 GLP10-01-01-15-081 Dud DAL SS SS26 0 0005 Lab Duplicate 1.3000 GLP10-01 -01-15-081 LMS DAL SS SS26 0 0005 Lab Matrix Spike 1.3835 GLP10-01-01-15-082 DAL SS SS26 0 0015 1.0482 GLP10-01 -01-15-082 Dud DAL SS SS26 0 0015 Lab Duplicate 1.2763 GLP10-01-01-15-082 LMS DAL SS SS26 0 0015 Lab Matrix Spike 1.2281 GLP10-01-01-15-083 DAL SS Trip2 0 0000 1.1433 GLP10-01-01-15-083 Dup DAL SS Trip2 0 0000 Lab Duplicate 1.2359 GLP10-01-01-15-083 LMS DAL SS Trip2 0 0000 Lab Matrix Spike 1.2206 GLP10-01-01-15-084 DAL SS SS12 0 0015 1.0000 GLP10-01-01-15-084 Dud DAL SS SS12 0 0015 Lab Duplicate 1.1541 GLP10-01-01-15-084 LMS DAL SS SS12 0 0015 Lab Matrix Spike 1.3665 GLP10-01-01-15-085 DAL SS SS19 0 0015 1.2878 GLP10-01-01-15-085 Dud DAL SS SS19 0 0015 Lab Duplicate 1.0079 GLP10-01-01-15-085 LMS DAL SS SS19 0 0015 Lab Matrix Spike 1.2791 GLP10-01 -01 -15-086 DAL SS SS20 0 0015 1.0848 GLP10-01-01-15-086 Dud DAL SS SS20 0 0015 Lab Duplicate 1.2886 GLP10-01-01-15-086 LMS DAL SS SS20 0 0015 Lab Matrix Spike 1.2103 GLP10-01-01-15-087 DAL SS SS14 0 0015 1.0114 GLP10-01-01-15-087 Dud DAL SS SS14 0 0015 Lab Duplicate 1.3074 GLP10-01-01-15-087 LMS DAL SS SS14 0 0015 Lab Matrix Spike 1.0076 GLP10-01-01-15-088 DAL SS SS17 0 0015 1.2963 GLP10-01-01-15-088 Dud DAL SS SS17 0 0015 Lab Duplicate 1.1603 GLP10-01-01-15-088 LMS DAL SS SS17 0 0015 Lab Matrix Spike 1.0745 GLP10-01-01-15-089 DAL SS SS13 0 0015 0.9631 GLP10-01-01-15-089 Dup DAL SS SS13 0 0015 Lab Duplicate 0.9645 GLP10-01-01-15-089 LMS DAL SS SS13 0 0015 Lab Matrix Spike 0.9256 GLP10-01-01-15-090 DAL SS SS15 0 0015 0.9608 GLP10-01-01-15-090 DUD DAL SS SS15 0 0015 Lab Duplicate 1.0234 GLP10-01-01-15-090 LMS DAL SS SS15 0 0015 Lab Matrix Spike 1.1252 GLP10-01-01-15-091 DAL SS SS18 0 0015 1.2579 GLP10-01-01-15-091 DUP DAL SS SS18 0 0015 Lab Duplicate 1.4970 GLP10-01-01-15-091 LMS DAL SS SS18 0 0015 Lab Matrix Spike 1.2183 GLP10-01 -01-15-092 DAL SS SS11 0 0015 1.2248 GLP10-01-01-15-092 Dud DAL SS SS11 0 0015 Lab Duplicate 1.2785 GLP10-01-01-15-092 LMS DAL SS SS11 0 0015 Lab Matrix Spike 1.1254 EC-110316-01 0.2 ng Extracted Curve Point 10 010-125 1.0708 EC-110316-02 0.5 ng Extracted Curve Point 10 010-125 1.1734 EC-110316-03 0.75 ng Extracted Curve Point 10 010-125 1.0797 K EC-110316-04 EC-110316-05 1 ng Extracted Curve Point 2.5 ng Extracted Curve Point 10 010-125 10 010-125 1.0801 1.1632 EC-110316-06 5 ng Extracted Curve Point 10 010-125 1.1030 EC-110316-07 10 no Extracted Curve Point 10 010-125 1.1014 EC-110316-08 25 ng Extracted Curve Point 10 010-125 1.1755 EC-110316-09 50 ng Extracted Curve Point 10 010-125 1.0343 EC-110316-10 100 ng Extracted Curve Point 10 010-125 1.1260 EC-110316-11 200 ng Extracted Curve Point 10 010-125 1.0769 EC-110316-12 500 ng Extracted Curve Point 10 010-125 1.1055 Prinm 52y & P10-01-02-15 Page 4 o f 5 Page 101 of 514 GLPlO-01-02-15 ETS-8-053 Sample ID Sample Description 1 LCS-110316-01 LCS-110316-02 LCS-110316-03 LCS-110316-04 LCS-110316-05 LCS-110316-06 LCS-110316-07 LCS-110316-08 LCS-110316-09 MB-110316-01 MB-110316-02 MB-110316-03 MB-110316-04 MB-110316-05 MB-110316-06 MB-110316-07 MB-110316-08 MB-110316-09 MB-110316-10 MB-110316-11 MB-110316-12 2 3 ng LCS in TCR-842 3 ng LCS in TCR-842 3 ng LCS in TCR-842 30 ng LCS in TCR-842 30 ng LCS in TCR-842 30 ng LCS in TCR-842 300ng LCS in TCR-842 300ng LCS in TCR-842 300ng LCS in TCR-842 Method Blank w/o IS Method Blank w /o IS Method Blank w /o IS Method Blank w / IS Method Blank w / IS Method Blank w/IS Method Blank w/ IS for dilutions Method Blank w/ IS for dilutions Method Blank w/ IS for dilutions Method Blank w/ IS for dilutions Method Blank w/ IS for dilutions Method Blank w/ IS for dilutions Note: Soils were weighed then stored in WR01 until extraction. C0I3&4 Balance ID: 900 Soils Weighed 15-Mar-2011 Soil Matrix ID Soil Weight Used (g) 3 10 010-125 10 010-125 10 010-125 10 010-125 10 010-125 10 010-125 10 010-125 10 010-125 10 010-125 10 010-125 10 010-125 10 010-125 10 010-125 10 010-125 10 010-125 10 010-125 10 010-125 10 010-125 10 010-125 10 010-125 10 010-125 4 1.1813 1.1563 1.0979 1.0850 1.0062 1.0361 1.1289 1.1103 1.1581 1.1995 1.0392 1.0345 1.0638 1.1538 1.1096 5.2632 4.7673 4.8628 4.9413 5.1839 4.9042 Printed 3/15/2011 3M Study GLP10-01-02-15 Page 5 o f 5 Page 102 of 514 GLPlO-01-02-15 ETS-8-053 Sample ID Sample Description 1 GLP10-01-01-15-001 GLP10-01-01-15-001 Dup GLP10-01-01-15-001 LMS GLP10-01-01-15-002 GLP10-01-01-15-002 Dup GLP10-01-01-15-002 LMS GLP10-01-01-15-003 GLP10-01-01-15-003 Dup GLP10-01-01-15-003 LMS GLP10-01-01-15-004 GLP10-01-01-15-004 Dup GLP10-01-01-15-004 LMS GLP10-01-01-15-005 GLP10-01-01-15-005 Dup GLP10-01-01-15-005 LMS GLP10-01-01-15-006 GLP10-01-01-15-006 Dup GLP10-01-01-15-006 LMS GLP10-01-01-15-007 GLP10-01-01-15-007 Dup GLP10-01-01-15-007 LMS GLP10-01-01-15-008 GLP10-01-01-15-008 Dup GLP10-01-01-15-008 LMS GLP10-01-01-15-009 GLP10-01-01-15-009 Dup GLP10-01-01-15-009 LMS GLP10-01-01-15-010 GLP10-01-01-15-010 Dup GLP10-01-01-15-010 LMS GLP10-01-01-15-011 GLP10-01-01-15-011 Dup GLP10-01-01-15-011 LMS GLP10-01-01-15-012 GLP10-01-01-15-012 Dup GLP10-01-01-15-012 LMS GLP10-01-01-15-014 GLP10-01-01-15-014 Dup GLP10-01-01-15-014 LMS GLP10-01-01-15-015 GLP10-01-01-15-015 Dup GLP10-01-01-15-015 LMS GLP10-01-01-15-016 GLP10-01-01-15-016 Dup GLP10-01-01-15-016 LMS GLP10-01-01-15-018 GLP10-01-01-15-018 Dup GLP10-01-01-15-018 LMS GLP10-01-01-15-020 GLP10-01-01-15-020 Dup GLP10-01-01-15-020 LMS GLP10-01-01-15-021 GLP10-01-01-15-021 Dup GLP10-01-01-15-021 LMS GLP10-01-01-15-022 GLP10-01-01-15-022 Dup GLP10-01-01-15-022 LMS GLP10-01-01-15-023 GLP10-01-01-15-023 Dup GLP10-01-01-15-023 LMS GLP10-01-01-15-024 GLP10-01-01-15-024 Dup GLP10-01-01-15-024 LMS GLP10-01-01-15-025 GLP10-01-01-15-025 Dup GLP10-01-01-15-025 LMS GLP10-01-01-15-026 GLP10-01-01-15-026 Dup GLP10-01-01-15-026 LMS GLP10-01-01-15-027 GLP10-01-01-15-027 Dup GLP10-01-01-15-027 LMS GLP10-01-01-15-028 GLP10-01-01-15-028 Dup GLP10-01-01-15-028 LMS GLP10-01-01-15-029 GLP10-01-01-15-029 Dup GLP10-01-01-15-029 LMS GLP10-01-01-15-030 GLP10-01-01-15-030 Dup 2 DAL SS SS Tripl 0 0000 DAL SS SS Tripl 0 0000 Lab Duplicate DAL SS SS Tripl 0 0000 Lab Matrix Spike DAL SS SS12 0 0000 DAL SS SS12 0 0000 Lab Duplicate DAL SS SS12 0 0000 Lab Matrix Spike DAL SS SS12 0 0005 DAL SS SS12 0 0005 Lab Duplicate DAL SS SS12 0 0005 Lab Matrix Spike DAL SS SS13 0 0000 DAL SS SS13 0 0000 Lab Duplicate DAL SS SS13 0 0000 Lab Matrix Spike DAL SS SS16 0 0000 DAL SS SS16 0 0000 Lab Duplicate DAL SS SS16 0 0000 Lab Matrix Spike DAL SS SS16 DB 0000 DAL SS SS16 DB 0000 Lab Duplicate DAL SS SS16 DB 0000 Lab Matrix Spike DAL SS SS11 0 0000 DAL SS SS11 0 0000 Lab Duplicate DAL SS SS110 0000 Lab Matrix Spike DAL SS SS11 0 0005 DAL SS SS11 0 0005 Lab Duplicate DAL SS SS11 0 0005 Lab Matrix Spike DAL SS SS20 0 0000 DAL SS SS20 0 0000 Lab Duplicate DAL SS SS20 0 0000 Lab Matrix Spike DAL SS SS20 DB 0000 DAL SS SS20 DB 0000 Lab Duplicate DAL SS SS20 0B 0000 Lab Matrix Spike DAL SS SS19 0 0000 DAL SS SS19 0 0000 Lab Duplicate DAL SS SS19 0 0000 Lab Matrix Spike DAL SS SS19 0 0005 DAL SS SS19 0 0005 Lab Duplicate DAL SS SS19 0 0005 Lab Matrix Spike DAL SS SS15 0 0000 DAL SS SS15 0 0000 Lab Duplicate DAL SS SS15 0 0000 Lab Matrix Spike DAL SS SS17 0 0000 DAL SS SS17 0 0000 Lab Duplicate DAL SS SS17 0 0000 Lab Matrix Spike DAL SS SS14 0 0000 DAL SS SS14 0 0000 Lab Duplicate DAL SS SS14 0 0000 Lab Matrix Spike DAL SS SS18 0 0000 DAL SS SS18 0 0000 Lab Duplicate DAL SS SS18 0 0000 Lab Matrix Spike DAL SS SS10 0 0000 DAL SS SS10 0 0000 Lab Duplicate DAL SS SS10 0 0000 Lab Matrix Spike DAL SS SS30 0 0000 DAL SS SS30 0 0000 Lab Duplicate DAL SS SS30 0 0000 Lab Matrix Spike DAL SS SS30 0 0005 DAL SS SS30 0 0005 Lab Duplicate DAL SS SS30 0 0005 Lab Matrix Spike DAL SS SS30 0 0015 DAL SS SS30 0 0015 Lab Duplicate DAL SS SS30 0 0015 Lab Matrix Spike DAL SS SS25 0 0000 DAL SS SS25 0 0000 Lab Duplicate DAL SS SS25 0 0000 Lab Matrix Spike DAL SS SS25 0 0005 DAL SS SS25 0 0005 Lab Duplicate DAL SS SS25 0 0005 Lab Matrix Spike DAL SS SS25 0 0015 DAL SS SS25 0 0015 Lab Duplicate DAL SS SS25 0 0015 Lab Matrix Spike DAL SD SD22 0 0000 DAL SD SD22 0 0000 Lab Duplicate DAL SD SD22 0 0000 Lab Matrix Spike DAL SD SD22 0 0005 DAL SD SD22 0 0005 Lab Duplicate DAL SD SD22 0 0005 Lab Matrix Spike DAL SD SD22 DB 0005 DAL SD SD22 DB 0005 Lab Duplicate DAL SD SD22 DB 0005 Lab Matrix Spike DAL SD SD22 0 0015 DAL SD SD22 0 0015 Lab Duplicate Printed 3/16/2011 3M Study GLP10-01-02-15 Soil Matrix ID Soil Weight Used (g) 3 Page 1 of 8 4 1.0969 1.1041 1:1639 2.1713 2.1685 2.2792 1.7306 1.6369 1.8023 1.4718 1.5972 1.4002 1.4346 1.2958 1.4129 1.4828 1.5002 1.5622 1.5738 1.5306 1.2980 1.8322 1.6269 1.7266 1.4855 1.3023 1.5702 1.5863 1.5513 1.5200 1.8169 1.7215 1.9596 1.3867 1.3293 1.2357 1.3064 1.1784 1.4972 1.3188 1,3474 1.3190 1.4883 1.5932 1.3255 1.5709 1.8341 1.7257 1.4118 1.1844 1.6224 0.9862 1.0133 1.1617 1,1939 1.0273 1.1540 1.1015 1.0546 1.0244 2.1757 2.3313 2.5810 1.2722 1.3291 1.3854 1.7182 1.5521 1.4726 1.2988 1.3968 1.6349 1.7902 1.9765 1.6704 1.9346 1.9990 1.6023 1.1968 1.1321 Spike ID 5 10 007-38-3 Soils Extracted 16-Mar-2011 Spike Volume (uL) 6 100 Internal Internal Standard Standard ID Volume (uL) 7 10 010-177 10 010-177 10010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10010-177 10010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10010-177 10010-177 10010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 8 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 Page 103 of 514 GLPlO-01-02-15 ETS-8-053 Sample ID Sample Description 1 GLP10-01-01-15-030 LMS GLP10-01-01-15-031 GLP10-01-01-15-031 Dup GLP10-01-01-15-031 LMS GLP10-01-01-15-032 GLP10-01-01-15-032 Dup GLP10-01-01-15-032 LMS GLP10-01-01-15-033 GLP10-01-01-15-033 Dup GLP10-01-01-15-033 LMS GLP10-01-01-15-034 GLP10-01-01-15-034 Dup GLP10-01-01-15-034 LMS GLP10-01-01-15-035 GLP10-01-01-15-035 Dup GLP10-01-01-15-035 LMS GLP10-01-01-15-036 GLP10-01-01-15-036 Dup GLP10-01-01-15-036 LMS GLP10-01-01-15037 GLP10-01-01-15-037 Dup GLP10-01-01-15037 LMS GLP10-01-01-15-038 GLP1501 -01-15038 Dup GLP10-01-01-15038 LMS GLP10-01-01-15-039 GLP10-01-01-15039 Dup GLP10-01-01-15-039 LMS GLP10-01-01-15-040 GLP10-01-01-15-040 Dup GLP10-01-01-15-040 LMS GLP10-01-01-15-041 GLP10-01-01-15-041 Dup GLP10-01-01-15041 LMS GLP10-01-01-15-042 GLP10-01-01-15-042 Dup GLP10-01-01-15-042 LMS GLP10-01-01-15-043 GLP10-01-01-15-043 Dup GLP10-01-01-15043 LMS GLP10-01-01-15-044 GLP10-01-01-15-044 Dup GLP10-01-01-15-044 LMS GLP10-01-01-15045 GLP10-01-01-15-045 Dup GLP10-01-01-15-045 LMS GLP10-01-01-15046 GLP1001-01-15-046 Dup GLP10-01-01-15-046 LMS GLP10-01-01-15-047 GLP10-01-01-15047 Dup GLP10-01-01-15-047 LMS GLP10-01-01-15048 GLP1001-01-15048 Dup GLP10-01-01-15-048 LMS GLP1O01-0M5-049 GLP10-01-01-15-049 Dup GLP1O01-01-15049 LMS GLP10-01-01-15-050 GLP10-01-01-15-050 Dup GLP1001-01-15-050 LMS GLP1001-01-15-051 GLP10-01-01-15-051 Dup GLP10-01-01-15051 LMS GLP10-01-01-15052 GLP10-01-01-15-052 Dup GLP1001-01-15052 LMS GLP1001-01-15053 GLP10-01-01-15-053 Dup GLP1001-01-15-053 LMS GLP1O01-01-15054 GLP1001-01-15-054 Dup GLP10-01-01-15-054 LMS GLP10-01-01-15055 GLP10-01-01-15055 Dup GLP10-01-01-15055 LMS GLP10-01-01-15056 GLP1001-01-15056 Dup GLP1001-01-15056 LMS GLP10-01-01-15057 2 DAL SD SD22 0 0015 Lab Matrix Spike DAL SD SD21 0 0000 DAL SD SD21 0 0000 Lab Duplicate DAL SD SD21 0 0000 Lab Matrix Spike DAL SD SD21 0 0005 DAL SD SD21 0 0005 Lab Duplicate DAL SD SD21 0 0005 Lab Matrix Spike DAL SD SD21 0 0015 DAL SD SD21 0 0015 Lab Duplicate DAL SD SD21 0 0015 Lab Matrix Spike DAL SS SS24 0 0000 DAL SS SS24 0 0000 Lab Duplicate DAL SS SS24 0 0000 Lab Matrix Spike DAL SS SS24 0 0005 DAL SS SS24 0 0005 Lab Duplicate DAL SS SS24 0 0005 Lab Matrix Spike DAL SS SS24 0 0015 DAL SS SS24 0 0015 Lab Duplicate DAL SS SS24 0 0015 Lab Matrix Spike DAL SS SS29 0 0000 DAL SS SS29 0 0000 Lab Duplicate DAL SS SS29 0 0000 Lab Matrix Spike DAL SS SS29 0 0005 DAL SS SS29 0 0005 Lab Duplicate DAL SS SS29 0 0005 Lab Matrix Spike DAL SS SS29 0 0015 DAL SS SS29 0 0015 Lab Duplicate DAL SS SS29 0 0015 Lab Matrix Spike DAL SS SS20 0 0005 DAL SS SS20 0 0005 Lab Duplicate DAL SS SS20 0 0005 Lab Matrix Spike DAL SS SS13 0 0005 DAL SS SS13 0 0005 Lab Duplicate DAL SS SS13 0 0005 Lab Matrix Spike DAL SS SS13 DB 0005 DAL SS SS13 DB 0005 Lab Duplicate DAL SS SS13 DB 0005 Lab Matrix Spike DAL SS SS15 0 0005 DAL SS SS15 0 0005 Lab Duplicate DAL SS SS15 0 0005 Lab Matrix Spike DAL SS SS17 0 0005 DAL SS SS17 0 0005 Lab Duplicate DAL SS SS17 0 0005 Lab Matrix Spike DAL SS SS14 0 0005 DAL SS SS14 0 0005 Lab Duplicate DAL SS SS14 0 0005 Lab Matrix Spike DAL SS SS18 0 0005 DAL SS SS18 0 0005 Lab Duplicate DAL SS SS18 0 0005 Lab Matrix Spike DAL SS SS16 0 0005 DAL SS SS16 0 0005 Lab Duplicate DAL SS SS16 0 0005 Lab Matrix Spike DAL SS SS16 0 0015 DAL SS SS16 0 0015 Lab Duplicate DAL SS SS16 0 0015 Lab Matrix Spike DAL SS SS10 0 0005 DAL SS SS10 0 0005 Lab Duplicate DAL SS SS10 0 0005 Lab Matrix Spike DAL SS SS10 DB 0005 DAL SS SS10 DB 0005 Lab Duplicate DAL SS SS10 DB 0005 Lab Matrix Spike DAL SS SS10 0 0015 DAL SS SS10 0 0015 Lab Duplicate DAL SS SS10 0 0015 Lab Matrix Spike DAL SD SD20 0 0000 DAL SD SD20 0 0000 Lab Duplicate DAL SD SD20 0 0000 Lab Matrix Spike DAL SD SD20 0 0005 DAL SD SD20 0 0005 Lab Duplicate DAL SD SD20 0 0005 Lab Matrix Spike DAL SD SD20 0 0015 DAL SD SD20 0 0015 Lab Duplicate DAL SD SD20 0 0015 Lab Matrix Spike DAL SD SD23 0 0000 DAL SD SD23 0 0000 Lab Duplicate DAL SD SD23 0 0000 Lab Matrix Spike DAL SD SD23 0 0005 DAL SD SD23 0 0005 Lab Duplicate DAL SD SD23 0 0005 Lab Matrix Spike DAL SD SD23 0 0015 Printed 3/16/2011 3M Study GLP10-01-02-15 ' Soil Matrix ID Soil Weight Used (g) 3 Page 2 of 8 4 1.1141 - 1.3400 ' 1.7710 1.7567 1.5533 1.4631 1.4255 1.3571 1.4063 1.4551 1.2169 1.2909 1.3334 2.8500 3.1143 2.6325 1.5557 1 3947 1.4021 1.0683 1.2359 1.1055 1.6665 1.3811 1.3100 1.5722 1.7359 1.8415 1.0491 1.3354. 1.1483 1.0287 1.1133 1.0559 1.4305 1.3816 1.2858 1.4217 1.6350 1.5553 1,4228 1.4283 1.3513 1.3901 .1.3273 1.2679 1.6793 1.4735 1.4360 1.4857 1 3636 1.4069 1.4755 1.4705 1.5459 1.6689 1.6383 1.7717 1.8480 1.5647 1.8236 2.3117 2.3619 2.2142 1.5251 1.5534 1.5162 1.2051 1.2705 1.4174 1.5316 1.4619 1.5515 1.6304 1.8054 1.5886 1.3277 1.4115 1.1674 1.3684 Spike ID 5 Soils Extracted 16-Mar-2011 Spike Volume (uL) 6 Internal Internal Standard Standard ID Volume (uL) 7 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10010*177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10010-177 10 010-177 10 010-177 8 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 Page 104 of 514 GLPlO-01-02-15 Sample ID Sample Description 1 GLP10-01-01-15-057 Dup GLP10-01-01-15-057 LMS GLP10-01-01-15-058 GLP10-01-01-15-058 Dup GLP10-01-01-15-058 LMS GLP10-01-01-15-059 GLP10-01-01-15-059 Dup GLP10-01-01-15-059 LMS GLP10-01-01-15-060 GLP10-01-01-15-060 Dup GLP10-01-01-15-060 LMS GLP10-01-01-15-061 GLP10-01-01-15-061 Dup GLP10-01-01-15-061 LMS GLP10-01-01-15-062 GLP10-01-01-15-062 Dup GLP10-01-01-15-062 LMS GLP10-01-01-15-063 GLP10-01-01-15-063 Dup GLP10-01-01-15-063 LMS GLP10-01-01-15-064 GLP10-01-01-15-064 Dup GLP10-01-01-15-064 LMS GLP10-01-01-15-065 GLP10-01-01-15-065 Dup GLP10-01-01-15-065 LMS GLP10-01-01-15-066 GLP10-01-01-15-066 Dup GLP10-01-01-15-066 LMS GLP10-01-01-15-067 GLP10-01-01-15-067 Dup GLP10-01-01-15-067 LMS GLP10-01-01-15-068 GLP10-01-01-15-068 Dup GLP10-01-01-15-068 LMS GLP10-01-01-15-069 GLP10-01-01-15-069 Dup GLP10-01-01-15-069 LMS GLP10-01-01-15-070 GLP10-01-01-15-070 Dup GLP10-01-01-15-070 LMS GLP10-01-01-15-071 GLP10-01-01-15-071 Dup GLP10-01-01-15-071 LMS GLP10-01-01-15-072 GLP10-01-01-15-072 Dup GLP10-01-01-15-072 LMS GLP10-01-01-15-073 GLP10-01-01-15-073 Dup GLP10-01-01-15-073 LMS GLP10-01-01-15-074 GLP10-01-01-15-074 Dup GLP10-01-01-15-074 LMS GLP10-01-01-15-075 GLP10-01-01-15-075 Dup GLP10-01-01-15-075 LMS GLP10-01-01 -15-076 GLP10-01-01-15-076 Dup GLP10-01-01-15-076 LMS GLP10-01-01-15-077 GLP10-01-01-15-077 Dup GLP10-01-01-15-077 LMS GLP10-01-01-15-079 GLP10-01-01-15-079 Dup GLP10-01-01-15-079 LMS GLP10-01-01-15-080 GLP10-01-01-15-080 Dup GLP10-01-01-15-080 LMS GLP10-01-01-15-081 GLP10-01-01-15-081 Dup GLP10-01-01-15-081 LMS GLP10-01-01-15-082 GLP10-01-01-15-082 Dup GLP10-01-01-15-082 LMS GLP10-01-01-15-083 GLP10-01-01-15-083 Dup GLP10-01-01-15-083 LMS GLP10-01-01-15-084 GLP10-01-01-15-084 Dup GLP10-01-01-15-084 LMS 2 DAL SD SD23 0 0015 Lab Duplicate DAL SD SD23 0 0015 Lab Matrix Spike DAL SS SS28 0 0000 DAL SS SS28 0 0000 Lab Duplicate DAL SS SS28 0 0000 Lab Matrix Spike DAL SS SS28 0 0005 DAL SS SS28 0 0005 Lab Duplicate DAL SS SS28 0 0005 Lab Matrix Spike DAL SS SS28 DB 0005 DAL SS SS28 DB 0005 Lab Duplicate DAL SS SS28 DB 0005 Lab Matrix Spike DAL SS SS28 0 0015 DAL SS SS28 0 0015 Lab Duplicate DAL SS SS28 0 0015 Lab Matrix Spike DAL SS SS27 0 0000 DAL SS SS27 0 0000 Lab Duplicate DAL SS SS27 0 0000 Lab Matrix Spike DAL SS SS27 0 0005 DAL SS SS27 0 0005 Lab Duplicate DAL SS SS27 0 0005 Lab Matrix Spike DAL SS SS27 0 0015 DAL SS SS27 0 0015 Lab Duplicate DAL SS SS27 0 0015 Lab Matrix Spike DAL SS SS22 0 0000 DAL SS SS22 0 0000 Lab Duplicate DAL SS SS22 0 0000 Lab Matrix Spike DAL SS SS22 0 0005 DAL SS SS22 0 0005 Lab Duplicate DAL SS SS22 0 0005 Lab Matrix Spike DAL SS SS22 DB 0005 DAL SS SS22 DB 0005 Lab Duplicate DAL SS SS22 DB 0005 Lab Matrix Spike DAL SS SS22 0 0015 DAL SS SS22 0 0015 Lab Duplicate DAL SS SS22 0 0015 Lab Matrix Spike DAL SS SS21 0 0000 DAL SS SS21 0 0000 Lab Duplicate DAL SS SS21 0 0000 Lab Matrix Spike DAL SS SS21 0 0005 DAL SS SS21 0 0005 Lab Duplicate DAL SS SS21 0 0005 Lab Matrix Spike DAL SS SS21 0 0015 DAL SS SS21 0 0015 Lab Duplicate DAL SS SS21 0 0015 Lab Matrix Spike DAL SD SD18 0 0000 DAL SD SD18 0 0000 Lab Duplicate DAL SD SD18 0 0000 Lab Matrix Spike DAL SD SD18 0 0005 DAL SD SD18 0 0005 Lab Duplicate DAL SD SD18 0 0005 Lab Matrix Spike DAL SD SD18 0 0015 DAL SD SD18 0 0015 Lab Duplicate DAL SD SD18 0 0015 Lab Matrix Spike DAL SD SD19 0 0000 DAL SD SD19 0 0000 Lab Duplicate DAL SD SD19 0 0000 Lab Matrix Spike DAL SD SD19 0 0005 DAL SD SD19 0 0005 Lab Duplicate DAL SD SD19 0 0005 Lab Matrix Spike DAL SD SD19 0 0015 DAL SD SD19 0 0015 Lab Duplicate DAL SD SD19 0 0015 Lab Matrix Spike DAL SS SS26 0 0000 DAL SS SS26 0 0000 Lab Duplicate DAL SS SS26 0 0000 Lab Matrix Spike DAL SS SS26 DB 0000 DAL SS SS26 DB 0000 Lab Duplicate DAL SS SS26 DB 0000 Lab Matrix Spike DAL SS SS26 0 0005 DAL SS SS26 0 0005 Lab Duplicate DAL SS SS26 0 0005 Lab Matrix Spike DAL SS SS26 0 0015 DAL SS SS26 0 0015 Lab Duplicate DAL SS SS26 0 0015 Lab Matrix Spike DAL SS Trip2 0 0000 DAL SS Trip2 0 0000 Lab Duplicate DAL SS Trip2 0 0000 Lab Matrix Spike DAL SS SS12 0 0015 DAL SS SS12 0 0015 Lab Duplicate DAL SS SS12 0 0015 Lab Matrix Spike Printed 3/16/2011 3M Study GLP10-01-02-15 ETS-8-053 Soil Matrix ID Soil Weight Used (g) 34 1.4116, 1.3105 : 1.0441 1.1800 1.5726 1.0451 1.1338 1.1206 1.5755 1.4069 1.3963 5 1.3283 1.3133 1.3205 1.0337 1.1024 1.3121 1.3914 1.2129 1.3036 1.2317 1.0243 1.2141 1:1009 1.0535 1.1390 1.3700 1.3156 1.3506 1.5326 1.2590 1.5503 1.4807 1.5275 1.6011 mmmmmm H H 0050B B B H 0T9626ai hdKll?0656Mifll HHQT9'8.7iUBH aSH170302flH MIU!fclir432i1^H mmmamm mmmsmm fiS lP 2 9 1 5 B Spike ID 5 BK4035H JH nK saaB rifilti:8 5 5 M kH K 552H ln ii2 8 2 '3 H a n r6 0 5 8 M H H lf536I1H B m 2 f0 0 9 0 H B HH1K1033m H C IR IB.52H n i3 6 6 M i ummwam wmnmmm w abmk SmbBrn^ msmm H 1 I3 3 6 5 ^H HK4M 6M B a B I6S S 6 H I vmssmmm 'mmmmmu mmf-msmm mmmszwM H KH 1 111 H lg 2 `3 5 9 H BH *2'206^H S n ro o o o B i mMmssmm H K lF 3 '6 6'5 H i Page 3 of 8 10 007-38-3 Soils Extracted 16-Mar-2011 Spike Volume (uL) 6 100 Internal Standard ID Internal Standard Volume (uL) 7 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 8 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 Page 105 of 514 GLPlO-01-02-15 Sample ID Sample Description 1 GLP10-01-01-15-085 GLP10-01-01-15-085 Dup GLP10-01-01-15-085 LMS GLP10-01-01-15-086 GLP10-01-01-15-086 Dup GLP10-01-01-15-086 LMS GLP10-01-01-15-087 GLP10-01-01-15-087 Dup GLP10-01-01-15-087 LMS GLP10-01-01-15-088 GLP10-01-01-15-088 Dup GLP10-01-01-15-088 LMS GLP10-01-01-15-089 GLP10-01-01-15-089 Dup GLP10-01-01-15-089 LMS GLP10-01-01-15-090 GLP10-01-01-15-090 Dup GLP10-01-01-15-090 LMS GLP10-01-01-15-091 GLP10-01-01-15-091 Dup GLP10-01-01-15-091 LMS GLP10-01-01-15-092 GLP10-01-01-15-092 Dup GLP10-01-01-15-092 LMS EC-110316-01 EC-110316-02 EC-110316-03 EC-110316-04 EC-110316-05 EC-110316-06 EC-110316-07 EC-110316-08 EC-110316-09 EC-110316-10 EC-110316-11 EC-110316-12 LCS-110316-01 LCS-110316-02 LCS-110316-03 LCS-110316-04 LCS-110316-05 LCS-110316-06 LCS-110316-07 LCS-110316-08 LCS-110316-09 MB-110316-01 MB-110316-02 MB-110316-03 MB-110316-04 MB-110316-05 MB-110316-06 MB-110316-07 MB-110316-08 MB-110316-09 MB-110316-10 MB-110316-11 MB-110316-12 2 DAL SS SS19 0 0015 DAL SS SS19 0 0015 Lab Duplicate DAL SS SS19 0 0015 Lab Matrix Spike DAL SSSS20 0 0015 DAL SS SS20 0 0015 Lab Duplicate DAL SS SS20 0 0015 Lab Matrix Spike DAL SS SS14 0 0015 DAL SS SS14 0 0015 Lab Duplicate DAL SS SS14 0 0015 Lab Matrix Spike DAL SS SS17 0 0015 DAL SS SS17 0 0015 Lab Duplicate DAL SS SS17 0 0015 Lab Matrix Spike DAL SS SS13 0 0015 DAL SS SS13 0 0015 Lab Duplicate DAL SS SS13 0 0015 Lab Matrix Spike DAL SS SS15 0 0015 DAL SS SS15 0 0015 Lab Duplicate DAL SS SS15 0 0015 Lab Matrix Spike DAL SS SS18 0 0015 DAL SS SS18 0 0015 Lab Duplicate DAL SS SS18 0 0015 Lab Matrix Spike DAL SS SS11 0 0015 DAL SS SS11 0 0015 Lab Duplicate DAL SS SS11 0 0015 Lab Matrix Spike 0.2 no Extracted Curve Point 0.5 na Extracted Curve Point 0.75 na Extracted Curve Point 1 na Extracted Curve Point 2.5 na Extracted Curve Point 5 na Extracted Curve Point 10 no Extracted Curve Point 25 na Extracted Curve Point 50 na Extracted Curve Point 100 na Extracted Curve Point 200 na Extracted Curve Point 500 na Extracted Curve Point 3 na LCS in TCR-842 3 na LCS in TCR-842 3 na LCS in TCR-842 30 na LCS in TCR-842 30 na LCS in TCR-842 30 na LCS in TCR-842 300na LCS in TCR-842 300na LCS in TCR-842 300na LCS in TCR-842 Method Blank w/o IS Method Blank w/o IS Method Method Method Method Blank Blank Blank Blank wwww////oIIISSSIS Method Blank w/ IS for dilutions Method Blank w/ IS for dilutions Method Blank w/ IS for dilutions Method Blank w/ IS for dilutions Method Blank w/ IS for dilutions Method Blank w/ IS for dilutions CoiSS.6: Pipette ID: 3402277 Pipette ID: 265893 (for volumes >100uL) ETS-8-053 Soil Matrix ID Soli Weight Used (g) 34 wmmmmi mmammm ^ ftl!2 8 8 6 B H Spike ID 5 h ih B m -- 1IB9B3M HB1RI1603SHI n in i d o ? 9 6 3 iin B M o ig e a a w i HH0192561H K )!9 6 0 S H B 1 I0 2 3 4 H H S aH H BBP25M 9JH rnmnamwa wmmsm flB B H llt2 '2 4 8 m BK1R M 5H K i n s mmmssm 10 007-38-3 n :o io 3 M if2 5 H w a mmomamm 10 007-38-3 10 007-38-3 M a ffia s * H B 1l 080;ia K t 10 007-38-3 H 1 H 0 i1 5 H H 1 M t6 3 2 ^B w m m tm im MEK1KI030BHI mmmemmmH M K IK IM 10 007-38-2 10 007-38-2 10 007-38-2 m em sm sm 10 007-38-1 w m soe soe m H liO M s S 10 007-38-1 W m ut m 1 K 1 '-2 6 0 a B 10 007-38-1 M H 0 0 S H I0 .7 i6 9 H B 10 006-67 nM:oi:iooiioims:ei>sT2 255H* b H Ak B o M s s B fi 10 006-67 10 010-183 S B B m i'5 6 3 a n 10 010-183 m e fioe s m H ^K 1|r09.7i9^H 10010-183 W'0M1PS25M M fiiiro 8 5 o n 10 010-182 V10IOI0325B K lI0 0 6 2 m i K1.0I03.CS2SHI mmwmm 10 010-182 10 010-182 M 1M 0JM 125* BBB1H1/289^B 10 006-68 M S * HHIXISI03BH 10 006-68 H tisMs oeo :&2 m5 fl w m a tm m m 10 006-68 WM0BS12SH H II0 3 9 2 S H mmnsmm K lfO % t59B I K i;oioam >25* iH iro 6 3 8 m w emams ma ^ 1 il!5 3 S B H B H IilB O B H i K 0 I0 i 2 5 H M (5 t2 6 3 2 H k :o m i:q3!2:5h K i:oioii:osi25S H C 4 < 8 6 28 M n 9 K 4 f9 4S I.3H :o io ;i.( 2 5 * ^ S tl!8 3 .9 ^H s i:o io j' :-2 5 * w m tom m m Col 7 & 8: /K r -> -/< ' II Pipette ID: 3402277 Pipette ID: 265893 (for volumes >100uL) Soils Extracted 16-Mar-2011 Spike Volume (uL) 6 20 50 75 100 25 50 100 25 50 100 20 50 30 30 30 30 30 30 30 30 30 Internal Internal Standard Standard ID Volume (uL) 7 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10010-177 10 010-177 10 010-177 10010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 8 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 10 010-177 30 30 30 150 150 150 150 150 150 Printed 3/16/2011 3M Study GLP10-01-02-15 Page 4 of 8 Page 106 of 514 GLP10-01-02-1S ETS-8-053 Soils Extracted 16-Mar-2011 Surrogate Spike ID 9 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10010-179 10010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10010-179 10 010-179 10 010-179 Surrogate Spike PFBS Spike Volume ID (uL) 10 11 30 30 30 30 30 30 10 007-47-4 30 30 30 10 007-47-3 30 30 30 10 007-47-5 30 30 30 10 007-47-3 30 30 30 10 007-47-3 30 30 30 10 007-47-5 30 30 30 10 007-47-4 30 30 30 10 007-47-5 30 30 30 10 007-47-5 30 30 30 10 007-47-5 30 30 30 10 007-47-4 30 30 30 10 007-47-5 30 30 30 10 007-47-5 30 30 30 10 007-47-5 30 30 30 10 007-47-5 30 30 30 10 007-47-4 30 30 30 10 007-47-5 30 30 30 10 007-47-5 30 30 30 10 007-47-5 30 30 30 10 007-47-3 30 30 30 10 007-47-3 30 30 30 10 007-47-3 30 30 30 10 007-47-3 30 30 30 10 007-47-3 30 30 30 10 007-47-3 30 30 oo PFBS Spike Volume (uL) 12 50 25 100 25 25 100 50 100 100 100 50 100 100 100 100 50 100 100 100 100 100 25 25 25 L-PFHxS Spike ID 13 L-PFHxS Spike Volume (uL) 14 L-PFOS Spike ID 15 10 007-48-3 100 10 007-49-1 10 007-48-2 50 10 007-49-1 10 007-48-4 50 10 010-194 10 007-48-3 25 10 010-194 10 007-48-3 25 10010-194 10 007-48-4 50 10 007-49-2 10 007-48-3 25 10 007-49-2 10 007-48-4 50 10 010-194 10 007-48-4 50 10010-194 10 007-48-4 50 10 010-194 10 007-48-3 25 10 010-194 10 007-48-4 50 10 010-194 10 007-48-4 50 10 007-49-2 10 007-48-3 25 10010-194 10 007-48-3 25 10 010-194 10 007-48-3 100 10 007-49-1 10 007-48-4 50 10 010-194 10 007-48-5 100 10 010-194 10 007-48-3 25 10010-194 10 007-48-2 100 10 007-49-1 10 007-48-2 100 10 007-49-1 10 007-48-2 50 10 007-49-1 10 007-48-2 25 10 007-49-1 10 007-48-3 100 10 010-194 10007-48-3 100 10 010-194 L-PFOS Spike Volume (uL) 16 50 50 25 50 50 100 100 25 25 25 50 25 100 50 25 50 50 25 25 50 50 50 50 100 100 Add Extraction Solvent <mL) Sonicate 1 hr 17 18 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 6 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM Centrifuge Comments 19 GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM 20 / I I j I I I I j I I I I I /I / I /i I I I N? A \\ \i ___ _________ j PrintM StUd91iL P 1 0 - 0 1 - 0 2 - 1 5 Page5of8 Page 107 of 514 GlPlO-01-02-15 ETS-8-053 Soils Extracted 16-Mar-2011 Surrogate Spike ID e 10010-179 10 010-179 10 010-179 10010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10010-179 10010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10010-179 10 010-179 10 010-179 10 010-179 10010-179 10010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10010-179 10 010-179 10 010-179 10010-179 10 010-179 10010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10010-179 10 010-179 10 010-179 10 010-179 10 010-179 Surrogate Spike PFBS Spike Volume ID (uL) 10 11 30 10 007-47-3 30 30 30 10 007-47-3 30 30 30 10 007-47-3 30 30 30 10 007-47-3 30 30 30 10 007-47-4 30 30 30 10 007-47-3 30 30 30 10 007-47-4 30 30 30 10 007-47-4 30 30 30 10 007-47-4 30 30 30 10 007-47-3 30 30 30 10 007-47-5 30 30 30 10 007-47-5 30 30 30 10 007-47-5 30 30 30 10 007-47-5 30 30 30 10 007-47-5 30 30 30 10 007-47-5 30 30 30 10 007-47-5 30 30 30 10 007-47-4 30 30 30 10 007-47-3 30 30 30 10 007-47-4 30 30 30 10 007-47-4 30 30 30 10 007-47-3 30 30 30 10 007-47-3 30 30 30 10 007-47-3 30 30 30 10 007-47-3 30 30 30 10 007-47-3 30 30 30 10 007-47-4 30 PFBS Spike Volume (uL) 12 25 L-PFHxS Spike ID 13 10 007-48-3 L-PFHxS Spike Volume (uL) 14 100 L-PFOS Spike ID 15 10 010-194 25 10 007-48-2 25 10 007-49-1 25 10 007-48-2 25 10 010-194 25 10 007-48-3 100 10010-194 50 10 007-48-3 100 10 010-194 25 10 007-48-2 25 10 007-49-1 50 10 007-48-3 100 10 010-194 50 10 007-48-3 25 10 010-194 50 10 007-48-4 50 10010-194 25 10 007-48-3 100 10010-194 100 10 007-48-5 100 10 007-49-2 100 10 007-48-4 50 10 010-194 100 10 007-48-4 50 10 010-194 100 10 007-48-4 50 10010-194 100 10 007-48-4 50 10 010-194 100 10 007-48-4 50 10 010-194 100 10 007-48-5 100 10 007-49-2 50 10 007-48-4 50 10 010-194 25 10 007-48-3 25 10 010-194 50 10 007-48-3 25 10 010-194 50 10007-48-3 25 10 010-194 25 10 007-48-3 100 10010-194 25 10 007-48-2 25 10 007-49-1 25 10 007-48-2 25 10 010-194 25 10 007-48-2 25 10010-194 25 10 007-48-3 100 10 010-194 50 10 007-48-3 25 10 010-194 L-PFOS Spike Volume (uL) 16 50 50 100 50 100 50 100 50 25 100 100 50 50 25 25 25 100 25 25 50 100 100 50 100 100 50 25 Add Extraction Solvent (mL) Sonicate 1 hr 17 18 8 GPM 8 GPM 8 GPM 6 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 6 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM Printed 3/16/2011 3M Study GLP10-01-02-15 Page 6 of 8 Centrifuge Comments 19 GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM 20 ' L O / _______ ______ II I11 1 j1 I j j j i Page 108 of 514 GLP10-01-02-15 ETS-8-053 Soils Extracted 16-Mar-2011 Surrogate Spike ID Surrogate Spike PFBS Spike Volume ID (uL) 9 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10010-179 10 010-179 10 11 30 30 10 007-47-4 30 30 30 10 007-47-4 30 30 30 10 007-47-5 30 30 30 10 007-47-5 30 30 30 10 007-47-4 30 30 30 10 007-47-5 30 30 30 10 007-47-5 30 30 30 10 007-47-5 30 30 30 10 007-47-4 30 30 30 10 007-47-4 30 30 30 10 007-47-4 30 30 30 10 007-47-5 30 30 30 10 007-47-5 30 30 30 10 00747-5 30 30 30 10 007474 30 30 30 10 00747-3 30 30 30 10 00747-3 30 30 30 10 007474 30 30 30 10 00747-3 30 30 30 10 00747-3 30 30 30 10 007-47-3 30 30 30 10 00747-5 30 30 30 10 00747-5 30 30 30 10 007474 30 30 30 10 007474 30 30 30 30 30 30 10 00747-3 PFBS Spike Volume (uL) 12 L-PFHxS Spike ID 13 L-PFHxS Spike Volume (uL) 14 L-PFOS Spike ID 15 50 10 00748-3 25 10010-194 50 10 00748-5 100 10010-194 100 10 007-48-5 100 10 010-194 100 10 00748-5 100 10 010-194 50 10 007484 50 10010-194 100 10 00748-5 100 10010-194 100 10 007-48-5 100 10 010-194 100 10 00748-5 100 10 010-194 50 10 007484 50 10 010-194 50 10 007484 50 10 010-194 50 10 007484 50 10010-194 100 10 00748-5 100 10 00749-2 100 10 00748-3 25 10 010-194 100 10 00748-3 25 10 010-194 50 10 00748-3 25 10 007-49-2 25 10 00748-2 25 10 010-194 25 10 00748-3 100 10 010-194 50 10 007-48-3 100 10 010-194 25 10 00748-2 25 10 010-194 25 10 00748-2 25 10 010-194 25 10 00748-3 100 10 010-194 100 10 007-48-3 25 10 010-194 100 10 00748-3 25 10 010-194 50 10 007-48-3 25 10010-194 50 10 00748-3 100 10010-194 25 10 007-48-2 50 10 007-49-1 L-PFOS Spike Volume (uL) 16 25 25 25 25 25 25 25 25 25 25 25 100 50 25 100 100 50 25 100 100 50 100 50 100 50 50 Add Extraction Solvent (mL) Sonicate 1 hr 17 18 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM Centrifuge 19 GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM Comments 20 ( / / / / / / 1 I I I I I I I I 1 I I I I I I I I I I I I I \ rv I Printed 3/16/2011 3M Study GLP10-01-02-15 Page 7 of 8 Page 109 of 514 GLP10-01-02-15 ETS-8-053 Soils Extracted 16-Mar-2011 Surrogate Spike ID 9 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10010-179 10 010-179 10 010-179 10 010-179 10 010-179 10010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-180 10 010-180 10 010-180 10 010-180 10010-179 10 010-179 10 010-179 10 010-178 10 010-178 10 010-178 10 010-178 10 010-178 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 Surrogate Spike PFBS Spike Volume ID (uL) 10 11 30 30 30 10 007-47-4 30 30 30 10 007-47-5 30 30 30 10 007-47-5 30 30 30 10 007-47-5 30 30 30 10 00747-4 30 30 30 10 00747-5 30 30 30 10 007-47-5 30 30 30 10 00747-5 20 50 75 100 25 50 100 25 50 100 200 200 30 30 30 30 30 30 30 30 30 PFBS Spike Volume (uL) 12 50 100 100 100 50 100 100 100 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 10 010-179 30 30 30 150 150 150 150 150 150 L-PFHxS Spike ID 13 L-PFHxS Spike Volume (uL) 14 L-PFOS Spike ID 15 10 007-48-3 25 10 010-194 10 007484 50 10 010-194 10 007484 50 10 010-194 10 007-48-4 50 10010-194 10 007-48-4 50 10 010-194 10 007484 50 10 00749-2 10 007484 50 10010-194 1000748-5 100 1000749-2 L-PFOS Spike Volume (uL) 16 50 25 25 25 25 100 25 25 Add Extraction Solvent (mL) Sonicate 1 hr 17 18 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 6 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 8 GPM 40 GPM 40 GPM 40 GPM 40 GPM 40 GPM 40 GPM Centrifuge 19 GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM Comments 20 j i i i i / i / / / / I I I 1 1 X N 4t 71 v> / / I 1 1 1 i 1 j j f I 1 j 1 1 1 / j 1 j j j j 1 j Col 9 & 10: Pipette ID: 3402277 Pipette ID: 265893 (for volumes >100uL) Col 11 & 12: >* P Pipette ID: 3402277 COM3. 14: 6 /W J J -/6 - >( Pipette ID: 3402277 Col 15 & 16: C f** Pipette ID: 3402277 Col 17: C P TM 3 - y i ' II Extraction Solvent ID: 10 006-80 10 006-81 for Curve & QC, Samples GLP10-01-01-15-001 through GLP10-01-01-15-031 Col 18: >V*7 3 / t - t l SonicatorlD: QEJ100595003 Col 19: /' Centrifuge ID: 021188-55,1521430 769613 (for 50mL tubes) 10 min @ 3000 RPM Printed 3/16/2011 3M Study GLP10-01-02-15 Page 8 of 8 Page 110 of 514 INTERNAL CHAIN-OF-CUSTODY environmental laboratory Sample Internal Transfer Sample set ID # Lims# N/A GLP10-01-01-15 Sample Description: Decatur Soils INTERNALCHAINOFCUSTODY # 3M Sample IDs Out: storage ID Init/date In: storage ID Init/date Comments/lnit/date 1 GLP10-01-01-15-001 L 5 R M C 9 r\ % )0 - If 2 GLP10-01-01-15-002 ______I________________ 3 GLP10-01-01-15-003 C 0 n D -/*-H 4 GLP10-01-01-15-004 5 GLP10-01-01-15-005 6 GLP10-01-01-15-006 7 GLP10-01-01-15-007 8 GLP10-01-01-15-008 9 GLP10-01-01-15-009 10 GLP10-01-01-15-010 I ______________________ _____ i______ 1 ' 11 GLP10-01-01-15-011 12 GLP10-01-01-15-012 13 GLP10-01-01-15-014 14 GLP10-01-01-15-015 15 GLP10-01-01-15-016 ____________________ 16 GLP10-01-01-15-018 17 GLP10-01-01-15-020 18 GLP10-01-01-15-021 19 GLP10-01-01-15-022 20 GLP10-01-01-15-023 21 GLP10-01-01-15-024 22 GLP10-01-01-15-025 23 GLP10-01-01-15-026 24 GLP10-01-01-15-027 /T vf 25 GLP10-01-01-15-028 26 GLP10-01-01-15-029 27 GLP10-01-01-15-030 28 GLP10-01-01-15-031 29 GLP10-01-01-15-032 i 1 ! 1 l| 30 GLP10-01-01-15-033 31 GLP10-01-01-15-034 32 GLP10-01-01-15-035 33 GLP10-01-01-15-036 34 GLP10-01-01-15-037 35 GLP10-01-01-15-038 36 GLP10-01-01-15-039 37 GLP10-01-01-15-040 38 GLP10-01-01-15-041 39 GLP10-01-01-15-042 40 GLP10-01-01-15-043 41 GLP10-01-01-15-044 42 GLP10-01-01-15-045 43 GLP10-01-01-15-046 44 GLP10-01-01-15-047 V\ y V Vy 3M Study GLP10-01-02-15 Page 1 of 2 Page 111 of 514 INTERNAL CHAIN-OF-CUSTODY environmental laboratory Sample Internal Transfer Sample set ID # Urns# N/A GLP10-01-01-15 Sample Description: Decatur Soils INTERNALCHAINOFCUSTODY # 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 3M Sample IDs GLP10-01-01-15-048 GLP10-01-01-15-049 GLP10-01-01-15-050 GLP10-01-01-15-051 GLP10-01-01-15-052 GLP10-01-01-15-053 GLP10-01 -01-15-054 GLP10-01-01-15-055 GLP10-01 -01 -15-056 GLP10-01-01-15-057 GLP10-01-01-15-058 GLP10-01-01-15-059 GLP10-01-01-15-060 G L P 1 0 -0 1 -0 1 -1 5-061 GLP10-01-01-15-062 GLP10-01-01-15-063 GLP10-01-01-15-064 GLP10-01-01-15-065 GLP10-01-01-15-066 GLP10-01-01-15-067 GLP10-01-01-15-068 GLP10-01-01-15-069 GLP10-01-01-15-070 G L P 1 0 -0 1 -0 1 -1 5-071 GLP10-01-01-15-072 GLP10-01-01-15-073 GLP10-01-01-15-074 GLP10-01-01-15-075 GLP10-01-01-15-076 GLP10-01-01-15-077 GLP10-01-01-15-079 GLP10-01-01-15-080 G L P 1 0 -0 1 -0 1 -1 5-081 GLP10-01-01-15-082 GLP10-01-01-15-083 GLP10-01-01-15-084 GLP10-01-01-15-085 GLP10-01-01-15-086 GLP10-01-01-15-087 GLP10-01-01-15-088 GLP10-01-01-15-089 GLP10-01-01-15-090 G L P 1 0 -0 1 -0 1 -1 5-091 GLP10-01-01-15-092 Out: storage ID InitJdate In: storage ID InitJdate P f t o \______ G r n D -/0 -I/ t ^ q o \ ______ C0*3-/o-H L______ ____ -y _____ \/ V/ Comments/lnitJdate / / / / / I 1 1 1 I 1 3M Study GLP10-01-02-15 Page 2 of 2 Page 112 of 514 INTERNAL CHAIN-OF-CUSTODY environmental laboratory Sample Internal Transfer Sample set ID # Urns# N/A GLP10-01-01-15 Sample Description: Decatur Soils INTERNALCHAINOFCUSTODY # 3M Sample IDs Out: storage ID InitJdate In: storage ID 1 GLP10-01-01-15-001 2 GLP10-01-01-15-002 3 GLP10-01-01-15-003 4 GLP10-01-01-15-004 5 GLP10-01-01-15-005 6 GLP10-01-01-15-006 7 GLP10-01-01-15-007 8 GLP10-01-01-15-008 9 GLP10-01-01-15-009 10 GLP10-01-01-15-010 11 GLP10-01-01-15-011 12 GLP10-01-01-15-012 13 GLP10-01-01-15-014 14 GLP10-01-01-15-015 15 GLP10-01-01-15-016 16 GLP10-01-01-15-018 17 GLP10-01-01-15-020 18 GLP10-01-01-15-021 19 GLP10-01-01-15-022 20 GLP10-01-01-15-023 21 GLP10-01-01-15-024 22 GLP10-01-01-15-025 23 GLP10-01-01-15-026 24 GLP10-01-01-15-027 25 GLP10-01-01-15-028 26 GLP10-01-01-15-029 27 GLP10-01-01-15-030 28 GLP10-01-01-15-031 29 GLP10-01-01-15-032 30 GLP10-01-01-15-033 31 GLP10-01-01-15-034 32 GLP10-01-01-15-035 33 GLP10-01-01-15-036 34 GLP10-01-01-15-037 35 GLP10-01-01-15-038 36 GLP10-01-01-15-039 37 GLP10-01-01-15-040 38 GLP10-01-01-15-041 39 GLP10-01-01-15-042 40 GLP10-01-01-15-043 41 GLP10-01-01-15-044 42 GLP10-01-01-15-045 43 GLP10-01-01-15-046 44 GLP10-01-01-15-047 Gf<* -5 -/^ /-il u f l - o l \ _____ _____ \ -------- ^ ; \J InitJdate /-/w Comments/lnitJdate / / / / / I j snL (1 1 3M Study GLP10-01-02-15 Page 1 of 2 Page 113 of 514 INTERNAL CHAIN-OF-CUSTODY environmental laboratory Sample Internal Transfer Sample set ID # Urns# N/A GLP10-01-01-15 Sample Description: Decatur Soils # 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 INTERNALCHAINOFCUSTODY 3M Sample IDs Out: storage ID InitJdate GLP10-01-01-15-048 GLP10-01 -01-15-049 GLP10-01-01-15-050 GLP10-01 -01-15-051 GLP10-01-01-15-052 GLP10-01-01-15-053 GLP10-01-01-15-054 GLP10-01-01-15-055 GLP10-01-01-15-056 GLP10-01 -01-15-057 GLP10-01-01-15-058 GLP10-01-01-15-059 GLP10-01 -01-15-060 G L P 1 0 -0 1 -0 1 -1 5-061 GLP10-01-01-15-062 G LP10-01-01-15-063 GLP10-01-01-15-064 GLP10-01-01-15-065 GLP10-01-01-15-066 GLP10-01 -01 -15-067 GLP10-01-01-15-068 GLP10-01 -01-15-069 GLP10-01-01-15-070 G L P 1 0 -0 1 -0 1 -1 5-071 GLP10-01-01-15-072 GLP10-01-01-15-073 GLP10-01-01-15-074 GLP10-01-01-15-075 GLP10-01-01-15-076 GLP10-01-01-15-077 GLP10-01-01-15-079 GLP10-01-01-15-080 GLP10-01-01-15-081 GLP10-01-01-15-082 GLP10-01 -01 -15-083 GLP10-01-01-15-084 GLP10-01-01-15-085 GLP10-01-01-15-086 GLP10-01-01-15-087 GLP10-01-01-15-088 GLP10-01-01-15-089 GLP10-01-01-15-090 GLP10-01 -01-15-091 GLP10-01-01-15-092 \7 ---- ^ -s--'--------- In: storage ID InitJdate Li(Lo\ '.b* 1 '/< /-!/ Comments/lnit/date / / / / / 1 1 il w ri I if 1 / V ---------^7 ------- ( 3M Study GLP10-01-02-15 Page 2 of 2 Page 114 of 514 INTERNAL CHAIN-OF-CUSTODY environmental laboratory Sample Internal Transfer Sample set ID # Urns# N/A GLP10-01-01-15 Sample Description: Decatur Soils INTERNALCHAINOFCUSTODY # 3M Sample IDs Out: storage ID Init/date 1 GLP10-01-01-15-001 Gt<v\ Z - & 'n 2 GLP10-01-01-15-002 3 GLP10-01-01-15-003 I 4 GLP10-01-01-15-004 5 GLP10-01-01-15-005 6 GLP10-01-01-15-006 1 7 GLP10-01-01-15-007 ____ _______ 8 GLP10-01-01-15-008 9 GLP10-01-01-15-009 10 GLP10-01-01-15-010 11 GLP10-01-01-15-011 12 GLP10-01-01-15-012 13 GLP10-01-01-15-014 14 GLP10-01-01-15-015 15 GLP10-01-01-15-016 16 GLP10-01-01-15-018 17 GLP10-01-01-15-020 18 GLP10-01-01-15-021 19 GLP10-01-01-15-022 20 GLP10-01-01-15-023 21 GLP10-01-01-15-024 22 GLP10-01-01-15-025 23 GLP10-01-01-15-026 24 GLP10-01-01-15-027 25 GLP10-01-01-15-028 26 GLP10-01-01-15-029 27 GLP10-01-01-15-030 28 GLP10-01-01-15-031 29 GLP10-01-01-15-032 30 GLP10-01-01-15-033 31 GLP10-01-01-15-034 32 GLP10-01-01-15-035 33 GLP10-01-01-15-036 34 GLP10-01-01-15-037 35 GLP10-01-01-15-038 36 GLP10-01-01-15-039 37 GLP10-01-01-15-040 38 GLP10-01-01-15-041 39 GLP10-01-01-15-042 40 GLP10-01-01-15-043 41 GLP10-01-01-15-044 42 GLP10-01-01-15-045 43 GLP10-01-01-15-046 44 GLP10-01-01-15-047 l I \y In: storage ID 1 Init/date G * i 3 - >y " J Comments/lnitJdate t V/ b\ 1l r 1 3M Study GLP10-01-02-15 Page 1 of 2 Page 115 of 514 INTERNAL CHAIN-OF-CUSTODY environmental laboratory Sample Internal Transfer Sample set ID # Urns# N/A GLP10-01-01-15 Sample Description: Decatur Soils INTERNALCHAINOFCUSTODY # 3M Sample IDs 45 GLP10-01-01-15-048 46 GLP10-01-01-15-049 47 GLP10-01-01-15-050 48 GLP10-01-01-15-051 49 GLP10-01-01-15-052 50 GLP10-01-01-15-053 51 GLP10-01-01-15-054 52 GLP10-01-01-15-055 53 GLP10-01-01-15-056 54 GLP10-01-01-15-057 55 GLP10-01-01-15-058 56 GLP10-01-01-15-059 57 GLP10-01-01-15-060 58 GLP10-01-01-15-061 59 GLP10-01-01-15-062 60 GLP10-01-01-15-063 61 GLP10-01-01-15-064 62 GLP10-01-01-15-065 63 GLP10-01-01-15-066 64 GLP10-01-01-15-067 65 GLP10-01-01-15-068 66 GLP10-01-01-15-069 67 GLP10-01-01-15-070 68 GLP10-01-01-15-071 69 GLP10-01-01-15-072 70 GLP10-01-01-15-073 71 GLP10-01-01-15-074 72 GLP10-01-01-15-075 73 GLP10-01-01-15-076 74 GLP10-01-01-15-077 75 GLP10-01-01-15-079 76 GLP10-01-01-15-080 77 GLP10-01-01-15-081 78 GLP10-01-01-15-082 79 GLP10-01-01-15-083 80 GLP10-01-01-15-084 81 GLP10-01-01-15-085 82 GLP10-01-01-15-086 83 GLP10-01-01-15-087 84 GLP10-01-01-15-088 85 GLP10-01-01-15-089 86 GLP10-01-01-15-090 87 GLP10-01-01-15-091 88 GLP10-01-01-15-092 Out: storage ID UO.o\ -------- ^ ---------- InitJdate In: storage ID <SP<*J-S-'i L~rfl-o t ^ ___ / ]/ InitJdate Comments/lnit/date ( / I / 1 I I / 'v/ 1* Vt I P)l r (> / \y I 3M Study GLP10-01-02-15 Page 2 of 2 Page 116 of 514 GLP10-01-01-15 Sample ID Sample Description 1 GLP10-01-01-15-001 GLP10-01-01-15-001 Dup GLP10-01-01-15-002 GLP10-01-01-15-002 Dup GLP10-01-01-15-003 GLP10-01-01-15-003 Dup GLP10-01-01-15-004 GLP10-01-01-15-004 Dup GLP10-01-01-15-005 GLP10-01-01-15-005 Dup GLP10-01-01-15-006 GLP10-01-01-15-006 Dup GLP10-01-01-15-007 GLP10-01-01-15-007 Dup GLP10-01-01-15-008 GLP10-01-01-15-008 Dup GLP10-01-01-15-009 GLP10-01-01-15-009 Dup GLP10-01-01-15-010 GLP10-01-01-15-010 Dup GLP10-01-01-15-011 GLP10-01-01-15-011 Dup GLP10-01-01-15-012 GLP10-01-01-15-012 Dup GLP10-01-01-15-014 GLP10-01-01-15-014 Dup GLP10-01-01-15-015 GLP10-01-01-15-015 Dup GLP10-01-01-15-016 GLP10-01-01-15-016 Dup 2 DAL SS SS Tripl 0 0000 DAL SS SS Tripl 0 0000 Lab Duplicate DAL SS SS12 0 0000 DAL SS SS12 0 0000 Lab Duplicate DAL SS SS12 0 0005 DAL SS SS12 0 0005 Lab Duplicate DAL SS SS13 0 0000 DAL SS SS13 0 0000 Lab Duplicate DAL SS SS16 0 0000 DAL SS SS16 0 0000 Lab Duplicate DAL SS SS16 DB 0000 DAL SS SS16 DB 0000 Lab Duplicate DAL SSSS11 0 0000 DAL SS SS11 0 0000 Lab Duplicate DAL SS SS11 0 0005 DAL SS SS11 0 0005 Lab Duplicate DAL SS SS20 0 0000 DAL SS SS20 0 0000 Lab Duplicate DAL SS SS20 DB 0000 DAL SS SS20 DB 0000 Lab Duplicate DAL SS SS19 0 0000 DAL SS SS19 0 0000 Lab Duplicate DAL SS SS19 0 0005 DAL SS SS19 0 0005 Lab Duplicate DAL SS SS15 0 0000 DAL SS SS15 0 0000 Lab Duplicate DAL SS SS17 0 0000 DAL SS SS17 0 0000 Lab Duplicate DAL SS SS14 0 0000 DAL SS SS14 0 0000 Lab Duplicate Column 3: Balance ID: Initial/Date: 909 mmh 3/14/11 Column 4: Balance ID: Temp of Oven ('C): Oven Time/Date In: Initial/Date: 909 105.6 3/14/2011 17:07 mmh 3/14/11 Oven ID: OV-1 Probe ID: Probe #1, RTD #14 % Moisture Determination Weight of Weighing Dish (g) Initial Weight (soil + Dish) (g) 1st Determination Weight (soil + Dish) (g) Difference (9) 2nd Determination Weight (soil + Dish) (g) Difference % Moisture * (g) 3 1.1562 1.1599 1.1630 1.1241 1.1781 1.1691 1.1879 1.1905 1.1903 1.1481 1.1757 1.1333 1.1308 1.1376 1.1224 1.1704 1.1690 1.1799 1.1638 1.1720 1.1938 1.1536 1.1800 1.1230 1.1613 1.1877 1.1575 1.1289 1.1732 1.1670 4 2.1775 2.3264 3.6895 3.6786 2.2711 2.8050 3.0341 2.8630 2.2951 2.3545 2.3462 2.3917 2.5694 2.9202 2.4203 2.3584 3.0387 2.4120 2.5073 2.4825 2.4688 2.3945 2.1600 2.2433 3.5783 2.8825 2.3600 2.5039 2.2381 2.3088 5 2.1430 2.2867 3.2297 3.2457 2.1807 2.6687 2.7249 2.5922 2.1011 2.1384 2.1075 2.1628 2.3392 2.6587 2.3194 2.2272 2.8978 2.3268 2.4003 2.3730 2.3500 2.2710 1.9999 2.0558 3.2826 2.7856 2.3048 2.4444 2.0930 2.1413 6 0.0345 0.0397 0.4598 0.4329 0.0904 0.1363 0.3092 0.2708 0.1940 0.2161 0.2387 0.2289 0.2302 0.2615 0.1009 0.1312 0.1409 0.0852 0.1070 0.1095 0.1188 0.1235 0.1601 0.1875 0.2957 0.0969 0.0552 0.0595 0.1451 0.1675 7 2.1441 2.2878 3.2302 3.2450 2.1809 2.6678 2.7249 2.5945 2.1012 2.1381 2.1071 2.1631 2.3394 2.6588 2.3192 2.2271 2.8983 2.3270 2.4002 2.3731 2.3501 2.2711 2.0000 2.0561 3.2830 2.7858 2.3048 2.4445 2.0931 2.1413 8 -0.0011 -0.0011 -0.0005 0.0007 -0.0002 0.0009 0.0000 -0.0023 -0.0001 0.0003 0.0004 -0.0003 -0.0002 -0.0001 0.0002 0.0001 -0.0005 -0.0002 0.0001 -0.0001 -0.0001 -0.0001 -0.0001 -0.0003 -0.0004 -0.0002 0.0000 -0.0001 -0.0001 0.0000 11 3.27 3.31 18.2 17.0 8.25 8.39 16.7 16.1 17.6 17.9 20.4 18.2 16.0 14.7 7.79 11.1 7.51 6.90 7.97 8.35 9.31 9.94 16.3 16.7 12.2 5.71 4.59 4.32 13.6 14.7 Average % Moisture 12 3.29 17.6 8.32 16.4 17.7 19.3 15.3 9.42 7.20 8.16 9.63 16.5 8.96 4.46 14.1 RPD (% Moisture) 13 1.2 6.9 1.6 4.2 2.2 12 8.6 35 8.5 4.6 6.6 2.3 73 6.1 7.4 Column 5: Temp of Oven ('C): Oven Time/Date Out: Oven Time/Date In: Balance ID: Initial/Date: 103.2 3/15/2011 10:17 3/15/2011 10:38 909 3/15/2011 mmh * The last recorded weight is used for the calculation of % moisture. Column 7: Temp of Oven ('C): Oven Time/Date Out: Oven Time/Date In: N/A Balance ID: Initial/Date: 100.2 3/15/2011 13:24 909 3/15/11 mmh 3M Study GLP10-01-02-15 Page 1 of 1 Page 117fof 5 GLP10-01-01- Sample ID Sample Description 1 GLP10-01-01-15-001 GLP10-01-01-15-001 Dup GLP10-01-01-15-002 GLP10-01-01-15-002 Dup GLP10-01-01-15-003 GLP10-01-01-15-003 Dup GLP10-01-01-15-004 GLP10-01-01-15-004 Dup GLP10-01-01-15-005 GLP10-01-01-15-005 Dup GLP10-01-01-15-006 GLP10-01-01-15-006 Dup GLP10-01-01-15-007 GLP10-01-01-15-007 Dup GLP10-01-01-15-008 GLP10-01-01-15-008 Dup GLP10-01-01-15-009 GLP10-01-01-15-009 Dup GLP10-01-01-15-010 GLP10-01-01-15-010 Dup GLP10-01-01-15-011 GLP10-01-01-15-011 Dup GLP10-01-01-15-012 GLP10-01-01-15-012 Dup GLP10-01-01-15-014 GLP10-01-01-15-014 Dup GLP10-01-01-15-015 GLP10-01-01-15-015 Dup GLP10-01-01-15-016 GLP10-01-01-15-016 Dup 2 DAL SS SS Tripl 0 0000 DAL SS SS Tripl 0 0000 Lab Duplicate DAL SS SS12 0 0000 DAL SS SS12 0 0000 Lab Duplicate DAL SS SS12 0 0005 DAL SS SS12 0 0005 Lab Duplicate DAL SS SS13 0 0000 DAL SS SS13 0 0000 Lab Duplicate DAL SS SS16 0 0000 DAL SS SS16 0 0000 Lab Duplicate DAL SS SS16DB0000 DAL SS SS16 DB 0000 Lab Duplicate DAL SS SS11 0 0000 DAL SS SS11 0 0000 Lab Duplicate DAL SS SS11 0 0005 DAL SS SS11 0 0005 Lab Duplicate DAL SS SS20 0 0000 DAL SS SS20 0 0000 Lab Duplicate DAL SS SS20 DB 0000 DAL SS SS20 DB 0000 Lab Duplicate DAL SS SS19 0 0000 DAL SS SS19 0 0000 Lab Duplicate DAL SS SS19 0 0005 DAL SS SS19 0 0005 Lab Duplicate DAL SS SS15 0 0000 DAL SS SS15 0 0000 Lab Duplicate DAL SS SS17 0 0000 DAL SS SS17 0 0000 Lab Duplicate DAL SS SS14 0 0000 DAL SS SS14 0 0000 Lab Duplicate Column 3: Balance ID: Initial/Date: Column 4: Balance ID: Temp of Oven ("C): Oven Tlme/Date In: Initial/Date: 909 105.6 3/14/2011 17:07 mmh 3/14/11 Oven ID: OV-1 Probe ID: Probe #1, RTD #14 \ % Moisture Determination Weight of Weighing Dish (g) Initial Weight (soil + Dish) (g) 1st Determination Weight (soil + lsh) (g) Difference (9) 2nd Determination Weight (soil + Dish) (g) Difference % Moisture * (9) Average % Moisture RPD (% Moisture) 3 1.1562 1.1599 1.1630 1.1241 1.1781 1.1691 1.1879 1.1905 1.1903 1.1481 1.1757 1.1333 1.1308 1.1376 1.1224 1.1704 1.1690 1.1799 1.1638 1.1720 1.1938 1.1536 1.1800 1.1230 1.1613 1.1877 1.1575 1.1289 1.1732 1.1670 4 2.1775 2.3264 3.6895 3.6786 2.2711 2.8050 3.0341 2.8630 2.2951 2.3545 2.3462 2.3917 2.5694 2.9202 2.4203 2.3584 3.0387 2.4120 2.5073 2.4825 2.4688 2.3945 2.1600 2.2433 3.5783 2.8825 2.3600 2.5039 2.2381 2.3088 567 w a rn fl-- h `* *- aaaaaaam m. *9 m * mam * mam M Wmtmm -m Sr * t r- mamas t mam * 8 11 u m % .-' - m m ; u- : i m m m - ' : UrJL- mmam .VM - mm 12 13 .. ;; , . ** . i-.' ** ty & m p ^K m ^ '0 (V - - ~JA. mammKM, '-m * ' 'A; ,, 0 ^ , ' WBiMMMik . mt , im y *, tn m mm K y,,,, lllll! 'm-. \ W%0?0$I$\ W$$$$mm M M B1 fe e m am mH - ma y, SSi &' m am -m . 