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'"^'\0 o ^*~ee / '' ViK^ * ''\\\\\S.''x v " o^v ' S\, ARnnnn??ftft4 ai m. Zm .fi- s n*b!.c!1 mSi S .--c C;nic:ryi.'fXrxzsGovto&i nrfPr *. 71k? i iiopr! InctltMt' fr.'CccuoctiorH 8cfctr SlfJ \'\V^ ABD00022685 N10SH POCKET GUIDE TO CHEMICAL HAZARDS US. DEPARTMENT OF HEALTH AND HUMAN SERVICES Public Health Service Centers for Disease Control and Prevention National Institute for Occupational Safety and Health June 1997 ABD00022686 DISCLAIMER Mention of the name of any company or product does not constitute endorsement by the National Institute for Occupational Safety and Health. To receive other information about occupational safety and health problems, call 1-800-35NIOSH (1-800-356-4674), or visit the NIOSH Home Page on the World Wide Web at http://www.cdc.gov/niosh/homepage.html DHHS (NIOSH) Publication No. 97-140 ABD00022687 COPYING AND REPRINTING This document is in the public domain and may be freely copied or reprinted. Printed and Distributed By: J. J. Keller & Associates, Inc. 3003 W. Breczewood Lane, P.O. Box 368 Neenah, Wisconsin 54957-0368 USA Phone: (800) 327-6868 iii ABD00022688 PREFACE The NIOSH Pocket Guide to Chemical Hazards presents information taken from the NIOSH/ OSHA Occupational Health Guidelines for Chemical Hazards, from National Institute for Occupational Safety and Health (NIOSH) criteria documents and Current Intelligence Bulletins, and from recognized references in the fields of industrial hygiene, occupational medicine, toxicology, and analytical chemis try. The information is presented in tabular form to provide a quick, convenient source of information on general industrial hygiene practices. The information in the Pocket Guide includes chemical struc tures or formulas, identification codes, synonyms, exposure limits, chemical and physical properties, incompatibilities and reactivities, measurement methods, respirator selections, signs and symptoms of exposure, and procedures for emergency treatment. The information assembled in the original 1978 printing of the Pocket Guide was the result of the Standards Completion Program, a joint effort by NIOSH and the Department of Labor to develop supple mental requirements for the approximately 380 workplace environmental exposure standards adopted by the Occupational Safety and Health Administration (OSHA) in 1971. This revision of the Pocket Guide includes updated sampling and analytical methods, updated Department of Transportation (DOT) identification and guide numbers, revised conversion factors, current exposure limits, guidelines for selecting "Part 84" respirators in Table 4, the new NIOSH carcinogen policy in Appendix A, an expanded synomyn and trade name index, and minor technical changes since the June 1994 Edition. ABD00022689 CONTENTS Preface.................................................................................................................................................... Acknowledgments.................................................................................................................................. Introduction.............................................................................................................................................. NIOSH Recommendations.................................................................................................................... How to Use This Pocket Guide............................................................................................................ iv vi vii viii ix Chemical Listing..................................................................................................................................... 1 Appendix A--NIOSH Occupational Carcinogens............................................................................... Appendix B--Thirteen OSHA-Regulated Carcinogens...................................................................... Appendix C--Supplementary Exposure Limits.................................................................................... Appendix D--Substances with No Established RELs........................................................................ Appendix E--Respirator Recommendations for Selected Chemicals............................................... Appendix F--Miscellaneous Notes....................................................................................................... Appendix G--Vacated 1989 OSHA PELs............................................................................................ 344 347 348 356 357 358 359 CAS Number Index................................................................................................................................. 