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SEVERN 1 REN T STL STL Chicago 2417 Bond Street University Park, IL 60466 Tel: 708 534 5200 Fax: 708 534 5211 HWW.Si/-ff7C.C0fn SEVERN TREN T LA B O R A TO R IES i l t io JOB NUMB ER : 233 5 07 P r e p a r e d "Por: W e s Lon Soluti, o n s , Inc . 14 0 C -Weston Way B u i l d i n g 5-2 :: . W est Ch.ester, PA 19380-1499 Project, : C o n f i d e n t i a l D e c a e n r ..A F C Inv e s t i g a r.i.c r. ALteneion : Jai Kesari Date : 01/28/2005 Title: Project Manager E - M a i l ; r w r i g h t O s t l - i n c .c o m Thns Report Contains Leaders in Environmental Testing Date STL Chicago 2417 B o n d LStroot. University Park, IL 0466 PHONE : (708) 5 2 4- 52 00 F A X . .: (708) 534 5211 ) Pages Severn I rout Laboratories, Inc. WET CHEMISTRY DATA PACKAGE CONFIDENTIAL DECATUR ~FC INVESTIGATION JOB# 233507 Data Summary......................................................... 1 Chain of Custody.................................................... 1$ Case Narrative........................................................19 Raw Data................................................................21 STL Chicago is part of Severn Trent Laboratories, Inc. i,;s / :|h . -p . l .....I N f o r n a t i o n ... Date: 01/28/2005 Job Number,: 233507 Customer,..: Ueston Solutions, Inc. A t t n . . ........ : J a i K e s a r i Project Number........ : 20004891 Customer P r o je c t ID.... : CONFIDENTIAL DECATUR P r o j e c t D e s c r i p t i o n . . . . : C o n f i d e n t i a l D e c a t u r - FC I n v e s t i g a t i o n Laboratory Sample ID 233507-1 233507-2 233507-3 233507-4 233507-5 233507-6 233507-7 233507-8 233507-9 233507-10 233507-11 Customer ;$ia(Tpe ID DLOI-SB-320L-0-0170 DL0I-SB-320L--0290 DLOI-SD-117L-0-0000 DLI-SB-T17L-O-0005 DLOI-SB-117L-0-0020 D L O 1-S B -117 L -2-0050 DLOI-SB-117L-0-0290 DL0I-SB-320L-0-0000 DLOI-SB-32OL-O-0005 DLOI-SB-320L-0-0020 DLQI-SB-32QL-0-0050 .. Sample Matrix Time Date Sampled... .Received /: Time :Received Soi L 01/13/2005 15:30 01/15/2005 09:00 Soi L 01/13/2005 16:10 01/15/2005 09:00 Soi l 01/13/2005 07:35 01/15/2005 09:00 Soil 01/13/2005 07:45 01/15/2005 09:00 soi l 01/13/2005 07:55 01/15/2005 09:00 Soil 01/13/2005 10:25 01/15/2005 09:00 Soi l 01/13/2005 12:10 01/15/2005 09:00 Soi 1 01/13/2005 13:40 01/15/2005 09:00 Soi 1 01/13/2005 13:45 01/15/2005 09:00 sot L 01/13/2005 13:50 01/15/2005 09:00 Soil 01/13/2005 14:35 01/15/2005 09:00 STL Chicago Page 1 1 STL Chicago is part of Severn Trent Laboratories, Inc. Job Number: 233507 CUSTOMER: Weston Solutions, Inc. Customer Sample ID Date Sampled..... Time Sampled..... Sample Matrix.... D LO E-SB-320 L*0 -0170 01/13/2005 15:30 Soi l TEST METHOD ; Lloyd Kahn :PARAMETER/TEST :DES CRIPTION : Total Organic Carbon (Soils) TOC Average Duplicates, Solid N LABORATORY TEST RESULTS PROJECT: CONFIDENTIAL DCA7UR Laboratory Sample 10: 233507-1 Date Received...... : 01/15/2005 Timte Received___ 09:00 Date:01/2fl/2005 ATTN: Jai Kesari S M P LE RESULT 1600 FLAGS: MOL 110 t RL. 430 0 1LUT EON UK] TS BATCH ;DT DATE/IIHE t e c h : mg/Kg 1403*7 01/25/05 1452 els * In Description = Dry W g t . Page 2 coi a U J H un STL Chicago is part of Severn Trent Laboratories, Inc. Job Nunber: 233507 : CUSTOMER: Weston Solutions, Inc. Customer Sample ID: DLOl-SB-320L-0-0290 Date Sampled..... : 1/13/2005 T ime Sampled..... : 16:10 Sample Matrix.... : Soi l TEST METHCO . PARAMETER/TEST DESCRIPTION . i Lloyd Kahn Total Organic Carbon (Soils) TOC Average Duplicates, Solid LABORATORY TEST RESULTS PROJECT: CONFIDENTIAL DECATUR . . Laboratory Sample ID: 233507-2 Date Received...... : 01/15/2005 Time Received...... : 09:00 Date:01/23/2005 ATTN: Ja Kesari SAMPLE RESULT 0 FLAGS:; 430 MDL 53 RL 0 1LUT ION UMITS BATCH DT DATE/71.ME . TECH 210 1 mg/Kg 140367 01/25/05 1513 els ! * In Description = Dry Ugt. Page 3 STL Chicago STL Chicago is part of Severn Trent Laboratoriesd Inc. Job Hurrper: 233507 : CUSTOMER: Weston Solutions ,, ]n e . Customer Sample ID: OLOI-SB-117L-Q-0000 Date Sampled...... :01/13/2005 Time Sampled...... :07:35 Sample Matrix..... :Soil LABORATORY TEST RESULTS PROJECT': COWfIDEMTIAL DECATUR Laboratory Sample ID: 253507-3 Date Received....... :01/15/2005 Time Received....... :09:00 Date:01/2S/2005 AT TN: Jai Kesari STL Chicago Ti STL Chicago is part ot Severn Trent Laboratories, Inc, Job Number: 233507 CUSTOMER: Weston So lut ions,. Inc.. Customer Sample Id Date Sampled..... Time Sampled..... Sample Matrix.... D L O i -SB-117L-0-GOQ5 01/13/2005 07:45 Soi L TEST METHOD Lloyd Kahn PARAMETER/TE ST ;DESCRI P H O B TotaL Organic Carbon <Soits) TOC Average Duplicates, Solid HT LABORATORY TEST RESULTS PROJECT: CONFIDENTIAL DECATUR Laboratory Sample ID: 233507-4 Date Received....... : 01/15/2005 Time Received...... : 09:00 Date:01/2B/2005 ATTN: Jai Kesari : SAMPLE RESULT J 3300 FLAGS: MDL 15D RL DELUTTOM UNITS : : BATCH d t ; d a t e /t i m e t e c h 5S0 mg/Kg 1437 01/25/05 1527 c l s STL Chicago ]n Description = Dry Wgt. Page 5 STL Chicago is part o-f Severn Trent Laboratories, Enc. Job Rumber: 233507 CUSTOMER: Weston Solutions, Inc. Customer Sample ID: DL0I-SB-117L-0-0020 Date Sampled...... :01/13/2005 Time Sampled...... :07:55 Sample Matrix..... :Soil TEST-METHOD Lloyd Kahn PARAMETER/TEST DESCRIPTION Total Organic Carbon <Soi Is) TOC Average Duplicates, Solid LABORATORY TEST RESULTS PROJECT:: COMFI DENTI AL: DECAUR Laboratory Sample ID 233507-5 Date Received..,___ 0 T/15/2005 Time Received...... 09:00 bate:01/28/2005 ATTN: Jai Kesari SAMPLE RESULT 0 IFLAGS 910 MOL 81 RL DILUTION UNITS BATCH1 :DT DATE/TIHE TECH 320 mg/Kg 140407 ! 01/27/05 0852 els STL Chicago * In Description = Dry Wgt. Page 6 STL Chicago is part of Severn Trent Laboratories, Inc. Job Number: 233507 CUSTOMER;: Weston Solutions , Inc. Customer Sample ID: DLOI-SB-117L-2-0050 Date Sampled..... : 01/13/2005 Time Sampled..... : 10:25 Sample Matrix.... : Soi l LABORATORY TEST RESULTS Date:01/28/2005 . PROJECT: CONFIDENTIAL DECATUR : : : , : ATTN: Jai Kesari Laboratory Sample ED: 233507-6 Date Received...... : 01/15/2005 Time Received...... : 09:00 STL Chicago o STL Chicago is part of Severn Trent Laboratories, Inc. Job Nienber : 233507 LU u iv(nLK - nUi^iLy|"1 b L u \ 1JJFty ~L-r1 Customer Sample ID: DLO]-SB-117L-0-0290 Date Sampled.......:01/13/2005 Time Sampled.......:12:10 Sample Hat ri x ......:Soil TEST METHOD Lloyd Kahn .PARAMETER/TEST;DESCRIPTION Total Organic Carbon (Soils) TOC Average Duplicates, Solid LABORATORY TEST RESULTS Fifty'd'Efe't : l-i/fllr HC IH kftL -UC Laboratory Sample ID: 233507-7 Date Received....... : 01/15/2005 Time Received....... : 09:00 Date:01/23/2005 . .Aitlift.* : JBt. .It&SBFil- S a m p l e -r e s u l t ::-:; FLAGS 390 MOL RL 52 200 DILUTION; UK3TS i BATCH DT DATE/TIME TECH I mg/Kg -140407 01/27/05 0953 els STL Chicago * In Description = Dry Wgt. Page 8 STL Chicago is part of Severn Trent Laboratories, Inc. LABORATORY TEST RESULTS c STL Chicago is part of Severn Trent Laboratories, ine. Job Number: 233507 : .CUSTOMER: Weston Solutions, nc. : Customer Sample 3D ;D LO1-SB-320L-0-0005 Date Sampled...... :01/13/2005 Time Sampled...... :13:A5 Sample Matrix..... :Soi L LABORATORY TEST RESULTS . PROJECT: CONFIDENTIAL DECATUR Laboratory sample ED: 233507-9 Date Received....... : 01/15/2005 Time Received...... : 09:00 Date:01/2B/2005 A7TM: Jai Kesari STL Chicago STL Chicago is part of Severn Treni Laboratories, Ine. Job Number: 233507 CUSTOMER: Weston Selliti ans, Inc. Customer Sanple ID: DLCt-SB-320L-0-CQ2Q Date Sampled...... :01/13/2005 Time Sampled...... :13:50 Sample Matrix..... :Soil TEST METHOD Lloyd Kahn PARAMETE R./TEST ;DESCRIP 7 ION Total Organic Carbon (Soils) TOC Average Duplicates, Solid LABORATORY TEST RESULTS PROJECT:' COW F.lDENTI AL DECATUR. Laboratory Sample ID: 233507-10 Date Received........:01/15/2005 Time Received........:09:00 