1 -lM i a fc r m & i: ' . a Y; ( I' i;. i- V o*. - mmmmsm l -3 Ti ' * ? ? -, im s s < i,x ^ Column 5: Temp of Oven ('C): Oven Time/Date Out: Oven Time/Date In: Balance ID: Initial/Date: * The last recorded weight is used for the calculation of % moisture. Column 7: Temp of Oven ('C): Oven Time/Date Out: Oven Time/Date In: N/A Balance ID: Initial/Date: 3M Study GLP10-01-02-15 Page 1 of 1 G L P 10-01-01-15 Sample ID Sample Description 1 GLP10-01-01-15-018 GLP10-01-01-15-018 Dup GLP10-01-01-15-020 GLP10-01-01-15-020 Dup GLP10-01-01-15-021 GLP10-01-01-15-021 Dup GLP10-01-01-15-022 GLP10-01-01-15-022 Dup GLP10-01-01-15-023 GLP10-01-01-15-023 Dup GLP10-01-01-15-024 GLP10-01-01-15-024 Dup GLP10-01-01-15-025 GLP10-01-01-15025 Dup GLP10-01-01-15-026 GLP10-01-01-15-026 Dup GLP10-01-01-15-027 GLP10-01-01-15-027 Dup GLP10-01-01-15028 GLP10-01-01-15-028 Dup GLP10-01-01-15029 GLP10-01-01-15029 Dup GLP10-01-01-15030 GLP10-01-01-15030 Dup GLP10-01-01-15031 GLP10-01-01-15031 Dup GLP10-01-01-15032 GLP10-01-01-15032 Dup GLP10-01-01-15033 GLP10-Q1-01-15Q33 Dup GLP1501-01-15034 GLP10-01-01-15034 Dup GLP10-01-01-15-035 GLP10-01-01-15035 Dup GLP10-01-01-15-036 GLP1501-01-15036 Dup GLP1501-01-15037 GLP10-01-01-15037 Dup GLP10-01-01-15-038 GLP10-01-01-15-038 Dup 2 DAL SS SS18 0 0000 DAL SS SS18 0 0000 Lab Duplicate DAL SS SS10 0 0000 DAL SS SS10 0 0000 Lab Duplicate DAL SS SS30 0 0000 DAL SS SS30 0 0000 Lab Duplicate DAL SS SS30 0 0005 DAL SS SS30 0 0005 Lab Duplicate DAL SS SS30 0 0015 DAL SS SS30 0 0015 Lab Duplicate DAL SS SS25 0 0000 DAL SS SS25 0 0000 Lab Duplicate DAL SS SS25 0 0005 DAL SS SS25 0 0005 Lab Duplicate DAL SS SS25 0 0015 DAL SS SS25 0 0015 Lab Duplicate DAL SD SD22 0 0000 DAL SD SD22 0 0000 Lab Duplicate DAL SD SD22 0 0005 DAL SD SD22 0 0005 Lab Duplicate DAL SD SD22 DB 0005 DAL SD SD22 DB 0005 Lab Duplicate DAL SD SD22 0 0015 DAL SD SD22 0 0015 Lab Duplicate DAL SD SD21 0 0000 DAL SD SD21 0 0000 Lab Duplicate DAL SD SD21 0 0005 DAL SD SD21 0 0005 Lab Duplicate DAL SD SD21 0 0015 DAL SD SD21 0 0015 Lab Duplicate DAL SS SS24 0 0000 DAL SS SS24 0 0000 Lab Duplicate DAL SS SS24 0 0005 DAL SS SS24 0 0005 Lab Duplicate DAL SS SS24 0 0015 DAL SS SS24 0 0015 Lab Duplicate DAL SS SS29 0 0000 DAL SS SS29 0 0000 Lab Duplicate DAL SS SS29 0 0005 DAL SS SS29 0 0005 Lab Duplicate % Moisture Determination Weight of Weighing Dish (g) Initial Weight (soil + Dish) (g) 1st Determination Weight (soil + Dish) (g) Difference (9) 2 nd Determination Weight (soil + Dish) (g) Difference % Moisture * (g) 3 ' 1.1214 1.1595 1.1912 1.1941 1.1900 1.1331 1.1733 1.1193 1.1572 1.1967 1.1606 1.1882 1.1641 1.1808 1.1405 1.1924 1.1239 1.1232 1.1757 1.1940 1.1820 1.1306 1.1226 1.1785 1.1877 1.1911 1.1643 1.1344 1.1772 1.1834 1.1430 1.1781 1.1951 1.1993 1.1313 1.1328 1.1365 1.1274 1.1575 1.1962 4 2.2208 2.3364 2.2642 2.6967 2.6088 2.6379 3.2595 3.0645 2.8422 2.5418 2.9411 3.0754 2.3811 2.6379 2.4915 2.5143 3.2150 3.1139 4.0405 3.4403 2.6314 3.0745 3.1237 2.8639 3.0818 4.4710 3.3083 2.8889 3.0002 3.2653 3.0973 2.8913 2.7825 3.0260 3.6210 3.2937 2.2325 2.5189 2.6351 2.5287 5 2.1189 2.2141 2.0144 2.3348 2.3137 2.3611 2.8959 2.7218 2.4999 2.2776 2.4814 2.5740 2.2094 2.4351 2.2678 2.2952 2.6979 2.5890 3.5422 3.0361 2.3714 2.7396 2.7978 2.5904 2.4466 3.3669 2.7563 2.4588 2.6880 2.9204 2.7344 2.5701 2.3757 2.5696 3.1714 2.9038 2.0128 2.2243 2.4230 2.3453 6 0.1019 0.1223 0.2498 0.3619 0.2951 0.2768 0.3636 0.3427 0.3423 0.2642 0.4597 0.5014 0.1717 0.2028 0.2237 0.2191 0.5171 0.5249 0.4983 0.4042 0.2600 0.3349 0.3259 0.2735 0.6352 1.1041 0.5520 0.4301 0.3122 0.3449 0.3629 0.3212 0.4068 0.4564 0.4496 0.3899 0.2197 0.2946 0 .2 1 2 1 0.1834 7 2.1191 2.2176 2.0140 2.3338 2.3128 2.3600 2.8956 2.7212 2.4990 2.2773 2.4806 2.5735 2.2087 2.4341 2.2667 2.2944 2.6962 2.5881 3.5415 3.0356 2.3717 2.7388 2.7965 2.5896 2.4451 3.3650 2.7547 2.4584 2.6871 2.9187 2.7335 2.5684 2.3747 2.5681 3.1702 2.9027 2.0116 2.2231 2.4225 2.3446 8 -0.0002 -0.0035 0.0004 0.0 0 10 0.0009 0 .0 0 1 1 0.0003 0.0006 0.0009 0.0003 0.0008 0.0005 0.0007 0 .0 0 1 0 0 .0 0 1 1 0.0008 0.0017 0.0009 0.0007 0.0005 -0.0003 0.0008 0.0013 0.0008 0.0015 0.0019 0.0016 0.0004 0.0009 0.0017 0.0009 0.0017 0.0 0 10 0.0015 0 .0 0 1 2 0 .0 0 1 1 0 .0012 0 .0 0 1 2 0.0005 0.0007 11 9.25 10.1 23.3 24.2 20.9 18.5 17.4 17.6 20.4 19.7 25.9 26.6 14.2 14.0 16.6 16.6 24.8 26.4 17.4 18.0 17.9 17.3 16.4 16.3 33.6 33.7 25.8 24.5 17.2 16.6 18.6 18.8 25.7 25.1 18.1 18.1 2 0 .2 21.3 14.4 13.8 Average % Moisture 12 9.67 23.7 19.7 17.5 2 0 .0 26.2 ___ 14.1 16.6 25.6 17.7 17.6 16.3 33.7 25.2 16.9 18.7 25.4 18.1 20.7 14.1 RPD (% Moisture) 13 8.7 3.5 12 1.2 3.5 2 .8 1.3 0.026 6.3 3.4 3.7 0.47 0.31 5.1 3.1 1.2 2.5 0.1 5.3 4.1 3M Study GLP10-01-02-15 Page 1 of 3 Page 119 of |514 GLP10-01-01-15 Sample ID Sample Description 1 GLP10-01-01-15-039 GLP10-01-01-15-039 Dup GLP10-01-01-15-040 GLP10-01-01-15-040 Dup GLP10-01-01-15-041 GLP10-01-01-15-041 Dup GLP10-01-01-15-042 GLP10-01-01-15-042 Dup GLP10-01-01-15-043 GLP10-01-01-15-043 Dup GLP10-01-01-15-044 GLP10-01-01-15-044 Dup GLP10-01-01-15-045 GLP10-01-01-15-045 Dup GLP10-01-01-15-046 GLP10-01-01-15-046 Dup GLP1001-01-15-047 GLP100101-15-047 Dup GLP1001-01-15-048 GLP100101-15048 Dup GLP100101-15049 GLP10-01-01-15-049 Dup GLP1001-01-15-050 GLP100101-15050 Dup GLP10-0101-15-051 GLP100101-15-051 Dup GLP100101-15052 GLP10-01-01-15-052 Dup GLP10O1-01-15-053 GLP10-01-01-15-053 Dup GLP10-0101-15-054 GLP100101-15054 Dup GLP1001-01-15055 GLP100101-15055 Dup GLP100101-15056 GLP10-01-01-15-056 Dup GLP100101-15-057 GLP100101-15057 Dup 2 DAL SS SS29 0 0015 DAL SS SS29 0 0015 Lab Duplicate DAL SS SS20 0 0005 DAL SS SS20 0 0005 Lab Duplicate DAL SS SS13 0 0005 DAL SS SS13 0 0005 Lab Duplicate DAL SS SS13 DB 0005 DAL SS SS13 DB 0005 Lab Duplicate DAL SS SS15 0 0005 DAL SS SS15 0 0005 Lab Duplicate DAL SS SS17 0 0005 DAL SS SS17 0 0005 Lab Duplicate DAL SS SS14 0 0005 DAL SS SS14 0 0005 Lab Duplicate DAL SS SS18 0 0005 DAL SS SS18 0 0005 Lab Duplicate DAL SS SS16 0 0005 DAL SS SS16 0 0005 Lab Duplicate DAL SS SS16 0 0015 DAL SS SS16 0 0015 Lab Duplicate DAL SS SS10 0 0005 DAL SS SS10 0 0005 Lab Duplicate DAL SS SS10DB0005 DAL SS SS10 DB 0005 Lab Duplicate DAL SS SS10 0 0015 DAL SS SS10 0 0015 Lab Duplicate DAL SD SD20 0 0000 DAL SD SD20 0 0000 Lab Duplicate DAL SD SD20 0 0005 DAL SD SD20 0 0005 Lab Duplicate DAL SD SD20 0 0015 DAL SD SD20 0 0015 Lab Duplicate DAL SD SD23 0 0000 DAL SD SD23 0 0000 Lab Duplicate DAL SD SD23 0 0005 DAL SD SD23 0 0005 Lab Duplicate DAL SD SD23 0 0015 DAL SD SD23 0 0015 Lab Duplicate % Moisture Determination Weight of Weighing Dish (g) Initial Weight (soil + Dish) (g) 1st Determination Weight (soil + Dish) (g) Difference (g) 2 nd Determination Weight (soil + Dish) (g) Difference % Moisture * (g) 3 1.1863 1.1897 1.1259 1.1247 1.1495 1.1740 1.1708 1.1777 1.1334 1.1684 1.1250 1.1233 1.1459 1.1213 1.1430 1.1577 1.1379 1.1843 1.1624 1.1357 1.1806 1.1647 1.1287 1.1136 1.1217 1.1271 1.1349 1.1897 1.1561 1.1311 1.1329 1.1278 1.1726 1.1810 1.1880 1.1375 1.1634 1.1715 4 2.5699 2.6672 2.2414 2.2369 2.5504 2.5060 2.6309 2.6814 2.8395 2.5637 2.2623 2.3955 2.2448 2.9343 2.3903 3.0758 2.7787 2.4065 2.2857 2.2519 3.9534 2.9220 2.6899 2.4282 3.3924 4.0129 3.1985 3.4565 3.2868 2.8154 2.3546 2.4192 3.6142 2.7795 2.5308 2.4439 2.4322 2.3651 5 2.3024 2.3873 2.0308 2 .0 1 0 2 2.3072 2.2627 2.3626 2.4018 2.5602 2.3600 2.0427 2.1677 2.1387 2.6990 2.1828 2.7629 2.5260 2.2131 2.0995 2.0740 3.5708 2.6841 2.4728 2.2507 2.8617 3.3597 2.5070 2.7517 2.7056 2.3663 2.0445 2.1035 3.0810 2.4196 2.3028 2.2286 2.2371 2.1842 6 0.2675 0.2799 0.2106 0.2267 0.2432 0.2433 0.2683 0.2796 0.2793 0.2037 0.2196 0.2278 0.1061 0.2353 0.2075 0.3129 0.2527 0.1934 0.1862 0.1779 0.3826 0.2379 0.2171 0.1775 0.5307 0.6532 0.6915 0.7048 0.5812 0.4491 0.3101 0.3157 0.5332 0.3599 0.2280 0.2153 0.1951 0.1809 7 2.3013 2.3864 2.0295 2.0093 2.3057 2.2610 2.3609 2.4002 2.5592 2.3591 2.0411 2.1662 2.1377 2.6970 2.1816 2.7609 2.5245 2.2123 2.0985 2.0726 3.5690 2.6824 2.4715 2.2491 2.8600 3.3564 2.5026 2.7478 2.7012 2.3633 2.0415 2.1003 3.0771 2.4161 2.3008 2.2266 2.2336 2.1824 8 0 .0 0 1 1 0.0009 0.0013 0.0009 0.0015 0.0017 0.0017 0.0016 0 .0 0 10 0.0009 0.0016 0.0015 0 .0 0 10 0 .0 0 20 0 .0 0 1 2 0 .0 0 20 0.0015 0.0008 0.0 0 10 0.0014 0.0018 0.0017 0.0013 0.0016 0.0017 0.0033 0.0044 0.0039 0.0044 0.0030 0.0030 0.0032 0.0039 0.0035 0 .0 0 2 0 0.0 0 20 0.0035 0.0018 11 19.4 19.0 19.0 20.5 17.5 18.4 18.5 18.7 16.4 14.7 19.4 18.0 9.75 13.1 16.7 16.4 15.5 15.9 16.7 16.1 13.9 13.6 14.0 13.6 23.4 22.7 33.7 31.3 27.5 26.8 25.6 24.7 2 2 .0 22.7 17.1 16.6 15.7 15.3 Average % Moisture 12 19.2 19.7 17.9 18.6 15.5 18.7 11.4 16.6 15.7 16.4 13.7 13.8 23.1 32.5 27.2 25.2 22.4 16.9 15.5 RPD (% Moisture) 13 2.1 7.4 5.2 1.1 11 7.6 29 1.9 2.5 3.7 1.7 2 .6 3.0 7.6 2.4 3.7 3.3 2.9 2 .2 3M Study GLP10-01-02-15 Page 2 of 3 Page 120 of 514 GLP10-01-01-15 % Moisture Determination Sample ID Sample Description GLP10-01-01-15-058 GLP10-01-01-15-058 Dup GLP10-01-01-15-059 GLP10-01-01-15-059 Dup GLP10-01-01-15-060 GLP10-01-01-15-060 Dup GLP10-01-01-15-061 GLP10-01-01-15-061 Dup GLP10-01-01-15-062 GLP10-01-01-15-062 Dup GLP10-01-01-15063 GLP10-01-01-15-063 Dup 2 DAL SS SS28 0 0000 DAL SS SS28 0 0000 Lab Duplicate DAL SS SS28 0 0005 DAL SS SS28 0 0005 Lab Duplicate DAL SS SS28 DB 0005 DAL SS SS28 DB 0005 Lab Duplicate DAL SS SS28 0 0015 DAL SS SS28 0 0015 Lab Duplicate DAL SS SS27 0 0000 DAL SS SS27 0 0000 Lab Duplicate DAL SS SS27 0 0005 DAL SS SS27 0 0005 Lab Duplicate . Column 3: Balance ID: Initial/Date: 909 3/15/2011 Column 4: Balance ID: Temp of Oven (-C): Oven Time/Date In: Initial/Date: for samples 18 to 31 909 102.3 3/15/2011 11:40 mmh 3/15/11 Balance ID: Temp of Oven fC): Oven Time/Date In: Initial/Date: for samples 32 to 63 909 102.7 3/15/2011 16:45 mmh 3/15/11 Oven ID: OV-1 Probe ID: Probe #1, RTD #14 Weight of Weighing Dish (g) Initial Weight (soil Dish) (9) 1st Determination Weight (soil + Dish) (g) Difference (g) 2 nd Determination Weight (soil + Dish) (g) Difference % Moisture * (g) 3 1.1228 1.1859 1.1848 1.1591 1.1834 1.1624 1.1928 1.1981 1.1408 1.1250 1.1842 1.1739 4 2.3002 2.2941 2.4479 2.5060 2.4183 2.4787 2.3628 2.7749 3.0224 2.4720 2.4285 2.3950 5 2.1183 2.1225 2.2688 2.3104 2.2346 2.2906 2.1087 2.4463 2.7389 2.2625 2.2555 2.2311 6 0.1819 0.1716 0.1791 0.1956 0.1837 0.1881 0.2541 0.3286 0.2835 0.2095 0.1730 0.1639 7 2.1158 2.1190 2.2658 2.3073 2.2316 2.2877 2.1058 2.4421 2.7340 2.2590 2.2524 2.2277 8 0.0025 0.0035 0.0030 0.0031 0.0030 0.0029 0.0029 0.0042 0.0049 0.0035 0.0031 0.0034 11 15.7 15.8 14.4 14.8 15.1 14.5 2 2 .0 21.1 15.3 15.8 14.2 13.7 Average % Moisture 12 15.7 14.6 14.8 21.5 15.6 13.9 RPD (% Moisture) 13 0.9 2.3 4.1 4.0 3.1 3.2 Column 5: Temp of Oven (X): Oven Time/Date Out: Oven Time/Date In: Balance ID: Initial/Date: 94.8 10:14am 3/16/11 11:05am 3/16/11 909 3/16/11 mmh * The last recorded weight is used for the calculation of % moisture. Column 7: Temp of Oven (X): Oven Time/Date Out: Oven Time/Date In: N/A Balance ID: Initial/Date: 100.7 3/18/2011 10:07 909 3/18/2011 3M Study GLP10-01-02-15 Page 3 of 3 Page 121 of 514 GLP10-01-01-15 Sample ID Sample Description 1 GLP10-01-01-15-018 GLP10-01-01-15-018 Dup GLP10-01-01-15-020 GLP10-01-01-15-020 Dup GLP10-01-01-15-021 GLP10-01-01-15-021 Dup GLP10-01-01-15-022 GLP10-01-01-15-022 Dup GLP10-01-01-15-023 GLP10-01-01-15-023 Dup GLP10-01-01-15-024 GLP10-01-01-15-024 Dup GLP10-01-01-15-025 GLP10-01-01-15-025 Dup GLP10-01-01-15-026 GLP10-01-01-15-026 Dup GLP10-01-01-15-027 GLP10-01-01-15-027 Dup GLP10-01-01-15-028 GLP10-01-01-15-028 Dup GLP10-01-01-15-029 GLP10-01-01-15-029 Dup GLP10-01-01-15-030 GLP10-01-01-15-030 Dup GLP10-01-01-15-031 GLP10-01-01-15-031 Dup GLP10-01-01-15-032 GLP10-01-01-15-032 Dup GLP10-01-01-15033 GLP10-01-01-15-033 Dup GLP10-01-01-15-034 GLP10-01-01-15-034 Dup GLP10-01-01-15-035 GLP10-01-01-15-035 Dup GLP10-01-01-15-036 GLP10-01-01-15036 Dup GLP10-01-01-15-037 GLP10-01-01-15037 Dup GLP10-01-01-15038 GLP10-01-01-15-038 Dup 2 DAL SS SS18 0 0000 DAL SS SS18 0 0000 Lab Duplicate DAL SS SS10 0 0000 DAL SS SS10 0 0000 Lab Duplicate DAL SS SS30 0 0000 DAL SS SS30 0 0000 Lab Duplicate DAL SS SS30 0 0005 DAL SS SS30 0 0005 Lab Duplicate DAL SS SS30 0 0015 DAL SS SS30 0 0015 Lab Duplicate DAL SS SS25 0 0000 DAL SS SS25 0 0000 Lab Duplicate DAL SS SS25 0 0005 DAL SS SS25 0 0005 Lab Duplicate DAL SS SS25 0 0015 DAL SS SS25 0 0015 Lab Duplicate DAL SD SD22 0 0000 DAL SD SD22 0 0000 Lab Duplicate DAL SD SD22 0 0005 DAL SD SD22 0 0005 Lab Duplicate DAL SD SD22 DB 0005 DAL SD SD22 DB 0005 Lab Duplicate DAL SD SD22 0 0015 DAL SD SD22 0 0015 Lab Duplicate DAL SD SD21 0 0000 DAL SD SD21 0 0000 Lab Duplicate DAL SD SD21 0 0005 DAL SD SD21 0 0005 Lab Duplicate DAL SD SD21 0 0015 DAL SD SD21 0 0015 Lab Duplicate DAL SS SS24 0 0000 DAL SS SS24 0 0000 Lab Duplicate DAL SS SS24 0 0005 DAL SS SS24 0 0005 Lab Duplicate DAL SS SS24 0 0015 DAL SS SS24 0 0015 Lab Duplicate DAL SS SS29 0 0000 DAL SS SS29 0 0000 Lab Duplicate DAL SS SS29 0 0005 DAL SS SS29 0 0005 Lab Duplicate % Moisture Determination Weight of Weighing Dish (g) Initial Weight (soil + Dish) (g) 1st Determination Weight (soil + Dish) (g) Difference (9) 2 nd Determination Weight (soli + Dish) (g) Difference % Moisture * (g) 3 1.1214 1.1595 1.1912 1.1941 1.1900 1.1331 1.1733 1.1193 1.1572 1.1967 1.1606 1.1882 1.1641 1.1808 1.1405 1.1924 1.1239 1.1232 1.1757 1.1940 1.1820 1.1306 1.1226 1.1785 1.1877 1.1911 1.1643 1.1344 1.1772 1.1834 1.1430 1.1781 1.1951 1.1993 1.1313 1.1328 1.1365 1.1274 1.1575 1.1962 4 2.2208 2.3364 2.2642 2.6967 2.6088 2.6379 3.2595 3.0645 2.8422 2.5418 2.9411 3.0754 2.3811 2.6379 2.4915 2.5143 3.2150 3.1139 4.0405 3.4403 2.6314 3.0745 3.1237 2.8639 3.0818 4.4710 3.3083 2.8889 3.0002 3.2653 3.0973 2.8913 2.7825 3.0260 3.6210 3.2937 2.2325 2.5189 2.6351 2.5287 5 2.1189 2.2141 2.0144 2.3348 2.3137 2.3611 2.8959 2.7218 2.4999 2.2776 2.4814 2.5740 2.2094 2.4351 2.2678 2.2952 2.6979 2.5890 3.5422 3.0361 2.3714 2.7396 2.7978 2.5904 2.4466 3.3669 2.7563 2.4588 2.6880 2.9204 2.7344 2.5701 2.3757 2.5696 3.1714 2.9038 2.0128 2.2243 2.4230 2.3453 6 0.1019 0.1223 0.2498 0.3619 0.2951 0.2768 0.3636 0.3427 0.3423 0.2642 0.4597 0.5014 0.1717 0.2028 0.2237 0.2191 0.5171 0.5249 0.4983 0.4042 0.2600 0.3349 0.3259 0.2735 0.6352 1.1041 0.5520 0.4301 0.3122 0.3449 0.3629 0.3212 0.4068 0.4564 0.4496 0.3899 0.2197 0.2946 0 .2 1 2 1 0.1834 7 8 11 Average % Moisture 12 RPD (% Moisture) 13 3M Study GLP10-01-02-15 Page 1 of 3 Page 122 of i4 GLP10-01-01-15 Sample ID Sample Description 1 GLP10-01-01-15-039 GLP10-01-01-15-039 Dup GLP10-01-01-15-040 GLP10-01-01-15040 Dup GLP10-01-01-15-041 GLP10-01-01-15-041 Dup GLP10-01-01-15-042 GLP10-01-01-15-042 Dup GLP10-01-01-15-043 GLP10-01-01-15-043 Dup GLP10-01-01-15044 GLP10-01-01-15044 Dup GLP10-01-01-15045 GLP10-01-01-15-045 Dup GLP1501-01-15046 GLP10-01-01-15046 Dup GLP10-01-01-15047 GLP1501-01-15047 Dup GLP10-01-01-15-048 GLP10-01-01-15-048 Dup GLP10-01-01-15-049 GLP1501-01-15049 Dup GLP10-01-01-15-050 GLP10-01-01-15-050 Dup GLP1501-01-15051 GLP1501-01-15051 Dup GLP1501-01-15052 GLP1501-01-15052 Dup GLP10-01-01-15053 GLP10-01-01-15053 Dup GLP1501-01-15054 GLP1501-01-15054 Dup GLP10-01-01-15-055 GLP10-01-01-15-055 Dup GLP10-01-01-15056 GLP10-01-01-15056 Dup GLP10-01-01-15-057 GLP10-01-01-15-057 Dup 2 DAL SS SS29 0 0015 DAL SS SS29 0 0015 Lab Duplicate DAL SS SS20 0 0005 DAL SS SS20 0 0005 Lab Duplicate DAL SS SS13 0 0005 DAL SS SS13 0 0005 Lab Duplicate DAL SS SS13 DB 0005 DAL SS SS13 DB 0005 Lab Duplicate DAL SS SS15 0 0005 DAL SS SS15 0 0005 Lab Duplicate DAL SS SS17 0 0005 DAL SS SS17 0 0005 Lab Duplicate DAL SS SS14 0 0005 DAL SS SS14 0 0005 Lab Duplicate DAL SS SS18 0 0005 DAL SS SS18 0 0005 Lab Duplicate DAL SS SS16 0 0005 DAL SS SS16 0 0005 Lab Duplicate DAL SS SS16 0 0015 DAL SS SS16 0 0015 Lab Duplicate DAL SS SS10 0 0005 DAL SS SS10 0 0005 Lab Duplicate DAL SS SS10 DB 0005 DAL SS SS10 DB 0005 Lab Duplicate DAL SS SS10 0 0015 DAL SS SS10 0 0015 Lab Duplicate DAL SD SD20 0 0000 DAL SD SD20 0 0000 Lab Duplicate DAL SD SD20 0 0005 DAL SD SD20 0 0005 Lab Duplicate DAL SD SD20 0 0015 DAL SD SD20 0 0015 Lab Duplicate DAL SD SD23 0 0000 DAL SD SD23 0 0000 Lab Duplicate DAL SD SD23 0 0005 DAL SD SD23 0 0005 Lab Duplicate DAL SD SD23 0 0015 DAL SD SD23 0 0015 Lab Duplicate % Moisture Determination Weight of Weighing Dish (g) Initial Weight (soil + Dish) (g) 1 st Determination Weight (soil + Dish) (g) Difference (9) 2 nd Determination Weight (soil + Dish)(g) Difference % Moisture * (g) 3 1.1863 1.1897 1.1259 1.1247 1.1495 1.1740 1.1708 1.1777 1.1334 1.1684 1.1250 1.1233 1.1459 1.1213 1.1430 1.1577 1.1379 1.1843 1.1624 1.1357 1.1806 1.1647 1.1287 1.1136 1.1217 1.1271 1.1349 1.1897 1.1561 1.1311 1.1329 1.1278 1.1726 1.1810 1.1880 1.1375 1.1634 1.1715 4 2.5699 2.6672 2.2414 2.2369 2.5504 2.5060 2.6309 2.6814 2.8395 2.5637 2.2623 2.3955 2.2448 2.9343 2.3903 3.0758 2.7787 2.4065 2.2857 2.2519 3.9534 2.9220 2.6899 2.4282 3.3924 4.0129 3.1985 3.4565 3.2868 2.8154 2.3546 2.4192 3.6142 2.7795 2.5308 2.4439 2.4322 2.3651 5 2.3024 2.3873 2.0308 2 .0 1 0 2 2.3072 2.2627 2.3626 2.4018 2.5602 2.3600 2.0427 2.1677 2.1387 2.6990 2.1828 2.7629 2.5260 2.2131 2.0995 2.0740 3.5708 2.6841 2.4728 2.2507 2.8617 3.3597 2.5070 2.7517 2.7056 2.3663 2.0445 2.1035 3.0810 2.4196 2.3028 2.2286 2.2371 2.1842 6 0.2675 0.2799 0.2106 0.2267 0.2432 0.2433 0.2683 0.2796 0.2793 0.2037 0.2196 0.2278 0.1061 0.2353 0.2075 0.3129 0.2527 0.1934 0.1862 0.1779 0.3826 0.2379 0.2171 0.1775 0.5307 0.6532 0.6915 0.7048 0.5812 0.4491 0.3101 0.3157 0.5332 0.3599 0.2280 0.2153 0.1951 0.1809 7 8 11 Average % Moisture 12 RPD (% Moisture) 13 3M Study GLP10-01-02-15 Page 2 of 3 Page 123 of 514 GLP10-01-01-15 Sample ID Sample Description 1 GLP10-01-01-15-058 GLP10-01-01-154)58 Dup GLP10-01-01-15-059 GLP10-01-01-15-059 Dup GLP10-01-01-15-060 GLP10-01-01-15-060 Dup GLP10-01-01-15-061 GLP10-01-01-15-061 Dup GLP10-01-01-15-062 GLP10-01-01-15-062 Dup GLP10-01-01-15-063 GLP10-01-01-15-063 Dup 2 DAL SS SS28 0 0000 DAL SS SS28 0 0000 Lab Duplicate DAL SS SS28 0 0005 DAL SS SS28 0 0005 Lab Duplicate DAL SS SS28 DB 0005 DAL SS SS28 DB 0005 Lab Duplicate DAL SS SS28 0 0015 DAL SS SS28 0 0015 Lab Duplicate DAL SS SS27 0 0000 DAL SS SS27 0 0000 Lab Duplicate DAL SS SS27 0 0005 DAL SS SS27 0 0005 Lab Duplicate Column 3: Balance ID: Initial/Date: 909 3/15/2011 Column 4: Balance ID: Temp of Oven (*C): Oven Time/Date In: Initial/Date: for samples 18 to 31 909 102.3 3/15/2011 11:40 mmh 3/15/11 Balance ID: Temp of Oven ("C): Oven Time/Date In: Initial/Date: for samples 32 to 63 909 102.7 3/15/2011 16:45 mmh 3/15/11 Oven ID: OV-1 Probe ID: Probe #1, RTD #14 % Moisture Determination Weight of Weighing Dish (g) Initial Weight (soil + Dish) (g) 1st Determination Weight (soil + Dish) (g) Difference (9) 2 nd Determination Weight (soil + Dish) (g) Difference % Moisture * (9) 3 1.1228 1.1859 1.1848 1.1591 1.1834 1.1624 1.1928 1.1981 1.1408 1.1250 1.1842 1.1739 4 2.3002 2.2941 2.4479 2.5060 2.4183 2.4787 2.3628 2.7749 3.0224 2.4720 2.4285 2.3950 5 2.1183 2.1225 2.2688 2.3104 2.2346 2.2906 2.1087 2.4463 2.7389 2.2625 2.2555 2.2311 6 0.1819 0.1716 0.1791 0.1956 0.1837 0.1881 0.2541 0.3286 0.2835 0.2095 0.1730 0.1639 7 8 11 Average % Moisture 12 RPD (% Moisture) 13 Column 5: Temp of Oven (*C): Oven Time/Date Out: Oven Time/Date In: Balance ID: Initial/Date: 94.8 10:14am 3/16/11 11:05am 3/16/11 909 3/16/11 mmh W * The last recorded weight is used for the calculation of % moisture. Column 7: Temp ot Oven fC): Oven Time/Date Out: Oven Time/Date In: N/A Balance ID: Initial/Date: 3M Study GLP10-01-02-15 Page 3 of 3 Page 124 of 514 GLP10-01-01-15 Sample ID Sample Description 1 GLP10-01-01-15-018 GLP10-01-01-15-018 Dup GLP10-01-01-15-020 GLP10-01-01-15-020 Dup GLP10-01-01-15-021 GLP10-01-01-15-021 Dup GLP10-01-01-15-022 GLP10-01-01-15-022 Dup GLP10-01-01-15-023 GLP10-01-01-15-023 Dup GLP10-01-01-15-024 GLP10-01-01-15-024 Dup GLP10-01-01-15-025 GLP10-01-01-15-025 Dup GLP10-01-01-15-026 GLP10-01-01-15-026 Dup GLP10-01-01-15-027 GLP10-01-01-15-027 Dup GLP10-01-01-15-028 GLP10-01-01-15-028 Dup GLP10-01-01-15-029 GLP10-01-01-15-029 Dup GLP10-01-01-15-030 GLP10-01-01-15-030 Dup GLP10-01-01-15-031 GLP10-01-01-15-031 Dup GLP10-01-01-15-032 GLP10-01-01-15-032 Dup GLP10-01-01-15-033 GLP10-01-01-15-033 Dup GLP10-01-01-15-034 GLP10-01-01-15-034 Dup GLP10-01-01-15-035 GLP10-01-01-15-035 Dup GLP10-01-01-15-036 GLP10-01-01-15-036 Dup GLP10-01-01-15-037 GLP10-01-01-15-037 Dup GLP10-01-01-15-038 GLP10-01-01-15-038 Dup 2 DAL SS SS18 0 0000 DAL SS SS18 0 0000 Lab Duplicate DAL SS SS10 0 0000 DAL SS SS10 0 0000 Lab Duplicate DAL SS SS30 0 0000 DAL SS SS30 0 0000 Lab Duplicate DAL SS SS30 0 0005 DAL SS SS30 0 0005 Lab Duplicate DAL SS SS30 0 0015 DAL SS SS30 0 0015 Lab Duplicate DAL SS SS25 0 0000 DAL SS SS25 0 0000 Lab Duplicate DAL SS SS25 0 0005 DAL SS SS25 0 0005 Lab Duplicate DAL SS SS25 0 0015 DAL SS SS25 0 0015 Lab Duplicate DAL SD SD22 0 0000 DAL SD SD22 0 0000 Lab Duplicate DAL SD SD22 0 0005 DAL SD SD22 0 0005 Lab Duplicate DAL SD SD22 DB 0005 DAL SD SD22 DB 0005 Lab Duplicate DAL SD SD22 0 0015 DAL SD SD22 0 0015 Lab Duplicate DAL SD SD21 0 0000 DAL SD SD21 0 0000 Lab Duplicate DAL SD SD21 0 0005 DAL SD SD21 0 0005 Lab Duplicate DAL SD SD21 0 0015 DAL SD SD21 0 0015 Lab Duplicate DAL SS SS24 0 0000 DAL SS SS24 0 0000 Lab Duplicate DAL SS SS24 0 0005 DAL SS SS24 0 0005 Lab Duplicate DAL SS SS24 0 0015 DAL SS SS24 0 0015 Lab Duplicate DAL SS SS29 0 0000 DAL SS SS29 0 0000 Lab Duplicate DAL SS SS29 0 0005 DAL SS SS29 0 0005 Lab Duplicate % Moisture Determination Weight of Weighing Dish (g) Initial Weight (soil + Dish) (g) 1st Determination Weight (soil + Dish) (g) Difference (9) 2 nd Determination Weight (soil + Dish)(g) Difference % Moisture * (9) 3 4 5 6 7 8 11 1.1214 2.2208 1.1595 2.3364 1.1912 2.2642 1.1941 2.6967 1.1900 2.6088 1.1331 2.6379 1.1733 3.2595 1.1193 3.0645 1.1572 2.8422 1.1967 2.5418 1.1606 2.9411 1.1882 3.0754 1.1641 2.3811 1.1808 2.6379 1.1405 2.4915 1.1924 2.5143 1.1239 3.2150 1.1232 3.1139 1.1757 4.0405 1.1940 3.4403 1.1820 2.6314 1.1306 3.0745 1.1226 3.1237 1.1785 2.8639 1.1877 3.0818 1.1911 4.4710 1.1643 3.3083 1.1344 2.8889 1.1772 3.0002 1.1834 3.2653 1.1430 3.0973 1.1781 2.8913 1.1951 2.7825 1.1993 3.0260 1.1313 3.6210 1.1328 3.2937 1.1365 2.2325 1.1274 2.5189 1.1575 2.6351 1.1962 2.5287 Average % Moisture 12 RPD (% Moisture) 13 3M Study GLP10-01-02-15 Page 1 of 3 PageX25 of 51 GLP10-01-01-15 Sample ID Sample Description 1 GLP10-01-01-15-039 GLP10-01-01-15-039 Dup GLP10-01-01-15-040 GLP10-01-01-15-040 Dup GLP10-01-01-15-041 GLP10-01-01-15-041 Dup GLP10-01-01-15-042 GLP10-01-01-15-042 Dup GLP10-01-01-15-043 GLP10-01-01-15-043 Dup GLP10-01-01-15-044 GLP10-01-01-15-044 Dup GLP10-01-01-15-045 GLP10-01-01-15-045 Dup GLP10-01-01-15-046 GLP10-01-01-15-046 Dup GLP10-01-01-15-047 GLP10-01-01-15-047 Dup GLP10-01-01-15-048 GLP10-01-01-15-048 Dup GLP10-01-01-15-049 GLP10-01-01-15-049 Dup GLP10-01-01-15-050 GLP10-01-01-15-050 Dup GLP10-01-01-15-051 GLP10-01-01-15-051 Dup GLP10-01-01-15-052 GLP10-01-01-15-052 Dup GLP10-01-01-15-053 GLP10-01-01-15-053 Dup GLP10-01-01-15-054 GLP10-01-01-15-054 Dup GLP10-01-01-15-055 GLP10-01-01-15-055 Dup GLP10-01-01 -15-056 GLP10-01-01-15-056 Dup GLP10-01-01-15-057 GLP10-01-01-15-057 Dup 2 DALSS SS29 0 0015 DAL SS SS29 0 0015 Lab Duplicate DAL SS SS20 0 0005 DAL SS SS20 0 0005 Lab Duplicate DAL SS SS13 0 0005 DAL SS SS13 0 0005 Lab Duplicate DAL SS SS13DB 0005 DAL SS SS13 DB 0005 Lab Duplicate DAL SS SS15 0 0005 DAL SS SS15 0 0005 Lab Duplicate DAL SS SS17 0 0005 DAL SS SS17 0 0005 Lab Duplicate DAL SS SS14 0 0005 DAL SS SS14 0 0005 Lab Duplicate DAL SS SS18 0 0005 DAL SS SS18 0 0005 Lab Duplicate DAL SS SS16 0 0005 DAL SS SS16 0 0005 Lab Duplicate DAL SS SS16 0 0015 DAL SS SS16 0 0015 Lab Duplicate DAL SS SS10 0 0005 DAL SS SS10 0 0005 Lab Duplicate DAL SS SS10 DB 0005 DAL SS SS10 DB 0005 Lab Duplicate DAL SS SS10 0 0015 DAL SS SS10 0 0015 Lab Duplicate DAL SD SD20 0 0000 DAL SD SD20 0 0000 Lab Duplicate DAL SD SD20 0 0005 DAL SD SD20 0 0005 Lab Duplicate DAL SD SD20 0 0015 DAL SD SD20 0 0015 Lab Duplicate DAL SD SD23 0 0000 DAL SD SD23 0 0000 Lab Duplicate DAL SD SD23 0 0005 DAL SD SD23 0 0005 Lab Duplicate DAL SD SD23 0 0015 DAL SD SD23 0 0015 Lab Duplicate % Moisture Determination Weight of Weighing Dish (g) Initial Weight (soil + Dish) (g) 1st Determination Weight (soil + Dish) (g) Difference (g) 2 nd Determination Weight (soil + Dish) (g) Difference % Moisture* (g) 34 56 7 8 11 1.1863 2.5699 1.1897 2.6672 1.1259 2.2414 1.1247 2.2369 1.1495 2.5504 1.1740 2.5060 1.1708 2.6309 1.1777 2.6814 1.1334 2.8395 1.1684 2.5637 1.1250 2.2623 1.1233 2.3955 1.1459 2.2448 1.1213 2.9343 1.1430 2.3903 1.1577 3.0758 1.1379 2.7787 1.1843 2.4065 1.1624 2.2857 1.1357 2.2519 1.1806 3.9534 1.1647 2.9220 1.1287 2.6899 1.1136 2.4282 1.1217 3.3924 1.1271 4.0129 1.1349 3.1985 1.1897 3.4565 1.1561 3.2868 1.1311 2.8154 1.1329 2.3546 1.1278 2.4192 1.1726 3.6142 1.1810 2.7795 1.1880 2.5308 1.1375 2.4439 1.1634 2.4322 1.1715 2.3651 Average % Moisture 12 RPD (% Moisture) 13 3M Study GLP10-01-02-15 Page 2 of 3 Page 126 of 514 GLP10-01-01-15 Sample ID Sample Description 1 GLP10-01-01-15-058 GLP10-01-01-15-058 Dup GLP10-01-01-15-059 GLP10-01-01-15-059 Dup GLP1001-01-15-060 GLP1001-01-15-060 Dup GLP10-01-01-15-061 GLP10-01-01-15-061 Dup GLP10-01-01-15-062 GLP10-0101-15-062 Dup GLP1001-01-15-063 GLP1001-01-15-063 Dup 2 DAL SS SS28 0 0000 DAL SS SS28 0 0000 Lab Duplicate DAL SS SS28 0 0005 DAL SS SS28 0 0005 Lab Duplicate DAL SS SS28 DB 0005 DAL SS SS28 DB 0005 Lab Duplicate DAL SS SS28 0 0015 DAL SS SS28 0 0015 Lab Duplicate DAL SS SS27 0 0000 DAL SS SS27 0 0000 Lab Duplicate DAL SS SS27 0 0005 DAL SS SS27 0 0005 Lab Duplicate Column 3: Balance ID: Initial/Date: 909 3/15/2011 Column 4: Balance ID: Temp of Oven ("C): Oven Time/Date In: Initial/Date: for samples 18 to 31 909 102.3 11:40 AM S '/S ' 11 mmh 3/15/11 Balance ID: Temp of Oven ("C): Oven Time/Date In: Initial/Date: for samples 32 to 63 909 102.7 3/15/2011 16:45 mmh 3/15/11 Oven ID: OV-1 Probe ID: Probe #1, RTD #14 % Moisture Determination Weight of Weighing Dish (g) Initial Weight (soil + Dish) (g) 1st Determination Weight (soil + Dish) (g) Difference (9) 2 nd Determination Weight (soil + Dish) (g) Difference % Moisture * (9) 3 4 5 6 7 8 11 1.1228 2.3002 1.1859 2.2941 1.1848 2.4479 1.1591 2.5060 1.1834 2.4183 1.1624 2.4787 1.1928 2.3628 1.1981 2.7749 1.1408 3.0224 1.1250 2.4720 1.1842 2.4285 1.1739 2.3950 Average % Moisture 12 RPD (% Moisture) 13 Column 5: Temp of Oven ('C): Oven Time/Date Out: Oven Time/Date In: Balance ID: Initial/Date: * The last recorded weight is used for the calculation of % moisture. Column 7: Temp of Oven ('C): Oven Time/Date Out: Oven Time/Date In: N/A Balance ID: Initial/Date: 3M Study GLP10-01-02-15 Page 3 of 3 Page 127 of 514 GLP10-01-01-15 Sample ID Sample Description 1 GLP10-01-01-15-064 GLP10-01-01-15-064 Dup GLP10-01-01-15-065 GLP10-01-01-15-065 Dup GLP10-01-01-15-066 GLP10-01-01-15-066 Dup GLP10-01-01-15-067 GLP10-01-01-15-067 Dup GLP10-01-01-15-068 GLP10-01-01-15-068 Dup GLP10-01-01-15-069 GLP10-01-01-15-069 Dup GLP10-01-01-15-070 GLP10-01-01-15-070 Dup GLP10-01-01-15-071 GLP10-01-01-15-071 Dup GLP10-01-01-15-072 GLP10-01-01-15-072 Dup GLP10-01-01-15-073 GLP10-01-01-15-073 Dup GLP10-01-01-15-074 GLP10-01-01-15-074 Dup GLP10-01-01-15-075 GLP10-01-01-15-075 Dup GLP10-01-01-15-076 GLP10-01-01-15-076 Dup GLP10-01-01-15-077 GLP10-01-01-15-077 Dup GLP10-01-01-15-079 GLP10-01-01-15-079 Dup GLP10-01-01-15-080 GLP10-01-01-15-080 Dup GLP10-01-01-15-081 GLP10-01-01-15-081 Dup GLP10-01-01-15-082 GLP10-01-01-15-082 Dup GLP10-01-01-15-083 GLP10-01-01-15-083 Dup GLP10-01-01-15-084 GLP10-01-01-15-084 Dup 2 DAL SS SS27 0 0015 DAL SS SS27 0 0015 Lab Duplicate DAL SS SS22 0 0000 DAL SS SS22 0 0000 Lab Duplicate DAL SS SS22 0 0005 DAL SS SS22 0 0005 Lab Duplicate DAL SS SS22 DB 0005 DAL SS SS22 DB 0005 Lab Duplicate DAL SS SS22 0 0015 DAL SS SS22 0 0015 Lab Duplicate DAL SS SS21 0 0000 DAL SS SS21 0 0000 Lab Duplicate DAL SS SS21 0 0005 DAL SS SS21 0 0005 Lab Duplicate DAL SS SS21 0 0015 DAL SS SS21 0 0015 Lab Duplicate DAL SD SD18 0 0000 DAL SD SD18 0 0000 Lab Duplicate DAL SD SD18 0 0005 DAL SD SD18 0 0005 Lab Duplicate DAL SD SD18 0 0015 DAL SD SD18 0 0015 Lab Duplicate DAL SD SD19 0 0000 DAL SD SD19 0 0000 Lab Duplicate DAL SD SD19 0 0005 DAL SD SD19 0 0005 Lab Duplicate DAL SD SD19 0 0015 DAL SD SD19 0 0015 Lab Duplicate DAL SS SS26 0 0000 DAL SS SS26 0 0000 Lab Duplicate DAL SS SS26 DB 0000 DAL SS SS26 DB 0000 Lab Duplicate DAL SS SS26 0 0005 DAL SS SS26 0 0005 Lab Duplicate DAL SS SS26 0 0015 DAL SS SS26 0 0015 Lab Duplicate DAL SS Trip2 0 0000 DAL SS Trip2 0 0000 Lab Duplicate DAL SS SS12 0 0015 DAL SS SS12 0 0015 Lab Duplicate % Moisture Determination Weight of Initial Weighing Weight (soil Dish (g) + Dish) (g) 3 1.1296 1.1631 1.1486 1.1744 1.1850 1.1888 1.1574 1.2036 1.1738 1.1736 1.1361 1.1321 1.1945 1.1422 1.1528 1.1577 1.1684 1.1497 1.1214 1.1296 1.1527 1.1544 1.1406 1.1700 1.1417 1.1990 1.1259 1.1697 1.1343 1.1251 1.1611 1.1424 1.1725 1.1386 1.1461 1.1880 1.1275 1.1406 1.1251 1.1850 4 2.3664 2.5297 2.4709 3.0890 2.3545 2.2658 2.4620 2.7203 2.9019 2.5599 2.4300 2.4191 2.6983 2.6118 2.4686 3.0286 2.6223 2.5617 2.4836 2.7079 2.3003 2.3327 3.0918 2.6677 2.6297 2.4750 2.5042 3.0300 2.5200 2.7112 3.0597 2.9945 2.4617 2.3460 2.3968 2.2869 2.1092 2.2468 2.3184 2.3320 1st Determination Weight (soil + Dish) (g) 5 2.1625 2.3075 2.2082 2.6994 2.1322 2.0632 2.2362 2.4398 2.6075 2.3275 2.1939 2.1462 2.4698 2.3982 2.2254 2.6884 2.2484 2.2400 2.1904 2.3715 1.9936 2.0261 2.6067 2.2940 2.3079 2.1973 2.1802 2.5537 2.2651 2.4150 2.7007 2.6478 2.2930 2.1980 2.2460 2.1488 2.0816 2.2138 2.1474 2.1720 Difference (9) 6 0.2039 0 .2 2 2 2 0.2627 0.3896 0.2223 0.2026 0.2258 0.2805 0.2944 0.2324 0.2361 0.2729 0.2285 0.2136 0.2432 0.3402 0.3739 0.3217 0.2932 0.3364 0.3067 0.3066 0.4851 0.3737 0.3218 0.2777 0.3240 0.4763 0.2549 0.2962 0.3590 0.3467 0.1687 0.1480 0.1508 0.1381 0.0276 0.0330 0.1710 0.1600 2 nd Determination Weight (soil + Dish) (g) Difference % Moisture * (g) 7 2.1631 2.3074 2.2090 2.6998 2.1324 2.0636 2.2364 2.4401 2.6077 2.3275 2.1944 2.1458 2.4698 2.3983 2.2254 2.6883 2.2480 2.2397 2.1897 2.3711 1.9924 2.0242 2.6065 2.2934 2.3065 2.1967 2.1784 2.5523 2.2650 2.4148 2.6987 2.6463 2.2925 2.1974 2.2454 2.1478 2.0803 2.2157 2.1466 2.1713 8 -0.0006 0 .0 0 0 1 -0.0008 -0.0004 -0.0002 -0.0004 -0.0002 -0.0003 -0.0002 0.0000 -0.0005 0.0004 0.0000 -0.0001 0 .0 0 0 0 0 .0 0 0 1 0.0004 0.0003 0.0007 0.0004 0 .0012 0.0019 0 .0 0 0 2 0.0006 0.0014 0.0006 0.0018 0.0014 0 .0 0 0 1 0 .0 0 0 2 0 .0 0 2 0 0.0015 0.0005 0.0006 0.0006 0 .0010 0.0013 -0.0019 0.0008 0.0007 11 16.4 16.3 19.8 20.3 19.0 18.8 17.3 18.5 17.0 16.8 18.2 2 1 .2 15.2 14.5 18.5 18.2 25.7 2 2 .8 2 1 .6 21.3 26.8 26.2 24.9 25.0 21.7 2 1 .8 23.6 25.7 18.4 18.7 19.0 18.8 13.1 12.3 12.1 12.7 2.94 2.81 14.4 14.0 Average % Moisture 12 16.4 20.1 18.9 17.9 16.9 19.7 14.9 18.3 24.3 21.5 26.5 24.9 2 1 .8 24.7 18.5 18.9 12.7 12.4 2.9 14.2 RPD (% Moisture) 13 1.0 2 .6 1.1 6 .6 1.5 15 4.5 1.6 12 1.1 2.4 0.48 0.41 8.3 1.5 1.1 6.4 4.5 4.6 2.7 3M Study GLP10-01-02-15 Page 1 of 2 GLP10-01-01-15 Sample ID Sample Description 1 GLP10-01-01-15-085 GLP10-01-01-15-085 Dup GLP10-01-01-15-086 GLP10-01-01-15-086 Dup GLP10-01-01-15-087 GLP10-01-01-15-087 Dup GLP10-01-01-15-088 GLP10-01-01-15-088 Dup GLP10-01-01-15-089 GLP10-01-01-15-089 Dup GLP10-01-01-15-090 GLP10-01-01-15-090 Dup GLP10-01-01-15-091 GLP10-01-01-15-091 Dup GLP10-01-01-15-092 GLP10-01-01-15-092 Dup GLP10-01-01-15-008 GLP10-01-01-15-008 Dup GLP10-01-01-15-014 GLP10-01-01-15-014 Dup 2 DAL SS SS19 0 0015 DAL SS SS19 0 0015 Lab Dupllcate DAL SS SS20 0 0015 DAL SS SS20 0 0015 Lab Dupllcate DAL SS SS14 0 0015 DAL SS SS14 0 0015 Lab Duplicate DAL SS SS17 0 0015 DAL SS SS17 0 0015 Lab Duplicate DAL SS SS13 0 0015 DAL SS SS13 0 0015 Lab Duplicate DAL SS SS15 0 0015 DAL SS SS15 0 0015 Lab Duplicate DAL SS SS18 0 0015 DAL SS SS18 0 0015 Lab Duplicate DAL SS SS11 0 0015 DAL SS SS11 0 0015 Lab Duplicate DAL SS SS11 0 0005 DAL SS SS11 0 0005 Lab Dupllcate DAL SS SS15 0 0000 DAL SS SS15 0 0000 Lab Dupllcate Column 3: Balance ID: Initlal/Date: Column 4: Balance ID: Temp of Oven ('C): Oven Time/Date In: Initial/Date: 909 3/16/11 mmh 909 104.3 3/16/11 3:00pm mmh 3/16/11 Oven ID: OV-1 Probe ID: Probe #1, RTD #14 % Moisture Determination Weight of Weighing Dish (g) Initial Weight (soil + Dish) (g) 1st Determination Weight (soil + Dish) (g) 3 1.1304 1.1650 1.1364 1.1785 1.1940 1.1545 1.1278 1.1306 1.1377 1.1265 1.1776 1 .1 2 2 0 1.1556 1.1635 1.1403 1.1602 1.1410 1.1588 1.1611 1 .1 2 1 1 4 2.2965 2.6599 2.4842 2.4326 2.2258 2.2507 2.4122 2.3379 2.2821 2.2520 2.5541 2.2744 2.4184 2.8976 2.7612 2.5561 2.3877 2.3228 2.6374 2.5537 5 2.0641 2.3755 2.1897 2.1705 2.0622 2.0566 2.1621 2.1071 2.0603 2.0286 2.3015 2.0586 2.2192 2.6195 2.5093 2.3300 2.2481 2.1920 2.5450 2.4420 Difference (9) 6 0.2324 0.2844 0.2945 0.2621 0.1636 0.1941 0.2501 0.2308 0.2218 0.2234 0.2526 0.2158 0.1992 0.2781 0.2519 0.2261 0.1396 0.1308 0.0924 0.1117 2 nd Determination Weight (soil + Dish) (g) Difference % Moisture * (g) 7 2.0631 2.3751 2.1891 2.1699 2.0620 2.0562 2.1612 2.1070 2.0594 2.0272 2.3032 2.0588 2.2190 2.6187 2.5084 2.3293 2.2476 2.1918 2.5447 2.4418 8 0.0 0 10 0.0004 0.0006 0.0006 0 .0 0 0 2 0.0004 0.0009 0 .0 0 0 1 0.0009 0.0014 -0.0017 -0.0002 0 .0 0 0 2 0.0008 0.0009 0.0007 0.0005 0 .0 0 0 2 0.0003 0 .0 0 0 2 11 2 0 .0 19.1 21.9 20.9 15.9 17.7 19.5 19.1 19.5 2 0 .0 18.2 18.7 15.8 16.1 15.6 16.2 1 1 .2 11.3 6.28 7.81 Average % Moisture 12 19.5 21.4 16.8 19.3 19.7 18.5 15.9 15.9 11.2 7.05 RPD (% Moisture) 13 4.9 4.4 h 2 .2 2 .6 2 .6 1.8 4.1 0.15 22 Column 5: Temp of Oven (-C): Oven Time/Date Out: Oven Time/Date In: Balance ID: Initlal/Date: 104.5 11:07am 3/18/11 3/18/2011 11:40 909 3/18/2011 mmh * The last recorded weight is used for the calculation of % moisture. Column 7: Temp of Oven ('C): Oven Time/Date Out: Oven Time/Date In: N/A Balance ID: Initial/Date: 118.2 1:57 pm 3/18/11 mmh 909 3/18/11 mmh 3M Study GLP10-01-02-15 Page 2 of 2 Page 129 of 514 GLP10-01-01-15 Sample ID Sample Description 1 GLP10-01-01-15-064 GLP10-01-01-15-064 Dup GLP10-01-01-15-065 GLP10-01-01-15-065 Dup GLP10-01-01-15-066 GLP10-01-01-15-066 Dup GLP10-01-01-15-067 GLP10-01-01-15-067 Dup GLP10-01-01-15-068 GLP10-01-01-15-068 Dup GLP10-01-01-15-069 GLP10-01-01-15-069 Dup GLP10-01-01-15-070 GLP10-01-01-15-070 Dup GLP10-01-01-15-071 GLP10-01-01-15-071 Dup GLP10-01-01-15-072 GLP10-01-01-15-072 Dup GLP10-01-01-15-073 GLP10-01-01-15-073 Dup GLP10-01-01-15-074 GLP10-01-01-15-074 Dup GLP10-01-01-15-075 GLP10-01-01-15-075 Dup GLP10-01-01-15-076 GLP10-01-01-15-076 Dup GLP10-01-01-15-077 GLP10-01-01-15-077 Dup GLP10-01-01-15-079 GLP10-01-01-15-079 Dup GLP10-01-01-15-080 GLP10-01-01-15-080 Dup GLP10-01-01-15-081 GLP10-01-01-15-081 Dup GLP10-01-01-15-082 GLP10-01-01-15-082 Dup GLP10-01-01-15-083 GLP10-01-01-15-083 Dup GLP10-01-01-15-084 GLP10-01-01-15-084 Dup 2 DAL SS SS27 0 0015 DAL SS SS27 0 0015 Lab Duplicate DAL SS SS22 0 0000 DAL SS SS22 0 0000 Lab Duplicate DAL SS SS22 0 0005 DAL SS SS22 0 0005 Lab Duplicate DAL SS SS22 DB 0005 DAL SS SS22 DB 0005 Lab Duplicate DAL SSSS22 0 0015 DAL SS SS22 0 0015 Lab Duplicate DAL SS SS21 0 0000 DAL SS SS21 0 0000 Lab Duplicate DAL SS SS21 0 0005 DAL SS SS21 0 0005 Lab Duplicate DAL SS SS21 0 0015 DAL SS SS21 0 0015 Lab Duplicate DAL SD SD18 0 0000 DAL SD SD18 0 0000 Lab Duplicate DAL SD SD18 0 0005 DAL SD SD18 0 0005 Lab Duplicate DAL SD SD18 0 0015 DAL SD SD18 0 0015 Lab Duplicate DAL SD SD19 0 0000 DAL SD SD19 0 0000 Lab Duplicate DAL SD SD19 0 0005 DAL SD SD19 0 0005 Lab Duplicate DAL SD SD19 0 0015 DAL SD SD19 0 0015 Lab Duplicate DAL SS SS26 0 0000 DAL SS SS26 0 0000 Lab Duplicate DAL SS SS26 DB 0000 DAL SS SS26 DB 0000 Lab Duplicate DAL SS SS26 0 0005 DAL SS SS26 0 0005 Lab Duplicate DAL SS SS26 0 0015 DAL SS SS26 0 0015 Lab Duplicate DAL SS Trip2 0 0000 DAL SS Trip2 0 0000 Lab Duplicate DAL SS SS12 0 0015 DAL SS SS12 0 0015 Lab Duplicate % Moisture Determination Weight of Weighing Dish (g) Initial Weight (soli + Dish) (g) 1st Determination Weight (soil + Dish) (g) Difference (9) 2 nd Determination Weight (soil + Dish) (g) Difference % Moisture * (9) 3 1.1296 1.1631 1.1486 1.1744 1.1850 1.1888 1.1574 1.2036 1.1738 1.1736 1.1361 1.1321 1.1945 1.1422 1.1528 1.1577 1.1684 1.1497 1.1214 1.1296 1.1527 1.1544 1.1406 1.1700 1.1417 1.1990 1.1259 1.1697 1.1343 1.1251 1.1611 1.1424 1.1725 1.1386 1.1461 1.1880 1.1275 1.1406 1.1251 1.1850 4 2.3664 2.5297 2.4709 3.0890 2.3545 2.2658 2.4620 2.7203 2.9019 2.5599 2.4300 2.4191 2.6983 2.6118 2.4686 3.0286 2.6223 2.5617 2.4836 2.7079 2.3003 2.3327 3.0918 2.6677 2.6297 2.4750 2.5042 3.0300 2.5200 2.7112 3.0597 2.9945 2.4617 2.3460 2.3968 2.2869 2.1092 2.2468 2.3184 2.3320 56 7 . :l .' 8 11 Average % Moisture 12 RPD (% Moisture) 13 3M Study GLP10-01-02-15 Page 1 of 2 Page 130 of 51 GLP10-01-01-15 Sample ID Sample Description 1 GLP10-01-01-15-085 GLP10-01-01-15-085 Dup GLP10-01-01-15-086 GLP10-01-01-15-086 Dup GLP10-01-01-15-087 GLP10-01-01-15-087 Dup GLP10-01-01-15-088 GLP10-01-01-15088 Dup GLP100101-15089 GLP100101-15089 Dup GLP1001-01-15090 GLP100101-15090 Dup GLP100101-15091 GLP100101-15091 Dup GLP10-0101-15-092 GLP10-0101-15092 Dup GLP10-0101-15-008 GLP10-01-01-15-008 Dup GLP10-01-01-15014 GLP100101-15-014 Dup 2 DAL SS SS19 0 0015 DAL SS SS19 0 0015 Lab Duplicate DAL SS SS20 0 0015 DAL SS SS20 0 0015 Lab Duplicate DAL SS SS14 0 0015 DAL SS SS14 0 0015 Lab Duplicate DAL SS SS17 0 0015 DAL SS SS17 0 0015 Lab Duplicate DAL SS SS13 0 0015 DAL SS SS13 0 0015 Lab Duplicate DAL SS SS15 0 0015 DAL SS SS15 0 0015 Lab Duplicate DAL SS SS18 0 0015 DAL SS SS18 0 0015 Lab Duplicate DAL SS SS11 0 0015 DAL SS SS110 0015 Lab Duplicate DAL SS SS11 0 0005 DAL SS SS11 0 0005 Lab Duplicate DAL SS SS15 0 0000 DAL SS SS15 0 0000 Lab Duplicate Column 3: Balance ID: Initial/Date: Column 4: Balance ID'. Temp of Oven fC): Oven Tlme/Date In: Initial/Date: 909 3/16/11 mmh 909 104.3 3/16/11 3:00pm mmh 3/15/11 Oven ID: OV-1 Probe ID: Probe #1, RTD#14 t/ll % Moisture Determination Weight of Weighing Dish (g) Initial Weight (soil + Dish) (g) 1st Determination Weight (soil + Dish) (g) Difference (g) 2 nd Determination Weight (soil + Dish) (g) Difference % Moisture * (9) 3 4 5 6 7 8 11 1.1304 2.2965 1.1650 2.6599 1.1364 2.4842 1.1785 2.4326 1.1940 2.2258 1.1545 2.2507 1.1278 2.4122 1.1306 2.3379 1.1377 2.2821 1.1265 2.2520 1.1776 2.5541 1 .1 2 2 0 2.2744 1.1556 2.4184 1.1635 2.8976 1.1403 2.7612 1.1602 2.5561 1.1410 2.3877 1.1588 2.3228 1.1611 2.6374 1 .1 2 1 1 2.5537 Average % Moisture 12 RPD (% Moisture) 13 Column 5: Temp of Oven (-C): Oven Time/Date Out: Oven Time/Date In: Balance ID: Initial/Date: * The last recorded weight is used for the calculation of % moisture. Column 7: Temp of Oven ('C): Oven Time/Date Out: Oven Time/Date In: N/A Balance ID: Initial/Date: 3M Study GLP10-01-02-15 Page 2 of 2 Page 131 of 514 a 0) a <3 1 GLP10-01-01-15-036 GLP10-01-01-15-036 Dup GLP10-01-01-15-036 LMS GLP10-01-01-15-037 GLP10-01-01-15-037 Dup GLP10-01-01-15-037 LMS GLP10-01-01-15-038 LMS GLP10-01-01-15-039 GLP10-01-01-15-039 Dup GLP10-01-01-15-039 LMS GLP10-01-01-15-041 GLP10-01-01-15-041 LMS GLP10-01-01-15-042 GLP10-01-01-15-042 Dup GLP10-01-01-15-042 LMS GLP10-01-01-15-043 LMS GLP10-01-01-15-045 LMS GLP10-01-01-15-047 LMS GLP10-01-01-15-048 LMS GLP10-01-01-15-049 GLP10-01-01-15-049 Dup GLP10-01-01-15-049 LMS GLP 10-01-01-15-050 GLP10-01-01-15-050 Dup GLP10-01-01-15-050 LMS GLP10-01-01-15-051 GLP10-01-01-15-051 Dup GLP10-01-01-15-051 LMS GLP10-01-01-15-052 GLP10-01-01-15-052 Dup GLP10-01-01-15-052 LMS GLP 10-01-01-15-053 GLP10-01-01-15-053 Dup GLP10-01-01-15-053 LMS GLP 10-01-01-15-054 GLP10-01-01-15-054 Dup GLP10-01-01-15-054 LMS GLP10-01-01-15-055 GLP10-01-01-15-055 Dup GLP10-01-01-15-055 LMS GLP10-01-01-15-056 LMS GLP10-01-01-15-058 LMS GLP10-01-01-15-060 LMS GLP10-01-01-15-063 LMS GLP10-01-01-15-065 LMS GLP10-01 -01-15-067 LMS GLP10-01-01-15-069 GLP10-01-01-15-069 Dup GLP10-01-01 -15-069 LMS GLP 10-01-01-15-070 LMS GLP10-01-01-15-072 GLP10-01-01-15-072 Dup GLP10-01-01-15-072 LMS GLP10-01-01-15-073 GLP10-01-01-15-073 Dup GLP10-01-01-15-073 LMS GLP10-01-01-15-075 GLP10-01-01-15-075 Dup GLP10-01-01-15-075 LMS GLP10-01-01-15-076 GLP10-01-01-15-076 Dup GLP10-01-01-15-076 LMS GLP10-01-01-15-077 LMS GLP10-01-01-15-079 GLP10-01-01-15-079 Dup GLP10-01-01-15-079 LMS GLP10-01-01-15-080 c .2 a H. io 2 DAL SS SS24 0 0015 DAL SS SS24 0 0015 Lab Duplicate DAL SS SS24 0 0015 Lab Matrix Spike DAL SS SS29 0 0000 DAL SS SS29 0 0000 Lab Duplicate DAL SS SS29 0 0000 Lab Matrix Spike OAL SS SS29 0 0005 Lab Matrix Spike OALSS SS29 0 0015 DAL SS SS29 0 0015 Lab Duplicate DAL SS SS29 0 0015 Lab Matrix Spike DAL SS SS13 0 0005 DAL SS SS13 0 0005 Lab Matrix Spike DAL SS SS13DB 0005 DAL SS SS13 DB 0005 Lab Duplicate DAL SS SS13 DB 0005 Lab Matrix Spike DAL SS SS15 0 0005 Lab Matrix Spike DAL SS SS14 0 0005 Lab Matrix Spike DAL SS SS16 0 0005 Lab Matrix Spike DAL SS SS16 0 0015 Lab Matrix Spike DAL SS SS10 0 0005 DAL SS SS10 0 0005 Lab Duplicate DAL SS SS10 0 0005 Lab Matrix Spike DAL SS SS10DB 0005 DAL SS SS10 DB 0005 Lab Duplicate DAL SS SS10 DB 0005 Lab Matrix Spike DAL SS SS10 0 0015 DAL SS SS10 0 0015 Lab Duplicate DAL SS SS10 0 0015 Lab Matrix Spike DAL SD SD20 0 0000 DAL SD SD20 0 0000 Lab Duplicate DAL SD SD20 0 0000 Lab Matrix Spike DAL SD SD20 0 0005 DAL SD SD20 0 0005 Lab Duplicate DAL SD SD20 0 0005 Lab Matrix Spike DAL SDSD20 0 0015 DAL SD SD20 0 0015 Lab Duplicate DAL SD SD20 0 0015 Lab Matrix Spike DAL SD SD23 0 0000 DAL SD SD23 0 0000 Lab Duplicate DAL SD SD23 0 0000 Lab Matrix Spike DAL SD SD23 0 0005 Lab Matrix Spike DAL SS SS28 0 0000 Lab Matrix Spike DAL SS SS28 DB 0005 Lab Matrix Spike DAL SS SS27 0 0005 Lab Matrix Spike DAL SS SS22 0 0000 Lab Matrix Spike DAL SS SS22 DB 0005 Lab Matrix Spike DAL SS SS21 0 0000 DAL SS SS21 0 0000 Lab Duplicate DAL SS SS21 0 0000 Lab Matrix Spike DAL SS SS21 0 0005 Lab Matrix Spike DAL SD SD18 0 0000 DAL SD SD16 0 0000 Lab Duplicate DAL SD SD18 0 0000 Lab Matrix Spike DAL SDSD18 0 0005 DAL SD SD18 0 0005 Lab Duplicate DAL SD SD18 0 0005 Lab Matrix Spike DAL SDSD19 0 0000 DAL SD SD19 0 0000 Lab Duplicate DAL SD SD19 0 0000 Lab Matrix Spike DAL SD SD19 0 0005 DAL SD SD19 0 0005 Lab Duplicate DAL SD SD19 0 0005 Lab Matrix Spike DAL SD SD19 0 0015 Lab Matrix Spike DAL SS SS26 0 0000 DAL SS SS26 0 0000 Lab Duplicate DAL SS SS26 0 0000 Lab Matrix Spike DAL SS SS26 DB 0000 _c c Oo tj 3 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 o If b >- 4 Yes Yea Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No 1s oS >8 s No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes 11 5* 6 No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No 5>1- 7 No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No if 6* 8 No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No No 3M Study GLP10-01-02-15 Page 1 of 2 P GLP10-01-01-15-080 Dup GLP10-01-01-15-080 LMS GLP10-01-01-15-081 GLP10-01-01-15-081 Dup GLP10-01-01-15-081 LMS GLP10-01-01-15-082 GLP10-01-01-15-082 Dup GLP10-01-01-15-082 LMS GLP10-01-01-15-084 GLP10-01-01-15-084 Dup GLP10-01 -01-15-084 LMS GLP10-01-01-15-085 LMS DAL SS SS26 DB 0000 Lab Duplicate DAL SS SS26 DB 0000 Lab Matrix Spike DAL SS SS26 0 0005 DAL SS SS26 0 0005 Lab Duplicate DAL SS SS26 0 0005 Lab Matrix Spike DAL SS SS26 0 0015 DAL SS SS26 0 0015 Lab Duplicate DAL SS SS26 0 0015 Lab Matrix Spike DAL SS SS12 0 0015 DAL SS SS12 0 0015 Lab Duplicate DAL SS SS12 0 0015 Lab Matrix Spike DAL SS SS19 0 0015 Lab Matrix Spike 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 3/16/2011 No No No No No No No No No No No No * If extract to be diluted is a dilution from another previous dilution, the original dilution factor is listed in the sample description Col 4: Col S: Volume of sample added*: 20 uL Volume of sample added*: 20 uL Volume of Diluent Added**: 980 uL Volume of Diluent Added**: 960 uL Diluent ID MB-11031M9 Oiluent ID MB-110316-10 Yes Yes Yes No No No No No No No No No No No No No No No Yes No Yes No Yes No Yes No Yes No Yes No Yes No Yes No Yes No Col 6: Volume of sample added*: 20 uL Volume of Diluent Added**: 980 uL Diluent ID MB-110316-11 No No No No No No No No No No No No * Pipette: Eppendorf Model: Research I.D.:_ Int/Date ** Pipette: Eppendorf Model: Reference I.D.: 265893 lnt/Date_ 3M Study GLP10-01-02-15 Page 2 of 2 Page 133 of 514 Sample ID Sample Description Date of O rig in a i Extraction Diluted? Ye$/No Diluted?* Yes/No Diluted?* Yes/No Diluted?* Yes/No Diluted?* Yes/No 1 2 34 s 6 7 8 G LP 10-01-01-15-002 DAL SS SS12 0 0000 3/16/2011 Yes No No No No GLP 10-01-01-15-002 Dup DAL SS SS12 0 0000 Lab Duplicate 3/16/2011 Yes No No No No GLP10-01-01-15-002 LMS DAL SS SS12 0 0000 Lab Matrix Spike 3/16/2011 Yes No No No No GLP10-01-01-15-003 DAL SS SS12 0 0005 3/16/2011 Yes No No No No GLP10-01-01-15-003 Dup DAL SS SS12 0 0005 Lab Duplicate 3/16/2011 Yes No No No No GLP10-01-01-15*003 LMS DAL SS SS12 0 0005 Lab Matrix Spike 3/16/2011 Yes No No No No GLP10-01-01-15-006 LMS DAL SS SS16 DB 0000 Lab Matrix Spike 3/16/2011 Yes No No No No GLP10*01-01-15-008 DAL SS SS11 0 0005 3/16/2011 Yes No No No No GLP10-01-01-15-010 LMS DAL SS SS20 DB 0000 Lab Matrix Spike 3/16/2011 Yes No No No N o GLP10-01-01-15-011 DAL SS SS19 0 0000 3/16/2011 Yes No No No No GLP10-01-01-15-011 LMS DAL SS SS19 0 0000 Lab Matrix Spike 3/16/2011 Yes No No No No GLP10-01-01-15-012 LMS DAL SS SS19 0 0005 Lab Matrix Spike 3/16/2011 Yes No No No No GLP10-01-01-15-014 Dup DAL SS SS15 0 0000 Lab Duplicate 3/16/2011 Yes No No No No GLP10-01-01-15-014 LMS DAL SS SS150 0000 Lab Matrix Spike 3/16/2011 Yes No No No No GLP10-01-01-15-016 Dup DAL SS SS14 0 0000 Lab Duplicate 3/16/2011 Yes No No No No GLP10-01-01-15-016 LMS DAL SS SS14 0 0000 Lab Matrix Spike 3/16/2011 Yea No No No No GLP10-01-01-15-020 DAL SS SS10 0 0000 3/16/2011 Yes No No No No GLP10-01-01-15-020 Dup DAL SS SS10 0 0000 Lab Duplicate 3/16/2011 Yes No No No No GLP10-01-01-15-020 LMS DAL SS SS10 0 0000 Lab Matrix Spike 3/16/2011 Yes No No No No GLP10-01-01-15-021 LMS DAL SS SS30 0 0000 Lab Matrix Spike 3/16/2011 Yes No No No No GLP10-01-01-15-023 LMS DAL SS SS30 0 0015 Lab Matrix Spike 3/16/2011 Yes No No No No GLP 10-01-01-15-024 DAL SS SS25 0 0000 3/16/2011 Yes No No No No GLP10-01-01-15-024 Dup DAL SS SS25 0 0000 Lab Duplicate 3/16/2011 Yes No No No N o GLP10-01-01-15-024 LMS DAL SS SS25 0 0000 Lab Matrix Spike 3/16/2011 Yes No No No N o GLP10-01-01-15-025 DAL SS SS25 0 0005 3/16/2011 Yes No No No No GLP10-01-01-15-025 Dup DAL SS SS25 0 0005 Lab Duplicate 3/16/2011 Yes No No No No GLP10-01-01-15-025 LMS DAL SS SS25 0 0005 Lab Matrix Spike 3/16/2011 Yes No No No No G LP 10-01 -01-15-026 DAL SS SS25 0 0015 3/16/2011 Yes No No No No GLP 10-01-01-15-026 Dup DAL SS SS25 0 0015 Lab Duplicate 3/16/2011 Yes No No No No GLP10-01-01-15-026 LMS DAL SS SS25 0 0015 Lab Matrix Spike 3/16/2011 Yes No No No No GLP 10-01-01-15-027 DAL SD SD22 0 0000 3/16/2011 Yes No No No No GLP10-01-01-15-027 Dup DAL SD SD22 0 0000 Lab Duplicate 3/16/2011 Yes No No No No GLP10-01-01-15-027 LMS DAL SD SD22 0 0000 Lab Matrix Spike 3/16/2011 Yes No No No No GLP 10-01*01-15-028 DAL SD SD22 0 0005 3/16/2011 Yes No No No No GLP10-01-01-15-028 Dup DAL SD SD22 0 0005 Lab Duplicate 3/16/2011 Yes No No No No GLP10-01-01-15-028 LMS DAL SD SD22 0 0005 Lab Matrix Spike 3/16/2011 No Yes No No No GLP10-01-01-15-029 DAL SD SD22 DB 0005 3/16/2011 No Yes No No No GLP10-01-01-15-029 Dup OAL SD SD22 DB 0005 Lab Duplicate 3/16/2011 No Yes No No No GLP10-01-01-15-029 LMS DAL SD SD22 DB 0005 Lab Matrix Spike 3/16/2011 No Yes N o No No GLP10-01-01-15-030 DAL SD SD22 0 0015 3/16/2011 No Yes No No No GLP10-01-01-15-030 Dup DAL SD SD22 0 0015 Lab Duplicate 3/16/2011 No Yes No No No GLP10-01-01-15-030 LMS DAL SD SD22 0 0015 Lab Matrix Spike 3/16/2011 No Yes No No No GLP10-01-01-15-031 DAL SD SD21 0 0000 3/16/2011 No Yes No No No GLP10-01-01-15-031 Dup DAL SD SD21 0 0000 Lab Duplicate 3/16/2011 No Yes No No No GLP10-01-01-15-031 LMS DAL SD SD21 0 0000 Lab Matrix Spike 3/16/2011 No Yes No No No GLP10-01-01-15-032 DAL SD SD21 0 0005 3/16/2011 No Yes No No No GLP10-01-01-15-032 Dup DAL SD SD21 0 0005 Lab Duplicate 3/16/2011 No Yes No No No GLP10-01-01-15-032 LMS DAL SD SD21 0 0005 Lab Matrix Spike 3/16/2011 No Yes No No No GLP10-01-01-15-033 DAL SD SD21 0 0015 3/16/2011 No Yes No No N o GLP10-01-01-15-033 Dup DAL SD SD21 0 0015 Lab Duplicate 3/16/2011 No Yes No No N o GLP10-01-01-15-033 LMS DAL SD SD21 0 0015 Lab Matrix Spike 3/16/2011 No Yes No No No GLP10-01-01-15-034 DAL SS SS24 0 0000 3/16/2011 No Yes No No No GLP10-01-01-15-034 Dup DAL SS SS24 0 0000 Lab Duplicate 3/16/2011 No Yes No No No GLP10-01-01-15-034 LMS OAL SS SS24 0 0000 Lab Matrix Spike 3/16/2011 No Yes No No No GLP10-01-01-15-035 DAL SS SS24 0 0005 3/16/2011 No Yes No No No GLP10-01-01-15-035 Dup DAL SS SS24 0 0005 Lab Duplicate 3/16/2011 No Yes No No No GLP10-01-01-15-035 LMS DAL SS SS24 0 0005 Lab Matrix Spike 3/16/2011 No Yes No No No 3M Study GLP10-01-02-15 Page 1 of 2 U l, Page 134 of 514 LCS-110316-07 LCS-110316-08 LCS-110316-09 300ng LCS in TCR-842 300ng LCS in TCR-842 300ng LCS in TCR-842 3/16/2011 3/16/2011 3/16/2011 No No No * If extract to be diluted is a dilution from another previous dilution, the original dilution factor is listed in the sample description Col 4: Col S: Volume of sample added*: 20 uL Volume of sample added*: 20 uL Volume of Diluent Added**: 980 uL Volume of Diluent Added**: 880 uL Diluent ID MB-110316-07 Diluent ID MB-110316-08 Dilution Factory Int/Date.^ '^ 0 " // No No No Yes No Yes No Yes No Col 6: Volume of sample added*: 100 uL Volume of Diluent Added**: 900 uL Diluent ID MB-110316-QB Dilution Factor: 10 y --v InVDate. No No No * Pipette: Epoendorf Model: Research I.D.:. In t/D a te _ ** Pipette: Epoendorf Model: Reference I.D.: 3824414 Int/Date. < 3 - > 3 -y / 3M Study GLP10-01-02-15 Page 2 of 2 Page 135 of 514 S a m p le ID S a m p le D e s c rip tio n D ate of O rig in al E x tra c tio n D ilu ted ? Y e s /N o D ilu ted ? * Y e s /N o D ilu ted ? * Y es/N o D ilu ted ? * Y es/N o D ilu ted ? * Y e s /N o 1 2 34 5 6 7 8 GLP10-01-01-15-005 LMS DAL SS SS16 0 0000 Lab Matrix Spike 3/16/2011 Yes No No No No * If extract to be diluted is a dilution from another previous dilution, the original dilution factor is listed in the sample description Col 4: Volume of sample added*: 20 uL Volume of Diluent Added**: 960 uL rr-t * ..... r (, _ Diluent ID MB-Vt03t6-Q& Dilution Factor: 50 lnl/g.1^^7/ ...J ' . i4}rf`*l'TT}:.....; s...' . - %jEtPnu^w e:' fifiru ,y.; r r r v 'iW f * f r __ .-'.HviXPFsiKrir-x.,.^__, ^HZSE>. :............................... * Pipette: Eooendorf Model: Research I.O.: 4215537 Int/Date - tV ** Pipette: Eopendorf___________ Model: Reference______ I.D.: 3824414 Int/Date^ ' Y .- y - z ' / 3M Study GLP10-01-02-15 Page 1 of 1 Page 136 GLP 10-01-02*15 rrs -8-053 Soils Extracted lS-Mar-2011 Sample ID Sample Description 1 GLP10-01-01-15-004 GLP10-01-01-15-004 Duo GLP10-01-01-15-004 LMS GLP10-01-01-15-008 GLP10-01-01-15-008 Duo GLP10-01-01-15-008 LMS GLP10-01-01-15-020 GLP10-01-01-15-020 Dup GLP10-01-01-15-020 LMS GLP10-01-01-15-024 GLP10-01-01-15-024 Dup GLP10-01-01-15-024 LMS GLP10-01-01-15-029 2 DAL SS SS13 0 0000 DAL SS SS13 0 0000 Lab Duplicate DAL SS SS13 0 0000 Lab Matrix Spike DAL SS SS11 0 0005 DAL SS SS11 0 0005 Lab Duplicate DAL SS SS11 0 0005 Lab Matrix Spike DAL SS SS10 0 0000 DAL SS SS10 0 0000 Lab Duplicate DAL SS SS10 0 0000 Lab Matrix Spike DAL SS SS25 0 0000 DAL SS SS25 0 0000 Lab Duplicate DAL SS SS25 0 0000 Lab Matrix Spike DAL SD SD22 DB 0005 GLP10-01-01-15-029 LMS GLP10-01-01-15-032 GLP10-01-01-15-032 Dup GLP10-01-01-15-032 LMS DAL SD SD22 DB 0005 Lab Matrix Spike DAL SD SD21 0 0005 DAL SD SD21 0 0005 Lab Duplicate DAL SD SD21 0 0005 Lab Matrix Spike GLP10-01-01-15-040 Dup GLP10-01-01-15-040 LMS DAL SS SS20 0 0005 Lab Duplicate DAL SS SS20 0 0005 Lab Matrix Spike GLP10-01-01-15-080 Dup GLP10-01-01-15-080 LMS GLP10-01-01-15-090 GLP10-01-01-15-090 Dup GLP10-01-01-15-090 LMS GLP10-01-01-15-092 GLP10-01-01-15-092 Dup GLP10-01-01-15-092 LMS EC-110407-01 EC-110407-02 EC-110407-03 EC-110407-04 EC-110407-05 EC-110407-06 EC-110407-07 EC-110407-08 EC-110407-09 EC-110407-10 EC-110407-11 EC-110407-12 LCS-110407-01 LCS-110407-02 LCS-110407-03 LCS-110407-04 LCS-110407-05 LCS-110407-06 MB-110407-01 MB-110407-02 MB-110407-03 MB-110407-04 MB-110407-05 MB-110407-06 DAL SS SS26 DB 0000 Lab Duplicate DAL SS SS26 DB 0000 Lab Matrix Spike DAL SS SS15 0 0015 DAL SS SS15 0 0015 Lab Duplicate DAL SS SS15 0 0015 Lab Matrix Spike DALSSSS11 0 0015 DAL SS SS11 0 0015 Lab Duplicate DAL SS SS11 0 0015 Lab Matrix Spike 0.2 na Extracted Curve Point 0.5 ng Extracted Curve Point 0.75 na Extracted Curve Point 1 na Extracted Curve Point 2.5 na Extracted Curve Point 5 na Extracted Curve Point 10 no Extracted Curve Point 25 na Extracted Curve Point 50 no Extracted Curve Point 100 no Extracted Curve Point 200 na Extracted Curve Point 500 no Extracted Curve Point 3 na LCS in TCR-842 3 na LCS in TCR-842 3 na LCS in TCR-842 30 na LCS in TCR-842 30 na LCS in TCR-842 30 nq LCS in TCR-842 Method Blank w/o IS Method Blank w/o IS Method Blank w/o IS Method Blank w/ IS Method Blank w/ IS Method Blank w/ IS Col 5 & 6: P ip ette ID: 34 0 2 2 7 7 P ip ette ID: 36 2 4 4 1 4 (for v o lu m e s > 1 0 0 u L ) Soil Weight Soil Matrix ID Used (g) 34 1.5559 1.7015 1.6205 1.5579 1.4396 1.5374 1.1655 1.2735 1.2653 1.4976 1.3492 1.6066 1.7821 1.3784 1.1200 1.3425 1.3587 1.5601 1.3247 Spike ID 5 Spike Volume (uL) 6 Internal Standard ID 7 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 Internal Standard Volume (uL) Surrogate Spike ID Surrogate Spike Volume (uL) PFBS Spike ID PFBS Spike Volume (uL) L-PFHxS Spike ID L-PFHxS Spike Volume (uL) L-PFOS Spike ID L-PFOS Spike Volume (uL) Add Extraction Solvent (mL) Sonicate 1 hr C e n tr ifu g e 89 30 11 002-52 30 11 002-52 30 11 002-52 30 11 002-52 30 11 002-52 30 11 002-52 30 11 002-52 30 11 002-52 30 11 002-52 30 11 002-52 30 11 002-52 30 11 002-52 30 11 002-52 10 11 12 13 15 16 30 30 " ": ........ . z" .. .... . . . ......... .......... _ 30 10 007-47-4 50 30 .........: : ...._.......-. ...................... " . : : : ........ 30 ___________ __________ ... _ 30 10 007-47-4 50 10 007-48-3 25 10 007-49-2 100 30 30 30 10 007-47-4 50 30 " : -- 10 007-49-1 50 30 __________ .......... . ..... :........ ... .................. .................. 30 i z : 10 007-48-2 100 -- 30 c z z z z c _________ L________ J C _____" Z I 17 8 8 8 8 8 8 8 8 8 8 6 8 8 18 mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh 19 mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 30 11 002-52 30 11 002-52 30 11 002-52 30 11 002-52 30 11 002-52 30 11 002-52 30 ^ ^ 5 30 30 I____________ I 30 10 007-47-3 25 ____ ] 25 i e " i Bg 30 BB Sb S SEI Bi f_ . --------- ! 30 100 8 8 8 6 8 8 mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh Comments 20 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11002-46 11 002-46 11 002-46 ! ! I ! 1.3230 1.3133 1.2422 1.3316 1.4039 1.4865 1.3330 1.3114 1.1383 1.1567 1.1842 1.1253 1.1191 1.1137 1.1453 1.1901 1.1080 1.1124 1.1163 1.1101 1.1414 1.1400 1.1419 1.1947 1.1519 1.1540 1.1283 1.1239 1.1217 1.0805 1.1479 1.1211 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 10 007-38-3 20 11 002-50 10 007-38-3 50 11 002-50 10 007-38-3 75 11 002-50 10 007-38-3 100 11 002-50 10 007-38-2 25 11 002-50 10 007-38-2 50 11 002-50 10 007-38-2 100 11 002-50 10 007-38-1 25 11 002-50 10 007-38-1 50 11 002-50 10 007-38-1 100 11 002-50 10 006-67 20 11 002-50 10 006-67 50 11 002-50 10 010-183 30 11 002-50 10 010-183 30 11 002-50 10 010-183 30 11 002-50 10 010-182 30 11 002-50 10 010-182 30 11 002-50 10 010-182 30 11 002-50 30 11 002-52 30 SS 30 11 002-52 30 10 007-47-4 50 50 50 30 11 002-52 30 11 002-52 30 11 002-52 30 11 002-52 30 11 002-52 30 11 002-52 30 11 002-53 30 11 002-5, 30 11 002-5 J 30 r _ . 30 30 30 r 30 30 r 20 50 - ' ......... ............... 1 . 1 r" _ ~: r_ ............. 10 007-49-2 100 r- HZ ................ .. 10 007-49-2 - ,-? \ d- - z. 30 11 002-5 30 11 002-5x 100 . *v wmmm 30 11 002-5/ 50 30 11 002-57 V . 4 - r. * s- -- 30 11 002-5 30 11 002-5- S S * * * 7 - * - q r SM'-so - r - * ** . > 30 11 002-51 100 .- - v S f a F F V*. 30 11 002-51 30 11 002-51 200 200 y -d-. , -- 30 11 002-52 30 --- 30 11 002-52 30 * ' 30 11 002-5. ^ F X J -- - ' T * - , -y? ~ ~ s- ,, - -< 30 11 002-5. - f* - - - -J -. 30 I 11 002-5- 30 * , % v \ . l . - M T - ,, 4 J' * . ' 30 . 11 002-52 I 30 - ` C 1 ,' * . * - -, , - - v m am m a* W V J S I .I l.f .e l v iz ia r: # :-< >.....M S S * . 11 002-50 11 002-50 11 002-50 __________ j ___________ I 30 11 002-5r 30 11 002-52 30 11 002-52 30 j X -y 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 6 8 8 8 8 6 8 8 8 mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh i : Col 7 & 8: P ip ette ID: 3402277 P ip ette ID: 382441 4 (for v o lu m e s >1 00uL) Col 9 & 10: P ipette ID: 3402277 P ipette ID: 38 2441 4 (for vo lu m es >100uL) Col 13 & 14: Pipette ID: 3402277 Col 17: Extraction S o lv e n t ID: 10 006-96 Col 19: C e n trifu g e ID: 021188 -5 5' Col 11 & 12: P ipette ID: 3402277 Col 15 & 16: Pipette ID: 3402277 Col 18: Son icato r ID: Q E J 1 00595003 10 m in @ 3 0 0 0 R P M 7 Printed 3/16/2011 3M Study GLP10-01-02-15 Page 1 o f 1 Page 13' 14 3 M S tudy G L P 1 0 -0 1 -0 2 -1 5 Pagel of 1 Page 138 of 514 O 3. I $ <O 3, $ 8. Ill * Sample ID Sample Description Date of Original Extraction Diluted? Yes/No Diluted?