Document Kdr7wXyBEoJ26mxZk1L8EYzK
tfaMET '*
MATTOL
'
...Used per Dwg-vv-------
.LVswa ' sJ.i--
r OB BS NT""B
Required under USOL'Seiety and Health Regulations for Ship Repairing, --------- ShipbuHdingrand-Shipbrealdng-tt9*ClfR-19io, lyiri, r&lTS
. SECTION 1
MANUFACTURER'S NAME
.'
.
, Plastics Engineering Company '
emergency telephone no.
. (414) 4S8r2121
addressCod<) 3518 LakeShore Road/ Sheboygan, WI. 53081
CHEMICAL NAME AND SYNONYMS
.
.
TRADENAME AND SYNONYMS
* Phenolic Molding-Compound
.CHEMICAL FAMILY
,, . ,
Phenol-Formaldehyde
FO* RMULA
_55_ 8_ _Brown .
PX.ENCO *
. '
.
.
. SECTION 11 - HAZARDOUS INGREDIENTS
.
paints, preservatives, a. SOLVENTS^
%
TLV (Untltl
ALLOYS AND METALLIC COATINGS ^
PIGMENTS
BASE METAL
^
.
TLV (Untu)
CATAL.YST VEHICLE SOLVENTS ADOITlVESQ/^
, OTHERS^
^ C/
\
.
ALLOYS
'
. ^ 5^
<*,/METALLIC COATINGS .
TILLER METAL
Js3^
PLUS COATING or corbSplux
OTHERS
HX
----m:
*
:
HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS^ OR CASES
% TLV (Units)
Not listed in. OSHA toxic substances list.
----
Contains.encapsulated asbestos.
,.
,.
BOILING POINT (P.) VAPOR PRESSURE (mm Hfl.) VAPOR OENSITV (AtRM) " * SOUJB ilitv in water appearance An'6 650 r
SECTION. Ill - PHYSICAL DATA
..
None. specific gravity
;
NA.'
* NA . . .NA'
PERCENT, VOLATILE 8Y VOLUME Oil
EVAPORATION rate ( ' "11
` .
' ' .....
NA NA
Negllglb e
--------------- .
Granular . Odor -- none to slightly phenolic.
. SECTION IV FIRE AND EXPLOSION HAZARD DATA
FLASH POINT <M*lhod und)
flammable limits - -
li
Ud
extinguishing media
-
Water, 002, Chemical Foam
.-
.
if SPECIAL FIRE FIGHTING PROCEDURES _
None indicated - but wear self-contained, breathing
... . .i..
12/1/2006 ^ , ; fa(
apparatus when fightingcEhrgSTjrn..Sh enclosed area.
HA3LAtlDS Avoid dust accumulations -- dust/air mixtures
.- are explosive.
.ccc.~ '
^
(Contimi^H nn
SC-EEI-0975
P3-/
mm.. . txHib!
2- '*.
4~ |
IRreshold limit v alue
^Sge-attacned for vapors -
ilrrg. nuisance dusiris. IS mg7rt^
eipepxs.of overexposure
May cause skin irritation or dermatitis in sensitized individuals,
emergency and first aid procedures <5ood-personal-hygieive-r-Avoid-Tepeated-orproionged-- contact with skin -- wash with soap and water at first opportunity. Flush'eyes with wpter for at least.15 min.
.
SECTION. VI .REACTIVITY DATA
..
STABILITY
unstable
.conditions to avoio None known '
....
STABLE
1NCOMPATR8IUTY* [ilatcrlali tv amid)
X
None known
.
hazardous OecoMPOsrnoN products
Carbon dioxide, carbon monoxide, phenols, ammonia, formaldehyde.
HAZARDOUS
.
POLYMERIZATION
MAY OCCUR WILL NOT OCCUR
1
1X
CONDITIONS TO AVOIO
-
None known
.
.
. SECTION VI! - SPILL OB LEAK PROCEDURES
STEPS TO 06 TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Vacuyjh or sweep with sweeping compound to avdid^generating.dust.
