Document KzJbeZ771XpG2OMDEEd4n5ygK

/tfUUSS ALLIED CORPORATION -- BENDIX FRICTION MATERIALS DIVISION MATERIAL SAFETY DATA SHEET --> *; caramav oe used to comply witn OSha j Hazara Communication Standara29CFR 1910 '200 T^eCSHA Standard mujt -cv*eer oe consulted for specific reouirements . ---e ~'<c::cn Material orooucts identified m this Sheet meet tne OSHA definition of an article" ana are exemot from tn# Hazara Communication Standard as to ail reasonaoie uses Some potential may. however exist for exposure to asoestos dust. -ha -ngr9s:en:s ,>n These Friction Material products are resm-oonaed ana cured. Hazaras normally associated with cxoosure to or contact zure ousts of tne listec ingredients are not expected to oe significant Allied nas listed an of tne essential ingredients present >- a series of Friction Material products of this general oescriotion All Fnction Material products identified on :m> MSOS contam processed cnrysotiie asoestos fibers. Out may contain some of tne other materials shown The recommended exposure units are tnose 'or tne most hazardous suostance m a class of substances Exact formulations are proprietary ano tnerefore rsnffoe"tiai Precise product information will not oe oiscioseo. otner tnan in accordance witn applicable taws ano regulations, or without a written Secrecy Agreement. . AUieo snail m no event ee responsible for any damages of whatsoever nature or kind directly or indirectly resulting from oransmg out of me Publication or use of or reliance uoon data contained nerein No express or implied warranty of any kina, including warranties of mercrramaoitity or fitness far use.- witn respect to tne Friction Material products or to tne data nereih is madt leresmoe^ ' PRODUCTS'--Sendix Fnction Materials covered by this Material Safety Qata Sheetcan be identified from 00s laoeisoAsace '!5jsa.feto.iiowsir . _. Drum Brake Segmentt And Sfockt-- Pncoon King", 'FX" FKD~ "O": "FXL". V. "M" "A E": "E". 'EOT 'EM": 'HP": S"" ano S-1100." OUc Brake Pads -- Organic" and FK ll" isemi-metaliicj. Nate. The weanng surface' of "FK II".disc pads does not contain processed cnrysotiie asbestos fiber However, processed cnrysotiie asoestos fibers may oe included m tne "backing layer" wtucn is "sandwicntd" between tne `nction material and the steel shoe plate. ' I j : SECTION 1 Manufacturer's Name: ALLIED CORPORATION . Bendix Friction Materials Division Address: P.O. Box 23S - Troy. New York 12111 Emergency Telephone Number Date Prepared Praparar 518-273-8550 July 30. 1986 E.L Rogars i SECTION II -- Hazardous Ingredienta/ldentlty Information Hazardous Components tSpecific Chemical Identity: Common Mamofa) OSHA Pel ACOIH TLV Aabestos (Chrysotile) Silica (oe quartz) 0.2 fibet/c.c. Silieata(s) Carbon Black 10 mg/m1 3.5 mg/mi Ccka (Petroleum derived) NA Cured phenolic ano casnew resins 10 rr g/m1 - Graphite . " Iron. Zinc. Aluminum and their oxides ' * Respirable Fraction as based uoon the formula 10 mg/m1 2 fibers/c.c * 10 mg/m1 3.5 mg/m1 NA 10 mg/m1 S Silica - 2 (See OSHA table Z-'OOO) ! * 1 . t 1 | SECTION III -- Physical/Chemical Characteristics Bolling Point .................................................................. NA Specific Gravity (H,Q * 1).................................... 1.1 - 3.T Vapor Pressure (mm Hg.) .............................................NA Melting Point........................................................... NA Vapor Oanslty (Air 1).................................................. NA Evaporation Rate .......................................................... 