* Yes/No Diluted?* Yes/No Diluted?* Yes/No Diluted?* Yes/No INTERNAL CHAIN-OF-CUSTODY environmental laboratory Sample Internal Transfer Sample set ID # Urns # N/A GLP10-01-01-15 Sample Description: Decatur Soils INTERNAL CHAIN OF CUSTODY # 3M Sam ple IDs Out: storage ID 1 GLP10-01-01-15-001 -/ 2 GLP10-01-01-15-002 3 GLP10-01 -01 -15-003 4 GLP10-01-01-15-004 5 GLP10-01-01-15-005 6 GLP10-01-01-15-006 7 GLP10-01-01-15-007 8 GLP10-01-01-15-008 \ 9 GLP10-01-01 -15-009 ____________ \_______ 10 GLP10-01-01-15-010 11 GLP10-01-01-15-011 12 GLP10-01-01-15-012 13 GLP10-01-01-15-014 14 GLP10-01-01-15-015 15 GLP10-01-01-15-016 16 GLP10-01-01-15-018 17 GLP10-01-01-15-020 18 GLP10-01-01-15-021 19 GLP10-01-01-15-022 20 GLP10-01-01-15-023 21 GLP10-01-01-15-024 22 GLP10-01-01-15-025 23 GLP10-01 -01-15-026 24 GLP10-01-01-15-027 25 GLP10-01-01-15-028 26 GLP10-01-01-15-029 27 GLP10-01-01-15-030 28 GLP10-01 -01 -15-031 29 GLP10-01-01-15-032 30 GLP10-01 -01 -15-033 31 GLP10-01-01-15-034 32 GLP10-01-01-15-035 33 GLP10-01 -01 -15-036 34 GLP10-01-01-15-037 35 GLP10-01-01-15-038 36 GLP10-01-01-15-039 37 GLP10-01-01-15-040 38 GLP10-01-01-15-041 39 GLP10-01-01-15-042 40 GLP10-01-01-15-043 41 GLP 10-01-01-15-044 42 GLP 10-01-01-15-045 43 GLP 10-01-01-15-046 44 GLP10-01-01-15-047 i In it./d a te In: storage ID _________ __________ V Init./date 1- " / ! Com ments/lnitJdate 3M Study GLP10-01-02-15 Page 1 of 2 Page 139 of 514 INTERNAL CHAIN-OF-CUSTODY environmental laboratory Sample Internal Transfer Sample set ID # Urns # N/A GLP10-01-01-15 Sample Description: Decatur Soils INTERNAL CHAIN OF CUSTODY # 3M Sam ple IDs Out: storage ID 45 GLP10-01-01-15-048 A j K - / _____ 46 GLP10-01-01-15-049 47 GLP10-01-01-15-050 48 GLP10-01-01-15-051 49 GLP10-01-01-15-052 50 GLP10-01-01-15-053 51 GLP10-01-01-15-054 52 GLP10-01 -01-15-055 53 GLP10-01-01-15-056 54 GLP10-01-01-15-057 55 GLP10-01-01-15-058 56 GLP10-01-01-15-059 57 GLP10-01-01-15-060 58 GLP10-01 -01-15-061 59 GLP10-01-01-15-062 60 GLP10-01-01-15-063 61 GLP10-01-01-15-064 62 GLP10-01-01-15-065 63 GLP10-01-01-15-066 __________ __________ 64 GLP10-01-01-15-067 65 GLP10-01-01 -15-068 66 GLP10-01-01-15-069 67 GLP10-01-01-15-070 68 GLP10-01-01-15-071 69 GLP10-01-01-15-072 70 GLP10-01-01-15-073 71 GLP10-01-01-15-074 72 GLP10-01-01-15-075 73 GLP10-01-01-15-076 74 GLP10-01 -01-15-077 75 GLP10-01-01-15-079 76 GLP10-01-01-15-080 77 GLP10-01-01-15-081 78 GLP10-01-01-15-082 79 GLP10-01-01-15-083 80 GLP10-01 -01 -15-084 81 GLP10-01-01-15-085 82 GLP10-01-01-15-086 83 GLP10-01 -01 -15-087 84 GLP10-01-01-15-088 85 GLP10-01-01-15-089 86 GLP10-01-01-15-090 87 GLP10-01-01-15-091 88 GLP10-01-01-15-092 IN " " -- > Init./date . n/t /r In: storage ID / K -! In lt/d a te A -*- / 1 1 1 V J. . Com ments/InltJdate 3M Study GLP10-01-02-15 Page 2 of 2 Page 140 of 514 GLPlO-01-02-15 ETS-8-053 Soils Extracted 08apr2011 Sample 10 Sample Description G LP 1 0 -0 1 -0 1 -1 5-004 G LP10-01-01-1S-004 Pup GLP10-01-01-1S-004 LM S G L P 1 0 -0 1 -0 1 -1 S -0 0 8 G LP10-01-01-1S-008 Pup GLP1O -01-01-15-O 0B L M S G L P 1 0-01-01-15-020 GLP10-01-01-15-020 Pup G LP10-01-01-1S-020 LM S G L P 1 0-01-01-15-024 G LP10-01-01-1S-024 Pup GLP1 0-0 1-01-15-024 LM S G L P 1 0 -0 1 -0 1 -1 S -0 2 9 G L P 1 0-01-01-15-029 P u p G L P 1 0-01-01-15-029 L M S G L P 1 00 1-01-15-032 G L P 1 0 0 101-15 -0 32 Pup G LP100 101 -1 5 0 3 2 LM S G LP10 0 101-15 040 G LP100 101 -1 5 0 4 0 Pup G LP100 101 -1 5 0 4 0 LM S G LP10 0 101-15 060 G LP100 101 -1 5 0 6 0 Pup G LP100 101 -1 5 0 6 0 LM S G LP10 0 101-15 090 G LP100 101 -1 5 0 9 0 Pup G LP1 0 0 1 0 1 -1 S0 9 0 LM S G LP10 0 101-15 092 G LP100 101 -1 5 0 9 2 Pup G LP100 101 -1 5 0 9 2 LM S E C - 1 1 0 4 0 7 0 1 ____________________ E C - 1 1 0 4 0 7 - 0 2 ____________________ E C - 1 1 0 4 0 7 0 3 ____________________ E C - 1 1 0 4 0 7 - 0 4 ____________________ E C - 1 1 0 4 0 7 - 0 5 ____________________ E C - 1 1 0 4 0 7 - 0 6 ____________________ E C - 1 1 0 4 0 7 0 7 ____________________ E C - 1 1 0 4 0 7 0 6 ____________________ E C - 1 1 0 4 0 7 0 9 ____________________ E C - 1 1 0 4 0 7 - 1 0 ____________________ E C -1 1 0 4 0 7 - 1 1 _____________________ E C - 1 1 0 4 0 7 - 1 2 ____________________ L C S - 1 1 0 4 0 7 Q 1 ___________________ L C S - 1 1 0 4 0 7 0 2 __________________ L C S - 1 1 0 4 0 7 0 3 __________________ L C S - 1 1 0 4 0 7 -0 4 __________________ L C S - 1 1 0 4 0 7 0 5 __________________ L C S - 1 1 0 4 0 7 0 6 __________________ M B -1 1 0 4 0 7 -0 1 ____________________ M B - 1 1 0 4 0 7 0 2 ____________________ M B - 1 1 0 4 0 7 0 3 ____________________ M B - 1 1 0 4 0 7 Q 4 ____________________ M B - 1 1 0 4 0 7 0 5 ____________________ M B-110 40706 _____________ 2__________ DAL SSSS13 0 0000________________ DAL SS SS13 0 0000 Lab Duplicate DAL SS SS13 0 0000 Lab Matrix Spike DAL SS SS11 0 0005________________ DAL SS SS11 0 0005 Lab Duplicate DAL SS SS11 0 0005 Lab Matrix Spike DAL SS SS10 0 0000________________ DAL SS SS10 0 0000 Lab Duplicate DAL SS SS10 0 0000 Lab Matrix Spike DAL SS SS2S 0 0000________________ DAL SS SS25 0 0000 Lab Duplicate DAL SS SS2S 0 0000 Lab Matrix Spike DAL SD SD22 DB POPS______________ DAL SD SD22 DB 0005 Lab Duplicate DAL SD SD22 DB 0005 Lab Matrix Spike DAL SD SD21 0 0005________________ DAL SD SD21 0 (05 Lab Duplicate DAL SD SD21 0 POPS Lab Matrix Spike DAL SS SS20 0 0005________________ DAL SS SS20 0 0005 Lab Duplicate DAL SS SS20 0 0005 Lab Matrix Spike DAL SS SS26 DB 0000______________ DAL SS SS26 DB 0000 Lab Duplicate DAL SS SS26 DB 0000 Lab Matrix Spike DAL SS SS15 0 0015________________ DAL SS SS15 0 0015 Lab Duplicate DAL SS SS15 0 0015 Lab Matrix Spike DALSSSS11 0 0015________________ DAL SS SS11 0 0015 Lab Duplicate DAL SS SS11 0 0015 Lab Matrix Spike 0.2 ng Extracted Curve Point__________ 0.5 ng Extracted Curve Point__________ 0.75 ng Extracted Curve Point_________ 1 ng Extracted Curve Point____________ 2.5 ng Extracted Curve Point__________ 5 ng Extracted Curve Point____________ 10 ng Extracted Curve Point__________ 25 ng Extracted Curve Point__________ 50 ng Extracted Curve Point__________ 100 ng Extracted Curve Point_________ 200 ng Extracted Curve Point_________ 500 ng Extracted Curve Point_________ 3 ng LCS in TCR-842________________ 3 ng LCS in TCR-642________________ 3 ng LCS in TCR-642________________ 30 ng LCS in TCR-842_______________ 30 ng LCS in TCR-842_______________ 30 ng LCS in TCR-842_______________ Method Blank w/o IS Method Blank w/o IS_________________ Method Blank w/o IS_________________ Method Blank w/ IS__________________ Method Blank w/ IS Method Blank w/ IS Col 5 & 6: Pipette ID: 3402277 Pipette ID: 3824414 (for volumes >100uL) Soil Matrix ID Soil Weight Used (g) Spike ID 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 Col 7 & 8: Pipette ID: 3402277 Pipette ID: 3624414 (for volumes >100uL) Spike Volume (uL) Internal Standard Internal Standard Volume (uL) Surrogate Spike ID Surrogate Spike Volume (uL) ~io PFBS Spike ID PFBS Spike Volume (uL) L-PFHxS Spike ID L-PFHxS Spike Volume (uL) L-PFOS Spike ID L-PFOS Spike Volume (uL) Add Extraction Solvent Sonicate 1 hr Centrifuge (mL) 18 mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh 19 mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh mmh Comments 20 Col 9 & 10: Pipette ID: 3402277 Pipette ID: 3824414 (for volumes >100uL) Col 13 & 14: Pipette ID: 3402277 Col 17: Col 19: Extraction Solvent ID: 10 006-96 Centrifuge ID: 021188-55 Col 11 & 12: Pipette ID: 3402277 Col 15 & 16: Pipette ID: 3402277 Col 18: Sonicator ID: QEJ100595003 10 min @3000 RPM W ^ ' Printed 4/8/2011 3M Study GLP10-01-02-15 Page 1 o f 1 Page 141 of GLPlO-Ol-02-15 ETS-8-053 Soils Extracted Sample ID Sample Description 1 GLP10-01-01-15-004 GLP10-01-01-15-004 Dup GLP10-01-01-15-004 LMS GLP10-01-01-15-008 GLP10-01-01-15-008 Dup GLP10-01-01-15-008 LMS GLP10-01-01-15-020 GLP10-01-01-15-020 Dup GLP10-01-01-15-020 LMS GLP10-01-01-15-024 GLP10-01-01-15-024 Dup GLP10-01-01-15-024 LMS GLP10-01-01-15-029 GLP10-01-01 -15-029 Dup GLP10-01-01-15-029 LMS GLP10-01-01-15-032 GLP10-01-01-15-032 Dup GLP10-01-01-15-032 LMS GLP10-01-01-15-040 GLP10-01-01-15-040 Dup GLP10-01-01-15-040 LMS GLP10-01-01-15-080 GLP10-01-01-15-080 Dup GLP10-01-01-15-080 LMS GLP10-01-01-15-090 GLP10-01-01-15-090 Dup GLP10-01-01-15-090 LMS GLP10-01-01-15-092 GLP10-01-01-15-092 Dup GLP10-01-01-15-092 LMS EC-110407-01 EC-110407-02 EC-110407-03 EC-110407-04 EC-110407-05 EC-110407-06 EC-110407-07 EC-110407-08 EC-110407-09 EC-110407-10 EC-110407-11 EC-110407-12 LCS-110407-01 LCS-110407-02 LCS-110407-03 LCS-110407-04 LCS-110407-05 LCS-110407-06 MB-110407-01 MB-110407-02 MB-110407-03 MB-110407-04 MB-110407-05 MB-110407-06 2 DAL SS SS13 0 0000 DAL SS SS13 0 0000 Lab Duplicate DAL SS SS13 0 0000 Lab Matrix Spike DAL SS SS11 0 0005 DAL SS SS11 0 0005 Lab Duplicate DAL SS SS11 0 0005 Lab Matrix Spike DAL SS SS10 0 0000 DAL SS SS10 0 0000 Lab Duplicate DAL SS SS10 0 0000 Lab Matrix Spike DAL SS SS25 0 0000 DAL SS SS25 0 0000 Lab Duplicate DAL SS SS25 0 0000 Lab Matrix Spike DAL SD SD22 DB 0005 DAL SD SD22 D8 0005 Lab Oupticale DAL SD SD22 DB 0005 Lab Matrix Spike DAL SD SD21 0 0005 DAL SD SD21 0 0005 Lab Duplicate DAL SD SD21 0 0005 Lab Matrix Spike DAL SS SS20 0 0005 DAL SS SS20 0 0005 Lab Duplicate DAL SS SS20 0 0005 Lab Matrix Spike DAL SS SS26 DB 0000 DAL SS SS26 DB 0000 Lab Duplicate DAL SS SS26 DB 0000 Lab Matrix Spike DAL SS SS15 0 0015 DAL SS SS15 0 0015 Lab Duplicate DAL SS SS15 0 0015 Lab Matrix Scike DALSSSS11 0 0015 DAL SS SS11 0 0015 Lab Duplicate DAL SS SS11 0 0015 Lab Matrix Spike 0.2 na Extracted Curve Point 0.5 r>a Extracted Curve Point 0.75 na Extracted Curve Point 1 no Extracted Curve Point 2.5 na Extracted Curve Point 5 no Extracted Curve Point 10 na Extracted Curve Point 25 na Extracted Curve Point 50 na Extracted Curve Point 100 na Extracted Curve Point 200 na Extracted Curve Point 500 na Extracted Curve Point 3 no LCS in TCR-842 3 na LCS in TCR-842 3 na LCS in TCR-842 30 na LCS in TCR-842 30 na LCS in TCR-842 30 na LCS in TCR-842 Method Blank w/o IS Method Blank w/o IS Method Blank w/o IS Method Blank w/ IS Method Blank w/ IS Method Blank w/ IS Col 5 & 6: Pipette ID: 3402277 'nPipette ID: 3824414 (for volumes >100uL| Soil Matrix ID 3 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 11 002-46 Soil Weight Used (g) 4 1.5559 1.7015 1.6205 1.5 1.4 1.5374 1.1655 1.2735 1.2653 1.4 1.3' 1.6066 1.7821 1.4 1.3 -* 1.1. . 1.3 1.3587 1.4122 1.5 ` 1.3247 1.4 1.3230 1.3133 1.2 1.3316 1.4039 1.4 --p 1.3330 1.3114 1.1383 1.1567 1.1842 1.1253 1.1191 1.1137 1.1453 1.1901 1.1080 1.1124 1.1163 1.1101 1.1414 1.1400 1.1419 1.1947 1.1519 1.1 > 1.1.-. 1.1239 1 .V 1.( ' 1.1479 1.1211 Spike ID 5 . 10 007-38-3 10 007-38-3 10 007-38-3 10 007-382 10 007-382 10 007-382 10 007-381 10 007-381 10 007-381 10 006-67 10 006-67 10010-183 10010-183 10 010-183 10 010-182 10 010-182 10010-182 Spike Volume (uL) 6 -u 50 75 100 25 50 100 25 50 100 20 50 30 30 30 30 30 30 Internal Standard ID Internal Standard Volume <uM Surrogate Spike ID 7 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 11 002-50 89 30 11 002-52 30 11 002-52 30 11 002-52 30 11 002-52 30 11 002-52 30 11 002-52 30 11 002-52 30 11 002-52 30 11 002-52 30 11 002-52 30 11 002-52 30 11 002-52 30 11 002-52 30 11 002-52 30 11 002-52 30 11 002-52 30 11 002-52 30 11 002-52 30 11 002-52 30 11 002-52 30 11 002-52 30 11 002-52 30 11 002-52 30 11 002-52 30 11 002-52 30 11 002-52 30 11 002-52 30 11 002-52 30 11 002-52 30 11 002-52 30 11 002-53 30 11 002-53 30 11 002-53 30 11 002-53 30 11 002-52 30 11 002-52 30 11 002-52 30 11 002-51 30 11 002-51 30 11 002-51 30 11 002-51 30 11 002-51 30 11 002-52 30 11 002-52 30 11 002-52 30 11 002-52 30 11 002-52 30 11 002-52 Surrogate Spike Volume (uL) PFBS Spike ID 10 11 30 30 30 10 007-47-4 30 30 30 10 007-47-4 30 30 30 10 007-47-4 30 30 30 30 30 ............... 30 30 30 30 30 30 30 30 30 30 10 007-47-4 30 30 30 30 30 30 20 50 75 100 25 50 100 25 50 100 200 200 30 30 30 30 30 30 PFBS Spike Volume (uL) 12 50 50 50 : 25 50 L-PFHxS Spike ID 13 L-PFHxS Spike Volume (uL) 14 L-PFOS Spike ID 15 L-PFOS Spike Volume (uL) 10 007-48-3 100 10 007-49-1 50 10 007-48-2 - 10 007-48-? 100 10 007-48-3 50 10010-194 50 10 007-49-2 100 10 007-49-2 ," % 5 s . .7 - ......... . 11 002-50 11 002-50 11 002-50 30 11 002-52 30 11 002-52 30 11 002-52 30 30 30 Add Extraction Solvent (mL) Sonicate 1 hr C e n tr ifu g e Comments 17 18 19 20 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh 6 mmh mmh 8 mmh mmh 8 mmh mmh - 6 mmh ' mmh 8 mmh mmh 8 mmh mmh 8 mmh . mmh 8 . .. mmh mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh mmh mmh mmh mmh ' mmh ... mmh mmh 1 8 " - k mmh mmh mmh ,mmh mmh ' "mmh mmh mmh . mmh mmh mmh 8 - mmh mmh -.m mh mmh ' mmh mmh mmh . mmh .... .. ....... > m m h' ' 6 mmh mnh 8 mmh mmh 8 mmh mmh 8 mmh mmh 8 mmh 8 mmh mmh mmh r- 8 mmh mmh 8 mmh mmh 8 - mmh - mmh mmh 5 8 mmh mmh 8 mmh mmh 8 -mmh mmh 8 rr-.mh mmh 8 mmh mmh 8 mmh mmh. mmh mmn 8 mmh mmh 8 mmh 8 mmh mmh - mmh - mmn 8 - mmh mmh Col 7 & 8: Pipette ID: 3402277 Pipette ID: 3824414 (for volumes >100uL) Col 9 & 10: J/C P h Col 13 & 14: Pipette ID: 3402277 yy' Pipette ID: 3402277 4^--^ . Pipette ID: 3824414 (for volumes >100uL) a 1 , Col 11 & 12: Pipette ID: 3402277 Col 15 & 16: Pipette ID: 3402277 Col 17: Col 19: Extraction Solvent ID: 10 006-96 /^ i 3M Study GLP10-01-02-15 Page 143 of 514 ENVIRONMENTAL LABORATORY INTERNAL CHAIN-OF-CUSTODY Sample Internal Transfer Sample set ID # Lims # N/A GLP10-01-01-15 Sample Description: Decatur Soils INTERNAL CHAIN OF CUSTODY # 3M Sample IDs Out: storage ID 1 GLP10-01-01-15-001 L U ri -- / 2 GLP10-01-01-15-002 3 GLP10-01-01-15-003 4 GLP10-01-01-15-004 11 1 5 GLP10-01-01-15-005 ______ l______ 6 GLP10-01-01-15-006 7 GLP10-01-01-15-007 8 GLP10-01-01-15-008 9 GLP10-01-01-15-009 10 GLP10-01-01-15-010 11 GLP10-01-01-15-011 12 GLP10-01-01-15-012 13 GLP10-01-01-15-014 14 GLP10-01-01-15-015 15 GLP10-01-01-15-016 16 GLP10-01-01-15-018 17 GLP10-01-01-15-020 18 GLP10-01-01-15-021 19 GLP10-01-01-15-022 20 GLP10-01-01-15-023 21 GLP10-01-01-15-024 22 GLP10-01-01-15-025 23 GLP10-01-01-15-026 24 GLP10-01 -01 -15-027 25 GLP10-01-01-15-028 26 GLP10-01-01-15-029 27 GLP10-01-01-15-030 28 GLP10-01-01-15-031 29 GLP10-01-01-15-032 30 GLP10-01-01-15-033 InitJdate In: storage ID AJUjitJdate < _____ 1______ ' W i U ' i 1 Out: storage ID ______ L _______\_____ 1 InitJdate In: storage ID InitJdate Comments/lnitJdate 3M Study GLP10-01-02-15 Page 1 of 3 Page 144 of 514 ENVIRONMENTAL LABORATORY INTERNAL CHAIN-OF-CUSTODY Sample Internal Transfer Sample set ID # Urns # N/A GLP10-01-01-15 Sample Description: Decatur Soils INTERNAL CHAIN OF CUSTODY # 3M Sample IDs boR'l 'T^r^31 GLP10-01-01-15-034 Out: storage ID ____ InitJdate 32 GLP10-01-01-15-035 33 GLP10-01-01-15-036 34 GLP10-01-01-15-037 35 GLP10-01-01-15-038 36 GLP10-01-01-15-039 37 GLP10-01-01-15-040 38 GLP10-01-01-15-041 39 GLP10-01-01-15-042 40 GLP10-01-01-15-043 41 GLP10-01-01-15-044 42 GLP10-01-01-15-045 43 GLP10-01-01-15-046 44 GLP10-01-01-15-047 45 GLP10-01-01-15-048 46 GLP10-01 -01 -15-049 47 GLP10-01-01-15-050 48 GLP10-01-01-15-051 49 GLP10-01-01-15-052 50 GLP10-01-01-15-053 51 GLP10-01-01-15-054 52 GLP10-01-01-15-055 53 GLP10-01-01-15-056 54 GLP10-01-01-15-057 55 GLP10-01-01-15-058 56 GLP10-01-01-15-059 57 GLP10-01-01-15-060 58 GLP10-01-01-15-061 59 GLP10-01-01-15-062 60 GLP10-01-01-15-063 61 GLP10-01-01-15-064 62 GLP10-01-01-15-065 d l/JVI-l OlirliIn: storage ID InitJdate ___ /______ il-- % --- Out: storage ID InitJdate In: storage ID InitJdate Comments/lnitJdate 3M Study GLP10-01-02-15 Page 2 of 3 Page 145 of 514 ENVIRONMENTAL LABORATORY INTERNAL CHAIN-OF-CUSTODY Sample Internal Transfer Sample set ID # Lims # N/A GLP10-01-01-15 Sample Description: Decatur Soils INTERNAL CHAIN OF CUSTODY # 3M Sample IDs Out: storage ID InitJdate In: storage ID InitJdate 63 GLP10-01-01-15-066 64 GLP10-01-01-15-067 65 GLP10-01-01-15-068 66 GLP10-01 -01-15-069 - / ____ h -/ X 'ft* it / X '7 h '7 ! ______ L______ 1 67 GLP10-01-01-15-070 68 GLP10-01-01-15-071 69 GLP10-01-01-15-072 70 GLP10-01-01-15-073 71 GLP10-01-01-15-074 72 GLP10-01-01-15-075 73 GLP10-01-01-15-076 74 GLP10-01-01-15-077 75 GLP10-01-01-15-079 76 GLP10-01-01-15-080 77 GLP10-01-01-15-081 78 GLP10-01-01-15-082 79 GLP10-01-01-15-083 80 GLP10-01-01-15-084 81 GLP10-01-01-15-085 82 GLP10-01-01-15-086 83 GLP10-01-01-15-087 84 GLP10-01-01-15-088 85 GLP10-01-01-15-089 86 GLP10-01-01-15-090 87 GLP10-01-01-15-091 88 GLP10-01-01-15-092 ____c ____ -- Out: storage ID InitJdate In: storage ID InitJdate Comments/lnitJdate 3M Study GLP10-01-02-15 Page 3 of 3 Page 146 of 514 Report Results `o: VOCs I Other Total Number o f Containers Environmental Laboratory Form 36778 - A PWO OHIppIrtQ A d d r a m 3M Center Bldg. 260-5N-17 St. Paul. MN 55144 Telephone; Sampln Rocdvlng: (65117M-6S59 Alternate: (651)7354873 FAX: (651) 733-5982 Contact Name Company / fr^ j Mailing Address City, State, Zip Telephone # 'T - <T"7 O S p ecial instructions a n d /o r Specific R egulatory Requirem ents: (method, limit of detection, reporting units, etc.) Chain of Custody /Request for Laboratory Analytical Project ID/Project Name Template U Project Lead Dept. # (main) j /O jO / S L A U fi /} S2>/<- Final Rep6rt Due Date Internal Due Date Class/Job/Project # Date Available 14967 3M Env. Lab Project # For Internal Use Only CPI ( ^ A -sr FAX # Date Due Contract Lab P re s e rv a tiv e s : < 6 fa A nalysis Requested: Com plete b elow . A ttach any associated inform ation. n ZO Z 0N) z 2 i 5 F tjE / : Co 0 Item # 1. 0 / 3 1 Client Sample Identification SS TZtPl D o o o 2. f i f ' ^ ^ 5 /7 oo <Si3 n <r>oor>3. D A L S S 4. 0 A t _ S Y /T . O o5* 3M Date Time Matrix/ LIMS# Sampled Sampled Media /) /) / TO G O 'S / y t/3 4 ./n I /Cto____ / :c S ' /r,2 S ------- 5 5- S Enter tho number of containers of cacti X t 1 1 1 X 5. D a l *7 A oooD AL SSil6. D a L, S S S S t k 7. S S OA c > n > 0 O oooo > 0 5T l /IB S ' S \ tl` 3 F 307 \ f/M 1 1 I 8. a l <r<r// o o o o <r 9. D a l SS r s z o o o o o o K ; /S " / /S.-oC ? y 1 /L 10. V a l ss sS 2& a s _ tM i /3 x > f s X 'l Collected by (print): Collector's signature: (Enter an `X in the box below to Indicate reauest) I Item # s o <o !-/ > c XL nyshed by/Affiliation Time Data Shipped Via: /2 Q O t'& S i! y & J * 7 3/ 7 Received by/Affitiation M Time Date &L M il Sample Condition Upon Receipt: Temperature: 0 ^C Other Associated CoCs; Acceptable 0 Other: ' 0 Received on Ice Copies to: JQPage / Ot Original Accompanying Samples Comments: Last Page Originator See Reverse Side for Instructions 3M Study GLP10-01-02-15 Page 147 of 514 Report Results to: VOCs Other Total Number of Containers Environmental Laboratory Chain of Custody /Request for Laboratory Analytical Forni 30778 A lWO Shipping Addro*: Tolophono; 3M Center Sample Receiving: (651) 736*6559 Project ID/Project Name Template # A Final Report Cue Date BWg. 260-5N-17 St. Paul, MN 55144 Alternato: (651) 733-9873 FAX: (651) 733-5982 Project Lead Dept. # (main) Internal Due Date Class/Job/Project # Contact Name Company A ftatSZsO C7TE. 1A / / Available Mailing Address City, State, Zip #Telephone l ' i ' l "3 S 1 Special tnstructlons and/or S pecific Regulatory Requirem ents: (m ethod, limit o f detection, reporting units, etc.) FAX# Date Due Contract Lab P re s e rv a tiv e s : 14 9 6 8 3M Env. Lab Project# For Internal Use Only ( b i f / o o iq t& 6 ? A nalysis Requested: Com plete below . A ttach an y a sso ciated Inform ation, 6 Z X iNti X o e0 z 5 > Item # Client Sample Identification 3M LIMS# 1. DAu i T 5 : 5 7 9 O O o o 2. D a l ^ s v r t 0 a o o S ~ 3. D a l . SS r 5 / r /OE . 4. LD A SS S 5 7 9 " O O D O 5. AL SS Z S (? O (D O oo> 6. D al, SS 1 * ? - o o o o o 7. DAL fS 5 7 8 M 0 0 0 ( 0 8. OAL S S S i R o 0 - 0 0 0 O l 0)7 2 )/V O IS d l{. od ipY 9. AL <57> A A P o o n on 10. ^ s s i r * o O O O ______ Date Time Matrix/ Sampled Sampled Media l/lt/ft (3-2J S / Tr s wA / S ' 2 . 6 5 /S .'S fc S S / V . ' 2 C > va/ \ y w iM J iL Enter the num txir o f containers of each >< 1 /t 1 1 11 1 f f 1 L X 1 (Enter an 'X1 in th e b ox below to indicalo request) f Item U fi 3 /- !Q * is * ished by/Affiliatlon ! Time /Z 0 Shipped Via: ? /*& Time u s . Date Sample Condition Upon Receipt: Temperature: Other Associated CoCs; rC X Acceptable 0 Other: 0 Received on Ice Copies to: Page o,J O Original Accompanying Samples 3M Study GLP10-01-02-15 Comments: Last Pago Originator See Reverse Sido for Instructions Page 148 of 514 Environmental Laboratory Form 38778 - A - PWO Shipping A ddm t: Ttftphonp: 3M Center Sample Receiving: (651) 73641559 Bldg. 260-5N-17 Alternate: (651) 733-9873 St. Paul. MN 55144 FAX: (651) 733-5982 Contact Name Company Mailing Address T City, State, Zip Telephone # ~ 3 < r? o Special Instructions and/or Specific Regulatory Requirements: (method, limit of detection, reporting units, etc.) Chain of Custody /Request for Laboratory Analytical Project ID/Project Name Template # Project Lead Dept. It (main) JHAL- '* / h ). A V O 1L./S 0.) Final Report Due'Date Internal Due Date Class/Job/Project # 14969 Date Available 3M Env. LaD Project 4 For Internal Use Only &L.P1O 0 ( lG r& . Date Due FAX# Contract Lab P re s e rv a tiv e s : A nalysis Requested: Complete below. Attach any associated Information. T o ta l Number o l Containers o JZz o oeo o QX Z Item # Client Sample Identification 3M LIMS# Date Time Sampled Sampled Matrix/ Media Enter the numtx r of containers of each 1. M L 5 " 5" S 3 a oog>c> Z j/ze/rt //:3lT 5 " X 1X 2. A L S S 3. P a l i f < r < r ? o a .o o o r o o o ir zz 13 / /(M r IMST 5 f I 4. O ftL jS'S' 5 S " 2 5 ' o O . 1 2 ^ < 5* 1 5. AL C 5 5 ^ 2 . 5 " o o f Z $ / 6. DA L f r ^ Z S " 0 . 0 0 . . / dz^ /*< < ; ' 5" 1 7. O AL SD . 2 2 O r>no<L> Z7 /A /<T T / 8. D a l <:D S3L3L O o O S " 9. DAL, <D> ^ 1 2 DA D o o ^ 10, P A L <;D 52.-Z, ^ Q / r i> ZY 02? >7^ /3 2 /A 2.0 /,23J> <r 7 T i LO -. I ed by/Affiiiation Time Date Shipped Via: 3 b o S X y^_ m eC> *5 c 31 <tou . C5/ K ? (Enter an 'X' in the box below to indica e reouost) Time Date t /n x 2 / i/ lt Sample Condition Upon Receipt: Temperature: Other Associated CoCs: '^A cceptable 0 Other: 0 Received on Ice Copies to: JL JO Original - Accompanying Samples Comments: Last Page - Originator See Reverse Side for Instructions 3M Study GLP10-01-02-15 Page 149 of 514 Report Results to: VOCs Other Total Number o f Containers Environmental Laboratory Chain of Custody /Request for Laboratory Analytical Forni 38778 * A - PW Shipping A d d ra u : TI*phone: 3M Center Semple Receiving: (651) 736-6899 Bldg. 260-SN-17 Alternate: (651) 733-9873 St. Paul. MN S5144 FAX: (651)733-5982 Project ID/Proiect Name Template # Project Lead Dept. # (main) & f\L E. A < "0 / L S O E . / ) Final Report Due Date Interna) Due Date Class/Job/Praject # Contact Name Company H ctfE j ^TfLt a / / Date Available Mailing Address L2 2 4 -- 5 -- ) 3 Date Due City, State, Zip Telephone# *73*? ~ 3,5*7 Special Instructions and/or Specific Regulatory Requirements: (method. Srrut of detection, reporting units, etc.) FAX# Contract Lab P re s e rv a tiv e s : 14970 ' 3M Env. Lab Project # For Internal Use Only & L .P /0 0 ( A nalysis Requested: Complete below. Attach any associated Information. Item # Client Sample Identification 3M LIMS# 1. Da l 3 5 / ) : 2 . / 0 o o G 2. n v c s t f S t O i U 0 o o r 3. iO t h - s o 3 v z l \ 0 / r S 34. P a c <5 2 4 0 0000 5. Dal 3 5 S S lA 0 O o o 5 " 6. Da l 5S - f S . Z . 4 0 o r w r 7. 8. 9. Da i 3 O/loalt. ? < SreSZ2.J7 fl (?) of l rotiofT < ? ,? / 7y 57 10. . ______________________________ Collected by (print): T 7 JtA f~/&/ Item # led by/Affiliation zA O OT XX z0c0 Date Time Matrix/ Sampled Sampled ifa fn / V 2 $ r Media 5 Enter the number of containers of each X1 X n /H 30 3 / /M o $ f /<T oo r 1 [ /S 'io r Lf \ /S'-xo 1 \ / 7t/o d i\ /<r 4 o / / rf <H<5r <rr 7 !7 x 1X S O . . __ c Collector's signature: 5 'Et r C XL > (Enter an X in the box below to indicate request) Time Date. Shipped Via: :vec^by/Affiliation-' Time Date LzZ . / X c .'i i ~Jm 1 / n iT T ZI L 3( Sample Condition Upon Receipt: Temperature: Other Associated CoCs: "^A cceptable 0 Other: O Received on Ice Copies to: Page i L Of IQ Original Accompanying Samples Comments: last Page - Originator Soo Reverse Side for Instructions 3M Study GLP10-01-02-15 Page 150 of 514 Report Results to: Total Number oi Containers Environmental Laboratory Form 38778 A - PWQ Shipping Address: 3M Center Bkfg. 260-5N-17 St. Paul, MN 55144 T elep h o n e: Sample Receiving: (651) 736-6559 Alternate.' (651) 733-9873 FAX: (651) 733-5982 Chain of Custody /Request for Laboratory Analytical Project ID/Project Name Template # Project Lead Dept. # (main) 0>P i L~ /il/E . / S r i - / -5/E/J Final Report<6ue Date Internal Due Date Ctass/Job/Project # Contact Name Company & A & \f / / / n/V /E yU S TE t f J Date Available Mailing Address City. State, Zip Telephone it / 7 ' 3 / 7 - 3 S * 7 C~> Special Instruction* and/or Specific Regulatory Requirements: (method. Untilof detection, reporting units, etc.) FAX # Date Due Contract Lab P re s e rv a tiv e s : 14971 3M Env. Lab Project # For Internal Use Only (3 r L- A nalysis Requested: Complete below. Attach any associated Information. 6A Oz z (0 X O0) O > zOe0 h. Item # Client Sample Identification 1. D A L S S SSZO 2. D A L 5"<! S S 1 3 O O nooC _ 3. A A L S S S S 13 OB n o o S~ 4. Da l S f s s iC o ooo? 5. A L S S S 17 O O t> o ~ 6. D A L S S f*> r > o d < T 7. Da l s s s s i o 0 0 0 r 8. n / \ L - O f l o o r 9. A L. S S < S t ( k O c l o t s ' 10. D A L S S O p o o r ___ Collected by (print): 3M LIMS# f)y > O HI w oyy $ vy <?V> d V7 Date Time Sampled Sampled Matrix/ Media Enter the number of containers of each t- lfi- /3 S S S X / / `i l t i r f i & S s s ( / :.H 3 s r\ / < / S 2 rf & e Z \C 1 'r A-27-/ iS 'M _ s _ Collector's signature: / 1 I 1 1 ] 1 K i ' c c ) (Enter an 'X1in the box below to indicate reouest) Item # ^jjplingpished by/Afliliatlon Time Date Shipped Via: pived ^/Affiliation Time Date /-/ > 2L Zot e Iz 3/ l z< h i Sample Condition Upon Receipt: Temperature: f i l ' C Other Associated CoCs: ^/Acceptable 0 Other: O Received on Ice Copies to: J OPage S" or Original Accompanying Samples Comments: Last Page - Orighator See Reverso Side for Instructions 3M Study GLP10-01-02-15 Page 151 of 514 Report Results to: Total Number of Containers 3M Environmental Laboratory Shipping Addras: 3M Center Bldg 260-5N-17 St. Paul. MN 55144 Tlphona: Sample Receiving: (651) 736-6559 Alternate: (651) 733-9673 FAX: (651) 733-5982 Contact Name S /K f Company / f-/o H Mailing Address City, State, Zip Telephone # Y 3 7 ~ "?5" 1 Special Instructions and/or Specific Regulatory Requirements: (method,emitofdetection, reportingunits, etc.) Chain of Custody /Request for Laboratory Analytical Project ID/ProJect Name Template # Project Lead Dept, ft (main) STTE. 7V T )A L A O tL A Sn 1L. / S /l ~Final Report Dde Date Internal Due Date Class/Job/Pro ect# Date Available FAX * Date Due Contract Lab Preservatives: 14972 3M Env. Lab Project # For Internal Use Only <7L o o g t e p r'l/ifli Analysis Requested: Complete below. Attach any associated information. n O 5 Z Z Z8 O(0 ZO o o 5 $ p5 Item # Client Sample Identification 3M Date Time Matrix/ LIMS# Sampled Sampled Media Sntorthenumbr rof containersofeach /Enteren'X*b theboxbelowtoindicatereauosi) 1. A L r s s s i o Oft c o o s ' 2. A L s<i lO o a t S~ <ro d S fT H o / is s s T r X. / X // 3. f ) A L . S S D 2 > O O O O O SI V r /r < 4. A L S S .O O Goc> S' O f S' 1 5. D a l S SOCtO O D C / S~ 7 )S J ? . s i 6. A L < < 0 X 3 o e o o O o rr 0 1 x 2 .0 T ( 7. A L < 0 ^ 0 X 3 o D o o r > r . \ 8. A L < [ ) S X.3 o o o t T .n< 9. A L k*5- S<;xK o & o s o . T r \ I 10. QAL SS2-Z Q POOS:_____ A t l'Z H ! r 'S f T 1 i /L X Li- * [ / Collected by (print): *T 7 /Ia M )A fa L Collector's signature: f Item # s O 'S c 'shed by/Affilialion lA } S Tc ^ Tim e Date_ Shipped Via: 1 2 -b O t- i 31 Tim e Date 7m i m . lh )>IL Sample Condition Upon Receipt: Temperature: T p l 'C 1OtherAssociated Cods: ^ Acceptable G Other: / O Received on Ice Copies lo. Pago ) or / > Original - Accompanying Samples Last Pago Originator See Reverse Side for Instructions 3M Study GLP10-01-02-15 Page 152 of 514 Environmental Laboratory Form 38770 - A PWO S h ip p in g Addrtr: 3M Conter BWg. 260-5N-17 St. Paul. MN 55144 Tolephono; Sample Receiving: (651) 736-6559 Alternate: (651) 733-9873 FAX: (651) 733-5982 Chain of Custody /Request for Laboratory Analytical 14973 Project ID/Project Name P A L. A E . A 5 o i C tc.U Template # Final Report Due Date Project Lead Internal Due Date Dept. # (main) Class/Job/Project # 3M Env. Lab Project# For Internal Use Only, , / C?L.f lO o (& tz n ' ) 5^ Contact Name Company ? /)/g . I f r h /c -h J 'i I /O Date Available Mailing Address Date Due City, State, Zip Telephone # 739 . 2 ^7 0 Special Instructions and/or Specific Regulatory Requirements: (method, limit of detector, reporting units, etc.) FAX# Contract Lab Preservatives: Analysis Requested: Complete below. Attach any associated information. VOCs Total Number of Containers on z X (ONfi X cO j&C z5 5r < C Item # Client Sample Identification 1. D A L C 5 5 5 2 $ T 8 O 2 PAL 55 O O I5 " 3. C \AL i s t S i S O n o 4. A L 5 5 5 5 2 ? D 0 0 0 5 " 5. H A L 5 5 6. C A L r s S S Z 1? O 5 S 2 .Z . o o / S '" an>an 7. A L 5 5 - 5 5 2 , 2 - a> 0 0 0 5 8. A L 5 5 S ^ y J Z . p rx O K 5 " 3M Date Time LIMS# Sampled Sampled O l-2?` lf A t,f U 1/ it c o O il // oS " < 5 /,? 7 /:/'T lt \ //3 S " O ,1 \ (4C > \ fM C > Matrix/ Media * < 5 Entor (he number of containers of each X / 1 / I X r *1 <; / / <r / i (Enter an 'XaIn the box below to indicate reouosO 9. D A L 5 5 S S 2 . 2 . 10. H a l 5 5 5 S 2 . / o Collected by (print): n n 7 C* 0 /a 9 U H T S' o o o q _________ & - k 2 3 d L '5 Collector's signature: 11 f ^ t 2 * L - 4 1-- Item# 3 o / -/ > j ^R^ngaished by/Afffllatlon U ) .< m 3 s o Time Date Shipped Via: _______ _^Z,,___XR_e_c_e_ivJejd by/Afffi_li_at_io_n_______ ________ Time Date / 2 0 A 3 / - / / z & J k jT P n 7 /) 7 } tT ( ' Sample Condition Upon Receipt: Temperature: f c l 'C Other Associated CoCs: '^Acceptable C Other: ' O Received on Ice Copies to: P a. J L Of J - Original Accompanying Samples Last Page Originator See Reverse Side for Instructions 3M Study GLP10-01-02-15 Page 153 of 514 Report Results to: VOCs Other Total Number ol Containers Environmental Laboratory Forni 38776 - A PWO Oftlpplng Aitiir 3M Center Bldg. 260-5N-17 SI. Paul, MN 55144 Talopbano; Sample Receiving: (651) 736*6559 Alternate: (651) 733-6873 FAX: (651) 733-5962 Contact Name Company Mailing Address //& * > /' City, State, Zip Telephone # "7 3 ^ Special tnstructfons and/or Specific Regulatory Requirements: (method, limit of detection, reporting unRs. etc.) Chain of Custody /Request for Laboratory Analytical 14974 Project ID/Project Name Template # Project Leed Dept. # (main) S \J A O E .A < O l L / <,' E O Final Report Du Date Internal Due Date Class/Job/Project # Date Available 3M Env. Lab Project# For Internal Use p a ly , G L f iO /r Date Due FAX # Contract Lab P re s e rv a tiv e s : n ZOZ z<M0 0c 1 A nalysis Requested: Complete below. Attach any associated Information. c5 >! X 5 Item # Client Sample Identification 3M Date Time LIMS# Sampled Sampled 1. M e r s - r r - ? / a oooS ' 2. D A L. S f a o i S' 3. D A I H i i % 0 6 0 0 1P O l\ ftix /-2 7 -/Z / Z / O / IZ 1% /3 C 4. p A i < t f ) S ' 0 i 2 5. D A L S P S O ) % o of rtO O lT VJ 01 Q /3 OSI (Z II 6. H a l < L < 0 / ^ r> q d ir /3 3 S 7. p j u < ) S l H o o ' Q lfr /3 4 0 8. P a i S S P o o iC ' A9. l , 5 S Z Z C - > f i C O H iv /SH? /S 'D O 10. P A L <r? s s z c JJL & O Q ________ Iz Z d i Matrix/ Media % { < 5 * W Enter the number of containers of each X (X I1 1 1( I1 1 1 1 1 11 I )( X o-L X (Enter an 'X' In die box botow to indicate reauest) f Item # 1 -1 0 hed by/Aftiliation Time Date Shipped Via: z o o iz 3 t U ? U )Z j A Time JL Z L Date Sample Condition Upon Receipt: / TTemperature: 'C Other Associated CoCs: ^c/Acceptable 0 Other: 0 Received on Ice Copies to: Page at / C> Origina} Accompanying Samples 3M Study GLP10-01-02-15 Last Page - Originator Sco Reverse Side for Instructions Page 154 of 514 Environmental Laboratory Form 38778 - A - PWO hipping A d d rm : 3M Center Bldg. 260-SN-17 St. Paul, MN 55144 T*lphor>o: Sample Receiving: (6S1) 736*6559 Alternate: (651) 733-6873 FAX: (651) 733*5682 Contact Name Company Mailing Address City, State. Zip Telephone # 731 3S" 7 Special instructions and/or Specific Regulatory Requirements: (method, ftmit of detection, reporting units, etc.) Chain of Custody /Request for Laboratory Analytical 14975 Project ID/Project Name Template # Project Lead Dept. It (main) ' A E - A So ! / Final Report Due Dat Internal Due Date Class/Job/Project # 5 " ) < rr-fc i s Q Date Available 3M Env. Lab Project # For Internal Use O nly otoie-g?(g fy Z h b l /S ' Date Due FAX# Contract Lab Preservatives: Analysis Requested: Complete below. Attach any associated information. Total Number of Containers Item Client Sample Identification # 0 0 Q 0 1 . Al Z S r>h 2. Ci 3. OA- SZzS Q c > o i< r 4. f it r ZS " lP X o D O 5. p i. <SS Z S IX 0 A n t *T 6 . nL. S5 n <? r r > i - 9 ~ o7. A L S S S S X O A l 5" 8 . D a l SS sr S/ U 0 A G 1 5 7 9. DA /? / r 10. n i - s s _Q_ o o 1 5 " Collected by (print): 1~7-- T y iis O J K ished by/Afflllation om Z <n to Oo o co x: ZX > zs 3M LIMS# Date Time Sampled Sampled Matrix/ Media Enter (he number of containers of each d i o r-z ? -// /Z /Z - d t f i r~ 2 % /l fS T l/p T S' X fX 1/ STL t-w -H /< rx 4 T 0 7 } t'TO it -- - X /X X 1 1 -2 2 -tl Z l Z 5* 7i J /4 " / o s rt/o c L1 d f t / o zr 1 077 o HO < M S.P 1 r \ <T /-ZZ-I JO 3 3 Collector's signature: ( K JLc St C,y ;c > (Enter an X* in the box below lo indicate reouest) Time Date Shipped Via: /2-ic>0h3(-i\ ^ 5 ? Regilved hy/Afniiallon 7 Time Date \ l i a - W-- L Sample Condition Upon Receipt: Temperature: Other Associated CoCs. J Acceptable 0 Other: O Received on Ice Copies (o: .2 .Paga O f 19 Original Accompanying Samples 3M Study GLP10-01-02-15 Comments: Last Page Originator See Reverso Side for Instructions Page 155 of 514 Chain of Custody Total Number of Containers Environmental Laboratory Form 38778 A - PWO Shipping Address; Telephone; 3M Center Sample Receiving: (651) 736-6569 Bldg. 260-5N-17 Alternate: (651) 733-9873 St. Paul, MN 55144 FAX: (651) 733-5982 Contact Name Company Mailing Address f City, State. Zip Telephone # 7 3 7 - 3 S''/5~ S p e c ia l In s tru c tio n and/or S p e c ific Regulatory Requirements; (method. Hrnitof datodtan. reporting unis. etc.) Chain of Custody /Request for Laboratory Analytical Project ID/Project Name Template # Project Lead Dept. # (main) TT7E1A ) /> ? . A o >4 Final Report Due Date Internal Due Date Ciass/Job/Project # - Date Available Date Due FAX# Contract Lab Preservatives: 14976 3M Env. Lab Project# For Internal Use Oqjy C L f / D O lO ie r& 7<r Analysis Requested: Complete below. Attach any associated Information. Item # 1. n>Ai 55 2. O A L .S 5 3. p A 1 ~ < , 5 4. 5. 6. 7. 8. 9. 10. Client Sample Identification S5\8 5511 o o o o i< r /r c lf Collected by (print): Item# T T zU l~ A /A A K - ^gakrfQuispd by/Affiliation /- 3 3M Date Time LIMS# Sampled Sampled 0 't D /-2 3 -lt /O < o 05! fO 5 "? o ?Z- llfiX on z Zi oUta & Matrix/ Media S' S Enter the numtw r of containers of each X X X / / / 5 't i - 6 y X X (Enter an 'X1In the box below to indicate reauostt Time Date Collector's signature: Shipped Via: /Z O O / 'J / ' / i x 1r -- ^ ^Received by/jmiliation -- Time Date z J ih i Sample Condition Upon Receipt: Temperature: ( `C Other Associated CoCs; jBrAcceptable 0 Other: O Received on fee Copies to: Pago / O Ot f e Original - Accompanying Samples 3M Study GLP10-01-02-15 Comments: Last Page Originator See Reversa Side for Instructions Page 156 of 514 Date: Analyst: JA SINGLE COM PONENT PREPARATION LOG Description: A P R ! A Book No. 10 005 Page No. 172 0%-TcStock Number: aoy-V. EWeight or Volume Used: fp ( Concentration or so ^Purity: (,__ Corrected Weight: fL Balance ID: VI Other Correction Factors: 0.19/ Solvent and TN-A Number: _ Final Volume: I f r v - x (-- Storage Location: f o ld Final Concentration: Expiration Date: H j ~) K - M i ! o - i? COPY OF ORIGINAI INITIAL date---- 3M Study GLP10-01-02-15 Reviewed by: Signature, I/^,//o Date Page 157 of 514 Date: I " ( Analyst: _ ,K 3 Description: A4 p r SING LE C O M PO NENT PREPARATION LOG 4 Book No. 10 005 Page No. 173 Stock Number: ' r a t P - m i - y . n Weight or Volume Used: . ~~ ( f ? Concentration or Purity: Corrected Weight: Balance ID: \n Other Correction Factors: Solvent and TN-A Number: o.W Final Volume: I < )- l / I A ( ____ Storage Location: AQ2 Final Concentration: n t 'v L c . Expiration Date: COPY OF ORIGINAL in it ia l ^ 5 tv date 3M Study GLP10-01-02-15 Page 158 of 514 Date: Analyst: (0 V 'lO J /?5 SINGLE COMPONENT PREPARATION LOG 5Description: I ^ F F O Book No. Page No, 10 005 174 Stock Number: T C H - 0 O V H ' V c , Weight or Volume 1 (/ (/Used: n T, sp -------------------------- i Balance ID: 1/7 Concentration or Purity: 50 Corrected Weight: n/ Other Correction Factors: e . % ~c Solvent and TN-A Number: --_ Final Volume: ) 7 L Final Concentration: nr Storage Location: A < no Expiration Date: - 0 '// ^ A C T COPY OF ORIGINAL INITIAL DATE 3M Study GLP10-01-02-15 Reviewed by: (__V Signature, / )p < * h / J Date Page 159 of 514 Date: ^ SINGLE COM PONENT PREPARATION LOG Analyst: Description: 1-Q~n i t o , m f ~ pp? Book No. Page No. 10 010 89 Stock Number: T e n - m e , </>Weight or Volume Used: if/Q A ^ 04 i f Concentration or Purity: T C "Y c. Corrected Weight: T il Y Y Balance ID: H T Other Correction Factors: 0TW Solvent and TN-A Number: -- Final Volume: Storage Location: Final Concentration: ^ Ll Expiration Date: 7 - C 'ii EXA^COPY OF ORIGINAL INITIAL DATE 3M Study GLP10-01-02-15 Page 160 of 514 Date: H ' i I Analyst: ,k < SINGLE CO M PO NENT PREPARATION LOG Book No. 10 010 Page No. 63 Description: M A C U I 'd0 I I: TStock Number: - 7/ Weight or Volume Used: 0.1075 Balance ID: 1/7 Concentration or Purity: _ % /Z Corrected Weight: O .K K p Other Correction Factors: 0 fK sr: ASolvent and TN-, Number: caj Final Volume: Final Concentration: Storage Location: A s ia Expiration Date: h tu 3M Study GLP10-01-02-15 Page 161 of 514 i l l 111Date: SINGLE COM PONENT PREPARATION LOG Analyst: PF (Ecf)Description: OA Book No. 10010 Page No. 67 TCP--X2,Stock Number: Weight or Volume Used: Concentration or Purity: O.IKSy Kl Corrected Weight: O.illa J Balance ID: Other Correction Factors: o, k y AcvSolvent and TN-A Number: Final Volume: Storage Location: -Klo Final Concentration: Expiration Date: U rn * * L i . r v \\ ( EXACTtOPY OF ORIGINAL INITIAL DATE 3M Study GLP10-01-02-15 Reviewed by: Signature, H I-/D Page 162 of 514 SINGLE COM PONENT PREPARATION LOG Date: Analyst: t Jfs FFSDescription: Book No. 10 010 Page No. 73 Stock Number: Weight or Volume Used: Oi Concentration or Purity: Corrected Weight: Final Volume: Storage Location: ) C ^ i-- A s lo Balance ID: In Other Correction Factors: Q, W y Solven' a ii f i c j j m m - m n , Final Concentration: mo m Expiration Date: i- m 3M Study GLP10-01-02-15 Reviewed b y -- M l Signature, Date Page 163 of 514 13' / /Date: SIN G LE C O M P O N E N T PR EPA RA TIO N LOG Analyst: Description: f*Fl"S Book No. 10 010 Page No. 74 Stock Number: tctin^-oois-1/, Weight or Volume Used: Concentration or Purity: Corrected Weight: o.imJ* to , 0 .I(>4 Balance ID: 9' /7f Other Correction Factors: L/. /f)Ci{Lf I Cs? " '" "LZ /4c4/ rm-ttm-'fic. Final Volume: \u'rii /^L.Final Concentration: ___ _____Storage Location: fJ Expiration Date: ^ ^ ^ ^/ EXAl COPY OF ORIGINAL INITIAL 3M Study GLP10-01-02-15 DATE Reviewed by: Signature? 4 - Date Page 164 of 514 SINGLE COM PONENT PREPARATION LOG Ip B te- h lL y'nalyst: At. *v A ki Description: PF o> Book No. 10 010 Page No. 75 S IE . Stock Number: ~rc-i% Weight or Volume Used: (m y & Concentration or Purity: _ k h i cL. IlYfejCorrected Weight: 0. Balance ID: Other Correction Factors: 0 ,^ 1 Solvent and TN-, Number: Final Volume: x^( Storage Location: A s ln Final Concentration: Sfsgro ^ Expiration Date: > * -// INITIAL DATE 3M Study GLP10-01-02-15 Page 165 of 514 z ' Diate: Analyst: H -// SINGLE COM PONENT PREPARATION LOG L-P R JSDescription: Book No. 10 010 Page No. 76 Stock Number: T c P -tN -0 0 0 1 ' '/, Weight or Volume Used: M - Concentration or Purity: _ o.m,Corrected Weight: 3- Balance ID: la Other Correction Factors: o.m Solvent and TN-A Number: Final Volume: Storage Location: 4 -^ x ) Final Concentration: % L ( ) % L Expiration Date: 2 EXACTCOPY OF ORIGINAL INITIAL DATE 3M Study GLP10-01-02-15 Page 166 of 514  mb*. f* ;, ; D a te : _ W/ SINGLE COM PONENT PREPARATION LOG ' ;|na|yst:- I -, *Descnption & * ' + * & i - P F oa Book No. 10 010 Page No. 68 :Stock Number: T (fc .Q 7 ~ 0 0 V l- Weight orVolume Used: .M1 & Concentration or Purity: _ w s i d. Corrected Weight: o rn o Final Volume: Storage Location: (_I k v - x S30- Balance ID: Other Correction Factors: 0w Solvent and TN-A Number:\ / \ C U T f J l O - ^ - ^ - % Final Concentration: Expiration Date: 7-H/ f exacX copy o f original INITIAL 3M Study GLP10-01-02-15 DATE Reviewed by: Signature, ( -k d rn ate ? Page 167 of 514 Date: Analyst: CL" IC - W GPf~l Description: SINGLE CO M PONENT PREPARATION LOG Book No. 10 010 Page No. 177 \?C Stock Number: 10 " 7 6 Weight or Volume Used: ,. Concentration or Purity: Corrected Weight: Balance ID: Other Correction Factors: C,H -'VtCSolvent and TN-A Number: A c n TbJ I o Final Volume:______2 Storage Location: /A ^ "7^ Final Concentration: 0 / L. Expiration Date: CO PY O F O RIG INAL IN ITIA L DATE 3M Study GLP10-01-02-15 Page 168 of 514 Date: 2L-1C ' ' t Analyst: Q ?r\ Description: SINGLE COM PONENT PREPARATION LOG Book No. 10 010 Page No. 178 Stock Number: 1> i> H t Weight or Volume Used: l oo Concentration or Purity: }o, o L Corrected Weight: Balance ID: Other Correction Factors: Solvent and TN-A Number: A O J 7V/Q nC Final Volume: ) ^ L- Storage Location:______/ \ Final Concentration: / L. Expiration Date: EXCTCOPY OF ORIGINAL INITIAL 3M Study GLP10-01-02-15 DATE Page 169 of 514 Date: Z - U ~H Analyst: GPm SINGLE COM PONENT PREPARATION LOG Description: p C jC t-r H yr Book No. 10010 Page No. 179 Stock Number >a o 10 ' i '$' Weight or Volume Used: Concentration or Purity:_____! A-t L Corrected Weight: Balance ID: Other Correction Factors: Solvent and TN-A Number: 77^/6- OVT? - Final Volume: 2 -S' M Z- Storage Location:______A S l^ > Final Concentration: <3, / Expiration Date: H 'l'Z '' 1I J COPY OF ORIGINA INITIAL DATE 3M Study GLP10-01-02-15 Page 170 of 514 Date: 2-1C ' Analyst: CrPm SING LE CO M PO NENT PREPARATION LOG Description: F ~C O r*~ t ^ Book No. 10 010 Page No. 180 Stock Number: i c G I ~ I ^ Weight or Volume Used: JoaO Z_ Concentration or Purity: . Corrected Weight: Balance ID: Other Correction Factors: Solvent and TN-A Number: A Chi T N / O - O 1/ ! ! ' v~/ c Final Volume:_____ / LStorage Location:______ .A SThO Final Concentration: I Ad e Expiration Date: H - i l - Il OPY OF ORIGINAL 3M Study u r n 02-15 DATE Page 171 of 514 SINGLE COM PONENT PREPARATION LOG Date: Analyst: HH/ JgL Description: / i a P P C Book No. 10 01Q. Page No. 88__ Stock Number: i; Weight or Volume Used:___ + //* Concentration or Purity: Corrected Weight: ^ tU o Balance ID: 1 /? --------------- Solvent and TN-A Number: Final Volume: Final Concentration: / I n oStorage Location:___ tompound Name Correction Factor Concentration (ug/mL) MPFBA 0 .9 9 5 5 .0 0 MPFHxA 0 .997 5.00 M8PFOA 0.998 5.00 M9PFNA M6PFDA 0 .998 0 .998 5 .0 0 5.00 M7PFUnA 0 .9 9 8 5 .0 0 MPFDoA 0 .9 9 8 5 .0 0 MPFHxS 0 .9 4 6 5 .0 0 M8PFOS 0.957 5 .0 0 JO (-HIM8FOSA 0.998 5 .0 0 Corrected Concentration (ug/mL) 4 .9 8 4 .9 9 4 .9 9 4 .9 9 4 .9 9 4 .9 9 4 .9 9 4 .7 3 4 .7 9 4 .9 9 3M Study GLP10-01-02-15 Expiration Date: l- i- u Reviewed by: Signature, Date PY OF ORIGINAL INITIAL DATE Page 172 of 514 H '// SINGLE COM PONENT PREPARATION LOG Book No. 10 010 Page No. 87 APfC AVDescription: ( atm-now-Vic.! ' StockNumber: ; Weight or Volume Used: Balance ID: 1 /7 Concentration or Purity:_ Corrected Weight: U Other Correction /j Factors: <> f U \ 0 u / Solvent and TN-A Number: Final Volume: Final Concentration: Storage Location: JR5 I'MCoNmapmoeund MPFBA MPFHxA MM98PPFFNOAA M6PFDA M7PFUnA MPFDoA MPFHxS M8PFOS M8FOSA Correction Factor 0.995 0.997 0.998 0.998 0.998 0.998 0.998 0.946 0.957 0.998 Concentration (ug/mL) 55..0000 5.00 5.00 5.00 5.00 55..0000 5.00 5.00 Corrected Concentration (ug/mL) 4.98 4.99 4.99 4.99 4.99 4.99 4.99 4.73 4.79 4.99 3M Study GLP10-01-02-15 C ) Expiration Date: Reviewed by: Signature, J h k jk H H ( la te INITIAL 173 of 514 Date: 2 - 1 6 - V l Analyst: GPtr\ SINGLE COM PONENT PREPARATION LOG Book No. 10 010 Page No. 181 Description: _ ? F t-K ( c p ) Stock Number: - OS' J Weight or Volume Used: Concentration or Purity: 4V o Corrected Weight: Balance ID: Other Correction Factors: O , ? I / Solvent and TN-A Number: /4 CN TN i ~ /7tT Final Volume:______ /C> ^ I-- Storage Location: Final Concentration: 2 . * / 0 //n L Expiration Date: -H > ' / ( 3M Study GLP10-01-02-15 Page 174 of 514 Date: 2.- IC' W Analyst: SINGLE COM PONENT PREPARATION LOG Description: C O 0>t ) F ^ n . * Book No. 10010 Page No. 1 8 2 Stock Number: 006 - Weight or Volume Used: . je o o ^ *-- Concentration or Purity:_____/Q , o j_ Corrected Weight: Balance ID: Other Correction Factors: Solvent and TN-A ?/ Number: - o N TN / Q ~ ' ! c Final Volume:____ w l -- Storage Location: -A Final Concentration: ) , 0 0 !~h < Expiration Date: T - ' J - l f EXATDPY OF ORIGINAL INITIAL date 3M Study GLP10-01-02-15 Page 175 of 514 Date: Analyst: Z 'U ~ n QPr'i Description: S .C -'F SING LE COM PONENT PREPARATION LOG I Book No. 10010 Page No. 183 Stock Number: /? 1^2^ Weight or Volume Used: M-1-- Concentration or Purity:_____ /_ Corrected Weight: Final Volume: 0 M .I-- Storage Location: A ^ Balance ID: Other Correction Factors: Solvent and TN-A Number: TN/U -?/ - // .Final Concentration: 0 I e J + jU L Expiration Date: 7 - 2 - 1 \ 3M Study GLP10-01-02-15 Page 176 of 514 SINGLE COM PONENT PREPARATION LOG Date: 2 j ' L Lj j l c > l l _________ Analyst: _ k ^ g _____________ Description: L - f f t f A 5,1^ m l(KrJL 5 t f i u h o < Q Book No. 10010 Page No. 194 Stock Number: j 0 16 - 1 L> Weight or Volume Used:________Le I *? U Concentration or Purity: d iM . Corrected Weight: Balance ID: Other Correction Factors: ACh/ i l iSolvent and TN-A Number: - ~Ta / 1 1 - < 7 ( 7 3 3 - Final Volume: 'Z 5 sri L Storage Location: A o lO Final Concentration: 9 ^ u Expiration Date: V j ^ T j i^- i\ 0^AbTCOPY OF ORIGINAL INITIAL DATE 3M Study GLP10-01-02-15 Page 177 of 514 Date: Analyst: 4 'if-ll CPr\ SINGLE COM PONENT PREPARATION LOG Description: A l \ ^ ^ A , J T tW l Book No. 11 002 Page No. 46 Stock Number: TC-ft- Weight or Volume Used: rS Concentration or Purity: rO g X vj Corrected Weight: Balance ID: Other Correction Factors: Solvent and TN-A Number: Final Volume:_______ Kl jAStorage Location:______ A `T'TQ Final Concentration: Expiration Date: f b ' 3M Study GLP10-01-02-15 Page 178 of 514 Date: Analyst: SINGLE CO M PONENT PREPARATION LOG /P ~~~/ / Description: / Y Y /<lS 7 / Book No. 11 002 Page No. 50 Stock Number: Weight or Volume Used: Concentration or Purity: Corrected Weight: - 9<o Balance ID: Other Correction Factors: Solvent and TN-A Number: < w / / - / > / < ? - y y Final Volume: Storage Location: /-A tS rK -S > Final Concentration: Expiration Date: COPY OF ORIGINAL ________ / INITIAL DAT 3M Study GLP10-01-02-15 Reviewed by: Signature, H -H - Date Page 179 of 514 SINGLE COMPONENT PREPARATION LOG Date: Analyst ^ ---------------- Description: / o DO Op " Stock Number: O JpJp p Book No. 11 2 Page No. 51 _ W eight or Volume Used: /O C D ^ c C ^ Concentration or Purity: Corrected Weight: Balance ID: Other Correction Factors: Solvent and TN-A f l& O c jf n U " Number: Final Volume: Storage Location: fP K > Final Concentration: Expiration Date: 3M Study GLP10-01-02-15 Reviewed by: Signature, ------------------ Date Page 180 of 514 Analyst: Description: SINGLE CO M PONENT PREPARATION LOG Book No. 11 002 Page No. 52 z> , H OCRStock Number: / Weight or Volume Used: 7 Concentration or Purity: / /A O / _ Corrected Weight: Balance ID: Other Correction Factors: A? QjSolvent and TN-A f- '/ / Final Volume: Storage Location: fiS lo Final Concentration: 3 ' / S `i / Expiration Date: -? -/W V P F /EXACTCOPY OF ORIGINAL hi ' INITIAL DATE 3M Study GLP10-01-02-15 Reviewed by: Signature, Date Page 181 of 514 Date: Analyst: tp ' / / Description: SINGLE COM PONENT PREPARATION LOG Book No. 11 002 Page No. 53 T s J rf./f _______ = -j J--, c /f ' Stock Number: Weight or Volume Used: Concentration or Purity: .I Corrected Weight: Balance ID: =T) Other Correction Factors: l^y-T/Q /Solvent and TN-A Number: // - a Pf 7V - Final Volume: Storage Location: rt = K > Final Concentration: o / Expiration Date: 7^EXAQTTCCOPY OF ORI NAL INITIAL DATE 3M Study GLP10-01-02-15 Reviewed by: Signature, Date Page 182 of 514 FC Ayp Description r\f . V Date Prepared J.W/ != ' Prepared By ^ v fV 'Storage Location M io M 5l Ana. | - Expiration Date Vr Standard ID # 10 006-11 MULTI-COMPONENT PREPARATION LOG Book No. 10 006 Page No. 11 Solvent:- M j L 3M Trace #: Expiration Date: - -ty n V_ _ _ |B H |K r (((^D e scrip tio n Component Standard ID# Cone, or Purity Expiration Date Weight or Volume Corrected Weight Balance ID Final Concentration B ffflA iam -fi) w % L V 'li'll ||V\(_ -- -- (| | M ( $ __ 1000!? '/7j H - H ' H 1- L ' Aar --- /o w r-p v H-un 1 ---- P l 'H -Il Final Volume Approximate Concentration of the mix 10.1) T i l J COPY OF ORIGINAL 7 INITIAL DATE 3M Study GLP10-01-02-15 Reviewed by: Signature, 'o ! / ' Date Page 183 of 514 $>; FC te W -.Description ' Date Prepared -L 'lt ^ Prepared By '-'Storage Location AF?n _Expiration Date MULTI-COMPONENT PREPARATION LOU Book No. 10 006 Page No. 46 Solvent: k e y 3M Trace #: T 'i//'P'Ocf'3'&l - 2/tc Expiration Date: ^ ~ 1 7 ~ ______ ^ 1 P - I ^^MBrajTescription Standard ID # 10 006-46 -- -- ------------------------------------------------------------------------------------------ Component Standard ID# Cone, or Purity Expiration Date Corrected Weight or Volume Balance ID Weight Final Concentration l B & m 10 0 / 0 - ^ 1 1 .1 *# 7 ~C-(f &0/A.(_ w lo o i - n 7 - L 'tj -- -- - m xL av 10 0 1 0 '? % e * ? / I'C 'i) ------ -- A \m I rr.SUlgihv.\- t i?; *i ; 1-C ,-/| Final Volume Approximate Concentration of the mix COPY OF ORIGINAL INITIAL DATE 3M Study GLP10-01-02-15 Reviewed by: _ Signature, Date Page 184 of 514 E S ;. IIIW H Book No. 10 006. Page No. 67 _ t- jS8* '- - . fettv. |p- D e s c rip tio n - C ,l T Date Prepared. _ 7 . - / 6 - H prepared By. _ Storage L o c a t io n . _ E x p ira tio n . ( T P '- t 4 < rfo 7 -3 -1 ____________ --------------------------- Solvent: A c h * ------ --------------- 3M Trace #: TM ) " ' f~7' / Z Expiration Date: _ ------- ------------- ||| f 11 ' u Description IrP fO A V L-PF^-S H' t 'P F H S ?FS |V;1 ? fB A Standard ID # 10 006-67 Component Standard Cone, or ID # Purity Jrt-\ 0 O \ b '( . I Corrected "I Weight Expiration I Weight or I g a|ance id 1 Date ( Volume Final Concentration l1 T '3'li \ go, S' M /4 / o . <D jo <51' 7 6 /. 5 -je-re-G> jo o)0"7H 4 ^ 6 6 f. !> O iO 'tl HHL0 ooio-CZ \Hl1o 1 -/> ^~Q> ; "I 1 s y ^ X6rr-&-G> t\ Final Volume Approximate . I Concentration of the mix / ' , L Q i. \ C nrv <~ -fw f EXACtOF/ OF ORIGINAL ^ -gtio o3M Studi 1-02-15 & ' x w7 Reviewed hV' ? ? x s ? '/ ^ ignature, / ^ T _?" L Date Page 185 of 514 MULTI-COMPONENT PREPARATION LOG ` Book No. 10 006 Page No. 68 Description: Soi l f~f>y Date Prepared: Prepared By: Storage Location: Expiration Date: _______________ GP^________ '________ A 'S~G<J______________ -3`li7 __________ Solvent: C N _______ 3M Trace#: tPI/o QVJ'f Expiration Date: ________ r Description ) PR A (e c ,f) pFs. C e ^ f ) pptfs. feci5) PFS PP /l #Standard ID 10 006-68 Component Standard Cone, or ID # Purity to c ~ Q 7 quo IO o \ o - 7 $ Expiration Date 7 -3 -n 7 -3 - M Weight or Volume [M LJ 5 L! Balance ID hi ( A Corrected Final Concentration Weight N/y4 ~T^ S H '5 1/O 0 )0 ~ ) i t Z H O r - / i * n 1(0 %n +O T * 0 1 6 - 7 3 W C 7 - 3-n <T6 % J7 /OO lo -< 3 H tfo 7 3- - n r?