Document KzvRpmnjqdd94Mp4gDkqmX8oN

Attachment #1 LHC III Ethylene Small Volume Raw Materials Chemical Name Tank Purpose Vendor Name 1 Dimethyl Sulfide D-5 Prevent Coke Gaylord Chemical Co. 2 Cortrol 778P T-4069 Boiler feed water Betz Chemical 3 BPJ206A T-4091 Boiler feed water Betz Chemical 4 BP6702A T-8048 Boiler feed water Betz Chemical 5 BP6703A T-4066 Boiler feed water Betz Chemical 6 NA-7 T-4092 Dilution Steam Bern Chemical 7 Optimeen 80358 T-891052/3 CT scrubber* Betz Chemical 8 38K T-8365 Cooling Tower Betz Chemical 9 2023 T-8364 Cooling Tower Betz Chemical 10 445 T-6366 Cooling Tower Betz Chemical 11 C-68 T-8661 Cooling Tower Betz Chemical 12 Foamtrol T-870458 Cooling Tower Betz Chemical 13 Corshield 736 ARU System Betz Chemical 14 6% Caustic T-4059 Caustic Scrubber Dowell 15 BP20Y15 T-880810 Causlin Scrubber Betz Chemical 16 BP20Y8 T-880620 Depropanizer Betz Chemical 17 Sodium bisulfite T-55 Carbonyl Wash TriChem 18 Tertiary Butyl Catechol - Polymer Inhibitor Van Waters & Rogers 19 methanol T-1650 dehydrator Hoechst celanese Methanol T-50 dehydrator Van Waters & Rogers Lube Oil T-4S Turboexpanders 24 23 24 25 Stonge Cap. (Max. LBS) 140000 15960 38400 58240 17800 17000 8100 18000 18600 4760 2410 3500 2120 12500 8000 14000 36700 135000 17000 3000 Render Quantity (LBS) 45000 13000 28800 27300 13350 12750 12130 13500 13950 3400 2410 280 2120 10000 6000 12000 32000 4000 30000 15000 2700 Annual Usage (LBS) 230000 68000 210000 86000 78000 48000 72000 138000 81000 6500 2400 700 2100 100000 90000 60000 880000 4000 5000 2000 2700 Delivery Mode LPG Truck Track Truck Truck Truck Trade Track Track Track Duck Semi-Bulk Track Drums Track Truck TVuck Track Drums Track Truck Thick RAWMATJCLS Page 1 D0 A 03604? oonfidfnttai Dow Confidential (JRW) Attachment #2 LHC III ETHYLENE PROCESS ANALYZERS Analyzer 1 AX 1001 2 AX 1001 3 AX 1001 4 AX 1001 j AX 1002 6 AX-MW2 7 AX 1002 0 AX 1002 9 AX-1003 to AX-1003 It AX-1003 12 AX-1003 13 AX 1004 14 AX 1004 15 AX 1004 1* AX-1004 17 AXIO05 IB AX 1005 10 AX 1003 20 AX-1005 21 AX-1006 22 AXIOM 23 AX 1006 24 AX 1006 25 AX I034 26 AX t016 27 AX 1007 2ft AX 1115 AX-1013 30 AX-1013 31 AX 1017 32 AXIOM 33 AX-2117A 34 AX I0MA liialin TLE 1A TliMB T1.E7A TLE-7B TI E 2A TIH 211 TLE-3A Tin 3H TLE4A Tin-4B T1.E-5A TTE5B nn6A TLE-6B TI-12A TIE 12a TIT 4A TTE-8B TLE-9A TUR-9B TLE-10A nn 10B ti.e-iia TIJB-llB C2116 From UICII C-l9Botlom* C-16/C-55 Bottom* P-23 ioT-1701 D-50D,D-51OH,FolyRee GJH6lo-M5 C-S2 Bottoms C 55 Overhead C-57 