Date:01/28/20Q5 ATTN: Jai Kesari : :s a m p l e ;RESULT Id FLAGS 1300 MOL 150 KL: 590 DILUTION .UNITS BATCH: DT DATE/TIME TECH mg/Kg j140487 01/27/05 1tOO e ls STL Chicago * ]n Description = Dry Ugt. Page 11 STL Chicago is part of Severn Trent Laboratories, Inc. Job Number: 233507 CUSTOMER: Weston Solutions, In c.. Customer Sample ID: DLOI-SB-320L-0-D050 Date Sampled..... : D1/13/20D5 Time Sampled..... : 14:35 Sample Matrix.... : Soi L i LABORATORY TEST RESULTS . PROJECT: CONFIDENTIAL DECATUR Laboratory Sample 3D: 233507-11 Date Received....... : 01/15/2005 Time Received....... : 09:00 Date:01/23/2005 : ATTN: - Jai.Kc-sari STL Chicago STL Chieggo is part of Severn Trent Laboratories, Inc. Job Number: 233507 LABORATORY CHRONICLE Date: 01/28/2005 CUSTOMER: Weston Solutions, Inc. Lab ID: 233507-1 METHOD EDD PKG INO (WC) Lloyd Kahn Client ID: DLOI-SB-320L-0-0170 DESCRIPTION Electronic Data Deliverable PKG INO (WET CHEMISTRY) Total Organic Carbon (Soils) Lab ID: 233507-2 Client ID: DLOI-SB-320L-0-0290 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233507-3 Client ID: DL01-SB-117L-0-0000 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233507-4 Client ID: DLOI-SB-117L-Q-0005 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233507-5 Client ID: OLD!-SB-117L-0-002 METHOD DESCRIPTION Lloyd Kahn TotaL Organic Carbon (Soils) Lab ID: 233507-6 Client ID: DLOI-SB-117L-2-0050 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233507-7 Client ID: DL0I-SB-117L-0-0290 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233507-8 Client ID: DL0I-SB-320L-0-0000 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233507-9 Client ID: DLOI-SB-320L-0-0005 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233507-10 Client ID: DLQI-SB-320L-0-0020 METHOD DESCRIPTION Lloyd Kahn TotaL Organic Carbon (Soils) Lab ID: 233507-11 Client ID: DLOI-SB-3ZPL-0-0050 METHOD DESCRIPTION Lloyd Kahn TotaL Organic Carbon (Soils) PROJECT: CONFIDENTIAL DECATUR ATTN: Jai Kesari Date Recvd: 01/15/2005 sanple Date: 01/13/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 1 1 140367 140367 01/25/2005 1452 DILUTION Date Recvd: 01/15/2005 Sample Date: 01/13/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 140367 140367 01/25/2005 1513 DILUTION Date Recvd: 01/15/2005 Sample Date: 01/13/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 140367 140367 01/25/2005 1543 DILUTION Date Recvd: 01/15/2005 Sample Date: 01/13/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 140367 140367 01/25/2005 1527 DILUTION Date Recvd: 01/15/2005 sample Date: 01/13/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 140487 140487 01/27/2005 0852 DILUTION Date Recvd: 01/15/2005 Sample Date: 01/13/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 140487 140487 01/27/2005 0937 DILUTION Date Recvd: 01/15/2005 Sample Date: 01/13/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 140487 140487 01/27/2005 0953 DILUTION Date Recvd: 01/15/2005 Sample Date: 01/13/2005 RUN# BATCH# PREP BT #(S> DATE/TIME ANALYZED 1 140487 140487 01/27/2005 1017 DILUTION Date Recvd: 01/15/2005 Sample Date: 01/13/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 140487 140487 01/27/2005 1034 DILUTION Date Recvd: 01/15/2005 sample Date: 01/13/2005 RUN# BATCH# PREP BT #<$) DATE/TIME ANALYZED 1 140487 140487 01/27/2005 1100 DILUTION Date Recvd: D1/15/20Q5 Sample Date: 01/13/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 144B7 140487 01/27/2005 1131 DILUTION Chicaeo Page 13 tl Job Number.: 233507 CUSTOMER: Westen Solutions, Inc. QUALITY CONTROL RESUL T S . .. PROJECT: CONFIDENTIAL DECATUR . Report Date.: O1./2/2005 ATTN: Jai Kesari Test Method.. .....: Lloyd Kahn Method Description.: Total Organic Carbon Parameter.. ;y:';;-.;y... : Organic Carbon,.Tot. (TOC);;; Batch............ : .140367 Equipment Code... : TQC4 .... Analyst...: els Test code.: TOC ' QC Lab ID Reagent Units ICV 140367-002 I04LSTTC2 MB 140367"003 LCS 140367-004 I0FSTLK3 LCD 140367-005 I00FSTLK3 mg/Kg mg/Kg mg/Kg mg/Kg CCV 140367-016 I04LSTTC2 CCB 140367-017 CCV 140367-016 I04LSTTC2 CCB 140367-017 mg/Kg mg/Kg mg/Kg mg/Kg QC ResuLt QC Result 2011.97 32.00 U 4964.74 4147.31 4964,74 1996.35 32.00 1969.76 32.00 U u True Value 2000.00 4780.00 4780.00 2000.00 2000.00 Orig. Value QC Calc. F * Limits Date Time 101 158.03 186.18 U 104 U 87 18 100 98 % 85-115 % 53-140 % 53-140 R 30 % 85-115 X 85-115 01/25/2005 0840 01/25/2005 0854 01/25/2005 0913 01/25/2005 0937 01/25/2005 1244 01/25/2005 1249 01/25/2005 1558 01/25/2005 1601 "Test Method. L:fnvd (fahrt Method Description.: Total-Organic Carbon (SoiLs) Parameter.-. Tot. (TC) QC Lab ID Reagent Units ICV 140487-002 I04LSTTC2 MB 140487-003 LCS 140487-004 I00FSTLK3 LCD 140487-005 I00FSTLK3 mg/Kg mg/Kg mg/Kg mg/Kg QC Result QC Result 1928.56 32.00 u 4761.61 4300.41 4761.61 CCV 140487-015 I04LSTTC2 CCB 140487-016 CCV 140487-015 I04LSTTC2 CCB 140487-016 mg/Kg mg/Kg mg/Kg mg/Kg 2034.14 32.00 2088.83 32.00 u u Rflfch ::.:: ', Equipment code ....: TQC3 Analyst;.. Test Code .: TOC True Va Lue 2000.00 4780.00 4780.00 2000.00 2000.00 Orig,, Value QC Calc. F * Limits Date Time 174.75 158.03 96 U 100 U 90 10 102 104 31 85-115 % 53-140 % 53-140 R 30 % 85-115 % 85-115 01/27/2005 0800 01/27/2005 0807 01/27/2005 0839 01/27/2005 0845 01/27/2005 1149 01/27/2005 1214 01/27/2005 1523 01/27/2005 1527 .Test Method....... Method Description. Parameter.... .v Lloyd Kahn Total ;Organic Carbon (Soits) ;; TOC Average Dupli cates Batch...... : 140487 . Equipment Code.... Analyst..,: els Te st.Code.:\.TOCAV2 ' QC Lab ID MS 233507-5 MSD 233507-5 Reagent Units I4LSTTC2 mg/Kg I04LSTTC2 mg/Kg QC ResuLt 2142.12 2242.53 QC ResuLt 2142.12 True Value 2000.00 2UOO.OQ Orig. Value 906.24 906.24 QC Calc. F * Limi ts Date Time 82 % 53-140 01/27/2005 0917 90 % 53-140 01/27/2005 0929 8 R 30 Page 14 X-% REC, R=RPD, A=ABS Di ff-, D=% Dl'ff.. Q U A L I Y > ' S U R A N C -E ' ;H T -t-Q 6 'S R E F E R E N C E S .A !N! D M O T E S ; ; ' ; Report pat; ;i/2B/.2O05 REPORT COMMENTS 1) A U pages of this report are integral parts of the analytical data. Therefore, this report shouLd be reproduced only in its entirety, 2) Soil, sediment and sludge sample results are reported on a "dry weight" basis except when anaLyzed for landfill disposal or incineration parameters. A U other solid matrix samples are reported on an "as received" basis unless noted differently. 3) Reporting limits are adjusted for sample size used, dilutions and moisture content if applicable. 4) Tho test results for the noted analytical method(s) meet the requirements of NELAC. Lab Cert, ID# 100201 5) According to 40CFR Part 136.3, pH, Chlorine Residual and Dissolved oxygen analyses are to be performed iwnediately after aqueous sampLe collection. When these parameters are not indicated as field (e.g. pH FieLd) they were not analyzed immediately, but as soon as possibLe on Laboratory receipt. Glossary of flags, qualifiers and abbreviations (any number of which may appear in the report) Inorganic Qualifiers (Q-Column) U Analyte was not detected at or above the stated Limit, i Not detected at or above the reporting limit. J Result is less than the RL, but greater than or equal to the method detection limit. B Result is Less than the CRDL/RL, but greater than or equal to the IDL/MDL. S Result was determined by the Method of Standard Additions. F AFCEE: Result is Less than the RL, but greater than or equal to the methoddetection limit. Inorganic Flags (Flag Column) ICV.CCv.iCB.ccB^SAflSBfCRIiCRAjMRL: instrument related QC exceed the upper or lower control limits. * LCS, LCD, MD: Batch QC exceeds the upper or lower controL limits. + MSA correlation coefficient is less than 0,995. it MS, MSD: The analyte present ih the original sampLe is 4 times greater than the matrix spike concentration; therefore, control limits are not applicable. E SD: Serial dilution exceeds the controL