/ >" \ 9 .7 7 V/ G> G Jcukfrt^ r r < ~ - U Final Volume ZSnL Approximate Concentration of the mix yo,o -^/Vn dci' ,i^ / /= /` ce'r ' n C s* ~ 3 -> -l> COPY OF ORIGINAL _______________ 3M Stud IN IT IA L . . i D ATE T Description: S t)'. cjQ ' Date Prepared: ) "* / " / / __________ Prepared By: ____________ Storage Location: Expiration Date: jS ______________ -- /b --~ ( MULTI-COMPONENT PREPARATION LOG Book No. 10 006 Page No. 80 Solvent: 3M Trace Expiration Date: / R I I R R CT COPY OF ORIGINAL INITIAL DATE 3M Study GLP10-01-02-15 Reviewed by: S f/r V Signature, Date Page 187 of 514 MULTI-COMPONENT PREPARATION L O J ' 'V Book No. 10 006 Page No. 81 .*.1 f i! W H ---:, '(V [ te ff Description: Date Prepared: <&>' / / __________ Prepared By: _ ____________ Storage Location: _ A 3 1 C > ____________ Expiration Date: _ c? 'Z C r V /____________ Solvent: 3M Trace #; //)/ Expiration Date: H&K 8 |- pr W S' - ** Description M ib b- h o L .. Standard ID # 10 006-81 Component Standard ID# Cone, or Purity Expiration Date Weight or Volume Corrected Weight Balance ID Final Concentration H - ' o % 3 -- S *> y \M , f m ob -- -- 30 / * /) ( / / l ' 1i h ` Final Volume / Approximate / L . Concentration of the mix > < > T COPY OF ORIGINAL INITIAL DATE 3M Study GLP10-01-02-15 Reviewed by: Signature, VS- K Date Page 188 of 514 Description: >-,1 F-4- t~1>x Date Prepared: 7 - )/;. 11________ Storage Location: ^ s y -o MULTI-LEVEL PREPARATION LOG Book No. 10 007 Page No. 38 Solvent: ___________ Description \ 1 7 ^ Hx 'V ' ---- ----"" Standard ID # Description 10 007-38-1 10 007-38-2 10 007-38-3 10 007-38-4 10 007-38-5 10 007-38-6 10 007-38-7 10 007-38-8 ! I -z- ---- - ---- Component Standards ID # / 0 CZCs(m>" ie Cone Expiration Date 7 -? -a Std 1 /?oo Std 2 --- Amount of Component Standard A d d e d ^ u ^ Std 3 -- Std 4 Std 5 Std 6 Std 7 S td ^ a as} ~~2S~1 ! * 5 /^ 1 7 - ? - V -- , / e -- j c ^ l- Z k - Z o . 1---T /p^v T. - 1) '---- ----- ---- / t) ---------- -- Final Volume / " Final Concentration ) c )o /> ! > I 3-0 I Description Standard ID # 10 007-38-9 10 007-38-10 10 007-38-11 10 007-38-12 10 007-38-13 10 007-38-14 10 007-38-15- -1lT6<>7-38-16 Description Component Standards ID # Cone Expiration Date Std 9 Std 10 Amount of Component Standgr-ACcIded Std 11 S td J 2 -" "std 13 Std 14 Std 15 Std 16 y * JV tv ^ m o v n c n a A M ii INITIAL DAyTE/ / 3M Study GLP10-01-02-15 Finai-Vfilume _ ^ - ^ ^ ^ R n a l Concentration 1 Reviewed b; Signature, -- .-- >-- ( " Date ge 189 of 514 Description: Date Prepared: ,?-- / / --/ / Storage Location: / } 0 ^ 0 M ULTI-LEVEL PREPARATION LQQ Book No. 10 007 Page No. 47 Solvent: Description `- Q k * pm s> Standard ID # Description 10 007-47-1 / 10 007-47-2 10 007-47-3 <3 10 007-47-4 v 10 007-47-5 T 10 007-47-6 10 007-47-7 10 007-47-8 y. 2 Component Standards ID # Cone Expiration Date Std 1 Std 2 Amount of Compon ent Standard Added Std 3 Std 4 Std 5 Std 6 Std 7 Std 8 1 1 1/ > < 9/L > -^S / o 0o "T- 3. y - i'// '? 3 'H r. Z ' / V / -----^ ----------- y _____ - ------- ----- - -------- / /CO/AL. / V : yQ / y ji / - /j Final Volume Final Concentration / > *^ -- y r< i 0 .9 5 *? . o f f * / .O*)*}0! Standard ID # 10 007-47-9 10 007-47-10 10 007-47-11 10 007-47-12 10 007-47-13 10 007-47-14 10^107=47-15 10 007-47-1 < Description Description Component Standards ID # Cone Expiration Date Amount of ComponenLStndard Added FZStd 9 r~ Std 10 Std 11 ^ ^ S td 1 2 Std 13 Std 14 Std 15 Std 16 ( A irf /] , A\ -- -- v y --------------------------- p *-- INTTML DATE 3M Study GLP10-01-02-15 -- ^^-'^Finai'volum e Fi nal Concentration Reviewed by: Sfasature, ~~(/ ^ -'\F a g e "/9 0 of 514 Date Description: Date Prepared: y?--- / / Storage Location: Expiration Date: 7 3 // Solvent: 3M V \BpKasbV"^4li0D'Sf`-i Page No. ' *48 f ' r j & - -- /'f C s ? : .i,K --( "" _ Description PPHS M rS V \^ S > Standard ID # 10 007-48-1 10 007-48-2 10 007-48-3 10 007-48-4 10 007-48-5 10 007-48-6 10 007-48-7 10 (J07-48-8 Description Component Standards ID # Cone Expiration Date / Std 1 / f - W ;> / ----- --------- fOcb~l-l /OJ^/W- 7 7 7 / J1 -- ^ / ^*' (K/ . . 7 ^ 7 / --------- & Std 2 -- 7 <5~ Amount of Component Standard Added / / Std 3 -- Std 4 -- ------------- y Std 5 Std 6 Sid 7 -- r i/v -- 7 1 /7 /my y - U V n) Std 8 eC A C TC O P yO FO raO M A L Final Volume , Final Concentration / -- JdO /o /D.O /o /-OCz /o /o 6 J > 0-/bC> IN IT IA L DATE Standard ID # 10 007-48-9 10 007-48-10 10 007-48-11 10 007-48-12 10 007-48-13 10 007-48-14 10 007-48-15 10 007-48-1 Description Description Component Standards ID # Cone Expiration Date Std 9 Std 10 Amount of Component Standard Added Std 11 Std 12 Std 13 J3tcrl4^ Std 15 Std 16 'T'7/7^ s ' \ \ IW CTC '` ^FlfiaTvolum e Final Concentration Study GLP10-01-02-15 ~x 11 '7 L Reviewed by: \ ature, \/ Date Page91 of 514 Description: Date Prepared: P&S , Storage Location: / t*v S Solvent:: Book No. 10 007 age No. 49 Standard ID # 10 007- 49-1 10 007- 49-2 10 007- 49-3 10 007- 49-4 10 007- 49-5 10 007- 49-6 10 007- 49-7 10 007- 49-8 __ 1 Vv ___,__I Description 1 'P ib S Description Component Standards ID # /o o lO - I t s Cone J, />o^b " ^ 7 J ''T f Expiration Date * A /,, Std 1 Final Volume /O Std 2 Amount of Component Standard Added Std 3 Std 4 Std 5 Std 6 f r W p - 7 tl r--c>----------- SlcKT^ Std 8 Final Concentration Standard ID # 10 007-49-9 10 007-49-10 10 007-49-11 10 007-49-12 10 007-49-13 10 007-49-14 10 007-49-15 10 0flZ49-16 *' ' Description ______ n Description Component Standards ID # Conc Expiration Date f j / /fA r X ( ].J v yb / \ ^^tilaVolurne Amount of Component StandardAdded Std 9 Std 10 Std 11 _ / /if' C/ (J/ b 'L ( c7 Std 1 2 ^ --Std 13 Std 14 Std 15 Std 16 ___----^^^Final Concentration MIML OWE 3M Study GLP10-01-02-15 Reviewed bVL Date Page 192 of 514 ' GLP10-01-01-15 Screening Sample ID ___________ 1 EC-110217-01 EC-110217-02 EC-110217-03 EC-110217-04 EC-110217-05 EC-110217-06 EC-110217-07 EC-110217-08 EC-110217-09 EC-110217-10 EC-110217-11 MB-110217-01 MB-110217-02 MB-110217-03 MB-110217-04 MB-110217-05 MB-110217-06 LCS-110217-01 LCS-110217-02 LCS-110217-03 LCS-110217-04 LCS-110217-05 LCS-110217-06 GLP10-01-01-15-001 GLP10-01-01-15-002 GLP10-01-01-15-003 GLP10-01-01-15-004 GLP10-01-01-15-005 GLP10-01-01-15-006 GLP10-01-01-15-007 GLP10-01-01-15-008 GLP10-01-01-15-009 GLP10-01-01-15-010 GLP10-01-01-15-011 GLP10-01-01-15-012 GLP10-01-01-15-014 GLP10-01-01-15-015 GLP10-01-01-15-016 GLP10-01-01-15-018 GLP10-01-01-15-020 GLP10-01-01-15-021 GLP10-01-01-15-022 GLP10-01-01-15-023 GLP10-01-01-15-024 GLP10-01-01-15-025 GLP10-01-01-15-026 GLP10-01-01-15-027 GLP10-01-01-15-028 GLP10-01-01-15-029 GLP10-01-01-15-030 GLP10-01-01-15-031 GLP10-01-01-15-032 GLP10-01-01-15-033 GLP10-01-01-15-034 Sample Description _____________ 2__________ 0.2 ng Extracted Curve Point 0.5 ng Extracted Curve Point 0.75 ng Extracted Curve Point 1ng Extracted Curve Point 2.5 ng Extracted Curve Point 5 ng Extracted Curve Point 10 ng Extracted Curve Point 25 ng Extracted Curve Point 50 ng Extracted Curve Point 100 ng Extracted Curve Point 200 ng Extracted Curve Point Method Blank 1w/o IS_____ Method Blank 2 w/o IS_____ Method Blank 3 w/o IS_____ Method Blank 4 w/ IS______ Method Blank 5 w/ IS______ Method Blank 6 w/ IS______ 3 ng LCS in TCR-842______ 3 ng LCS in TCR-842______ 3 ng LCS in TCR-842______ 30 ng LCS in TCR-842 30 ng LCS in TCR-842 30 ng LCS in TCR-842 DAL SS SS Tripl 0 0000 DAL SS SS12 0 0000______ DAL SS SS12 0 0005______ DAL SS SS13 0 0000______ DAL SS SS16 0 0000______ DAL SS SS16DB 0000 DAL SS SS11 0 0000______ DAL SS SS11 0 0005______ DAL SS SS20 0 0000______ DAL SS SS20 DB 0000 DAL SS SS19 0 0000______ DAL SS SS19 0 0005______ DAL SS SS15 0 0000______ DAL SS SS17 0 0000______ DAL SS SS14 0 0000______ DAL SS SS18 0 0000______ DAL SS SS10 0 0000______ DAL SS SS30 0 0000______ DAL SS SS30 0 0005______ DAL SS SS30 0 0015______ DAL SS SS25 0 0000______ DAL SS SS25 0 0005______ DAL SS SS25 0 0015______ DAL SD SD22 0 0000______ DAL SD SD22 0 0005______ DAL SD SD22 DB 0005 DAL SD SD22 0 0015 DAL SD SD21 0 0000______ DAL SD SD21 0 0005 DAL SD SD21 0 0015______ DAL SS SS24 0 0000 Printed 2/18/2011 3M Study GLP10-01-02-15 ETS-8-053 Page 1 of 3 Soils Weighed 18-Feb-2011 Comments Page 193 of 514 GLP10-01-01-15 Screening ETS-8-053 Soils Weighed 18-Feb-2011 Sample ID 1 GLP10-01-01-15-035 GLP10-01-01-15-036 GLP10-01-01-15-037 GLP10-01-01-15-038 GLP10-01-01-15-039 GLP10-01-01-15-040 GLP10-01-01-15-041 GLP10-01-01-15-042 GLP10-01-01-15-043 GLP10-01-01-15-044 GLP10-01-01-15-045 GLP10-01-01-15-046 GLP10-01-01-15-047 GLP10-01-01-15-048 GLP10-01-01-15-049 GLP10-01-01-15-050 GLP10-01-01-15-051 GLP10-01-01-15-052 GLP10-01-01-15-053 GLP10-01-01-15-054 GLP10-01-01-15-055 GLP10-01-01-15-056 GLP10-01-01-15-057 GLP10-01-01-15-058 GLP10-01-01-15-059 GLP10-01-01-15-060 GLP10-01-01-15-061 GLP10-01-01-15-062 GLP10-01-01-15-063 GLP10-01-01-15-064 GLP10-01-01-15-065 GLP10-01-01-15-066 GLP10-01-01-15-067 GLP10-01-01-15-068 GLP10-01-01-15-069 GLP10-01-01-15-070 Sample Description 2 DAL SS SS24 0 0005 DAL SS SS24 0 0015 DAL SS SS29 0 0000 DAL SS SS29 0 0005 DAL SS SS29 0 0015 DAL SS SS20 0 0005 DAL SS SS13 0 0005 DAL SS SS13DB0005 DAL SS SS15 0 0005 DAL SS SS17 0 0005 DAL SS SS14 0 0005 DAL SS SS18 0 0005 DAL SS SS16 0 0005 DAL SS SS16 0 0015 DAL SS SS10 0 0005 DAL SS SS10 DB 0005 DAL SS SS10 0 0015 DAL SD SD20 0 0000 DAL SD SD20 0 0005 DAL SD SD20 0 0015 DAL SD SD23 0 0000 DAL SD SD23 0 0005 DAL SD SD23 0 0015 DAL SS SS28 0 0000 DAL SS SS28 0 0005 DAL SS SS28 DB 0005 DAL SS SS28 0 0015 DAL SS SS27 0 0000 DAL SS SS27 0 0005 DAL SS SS27 0 0015 DAL SS SS22 0 0000 DAL SS SS22 0 0005 DAL SS SS22 DB 0005 DAL SS SS22 0 0015 DAL SS SS21 0 0000 DAL SS SS21 0 0005 Soil Matrix ID Soil Weight Used (g) Spike ID Spike Volume (uL) Internal Standard ID Internal StandardV olume (uL) Surrogate Spike ID Surrogate Spike Volume (uL> Add 8 mL Extraction Solvent Sonicate 1 hr Centrifuge Comments 34 5 6 7 8 9 10 11 12 13 2 5775 ** a ia H B H ii Ili! m am 8 -mm 1 6074 1.1735 1.2309 1.8930 1.5019 1.0124 1.0693 1.2005 ' ' ib > -** .............. m . '......- B - ' r " ' . . i -j M?i B lia B a i ...."%' # . .a . mmmmmmmm r : dsa m i im am m a m - - m m ** mm a s i r a m m I S M H _ iTT~ 8* - S ili! mmmmmmmmm 1a i-- mum m HK mm mammm m i M m ass B M I aSISm - # H *K WV ' - - m ssm m i"V. i.m m is** -A' i sir 1^-- *** laarac* m am m am m tP -- i 8 mmMm .L r i s m m mmmmm M l mm Pf r f 1W MPT ... mmmmm _ wxkknb mammmm a w HM m wmammmtmmmm ,* $ wmaamm a . . ' >\ 31 Mm m 4m S I mi m 'SB* Bit n h s m z : 111* m 1 1 m " . -. '* -- . . . . f .* W0t> Mi *** *"-13 v- y -i \ ^ wmmm* 's __ :liilillllill \m m s i ** - - dOuxWn, 1 / S3* M'4* .5' mm .,. - mt -wmm - 1 . flNK * ' WMmMmr ' liippfl ,~i * mammm mmmmm K 5? A ' V Mi r a f f ! mmmmm m- ?. ^ B i & mmmmm <t*'A _ -w i ` 'tots? '* -OiV. * 14 \"VAr,' I -/' ; ' \ - - ' w, Hf Printed 2/18/2011 3M Study GLP10-01-02-15 Page 2 of 3 Page 194 of 514 GLP10-01-01-15 Screening ETS-8-053 Soils Weighed 18-Feb-2011 Sample ID 1 GLP10-01-01-15-090 GLP10-01-01-15-091 GLP10-01-01-15-092 Sample Description 2 DAL SS SS15 0 0015 DAL SS SS18 0 0015 DAL SS SS11 0 0015 Soil Matrix ID Soil Weight Used (g) 34 Spike ID 5 Spike Volume (uL) Internal Standard ID Internal StandardV olume (uL) Surrogate Spike ID Surrogate Spike Volume (uL) Add 8 mL Extraction Solvent Sonicate 1 hr Centrifuge Comments 6 7 8 9 10 11 12 13 14 * . , ,,\y ' Col 3 &4: Balance ID: 900 Note: Soils were weighed then stored in WR01 until extraction. Printed 2/18/2011 3M Study GLP10-01-02-15 Page 3 of 3 Page 195 of 514 GLP10-01-01-15 Screening ETS-8-053 Soils Weighed 22-Feb-2011 GLP10-01-01-15-028 GLP10-01-01-15-029 DAL SD SD22 0 0005 ' DAL SD SD22 DB 0005 Printed 2/22/2011 3M Study GLP10-01-02-15 2 1744 Page 1 of 3 HHHI " gg|Ptl| Page 196 of 514 GLP10-01-01-15 Screening ETS-8-053 Soils Weighed 22-Feb-2011 Printed 2/22/2011 3M Study GLP10-01-02-15 Page 2 of 3 Page 197 of 514 GLP10-01-01-15 Screening ETS-8-053 Soils Weighed 22-Feb-2011 Sample ID Sample Description 1 GLP10-01-01-15-090 GLP10-01-01-15-091 GLP10-01-01-15-092 2 DAL SS SS15 0 0015 DAL SS SS18 0 0015 DAL SS SS11 0 0015 Col 3 & 4: 6 f i t 2 ' Z Z ' M Balance ID: 900 Soil Matrix ID Soil Weight Used (g) 34 1.5684 1.0109 1.3534 Spike ID 5 Spike Volume <uL) Internal Standard ID Internal StandardV olume (uL) Surrogate Spike ID Surrogate Spike Volume (uL) Add 8 mL Extraction Solvent Sonicate 1 hr Centrifuge 6 7 8 9 10 11 12 13 Note: Soils were weighed then stored in WR01 until extraction. Comments 14 Printed 2/22/2011 3M Study GLP10-01-02-15 Page 3 of 3 Page 198 of 514 GLP10-01-01-15 Screening ETS-8-053 Soils Extracted 23-Feb-2011 Sample ID 1 EC-110217-01 EC-110217-02 EC-110217-03 EC-110217-04 EC-110217-05 EC-110217-06 EC-110217-07 EC-110217-08 EC-110217-09 EC-110217-10 EC-110217-11 MB-110217-01 MB-110217-02 MB-110217-03 MB--110217-04 MB-110217-05 MB--110217-06 LCS-110217-01 LCS-110217-02 LCS-110217-03 LCS-110217-04 LCS-110217-05 LCS-110217-06 GLP10-01-01-15-001 GLP10-01-01-15-002 GLP10-01-01-15-003 GLP10-01-01-15-004 GLP10-01-01-15-005 GLP10-01-01-15-006 GLP10-01-01-15-007 GLP10-01-01-15-008 GLP10-01-01-15-009 GLP10-01-01-15-010 GLP10-01-01-15-011 GLP10-01-01-15-012 GLP10-01-01-15-014 GLP10-01-01-15-015 GLP10-01-01-15-016 GLP10-01-01-15-018 GLP10-01-01-15-020 GLP10-01-01-15-021 GLP10-01-01-15-022 GLP10-01-01-15-023 GLP10-01-01-15-024 GLP10-01-01-15-025 GLP10-01-01-15-026 GLP10-01-01-15-027 GLP10-01-01-15-028 GLP10-01-01-15-029 GLP10-01-01-15-030 GLP10-01-01-15-031 GLP10-01-01-15-032 GLP10-01-01-15-033 GLP10-01-01-15-034 Sample Description Soil Matrix ID Soil Weight Used(g) Spike ID Spike Volume (uL) Internal Standard ID Internal StandardV olume (uL) Surrogate Spike ID Surrogate Spike Volume (uL) Add 8 mL Extraction Solvent Sonicate 1 hr Centrifuge Comments 2 0.2 ng Extracted Curve Point 0.5 ng Extracted Curve Point 0.75 ng Extracted Curve Point 1ng Extracted Curve Point 2.5 ng Extracted Curve Point 5 ng Extracted Curve Point 10 ng Extracted Curve Point 25 ng Extracted Curve Point 50 ng Extracted Curve Point 100 ng Extracted Curve Point 200 ng Extracted Curve Point Method Blank 1w/o IS Method Blank 2 w/o IS Method Blank 3 w/o IS Method Blank 4 w/ IS Method Blank 5 w/ IS Method Blank 6 w/ IS 3 ng LCS in TCR-842 3 ng LCS in TCR-842 3 ng LCS in TCR-842 30 ng LCS in TCR-842 30 ng LCS in TCR-842 30 ng LCS in TCR-842 DAL SS SS Tripl 0 0000 DAL SS SS12 0 0000 DAL SS SS12 0 0005 DAL SS SS13 0 0000 DAL SS SS16 0 0000 DAL SS SS16DB 0000 DAL SS SS11 0 0000 DAL SS SS11 0 0005 DAL SS SS20 0 0000 DAL SS SS20 DB 0000 DAL SS SS19 0 0000 DAL SS SS19 0 0005 DAL SS SS15 0 0000 DAL SS SS17 0 0000 DAL SS SS14 0 0000 DAL SS SS18 0 0000 DAL SS SS10 0 0000 DAL SS SS30 0 0000 DAL SS SS30 0 0005 DAL SS SS30 0 0015 DAL SS SS25 0 0000 DAL SS SS25 0 0005 DAL SS SS25 0 0015 DAL SD SD22 0 0000 DAL SD SD22 0 0005 DAL SD SD22 DB 0005 DAL SD SD22 0 0015 DAL SD SD21 0 0000 DAL SD SD21 0 0005 DAL SDSD21 0 0015 ' DAL SS SS24 0 0000 34 5 6 7 8 9 10 10 010-125 1 1286 10 007-38-3 20 10 010-177 30 10 010-180 20 10010 125 1 1391 10 007-38-3 50 10 010-177 30 10 010-180 50 10010-125 1 1354 10 007-38-3 75 10 010-177 30 10 010-180 75 10 010-125 1 1977 10 007-38-3 100 10 010-177 30 10 010-180 100 10 010-125 ` 1*1092 10 007-38-2 25 10010-177 30 10 010-179 25 10 010-125% 1.1267 10 007-38-2 50 10 010-177 30 10 010-179 50 10 010-125 1 1498 10 007-38-2 100 10 010-177 30 10 010-179 100 10 010-125 1 1134 10 007-38-1 25 10 010-177 30 10 010-178 25 10 010-125 1 4 )5 8 4 10 007-38-1 50 10 010-177 30 10 010-178 50 10010-125 1 1690 10 007-38-1 100 10 010-177 30 10 010-178 100 10 010-125 1 1427 10 OCJ7-38-1 DO 10 010-177 30 10 010-178 200 10 010-125 1 1397 - 10010-125 4 1654 i l i s i l i * ' mm WiM ` * WMKSBISm ' 10010-125 - 11677. .1110010-125 1 1579' 1 ` 0010125 1 1382 - i l l * . -- --- 1 10 010-177 10 010-177 30 10 010-179 30 10 010-179 30 30 10 010-1253 * 1 1100 * . 10 010-177 30 10 010-179 30 ' 10010-1251 <** 1 1236 * 10 010-183 30 10 010-177 30 10 010-179 30 10,010,125 * 1-1056 . 10 010-183 30 10 010-177 30 10 010-179 30 M 0 `010?125l 1 1 1207 10*010425* - i i 10 010-183 10 010-182 30 10 010-177 30 10 010-179 30 10 010-177 30 10 010-179 30 30 10010125 ' 10909 ; 10 010-182 30 10 010-177 30 10 010-179 30 10 010-125 * 1 1055 ` 10 010-182 10 010-177 30 10010-179 30 ' '<>*- H 1 1715 2 0581 isms " 10 010-177 10 010-177 30 10 010-179 30 10 010-179 30 30 . V BA1*37<17AV s$ i 10 010-177 30 10 010-179 30 *^t<6298 * mm 10 010-177 30 10 010-179 30 14802 10010-177 30 10 010-179 30 1 4757 10 010-177 30 10 010-179 30 1.4894 10 010-177 30 10 010-179 30 16614 10 010-177 30 10 010-179 30 16042 10 010-177 30 10 010-179 30 1718B m 10 010-177 30 10 010-179 30 1 5564 m 10 010-177 30 10 010-179 30 1 2359 i ^ ..4.. 10 010-177 30 10 010-179 30 10562 M8i l 10 010-177 30 10 010-179 30 1 0437 10 010-177 30 10 010-179 30 13716 10 010-177 13967 mmmsmmmmmm . .. . 10 010-177 30 10 010-179 30 10 010-179 30 30 15262 B H iW H iH i mm 10 010-177 30 10 010-179 30 10 010-177 30 10 010-179 30 1 1057 ? t i 1 1526 i f ----- - MM - 10 010-177 10 010-177 30 10 010-179 30 10 010-179 30 30 * 18507 - 12___ M 10 010-177 30 10 010-179 30 ' M it* . 4 10022 C 10 010-177 30 10 010-179 30 i r . S 15775 , i 1 H 10 010-177 30 10 010-179 30 18529 ! M i l S I i 10 010-177 30 10 010-179 30 I f21744 : - - 18924-*. ' ;. mmm 10 010-177 m m S 10 010-177 30 10 010-179 30 10 010-179 30 30 1 6166 10 010-177 30 10010-179 30 13699 n 12928 I f i mm sm mmm 10 010-177 m r 10 010-177 30 10010-179 30 10010-179 30 30 15725 m 10 010-177 30 10 010-179 30 1441b I 10 010-177 30 10 010-179 30 11 GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM 12 GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM 13 GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM 14 ( j i 1 I 1 1 j 1 1 j 1 1 j j 1 j 1 I j Vi ir---------- -- t ft g-------------- ____ i 7 ----------------------- 77 7 ............. Printed 2/23/2011 3M Study GLP10-01-02-15 Page 1 of 3 Page 199 of 514 GLP10-01-01-15 Screening ETS-8-053 Soils Extracted 23-Feb-2011 Sample ID 1 GLP10-01-01-15-035 GLP10-01-01-15-036 GLP10-01-01-15-037 GLP10-01-01-15-038 GLP10-01-01-15-039 GLP10-01-01-15-040 GLP10-01-01-15-041 GLP10-01-01-15-042 GLP10-01-01-15-043 GLP10-01-01-15-044 GLP10-01-01-15-045 GLP10-01-01-15-046 GLP10-01-01-15-047 GLP10-01-01-15-048 GLP10-01-01-15-049 GLP10-01-01-15-050 GLP10-01-1-15-051 GLP10-01-01-15-052 GLP10-01-1-15-053 GLP10-01-01-15-054 GLP10-01-01-15-055 GLP10-01-01-15-056 GLP10-01-01-15-057 GLP10-01-01-15-058 GLP10-01-01-15-059 GLP10-01-01-15-060 GLP10-01-01-15-061 GLP10-01-01-15-062 GLP10-01-01-15-063 GLP10-01-01-15-064 GLP10-01-01-15-065 GLP10-01-01-15-066 GLP10-01-01-15-067 GLP10-01-01-15-068 GLP10-01-01-15-069 GLP10-01-01-15-070 GLP10-01-01-15-071 GLP10-01-01-15-072 GLP10-01-01-15-073 GLP10-01-01-15-074 GLP10-01-01-15-075 GLP10-01-01-15-076 GLP10-01-01-15-077 GLP10-01-01-15-079 GLP10-01-01-15-080 GLP10-01-01-15-081 GLP10-01-01-15-082 GLP10-01-01-15-083 GLP10-01-01-15-084 GLP10-01-01-15-085 GLP10-01-01-15-086 GLP10-01-01-15-087 GLP10-01-01-15-088 GLP10-01-01-15-089 Sample Description 2 DAL SS SS24 0 0005 DAL SS SS24 0 0015 DAL SS SS29 0 0000 DAL SS SS29 0 0005 DAL SS SS29 0 0015 DAL SS SS20 0 0005 DAL SS SS13 0 0005 DAL SS SS13DB 0005 DAL SS SS15 0 0005 DAL SS SS17 0 0005 DAL SS SS14 0 0005 DAL SS SS18 0 0005 DAL SS SS16 0 0005 DAL SS SS16 0 0015 DAL SS SS10 0 0005 DAL SS SS10DB0005 DAL SS SS10 0 0015 DAL SD SD20 0 0000 DAL SD SD20 0 0005 DAL SD SD20 0 0015 DAL SD SD23 0 0000 DAL SD SD23 0 0005 DAL SD SD23 0 0015 DAL SS SS28 0 0000 DAL SS SS28 0 0005 DAL SS SS28 DB 0005 DAL SS SS28 0 0015 DAL SS SS27 0 0000 DAL SS SS27 0 0005 DAL SS SS27 0 0015 DAL SS SS22 0 0000 DAL SS SS22 0 0005 DAL SS SS22 DB 0005 DAL SS SS22 0 0015 DAL SS SS21 0 0000 DAL SS SS21 0 0005 DAL SS SS21 0 0015 DAL SD SD18 0 0000 DAL SD SD18 0 0005 DAL SD SD18 0 0015 DAL SD SD19 0 0000 DAL SD SD19 0 0005 DAL SD SD19 0 0015 DAL SS SS26 0 0000 DAL SS SS26 DB 0000 DAL SS SS26 0 0005 DAL SS SS26 0 0015 DAL SS Trip2 0 0000 DAL SS SS12 0 0015 DAL SS SS19 0 0015 DAL SS SS20 0 0015 DAL SS SS14 0 0015 DAL SS SS17 0 0015 DAL SS SS13 0 0015 Soil Matrix ID Soil Weight Used (g) Spike ID 3 ': 4 2 5775 1.6674 1J735 1 2309 18930 1.5019 1.0124 .0693 2005 10737 13957 14004 1.5790 1.2283 1 6850 18035 2.5533 1.3417 13415 .1.5042 ' 2 0879 1.5188 16013 12731 1 3505 1.4764 1.4436 1.5243 . 1.1742 1.3343 1.2031 1.5173 .5768 , .7782 1 5610 1 2841 1.3556 1.7468 . 1.6258 13452 1.9813 1.2778 1 1926 16713 18099 1.1327 1 5346 1220 3g; 9 14165 1.2807 . 1.4643 1.1299 1 1312 5 Spike Volume (uL) Internal Standard ID Internal StandardV olume (uL) Surrogate Spike ID Surrogate Spike Volume (uL) Add 8 mL Extraction Solvent Sonicate 1 hr Centrifuge Comments 6 7 8 9 10 10 010-177 30 10 010-179 30 10 010-177 30 10010-179 30 10 010-177 30 10 010-179 30 10 010-177 30 10 010-179 30 10 010-177 30 10010-179 30 10010-177 30 10010-179 30 10 010-177 30 10 010-179 30 10 010-177 30 10010-179 30 10 010-177 30 10 010-179 30 10 010-177 30 10 010-179 30 10 010-177 30 10 010-179 30 10 010-177 30 10 010-179 30 10 010-177 30 10 010-179 30 10010-177 30 10 010-179 30 10010-177 30 10 010-179 30 10 010-177 30 10 010-179 30 10010-177 30 10 010-179 30 10010-177 30 10 010-179 30 10010-177 30 10 010-179 30 10010-177 30 10 010-179 30 10010-177 30 10 010-179 30 10010-177 30 10 010-179 30 10 010-177 30 10 010-179 30 10 010-177 30 10 010-179 30 10 010-177 30 10 010-179 30 10 010-177 30 10 010-179 30 10 010-177 30 10 010-179 30 10 010-177 30 10 010-179 30 10 010-177 30 10 010-179 30 10 010-177 30 10 010-179 30 10 010-177 30 10 010-179 30 10 010-177 30 10 010-179 30 10 010-177 30 10 010-179 30 10 010-177 30 10 010-179 30 10 010-177 30 10 010-179 30 10 010-177 30 10 010-179 30 10 010-177 30 10 010-179 30 10 010-177 30 10 010-179 30 10 010-177 30 10 010-179 30 10010-177 30 10 010-179 30 10 010-177 30 10 010-179 30 10 010-177 30 10 010-179 30 10 010-177 30 10 010-179 30 10 010-177 30 10 010-179 30 10 010-177 30 10 010-179 30 10 010-177 30 10 010-179 30 10 010-177 30 10 010-179 30 10 010-177 30 10 010-179 30 10 010-177 30 10 010-179 30 10010-177 30 10 010-179 30 10 010-177 30 10 010-179 30 10010-177 30 10 010-179 30 10010-177 30 10 010-179 30 10010-177 30 10 010-179 30 11 GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM 12 GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM 13 GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM 14 < I / j j / I j j 1 I I\ 1 11 v>/n / 1 1 j j 1 1 7---------------------------- Printed 2/23/2011 3M Study GLP10-01-02-15 Page 2 of 3 Page 200 of 514 GLP10-01-01-15 Screening ETS-8-053 Soils Extracted 23-Feb-2011 Sample ID 1 GLP10-01-01-15-090 GLP10-01-01-15-091 GLP10-01-01-15-092 Col 5 & 6: Pipette ID: 4215537 Sample Description 2 DAL SS SS15 0 0015 DAL SS SS18 0 0015 DAL SS SS11 0 0015 Soil Matrix ID Soil Weight Used (g) 34 1.5684 1.0109 \1.3534 Spike ID 5 Spike Volume (uL) Internal Standard ID Internal StandardV olume (uL) Surrogate Spike ID Surrogate Spike Volume (uL) Add 8 mL Extraction Solvent Sonicate 1 hr Centrifuge 6 7 8 9 10 10 010-177 30 10 010-179 30 10 010-177 30 10 010-179 30 10 010-177 30 10 010-179 30 11 GPM GPM GPM 12 GPM GPM GPM 13 GPM GPM GPM Comments 14 Gtr'-z-' ' Col 7 & 8: G''"'* 'Z Z 'i - h Pipette ID: 4215537 Col9 & 10: Cr'r-r 1 ' 2 3 - H Pipette ID: 4215537 Col 11: Z-ZZS-K Extraction Solvent !D: 10 006-71 COM2: `Z -^ '3 ' n SonicatorlD: QEJ100595003 Col 13: f r * t - t t - >\ Centrifuge ID: 1521430 10 min @3000 RPM COH4: ^ Printed 2/23/2011 3M Study GLP10-01-02-15 Page 3 of 3 Page 201 of 514 INTERNAL CHAIN-OF-CUSTODY environmental laboratory Sample Internal Transfer Sample set ID # Lims# N/A GLP10-01-01-15 Sample Description: Decatur Soils INTERNALCHAINOFCUSTODY # 3M Sample IDs 1 GLP10-01-01-15-001 2 GLP10-01-01-15-002 3 GLP10-01-01-15-003 4 GLP10-01-01-15-004 5 GLP10-01-01-15-005 6 GLP10-01-01-15-006 7 GLP10-01-01-15-007 8 GLP10-01-01-15-008 9 GLP10-01-01-15-009 10 GLP10-01-01-15-010 11 GLP10-01-01-15-011 12 GLP10-01-01-15-012 13 GLP10-01-01-15-014 14 GLP10-01-01-15-015 15 GLP10-01-01-15-016 16 GLP10-01-01-15-018 17 GLP10-01-01-15-020 18 GLP10-01-01-15-021 19 GLP10-01-01-15-022 20 GLP10-01-01-15-023 21 GLP10-01-01-15-024 22 GLP10-01-01-15-025 23 GLP10-01-01-15-026 24 GLP10-01-01-15-027 25 GLP10-01-01-15-028 26 GLP10-01-01-15-029 27 GLP10-01-01-15-030 28 GLP10-01-01-15-031 29 GLP10-01-01-15-032 30 GLP10-01-01-15-033 31 GLP10-01-01-15-034 32 GLP10-01-01-15-035 33 GLP10-01-01-15-036 34 GLP10-01-01-15-037 35 GLP10-01-01-15-038 36 GLP10-01-01-15-039 37 GLP10-01-01-15-040 38 GLP10-01-01-15-041 39 GLP10-01-01-15-042 40 GLP10-01-01-15-043 41 GLP10-01-01-15-044 42 GLP10-01-01-15-045 43 GLP10-01-01-15-046 44 GLP10-01-01-15-047 Out: storage ID UK?\ ____ I________ I 1 InltJdate In: storage ID V-H- U LiS -oi )\ A.V ____J ;/ InltJdate Comments/InltJdate I / ________________L _ / / / / / I 1 N^ / A. 1 f ^ -y------- ( 3M Study GLP10-01-02-15 Page 1 of 2 Page 202 of 514 INTERNAL CHAIN-OF-CUSTODY environmental laboratory Sample Internal Transfer Sample set ID # Lims# N/A GLP10-01-01-15 Sample Description: Decatur Soils INTERNALCHAINOFCUSTODY # 3M Sample IDs 45 GLP10-01-01-15-048 46 GLP10-01-01-15-049 47 GLP10-01-01-15-050 48 GLP10-01-01-15-051 49 GLP10-01-01-15-052 50 GLP10-01-01-15-053 51 GLP10-01-01-15-054 52 GLP10-01-01-15-055 53 GLP10-01-01-15-056 54 GLP10-01-01-15-057 55 GLP10-01-01-15-058 56 GLP10-01-01-15-059 57 GLP10-01-01-15-060 58 GLP10-01-01-15-061 59 GLP10-01-01-15-062 60 GLP10-01-01-15-063 61 GLP10-01-01-15-064 62 GLP10-01-01-15-065 63 GLP10-01-01-15-066 64 GLP10-01-01-15-067 65 GLP10-01-01-15-068 66 GLP10-01-01-15-069 67 GLP10-01-01-15-070 68 GLP10-01-01-15-071 69 GLP10-01-01-15-072 70 GLP10-01-01-15-073 71 GLP10-01-01-15-074 72 GLP10-01-01-15-075 73 GLP10-01-01-15-076 74 GLP10-01-01-15-077 75 GLP10-01-01-15-079 76 GLP10-01-01-15-080 77 GLP10-01-01-15-081 78 GLP10-01-01-15-082 79 GLP10-01-01-15-083 80 GLP10-01-01-15-084 81 GLP10-01-01-15-085 82 GLP10-01-01-15-086 83 GLP10-01-01-15-087 84 GLP10-01-01-15-088 85 GLP10-01-01-15-089 86 GLP10-01-01-15-090 87 GLP10-01-01-15-091 88 GLP10-01-01-15-092 Out: storage ID Li.oV \ \ Init/date In: storage ID InitJdate z-<r-n Gerr L-fg'M ------ r i II [ \ \ I I i I \ _____ V L___ ____ X . / ____ vV \y Comments/lnit/date / / / / /I V, h!j VJ IhnI? I . 3M Study GLP10-01-02-15 Page 2 of 2 Page 203 of 514 INTERNAL CHAIN-OF-CUSTODY environmental laboratory Sample Internal Transfer Sample set ID # Urns# N/A GLP10-01-01-15 Sample Description: Decatur Soils INTERNALCHAINOFCUSTODY # 3M Sample IDs Out: storage ID InitJdate 1 GLP10-01-01-15-001 2 GLP10-01-01-15-002 3 GLP10-01-01-15-003 4 GLP10-01-01-15-004 \\\ <SfH T.-2A- il 5 GLP10-01-01-15-005 6 GLP10-01-01-15-006 7 GLP10-01-01-15-007 8 GLP10-01-01-15-008 9 GLP10-01-01-15-009 10 GLP10-01-01-15-010 i I 11 GLP10-01-01-15-011 12 GLP10-01-01-15-012 13 GLP10-01-01-15-014 14 GLP10-01-01-15-015 15 GLP10-01-01-15-016 ____ ___ 16 GLP10-01-01-15-018 17 GLP10-01-01-15-020 18 GLP10-01-01-15-021 19 GLP10-01-01-15-022 20 GLP10-01-01-15-023 21 GLP10-01-01-15-024 22 GLP10-01-01-15-025 23 GLP10-01-01-15-026 24 GLP10-01-01-15-027 25 GLP10-01-01-15-028 26 GLP10-01-01-15-029 27 GLP10-01-01-15-030 28 GLP10-01-01-15-031 29 GLP10-01-01-15-032 30 GLP10-01-01-15-033 31 GLP10-01-01-15-034 32 GLP10-01-01-15-035 33 GLP10-01-01-15-036 34 GLP10-01-01-15-037 35 GLP10-01-01-15-038 36 GLP10-01-01-15-039 37 GLP10-01-01-15-040 38 GLP10-01-01-15-041 39 GLP10-01-01-15-042 40 GLP10-01-01-15-043 41 GLP10-01-01-15-044 42 GLP10-01-01-15-045 43 GLP10-01-01-15-046 44 GLP10-01-01-15-047 ---- S' In: storage ID L-rQ-oy , sy InitJdate :___ ///Comments/lnit/date Ii I 1 iI1 H/ *1/v 0///Ki 1 1 1 I) 3M Study GLP10-01-02-15 Page 1 of 2 Page 204 of 514 INTERNAL CHAIN-OF-CUSTODY e n v ir o n m e n t a l l a b o r a t o r y Sample Internal Transfer Sample set ID # Urns# N/A GLP10-01-01-15 Sample Description: Decatur Soils INTERNAL CHAIN OF CUSTODY # 3M Sample IDs Out: storage ID 45 GLP10-01-01-15-048 UfLV 46 GLP10-01-01-15-049 47 GLP10-01-01-15-050 48 GLP10-01-01-15-051 49 GLP10-01-01-15-052 50 GLP10-01-01-15-053 51 GLP10-01-01-15-054 52 GLP10-01-01-15-055 53 GLP10-01-01-15-056 54 GLP10-01-01-15-057 55 GLP10-01-01-15-058 56 GLP10-01-01-15-059 57 GLP10-01-01-15-060 \ \ \ \ 58 GLP10-01-01-15-061 _______ \____ 59 GLP10-01-01-15-062 60 GLP10-01-01-15-063 61 GLP10-01-01-15-064 62 GLP10-01-01-15-065 63 GLP10-01-01-15-066 64 GLP10-01-01-15-067 65 GLP10-01-01-15-068 66 GLP10-01-01-15-069 67 GLP10-01-01-15-070 68 GLP10-01-01-15-071 69 GLP10-01-01-15-072 70 GLP10-01-01-15-073 71 GLP10-01-01-15-074 72 GLP10-01-01-15-075 73 GLP10-01-01-15-076 74 GLP10-01-01-15-077 75 GLP10-01-01-15-079 76 GLP10-01-01-15-080 77 GLP10-01-01-15-081 78 GLP10-01-01-15-082 79 GLP10-01-01-15-083 80 GLP10-01-01-15-084 81 GLP10-01-01-15-085 82 GLP10-01-01-15-086 83 GLP10-01-01-15-087 84 GLP10-01-01-15-088 85 GLP10-01-01-15-089 86 GLP10-01-01-15-090 87 GLP10-01-01-15-091 88 GLP10-01-01-15-092 InltJdate Ctr* In: storage ID L-(Lo\ InltJdate Z.-'VL- if I _____ ______ Comments/lnit/date / / 1 I ____i________ r 1 **'s y 1n 1 1 1 I ;v ( 3M Study GLP10-01-02-15 Page 2 of 2 Page 205 of 514 Date: 4/5/2011 Data Analyst: mmh__________ Study #: GLP10-01-02-15 Description: Decatur Soils Batch: si 10317a Results Table: s!10317a.rdb Instrument: Stan V I660305 Method(s): ETS-8-053.0 DATA REVIEW SUM M ARY FORM Data Review Sign-Off Analyst Review and Accofittaannccee'dof'Manual Integrations Name / Date: ___ ^ j Technical and Manual Integration Review Name / Date: V 7^ ^-vo-// Comments / Justifications: Analyte: PFBS Comments/Justifications: Acceptable Linear Range: Internal Standard: LOQ: 0.200 ng NA 0.200 ng to 500 ng MPFBS Analyte: PFHS______________________ Comments/Justifications: NA_____________ Acceptable Linear Range: 0.199 ng to 499 ng Internal Standard: MPFHxS_________ LOQ: 0.199 ng____________________ Analyte: PFOS Comments/Justifications: Acceptable Linear Range: Internal Standard: LOQ: 0.200 ng /J ^ 0.200 ng to 500 ng M8PFOS Analyte: MPFOS Comments/Justifications: Acceptable Linear Range: Internal Standard: LOQ: 0.191 ng NA 0.191 ng to 478 ng M8PFOS Analyte: N/A Comments/Justifications: N/A Acceptable Linear Range: N/A Internal Standard: N/A LOQ: N/A____________ 3M Study GLP10-01-02-15 Page 1 of 1 Page 206 of 514 Stan: API4000: V1660305 DATE 3/17/11 ANALYST:mmh STUDY NUMBER:GLP 10-01-01-15 Matrix: Soils Injection volume: U^uL Electrode: Turbo ion spray Mobile Phase: (A.12 mM ammonium acetate (B ) acetonitrile TN-A- or standard number (A) 11 002-10_______ (B) tnl 1-0033-1/8 page 1/1 Guard (pre-autosampler) column Prism RP Size: 2.1 mm X 50 mm__________ Type: C12 Sphere size: 5______ Part number: 32105-052130 Lot number: 9660 Serial number 0110498T Analytical column 1 Oasis HLB Size: 3 X 20 mm________ Type: NA Sphere size: 25 um Part number: 186002039 serial number: 006A300055105 03 Analytical column 2 Betasil C l8 Size: 2.1 mm X 100 mm_________ Type: C l8 Sphere size: 5______ Part number: 70105-102130 Lot number: 10559 Serial number 0701663T Printed: Thursday, March 17, 2011 5:08 PM 3M Study GLP10-01-02-15 Pag ETS S ta n V1660305 Acquisition Information: AAACCLSyaracucetsnqqmtatocuuteh-eMiinEssrdtoiio:q:ttndiiuooiiizfnnliaiebtMdDiro:auenttrhiaoMotdinoo::dne:: ANPuecmrqibouedirssiOtiIfonnSFcMainloesd::ule: ASPuognfitplweMnartoedLevCl:ePrsuimopnMethod Properties MMMMDeaiaanxaxxiidmiimrmauuVmmmmolPFPPulrrrtoeeeewsss sss(Ruuuprrraieeen)p: R((app(rmrsspiil/))m::( pins2i)/:s e c ) : WMTOELCThfeeSfutdShrn8yoseddn-s5acd3yfaoyM2rM3aSramcurhclinfho1S71n6uat2lef0os1n1a17t1e3sm2: i.nd4ua9mt:e 5g6raEdMien2t011 16: 47: 18 EM 21139n5in0sec AA1 nc qa luyisstiti1o.n4 .2Method Agilent 1100 LC Binary Punp 05480.00.01.0 219000..00 23SSC1tteepp 4c 76 Ta22T033111b0379...7o050l.....t00e550000a:00000l Time (min) 4444444F400000000lo00000000w Rate(pl/min) A7411999900007777........(00000000%) 33B333699..0000..0000....(0000%) RRLRLRLLiieeieeiggggffffhhhtthtt ttttSCSDSCSDoteorotaelaomrdvalorkvdeppkVeenrreVoneteVl:ostuVslo:smusloimuiblebmueimile(iletip(ytp(iy:p()i:p:)i):i:)AB4415:210010.5..000.0 --11..00 TAAENSDI neyrjeugaemjretwieicodlnpcetlsgeSetnairSepntoaLpeptnASeeueldeeirvuVzedreteool(CMlp(supoa(i(mor/pnlnrdm/empteimr)li)lo::ne:(ilnpr) :)iP:) :r o WSeatsphoiisntno(4t u- se4d0 C): pAE222011e00500.ng00r.00ai00tb..li000eelensdt 1100 Thermo Autosanpler Use Custan Injecto r Program No ATSTCUTLRP05..iosoaotei00gmegarfCCtlsieuaphtrlisettlmteaTiTnromATTaatLRanSiebettcmeiuCpwmlgqfpeferoehtiuopeol(rttueimcrasmsTrhtiiiaufntniottini)irulooregOernnservaVte(nTfna(osCcloavePCr)lmee:r)a+ro:pal/plVnI3(e-lenN0carses.ilo(t0vnatti0eame+CUlst/p)lhPs-:eleeeoddss)(bitiaCintoc)n:hth: e 30.00 01..5000 hatRcihght Period 1: SREcxeaplnaestriivmineenSPtsetariirontdT:Piemrieo:d: 0111.0905 msec Period 1 Experiment 1: SSRRSMIPIonccReoeenaatsstlennPtaoolSnarlliMTouuuisntysuittoygiitepdrooy::ceennT:e: T:imQQh3elr:::es.: MNNTUU005F...u/nne000AMrgii000btta07o(tM00civSpRmmMesp)rssaeeycc Printing Date: Thursday, March 1 1 , 2011 Printing Time: 4:53:32 PM 3M Study GLP10-01-02-15 Page 1 of 3 Page 208 o ETS S tan V1660305 MSCteAp: SizNe:o 0.00 aim Q3199M.0aCss (amu) Q993.0to0ss (arm) D10w0e.0ll0(msec) CPDEEaram CXE S---155t00.a0.0r00t.000-S--155t0e0.0p0.00.000 Q3199M.0aCss (amu) Q803.0to0ss (amu) D10w0e.0ll0(msec) CCPDXEEarEam S tart Stop ---515.600.000.000---15506.00.00.000 Q4102M.0aCss (arm) Q803.0to0ss (arm) D10w0e.0ll0(msec) OECPDXEarFam S---515t00.a0.0r00t.000-S--155to00.0p0.00.000 Q2199t.o0Css (arm) Q993.0to0ss (arm) D10w0e.0ll0(msec) OECPDXEaEram S---575t50.a0..r000t00 S---755to50.0p..00000 Q2199t.o0Css (arm) Q803.0to0ss (amu) D10w0e.0ll0(msec) CCDPXEEaEram S---755t50.a0..r000t00 -S--575te50.0p..00000 Q3013t.o0Css (amu) Q843.0to0ss (amu) D10w0e.0ll0(msec) PDEaram OECXE S---755t50.a0..r000t00 S---575te50.0p..00000 Q4199t.o0Css (arm) Q803.0to0ss (arm) E10to0e.0ll0(msec) CCDPXEEarEam S---155t06.a00.r00t.000 S---155te06.0p0.00.000 Q4199t.o0Css (amu) Q993.0to0ss (amu) D10w0e.0ll0(msec) OECDPXPaEram S---155t06.a0.0r00t.000-S--155t0e6.0p0.00.000 Q4199t.o0Css (amu) Q1330t.o0Css (arm) D10w0e.0ll0(msec) CCPDXEEarEam S---157t06.a0.0r00t.000-S--175t0o6.0p0.00.000 Q5103t.o0Css (arm) Q803.0to0ss (aim) D10w0e.0ll0(msec) CCDPXEPaEram S---155t06.a00.r00t.000-S--155t0o6.0p0.00.000 Q5107t.o0Css (arm) Q803.0to0ss (arm) D10w0e.0ll0(msec) CCPDEXEarEam Start Step ---15560.0.000.000---15506.00.00.000 CCGGTPiEIhSEEAUSSaMe:DR12r:a:::::meter Table C(--634644P1M5505.050e0...00000r..0i00000o00.d001 Experiment 1): Printing Date: Thursday, March 17, 2011 Printing Time: 4:53:32 PM 3M Study GLP10-01-02-15 Page 2 of 3 Page 209 of 514 ETS S tan V1660305 Printing Date: Thursday, March 17, 2011 Printing Time: 4:53:32 PM 3M Study GLP10-01-02-15 Page 3 of 3 Page 210 of 514 ETS Scan V166Q305 P roject: \\W in sn a s0 1 a \b 2 \P ro je cts\L a b Jn stru m e n t D a ta \S ta n \S ta n Data F ile s\P roje cts\fluorochem icals\so il B a tch:s1103 17a T a b :S a m p le S e t:S E T 01 A c q M e th o d :e ts 8 -5 3 23 m in S u lfonates2 S am ple rr 1 s110317a001 10 0 0 6 -8 0 s o lv e n t blank 2 s110 3 1 7 a 0 0 2 10 0 0 6 -8 0 s o lv e n t blank 3 s110317a003 EC -110316-09 50 ng W arm up standard 4 s110317a004 EC -110316-09 50 ng W arm up standard 5 s1 1 0 3 1 7 a 0 0 5 10 0 0 6 -8 0 s o lv e n t blank 6 s110 3 1 7 a 0 0 6 10 0 0 6 -8 0 s o lv e n t blank 7 s1 1 0 3 1 7 a 0 0 7 10 0 0 6 -8 0 s o lv e n t blank 8 s1 1 0 3 1 7 a 0 0 8 10 0 0 6 -8 0 s o lv e n t blank 9 s1 1 0 3 1 7 a 0 0 9 10 0 0 6 -8 0 s o lv e n t blank 10 s 1 1 0 3 1 7 a 0 1 0 E C -1 10316-01 0.2 ng E xtra c te d C u rv e Point 11 s 1 1 0 3 1 7 a 0 1 1 E C -1 1 0 3 1 6 -0 2 0 .5 n g E x tra c te d C u rv e P o int 12 s 11 0 3 1 7 a 0 1 2 E C -11 0 3 1 6 -0 3 0 .7 5 ng E xtra c te d C u rv e Point 13 s1 1 G 3 1 7 a 0 1 3 E C -1 1 0 3 1 6 -0 4 1 ng E x tra c te d C u rv e Point 14 s1 1 0 3 1 7 a 0 1 4 E C -1 1 0 3 1 6 -0 5 2 .5 ng E x tra c te d C u rv e Point 15 s 1 1 0 3 1 7 a 0 1 5 E C -1 1 0 3 1 6 -0 6 5 ng E xtra c te d C u rv e Point 16 s1 1 0 3 1 7 a 0 1 6 E C -11 0 3 1 6 -0 7 10 ng E xtra c te d C u rv e Point 17 s 1 1 0 3 1 7 a 0 1 7 E C -1 1 0 3 1 6 -0 8 2 5 ng E x tra c te d C u rv e Point 18 s 1 1 0 3 1 7 a 0 1 8 E C -1 1 0 3 1 6 -0 9 5 0 ng E x tra c te d C u rv e Point 19 s 1 1 0 3 1 7 a 0 1 9 E C -1 1 0 3 1 6 -1 0 100 ng E x tra c te d C u rv e Point 20 s 1 1 0 3 1 7 a 0 2 0 E C -1 10316-11 2 0 0 ng E x tra c te d C u rv e Point 21 s 1 1 0 3 1 7 a 0 2 1 E C -1 1 0 3 1 6 -1 2 5 0 0 ng E x tra c te d C u rv e Point 22 s110 3 1 7 a 0 2 2 10 0 0 6 -8 0 s o lv e n t blank 23 s110 3 1 7 a 0 2 3 10 0 0 6 -8 0 s o lv e n t blank 24 s110 3 1 7 a 0 2 4 10 0 0 6 -8 0 s o lv e n t blank '' " 25 s 1 1 0 3 1 7 a 0 2 5 10 0 0 6 -8 0 s o lv e n t blank 2 6 s 1 1 0 3 1 7 a 0 2 6 M B -1 1 0 3 1 6 -0 1 M e th o d B la n k w / o IS 2 7 s 1 1 0 3 1 7 a 0 2 7 M B - 1 1 0 3 1 6 -0 2 M e th o d B l a n k w / o IS 2 8 s 1 1 0 3 1 7 a 0 2 8 M B -1 1 0 3 1 6 -0 3 M e th o d B l a n k w / o IS 2 9 s 1 1 0 3 1 7 a 0 2 9 M B - 1 1 0 3 1 6 -0 4 M e th o d B la n k w / IS 30 s 1 1 0 3 1 7 a 0 3 0 M B -1 1 0 3 1 6 -0 5 M e th o d B la n k w / IS 31 s 1 1 0 3 1 7 a 0 3 1 M B -1 1 0 3 1 6 -0 6 M e th o d B la n k w / IS 32 s 1 1 0 3 1 7 a 0 3 2 M B -1 1 0 3 1 6 -0 7 M e th o d B la n k w / IS f o r d ilu tio n s 33 s 1 1 0 3 1 7 a 0 3 3 'M B - 1 1 0 3 1 6 -0 8 M e th o d B la n k w / IS f o r d ilu tio n s 34 s 1 1 0 3 1 7 a 0 3 4 M B -1 1 0 3 1 6 -0 9 M e th o d B la n k w / IS f o r d ilu tio n s 35 s 1 1 0 3 1 7 a 0 3 5 M B -1 1 0 3 1 6 -1 0 M e th o d B la n k w / IS f o r d ilu tio n s 36 s1 1 0 3 1 7 a 0 3 6 ;M B -11 0316-11 M ethod B lank w / I S fo r dilutions 3 7 s 1 1 0 3 1 7 a 0 3 7 . M B -1 1 0 3 1 6 -1 2 M e th o d B la n k w / IS f o r d ilu tio n s 38 s 1 1 0 3 1 7 a 0 3 8 ,L C S -1 1 0 3 1 6 -0 1 3 ng LC S in TC R -842 39 s 1 1 0 3 1 7 a 0 3 9 , L C S -1 1 0 3 1 6 -0 2 3 ng LC S in TC R -842 40 s 1 1 0 3 1 7 a 0 4 0 L C S -1 1 0 3 1 6 -0 3 3 ng LC S in TC R -842 41 s 110317 a 0 4 1 ! 10 0 0 6 -8 0 so lv e n t blank 42 s1 1 0 3 1 7 a 0 4 2 \ E C -11 0 3 1 6 -0 5 2 .5 ng E xtra c te d C u rv e Point 43 s1 1 0 3 1 7 a 0 4 3 ,10 0 0 6 -8 0 s o lv e n t blank 44 s110317a044 G LP10-01-01-15-001 D A L S S S S T rip l 0 0000 45 s 1 1 0 3 1 7 a 0 4 5 G LP 10 -0 1 -0 1 -1 5 -0 0 1 Dup D A L SS S S T rip l 0 0 0 0 0 L ab D uplicate 46 s 1 1 0 3 1 7 a 0 4 6 G L P 1 0 -0 1 -0 1 -1 5 -0 0 1 LM S D A L S S S S T rip l 0 0 0 0 0 Lab M atrix S pike 47 s110317a04 7 G LP 10-01-01-15-083 D A L S S T rip 2 0 0000 48 s 1 1 0 3 1 7 a 0 4 8 G L P 1 0 -0 1 -0 1 -1 5 -0 8 3 Dup D A L S S T rip 2 0 0 00 0 Lab D uplicate 49 s 1 1 0 3 1 7 a 0 4 9 G L P 1 0 -0 1 -0 1 -1 5 -0 8 3 LM S D A L S S T rip 2 0 0 0 0 0 L a b M atrix Spike 50 s110317a050 GLP10-01-01-15-002 D AL SS SS12 0 0000 51 s 1 1 0 3 1 7 a 0 5 1 G L P 1 0 - 0 1 - 0 1 - 1 5 - 0 0 2 D u p D A L S S S S 1 2 0 0 0 0 0 L a b D u p lic a te 52 s 1 1 0 3 1 7 a 0 5 2 G L P 1 0 -0 1 -0 1 -1 5 -0 0 2 LM S D A L S S S S 12 0 0 0 0 0 Lab M atrix S pike 53 s110317a053 G LP10-01-01-15-003 D AL SS SS12 0 0005 54 s1 1 0 3 1 7 a 0 5 4 G L P 1 0 -0 1 -0 1 -1 5 -0 0 3 D up D A L S S S S 12 0 0 00 5 Lab D uplicate 55 s 1 1 0 3 1 7 a 0 5 5 G L P 1 0 -0 1 -0 1 -1 5 -0 0 3 LM S D A L S S S S 12 0 0 0 0 5 Lab M atrix S pike 56 s110317a056 GLP10-01-01-15-004 D AL SS SS13 0 0000 57 s1 1 0 3 1 7 a 0 5 7 G LP10 -0 1 -0 1 -1 5 -0 0 4 D up D A L SS S S 13 0 0 00 0 Lab D uplicate 58 s1 1 0 3 1 7 a 0 5 8 G LP 10 -0 1 -0 1 -1 5 -0 0 4 LM S D A L S S S S 13 0 0 0 0 0 L a b M atrix S pike 59 s1 1 0 3 1 7 a 0 5 9 10 0 0 6 -8 0 so lv e n t blank 60 s 1 1 0 3 1 7 a 0 6 0 : E C -11 0 3 1 6 -0 6 5 ng E x tra c te d C u rv e Point 61 s 1 1 0 3 1 7 a 0 6 1 ,1 0 0 0 6 -8 0 s o lv e n t b la n k Printing Date: Thursday, March 17, 2011 Rack Code Vial Position Data File Inj.Volume (Ml) 10 By 10 9 f 10 By 10 10 By 10 10 By 10 91 9 9 10 B y 10 91 10 B y 10 91 10 B y 10 91 10 B y 10 91 10 By 10 92 10 By 10 1 10 By 10 10 By 10 10 By 10 10 By 10 10 By 10 10 By 10 10 By 10 10 By 10 10 By 10 2 3 5 6 7 8 9 10 1 0 B y 10 11 10 By 10 12 10 By 10 92 10 By 10 92 _10" B y 10 92 10 By 10 93 10 By 10 13 10 By 10 14 10 By 10 15 10 By 10 16 10 By 10 17 10 By 10 18 10 By 10 19 10 By 10 20 1 0 B y 10 21 10 By 10 22 10 By 10 23 10 By 10 24 10 By 10 25 10 By 10 26 10 By 10 27 10 By 10 93 10 By 10 5 TO B y 10 94 10 By 10 28 10 By 10 29 10 By 10 30 1 0 B y 10 31 10 By 10 32 10 By 10 33 10 By 10 34 10 By 10 35 10 By 10 36 10 By 10 37 10 By 10 38 10 By 10 39 10 By 10 40 10 By 10 41 10 By 10 42 10 By 10 94 10 By 10 6 10 By 10 95 sTi03i7a" 254 )00 s110317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 sT 10317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 sTT0317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 s110317a 25.000 ' ' , ' : : ; : : ! , ; ; . | , ; < . ; ; 1 ; I : Page 1 of 3 3M Study GLP10-01-02-15 Pge 211 o ETS S ta n V I660305 P roject: \\W m snas01a\b2\P rojectsM -ab_lnstrum ent D a ta\S tan\S tan Data F ileshP rojects\fluorochem icals\soil B a tch:s1103 17a T a b :S a m p le S e t:S E T 01 A c q M e th o d :e ts 8-53 23 m in S ulfonates2 S am ple SiTm PIe S a m p le 10 Rack Code Vial Position Data File Inj.Volume (MO , 62 s110317a062 GLP10 -01-01-15-005 D A L SS SS16 0 0000 63 ,s 1 1 0 3 1 7 a 0 6 3 :G LP 10 -0 1 -0 1 -1 5 -0 0 5 D up D A L S S S S 16 0 0 0 0 0 La b D uplicate 64 ,s 1 1 0 3 1 7 a 0 6 4 G LP10 -0 1 -0 1 -1 5 -0 0 5 LM S D A L S S S S 16 0 0 00 0 Lab M atrix S pike 65 s110317a065 GLP10-01-01-15-006 D AL SS SS16 DB 0000 66 s 1 1 0 3 1 7 a 0 6 6 G LP10 -0 1 -0 1 -1 5 -0 0 6 D up D A L S S S S 16 DB 0 00 0 La b D uplicate 67 s 1 1 0 3 1 7 a 0 6 7 G L P 1 0 -0 1 -0 1 -1 5 -0 0 6 LM S D A L S S S S 1 6 DB 0 00 0 Lab M atrix S pike 68 s110317a068 GLP10-01-01-15-007 DAL SS SS 11 0 0000 69 s 1 1 0 3 1 7 a 0 6 9 G L P 1 0 -0 1 -0 1 -1 5 -0 0 7 D u p D A L S S S S 1 1 0 0 00 0 Lab D uplicate 70 s1 1 0 3 1 7 a 0 7 0 G L P 1 0 -0 1 -0 1 -1 5 -0 0 7 LM S D A L S S SS11 0 0 0 0 0 Lab M atrix S pike 71 s 1 1 0 3 1 7 a 0 7 1 G L P 1 0 - 0 1 - 0 1 - 1 5 - 0 0 8 D A L S S S S 1 1 0 0 0 0 5 72 s1 1 0 3 1 7 a 0 7 2 G L P 1 0 -0 1 -0 1 -1 5 -0 0 8 Dup D A L S S S S 1 1 0 0 00 5 Lab D uplicate 73 s 1 1 0 3 1 7 a 0 7 3 G LP 10 -0 1 -0 1 -1 5 -0 0 8 L M S D A L S S S S 1 1 0 0 0 0 5 Lab M atrix S pike 74 s110317a074 |GLP10-01-01-15-009 DAL SS SS20 0 0000 75 s 1 1 0 3 1 7 a 0 7 5 G LP10 -0 1 -0 1 -1 5 -0 0 9 Dup D A L SS S S 20 0 0000 Lab D uplicate 76 s 1 1 0 3 1 7 a 0 7 6 G LP 10 -0 1 -0 1 -1 5 -0 0 9 LM S D A L S S S S 20 0 0 0 0 0 L a b M atrix S pike 77 s110 317a07 7 10 00 6 -8 0 so lve n t blank . 78 s 1 1 0 3 1 7 a 0 7 8 ; E C -11 0 3 1 6 -0 7 10 ng E x tra c te d C u rv e Peint 79 s 110317a0 79 .10 0 0 6 -8 0 s o lv e n t blank 80 s110317a080 .GLP10-01-01-15-010 DAL SS SS20 DB 0000 81 s 1 1 0 3 1 7 a 0 8 1 ; G L P 1 0 - 0 1 - 0 1 - 1 5 - 0 1 0 D u p D A L S S S S 2 0 D B 0 0 0 0 L a b D u p lic a te 82 s 1 1 0 3 1 7 a 0 8 2 G LP 10 -0 1 -0 1 -1 5 -0 1 0 LM S D A L S S S S 2 0 DB 0 0 0 0 Lab M atrix S pike 83 s110317a083 G LP10-01-01-15-011 D AL SS SS19 0 0000 84 s 1 1 0 3 1 7 a 0 8 4 G L P 1 0 -0 1 -0 1 -1 5 -0 1 1 Dup D A L SS S S 19 0 00 0 0 Lab D uplicate 85 s 1 1 0 3 1 7 a 0 8 5 G L P 1 0 -0 1 -0 1 -1 5 -0 1 1 LM S D A L S S S S 1 9 0 0 0 0 0 Lab M atrix S pike 86 s110317a086 -GLP10 -01-01-15-012 D A L SS SS 19 0 0005 87 s 1 1 0 3 1 7 a 0 8 7 G LP10 -0 1 -0 1 -1 5 -0 1 2 D up D A L SS S S 19 0 0 00 5 Lab D uplicate 88 s1 1 0 3 1 7 a 0 8 8 i G LP 10 -0 1 -0 1 -1 5 -0 1 2 LM S D A L S S S S 1 9 0 0 0 0 5 L a b M atrix S pike 89 s110317a089 GLP10-01-01-15-014 DAL SS SS15 0 0000 90 s 1 1 0 3 1 7 a 0 9 0 'G L P 1 0 -0 -0 1 -1 5 -0 1 4 Dup D A L SS S S 15 0 0 00 0 Lab D uplicate 91 s 1 1 0 3 1 7 a 0 9 1 G L P 1 0 -0 1 -0 1 -1 5 -0 1 4 LM S D A L S S S S 1 5 0 0 0 0 0 L a b M a trix S p ike 92 s 110317a092 ;GLP10-01-01-15-015 DAL SS SS 1 7 0 0 0 0 0 93 s 1 1 0 3 1 7 a 0 9 3 IG LP 10 -0 1 -0 1 -1 5 -0 1 5 Dup D A L S S S S 17 0 000 0 Lab D uplicate 94 s1 1 0 3 1 7 a 0 9 4 G LP 10 -0 1 -0 1 -1 5 -0 1 5 LM S D A L S S S S 17 0 0 00 0 L a b M atrix S pike 95 s 1 1 0 3 1 7 a 0 9 5 ,10 0 0 6 -8 0 s o lv e n t blank 96 ;s 1 1 0 3 1 7 a 0 9 6 IE C -1 1 0 3 1 6 -0 5 2 .5 ng E xtra c te d C u rv e Point 97 s110 3 1 7 a 0 9 7 \ 10 0 0 6 -8 0 so lv e n t blank 98 s110317a098 G LP10-01-01-15-016 D AL SS SS14 0 0000 99 s 1 1 0 3 1 7 a 0 9 9 G L P 1 0 -0 1 -0 1 -1 5 -0 1 6 Dup D A L SS S S 14 0 0 00 0 L ab D uplicate 100 s 1 1 0 3 1 7 a 1 0 0 IG L P 1 0 -0 1 -0 1 -1 5 -0 1 6 LM S D A L S S S S 1 4 0 0 0 0 0 L a b M atrix S pike 101 s 1 1 0 3 1 7 a 1 0 1 ! G L P 1 0 -0 1 -0 1 -1 5 -0 1 8 D A L S S S S 1 8 0 0 00 0 102 s 1 1 0 3 1 7 a 1 0 2 G LP10 -0 1 -0 1 -1 5 -0 1 8 Dup D A L SS S S 18 0 0 00 0 Lab D uplicate 103 s 1 1 0 3 1 7 a 1 0 3 G LP 10 -0 1 -0 1 -1 5 -0 1 8 LM S D A L S S S S 1 8 0 0 0 0 0 Lab M atrix S pike 104 s110317a104 GLP10 -01-01-15-020 D A L SS SS10 0 0000 105 s 1 1 0 3 1 7 a 1 0 5 G LP10 -0 1 -0 1 -1 5 -0 2 0 D up D A L SS S S 10 0 0 00 0 Lab D uplicate 106 s1 1 0 3 1 7 a 1 0 6 G L P 1 0 -0 1 -0 1 -1 5 -0 2 0 LM S D A L S S S S 1 0 0 0 0 0 0 Lab M atrix S pike 107 s110317a107 !GLP10-01-01-15-021 D AL SS SS30 0 0000 108 ,s 1 1 0 3 1 7 a 1 0 8 ;G L P 1 0 -0 1 -0 1 -1 5 -0 2 1 D up D A L S S S S 30 0 0 00 0 Lab D uplicate 109 ,s 1 1 0 3 1 7 a 1 09 G L P 1 0 -0 1 -0 1 -1 5 -0 2 1 LM S D A L S S S S 3 0 0 0 0 0 0 Lab M atrix S pike 110 s110317a110 j GLP10-01 -0 1-15-022 D A L SS SS30 0 0005 111 s 1 1 0 3 1 7 a 1 11 ! G L P 1 0 - 0 1 - 0 1 - 1 5 - 0 2 2 D u p D A L S S S S 3 0 0 0 0 0 5 L a b D u p lic a te 112 s 1 1 0 3 1 7 a 1 1 2 G LP 10 -0 1 -0 1 -1 5 -0 2 2 LM S D A L S S S S 3 0 0 0 0 0 5 Lab M atrix S pike s1 1 0 3 1 7 a 1 1 3 10 0 0 6 -8 0 s o lv e n t blank 11j - J ^ s 1 1 0 3 1 7 a 1 1 4 E C -1 1 0 3 1 6 -0 6 5 n g E x tra c te d C u rv e P o int 's 1 1 0 3 1 7 a 1 15 :10 0 0 6 -8 0 s o lv e n t blank "TTe s 110317a 116 IGLP10 -01-01-15-023 D A L SS SS30 0 0015 117 s 1 1 0 3 1 7 a 1 1 7 G LP10 -0 1 -0 1 -1 5 -0 2 3 Dup D A L SS S S 30 0 0 01 5 L ab D uplicate 118 ' s 1 1 0 3 1 7 a 1 1 8 ;G LP 10 -0 1 -0 1 -1 5 -0 2 3 LM S D A L SS S S 30 0 0 01 5 L ab M atrix.S pike 119 s110 3 1 7 a 1 1 9 ,G LP 10 -0 1 -0 1 -1 5 -0 2 4 D A L SS S S 25 0 000 0 120 s1 1 0 3 1 7 a 1 2 0 .G L P 1 0 -0 1 -0 1 -1 5 -0 2 4 Dup D A L SS S S 25 0 0 00 0 L ab D uplicate 121 ,s1 1 0 3 1 7 a 1 2 1 G LP10 -0 1 -0 1 -1 5 -0 2 4 LM S D A L S S S S 2 5 0 0 0 0 0 L a b M a trix S pike 122 s110317a122 GLP10-01-01-15-025 DAL SS SS 25 0 0005 Printing Date: Thursday, March 17, 2011 10 By 10 43 10 By 10 44 10 By 10 45 10 By 10 46 10 By 10 47 10 By 10 48 10 By 10 49 10 By 10 50 10 B y 10 51 10 By 10 52 10 By 10 53 10 By 10 54 10 By 10 55 10 By 10 56 10 By 10 57 10 By 10 95 10 By 10 7 10 By 10 96 10 By 10 58 10 By 10 59 10 By 10 60 10 B y 10 61 10 By 10 62 10 By 10 63 10 By 10 64 10 By 10 65 10 By 10 66 10 By 10 67 10 By 10 68 10 B y 10 69 10 By 10 70 10 B y 10 71 10 B y 10 72 10 By 10 96 10 By 10 5 10 By 10 97 10 By 10 73 10 By 10 74 10 By 10 75 10 By 10 76 10 By 10 77 10 By 10 78 10 By 10 79 10 By 10 80 1 0 B y 10 81 10 By 10 82 10 By 10 83 10 By 10 84 10 By 10 85 10 By 10 86 10 By 10 87 10 By 10 97 10 By 10 6 10 By 10 98 10 By 10 13 10 By 10 14 10 By 10 15 10 By 10 16 10 By 10 17 10 By 10 18 10 By 10 19 s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a , s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 Page 2 of 3 ; ! , , ; ' : , i ( : ; : ; ; : ! ; 1 ; ( , ; : : ! ` . ! 1 1 1 J ; ! , ; \ ; 1 4 ; * ! : : ; ! : . Printing Time: 4:52:44 PM ((^J^)) v/a/s/ -/o / / ^ />7 y/^' /^ --/t[/y /O f& rO ETS S ta n V1660305 Project: \\Winsnas01a\b2\Projects\LabJnstrument Data\Stan\Stan Data Files^Projects\fluorochemicals\soil Batch:s110317a Tab:Sample Set:SET01 AcqMethod:ets8-53 23 min Sulfonates2 Sample ! SnZ I 6 Sample ID Rack Code Vial Pos ition Data File Inj.Volume (Ml) 123 124 125 126 127 128 129 130 131 132 133 134 135 136 137 138 ' 139 140 141 142 143 144 145 146 147 148 149 150 151 152 153 154 155 156 157 158 159 160 161 162 163 s 1 1 0 3 1 7 a 1 2 3 G LP10 -0 1 -0 1 -1 5 -0 2 5 Dup D A L S S S S 25 0 0 00 5 Lab D uplicate s 1 1 0 3 1 7 a 1 2 4 G LP10 -0 1 -0 1 -1 5 -0 2 5 LM S D A L S S S S 25 0 0 00 5 Lab M atrix S pike s110317a125 GLP10-01-01-15-026 D AL SS SS25 0 0015 s1 1 0 3 1 7 a 1 2 6 |G LP 10 -0 1 -0 1 -1 5 -0 2 6 D up D A L S S S S 2 5 0 0 0 1 5 La b D uplicate s1 1 0 3 1 7 a 1 2 7 ;G LP 10 -0 1 -0 1 -1 5 -0 2 6 LM S D A L S S S S 2 5 0 0 0 1 5 L a b M atrix S pike s110317a128 G LP10-01-01-15-027 DAL SD S D 22 0 0000 s 1 1 0 3 1 7 a 1 2 9 G LP10 -0 1 -0 1 -1 5 -0 2 7 Dup D A L S D S D 2 2 0 0 00 0 La b D uplicate s 1 1 0 3 1 7 a 1 3 0 G L P 1 0 -0 1 -0 1 -1 5 -0 2 7 LM S D A L S D S D 2 2 0 0 0 0 0 Lab M atrix S pike s110 317a13 1 ,10 0 0 6 -8 0 s o lv e n t blank s 1 1 0 3 1 7 a 1 3 2 E C -1 1 0 3 1 6 -0 7 10 n g E x tra c te d C u rv e Point s 110317a 133 ; 10 0 0 6 -8 0 s o lv e n t blank s110317a134 G LP10-01-01-15-028 DAL S D S D 22 0 0005 s 1 1 0 3 1 7 a 1 3 5 G L P 1 0 -0 1 -0 1 -1 5 -0 2 8 Dup D A L S D S D 2 2 0 0 00 5 L ab D uplicate s 1 1 0 3 1 7 a 1 3 6 G L P 1 0 -0 1 -0 1 -1 5 -0 2 8 LM S D A L S D S D 2 2 0 0 0 0 5 Lab M atrix S pike :s 110317a137 iGLP10-01 -01 -15-029 D AL SD SD22 DB 0005 :s 1 1 0 3 1 7 a 1 3 8 G LP10 -0 1 -0 1 -1 5 -0 2 9 Dup D A L S D S D 2 2 DB 0 00 5 Lab D uplicate s 1 1 0 3 1 7 a 1 3 9 G L P 1 0 -0 1 -0 1 -1 5 -0 2 9 LM S D A L S D S D 2 2 DB 0 0 0 5 Lab M atrix S pike s110317a140 G LP10-01-01-15-030 DAL SD S D 22 0 0015 s1 1 0 317a14 1 G LP10 -0 1 -0 1 -1 5 -0 3 0 Dup D A L S D S D 2 2 0 00 1 5 L ab D uplicate s 1 1 0 3 1 7 a 1 4 2 G L P 1 0 -0 1 -0 1 -1 5 -0 3 0 LM S D A L S D S D 2 2 0 0 0 1 5 Lab M atrix S pike s110317a143 G LP10-01-01-15-031 D A LS D S D 21 0 0000 s 1 1 0 3 1 7 a 1 4 4 G L P 1 0 -01-01-15-031 D u p D A L S D S D 2 1 0 00 0 0 Lab D uplicate s 1 1 0 3 1 7 a 1 4 5 G LP 10 -0 1 -0 1 -1 5 -0 3 1 L M S D A L S D S D 2 1 0 0 00 0 L a b M atrix S pike s110317a146 GLP10-01-01-15-032 D AL SD SD21 0 0005 s 1 1 0 3 1 7 a 1 4 7 G LP10 -0 1 -0 1 -1 5 -0 3 2 Dup D A L S D SD21 0 0 00 5 L ab D uplicate js 1 1 0 3 1 7 a 1 4 8 IG L P 1 0 -0 1 -0 1 -1 5 -0 3 2 L M S D A L S D S D 2 1 0 0 0 0 5 Lab M atrix S pike s1 1 0 3 1 7 a 1 4 9 110 0 0 6 -8 0 s o lv e n t blank s 1 1 0 3 1 7 a 1 5 0 E C -1 1 0 3 1 6 -0 5 2 .5 ng E xtra c te d C u rv e Point s 1 103 17 a 1 51 110 0 0 6 -8 0 s o lv e n t blank ,s 1 1 0 3 1 7 a 1 5 2 jG L P 1 0 -0 1 -0 1 -1 5 -0 3 3 D A L S D S D 2 1 0 0 0 1 5 s 1 1 0 3 1 7 a 1 5 3 G L P 1 0 -0 1 -0 1 -1 5 -0 3 3 D u p D A L S D S D 2 1 0 0 0 1 5 L ab D uplicate s 1 1 0 3 1 7 a 1 5 4 G L P 1 0 -0 1 -0 1 -1 5 -0 3 3 L M S D A L S D S D 2 1 0 0 0 1 5 L a b M atrix S pike s110317a155 GLP10-01-01-15-034 DAL SS SS24 0 0000 s 1 1 0 3 1 7 a 1 5 6 G LP10 -0 1 -0 1 -1 5 -0 3 4 Dup D A L SS S S 24 0 0 00 0 Lab D uplicate s 1 1 0 3 1 7 a 1 5 7 ,G LP 10 -0 1 -0 1 -1 5 -0 3 4 LM S D A L S S S S 2 4 0 0 0 0 0 Lab M atrix S pike s110317a158 ;GLP10 -01-01-15-035 DA L SS SS24 0 0005 s 1 1 0 3 1 7 a 1 5 9 G LP10 -0 1 -0 1 -1 5 -0 3 5 Dup D A L S S S S 24 0 0 00 5 Lab D uplicate s 1 1 0 3 1 7 a 1 6 0 |G LP 10 -0 1 -0 1 -1 5 -0 3 5 LM S D A L S S S S 24 0 0 0 0 5 L a b M atrix S pike s 110 317 a 1 61 110 0 0 6 -8 0 s o lv e n t blank s1 1 0 3 1 7 a 1 6 2 j E C -1 1 0 3 1 6 -0 6 5 ng E x tra c te d C u rv e Point s1 1 0 3 1 7 a 1 6 3 ; 10 0 0 6 -8 0 s o lv e n t blank 10 By 10 20 10 B y 10 21 10 By 10 22 10 By 10 23 10 By 10 24 10 By 10 25 10 By 10 26 10 By 10 27 10 By 10 98 10 By 10 7 10 By 10 99 10 By 10 28 10 By 10 29 10 By 10 30 10 B y 10 31 10 By 10 32 10 By 10 33 10 By 10 34 10 By 10 35 10 By 10 36 10 By 10 37 10 By 10 38 10 By 10 39 10 By 10 40 10 By 10 41 10 By 10 42 10 By 10 99 10 By 10 5 10 By 10 100 10 By 10 43 10 By 10 44 10 By 10 45 10 By 10 46 10 By 10 47 10 By 10 48 10 By 10 88 10 By 10 89 10 By 10 90 10 By 10 100 10 By 10 6 10 B y 10 91 s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a s110317a 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 2 5 .0 0 0 ; ' i i ; ; ; ! , ; ; ; ! ' ; j | \ < [ I 1 j j ' Printing Date: Thursday, March 17, 2011 Printing Time: 4:52:44 PM 3M Study GLP10-01-02-15 Page 3 of 3 Page 213 of 514 Stan V1660305 *3M Environmental Lab Sample Name Sample ID Analyte Pea Mime ( Sample Type 1 s110317a001 2 $110317a002 3 - s110317a003 4 S110317a0O4 5 : s110317a005 6 s110317a006 7 s110317a007 8 s110317a008 9 $110317a0O9 10.. s110317a010 11 s110317a011 12 s110317a012 13 s110317a013 14 : s110317a014 15 $110317a015 16 $110317a016 17 s110317a017 18 - s110317a018 19 S110317a019 20 s110317a020 21 s110317a021 22 s110317a022 23 s110317a023 24 s110317a024 25 $110317a025 26 s110317a026 27 s110317a027 28 s110317a028 29 s110317a029 30 s110317a030 31 s110317a031 32 s110317a032 33 s110317a033 34. s110317a034 35 s110317a035 36 s110317a036 37 s110317a037 38 s110317a038 39 s110317a039 40 $110317a040 41 s110317a041 42 s110317a042 43 s110317a043 44 s110317a044 45 s110317a045 46 s110317a046 47 s110317a047 48 s110317a048 49 . s 1103173049 50 $110317a050 51 s110317a051 52 s110317a052 53 s110317a053 54 . s110317a054 55 s1103l7a055 56 s110317a056 57 s110317a057 58 s110317a058 59 s1103173059 60 s110317a060 61 s110317a061 62 s110317a062 63 s110317a063 64 s110317a064 10 006-80 solvent blank MPFOS 10 006-80 solvent blank MPFOS EC-110316-09 50 ng Warm up standard MPFOS EC-110316'09 50 ng Warm up standard MPFOS 10 006-80 solvent blank MPFOS 10 006-80 solvent blank MPFOS 10 006-80 solvent blank MPFOS 10 006-80 solvent blank MPFOS 10 006-80 solvent blank MPFOS EC-11031601 0.2 ng Extracted Curve Point MPFOS EC-11031602 0.5 ng Extracted Curve Point MPFOS EC-11031603 0.75 ng Extracted Curve Point MPFOS EC-11031604 1 ng Extracted Curve Point MPFOS EC-11031605 2.5 ng Extracted Cuve Point MPFOS EC-11031606 5 ng Extracted Curve Point MPFOS EC-11031607 10 ng Extracted Curve Point MPFOS EC-11031608 25 ng Extracted Curve Point MPFOS EC-11031609 50 ng Extracted Curve Point MPFOS EC-110316-10100 ng Extracted Curve Point MPFOS EC-110316-11 200 ng Extracted Curve Point MPFOS EC-11031&-12 500 ng Extracted Curve Point MPFOS 10 006-80 solvent blank MPFOS 10 006-80 solvent blank MPFOS 10 006-80 solvent blank MPFOS 10 006-80 solvent blank MPFOS MB-11031&-01 Method Blank w/o IS MPFOS MB-110316-Q2 Method Blank w/o IS MPFOS MB-110316-03 Method Blank w/o IS MPFOS MB-110316-04 Method Blank w/ IS MPFOS MB-110316-05 Method Blank w/ IS MPFOS MB-110316-06 Method Blank w/ IS MPFOS MB-110316-07 Method Blank w/ IS for dlutions MPFOS MB-110316-08 Method Blank w/ IS for dilutions MPFOS MB-110316-09 Method Blank w/ IS for tflutions MPFOS MB-110316-10 Method Blank vd IS for dilutions MPFOS MB-11031&-11 Method Blank w/ IS for dilutions MPFOS MB-110316-12 Method Blank w/ IS for dilutions MPFOS LCS-110316-01 3 ng LCS in TCR-842 MPFOS LCS-110316-02 3 ng LCS in TCR-842 MPFOS LCS-11031683 3 ng LCS in TCR-842 MPFOS 10 006-80 solvent blank MPFOS EC-11031685 2.5 ng Extracted Curve Point MPFOS 10 006-60 solvent blank MPFOS GLP1081-01-15-001 DAL SS SS Tripl 0 0000 MPFOS GLP1081-01-15801 Dup DAL SS SS Tripl 0 0000 Lab Delicate MPFOS GLP10-01-01-15-001 LMS DAL SS SS Tripl 0 0000 Lab Matrix Spike MPFOS GLP1081-01-15883 DAL SS Trip2 0 0000 MPFOS GLP10-01-01-15-083 Dup DAL SS Trip2 0 0000 Lifo Duplicate MPFOS GLP10-01-01-15-083 LMS DAL SS Trip2 0 0000 Lab Matrix Spike MPFOS GLP10-0181-15802 DAL SS SS12 0 0000 MPFOS GLP108181-15-002 Dup DAL SS SS12 0 0000 Lab Duplicate MPFOS GLP10-0181-15-002 LMS DAL SS SS12 0 0000 Lab Matrix Spike MPFOS GLP108181-15-003 DAL SS SS12 0 0005 MPFOS GLP108181-15-003 Dup DAL SS SS12 0 0005 Lab Delicate MPFOS GLP1O8181-1S803 LMS DAL SS SS12 0 0005 Lab Matrix Spike MPFOS GLP108181-15804 DAL SS SS13 0 0000 MPFOS GLP10-0181-15-004 Dup DAL SS SS13 0 0000 Lab Duplicate MPFOS GLP108181-15804 LMS DAL SS SS13 0 0000 Lab Matrix Spike MPFOS 10 00680 solvent blank MPFOS EC-11031686 5 ng Extracted Curve Point MPFOS 10 006-80 solvent blank MPFOS GLP10-0181-15-005 DAL SS SS16 0 0000 MPFOS GLP10-0181-15-005 Dup DAL SS SS16 0 0000 Lab Delicate MPFOS GLP108181-15-005 LMS DAL SS SS16 0 0000 Lab Matrix Spike MPFOS Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Results Name: sll0317a.rdb Use Record Analyte Concentration (ng/mL) Analyte Retention Time (min) Analyte Peal Area (counts IS Peak Nam< IS Peak Area (counts) IS Concentration (ng/mL) R o J __do, n r Caleul,llt d Concentration (min) ! 