376 DOT ID Number Index............................................................................................................................ 384 Synonym and Trade Name Index......................................................................................................... 389 ABD00022690 ACKNOWLEDGMENTS The Education and Information Division (EID), National Institute for Occupational Safety and Health (NIOSH), had primary responsibility for the development of the Pocket Guide. I would like to express my appreciation to the following people within ElD for their assistance in preparing the Pocket Guide: Howard Ludwig (former Technical Editor) for general guidance, David Case and Rolland Rogers for reformatting and computerization; Richard Niemeier, John Whalen, Ralph Zumwalde, Barb Dames, Laurence Reed, and Heinz Ahlers for policy review; Susan Cairelli and Kent Hatfield for consultation on toxicology issues; David Votaw, Joann Wess, Crystal Ellison, Faye Rice, John Palassis, Charles Bryant, Walter Ruch, Leela Murthy, Henryka Nagy, Clayton Doak, Sherry Medley, and Eileen Kuempel for assistance in updating and adding new information; Ronald Schuler, Vicki Reuss, Lucy Schoolfield, and Lawrence Foster for data acquisition; Sharon Cheesman for administrative support; Anne Hamilton and Vanessa Becks for editorial review; Vivian Morgan for electronic database negotiations; Charlene Maloney for publication dissemination; Shirley Carr for printing procurement; Pauline Elliott for graphic design; and Midwest Publications Consultants (Sherri Diana, Gary Litfin, Rob Schattauer, and Carla Brooks) for answering requests and mailing thousands of copies of the Pocket Guide. In addition, the following people from other Divisions in NIOSH also contributed greatly to the Pocket Guide: Mary Ellen Cassinelli, Donald Dollberg, and Peter Eller from the Division of Physical Sciences and Engineering (DPSE) for the development of the measurement methods section; Shiro Tanaka from the Division of Surveillance, Hazard Evaluations, and Field Studies (DSHEFS) for medical terminol ogy; and Donald Campbell, Chris Coffey, and John Dower, from the Division of Safety Research (DSR) for the development of the respirator recommendations. Also, thanks are due to those individuals who reviewed and constructively commented on the Pocket Guide during its initial development and subsequent revisions. Henry Chan (Technical Editor) ABD00022691 INTRODUCTION The NIOSH Pocket Guide to Chemical Hazards is intended as a source of general industrial hygiene information for work ers, employers, and occupational health professionals. The Pocket Guide presents key information and data in abbreviated tabular form for 677 chemicals or substance groupings (e.g., manganese compounds, tellurium compounds, inorganic tin compounds, etc.) that are found in the work environment. The industrial hygiene information found in the Pocket Guide should help users recognize and control occupational chemical haz ards. The chemicals or substances contained in this revision include all substances for which the National Institute for Occu pational Safety and Health (NIOSH) has recommended expo sure limits (RELs) and those with permissible exposure limits (PELs) as found in the Occupational Safety and Health Admin istration (OSHA) General Industry Air Contaminants Standard (29CFR 1910.1000). Background In 1974, NIOSH (which is responsible for recommending health and safety standards) joined OSHA (whose jurisdictions include promulgation and enforcement activities) in developing a series of occupational health standards for substances with existing PELs. This joint effort was labeled the Standards Completion Program and involved the cooperative efforts of several contractors and personnel from various divisions within NIOSH and OSHA. The Standards Completion Program devel oped 360 substance-specific draft standards with supporting documentation that contained technical information and recom mendations needed for the promulgation of new occupational health regulations. The Pocket Guide was developed to make the technical information in those draft standards more conve niently available to workers, employers, and occupational health professionals. The Pocket Guide is updated periodically to re flect new data regarding the toxicity of various substances and any changes in exposure standards or recommendations. Data Collection and Application The data collected for this revision were derived