Document KRrXdJ63OLVqYkzDONgvqp8Jx
Shell
MATERIAL SAFETY DATA SHEET
573?7 M-S5)
MSDS NUMBER ^
840,311
PAGE 1
SECTION II-A NO.
PRODUCT/INGREDIENT COMPOSITION
CAS NUMBER
PERCENT
P HCU/CR2 SEWER DRAIN SLUDGE
MIXTURE
lOO
1 SPENT ABRASIVE MATERIAL 1A SILICON DIOXIDE IB SULFIDES 2 SOIL, GRAVEL. SAND, GLASS, TRASH, ETC. 3 VESSEL SLUDGE 4 INSULATION 4 A ASBESTOS FIBERS 5 NICKEL COMPOUNDS 6 ALUMINA COMPOUNDS 7 SILICA GEL
MIXTURE 7631-86-9 MIXTURE MIXTURE MIXTURE MIXTURE 1332-21-4
MIXTURE MIXTURE 63231-67-4
60-70 * *
22-32 4 1-2 *
1 1 1
COMPONENT 1'IS USED ABRASIVE BLASTING MATERIAL WHICH PROBABLY CONTAINS OTHER UNIDENTIFIED ORGANIC AND INORGANIC COMPOUNDS.
SECTION II-B NO. ACUTE ORAL L050
P NOT AVAILABLE
ACUTE TOXICITY DATA ACUTE DERMAL LD50
ACUTE INHALATION LC50
SECTION III
HEALTH INFORMATION
THE HEALTH EFFECTS NOTED BELOW ARE CONSISTENT WITH REQUIREMENTS UNDER THE OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200).
EYE CONTACT MATERIAL MAY BE IRRITATING TO THE EYES.
LAM 026480
SKIN CONTACT MATERIAL MAY BE IRRITATING TO THE SKIN.
SENSITIZATION.
BASED UPON THE PRESENCE OF COMPONENT 5. MAY CAUSE SKIN
ABS-044433
PRODUCT NAME: HCU/CR2 SEWER DRAIN SLUDGE
MSDS 840,311
PAGE
2
INHALATION DUST MAY CAUSE IRRITATION TO THE NOSE. THROAT AND RESPIRATORY TRACT. INHALATION OF DUST CONTAINING SILICON DIOXIDE MAY CAUSE SILICOSIS. INHALATION OF DUST CONTAINING ASBESTOS FIBER MAY CAUSE ASBESTOSIS (FIBROSIS OF THE LUNGS). LUNG CANCER OR MESOTHELIOMA (SEE OTHER HEALTH EFFECTS).
INGESTION ALTHOUGH INGESTION IS NOT A PROBABLE ROUTE OF EXPOSURE, MATERIAL MAY BE HARMFUL IF SWALLOWED.
SIGNS AND SYMPTOMS IRRITATION AS NOTED ASOVE. SKIN SENSITIZATION (ALLERGY) MAY BE EVIDENCED BY RASHES. ESPECIALLY HIVES. LUNG DAMAGE (SCARRING. BRONCHITIS. EMPHYSEMA) MAY BE EVIDENCED BY SHORTNESS OF BREATH. ESPECIALLY ON EXERTION. AND MAY BE ACCOMPANIED BY CHRONIC COUGH.
AGGRAVATED MEDICAL CONDITIONS PREEXISTING EYE, SKIN, AND RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS MATERIAL. IMPAIRED RESPIRATORY FUNCTION FROM PREEXISTING DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS MATERIAL. PREEXISTING SKIN OR LUNG ALLERGIES MAY INCREASE THE CHANCE OF DEVELOPING INCREASED ALLERGY SYMPTOMS FROM EXPOSURE TO THIS MATERIAL.
OTHER HEALTH EFFECTS IN REFERENCE TO COMPONENT 1A. THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER HAS DETERMINED THERE IS SUFFICIENT EVIDENCE FOR THE CARCINOGENICITY OF CRYSTALLINE SILICON DIOXIDE IN EXPERIMENTAL ANIMALS AND LIMITED EVIDENCE FOR THE CARCINOGENICITY OF CRYSTALLINE SILICON DIOXIDE IN HUMANS. IN REFERENCE TO COMPONENT 4A. THE OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION, THE NATIONAL TOXICOLOGY PROGRAM AND THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER HAVE DETERMINED THERE IS SUFFICIENT EVIDENCE FOR THE CARCINOGENICITY OF ASBESTOS IN BOTH HUMANS AND EXPERIMENTAL ANIMALS. IN REFERENCE TO COMPONENT 5. THE NATIONAL TOXICOLOGY PROGRAM AND THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER HAVE DETERMINED THERE IS SUFFICIENT EVIDENCE FOR THE CARCINOGENICITY OF NICKEL AND CERTAIN NICKEL COMPOUNDS IN EXPERIMENTAL ANIMALS. SOME EPIDEMIOLOGICAL STUDIES ON WORKERS IN SOME NICKEL REFINERIES HAVE DEMONSTRATED AN EXCESS RISK OF CANCER OF THE NASAL CAVITY AND LUNG.