WASTE DISPOSAL METHOO
1. Sanitary landfill recommended 2. Incineration
SECTION VIII SPECIAL PROTECTION INFORMATION
ifpe)RESPIRATORY PAOTEC'nONfSprq/V
VENTILATION
- '
LOCAL EXHAUST
mechanical (General)
PROTECTIVE GLOVES
.
Dust mask for nuisance dust
X'-
SPECIAL
X ..
.OTHER
X EYE PROTECTION
'
`'
OTHER protective EQuiPMENT^Dust collection system, Work areas to he.JJLSPmpiiance witli
OSHA asbestos reguiatlSfts
SECTION IX - SPECIAL PRECAUTIONS
PRECAUTIONS TO OE TAKEN IN HANDLING ANO STORING Avoid exposure to temperature, extremes
and moisture -- can affect product' performance. ~ OTHER PRECAUTIONS Avoid .prolonged or repeated contact with skin.. Avoid prolonged or
repeated breathing of dust or vapors. Use with adeausfe ventilation.
.PAGE |2]
.'
CUTLER 386/399
12/1/2096 .
'
cpo pa-t.uo
Foroi OSHA-20
Rav. May 72 .
I? "`v
K
Dept'
in- Dept* per Dwg.
ion Name;_
ifpp LABORS iafety and Health Administration
5tMAL S1FEIY DATA SHEET
Required under USOL Safety and Health Regulations for Ship Repairing, Shipbuilding, and Shipbreaking (29 CFR 1915, 1916, 19171_____
manufacturers name
.
.
.
SECTION l uurez Division,.
.. . EMERGENCY TELEPHONE NO.
Hooker Chemicals & Plastics Corporation
(716) 696-6000
. address {Humber. Street, Ciffj Stare, end ZIP Code)
.
WaTck Koad, worth Tonawanaa. New York 14120 "
.
CHEMICAL NAME ANO SYNONYMS.
N/A ''
`
trade name and SYNONYMS,
Durez 1308 Black
.
' .
SECTION II - HAZARDOUS INGREDIENTS -
%PAINTS, PRESERVATIVES, 8t SOLVENTS '
TLV . (Unit)
ALLOYS AND METALLIC COATING'S
PIGMENTS
' -
.
BASE METAL
.
CATALYST
' ,
ALLOYS
-'
VEHICLE
SOLVENTS
( AOOlTtVES I 1 OTHERS
.
. .
METALUC COALINGS
.
FILLER METAL'
.'
PLUS COATING OR CORE FLUX
OTHERS
.
.
HAZARDOUS MIXTURES OF OTHER LIQUIDS,'SOUOS, OR GASES
.
%' .
TLV (Units)'
.
Phenol
<57.
skin - 5PPM or 19me/M3
Asbestos
' ; 357.
2 fibers/ml >5X in length
.
'
_
% . TLV (Units) .
%. TLV (Units!
..
, ' SECTION III - PHYSICAL DATA
.
BOILING POINT (F.| *> VAPOR PRESSURE 1mm HjJ ` VAPOR OENSITY (AIR-1)
N/A '
SPECIFICGRAVITY (HjOl|-
'
"]_ .'53-1.55
'.
N/A"*'" N/A
PERCENT. VOLATILE BY VOLUME {%)
TrEVAPORATION RATE
i ~""a
'.
U/A ... M/A .
SOLUBILITY IN WATER
^ gligib 1
Blackappearanceanoooo.r granular material with slight' odor of phenol .
