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Region 6 - Enforcement & Compliance Assurance Division INSPECTION REPORT Inspection Date(s): Media: Regulatory Program(s) 07/24/2019 to 7/26/2019 Resource Conservation and Recovery Act Conditionally Exempt Small Quantity Generator & Treatment, Storage, and Disposal Facility Company Name: Facility Name: Facility Physical Location: (city, state, zip code) Mailing address: (city, state, zip code) County/Parish: Facility Contact: Central Plains Cement Company Tulsa Cement 2609 N 145th E. Ave Tulsa, Oklahoma 74116 2609 N 145th E. Ave Tulsa, Oklahoma 74116 Rogers County Jennifer Smith Environmental Manager Jennifer.smith@centralplainscement.com FRS Number: Identification/Permit Number: Media Number: NAICS: SIC: 110039076077 RCRA OKD064558703 OKD064558703 562211 4953 ODEQ Operations Permit No. 064557803 Personnel participating in inspection: Angela Hays EPA ECAD John Penland EPA ECAD Alicia Chen ODEQ Jennifer Smith Tulsa Cement Alan Gee Tulsa Cement Dirk Cox Tulsa Cement Debbie Ratliff Tulsa Cement Brad Porter Tulsa Cement Lead Inspector Inspector Inspector Environmental Manager President Plant Manager Laboratory Technician General Manager 214-665-2285 214-665-9717 405-702-5219 918-437-3902 x271 918-437-3902 918-437-3902 x272 918-437-3902 918-437-3902 EPA Lead Inspector Signature/Date Supervisor Signature/Date Angela Hays Angela Hays JEFFREY YURK Jeff Yurk Digitally signed by JEFFREY YURK DN: c=US, o=U.S. Government, ou=Environmental Protection Agency, cn=JEFFREY YURK, 0.9.2342.19200300.100.1.1=68001003652717 Date: 2019.11.22 09:18:06 -06'00' 11/20/2019 Date Date 6ENFORM-019-R7.3 (6/19/2019) 1 Section I - INTRODUCTION Central Plaines Cement Company / Tulsa Cement Inspection Date 07/24 -26/2019 PURPOSE OF THE INSPECTION From 07/24-26/2019, I, Angela Hays, conducted an unannounced Compliance Evaluation Inspection (CEI) of the Central Plains Cement Company also known as Tulsa Cement, located in Tulsa, Oklahoma, for compliance with the Resource Conservation and Recovery Act (RCRA). I was assisted on the inspection by Environmental Protection Agency (EPA) inspector John Penland and Oklahoma Department of Environmental Quality (ODEQ) inspector Alicia Chen. Beginning 07/24/2019, we met with representative Ms. Jennifer Smith, Environmental Manager of Tulsa Cement, and conducted an opening briefing. During this briefing we presented our credentials to Ms. Smith and explained that the inspection was being conducted under the authority of Section 3007 of RCRA. The inspection included walkthroughs of the facility's hazardous waste storage and treatment units, laboratory, and a review of the facility records related to hazardous waste management and specific evaluation of the facility's compliance with the RCRA air pollution control requirements. We concluded the inspection on 7/26/2019, with a closing conference where we presented provisional areas of concern to the facility representatives, Alan Gee, President and Dirk Cox, Plant Manager; along with Tulsa Cements neighboring facility, Systech Environmental Corporation's representative Joseph Sommer. Ms. Smith was unable to attend the closing conference. This report serves as documentation of all onsite activities and observations during the inspection of Tulsa Cement. Photographs taken during the inspection to document onsite observations are included as Attachment 1. A summary of all areas of concern identified during the inspection is provided in Section III. FACILITY DESCRIPTION Tulsa Cement LLC. d/b/a Central Plaines Cement Company, formerly Lafarge Cement, is located at 2609 N 145th E. Avenue in Tulsa, Oklahoma (Appendix 2). The facility operates two dry process rotary kilns to produce Portland cement from limestone, clay, sand, and other raw material substitutes. The kilns burn a fuel quality waste (FQW) supplied by the permitted hazardous waste storage facility of Systech Environmental Corporation (ODEQ Permit #000052452) that is located within the Tulsa Cement site. Each of these companies have different management and ownership. Systech owns the property it operates on within the Tulsa Cement plant. The air emissions from the Tulsa Cement kilns are regulated under a Title V air permit which includes the emission limits of 40 Code of Federal Regulations (CFR) 63, Subpart EEE. Tulsa Cement has elected to determine compliance with the applicable portions of CFR 264 Subpart BB Air Emission Standards for Equipment Leaks by preforming the required monitoring and inspections in compliance with the relevant provisions of 40 CFR Part 63, Subpart DD as specified in 40CFR 264.1064(m). 2 Central Plaines Cement Company / Tulsa Cement Inspection Date 07/24 -26/2019 The facility last notified as a conditionally exempt small quantity generator (CESQG) and treatment, storage, and disposal facility (TSD) on January 17, 2019. Tulsa Cement employs 120 people with a 24-hour operation schedule. Tulsa Cement operates two, 12- hour work shifts: 7:00 am to 7:00 pm and 7:00 pm to 7:00 am. Section II - OBSERVATIONS On 07/24/2019 we entered the Tulsa Cement facility at approximately 12:30. After the opening meeting, Ms. Smith assisted Alicia Chen, John Penland, and I with obtaining records for review and a tour of the laboratory and control room. The following day, 07/25/2019, we continued the facility tour with Brad Porter and viewed the cement kilns, shop, mobile garage, and oil storage area. This section documents EPA observations made during the inspection and includes reference to photographs taken during the inspection (Appendix 1). This section is sub-divided by the areas of the facility we observed. Laboratory Ms. Smith stated that the laboratory generates the only hazardous waste for the facility; one 55-gallon drum of hazardous waste every 16 months. Debbie Ratliff, the laboratory technician, stated that testing and specifications for products are conducted in the laboratory and the waste that is generated is spent ethanol, sodium hydroxide, barium chloride, and methanol. We observed the collection drum in a closed area with a closed funnel. The drum was labeled hazardous waste. Cement Kilns Hazardous waste in the form of fuel quality waste (FQW) is pumped directly from Systech Environmental to Tulsa Cement kilns. The kilns operate at 1700 degrees Celsius with higher than 10,000 Btu. Raw materials presented in the kilns are incorporated into clinker. Dust created in the kiln is caught by baghouses and reprocessed in the kiln feeding system. Cement kiln dust created is regulated under the Bevill Exclusion and not considered a hazardous waste. RCRA permit 064558703 (F1.2) specifies signs bearing the legend "DANGER--UNAUTHORIZRD PERSONNEL KEEP OUT", or similar language, be posted at the entrances to the facility and at access stairways to the kiln floor area. These signs are to be legible from a distance of at least 25 feet and are visible from all angles of approach to the kiln floors. We saw no warning signs posted at accessible areas to the kiln floor (Appendix 1, Photos:1-5). Mobile Garage The mobile garage is located west of the north storage building. Brad Porter the general manager stated that general vehicle maintenance is performed in this area. Parts washers located in the shop are maintained by Crystal Clean. During the walkthrough, we saw nine spent lead-acid batteries and one bucket of universal waste stored on a pallet with signage stating, "used lead batteries" and "universal waste" (Appendix 1: photos 9 and 10). Next to this pallet we observed one labeled 55-gallon hazardous 3 Central Plaines Cement Company / Tulsa Cement Inspection Date 07/24 -26/2019 waste drum of aerosol residue with an open funnel and identified it to Mr. Porter. The funnel was closed before we left the area (Appendix 1: Photos 6, 7, 10, and 11). Oil Storage Located east of Systech's hazardous waste tanks is the oil storage area. The area is managed by Tulsa Cement per Mr. Porter. We observed 16 drums and two totes labeled non-hazardous materials. Two unlabeled drums and one unlabeled tote stacked on top of a labeled caged tote were in the storage area (Appendix 1, Photos: 14- 18). Outside drums We observed approximately 130 drums located north of the Systech office containing spent grinding balls and cement material. Brad Porter said the material is potentially sent for recycling. Drums were damaged, unlabeled, open and material had solidified around the grinding balls. Mr. Porter was unaware of how long the drums had been in the area (Appendix 1, Photos: 12-13). Upon returning to Ms. Smith's office I requested analytical data for the spent materials in the drums. Ms. Smith stated she was unaware of any analytical data for the spent material but could provide a safety data sheet of the raw materials. She was also unaware of