SECTION IV
OCCUPATIONAL EXPOSURE LIMITS
OSHA
NO. PEL/TWA
PEL/CEILING
TLV/TWA
ACGIH TLV/STEL
OTHER
1 A 0.05 MG/M3*
0.05 MG/M3
4 A 0.2 F/CC
1 F/CC 30 MIN
2 F/CC. A1
* 1 0.5 F/CC, A1
*2 2 F/FCC, A 1
*3 0.2 F/CC, A1
*4 2 F/CC. A1
5 1 MG/M3-*
1 MG/M3--
0.1 MG/M3*- *
0.1 MG/M3* * *
7 10 MG/M3
10 MG/M3
-CRYSTALLINE SILICA, CRISTOBALITE, RESPIRABLE * 1-AMOSITE. -2-CHRYSOTILE. -3-CROCIDOLITE. -4-OTHER FORMS OF ASBESTOS --METAL AND INSOLUBLE COMPOUNDS, AS NI. ---SOLUBLE COMPOUNDS. AS NI.
SECTION V
EMERGENCY AND FIRST AID PROCEDURES
EYE CONTACT IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION.
SKIN CONTACT IMMEDIATELY REMOVE CONTAMINATED CLOTHING/SHOES, WIPE EXCESS FROM SKIN AND FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. USE SOAP IF AVAILABLE OR FOLLOW BY WASHING WITH SOAP AND WATER. NOT REUSE CLOTHING UNTIL THOROUGHLY CLEANED. GET MEDICAL ATTENTION.
DO
INHALATION REMOVE VICTIM TO FRESH AIR AND PROVIDE OXYGEN IF BREATHING IS DIFFICULT.
RESPIRATION IF NOT BREATHING. GET MEDICAL ATTENTION.
GIVE ARTIFICIAL
INGESTION DO NOT INDUCE VOMITING. GET MEDICAL ADVICE.
LAM 026481
ABS-044434
PRODUCT NAME: HCU/CR2 SEWER DRAIN SLUDGE
SECTION VI NONE KNOWN.
SUPPLEMENTAL HEALTH INFORMATION
MSDS 840,311
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3
SECTION VII
PHYSICAL DATA
BOILING POINT: N/AV (DEG F)
SPECIFIC GRAVITY: N/AV (H20=1)
MELTING POINT: N/AV (DEG F)
SOLUBILITY: (IN WATER)
INSOLUBLE
EVAPORATION RATE (N-BUTYL ACETATE = 1): N/AV
APPEARANCE AND ODOR: BLACK SOLID/SLUDGE
VAPOR PRESSURE: N/AV (MM HG)
VAPOR DENSITY: N/AV (AIR=1)
SECTION VIII
FIRE AND EXPLOSION HAZARDS
FLASH POINT AND METHOD: >200 DEG F
FLAMMABLE LIMITS /% VOLUME IN AIR
LOWER: N/AV
UPPER: N/AV
EXTINGUISHING MEDIA USE WATER FOG, FOAM, DRY CHEMICAL OR C02.
SPECIAL FIRE FIGHTING PROCEDURES AND PRECAUTIONS MATERIAL WILL NOT BURN UNLESS PREHEATED. DO NOT ENTER CONFINED FIRE SPACE WITHOUT FULL BUNKER GEAR (HELMET WITH FACE SHIELD, BUNKER COATS. GLOVES AND RUBBER BOOTS). INCLUDING A POSITIVE PRESSURE NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS WITH WATER.
UNUSUAL FIRE AND EXPLOSION HAZARDS SULFUR OXIDES AND HYDROGEN SULFIDE. BOTH OF WHICH ARE TOXIC, MAY BE RELEASED UPON COMBUSTION.
SECTION IX
REACTIVITY
STABILITY: STABLE
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
CONDITIONS AND MATERIALS TO AVOID: THIS MATERIAL MAY FORM HIGHLY TOXIC HYDROGEN SULFIDE ON CONTACT WITH ACIDS: PREVENT CONTACT WITH ACIDS.
HAZARDOUS DECOMPOSITION PRODUCTS CARBON MONOXIDE. SULFUR OXIDES, HYDROGEN SULFIDE AND UNIDENTIFIED ORGANIC COMPOUNDS MAY BE FORMED DURING COMBUSTION.