from a vari ety of sources, including NIOSH policy documents such as cri teria documents and Current Intelligence Bulletins (CIBs), and recognized references in the fields of industrial hygiene, occu pational medicine, toxicology, and analytical chemistry. ABD00022692 NIOSH RECOMMENDATIONS port new data on a known hazard, or present information on hazard control. Acting under the authority of the Occupational Safety and Alerts, Special Hazard Reviews, Occupational Hazard As Health Act of 1970 (29 USC Chapter 15) and the Federal Mine sessments, and Technical Guidelines support and complement Safety and Health Act of 1977 (30 USC Chapter 22), NIOSH the other standards development activities of the Institute. Their develops and periodically revises recommended exposure lim purpose is to assess the safety and health problems associ its (RELs) for hazardous substances or conditions in the work ated with a given agent or hazard (e.g., the potential for injury or place. NIOSH also recommends appropriate preventive mea for carcinogenic, mutagenic, or teratogenic effects) and to rec sures to reduce or eliminate the adverse health and safety ef ommend appropriate control and surveillance methods. Although viii fects of these hazards. To formulate these recommendations, NIOSH evaluates all known and available medical, biological, these documents are not intended to supplant the more com prehensive criteria documents, they are prepared to assist OSHA engineering, chemical, trade, and other information relevant to and MSHA in the formulation of regulations. the hazard. These recommendations are then published and In addition to these publications, NIOSH periodically pre transmitted to OSHA and the Mine Safety and Health Adminis sents testimony before various Congressional committees and tration (MSHA) for use in promulgating legal standards. at OSHA and MSHA rulemaking hearings. NIOSH recommendations are published in a variety of docu A complete list of occupational safely and health issues for ments. Criteria documents recommend workplace exposure which NIOSH has formal policies (e.g., recommendations for limits and appropriate preventive measures to reduce or elimi occupational exposure to chemical and physical hazards, engi nate adverse health effects and accidental injuries. neering controls, work practices, safety considerations, etc.) can Current Intelligence Bulletins (CIBs) are issued to dissemi be found in NIOSH Recommendations for Occupational Safety nate new scientific information about occupational hazards. A and Health: Compendium of Policy Documents and Statements CIB may draw attention to a formerly unrecognized hazard, re [DHHS (NIOSH) Publication No. 92-100], ABD00022693 HOW TO USE THIS POCKET GUIDE The Pocket Guide has been designed to provide chemicalspecific data to supplement general industrial hygiene knowl edge. To maximize the amount of data provided in this limited space, abbreviations and codes have been used extensively. These abbreviations and codes, which have been designed to permit rapid comprehension by the regular user, are discussed for each column in the following subsections. Chemical Name and Structure/Formula, CAS and RTECS Numbers, and DOT ID and Guide Numbers Chemical Name and Structure/Formula. -- The chemi cal name found in the OSHA General Industry Air Contaminants Standard (29CFR* 1910.1000) is listed first. The chemical struc ture or formula is also provided; carbon-carbon double bonds (-C=C-) and carbon-carbon triple bonds (-C=C-) have been indi cated where applicable. A page index for synonyms and trade names is included at the back of the Pocket Guide to help the user locate a specific substance. CAS and RTECS Numbers. -- Below the chemical struc- 'Code of Federal Regulations ture/formula is the Chemical Abstracts Service (CAS) registry number. This number, in the format xxx-xx-x, is unique for each chemical and allows efficient searching on computerized data bases. A page index for all CAS registry numbers listed is included at the back of the Pocket Guide to help the user locate a specific substance. Immediately below the CAS number is the NIOSH Registry of Toxic Effects of Chemical Substances (RTECS) number, in the format ABxxxxxxx. RTECS may be useful for obtaining additional toxicologic information on a specific substance. DOT ID and GUIDE Number. -- Under the RTECS number are the U S. Department of Transportation (DOT) identification number and the corresponding guide number. Their format is xxxx xxx. The Identification number (xxxx) indicates that the chemical is regulated by DOT. The Guide number (xxx) refers