how long the spent materials have been onsite. On 07-26-2019, at the closing conference, Dirk Cox confirmed there was no analytical data for the spent material but would follow up with safety data sheets for the cement material and grinding balls. Mr. Cox also confirmed no other additive was placed into the drums. Records Review We requested access to various documents for review during the inspection. Ms. Smith provided the documents listed below for our review. The document's name is followed by any relevant comment from our review. Manifests - Hazardous waste shipment every 16 months. Manifest number 011651510FLE, 03/29/2018 does not have EPA ID number listed (Appendix 3). Contingency Plan - Plan lists Systech Environmental as spill response coordinators (Appendix 5). Emergency plan Financial assurance Waste analysis plan Kiln analytical report from 07/23/2019- collected each minute with one-hour parameter. Company training requirements per position Training Records - Certification of waste shipping maintained by company environmental manager, quality control manager, and shipping manager. NWC - NESHAP notification of compliance and comprehensive performance tests for December 2017, April 2018 CPCC - 07/25/2019 4 Central Plaines Cement Company / Tulsa Cement Inspection Date 07/24 -26/2019 Marsh bond # 022027302 and closure Site map Process flow diagram Tulsa air quality limits January 2019 Analytical results for bill of lading shipments / non-hazardous waste FOW 5 - Air quality permit Inspection schedule Section III - AREAS OF CONCERN Areas of concern identified during the inspection and based on document reviews are as follows: Contingency plan arrangements with first responders not documented in contingency plan per 40 CFR 264.53 (c). Contingency plan spill arrangements with Systech are inadequate based on lack of HAZWOPER training of personnel to handle hazardous waste spill response per 40 CFR 264.53 (b). Warning signage not posted near or on kiln floor per ODEQ Operations Permit No. 064557803 and 40 CFR 271.16 EPA ID number missing from manifest number 011651510FLE per 40 CFR 262.21. Hazardous waste determination for spent grind material stored in drums north of the Systech office. Safety Data Sheet (SDS) for raw material has pH level of 13+ (Appendix 3). Material has potential to be hazardous per 40 CFR 262.11. Spent grind material has potential for speculative accumulation per 261.1(c)(8). Section IV - FOLLOW UP The following information was received via e-mail from Mr. Cox of Tulsa Cement on 07/26/2019. Safety Data Sheet for Portland Cement Concrete Mixture Safety Data Sheet for Cemex Hardened Concrete (dry) Safety Data Sheet for Low CR White Iron Balls & Castings Safety Data Sheet for Medium CR White Iron Balls & Castings Analytical for grinding aid Section V - LIST OF APPENDICES Appendix 1 - Photo Log - 24 photos taken 07/25/2019 Appendix 2 - Process flow diagram Appendix 3 - Manifest Appendix 4 - Safety Data Sheets Appendix 5 - Contingency Plan 5 Central Plaines Cement Company / Tulsa Cement Inspection Date 07/24 -26/2019 Appendix 1 - Photo Log - 24 photos taken 07/25/2019 6 Central Plaines Cement Company/ Tulsa Cement Inspection Photos 07/24 - 26/2019 Photographer: Angela Hays UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Photograph Log Photo No. 1 Location: Central Plaines Cement Company/ Tulsa Cement 2609 N 145th E. Ave City: Tulsa County/Parish: Rogers State: Oklahoma Photograph File Name: DSCN0530 Date: 7/25/2019 Approximate Time: 1:00 pm Photographer: Angela Hays, EPA Description: Signage on the outside of kiln floor building Central Plaines Cement Company/ Tulsa Cement Inspection Photos 07/24 - 26/2019 Photographer: Angela Hays UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Photograph Log Photo No. 2 Location: Central Plaines Cement Company/ Tulsa Cement 2609 N 145th E. Ave City: Tulsa County/Parish: Rogers State: Oklahoma Photograph File Name: DSCN0531 Date: 7/25/2019 Approximate Time: 1:05 pm Photographer: Angela Hays, EPA Description: Overview of signage on the outside of kiln floor building Central Plaines Cement Company/ Tulsa Cement Inspection Photos 07/24 - 26/2019 Photographer: Angela Hays UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Photograph Log Photo No. 3 Location: Central Plaines Cement Company/ Tulsa Cement 2609 N 145th E. Ave City: Tulsa County/Parish: Rogers State: Oklahoma Photograph File Name: DSCN0532 Date: 7/25/2019 Approximate Time: 1:10 pm Photographer: Angela Hays, EPA Description: Signage on the inside of kiln floor building - Fuel Quality Waste Personal Protective Equipment cabinet Central Plaines Cement Company/ Tulsa Cement Inspection Photos 07/24 - 26/2019 Photographer: Angela Hays UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Photograph Log Photo No. 4 Location: Central Plaines Cement Company/ Tulsa Cement 2609 N 145th E. Ave City: Tulsa County/Parish: Rogers State: Oklahoma Photograph File Name: DSCN0533 Date: 7/25/2019 Approximate Time: 1:15 pm Photographer: Angela Hays, EPA Description: Signage on the inside of kiln floor building - Gun Room Central Plaines Cement Company/ Tulsa Cement Inspection Photos 07/24 - 26/2019 Photographer: Angela Hays UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Photograph Log Photo No. 5 Location: Central Plaines Cement Company/ Tulsa Cement 2609 N 145th E. Ave City: Tulsa County/Parish: Rogers State: Oklahoma Photograph File Name: DSCN0534 Date: 7/25/2019 Approximate Time: 1:20 pm Photographer: Angela Hays, EPA Description: Signage on the inside of kiln floor building Central Plaines Cement Company/ Tulsa Cement Inspection Photos 07/24 - 26/2019 Photographer: Angela Hays UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Photograph Log Photo No. 6 Location: Central Plaines Cement Company/ Tulsa Cement 2609 N 145th E. Ave City: Tulsa County/Parish: Rogers State: Oklahoma Photograph File Name: DSCN0535 Date: 7/25/2019 Approximate Time: 1:30 pm Photographer: Angela Hays, EPA Description: Open drum of aerosol residue between spent lead battery accumulation area and open collection container for punctured aerosol cans located in the mobile garage. Central Plaines Cement Company/ Tulsa Cement Inspection Photos 07/24 - 26/2019 Photographer: Angela Hays UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Photograph Log Photo No. 7 Location: Central Plaines Cement Company/ Tulsa Cement 2609 N 145th E. Ave City: Tulsa County/Parish: Rogers State: Oklahoma Photograph File Name: DSCN0536 Date: 7/25/2019 Approximate Time: 1:32 pm Photographer: Angela Hays, EPA Description: Close up of open drum of aerosol residue located in the mobile garage. Central Plaines Cement Company/ Tulsa Cement Inspection Photos 07/24 - 26/2019 Photographer: Angela Hays UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Photograph Log Photo No. 8 Location: Central Plaines Cement Company/ Tulsa Cement 2609 N 145th E. Ave City: Tulsa County/Parish: Rogers State: Oklahoma Photograph File Name: DSCN0537 Date: 7/25/2019 Approximate Time: 1:34 pm Photographer: Angela Hays, EPA Description: Close up of open collection container for punctured aerosol cans located in the mobile garage. Central Plaines Cement Company/ Tulsa Cement Inspection Photos 07/24 - 26/2019 Photographer: Angela Hays UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Photograph Log Photo No. 9 Location: Central Plaines Cement Company/ Tulsa Cement 2609 N 145th E. Ave City: Tulsa County/Parish: Rogers State: Oklahoma Photograph File Name: DSCN0538 Date: 7/25/2019 Approximate Time: 1:36 pm Photographer: Angela Hays, EPA Description: Close up of spent battery accumulation area located in the mobile garage. Central Plaines Cement Company/ Tulsa Cement Inspection Photos 07/24 - 26/2019 Photographer: Angela Hays UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Photograph Log Photo No. 10 Location: Central Plaines Cement Company/ Tulsa Cement 2609 N 145th E. Ave City: Tulsa County/Parish: Rogers State: Oklahoma Photograph File Name: DSCN0539 Date: 7/25/2019 Approximate Time: 1:38 pm Photographer: Angela Hays, EPA Description: Overview of drum of aerosol residue between spent lead battery accumulation area and open collection container for punctured aerosol cans located in the mobile garage. Central Plaines Cement Company/ Tulsa Cement Inspection Photos 07/24 - 26/2019 Photographer: Angela Hays UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Photograph Log Photo No. 11 Location: Central Plaines Cement Company/ Tulsa Cement 2609 N 145th E. Ave City: Tulsa County/Parish: Rogers State: Oklahoma Photograph File Name: DSCN0540 Date: 7/25/2019 Approximate Time: 1:40 pm Photographer: Angela Hays, EPA Description: Overview of corrected closed drum of aerosol located in the mobile garage. Central Plaines Cement Company/ Tulsa Cement