LAM 026482
ABS-044435
PRODUCT NAME: HCU/CR2 SEWER DRAIN SLUDGE
MSDS 840,311
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SECTION X
EMPLOYEE PROTECTION
RESPIRATORY PROTECTION IF EXPOSURE MAY OR DOES EXCEED OCCUPATIONAL EXPOSURE LIMITS (SEC. IV) USE A NIOSH-APPROVED RESPIRATOR TO PREVENT OVEREXPOSURE. IN ACCORD WITH 29 CFR 1910.134 USE EITHER A FULL-FACE, ATMOSPHERE-SUPPLYING RESPIRATOR OR AIR-PURIFYING RESPIRATOR FOR PARTICULATES.
PROTECTIVE CLOTHING AVOID CONTACT OF DUST, VAPORS AND FUMES WITH EYES. WEAR CHEMICAL GOGGLES CONTACT WITH EYES. AVOID CONTACT OF DUST. VAPORS AND FUMES WITH SKIN AND CHEMICAL-RESISTANT GLOVES AND PROTECTIVE CLOTHING.
IP THERE IS LIKELIHOOC CLOTHING. WEAR
OF
ADDITIONAL PROTECTIVE MEASURES USE EXPLOSION-PROOF VENTILATION AS REQUIRED TO CONTROL PARTICULATE CONCENTRATIONS.
SECTION XI
ENVIRONMENTAL PROTECTION
SPILL OR LEAK PROCEDURES MAY BURN. ALTHOUGH NOT READILY IGNITABLE. USE CAUTIOUS JUDGEMENT WHEN CLEANING UP LARGE SPILLS. WEAR RESPIRATOR AND PROTECTIVE CLOTHING, AS APPROPRIATE. *** SHOVEL AND SWEEP UP OR USE INDUSTRIAL VACUUM CLEANER. AVOID GENERATING DUST CLOUDS. *** PUT INTO CONTAINERS FOR RECLAIMING OR DISPOSAL.
SECTION XII
SPECIAL PRECAUTIONS
KEEP AWAY FROM ACIDS. THIS MATERIAL MAY REACT WITH ACIDS AND PRODUCE TOXIC HYDROGEN SULFIDE. STORE IN A COOL, DRY PLACE WITH ADEOUATE VENTILATION. KEEP AWAY FROM OPEN FLAMES AND HIGH TEMPERATURES. WASH WITH SOAP AND WATER BEFORE EATING, DRINKING, SMOKING, APPLYING COSMETICS, USING TOILET FACILITIES. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
OR
SECTION XIII
TRANSPORTATION REQUIREMENTS
DEPARTMENT OF TRANSPORTATION CLASSIFICATION: TRANSPORTATION REQUIREMENTS DETERMINED ON A CASE BY CASE BASIS BY SHIPPING LOCATION.
SECTION XIV
OTHER REGULATORY CONTROLS
WITHIN THE LIMITATIONS SPECIFIED IN 40 CFR 710.4(D)(2), THIS BYPRODUCT IS EXCLUDED FROM LISTING ON THE EPA/TSCA INVENTORY OF CHEMICAL SUBSTANCES.
IN ACCORDANCE WITH SARA TITLE III, SECTION 313, THE EDS SHOULD ALWAYS BE COPIED AND SENT WITH THE MSDS .
SECTION XV
STATE REGULATORY INFORMATION
THE FOLLOWING CHEMICALS ARE SPECIFICALLY LISTED BY INDIVIDUAL STATES; OTHER PRODUCT SPECIFIC HEALTH AND SAFETY DATA IN OTHER SECTIONS OF THE MSDS MAY ALSO BE APPLICABLE FOR STATE REQUIREMENTS. FOR DETAILS ON YOUR REGULATORY REQUIREMENTS YOU SHOULD CONTACT THE APPROPRIATE AGENCY IN YOUR STATE.
lam 026483 ABS-044436
PRODUCT NAME: HCU/CR2 SEWER DRAIN SLUDGE STATE LISTED COMPONENT
PERCENT
STATE CODE
MSDS 840,311
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5
SILICON DIOXIDE (CAS NO: 7631-86-9
ASBESTOS (CAS NO: 1332-21-4 )
NICKEL COMPOUNDS (CAS NO: MIXTURE
)
SILICA GEL (CAS NO: 63231-67-4
FL. MA, NJ. PA
CA , FL. IL, MA. ME, MN. NJ. PA RI . CA65 CA, FL. IL. MA. ME , MN. NJ . PA 1 RI, CA65 CA
CA = CALIFORNIA HAZ. SUBST. LIST; CA65 = CALIFORNIA SAFE DRINKING WATER AND TOXICS ENFORCEMENT ACT LIST; FL = FLORIDA SUBST. LIST; IL = ILLINOIS TOX. SUBST. LIST; MA = MASSACHUSETTS SUBST. LIST; ME = MAINE HAZ SUBST. LIST; MN = MINNESOTA HAZ. SUBST. LIST; NU = NEW JERSEY HAZ. SUBST. LIST; PA = PENNSYLVANIA HAZ. SUBST. LIST; RI = RHODE ISLAND HAZ. SUBST. LIST.