Limits, H MB, EB1, EB2, EB3: Batch QC is greater than reporting limit or had a negative instrument reading lower than tho absoLute value of the reporting Limit, hi MS, MSD; Spike recovery exceeds the upper or lower control limits. U AS(GFAA) Post-digestion spike was outside 85-115% control limits. Organic Qualifiers (Q - Column) U AnaLyte was not detected at or above the stated limit. ND Compound not detected. J Result is an estimated vaLue below the reporting Limit or a tentatively identified compound (TIC). Q Result was qualitatively confirmed, but not quantified. C Pesticide identification was confirmed by GC/MS. Y The chromatographic response resembles a typical fuel pattern. Z The chromatographic response does not resembLe a typical fuel pattern. E Result exceeded calibration range, secondary dilution required. F AFCEE:Result is an estimated value below the reporting Limit or atentativelyidentified compound (TIC) Organic Flags (Flags Column) B MB: Batch QC is greater than reporting limit. * LCS, LCD, ELC, ELD, CV, MS, MSD, Surrogate: Batch QC exceeds theupper orlower controLLimits. EB1, EB2, EB3, MLE: Batch QC is greater than reporting Limit A Concentration exceeds the instrument calibration range a Concentration is below the method Reporting Limit (RL) B Compound was found in the blank and sample. D Surrogate or matrix spike recoveries were not obtained because the extract was diluted for analysis; also compounds analyzed at a dilution wiLL be flagged with a D. H Alternate peak selection upon analytical review I Indicates the presence of an interfence, recovery is not calculated. M Manually integrated compound. P The lower of the two values is reported when the % difference between the results of two GC columns is Page 15 STLChicaeo Q U A I , T Y A S S U R A N C E . N |.:T . HIC! D S R F R E N C E S AND NOT S . Report.;D;ate:\ 01/23/2005 greater than 25%. A b b re v ia tio n s AS Post Digestion Spike (GFAA Samples - See Note 1 beLou) Batch Designation given to identify a specific extraction, digestion, preparation set, or analysis set CAP Capillary Column CCB continuing Calibration BLank CCV Continuing Calibration Verification CF Confirmation analysis of original Cl Confirmation analysis of A1 or D1 C2 Confirmation ana Lysis of A2 or D2 C3 Confirmation analysis of A3 or D3 CRA Low Level Standard Check - GFAA; Mercury CRI Lou Level Standard Check - ICP cv CaliLbration Verification standard D U Fac Dilution Factor - Secondary dilution anaLysis D 1 D ilut ion 1 D2 Di Lution 2 D3 Dilution 3 DLFac Detection Limit Factor DSH Distilled Standard - High Level DSL Distilled Standard - Lou Level DSM Distilled Standard - Medium LeveL EB1 Extraction Blank 1 EB2 Extraction BLank 2 EB3 DI Blank ELC Method Extracted LCS ELD Method Extracted LCD ICAL Initial calibration ICB Initial Calibration Blank ICV Initial Calibration Verification JDL Instrument Detection Limit ISA interference Check Sample A - ICAP ISB Interference Check Sample B ICAP Job No. The first six digits of the sample ID which refers to a specific client, proj'ect and sample group Lab ID An B number unique laboratory identification LCD Laboratory ControL Standard Duplicate LCS Laboratory Control Standard with reagent grade water or a matrix free from the analyte of interest MB Method Blank or (PB) Preparation BLank MD Method Duplicate MDL Method Detection Limit MLE Medium Level Extraction Blank MRL Method Reporting Limit Standard MSA Method of Standard Additions MS Matrix Spike MSD Matrix Spike Duplicate ND Not Detected PREPF Preparation factor used by the Laboratory's Information Management System (LIMS) PDS Post Digestion Spike ClCAP) RA Re-ana lysis of original Al Re-ana lysis of Dl A2 Re-gnalysis of D2 A3 Re-ana lysis of 03 RD Re-extraction of dilution RE Re-extract ion of original RC Re-extraction Confirmation RL Reporting Limit RPD Relative Percent Difference of duplicate (unrounded) analyses RRF Relative Response Factor RT Retention Time Page 16 STL O ticago 16 q u a l t Ty- i n s u r a n c e met h b s . R F R E N C E S AND' N O T $ . . . Report. Date; G1/B/20G$ RTU Retention Time UihdaW SampLe ID A 9 digit number unique for each sample, the first six digits are referred as the job number 5CB Seeded Control Blank SD SeriaL Dilution (Calculated when sample concentration exceeds SO times the MOL) UCG Unseeded Control Blank ssv Second Source Verification Standard 3LCS Solid Laboratory Control Standard(LCS) PHC pH Calibration Check LCSP pH Laboratory Control Sample LCDP pH Laboratory Control Sample Duplicate MDPH pH SampLe Duplicate MDFP FLashpOl'nt Sample Duplicate LCFP Flashpoint LCS Gl GeLeX Check Standard Range 0~1 G2 Gclcx Check Standard Range 1-10 G3 Gelex Check Standard Range 10-100 G Gelex check Standard Range 100-1000 Note 1: The Post Spike Designation on Batch QC for GFAA is designated uith an "S" added to the current abbreviation used. EX. LCS S=LCS Post Spike (GFAA); MS5=MS Post Spike (GFAA) Note 2: The MD calculates an absoLute difference (A) when the sample concentration is less than 5 times the reporting limit. The control Limit is represented as +/- the RL. STL Chicago Page 17 17 CHAIN OF CUSTODY CHAIN OF CUSTODY / ANALYSIS REQUEST FORM Severn Trent Laboratories T: 708-534-5200 F: 708-534-5211 2417 Bond Street University Park, IL 60466 PAGE `T ' of PROJECT INFORMATION Client: Weston Solutions, Inc. 1400 Weston Way, Bldg. 5-2 West Chester, PA 19380 T: 610-701-3761 F: 610-701-7401 Project Manager: Jai Kesari email: t.kesariffiwestonsol uti ons. com Project Name: Reference No: Decatur, Alabama 02181-129-081-0001 ANALYSES REQUESTED Sampler: E. Caldwell, B. McCanless 256-552-6189 P.O. U\ Quotation #: SAMPLE ANALYSIS E x y L I M S # Client Sample Identification 1 DLOJ SB 320L 0 0170 Collection Date 13-Jan-05 Collection Time 15:30 DLOI SB 320L 0290 13-Jan-05 16:10 OI9 o. co ZO Sample Matrix 1 SOIL SOIL Comments CHAIN OF CUSTODY Rei ing y is jje if y ^ Date dJ / '/ Cooler ID No.: Time Received By: Fed fEx b ft Cooler Temp. (cC): Date Time //*stT x l|fe fe * t>100 PROJECT REQUIREMENTS Results Deadline: Laboratory Report Options: Sample Results Only Add Case Narrative Add Quality Control Summary Add Calibration Summary Add Raw Data Other: CHAIN OF CUSTODY/ANALYSIS REQUEST FORM Q.Yb'S vi Severn Trent Laboratories 2417 Bond Street University Park, IL 60466 PAGE ^ of T: 708-534-5200 F: 708-534-5211 PROJECT INFORMATION Client: Weston Solutions, Inc. 1400 Weston Way, Bldg. 5-2 West Chester, PA 19380 T: 610-701-3761 F: 610-701 -7401 Project Manager: Jai Kesari email: i.kesari weston solution s.com Project Name: Reference No: Decatur, Aiabama 02181-129-081-0001 ANALYSES REQUESTED Sampler: E. Caldwell, B. McCanless 256-552-6189 P.O. #: Quotation #: SAMPLE ANALYSIS ExyLIMS # 3 Client Sample Identification DLOI SB 117L 0 0000 DLOI SB 117L 0 0005 DLOI SB 117L 0 0020 Collection Date 13-Jan-05 13-Jan-05 13-Jan-05 Collection Tim e 7:35 7:45 7:55 o Q. WEM <*&* oEL 1 e O E Oo X X X 1 1 1 No. of Containers Sam ple M atrix SOIL SOIL SOIL t> DLOI SB 117L 2 0050 13-Jan-05 10:25 X 1 SOIL '1 DLOJ SB 117L 0 0290 13-Jan-G5 12:10 X 1 SOIL r DLOI SB 320L 0 0000 13-Jan-05 13:40 X 1 SOIL 1 DLOI SB 320L 0 0005 13-Jan-05 13:45 X 1 SOIL ro DLOI SB 320L 0 0020 13-Jan-05 13:50 X 1 SOIL r; DLOI SB 320L 0 0050 13-Jan-05 14:35 X 1 SOIL CHAIN OF CUSTODY Cooler ID No.: Re 1tngjj i^Fd^Pi: Pat? I Time / / / i r /oO // Received By: Fed Ex VJr i Cooler Temp. (C): Date Time Ad O O^OQ Comments o O 1X X X X X X X X Ix PROJECT REQUIREMENTS Results Deadline: Laboratory Report Options: Sample Results Only Add Case Narrative Add Quality Control Summary Add Calibration Summary Add Raw Data Other: Sample Lot#:_ Sample No. Analysis STL Chicago Internal Sample Custody Transfer Record Client: VJ ^ Relinquished by: Received by: Date _ __ . x d r * y * - C T ?i I-- ! Time Comments ^\rCy CHI-22>11-001/C-1/99 rpjsckl Job Sample Receipt Checklist Report Job Number.: 233507 Location.: 57222 Check List Number.: 1 Description.: Customer Job ID.... : Job Check List Date.: 01/15/2005 Project Number.: 2QQQ4891 Project Description.: Confidential Decatur - FC Investigation Customer...... : ueston Solutions, Inc. Contact.: Jai Kesari Questions ? (Y/N) comments V2 Date of the Report.. : 01/20/2005 Project Manager.... : rew Chain-of-Custody Present?.......... ............. . Y Were samples dropped off at or picked up by STL?. . N Custody seal on shipping container?.............. . Y ...If "yes", custody seal intact?................ . Y Custody seals on sample containers?.... ......... . N ...]f "yes", custody seal intact?....... ........ - Samp Las iced?........................... . Y Temperature of cooler acceptable? (4 deg C +/* 2; . Y 3.1 SampLes received intact (good condition)?..... . . Y VoLatile samples acceptable? (no headspace)...... Correct containers used?.... .................... . r Adequate sample voLurie provided?................. . Y Samples preserved correctly?.................. . , Y Samples received within holding-time?.......... . Y Agreement between COC and sampLe labels?....... . Y Radioactivity at or be Lou background levels?___ . Y A Sample Discrepancy Report (SDR) was needed?... . N If samples were shipped uas there an air bill #? . Y Sample custodian Signature/Date....... ......... . Y Page 1 . USAirbill 4 4 4 0Express fi Sb flSTrFottKix M n te f From , e rOrta :r ^ - G ir r /A ^ r, SCtfldW^S Nb w -- / / / } fI 'L L f . s A-J t t Phone -A--<--- ---<--<-%-----C--/-&--7- Company n s~r ? AJy > l L f O A.- i/ a j C _ --------------------- if s-\/h ^ r Addree / y > c - 5 rr > r r J X c -.'> R / > ' 4a Express Package Servie ^F eVdiEfcKtMPinrwwi.rrtaYn!lOnfvernight fl--~J] rFffeldaEtoxrSatsajnftdinaruduO^w m iflht PmektggsatsiS. *Ti twUcato -p--7IBFiliadi[ylBnnetwU^fwiIScMlwteinmrrfwinlfhi*ar1 I-- 1Seoorribuw fed&r Express Saver T M t H tvA r* . --- FrifaBEWiiWneHmnainagnanB>nt>ftaf.aM.iMkwriBii.Oimnnini---- '1 o a a iH f DLJ SFwerilfExu2sDiB*y*f*rm"^gtit M bv M" fcwwilHhtIutme) r1--~ IPFuldit6oi3n0ia^yffa i|jf Cto /S 7 _tr- 2 w M e n t B illin g R etaron^ 3 To .5 2Recipienti Kme -y-.,_________ Stata _ ZIP 7 2 7 S t I " / ?' ^ ^ ZX. i V H S Phone "> 2 1 'r i V V2- G *D K H (itnfc.hii Fetf&cPak* G fs d b Q fd&c S fo ifc y r ' uh^tWElw*3ftdEikn1E.o,rFfiyftc.iurtTrtk "Sox . Tfuubl*e /' V^ . ~ 6 Special HamUiog MalaFdExaUmiin6Kda3. i - tMQfmwfUntijehtoitiunitoW'HMr&ihu.SfttSftrMi Company ^L *= tr fr ARdedcirpeiessnts latuTM:lliwtPO.taewf',D-Ilrd*#t f -Jti L a /K XA --r* - r - r j^ s s s s s s s r ^ * ^ _ dfJitOS fItiPJ \ Vn - i *.tv> tllW G1-- I YEetrsa'iDttfcnt agaukpKMHa DrvtM.lmtb* Ap*l'Fi4&pKtafH' .`r--~i1OaTrBUyai..aca.er.4niK. Q Cae^o A ircraft Only Pa1vono! Sr1it--e --- B*fha&te.ittrCiwifc.**w, Address L L ^ / 7 - L > < > * * * - y* Tq5*t^irtBobe*u*tjpKtitFed&btni*vp*heb totas*hu*. Cty J t / s < { Y- / LStasa zip V6^ *HQurttre.fria1ttJior*intytiGf>.Y.F*itrIrt.6u/KloSMEf3.Wl-en13h3I3SMi-t.!enaa.trMrtej:s-tmointOHqSA Ma*.* ** CASE NARRATIVE Client; Job #: STL Chicago Wet Chemistry Case Narrative Weston Solutions, Inc. 233507 Date Rac'd; 01/15/05 1. This narrative covers the analysis o f the samples in the above Job # for TOC by the Lloyd Kahn Method. The samples were analyzed for TOC in duplicate by furnace combustion and nondispersive infrared detection on a Dohrmann Phoenix 8000 TOC analyzer, after acidification to remove inorganic carbon, and drying. No correction was made, therefore, for moisture content. The average of the sample bums is reported, 2. The method-recommended holding time o f 2 weeks was met. Refer to the Laboratory Chronicle Page for dates of sampling, receipt, and analysis. 3. The TOC calibration curve and the initial and continuing verification standards and blanks met acceptance criteria. 4. The method blanks were less than the reporting limit. 5. The LCSs were within acceptance limits. 6. The matrix QC done on sample 233507-5 was within acceptance limits. Diane L. Harper ^ Wet Chemistry Section Manager STL Chicago Date 20 RAW DATA UC TOCS *** RUN LOG *** ) 1/26/05 16:19 Total Organic Carbon (Soils) Method Code..: TOCS Batch Code...: 140367 Status :RVWD Batch Date,,.: 01/26/05 Batch Time.,.: 1519 User Name.*., ; cls QC Code......... :TOCS Cale Code....... :TOCS Location Code,.: 57222 Equipment Code.: T0C4 Import Code---- : TEST CODE TTTTTTTTTTTTT 0OOO000CCC III Cc CCCcCSSSCCC 23 4AAA 2A SSS VVV V 2A 234 2 2 SAMPLE: Grp Pos Sample IP 11 ___ I C A L J 0 5 A S T C 1 _ 12 ,___ICV_IQ4LSTTC2_ 13 ___M B _ 14 ___ L C S J 0 0 F S T L K 3 _ 3 15 ___ L C D J 0 F S T L K 3 . 3 16 233598_1_S___ 17 233598_1_S_MS_I04LSTTC2_6 18 233598J_SJISDJ04LSTTC2_6 19 233598_2,,S_ 1 10 233598_3_S___ 1n 233469J _S, 1 12 233469_2_S___ 1 13 233469m3_S___ 1 14 233469_4_S___ 1 15 233469_5_S___ 1 16 ___CCV_I04LSTTC2_ 1 17 CCB 1 18 233469_6_S___ 1 19 2 3 3 4 6 9 ^ 3 ___ 1 20 233469.8^3___ 1 21 233469_9_S___ 1 22 23357_1_S___ 1 23 233507_2_S___ 1 24 2335Q7_4_S___ 1 25 2335Q7_3_S___ Di Lution TEST POS Date / T i m e 12 3 4 567 111222 78 9 0 12 0 1/25/05 0840 0 1/25/05 0854 0 1/25/05 0913 0 1/25/05 0937 0 1/25/05 0945 0 1/25/05 1004 N 1/25/05 1013 0 1/25/05 1023 0 1/25/05 1037 0 1/25/05 1052 0 1/25/05 1131 0 1/25/05 1151 0 1/25/05 1215 0 1/25/05 1229 0 1/25/05 1244 0 1/25/05 1249 0 1/25/05 1340 0 1/25/05 1356 1/25/05 1414 0 0 1/25/05 1435 0 1/25/05 1452 0 1/25/05 1513 0 1/25/05 1527 0 1/25/05 1543 0 1 26 1 27 ___ CCV_I04LSTTC2_ ___C C B _ 1/25/05 1558 0 1/25/05 1601 0 *** QC Summary *#* CV2 ) Total Organic Carbon (Soils) Method Code..: TOCS Batch Code...: 140367 Status....,..: RVWD Batch Date...: 01/26/05 Batch Time...: 1519 User Name....: els QC Code........ : TOCS Calc Code......; TOCS Location code..: 57222 Grp Smp Sample ID Pos Test Result Known Original 1 2 ___ICV_I04LSTTC2_ 1 TOC 2011.97 2000 1 3 ___MB__ 1 TOC -2.78 1 4 ___LCS_I00FSTLK3_3 1 TOC 4964.74 4780 -2.78 15 17 ___L C DJ 00 FS TL K3 J 233598_1_S_MS_l04l_STTC2_6 1 TOC 4147.31 5 T0CAV2 5555.9B 4780 2000 -2.78 2601.46 1 B 233598J_SJ1SDJ04LSTTC2,,0 1 16 ___CCVJ04LSTTC2_ 1 17 ___CCB__ 5 T0CAV2 4993.39 1 TOC 1996.35 1 TOC 4.48 2000 2000 2601.46 1 26 ___CCl/_I04LSTTC2_ 1 TOC 1969.76 2000 1 27 ___CCB__ 1 TOC -3.45 Report Date: 1/26/05 16;19 Equipment Code.: T0C4 Import Code,,..: Alternate QC Res 101 F QC Res F 4964.74 5555.98 104 87 149 112 100 18 N 21 98 STL Chicago Page 1 21 *** RAW TEST DATA *** V2 ) Total Organic Carboh (Soils) Method code.. : TOCS Batch Code... : 140367 status...... : RVWD Batch Date... : 01/26/05 Batch Time,.. ; 1519 User Name,... : els SAMPLE: Grp Pos Sample ID 11 ICAL I05ASTTC1 12 ICV I04LSTTC2 13 MB 14 LCS IQFSTLK3 3 15 LCD I00FSTLK3 3 1 233598 1 S 17 233598 1 S MS I04LSTTC2 6 18 233598 1 S MSD I04LSTTC2 6 19 233598 2 s 1 10 233598 3 S 1 11 233 4 6 9 1 S 1 12 233469 2 S 1 13 233469 3 S 1 14 2 3 3 4 6 9 4 S 1 15 2 3 3 4 6 9 5 S 1 16 CCV IQ4LSTTC2 1 17 CCS 1 18 233469 6 S 1 19 233469 7 S 1 20 2334 6 9 8 S 1 21 2 3 3 4 6 9 9 S 1 22 233507 1 S 1 23 233507 2 S 1 24 233507 4 S 1 25 233507 3 S 1 26 CCV I04LSTTC2 1 27 CCB QC code... ____: TOCS CaLc Code. ____: TOCS Location Code..: 57222 Di Lut ion TOC mg/Kg OC2 mg/Kg Report Date: 1/26/05 16:19 Equipment code.: TOC4 import code....: TOC3 mg/Kg TC4 mg/Kg TQCAV2 mg/Kg 2011.97 -2.78 4964.74 4147.31 2114.77 5555.98 4993.39 1269.51 126.84 976.29 6420.08 628.14 13292.33 1633.22 1996.35 -4.48 7857.95 6437.41 644.72 11849.23 1877.12 393.78 2905.22 18066.78 1969.76 -3.45 3088.15 1362.27 209.87 809.23 7265.24 940.78 12441.23 1762.20 8337.32 5571.70 905.71 10287.26 1319.29 458.20 3613.01 13592.99 2601.46 5555.98 4993.39 1315.89 168.35 892.76 6842.66 784.46 12866.78 1697.71 8097.64 6004.56 775.22 11068.24 1598.20 425.99 3259.11 15829.88 STL Chicago Page 1 24 *** RAW TEST DATA *** (V2 ) Total Organic Carbon (Soi le) Method Code..: TOCS Batch Coderil.: 140367 Status.