Inspection Photos 07/24 - 26/2019 Photographer: Angela Hays UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Photograph Log Photo No. 12 Location: Central Plaines Cement Company/ Tulsa Cement 2609 N 145th E. Ave City: Tulsa County/Parish: Rogers State: Oklahoma Photograph File Name: DSCN0541 Date: 7/25/2019 Approximate Time: 1:50 pm Photographer: Angela Hays, EPA Description: Overview of damaged and open drums containing grinding balls and cement located on the north side of the north storage building. Central Plaines Cement Company/ Tulsa Cement Inspection Photos 07/24 - 26/2019 Photographer: Angela Hays UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Photograph Log Photo No. 13 Location: Central Plaines Cement Company/ Tulsa Cement 2609 N 145th E. Ave City: Tulsa County/Parish: Rogers State: Oklahoma Photograph File Name: DSCN0542 Date: 7/25/2019 Approximate Time: 1:55 pm Photographer: Angela Hays, EPA Description: Overview of damaged and open drums containing grinding balls and cement located on the north side of the north storage building. Central Plaines Cement Company/ Tulsa Cement Inspection Photos 07/24 - 26/2019 Photographer: Angela Hays UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Photograph Log Photo No. 14 Location: Central Plaines Cement Company/ Tulsa Cement 2609 N 145th E. Ave City: Tulsa County/Parish: Rogers State: Oklahoma Photograph File Name: DSCN0543 Date: 7/25/2019 Approximate Time: 1:55 pm Photographer: Angela Hays, EPA Description: Unlabeled drum in oil storage area. Central Plaines Cement Company/ Tulsa Cement Inspection Photos 07/24 - 26/2019 Photographer: Angela Hays UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Photograph Log Photo No. 15 Location: Central Plaines Cement Company/ Tulsa Cement 2609 N 145th E. Ave City: Tulsa County/Parish: Rogers State: Oklahoma Photograph File Name: DSCN0546 Date: 7/25/2019 Approximate Time: 2:05 pm Photographer: Angela Hays, EPA Description: Overview of oil storage area. Both drums and top tote in foreground are unlabeled. Central Plaines Cement Company/ Tulsa Cement Inspection Photos 07/24 - 26/2019 Photographer: Angela Hays UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Photograph Log Photo No. 16 Location: Central Plaines Cement Company/ Tulsa Cement 2609 N 145th E. Ave City: Tulsa County/Parish: Rogers State: Oklahoma Photograph File Name: DSCN0547 Date: 7/25/2019 Approximate Time: 2:10 pm Photographer: Angela Hays, EPA Description: Unlabeled drum in oil storage area. Central Plaines Cement Company/ Tulsa Cement Inspection Photos 07/24 - 26/2019 Photographer: Angela Hays UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Photograph Log Photo No. 17 Location: Central Plaines Cement Company/ Tulsa Cement 2609 N 145th E. Ave City: Tulsa County/Parish: Rogers State: Oklahoma Photograph File Name: DSCN0548 Date: 7/25/2019 Approximate Time: 2:15 pm Photographer: Angela Hays, EPA Description: Unlabeled top tote in oil storage area. Central Plaines Cement Company/ Tulsa Cement Inspection Photos 07/24 - 26/2019 Photographer: Angela Hays UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Photograph Log Photo No. 18 Location: Central Plaines Cement Company/ Tulsa Cement 2609 N 145th E. Ave City: Tulsa County/Parish: Rogers State: Oklahoma Photograph File Name: DSCN0549 Date: 7/25/2019 Approximate Time: 2:18 pm Photographer: Angela Hays, EPA Description: Unlabeled top tote in oil storage area. Central Plaines Cement Company/ Tulsa Cement Inspection Photos 07/24 - 26/2019 Photographer: Angela Hays UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Photograph Log Photo No. 19 Location: Central Plaines Cement Company/ Tulsa Cement 2609 N 145th E. Ave City: Tulsa County/Parish: Rogers State: Oklahoma Photograph File Name: DSCN0550 Date: 7/25/2019 Approximate Time: 2:30 pm Photographer: Angela Hays, EPA Description: Overview of open funnel on used oil collection tote in shop Central Plaines Cement Company/ Tulsa Cement Inspection Photos 07/24 - 26/2019 Photographer: Angela Hays UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Photograph Log Photo No. 20 Location: Central Plaines Cement Company/ Tulsa Cement 2609 N 145th E. Ave City: Tulsa County/Parish: Rogers State: Oklahoma Photograph File Name: DSCN0551 Date: 7/25/2019 Approximate Time: 2:32 pm Photographer: Angela Hays, EPA Description: Close up of open funnel on used oil collection tote in shop Central Plaines Cement Company/ Tulsa Cement Inspection Photos 07/24 - 26/2019 Photographer: Angela Hays UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Photograph Log Photo No. 21 Location: Central Plaines Cement Company/ Tulsa Cement 2609 N 145th E. Ave City: Tulsa County/Parish: Rogers State: Oklahoma Photograph File Name: DSCN0552 Date: 7/25/2019 Approximate Time: 2:40 pm Photographer: Angela Hays, EPA Description: Signage in shop for waste labeling station and logbook as well as lead-acid battery accumulation. The area is now used for a parts washer unit and is not utilized for lead-acid accumulation. Central Plaines Cement Company/ Tulsa Cement Inspection Photos 07/24 - 26/2019 Photographer: Angela Hays UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Photograph Log Photo No. 22 Location: Central Plaines Cement Company/ Tulsa Cement 2609 N 145th E. Ave City: Tulsa County/Parish: Rogers State: Oklahoma Photograph File Name: DSCN0553 Date: 7/25/2019 Approximate Time: 2:45 pm Photographer: Angela Hays, EPA Description: Overview of signage in shop for regulated waste storage area and guidelines. This area currently used this area for a parts washer and products; it is not utilized for hazardous waste storage. Central Plaines Cement Company/ Tulsa Cement Inspection Photos 07/24 - 26/2019 Photographer: Angela Hays UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Photograph Log Photo No. 23 Location: Central Plaines Cement Company/ Tulsa Cement 2609 N 145th E. Ave City: Tulsa County/Parish: Rogers State: Oklahoma Photograph File Name: DSCN0554 Date: 7/25/2019 Approximate Time: 2:50 pm Photographer: Angela Hays, EPA Description: Signage in shop for regulated waste storage area and guidelines. This area currently used this area for a parts washer and products; it is not utilized for hazardous waste storage. Central Plaines Cement Company/ Tulsa Cement Inspection Photos 07/24 - 26/2019 Photographer: Angela Hays UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Photograph Log Photo No. 24 Location: Central Plaines Cement Company/ Tulsa Cement 2609 N 145th E. Ave City: Tulsa County/Parish: Rogers State: Oklahoma Photograph File Name: DSCN0555 Date: 7/25/2019 Approximate Time: 2:55 pm Photographer: Angela Hays, EPA Description: Soiled PPE in regular trash Central Plaines Cement Company / Tulsa Cement Inspection Date 07/24 -26/2019 Appendix 2 - Process flow diagram 7 Central Plaines Cement Company / Tulsa Cement Inspection Date 07/24 -26/2019 Appendix - Manifest 9 Central Plaines Cement Company / Tulsa Cement Inspection Date 07/24 -26/2019 Appendix - Safety Data Sheets 10 Portland Cement Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations Revision Date: 04/17/2015 Date of issue: 03/12/2015 Version: 1.0 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Mixture Product Name: Portland Cement Synonyms: Central Plains Cement - Portland Cement - Type I, I Low alkali, II, II Low alkali, II MH, III, V, Masonry Type N, Masonry Type S, Oil Well - Class C, Class G, Class H. Hydraulic cement. 1.2. Intended Use of the Product Concrete mixes for construction 1.3. Name, Address, and Telephone of the Responsible Party Manufacturer Manufacturer Central Plains Cement Central Plains Cement 2609 N. 145th East Ave 200 N Courtney Road 74116 Tulsa, OK - USA T 918-437-3902 64050 Sugar Creek, MO - USA T 816-257-3683 www.centralplainscement.com 1.4. Emergency Telephone Number Emergency Number : 816-257-3676 SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Skin Corr. 1A Eye Dam. 1 H314 H318 Skin Sens. 1 H317 STOT SE 3 H335 Full text of H-phrases: see section 16 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) : Signal Word (GHS-US) Hazard Statements (GHS-US) Precautionary Statements (GHS-US) 04/17/2015 GHS05 GHS07 : Danger : H314 - Causes severe skin burns and eye damage. H317 - May cause an allergic skin reaction. H318 - Causes serious eye damage. H335 - May cause respiratory irritation. : P260 - Do not breathe dust. P264 - Wash hands, forearms, and exposed areas thoroughly after handling. P271 - Use only outdoors or in a well-ventilated area. P272 - Contaminated work clothing must not be allowed out of the workplace. P280 - Wear eye protection, face protection, protective clothing, and protective gloves. P301+P330+P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P302+P352 - IF ON SKIN: Wash with plenty of water. P303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 - IF INHALED: Remove person to fresh air and keep at rest in a position comfortable for breathing. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 - Immediately call a POISON CENTER, a doctor. P333+P313 - If skin irritation or rash occurs: Get medical advice/attention. P362+P364 - Take off contaminated clothing and wash it before reuse. P403+P233 - Store in a well-ventilated place. Keep container tightly closed. P405 - Store locked up. P501 - Dispose of contents/container in accordance with local, regional, national, EN (English US) 1/7 Portland Cement Safety Data Sheet According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations and international regulations. 2.3. Other Hazards Exposure may aggravate those with pre-existing eye, skin, or respiratory conditions. 2.4. Unknown Acute Toxicity (GHS-US) No data available SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Not applicable 3.2. Mixture Name Product Identifier % Classification (GHS-US) Cement, portland, chemicals (CAS No) 65997-15-1 30 - 100 Skin Irrit. 2, H315 Eye Dam. 1, H318 Skin Sens. 1, H317 STOT SE 3, H335 Limestone (CAS No) 1317-65-3 0 - 50 Not classified Calcium hydroxide (CAS No) 1305-62-0 0 - 20 Skin Irrit. 2, H315 Eye Dam. 1, H318 STOT SE 3, H335 Aquatic Acute 3, H402 Gypsum (Ca(SO4).2H2O) (CAS No) 13397-24-5 2 - 10 Not classified Calcium oxide (CAS No) 1305-78-8 0 - 5 Skin Irrit. 2, H315 Eye Dam. 1, H318 STOT SE 3, H335 Magnesium oxide (MgO) (CAS No) 1309-48-4 0 - 4 Not classified Full text of H-phrases: see section 16 SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid Measures After Inhalation: When symptoms occur: go into open air and ventilate suspected area. Obtain medical attention if breathing difficulty persists. First-aid Measures After Skin Contact: Remove contaminated clothing. Immediately flush skin with plenty of water for at least 60 minutes. Get medical advice/attention. Wash contaminated clothing before reuse. First-aid Measures After Eye Contact: Rinse cautiously with water for at least 60 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Obtain medical attention. First-aid Measures After Ingestion: Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor/physician. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Causes severe skin burns and eye damage. May cause an allergic skin reaction. May cause respiratory irritation. Symptoms/Injuries After Inhalation: Dust may cause respiratory irritation. Symptoms/Injuries After Skin Contact: Causes severe skin burns. May cause an allergic skin reaction. Symptoms/Injuries After Eye Contact: Causes serious eye damage. Symptoms/Injuries After Ingestion: Ingestion is likely to be harmful or have adverse effects. Cement should not be eaten under any circumstances. Chronic Symptoms: Portland cement may contain trace amounts (<0.1%) of free crystalline silica. Repeated or prolonged exposure to respirable (airborne) crystalline silica dust will cause lung damage in the form of silicosis. Symptoms will include progressively more difficult breathing, cough, fever, and weight loss. 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed If you feel unwell, seek medical advice. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Use extinguishing media appropriate for surrounding fire. Unsuitable Extinguishing Media: Do not use a heavy water stream. 04/17/2015 EN (English US) 2/7 Portland Cement Safety Data Sheet According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Non-combustible. Explosion Hazard: Product is not explosive. Reactivity: Wet cement is alkaline and is incompatible with acids, ammonium salts and aluminum metal. Cement dissolves in hydrofluoric acid, producing corrosive silicon tetrafluoride gas. Cement reacts with water to form silicates and calcium hydroxide. Silicates react with powerful oxidizers such as fluorine, boron trifluoride, chlorine trifluoride, manganese trifluoride, and oxygen difluoride. 5.3. Advice for Firefighters Precautionary Measures Fire: Exercise caution when fighting any chemical fire. Firefighting Instructions: Do not allow run-off from fire fighting to enter drains or water sources. Do not breathe fumes or vapors from fire. Protection During Firefighting: Do not enter fire area without proper protective equipment, including respiratory protection. Other Information: Refer to Section 9 for flammability properties. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Avoid all contact with skin, eyes, or clothing. Do not breathe dust. 6.1.1. For Non-emergency Personnel Protective Equipment: Use appropriate personal protection equipment (PPE). Emergency Procedures: Evacuate unnecessary personnel. 6.1.2. For Emergency Responders Protective Equipment: Equip cleanup crew with proper protection. Emergency Procedures: Upon arrival at the scene, a first responder is expected to recognize the presence of dangerous goods, protect oneself and the public, secure the area, and call for the assistance of trained personnel as soon as conditions permit. 6.2. Environmental Precautions Prevent entry to sewers and public waters. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Contain and collect as any solid. Avoid creating or spreading dust. Methods for Cleaning Up: Clean up spills immediately and dispose of waste safely. Recover the spillage in a dry state if possible. Minimize generation of airborne dust. The product can be slurried by the addition of water but will subsequently set as a hard material. Keep children away from the clean-up operation. Transfer spilled material to a suitable container for disposal. Utilize a dust suppressant when removing mechanically. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. Concerning disposal elimination after cleaning, see item 13. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Precautions for Safe Handling: Do not breathe dust. Use only outdoors or in a well-ventilated area. Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures. Wash hands and other exposed areas with mild soap and water before eating, drinking, or smoking and again when leaving work. Do not eat, drink or smoke when using this product. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Comply with applicable regulations. Storage Conditions: Store in a dry, cool and well-ventilated place. Keep container closed when not in use. Incompatible Products: Strong acids. Strong bases. Strong oxidizers. 7.3. Specific End Use(s) Concrete mixes for construction SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters For substances listed in section 3 that are not listed here, there are no established exposure limits from the manufacturer, supplier, importer, or the appropriate advisory agency including: ACGIH (TLV), NIOSH (REL), or OSHA (PEL). Cement, portland, chemicals (65997-15-1) USA ACGIH ACGIH TWA (mg/m) USA ACGIH ACGIH chemical category USA NIOSH NIOSH REL (TWA) (mg/m) USA IDLH US IDLH (mg/m) 1 mg/m (particulate matter containing no asbestos and <1% crystalline silica, respirable fraction) Not Classifiable as a Human Carcinogen 10 mg/m (total dust) 5 mg/m (respirable dust) 5000 mg/m 04/17/2015 EN (English US) 3/7 Portland Cement Safety Data Sheet According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations USA OSHA OSHA PEL (TWA) (mg/m) Gypsum (Ca(SO4).2H2O) (13397-24-5) USA ACGIH ACGIH TWA (mg/m) USA NIOSH NIOSH REL (TWA) (mg/m) USA OSHA OSHA PEL (TWA) (mg/m) Limestone (1317-65-3) USA NIOSH NIOSH REL (TWA) (mg/m) USA OSHA OSHA PEL (TWA) (mg/m) Calcium hydroxide (1305-62-0) USA ACGIH ACGIH TWA (mg/m) USA NIOSH NIOSH REL (TWA) (mg/m) USA OSHA OSHA PEL (TWA) (mg/m) Calcium oxide (1305-78-8) USA ACGIH ACGIH TWA (mg/m) USA NIOSH NIOSH REL (TWA) (mg/m) USA IDLH US IDLH (mg/m) USA OSHA OSHA PEL (TWA) (mg/m) Magnesium oxide (MgO) (1309-48-4) USA ACGIH ACGIH TWA (mg/m) USA ACGIH ACGIH chemical category USA IDLH US IDLH (mg/m) USA OSHA OSHA PEL (TWA) (mg/m) 8.2. Exposure Controls Appropriate Engineering Controls Personal Protective Equipment 15 mg/m (total dust) 5 mg/m (respirable fraction) 10 mg/m (inhalable fraction) 10 mg/m (total dust) 5 mg/m (respirable dust) 15 mg/m (total dust) 5 mg/m (respirable fraction) 10 mg/m (total dust) 5 mg/m (respirable dust) 15 mg/m (total dust) 5 mg/m (respirable fraction) 5 mg/m 5 mg/m 15 mg/m (total dust) 5 mg/m (respirable fraction) 2 mg/m 2 mg/m 25 mg/m 5 mg/m 10 mg/m (inhalable fraction) Not Classifiable as a Human Carcinogen 750 mg/m (fume) 15 mg/m (fume, total particulate) : Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Ensure adequate ventilation, especially in confined areas. Ensure all national/local regulations are observed. : Protective goggles. Face shield. Gloves. Protective clothing. Insufficient ventilation: wear respiratory protection. Materials for Protective Clothing Hand Protection Eye Protection Skin and Body Protection Respiratory Protection Environmental Exposure Controls Consumer Exposure Controls : Corrosion-proof clothing. : Wear chemically resistant protective gloves. : Chemical safety goggles and face shield. : Wear suitable protective clothing. : If exposure limits are exceeded or irritation is experienced, approved respiratory protection should be worn. : Avoid release to the environment. : Do not eat, drink or smoke during use. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State : Solid Appearance Odor : Gray or white powder : No distinct odor Odor Threshold : No data available pH : 12 - 13 Evaporation Rate : No data available 04/17/2015 EN (English US) 4/7 Portland Cement Safety Data Sheet According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Melting Point : No data available Freezing Point : No data available Boiling Point : > 1000 C (1832 F) Flash Point : No data available Auto-ignition Temperature : No data available Decomposition Temperature : No data available Flammability (solid, gas) : No data available Vapor Pressure : No data available Relative Vapor Density at 20 C : No data available Relative Density : No data available Specific Gravity Solubility : 3.15 : Water: Slightly soluble (0.1 to 1%) Partition Coefficient: N-Octanol/Water : No data available Viscosity : No data available 9.2. Other Information No additional information available SECTION 10: STABILITY AND REACTIVITY 10.1. Reactivity: Wet cement is alkaline and is incompatible with acids, ammonium salts and aluminum metal. Cement dissolves in hydrofluoric acid, producing corrosive silicon tetrafluoride gas. Cement reacts with water to form silicates and calcium hydroxide. Silicates react with powerful oxidizers such as fluorine, boron trifluoride, chlorine trifluoride, manganese trifluoride, and oxygen difluoride. 10.2. Chemical Stability: Stable under normal ambient conditions. 10.3. Possibility of Hazardous Reactions: Hazardous polymerization will not occur. 10.4. Conditions to Avoid: Direct sunlight. Extremely high or low temperatures. Incompatible materials. 10.5. Incompatible Materials: Acids. Ammonium salts. Aluminum. 10.6. Hazardous Decomposition Products: None known. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information On Toxicological Effects Acute Toxicity: Not classified Calcium hydroxide (1305-62-0) LD50 Oral Rat 7340 mg/kg Calcium oxide (1305-78-8) LD50 Oral Rat LD50 Dermal Rabbit > 2000 mg/kg > 2500 mg/kg Skin Corrosion/Irritation: Causes severe skin burns and eye damage. pH: 12 - 13 Serious Eye Damage/Irritation: Causes serious eye damage. pH: 12 - 13 Respiratory or Skin Sensitization: May cause an allergic skin reaction. Germ Cell Mutagenicity: Not classified Carcinogenicity: Not classified Reproductive Toxicity: Not classified Specific Target Organ Toxicity (Single Exposure): May cause respiratory irritation. Specific Target Organ Toxicity (Repeated Exposure): Not classified Aspiration Hazard: Not classified Symptoms/Injuries After Inhalation: Dust may cause respiratory irritation. Symptoms/Injuries After Skin Contact: Causes severe skin burns. May cause an allergic skin reaction. Symptoms/Injuries After Eye Contact: Causes serious eye damage. Symptoms/Injuries After Ingestion: Ingestion is likely to be harmful or have adverse effects. Cement should not be eaten under any circumstances. Chronic Symptoms: Portland cement may contain trace amounts (<0.1%) of free crystalline silica. Repeated or prolonged exposure to respirable (airborne) crystalline silica dust will cause lung damage in the form of silicosis. Symptoms will include progressively more difficult breathing, cough, fever, and weight loss. 04/17/2015 EN (English US) 5/7 Portland Cement Safety Data Sheet According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Calcium hydroxide (1305-62-0) LC50 Fish 1 50.6 mg/l Calcium oxide (1305-78-8) LC50 Fish 1 1070 mg/l (Exposure time: 96 h - Species: Cyprinus carpio [static]) 12.2. Persistence and Degradability Portland Cement (68475-76-3) Persistence and Degradability Not established. 12.3. Bioaccumulative Potential Portland Cement (68475-76-3) Bioaccumulative Potential Calcium hydroxide (1305-62-0) BCF fish 1 Calcium oxide (1305-78-8) BCF fish 1 Not established. (no bioaccumulation) (no bioaccumulation) 12.4. Mobility in Soil No additional information available 12.5. Other Adverse Effects Other Information : Avoid release to the environment. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Sewage Disposal Recommendations: Do not empty into drains. Do not dispose of waste into sewer. Waste Disposal Recommendations: Dispose of waste material in accordance with all local, regional, national, and international regulations. SECTION 14: TRANSPORT INFORMATION 14.1. In Accordance with DOT Not regulated for transport 14.2. In Accordance with IMDG Not regulated for transport 14.3. In Accordance with IATA Not regulated for transport SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations Portland Cement (68475-76-3) SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Delayed (chronic) health hazard Cement, portland, chemicals (65997-15-1) Listed on the United States TSCA (Toxic Substances Control Act) inventory Limestone (1317-65-3) Listed on the United States TSCA (Toxic Substances Control Act) inventory Calcium hydroxide (1305-62-0) Listed on the United States TSCA (Toxic Substances Control Act) inventory Calcium oxide (1305-78-8) Listed on the United States TSCA (Toxic Substances Control Act) inventory SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Magnesium oxide (MgO) (1309-48-4) Listed on the United States TSCA (Toxic Substances Control Act) inventory 15.2 US State Regulations Cement, portland, chemicals (65997-15-1) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List Gypsum (Ca(SO4).2H2O) (13397-24-5) U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List 04/17/2015 EN (English US) 6/7 Portland Cement Safety Data Sheet According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Limestone (1317-65-3) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List Calcium hydroxide (1305-62-0) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List Calcium oxide (1305-78-8) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List Magnesium oxide (MgO) (1309-48-4) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision Date Other Information : 04/17/2015 : This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR 1910.1200. Portland cement should only be used by knowledgeable persons. Inexperienced product users must obtain proper training before using this product. A key to using the product safely requires the user to recognize that Portland cement chemically reacts with water, and that some of the intermediate products of this reaction (that is, those present while a Portland cement product is "setting") pose a far more severe hazard than does Portland cement itself. GHS Full Text Phrases: ------ Aquatic Acute 3 ------ Eye Dam. 1 ------ Skin Corr. 1A ------ Skin Irrit. 2 ------ Skin Sens. 1 ------ STOT SE 3 ------ H314 ------ H315 ------ H317 ------ H318 ------ H335 ------ H402 Hazardous to the aquatic environment - Acute Hazard Category 3 Serious eye damage/eye irritation Category 1 Skin corrosion/irritation Category 1A Skin corrosion/irritation Category 2 Skin sensitization Category 1 Specific target organ toxicity (single exposure) Category 3 Causes severe skin burns and eye damage Causes skin irritation May cause an allergic skin reaction Causes serious eye damage May cause respiratory irritation Harmful to aquatic life This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product. SDS US (GHS HazCom) 04/17/2015 EN (English US) 7/7 Safety Data Sheet Page 1 of 11 Hardened Concrete (dry) Section 1. Identification Product identifier: Other means of identification: Chemical name: Relevant Uses: Manufacturers Name: Address: Emergency telephone number: Hardened Concrete (dry) Dried Concrete Calcium compounds, calcium silicate compounds, and other calcium compounds containing iron and aluminum make up the majority of this product. Building materials, a basic structural component in construction. CEMEX 10100 Katy Freeway, Suite 300 Houston, TX 77043 T Customer Care 1-800-99-CEMEX CHEMTREC: 1-800-424-9300 Section 2. Hazards Identification As packaged, this material does not present significant health hazards. The hazards below apply to the product if aerosols or dusts are generated from cutting, grinding, or pulverizing. OSHA/HCS status: This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Category Classification(s): GHS label elements: SKIN CORROSION/IRRITATION - Category 1 EYE DAMAGE - Category 1 SKIN SENSITIZATION - Category 1 CARCINOGENICITY/INHALATION - Category 1 SINGLE TARGET ORGAN TOXICITY (SINGLE EXPOSURE) - Category 