to actions to be taken to stabilize an emergency situation; this information can be found in the 1996 North American Emer gency Response Guidebook, (Office of Hazardous Materials Transportation [DHM-S11, U S. Department of Transportation, 400 Seventh Street S.W., Washington, D C 20590-0001) A page index for all DOT ID numbers listed is included at the back of the Pocket Guide to help the user locate a specific sub- ABD00022694 stance; please note however, that many DOT numbers are NOT unique for specific substances. Synonyms, Trade Names, and Conversion Factors Common synonyms and trade names are listed alphabeti cally for each chemical. Factors for the conversion of ppm (parts of vapor or gas per million parts of contaminated air by volume) to mg/m3 (milligrams of vapor or gas per cubic meter of contaminated air) at 25C and 1 atmosphere are listed for chemi cals with exposure limits expressed in ppm. Exposure Limits The NIOSH recommended exposure limits (RELs) are listed first in this column. Unless noted otherwise, RELs are timeweighted average (TWA) concentrations for up to a 10-hour workday during a 40-hour workweek. A short-term exposure limit (STEL) is designated by "ST" preceding the value; unless noted otherwise, the STEL is a 15-minute TWA exposure that should not be exceeded at any time during a workday. A ceiling REL is designated by "C" preceding the value; unless noted otherwise, the ceiling value should not be exceeded at any time. Any substance that NIOSH considers to be a potential occupational carcinogen is designated by the notation "Ca" (see Appendix A, which contains a brief discussion of poten tial occupational carcinogens). The OSHA permissible exposure limits (PELS), as found in Tables Z-1, Z-2. and Z-3 of the OSHA General Industry Air Contaminants Standard (29 CFR 1910.1000), that were effec tive on July 1, 1993* and which are currently enforced by OSHA are listed next. ('Note: In July 1992, the 11th Circuit Court of Appeals in its decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992) vacated more protective PELs set by OSHA in 1989 for 212 substances, moving them back to PELs estab lished in 1971. The appeals court also vacated new PELs for 164 substances that were not previously regulated. Although OSHA is currently enforcing exposure limits in Tables Z-1, Z-2, and Z-3 of 29 CFR 1910.1000 which were in effect before 1989, violations of the "general duty clause" as contained in Section 5(a)(1) of the Occupational Safety and Health Act may be considered when worker exposures exceed the 1989 PELs for the 164 substances that were not previously regulated. The substances for which OSHA PELs were vacated on June 30,1993 are indicated by the symbol "f" following OSHA in this column and previous values are listed in Appendix G.] Unless ABD00022695 noted otherwise, PELs are TWA concentrations that must not be exceeded during any 8-hour workshift of a 40-hour work week.. A STEL is designated by "ST" preceding the value and is measured over a 15-minute period unless noted otherwise. OSHA ceiling concentrations (designated by "C" preceding the value) must not be exceeded during any part of the workday; if instantaneous monitoring is not feasible, the ceiling must be assessed as a 15-minute TWA exposure. In addition, there are a number of substances from Table Z-2 (e.g., beryllium, ethyl ene dibromide, and methylene chloride) that have PEL ceiling values that must not be exceeded except for a maximum peak over a specified period (e g., a 5-minute maximum peak in any 2 hours). Appendix B contains a brief discussion of substances regulated as carcinogens by OSHA. Concentrations are given in ppm, mg/m3, mppcf (millions of particles per cubic foot of air as determined from counting an impinger sample), or fibers/cm3 (fibers per cubic centimeter). The "[skin]" designation indicates the potential for dermal ab sorption; skin exposure should be prevented as necessary through the use of good work practices and gloves, coveralls, goggles, and other appropriate equipment. The "(total)" desig nation indicates that the REL or PEL listed is for "total particu late" versus the "(resp)" designation which refers to the "re spirable fraction" of the airborne particulate. Appendix C con tains more detailed discussions of the specific exposure limits for certain low-molecular-weight aldehydes, asbestos, vari ous dyes (benzidine-, o-tolidine-, and o-dianisidine-based), carbon black, the various chromium compounds (chromic acid and chromates, chromium(ll) and chromium(lll) compounds, and chromium metal), coal tar pitch volatiles, coke oven