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 EEEEEEEEEEEE 0.00 0.191 0.478 0.717 0.956 2.39 4.78 9.56 23.9 47.8 95.6 191. 478. 0.00 0.00 0.00 0.00 0.00 0.00 0.00 N/A N/A NIA N/A N/A N/A N/A N/A N/A N/A N/A N/A E 0.00 2.39 0.00 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A E 0.00 4.78 0.00 N/A N/A N/A 13.213 13.521 13.155 13.136 13.116 0.000 13.232 13.155 13.174 13.136 13.193 13.136 13.116 13.116 13.097 13.097 13.136 13.136 13.116 13.097 13.078 13.116 13.116 13.097 13.039 13.136 12.924 13.039 13.116 13.078 13.116 13.078 13.078 13.097 13.097 13.116 13.059 13.078 13.078 13.097 12.847 13.116 13.270 13.039 13.097 13.020 13.097 13.097 13.097 13.097 13.116 13.059 13.078 13.116 13.020 13.097 13.097 13.097 0.000 13.116 12.789 13.097 13.039 13.116 231 58 1422277 1527459 347 0 231 104 81 9245 20224 27827 37466 90989 177188 345045 899594 1603828 2860818 4400625 8749000 4230 1156 462 254 208 231 208 111825 111670 111896 117544 107378 120776 114517 116010 114020 110413 114126 109288 162 91291 69 104929 109224 113358 111972 108377 113864 57548 55228 48087 42286 45562 43569 69179 95452 76106 0 165563 104 77504 84568 68145 M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS 0 0 71041 74578 92 3S 104 23 81 86821 84743 86392 83869 83249 86137 87976 84600 80137 73465 62446 50366 69 0 0 58 104 23 92 79137 86476 62358 92833 89971 86799 93701 92750 91133 82221 87261 87093 0 90561 0 84895 83653 84869 84267 84642 87292 36901 39958 25953 26379 29263 23546 67555 66596 57331 12 78659 104 64889 66160 50595 N/A N/A N/A N/A N/A N/A N/A N/A N/A 2.87 287 2.87 287 287 287 287 287 287 287 287 287 N/A N/A N/A N/A N/A N/A N/A 287 287 287 287 287 287 287 287 287 2.87 2.87 2.87 N/A 287 N/A 287 287 287 287 287 287 287 287 287 287 287 287 287 287 287 N/A 287 N/A 287 287 287 0.00 IN/A 0.00 (N/A 13.2 N/A 13.2 N/A 13.1 N/A 13.2 N/A 129 N/A 13.0 N/A 13.1 N/A 13.2 0.153 13.1 0.477 13.1 0.682 13.1 0.988 13.1 2.58 13.1 4.95 13.1 9.54 13.1 26.2 13.1 49.6 13.1 97.8 13.1 181. 13.1 482. 13.1 N/A 0.00 N/A 0.00 N/A 129 N/A 13.3 N/A 13.0 N/A 13.3 N/A 13.1 3.36 13.1 3.06 13.1 3.23 13.1 3.00 13.1 2.62 13.1 3.31 13.1 2.89 13.1 296 13.1 2.96 13.1 3.19 13.1 3.10 13.1 2.97 0.00 N/A 13.1 2.37 0.00 N/A 13.0 2.93 13.1 3.09 13.1 3.17 13.1 3.15 13.1 3.04 13.1 3.10 13.1 3.53 13.1 3.29 13.1 4.44 13.1 3.83 13.1 3.72 13.0 4.44 13.1 3.13 13.1 3.41 13.1 3.15 13.2 N/A 13.1 5.06 13.0 N/A 13.1 2.82 13.1 3.03 13.1 3.20 i i Accuracy ; Record (%) ] Modified File Name N/A ! s1 10317 awiff N/A ] s110317a.wiff N/A N/A N/A N/A N/A N/A N/A 79.9 99.8 95.1 103. 108. 103. 99.8 109. 104. 102. 94.6 101. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 99.0 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 106. N/A N/A n n n n s110317a.wiff s110317a.wiff s110317a.wiff s110317a.will s110317a.wifl s110317a.wi(l s110317a.wiff s110317a.wiff s110317a.wiff s110317 awilt s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wi!F s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wi!f s110317awiff s110317awiff s110317awiff s110317awiff s110317awiff s110317awiff s110317a.wiir s110317a.wiff s1 10317 a wiff s110317awiff s1 10317 a wiff s110317a.wiff s110317 awiff s 1 10317a.wiff s110317awiff s110317a.wiff s110317a.wiff s110317awiff s110317awiff s110317a.wiff s110317a.wiff s110317awiff s110317a.wiff s110317a.wiff s110317a.wiff s110317awiff s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff s110317awiff s110317a.wiff s110317awiff s110317a wiff s 1 10317a. wiff $110317awiff s1 10317a.wiff s 1 10317a.wiff N/A N/A s110317a.wiff s110317a.wiff Printing Date: Tuesday, April 05, 2011 Printing TgM Study GLP1Q-Q1-Q2-15 Stari V1660305 Results Name: sll0317a.rdb *3M Environmental Lab ' . fv Sample Name [ . ' - Sample ID .. 65 s110317a065 66 s110317a066 67 s110317a067 68 ' s110317a068 69 s110317a069 70 s110317a070 71 s110317a071 72 s110317a072 73 s110317a073 74 s110317a074 75 s110317a075 76 s110317a076 77 s110317a077 78 s110317a078 79 s110317a079 80 $110317a080 81 s110317a081 82 s110317a082 83 s110317a083 84 s110317a084 85 s110317a085 86 s110317a086 87 s110317a087 88 S110317a088 89 $110317a089 90 s110317a090 91 S110317a091 92 s110317a092 93 s110317a093 94 S110317a094 95 s110317a095 96 s110317a096 97 s110317a097 98 s110317a098 99 s110317a099 100 s110317a100 101 s110317a101 102 s110317a102 103 s110317a103 104 s110317a104 105 s110317a105 106- s110317a106 107 s110317a107 108 5110317a108 109 s110317a109 110 s110317a110 111 s110317a111 112 s110317a112 113 s110317a113 114 s110317a114 115 s110317a115 117116 s110317a116 s110317a117 118 s110317a118 119 s110317a119 120 s110317a120 121 s110317a121 122, s110317a122 123 s110317a123 124 s110317a124 125 s110317a125 126 s110317a126 127 s110317a127 128 s110317a128 GLP10-01-01-15-006 DAL SS SS16 DB 0000 GLP10-01-01-15-006 Dup DAL SS SS16 DB 0000 Lab Duplicate GLP10-01-01-15-006 LMS DAL SS SS16 DB 0000 Lab Matrix Spike GLP10-01-01-15-007 DAL SS SS11 0 0000 GLP10-01-01-15-007 Dup DAL SS SS11 0 0000 Lab Duplicate GLP10-01-01-15-007 LMS DAL SS SS11 0 0000 Lab Matrix Spike GLP10-01-01-15-008 DAL SS SS11 0 0005 GLP10-01-01-15-008 Dup DAL SS SS11 0 0005 Lab Duplicate GLP10-01-01-15-008 LMS DAL SS SS11 0 0005 Lab Matrix Spike GLP10-01-01-15-009 DAL SS SS20 0 0000 GLP10-01-01-15-009 Dup DAL SS SS20 0 0000 Lab Delicate GLP10-01-01-15-009 LMS DAL SS SS20 0 0000 Lab Matrix Spike 10 0 0 6 -8 0 solvent blank EC-110316-07 10 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-010 DAL SS SS20 DB 0000 GLP10-01-01-15-010 Dup DAL SS SS20 DB 0000 Lab Duplicate GLP10-01-01-15-010 LMS DAL SS SS20 DB 0000 Urf> Matrix Spike GLP10-01-01-15-011 DAL SS SS19 0 0000 GLP10-01-01-15011 Dup DAL SS SS19 0 0000 Lab Duplicate GLP10-01-01-15-011 LMS DAL SS SS19 0 0000 Lab Matrix Spike GLP10-01-01-15-012 DAL SS SS19 0 0005 GLP10-01-01-15-012 Dup DAL SS SS19 0 0005 Lab Dedicate GLP1601-01-15-012 LMS DAL SS SS19 0 0005 Lab Matrix Spike GLP1601-01-15-014 DAL SS SS15 0 0000 GLP1601-01-15-014 Dip DAL SS SS15 0 0000 Lab Diplicate GLP1601-01-15-014 LMS DAL SS SS15 0 0000 Lab Matrix Spike GLP1601-01-15-015 DAL SS SS17 0 0000 GLP1601-01-15-015 Dup DAL SS SS17 0 0000 Lab Duplicate GLP1601-01-15-015 LMS DAL SS SS17 0 0000 Lab Matrix Spike 10 006-80 solvent blank EC-110316-05 2.5 ng Extracted Cune Point 10 006-80 solvent blank GLP1601-01-15-016 DAL SS SS14 0 0000 GLP16O1-01-15-016 Dup DAL SS SS14 0 0000 Lab Duplicate GLP1601-01-15016 LMS DAL SS SS14 0 0000 Lab Matrix Spike GLP1601-01-15-018 DAL SS SS18 0 0000 GLP1601-01-15-018 Dup DAL SS SS18 0 0000 Lab Duplicate GLP1601-01-15-018 LMS DAL SS SS18 0 0000 Lab Matrix Spike GLP1601-01-15-020 DAL SS SS10 0 0000 GLP10-01-01-15-020 Dip DAL SS SS10 0 0000 Lab Diplicate GLP1601-01-15-020 IMS DAL SS SS10 0 0000 Lab Matrix Spike GLP1601-01-15021 DAL SS SS30 0 0000 GLP1601-01-15021 Dup DAL SS SS30 0 0000 Lab Diplicate GLP160101-15021 LMS DAL SS SS30 0 0000 Lab Matrix Spike GLP1601-01-15022 DAL SS SS30 0 0005 GLP1601-01-15022 Dup DAL SS SS30 0 0005 Lab Duplicate GLP100101-15022 LMS DAL SS SS30 0 0005 Lab Matrix Spike 10 006-80 solvent blank EC-110316-06 5 ng Extracted Curve Point 10 006-80 solvent blank GLP100101-15023 DAL SS SS30 0 0015 GLP10O101-15023 Dup DAL SS SS30 0 0015 Lab Diplicate GLP100101-15023 LMS DAL SS SS30 0 0015 Lab Matrix Spike GLP160101-15024 DAL SS SS25 0 0000 GLP100101-15024 Dup DAL SS SS25 0 0000 Lab Diplicate GLP100101-15024 IMS DAL SS SS25 0 0000 Lab Matrix Spike GLP100101-15-025 DAL SS SS25 0 0005 GLP1601O1-15025 Dup DAL SS SS25 0 0005 Lab Diplicate GLP100101-15025 LMS DAL SS SS25 0 0005 Lab Matrix Spike GLP100101-15-026 DAL SS SS25 0 0015 GLP100101-15026 Dup DAL SS SS25 0 0015 Lab Diplicate GLP100101-15026 LMS DAL SS SS25 0 0015 Lab Matrix Spike GLP160101-15-027 DAL SD SD22 0 0000 I Analyte Pea Marne ` U Sample Type ; Reoord i ] MPFOS Unknown i MPFOS Unknown \ MPFOS Unknown MPFOS Unknown MPFOS Unknown MPFOS Unknown MPFOS Unknown MPFOS Unknown MPFOS Unknown MPFOS MPFOS Unknown Unknown MPFOS Unknown MPFOS MPFOS MPFOS Double Blank Quality Control Double Blank E MPFOS Unknown MPFOS Unknown MPFOS Unknown MPFOS Unknown MPFOS Unknown MPFOS Unknown MPFOS Unknown MPFOS Unknown MPFOS Unknown MPFOS Unknown MPFOS Unknown MPFOS Unknown MPFOS Unknown MPFOS Unknown MPFOS Unknown MPFOS MPFOS MPFOS Double Blank Quality Control Double Blank E MPFOS Unknown MPFOS Unknown MPFOS Unknown MPFOS Unknown MPFOS Unknown MPFOS Unknown MPFOS Unknown MPFOS Unknown MPFOS Unknown MPFOS Unknown MPFOS Unknown MPFOS Unknown MPFOS Unknown MPFOS Unknown MPFOS Unknown MPFOS MPFOS MPFOS Double Blank Quality Control Double Blank E MPFOS Unknown MPFOS Unknown MPFOS Unknown MPFOS Unknown MPFOS Unknown MPFOS Unknown MPFOS Unknown MPFOS Unknown MPFOS Unknown MPFOS MPFOS MPFOS Unknown Unknown Unknown MPFOS Unknown Analyte Concentration (ng/mL) Analyte Retention Time (min) Analyte Peal Area (county IS Peak Nami IS Peak Area (counts) . IS., jIS Calculated Concentration Re? ^ o n ! Concentration (ng/mL) (min) ! <n,mL> N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 0.00 9.56 0.00 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 0.00 2.39 0.00 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 0.00 4.78 0.00 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 13.039 13.116 13.059 13.078 13.116 13.116 13.097 13.078 13.116 13.078 13.078 13.039 13.155 13.097 12.885 13.078 13.039 13.039 13.116 13.078 13.097 13.039 13.059 13.059 13.097 13.078 13.020 13.097 13.078 13.001 13.001 13.078 0.000 13.097 13.039 13.039 13.039 13.059 13.078 13.039 13.078 13.020 13.059 13.059 13.020 13.059 13.059 13.039 0.000 13.059 0.000 13.059 13.059 13.078 13.078 13.020 13.059 13.059 13.039 13.001 13.020 13.059 13.020 13.039 86032 85477 64208 95613 98608 87522 46607 62336 82335 98051 105863 80307 185 340119 92 99650 91655 80888 73328 75363 74086 76737 78489 67433 99533 75725 62285 96425 98277 65330 324 94552 0 11338 77877 66055 96356 99110 77099 64784 53203 40838 81477 83950 69676 89448 92298 81120 0 171243 0 91425 84789 77802 47419 40855 44865 57745 55328 46275 57491 53116 40353 48090 M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M6PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M6PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS 65898 64550 48760 72962 81076 70641 28799 61761 69663 74628 76257 59477 0 82676 92 77263 75708 59445 56262 57873 58689 61275 59988 48739 76833 59193 52047 76157 76954 69267 243 84812 92 9430 52792 45057 74231 78701 61208 46067 40581 25248 63383 64904 46285 68139 67408 57696 58 84651 243 71212 64331 58198 32988 28453 28828 40539 40685 27141 36863 38244 26267 32876 287 287 287 287 287 287 287 287 287 2.87 287 287 N/A 287 N/A 287 287 287 2.87 287 287 287 287 287 287 287 287 287 267 287 N/A 287 N/A 287 287 2.87 287 287 287 2.87 2.87 287 2.87 2.87 287 2.87 2.87 2.87 N/A 287 N/A 287 287 287 287 287 287 287 2.87 287 287 287 287 287 131 13.1 13.1 13.1 13.1 13.0 13.0 13.1 13.1 13.1 13.1 13.0 0.00 13.1 13.1 13.1 13.1 13.1 13.1 13.0 13.1 13.1 13.1 13.1 13.1 13.1 13.0 13.1 13.1 13.0 12.6 13.1 13.0 13.1 13.0 13.1 13.1 13.0 13.1 13.1 13.0 13.1 13.1 13.1 13.1 13.1 13.1 13.0 13.1 13.0 13.1 13.0 13.1 13.1 13.0 13.1 13.1 13.1 13.0 13.0 13.1 13.0 13.0 13.1 3.10 3.14 3.13 3.11 2.88 2.93 3.87 3.17 2.79 3.12 3.30 3.21 N/A 10.0 N/A 3.06 2.86 3.23 3.09 3.09 2.99 2.97 3.10 3.29 3.07 3.03 2.83 3.07 2.95 292 N/A 2.63 N/A 2.84 3.51 3.49 3.08 2.98 2.99 3.35 3.11 3.86 3.05 3.07 3.59 3.12 3.25 3.34 N/A 4.86 N/A 3.04 3.13 3.17 3.42 3.42 3.71 3.39 3.23 4.08 3.72 3.30 3.67 3.48 ' I ./ . iAccuracy Record (%) ! Modified File Name i_ N/A s110317awiff N/A s110317awiff N/A s110317a.wiff N/A s110317a.wiff N/A s110317a.wiff N/A s110317a.vriff N/A s110317a.wiff N/A s110317a.wiff N/A s110317a.wiff N/A s110317a.wiff N/A s110317a.wiff N/A s110317a.wiff N/A s110317a.wiff 105. s110317a.wiff N/A s110317a.wiff N/A s110317a.wiff N/A s110317a.wiff N/A 5110317a.wiff N/A s110317a.wiff N/A s110317a.wiff N/A s110317a.wiff N/A s110317a.wiff N/A s110317a.wiff N/A o s110317a.wiff N/A a s110317a.wiff N/A s110317a.wiff nN/A s110317awiff N/A s110317a.wiff N/A s110317a.wiff N/A s110317a.wiff N/A 110. s110317a.wiff s110317a.wiff N/A s110317awiff N/A s110317a.wiff N/A s110317awiff N/A s110317a.wiff N/A s110317a.wiff N/A s110317a.wiff N/A s110317a.wiff EN/A s110317awiff N/A s110317awiff N/A s110317awiff N/A s110317a.wiff N/A s110317a.wiff N/A s110317awiff N/A s110317a.wiff N/A s110317a.wiff N/A s110317a.wiff N/A 102 5110317a.wiff s110317a.wiff N/A s110317a.wiff N/A s110317a.wiff N/A s110317awiff N/A s110317a.wiff N/A s110317awiff N/A s110317a.wi(F N/A s110317awiff N/A 5110317a.wiff N/A s110317a.wiff N/A s110317a.wiff N/A s110317a.wiff N/A 5110317a.wiff nN/A s110317a.wiff N/A s110317a.wiff Printing Date: Tuesday, April 05, 2011 Printing TgM Study <SL:P10-Q1-Q2-15 Page 2 of 11 Page 215 of 514 *Stan V1660305 *3M Environmental Lab Sample Name Sample ID Results Name: sll0317a.rdb Analyte Pea Name ( Sample Type Use Record Analyte Concentration (ng/mL) . Analyte Retention Time (min) Analyte Peat Area (counts! IS Peak Kami 13 Peak Area (COlfftS) IS Concentration (ng/mL) IS Retention Time (min) Calculated Concentration (ng/mL) Accuracy W Record Modified File Name 129 s110317a129 130: s110317a130 131 s110317a131 132 s110317a132 133 s110317a133 134 s110317a134 135 s110317a135 136 s110317a136 137 s110317a137 138 s110317a138 139 s110317a139 140 s110317a140 14' s110317a141 142 s110317a142 143 S110317a143 144 s110317a144 145 s110317a145 146 s110317a146 147 s110317a147 148 s110317a148 149 s110317a149 150 s110317a150 151 s110317a151 152 s110317a152 153 s110317a153 154 s110317a154 155 s110317a155 156 s110317a156 157 s110317a157 1 58 ^ s110317a158 159 s110317a159 160 s110317a160 161 s110317a161 162 s110317a162 163 s110317a163 164 s110317a001 165 s110317a002 166 s110317a003 167 s110317a004 168 s110317a005 169 s110317a006 170 S110317a007 171 s1103173008 172 s110317a009 173 s110317a010 174 s110317a011 175 s110317a012 176 s110317a013 177 s110317a014 178 s110317a015 179 s110317a016 180 s110317a017 181 $110317a018 182 s110317a019 163 s110317a020 184 s110317a021 185 s110317a022 186 s110317a023 187 s110317a024 188 s110317a025 189 s110317a026 190 s110317a027 191 s110317a028 192 s110317a029 GLP10-01-01-15-027 Dup DAL SD SD22 0 0000 Lab Delicate GLP1001-01-15-027 LMS DAL SD SD22 0 0000 Lab Matrix Spike 10 006-80 solvent blank EC-110316-07 10 ng Extracted Cun Point 10 006-80 solvent blank GLP1001-01-15-028 DAL SD SD22 0 0005 GLP1001-01-15028 Dup DAL SD SD22 0 0005 Lab Delicate GLP100101-15-028 LMS DAL SD SD22 0 0005 Lab Matrix Spike GLP100101-15029 DAL SD SD22 DB 0005 GLP100101-15029 Dup DAL SD SD22 DB 0005 Lab Duplicate GLP100101-15-029 LMS DAL SD SD22 DB 0005 Lab Matrix Spike GLP100101-15030 DAL SD SD22 0 0015 GLP100101-15030 Dup DAL SD SD22 0 0015 Lab Duplicate GLP100101-15030 LMS DAL SD SD22 0 0015 Lab Matrix Spike GLP100101-15031 DAL SD SD21 0 0000 GLP100101-15031 Dup DAL SD SD21 0 0000 Lab Delicate GLP100101-15031 LMS DAL SD SD21 0 0000 Lab Matrix Spike GLP100101-15032 DAL SD SD21 0 0005 GLP100101-15032 Dup DAL SD SD21 0 0005 Lab Duplicate GLP100101-15032 LMS DAL SD SD21 0 0005 Lab Matrix Spike 10 006-80 solvent blank EC-110316-05 2.5 ng Extracted Cune Point 10 00680 solvent blank GLP100101-15033 DAL SD SD21 0 0015 GLP100101-15033 Dup DAL SD SD21 0 0015 Lab Duplicate GLP100101-15033 LMS DAL SD SD21 0 0015 Lab Matrix Spike GLP100101-15034 DAL SS SS24 0 0000 GLP100101-15034 Dup DAL SS SS24 0 0000 Lab Duplicate GLP100101-15034 LMS DAL SS SS24 0 0000 Lab Matrix Spike GLP10O1O1-15-035 DAL SS SS24 0 0005 GLP100101-15035 Dup DAL SS SS24 0 0005 Lab Delicate GLP100101-15035 LMS DAL SS SS24 0 0005 Lab Matrix Spike 10 00600 solvent blank EC-11031606 5 ng Extracted Curve Point 10 00680 solvent blank 10 00680 solvent blank 10 00600 solvent blank EC-110316-09 50 ng Warm up standard EC-110316-09 50 ng Warm up standard 10 00680 solvent blank 10 00600 solvent blank 10 00680 solvent blank 10 00680 solvent blank 10 00600 solvent blank EC-11031601 0.2 ng Extracted Cune Point EC-110316-02 0.5 ng Extracted Cune Point EC-11031683 0.75 ng Extracted Curve Point EC-110316-04 1 ng Extracted Curve Point EC-110316-05 2.5 ng Extracted Cuve Point EC-110316-06 5 ng Extracted Curve Point EC-110316-07 10 ng Extracted C ura Point EC-110316-08 25 ng Extracted Cura Point EC-11031689 50 ng Extracted Cura Point EC-110316-10 100 ng Extracted Cura Point EC-110316-11 200 ng Extracted Cura Point EC-110316-12 500 ng Extracted Cura Point 10 00680 solvent blank 10 00680 solvent blank 10 00680 solvent blank 10 00680 solvent blank MB-11031681 Method Blaik w/o IS MB-11031682 Method Blmk w/o IS /MB-11031683 Method Blank w/o IS MB-110316-04 Method Blvik w 1S MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Unknown N/A N/A E 0.00 9.56 0.00 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A E 0.00 2.39 0.00 N/A N/A N/A N/A N/A N/A N/A N/A N/A E 0.00 4.78 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.200 EE 0.500 0.749 EE 0.999 E 2.50 E 5.00 E 9.99 E 25.Q E 50.0 E 99.9 E 200. E 500. 0.00 0.00 0.00 0.00 0.00 0.00 0.00 N/A 13.078 13.059 13.386 13.059 0.000 13.059 13.097 13.078 13.020 13.059 13.078 13.059 13.078 13.001 13.059 13.059 13.039 13.078 13.020 13.001 13.078 13.078 13.213 13.059 13.059 13.078 13.059 13.020 13.039 13.078 13.001 13.059 12.982 13.078 13.097 7.820 7.762 7.858 7.877 7.916 7.858 7.800 7.858 0.000 7.858 7.858 7.839 7.858 7.839 7.839 7.858 7.839 7.839 7.839 7.839 7.820 7.916 7.916 7.897 7.897 7.858 7.858 7.820 7.839 51884 40719 300 320555 0 70785 61685 54486 56321 62416 51492 77224 61318 64198 58269 61339 44441 57134 59461 48598 116 91826 104 66688 80195 60973 62216 65569 54987 55869 57643 40463 23 168396 254 921 71 4311843 4439863 1435 114 215 87 0 27208 53592 83457 99896 269327 511447 1003793 2558350 4938165 9042006 15661805 30269716 9083 1561 1075 783 1440 1588 1677 2465 M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS 36951 24842 69 81594 162 52259 50077 43569 42146 50415 40144 56597 61541 51048 43856 39283 24655 40746 41709 33889 0 81280 92 52553 60914 461S8 47268 46553 41489 39141 39804 24846 12 78460 0 69 23 203873 217479 0 0 46 0 81 239606 240563 231606 235289 245482 236192 239439 240071 233801 234003 213997 185396 0 81 46 0 23 173 21 230545 2.87 2.87 N/A Z87 N/A 2.87 2.87 2.87 2.87 2.87 2.87 2.87 2.87 2.87 2.87 287 287 287 287 287 N/A 2.87 N/A 2.87 287 287 287 2.87 287 2.87 287 287 N/A 287 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 2.93 2.93 2.93 293 293 293 293 293 293 293 293 2.93 N/A N/A N/A N/A N/A N/A N/A 293 13.1 13.0 13.2 13.0 13.2 13.1 13.0 13.0 13.0 13.1 13.1 13.1 13.0 13.0 13.0 13.1 13.1 13.0 13.1 13.0 0.00 13.1 128 13.1 13.1 13.1 13.1 13.1 13.0 13.1 13.1 13.0 13.0 13.1 0.00 7.68 7.86 7.86 7.88 0.00 0.00 7.76 0.00 7.84 7.86 7.86 7.86 7.84 7.84 7.84 7.86 7.84 7.84 7.84 7.84 7.82 0.00 7.84 7.99 0.00 7.72 8.07 7.88 7.84 3.34 3.92 N/A 9.56 N/A 3.22 2.92 2.96 3.29 2.93 3.04 3.24 3.14 2.98 3.15 3.73 4.32 3.34 3.39 3.41 N/A 2.67 N/A 3.01 3.12 3.14 3.12 3.35 3.15 3.40 3.45 3.89 N/A 5.17 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 0.189 0.455 0.789 0.946 2.56 5.19 10.1 26.1 52.4 97.8 196. 502. N/A N/A N/A N/A N/A N/A N/A <0 N/A N/A N/A 100. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 112. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 108. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 94.7 91.0 105. 94.7 103. 104. 102 104. 105. 97.9 98.1 100. N/A N/A N/A N/A N/A N/A N/A N/A s110317a.wiff s110317a.wiff s110317awiff s110317a.wiff s110317a.will s i 10317a.will s110317a.will s110317a.wiff s110317a.wifF s110317a.wifT s110317a.wiff $110317a.wiff s110317a.wiff s1317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff nn s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff n s110317awiff s110317awiff s110317a.wiff s110317awtff s110317a.wiff s11Q317awiff s110317awiff 5110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff s110317awiff s110317awiff s110317awiff s110317awiff s110317awiff s110317awiff s110317awiff s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff s110317awiff s110317a.wiff s110317a.wiff s110317a.wiff s110317awiff s110317a.wiff $110317a.wiff s110317awiff E s110317a.wiff s110317a.wiff s110317a.wiff S110317a.wiff s110317a.wiff Printing Date: Tuesday, April 05, 2011 Printing T3M Study <SbPlQ-01-Q2-15 Page 3 of 11 Page 216 of 514 Stan V1660305 *3M Environmental Lab '. :V 'V Sample Name . : .- ' . 8ample ID ' Analyte Pea Name Sample Type 193 s110317a030 194 s110317a031 195 s110317a032 196 s110317a033 197 s110317a034 198 s110317a035 199 s110317a036 200 s110317a037 201; s110317a038 202 s110317a039 203 s110317a040 204 s110317a041 205 s110317a042 206 s110317a043 207 s110317a044 206 s110317a045 209 s110317a046 210 s110317a047 211 s110317a048 212 s110317a049 213 s110317a050 214 s110317a051 215 s110317a052 216 s110317a053 217 s110317a054 218 s110317a055 219 s110317a056 220 s110317a057 221 s110317a056 222 s110317a059 223 s1103173060 224 s110317a061 225 s110317a062 226 s110317a063 227 s110317a064 228 s110317a065 229 s110317a066 230 s110317a067 231 s110317a068 232 s110317a069 233 s110317a070 234 s110317a071 235 s110317a072 236 s110317a073 237 s110317a074 238 s110317a075 239 s110317a076 240 s110317a077 241 s110317a078 242 s110317a079 243 $110317a080 244 s110317a081 245 s110317a082 246 $110317a083 247 s110317a084 248 s110317a085 249 s1103173086 250 s110317a087 251 s110317a088 252 S110317a089 253 s110317a090 254 s110317aO91 255 s1103l7a092 256 s110317a093 MB-110316-05 Method Blank w/ IS MB-110316-06 Method Blank w/ IS MB-110316-07 Method Blank w/ IS for dilutions MB-110316-08 Method Blank w/ IS for dilutions MB-110316-09 Method Blank w/ IS for dilutions MB-110316-10 Method Blank w/ IS for dilutions MB-110316-11 Method Blank W IS for dilutions MB-110316-12 Method Blank w/ IS for dilutions LCS-11031601 3 ng LCS in TCR-842 LCS-110316-02 3 ng LCS in TCR-842 LCS-110316-03 3 ng LCS in TCR-842 10 00680 solvent blank EC-11031605 2.5 ng Extracted Curve Point 10 00680 solvent blank GLP1601-01-15-001 DAL SS SS Tripl 0 0000 GLP1001-01-15-001 Dup DAL SS SS Tripl 0 0000 Lab Delicate GLP100101-15-001 LMS DAL SS SS Tripl 0 0000 Lab Matrix Spike GLP100101-15083 DAL SS Trip2 0 0000 GLP100101-16083 Dup DAL SS Trip2 0 0000 Lab Duplicate GLP100101-15083 LMS DAL SS Trip2 0 0000 Lab Matrix Spike GLP100101-15002 DAL SS SS12 0 0000 GLP100101-15002 Dup DAL SS SS12 0 0000 Lab Delicate GLP100101-15002 LMS DAL SS SS12 0 0000 Lab Matrix Spike GLP100101-16003 DAL SS SS12 0 0005 GLP1001-01-15003 Dup DAL SS SS12 0 0005 Lab Delicate GLP100101-16003 LMS DAL SS SS12 0 0005 Lab Matrix Spike GLP100101-16004 DAL SS SS13 0 0000 GLP100101-15-004 Dup DAL SS SS13 0 0000 Lab Duplicate GLP100101-15-004 LMS DAL SS SS13 0 0000 Lab Matrix Spike 10 00680 solvent blank EC-11031606 5 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-005 DAL SS SS16 0 0000 GLP1601-01-16005 Dup DAL SS SS16 0 0000 Lab Delicate GLP10-01-01-15-005 LMS DAL SS SS16 0 0000 Lab Matrix Spike GLP10-01-01-15-006 DAL SS SS16 DB 0000 GLP1Q-01-01-16006 Dup DAL SS SS16 DB 0000 Lab Duplicate GLP1001-01-15-006 LMS DAL SS SS16 DB 0000 L4> Matrix Spike GLP1001-01-15-007 DAL SS SS11 0 0000 GLP1001-01-15-007 Dup DAL SS SS11 0 0000 Lab Delicate GLP1001-01-16007 LMS DAL SS SS11 0 0000 Lab Matrix Spike GLP1001-01-15-008 DAL SS SS11 0 0005 GLP1001-01-15-008 Dup DAL SS SS11 0 0005 Lab Duplicate GLP1001-01-16008 LMS DAL SS SS11 0 0005 Lab Matrix Spike GLP1001-01-15-009 DAL SS SS20 0 0000 GLP10-01-01-15-009 Dup DAL SS SS20 0 0000 Lab Delicate GLP10-01-01-15-009 LMS DAL SS SS20 0 0000 Lab Matrix Spike 10 00680 solvent blank EC-11031607 10 ng Extracted Curve Point 10 00680 solvent blank GLP1601-01-16010 DAL SS SS20 DB 0000 GLP10-01-01-15-010 Dup DAL SS SS20 DB 0000 Lab Duplicate GLP1601-01-15-010 LMS DAL SS SS20 DB 0000 Lab Matrix Spike GLP10-01-01-15-011 DAL SS SS19 0 0000 GLP10-01-01-15-011 Dup DAL SS SS19 0 0000 Lab Delicate GLP1601-01-15-011 LMS DAL SS SS19 0 0000 Lab Matrix Spike GLP1601-01-15-012 DAL SS SS19 0 0005 GLP1601-01-15012 Dup DAL SS SS19 0 0005 Lab Duplicate GLP100101-15012 LMS DAL SS SS19 0 0005 Lab Matrix Spike GLP100101-15014 DAL SS SS15 0 0000 GLP100101-15014 Dup DAL SS SS15 0 0000 Lab Dedicate GLP100101-15014 LMS DAL SS SS15 0 0000 Lab Matrix Spike GLP100101-16015 DAL SS SS17 0 0000 GLP100101-15015 Dup DAL SS SS17 0 0000 Lab Delicate PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Results Name: sll0317a.rdb Use Record Analyte Concentration (ng/mL) Analyte Retention Time (min) .... Analyte Peal Area (counts; IS Peak Nam< I8 Peak Area (counts) IS Concentration (ng/mL) IS Retention Time (min) Calculated Concentration (ng/mL) Accuracy (%) N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A E 0.00 2.S0 0.00 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A E 0.00 5.00 0.00 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A E 0.00 9.99 0.00 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 7.820 7.839 7.800 7.820 7.897 7.858 7.820 7.820 7.820 7.820 7.820 7.781 7.826 7.800 7.955 7.858 7.820 7.916 7.800 7.839 7.820 7.820 7.820 7.820 7.820 7.820 7.820 7.822 7.816 7.877 7.820 7.955 7.824 7.820 7.820 7.800 7.820 7.820 7.620 7.820 7.820 7.820 7.820 7.820 7.620 7.820 7.820 7.877 7.820 7.916 7.807 7.820 7.820 7.820 7.820 7.820 7.820 7.820 7.820 7.820 7.819 7.800 7.897 7.820 3121 4090 5999 2540 2623 3493 6024 3241 285037 309633 331660 498 250457 580 5413 3541 102684 3753 2430 104320 219327 162006 775390 839290 562640 3029698 84624 101800 323760 144 495533 446 764868 747873 3389954 1013861 731682 3339478 100333 85190 201308 2205209 73558 579183 51189 43151 158447 989 969590 936 43670 43883 183861 40138 40532 151602 145453 144573 673954 34860 42979 173745 39070 34495 MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS 225259 214809 246601 229498 254079 238044 241285 244431 226271 234828 239671 0 240401 173 226926 222550 233673 231241 213315 236825 213448 209557 221473 220881 225391 224844 217361 214537 214628 127 219111 0 225619 224480 233214 237810 225063 215988 221135 230275 223997 206384 221960 223464 243184 227580 234714 335 241966 139 238670 242303 232569 225128 216260 224143 216651 233563 229891 233918 228824 241536 238752 235965 293 293 2.93 2.93 2.93 2.93 293 293 293 293 293 N/A 293 N/A 293 293 293 2.93 2.93 2.93 2.93 293 293 293 293 293 2.93 2.93 2.93 N/A 293 N/A 293 293 2.93 293 293 293 293 293 293 2.93 2.93 293 2.93 293 293 N/A 293 N/A 293 293 293 293 2.93 293 2.93 2.93 2.93 2.93 2.93 293 293 293 7.82 7.84 7.82 7.82 7.82 7.82 7.82 7.82 7.82 7.82 7.82 0.00 7.82 8.09 7.82 7.82 7.82 7.80 7.82 7.84 7.82 7.82 7.82 7.82 7.82 7.82 7.82 7.82 7.82 7.74 7.82 0.00 7.82 7.80 7.80 7.80 7.82 7.82 7.82 7.82 7.80 7.82 7.82 7.82 7.82 7.80 7.82 7.55 7.82 8.03 7.80 7.90 7.82 7.80 7.80 7.82 7.82 7.80 7.82 7.82 7.82 7.80 7.82 7.80 <0 <0 <0 <0 <0 <0 <0 <0 2.98 3.12 3.28 N/A 2.45 N/A <0 <0 0.982 <0 <0 0.984 2.41 1.79 8.45 9.18 6.00 33.1 0.860 1.07 3.59 N/A 5.42 N/A 8.18 8.04 35.8 10.3 7.84 38.1 1.02 0.813 2.10 25.9 0.719 6.23 0.425 0.374 1.56 N/A 9.69 N/A 0.358 0.354 1.84 0.347 0.369 1.56 1.53 1.42 7.06 0.276 0.370 1.66 0.311 0.269 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 97.9 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 108. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 97.0 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A Reeord Modified File Name E s110317awiff s110317awiff s110317a.vviff s110317a.wiff s110317a.wiff s110317a.wiff s110317awiff s110317a.wiff s110317awiff s110317a.wiff s110317a.wiff E s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff s110317awiff s110317awiff E s110317awiff s110317awiff s110317a.wiff s110317a.wiff s110317awiff s110317a.wiff s110317awiff s110317awiff s110317a.wiff E s110317a.wiff E s110317a.wiff E s110317a.wiff s110317a.wiff s110317awiff E s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff n s110317a.wiff s110317a.wiff s110317a.wiff s110317awiff s110317awiff s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff E s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff E 5110317a.wiff s110317a.wiff s110317a.wiff s110317awiff s110317awiff s110317awiff E s110317a.wiff s110317a.wiff s110317a.wiff EE s110317a.wiff s110317a.wiff s110317a.wiff E s110317a.wiff s110317a.wiff s110317a.wiff Printing Date: Tuesday, April 05, 2011 3MStudy^10-01-02-15Printing t Page 4 of 11 Page217of514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Sample Name Sample ID Analyte Pea Name Sample Type 257 s110317a094 258 s110317a095 259 s110317a096 260 s110317a097 261 s110317a098 262 s110317a099 263 s110317a100 264 s110317a101 265 s110317a102 266 s110317a103 267 $110317a104 268 s110317a105 269 s110317a106 270 s110317a107 271 s110317a108 272 s110317a109 273 s110317a110 274 s110317a111 275 - s110317a112 276 s110317a113 277 s110317a114 278 s110317a115 279 s110317a116 280 s110317a117 281 s110317a118 282 s110317a119 283 s110317a120 284 s110317a121 285 s110317a122 286 s110317a123 287 s110317a124 288 s110317a125 289 s110317a126 290 s110317a127 291 s110317a128 292 ;s110317a129 293 s1103l7a130 294 s110317a131 295 s110317a132 296 s110317a133 297 s110317a134 298 s110317a135 299 s110317a136 300 s110317a137 301 s110317a138 302 s110317a139 303 s110317a140 304 s110317a141 305 s110317a142 306 s110317a143 307 s110317a144 308 s110317a145 309 s110317a146 310 s110317a147 311 S110317a148 312 s110317a149 313 s110317a150 314 s110317a151 315- s110317a1S2 316 s110317a153 317 s110317a154 318 s110317a155 319 s110317a156 320 s110317a157 GLP10-01-01-15-015 LMS DAL SS SS17 0 0000 Lab Matrix Spike 10 006-80 solvent blank EC-110316-05 2.5 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-016 DAL SS SS14 0 0000 GLP10-01-01-15016 Dup DAL SS SS14 0 0000 Lab Delicate GLP100101-15016 LMS DAL SS SS14 0 0000 Lab Matrix Spike GLP100101-15018 DAL SS SS18 0 0000 GLP100101-15018 Dup DAL SS SS18 0 0000 Lab Delicate GLP100101-15-018 LMS DAL SS SS18 0 0000 Lab Matrix Spike GLP100101-15-020 DAL SS SS10 0 0000 GLP100101-15-020 Dup DAL SS SS10 0 0000 Lab Delicate GLP100101-15020 LMS DAL SS SS10 0 0000 Lab Matrix Spike GLP100101-15021 DAL SS SS30 0 0000 GLP10O1O1-15-G21 Dup DAL SS SS30 0 0000 Lab Delicate GLP100101-15-021 LMS DAL SS SS30 0 0000 Lab Matrix Spike GLP100101-15022 DAL SS SS30 0 0005 GLP100101-15022 Dup DAL SS SS30 0 0005 Lab Delicate GLP100101-15022 LMS DAL SS SS30 0 0005 Lab Matrix Spike 10 006-80 solvent blank EC-110316-06 5 ng Extracted Curve Pant 10 006-80 solvent blank GLP1001-01-15023 DAL SS SS30 0 0015 GLP100101-15023 Dup DAL SS SS30 0 0015 Lab Delicate GLP100101-15-023 LMS DAL SS SS30 0 0015 Lab Matrix Spike GLP10O1O1-15-Q24 DAL SS SS25 0 0000 GLP10O1O1-15-Q24 Dup DAL SS SS25 0 0000 Lab Di^icate GLP100101-15024 LMS DAL SS SS25 0 0000 Lab Matrix Spike GLP1OO1-01-15-Q25 DAL SS SS25 0 0005 GLP10O1O1-15-Q25 Dup DAL SS SS25 0 0005 Lab Duplicate GLP100101-15025 LMS DAL SS SS25 0 0005 Lab Matrix Spike GLP100101-15-026 DAL SS SS25 0 0015 GLP100101-15026 Dup DAL SS SS25 0 0015 Lab Delicate GLP100101-15026 LMS DAL SS SS25 0 0015 Lab Matrix Spike GLP1001-01-15027 DAL SD SD22 0 0000 GLP1001-01-15027 Dup DAL SD SD22 0 0000 Lab Duplicate GLP100101-15027 LMS DAL SD SD22 0 0000 Lab Matrix Spike 10 00&60 solvent blank EC-11031607 10 ng Extracted Curve Point 10 006-80 solvent blank GLP100101-15028 DAL SD SD22 0 0005 GLP100101-15-028 Dup DAL SD SD22 0 0005 Lab Delicate GLP100101-15028 LMS DAL SD SD22 0 0005 Lab Matrix Spike GLP100101-15029 DAL SD SD22 DB 0005 GLP100101-15-029 Dup DAL SD SD22 DB 0005 Lab Duplicate GLP100101-15029 LMS DAL SD SD22 DB 0005 Lab Matrix Spike GLP100101-15-030 DAL SD SD22 0 0015 GLP100101-15-030 Dup DAL SD SD22 0 0015 Lab Duplicate GLP10-01-01-15-030 LMS DAL SD SD22 0 0015 Lab Matrix Spike GLP1001-01-15031 DALSDSD21 0 0000 GLP10-01-01-15-Q31 Dup DAL SD SD21 0 0000 Lab Delicate GLP100101-15031 LMS DAL SD SD21 0 0000 Lab Matrix Spike GLP100101-15032 DAL SD SD21 0 0005 GLP100101-15032 Dup DAL SD SD21 0 0005 Lab Delicate GLP1001-01-15032 LMS DAL SD SD21 0 0005 Lab Matrix Spike 10 006-80 solvent blank EC-110316-05 2.5 ng Extracted Curve Point 10 00600 solvent blank GLP100101-15033 DAL SD SD21 0 0015 GLP100101-15033 Dup DAL SD SD21 0 0015 Lab Duplicate GLP100101-15-033 LMS DAL SD SD21 0 0015 Lab Matrix Spike GLP100101-15034 DAL SS SS24 0 0000 GLP100101-15034 Dup DAL SS SS24 0 0000 Lab Duplicate GLP100101-15034 LMS DAL SS SS24 0 0000 Lab Matrix Spike PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Use Record Analyte Concentration (ng/mL) IS Peak Nam< Tim . (min) ;A ru 'ooun,s* 13 Peak Area (counts) IS Concentration (ng/mL) IS Retention Time (min) Calculated Concentration (ng/mL) Accuracy <*> N/A E 0.00 2.50 0.00 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A E 0.00 5.00 0.00 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A E 0.00 9.99 0.00 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A E 0.00 2.50 0.00 N/A N/A N/A N/A N/A N/A 7.909 7.800 7.820 7.839 7.916 7.800 7.820 7.820 7.820 7.820 7.820 7.897 7.820 7.897 7.820 7.820 7.820 7.800 7.800 7.839 7.800 7.858 7.800 7.820 7.800 7.820 7.820 7.820 7.820 7.800 7.820 7.800 7.820 7.800 7.820 7.820 7.820 7.781 7.820 7.916 7.839 7.820 7.897 7.820 7.800 7.820 7.820 7.839 7.897 7.820 7.800 7.897 7.800 7.800 7.820 7.839 7.820 7.916 7.820 7.839 7.878 7.800 7.820 7.800 150588 346 245513 210 6288 74385 172499 90006 168665 207284 230142 308416 1046654 49141 50554 156603 22155 22966 144901 122 498963 160 99099 105131 203064 2205994 2999314 10442094 3287261 3213196 11574004 3727412 3757807 11512317 1389996 994597 3770549 412 939561 355 926875 1101733 3259463 1066777 805216 3550084 602934 712281 3129374 628360 829209 3410831 931753 862189 3050997 1196 239678 435 488353 501568 2926889 489921 581682 1059032 MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS MPFBS 219635 150 225245 46 22129 228587 227510 234589 228815 224662 217534 209938 213289 230989 229594 225761 208985 210432 224430 150 222022 162 216207 219424 224925 206470 186287 194446 206342 218305 204575 195813 193411 182828 211906 206557 217025 81 216300 208 202796 208937 213692 222258 207015 197494 194797 203314 213523 215859 216321 209178 187470 165602 178049 127 224862 139 176038 205872 204461 208698 202327 219594 2.93 N/A 2.93 N/A 2.93 2.93 2.93 2.93 2.93 2.93 293 293 293 293 2.93 293 293 293 293 N/A 293 N/A 293 293 2.93 293 293 2.93 293 293 293 293 293 293 2.93 293 293 N/A 293 N/A 293 293 293 293 293 293 293 2.93 293 293 2.93 293 2.93 2.93 2.93 N/A 293 N/A 293 2.93 2.93 293 2.93 293 . 7.82 7.59 7.82 7.97 7.92 7.80 7.80 7.82 7.82 7.80 7.82 7.80 7.82 7.82 7.82 7.82 7.82 7.80 7.82 7.78 7.80 7.90 7.80 7.80 7.80 7.82 7.82 7.82 7.82 7.82 7.82 7.80 7.82 7.82 7.84 7.82 7.82 7.95 7.84 7.86 7.90 7.82 7.82 7.82 7.82 7.80 7.80 7.80 7.80 7.90 7.88 7.90 7.80 7.90 7.90 7.94 7.82 8.22 7.88 7.82 7.80 7.80 7.82 7.88 1.58 N/A 2.57 N/A 0.604 0.705 1.76 0.846 1.71 2.16 2.49 3.49 11.9 0.431 0.449 1.60 0.171 0.179 1.48 N/A 5.39 N/A 1.03 1.08 2.11 26.2 39.7 138. 39.3 36.2 146. 47.1 48.1 164. 16.0 11.7 42.9 N/A 10.5 N/A 11.1 12.8 37.6 11.6 9.40 44.4 7.46 8.46 36.1 7.01 9.27 40.2 12.1 11.3 4Z2 N/A 2.51 N/A 6.67 5.85 35.2 5.63 6.92 11.7 N/A N/A 103. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 108. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 105. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 100. N/A N/A N/A N/A N/A N/A N/A Record Modified File Name E s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff nEE s110317a.wiff $110317awiff s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff $110317a.wiff E s110317awiff $110317awiff s110317awiff s110317a.wif EE $110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff s110317awiff s110317a.wiff s110317a.wiff s110317awiff E s110317awiff $110317awiff s110317awiff n s110317a.wiff s110317a.wiff $110317a.wiff s110317awiff s110317a.wjff s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff n s110317awiff s110317a.wiff s110317awiff s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff a s110317awiff s110317awiff n s110317awiff s110317awiff n s110317a.wiff s110317a.wiff s110317awiff s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff a s110317awiff s110317a.wiff s110317awiff s110317awiff s110317a.wiff s110317awiff Printing Date: Tuesday, April 05, 2011 Printing T3MStUdy: GLR10-01-02-15 Page 5 of 11 Page 218 of 514 33 *Stan V1660305 *3M Environmental Lab Sample Name S.m ptelO I ' I . ' i l"-: 321 s110317a158 GLP1001-01-15-035 DAL SS SS24 0 0005 PFBS 322 s110317a159 6LP 1 M 1-0M 5-035 Dup DAL SS SS24 0 0005 Lab Duplicate PFBS 323 s110317a160 GLP10-01-01-15-035 LMS DAL SS SS24 0 0005 Lab Matrix Spike PFBS 324 s110317a161 10 006-80 solvent blank PFBS 325 s110317a162 EC-110316-06 5 ng Extracted Curve Point PFBS 326 s110317a163 10 00680 solvent blank PFBS 327 s110317a001 10 00680 solvent blank PFHS 328 s110317a002 10 00680 solvent blank PFHS 329 s110317a003 EC-110316-09 50 ng Warm up standard PFHS 330 s110317a004 EC-110316-09 50 ng Warm up standard PFHS 331 s110317a005 10 00680 solvent blank PFHS 332 s110317a006 10 006-80 solvent blank PFHS 333 s110317a007 10 00660 solvent blank PFHS 334 s110317a008 10 00660 solvent blank PFHS 335 s110317a009 10 00660 solvent blank PFHS 336 s110317a010 EC-11031601 0.2 ng Extracted Cuve Point PFHS 337 s110317a011 EC-110316-02 0.5 ng Extracted Curve Point PFHS 338 s110317a012 EC-11031603 0.75 ng Extracted Curve Point PFHS 339 s110317a013 EC-110316-04 1 ng Extracted Curve Pant PFHS 340 s110317a014 EC-110316-05 2.5 ng Extracted Cuve Point PFHS s110317a015 EC-110316-06 5 ng Extracted Curve Point PFHS s110317a016 EC-110316-07 10 ng Extracted Curve Point PFHS 343 s110317a017 EC-110316-08 25 ng Extracted Curve Point PFHS 344 S110317a016 EC-11031609 50 ng Extracted Cun Point PFHS 345 s110317a019 EC-11031610 100 ng Extracted Cune Point PFHS 346 s110317a020 EC-11031611 200 ng Extracted Cun Point PFHS 347 s110317a021 EC-11031612 500 ng Extracted Curve Point PFHS 348 s110317a022 10 00660 solvent blank PFHS 349 s110317a023 10 00660 solvent blank PFHS 350 s110317a024 10 00660 solvent blank PFHS 351 s110317a025 10 00680 solvent blank PFHS 352 s110317a026 MB-110316-01 Method Blaik w/o IS PFHS 353 s110317a027 MB-11031602 Method Blaik w/o IS PFHS 354 s110317a028 MB-110316-03 Method Blank w/o IS PFHS 355 s110317a029 356 s110317a030 MB-110316-04 Method Blank w/ 1S MB-110316-05 Method Blank w11S PFHS PFHS 357 s110317a031 M6110316-06 Method B laik w/ IS PFHS 358 s110317a032 M6110316-07 Method B laik w/ IS for dilutions PFHS 359 s110317a033 360 s110317a034 MB-110316-08 Method B laik w/ IS tor dlutions M 6 1 1031609 Method Blank w11S for dilutions PFHS PFHS 361 s110317a035 MB-11031610 Method Blaik w/ IS for dilutions PFHS 362 s110317a036 MB-11031611 Method Blank w/ IS for dilutions PFHS 363 s110317a037 MB-11031612 Method 8 laik w/ IS for dilutions PFHS 364 s110317a038 LCS-11031601 3 ng LCS in TCR-842 PFHS 365 s110317a039 LCS-11031602 3 ng LCS in TCR-842 PFHS 366 s110317a040 LCS-11031603 3 ng LCS in TCR-842 PFHS 367 s110317a041 10 00660 solvent blank PFHS 368 s110317a042 EC-11031605 2.5 ng Extracted Cuve Point PFHS 369 s110317a043 10 00660 solvent blank PFHS 370 s110317a044 GLP10-01-01-15-001 DAL SS SS Tripl 0 0000 PFHS 371 s110317a045 GLP1601-01-15-001 Dup DAL SS SS Tripl 0 0000 Lab Duplicate PFHS 372 s110317a046 GLP10-01-01-15-001 LMS DAL SS SS Tripl 0 0000 lab Matrix Spike PFHS 373 s110317a047 GLP1601-01-16083 DAL SS Trip2 0 0000 PFHS 374 s110317a048 GLP10-01-01-16083 Dup DAL SS Trip2 0 0000 Lab Duplicate PFHS 375 s110317a049 GLP10-01-01-15-083 LMS DAL SS Trip2 0 0000 Lab Matrix Spike PFHS 376 s110317a050 GLP10-01-01-15-002 DAL SS SS12 0 0000 PFHS 377 s110317a051 GLP10-01-01-15-002 Dup DAL SS SS12 0 0000 Lab Delicate PFHS 378 s110317a052 GLP10-01-01-1S-002 LMS DAL SS SS12 0 0000 la b Matrix Spike PFHS 379 s110317a053 GLP10-01-01-15-003 DAL SS SS12 0 0005 PFHS 380 s110317a054 GLP10-01-01-15-003 Dup DAL SS SS12 0 0005 Lab Delicate PFHS 381 s110317a055 GLP10-01-01-15-003 LMS DAL SS SS12 0 0005 Lab Matrix Spike PFHS 382 s110317a056 GLP10-01-01-16004 DAL SS SS13 0 0000 PFHS 383 $110317a057 GLP10-01-01-15-004 Dup DAL SS SS13 0 0000 Lab Duplicate PFHS 384 s110317a058 GLP1601-01-16004 LMS DAL SS SS13 0 0000 Lab Matrix Spike PFHS l ! | 1 Unknown Unknown Unknown Double Blank Quality Control Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown II ^ i E EEEEEEEEEEEE E Results Name: sll0317a.rdb IIe-- . : " ^ <n'mL>! (ng/mL| Analyte Retention Time (min) Analyte Peal Area (county IS Peak Nam IS Peak Area (counts) IS Concentration (ng/mL) Re_litme_n_etionConce,ntra. tio.n. (min) N/A 7.877 1669905 MPFBS 209179 2.93 7.90 19.5 N/A 7.820 1493861 MPFBS 186357 2.93 7.88 19.6 N/A 7.878 3367996 MPFBS 168889 2.93 7.88 44.1 0.00 7.820 157 MPFBS 139 N/A 7.90 N/A 5.00 7.877 489940 MPFBS 211149 Z93 7.86 5.57 0.00 7.839 34 MPFBS 35 N/A 7.88 N/A 0.00 10.227 766 MPFHxS 207 N/A 10.2 N/A O.X 10.362 48 MPFHxS 35 N/A 10.3 N/A 0.00 10.343 336X30 MPFHxS 128764 N/A 10.3 N/A O.X 10.362 3456067 MPFHxS 130146 N/A 10.4 N/A O.X 10.401 1321 MPFHxS 185 N/A 10.4 N/A O.X 10.420 364 MPFHxS 69 N/A 10.4 N/A O.X 10.304 141 MPFHxS 23 N/A 10.3 N/A O.X 10.381 385 MPFHxS 23 N/A 10.3 N/A O.X 0.199 10.266 10.324 220 15333 MPFHxS MPFHxS 173 136120 N/A 2.64 10.5 N/A 10.3 0.198 0.499 10.343 34659 MPFHxS 143102 2.84 10.3 0.444 0.748 10.324 57374 MPFHxS 135842 2.84 10.3 0.781 0.997 10.304 77033 MPFHxS 143561 2.84 10.3 0.997 2.49 10.285 182644 MPFHxS 140288 2.84 10.3 2.44 4 .X 10.304 382961 MPFHxS 141363 2.84 10.3 5.10 9.97 10.324 745X9 MPFHxS 141104 2.84 10.3 9.97 24.9 10.285 19718X MPFHxS 141096 2.84 10.3 26.5 49.9 10.285 3724702 MPFHxS 136307 2.84 10.3 5Z2 X .7 10.285 6862985 MPFHxS 137565 2.84 10.3 96.5 1X. 10.285 12075625 MPFHxS 122113 2.84 10.3 197. 499. 10.285 24138669 MPFHxS 105150 2.84 10.3 500. O.X 10.285 6099 MPFHxS 69 N/A 10.1 N/A O.X 10.420 1033 MPFHxS 208 N/A 10.3 N/A O.X 10.304 548 MPFHxS 35 O.X 10.266 235 MPFHxS 116 O.X 10.381 115 MPFHxS 68 N/A 10.3 N/A N/A 10.3 N/A N/A 10.6 N/A O.X 10.324 282 MPFHxS 219 N/A 10.6 N/A O.X 10.343 821 MPFHxS 139 N/A 10.2 N/A <0N/A 10.304 1108 MPFHxS 129528 2.84 10.3 0.00135 N/A 10.208 837 MPFHxS 136163 2.84 10.3 <0N/A 10.266 1655 MPFHxS 125636 2.64 10.3 0.0100 N/A 10.266 437 MPFHxS 156085 2.64 10.3 N/A 10.285 1458 MPFHxS 142922 2.64 10.3 0.00445 <0N/A 10.343 1062 MPFHxS 151479 2.64 10.2 <0N/A 10.285 1015 MPFHxS 142122 2.84 10.3 <0N/A 10.266 10X MPFHxS 148286 2.84 10.3 <0N/A 10.266 1046 MPFHxS 145592 2.84 10.2 N/A 10.266 230455 MPFHxS 134976 2.84 10.3 3.21 N/A 10.247 256423 MPFHxS 140931 2.84 10.2 3.42 N/A 10.266 257782 MPFHxS 145967 2.84 10.2 3.32 O.X 10.247 X MPFHxS 243 N/A 10.5 N/A 2.49 10.266 191996 MPFHxS 143937 2.84 10.3 2.50 O.X 10.324 152 MPFHxS 289 N/A 10.4 N/A N/A 10.343 2468 MPFHxS 143818 2.84 10.2 0.0176 N/A 10.362 3170 MPFHxS 139615 2.84 10.2 0.0280 N/A 10.247 76145 MPFHxS 144504 2.84 10.2 0.978 N/A 10.208 2568 MPFHxS 150982 2.84 10.2 0.0173 N/A 10.343 2412 MPFHxS 144427 2.84 10.2 0.0167 N/A 10.247 80636 MPFHxS 149441 Z84 10.2 1.00 N/A 10.247 1904593 MPFHxS 131514 2.84 10.2 27.5 N/A 10.247 1372161 MPFHxS 121549 2.64 10.2 21.4 N/A 10.247 82X372 MPFHxS 128612 Z84 10.2 126. N/A 10.247 16444782 MPFHxS 108518 Z84 10.2 312. N/A 10.247 14777567 MPFHxS 113739 Z84 10.2 264. N/A 10.247 33493704 MPFHxS 85467 2.64 10.2 1020. N/A 10.247 142231 MPFHxS 125142 Z84 10.2 2.13 N/A 10.247 198762 MPFHxS 131316 2.84 10,2 2.64 N/A 10.247 492752 MPFHxS 129609 2.84 10.2 7.16 (%>Accuracy Record Modified File Name !! N/A Q s110317a.wiff N/A s110317a.wiff N/A s110317a.wiff N/A s110317a.wiff 111. S110317a.wifF nN/A s110317a.wiff N/A s110317a.witr EEEEN/A s110317a.witf N/A s110317a.wiff N/A s110317a.wiir N/A s110317a.wiff N/A s110317a.wiff N/A s110317a.wiff N/A s110317a.wiff N/A s110317a.wiff 99.2 s110317a.wiff 89.0 s110317a.wiff 104. s110317a.wiff 100. s1103l7a.wiff 98.0 s110317a.wiff 102. s110317a.wiff 100. s110317a.wiff 106. s110317a.wiff 105. s1103l7a.wiff 96.8 s110317a.wiff 98.9 s110317a.wiff 100. s110317a.wiff N/A s110317a.wiff N/A s110317a.wiff N/A s110317a.witr N/A s110317a.wiff aN/A s110317a.wiff nN/A s110317a.wiff N/A s110317a.wiff EN/A s110317a.wiff N/A s110317a.wiff nnN/A s110317a.wiff N/A s110317a.wiff N/A s110317a.wiff N/A s110317a.wiff N/A s110317a.wiff N/A s110317a.wiff N/A s110317a.wiff EN/A s110317a.wiff EN/A s110317a.wiff EN/A s110317a.wiff N/A s110317a.wiff 100. s110317a.wiff N/A s110317a.wiff N/A s110317a.wiff N/A s110317a.wiff nN/A s110317a.wiff N/A s110317a.wiff EN/A s110317a.wiff N/A 8110317a.wiff EN/A s110317a.wiff EN/A s110317a.wiff EN/A s110317a.wiff EN/A s110317a.wiff N/A s110317a.wiff EEN/A 8110317a.wiff EN/A s110317a.wiff N/A 8110317a.wiff EEN/A s110317a.wiff StudyGLP10-01-02-15t mPrinting Date: Tuesday, April 05, 2011 Printing Page 6 of 11 Page219of514 *Stan V1660305 *3M Environmental Lab .. ! .. " Sample Name j "! -- Sample ID . :: - - 385 s110317a059 386 s i 10317a060 387 s110317a061 388 s110317a062 389 s110317a063 390 s110317aO64 391 s110317a065 392 s110317a066 393 s110317a067 394 s110317a068 39S s110317a069 396 s110317a070 397 s110317a071 398-- s110317a072 399 s110317a073 400 s110317a074 401 s110317a075 402 s110317a076 403 s110317a077 404 s110317a078 405 S110317a079 406 s110317a080 407 s110317a081 408 s110317a082 409 s110317a083 410 s110317a084 411 s110317a085 412 s110317a086 413 s110317a087 414 $110317a088 415 s110317a089 416 s110317a090 417 s110317a091 418 s110317a092 419 s110317a093 420 s110317a094 421 s110317a095 422 s110317a096 423 s110317a097 424 s110317a098 425 s110317a099 426 s110317a100 427 s110317a101 428 s110317a102 429 s110317a103 430 s110317a104 431 s110317a105 432 s110317a106 433 s110317a107 434 s110317a108 435 S110317a109 436 s110317a110 437 s110317a111 438 s110317a112 439 s110317a113 440 s110317a114 441 s110317a115 442 s110317a116 443 s110317a117 444: $110317a118 445 s110317a119 446 s110317a120 447 s110317a121 448 s110317a122 j] 10 00660 solvent blank EC-110316-06 5 ng Extracted Curve Point 10 00660 solvent blank GLP10-01-01-15-005 DAL SS SS16 0 0000 GLP10-01-01-15-005 Dup DAL SS SS16 0 0000 Lab Delicate GLP10-01-01-15-005 LMS DAL SS SS16 0 0000 Lab Matrix Spike GLP10-01-01-15-006 DAL SS SS16 DB 0000 GLP10-01-01-16006 Dup DAL SS SS16 DB 0000 Lab Duplicate GLP1WJ1-01-15-006 LMS DAL SS SS16 DB 0000 Lab Matrix Spike GLP10-01-01-15-007 DAL SS SS11 0 0000 GLP10-01-01-15-007 Dup DAL SS SS11 0 0000 Lab D ic a le GLP10-01-01-15-007 LMS DAL SS SS11 0 0000 Lab Matrix Spike GLP10-01-01-15-008 DAL SS SS11 0 0005 GLP10-01-01-15-008 Dup DAL SS SS11 0 0005 Lab Duplicate GLP10-01-01-15-008 LMS DAL SS SS11 0 0005 Lab Matrix Spike GLP10-01-01-15-009 DAL SS SS20 0 0000 GLP10-01-01-15-009 Dup DAL SS SS20 0 0000 Lab Delicate GLP1001-01-15-009 LMS DAL SS SS20 0 0000 Lab Matrix Spike 10 00660 solvent blank EC-110316-07 10 ng Extracted Cune Point 10 00660 solvent blank GLP10-01-01-16010 DAL SS SS20 DB 0000 GLP1001-01-15-010 Dup DAL SS SS20 DB 0000 Lab Duplicate GLP10-01-01-15-010 LMS DAL SS SS20 DB 0000 Lab Matrix Spike GLP10O1-01-16011 DAL SS SS19 0 0000 GLP1601-01-15-011 Dup DAL SS SS19 0 0000 Lab Duplicate GLP10-01-01-15-011 LMS DAL SS SS19 0 0000 Lab Matrix Spike GLP10-01-01-15-012 DAL SS SS19 0 0005 GLP10-01-01-15-012 Dup DAL SS SS19 0 0005 Lab Duplicate GLP10-01-01-16012 LMS DAL SS SS19 0 0005 Lab Matrix Spike GLP10-01-01-16014 DAL SS SS15 0 0000 GLP10-01-01-15-014 Dup DAL SS SS15 0 0000 Lab Delicate GLP10-01-01-15-014 LMS DAL SS SS15 0 0000 Lab Matrix Spike GLP10-01-01-15-01S DAL SS SS17 0 0000 GLP1661-01-16015 Dup DAL SS SS17 0 0000 Lab Delicate GLP10-01-01-16015 LMS DAL SS SS17 0 0000 Lab Matrix Spike 10 00660 solvent blank EC-110316-05 2.5 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-016 DAL SS SS14 0 0000 GLP10-01-01-15-016 Dup DAL SS SS14 0 0000 Lab Delicate GLP1601-01-16016 LMS DAL SS SS14 0 0000 Lab Matrix Spike GLP10-01-01-15-018 DAL SS SS18 0 0000 GLP10-01-01-15-018 Dup DAL SS SS18 0 0000 Lab Duplicate GLP10-01-01-15-018 LMS DAL SS SS16 0 0000 Lab Matrix Spike GLP10-01-01-16020 DAL SS SS10 0 0000 GLP10-01-01-1S-Q20 Dup DAL SS SS10 0 0000 Lab Delicate GLP10-01-01-15-C20 LMS DAL SS SS10 0 0000 Lab Matrix Spike GLP10-01-01-15-021 DAL SS SS30 0 0000 GLP10-01-01-15-Q21 Dup DAL SS SS30 0 0000 Lab Duplicate GLP10-01-01-15-021 LMS DAL SS SS30 0 0000 Lab Matrix Spike GLP10-01-01-15-022 DAL SS SS30 0 0005 GLP10-01-01-16022 Dup DAL SS SS30 0 0005 Lab Delicate GLP10-01-01-15-022 LMS DAL SS SS30 0 0005 Lab Matrix Spike 10 00680 solvent blank EC-110316-06 5 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-023 DAL SS SS30 0 0015 GLP10-01-01-15-023 Dup DAL SS SS30 0 0015 Lab Duplicate GLP10-01-01-15-023 LMS DAL SS SS30 0 0015 Lab Matrix Spike GLP1Q-01-01-15-024 DAL SS SS25 0 0000 GLP10-01-01-15-024 Dup DAL SS SS25 0 0000 Lab Duplicate GLP10-01-01-15-024 LMS DAL SS SS25 0 0000 Lab Matrix Spike GLP10-01-01-15-025 DAL SS SS25 0 0005 Analyte Pea Mame Sample Type PFKS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control iDouble Blank [Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Results Name: sl!03l7a.rdb Use Record Analyte Concentration (ng/mL) . .. Analyte Retention Urne (min) Analyte Peal Area (countsj iS Peak Nairn 18 Peak Area (counts) - -| Concentration ' - ! . E 0.00 4.99 0.00 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A E 0.00 9.97 0.00 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A E 0.00 2.49 0.00 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A E 0.00 4.99 O.X N/A N/A N/A N/A N/A N/A N/A 10.343 10.227 10.381 10.227 10.227 10.227 10.227 10.227 10.247 10.227 10.227 10.247 10.247 10.247 10.247 10.247 10.227 10.247 10.420 10.266 10.343 10.247 10.266 10.285 10.247 10.247 10.247 10.247 10.266 10.266 10.266 10.266 10.247 10.266 10.247 10.266 10.285 10.266 10.401 10.381 10.247 10.266 10.266 10.266 10.247 10.247 10.266 10.266 10.266 10.266 10.266 10.247 10.247 10.247 10.381 10.247 10.266 10.247 10.266 10.266 10.247 10.266 10.266 10.266 1004 387025 462 560803 546921 2521185 585369 543649 2518S74 60252 97467 467118 32554644 521566 2252606 262981 253011 668839 383 736254 318 242769 249807 807309 280644 228270 587113 1149743 1242999 3012011 169791 432621 824587 212093 211835 601556 925 191482 319 34831 457554 2223434 305185 228973 2285984 1449163 2340517 10772788 224706 218406 594459 56630 56241 156169 155 408355 456 402871 590468 2301897 24421206 35159264 53514646 28249434 MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS 35 133177 220 137789 138513 136715 139833 132663 129902 135409 138610 139730 98468 133867 135020 136143 144313 143798 104 139208 46 145564 137008 142217 135224 132975 137281 138273 134866 137495 145834 143662 137686 152160 140868 140596 138 151306 93 13276 140200 138556 141373 144587 136096 138702 123600 123332 131974 139430 138763 134420 133692 144281 161 139003 139 136431 134361 135846 97360 76916 80106 99588 N/A 2.84 N/A 2.84 2.84 2.84 2.84 2.84 2.84 2.84 2.64 2.84 2.84 2.84 2.84 2.84 2.64 284 N/A 2.84 N/A 2.84 2.84 284 284 284 284 2.84 284 284 284 264 284 284 284 2.84 N/A 2.84 N/A 284 284 284 2.84 284 2.84 2.84 2.84 284 284 284 284 284 284 284 N/A 284 N/A 284 284 284 2.84 284 2.84 284 li 10.1 10.2 10.1 10.2 10.2 10.2 10.2 10.2 10.2 10.2 10.2 10.2 10.2 10.2 10.2 10.2 10.2 10.2 10.2 10.3 10.4 10.2 10.3 10.3 10.2 10.2 10.3 10.2 10.2 10.3 10.3 10.2 10.2 10.3 10.2 10.2 10.3 10.3 10.3 10.4 10.2 10.2 10.3 10.3 10.2 10.2 10.2 10.2 10.3 10.3 10.3 10.3 10.3 10.2 10.4 10.2 10.3 10.2 10.3 10.2 10.3 10.2 10.3 10.2 [N/A [5.47 N/A 7.67 7.44 35.1 7.89 7.71 36.9 1.10 1.31 6.30 794. 