Bottom C-54 Bottoms Cycle time (accoodi) 660 660 660 660 660 660 660 660 660 660 660 660 660 660 660 660 660 660 660 660 660 660 660 660 900 320 500 600 300 960 500 360 Computer Control No No No No No No No No No No No No No No No No No No No No No No No No No Ye* Ye* No Va Yes Ye* Ye* Ye* 02 m 01% 0 1% 0.1* 0.1% 0 1% 01% 0 1% 0 1% 01% 0 1% 0.1% 0.1% 0.1* 0.1* 0 1% 01% 0.1% 01% 0.1* 0 1% 01% 0.1* 01% 01% txi 0*2 014 01% 0 1% 01% 01% 0 1% 01% 0 1% 0 1% 01% 01% 0 1% 0 1% 01% 0 1% 0.1% 0.1% ot% 01% 01* 01% 0 1% 0 1% 01% 01% 0.1% 01% 0.1% 0 1% 0.1* 01% 0 1% 0 1% 0.1% 0 1% 0.1% 01% 0 1% 0 1% 01% 01% 0.1% 01% 0 1% 01% 01% 0 1% 01% 01% 01% 01% 1 0.1% C2H2 01% 0 1% 01% 01% 0 1% 01% 0.1% 0 1% 01% 0 1% 01% 01% 01% 01% 0.1% ot% 01% 01% 0.1% 01% 03% 01% 01% 0.1% 0 1% COMPONENT MEASl WEI > (t J)l.) C21I4 C2H6 cr C3I16 C311B C3< 0 1% 0 1% 01% 0.1% 01% 01% 01% 01% 0 1% 01% 01% 0 1% 01% 0.1% 01% 01% 0 1% o r% 01% 01% 01% 01% 0.1% 0 1% 01% 0 1% 0 t% 0.1% 01% 01% 01% 0.1% 01% 01% 0.1% 0.1% 01% 01% 01% 0.1% 01% 01% 01% 01% 01% 01% 01% 0 1% 01% 0 1% 01% 0.1% 01% 01% 0.|% 0.1% 0 1% ot% 01% ot% 0.1* 0.1% 0.1% 01% 01% 0.1% 0.1% 01% r0t% 01% 0.1% 0.1% 01% 01% 0.1% CZI lOOppm 0.1% 01% 0 1% __ _ 1 But KBut Kateoe ZZj -j 01% ' o.i% 200ppm 200ppm c-Batae laTBats OTi 1 lOOppo 200ppai 200ppm Sdppm i ii 0.1% 0.1% 0i% 0.1% 01% 0.1* 0.1* OTHER .1% Naphthalene Btu, Density, and MoLWt. .1% Heavies .1% MAand PPD .1% PPD ANAI.Y7HR XIS P*te1 Dow ConlhJcntial (JRW) n Oz Vo "H -a 3> Vm o Z^ -A O' -H O >^ Attachment #2 LHC III ETHYLENE PROCESS ANALYZERS Cycle time Auhricr 1 JtcatKwi (Kd.) 15 AX-1039 < 3fl* Product Hdr, WcD 900 36 AX 1039 and !>ocfcj 37 AX-1015 C-54 Ovrrtead 1200 38 AX 1028 C2I14 lo Vinyl, Poly C, ind 400 39 AX-1028 toWcM 40 AX 1032 C2f (4 in Vinyl. Pnty Ct and 900 41 AX 1032 lo Well 42 AX 2087 PyK)*(rnm LI 1C 11 700 43 AX-1024 057 Overhead 900, 44 AX-2117B C 57 fced from C-54 500 45 AX-2088 D-55B Intoul 1000 46 AX-1020 C-151 OH.D-E5I01I, 480 47 AX 1020 C-51 Blms, C-520H 48 AX 1021 R-2A/B ouikl 150 49 AX-102IA R-2A/B outlet ISO 50 AX-1022 C 1520H 350 St AX-1022 D-152 btms/overheads 52 AX 1023 C-152 overhead 200 53 AX 1029 Fuel Rat lo Fur,Turb. Power 900 54 AX-1031 R-IAoul, Tot Rxoul 200 55 AX-1931A R-l/2 in, C-152 bottoms 500 AX-1031A Toul Rl cm! 57 AX-685-Z C3118 Feed to Rnmxa 600 58 AX-1030 Air moniior for Bi/Tol 200 59 AX-1519-O E-35 lo Waste Treatment 500 60 AX-1037 C31 (8 lo Furnace 600 61 AX-545A-M Fl-F120jiYiten Continuous 62 AX-549A M F1-FI2 Carbon Monaode Continuous 