SECTION tV - FIRE AND EXPLOSION HAZARD DATA '
FLASH POINT (MoUiod u4)
N/A
XJ/Aflammable umitS'-
L
water,extinguishing meo.a chemical foams or C.02 .with water the preferred tledia
SPECIA-CejjEC&UrGHT-ING PROCEOURES. Use normal
- VjSLlXL-CR-307/399--------- ---------
12/1/2006 __________________
;NUSl/RL'FiRE AN6 J<PLOSION HAZARDS'
Organic
epgi'pigg&ixi:
and procedures.
ia^es ran Ho 1 apH"
p e-r--rr~ in Tfame: ' ' _
' Occupational Safety and Hsallfa^Mininistration---
Iaterial safety data sheet
f^ortn Approved OM0 No. *4-Rtt$7
nations for Ship Repairing, Shipbuilding, and Shipbreaking (29CFR 1915,1916', 19171 .
i. - __________ ;____________
SECTION I
Y.*' F MANUFACTURER'S NAME
'
":
llUTeZ DiVtSlbll,
EMERGENCY TELEPHONE NO.
Hooker Chemicals & Plastics Corporation
. (716) 696-6000
ms; .amggha%agg^.
CHEMICAL NAME ANO SYNONYMS CHEMICAL FAMILY
N/A n/a
Hew York 14120
TRADENAME NQ SYNONYMS
Durez 18519 Brown
FORMULA
R/A
`
SECTION U - HAZARDOUS INGREDIENTS v V4 ^-` '
%PAINTS, PRESERVATIVES, & SOLVENTS '`
TLV runitri
* ' ALLOYS AND METALLIC COATINGS
PIGMENTS
.
''
BASE METAL
CATALYST
. '. '
ALLOYS.
'
VEHICLE SOLVENTS ADOITIVES ' OTHERS
' '
/
.
V* .`
METALLIC COATINGS
FILLER METAL ' PLUS COATING OR CORE FU1X
. OTHERS
-
.
.:
.
. HAZARDOUS MIXTURES OF OTHER.LIQUIDS, SOLIDS, OR GASES
. 7. '
TLV (Units)
.
: Phenol . .<5%..
.Skin - 5PPK or Wmg/M3
Asbestos ' ' 40%
5 fibers/ml >5 /{in length
.
.'
. * ' .'
`.
.
TLV * ttWbl
' .f--
% ' TLV
. (VWttl * J
SECTION HI - PHYSICAL DATA ;
POIUNO POINT (F0 VAPOR PRESSURElmm HsJ VAPOR OCNSITV <aIR1)
SOLUBILITY IN'WATER
. ' - -- ' tf/A~:c- ' SPECIFIC GRAVITY (HjO1>
1 H/A^. PERCENT, VOLATILE. BY VOLUME pH
-N/A
evaporation rate
1 *1)
gligiblE
. '
.
. ]_ .72^.1/74
. *
H,ZA.-'.. H7A
appearance ano ooor . Brown granular material with slight odor of'phenol
SECTION IV - FIRE AND .EXPLOSION HAZARD DATA
FLASH POINT tMolhod vs4)
H/A
N/Aflammable limits
Water sextinguishing media chemical foams or CO?, with water the preferred j ledia
- -SPECIAL FIRE FIGHTING PROCEDURES
---------CMUITTrCREWRt-R38R8W73U9a9 ---------------
--~~use no--r--m-----a---l equi"pment an~d procedI ure^s -- ' --a ---------------------------------------------------------------
12/172006
m
c SECTION V HEALTH HAZARD DATA
THRESHOLD LIMIT VALUE
Treat as nuisance dust - TLV limit - lOmg/MJ
'' n ""*
' ' ~~........... . 1 """* " ,'"1 ' "* `
......
~ ^
Skin' rasli_ip_allergir. persona TinisanNe dnst-
irritation to eyes and respiratory tract.
EMERGENCY AND FIRST AID PROCEDURES
Use protective cream for skin of allergic
persons: - Flush, eyes with clean water.
I l
n-
. - .
' SECTION VI REACTIVITY DATA
stability
unstable
* CONDITIONS TO AVOID 'v.
* stable
.. X
. <.
INCOMiPATABILITY illiuerialt to evoidj
None known_ .
..