emissions, cotton dust, lead, NIAX Catalyst ESN, trichloroethylene, and tungsten carbide (cemented). Appendix D contains a brief discussion of substances included in the Pocket Guide with no established RELs at this time and Appendix F contains mis cellaneous notes regarding the OSHA PELs. Appendix G lists the OSHA PELS that were vacated on June 30, 1993. IDLH For the June 1994 Edition of the Pocket Guide, immediately dangerous to life or health concentrations (lOLHs) were re viewed and, in many cases, were revised and made more protective. As a consequence of the IDLH changes, many of the respirator recommendations for these substances were also revised. The criteria utilized to determine the adequacy of existing IDLH values were a combination of those used during ABD00022696 the Standards Completion Program and a newer methodology developed by NIOSH. These "interim" criteria form a tiered ap proach with acute human toxicity data being used preferen tially, followed next by acute animal inhalation toxicity data, and then finally by acute animal oral toxicity data to determine an updated IDLH value. When relevant acute toxicity data were insufficient or unavailable, the use of chronic toxicity data or an analogy to a chemically similar substance was considered. The criteria and information sources for both the original and revised IDLH values are given in Documentation for Immediately Dangerous to Life and Health Concentrations (IDLHs) (NTIS Publication No. PB-94-195047). NIOSH is currently assessing the various uses of IDLHs and whether the original criteria used to derive the IDLH values are valid or if other information or criteria should be utilized. Based on this assessment, NIOSH will develop a new strategy for revising the IDLH values cur rently listed, as well as for developing new IDLH values for the more than 300 substances listed in the Pocket Guide without IDLHs. The definition of IDLH that was derived during the Stan dards Completion Program was based on the Mine Safety and Health Administration (MSHA) definition stipulated in 30 CFR 11.3(t). The purpose for establishing an IDLH value in the Standards Completion Program was to ensure that a worker could escape without injury or irreversible health effects from an IDLH exposure in the event of the failure of respiratory protection equipment. The IDLH was considered a maximum concentration above which only a highly reliable breathing ap paratus providing maximum worker protection was permitted. In determining IDLH values, the ability of a worker to escape without loss of life or irreversible health effects was consid ered along with severe eye or respiratory irritation and other deleterious effects {e.g., disorientation or incoordination) that could prevent escape. As a safety margin, the Standards Completion Program IDLH values were based on the effects that might occur as a consequence of a 30-minute exposure. However, the 30-minute period was NOT meant to imply that workers should stay in the work environment any longer than necessary, in fact, EVERY EFFORT SHOULD BE MADE TO EXIT IMMEDIATELY) The current NIOSH definition for an IDLH exposure condi tion, as stipulated in the NIOSH Respirator Decision Logic (DHHS [NIOSH] Publication No. 87-108, NTIS Publication No. PB91-151183), is a condition "that poses a threat of exposure to airborne contaminants when that exposure is likely to cause death or immediate or delayed permanent adverse health ef- ABD00022697 fects or prevent escape from such an environment." The pur pose of establishing an IDLH exposure concentration is to ' en sure that the worker can escape from a given contaminated environment in the event of failure of the respiratory protection equipment." The NIOSH Respirator Decision Logic uses these IDLH values as one of several respirator selection criteria. Under the NIOSH Respirator Decision Logic, the most protec tive respirators (e g., a self-contained breathing apparatus equipped with a full facepiece and operated in a pressuredemand or other positive-pressure mode) would be selected for firefighting, exposure to carcinogens, entry into oxygendeficient atmospheres, in emergency situations, during entry into an atmosphere that contains a substance at a concentra tion greater than 2,000 times the NIOSH REL orOSHA PEL, and for entry into IDLH atmospheres. IDLH values are listed for over 380 substances. The nota tion "Ca" appears in this column for all substances that NIOSH considers to be potential occupational carcinogens. However, IDLH values that were originally determined in the Standards Completion Program or were recently