-.---- : RWID Botch Date... 01/26/05 Batch Time..., 1519 User Hanne___ ,: els SAMPLE: Grp Pos SampLe ID 11 ICAL I05ASTTC1 12 ICV I04LSTTC2 13 MB ^ 14 LCS I00FSTLK3 3 15 LCD IOOFSTLK3 3 1 6 233598 1 S 17 1a 2335VS 1 S MS I04LSTTC2 6 233598 1 S MSD I04LSTTC2 6 1 9 233598 2 S 1 10 233598 3 S 1 11 233469 1 S 1 12 233469 2 S 1 13 233469 3 S 1 14 233469 4 S 1 15 233469 5 S 1 16 CCV I04LSTTC2 1 17 CCB 1 18 233469 6 S 1 19 233469 7 S 1 20 233469 8 S 1 21 233469 9 S 1 22 233507 1 S 1 23 233507 2 S 1 24 233507 4 S 1 25 233507 3 S 1 26 CCV I04LSTTC2 1 27 CCB OC Code....... : TOCS Cale Code..... : TOCS Location Code.. : 57222 Dilution DCAV3 mg/Kg TOCAV4 mg/Kg Report Date: 1/26/05 16:19 Equipment code.: T0C4 Import Code..,: TODR1 ug T0CR2 ug TQCR3 ug 100.5983 -0.4453 160.8576 114.0509 73.1709 280.5770 233.6905 72.2352 9.6777 68.0471 176.5521 34.0451 59.8155 43.1171 99.8174 -0.7162 227.8806 198.9161 25.0151 122.0471 76.9618 37.2121 98.4869 359.5289 98.4878 -0.5523 127.2319 94.8142 20.8819 52.1142 215.0512 5Q.78 70.9150 52.8659 246.7846 163.8081 60.4107 144.0216 69.5268 44.8119 125.3715 183.5053 STL Chicago Page 2 25 *** RAW TEST DATA *** (V2 ) Total Organic Carbon (Soils) Method Code TOCS Batch coda. ..: 140367 Status.... ..: RVWD Batch Date...; 01/26/05 Batch Time....: 1519 User Name___ .: els SAMPLE: Grp Pos Sample id l1 ICAL I05ASTTC1 l2 ICV I04LSTTC2 13 MB 14 LCS I00FSTLK3 3 15 LCD I00FSTLK3 3 1 6 23359B 1 S 1 7 233598 1 S MS I04LSTTC2 6 1 8 233598 1 S MSD IQ4LSTTC2 6 1 9 233598 2 S 1 10 233598 3 S 1 11 233469 1 S 1 12 233469 2 S 1 13 233469 3 S l 14 233469 4 S 1 15 233469 5 S 1 16 CCV I04LSTTC2 1 17 CCB 1 18 233469 6 S 1 19 233469 7 S 1 20 233469 8 S 1 21 233469 9 S 1 22 233507 1 S 1 23 233507 2 S 1 24 233507 4 S 1 25 233507 3 S 1 26 CCV I04LSTTC2 1 27 CCB QC Code....... : TOCS calc code..... : TOCS Location code..: 57222 Dilution TGCR4 ug WT1 9 Report Date: 1/26/05 16:19 Equipment code.: TOCA Import Code___ : WT2 WT3 gas WT4 0.05 0.16 0.0324 0.0275 0.0346 0.0505 0.0468 0.0569 0.0763 0.0697 0.0275 0.0542 0.0045 0.0264 0.05 0.16 0.0290 0.0309 0.0388 0.0103 0.0410 0.0945 0.0339 0.0199 0.05 0.16 0.0412 0.0696 0.0995 0.0644 0.0296 0.0539 0.0057 0.0300 0.0296 0.0294 0.0667 0.0140 0.0527 0.0978 0.0347 0.0135 STL Chicago Page 3 26 *** raw test data *** TotaL Organic Carbon (Soils) Method Code..: TOCS Batch Code,,,: 140367 Status...___ : RVWD Batch Dato...: 01/26/05 Batch Timeh-.: 1519 User Marne___ : els SAMPLE Grp Poe SampLe ID 1 1 ___ IC A L _ I 0 5 A S T T C 1 _ 12 ___ ICV _ I 0 4 L S T T C 2 _ 13 MB 14 ___ L C S _ I Q 0 F S T L K 3 _ 3 15 ,___ L C D _ I 0 0 F S L K 3 _ 3 16 2 3 3 5 9 B _ 1 _ 5 ___ 17 23359B 1 S MS I04LSTTC2 6 10 233598" i ""s " m SD I4LSTTC2 6 19 233 598^2V ' 1 10 233598_3_S___ 1 11 2 3 3 4 6 9 _ 1 _ S ___ 1 12 233 4 6 9 2 S___ 1 13 2 3 3 4 6 9 ~ 3 ~ S ___ 1 14 2 3 3 4 6 9 _ 4 _ S ___ 1 15 233 4 6 9 5 _ S _ 1 16 ___ C C V J 0 4 L S T T C 2 _ 1 17 CCB 1 18 233 4 6 9 6 S _ _ 1 19 2 3 3 4 6 9 " 7" s___ 1 20 2 3 3 4 6 9 _ S _ S ___ 1 21 233 4 6 9 9 S,___, 1 22 2 3 3 5 0 7 " l" s___ 1 23 2 3 3 5 0 7 ^ 2 " s ___ 1 24 2 3 3 5 0 7 _ 4 _ S ___ 1 25 2 3 3 5 0 7 _ 3 S _ 1 26 ___ C C V _ I 0 4 L S T T C 2 _ 1 27 CCB QC Code....... TOCS CaLc Code........... TOCS Location Code.. 57222 Dilution DLFAC N/A TCS mg/Kg 3.2000 1.0000 4.93S3 5.8182 4.2216 3.1683 3.4188 2.5296 1.8203 2.3863 5.6042 2.9602 31.3725 5.6738 3.2000 1.0000 5.4608 5.3068 3.0332 13.1687 3.4152 1.6641 4.6647 9.5808 3.2000 1.0000 CV2 ) Report Dete; 1/26/05 16:19 Equipment Code.: TOC4 Import Code___ : TCS2 mg/Kg TCSAV2 mg/Kg TICS mg/Kg STL Cliicago Page 4 27 Calibration Report Print Date/Time: 2005/01/25 8:29:32 Cal. Curve ID: SOILCURVE Created: 01/17/2005 11:33 Calibration Factor (m): 8.538e+Q4 Y Intercept (b): 436425 r-squared: 0,99800 Standard ID Y X Expected Measured Message Date & Raw Data ug C ug C Time 0 ugram C -4530 0.000 "5. 165 No Sample Det 01/17/2005 09:53 10ugramC 1085240 10.000 7.599 01/17/2005 10:15 20 ugram C 1870210 20.000 16J94 01/17/2005 10:26 40 ugram C 3806480 40.000 39.473 01/17/2005 10:34 80 ugram C 7357282 80.000 81.062 01/17/2005 10:45 120 ugram C 11114689 120.000 125.072 01/17/200510:58 200 ugram C 18428840 200.000 210.740 01/17/2005 11:07 300 ugram C 26478564 300.000 305.025 01/17/200511:15 400 ugram C 33682344 400.000 389.401 01/17/200511:32 STL Chicago 28 Multiple Analysis Report Print Date/Time: 2005/01/26 7:19:09 Sample ID Result S td Dev. RSD Mode ALT ICV 100.5983 TC ICB-MB -0.4453 TC LCS 160.8576 TC LCD....................... .......... 114.0509.............. ...TC . 233596-1 73.1709 TC 233598-1 127.2319 TC 233598-1 ms......... ................ 280.5770... ........... TC 233598-1 ms 233.6905 TC 233698-2 72.2352 TC 233598-2.............. ............. 94.8142... ........... TC 233598-2 9.6777 TC 233598-3 20.8819 TC 233469-1.............. ............. 66.0471... ........... TC 233469-1 52,1142 TC 233469-2 489.3237 TC 233469-2.............. ............. 176.5521... ........... TC 233469-2 215.0512 TC 233469-3 34.0451 TC 233469-3.............. .......... . 50.7080... ........... TC 233469-4 59.8155 TC 233469-4 70.9150 TC 233469-5.............. ............. 43.1171... ........... TC 233469-5 ccv 52.8659 99,8174 TC TC CCB....................... ...........-0.7162............... ...TC ,, 233469-6 227.8806 TC 233469-6 246.7846 TC 233469-7.............. ............. 198,9161... ........... TC 233469-7 163.8081 TC 233469-8 25.0151 TC 233469*8.............. ............. 60.4107... ........... T C 233469-9 122.0471 TC 233469-9 144.0216 TC 233507-1.............. ............. 76.9618... ........... TC 233507-1 69.5268 TC 233507-2 37.2121 TC 233507-2.............. ............. 44,8119... ........... TC 233507-3 98.4869 TC 233507-3 125.3715 TC 233507-3.............. ............. 359,5289... ........... TC 233507-3 183.5053 TC CCV 98.4878 TC CCB....................... .....,..,,-0.5523.............. .,,TC .. STL Chicago Detailed Analysis Report Print Date/Time: 2005/01/26 7:19:20 Sample ID: ICV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 01250835 Timestamp: 01/25/200^08:40 Sample Type: Cal. Verificathm--- Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 100.5983 100.5983 9025227 2.213 3.212 269 Sample ID: ICB-MB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 01250846 Timestamp: 1/25/200; Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 -0.4453 -0.4453 -12252 2.333 2.212 120 Last Message: No Sample Detected Sample ID: LCS Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 01250908 ^ Timestamp: 01/25/2005 09:13 Sample Type: Sample R e p # ppm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 160.8576 160.8576 13759332 2.674 3.672 265 Sample ID: LCD Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 01250932 > Timestamp: 01/25/2005 09:37 Sample Type: Sample V__ / Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 114.0509 114.0509 9763112 2.212 3.209 269 Sample ID: 233598-1 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL X Mode: TC F(lfc<jame: 01250940 Xjmestamp: 01/25/20 Samp|e Type: Sample Rep # ppm C ug C Raw Data B e g in n in g Ending Integration Baseline Baseline Time STL Chicago 1 59.8155 59.8155 5132640 1.984 2.983 241 Sample ID: 23\469~4 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL^ Mode: TC Filename: 01251217 Timestamp: 01/25/2005 12:22 Sample Type: Sample R e p # ppm C u g C \R a w D a ta Beginning Ending Integration seline Baseline Time 1 70.9150 70.9150 6080288 2.145 3.145 255 Sample ID: 233469-5 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 01251224 A Timestamp: 01/25/2005^2:29 tmple Type: Sample -_ '> ! R e p # ppm C u g C Raw Data Beginning Ending Integration Baseline Baseline^ Time 1 43.1171 43.1171 3706978 2.253 \ 3.252 229 Sample ID: 233469-5 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 0125123C Timestamp: 01/25/2005 12:36 Sample Type: Samp! Rep # ppm C ug C Raw Data Beginning Ending itegration Baseline Baseline Time 1 52.8659 52.8659 4539306 2.436 3.431 230 Sample ID: CCV Method: boat C a l Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 01251238 Timestamp: 01/25/2006 12:44 Sample Type: Cal. Verification Rep # ppm Q ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 99.8174 99.8174 8958549 1.985 2.984 316 Sample ID: CCB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC _____ Filename: 01251245 s' Timestamp: 01/25/2005 12:49 Sample Type: Sample \ Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 -0.7162 -0.7162 -35378 2.571 2.216 120 y u > a *.