*r. HAZARDOUS DECOMPOSITION PRODUCTS
CO,' C02 y NH3
HAZARDOUS
' V MAY.OCCUR
'
* f
CONDITIONS TP AVOID
WILL NOT OCCUR
* x^
------------------------;--5
.
.
... *,
*
SECTION;VU 7 SPILL OR LEAK PROCEDURES '
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Z
'
TTT
;,
Sweep or vacuum spills. To
minimize dust, vacuum'cleaning preferred.
"
WASTE OISPOSAL METHOD
Incinerate or dispose,as land, fill-in accordance
with local and Federal regulations,
''
SECTION VIII - SPECIAL-PROTECTION INFORMATION
/specify typtfrespiratory^protection
Not''required foFh'ormal "handling.
recommended for' heavy dust concentration.
VENTILATION *
local exhaust
. Only 1$ du?t or
SPECIAL
#
"uusc mask
*
rttmp Pfinrpntl-aMhn ve~VrrorVi
('General)MECHANICAL
. S_ame . as a.bovue1. .
other
PROTECTIVE GLOVES
. ......... `
not required
I EYE ROTECTION hOCTia JL protection Or Idust or mat-arlal narElcles.
other protective equipment Dust collection equipment may be'necessary for L-j--------------------------------------------------- ---mechanical- exhausfev--------------
'
SECTION IX SPECIAL PRECAUTIONS
precautTons TO betaken .nhanoling AND rr9R.Na_.A3_thoueh not & hazard, exposure
^
- " ---- "
*
t
to hLg^temgarature and/or~%^^tUr-& affects product performance. &
OTH
ee-
12/1/2006______ Traces of gjmpotULe-.^nd rshanol are present in vapors^
ted during curing-.
jo ariAmiai-p
P^- 1
.
' Seojrtcd untlei-USDl: Safety an'd Hiahl' Fit-a.aa'.-ynv to' Stic 5':: . Sninbuildmc. and Shifib'fcatinp (29 CFfi 191$. 1916. 1917) .
* . ________ '
.amuF act.USCR'S ris-MC
SECTION 1
CMcpctMCv.iEuCr-- ;nc no.
Fiberite Corporation
(507) 454-3611 .
aDSREU (S'umhtr. iirel. City. Sntc. end 7J1' Code}
:__ 5iLi_HssX_3i:V' .............................
CHCMICAL NSUC AND SYNONYMS' .
-
"ckTmical f~wiu\ :
~' .
___Phenolic Holding 'Compound.
Jir_U4F.DCibNe*Mritte**<.0.
SVNONVMi .
FM-6101__
j KSfi'
.
_________
SECTION U - HAZARDOUS INGREDIENTS _ __
n
;.
. paints,preservatives.r solvents
pigments catalyst vehicle
SOLVENTS
IU^uV. 1
At,lOYS AND METALLIC CO-T INGS
|
I BASE METAU
TT
! fALLOYS
.1
I
WET ALUC COATINQS.
-*
-- . -- - --
f ILL&A WCT AL
.PLUS COATING qh cope flux
1I
..
Apomves
Ol WRS
OTWEKS
1 -l
.
....
.
. .
HAZARDOUS MIXTURES OF .OTHFR l OUIDS. SDl>OS. OR CARES
*
Asbestos - 2 . fibers lonter'ithan 5 microns per cubic.___ .
1,1 tlv I-* 1 WJr.il_
_3 _J
.,,c&^^ater o^lr^j|^J^-I^J.6)^.ermUsible_&xosur&---------- L;
.(8-hour time-weighted averaefe-airborne concentrations^)- ___ j._L
Phenol
. . .-
.
. . .
1.251 Sppto
v .. . .
.
SECTION 111 - PHYSICAL .DATA
-. .
FOILING POWT lcFd
_
VAPOCPRtSSURE I'nmHsO
vapor ocNsrrv (airu -
' *
N/A N/A'
*
N/A
SPECIFIC ORftVlTY |M-0 n
PERCENT. VOLATILE ' BY VOLUME iU.)
evaporation RATE'
( ' =11
' '
SOLUBILITY IN viaYCR
, .'