3 SINGLE TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Hazard pictograms: Signal word: Hazard statements: GHS05 GHS07 GHS08 Danger Causes severe skin burns and eye damage May cause an allergic skin reaction Causes serious eye damage May cause respiratory irritation May cause cancer (Dermal, Inhalation) May cause damage to organs (eye, lung/respiratory system, Skin) through prolonged or repeated exposure (Dermal, Inhalation) Precautionary Statements: Other Hazards: Safety Data Sheet Page 2 of 11 Obtain special instructions before use Do not handle until all safety precautions have been read and understood Do not breathe dust, spray, mist, fume Avoid breathing dust, spray, mist, fume Wash clothing, hands, forearms and face thoroughly after handling Use only outdoors or in a well-ventilated area Contaminated work clothing must not be allowed out of the workplace Wear eye protection, protective clothing, protective gloves If swallowed: rinse mouth. Do NOT induce vomiting If on skin: Wash with plenty of soap and water If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower If inhaled: Remove person to fresh air and keep comfortable for breathing If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If exposed or concerned: Get medical advice/attention Immediately call a POISON CENTER Call a poison center if you feel unwell Get medical advice/attention if you feel unwell Specific treatment (see Section 4 on this label) If skin irritation or rash occurs: Get medical advice/attention Take off contaminated clothing and wash it before reuse Wash contaminated clothing before reuse Store in a well-ventilated place. Keep container tightly closed Dispose of contents/container to comply with local/regional/national regulations Trace amounts of naturally occurring chemicals might be detected during chemical analysis. Trace constituents may include insoluble residue, some of which may be free Quartz (crystalline silica), calcium oxide (Also known as lime or quick lime), magnesium oxide, potassium sulfate, sodium sulfate, chromium compounds, and nickel compounds. Section 3. Composition / Information on Ingredients Substance/mixture: Hardened Concrete (dry) - mixture Chemical name: Calcium compounds; calcium silicates and calcium oxides make up the majority of this product - calcium compounds can contain small amounts or iron and aluminum. Portland Cement Limestone Ingredient Name % Content 10 - 30 25 - 65 CAS number 65997-15-1 1317-65-3 Calcium Oxide Amorphous Silica Quartz (crystalline silica) Hexavalent chromium* <=20.85 <=6.55 0 - 1.8 * 1305-78-8 61790-53-2 14808-60-7 18450-29-9 Any concentration shown as a range is to protect confidentiality or is due to process variation. *Hexavalent chromium is included due to dermal sensitivity associated with the component. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Section 4. First-Aid Measures As packaged, this material does not present significant health hazards. The hazards below apply to the product if aerosols or dusts are generated from cutting, grinding, or pulverizing. Description of necessary first aid measures: Safety Data Sheet Page 3 of 11 General: Eye contact: Inhalation: Skin contact: Ingestion: Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Get medical attention immediately. Call a poison center or physician. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 15 minutes. Chemical burns must be treated promptly by a physician. Seek medical help if coughing or other symptoms persist. Inhalation of large amounts of Hardened Concrete (dry) dust requires immediate medical attention. Call a poison center or physician. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If the individual is not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Get medical attention immediately. Heavy exposure to Hardened Concrete (dry) dust, wet concrete or associated water requires prompt attention. Quickly remove contaminated clothing, shoes, and leather goods such as watchbands and belts. Quickly and gently blot or brush away excess Hardened Concrete (dry) dust. Immediately wash thoroughly with lukewarm, gently flowing water and non-abrasive pH neutral soap. Seek medical attention for rashes, burns, irritation, dermatitis and prolonged unprotected exposures to wet cement, cement mixtures or liquids from wet cement. Burns should be treated as caustic burns. Get medical attention immediately. Call a poison center or physician. Have victim rinse mouth thoroughly with water. DO NOT INDUCE VOMITING unless directed to do so by medical personnel. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Have victim drink 60 to 240 mL (2 to 8 oz.) of water. Stop giving water if the exposed person feels sick as vomiting may be dangerous. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Chemical burns must be treated promptly by a physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Potential symptoms and effects from acute exposures (delayed or immediate): Eye contact: Causes serious eye damage. Inhalation: May cause respiratory irritation. Skin contact: Causes severe burns. Discomfort or pain cannot be relied upon to alert a person to a serious injury. You may not feel pain or the severity of the burn until hours after the exposure. Chemical burns must be treated promptly by a physician. May cause an allergic skin reaction. Ingestion: Not expected to be a significant route of entry. May cause burns to mouth, throat and stomach. Potential symptoms and effects from over-exposures: Eye contact: Adverse symptoms may include the following: pain, watering and redness Inhalation: Adverse symptoms may include the following: respiratory tract irritation and coughing Skin contact: Adverse symptoms may include the following: pain or irritation, redness and blistering may occur, skin burns, ulceration and necrosis may occur Ingestion: Adverse symptoms may include the following: stomach pains Recommendations for immediate medical attention / treatment: If large quantities have been Ingested or inhaled: Seek medical attention and contact poison treatment specialist immediately. Notes to physician: Treat symptomatically. Protection of first-aiders: Safety Data Sheet Page 4 of 11 No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Section 5. Fire-fighting Measures Extinguishing media Suitable extinguishing media: Non-flammable. Use an extinguishing agent suitable for the surrounding fire. Specific hazards arising from the chemical: No specific fire or explosion hazard. Hazardous thermal decomposition Decomposition products may include the following materials: carbon dioxide, carbon products: monoxide, sulfur oxides and metal oxide/oxides products: Special protective actions for firefighters: Evacuate area. Fight fire with normal precautions from a reasonable distance. Move containers from fire area if this can be done without risk. Special protective equipment for fire-fighters: Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters' protective clothing will provide adequate protection. Section 6. Accidental Release Measures Personal precautions, protective equipment and emergency procedures No action shall be taken involving any personal risk or without suitable training. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For personal protective clothing requirements, please see Section 8. For non-emergency personnel: For emergency responders: Environmental precautions: Evacuate area, if necessary. Contact emergency personnel, if needed. Do not breathe dust. Stay upwind. Evacuate surrounding areas if necessary. Keep unnecessary and unprotected personnel from entering. Do not breathe dust. Provide adequate ventilation. Avoid release to the environment. Contain the spill to avoid the discharge of spilled material into drains, surface waters and/or groundwater. If the spilled material enters any drainage systems, surface waters and/or groundwater, follow all applicable local, state and federal laws and regulations for additional clean-up and/or reporting requirements. Methods and materials for containment and cleaning up Small and large spills: Wear appropriate personal protective equipment as described in Section 8 for cleaning, containing and removing the spill. Minimize generation of dust. For small spills, clean with a vacuum with a filtration system sufficient to remove and prevent recirculation of cement dust (a vacuum equipped with a high-efficiency particulate air (HEPA) filter is recommended). For large spills, use control dust measures and carefully scoop or shovel into clean dry container for later reuse or disposal. DO NOT USE COMPRESSED AIR TO CLEAN SPILLS. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Section 7. Handling and Storage As packaged, this material does not present significant health hazards. The hazards below apply to the product if aerosols or dusts are generated from cutting, grinding, or pulverizing. Precautions for safe handling Protective measures: Advice on general occupational hygiene: Conditions for safe storage: Safety Data Sheet Page 5 of 11 Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid exposure by obtaining and following special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe dust. Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Store and handle in accordance with all current regulations and standards. Keep separated from incompatible substances. Section 8. Exposure Controls / Personal Protection Occupational Exposure Limits Ingredient name Portland Cement Quartz (crystalline silica) Limestone Calcium Oxide Amorphous Silica Exposure limits ACGIH TLV (United States, 3/2012). TWA: 1 mg/m3 8 hours. Form: Respirable NIOSH REL (United States, 6/2009). TWA: 5 mg/m3 10 hours. Form: Respirable TWA: 10 mg/m3 10 hours. Form: Total OSHA PEL (United States, 6/2010). TWA: 5 mg/m3 8 hours. Form: Respirable TWA: 15 mg/m3 8 hours. Form: Total ACGIH TLV (United States, 3/2012). TWA: 0.025 mg/m3 8 hours. Form: Respirable NIOSH REL (United States, 6/2009). TWA: 0.05 mg/m3 8 hours. Form: Respirable OSHA PEL Z-3 (United States, 9/2005). TWA: 10mg/m3 divided by %SiO2 + 2: Respirable TWA: 30mg/m3 divided by %SiO2 + 2: Total ACGIH TLV (United States, 3/2012). TWA: 10 mg/m3 8 hours. Form: Total NIOSH REL (United States, 6/2009). TWA: 5 mg/m3 10 hours. Form: Respirable TWA: 10 mg/m3 10 hours. Form: Total Dust OSHA PEL (United States, 6/2010). TWA: 5 mg/m3 8 hours. Form: Respirable TWA: 15 mg/m3 8 hours. Form: Total dust ACGIH TLV (United States, 3/2012) TWA: 2 mg/m3 8 hours. NIOSH REL (United States, 6/2009) TWA 2 mg/m3 8 hours. OSHA PEL Z-1 (United States, 2/2006) TWA 5 mg/m3 8 hours. ACGIH TLV (United States, 3/2012) Not Established NIOSH REL (United States, 6/2009) 6 mg/m3 TWA; Appendix C - Supplementary Exposure Limits (Mineral Dusts). OSHA PEL Z-1 (United States, 2/2006) 20 mppcf, 80 mg/m3/%SiO2 TWA (PEL listed under Silica, Amorphous, including natural Safety Data Sheet Page 6 of 11 Particulates Not Otherwise Regulated (Total Dust) diatomaceous earth) (3) See Table Z-3. ACGIH TLV (United States, 3/2012) TWA: 3 mg/m3 8 hours. Form: Respirable TWA: 10 mg/m3 8 hours. Form: Total dust OSHA PEL (United States, 6/2010). TWA: 5mg/m3 8 hours. Form: Respirable TWA: 15 mg/m3 8 hours. Form: Total dust Controls Appropriate engineering controls: Environmental exposure controls: Hygiene Wash PPE Eye/face protection: Hand protection: Body protection: Other skin protection: Respiratory protection: Use only with adequate ventilation. If user operations generate dust, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. Clean water should always be readily available for skin and (emergency) eye washing. Periodically wash areas contacted by Hardened Concrete (dry) with a pH neutral soap and clean, uncontaminated water. If clothing becomes saturated with Hardened Concrete (dry), garments should be removed and replaced with clean, dry clothing. Remove protective equipment and saturated clothing before entering eating areas. To prevent eye contact, wear safety glasses with side shields, safety goggles or face shields when handling dust or wet Hardened Concrete (dry). Wearing contact lenses when working with Hardened Concrete (dry) is not recommended. If dust is generated: Use impervious, waterproof, and alkali-resistant gloves. Do not rely on barrier creams in place of impervious gloves. Do not get Hardened Concrete (dry) inside gloves. Recommended material: Nitrile If dust is generated: Use impervious, waterproof, abrasion and alkali-resistant boots and protective long-sleeved and long- legged clothing to protect the skin from contact with wet Hardened Concrete (dry). To reduce foot and ankle exposure, wear impervious boots that are high enough to prevent Hardened Concrete (dry) from getting inside them. Do not get Hardened Concrete (dry) inside boots, shoes, or gloves. Remove clothing and protective equipment that becomes saturated with Hardened Concrete (dry) and immediately wash exposed areas of the body. Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved. Footwear and other gear to protect the skin should be approved by a specialist before handling this product. If dust is generated: Use a properly fitted, particulate filter respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. (See OSHA Respiratory Protection Standard 29 CFR 1910.134) Safety Data Sheet Page 7 of 11 Section 9. Physical and Chemical Properties Physical State: Color: Odor: Odor threshold: pH (in water): Melting point: Boiling point: Flash point: Burning time: Burning rate: Evaporation rate: Flammability (solid, gas): Solid. Gray or white. Odorless. Not available. 12 - 13 Not available. >1000C (>1832F) Not flammable. Not combustible. Not available. Not available. Not applicable. Not applicable. Section 10. Stability and Reactivity Lower and upper explosive (flammable) limits: Vapor pressure: Vapor density: Relative density: Solubility: Solubility in water: Partition coefficient: n-octanol/water: Auto-ignition temperature: Decomposition temperature: SADT: Viscosity: Not applicable. Not applicable. Not applicable. Unknown. Not applicable. Not applicable. Not applicable. Not applicable. Not available. Not available. Not applicable. Reactivity: Not reactive under normal conditions of storage and use. Chemical stability: The product is stable. Possibility of hazardous reactions: Under normal conditions of storage and use, hazardous reactions will not occur. Conditions to avoid: No specific data. Incompatible materials: Reactive or incompatible with the following materials: oxidizing materials, acids, aluminum and ammonium salt. Hardened Concrete (dry) is highly alkaline and will react with acids to produce a violent, heat-generating reaction. Toxic gases or vapors may be given off depending on the acid involved. Reacts with acids, aluminum metals and ammonium salts. Aluminum powder and other alkali and alkaline earth elements will react in wet mortar or concrete, liberating hydrogen gas. Limestone ignites on contact with fluorine and is incompatible with acids, alum, ammonium salts, and magnesium. Silica reacts violently with powerful oxidizing agents such as fluorine, boron trifluoride, chlorine trifluoride, manganese trifluoride, and oxygen difluoride yielding possible fire and/or explosions. Silicates dissolve readily in hydrofluoric acid producing a corrosive gas -- silicon tetrafluoride. Hazardous decomposition products: Under normal conditions of storage and use, hazardous decomposition products should not be produced. Section 11. Toxicological Information Toxicological Effects Acute toxicity: Irritation/Corrosion: Sensitization: Hardened Concrete (dry) LD50/LC50 = Not available Skin: Dust may cause skin irritation. Eyes: Dust may cause eye irritation. Respiratory: Dust may cause respiratory tract irritation when cutting or grinding. Dust may cause sensitization due to the potential presence of trace amounts of hexavalent chromium. Mutagenicity: Reproductive toxicity: Teratogenicity: Aspiration hazard: Carcinogenicity Classification: Safety Data Sheet Not classified. Not classified. Not classified. Not classified. Page 8 of 11 Ingredient Portland Cement Quartz (crystalline silica) OSHA -- -- IARC -- 1 ACGIH A4 A2 NTP -- Known to be a human carcinogen. Specific target organ toxicity (single exposure): Ingredient Quartz (crystalline silica) Calcium Oxide Amorphous Silica Category Category 3 Category 3 Category 3 Route of Exposure Inhalation and skin contact Inhalation and skin contact Inhalation Target Organs Respiratory tract irritation; skin irritation Eyes, skin, respiratory system Respiratory tract and kidneys Specific target organ toxicity (repeated exposure): Ingredient Quartz (crystalline silica) Amorphous Silica Category Category 2 Category 2 Route of Exposure Inhalation Inhalation Target Organs Respiratory tract and kidneys Respiratory tract and kidneys Routes of exposure - Dermal contact, Eye contact, Inhalation, and Ingestion. Potential acute health effects: Symptoms related to the physical, chemical and toxicological characteristics: Delayed and immediate effects and also chronic effects from short and long term exposure: Potential chronic health effects: Eye contact: Dust may cause eye irritation. Inhalation: Dust may cause respiratory irritation. Skin contact: Dust may cause skin irritation. May cause an allergic skin reaction. Ingestion: Dust may cause irritation. Eye contact: Adverse symptoms may include the following: pain, watering, redness Inhalation: Adverse symptoms may include the following: respiratory tract irritation, coughing Skin contact: Adverse symptoms may include the following: pain or