8 Solubility in Water.........................................................NO Appearance and Odor Solid. Odorless. Light Tan to Dark Grey Color Plaintiffs Exhibit SECTION IV -- Hr* and Explosion Hazard Data Flash Point (Method Usad): NA Flammable Umlta: NA Extinguishing Modia: Water. (Cisss A. 8. or C), Fog or Foam Special Fire Fighting Procedures: NA Unusual Fire and Explosion Hazards: NA LEL; NA UEL: NA SECTION V -- Reactivity Data Stability Unstable: Conditions to Avoid: None Known Incompatibility (Mataclali to Avoid):. None. Known Hazardous Oecompoelttorror Byproducts? incomplete compilation will eroata carbon monoxide and carbon dioxides Hazardous Poiymertzation WllTNot Occur p r SECTION VI -- Hoalth Hazard Data t i Route(s) of Exposure: Inhalation? Yes Skin? Yee Ingestion? Yss Health Hazards (Acute and Chronic) , Some persons may be sensitive to partially cured pnenoiie or cashew raslns and develop dermatitis-type reactions. Ousts ot crystalline silica may Droduce silicosis. Metal dusts can be irntants of the eyea and upper respiratory system. Thera is littte known evidence of chronic industrial poisoning from iron, aluminum, and zine dusts. ___ inhalation of concentrations of airborne asbestos fibers in excess of the OSHA limits may be hazardous to health and may causa sanous bodily narm. suen as asoestosis. lung cancer or mesotneuoma. Those diseases may not be recognized until many years after exposure. Medical literature indicates tnat pooois who smoks are at a significantly increased naaitn risk when working with airooma asoestos fibers. Carcinogenicity Usdng: Asbestos fibers NTP? ' Yea IARC Monographs? Yea OSHA Regutated? Yea Signs and Symptoms of Exposure: Partially Cured Cashew Resins -- skin sruptions similar in appearance to poison ivy. Lung Effects from asbestos and crystalline silica -- coughing, wnaezing. shortness of breatn. imoairsd pulmonary function. Dusts in aye may cause irritation. Gastrointestinal disturbances possible from ingestion. Cmergency and First AM Procedures -- Snoula not be necessary from t proper nanciing pf this Friction Material product. SECTION VII - SPILL OR LEAK PROCEDURES Sttpa to B* taken In caae-metertet la refeeaed or spilled: Qeter ;o Section IY (Soeciai Precautions) Below ana Recommended Procedures' on Page * Waste Olapoaal Method: Cisoose of m proper receptacles approoriateiy laoeiiea >n accoraance witn aooucaoie federal, state ana local lews ano regulations P'ace receptacles m an "Authorized Landfill" as designated By federal or state authorities. SECTION VIII -- Special Protection Information Respiratory Protection (Speedy Typo): Not Required under normal conditions. However it concentration of air&orne asoestos fibers m excess of the OSHA standard is created, respirators aoproveo By NiOSH *or asoestos fibers sftouid be used. __________ Ventilation: .during machining -- including grinding ana dritiingj Local Exhaust: Preferred Mechanical (General): Not applicable itectlve Gloves: Recommended Eye Protection: Safety Glasses Suggested Other Protective Equipment: See paragraph 7 of Recommended Procedures on Page 4 SECTION IX -- SPECIAL PRECAUTIONS The Friction Material product, as shipped, is not considered hazardous, but machining (grinding and drilling) and/or normal use may create asoestos dust or sirocme asbestos fibers m excess of OSHA standard and snouid be considered Hazardous. Recommended Precaution -- if airbomo asbestos fiber concentrations excaed OSHA limits. NIOSH approved respirators snouid oe worn ana proper engineering controls implemented. If product is ground or machined, local exhaust to control axposure to airoorne asoestos fibers or duet is recommended. (See "Recommended Procedures" on Page 4.) The work environment snouid be monitored to determine whether employee exposure exceed OSHA permissible exposure level m accordance with OSHA regulation 29 CFR Part 1910.1001. Back'ages containing tha Friction Matanal Product should ba labelled in accordance with OSHA regulation 29 CFR Pan 1910.1001 (j) (2) as follows: DANGER CONTAINS ASSESTOS RISERS AVOID CREATING OUST CANCER ANO LUNG DISEASE HA2AR0 Standard industrial hygiene oractices. including good housekeeping and vacuuming or wet cleaning work surfaces to prevent jscestcs `.;ers or dust from oecommg airoorne. should