\-.r- . ^/V/" /j STL Chicago 1 25.0151 25.0151 2161483 2.611 3.606 193 Sample ID: 23346^-8 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 01251420 Timestamp: 01/25/2005 14:24 Sample Type; Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 60.4107 60.4107 5183456 2.498 3.495 236 Sample ID: 233469-9 Method; boat Cal. Curve: SOILCURVE Operator ID: CAROL lode: TC Filerifcme: 01251430 ^mestamp: 01/25/200^14:35 Sample Type; Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline \ T `me 1 122.0471 122.0471 10445806 1.879 \2 .8 7 5 268 Sample ID; 233469-9 Method; boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 01251439 Timestamp: 0 1 /2 5 /2 ^ 5 14:46 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 144.0210 144.0216 12321925 1.971 2.970 322 Sample ID: 233507-1 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 01251446 Timestamp: 01/25/2005 14:52 Sample Type: Sample R e p # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 76.9618 76.9618 6596549 2.310 3.310 246 Sample ID: 233507-1 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 01251454 Timestamp: 01/25/200514:59 Sample Type: Sample R e p # p p m C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 69.5268 69.5268 5961764 2.454 3.454 264 STL Chicago rtnr-K-i Sample ID: 233507-2 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 01251508 Timestamp: 01/25/20^5 15:13] Sample Type: Sample [ J Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 37.2121 37.2121 3202830 1.850 2.850 237 Sample ID: 233507-2 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 01251516 Timestamp: 01/25/2005 15:21 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 44.8119 44.8119 3851676 2.033 3.032 269 4 Sample ID: 233507-fe 4 ( / Method: boat 4 [V- Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 01251522 Timestamp: 01/25/200515:2/ Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 98.4869 98.4869 8434295 2.800 3.796 245 Sample ID: 2 3 3 5 0 7 -\ ^ Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 01251528 Timestamp: 01/25/200515:33 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 125.3715 125.3715 10729628 2,595 3.591 252 Sample ID: 233507-3 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 01251537 Timestamp: 01/25/2005 15:43 Sample Type: Sample V Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 359.5289 359.5289 30721326 2.613 3.607 302 STL Chicago 33 Sample ID: 233507-3 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 01251543 Timestamp: 01/25/200515:50 Sample Type: Sample R e p # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 183.5053 183.5053 15692925 2.707 3.706 284 Sample ID: CCV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 01251552 ....------ f' j A Timestamp: 01/25/2005^1 Sample Type: Cal. Verification^ R e p # ppm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 98.4878 98.4878 8845034 2.123 3.122 327 Sample ID: CCB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 01251559 Timestamp: 01/25/200! Sample Type: Sample 16:01 "A R e p # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 -0.5523 -0.5523 -21385 2.519 2.239 120 Last Message: No Sample Detected STL Chicago STL Chicago TOC in Soils Pag Nq.;_ 128 Book No.: 1T7t 7 Method: Lloyd Kahn Instrument Phoenix BQ00 (TOC41 LabNetBatch: /V 3 Cl Calculation: TOC (mg/kg) = ug C / grama sample Date of Standard Curvi / / /7/ jT~ : Book # 3 77 7 Page # / - - / MS, MSD Known Cone, (mg/kg) 100 ug C / grams simple MS. MSD Observed (mg/kg) ugC/grama sample MS, MSD Rc. Tobaarved mg/kg - ava. mol raault (rnq/ko)l x 100 known concentration in mg/kg standard Traceability. (Note: Working Standard* are pre noted Stock Solutions.) Stock 1(Curve) 'P S A S r f j . Stock tl (ICWCCV) 7 T C ,^ - LS Source ID t& ify LCSTnie Value jL j7/> Acceptance Range. ^3 S a m p le ID: Sam ple W eight (g) 7 (1 1 /... , . M /c e ^ n .. C om m ents: .....r t- '4 4 : / r T 0 ;O 'b X l : ili! A l j : 0 < n J. 5 r / 'f f / 0 , 0 . 3 9 0 ' 7 3 - n o r \--6oi,</C : -/ (7 o y / ? ; A <>. o ...o 3~ o r v f ifP iJ S , / 3 3 t?o -A w CL : y w jw * . 7V u m .r j- 77.23 2 ...- . - 2 - (J^O C e fQ 7 y - 0 / 7 "2-- - -3 4 /' - \ a , o ik 's o * ? ?r' 7. OG ? 7 9 :0 :0 7 70 Y .0 H 7 /- .... - . - , .. r - J il` . O Y V ^ < 7 : H 9 ? U. 7 X * '' t------- - T H r ? ? * ' ----i.*. (+- *?. ^ ... ... - r - a r : -e> o ( r . 9v /7 <"V ? - 3.Yr 0V r / . <*$7 Yj.0$O . ,~ ' 7 7 TM & ^ 0 0 - ' t < r /. M r & f 'i 0 3 l;ftS r 70, Vrts .. {?)-. ? Q-4 7 ... 7 3 . / / ' 7 / i Prep Analyst:, Analyst; Reviewed Y |. f/jl/K n Date: if3Lff Y ^ 3 '^ '' 1 Date: //$ < " / Dale: I(SLj{y 1 STL Chicago 35 bNo.;, 128 .Un- 8 7 Y7 fitPhoenix6000 (TOC4) :Batch: /V 3 I Curva; f //?W/# T 7 P a g a # / -) he noted Stock Solutions-) S L -_ ,, 5#- /73 Commenta: ' o i.V C 1 ? i/i6 ,X > \ t f f - O ] i\ar%,70 h m . STL Chicago TOC in Soils Page No. 129 Method: Lloyd Kahn Book No. Instrument; Phoenix flnr Calculation*; LabNer Batch: Data of Standard Curve: / Y&} ///? / & * '/ . TOC(mg/kg) ug C / grams sample Book# 'Y l h l Paoa# /H-j MS, MSD Known Cone, (mg/kg) 100 ug C / grami sample MS, MSD Observed (mg/kg) = ug C / grams sample MS, MSD Ree. * fobserved mo/ko - ava, semole result fmq/kall x 10Q known concentration in mg/kg 3t.flPdflrd Tfgcei hllltyi (Not; Working Standards are prepared daily from the noted Stock Solutions ) SSttoocckk II((CCuurrvvee))________ Stock II (ICV/CCV) LCS Source ID /u fo *' q ^ / i r n : f f ' /iif -- / / p r /rft- CHI-23-12-09WB-QWQ1 Pf9pAna(yfc_ Analyst C. Reviewed by: ,/ . Date:_/ / & / O ^ y CHF-S3-12^S/B-(I3/0f STL Chicago *** RUN LOG ### L 1DO ) 1/28/Q5 10:01 Total Organic Carbon (Soils) Method Code.,,: TOCS Batch Code.r,,: 140487 Status.... . : RPT Batch Date.. : 01/27/05 Batch Time., : 152B User Name___ ..: els QC Code..... TOCS Cole Code___ TOCS Location Code.. 57222 Equipment Code. T0C3 Import Code___ TEST CODE TT TTTTTTTTTTT 0DOG0cCC 11I CC CCCccSSsCCC 234AAA 2A SsS VVV V 2A 234 2 2 SAMPLE: Grp Pos Sample It> D i lution TEST POS Date / Time 12 34 56 7 1 1 122 2 7e90 12 11 ___ICAL_I05ASTTC1_ 0 12 1CV I04L5TTC2 1/27/05 0800 0 13 ___MB__ 1/27/05 0807 0 14 ___LCSJOOFSTLKS_3 1/27/05 0B39 0 15 ___ LCD_IOOFSTLK3_3 1/27/05 0845 0 16 233507_5_S___ 1/27/05 0852 0 11 233507_5_S_MS_I04LSTTC2_6 1/27/05 0917 0 18 233507_5_S_MSDJ04LSTTC2_6 1/27/05 0929 0 19 233507 6 S___ 1/27/05 0937 0 1 10 2 3 3 5 0 7 _ 7 _ S _ 1/27/05 0953 0 1 11 233507 8 S 1/27/05 1017 0 1 12 2335Q7_9_S___ 1/27/05 1034 0 1 13 233507_10_S___ 1/27/05 1100 0 1 14 233507_11_S___ 1/27/05 1131 0 1 15 ___CCV_I04LSTTC2_ 1/27/05 1149 0 1 16 ___CCB__ 1/27/05 1214 0 1 17 233629m 1i_S___ 1/27/05 1405 0 1 18 233629_2_S___ 1/27/05 1423 0 1 19 233629_3_S___ 1/27/05 1439 0 1 20 233629_4_S___ 1/27/05 1451 0 1 21 233629_5_S___ 1/27/05 1510 0 1 22 1 23 ___ CCV_I04LSTTC2_ ___ CCB__ 1/27/05 1523 0 1/27/05 1527 0 STL Chicago 37 *** QC Summary <V2 ) Total Organic Carbon (Soils) Method Code..: TOCS Batch Code...: 140487 Status..... RPT Batch Date.. .: 01/27/05 Batch Time.. .: 1528 User Name... .: els QC code....... TOCS Calc Code.... *. TOCS Location code.. 57222 Grp Smp Sample ID Pos Test RcsuLt Known Origihal 1 2 ___ICV_I04LSTTC2_ 1 TOC 1928.56 2000 13 MB 1 TOC `2.33 1 4 ___LC5_l00F5TLlC3_3 1 TOC 4761.61 4780 -2.33 1 5 ,__ LCD_I00FSTLK3_3 1 TOC 4300.41 4780 2.33 1 7 233507_5_S_M$J04L5TTC2^6 5 TOCAV2 2142.12 2000 906.24 1 8 233507_5_S_MSD_J04LSTTC2_6 5 TCAV2 2242.53 2000 906.24 1 15 ,__ CCVJ04LSTTC2_ 1 TOC 2034.14 2000 1 16 ___CCB__ 1 TOC 1.98 1 22 CCV I04LSTTC2 1 TOC 2088.83 2000 1 23 ___CCB__ 1 TOC "2.90 Report Date: 1/28/05 10;01 Equipment code.: TOC3 Import Code___ : Alternate QC Res 96 F QC Res F 4761.61 2142.12 100 90 82 90 102 10 8 104 STL Chicago Page 1 38 *** RAW TEST DATA *** CV2 ) Total Organic Carbon (SoiLs) Method Code.. TOCS Batch Code... 140487 Status...... RP Rntoh flato... : 01/27/05 Batch Time...: 1523 User Name___ : els SAMPLE: Grp Pos Sample ID 11 ICAL I05ASTTC1 12 ICV I04LSTTC2 13 MB 14 LCS IOOFSTLK3 3 15 LCD I00FSTLK3 3 1 6 233507 5 S 1 7 233507 5 S MS I04LSTTC2 6 1 8 233507 5 S MSD I04LSTTC2 6 1 9 233507 6 S 1 10 233507 7 S 1 11 233507 S S 1 12 233507 9 S 1 13 2335Q7 10 S 1 14 233507 11 S 1 15 CCV 04LSTC2 1 16 CCS 1 17 233629 1 S 1 IB 233629 2 S 1 19 233629 3 S 1 20 233629 4 S 1 21 233629 5 S 1 22 CCV IQ4LSTTC2 1 23 CCB QC code... .... : TOCS Calc Code. .... : TOCS Location Code..; 57222 Di Lut ion TOC mg/ Kg T0C2 mg/Kg Report Date: 1/2S/05 10:01 Equipment Code.: TOC3 Import Code.... : T0C3 mg/Kg TOC4 mg/Kg TOCAV2 mg/Kg 1920.56 -2.33 4761.61 4300.41 928.65 2142.12 2242.53 404.15 423.10 27231.75 2003.66 1524.39 1123.08 2034.14 -1.98 12790.69 9670.66 2877.12 2427.88 815.33 2088.83 "2.90 BB3.82 289.32 363.79 26351.91 2510.29 1048.63 751.41 21624.69 6896.69 2295.93 1933.62 576.51 906.24 2142.12 2242.53 386.74 393.44 26791.B3 2696.97 1286.51 937.25 17207.69 8283.67 2586.53 2180.75 695.92 STL Chicago Page 1 39 *** RAW TEST DATA #** (V2 ) Total Organic Carbon (Soils) Method Code..: TOCS Batch Code...: 140487 Status. RPT Batch Date...: 01/27/05 Batch Timo.. .: 1528 User Name... .: els SAMPLE: Grp Pos Sample ID 11 12 13 14 15 16 17 ICAL I05ASTTC1 ICV I04LSTTC2 MB ICS I0QFSTLK3 3 LCD I00FSTLK3 3 233507 5 S 233507 5 S MS I04LSTC2 6 1 8 233507 5 S MSD I04LSTTC2 6 1 9 233507 6 S 1 10 233507 7 S 1 11 233507 8 S 1 12 233507 9 S 1 13 233507 10 S 1 14 233507 11 S 1 15 CCV I04LSTTC2 1 16 CCB 1 17 233629 1 S 1 18 233629 2 S 1 19 233629 3 S 1 20 233629 4 S 1 21 233629 5 S 1 22 CCV I4LSTTC2 1 23 CCB QC Code.... . : TGCS Calc Code..... : TOCS Location Code..: 57222 Dilution T0CAV3 mg/Kg TOCAV4 mg/Kg Report Date: 1/28/05 10-.01 Equipment Code.: TQC3 Inport Coda,... : TOCRI ug TOCRZ ug T0CR3 ug 96.4279 "0.3735 139.5152 139.3332 58.6906 141.5939 150.9224 40.4262 41.0404 313.1651 128.3230 44.6645 59.6358 101.7072 -0.3164 65.2325 85.1018 53.8022 75.2644 33.1839 104.4414 -0.4647 55.5039 24.7368 36.4885 292.5062 129.2797 40.4770 39.8247 175.1600 94.4846 73.6993 69.4171 37.0118 STL Chicago Page 2 4ft *** RAW TEST DATA *** (V2 ) Total Organic Carbon (Soils) Method Code..: TOCS Batch Code.,,.; 140487 Status...... : RPT Batch Date...: 01/27/05 Batch T ime...: 1528 User Name___ : els SAMPLE: Grp Pos Sample ID 11 ICAL I05ASTTC1 1Z ICV I4LSTTC2 13 MB 14 LCS ID0FSTLK3 3 15 LCD I00FSTLK3 3 1 6 233507 5 S 1 7 233507 5 S MS I04LSTTC2 6 1 8 233507 5 S M5D I04LSTC2 6 1 9 233507 6 S 1 10 233507 7 S 1 11 233507 6 S 1 12 233507 9 S 1 13 233507 10 S 1 14 233507 11 S 1 15 CCV I04LSTTCZ 1 16 CCB 1 17 233629 1 S 1 18 233629 2 S 1 19 233629 3 S 1 ZD 233629 4 S 1 21 233629 5 S 1 22 CCV I04LSTTC2 1 23 ___CCB__ QC Code... k; TOCS Calo Code. ___ : TOCS Location Code..: 57222 Dilution TQCR4 ug WT1 g Report Date: 1/28/05 10:01 Equipment Code.: T0C3 Import Code___ : WT2 WT3 UT4 ggg 0.05 0.16 0.0293 0.0324 0.0632 0.0661 0.0673 0.0835 0.0970 0.0115 0.0445 0.0293 0.0531 0.05 0.16 0.0051 0.0088 0.0187 0.0310 0.0407 0.05 0.16 0.0628 0.0855 0.1003 0,0111 0,0515 0.0386 0.0530 0.0081 0.0137 0.0321 0.0359 0,0642 STL Chicago Page 3 41 *** RAW TEST DATA <V2 ) Total Organic Carbon (Soils) Method Code,,: TOCS Batch Code...: 140487 Status...... : RPY Batch Date...: 01/27/05 Batch Time,,,: 1528 User Name,,,,: els SAMPLE: Grp Pos SompLe ID 11 ICAL I5ASTTC1 12 ICV I04LSTTC2 13 MB 14 LCS I00FSTLK3 3 15 LCD I0FSTLK3 3 1 6 233507 5 S 1 T 233507 5 S MS 104LSTTC2 6 1 0 233507 5 S MSD I04LSTTC2 6 1 9 233507 6 S 1 10 233507 7 S 1 11 233507 8 S 1 12 233507 9 S 1 13 233507 10 S 1 14 233507 11 S 1 15 CCV I04L5TTC2 1 16 CCB 1 17 233629 1 S 1 18 233629 2 S 1 19 233629 3 S 1 20 233629 4 S 1 21 233629 5 S 1 22 CCV I04LSTTC2 1 23 CCB QC Code..... . TOCS Calc Code......: TOCS Location Code..: 57222 Dilution DLFAC N/A TCS mg/Kg Report Date: 1/28/05 10:01 Equipment Code,: TOC3 Import Code____ : TCS2 mg/Kg TCSAV2 mg/Kg TICS mg/Kg 3.2000 1.0000 5.4608 4.9383 2.5397 2.4206 2,3774 1.8935 1.6219 14.1593 3.3333 4.7128 3.0160 3.2000 1.0000 24,2424 14.2222 6.2992 4.7833 3.0505 3.2000 1.0000 STL Chicago Pago 4 42 Multiple Analysis Report Print Date/Time: 2005/01/27 15:34:24 Sample ID Result Std, Dev. RSD Mode ALT ICV 96.4279 ICB-MB -0.3735 LCS 139.5152 LCD........................ .........139.3332.............. 233507-5 58.6906 233507-5 55.5039 TC TC TC ...TC TC TC 233607-5ms.......... ................141.5939... ........... TC 233507-5msd 150.9224 TC 233507-6 40.4262 233507-6............... ............ 247368... TC ........... TC 233507-7 41.0404 TC 233507-7 36.4885 233507-8............... ............ 1038.8387... TC ........... TC 233507-8 233507-8 313.1651 292,5062 TC TC 233507-9............... ............ 128.3230... 233507-9 129.2797 .. ,..TC TC 233507-10 44.6645 TC 233507-10............. ..............40.4770... ., ...TC 233507-11 233507-11 59.6358 39.8297 TC TC CCV....................... ..........101.7072... . ,,,TC . COB -0.3164 TC 233629-1 431.2907 TC 233629-1............... ............. 65.2325... ........... TC 233629-1 175.1600 TC 233629-2 85.1018 TC 233629-2.............. ............. 94.4846... ........... TC 233629-3 53.8022 TC 233629-3 73.6993 TC 233629-3.............. ............. 75.2644... ........... TC 233629-4 69,4171 TC 233629-5 33.1839 TC 233629-5.............. ............. 37.0118... ........... TC CCV 104.4414 TC CCB -0.4647 TC STL Chicago 43 Calibration Report Print Date/Time: 2005/01/27 7:40:56 Cal. Curve ID: SOILCURVE Created: 01/17/2005 11:33 Calibration Factor (m): 8.538e+04 Y Intercept (b): 436425 r-squared: 0.99800 Standard ID Y X Expected Measured Message Date & Raw Data ugC ugC Time 0 ugram C -4530 0.000 5,165 No Sample Det 01/17/2005 09:53 10ugramC 1085240 10.000 7.599 01/17/200510:15 20 ugram C 1870210 20.000 16.794 01/17/2005 10:26 40 ugram C 3806480 40.000 39.473 01/17/2005 10:34 80 ugram C 7357282 80.000 81.062 01/17/200510:45 120 ugram C 11114689 120.000 125.072 01/17/2005 10:58 200 ugram C 18428840 200.000 210.740 01/17/200511:07 300 ugram C 26478564 300.000 305.025 01/17/200511:15 400 ugram C 33682344 400.000 389.401 01/17/200511:32 STL Chicago Detailed Analysis Report Print Data/Time: 2005/01/27 15:34:29 Sample ID: ICV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 01270753 Timestamp; 01/27/2003^08:00 Sample Type: Cal. Verification Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 96.4279 96.4279 8669169 0.795 1.794 327 Sample ID: ICB-MB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 01270804 \ Timestamp. 01/27/200508:07. Sample Type: Sample / Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 -0.3735 -0.3735 -6120 1.073 0.986 120 Last Message: No Sample Detected Sample ID: LCS Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 01270834 Timestamp: 01/27/2005 Sample Type: Sample R e p # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 139.5152 139.5152 11937182 1.135 2.132 279 Sample ID: LCD Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 01270840 - Timestamp: 0l/27/20p5^8:45 Sample Type: Sample ( Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 139.3332 139.3332 11921644 1,692 2.690 261 Sample ID: 233507-5 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 01270847 Timestamp: 01/27/ Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time STL Chicago 45 1 58.6906 58.6906 5036605 1.920 2.916 234 Sample ID; 233507-5 Method; boat Cal. Curve; SOILCURVE Operator ID; CAROL Mode; TC Filename: 01270901 Timestamp: 01/27/2005 09:06 Sample Type: Sample R e p # ppm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 55.5039 55.5039 4764530 1.126 2.125 240 Sample ID: 233507-5ms Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 01270912 N Timestamp: 01^27/2005 0 9 :1 ^ Sample Type: Sample V _ _ . Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 141.5939 141.5939 12114654 7.250 8.244 232 Sample ID: 233507-5msd Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 01270924 Timestamp: 01/27/2 Sample Type: Sample R e p # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 150.9224 150.9224 12911097 5.322 6.319 233 Sample ID: 233507-6 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC _ Filename: 01270932 Timestamp: 01/27/2005 09:37 Sample Type: Sample / y Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 40.4262 40.4262 3477243 1.660 2.656 232 Sample ID: 233507-6 Method: boat Cal, Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 01270940 Timestamp: 01/27/2005 09:44 Sample Type: Sample Rep# ppmC u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 24.7368 24.7368 2137723 1.198 2.197 217 STL Chicago 46 Sample ID: 233507-7 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC _____ _ Filename: 01270946 ,...) Timestamp: 01/27/2005 09:55K, Sample Type: Sample v_ Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 41.0404 41.0404 3529678 1.490 2.489 243 Sample ID: 233507-7 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 01270954 Timestamp: 01/27/2005 09:58 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 36.4885 36.4885 3141054 1.669 2.668 227 Sample ID: \233507-8 Method: boat Cal. Curve: SQJLCURVE Operator ID: CAF^OL Mode: TC Filename: 01271003 Timestamp: 01/27/2005 10:11 Sample Type: Sample Rep # ppm C ug C l^aw Data Beginning Ending \ Baseline Baseline Time 1 1038.8387 1038.8387 88718888 1.674 2.673 Integration 438 Last Message: Over-range Sample ID: 233507-8 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC ^ Filename: 01271012 ^ Timestamp: 01/27/2005 10:17 Sample Type: Sample ( / Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 313.1651 313.1651 26762916 2.436 3.431 291 Sample ID: 233507-8 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 01271018 Timestamp: 01/27/200510:24 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time STL Chicago 1 292.5062 292.5062 24999120 2,207 3.207 297 Sample ID: 233507-9 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 01271028 Timestamp: 01 Z27/2' Sample Type: Sample 610:34 R e p # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 128.3230 128.3230 10981620 1.694 2.694 287 Sample ID: 233507-9 Method: boat 1037 CaL Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 0127 Timestamp: 01/27/200510:42 Sample Type: Sample R e p # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 129.2797 129.2797 11063303 3.260 4.256 259 Sample ID: 233507-10 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 01271056 f Timestamp: 01/27/2005 11:00 Sample Type: Sample [ / R e p # ppm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 44.6645 44.6645 3839090 1.504 2 502 232 Sample ID: 233507-10 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 01271116 Timestamp: 01/27/2005 11:20 Sample Type: Sample R e p # ppm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 40.4770 40,4770 3481580 1.568 2.565 220 Sample ID: 233507-11 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 01271126 Timestamp: 01/27/2005 11:31 Sample Type: Sample ( Rep# ppmC ugC Raw Data Beginning Ending Integration Baseline Baseline Time STL Chicago 1 59.6358 59.6358 5117301 1.754 2.750 240 Sample ID: 233507-11 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 01271133 Timestamp: 01/27/2005 11:37 Sample Type: Sample R e p # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 39.8297 39.8297 3426312 1.854 2.853 223 Sem pie ID: CCV Method: boat Cai. Curve: SOILCURVE Operatorio: CAROL Mode: TC Filename: 01271143 f Timestamp: 0 1 /2 7 /2 0 0 5 (1 1 :4 ^ Sample Type: Cal. Verification^ Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 101.7072 1017072 9119898 1.495 2.494 280 Sample ID: CCB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 01271212 Timestamp: 01/27/20' Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 -0.3164 -0.3164 -1251 1.551 1.550 120 Last Message: No Sample Detected Sample ID: 233629-1 Method: boat Cal. Curve: S O IL C U R V E ^ Operator ID: CAROL Mode: TC filen am e: 01271353 ? Timestamp: 01/27/2005 13:58 Sample Type: Sample Rep # ppm C ug C Raw Data "Beginning Ending Integration Baseline Baseline Time 1 431.2907 431.2907 3 6 8 4 8 m 5 .^ 3 6.878 296 Sample ID: 233629-1 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL \ Mode: T C \ Filename: 012714 Timestamp: 0lVlZ7/2005f 14:05 Sample Type: Sampt Rep # ppm C ug C Raw Data Beginning Ending I sgration STL Chicago 49 STL Chicago TOC in S o il* PageHo.: ^ . 1 3 0 Book Nq~ ;' 7 c/ ~ ? Method: Lloyd Kahn instrument Ptioenix eooo tre e *! Calciibrtwni: Datad StLanabdaNredt BCuarevcfai::*/ /.V/fC/ ^Sry - TOC(mg/kg) = ugC/gramssample Bookt3'77? Page# i2-f MS,MSDKnownConcL(rngikgi = 1DOugCSgramasample MS,MSDObserved(rrg/kg} = ugC/gramssample MS,MSDRee. Ibfcserviedma/ka-ava,sampleraaBftno/taVI x100 knownconcenlraBcnInmgfltg StandardTracaabtttfv: (Meta:WortungStandardsareprepareddailyfromfrianotedStockSolutions.) stockI(Curve) f'C K f \ S 7 - r o . S Sloe*tt(ICVi'CCV) ./.'// 7 2i. LCSSourceID'&7C&1?LC5TrueValue V?\y- My AcoertanceRare S 1 ____ Sample ID: _7 i ' Lr 'i '7 / / v - Sample W eight (g) r 'i , r . < 3 rJ , / ug C 7 A ; / ^ J 73s Commenta: 3 i '3 L 1" -2 3 3 V3 7 - s. . 0 y (' i s / v x y A 73 J A / r / S ' ; Z y 7 3 73 5T 1 3 3 - 7? Z , 27 i !7 7i <) 1 ! *- J . a -S ' ! ~ ' )fc,c. ^ r Z Q J ... --------------T!;-----------y-V'l'3.V" ,0 - - O c~ r y 73 {- y ' 7 3' ' i ^ f - . :- < 7 r / y / A 77 / A 732 / Vr? ^J-C'2 j-V /y j-.c 7^ ' -3 V2 . y 2 / 3 / 7 ^ i 7 2,7 2.3 73 f? V f i b r / 7i '3 i i -n y- . Q ' t ? c - 7 0 - / rr- 3 ; / - - 5 -- ;. 7 / Zo-f ZZr' , r ' 7,,Z -''-^r 7^ x ' /;. ,\j / / S ~ ~ 3 / 3 / / 7/ - v c\ c / / / J -*{ . "7 -- ^r O , 1 7 y r '" 0, c y /\ 7 .2 3 ^- / y ? . .: -> 7 -/ O - c a ? 3 73 3 3 v r - /./ r.~. " / / i- fi 2 0o 7 3 s17 r- % 3 f (3 C- '73 <7 ,3 C > 0 .- V' 7 3 ^ 7 7 - 3r f 3 ^ i7 v 7 Prep Analyst: 7 7 V Analyst: . 7 Reviewed bv: 77 -/V. 2 1 _________________ Dale: ' '7 _/' ,_________________ Date: j/2 7/ V i: __ .. {/ Date: t Cni-M a-aam*soi STL Chicago TOC in Sorte Page No : Bcok Mo.. iai Method: Lloyd Kahn .'nstornenf Pftoeflrjc flCOQ T O C ^i TaeNet Batcfr /V r v ~> CaleuiaHont: Dais erfStandard Curve1 TOC (mg/kg) * ug C 1grams sample Bod*# Paael* MS, M5D Known Cone, (mg/kg} = 100 ug C (gams sampd ^ '' MS, MSD Observed (mgTkg) ug C / grams sample MS. MSD ft l = r&bserved mjjV.-a - ava- aanurie rasuft fma/kall x-tfSa knoam concentration in mg/kg ~ r Standard Traceability. (Nate: Working SliiodgKiaa n prepared dailyfrom the noted Stac* Sotuttor.s) Stock I(Curve)______ i1i 7 7 _______ ^tstock ri (jcviccv) LOS Source 10 -LOS True Value , Acceptance Range, Sample ID: Sample Weight (g) ugC o e ft . x X x x / nX ~ o . X .v c'X1' X t A 1 * ; : - i; - / \ ~x ! ^x. & ^z 7 U -- . r i n <"*'/ . tX 7 ^` X`x OJ y X .. X 1 7 _ \7 < r r S i r . I7 C J C U XX XX X .V X _______ i -X j T.. --T -^1 1 5 e V !j r xxX x? -X (7 ,'c 3 / X X . XVV . _ x /_ O. C X X XX 7/ . 'X _____ / _ X` _____ /i_-__f_\ itZr______ C0 C .O f7 X v X XCX_ r . /6 ?3? 3 7 .3 X . /X \ vvX - (V X ? V X. _. _ \t \ Comments: ' / -rj X -------X--- 7 \x " _x ;Y W r XX2 X X Prep Analyse. Analyst Reviewed by:. .7 r-' D a t s ^ ^ ^ S . ........ .. . o a t .,- , ., ^ r . r ' v- _ .--r H ?-'>'.* 3Zsicto!
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