63 AX-547AM FI-FI 2 Combustibles Continuous 64 AX-1041 A B-l A Nitrous Oxides Continuous 65 AX-I041B B-l A Carbon Monoxide Continuous 66 AX-1041C B-1A Oxygen Continuous 67 AX-1042A B-1B Nitrous Oxides Continuous <8 AX 1042B B-1B Carbon Monoxide (Continuous (Computer Control No Yes No No No Yes Yes No No Yes Yes Yes Yes No Yes No Yet Yes No Yes No No Yes Yes No No No No No No No 02 111 COMPONENT MICAS!JRI ID < IJ >1 ) CO Cl>2 a 14 C2II2 C2II4 C2lf6 C2*i C3H6 C3IIH CTs 0 5ppm 0 5ppm SOOppm 1 Bui N But Butene c-Bittcnc LTIIuta C4's Ippm 0 Ippm lOOppm Ippm 01% 01% 0.1% 0.1% 01% Ippm Ippm 0.1% 20ppm 0 1% 0.1% 0 1% 01% 05ppm 05ppm Ippm OSppm Ippm Ippm 05ppm 0 1% 0.1% 0.1% 0 1% 0 |% 01% 0 1% 0 1% 0 1% 01% 01% 0.1% 0.1% 0.1% 01% Ippm 0.1% 01% 01% tppra Ippm 0 t% Ippm 01% 0 1% 0.1% 01% 0.1% 0.1% 0.1% 01% 0.1% 01% 01% 0.1% 0.1% 0.1% 0.1% 0.1% 0.1% 0.1% OTHER Ippm MAand PPD .1% MA and PPI) .Ippm L, P, and M Alcohol .1% heavies Ippm .1% MAand PPD 5 ppm Ace. and Acetald. Blu, Density, and Mol Wt .1 ppm Benzene an toluene SO ppb benzene 0.1 % Combustibles IppmNOX Ippm NOX ANAl.YZER.XfS Psrc2 Dow Confidential (JR W) Attachment #2 LHC III ETIIYLENE PROCESS ANALYZERS Cyckr Imtc An.ity/cr 1 JMVtlHHt (second*) (W AX I042C 11 IB Oxygen Coni i nont 70 AX I0W Cracked (iAslo C 30 Con 1 monos 71 AX iwn C 52 twerhead Coniinunoi 72 AX 1*53 Cracked ti to K-7113 Cottiinunui 73 AX 1848 Hydrogen lo Reactors Coni i minus 74 AX 1859 Hydrogen In R-2(50 100%) Conlimioui 75 AX 1858 Hydrogen In R 1(50 100%) Coniimious 74V AX 1849 R 1 OifJ Mydrc>gcn(0 2%) Ctwilinunui 77 AX 1847 K 2 Dill Mydmgcn(0 2%) Continuous 78 AX 1981 C-152 Overhead CO2 Continuous 79 AX 1949 C 152 Tray *5 Conlinumn 80 AX 1027 C2II4 to VmyJ.PolyC.WeJI Continuous 81 AX-1025 C-57 overhead 1120 Continuous 82 AXIOM 83 AX 1010 84 AX 15*9 0150 inAnil 1120 C 40 s outlet 1120 C 40A/TW- H20dewpomt Continuous Continuous Continuous 85 AX 1009 057/019 111 ms Dewpoini Cnntinuf>us 8* AX 735IA (il 71 NHX Continuous 87 AX 7351II (iT 71 CO Continuous 88 AX 735IC or 71 02 Continuous 89 AX 738IA GT 120 NOX Continuous 90 AX 738113 (ill 20 CO Continuous 91 AX-738IC GT 130 02 Conlinuous 92 AX *201 l:uel Gas in l-'urnaccs 112 Ownprter Control No No No No Yes Yes Yes Yes Yes No Yes No No No Net No No No No No No No No 02 0.1% M2 50 0% 50 0% 0 1% 0 1% CM Ippm Ippm <02 <114 Ippm Ippm Ippm C2M2 I Ifni C2H4 (XI 4PONENTMliAS IRLMfl IH) <711* CZi <311* (3118 (3* 01% ot% Ippm 0 1% 0 5% Ippm 1 lltil N llul Butene c llutcnc 13 lima C4 OTHER 0 1 ppm M2M 0 1 ppm 1120 0 I ppm 1120 01 ppm 1120 0.1 ppm 1120 1 ppm NO* tppmNOs AN AI Y/l-K XI S n bd 2n O ^a j> ^o 2 U) H O' -* o in J Dim Confidential 1 IRW) Attao ;nt #3 INDIVIDUALS WITH MOVING RANGE CHART ==Qualitv.