7.34 31.7 3.63 3.29 8.77 N/A 9.98 N/A 3.13 3.42 10.7 3.90 3.22 8.06 15.7 17.4 41.7 2.18 5.67 11.3 2.61 2.82 8.07 N/A 2.37 N/A 4.94 6.15 30.5 4.06 2.97 31.9 19.8 36.0 173. 3.20 2.94 8.07 0.807 0.778 2.03 N/A 5.53 N/A 5.56 8.28 32.2 557. 1370. No Intercept 649. . j. . 1 !N/A 110. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 100. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 95.2 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 111. N/A N/A N/A N/A N/A N/A N/A N/A Record Modified File Name ij Q ft EEEEEEEEEEEEEEE EEEEEEEEEEEEEEE EEEEEEEEEEEEEEE EEEEEEE js110317a.wiff |s110317awiff s110317a.will s110317awiff s110317awiff s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff s110317awiff s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff s110317awiff s110317a.wiff s110317a.wiff s110317awiff s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff s110317awiff s110317a.wtff s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff s110317awiff s110317a.wiff s110317awiff s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff s110317awiff s110317awiff s110317awiff s110317a.wiff s110317awiff s110317awiff s110317a.wiff s110317a.wiff s110317a.wiff S110317a.wiff s110317awiff s110317a,wiff s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff s110317awifl s110317awiff s110317a.wiff s110317awiff s110317a.wiff s110317a.wiff s110317a.wiff Printing Date: Tuesday, April 05, 2011 Printing e^ dy GLP10-Q1-02-15 Page 7 of 11 Page 220 of 514 *Stan V1660305 *3M Environmental Lab Sample Name Sample ID Results Name: sll0317a.rdb Analyte Peai Name Sample Type Use Record - I Analyte I Concentration j (ng/mL) j Analyte Retention Time (min) Analyte Peak Area (counts) IS Peak Nam< IS Peak Area (counts) IS Concentration (ngtmL) j is i! Ac^ " cy' Calmilatad I Conoentiation j (no/mL, ! <*> Record Modified File Name 449 s110317a123 450 s110317a124 451 s110317a125 452 s110317a126 453 s110317a127 454 s110317a128 455 s110317a129 456 s110317a130 457 s110317a131 456 s110317a132 459 s110317a133 460 s110317a134 461 s110317a135 462 s110317a136 463` s110317a137 464 s110317a138 465 s110317a139 466 s110317a140 467 s110317a141 468 s110317a142 469 s110317a143 47 s110317a144 471 s110317a145 472 s110317a146 473 s110317a147 474 s110317a148 475 s110317a149 476. s110317a150 477 s110317a151 478 s110317a152 479 s110317a153 480 L s110317a154 481' s110317a155 482 s110317a156 483 s110317a157 484 s110317a158 485 s110317a159 486-- s110317a160 487 s110317a161 488 s110317a162 489 ' s110317a163 490 s110317a001 491 s110317a002 492 s1103l7a003 493 s110317a004 494 s110317a005 495 s110317a006 496 s110317a007 497 $110317a008 498 s110317a009 499 s110317a010 500 s110317a011 501 s110317a012 502 s110317a013 503 s110317a014 504 s110317a015 505 - s1103l7a016 506 s110317a017 507 : s110317a018 508 s110317a019 509 s110317a020 510 s110317a021 511 s110317a022 512 s110317a023 IGLP10-01-01-15-025 Dup DAL SS SS2S 0 0005 Lab Delicate GLP10-01-01-15-025 LMS DAL SS SS25 0 0005 Lab Matrix Spike GLP10-01-01-15-026 DAL SS SS25 0 0015 GLP10-01-01-15-026 Dup DAL SS SS25 0 0015 Lab Duplicate GLP10-01-01-15-026 LMS DAL SS SS25 0 0015 Lab Matrix Spike GLP10-O1-O1-15-O27 DAL SD SD22 0 0000 GLP10-01-01-15-Q27 Dup DAL SD SD22 0 0000 Lab Delicate GLP1001-01-15-027 LMS DAL SD SD22 0 0000 Lab Matrix Spike 10 006-80 solvent blank EC-110316-07 10 ng Extracted Curve Point 10 006-80 sotveni blank GLP10-01-01-15-028 DAL SD SD22 0 0005 GLP10-01-01-15-Q28 Dup DAL SD SD22 0 0005 Lab Duplicate GLP10-01-01-15-028 LMS DAL SD SD22 0 0005 Lab Matrix Spike GLP10-01-01-15-Q29 DAL SD SD22 DB 0005 GLP10-01-01-15-029 Dup DAL SD SD22 DB 0005 Lab Duplicate GLP10-01-01-15-G29 LMS DAL SD SD22 DB 0005 Ls* Matrix Spike GLP10-01-01-15-030 DAL SD SD22 0 0015 GLP10-01-01-15-030 Dup DAL SD SD22 0 0015 Lab Delicate GLP10-01-01-15-030 LMS DAL SD SD22 0 0015 Lab Matrix Spike GLP10-01-01-15-031 DAL SD SD21 0 0000 GLP10-01-01-15-031 Dup DAL SD SD21 0 0000 Lab Delicate GLP10-01-01-15-031 LMS DAL SD SD21 0 0000 Lab Matrix Spike GLP10-01-01-15-032 DAL SD SD21 0 0005 GLP10-01-01-15-032 Dup DAL SD SD21 0 0005 Lab Delicate GLP10-01-01-15-032 LMS DAL SD SD21 0 0005 Lab Matrix Spike 10 00S-80 solvent blank EC-110316-05 2.5 ng Extracted Cune Point 10 006-80 solvent blank GLP10-01-01-15-033 DAL SD SD21 0 0015 GLP10-01-01-15-033 Dup DAL SD SD21 0 0015 Lab Dt^icate GLP10-01-01-15-033 LMS DAL SD SD21 0 0015 Lab Matrix Spike GLP10-01-01-15-C34 DAL SS SS24 0 0000 GLP10-01-01-15-C34 Dup DAL SS SS24 0 0000 Lab Duplicate GLP10-01-01-15034 LMS DAL SS SS24 0 0000 Lab Matrix Spike GLP10-01-01-15-035 DAL SS SS24 0 0005 GLP1001-01-15-035 Dup DAL SS SS24 0 0005 Lab Duplicate GLP1001-01-15-035 LMS DAL SS SS24 0 0005 Lab Matrix Spike 10 006-80 solvent blank EC-110316-06 5 ng Extracted Cune Point 10 006-80 solvent blank 10 006-80 solvent blank 10 00&80 solvent blank EC-110316-09 50 ng Warm up standard EC-110316-09 50 ng Warm up standard 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank 10 006-80 solvent blank EC-110316-01 0.2 ng Extracted Ctxve Point EC-110316-02 0.5 ng Extracted Curve Point EC-110316-03 0.75 ng Extracted Cune Point EC-110316-04 1 ng Extracted Curve Point EC-110316-05 2.5 ng Extracted Curve Point EC-110316-06 5 ng Extracted Curve Pant EC-110316-07 10 ng Extracted Curve Point EC-110316-08 25 ng Extracted Curve Point EC-110316-09 50 ng Extracted Cune Point EC-110316-10 100 ng Extracted Curve Point EC-110316-11 200 ng Extracted Curve Point EC-110316-12 500 ng Extracted Curve Point 10 006-80 solvent blank 10 006-80 solvent blank PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS Unknown IUnknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Double Blank Double Blank N/A N/A N/A N/A N/A N/A N/A N/A E 0.00 9.97 0.00 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A E 0.00 2.49 0.00 N/A N/A N/A N/A N/A N/A N/A N/A N/A E 0.00 4.99 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 EEEEEEEEEEEE 0.00 0.200 0.500 0.749 0.999 2.50 5.00 9.99 25.0 50.0 99.9 200. 500. O.X 0.00 10.247 10.247 10.247 10.266 10.266 10.285 10.266 10.247 10.285 10.285 10.324 10.266 10.266 10.266 10.266 10.266 10.266 10.266 10.266 10.266 10.247 10.266 10.266 10.266 10.247 10.266 10.285 10.266 10.227 10.266 10.266 10.266 10.266 10.285 10.247 10.285 10.285 10.285 10.285 10.266 10.381 13.136 13.059 13.213 13.155 13.251 13.136 13.078 12.924 13.020 13.174 13.155 13.097 13.155 13.116 13.097 13.097 13.116 13.116 13.155 13.136 13.097 13.174 13.097 28607541 57573824 20703529 20290843 37914749 12106411 9842082 25471521 8265 725943 1564 5855473 7345156 11982630 8021351 5724186 14438065 3862271 3893076 9930030 6492789 8680007 22625842 9915334 8853162 20712464 6319 195076 1135 4063624 4107638 10860552 3174500 4716013 10146994 8863425 7813208 18735143 6615 384719 731 1023 19 1867886 1948476 1253 407 363 392 349 14S16 22802 38562 46364 116861 240934 473799 1184003 2165014 3753934 6695919 12126067 6010 2894 MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS MPFHxS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M6PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS 101349 78964 107360 108419 86428 109114 119804 108463 335 13834S 254 117768 123331 116692 120881 121088 112270 121953 121052 122249 126589 138118 121327 111950 109212 93926 81 131770 218 112648 124721 118390 121873 119558 122058 120846 121193 106475 23 136838 35 0 0 71041 74578 92 35 104 23 81 86821 84743 86392 83869 83249 86137 87976 84600 80137 73465 62446 50366 69 0 2.84 2.84 2.84 2.84 2.64 2.84 284 2.64 N/A 284 N/A 284 284 264 284 284 264 284 264 264 264 264 284 264 264 264 N/A 284 N/A 264 264 284 284 264 264 284 264 284 N/A 284 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 287 287 287 287 287 287 287 287 287 287 287 287 N/A N/A 10.2 644. N/A Sg s110317a.wiff 10.2 iNo Intercept N/A 10.2 409. N/A 10.2 395. N/A 10.2 1250. N/A 10.3 222. N/A 10.3 162. N/A 10.2 514. N/A j EEEEEEE s1l0317awiff s1l0317awiff s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff s il 0 3 1 7 a w iff 10.4 N/A 10.3 9.90 EN/A s110317awiff 99.3 s110317awiff 10.4 N/A 10.3 96.2 10.2 116. 10.3 205. 10.3 130. 10.3 91.3 10.3 261. 10.3 60.7 10.2 61.6 10.3 160. 10.2 99.3 10.2 122. 10.3 393. 10.3 175. 10.3 160. 10.3 477. N/A s110317a.wiff EN/A s110317a.wifT EN/A s1l0317a.wiff EN/A s1l0317a.wiff EN/A s110317awiff N/A s110317a.wiff EN/A s110317awiff EEN/A s110317a.wiff N/A s110317awi!f EN/A s110317a.wiff EEN/A s110317a.wff N/A s110317a.wiff EN/A s110317a.wiff EN/A s110317a.wiff EEN/A s110317awiff EN/A s110317awiff 10.3 N/A 10.3 2.78 10.3 N/A 10.3 69.3 10.3 63.1 10.3 182. 10.2 49.7 10.3 75.9 10.2 164. 10.4 144. 10.3 126. 10.3 368. N/A s1l0317a.wiff 112 s1i0317a.wiff N/A s110317a.wiff N/A s110317a.wiff EN/A s110317a.wiff EEN/A s110317awiff EN/A s110317awiff EN/A s1l0317a.wiff EN/A s110317awiff EN/A s110317a.wiff EN/A s1l0317a.wiff EN/A s1l0317a.wiff 10.2 N/A 10.3 5.29 EN/A s1l0317a.wiff 106. s110317a.wiff 10.5 N/A 0.00 N/A 0.00 N/A 13.2 N/A 13.2 N/A 13.1 N/A 13.2 N/A 129 N/A 13.0 N/A 13.1 N/A 13.2 0.241 13.1 0.427 13.1 0.751 13.1 0.945 13.1 2.50 13.1 5.05 N/A s1l0317awiff N/A s110317a.wiff N/A s110317awiff N/A s110317a.wiff N/A s110317a.wiff N/A s110317a.wiff N/A s110317a.wiff N/A s110317a.wiff N/A s110317a.wiff N/A s110317a.wiff 120. s1l0317a.wiff 85.3 s110317a.wiff 100. s110317a.wiff 94.6 s110317a.wiff n100. s110317a.wiff 101. s110317a.wiff 13.1 9.79 13.1 25.7 13.1 49.9 13.1 95.4 13.1 206. 13.1 498. 13.1 N/A 0.00 N/A 96.0 s110317a.wiff 103. s11317awiff 99.7 s110317a.wiff 95.5 s110317a.wiff 103. s110317a.wiff 99.7 s1l0317a.wiff N/A s110317a.wiff N/A s1l0317a.wiff Printing Date: Tuesday, April 05, 2011 Printing T&M StUdy GUPf0-01-02-15 Page 8 of 11 Page 221 of 514 *Stan VT660305 *3M Environmental Lab Results Name: sll0317a.rdb Sample Name 8ample ID Analyte Pea Name Sample Type Use Record Analyte Concentration (ng/mL) IS Peak Norm Tim . (min) i*TM " 'counK* IS Peak Area (counts) IS Concentration (ng/mL) IS Retention Time (min) Calculated Concentration (ng/mL) : Accuracy W Record Modified File Name 513 s110317a024 514 $110317a025 515 s110317a026 516 s110317a027 517 s110317a028 518 s110317a029 519 : s110317a030 520 s110317a031 521 s110317a032 522 s110317a033 523 s110317a034 524 s110317a035 525 s110317a036 526 s110317a037 527 s110317a038 528 s110317a039 529 s110317a040 530 s110317a041 531 s110317a042 532 s110317a043 533 s110317a044 534% s110317a045 535 s110317a046 536 s110317a047 537 s110317a048 538 s110317a049 539 s110317a050 540 s110317a051 541 s110317a052 542 s110317a053 543 s110317a054 544 s110317a05S 545 s110317a056 546 s110317a057 547 s110317a058 548 s110317a059 549 - S1103173060 550 s110317a061 551 s110317a062 552 s110317a063 553 s110317a064 554 s110317a065 555 s110317a066 556 s110317a067 557 s1103173068 556 s110317a069 559 s110317a070 560 s110317a071 561 s110317a072 562 s110317a073 563 s110317a074 564 s110317a075 565 s110317a076 566 s110317a077 567 s110317a078 568 s110317a079 569 s110317a080 570 s110317a081 571 s110317a082 572 s110317a063 573 s110317a084 574 s110317a085 675 s110317a086 576 s110317a087 10 006-80 solvent blank 10 006-80 solvent blank MB-110316-01 Method Blank w/o IS MB-110316-02 Method Bltnk w/o IS MB-110316-03 Method Blank w/o IS MB-110316-04 Method Blank w/ IS MB-110316-05 Method Blank w/ IS MB-110316-06 Method Blank w/ IS MB-110316-07 Method Blank w/ IS for dlutions MB-110316-08 Method Blmk w/ IS for cfilutions MB-110316-09 Method Blank w/ IS for dilutions MB-110316-10 Method Blank w/ IS for dilutions MB-110316-11 Method Blank w/ IS for dilutions MB-110316-12 Method Blvtk w/ IS for dilutions LCS-110316-01 3ngLCS inTCR-842 LCS-110316-02 3 ng LCS in TCR-842 LCS-110316-03 3 ng LCS in TCR-842 10 006-60 solvent blank EC-110316-05 2.5 ng Extracted Curve Point 10 006-80 solvent blank GLP1Q-01-01-1S-001 DAL SS SS Tripl 0 0000 GLP10-01-01-15-001 Dup DAL SS SS Tripl 0 0000 Lab Duplicate GLP10-01-01-15-001 LMS DAL SS SS Tripl 0 0000 Lab Matrix Spike GLP10-01-01-15-083 DAL SS Trip2 0 0000 GLP10-01-01-15-083 Dup DAL SS Trip2 0 0000 Lab Duplicate GLP10-01-01-15-083 LMS DAL SS Trip2 0 0000 Lab Matrix Spike GLP1Q-01-01-15-002 DAL SS SS12 0 0000 GLP10-01-01-15-002 Dup DAL SS SS12 0 0000 Lab Delicate GLP10-01-01-15-002 LMS DAL SS SS12 0 0000 Lab Matrix Spike GLP10-01-01-15-003 DAL SS SS12 0 0005 GLP10-01-01-15-003 Dup DAL SS SS12 0 0005 Lab Delicate GLP10-01-01-15-003 LMS DAL SS SS12 0 0005 Lab Matrix Spike GLP10-01-01-15-004 DAL SS SS13 0 0000 GLP10-01-01-15-004 Dup DAL SS SS13 0 0000 Lab Duplicate GLP10-01-01-15-004 IMS DAL SS SS13 0 0000 Lab Matrix Spike 10 006-60 solvent blank EC-110316-06 5 ng Extracted Cune Point 10 006-80 solvent blank GLP10-01-01-15-005 DAL SS SS16 0 0000 GLP10-01-01-15-005 Dup DAL SS SS16 0 0000 Lab Delicate GLP10-01-01-15-005 LMS DAL SS SS16 0 0000 Lab Matrix Spike GLP1Q-01-01-15-006 DAL SS SS16 DB 0000 GLP10-01-01-15-006 Dup DAL SS SS16 DB 0000 Lab Duplicate GLP10-01-01-15-006 LMS DAL SS SS16 DB 0000 L4> Matrix Spike GLP10-01-01-15-007 DAL SS SS11 0 0000 GLP10-01-01-15-007 Dup DAL SS SS11 0 0000 Lab Delicate GLP10-01-01-15-007 LMS DAL SS SS11 0 0000 Lab Matrix Spike GLP10-01-01-15-008 DAL SS SS11 0 0005 GLP10-01-01-15-008 Dup DAL SS SS11 0 0005 Lab Duplicate GLP10-01-01-15-008 IMS DAL SS SS11 0 0005 Lab Matrix Spike GLP10-01-01-15-009 DAL SS SS20 0 0000 GLP10-01-01-15-009 Dup DAL SS SS20 0 0000 Lab Duplicate GLP10-01-01-15-009 IMS DAL SS SS20 0 0000 Lab Matrix Spike 10 006-80 solvent blank EC-110316-07 10 ng Extracted Curve Point 10 006-60 solvent blank GLP10-01-01-15-010 DAL SS SS20 DB 0000 GLP10-01-01-15-010 Dup DAL SS SS20 DB 0000 Lab Duplicate GLP10-01-01-15-010 IMS DAL SS SS20 DB 0000 L^> Matrix Spike GLP10-01-01-15-011 DAL SS SS19 0 0000 GLP10-01-01-15-011 Dup DAL SS SS19 0 0000 Lab Duplicate GLP10-01-01-15-011 LMS DAL SS SS19 0 0000 Lab Matrix Spike GLP10-01-01-15-012 DAL SS SS19 0 0005 GLP10-01-01-15-012 Dup DAL SS SS19 0 0005 Lab Duplicate PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS Double Blank Double Blank Double Blank Double Blank Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown 0.00 0.00 0.00 0.00 0.00 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A E 0.00 2.50 0.00 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A E 0.00 5.00 0.00 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A E 0.00 9.99 0.00 N/A N/A N/A N/A N/A N/A N/A N/A 13.136 13.136 13.172 13.139 13.043 13.101 13.123 13.017 13.096 13.086 13.034 13.099 13.127 13.064 13.093 13.087 13.098 13.116 13.116 13.032 13.023 13.141 13.097 13.074 13.121 13.129 13.096 13.088 13.069 13.081 13.110 13.089 13.087 13.074 13.077 13.097 13.116 13.124 13.112 13.078 13.082 13.105 13.100 13.097 13.085 13.107 13.108 13.100 13.062 13.104 13.092 13.104 13.058 13.110 13.097 13.017 13.075 13.038 13.048 13.089 13.070 13.062 13.066 13.045 1075 1274 5937 5713 4995 6025 6365 5686 6359 5983 5511 7971 5436 5669 147940 154414 154773 1097 123048 4294 6487 7460 48830 22551 9095 55411 43844460 35608408 87245714 146110297 136261261 169308060 5207952 5920053 11797986 21640 237727 17085 12338382 10733040 22829168 11902004 11684837 23171196 3296274 2930108 6344638 91333594 10050414 8589890 5390446 5173127 13091485 19659 464850 14242 4783572 7550935 14689257 15605687 12044611 15995655 12956962 13730817 M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS 0 58 104 23 92 79137 86476 62356 92833 89971 86799 93701 92750 91133 82221 87261 87093 0 90561 0 84895 83853 84869 84287 84642 87292 38901 39956 25953 26379 29263 23546 67555 66596 57331 12 78659 104 64889 66160 50595 65898 64550 48760 72962 81076 70641 28799 61761 69663 74628 76257 59477 0 82676 92 77263 75708 59445 56262 57873 58689 61275 59988 N/A N/A N/A N/A N/A 2.87 2.87 2.87 2.87 2.87 2.87 2.87 2.87 287 287 287 287 N/A 2.87 N/A 2.87 287 287 287 287 287 2.87 2.87 2.87 287 287 2.87 2.87 2.87 2.87 N/A 287 N/A 287 287 287 2.87 2.87 287 287 287 287 287 287 2.87 287 287 287 N/A 287 N/A 287 287 2.87 287 2.87 287 287 287 0.00 12.9 13.3 13.0 13.3 13.1 13.1 13.1 13.1 13.1 13.1 13.1 13.1 13.1 13.1 13.1 13.1 0.00 13.1 0.00 13.0 13.1 13.1 13.1 13.1 13.1 13.1 13.1 13.1 13.1 13.1 13.0 13.1 13.1 13.1 13.2 13.1 13.0 13.1 13.1 13.1 13.1 13.1 13.1 13.1 13.1 13.0 13.0 13.1 13.1 13.1 13.1 13.0 0.00 13.1 13.1 13.1 13.1 13.1 13.1 13.0 13.1 13.1 13.1 N/A N/A N/A N/A N/A 0.0743 0.0696 0.0613 0.0997 0.0567 0.0512 0.0906 0.0423 0.0488 3.22 3.17 3.18 N/A 2.42 N/A 0.118 0.0981 0.986 0.424 0.131 1.09 No Intercept No Intercept No Intercept No Intercept No Intercept No Intercept 146. 169. 417. N/A S.46 N/A 382. 321. 1120. 361. 361. 1220. 84.1 67.0 171. No Intercept 322. 239. 136. 128. 450. N/A 10.2 N/A 116. 191. 514. 588. 422. 575. 430. 470. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 96.7 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 109. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 102 N/A N/A N/A N/A N/A N/A N/A N/A N/A s110317awiff s110317awiff s110317a.wiff EE s110317awiff E s110317a.wiff s110317a.wiff E s110317a.wiff E s110317a.wiff EE s110317a.wiff s110317a.wiff E s110317a.wiff E s110317a.wiff EE s110317a.wiff s110317a.wiff EE s110317a.wiff E s110317a.wiff E s110317a.wiff s110317a.wiff s110317a.wiff E s110317a.wiff s110317awiff EE s110317a.wiff E s110317a.wiff s110317a.wiff EE s110317a.wiff E s110317a.wiff E s110317a.wiff E s110317a.wiff s110317a.wiff EE s110317awiff E s110317awiff s110317a.wiff E s110317a.wiff EE s110317a.wiff E s110317a.wiff E s110317a.wiff s110317a.wiff E s110317awiff s110317awiff EE s110317a.wiff E s110317a.wiff s110317a.wiff EE s110317a.wiff E s110317a.wiff E s110317a.wiff E s110317a.wiff $110317a.wiff EE s110317a.wiff E s110317a.wiff s110317a.wiff EE s110317awiff s110317awiff EE s110317awiff E s110317a.wiff EEEEEEEEE s110317awiff s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff Printing Date: Tuesday, April 05, 2011 Printing St&8y GLP10-01-02-15 Page 9 of 11 Page 222 of 514 *Stan V1660305 *3M Environmental Lab Results Name: Sll0317a.rdb Sample Name Sample ID 577 S110317a088 578 S1103173089 579 S110317a090 580 s110317a091 581 s1103173092 562 s110317a093 583 S110317a094 564 S110317a095 585 s110317a096 586 s110317a097 587 s110317a098 588 S1103173099 589 s110317a100 590 s110317a101 591 s110317a1Q2 592 s110317a103 593 s110317a104 594 s110317a105 595 s110317a106 596 s110317a107 597 s110317a108 598 s110317a109 599 s110317a110 600 s110317a111 601 s110317a112 602 s110317a113 603 s110317a114 604 s110317a115 605 s137a16 606 s110317a117 607 s110317a116 608 s110317a119 609 s110317a120 610 s110317a121 611 S110317a122 612 s110317a123 613 s110317a124 614 s110317a125 615 s110317a126 616 s110317a127 617 s110317a128 618 s110317a129 619 s110317a130 620 s110317a131 621 s110317a132 622 s110317a133 623 s110317a134 624 s110317a135 625 s110317a136 626 s110317a137 627 s110317a138 628 s110317a139 629 s110317a140 630 s110317a141 631 s110317a142 632 s110317a143 633 s110317a144 634 s110317a145 635 s110317a146 636 s110317a147 637 s110317a148 638 s110317a149 639 s110317a150 640 s110317a151 GLP10-01-01-15-012 LMS DAL SS SS19 0 0005 Lab Matrix Spike GLP10-01-01-15-014 DAL SS SS15 0 0000 GLP10-01-01-15-014 Dup DAL SS SS15 0 0000 Lab Delicate GLP1001-01-15-014 LMS DAL SS SS15 0 0000 Lab Matrix Spike GLP10-01-01-15-015 DAL SS SS17 0 0000 GLP10-01-01-15-015 Dup DAL SS SS17 0 0000 Lab Delicate GLP1(W)1-01-15-015 LMS DAL SS SS17 0 0000 Lab Matrix Spike 10 006-80 solvent blank EC-110316-05 2.5 ng Extracted Cune Point 10 006-80 solvent blank GLP10-01-01-15-016 DAL SS SS14 0 0000 GLP1W)1-01-15-016 Dup DAL SS SS14 0 0000 Lab Duplicate GLP10-01-01-15-016 LMS DAL SS SS14 0 0000 Lab Matrix Spike GLP10-01-01-15-018 DAL SS SS18 0 0000 GLP10-01-01-15-018 Dup DAL SS SS16 0 0000 Lab Delicate GLP10-01-01-15-018 LMS DAL SS SS18 0 0000 Lab Matrix Spike GLP10-01-01-15-020 DAL SS SS10 0 0000 GLP10-01-01-15-020 Dup DAL SS SS10 0 0000 Lab Duplicate GLP10-01-01-15-020 LMS DAL SS SS10 0 0000 Lab Matrix Spike GLP10-01-01-15-Q21 DAL SS SS30 0 0000 GLP10-01-01-15-021 Dup DAL SS SS30 0 0000 Lab Di^icate GLP10-01-01-15-021 LMS DAL SS SS30 0 0000 Lab Matrix Spike GLP10-01-01-15-022 DAL SS SS30 0 0005 GLP10-01-01-15-022 Dup DAL SS SS30 0 0005 Lab Duplicate GLP10-01-01-15-022 LMS DAL SS SS30 0 0005 Lab Matrix Spike 10 0 0 6 -8 0 solvent blank EC-110316-06 5 ng Extracted Curve Point 10 006-80 solvent blank GLP10-01-01-15-023 DAL SS SS30 0 0015 GLP10-01-01-15-023 Dup DAL SS SS30 0 0015 Lab Duplicate GLP1001-01-15023 LMS DAL SS SS30 0 0015 Lab Matrix Spike GLP1001-01-15024 DAL SS SS25 0 0000 GLP100101-15-024 Dup DAL SS SS25 0 0000 Lab Dedicate GLP100101-15024 LMS DAL SS SS25 0 0000 Lab Matrix Spike GLP100101-15025 DAL SS SS25 0 0005 GLP100101-15025 Dup DAL SS SS25 0 0005 Lab Dedicate GLP100101-15025 LMS DAL SS SS25 0 0005 Lab Matrix Spike GLP100101-15026 DAL SS SS25 0 0015 GLP100101-15026 Dup DAL SS SS25 0 0015 Lab Diplicate GLP100101-15026 LMS DAL SS SS25 0 0015 Lab Matrix Spike GLP100101-15027 DAL SD SD22 0 0000 GLP100101-15027 Dup DAL SD SD22 0 0000 Lab Duplicate GLP100101-15027 LMS DAL SD SD22 0 0000 Lab Matrix Spike 10 0 0 6 -8 0 solvent blank EC-11031607 10 ng Extracted Curve Point 10 0 0 6 -8 0 solvent blank GLP100101-15028 DAL SD SD22 0 0005 GLP1001-01-15028 Dup DAL SD SD22 0 0005 Lab Delicate GLP100101-15028 LMS DAL SD SD22 0 0005 Lab Matrix Spike GLP100101-15029 DAL SD SD22 DB 0005 GLP100101-15-029 Dup DAL SD SD22 DB 0005 Lab Duplicate GLP100101-15029 LMS DAL SD SD22 DB 0005 L*> Matrix Spike GLP100101-15030 DAL SD SD22 0 0015 GLP100101-15030 Dup DAL SD SD22 0 0015 Lab Duplicate GLP100101-15030 LMS DAL SD SD22 0 0015 Lab Matrix Spike GLP100101-15031 DAL SD SD21 0 0000 GLP100101-15031 Dup DAL SD SD21 0 0000 Lab Delicate GLP100101-15031 LMS DAL SD SD21 0 0000 Lab Matrix Spike GLP100101-15032 DAL SD SD21 0 0005 GLP100101-15032 Dup DAL SD SD21 0 0005 Lab Duplicate GLP100101-15-032 LMS DAL SD SD21 0 0005 Lab Matrix Spike 10 00680 solvent blank EC-110316-05 2.5 ng Extracted Cune Point 10 00680 solvent blank Analyte Pea Name ` Sample Type Use Record Analyte Concentration (ng/mL) Analyte Retention Time (min) Analyte Peal Area (counts) IS Peak Nami IS Peak Area (counts) IS Concentration (ng/mL) IS Retention Time (min) Calculated Concentration (ng/mL) wiAccuracy PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS Unknown N/A Unknown N/A Unknown N/A Unknown N/A Unknown N/A Unknown N/A Unknown N/A Double Blank Quality Control E 0.00 2.50 Double Blank 0.00 Unknown N/A Unknown N/A Unknown N/A Unknown N/A Unknown N/A Unknown N/A Unknown N/A Unknown N/A Unknown N/A Unknown N/A Unknown N/A Unknown N/A Unknown N/A Unknown N/A Unknown N/A Double Blank Quality Control E 0.00 S.00 Double Blank 0.00 Unknown i N/A Unknown i N/A Unknown N/A Unknown N/A Unknown N/A Unknown N/A Unknown N/A Unknown N/A Unknown N/A Unknown N/A Unknown N/A Unknown N/A Unknown N/A Unknown N/A Unknown N/A Double Blank Quality Control E 0.00 9.99 Double Blank 0.00 Unknown N/A Unknown N/A Unknown N/A Unknown N/A Unknown N/A Unknown N/A Unknown N/A Unknown N/A Unknown N/A Unknown N/A Unknown N/A Unknown N/A Unknown N/A Unknown N/A Unknown N/A Double Blank Quality Control IS 0.00 2.50 Double Blank 0.00 13.069 13.055 13.067 13.027 13.088 13.078 13.060 13.078 13.078 12.982 13.103 13.057 13.043 13.044 13.046 13.080 13.043 13.074 13.062 13.054 13.090 13.008 13.067 13.080 13.045 13.078 13.020 13.155 13.052 13.025 13.099 13.066 13.058 13.056 13.056 13.036 13.052 13.035 13.064 13.035 13.064 13.073 13.064 13.046 13.055 13.068 13.076 13.043 13.052 13.063 13.069 13.071 13.071 13.051 13.026 13.020 13.059 13.061 13.075 13.062 13.034 13.061 13.078 13.078 23516209 5320655 18531555 19100771 3215756 3288444 6753923 15371 118493 1403 1812161 13563078 21728748 6000977 3498060 12566943 24725338 31051913 99833174 11631371 10970731 232S4043 4220166 4336066 12667099 5869 245013 2062 5840841 11969711 14324362 74214776 85591239 124642557 75093227 77233676 131329262 72123751 70917888 121964576 63816628 73973223 151007664 134355 472430 16433 30866590 42269206 49279338 58194786 35519895 56881386 20184691 15985877 29275962 51651625 61060935 119890665 52629716 46457740 60116288 41612 124063 8714 M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M6PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS 48739 76833 59193 52047 76157 78954 69267 243 84812 92 9430 52792 45057 74231 78701 61208 46067 40581 25248 63383 64904 46285 68139 67408 57696 58 84651 243 71212 64331 58198 32988 28453 28828 40539 40685 27141 36863 38244 26267 32876 36951 24842 69 81594 162 52259 50077 43569 42146 50415 40144 56597 61541 51048 43856 39283 24655 40746 41709 33889 0 81280 92 2.87 2.87 2.87 2.87 2.87 2.87 2.87 N/A 2.87 N/A 2.87 2.87 Z87 2.87 Z87 2.87 Z87 2.87 Z87 Z87 Z87 Z87 Z87 2.87 Z87 N/A Z87 N/A 2.87 2.87 2.87 2.87 2.87 Z87 2.87 Z87 2.87 Z87 Z87 Z87 Z87 2.87 Z87 N/A Z87 N/A 2.87 2.87 2.87 2.87 2.87 2.87 2.87 Z87 2.87 Z87 2.87 Z87 Z87 Z87 Z87 N/A Z87 N/A 13.1 13.1 13.1 13.0 13.1 13.1 13.0 12.8 13.1 13.0 13.1 13.0 13.1 13.1 13.0 13.1 13.1 13.0 13.1 13.1 13.1 13.1 13.1 13.1 13.0 13.1 13.0 13.1 13.0 13.1 13.1 13.0 13.1 13.1 13.1 13.0 13.0 13.1 13.0 13.0 13.1 13.1 13.0 13.2 13.0 13.2 13.1 13.0 13,0 13.0 13.1 13.1 13.1 13.0 13.0 13.0 13.1 13.1 13.0 13.1 13.0 0.00 13.1 12.8 1250. 130. 681. 835. 78.5 77.4 186. N/A 2.49 N/A 366. 537. 1250. 153. 8Z7 416. 1540. No Intercept No intercept 367. 335. 1340. 116. 121. 448. N/A 5.23 N/A 155. 373. 511. No Intercept No Intercept No Intercept No Intercept No Intercept No Intercept No Intercept No Intercept No Intercept No Intercept No Intercept No Intercept N/A 10.5 N/A No Intercept No Intercept No Intercept No Intercept No Intercept No Intercept 804. 544. 1900. No Intercept No Intercept No Intercept No Intercept No Intercept No Intercept N/A 2.72 N/A N/A N/A N/A N/A N/A N/A N/A N/A 99.5 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 105. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 105. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 109. N/A Record Modified File Name EEEEEEEE s110317awiff s110317a.wiff s110317a.wiff s110317a.wiff s110317a.wiff s110317a,wi!T s110317a.wiff s110317a.wiff s110317awiff s110317a.wiff E s110317a.wiff E s110317awiff E s110317a.wi!F E s110317awiff E s110317awiff E s110317a.wiff E s110317awiff E s110317awiff E s110317a.wiff E s110317a.wiff E s110317awiff E s110317awiff E s110317awiff E s110317a.wiff E s110317awitf s110317a.wiff s110317a.wiff s110317a.wiff E s110317a.wiff s110317a.wiff E s110317a.wiff EE s110317awiff E s110317awiff E s110317awiff E s110317a.wiff E s110317a.wiff E s110317awiff E s110317a.wiff E s110317a.wiff s110317awiff EE s110317a.wiff E s110317awiff s110317a.wiff EE s110317a.wiff s110317a.wiff EE s110317a.wiff E s110317a.wiff E s110317a.wiff E s110317a.wiff E s110317a.wiff E s110317awiff E s110317a.wiff E s110317awiff E s110317awiff E s110317a.wiff E s110317a.wiff E s110317awiff E s110317a.wiff E s110317a.wiff E s110317awiff s110317a.wiff EE s110317a.wiff E s110317a.wiff s110317a.wiff Printing Date: Tuesday, April 05, 2011 Printing StUdy GLP10-01-02-15 Page 10 of 11 Page 223 of 514 Stan V1660305 *3M Environmental Lab Sample Name ; Sample ID 641 s110317a152 642 s110317a153 643 s110317a154 644 s110317a155 645 s110317a156 646 s110317a157 647 s110317a158 648 s110317a159 649 s110317a160 650 S110317a161 651 s110317a162 652 s110317a163 {GLP10-01-01-15-033 DAL SD SD21 0 0015 {GLP10-01-01-15-033 Dup DAL SD SD21 0 0015 Lab Delicate {GLP10-01-01-15-033 LMS DAL SD SD21 0 0015 Lab Matrix Spike iGLPIO-01-01-15-034 DAL SS SS24 0 0000 IGLP10-01-01-15-034 Dup DAL SS SS24 0 0000 Lab Delicate jGLP10-01-01-15-034 LMS DAL SS SS24 0 0000 Lab Matrix Spike jGLP1001-01-15-035 DAL SS SS24 0 0005 IGLP10-01-01-15-035 Dup DAL SS SS24 0 0005 Lab Dedicate iGLP10-01-01-15-035 LMS DAL SS SS24 0 0005 Lab Matrix Spike j 10 00&S0 solvent blank |EC-1103164 5 ng Extracted Curve Point {10 006-80 solvent blank Analyte Pea Name Sample Type PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Use Record . ; . '{ Analyte Concentration (ng/mL) Analyte Retention Time (min) Analyte Peal Area (counts! IS Peak (tom i N/A N/A N/A N/A N/A N/A N/A N/A N/A E 0.00 5.00 0.00 13.073 13.058 13.067 13.066 13.059 13.069 13.048 13.065 13.068 13.035 13.097 13.124 21669523 17573159 33934713 33896194 39427079 52092620 56594002 51539399 96396510 80878 246677 8890 M8PFOS M8PFOS M8PFOS M8PFOS M6PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS I' 52553 60914 46158 47268 46553 41489 39141 39804 24846 12 78460 0 Results Name: sll0317a.rdb ^ IS Concentration (ng/mL) IS Retention Time (min) Calculated Concentration (ng/mL) Accuracy w Record Modified File Name 2.87 13.1 980. N/A 2.87 13.1 617. N/A 2.87 13.1 No Intercept N/A 2.87 13.1 No Intercept N/A 2.87 13.1 No Intercept N/A 2.87 13.0 No Intercept N/A 2.87 13.1 No Intercept N/A 2.87 13.1 No Intercept N/A 2.87 13.0 No Intercept N/A N/A 13.0 N/A N/A 287 13.1 5.69 114. N/A 0.00 N/A N/A K s110317a.wiff K s110317awiff EEEEEEEK s110317a.will s110317awiff s110317a.wiff s110317awiff s110317a.wiff s110317a.wiff s110317a.witf s110317awiff E s110317a.wiff s110317awiff Printing Date: Tuesday, April 05, 2011 3MStudy<SLRtQ-Q4-Q2-15Printing t t Page 11 of 11 Page224of514 *Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Stan V1660305 *3M Environmental Lab H s110317a.rdb (PFOS): "Quadratic" Regression ("1 / x" weighting): y = -0.00107 xA2 + 1.57 x + 0.0355 (r = 0.9998) Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 StudySLPf0-01-Q2-15Printing Page 1 of 1 Pahe 2 2 7 0 f 514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb *Stan V1660305 Results Name: sll0317a. V1660305 Date: Tuesday, April 05, 2011 TSfofeStiMy UPflOJSM -02-15 tj ^ S' S' rt rt *'Giii111 1 *m . m. *. * w p . m -A i iS : f IN -'fl W i\ ifs f'lis sliSfS i!" !1 ,l - - f I , " - !f ? r in J" ' 5 'Will f t ; ' ; L f - f lls m '1 .1 . . : ! ' , ! if --: i i * M M s i M I.!.!.!.! t if ? = f is *js__! f s ; H { l " i[ |l V 5 1 .... ..8 ........ ? . Results Name: sll0317a. Page 2 of 286 Page 230 of 514 *Stan V1660305 Results Name: sll0317a. Printing Date: Tuesday, April 05, 2011 P r in tin g T3MSta<iyt U P W B I-02-15 Page 3 of 286 Page 231 of 514 *Stan V1660305 *3M Environmental Lab I S a m p le N a m e: "s 1 1 0 3 l7 a 0 l3 " S a m p le ID: "E C - 1 10 315-04 1 n g Extracted C u rv e Po in t" P e a k N a m e: " P F B S " M a s s(e s): "299.0 /99.0 am u.2 99.0/60 .0 am u" I Com m ent A n n o ta tio n :"" Sample Index: 13 Sample Type: Standard Concentration: 0.999 ng/mL Calculated Cone: 0.946 ng/mL Acq. Date: 3/17/2011 1 .0 0 e 4 Acq. Time: 7:15:34 PM 9 5 0 0 .0 0 Modified: NO Proc. Algorithm: IntelliQuan - MQII Noise Percentage SO Base. sub. Window: 1.00 min Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height 0.0 cps Min. Peak Width: 0.0 sec Smoothing Width: 3 points RT Window; 30.0 sec Expected RT: 7 86 min Use Relative RT: NO 9 0 0 0 .0 0 6 5 0 0 .0 0 8 0 0 0 .0 0 7 5 0 0 .0 0 7 0 0 0 .0 0 6 5 0 0 .0 0 File: "s110317a.w rff' Int. Type: Retention Time: Area: Height: Stare Time: End Time: Valley 7.858 min 9896 counts .04e+004 cps 7.627 min 8.186 min 6 0 0 0 .0 0 1 5500.00 5000.00 ^ 4500.00 J Sam p le Nam e: "s110317a015" Sam p le ID: "E C -11 031 6-0 6 5 n g Exi P e a k N a m e: " P F B S " M a s s(e s): "29 9.0 /99.0 am u.2 99.0/80 .0 am u" C o m m e n t"" A n n o ta tio n :" Sample index: Sample Type: concentration: Calculated Cone: Acq. Date: Acq. Time: Modified: No Proc. Algorithm: IntelliQuan - MQII Noise Percentage: 50 Base. Sub. Window: Peak-Split. Factor: Report Largest Peak: Min. Peak Height: Min. Peak width: Smoothing Width: RT Window: Expected RT: use Relative RT: Int. Type: valley Retention Time: 7.S3 9 min Area: 511447 counts Height: 5 .29e*004 CpS Start Time 7.627 End Time: 8.224 Printing Date: Tuesday, April 05, 2011 StudyGLPW-Q1-Q2-15Printing Results Name: sll03l7a.rdb I S a m p le N a m e: "s110317a014" S a m p le ID: "E C -1 10316-05 2 .5 n g Extracted C u rv e Point" P e a k N a m e : "P F B S " M a s s e s ) : "299.0/9 9.0 am u,299.0 /80.0 am u" I C o m m e n tA n n o ta tio n : ~ Sample Index: 14 Sample Type: Standard Concentration: 2.50 ng/mL Calculated Cone: 2.SB ng/oL Acq. Date: 3/17/2011 Acq. Time: 7:39: PM File: "s110 317 a.w iff' Modified: No Proc. Algorithm: IntelliQuan - MQII Noise Percentage: 50 Base. Sub. Window: 1.00 min Peak-Split. Factor: 2 Report Largest Peak Min. Peak Height: 0.00 cps Min. Peak Width: o.oo sec Smoothing width: RT Window: 3 points 30.0 sec Expected RT: 7.86 min Use Relative RT: NO Area : Height : start Time: End Time: ?3e+004 7.627 8.494 S a m p le N a m e : "s1 10 3 1 7 a0 1 6 " S a m p le ID: 'E C -1 1 0 3 1 6 -0 7 10 n g Extracted C u rv e Point" P e a k N a m e : "P F B S " M a s s(e s): "2 99.0/9 9.0 am u.2 99.0/80 .0 am u" C om m en t: "" A n n o ta tio n :"" Sample Index: 16 Sample Type: Standard Concent ration: ng/mL Calculated Cone: ng/mL Acq. Date: Acq. Time: File: "s110 317 a.w ifT Modified: No Proc. Algorithm: IntelliQuan - MQII Noise Percentage: 50 Base. Sub. Window: 1.00 Peak-Split. Factor: Report Largest Peak: Min. Peak Height: Min. Peak Width: Smoothing Width: RT Window: Expected RT: Use Relative RT: Area: Height: Start Time: End Time: Page 4 of 286 Page232of514 Stan V1660305 *3M Environmental Lab I S a m p le N a m e: "s1 1 0 3 1 7 a 0 1 7 ` S a m p le ID: "E C-1 1 0 3 1 6 -0 8 25 n g Extracted C u rv e Point" P e a k N a m e: " P F B S " M a ss(e s): "299.0/99.0 a m u ,299.0/80.0 am u" I C o m m e n t "" A nn otation : "" Sample Index: Sample Type: concentration: Calculated Cone: ng/mL ng/mL Acq. Date: Acq. Time: FHe: "s1 1 0 3 1 7 a .w iff Modified: Ho Proc. Algorithm: IntelliQuan - MQII Noise Percentage: Base. Sub. Window: 50 1.00 min Peak-Split. Factor: 2 Report Largest Peak Min. Peak Height: cps Min. Peak width: sec Smoothing Width: RT Window: points Expected RT: Use Relative RT: No Int. Type: Base To Base Retention Time: 7.839 min Area: 2558350 counts Height: 2.66e+005 Cps Start Time: 7.473 min End Time: 8.513 min TSam p le N am e: "s110317a019" Sam p le ID: "E C -110316-10 100 n g Extracted C urv e Point" P e a k N a m e : " P F B S " M a s s ( e s ) : "2 9 9 .0 / 9 9 .0 a m u ,2 9 9 .0 / 8 0 0 am u " C o m m e n t "" A n n o ta tio n : *" Sample Index: File: "s1 1 0 3 1 7 a.w ifr Printing Date: Tuesday, April 05, 2011 TJMStUdy:LPTO-01-02-15Printing Results Name: sll0317a.rdb Sa m p le N a m e: "s 1 1 0 3 l7 a 0 1 8 " Sa m p le ID: " EC-1103 16-09 50 n g Extracted C u rv e Point" P e a k N a m e : " P F B S " M ass(es): "29 9.0 /99.0 am u ,299.0/80.0 a m u " C o m m e n t:"" Annotation: Sample Index: 18 Sample Type: standard Concentration: SO.O ng/mL -- - calculated Cone: 52.4 ng/mL Acq. Date: 3/17/2011 4.6e5 Acq. Time: 9:16:2? PM File: "s110 317 a.w iff' Modified: No Proc. Algorithm: IntelliQuan Noise Percentage: so Base. Sub. window: 1.00 Peak-Split. Factor: Report Largest Peak: Min. Peak Height: Min. Peak width: 0.00 Smoothing Width: RT Window: 30.0 Expected RT: 7.86 Use Relative RT: No P4e*005 7.492 8.629 I Sam p le N am e: s110317a020" Sam p le ID: "EC-110316-11 200 n g Extracted C u rv e Point' P e a k N a m e : " P F B S " M a s s ( e s ) : "2 9 9 .0 / 9 9 .0 a m u ,2 9 9 .0 / 8 0 .0 a m u " I C o m m e n t "" Annotation: "" Sample Index: 20 Sample Type: Standard Concent rat ion: 200. ng/mL calculated cone: 196 . ng/mL Acq. Date: 3/17/2011 I Acq. Time: 10:04:49 PM File: "s1 1 0 3 1 7 a .w iff Modified: No Proc. Algorithm: IntelliQuan - MQII Noise Percentage: Base. Sub. Window: SO 1.00 min Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: o.oo cps Min. Peak Width: o.oo sec Smoothing Width: 3 point: RT Window: 3o.o sec Expected RT: 7.86 min Use Relative RT: No Height: Start Time: End Time: 1. S7e+006 7.512 8.609 Page 5 of 286 Page233of514 *Stan V1660305 *3M Environmental Lab Results Name: sll03l7a.rdb Printing Date: Tuesday, April 05, 2011 T3MStUdyLP10-01-02-15Printing Page 6 of 286 Page234of514 *Stan V1660305 Results Name: sll0317a. Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 T$MStudyGUPWJ01-02-15Printing Page 8 of 286 Page236of514 *Stan V1660305 *3M Environmental Lab IS a m p le N a m e : "8 1 1 0 3 1 7 8 0 3 3 " S a m p le ID : " M B -1 1 0 3 1 6 -0 8 M e th o d B la n k w/ IS fo r dilutions' P e a k N a m e: " P F 8 S " M a s s(e s): "29 9.0 /99.0 am u.2 99.Q /80 .0 am u" C o m m e n t "" Annotation: " Semple Index-. 33 Sample Type: Unknown Concentration: N/A Calculated cone: <0 Acq. Date: 3/18/2011 Acq. Time: 3:19:23 AH File: "s1 1 0 3 1 7 a.w ifr Modified: Ho Proc. Algorithm: IntelliQuan - MQII Noise Percentage: so Base. Sub. Window: l.oo min Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 7.86 min Use Relative RT: No Height : Start Time: End Time: .59e+0 02 7.723 8.032 IS a m p le N a m e : "s1 1 0 3 1 7 a 0 3 5 " S a m p le ID : " M B -1 1 0 3 1 6 -1 0 M e th o d B la n k w/ IS fo r dilutions" P e a k N a m e : " P F B S " M a s s ie s ) . "2 9 9 .0 / 9 9 .0 a m u ,2 9 9 .0 / 8 0 .0 am u" Com m ent Annotation: ~ Sample Index: 3S Sample Type: "' Concentration: Calculated Cone: Acq. Date: Acq. Time: File: "s110317a.w rtT Modified: IntelliQuan - MQI Proc. Algorithm: 0 Noise Percentage: .00 Base. Sub. Window: Peak-Split. Factor: Report Largest Peak Min. Peak Height: Min. Peak width: Smoothing width: RT Window: : Expected RT: use Relative RT: No Int. Type: Retention Time: Area: Height: Start Time: Base To Base 7.8S8 min 3493 counts 3.33e+002 Cps 7.646 End Time: 8.051 TJ StUdyLPPQ-Q1-Q2-15mPrinting Date: Tuesday, April 05, 2011 Printing Results Name: sll0317a.rdb I S a m p le N a m e : "s1 1 0 3 1 7 a 0 3 4 * S a m p le ID : "M B -1 1 0 3 1 6 -0 9 M e th o d B la n k w/ I S fo r dilu tion s* P e a k N a m e: "P F B S~ M a s s e s ) : "29 9.0 /99.0 a m u ,299.0/80.0 am u" C o m m e n t -- Annotation: -- Sample index-. 34 Sample Type: Unknown Concentration: N/A Calculated Cone: <o Acq. Date: 3/18/2011 Acq. Time: 3:43:35 AH File: "s1 1 0 3 1 7 a .w iff Modified: No Proc. Algorithm: IntelliQuan - HQ1I Noise Percentage: 50 Base. Sub. Window: 1.00 min Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: o.oo cps |Min. Peak Width: o.oo eec Smoothing width: 3 points RT Window: 30.0 sec Expected RT: Use Relative RT: 7.86 No min Int. Type: Retention Time: Area : Height : Start Time: End Time: Valley 7.897 min 2623 counts 2 .60e+002 cps 7.723 min 7.993 min I" S a m p le N a m e : "s 1 1 0 3 1 7 a 0 3 6 " S a m p le ID : " M B -1 10316-11 M e th o d B la n k w/ IS fo r dilutions" P e a k N a m e : " P F B S " M a s s e s / . "299.0/9 9.0 am u,29 9.0 /80.0 am u" C o m m e n t "* A nn o tation : " Sample index: 36 Sample Type: Unknown Concentration: N/A Calculated Cone: <0 Acq. Date: 3/18/2011 Acq. Time: 4:32:03 AM FUe: "s110317a.w ifT Modified: No Proc. Algorithm: IntelliQuan MQII Noise Percentage: 50 Base. sub. window: l.oo min Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sac Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 7.86 min Use Relative RT: No Int. Type: Base To Base Retention Time: 7.820 min Area: Height: Start Time: End Time: 6024 counts S .B2e*002 cps 7 .608 min 8.089 min Page 9 of 286 Page237of514 Stan V1660305 Results Name: sl!0317a. Printing Printing DTaStie^:stiTlduyesdUayM,MAMpr-i0l2-1055, 2011 Page 10 of 286 Page 238 of 514 Stan V1660305 *3M Environmental Lab Results Name: s!10317a.rdb Printing Date: Tuesday, April 05, 2011 StiMyGLP10-01-02-15Printing Page 11 of 286 Page239of514 *Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 TMStUdGLPTO-O1-02-15Printing Page 12 of 286 Page240of514 Stan V1660305 Results Name: sll0317a. Printing Date: Tuesday, April 05, 2011 P r in tin g T ^ s tO d y LfliOJOl-02-15 Page 13 of 286 Page 241 of 514 *Stan V1660305 Results Name: sll0317a.rdb ting Date: Tuesday, April 05, 2011 ti n g TlffliStiMy kPTO-W -02-15 Page 14 of 286 Page 242 of 514 *Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 T3MStd:LP1O-O1-02-15Printing Page 15 of 286 Page243of514 *Stan V1660305 *3M Environmental Lab I Sample Name: " s110317a061" Sample ID: '1 0 006-60 solvent blank" Peak Name: " PFBS" M a s te s ): "299 0/99.0 amu,299.0/80.0 am u' C om m en t" Annotation: ~ Sample Index: 61 Sample Type: Double Blank File: "s110317a.wT Results Name: sll0317a.rdb I Sample Name: 's110317a06T S a np le ID: "GLP10-01-01-15-005 DAL SS SS16 0 0000" | Peak Name: 'P F B S ' Ma$s(es): *299.0/99.0 amu,299.0/80.0 am u' m C om m ent ~ Annotation: ~ Sample Index: 62 Sample Type: Unknown Concentration: N/A calculated Cone : 8.18 ng> Acq. Date: 3/18/2011 Acq. Time: 3:01:54 PM F ile :'s 1 1 0 3 1 7 a .w tfT Modified: RT Window: Expected RT; Use Relative RT : Yes 30.0 7.86 No sec min Int. Type: Manual Retention Time: 7.824 min Area: '764868 counts Height: 7.34e+004 cps Start Time: 7.646 min End Time: 8.243 min I Sample Name: 's110317a063' Sarrple ID:'GLP10-01-01-15-005 Dup DAL SS SS16 0 0000 Lab Duplicate' Peak Name: T F B S " Mass(es): '2 99.0/99.0 amu,299.0/80.0 a n v ' C om m en t-- Annotation: " Sample Index: 63 File: ' s110317&vnfT Printing Date: Tuesday, April 05, 2011 T^MStUfyLPfO-01-02-15Printing I Sample Name: 's110317a064' Sample ID: 'G LP10-01-01-1S-005 LMS DAL SS SS16 0 0000 Lab Matrix S pike' Peak Name: "PFBS* M asses): -299.0/99.0 amu.299.0/60.0 anuT C om m ent " Annotation: "* Sample Index: 64 Sample Type-. Unknown 7 82 Concentration: N/A Calculated Cone: 35.8 ng/mL . Acq. Date: 3 /18/2011 * Acq. Time: 3:S0:20 PM Modified: No 3 Proc. Algorithm: IntelliQuan - HQII Noise Percentage: So Base. Sub. Window: 1.00 min Peak-Split. Pactor: 2 2. Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak Width: 0.00 sec 2. Smoothing Width: 3 points RT Window: 30.0 sec 2 Expected RT: 7.86 min Use Relative RT: No File: 's110317a.w iT Int. Type: Valley Retention Time 7.820 Area : 3389954 counts Height : 3.33e*00S cps Start Time 7.646 min End Time: 8.263 min 1.4e5 1,2e5 1.0e5 8.0e4 6.0e4 4.04 2.0e4 Page 16 of 286 Page244of514 Stan V1660305 *3M Environmental Lab Results Name: sll03l7a.rdb Printing Date: Tuesday, April 05, 2011 T3MSttfGLP10-01-02-15Printing Page 17 of 286 Page245of514 Stan V1660305 Si? 5' 5' rr rt a i o a IQn> 03 0 hti N) 00 0> K) > Results Name: sll0317a. *3MStaEnnVv1ir6o6n0m30e5ntal Lab Results Name: sll0317a.rdb PPrriinnttiinngg Dt$awte:StuTduyeGsdLaPyT,0-A91p-rQil2-1055, 2011 Page 19 of 286 Page247of514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 TMStUdyGL:Pf0-S1-02-15Printing 3 Page 20 of 286 Page248of514 *Stan V1660305 Results Name: sll0317a. Printing Date: Tuesday, April 05, 2011 Printing TShfeStiMy LiW4M-02-15 Page 21 of 286 Page 249 of 514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 T3MStudyGbPtQ-Q1-Q2-15Printing Page 22 of 286 Page250of514 Stan V1660305 Results Name: sll0317a. inting Date: Tuesday, April 05, 2011 inting U P ) -02-15 Page 23 of 286 Page 251 of 514 Stan V1660305 Printing Date: Tuesday, April 05, 2011 Printing TSMBStukfyLfBfO-OT-02-15 mw1 if a !fi s h M H l 1 si f [i s > 8 8 M M M M M 8 M M s s| a < "' n 5 h ! s 51 " !" : IIII1Ii IjIIiIIII1 I % I E f 9 i 8 Results Name: sll0317a. Page 24 of 286 mmj.,,Xi i l ' i f ..HS8.SSJf' i ll Ies 55 ` J it j! yppsp H f l l isHf! * IH U Ss U| i illIII8IIIIIlglfllSUIi.il i ; ii 8 Ii -s- i r ls{ I E I -F i::F I is- S t? I Sa I Sa gs- gs- 8*js gs iss gs 5 8 1 Page 252 of 514 Stan V1660305 S i? inting Date: Tuesday, April 05, 2011 inting t $ |# st&0y33liPfC W l-02-15 Results Name: sll0317a. Page 25 of 286 "" S"s*aa"-L 1|S8ss--f t Ss- : 1 i- *i ssSSS si* 8 f B= ss . ! i }>* ' ! i " ISi>ss ` s~ s* - i&1 f - TMo' S- !s- Ss gs Is 1= - ssrss UisrH "I " ` Ss s i" f s " SS * ?SS i i 3, Page 253 of 514 *Stan V1660305 Results Name: sll0317a. Printing Date: Tuesday, April 05, 2011 Printing T$ftStlJdy GUPTOAM -02-15 Page 26 of 286 Page 254 of 514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb StudyGLP10-01-02-15tjmPrinting Date: Tuesday, April 05, 2011 Printing Page 27 of 286 Page255of514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 StUdySLPftf-01-02-15Printing Page 28 of 286 Page256of514 *Stan V1660305 Printing Date: Tuesday, April 05, 2011 Printing T l ^ s t i k ^ SS!I s; W ill- I* ll -Iss,|l * ` " ==-" 5sf I l l . ! 1 *6 ! " ' 1 H8 Wiki Is s- f 1 r S Ti,, " si ?i r iH B8 8 8M M M M M 8 M M M || r 5 5 Results Name: s!10317a. Page 29 of 286 .JLs s s s n s? "8 Hill - ;PP! r . o o 5" r:: Is i - ' : "I f 5i Sif" lJ || is 1 * 5 *" f i " ? M H I | | | | g g II 8 s s 2~ S-F 3- ? |Ss- Ss s|| S' * l"PIIP11 : d.=k l -.- hr- - . I N ! i. l.-! :Si,*I IHSIs s ! ,, " i!= Iss ' " . - . * i " i s 5 - 5S ' * IS8 8 i i s 88* II * II I I i i Page 257 of 514 *Stan V1660305 Results Name: s!10317a.rdb Printing Date: Tuesday, April 05, 2011 Printing 6 L W 0 -W -0 2-1 5 Page 30 of 286 Page 258 of 514 *Stan V1660305 *3M Environmental Lab [S a m p le N a m e : " s 1 t 0 3 1 7 a 1 2 r S a r r p le IO : "G L P 1 Q -0 1 -0 1 -1 5 -0 2 4 LW IS D A L S S S S 2 S 0 0 0 0 0 L a b M atrix S p ik e " P e a k N a m e: " P F B S " M a s s e s ) : "299.0/99.0 am u,2 99.0/80 .0 am u" SamCpolmem Ie nn dt e""x: A n n o ta t1io2n1: "" Sample Type: Unknown Concentration: N/A Calculated Cone: 138. I Acq. Date: 3/19/2011 Acq. Time: 2:52:23 PH File: "s 1 1 0 3 1 7 a .w tr Modified: No Proc. Algorithm: IntelliQuan KQII Noise Percentage: 50 Base. Sub. Window: 1.00 min Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: o.oo cps Min. Peak Width: o.oo sec Smoothing Width: 3 point: RT Window: 30.0 sec Expected RT: 7.86 min Use Relative RT: No Area: Height : Start Time: End Time: counts :S CpS < min ' min Results Name: sll0317a.rdb I Sam p le Nam e: "s110317a122" Sam p le ID: "G L P 1 0 -0 1 -0 M 5 -0 2 5 D A L S S S S 2 S 0 0005" P e a k N a m e: " P F B S " M a s s e s ) : "299.0/99.0 am u,2 99.0/80 .0 am u" I Com m ent A n n o ta tio n : Sample Index: 122 Sample Type: Unknown Concentration: N/A Calculated Cone: 39.3 I Acq. Date: 3/19/2011 Acq. Time: 3:16:35 PM File: "s110317a.w ifT Modified: NO Proc. Algorithm; IntelliQuan - Noise Percentage: 50 Base. Sub. Window: 1.00 t Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: 0.00 Min. Peak Width: 0.00 Smoothing Width: 3 RT Window: 30.0 sei Expected RT: 7.86 mil use Relative RT: No Area : Height : Start Time: End Time: cps J Sam p le N am e: ''s110317a123'' S a n p le ID: "G LP1D -01-01-15-025 D u p D A L S S S S 2 S 0 0005 Lab Duplicate" P e a k N a m e: "P F B S " M a s s e s ) : "299.0/99.0 a m u ,299.0/80.0 am u" M C o m m e n t "" A nn otation : "" Sample Index: 123 File: "s1 1 0 3 1 7 a.w ifr IS a m p le N a m e : "s 1 1 0 3 1 7 a 1 2 4 " S a m p le ID : " G L P 1 0 -0 1 -0 1 -1 5 -0 2 5 L M S D A L S S S S 2 5 0 0005 L ab M atrix S p ik e " P e a k N a m e: " P F B S " M a s s e s ) : "299.0/99.0 a m u ,299.0/80.0 am u' SamCpolmem eInntde""x:A n n o ta ti1o2n4: "" Sample Type: Unknown Concentration: N/A calculated cone: 146. ng/mL Acq. Date: 3/19/2011 Acq. Time: 4:04:59 PM File: "s1 1 0 3 1 7 a .w iT Modified: No Proc. Algorithm: IntelliQuan MQ11 Noise Percentage: so Base. Sub. Window: 1.00 min Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak width: sec Smoothing width: points RT Window: Expected RT: Use Relative RT: Height: start Time: End Time: 06e+005 cps 7.646 min 8.513 Printing Date: Tuesday, April 05, 2011 3MStudyGLB10-G1-02-15Printing t Page 31 of 286 Page259of514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb StudyGLP10-01-02-15tjmPrinting Date: Tuesday, April 05, 2011 Printing Page 32 of 286 Page260of514 *Stan V1660305 Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 Printing T ^ S t O d y U P 1 0 -W -0 2 - 1 5 Page 33 of 286 Page 261 of 514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb StudyGLP10-QI-02-15t mPrinting Date: Tuesday, April 05, 2011 Printing Page 34 of 286 Page262of514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 T3MStUdGLP10-01-02-15Printing Page 35 of 286 Page263of514 *Stan V1660305 *3M Environmental Lab Results Name: s!10317a.rdb Printing Date: Tuesday, April 05, 2011 TMStUdySLP1Q-Q1-Q2-15Printing 3 Page 36 of 286 Page264of514  StanV1660305 *3M Environmental Lab Results Name: sl!0317a.rdb PPrriinnttiinngg DTgaWte:StuTduyeGsdLaPy?,0-AOp1-r0il2-1055, 2011 Page 37 of 286 Page265of514 *Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 StUdyGLP1Q-Q1-Q2-15Printing Page 38 of 286 Page266of514 PPrriinnttiinngg TDajitpep:sydTyu:egsLdPa>yf,t)-Apfr-i0l2-1055, 2011 Page 39 of 286 Page 267 of 514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 StudyGbPfO-01-02-15Printing Page 40 of 286 Page268of514 *Stan V16603 05 Printing Date: Tuesday, April 05, 2011 Printing -02-15 Results Name: sll0317a. Page 41 of 286 P f! h ss 1 5" J ? u.u.u.M.u.u.njjjj.u.u.ujj. H 1 M i fm i. I \* i* * 3 ~ a. S-P s- 1 1 8 fi m iii j -i f f-'f.iIl ii5ii '55...!:;-St' ft* .*sssss p iHVs H 1 f M if B i m m m m m i.I 5 i s I Page 269 of 514 gs- 8 si 8 s5 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 TSfflestuWy:GLP10-01-02-15Printing Page 42 of 286 Page270of514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 TgM'Study:SLP10-01-02-15Printing Page 43 of 286 Page 271 of514 Stan V1660305 Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 printing T ^ s t i M y L:Pf03M -02-15 Page 44 of 286 Page 272 of 514 *Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 TMStddVGLP1Q-Q1-Q2-15Printing 3 Page 45 of 286 Page273of514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday/ April 05, 2011 TSMStd:@LPTO-01-02-15Printing Page 46 of 286 Page274of514 *Stan V1660305 Results Name: sll0317a. ting Date: Tuesday, April 05, 2011 tin g T ^stO d y -02-15 Page 47 of 286 Page 275 of 514 Stan V1660305 Results Name: sl!0317a. inting Date: Tuesday, April 05, 2011 i n t in g T j^ s t iM y U P fO -02-15 Page 48 of 286 Page 276 of 514 *Stan V1660305 Results Name: sll0317a. Printing Date: Tuesday, April 05, 2011 Printing TgW StM y -02-15 Page 49 of 286 Page 277 of 514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb StudyQUP1Q-Q1-Q2-15t mPrinting Date: Tuesday, April 05, 2011 Printing Page SO of 286 Page278of514 *Stan V1660305 Results Name: s!10317a.rdb inting Date: Tuesday, April 05, 2011 -inting T ^ s t iJ d y -02-15 Page 51 of 286 Page 279 of 514 Stan V1660305 Results Name: sll0317a. M M M I I M . M . !| " S eh I ii .. " f '< - s. ' iififH! zs ? ; s 5 8 " ' i | l SSS'3 f>5 S f 5s 8 || =1 * l i f 1 S 88 33* \\ s:. -* 53 l! Printing Date: Tuesday, April 05, 2011 Printing T j^ s t iM y -02-15 Page 52 of 286 Page 280 of 514 Stan V1660305 inting Date: Tuesday, April 05, 2011 in tin g _02-15 i i"8! . ,h ,s I H lS d ' ='? s t ; :\ f!isf*`| s ~ 1` ` i 1 j I I 8 i E M . . M 8. 