irritation, redness, Ingestion: Adverse symptoms may include the following: stomach pains Short term exposure Potential immediate effects: No known significant effects or critical hazards. Potential delayed effects: No known significant effects or critical hazards. Long term exposure Potential immediate effects: No known significant effects or critical hazards. Potential delayed effects: No known significant effects or critical hazards. General: Repeated or prolonged inhalation of dust may lead to chronic respiratory irritation. If sensitized to hexavalent chromium, a severe allergic dermal reaction may occur when subsequently exposed to very low levels. Carcinogenicity: Quartz (crystalline silica) is considered a hazard by inhalation. IARC has classified Quartz (crystalline silica) as a Group 1 substance, carcinogenic to humans. This classification is based on the findings of laboratory animal studies (inhalation and implantation) and epidemiology studies that were considered sufficient for carcinogenicity. Excessive exposure to Quartz (crystalline silica) can cause silicosis, a non-cancerous lung disease. Mutagenicity: No known significant effects or critical hazards. Safety Data Sheet Numerical measures of toxicity: Teratogenicity: No known significant effects or critical hazards. Developmental effects: No known significant effects or critical hazards. Fertility effects: No known significant effects or critical hazards. There are no data available - acute toxicity estimates. Page 9 of 11 Section 12. Ecological Toxicity Persistence and degradability: Bioaccumulation potential: Mobility in soil: Other adverse effects: Ecotoxicity: There are no data available. There are no data available. Soil/water partition coefficient (Koc): Not available. No known significant effects or critical hazards. No recognized unusual toxicity to plants or animals Section 13. Disposal Considerations Disposal methods: Salvage spilled Hardened Concrete (dry) material where possible. Uncontaminated Hardened Concrete (dry) material may be reused. Dispose of waste material in accordance with local, state and federal laws and regulations. Section 14. Transport Information Special precautions for user: spillage. Transport in bulk according to Annex II of MARPOL 73/ 78 and the IBC Code: Ensure that persons transporting the product know what to do in the event of an accident or Not Regulated. Transport Parameters UN Number UN Proper Shipping Name Transport Hazard Class Packing Group Environmental Hazard Additional Information DOT Classification Not Regulated None - IMDG Not Regulated None - IATA Not Regulated None - Section 15. Regulatory Information Status under USDOL-OSHA Hazard Communication Rule, 29 CFR 1910.1200 This product is considered a "hazardous chemical" under this regulation, and should be part of any hazard communication program. Safety Data Sheet Page 10 of 11 Status under CERCLA/SUPERFUND 40 CFR 117 and 302 Not listed. Hazard Category under SARA(Title III), Sections 311 and 312 This product qualifies as a "hazardous substance" with delayed health effects. Status under SARA (Title III), Section 313 This product does not contain Emergency Planning and Community Right to Know (EPCRA") Section 313 chemicals in excess of the applicable de minimis concentration specified in EPCRA Section 313 Section 372.38(a). Trace amounts of naturally occurring chemicals might be detected during chemical analysis. Status under TSCA (as of May 1997) The ingredients of this product are listed on the TSCA inventory or are exempt. Status under the Federal Hazardous Substances Act This product is a "hazardous substance" subject to statutes promulgated under the subject act. Status under California Proposition 65 This product contains up to 0.05 percent of chemicals (trace elements) known to the State of California to cause cancer, birth defects or other reproductive harm. California law requires the manufacturer to give the above warning in the absence of definitive testing to prove that the defined risks do not exist. State Right to Know: Portland Cement (65997-15-1) U.S. - Idaho - Non-Carcinogenic Toxic Air Pollutants - Acceptable Ambient Concentrations U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Washington - Permissible Exposure Limits - TWAs Quartz (crystalline silica) (14808-60-7) U.S. - Idaho - Non-Carcinogenic Toxic Air Pollutants - Acceptable Ambient Concentrations U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Washington - Permissible Exposure Limits - TWAs Limestone (1317-65-3) U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Washington - Permissible Exposure Limits - TWAs Calcium Oxide (1305-78-8) U.S. - Idaho - Non-Carcinogenic Toxic Air Pollutants - Acceptable Ambient Concentrations U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - New York - Reporting of Releases Part 597 - List of Hazardous Substances Amorphous Silica (61790-53-2) U.S. - Idaho - Non-Carcinogenic Toxic Air Pollutants - Acceptable Ambient Concentrations U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Washington - Permissible Exposure Limits - TWAs Section 16. Other Information Approval or Revision History Date of issue (mm/dd/yyyy): Revision: Revision: Revision: July 1998 April 2011 (Michael Tilton) May 2015 - Revised Section(s) per HCS-GHS April 2017 - related to address Notice to reader While the information provided in this safety data sheet is believed to provide a useful summary of the hazards of Portland Hardened Concrete (dry) as it is commonly used, the sheet cannot anticipate and provide all of the information that might be needed in every situation. Inexperienced product users should obtain proper training before using this product. In particular, the data furnished in this sheet do not address hazards that may be posed by other materials mixed with Portland Hardened Concrete (dry) to produce Portland Hardened Concrete (dry) products. Users should review other relevant material safety data Safety Data Sheet Page 11 of 11 sheets before working with this Portland Hardened Concrete (dry) or working on Portland Hardened Concrete (dry) products, for example, Portland Hardened Concrete (dry) concrete. SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR THE MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE OR CONCERNING THE ACCURACY OF ANY INFORMATION PROVIDED BY CEMEX, Inc. except that the product shall conform to contracted specifications. The information provided herein was believed by CEMEX to be accurate at the time of preparation or prepared from sources believed to be reliable, but it is the responsibility of the user to investigate and understand other pertinent sources of information to comply with all laws and procedures applicable to the safe handling and use of product and to determine the suitability of the product for its intended use. Buyer's exclusive remedy shall be for damages and no claim of any kind, whether as to product delivered or for nondelivery of product, and whether based on contract, breach of warranty, negligence, or otherwise shall be greater in amount than the purchase price of the quantity of product in respect of which damages are claimed. In no event shall Seller be liable for incidental or consequential damages, whether Buyer's claim is based on contract, breach of warranty, negligence or otherwise. In particular, the data furnished in this sheet do not address hazards that may be posed by other materials mixed with Hardened Concrete (dry) to produce Hardened Concrete (dry) products. Users should review other relevant safety data sheets before working with Hardened Concrete (dry) or working on Hardened Concrete (dry) products, for example, Hardened Concrete (dry). Abbreviations ACGIH -- American Conference of Governmental Industrial Hygienists CAS -- Chemical Abstract Service CERCLA -- Comprehensive Emergency Response and Comprehensive Liability Act CFR -- Code of Federal Regulations DOT -- Department of Transportation GHS - Globally Harmonized System Globally Harmonized System HEPA - High Efficiency Particulate Air IATA -- International Air Transport Association IARC -- International Agency for Research on Cancer IMDG -- International Maritime Dangerous Goods NIOSH -- National Institute of Occupational Safety and Health NOEC -- No Observed Effect Concentration NTP -- National Toxicology Program OSHA -- Occupational Safety and Health Administration PEL -- Permissible Exposure Limit REL -- Recommended Exposure Limit RQ -- Reportable Quantity SARA -- Superfund Amendments and Reauthorization Act SDS -- Safety Data Sheet TLV -- Threshold Limit Value TPQ -- Threshold Planning Quantity TSCA -- Toxic Substances Control Act TWA -- Time-Weighted Average UN -- United Nations Central Plaines Cement Company / Tulsa Cement Inspection Date 07/24 -26/2019 Appendix - Contingency Plan 11