RA'p pLgible
Maximum ` Bulk. Factor
appearance and coop, natural ..and black choooed Fibers .
. '
.' .
.
`
* N/A NONE N/A
: $__________
'
SECTION IV. V^IBE AND EXPLOSION HAZARD DATA
PLASM POINT (Mctnpo uled)
H/A U _
|rLAMMA9LE LIMITS .... I
*-**
_L_________________h/A_Il~~
' EXT ImCUISiMinG MEDIA
>
- Water-sprey , 'COo, Dry Chemical
il'tCIAL flC FiCMIINCr- PPBbOAHCEPDmUmBE#=Sr ... " '-1
"* ..
_ __
...'..1:_ "------ranfainp/l hrpafhing
Ue<
I concentrin'nno
air may be flarmafe^A^
P3-k
n v ,.j3}
Thy.. is_ mix tur-e..-- ;_;....
LFTLZI*
UC>.i,0,.UH^ ..
.. .
.
, ' . - - ___ _'__ 1__ Conti rvuous _e;xop s ure __ to C5bestos_.fi-bers_.ex tending..
'____9.Y,eJT. sovarnl.yenr s.-.re-ey_xc s\iVtUtlL_limitod .lunr^cap.a.city.
Cl.-.t'il'.Cl'CV viaflfiVT MOrfiperruRES
'.
"NO.NR
.* .
*.
- '
. 4. ,
STABILITY
.
* ; ' ' ' . SECTION VI -! REACTIVITY DATA
able J
. ' cojojtions to avoid
. '
/ \\; *, ..
*
.*
v'-
STABLE '
|
Irvcci.-.PAT ABILITY {Mucriuh lb eioldj
% . *V
.* ' *
xx ..
RONE HONE
\
* ' .
.'
*
; nousha as
decomposition products
' . '
.
.
. -.Phenol, formaldehyde. CO. COo
HATARDOUS
.
POLYMERIZATION '
. may* occur * ' * `
. .conoii-ions-to AVOID ~
*wtL.U NOT OCQUa . . XX
. ` -none
' '
, * , *
' . ,
.
.
,
*
..
'
.:
\ .
. . .
'
SECTION Vtl.- SPitLOR LEAK PROCEDURES. '
"
STEPS TO BE TAKEN IN case MATERIAL IS R.ELt&SED OR SPILLED
* materials ,and discard'if' contaminated.-
. Vacuum or scood up spilled Use. iudicious handling ' *
' .
methods to prevent dust genera tio'n.
i WASTE DISPOSAL METHOD
....
.
i
.
, . Bury-'as a Chemical waste in. accordance to federal.
*, p %
,*
> state, and`local regulations.
'
'1 '
'
'.
SECTION VIII - SPECIAL PROTECTION INFORMATION
RCiPIR^TOHY PAO Lection fS/irciA' Type/
' ..
....
.
As speci Eied.by OSHA-according to-fiber concentration*.
" /
(Qcntret) 1 VCNTitATlON . '
As specified by ANS1tZ9-2-
..
mechanical
..
' OTHER
'
.
Designed to meet-'exposure limits ' .
.
.
. ' ......
RHOTLCTIVE CLOVES '
' " .
/" .
Rubber or plastic
' E-YC PROTECTION .'
" Safety glasses
" -
.
QTHCK PROTECTiyt EOUirAieNT
-.
-
.
. As reqprred- by OSHA for exposures exceeding ceiling values .
SECTION IX - SPECIAL PRECAUTIONS
PRECAUTIONS TO BE. TAKEN IM MANOUNC AMO SIOKINO'"
.
.
Avoid, creating dust. The resin dus-t mav be flammable an.d-lthe_
fibers are a d e fin i. te--d,
othcr rneCAUTiOrys
See Sections TXt -IV .arid. V.
CUTLER 391/339 1?/-1/2006--------------
*.. ------- -r .
5E (Z)
23-n