oe instituted or imoiemented and maintained ""c REVERSE SIDE FOR FRICTION MATERIALS STANDARDS INSTITUTE'S RECOMMEN0ED PROCEDURES FOR DUONG ASBESTOS OUST DURING BRAKE SERVICING. RECOMMENDED PROCEDURES rOH HSDUClfiG ASBESTOS DUST DURING SHAKE SERVICING Because studies have indicated that exposure to excessive amounts of asbestos dust may oe a potential health hazard. OSHA has set maximum limits of levels of airoome asbestos dust to -.vhich workers may oe exposed. Since most automotive friction materials normally contain a sizable amount of asbestos, it is important :ha; people wno handle brake linings and clutch facings understand the nature of the problem and knew the precautions to be taken. ' in regulates areas wrere cr?*e ao?< 3 cone 3"c me air cuan; sta^carc exceecs me C5- Should oe oostso witn a warning sign as `oncws __ DANGER ASBESTOS CANCER AND LUNG DISEASE HAZARD AUTHORIZED PERSONNEL ONLY RESPIRATORS ANO PROTECTIVE CLOTHING ..........-- are REQUIRED IN THIS AREA s-va-css ---------- 2. The amount of asbestos in tne dust from oraxe immg wear :s normally at an extremely >ow evei oecauSe ot chemical oreakaown during use. and if macnnmg of friction material cces not take otace. simple oroceaures w. minimize exposure During brake servicing, the mecnar.ic snould wear a respirator aooroveo by NiOSH for aseestos dust, it should be worn cunng all procedures sorting with the removal of wheels ana mefuemg reassembly- ^ 3. When removing worn fncticn materials, remove me acc^--_:a:ec rJ*: .n tneassemeres v:tn arrmaustnai vacuum-cieaner ecu:pDeaswitma;nTgrreffici6rcy * iter system if suc-^ec-^merrs -crav-ai-aoe Cus: ran jereiniavec with a came ciotn Do not use comcresseo air or O'y crushing `cr c:eanmg jniesstre assempiy s enclosed-anc properly exhausted a whenever possible, purchase friction materials pre-grouna ana reacy 'or installation *f macninmg is necessary the precautions which must be taken are of extreme importance. This is tne operation praxe service when exposure to asoestos dust may be at its n.gnest. This increases tne difficulty m comoiying .v:m me OSHA standards. In addition to the approved respirator, there must be local exnaust ventilation suen that worker exoosures are maintained be-ow the OSHA asbestos standards, if there is any Question as to the efficiency 3? aseestos dust removal by the maemne. the manufacturer snould be contacted 5. industrial vacuum cleaner bags containing asoestos dust 3nc ciotrs usee `or wiping praxe asse-c-es snouic be sealed m plastic oags and labeled witn the following warning taoei printeo m letters of sufficient size an; contras: :p be readily visible and legible. ~ OANGER CONTAINS ASBESTOS FIBERS AVOID CREATING DUST CANCER AND LUNG OISEASE HAZARD All asbestos waste should be disposed of in accordance with OSHA and EPA asoestos regulations Curing remova1 ?f vacuum oags. an approved respirator, as aesenoed in (2) above snouia oe worn. 6. Good housekeeping is essential in a workotace where asoestos containing materials are nanciac mcustr-ai vacuum cleaners equipped with multiple stage hign efficiency fitters snouid oe useo for removing accum.iatipns cf asbestos dust and waste. Never use compressed air or dry sweeping for cleaning. Water or other rust succressar.ts snould be applied if.brooms are used. ' 7. Good personal hygiene practices are important in minimizing asoestos dust exposure Oo not s moxe Wasn before eating Shower aft*'.vc'k Change to .W-c s`v mt -* - - '#> a>?3 conclusion of work. Work ootning snouic not pe taken .-.cm* '_=.ncar,.r*g 3* asbestos center 'ate. : ;c`3 -a lone so as to orevent release of airborne asbestos f>bers -n excess of me exoosure -imits CAUTION: DO NOT BREATHE ASEESTOS DUST Reproduced from tha 1986 Friction Malarial* Standards Instituta Automotive Da:j Seok with the warning sign m .aragrapn 1 and the warning label in paragraph 5 revised to conform to OSHA Standard afiacti-.* Juiy 21. i9dS.