== Performance Means More A1 Dew LA. STOCK *3571890 (REV. M9} >3h> O* Attain xnt #4 i INDIVIDUALS WITH MOVING RANGE CHART Performance Means More A! Dow. ,TEM Cak in I-#* <>H plant OATE Jint*'.. /i | M ^ 3 < l1 woman )| | gl-PlfrWl INDIVIDUALS^ CHART UNPL -X+2 66RTF^ ~ ____ - -- ___ _ 1`X-AVERAGE OFX Y - 2tt> LNPL -X-2.66Ron/i > V- J 3f7cr.C sd ZL lio > z 776 YEAR m( 1*. 1L it lp- TARGET 5 C. to w 3 CHART NO. ,,-JSSL, p3 Is3|37l 1 1 -Z y m 1 /< Is irnynE"C1 'J ToU * *K~n fr>lzJ ^ [a it _, , tr , ' ___ V ~ zv,__ ] _j T\ r1 - 7_ \~ "V 7 r \ < ___ ___ Y T~ Y \ / ___ ^__ id id / --1 iY Y7 Y Y/ / ____ Y- i _ Y1 Y _ Iz r /\ z ___ \ MOVING RANGE. CHART UCL -3.266R* sfo -.20____ , R-AVERAGE OF R L (i-_2_____ ? lclh-o.o(R|- \ -0.0 LJ ( / Y if ioi>J ---- z V__ y : i\ 1____ r / EZ Y~fL /V - I____ - z Y r !V Zy r \T / j1 s j~ ~T r- rtJr- 33 . _. "T ~1 nf \ 2> 3 C . n.f rSfO'Jj 1 ~7 Y y1 / r ! LI ill y~ / _i -- h y ---- Sen.| J..- T./ruat? CONTROL LMTB BASED ON . FOR. LA. STOCK (0571890 (REV. 6/89) o bo x o-----------T) 3U0H . ',o" o 37 ^ FOR CHART (BMHATUWE): DATE Attachment #5 V LHC HI ANALYTICAL LAB 5 YEAR QUALITY PLAN YEAR 1990 1991 1992 1993 1994 PRINCIPAL GOAL Improve analyzer reliability, establish preventative maintenance program, clearly define operator troubleshooting procedures SQC for lab analyzers in place. Continue automating data acquistion and distribution SQC for Benzene process analyzers in place, ISO-9000 j' Credible benzene process analyzers Less routine sampling, More project work. Set up lab at tank farm Redefine lab function to be the BACKUP for process analyzers, but to focus on engineering projects, env. projects, SQC, new method development EQUIPMENT REQUIRED Replace unreliable analyzers (distillation, sulfur, four GCs, install autosampler on 8 GCs) 1) Computer upgrade S30K 2) Continue to replace unreliable analyzers: two GCs SSOK 3) New analysis: BHT in RO S20K MTBE in naphtha SISK 1) Computer upgrade S30K 2) Laser guns, intermec terminals S20K 3) New lab S1700K 4) GC / MS SSOK 1) Computer upgrade S30K 2) Equip small lab at tank farm: hood, GC,density meter, sulfur, chlorides, S100K 1) Computer Upgrade S30K 2) New Methods SSOK 3) Replace unreliable analyzers SSOK Anne Boussert October 30,1990 A 03604 DO coWF TDF^^ "