revised are shown in brackets following the "Ca'' designations. "10%LEL" indicates that the IDLH was based on 10% of the lower explosive limit for safety considerations even though the relevant toxicological data indicated that irreversible health effects or impairment of escape existed only at higher concentrations. "N.D." indicates that an IDLH has not as yet been determined. Physical Description This column provides a brief description of the appearance and odor of each substance. Notations are made as to whether a substance can be shipped as a liquefied compressed gas or whether it has major use as a pesticide. Chemical and Physical Properties The following abbreviations are used for the chemical and physical properties given for each substance. "NA" indicates that a property is not applicable, and a question mark (?) indi cates that it is unknown. MW....................... Molecular weight BP.......................... Boiling point at 1 atmosphere, F ABD00022698 Sol........................ FI.P....................... IP**........................ VP........................ MLT....................... FRZ...................... UEL....................... LEL....................... MEC...................... Sp.Gr.................... Solubility in water at 688F*, % by weight (i.e., g/100 ml) Flash point (i.e., the temperature at which the liquid phase gives off enough vapor to flash when exposed to an external ignition source), closed cup (unless annotated "(oc)" for open cup),F Ionization potential, eV (electron volts) Vapor pressure at 688F*, mm Hg; "approx" indicates approximately Melting point for solids, F Freezing point for liquids and gases, F Upper explosive (flammable) limit in air, % by volume (at room temperature*) Lower explosive (flammable) limit in air, % by volume (at room temperature*) Minimum explosive concentration, g/m3 (when available) Specific gravity at 68F* referenced to water at 39.28F(4C) 'If noted after a specific entry, these properties may be reported at other temperatures "Ionization potentials are given as a guideline for the selection of photoionization detector lamps used in some direct-reading instruments RGasD.................. Relative density of gases referenced to air = 1 (indicates how many times a gas is heavier than air at the same temperature) When possible, the flammability/combustibility of a substance was determined and listed after the specific gravity. The fol lowing OSHA criteria (29 CFR 1910.106) were used to classify flammable or combustible liquids: Class IAflammable liquid........... FI.P. below 738F and BP below 1008F. Class IB flammable liquid........... FI.P. below 738F and BP at or above 10Q8F Class 1C flammable liquid.......... FI.P. at or above 73F and below 1008F. Class II combustible liquid......... FI.P. at or above 100F and below 140F. ClasslllAcombustibleliquid....... FI.P. at or above 140F and below 2008F. Class IIIB combustible liquid....... FI.P. at or above 200F. ABD00022699 Incompatibilities and Reactivities This column lists important hazardous incompatibilities or reactivities of each substance. Measurement Method This column provides a brief, key word description of the suggested sampling and analysis method. Each description com prises fourcomponents: (1)the collection method, (2)the sample work-up, (3) the analytical method, and (4) the method number. The method number is usually from the 4th edition of the NIOSH Manual ofAnalytical Methods (DHHS [NIOSH] Publication No. 94113) and is indicated by "IV" following the sample work-up. If a different edition of the NIOSH Manual of Analytical Methods is cited, the appropriate edition (and, for the 2nd edition only, the volume number) would be noted [e.g., 11(4)]. In a number of instances, the table cites the OSHA Analytical Methods Manual (or the OSHA web site, http://www.osha-slc.gov/) and appli cable method number (e.g,, OSHA (#21 ]). When a method for a particular substance is not included in the latest NIOSH or OSHA analytical methods manuals or at the OSHA web site, "None available" is listed. The codes listed are explained in Table 1. Table 2 presents ordering information for the measurement meth ods cited. Personal Protection and Sanitation This column presents a summary of recommended practices for each toxic substance. These recommendations supplement general work practices (e.g., no eating, drinking, or smoking where chemicals are used). Table 3 explains the codes used. Each category is described as follows: SKIN: EYES: WASH SKIN: REMOVE: CHANGE: PROVIDE: Recommends the need for personal protective clothing. Recommends