1 5 I I i i S3S Si " r IH II5 ss s f Is r `i iu M SSgSi '|5 sK is ! ? i %I i I M I S M ! W& 'C J - iiisN " 1 ss S I 5" mu is . f si Results Name: sll0317a. Page 53 of 286 P a g e 2 8 1 o f5 1 4 Stan V1660305 *3M Environmental Lab Results Name: sll03l7a.rdb Printing Date: Tuesday, April 05, 2011 St GLP10-01-02-15Printing Udf Page 54 of 286 Page282of514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 StUdyGL:PfO1-02-15Printing Page 55 of 286 Page283of514 Stan V1660305 Printing Date: Tuesday, April 05, 2011 Printing LFft)-W-02-15 tm a s a" 3- 3 t Sa gs- Bs|? Ss- .I 8 | ..= ; s s ! IS I " 3 `I r \n n > s n "" L ! ss" s I . n. 11 m m m f f.f iilJfll n i a i H 9" sHb= 9? is " |H =s !! 'i I iMiOr j i i f a- o i SM "'i i U B M iiiHHUiiHifiit r s S8~ 3' I Sa gs- Ssi Si " S' <1 I I i% I E i 1 w 4 . \ ? "tiiH ! j - . m __ SS S I 3s r a Results Name: sll03l7a. Page 56 of 286 P a g e 2 8 4 o f5 1 4 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 TSMStLP10-1-02-15Printing Page 57 of 286 Page285of514 Stan V1660305 Results Name: sll0317a.rdb pPrriinnttiinngg ^DaetSetu:ityT:uestFda2y|$,)-&ApMri2l-1055, 2011 Page 58 of 286 Page 286 of 514 *Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 StUdyGLPfQ-91-02-15Printing Page 59 of 286 Page287of514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb 3 StudyGLP1QJ01-Q2-15t mPrinting Date: Tuesday, April 05, 2011 Printing Page 60 of 286 Page288of514 Stan V1660305 Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 Printing Tjflpstikty:LfSffi-W-02-15 Page 61 of 286 Page 289 of 514 Stan V1660305 Results Name: sll0317a. Printing Date: Tuesday, April 05, 2011 Printing 'i^R^StLPdV1i_1=a1c0-r1I-02-15 Page 62 of 286 Page 290 of 514 *Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 TMStUdyGLP10-Q1-02-15Printing 3 Page 63 of 286 Page 291 of514 *Stan V1660305 Results Name: sl!0317a.rdb DTaatNeP:StiTkfuye1s6dUa*y,f0-AWpr-0i2l-1055, 2011 Page 64 of 286 Page 292 of 514 Kill! s h M Vz %% 1 *" f | I I T i fm .MJ n m '" la'!/J i i" ,.a ,,` *w,`ik"'-v!' |P! '! e sH " , 1. j t I* 5 Printing Printing DTaStuep:stdcTfuye: sgdLafyS,f t iA^p-r0i2l- 1055, 2011 m Page 65 of 286 Page 293 of 514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 TjMStUfySLP10-01-02-15Printing Page 66 of 286 Page294of514 Stan V1660305 Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 Printing _02_15 Page 67 of 286 Page 295 of 514 Stan V1660305 Results Name: sl!0317a.rdb Printing Date: Tuesday, April 05, 2011 Printing 5 Page 68 of 286 Page 296 of 514 Stan V1660305 Results Name: sl!0317a.rdb Printing Date: Tuesday, April 05, 2011 Printing T^j^stukfy6Lff0-W -02-15 Page 69 of 286 Page 297 of 514 Stan V1660305 *3M Environmental Lab Sample Name: s110317a114" Sample ID: EC-11Q316-06 5 ng Extracted Curve Point" Peak Name: "PFHS" Masses): "399.0/60.0 amu.399.0/99.0 amu" I Comment " Annotation:"" Sample Index: 114 Sample Type: QC Concentration: 4.99 ng/mL calculated Cone: 5.53 ng/mL Acq. Date: 3/19/2011 Acq. Time: 12:02:44 PM File: s i 10317 a.w ifr Modified: No Proc. Algorithm: IntelliQuan - MQi; Noise Percentage: SO Base. Sub. Window; l.oo min Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak width: 0.00 sec Smoothing width: 3 poll RT Window: 30.0 sec Expected RT: 10.3 min Dse Relative RT: No Area: Height : start Time: End Time: 3.44e+004 10.054 10. 853 I Sample Name: "s110317a1l6" Sample ID: "GLP10-01-01-15-023 DAL SS SS30 0 0015" Peak Name: "PFHS" Masses): "399.0/80.0 amu.399.0/99.0 amu' Comment"" Annotation: "* Sample Index: 118 File: "s110317a.wiff" Time, min Printing Date: Tuesday, April 05, 2011 TIMStUdSLPf0-1-02-15Printing Time, min Results Name: sll03l7a.rdb I Sample Name: "s110317a115 Sample ID: "10 006-80 solvent blank" Peak Name: "PFHS" Mass(es): "399.0/80.0 amu.399.0/99.0 amu" Comment *" Annotation: Sample Index: n s Sample Type: Double Blank File: "s110317a.wtfT I Sample Name: "s110317a117" Sample ID: "GLP10-01-01-15-023 Dup DAL SS SS30 0 0015 Lab Duplicate" Peak Name: "PFHS" Mass(es): "399.0/80.0 amu.399.0/99.0 amu' I Comment "" Annotation: "" Sample Index: 117 Sample Type: Unknown Concentration: N/A Calculated cone: Acq. Date: 3 /19/2011 Acq. Time: 1:15:27 PM File: "s110317a.witT Modified: Yes Proc. Algorithm: IntelliQuan - 1 Noise Percentage: so Base. Sub. Window: 1.00 mil Peak-Split. Factor: 6 Report Largest Peak: No Min. Peak Height: 0.00 cj Min. Peak Width: 0.00 si Smoothing width: 3 ] RT Window: 30.0 sec Expected RT: 10.3 min Use Relative RT: No Int. Type: Base To Base Retention Time: 10.266 min Area: 590468 counts Height: 4.S4e*004 Cps Start Time: 9.S92 min End Time: 10.709 Page 70 of 286 Time, min Page298of514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 SLP400i-02-15Printing Page 71 of 286 Page299of514 **3SMtanEnVv1ir6o6n0m30e5ntal Lab Results Name: sll0317a.rdb PPrriinnttiinngg DTaMte:8t&T0uye^sd^a1y0,-0A1p-0ri2l-1055, 2011 Page 72 of 286 Page300of514 Stari V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 MStuWGLP10-01-02-15Printing r Page 73 of 286 Page 301 of514 Stan V1660305 Printing Date: Tuesday, April 05, 2011 p rin tin g 5 J.r Bflli /' I r?5S?S Is S!.. m i tulnss 0t U o o " . " S | " issss '*? IH ''h " : 1 ,= . s 5* i j t i i < i f i i i II m S~8*a~ ssB f I Sa gsSs-- Si' I* i - ig '1 * f. iH i H S I Sa gs gs ss 1 5 m III 1 !| j ! s!lH! J ., HS=I! Js H=ipi| ,, " : r " ' ,i< f Is tm m m m I s I I i =J!il. >W ' H. IH! IJkV^$fl ihIi> i." :1 ,f = ? [ ? * . * 5- fflilfll F !| | MV h u n " : 1 . s - f '! * I ,,S..B. s ,,,8..8..S A . J . J . J . J . J J . . . f| Results Name: sll0317a. Page 74 of 286 Page 302 of 514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 MStutyiPTO-01-02-15Printing ^ Page 75 of 286 Page303of514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 T3MStud:GLP10-01-02-15Printing Page 76 of 286 Page304of514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 T$MStudyGLP10-Q1-02-15Printing Page 77 of 286 Page305of514 *Stan VT660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 StUdyGL:P1Q-Q1-Q2-15Printing Page 78 of 286 Page3Q6of514 *Stan V1660305 *3M Environmental Lab I Sam p le Nam e: "s110317a15Cr S a n p le ID :'E C -1 1 0 3 1 6 -0 5 2 .5 n g Extracted Curv e PoinT P e a k N a m e: " P F H S " M a s s e s ) : "399.0/B0.0 a m u ,399.0/99.0 am u" I C o m m e n t "" A n n o t a t io n :"" Sample Index; 1SQ Sample Type: QC Concentration: 2.49 ng/raL Calculated Cone: 2.7a ng/mL Acq. Date: 3 /20 /2 01 1 Acq. Time: 2:34:55 AM File: "s110317a.w rfr Modified: No Proc. Algorithm: IntelliQuan Noise Percentage: SO Base. Sub. window: 1 . 0 0 Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: 0.00 1 CpS Min. Peak Width: 0.00 1 s e c Smoothing Width: 3 points RT Window: 31 s e c Expected RT: min Dae Relative RT: 1 Int. Type: Base To Base Retention Time: 1 0 . 2 6 6 min Area : 195076 counts Height: 1.44e+004 cps Start Time: 10.03S min End Time: 10.978 min I Sam p le Nam e: "s110317a152" Sam p le ID: "GLP10-01-01-15-033 D A L S O SD 21 0 0015" , P e a k N a m e : "P F H S " M a s s e s ) : "399.0/8 0.0 am u.3 99.0/99 .0 am u' I C o m m en t " Annotation: " Sample Index: 152 Sample Type: Unknown Concentration: N/A Calculated Cone: 69.3 i Acq. Date: 3/20/2011 Acq. Time: 3:23:24 AM File: "s1 1 0 3 1 7 a.w ifr Modified: Yes Proc. Algorithm: IntelliQuan I Noise Percentage: 50 Base. Sub. window: 1.00 mil Peak-Split. Factor: 8 Report Largest Peak: No Min. Peak Height: 0.00 C] Min. Peak Width: 0.00 si Smoothing Width: 3 ] RT Window: 30.0 sec Expected RT: 10.3 min Dse Relative RT: No Int. Type: Base To Base Retention Time : 1 0 . 2 6 6 min Area: 4i 63624 counts Height : 2.77e*00S cps Start Time: 9.611 min End Time: 10.863 min StudyQL=Pf0-01-02-15tjmPrinting Date: Tuesday, April 05, 2011 Printing Results Name: sll0317a.rdb I Sam p le Nam e: "s1 1 0 3 1 7 a1 5 r Sam p le ID: "10 006-80 solvent blank" P e a k N a m e: " P F H S ' M a s s e s ) : -399.0/8 0.0 am u.3 99.0/99 .0 am u" C o m m en t -- Annotation: ~ Sample index-. 151 Sample Type: Double Blank File: "s110 317 a.w ilT IS a m p le N a m e : " s 1 1 0 3 1 7 a 1 5 3 * S a m p le ID: "G L P 1 0 -0 1 -0 1 -1 5 -0 3 3 D u p D A L S D S D 2 1 0 0 0 15 L a b D u p lic a te " P e a k N a m e : "P F H S " M a s s e s ) . "3 99.0/8 0.0 am u.3 9 9 .0 /9 9 .0 am u" SamCpolmem einntdex:A n n o tat1io5n3: ~ Sample Type: Unknown Concentration: N/A Calculated Cone: Acq. Date: Acq. Time: File: "s1 1 0 3 1 7 a.w ifr Modified: Yes Proc. Algorithm: IntelliQuan - MQII Noise Percentage: 50 Base. Sub. window: Peak-Split. Factor: Report Largest Peak: Min. Peak Height Cps Min. Peak width: sec Smoothing Width: points RT Window: Expected RT: Use Relative RT: Int. Type: Base To Base Retention Time: 1 0 . 2 6 6 min Area: 107638 counts Height: 2.65e+005 cps Start Time: 9.611 min End Time: 10.824 min Page 79 of 286 Page307of514 Stan V1660305 *3M Environmental Lab I S a n p le N a m e: '51103173154' Sa m p le ID: "G L P 1 0-01-01 -15 -0 33 L M S D A L S D S D 2 1 0 0015 Lab Matrix S p ik e ' P e a k N a m e: 'P F H S ' M a s s e s ) : "399.0/80.0 a m u ,399.0/99.0 a m u ' Com m ent A n n o ta tio n : Sample Index: 154 File: 's1 1 0 3 1 7 a.w ifr Results Name: sll0317a.rdb [S a m p le N a m e : 's 1 1 0 3 1 7 a 1 5 5 ' S a m p le ID : 'G L P 1 0 -0 1 -0 1 -1 5 -0 3 4 D A L S S S S 2 4 0 0 0 0 0 " P e a k N a m e: 'P F H S ' M a s s(e s): "399.0/80.0 am u.3 99.0/99 .0 a m u ' SamCpolmem eInntdex:A n n o ta tiiosns: *" Sample Type: Unknown Concentration: N/A Calculated Cone: 49.7 I Acq. Date: 3/20/2011 Acq. Time: 4:36:08 AM File: 's1 103 17a.w ifT Modified: Yes Proc. Algorithm: IntelliQuan - MQI1 Noise Percentage: 50 Base. Sub. Window: 1.00 min Peak-Split. Factor: 8 Report Largest Peak: No Min. Peak Height: o.oo cps Min. Peak Width: o.oo sec Smoothing Width: point RT Window: Expected RT: Use Relative RT: Int. Type: Base To Base Retention Time: 1 0 . 2 6 6 min Area: 174500 counts Height: 2.11e*005 cps Start Time: 9.611 min End Time: 10.767 min TS a m p le N a m e : '8 1 1 0 3 1 7 3 1 5 6 " S a m p le ID : 'G L P 1 0 -0 1 -0 1 - 1 5 - 0 3 4 D u p D A L S S S S 2 4 0 0 0 0 0 L a b D u p lic a te ' P e a k N a m e: 'P F H S * M a s s e s ) : "399.0/80.0 a m u ,399.0 /99.0 a m u ' C o m m e n t *" A n n o ta tio n : "" Sample Index: File: ' s1 103 17a.vn ir I S a m p le N a m e :'s 1 1 0 3 1 7 a 1 5 r Sam p le ID: "GLP10-01-01-15-034 L M S D A L S S S S 2 4 0 0000 Lab Matrix Spik e" P e a k N a m e :'P F H S " M a s s e s ) : -399.0/8 0.0 am u.3 99.0/99 .0 am u" I Com m ent A n n o tatio n :"" Sample Index: 157 Sample Type: Unknown Concentration: N/A Calculated Cone: 164 . l Acq. Date: 3/20/2011 Acq. Time: 5 : 2 4 : 3 3 AM File:'61 1031 7a.w tfT Modified: Y Proc. Algorithm: Inte Noise Percentage: Base. Sub. Window: Peak-Split. Factor: Report Largest Peak: Min. Peak Height: Min. Peak Width: Smoothing Width: RT Window: 30 Expected RT: l Use Relative RT: N Height : Start Time: End Time: 6.67e+00S 9.572 10.959 Printing Date: Tuesday, April 05, 2011 TjMStUdyGLPfO-01-02-15Printing Page 80 of 286 Page308of514 *Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 T$MStUdV:GLPfa-01-02-15Printing Page 81 of 286 Page309of514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 T3MStudyGLP10-6W-Q2-15Printing Page 82 of 286 Page310of514 fD (e0 i *3M Environmental Printing Date: Tuesday, April 05, 2011 Printing T ^ n / p s t i J d y -02-15 Page 83 of 286 Page311of514 Stan V1660305 Results Name: sl!0317a. PPrriinnttiinngg TDa^tse:tiJTduyesdUa*yT,O-Ap1r-i0l2-1055, 2011 Page 84 of 286 Page 312 of 514 Stan V1660305 Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 Printing _02-l5 Page 85 of 286 Page 313 of 514 *Stan V1660305 *3M Environmental Lab Results Name: sl!0317a.rdb Printing Date: Tuesday, April 05, 2011 TMStUdyGLP1Q-Q1-Q2-15Printing 3 Page 86 of 286 Page314of514 *Stan V1660305 Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 Printing T^ippstJdy ^_:fSfo^1-02-15 Page 87 of 286 Page 315 of 514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 StUdGLP10W-02-15Printing Page 88 of 286 Page316of514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 TMStUdyGLP10-01-02-15Printing 3 Page 89 of 286 Page317of514 *Stan V1660305 Results Name: sll0317a. *Stan V1660305 Results Name: sll0317a.rdb U> 2 r O&'> Printing Date: Tuesday, April 05, 2011 Printing gjUSft)^_o2_i 5 Page 91 of 286 Page 319 of 514 *Stan V1660305 Printing Date: Tuesday, April 05, 2011 Printing T30Fstuty:Lfft>"W-O2-15 L- . $ mi i *r n i 'fill, .-s "iHV"s! L It..lih r ir 1 J J . M J J J J J .i 1 fill i r t l I?m!i - I H e i m m m m m . siisti 11 B * _ I I Results Name: sll0317a. Page 92 of 286 sHVs si . : a 111SI 11111111fi !I5 <1 IjI MM j ;jj,5 i " ........ m ." S 5 s ! " s !S 5 = : s p : s h f i f Pi n n n |-- - ll 188188888188888188 as* 2-, ssf 4?Sa gs- Sjs-js 1 5* II- ii ' i a3 |S Si 3 Is 3 II Page 320 of 514 Stan V1660305 inting Date: Tuesday, April 05, 2011 inting t &m s tM y U liP fO W -02-15 55 jl! SSI*IInu iisbp " 5" &HSs si | 1 | 8M M M M ?M 9M M $ --------------------------- s m t m i mn .. H- - i mi ih U w $ f Hi W i\ IV V-'stl s-:.k ! v | ' fS H lfi H " !. !' `> 8 | 11111 1 1 1 1 1 1 1 1 1 1 s i ?; ^ m iii*i**i* ssi i s si ! Si I? ss if 1 i i Results Name: sll0317a. Page 93 of 286 Page 321 of 514 *Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 TMStUdyGLiPfQ-Q1-Q2-15Printing 3 Page 94 of 286 Page322of514 Stan V1660305 *3M Environmental Lab I Sa m p le N a m e :'s 1 1 0 3 1 7 a 0 5 1 " Sa m p le ID: "G LP10-01-01 15-002 D u p D A L S S S S 1 2 0 0000 Lab D uplicate' P e a k N a m e : "P F O S " M a s s e s ) : 499.0/80 0 am u .4 9 9 .0 /9 9 .0 a m u ,4 9 9 ,0 1 1 3 0 .0 a m u " I C o m m e n t " A nn otation : *" Sample Index: SI Sample Type: Unknown Concent rat io n : N/A Calculated Cone: No Intercept Acq. Date: 3/18/2011 Acq. Tine: 10 :35 :23 AM R ie : "s1 1 0 3 1 7 a .w ir Modified: RT Window: Expected RT: Use Relative RT: Ves 30.0 13.1 No sec tain I n t . Type: Manual Retention Tine: 13.088 min Area: 35603408 Count! Height: 2.07e*006 cps start Time: 11.807 a in End Time: 13.790 min Results Name: sll0317a.rdb IS a m p le N a m e : " s 1 1 0 3 1 7 a 0 5 2 " S a m p le ID : " G L P 1 0 - 0 1 - 0 M 5 - 0 0 2 L M S D A L S S S S 1 2 0 0 0 00 L a b M atrix S p ik e " P e a k N a m e: " P F O S * M a s s e s ) : "499.0/8 0.0 am u,499.0 /99.0 a m u ,499.0/130.0 am u* 1 C o m m e n t " Annotation: " Sample Index: S2 Sample Type: Unknown Concentration: N/A Calculated Cone : No Intercept Acq. Date: 3/18/2011 Acq. Time: 10 :S 9 :33 AM File: "s 1 1 0 3 1 7 a w iT Modified: RT Window: Expected RT: Use Relative RT : ves 30.0 13.1 NO sec min Int. Type: Manual Retention Time: 13.069 min Area: 8 724 S714 counts Height: S .39e+006 cps start Time: 11.730 min End Time: 14.619 min II S a m p le N a m e : " s 1 1 0 3 1 7 a 0 5 3 " S a m p le ID : "G L P 1 D -0 1 -0 1 1 5 -0 0 3 C P e a k N a m e : ' P F O S " M a s s e s ) : "4 9 9 .0 / 8 0 .0 a m u ,4 9 9 .0 /99 0 a m u ,4$ I C o m m en t ~ Annotation: ~ Sample Index: S3 Sample Type: Unknown Concentration: N/A Calculated Cone: No Intercept Acq. Date: 3/18/201: Acq. Time: 11:23 :4S AM Modified: RT Window: Expected RT: Use Relative RT: Yes 30.0 13 .1 No sec min Int. Type: Manual Retention Time: 13.081 Area: 14 6110297 Height: 4 . 77e +006 Start Time: 11.710 End Time: 13.868 min counts cps min min I S a m p le N a m e: "s110 317 a054 " S a m p le ID: " G L P 10-01-01-15-003 D up D A L S S S S 1 2 0 05 Lab D uplicate" I P e a k N a m e : " P F O S " M a s s e s ) : "499.0/80.0 a m u ,499.0 /99.0 am u.4 99.0/13 0.0 am u" m C o m m e n t -- Annotation: ~ Sample Index: S4 Sample Type: Unknown Concentration: N/A Calculated Cone: No Intercept Acq. Date: 3/18/2011 Acq. Time: 11: 47 :S 9 AM File: "s110 317 a.w ifr Modified: RT Window: Expected RT: Use Relative RT: Yes 30.0 13.1 NO sec m in Int. Type: Manual Retention Time: 13.110 Area: 136261261 Height : 4.6 0e +006 Start Time: 11.730 End Time: 13.790 min counts cps min min Printing Date: Tuesday, April 05, 2011 StliyGL:Pf-Q1-2-15Printing Page 95 of 286 Page323of514 **3SMtanEnVv1ir6o6n0m30e5ntal Lab I Sa m p le N a m e: "s110317a055" Sa m p le ID: "G L P 10-01-01 -1S-003 L M S D A L S S S S 1 2 0 0005 L a b Matrix Spike" P e a k N a m e: "P F O S " M a s s e s ) : "499.0/80.0 am u .4 9 9 .0/99.0 a m u ,499.0 /130 .0 am u" I Com m ent: A n n o ta tio n : "" sample Index: 55 Sample Type: Unknown Concent rat ion: N/A Calculated cone: Mo Intercept Acq. Date: 3/18/2011 Acq. Time: 12 :12 :IS PM File: "s110 317 a.w tff Modified: RT Window: Expected RT: Use Relative RT: Yes 30.0 13.1 NO sec min Int. Type: Manual Retention Time: 13.089 Area: 16 9308060 Height: 6.41e +006 start Time: 11.710 End Time: 14.079 min counts cps min Results Name: sll03l7a.rdb I S a m p le N a m e: "s110 317 a0S6" S a m p le ID: "G L P 10-01-01 -15 -0 04 D A L S S S S 1 3 0 0000" P e a k N a m e: " P F O S " M ass(es): "499.0/8 0.0 am u ,4 9 9 .0/99.0 a m u ,499.0/130.0 am u" M C o m m e n t " A n n o ta tio n : "" Sample Index: 56 Sample Type: Unknown Concentration: N/A Calculated cone: 146 . ng/ Acq. Date: 3/18/2013 Acq. Time: 12 :36:28 PM File: "s 1 1 0 3 1 7 a .w iff Modified: RT Window: Expected RT: Use Relative RT: Yes 3 0.0 13.1 NO sec min Int. Type: Manual Retention Time: 13.08? min Area: 5207952 counts Height : 3.6 8e +0 05 cps Start Time: 11.768 min End Time: 13.829 min I Sa m p le N a m e; "s110317a057" S a irp le ID: " G L P 1 0-01-01-15-004 D u p D A L S S S S 1 3 0 0000 L a b D uplicate" I P e a k N a m e : "P F O S " M a s s e s ) : "499.0/80.0 a m u ,499.0/99.0 a m u ,499.0 /130 .0 am u" C o m m e n t "" A n n o ta to ri: "" Sample Index : 57 Sample Type: Unknown Concentraticin: N/A calculated Cone: 169. ngy Acq. Date: 3/18/201 Acq. Time: 1:00:42 :PM File: "s1 10 3 1 7 a.w iff Modified: RT Window: Expected RT: Use Relative RT: Yes 30.0 13.1 NO sec min Int. Type: Manual Retention Time: 13.074 min Area: 5920053 counts Height: 4 . lSe+005 cps Start Time: 11.749 min End Time: 14.041 min I S a m p le N a m e: "s110317a058" S a m p le ID: "G L P 10-01-01 -15 -0 04 L M S D A L S S S S 1 3 0 0000 Lab Matrix S p ik e " P e a k N a m e: "P F O S " M a s s e s ) : "499.0/6 0.0 a m u ,499.0 /99.0 am u.4 99.0/13 0.0 am u " I C o m m e n tA n n o ta tio n : Sample Index: se Sample Type: Unknown Concentration: N/A calculated cone: 417. l Acq. Date: 3/18/2011 Acq. Time: 1:24:58 PM File: "s110317a.w iff' Modified: RT Window: Expected RT: Use Relative RT: Yes 30.0 13.1 Ho Si m: Int. Type: Manual Retention Time 13.077 min Area: 11797986 counts Height: 8.4 2e + 005 cps Start Time 11.691 min End Time: 14.445 min PPrriinnttiinngg DT3aMte:StUTduyeSsdLaPy1,WA01p-r0i2l-1055, 2011 Page 96 of 286 Page324of514 Stan V1660305 Printing Date: Tuesday, April 05, 2011 Printing Tjfjpstddy fW illi ./ K |. iiils Intensity, c p s glS8Sgslgsil * J :\ii ss Y 1 IP1!i 111 j" Siilil *s!i if5h|i . 5Hfl tl r f J j g Intensity, c p s | g JJ.Illll.g .,8 8 8 H ? 8 M U H i 3 | II -02-15 Ifif I I I l l p S ==t= p = f s h ts fS * \ IJ. J.J. J.J.J. fIntensity,cps IJ. J. J. J.J. J.. " V s jl * '" ?53? ,, ,, s ?5 s , s s - s 111 g1I 1I 1j 1I ,H,f I1I IHHr- t ?1i; ii t I! I I!P Si Results Name: sll0317a. Page 97 of 286 Page 325 of 514 *Stan V1660305 *3M Environmental Lab IS a m p le N a m e : "s1 1 0 3 1 7 a 0 6 3 " S a r r p le ID : " G L P 1 0 -0 1 -0 1 -1 5 -0 0 5 D u p D A L S S S S 1 6 0 00 0 0 L a b D u p lic a te " P e a k N a m e : " P F O S " M a s s e s ) : "499.0/80.0 am u.4 99.0/99 .0 am u.4 99.0/13 0.0 am u" Com m ent A n n o ta tio n : "" Sample Index: 63 Sample Type: Unknown Concent ration: N/A Calculated Cone:: 321. ng/i Acq. Date: 3/18/2011 Acq. Time: 3:26:09 PM File: "s1 103 17a.w itr Modified: RT Window: Expected RT: Use Relative RT:: Yes 30.0 13.1 NO sec min Int. Type: Manual Retention Time: 13.078 min Area: 10733040 counts Height: 6.69e*00 cps Start Time: 11.672 min End Time: 14.118 min Results Name: sll0317a.rdb I Sa m p le N a m e: "s1103 17a0 64" S a m p le ID: " G L P 1 0 -0 1 -01-15-005 L M S D A L S S S S 1 6 0 0000 L ab Matrix Spike" P e a k N a m e: " P F O S " M a s s e s } : "499.0/60.0 am u.4 99.0/99 .0 am u.4 99.0/13 0.0 am u' I C o m m e n t ~ A n n o ta tio n : "" Sample Index: 64 Sample Type: Unknown Concentration: N/A Calculated Cone: 1120. ng/i Acq. Date: 3/18/201 1 Acq. Time: 3:50:20 PM File: "s110 317 a.w iff' Modified: RT Window: Expected RT: Use Relative RT: Yes 30.0 13.1 No sec min Int. Type: Manual Retention Time: 13.082 min Area: 22829168 counts Height: 1 .S4e +006 cps Start Time: 11.730 min End Time: 14.503 min I Sam p le N a m e: "s110317a065" Sa m p le ID: "G L P1 0-0 1-01-15-006 D A L S S S S 1 6 D B 0000" I P e a k N a m e : "P F O S " M a s s(e s): "499.0/80.0 am u.4 99.0/99 .0 am u.4 99.0/13 0.0 am u" m C o m m e n t "" Annotation: "" Sample Index: 6S Sample Type: Unknown Concentration: N/A Calculated Cone: 361. ng/: Acq. Date: 3/18/201 1 Acq. Time: 4:14:31 PM File: "s110 317 a.w iff" Modified: RT Window: Expected RT: Use Relative RT: Yes 30.0 13 .1 No sec min Int. Type: Manual Retention Time: 13.105 min Area: 11902004 counts Height : 7 .S2 e+oos cps start Time: 11.749 min End Time: 13.945 min I S a m p le N a m e: "s110 317 a066 " S a m p le ID: "GLP10-01- 1 -15 -0 06 D u p D A L S S S S 1 6 D B 0000 Lab D uplicate" P e a k N a m e: " P F O S " M a s s e s ) : "499.0/60.0 am u.4 99.0/99 .0 am u.4 9 9 .Q /1 3 0 .0 am u " I C o m m e n t "" A n n o ta tio n : "" Sample Index: 66 Sample Type: Unknown Concentration: N/A Calculated Cone:: 361. ng/i Acq. Date: 3/18/201 1 Acq. Time: 4:38:45 PM File: "s110317a.w jff' Modified: RT Window: Expected RT: Use Relative RT:: Yes 3 0.0 13.1 NO sec min Int. Type: Manual Retention Time: 13.100 min Area: 11684837 counts Height: 7.17e*00S cps Start Time: 11.691 min End Time: 14.060 min 3 Study0LWQ-Q1-Q2-15t mPrinting Date: Tuesday, April 05, 2011 Printing Page 98 of 286 Page326of514  StanV1660305 *3M Environmental Lab Results Name: sll03l7a.rdb PPrriinnttiinngg TD-ajMte:stuTdyu:esd^a0y0,1A-0p2ri-l1505, 2011 Page 99 of 286 Page327of514 Stan V1660305 *3M Environmental Lab I Sam p le N am e: "s110317a071" Sam p le ID: 'G L P10 -0 1-0 1-15-006 D A L S S SS1 1 0 0005* P e a k N a m e : " P F O S * M a s s e s ) : -499.0/8 0.0 am u.499.0/99.0 am u,4 99.0/13 0.0 am u" I C om m ent: " * A n n o tation :"" Sample Index: 71 Sample Type: Unknown Concentration: N/A Calculated Cone: No intercept Acq. sate: 3/18/2011 Acq. Time: 6:39:58 PM Rile: "s1 1 0 3 l7 a .w tfr Modified: RT Window: Expected RT: Use Relative RT: Yes 30.0 13.1 sec min Area : Height: Start Time: End Time: 3.84e+006 c p s 11.74 9 min 13.829 Results Name: sll0317a.rdb I Sam p le N am e: "s110317a072" Sam p le ID: -G LP 10-01 -01 -1 5-0 08 Dup D A L S S S S 1 1 0 0005 Lab D up licate" P e a k N a m e : " P F O S " M a s s e s ) : "499.0/8 0.0 am u ,49 9.0 /99.0 a m u ,499.0/130.0 am u" I C o m m e n t ~ A n n o ta tio n : "" Sample Index: 72 Sample Type: Unknown Concentration: N/A Calculated Cone: 322. ng/i Acq. Date: 3/18/2011 Acq. Time: 7:04:13 PM File: "s110 317 a.w ifT Modified: RT Window: Expected RT: Use Relative RT: Yes 30.0 13.1 sec min Int. Type: Manual Retention Time: 13.062 min Area: 10050414 counts Height: 6.2ie+oos cps Start Time: 11.749 min End Time: 13.636 min [S a m p le N a m e : " s 1 1 0 3 1 7 a 0 7 3 " S a n p l e ID : " G L P 1 0 -0 1 -0 1 -1 5 -0 0 8 L M S D A L S S S S 1 1 0 0 0 0 5 L P e a k N a m e: " P F O S * M a s s e s ) : "499.0/6 0.0 a m u ,499.0/99.0 a m u ,499.0/130.0 am u" C om m e n t -- Annotation: " Sample Index; 73 Sample Type: Unknown Concentration: N/A Calculated Cone: 239. n Acq. Date: 3/18/2011 Acq. Time: 7:28:26 PM Modified: RT Window: Expected RT: use Relative RT: Yes 30.0 13.1 j Matrix Spike" File: -s11 0317 a.w ifT Int. Type: Retention Time: 8589890 counts Height: 6.14e+005 cps start Time: 11.787 min End Time: 13.964 min rS a m p le N a m e : "8 1 1 0 3 1 7 3 0 7 4 - S a m p le ID : " G L P 1 0 -0 1 -0 1 -1 5 -0 0 9 D A L S S S S 2 0 0 0 0 0 0 " P e a k N a m e: " P F O S " M a s s e s ) : "499.0/6 0.0 a m u ,499.0 /99.0 a m u ,499.0/130.0 am u' B C o m m e n t "" A n n o ta tio n : -- Sample Index: 74 Sample Type: Unknown Concentration: N/A Calculated Cone:: 136. ng / Acq. Date: 3/18/2011 Acq. Time: 7:52:43 PM File: "s110317a.w ifT Modified: RT Window: Expected RT: Use Relative RT:: Yes 30.0 13.1 No sec min Int. Type: Manual Retention Time: 13.092 min Area: s:190446 counts Height: 3.76e*005 cps Start Time: 11.826 min End Time: 13.67S min Printing Date: Tuesday, April 05, 2011 T3MSty:LF10-01-02-15Printing Page 100 of 286 Page328of514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 TMStdd/GLP10-01-02-15Printing 3 Page 101 of 286 Page329of514 Stan V1660305 *3M Environmental Lab I S a m p le N a m e: "s1 1 0 3 1 7 a0 7 9 " S a m p le ID: "1 0 006-80 so lven t blank" File: s110317a.w tfT P e a k N a m e: " P F O S " M a s s(e s): "499.0/80.0 ai M C o m m e n t ~ A nnotation: "" u .499.0/130.0 am u" Sample Index: 79 Sample Type: Double Blank Concentration: 0,00 ng/mL Calculated Cone: N/A Acq. Date: 3/18/2011 Acq. Time: 9:54:00 PM Modified: RT Window: Expected RT: Use Relative RT: Yes 3o.o 13.1 No sec min Int. Type: Manual Retention Time: 13.017 min Area: 14242 counts Height : e .07e+002 Start Time: ll.903 End Time: 13.309 Results Name: sll0317a.rdb [S a m p le N a m e : "s1 1 0 3 1 7 a 0 B 0 " S a m p le ID : "G L P 1 0 -0 1 -0 1 -1 S -0 1 0 D A L S S S S 2 0 D B 0 0 00" P e a k N a m e: "P F O S " M a s s e s ) : "499.0/8 0.0 a m u ,499.0/99.0 a m u ,499.0/130.0 am u* SamCpolmem eInntde" *x:A n n o ta tio8n0: "" Sample Type: Unknown concentration: N/A Calculated Cone: 1 1 6 . n< Acq. Date: 3/18/2011 Acq. Time: 10:18:14 PM File: "s1 1 0 3 1 7 a.w ifr Modified: RT Window; Expected RT: Use Relative RT: Int. Type: Manual Retention Time: 13.075 min '83572 counts Height: 3.36e+00S cps start Time: 11.710 min End Time: 13.964 min I Sa m p le N a m e: "s110 317 a081 " Sa m p le ID: GLP10-0 1-01-15-010 D up D A L S S S S 2 0 D B 00 00 L ab D uplicate" | P e a k N a m e: " P F O S " M a s s e s ) : "499.0/80.0 a m u ,499.0/99.0 am u,4 99.0/13 0.0 am u" 1 C o m m e n t "" Annotation: ~ Sample Index: 81 sample Type: Unknown Concentration: N/A Calculated Cone:: 191. ng/ Acq. Date: 3/18/2011 Acq. Time: 10:42:35 PM File: "s1 1 0 3 1 7 a.w iT Modified: RT Window: Expected RT: Use Relative RT:. Yes 30.0 13.1 NO sec min Int. Type: Manual Retention Time: 13.038 min Area: 7550935 counts Height : 4.83e*00S cps start Time: 11.730 min End Time: 13.656 min I Sam p le N am e: "s110317a082" Sam p le ID: "G L P 10-01-01 -1S-010 L M S D A L S S S S 2 0 D B 0000 Lab Matrix Spike" P e a k N a m e : " P F O S " M a s s e s ) : "4 9 9 .0 / 6 0 .0 a: u .4 9 9 .0 / 9 9 .0 a m u ,4 9 9 .0 / 1 3 0 .0 am u " C o m m e n t "" A nn otation : "" Sample Index: 82 Sample Type: Unknown Concentration: N/A Calculated cone: 514. ng/mL Acq. Date: 3/18/2011 Acq. Time: 11:06:50 PM F ile: "s 1 1 0 3 1 7 a .w iT Modified: RT window: Expected RT: Use Relative RT: Yes 30.0 13.1 No sec min Int. Type: Manual Retention Time: 13.048 min Area: 146892S7 counts Height: 1.04e+006 CpS Start Time: 11.749 min End Time: 14.099 Printing Date: Tuesday, April 05, 2011 TgWStUdyGLP10-01-02-15Printing Page 102 of 286 Page330of514 Stan V1660305 *3M Environmental Lab I S a m p le N a m e: "s110317a083* Sa m p le ID: 'G L P 1 0 -0 1 -0 1 -1 S -0 1 1 D A L S S S S 1 9 0 0000" P e a k N a m e: " P F O S " M a s s e s ) : "499.0/80.0 a m u ,499.0 /99.0 a m u ,499.0/130.0 a m u ' C o m m e n t"" A n n o tation :"" sample Index: 83 Sample Type: Unknown Concentration: N/A Calculated Cone: S88. ng/i Acq. Date: 3/IB/2011 Acq. Time: 11:31:06 PM File: "s1 1 0 3 l7 a .w iff' Modified: RT Window: Expected RT: Use Relative RT: Yea 30.0 13.1 Ho sec min Area : Height : Start Time: End Time: 8.75e+OOS 11.691 13.713 Results Name: sll0317a.rdb S am p le Nam e: "s110317a084* S am p le ID: "G LP10-01-01-15-011 D u p D A L S S S S 1 9 0 0000 Lab D uplicate" IP e a k N a m e : " P F O S " M a s s (e s ): '4 9 9 .0 / 6 0 .0 a C o m m e n t: ~ A n n o ta tio n : "" Sample Index: 84 u ,499.0/99.0 a m u .499.0/130.0 am u* Sample Type: Unknown Concentration: N/A Calculated Cone : 422. ng/j Acq. Date: 3/18/2011 Acq. Time: 11:55:21 PM File: "s1 1 0 3 1 7 a .w iff Modified: RT Window: Expected RT: Use Relative RT : Yes 30.0 13.1 HO sec min Int. Type: Manual Retention Time: 13.070 min Area: l:2044611 counts Height: 7.S6e+005 cps start Time: 11.730 min End Time: 13.636 min I Sa m p le N a m e: "s1103 17a0 85" S a rrp le ID: "G L P 1 0 -0 1 -0 1 -1 5-011 L M S D A L S S S S 1 9 0 0000 L P e a k N a m e : 'P F O S * M a s s e s ) : *499.0/80.0 a m u .49 9.0 /99.0 am u.4 99.0/13 0.0 am u* m C o m m e n t ** A nnotation: "* Sample Index: 85 Sample Type: Unknown Concentration: N/A Calculated Cone:: 576. ng/t Acq. Date: 3/19/2011 Acq. Time: 12:19:33 AM ) Matrix Spike" File: *s110317a.w rfT Modified: RT Window: Expected RT: Use Relative RT:: Yes 30.0 13.1 HO sec min Int. Type: Manual Retention Time: 13.062 min Area: 15995655 counts Height : l.09e+006 cps stort Time: 11.710 min End Time: 14.002 min I Sam p le N am e: "s110317a086* Sam p le ID: " G L P 10-01-01-15-012 D A L S S S S 1 9 0 00 0 5 ' P e a k N a m e : 'P F O S * M a s s e s ) : *499.0/80.0 am u.4 99.0/99 .0 am u.4 99.0/13 0.0 a tm " C om m en t ~ Annotation: " Sample Index: 86 Sample Type: Unknown Concentration: N/A Calculated Cone:: 430. ng/i Acq. Date: 3/19/201 1 Acq. Time: 12:43:49 AM File: "s110 317 a.w rff Modified: RT Window: Expected RT: Use Relative RT:. Yes 30.0 13.1 Ho sec min Int. Type : Manual Retention Time: 13.066 min Area: 12956962 counts Height : 8.22e*005 cps Start Time: 11.710 min End Time: 14.022 min Printing Date: Tuesday, April 05, 2011 TMStJdGLP10-01-02-15Printing 3 Page 103 of 286 Page 331 of514 Stan V1660305 Results Name: sll0317a.rdb ting Date: Tuesday, April 05, 2011 t in g T3W S tl]<fy g L :[S f0 .^_ 0 2 -i5 Page 104 of 286 Page 332 of 514 *Stan V1660305 *3M Environmental Lab Sample Name: "s110317a091" Sarrple ID: "GLP10-01-01-15-014 LMS DAL SS SS15 0 0000 Lab Matrix Spike" Peak Name: " PFOS* M asses): "499.0/80.0 amu,499.0/99.0 amu.499.0/130.0 amu" B Com m ent " Annotation: " Sam ple In d e x : 91 Sam ple T ype : Unknown C o n c e n tra tio n : N /A C a lc u la te d Cone: 835. ng/m L 1.15e6 Acq. D ate : 3/19 /20 11 Acq. T im e: 2 : 4 5 : 0 6 AM l-iw e o File: "s11 03 17 a.w ir M o d ifie d : RT W indow : Expected RT: Use R e la tiv e RT: Yes 30 .0 13 .1 Mo sec m in 1 00e6 9.50e5 In t. Type: Manual R e te n tio n T im e : 1 3 .0 2 7 m in A re a : 19100771 cou nts H e ig h t, S t a r t Tim e: 1 . lBe+006 ops 1 1 .7 4 9 m in End T im e: 1 3 .8 2 9 m in 9.00e5 8.50e5 R nOeh 3 7 SOeS 7.00e5 Results Name: sll0317a.rdb Sample Name: "s110317a092" Sample ID: "GLP10-01-01-15-015 DAL SS SS17 0 0000" 1 Peak Name: "P FOS" Mass(es): *499.0/80.0 amu,499.0/99.0 amu.499.0/130.0 amu" B Comment Annotation:"" sam p le In d e x : 92 Sam ple T yp e : Unknown C o n c e n tra tio n : C a lc u la te d Cone: N /A 78 .5 ng/m L .j Z.3eo Acq. D ate : Acq. T im e: 3 /19 /20 11 3 : 0 9 : 2 1 AM 22e5 M o d ifie d : RT W indow : Yea 30 .0 sec 2.1e5 2.0e5 E xpected RT: Use R e la tiv e RT: 13 .1 No m in 1.9e5 File: "s110317a.wifr In t. Type: M anual R e te n tio n T im e : 1 3 .0 8 8 m in A re a : 3215756 cou nts H e ig h t: S t a r t T im e: 2.35e+oos cps 1 1 .8 0 7 m in End T im e: 1 3 .8 6 7 m in 1.8e5 ._ _ 1 6e5 1.5e5- 1.4e5 ZZ . 1.2e5 c 5.50e5 f 1.1e5 - 5,00e5 4.50e5 - 1.0e5 9,0e4 4.00e5 8.0e4 3,50e5 7.0e4 3,00e5 6.0e4 2.50e5 5.0e4 2 .0 0 e 5 1.50e5 I.OOeS 12.57s. ii 4.0e4 3.0e4 2.0e4 5.00e4 0.00 1- 2 4 6 8 10 12 14 16 18 20 22 1.0e4 0.0 k 2 4 6 8 10 12 14 16 18 20 22 105 209 313 416 520 624 728 832 936 1039 1143 105 209 313 416 520 624 728 832 936 1039 1143 Time, min Time, min Sample Name: " s110317a093" Sample ID: "GLP10-01-01-15-015 Dup DAL SS SS17 0 0000 Lab Ouplicate* Fe: "s110317a.w ifr Sample Name: "s1 10317a094" Sample ID: "GLP10-01-01-15-015 LMS DAL SS SS17 0 0000 Lab Matrix Spike" File: "s110317a.witT 1 Peak Name: "PFOS" M a s te s ): " 499.0/80.0 amu,499.0/99.0 amu.499.0/130.0 amu" 1 C om m ent " Annotation: " * 1 Peak Name: "P FOS" M asses): "499.0/80.0 amu.499.0/99.0 amu,499.0/130.0 amu' B C om m ent"" Annotation:"" Sam ple In d e x : 93 Sam ple In d e x : 94 Sam ple Type: Unknown Sam ple T yp e : Unknown C o n c e n tra tio n : N /A C a lc u la te d Cone: 7 7 .4 Acq. D ate : 3/19 /20 11 ng/m L 2.5e5 2.4e5 C o n c e n tra tio n : N /A C a lc u la te d Cone: 186. Acq. D ate : 3 /19 /20 11 ng/m L 52e5J 5.0e5 Acq. Tim e: 3 : 3 3 : 3 5 AM 2 3e5 Acq. Tim e: 3 : 5 7 : 4 9 AM ^ M o d ifie d : RT W indow : E xp ected RT: use R e la tiv e RT: Yes 30 .0 1 3 .1 No sec m in 2.2e5 2.1e5 20e5 M o d ifie d : RT w in d o w : E xp ected RT: Use R e la tiv e RT: Yes 30 .0 13 .1 No sec m in 46e5 4.4e5 4 2e5 In t. Type: R e te n tio n Tim e: Manual 1 3 .0 7 8 m in A re a : 3288444 counts H e ig h t: 2 .50e*005 cps S t a r t Tim e: 11 .7 30 m in End T im e : 13 .8 87 m in 1 9e5 1.8e5 175 1 ' e3 1 6e5 1.5e5 1.4e5 1.3e5 - c c 1.1e5 1.0eS 9.0e4 In t. Type: Manual R e te n tio n Tim e: 1 3 .0 6 0 m in A rea: 6753923 cou nts H e ig h t: 5.26e+00S cps S t a r t T im e : 1 1 .7 4 9 m in End T im e: 1 3 .8 4 8 m in 4.0e5 3.8e5 3 6e5 3.4e5 3.2e5 3.0e5 | 2.8e5 2.0e5 1.8e5 1.6e5 5.0e4 4.0e4 3.0e4 2.0e4 1.0e4 00 12.56s, rki L. - 2 4 6 8 10 12 14 16 18 20 22 105 209 313 416 520 624 728 832 936 1039 1143 Time, min 1.0e5 6.0e4 6.0e4 4.0e4 0.0 12.55s. 2 4 6 8 10 12 14 16 18 20 22 105 209 313 416 520 624 728 832 936 1039 1143 Time, min Printing Date: Tuesday, April 05, 2011 MstUdyGLPfO-01-02-15Printing T Page 105 of 286 Page333of514 Stan V1660305 +3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 T3MStUdLPO-01-Q2-15Printing Page 106 of 286 Page334of514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 TjMStUfySLP10-01-02-15Printing Page 107 of 286 Page335of514 V1660305 Results Name: sll0317a.rdb Printing Printing sDate: Ti^j^ tTauaeysd^aiyi t,t oAwpr-i0l2-1055, 2011 Page 108 of 286 Page 336 of 514 **3SMtanEnVv1ir6o6n0m30e5ntal Lab I Sample Name: "s110317a107" Sample ID: 'GLP10-01-01-15-021 DAL SS SS30 0 0000" | Peak Name: "PFOS" Masses): "499.0/80.0 amu,499.0/99.0 amu,499.0/130.0 amu" m Comment "" Annotation: "* Sample Index.: 107 Sample Type: Unknown Concentratloi1: N/A Calculated Cone: 367. ng/t Acq. Date: 3/19/2011 Acq. Time: 9:13:13 AM File:~s1103l7a.wifT Modified: RT window: Expected RT: Dae Relative RT: Yes 30.0 13.1 NO aec min Int. Type: Manual Retention Time: 13.054 min Area: 11631371 counts Height: 7.38e+00S cps start Time: 11.749 min End Time: 14.022 min Results Name: sll0317a.rdb ISample Name: "s110317a108' Sample IO: "GLP10-01-01-15-021 Dup DAL SS SS30 0 0000 Lab Duplicate" Peak Name: 'PFOS' Masses): "499.0/80.0 amu,499.0/99.0 amu,499.0/130.0 amu* Comment ~ Annotation: " Sample Index: 108 Sample Type: Unknown Concentration: N/A Calculated Cone: 33S . ng, Acq. Date: 3/19/2011 Acq. Time: 9:37:2S AM File: "s11D317a.wir Modified: RT Window: Expected RT: Use Relative RT: Yes 30.0 13 .1 NO sec min Int. Type: Manual Retention Time: 13.090 min Area: 10970731 count! Height : 6.8 6e+OOS cps Start Time: 11.710 min End Time: 13.7S2 min I Sample Name: "s110317a109" Sample ID: "GLP10-01-01-15-021 LMS DAL SS SS3000000 Lab Matrix Spike" | Peak Name: 'PFOS' Masses): "499.0/80.0 amu,499.0/99.0 amu,499.0/130.0 amu' 1 Comment " Annotation: ~ Sample Index: 109 Sample Type: Unknown Concentration: N/A Calculated Cone: 1340. ng/i Acq. Date: 3/19/2011 Acq. Time: 10:01:36 AM File: *s110317a.wifT Modified: RT Window: Expected RT: use Relative RT: Yes 30.0 13.1 No sec min Int. Type: Manual Retention Time: 13.008 min Area: 23254043 counts Height: 1 .54e+006 cps start Time: 11.749 min End Time: 13.848 min ISample Name: 's110317a110" Sample ID: 'GLP10-01-01-15-022 DAL SS SS30 0 0005" Peak Name: "PFOS* Masses): '499.0/80.0 amu,499.0/99.0 amu,499.0/130.0 amu' SamCpolmemeInndt e""x:Annotat1io1n0: ~ Sample Type: Unknown Concentration: N/A Calculated Cone: Acq. Date: Acq. Time: File: "s110317a.wifr Modified: RT Window: Expected RT: Use Relative RT: Area: Height : start Time: End Time: 2 .aoe+oos 11.84 S 13.559 PPrriinnttiinngg DateS:tMTuye^s^d^a1y0,-0A1p-0r2il-1055, 2011 Page 109 of 286 Page337of514 *Stan V1660305 Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 Printing gfoa-po-W _02-i 5 Page 110 of 286 Page 338 of 514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 TMStUfySLPf0-01-02-15Printing 3 Page 111 of 286 Page339of514 Stan V1660305 *3M Environmental Lab I Sample Name: *51103178119* Sample ID: "GLP10-01-01-1 Peak Name: "PFOS" Masses): '499.0/80.0 amu,499.0/99.0 m Comment ~ Annotation: ~ sample Index: 119 Sample Type: Unknown Concentration: N/A Calculated Cone: No Intercept Acq. Date: 3/19/2011 Acq. Time: 2 ;03 :S6 PM Modified: RT Window: Expected RT: Use Relative RT: Yes 30.0 13.1 NO sec ain Int. Type: Manual Retention Time: 13.066 ain Area: 74:214776 counts Height: :2 .SSe+006 Cp8 start Time: 11.710 ain End Time: 13.771 ain 4 DAL SS SS25 0 0000" 1.499.0/130.0 amu' :"s110317a.wrtr Results Name: sll0317a.rdb I Sample Name: "s110317a120" Sample ID: "GLP10-01-01-15-024 Dup DAL SS SS25 0 0000 Lab Duplicate" Peak Name:' PFOS' Masses):' 499.0/80.0 amu,499.0/99.0 amu.499.0/130.0 arra/ 1 Comment "" Annotation: -- Sample Index: 120 Sample Type: Unknown Concentration: N/A Calculated Cone:: No Intercept Acq. Date: 3/19/201 1 Acq. Time: 2:28:10 PM File:' s110317a.wifT Modified: RT Window: Expected RT: Use Relative RT:: Yes 30.0 13.1 NO sec min Int. Type: Manual Retention Time: 13.058 ain Area: 65591239 counts Height: 2.67e*006 cps Start Time: 11.691 min End Time: 14.349 ain I Sample Name: "s110317a121" Sarrple ID: "GLP1tW31-01-T5^024 LMS DAL SS SS25 0 0000 la b Matrix Spike" Peak Name: "PFOS* Masses): "499.0/80.0 amu.499.0/99.0 amu.499.0/130.0 amu' I Comment -- Annotation:-- Sample Index: 121 Sample Type: Unknown Concentration: N/A Calculated Cone: No Intercept Acq. Date: 3/19/2011 Acq. Time: 2:52:23 PM File; "s110317a.wtfT Modified: RT Window: Expected RT: Use Relative RT: NO Int. Type: Manual Retention Time: 13.056 min 124642557 counts Height: S.39e+006 cps Start Time: 11.730 Bin End Tiae: 13.629 ain I Sample Name: ' s110317a122" Sample ID: "GLP1CW31-01-1S-025 DAL SS SS2S 00005" | Peak Name: ' PFOS' Masses): *499.0/80.0 amu,499.0/99.0 amu,499.Q/130.0 amu* Comment "" Annotation: "" Sample Index: 122 Sample Type: Unknown Concentration: N/A Calculated Cone:: No Intercept Acq. Date: 3/19/2011 Acq. Time: 3:16:35 PM File: "s110317a.wtfT Modified: RT Window: Expected RT: Use Relative RT:: Yes 30.0 13.1 NO sec min Int. Type: Manual Retention Time: 13.056 min Area: 75093227 counts Height : 2.19e+006 cps Start Time: 11.672 min End Time: 13.694 min Printing Date: Tuesday, April 05, 2011 TgMStagy LPIO-01-02-15Printing ^ Page 112 of 286 Page340of514 Stan V1660305 *3M Environmental Lab I Sample Name: "51103178123" Sample IO: "GLP10-01-01-15-025 Dup DAL SS SS25 0 0005 Lab Duplicate' Peak Name: 'PROS' Mass(es): '499. .0 amu,499.0/99.0 amu,499.0/130.0 amu" Comment ~ Annotation: ~ Sample Index: 123 Sample Type: Unknown Concentration: N/A Calculated Cone:: No Intercept Acq. Date: 3/19/2011 Acq. Time: 3:40:46 RM File: "s110317a.wiTT Modified: RT Window: Expected RT: Use Relative RT;: Yes 30.0 NO sec In Int. Type: Manual Retention Time: 13.036 min Area: 77233676 count! Height: 2.34e*006 cps Start Time: 11.691 min End Time: 13.771 min Results Name: sll0317a.rdb Sample Name: 's110317a124` Sample ID: 'GLP10-01-01-15-025 LMS DAL SS SS25 0 0005 Lab Matrix Spike' Peak Name:'PFOS" Masses): "499.0/80.0 amu.499.0/99.0 amu,499.0/130.0 amu* I Comment Annotation: " Sample Index: 124 I Sample Type: Unknown Concentration: N/A Calculated Cone: No Intercept Acq. Date: 3/19/2011 Acq. Time: 4:04:59 PM File: 's110317a.wifr Modified: RT Window: Expected RT: Ose Relative RT: Int. Type: Retention Time: min Area: 31329262 counts Height: 5.34e+006 cps Start Time 11.710 End Time: 13.771 [SampleName:"s110317a125` Sample ID: 'GLP10-01-01-15-026 DAL SS SS25 0 0015" Peak Name: 'PFOS" Masses): '499. 499.0/99.0 amu.499.0/130.0 amu* 1 Comment " Annotation: sample Index: 125 Sample Type: Unknown Concentration: N/A Calculated Cone: No Intercept Acq. Date: 3/19/2011 Acq. Time: 4:29:13 PM File: "s110317a.wifr Modified: RT Window: Expected RT: Use Relative RT: Yes 30.0 13.1 No sec ain Int. Type: Manual Retention Time: 13.03S min Area: 72 123751 counts Height: 2.27e*006 cps Start Time: 11.653 End Time: 13.694 min I pSample Name: "s110317a126" Sample ID: "GLP10-01-01-15-026 Dup DAL SS SS25 0 0015 Lab Duplicate' Peak Name: 'PFOS' Mass/es): "499.0/80.0 arru.499.0/99.0 amu,499.0/130.0 amu' Ccomment *" Annotation: ~ Sample Index: 126 Sample Type: Unknown Concentrt ion: N/A Calculated Cone:: No Intercept Acq. Date: 3/19/2011 Acq. Time: 4:53:24 PM File: "s110317a.wifT Modified: RT Window: Expected RT: Use Relative RT:: Yes 30.0 13.1 NO sec min Int. Type : Manual Retention Time: 13.064 min Area: 70917688 counts Height : 2.19e+006 cps Start Time: 11.710 min End Time: 13.790 min Printing Date: Tuesday, April 05, 2011 T:QMSft0y23L.P1O-O1-O2-15Printing Page 113 of 286 Page 341 of514 *Stan V1660305 *3M Environmental Lab I Sample Name: "s110317a127" Sample ID: "GLP10-01-01-15-026 IMS DAL SS SS25 0 0015 Lab Matrix Spike" I Peak Name: "PFOS" Mass(es): "499.0/80.0 amu,499.0/99.0 amu,499.0/130.0 amu" m Comment Annotation: "" Sample Index: 127 Sample Type: Unknown Concentration: N/A Calculated Cone: No Intercept A cg. Date : 3/19/201 1 Acq. Time: 5:17:34 PM File: "s110317a.wff' Modified: RT Window: Expected RT: Use Relative RT: Yes 30.0 13.1 No sec min Int. Type : Manual Retention Time: 13.035 min Area: 121964S76 counts Height: 5.36e+006 cps Start Time: 11.710 min End Time: 13.925 min I Sample Name: "s110317a129" Sanale ID: "GLP10-1-01-15-027 Dup DAL SD SD22 0 0000 Lab Duplicate" [ Peak Name: "PFOS" Masses): "499.0/80.0 amu,499.0/99.0 auu.499.0/130.0 amu" Comment " Annotation: " sample Index: 129 Sample Type: Unknown Concentration: N/A Calculated Cone: No Intercept Acq. Date: 3/19/2011 Acq. Time: 6:06:02 PM File: "s110317a.wifT Modified: RT Window: Expected RT: use Relative RT: Yes 30.0 13.1 NO sec min Int. Type: Manual Retention Time: 13.073 min Area: 73973223 counts Height: 2.25e+006 cps start Time: 11.691 min End Time : 13.906 min Results Name: sll0317a.rdb [Sample Name: "s110317a128" Sample ID:"GLP10-01-01-1S-027 DALSDSD22 00000" I Peak Name: "PFOS" Mass(es): "499.0/80.0 amu.499.0/99.0 amu.499.0/130.0 amu" Comment "" Annotation: -- Sample Index: 126 Sample Type: Unknown Concentration: N/A 2.6e6- Calculated Cone No Intercept Acq. Date: 3/19/2011 2.5e6 Acq. Time: 5:41:46 PM 2.4e6 File: "s110317a.wifT Modified: RT Window: Expected RT: Use Relative RT Yes 30.0 13.1 No sec min 2.3e6 2.2e6 2.1e6 Int. Type: Manual Retention Time: 13.064 min Area: 83616628 counts Height: 2 .6 1 e+ 0 0 6 cps start Time: 11.710 min End Time: 13.029 min 2.0e6 1.9e6 1.8e6 1.7e6 1.6e6- 1.5e6- 1.4e6- 1.3e6- 1.2e6- 1.1e6- 1.0e6- 9.0e5- 6.0e5- 7.0e5- 6.0e5- 5.0e5- 4.0e5 3.0eS 2.0e5 1.0e5- 0.0 ISample Name: "s110317a130" Sample ID: "GLP10-01-01-15-027 LMS DAL SD SD22 0 0000 Lab Matrix Spike" Peak Name: "PFOS" Mass(es): "499.0/60.0 amu.499.0/99.0 amu,499.0/130.0 amu' Comment Annotation: Sample Index: 130 Sample Type: Unknown Concentration: N/A Calculated Cone : No Intercept Acq. Date: 3/19/2011 Acq. Time: 6:30:16 PM File: "s110317a.wiff Modified: RT Window: Expected RT: Use Relative RT : Yes 30.0 13.1 No sec min Int. Type: Manual Retention Time: 13.064 rain Area: l:51007664 counts Height: 5.72e*O06 cps Start Time: 11.710 min End Time: 13.687 min Printing Date: Tuesday, April 05, 2011 TMStUdyGLPf0-01-02-15Printing 3 Page 114 of 286 Page342of514 Stan V1660305 Results Name: s!10317a. Printing Date: Tuesday, April 05, 2011 Printing T j ^ p g t _02-15 Page 115 of 286 Page 343 of 514 *Stan V1660305 *3M Environmental Lab Results Name: sll03l7a.rdb Printing Date: Tuesday, April 05, 2011 stiGLP1Q--Q1-Q2-15Printing i Page 116 of 286 Page344of514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 TMStUdyGLPfD-01-02-15Printing 3 Page 117 of 286 Page345of514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 T3MStJdLPfQ-Q1-Q2-15Printing Page 118 of 28G Page346of514 *Stan V1660305 Results Name: sll0317a. Printing Date: Tuesday, April 05, 2011 Printing .02-i 5 Page 119 of 286 Page 347 of 514 *Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 Tg^St&0?^^10-01-02-15Printing Page 120 of 286 Page348of514 Stan V1660305 *3M Environmental Lab I Sample Name: "s110317a155" Sample ID: "GLP10-01-01-1S-034 DAL SS SS24 0 0000" I Peak Name:' PFOS' Masses): ' 499.0/60.0 amu.499.0/99.0 amu,499.0/130.0 amu" m Comment " Annotation: " Sample index: 1SS Sample Type: Unknown Concentration: N/A Calculated Cone: Ho Intercept Acq. Date: 3/20/2011 Acq. Time: 4:36:08 AM File:"s110317a.wir Modified: RT Window; Expected RT: Use Relative RT: Yes 30.0 13.1 Ho sec Bin Int. Type: Manual Retention Time: 13.066 min Area: 33096194 counts Height: 1.36e+006 cps start Time: 1 1 .710 min End Time: 13.771 min Results Name: sll0317a.rdb I Sample Name:'s110317a156" Sarrple ID: "GLP10-01-01-15-034 Dup DAL SS SS24 0 0000 Lab Duplicate" Peak Name: "PFOS' Masses): "499.0/80.0 amu.499.0/99.0 amu,499.0/130.0 amu' M Comment " Annotation: ~ Sample Index: 156 Sample Type: Unknown Concentration: N/A Calculated Cone: Ho Intercept Acq. Date: 3/20/201 1 Acq. Time: 5:00:10 AM File: "s110317a.wiff Modified: RT Window: Expected RT: Use Relative RT: Yes 30.0 13.1 No sec min Int. Type: Manual Retention Time: 13.059 min Area: 39427079 counts Height : 1.56e+006 cps Start Time: 11.710 min End Time: 13.675 min I SampleName:' s110317a157" SampeD:'GLP10-01-01-15-034 LMSDAL SS SS24 0 0000 Lab Matrix Spike' | Peak Name: 'PFOS* Masses): "499.0/60.0 amu.499.0/99.0 amu.499.0/130.0 amu' Comment ~ Annotation: ~ sample Index: 157 Sample Type: Unknown Concentration: N/A 2.5e6 Calculated Cone Ho Intercept Acq. Date: 3/20/2011 2.4e6 Acq. Time: 5:24:33 AM 2.3e6 File: us110317a.wrfT Modified: RT Window: Expected RT: Use Relative RT Yes 30.0 13 .1 No sec min 2.2e6 2.1e6 2.0e6 Int. Type: Manual Retention Time: 13.069 min Area: 52092620 counts Height : 2.53e+006 cps Start Time: 11.691 min End Time: 13.829 in 1.9e6 1.8e61.7e6 1.6e6 1.5e6 1.4e6 1.3e6 1.2e6 1.1e6 1.0e6 9.0e5 8.0e5 7.0e5 6.0eS 5.0e5 4.0e5 3.0e5 2.0e5 1.0e5 0.0 105 209 313 416 520 624 726 632 ____________________________________ Time, min________________ Printing Date: Tuesday, April 05, 2011 StUfyL;? 1-02-15Printing ft>$ ISample Name: Ms110317a156' Sample ID: ' GLP10-01-01-15-035 DAL SS SS24 0 0005" Peak Name: ' PFOS" Masses): "499.0/80.0 amu.499.0/99.0 amu.499.0/130.0 amu' SamCpolmemeInntde~x:Annotat1io5n8: " Sample Type: Unknown Concentration: N/A calculated Cone: No Intercept Acq. Date: 3/20/2011 Acq. Time: S :48:48 AM File: 's110317a.wifr Modified: RT Window: Expected RT: Use Relative RT: Yes 30.0 13.1 No sec min Int. Type: Manual Retention Time: 13.048 min Area: 56594002 counts Height : 2 .08e00<> cps Start Time: 11.730 min End Time: 13.733 ain Page 121 of 286 Page349of514 Stan V1660305 Results Name: s!10317a.rdb Printing Date: Tuesday, April 05, 2011 Printing 5 Page 122 of 286 Page 350 of514 Stari V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 T3MStUdSLPfQ 1-Q2-15Printing - Page 123 of 286 Page 351 of514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb StudyGLP1Q-Q1-Q2-15tjmPrinting Date: Tuesday, April 05, 2011 Printing Page 124 of 286 Page352of514 *Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 T$MStuUy=GLP1Q-01-Q2-15Printing Page 125 of 286 Page353of514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 MstUdyGL:Pf0-01-02-15Printing T5 Page 126 of 286 Page354of514 Stan V1660305 Results Name: s!10317a.rdb Printing Date: Tuesday, April 05, 2011 Printing T^stddy SUPfO-W -02-15 Page 127 of 286 Page 355 of 514 Stan V1660305 Results Name: s!10317a.rdb Printing Date: Tuesday, April 05, 2011 Printing 5 Page 128 of 286 Page 356 of514 Stan V1660305 Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 Printing 5 Page 129 of 286 Page 357 of514 *Stan V1660305 Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 Printing TSmastuUy^fSTO-W-CE-IS Page 130 of 286 Page 358 of514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 TMStUdyGL:Pf0-$1-02-15Printing 3 Page 131 of 286 Page359of514 V1660305 Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 Printing _02-1 5 Page 132 of 286 Page 360 of 514 *Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 TMStUdGLPiO1-02-15Printing 3 Page 133 of 286 Page 361 of514 *Stan V1660305 Results Name: sll0317a. Printing Date: Tuesday, April 05, 2011 Printing -02-15 Page 134 of 286 Page 362 of 514 Stan V1660305 Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 Printing Page 135 of 286 Page 363 of 514 *Stan V1660305 Results Name: sll0317a. Printing Date: Tuesday, April 05, 2011 Printing 5 Page 136 of 286 P a g e 3 6 4 o f5 1 4 *Stan V1660305 Results Name: sll0317a.rdb T$wstiMyPrinting Date: Tuesday, April 05, 2011 Printing QL=PfO-W -02-15 Page 137 of 286 Page 365 of 514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 StUdySL:Pf0-Q1-02-15Printing Page 138 of 286 Page366of514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 StUdyGLPf0$1-02-15Printing Page 139 of 28G Page367of514 *Stan V1660305 Results Name: sll0317a.rdb Printing Printing TDat^e:s tTjueysdya:y,- QAp2ri-l1 055, 2011 Page 140 of 286 Page 368 of 514 Stan V1660305 *3M Environmental Lab ISanale Name: "s110317a07Z' Sample ID: "GLP10-01-01-15-008 Dup DAL i SSS11 0 0005 Lab Duplicate" Peak Name: "MPFOS" Mass(es): "503.0/80,0 ami" Comment "" Annotation: ~ Sample index: 72 File: "s110317a.wrfP' Results Name: sll0317a.rdb I Sample Name: "s110317a073" Sample ID: "GLP10-01-01-15-008 LMS DAL SS SS11 0 0005 Lab Matrix Spike" Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu" Comment"" Annotation: Sample index: 73 Sample Type: Unknown Concentration: N/A Calculated Cone: 2.79 ng/mL Acq. Date: 3/1B/2011 Acq. Time: 7:26:26 PM File: "s110317a.wifT Modified: Ho Proc. Algorithm: IntelliQuan * HQII Noise Percentage: so Base. Sub. Window: 1.00 min Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: Min. Peak Width: o.oo o.oo cps sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 13.1 min Use Relative RT: No Int. Type: Retention Time; Area: Height: Start Time: End Time: Valley 13.116 min 62335 counts 7.47C+003 cps 12.885 13.617 I Sample Name: "s110317a074" Sarrple ID: "GLP10-01-01-15-009 C Peak Name: "MPFOS" Masses): "503.0/80.0 amu" Comment Annotation: ~ Sample Index: 74 Sample Type: Unknown Concentration: N/A Calculated Cone: 3.12 ng/mL8000 Acq. Time: 7 :S2 :43 PM Acq. Date: ` 7500 Modified: Ho Proc. Algorithm: IntelliQuan Noise Percentage: SO Base. Sub. Window: 1.00 i Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: o.oo Min. Peak width: 0.00 Smoothing Width: 3 RT Window; 30.o se< Expected RT: 13.1 mil Use Relative RT: Ho Int. Type-. Retention Time: Height : start Time: End Time: Valley 13.078 min 980S1 counts 8.17e+003 cps 12.847 min 13.521 .in * g- t J 3/18/2011 . Sample Name: "s110317a075" Sarrple ID: "GLP10-C1-01-15-009 Dup DAL SS SS20 0 0000 Lab Duplicate" I Peak Name: "MPFOS" Masses): "503.0/80.0 amu' I Comment ~ Annotation: "" Sample Index: 75 Sample Type: Unknown Concentration: N/A --- Calculated Cone: 3.30 ng/mL Acq. Date: 3/18/2011 Acq. Time: 8:16:59 PM Time, min File: "s1 l0317a.wiT Modified: No Proc. Algorithm: IntelliQuan - MQII Noise Percentage: so Base. Sub. Window: l.oo min Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: o.oo cps Min. Peak Width: 0.00 Smoothing width: RT Window: Expected RT: Use Relative RT: Area: Height: Start Time: End Time: 9.08e+003 12.808 13.636 Printing Date: Tuesday, April 05, 2011 StUdyGL:Pf0-01-02-15Printing Page 141 of 286 Page369of514 *Stan V1660305 *3M Environmental Lab Results Name: s110317a.rdb J StudyGLP10-81-Q2-15t mPrinting Date: Tuesday, April 05, 2011 Printing Page 142 of 286 Page370of514 Stan V1660305 Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 Printing 5 Page 143 of 286 Page 371 of 514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 StUfySL:Pftl--01-02-15Printing Page 144 of 286 Page372of514 Stan V1660305 Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 Printing y*fo_W -02-15 Page 145 of 286 Page 373 of 514 Stan V1660305 *3M Environmental Lab I Sample Name: "s110317a092" Sample ID: "GLP10-01-01-15-015 DAL SS SS17 0 0000" Peak Name: "MPFOS" Masses): "503.0/80.0 amu" Comment " * Annotation: ~ sample Index: 92 Sample Type: Unknown Concentration: N/A Calculated Cone: 3.07 ng/mL Acq. Date: 3/19/2011 Acq. Time: 3:09:21 AM File: "s110317a.wifT Modified: No Proc. Algorithm: IntelliQuan * MQ! Noiae Percentage: so Base. Sub. Window: 1.00 min Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: o.oo cps Min. Peak width: 0.00 sec Smoothing width: 3 po RT Window: 30.0 sec Expected RT: Use Relative RT: 13.1 No min Int. Type: Base To Base Retention Time: 13.097 min Area : 9842S counts Height : e .ooe+oo3 cps Start Time: 12.750 min End Time: 13.771 min Results Name: sll0317a.rdb I Sample Name: "s110317a093~ Sample ID: "GLP10-01-01-15-015 Dup OAL SS SS17 0 0000 Lab Duplicate' Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu" Comment "" Annotation:"" Sample Index: 93 Sample Type: Unknown Concentration: N/A Calculated Cone: 2.95 ng/mL Acq. Date: 3/19/2011 Acq. Time: 3:33 :3S AM File: "s110317a.wifr Modified: No Proc. Algorithm: IntelliQuan - MQII Noise Percentage: so Base. Sub. Window: l.oo min Peak-Split. Factor: 2 Report Largest Peak: No Min. PMeiank. wPiedatkh:Height cps sec Smoothing width: points RT Window: Expected RT: Use Relative RT: Int. Type: Retention Time: Area: 9 Height: 8.71e*003 start Time: 12.616 End Time: 13.444 ( Sample Name: "s110317a094" Sample ID: "GLP10-01-01-15-015 IM S DAL SS SS17 0 0000 Lab Matrix Spike" Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu" Comment Annotation:" Sample Index: 94 Sample Type: Unknown Concentration: N/A Calculated Cone: 2.92 ng/mL Acq. Date: 3/19/2011 Acq. Time: 3:57:49 AM File: "s110317a.wrfT Modified: No Proc. Algorithm: IntelliQuan * MQI1 Noise Percentage: 50 Base. Sub. Window: 1.00 min Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak width: 0.00 sec SRmToWoitnhdionwg: Width: 30.0 3 sec points Expected RT: 13.1 min Use Relative RT:: No Int. Type: Valley Retention Time: 13.001 min Area: 85330 counts Height: 7.03e+003 cps Start Time: 12.712 min End Time: 13.617 min a 2? |B 2000 1500 1000 Printing Date: Tuesday, April 05, 2011 TMStUdySLPf0-$1-02-15Printing 3 Sample Name: "s1103l7a095" Sample ID: "10 006-80 solvent blank" Peak Name: "MPFOS" Mass(es): "503.0/80.0 amu" CommentAnnotation: " Sample Index: 95 Sample Type: Double Blank Concentration: 0.00 ng/mL Calculated cone: N/A Acq. Date: 3/19/2011 Acq. Time: 4:22:00 AM File: "s110317a.wifT Modified: No Proc. Algorithm: IntelliQuan - MQII Noise Percentage: So Base. Sub. Window: l.oo min Peak-split. Factor: 2 Report Largest Peak: No Min. Peak Height: Min. Peak Width: 0i.. 0o0o cps sec Smoothing width: points RT Window: Expected RT: Use Relative RT: Int. Type: Retention Time: Area: Height: 6 Start Time: End Time: Page 146 of 286 Page374of514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 TjMStJdySLP1O-01-O2-15Printing Page 147 of 286 Page375of514 *Stan V1660305 Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 Printing lrtt)-W-02-15 Page 148 of 286 Page 376 of 514 Stan V1660305 Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 Printing ^.