THIS MATERIAL CONTAINS A CHEMICAL OR CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER AND/OR REPRODUCTIVE TOXICITY.
SECTION XVI
SPECIAL NOTES
NEW MSDS. SEE ENVIRONMENTAL DATA SHEET FOR WASTE DISPOSAL AND OTHER ENVIRONMENTAL INFORMATION.
THE INFORMATION CONTAINED HEREIN IS BASED ON THE DATA AVAILABLE TO US AND IS BELIEVED TO BE CORRECT. HOWEVER, SHELL MAKES NO WARRANTY, EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. SHELL ASSUMES NO RESPONSIBILITY FOR INJURY FROM THE USE OF THE PRODUCT DESCRIBED HEREIN.
DATE PREPARED:SEPTEMBER 23. 1991
BE SAFE
READ OUR PRODUCT SAFETY INFORMATION ...AND PASS IT ON
(PRODUCT LIABILITY LAW REQUIRES IT)
G. A. VAN GELDER
SHELL OIL COMPANY PRODUCT SAFETY AND COMPLIANCE P. 0. BOX 4320 HOUSTON, TX 77210
LAM 026484 ABS-044437
Shell
ENVIRONMENTAL DATA SHEET
?7449 f? - 07?
EDS NUMBER 840,311
PAGE 1
PRODUCT HCU/CR2 SEWER DRAIN SLUDGE
PRODUCT CODE
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SECTION I NO.
PRODUCT/COMPOSITION COMPONENT
CAS NUMBER
PERCENT
P HCU/CR2 SEWER DRAIN SLUDGE
MIXTURE
100
1 SPENT ABRASIVE MATERIAL 1A SILICON DIOXIDE
IB SULFIDES 2 SOIL, GRAVEL, SAND, GLASS, TRASH, ETC. 3 VESSEL SLUDGE 4 INSULATION 4A ASBESTOS FIBERS 5 NICKEL COMPOUNDS 6 ALUMINA COMPOUNDS 7 SILICA GEL
MIXTURE 7631-86-9 MIXTURE MIXTURE MIXTURE MIXTURE 1332-21-4 MIXTURE MIXTURE 63231-67-4
60-70 * *
22-32 4 1-2 *
1 1 1
COMPONENT 1 IS USED ABRASIVE BLASTING MATERIAL WHICH PROBABLY CONTAINS OTHER UNIDENTIFIED ORGANIC AND INORGANIC COMPOUNDS.
SECTION II
NO.
EHS RQ (LBS) (*1)
SARA TITLE III INFORMATION
EHS TPQ (LBS) ( *2)
SEC 313 ( *3)
313 CATEGORY (*4)
P
5
YES
NICKEL COMPOUNDS
311/312 CATEGORIES ("5)
H-1, H-2
-................................................................................................................... FOOTNOTES..........................................................................................................................
s'
*1 = REPORTABLE OUANTITY OF EXTREMELY HAZARDOUS SUBSTANCE. SEC.302
*2 = THRESHOLD PLANNING OUANTITY, EXTREMELY HAZARDOUS SUBSTANCE, SEC 302
*3 = TOXIC CHEMICAL. SEC 313
*4 => CATEGORY AS REQUIRED BY SEC 313 (40 CFR 372.G5 C), MUST BE USED ON TOXIC RELEASE INVENTORY FORM
*5 = HAZARD CATEGORY FOR SARA SEC. 311/312 REPORTING
HEALTH
H-1 = IMMEDIATE (ACUTE) HEALTH HAZARD
H-2 * DELAYED (CHRONIC) HEALTH HAZARD
PHYSICAL P-3 * FIRE HAZARD
P-4 = SUDDEN RELEASE OF PRESSURE HAZARD
P-5 - REACTIVE HAZARD
SECTION III
ENVIRONMENTAL RELEASE INFORMATION
EPA - COMPREHENSIVE ENVIRONMENTAL RESPONSE. COMPENSATION AND LIABILITY ACT. UNDER EPA-CERCLA ("SUPERFUND") RELEASES TO AIR, LAND OR WATER WHICH EXCEED THE REPORTABLE OUANTITY MUST BE REPORTED TO THE NATIONAL RESPONSE CENTER, 800-424-8802.
THE REPORTABLE OUANTITY FOR A RELEASE OF THIS MATERIAL IS 100 LBS., WHICH IS BASED ON THE RCRA CODE 0003.
LAM 026485
ABS-044438