^.^-02-15 Page 149 of 286 Page 377 of 514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 TMStlMyGLP1O--01-O2-15Printing 3 Page 150 of 286 Page378of514 *Stan V1660305 Results Name: sll0317a.rdb t"1 0cr Printing Date: Tuesday, April 05, 2011 Printing TgW s ^ _02-i 5 Page 151 of 286 Page 379 of 514 Stan V1660305 Results Name: s!10317a.rdb Printing Date: Tuesday, April 05, 2011 Printing -02--15 Page 152 of 286 Page 380 of 514 Stan V1660305 Results Name: sll0317a. Printing Date: Tuesday, April 05, 2011 Printing 1 3 ^ 5 ^ 6 1 ^ - ^ - 0 2 - 1 5 Page 153 of 286 Page 381 of 514 *Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 TM SLPf0-W-02-15Printing 3 stMf Page 1S4 of 286 Page382of514 Stan V1660305 Results Name: sll0317a. 8 2. 3 IE & Printing Date: Tuesday, April 05, 2011 Printing _02-1 5 Page 155 of 286 Page 383 of 514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 T^MStJdyGLP10-01-02-15Printing Page 156 of 286 Page384of514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 StUdySL:Pf0-01-02-15Printing Page 157 of 286 Page385of514 *Stan V1660305 *3M Environmental Lab I Sam ple N am e: "s1 l031 7a14 0" Sam p le ID: "G LP10-01-01-15-030 D A L S D S D 2 2 0 0015" P e a k N a m e: " M P F O S " M a s s e s ) : "503.0/60.0 am u" l C o m m e n t ~ Annotation: Saaple Index: 140 Sample Type: Unknown Concentration: N/A Calculated Cone: Acq. Date: Acq. Tine: File: 's110 317 a.w ifr Modified: Ho Proc. Algorithm: IntelliQuan I Noise Percentage: Base. Sub. Window: so l.oo rail Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: 0.00 c| Min. Peak width: 0.00 s< Smoothing Width: 3 j RT Window: 30.0 sec Expected RT: 13.1 min Use Relative RT: Ho Int. Type: Valley Retention Time: 13.059 min Area: 77224 counts Height: 6.38e*O03 cps Start Time: 12.608 min End Time: 13.424 min Results Name: sll0317a.rdb I S am p le Nam e: "s110 317 a141 " Sam p le ID: "G LP 1 0 -0 1 -0 1 -1 5-030 D up D A L S D S D 2 2 0 0015 Lab Duplicate" P e a k N a m e: " M P F O S " M a s s e s ) : " 503.0/80.0 am u" I C o m m e n t "* A nn otation : "" I Sample Index: 141 | Sample Type: Unknown | Concentration: H/A 0 Calculated cone: Acq. Date: Acq. Time: File: "s1 1 0 3 1 7 a.w tff Modified: No Proc. Algorithm: IntelliQuan - MQII Noise Percentage: SO Base. Sub. Window: 1.00 min Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: o.oo cps Min. Peak Width: o.oo sec Smoothing Width: 3 point RT window: 30.0 sec Expected RT: 13.1 min Use Relative RT: No Int. Type: Retention Timi Area: Height: start Time: End Time: Valley 13.078 min 81318 counts 6.32e+003 cps 12.750 min 13.733 min I Sam p le N a m e: "s110 317 a142 " Sa m p le ID: "G L P 10-01-01 -15 -0 30 L M S D A L S D S D 2 2 0 0015 L a b Matrix S p ik e " I P e a k N a m e : " M P F O S " M a s s e s ) : " 50 3.Q /BO.O am u " I C om m ent "* Annotation: ~ Sample Index: 142 Sample Type: Unknown concentration: N/A Calculated Cone: 2.98 Acq. Date: 3/19/2011 Acq. Time: 11:21:06 PI File: "s110317a.w ifT Modified Ho Proc. Algorithm: IntelliQuan - MQII Hoise Percentage: so Base. Sub. Window: l.oo min Peak-Split. Factor: 2 Report Largest peak: Ho Min. Peak Height Cps Min. Peak Width: sec Smoothing Width: points RT Window: 30.0 sec Expected RT: 13.1 min Use Relative RT: No Int. Type: Valley Retention Time: 13.001 min Area: 64198 counts Height: 4.86e*003 Cps Start Time 12.789 min End Time: 13.482 Sam p le Nam e: *s110317a143" Sam p le ID: "GLP10-01-01-15-031 D A L S D S D 2 1 0 0000" I P e a k N a m e: "M P F O S " M ass(es): "503.0/80.0 IsC o m m e n t " A nnotation: " Sample Index: 143 Sample Type: Unknown Concentration: N/A Calculated Cone: 3.IS ng/mL Acq. Date: 3/19/2011 Acq. Time: 11:4S:17 PM File: "s110 317 a.w ifT Modified: No Proc. Algorithm: IntelliQuan - MQII Noise Percentage: so Base. Sub. Window: 1.00 min Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak width: 0.00 sec Smoothing Width: RT Window: 30.0 sec Expected RT: 13 .1 min Use Relative RT No Int. Type: Retention Time: Area: Height: Start Time: End Time: Valley 13 059 min 58269 counts 4.10e+003 cps 12.770 min 13 .S21 * i " 3000- 2800- 0 2600- & 2400- | 2200 2000- Printing Date: Tuesday, April 05, 2011 StUdyGLPf0-W-02-15Printing Page 158 of 286 Page386of514 Stan V1660305 Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 Printing Page 159 of 286 Page 387 of514 Stan V1660305 Results Name: s!10317a.rdb Date: Tuesday, April 05, 2011 T3WPStiidV:Si-Tsft)-W-02-15 Page 160 of 286 Page 388 of514 *Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 StUdySLP?0-01-02-15Printing Page 161 of 286 Page389of514 *Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 StUdyGL!Pto-0fi-02-15Printing Page 162 of 286 Page390of514 Stan V1660305 Results Name: sll0317a. Printing Date: Tuesday, April 05, 2011 Printing 5 Page 163 of 286 Page 391 of514 **3SMtanEnVv1ir6o6n0m30e5ntal Lab Results Name: sll0317a.rdb PPrriinnttiinngg DateS:tUTduyeGsLd:aPyfb,-0A1p-Or2il-1505, 2011 Page 164 of 286 Page392of514 *Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 TMStUdySL:Pf0--01-02-15Printing 3 Page 165 of 286 Page393of514 *Stan VT660305 *3M Environmental Lab I Sample Name: "s110317a009" Sample ID: "10 006-80 solvent blank" Peak Name: "MPFBS(IS)" M asses): "303.0/84.0 amu" C o m m e n tA n n o ta tio n : ~ Sample Index: a sample Type: Double Blank Concentration: 1.00 ng/mL Calculated Cone: N/A Acq. Date: 3/17/2011 Acq. Time; 5:38:44 PM File: "s110317a.w iff' 5.10 Modified: No Proc. Algorithm: IntelliQuan - MQII Noise Percentage: 50 Base. Sub. window: l.oo min Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: Min. Peak Width: Smoothing Width: RT Window: Expected RT: Use Relative RT: Int. Type: Retention Time: Area: Height: Start Time: End Time: Base To Base 7.84 min 8 1 counts 3.00e+00i cps 7.80 min 8.05 min I Sample Name: "s110317aQ11" Sample ID: "EC-110316-02 0.5 ng Extracted Curve Point" Peak Name: "M P F B S(ISf M asses): "303.0/84.0 amu" C o m m e n t" Annotation:"" sample Index: ll File: "s110317a.wifT Printing Date: Tuesday, April 05, 2011 T-jMStudyGLPiO-01-02-15Printing Results Name: sll0317a.rdb I Sample Name: " s110317a010" S a np le ID: "EC-110316-01 0.2 ng Extracted Curve Point" Peak Name: "MPFBS(IS)" M asses): "303.0/84.0 amu" I C om m ent Annotation: ~ Sample Index: 10 Sample Type: standard Concentration: 2.93 ng/mL Calculated Cone: N/A Acq. Date: 3/17/2011 Acq. Time: 6:02:55 PH File: "s110317a.wifT Modified: No Proc. Algorithm: IntelliQuan - MQI: Noise Percentage: 50 Base. sub. Window: 1.00 min Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: o.oo cps Min. Peak Width: o.oo sec Smoothing Width: 3 poii RT Window: 30.0 sec Expected RT: 7.86 min Use Relative RT: No Int. Type: Valley Retention Time: 7.86 min Area : 239606 counts Height : 2.4 9e+004 cps Start Time 7.68 min End Time : 8.38 min fSample Name: "s110317a012" Sample ID: "EC-110316-03 0 Peak Name: "M P F B S (lS r M asses): '-303.0/84.0 amu" C om m ent "" Annotation: "" Sample Index: 12 Sample Type: Standard Concentration: 2.93 Calculated Cone: N/A Acq. Date: 3/17/2011 Acq. Time: 6 :S1:22 PM Modified: No Proc. Algorithm: IntelliQuan - MQII Noise Percentage: SO Base. Sub. Window: l.oo min Peak-Split. Factor: Report Largest Peak Min. Peak Height: Min. Peak Width: Smoothing Width: RT Window: : Expected RT: Use Relative RT: Int. Type-. Valley Retention Time: 7.86 min Area: 231606 counts Height: 2.36e+004 cps Start Time 7.63 End Time: 8.46 Page 166 of 286 ) 624 728 Time, min__________ Page394of514 Stan V1660305 Results Name: sll0317a.rdb Printing Printing DTajtflep:stjTjujyesgdfjajfyS,fti-AWpr_i0l2-i055, 2011 Page 167 of 286 Page 395 of 514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 StUdGL!P?0-O1-02-15Printing Page 168 of 286 Page396of514 *Stan V1660305 Results Name: sll0317a. Printing Date: Tuesday, April 05, 2011 Printing < ^ [^ 4 9 1 -0 2 -1 5 Page 169 of 286 Page 397 of 514 *Stan V1660305 Results Name: sll0317a.rdb Printing Printing DTajft5eF:StlTjtuye:sdi.afiy>,fo-AWpr-0i2l-1055, 2011 Page 170 of 286 Page 398 of 514 Stan V1660305 Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 Printing i.ii>iti_$f-02-15 Page 171 of 286 Page 399 of 514 Stan V1660305 Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 Printing 5 Page 172 of 286 Page 400 of 514 *Stan V1660305 *3M Environmental Lab I Sample Name: "s11D3l7a037" Sample ID: "MB-110316-12 Method Blank w/ IS for dilutions' Peak Name: "MPFBS(IS)" Masses): " 303.0/84.0 amu" I Comment: "" Annotation: " Semple Index: 37 Semple Type: Unknown Concentration: 2.93 ng/rnL Calculated Cone: N/A Acq. Date: 3/18/2011 Acq. Time: 4:58:13 AM File:'s110317a.wifr Modified: No Proc. Algorithm: IntelliQuan * MQII Noise Percentage: 50 Base. Sub. Window: 1.00 min Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: o.oo cps Min. Peak Width: o.oo sec Smoothing Width: 3 points r t window: 30.0 sec Expected RT: 7.86 min : Relative RT: No Int. Type: Valley Retention Time: 7.82 min Area: :44431 counts Height: 2.S2e+004 CpS Start Time: End Time: TSample Name: "s110317a039" Sample IO: "LCS-110316-02 3 ng LCS in TCR-842" Peak Name: 'MPFBS(IS)" Masses): "303.0/84.0 amu" Comment Annotation: Sample Index: 39 Sample Type: Unknown Concentration: 2.93 I Calculated Cone: N/A Acq. Date: 3/18/2011 Acq. Time: 5:44:38 AM File: Ms110317a.wifr Modified: No Proc. Algorithm IntelliQuan - MQII Noise Percentage: 50 Base. Sub. Window: 1.00 min Peak-Split. Factor: 2 Report Largest Peak No Min. Peak Height: 0.00 cps Min. Peak Width: o.oo sec Smoothing Width: 3 points RT Window: : Expected RT: Use Relative RT: Int. Type: Retention Time: Area: 234828 Counts Height: 2.3 8e + 004 cps Start Time: 7.S3 min End Time: Printing Date: Tuesday, April 05, 2011 T^udy SLPfo-0f-O2-15Printing Results Name: sll0317a.rdb Sample Name: `61103178038' Sample ID: "LCS-110316-01 3 ng ICS in TCR-842" Peak Name: 'MPFBS(IS)" Masses): "303.0/84.0 amu" Comment:"" Annotation:"" Sample Index: 38 Sample Type: Unknown Concentration: 2.93 ng/ Calculated Cone: N/A Acq. Date: 3/18/2011 Acq. Time: 5:20:25 AM File: 's110317a.wifr Modified: No Proc. Algorithm: IntelliQuan - Noise Percentage: 50 Base. Sub. Window: 1.00 mi Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: o.oo c Min. Peak Width: o.oo s Smoothing Width: 3 RT Window: 30.0 sec Expected RT: 7.86 min Use Relative RT: No Area : Height : Start Time: End Time: 30e+004 7.65 8.44 I' Sample Name: "s110317a040" Sample ID: "LCS-110316-03 3 ng LCS in TCR-842' Peak Name: 'MPFBS(IS)' Mass(es): "303.0/84.0 amu" Comment "" Annotation: "" Sample Index: File: "s110317a.wiff" Page 173 of 286 Page 401 of514 *Stan V1660305 *3M Environmental Lab Results Name: sll03l7a.rdb Printing 3tP1%-01-02-15Printing Date: Tuesday, April 05, 2011 Page 174 of 286 Page402of514 *Stan V1660305 *3M Environmental Lab I Sample Name: "s110317a045" Sample ID: "GLP10-01-01-15-001 Dup DAL SS SS Tripl 0 0000 Lab Duplicate" Peak Name: "MPFBS(IS)" Mass(es): "303.0/84.0 amu" Comment Annotation: "" Sam ple In d e x : 45 CS aomn cpelen t Tr ay pt ieo: n : 2 .9 3 ng/m L C a lc u la te d Cone: N /A 2.4e4 Acq. D ate: A cq . Tim e: 3/18 /20 11 8 : 1 0 : 0 0 AM 2.3e4 M o d ifie d : NO P ro c . A lg o rith m : I n t e lliQ u a n - M Q II N o ise P e rce ntag e: SO B a s e . S u b. W indow : 1 . 0 0 m in P e a k -S p lit. Factor-. 2 R e p o r t L a r g e s t P e a k: No M in . Peak H e ig h t: 0 .0 0 cps M in . Peak W id th : 0.00 sec S m o o th in g w id th : 3 p o in t s RT W indow : 30 .0 sec E xp e cte d RT: 7 .8 6 m in Use R e la tiv e RT: NO 2.2e4 2.1e4 2.0e4 1.9e4 1.8e4 1,7e4 1.6e4 1.5e4 In t. Type: V a lle y R e te n tio n T im e: 7 .8 2 m in A rea: 222550 counts H e ig h t: 2 .46e+004 cps S t a r t Tim e: 7 .6 5 m in End T im e: 8 .4 7 m in 1.4e4 !& 1.3e4 1.2e4 1 1.1e4 File: "s110317a.wiff Results Name: sll0317a.rdb Sample Name: "s110317a046* Sarrple ID: "GLP10-01-01-15-001 LMS DALS iSSTripl 0 0000 Lab Matrix Spike" Peak Name: "MPFBS(IS)" Mass(es): "303.0/84.0 amu" Comment "" Annotation: ~ Sample Index: 46 File: "s110317a.wifT I Sample Name: "s110317a04r Sample ID: 'GLP10-01-01-15 I Peak Name: ' MPFBS(IS)' Masses): "303.0/84.0 amu* I Comment "* Annotation: Sam ple In d e x : 47 Sam ple Type: Unknown C o n c e n tra tio n : C a lc u la te d Cone: 2 93 N /A ng/m L 2.2e4- Acq. D ate: A cq . Tim e: 3 /18 /20 11 8 : 5 8 : 2 8 AM 2.1 e4 M o d ifie d : No P ro c . A lg o rith m : I n t e lliQ u a n - M Q II N o ise P e rce ntag e SO B a s e . S u b. W indow : 1 . 0 0 m in P e a k -S p lit. F a c to r: 2 R e p o r t L a r g e s t P e a k : No M in . Peak H e ig h t 0.0 cps M in . Peak w id th : 0 .0 ec S m o o th in g W id th : 3 p o in ts RT W indow : 30 .0 sec E x p e c te d RT: 7 .8 6 m in use R e la tiv e RT: No 2.0e4 1.9e4 1.6e4 1.7e4 1.6e4 1.5e4- In t. Type: V a lle y R e te n tio n T im e : 7 .8 0 m in A rea: 231241 counts H e ig h t : 2 .25e*004 cps s t a r t T im e: 7 .6 1 m in End Tim e: 8 24 * t 1.3e4 ft 1.2e4 1.1e4 I 1.0e4 9000 0 8000.0 7000.0 6000.0 SOOD.O 4000.0- 3000.0 2000.0 1000.0 O.oJ Printing Date: Tuesday, April 05, 2011 3 GLP^`0-01-02-15Printing ^ ^ Sample Name: "s110317a046" Sarrple ID: ' GLP10-01-01-15-083 Dup DAL SS Trip2 0 0000 Lab Duplicate* Peak Name: 'MPFBS(IS)' Masses): *303.0/84.0 amu* Comment -- Annotation: " Sample Index: 48 Sample Type: Unknown Concentration: 2.93 ng/mL2. Calculated Cone: N/A Acq. Date: 3/16/2011 2. Acq. Time: 9:22:44 AH File: "s1 Modified: Yes Proc. Algorithm: IntelliQuan - MQII Noise Percentage: So Base. sub. window: 1.00 min Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height cps M in . Peak W id th : sec S m o o th in g W id th : points RT w in d o w : E xp e cte d RT: Use R e la tiv e RT: No In t. Type: Valley R e te n tio n T im e: 7.82 A rea: 21331S counts H e ig h t: 2.10e+004 Cps S t a r t Tim e: 7.65 End Tim e: 8.36 Page 175 of 286 Page403of514 Stan V1660305 *3M Environmental Lab I Sample Name: "s1103178049" Sample >0: "GLP10-01-01-15-083 LMS DAL SS Trip2 0 0000 Lab Matrix Spike" Peak Name: ' MPFBS(IS)' Masses): -303.0/84.0 amu' I Comment *" Annotation: ~ sample Index: 49 sample Type: Unknown Concentration: 2.93 ng/t Calculated Cone: N/A Acq. Date: 3/18/2011 Acq. Time: 9:46:57 AM File: "s110317a.wtfT Modified: No Proc. Algorithm: IntelliQuan I Noise Percentage: 50 Base. Sub. Window: 1.00 mi: Peak-split. Factor-. 2 Report Largest Peak: No Min. Peak Height: o.oo cj Min. Peak Width: o.oo s< Smoothing Width: 3 1 RT Window: 30.0 sec Expected RT: 7.88 min Dse Relative RT: No Int. Type : Valley Retention Timi : 7.84 min Area: 236825 counts Height : 2 .36e+004 CpS Start Time: End Time : Results Name: sll0317a.rdb I Sample Name: ' s110317a050" Sanple ID: "GLP10-01-01-15-002 DAL SS SS12 0 0000' Peak Name: ' MPFBS(IS)* Masses): "303.0/84.0 amu' Comment"" Annotation: -- Sample Index sample Type: Unknown Concentration: 2N./9A3 ng/mL Calculated cone: 3/18/'2011 Acq. Date Acq. Time File: 's110317a.wifr Modified: No Proc. Algorithm: IntelliQuan MQII Noise Percentage: SO Base. Sub. Window: 1.00 min Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: o.oo cps Min. Peak Width: o.oo sec Smoothing Width: 3 points RT Window: Expected RT: Use Relative RT Area: Height: Start Time: End Time: 2 .24e004 cps 7.67 8.15 I Sample Name: "s1l0317a051" Sample ID: ' GLP10-01-01-1S-002 Dup DAL SS SS12 0 0000 Lab Duplicate" Peak Name:-MPFBSflSr Mass<es):-303.0/84.0 amu" I Comment "" Annotation: ~ sample Index: si Sample Type: Unknown Concentration: 2.93 n Calculated Cone: N/A Acq. Date: 3/18/20H Acq. Time: 10:35:23 AM F ile :' s110317a.wiT Modified: No Proc. Algorithm: Inte Noise Percentage: Base. sub. window: Peak-split. Factor: Report Largest Peak: Min. Peak Height: Min. Peak width: Smoothing Width: RT Window: 30 Expected RT: 7 Use Relative RT: N Area: Height: Start Time: End Time: 2.27e+004 7.63 8.40 Printing Date: Tuesday, April 05, 2011 SL:Pflob1-02-15Printing J Sample Name: "s110317a052" Sanple ID: "GLP10-01-01-15-002 LMS DAL SS SS12 0 0000 Lab Matrix Spike' Peak Name:'MPFBS(IS)' Masses): "303.0/84.0 amu" I Com m entAnnotation: " Sample Index: 52 Sample Type: Unknown 7^7 Concentration: 2.93 nc Calculated Cone: N/A Acq. Date: 3/18/2011 Acq. Time: 10:59:33 AM File: "sl10317a.wifT Modified: No Proc. Algorithm: IntelliQuan Noise Percentage: 50 Base. Sub. Window: 1.00 1 Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: 0.00 Min. Peak Width: 0.00 Smoothing Width: 3 RT Window: 30.0 sei Expected RT: 7.86 oil Use Relative RT: No points Area: Height: start Time: End Time: cps min 8000.0 7000.0 6000.0 5000.0 4000.0 3000.0 2000.0 1000.0 Page 176 of 286 Page404of514 *Stan V1660305 *3M Environmental Lab Results Name: s!10317a.rdb Printing Date: Tuesday, April 05, 2011 T^MStJdLpQ-01-02-15Printing Page 177 of 286 Page405of514 *Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb PPrriinnttiinngg Digafftleeg:tuTtuye^sPda1y%,-0A1p-0r2il-1055, 2011 Page 178 of 286 Page406of514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 TMStUdyGL:P?0--fl1-02-15Printing 3 Page 179 of 286 Page407of514 *Stan V1660305 *3M Environmental Lab [ Sample Name: ~s110317a065' Sample IO: "GLP10-01-01-15-006 DAL SS SS16 DB 000CT Peak Name: 'MPFBS(IS)' Masses): " 303.0/84.0 amu" I Comment "" Annotation: Sam ple In d e x : 6S sam p le T ype : Unknown C o n c e n tra tio n : 2 .9 3 ng /o L C a lc u la te d Cone: N /A Acq. D ate: 3/18 /20 11 Acq. Tim e: 4 : 1 4 : 3 1 PM 2.1e4 File: "s110317a.wrfT M o d ifie d : NO P roc. A lg o rith m : In te lliQ u a n - m q ii N o ise P e rce ntag e- 50 B a se . S u b. W in do w : l.O O m in P e a k -s p lit. F a c to r: 2 R e p o rt L a r g e s t P e a k : No M in . Peak H e ig h t 0 .0 0 cps M in . Peak W id th : S m o o th in g W id th : 3 p o in ts RT W indow; 30 .0 sec E xp e cte d RT: 7 .6 6 m in Use R e la tiv e RT: No 2.0e4 1.9e4 l./e 4 I.6e4 ... 1.4e4 In t. Type: Base To Base R e te n tio n Tim e: 7 .8 0 m in A re a : 2 : 7610 counts H e ig h t; 2 . 28e +004 cps s t a r t Tim e: 7 .6 3 m in 1.34 ft- 1.2e4 1.0e4 9000.0 8000.0 7000.0 6000.0 5000.0 4000.0 3000.0 2000.0 1000.0 0.0 I Sample Name: "s110317a067" Sample ID: "GLP10-01-OM5-006 LMS DAL SS SS16 OB 0000 Lab Matrix Spike" I Peak Name: 'MPFBS(IS)' Masses): "303.0/84.0 amu" I Comment "" Annotation: ` Sam ple In d e x : 67 sam p le T ype : Unknown C o n c e n tra tio n : 2 .9 3 ng/m L C a lc u la te d Cone: N /A Acq. D ate : 3/18 /20 11 1.8e4- Acq. Tim e: 5 : 0 2 : 5 9 PM M o d ifie d : No P ro c . A lg o r ith m : In te lliQ u a n - M Q II N oise P e rce n ta g e : 50 B ase. s u b . window : 1 . 0 0 m in P e a k -S p lit. F a c to r: 2 R e p o rt L a r g e s t P e a k: No M in . Peak H e ig h t: 0 .0 0 cps M in . Peak w id th : 0.00 sec S m o o th in g W id th : 3 p o in ts RT W in do w : 30 .0 sec E xpected RT: 7 .8 6 m in Use R e la tiv e RT: No 1.7e411.r0t41 1.4e4- 17 4 File: 's110317a.wifT In t. Type: V a lle y R e te n tio n Tim e: 7 .8 2 m in A rea: 215966 counts H e ig h t: 1 . 90 e+ 0 04 CpS S t a r t T im e: 7 .6 5 m in End T im e: 8 .4 7 m in 1.1e4S' 1.0e4- " 8000.0- 7000.0- 6000.0- SOOO.O- 4000.0- 3000.0- 2000.0 1000.0- 0.0- Printing Date: Tuesday, April 05, 2011 stlMyLPfO--01-O2-15Printing Results Name: sll03l7a.rdb Sample Name: "s110317a066" Sample ID: "GLP1Q-01-01-15-006 Dup DAL SS SS16 DB 0000 Lab Duplicate* Peak Name: ' MPFBS(IS)" Mass(es): "303.0/84.0 amu' Comment " Annotation: *" Sample Index: 66 Sample Type: Unknown Concentration: 2.93 n Calculated Cone: N/A Acq. Date: 3/16/2011 Acq. Time: 4:36:45 PM File: "s110317a.wtff Modified: Ho Proc. Algorithm: IntelliQuan Noise Percentage: so Base. Sub. Window: l.oo Peak-Split. Factor: 2 Report Largest Peak: Ho Min. Peak Height: 0.00 cps Min. Peak width: 0.00 s e c Smoothing width: 3 p o i n t s RT Window; 30.0se Expected RT: 7.66 mi Use Relative RT: No In t. Type: v a lle y R e te n tio n Tim e: 7.62 Area : 22S063 counts H e ig h t : 2.16e+004 cps S t a r t T im e: 7 .6 3 m in End Tim e: I Sample Name: "s110317a068" Sanale ID: "GLP10-01-01-15-007 DALSSSS11 0 0000" Peak Name: "MPFBS(IS)" Masses): "303.0/84.0 amu" Comment Annotatio6n6:-- Sam ple In d e x : Unknown Sam ple Type: C o n c e n tra tio n : 2.93 N/A l C a lc u la te d Cone: 3/16/2011 Acq. S a te : 5:27:13 PM A cq . T im e: Modified: No Proc. Algorithm: IntelliQuan - MQII Noise Percentage: Base. sub. window: Peak-Split. Factor: SO l.oo 2 min Report Largest Peak: No Min. Peak Height: o.oo cps Min. Peak Width: Smoothing Width: RT Window: Expected RT: Use Relative RT: 0.00 sec 3 points 30.0 sec 7.66 min Ho File: "s1l0317a wifT Area: Height: start Time: End Time: 2.23e+004 Page 180 of 286 Page408of514 *Stan V1660305 Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 Printing 5 Page 181 of 286 Page 409 of 514 *Stan V1660305 Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 Printing t^ s ^ : ^ ^ . ^ - 0 2 - 1 5 Page 182 of 286 Page 410 of 514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 StUdySUPl70-Q1-02-15Printing Page 183 of 286 Page 411 of514 Stan V1660305 Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 Printing T$NpstiMy UPTO-W -02-15 Page 184 of 286 Page 412 of 514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 StJdVSLP10-W-02-15Printing Page 185 of 286 Page413of514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 StUdyGL!P?0-01-02-15Printing Page 186 of 286 Page414of514 Stan V1660305 Results Name: sll0317a. 5 2. 0 rf I Printing Date: Tuesday, April 05, 2011 Printing T ^stiJdy 5gfoSfMfl-02-1 Page 187 of 286 Page 415 of 514 Stan V I 660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 ;G.P1Q-Q1-Q2-15Printing Page 188 of 286 Page416of514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 ISlMStutyGLP10-01-02-15Printing Page 189 of 286 Page417of514 *Stan V1660305 Results Name: sll0317a. Printing Date: Tuesday, April 05, 2011 Printing -02^ 5 Page 190 of 286 Page 418 of514 *Stan V1660305 *3M Environmental Lab I Samp) Name: "s110317a109" Sample IP: "GLP10-01-01-1S-021 LMS DAL SS SS30 0 0000 Lab Matrix Spike" Peak Name: "MPFBS(ISf Masses): "303.0/64.0 amu" Comment ~ Annotation: Sample Index: 109 File: "s110317a.wifr Results Name: sll0317a.rdb I Sample Name: "s1103l7a110" Sample IP: "GLP10-01-01-15 Peak Name, " M PF 8S (tSr Masses). "3Q3.Q/84. arruT Comment Annotation: "* Sample Index: no Sample Type: Unknown Concentration: 2.93 ng/mL Calculated Cone: N/A Acq. Date: 3 /1 9 / 2 0 1 1 Acq. Time: 10:2S:S0 AM Modified: Proc. Algorithm: Noise Percentage: Base. sub. window: Peak*split. Factor: Report Largest Peak: Min. Peak Height: Min. Peak Width: Smoothing Width: RT window: 3i Expected RT: ` use Relative R T : 1 Int. Type: Retention Time: Area: 2 Height: ..S9e*004 Start Time: 7.63 End Time: 8.S7 cps min min I Sample Name: "s110317a11i" Sample ID: "GLP10-01-01-15-022 Pup DAL SS SS30 0 0005 Lab Duplicate" Peak Name: ' MPFBS(IS)" Masses): "303.0/64.0 amu" Comment "" Annotation: ~ sample Index: 111 File: "s110317awifr Printing Date: Tuesday, April 05, 2011 TMStUdySL:PfQ-01-Q2-15Printing 3 I Sample Name: "s1103l7a112" Sample ID: "GLP1(WH*01-15-022 LMS DAL S ! SS30 0 0005 Lab Matrix Spike" Peak Name: ' MPFBS(IS)' Masses): "303.0/84.0 amu" Comment -- Annotation: " * Sample Index: 112 Sample Type: Unknown Concentration: 2.93 ng/oL 2.0e4 Calculated Cone: N/A Acq. Date: Acq. Time: 3/19/2011 11:14:12 AM 1.9e4 Modified: No Proc. Algorithm: IntelliQuan Noise Percentage: 50 Base. Sub. Window: 1.00 Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: 0.00 Cps Min. Peak Width: 0.00 sec Smoothing Width; 3 points RT Window: 30.0 se Expected RT: 7.86 mi Use Relative RT: No 1.6e4 1.7e4 1.6e4 1.5e4 1,4e4 1.3e4 Int. Type: valley Retention Time: 224430 counts Height: 2.oSe+004 cps start Time: 7.65 min End Time: 8 . 2 8 min 1.2e4 1.1e4 1.0e4 9000.0 File: "s1103l7a.wiff' 6000.0 7000.0 6000.0 5000.0 4000.0 3000.0 2000.0 1000.0 0.0 Page 191 of 286 Page419of514 *Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 stJd/ SLPf0-01-02-15Printing Page 192 of 28S Page420of514 *Stan V1660305 Results Name: sl!0317a.rdb Printing Date: Tuesday, April 05, 2011 Printing gfoSfb-W_02-i 5 Page 193 of 286 Page 421 of 514 Stan V1660305 Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 Printing g y 2 fb _ ^ _ o 2_i 5 Page 194 of 286 Page 422 of 514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 TMStUdySL:Pf0-01-02-15Printing 3 Page 195 of 286 Page423of514 Stan V1660305 Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 Printing 5 Page 196 of 286 P a g e 4 2 4 o f5 1 4 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 TMStUdyGLPf0--0f-02-15Printing 3 Page 197 of 286 Page425of514 Stan V1660305 Results Name: sll0317a. Printing Date: Tuesday, April 05, 2011 Printing 5 Page 198 of 286 Page 426 of 514 *Stan V1660305 *3M Environmental Lab Results Name: S110317a.rdb Printing Date: Tuesday, April 05, 2011 TjMStAfyGjPftl-01-02-15Printing Page 199 of 286 Page427of514 Stan V1660305 Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 Printing 5 Page 200 of 286 Page 428 of 514 *Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 TjMStUdyGLP10-01-O2-15Printing Page 201 of 286 Page429of514 Stan V1660305 Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 Printing Tgfppgtjjfy: gLpSfo.W_02-i 5 Page 202 of 286 Page 430 of 514 *stan VI6603 05 *3M Environmental Lab Results Name: sll03l7a.rdb Printing Date: Tuesday, April 05, 2011 Tj^StJdVSl:Pf0-01-02-15Printing Page 203 of 286 Page 431 of514 Stan V I66 0305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 Tj^StUdVSL:Pl0-W-02-15Printing Page 204 of 286 Page432of514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 SLPiO-01-02-15Printing Page 205 of 286 Page433of514 Stan V1660305 *3M Environmental Lab Results Name: s!10317a.rdb Printing Date: Tuesday, April 05, 2011 jMStJdLPfo-W-02-15Printing T Page 206 of 286 Page434of514 *Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing =gLp|0-d1-O2-15Printing Date: Tuesday, April 05, 2011 Page 207 of 286 Page435of514 *Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 TMstUdVSLP10-W-02-15Printing 3 Page 208 of 286 Page436of514 *Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 StUdyGL!Pfb-M1-02-15Printing Page 209 of 286 Page437of514 *Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 StUdySLPf0-01-02-15Printing = Page 210 of 286 Page438of514 Stan V1660305 *3M Environmental Lab Results Name: sll03l7a.`rdb Printing Date: Tuesday, April 05, 2011 GL:Pf0-01-02-15Printing Page 211 of 286 Page439of514 *Stan V1660305 Results Name: s!10317a.rdb Printing Date: Tuesday, April 05, 2011 Printing Tjfl)fstucPy: 6fo*fo-W -02-15 Page 212 of 286 Page 440 of 514 *Stan V1660305 *3M Environmental Lab I Sample Name: "s110317a034" Sample I0: "MB-110316-09 Method Blank w/ IS for dilutions' Peak Name: "MPFHxS(IS)" Mass(es): "402.0/80.0 amu" I Comment "" Annotation: ~ Sample index: 34 sample Type: Unknown Concentration: 2.84 ng/mL Calculated Cone: N/A Acq. Date: 3/18/2011 Acq. Time: 3 :43 :3S AM File: "s110317a.wrff` Modified: No Proc. Algorithm: IntelliQuan - MQII Noise Percentage: so Base. Sub. Window; 1.00 min Peak-split. Factor: 2 Report Largest Peak Min. Peak Height: Min. Peak width: cps 0.0 sec Smoothing width: points RT Window: Expected RT: : Relative RT: No Int. Type: Base To Base Retention Time: 1 0 . 2 min .51479 counts Height: cps start Time: 9.96 min End Time: I Sample Name: "s110317a036" Sample ID: "MB-110316-11 Method Blank w/ IS for dilutions" I Peak Name: "MPFHxS(IS)" Mass(es): "402.0/80.0 amu" I Comment"" Annotation: Sample Index: 36 Sample Type: Unknown Concentration: 2.84 i Calculated Cone: N/A Acq. Date: 3/18/2011 Acq. Time: 4:32:03 AM File: Ms110317a.wtfT Modified: No Proc. Algorithm: IntelliOuan - MQII Noise Percentage: 50 Base. Sub. Window: 1.00 Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: o.oo Min. Peak Width: 0.00 Smoothing Width: 3 RT Window: 30.0 S< Expected RT: io.3 m: Use Relative RT: No Int. Type: Retention Time: Height : start Time: End Time: Base To Base 10.3 min i8 2 8 6 counts Printing Date: Tuesday, April 05, 2011 StddGLPtefl-02-15Printing Results Name: sll0317a.rdb ISample Name: "s110317a03S" Sample ID: "MB-110316-10 Method Blank w/ IS for dilutions" Peak Name: 'MPFHxS(IS)" Masses): "402.0/80.0 amu" SamCpolmemIenndt e""x:Annotatio3n5: Sample Type: Unknown Concentration: 2.84 ] Calculated Cone: N/A Acq. Date: 3/18/2011 Acq. Time: 4:07:53 AM File: "s110317a.wifT Modified: No Proc. Algorithm; Int Noise Percentage: Base. Sub. Window: Peak-Split. Factor: Report Largest Peak: Min. Peak Height: Min. Peak Width: Smoothing width: RT Window: ; Expected RT: use Relative RT: No Int. Type: Base To Base Retention Time: 10.3 mi: Area: 142122 counts Height: 1.28e+O04 cps Start Time 9.94 min End Time: il.O min (Sample Name: "s110317a037~ Sarrple ID: "MB-110316-12 Method Blank w/ IS for dilutions' Peak Name: "MPFHxS(IS)" Masses): "402.0/80-0 amu" SamCpolmemIenndt e""x:Annotatio3n7: "" Sample Type: Unknown Concentrt ion: Calculated Cone: 2.84 N/A ng/mL 1.25e4 Acq. Date: Acq. Time: 3/18/2011 4:56:13 AM 1.20e4 1.15e4 Modified: NO Proc. Algorithm: IntelliQuan - MQII 1.10e4 Noise Percentage : Base. Sub. Window; SO i.oo min 1.05e4 Peak-Split. Pact or: 2 1.00e4 Report Largest Peak: No Min. Peak Height : 0.00 Cps 9500.00 Min. Peak Width: Smoothing width: o.oo sec 9000.00 3 points RT Window: 30.0 sec 8500.00 Expected RT: Use Relative RT: 10.3 min No 8000.00 Int. Type: Base To Base Retention Time: 1 0 . 2 min Area: 145S92 counts Height: 1.28e004 cps Start Time: 9.92 min End Time: 1 1 . 0 min 7500.00 ,, 7000.00 ^ 6500.00 1 6000.00 Page 213 of 286 Page 441 of514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 Tj^StUdVGL:Pf0-1-02-15Printing Page 214 of 286 Page442of514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 stUdySLPfo-01-02-15Printing Page 215 of 286 Page443of514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 L:PtO-01-02-15Printing 3^ Page 216 of 286 Page444of514 **3SMtanEnVv1ir6o6n0m30e5ntal Lab Results Name: sll0317a.rdb PPrriinnttiinngg Dates:tJTduyegsLdaPyf0,-WAp-0r2il-1505, 2011 Page 217 of 286 Page445of514 *Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 StUdyGLP10-01-02-15Printing Page 218 of 286 Page446of514 V1660305 Results Name: sll0317a. Printing Date: Tuesday, April 05, 2011 Printing 5 Page 219 of 286 Page 447 of 514 *Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing w w dy : ^0-61- 2- 5glp o iPrinting Date: Tuesday, April 05, 2011 Page 220 of 286 Page448of514 *Stan V1660305 *3M Environmental Lab Results Name: s110317a.rdb Printing Date: Tuesday, April 05, 2011 StUdySIPWI-Q2-15Printing Page 221 of 286 Page449of514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb GL=P1 -81-02-15qPrinting Date: Tuesday, April 05, 2011 Printing Page 222 of 286 Page450of514 *3MStaEnnVv1ir6o6n0m30e5ntal Lab Results Name: sll0317a.rdb PPrriinnttiinngg Date$:tUTiyuesLd:aPytO, -AWp-r0i2l-1055, 2011 Page 223 of 286 Page 451 of514 *Stan V1660305 *3M Environmental Lab I Sa m p le N a m e: "s110317a078" Sam p le ID: " E C - 1 10316-07 10 ng Extracted C u rv e P o in t" P e a k N a m e: ' M P F H x S (iS )' M a s s e s ) : "402.0/80 0 am u" I Com m ent: "* Annotation: - Sample Index: Sample Type: Concentrt Ion: 2.84 Calculated Cone: N/A Acq. Date: 3/18/201: Acq. Time: 9:29:43 : File: "s 1 1 0 3 l7 a .w iffl Modified: NO Proc. Algorithm: IntelliQuan - > Noise Percentage: So Base. Sub. Window: l.oo oii Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: 0.00 ci Min. Peak Width: 0.00 si Smoothing Width: 3 j RT Window: 30.0 sec Expected RT: 10.3 min use Relative RT: No Int. Type: Base To Base Retention Time: 10.3 min Area: 139208 counts Height: l.lSe+004 cps Start Time: 10.1 min End Time: 11.o Results Name: sll0317a.rdb ( Sa m p le N a m e: "s110 317 a079 " Sa m p le ID: ` 10 006-80 so lven t blank" P e a k N a m e: "M P F H x S (lS )` M a s s e s ) : ` 402.0/00.0 am u ' C o m m e n t"" Annotation: " Sample Index: 19 Sample Type: Double Blank Concentration: l.oo ng/mL Calculated Cone: N/A Acq. Date: 3/18/2011 Acq. Time: 9:S4:0O PM File: "s110317a.w iff' Modified: No Proc. Algorithm: IntelliQuan MQII Noise Percentage: so Base. Sub. Window: 1.00 min Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: o.oo cps Min. Peak width: 0.00 sec Smoothing width: 3 point: RT Window: 30.0 sec Expected RT: 10.3 min Use Relative RT: No int. Type: Retention Time: Area: Height: Start Time: End Time: Base To Base 10.4 min 46 counts l.S6e+O0l cps 10.3 min 10.8 min I Sa m p le N a m e: "s110 317 a080 " S arrp le ID: "G L P 10-01-01 -15 -0 10 D A L S S S P e a k N a m e : " M P F H x S (IS )` M a s s e s ) : "402.0/8 0.0 am u" I C o m m e n t -- Annotation: "" Sample index: 80 Sample Type: Unknown Concentration: 2.84 ng/mL Calculated Cone: N/A Acq. Date: Acq. Time: 3/18/2011 10:18:14 PM 1.15e4 O D B O O O O " F ile: "s110 317 a.w ifT Modified: Yes Proc. Algorithm: IntelliQuan - MQII Noise Percentage SO Base. Sub. Window : 1.00 min Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height 0.00 cps Min. Peak width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 10.3 min Use Relative RT: No 1.05e4 1.00e4 9 5 0 0 .0 0 8 5 0 0 .0 0 8 0 0 0 .0 0 7 5 0 0 .0 0 Int. Type: Valley Retention Time: 10.2 min Area: 14SS64 counts Height: 1 .23e+004 cps Start Time: 10.0 min End Time: 10.8 min 7 0 0 0 .0 0 8- 6500.00 6000.00 | S500 .00 5 0 0 0 .0 0 4 5 0 0 .0 0 4 0 0 0 .0 0 3 5 0 0 .0 0 3 0 0 0 .0 0 2 5 0 0 .0 0 2 0 0 0 .0 0 1 5 0 0 .0 0 1 0 0 0 .0 0 50 0.0 0 Printing Date: Tuesday, April 05, 2011 StUdyGL!P?0-01-02-15Printing 1 4 .6 2 [S a m p le N a m e : *s 1 1 0 3 1 7 a 0 8 1 ` S a m p le ID : " G L P 1 0 -0 1 -0 1 -1 5 -0 1 0 D u p D A L S S S S 2 0 D B 0 0 00 L a b D u p lic a t e ' P e a k N a m e: ` M P F H x S (IS )' M a s s e s ) : ` 402.0 /80.0 am u* samCpolmem eInntde" x:A n n o ta tio8n1: " Sample Type: Unknown Concentrt ion: 2.84 ng/mL Calculated Cone: N/A Acq. Date: 3/18/2011 1.10e4 Acq. Time: 10:42:35 PM 1.05e4 FUe: "s1 1 0 3 1 7 a.w ifr Modified: Yes Proc. Algorithm: IntelliQuan - MQII Noise Percentage SO Base. Sub. window: 1.00 min Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height 0.00 cps Min. Peak Width: 0.00 ec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 10.3 min Use Relative RT: No 1.00e4 9 5 0 0 .0 0 9 0 0 0 .0 0 8 5 0 0 .0 0 8 0 0 0 .0 0 7 5 0 0 .0 0 7 0 0 0 .0 0 Int. Type: Valley Retention Time: 10.3 min Area: 137008 counts Height : 1.14e+004 cps Start Time: lo.o min End Time : 10.9 min 8 -6 0 0 0 .0 0 t 5500.00 I 5000.00 4 5 0 0 .0 0 4 0 0 0 .0 0 3 5 0 0 .0 0 3 0 0 0 .0 0 2 5 0 0 .0 0 2 0 0 0 .0 0 1 5 0 0 .0 0 1 0 0 0 .0 0 500 00 520 624 __________ T im e , min Page 224 of 286 Page452of514 ss i$ fl> 0) & car Printing Date: Tuesday, April 05, 2011 Printing Tj(^pgtuy^:gj_ift).$f-02-15 Page 225 of 286 Page 453 of 514 *Stan V1660305 Results Name: s!10317a.rdb Printing Date: Tuesday, April 05, 2011 Printing 5 Page 226 of 286 Page454of514 *Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 StUdyGL:Pf0-Q1-02-15Printing Page 227 of 286 Page455of514 *Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 StU9y^0-01-02-15P rin ting Page 228 of 286 Page456of514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 StUdySL:P?0-ft1-02-15Printing Page 229 of 286 Page457of514 *Stan V1660305 Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 Printing 5 Page 230 of 286 Page 458 of 514 Stari V1660305 *3M Environmental Lab Results Name: sl!0317a.rdb Printing Date: Tuesday, April 05, 2011 GLP1b-b1-b2-15Printing Page 231 of 286 Page459of514 **3SMtanEnVv1ir6o6n0m30e5ntal Lab Results Name: sll0317a.rdb PPrriinnttiinngg DateS:tUTduyes^da0y-,01A-p0r2i-l1505, 2011 Page 232 of 286 Page460of514 Stan V1660305 Results Name: sll0317a. Printing Date: Tuesday, April 05, 2011 Printing stdfly&|9k)33,l-02-15 Page 233 of 286 Page 461 of 514 Stan V1660305 Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 Printing -02-15 Page 234 of 286 Page 462 of 514 *3MStaEnnVv1ir6o6n0m30e5ntal Lab Results Name: sll0317a.rdb PPrriinnttiinngg Dateg:tTueGsdlaPy1,q-Ap|-0r2il-1055 Page 235 of 286 Page463of514 *3MStaEnnVv1ir6o6n0m30e5ntal Lab Results Name: sll0317a.rdb PPrriinnttiinngg DateS:tUTduy^es0da-y0,1-A0p2r-il1505, 2011 Page 236 of 286 Page464of514 *Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 Printing T3MStUdyG PI -01-02-15l o Page 237 of 286 Page465of514 *Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 jMStJd/GLPfa-W-02-15Printing T Page 238 of 286 Page466of514 **3SMtanEnVv1ir6o6n0m30e5ntal Lab Results Name: sll0317a.rdb PPrriinnttiinngg DateS:ti8Tyu"eGsdlaPy1,o-A01p-0r2il-1055, 2011 Page 239 of 286 Page467of514 Stan V1660305 Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 Printing ^-W o-W -02-15 Page 240 of 286 Page 468 of 514 **3SMtanEnVv1ir6o6n0m30e5ntal Lab Results Name: sll0317a.rdb PPrriinnttiinngg Date: Tu8es^d-a0y,1-A0p2r-i1l505, 2011 Page 241 of 286 Page469of514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb ^MstuePy16!P 0-01-02-15tPrinting Date: Tuesday, April 05, 2011 Printing Page 242 of 286 Page470of514 *Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 ^ GLP10-01-O2-15Printing 3 Page 243 of 286 Page 471 of514 *Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 T^St^ gLP*-W-02-15Printing Page 244 of 286 Page472of514 *Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 TMStUdy&L:Pf0-01-Q2-15Printing 3 Page 245 of 286 Page473of514 *Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 TMStUdyGLP1Q-Q1-Q2-15Printing 3 Page 246 of 286 Page474of514 *Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb PPrriinnttiinngg DateS:tUTdyueGsLd:aPyf,0-0Ai-p0r2il-1505, 2011 Page 247 of 286 Page475of514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 TjMStUdySLPf0-01-02-15Printing Page 248 of 286 Page476of514 Stan VT660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 rjMStddGLPfO-01-02-15Printing Page 249 of 286 Page477of514 Stan VI660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 Tg^StUdySLPfo-W-02-15Printing Page 250 of 286 Page478of514 *Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb St^y^10-01-02-15jmPrinting Date: Tuesday, April 05, 2011 P rin tin g T Page 251 of 286 Page479of514 Stan V1660305 *3M Environmental Lab Results Name: s!10317a.rdb Printing Date: Tuesday, April 05, 2011 StUfySLPf0#1-02-15Printing Page 252 of 286 Page480of514 V1660305 Results Name: sl!0317a.rdb Printing Date: Tuesday, April 05, 2011 Printing g jjfi-fo _ $ 1 _ 0 2 -1 5 Page 253 of 286 Page 481 of 514 Stan V1660305 Results Name: sll0317a.rdb PPrriinnttiinngg DTagtWep:s tjT(uj yes^d:aFy3,ft_$Afplr_iol2-i055, 2011 Page 254 of 286 Page 482 of 514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 TMStUfySL:P1W01-02-15Printing 3 Page 255 of 286 Page483of514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 StUdyGL:Pf0--01-02-15Printing Page 256 of 286 Page484of514 Stan V1660305 *3M Environmental Lab I Sample Name: "s110317a047" Sanale ID: "GLP10-01-01-15-083 DAL SS Trip2 0 0000" Peak Name: "M8PFOS(ISr M asses): ' 507.0/80.0 amu" C om m ent Annotation: "" Sample Index: 47 File: "s110317a.w ifr Results Name: sll0317a.rdb I Sample Name: s110317a048" Sample ID: "G LP10-01-01-15-063 Dup DAL SS Trip2 0 0000 Lab Duplicate" Peak Name: "M8PFOS(IS)" M asses): "507.0/80.0 amu" C om m ent " Annotation: Sample Index: 48 Sample Type: Unknown Concentration: 2.87 : Calculated Cone: N/A Acq. Date: 3 /18 /2 0 1 1 Acq. Time: 9:22:44 AM File: "s110317a.wtfr Modified: Proc. Algorithm: Noise Percentage: Base. Sub. Window: Peak-Split, Factor: Report Largest Peak: Min. Peak Height: Min. Peak Width: Smoothing Width: RT Window: 3 Expected RT: use Relative RT: No Int. Type: Retention Time Area : Height: Start Time: End Time: Valley 13.1 min 84642 counts 7.16e+003 CpS 1 2 . 8 min 13.5 min Sample Name: "s110317a049" Sample Id7"GLP10-01-01-15-083 LMS DAL S S T hp 2 0 0000 Lab Matrix Spike" Peak Name: "M8PFOS(IS)` M a s te s ): "507.0/80.0 amu' C om m ent "" Annotation:"" Sample Index: 49 Time, min Fiie: "s110317a.wrfT TSample Name: "s110317a050" Sarrple ID: "GLP10-01-01-15-002 DAL SS SS12 0 0000" Peak Name: "M8PFOS(IS)' Mass/es): "507.0/80.0 amu" C o m m e n t"" Annotation: " * sample Index: SO Sample Type: Unknown Concentration: 2.87 ng/mL Calculated Cone: N/A Acq. Date: 3 /I8 / 2 0 1 1 Acq. Time: 10:11:11 AM File: "s1 l0 3 1 7 a .w iff Modified: Proc. Algorithm: Noise Percentage: Base. Sub. Window: Peak-Split. Factor: Report Largest Peak: Min. Peak Height: Min. Peak width: Smoothing Width: RT Window: : Expected RT: Use Relative RT: No Int. Type: Valley Retention Time: 13. 1 Area: 38901 coi Height: 2.90e+003 Start Time: 12.8 End Time: 13.5 Printing Date: Tuesday, April 05, 2011 StUdyLPbbl-02-15Printing Time, min Page 257 of 286 Page485of514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb StifiyG P10-01-02-15lPrinting Date: Tuesday, April 05, 2011 Printing Page 258 of 286 Page486of514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 StlMyGL:Pf0-$f-02-15Printing Page 259 of 286 Page487of514 Stan V1660305 Results Name: sll0317a Printing Date: Tuesday, April 05, 2011 Printing _0 2 - i 5 Page 260 of 286 Page 488 of 514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 MStUdyGL:PfQ--Q1-Q2-15Printing T3 Page 261 of 286 Page489of514 *Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 stlMyGUPf-1-02-15Printing Page 262 of 286 Page490of514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb StUdyG P?0-01-02-15lPrinting Date: Tuesday, April 05, 2011 Printing Page 263 of 286 Page 491 of514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 TMStUdySLPfD-W-02-15Printing 3 Page 264 of 286 Page492of514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 StUdyGL:P?0-01-02-15Printing Page 265 of 286 Page493of514 Stan V1660305 *3M Environmental Lab I Sam p le N a m e: "s110 317 a083 " Sa m p le ID: "G L P 10-01-01 -15 -0 11 D A L S S S S 1 9 0 0000" P e a k N a m e: "M 8 P F O S ( IS ) ' M a ss(e s): "507.0/80.0 am u" C o m m e n t"" Annotation: ~ Sample Index: 83 Sample Type: Unknown Concentration: 2.87 ng/mL Calculated Cone: N/A Acq. Date: 3/18/2011 Acq. Time: 11:31:08 PH File: "s1 1 0 3 1 7 a .wtfl" Modified: Yes Proc. Algorithm: IntelliQuan HQ: Noise Percentage: 50 Base. Sub. Window: 1.00 min Peak-split. Factor:2 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak width: 0.00 sec Smoothing Width: 3 po: RT Window; 30.0 sec Expected RT: 13.1 min Use Relative RT: No Int. Type: Retention Time: Area: Height: Start Time: End Time: Valley S626213.1 S3e*003 12.7 13.8 min Results Name: sll0317a.rdb I S am p le Nam e: "s110 317 a084 " S a n d le ID: "GLP1 0-0 1-01-15 P e a k N a m e: "M 8 P F O S (IS )` M a s s e s ) : "507.0/80.0 am u" C o m m e n t"" A n n o ta tio n :"" Sample Index: 84 Sample Type: Unknown Concentration: Calculated Cone: N/A Acq. Date: 3/18/2011 Acq. Time: 11:55:21 PM Modified: Proc. Algorithm: Noise Percentage: Base. Sub. Window: Peak-Split. Factor: Report Largest Peak: Min. Peak Height: Min. Peak width: Smoothing Width: RT Window: 3 Expected RT: Use Relative RT: Int. Type: Base To Base Retention Time: 13.0 min 57873 Height: 4.84e+003 Start Time End Time: 1S a m p le N a m e : "s 1 1 0 3 1 7 a 0 8 5 " S a m p le ID : 'G L P 1 0 -0 1 -0 1 -1 5 -0 1 1 I M S D A L S S S S 1 9 0 0 0 00 L a b M atrix S p ik e " P e a k N a m e: "M S P F O S (IS )" M a s s e s ) : " 507.0/80.0 am u" C o m m e n t"" Annotation: ~ Sample Type: Sample Index: 85 Concentration: Unknown calculated cone: 2.87 ng/mL Acq. Date: N/A Acq. Time: 3/19/2011 12:19:33 AM Modified: Yes Proc. Algorithm: IntelliQuan - Noise Percentage: 50 Base. Sub. Window: l.o o i Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: 0.00 Min. Peak Width: 0.00 Smoothing width: 3 RT Window: 30.0 set Expected RT: 13.1 mil Use Relative RT: No T im e, min F ile : Hs1 1 0 3 1 7 a .w iff' Int. Type: Retention Time: Area : Height : Start Time: End Time: Valley TMS a m p le N a m e : "s 1 1 0 3 1 7 a 0 8 6 " S a m p le ID : "G L P 1 0 -0 1 -0 1 -1 5 -0 1 2 D A L S S S S 1 9 0 00 0 5 " P e a k N a m e : " M 8 P F O S ( I S ) " M a s s ( e s ) : "5 0 7 .0 / 8 0 .0 ai Com m ent A n n o ta tio n : Sample Index: 86 sample Type: Unknown Concentration: 2.87 ng/mL Calculated Cone: N/A Acq. Date: 3/19/2011 Acq. Time: 12:43:49 AM File: "110317a.w iff* Modified: Yes Proc. Algorithm: IntelliQuan - MQII Noise Percentage: 50 Base. Sub. Window: Peak-Split. Factor: Report Largest Peak: Min. Peak Height: Min. Peak width: Smoothing Width: RT Window: 3 Expected RT: Use Relative RT: Int. Type: Retention Time: Area: Height: Start Time: End Time: Va 6127 5.18 Printing Date: Tuesday, April 05, 2011 TMStUdyGLP1001-02-15Printing 3 Page 266 of 286 Page494of514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 TjWStUdyGL:Pt0--Q1-02-15Printing Page 267 of 286 Page495of514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 TMStUdyGLPf0-01-Q2-15Printing 3 Page 268 of 286 Page496of514 Stan V1660305 Results Name: sll03l7a.rdb Printing Date: Tuesday, April 05, 2011 Printing T ^ s t ^ ^ ^ 0 1 - 0 2 - 1 5 Page 269 of 286 Page 497 of 514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 StUdySL:Pf0--Ql-02-15Printing Page 270 of 286 Page498of514 Stan V1660305 Results Name: s!10317a.rdb inting Date: Tuesday, April 05, 2011 inting stiMy m .= P fO ^ -02-15 Page 271 of 286 Page 499 of 514 *Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb PPrriinnttiinngg D-3a^t6e3:^T=uegsidPa1y0,-0Ap-0r2il-1505, 2011 Page 272 of 28S Page500of514 *Stan V1660305 *3M Environmental Lab Results Name: sll03l7a.rdb Printing Date: Tuesday, April 05, 2011 TMStUdyGLPfQ-01-Q2-15Printing 3 = Page 273 of 286 Page5Q1of514 **3SMtanEnVv1ir6o6n0m30e5ntal Lab Results Name: sll0317a.rdb PPrriinnttiinngg DateS:tJTduyeGsdLaPyT,0-AOpI-r0i2l-1055, 2011 Page 274 of 286 Page502of514 Stan V1660305 Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 Printing ^^-po-W -02-15 Page 275 of 286 Page 503 of 514 Stan V1660305 Results Name: sl!0317a.rdb Printing Printing TDaj^tep:stj^Tujyesgdjjafy3,fo-AWpr_i0l2-i055, 2011 Page 276 of 286 Page 504 of 514 *Stan V1660305 Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 Printing Tjfppgujyy 8 u *ft)-W -0 2 -1 5 Page 277 of 286 Page 505 of 514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 :@LPl0-01-02-15Printing Page 278 of 286 Page506of514 Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 TMStdLP10-01-02-15Printing Page 279 of 286 Page507of514 *Stan V1660305 Results Name: sll0317a.rdb Printing Printing DTa^tSet:ifciTyu-esLdPa*yT,O-AOpTr-i0l2-1055, 2011 Page 280 of 286 Page 508 of 514 *Stan V1660305 Results Name: sll0317a. Printing Date: Tuesday, April 05, 2011 Printing _02-15 Page 281 of 286 Page 509 of 514 tJ *0 to o i0>Q n> t0o0 to 0 hh t00o <7\ O o Stan V1660305 Results Name: sll0317a.rdb Stan V1660305 *3M Environmental Lab Results Name: sll0317a.rdb Printing Date: Tuesday, April 05, 2011 TMStyGLP10-01-02-15Printing Page 283 of 28S Page 511 of514 *Stan V1660305 *3M Environmental Lab I Sam p le N am e: "s110317a155" Sarrp le ID: "GLP10-01-01-15-034 D A L S S S S 2 4 OOOOCT P e a k N a m e: " M 8 P F O S ( IS ) ' M a s s e s ) : "507.0/8 0.0 am u' C o m m e n t"" Annotation: "" Sample Index: F ile : "s 1 1 0 3 1 7 a .w ifT Results Name: sll0317a.rdb I Sa m p le N a m e: "s 1 l0 3 1 7 a 1 5 6 " S a rrp le ID: "G LP1Q -01-01-15-034 D up D A L S S S S 2 4 0 0000 Lab D up licate" P e a k N a m e : "M 8 P F O S ( IS ) ' M a s s e s ) : ` 507.0/80.0 am u" C om m e n t ~ Annotation: "" Sample Index: 156 Sample Type: Unknown Concentration: 2.87 ng/mL Calculated cone: N/A Acq. Date: 3/20/2011 Acq. Time: 5:00:18 AM File: "s1 1 0 3 1 7 a.w ifr Modified: Yes Proc. Algorithm: IntelliQuan - MQII Noise Percentage: 50 Base. Sub. Window: 1.00 min Peak-Split. Factor: 2 Report Largest Peak: No Min. Peak Height: o.oo cps Min. Peak width: 0.00 sec Smoothing Width: 3 points RT Window: 30.0 sec Expected RT: 13.1 min Use Relative RT: No Int. Type: Retention Time: Area: Height: Start Time: End Time: Valley 13.1 min 46553 counts 3.7e*003 cps 12.8 ain 13.5 min I Sa m p le N a m e: "s110 317 a157 " Sa m p le ID: "GLP 10-01-01 -15 -0 34 L M S D A L S S S S 2 4 0 0000 L a b Matrix S p ik e " P e a k N a m e : nM 6 P F O S ( I S ) " M a s s e s ) : "5 0 7 .0 / 8 0 .0 am u " C o m m e n t ~ Annotation: Sample Index: 1S7 File: "s110317a.w ifT Printing Date: Tuesday, April 05, 2011 TMStUdyGLPftl-W-02-15Printing 3 S a m p le N a m e : " s 1 1 0 3 1 7 a 1 5 8 " S a m p le ID : "G L P 1 0 -0 1 -0 1 -1 5 -0 3 S D A L S S S S 2 4 0 00 0 5 " P e a k N a m e: "M 8 P F O S ( IS ) ' M a s s e s ) : "507.0/80.0 am u ' C o m m e n t "" A n n o ta tio n : "" Sample Index: 156 Sample Type: Unknown Concentration: 2.87 ng/mL Calculated Cone: n /a Acq. Date: 3/20/2011 Acq. Time: S:48:48 AM File: "s1 1 0 3 1 7 a .w iff Modified: Ye9 Proc. Algorithm: IntelliQuan - MQII Noise Percentage: 50 Base. Sub. Window: 1.00 min Peak-split. Factor: 2 Report Largest Peak: No Min. Peak Height: 0.00 cps Min. Peak Width: o.oo sec Smoothing Width: 3 point RT Window: 30.0 sec Expected RT: 13.1 min Use Relative RT: No Valley Int. Type: 13.1 min Retention Time: 39141 counts Height: Start Time: End Time: 1200 1000 800 600 400 200 520 624 __________ T im e . mn Page 284 of 286 Page512of514 Stari V1660305 *3M Environmental Lab Results Name: sll0317a.rdb StudyGLP10-91-Q2-15tjmPrinting Date: Tuesday, April 05, 2011 Printing Page 285 of 286 Page513of514 Stan V1660305 *3M Environmental Lab IS a m p le N a m e : "s 1 1 0 3 1 7 a 1 6 3 " S a m p le ID : 10 0 0 6 -0 0 so lv e n t W a n lr P e a k N a m e: "M 8 P F O S (IS )" M a s s e s ) : "507.0/80.0 am u" SamCpolmem Ienndte""x:A n n o ta ti1o6n3: -- Sample Type: Double Blank Concentration: 1.00 ng/mL Calculated Cone: N/A Acq. Date: 3/20/2011 Acq. Time: 7 :SO:02 AM File: "s110317a.w rfr Modified: Yes 40- & 35- 1 30- 25- 20- 15- 10- 5- 2 46 8 10 12 14 16 18 20 22 105 209 313 416 520 624 728 832 936 1039 1143 ___________________________________________________________T im e , min_____________________________________________________________________________________ Printing Date: Tuesday, April 05, 2011 -02-15Printing Results Name: sll0317a.rdb Page 286 of 286 Page514of514