the need for eye protection. Recommends when workers should wash the spilled chemical from the body in addition to normal washing (e.g., before eating). Advises workers when to remove clothing that has accidentally become wet or significantly contaminated. Recommends whether the routine changing of clothing is needed. Recommends the need for eyewash fountains and/or quick drench facilities. ABD00022700 Recommendations for Respirator Selection This column provides a condensed table of allowable respi rator use for those substances for which IDLH values have been determined. NIOSH is currently reevaluating the IDLH values, and as new or revised IDLH values are developed, respirator selection recommendations will be incorporated into subsequent editions of the Pocket Guide. In the interim no respirator recommendations will be made for substances with out IDLH values (these will be noted by "TBAL" -- to be added later). NIOSH has developed a new set of regulations in 42 CFR 84 (also referred to as "Part 84") for testing and certifying nonpowered, air-purifying, particulate-filter respirators. The new Part 84 respirators have passed a more demanding certi fication test than the old respirators (e.g.; dust [D]; dust and mist [DM]; dust, mist, and fume [DMFu]; spray paint; pesticide; etc.) certified under 30 CFR 11 (also referred to as "Part 11"). Under Part 84, NIOSH is allowing manufacturers to continue selling and shipping Part 11 particulate filters as NIOSH-certified until July 10, 1998. It is important to see Table 4 (pages xxxi-xxxii) for substitution of Part 84 respirators for Part 11 respirators. Also see the NIOSH Guide to the Selection and Use of Particulate Respirators (DHHS [NIOSH] publication 96- Id). The first line in the column indicates whether the "NIOSH" or the "OSHA" exposure limit is used on which to base the respi rator recommendations. The more protective limit between the NIOSH REL or the OSHA PEL is always used. "NIOSH/OSHA" indicates that the limits are equivalent. Each subsequent line lists a maximum use concentration (MUC) followed by a series of codes representing classes of respirators that are acceptable for use below the MUC. Indi vidual respirator class codes are separated by diagonal lines (/). More protective respirators may be worn. Emergency or planned entry into unknown concentrations or entry into IDLH conditions are designated by the symbol and followed by the codes for classes of respirators acceptable for these condi tions. "Escape" indicates that the respirators are to be used only for escape purposes. For each MUC or condition the table lists only those respirators with the required protection factor and other use restrictions based on the NIOSH Respirator Decision Logic. All respirators selected must be approved by NIOSH and MSHA under the provisions of 30 CFR 11 or by NIOSH under 42 CFR 84. The current listing of NIOSH/MSHA certified respira- ABD00022701 tors can be found in the NlOSH Certified Equipment List (DHHS [NIOSH] Publication No. 94-104). A list of Part 84 respirators can be found on the NIOSH Home Page (http://www.cdc.gov/ niosh/homepage.html) or obtained by calling 1-800-35-NIOSH. A complete respiratory protection program must be imple mented and must fulfill all requirements of 29CFR 1910.134. A respiratory protection program must include a written standard operating procedure covering regular training, fit-testing, fitchecking, periodic environmental monitoring, maintenance, medi cal monitoring, inspection, cleaning, storage, and periodic pro gram evaluation. Selection of a specific respirator within a given class of recommended respirators depends on the par ticular situation: this choice should be made only by a knowl edgeable person. REMEMBER: Air-purifying respirators will not protect users against oxygen-deficient atmospheres, and they are not to be used in IDLH conditions. The only respirators recommended for fire fighting are self-contained breathing ap paratuses that have full facepieces and are operated in a pres sure-demand or other positive-pressure modes. Additional information on the selection and use of respirators can be found in the NIOSH Respirator Decision Logic and the NIOSH Guide to Industrial Respiratory Protection (DHHS [NIOSH] Pub lication No. 87-116). Codes for the various categories of respirators are defined in Table 4. In addition, the assigned protection factor (APF) is indicated for each respirator class. Route of Health Hazard This column lists the toxicoiogically important routes of en try for each substance and whether contact with the skin or eyes is potentially hazardous, abbreviated as follows: Inh........ Inhalation Abs...... Skin absorption Ing........ Ingestion Con....... Skin and/or eye contact (liq)....... Liquid (sol)...... Solid (soln). ... Solution Symptoms This column lists the potential symptoms of exposure. Their abbreviations are defined in Table 5. xvii ABD00022702 First Aid This column lists emergency procedures for eye and skin contact, inhalation, and ingestion of the toxic substance. Ab breviations are defined in Table 6. Target Organs This column lists the organs that are affected by exposure to each substance. Abbreviations are defined in Table 5. ABD00022703 Table 1. -- Codes for measurement methods Code Method/reagent Code Method/reagent Collection method:* Ambersorb Anasorb Bag Bub Carbo-B Char Char (low-Ni) Char (pet) Chrom Dry tube Filter Florisil G-chrom P Hydrar Imp Mol-sieve OVS Pad/Pre-ftlter Porapak Si gel Soda lime TD Tenax GC Ambersorb XE-347 tube Anasorb tube Gas collection bag Bubbler Carbosieve B tube Charcoal tube Charcoal tube (low nickel content) Charcoal tube (petroleum-based) Chromosorb tube Drying tube Particulate filter Florisil tube Gas-chrom P tube Hydrar sorbent tube Impinger Molecular sieve tube OSHA versatile sampler Treated pad with a pre-filter Porapak tube Silica gel tube Soda lime sorbent tube Thermal desorption tube Tenax GC tube T-Sorb Vertical elut XAD Sample work-up CCI4 CHClj CH2CI2 CH3CN CH,COOH CS2 DCE DMF DMSO EDTA FeCI3 HCI HCOOH HN03 HA HPLC h3po< HSA Thermosorb tube Vertical elutriator XAD tube Carbon tetrachloride Chloroform Methylene chloride Acetonitrile Acetic acid Carbon disulfide 1,2-Dichloroethane Dimethylformamide Dimethyl sulfoxide Ethylenedmitrilo-tetraacetic acid Ferric chloride Hydrochloric acid Formic acid Nitric acid Hydrogen peroxide High-pressure liquid chromatography Phosphoric acid Hexanesulfonic acid (Continued) `In the chemical listing, an asterisk following art adsorbent tube code (e g.. Char*, Si gel', XAD-2*. etc ) indicates that a special coating must be added. The figure "2" in parentheses following a collection device (e g., Filter(2), lmp(2), Char(2), etc.) indicates that two are used in series. Code h2so4 K1 KOH LTA Na2C03 NaHC03 NaOH Na2S203 nh4oh Pho-acid Thermal desorp THF Analytical method: DPCSP ECA EGA FAAS GC GC/AlkFID ABD00022704 Table 1. -- Codes for measurement methods (Continued) Method/reagent Code Method/reagent Sulfuric acid Potassium iodide Potassium hydroxide Low-temperature ashing Sodium carbonate Sodium bicarbonate Sodium hydroxide Sodium thiosulfate Ammonium hydroxide Phosphomolybdic acid Thermal desorption apparatus Tetrahydrofuran Differential pulse cathodic stripping polarography Electrochemical analysis Evolved gas analysis Flame atomic absorption spectro- metry Gas chromatography GC with alkaline flame ionization detection GC/ECD GC/EConD GC/FID GC/FPD GC/NPD GC/PID GC/TCD GC/TEA GC/TEA-EAP GFAAS Grav HPLC/GFAAS HPIC/FLD GC with electron capture detection GC with electrolytic conductivity detection GC with flame Ionization detection GC with flame photometric detection for sulfur, nitrogen, or phosphorus GC with nitrogen/phosphorus detection GC with photoionization detection GC with thermal conductivity detection GC with thermal energy analyzer detection GC/TEA with explosives package Graphite furnace atomic absorption spectrometry Gravimetric High-pressure liquid chromatography with GFAAS High-pressure liquid chromatography with fluorescence detection (Continued) Code HPLC/UVD HPLC/UV/ECD HPLCAJV/FLD HYAAS C ICP ABD00022705 Table 1. -- Codes for measurement methods (Continued) Method/reagent Code Method/reagent High-pressure liquid chromatography with ultraviolet detection High-pressure liquid chromatography with ultraviolet and electrochemical detection High-pressure liquid chromatography with ultraviolet and fluorescence detection Hydride generation atomic absorption spectrometry Ion chromatography Inductively coupled plasma R ISE PCM PES PLR TBd TOA Titrate UV-vis Vis XRF XRD Infrared spectrometry Ion-specific electrode Phase contrast microscopy Plasma emission spectroscopy Polarography Transmission electron microscopy Thermal optical analyzer Titration Ultraviolet-visible spectrophotometry Visible spectrophotometry X-ray fluorescence spectrometry X-ray diffraction spectrometry xxi xxii ABD00022706 Manual Table 2. -- Ordering information for measurement methods Publication No. Ordering No. Manual Publication No. Ordering No. NIOSH Manual of Analytical Methods, 2nd edition (II): Vol. 1 Vol. 2 Vol. 3 Vol. 4 Vol. 5 Vol. 6 Vol. 7 NIOSH Manual of Analytical Methods (NMAM), 3rd edition (HI) NIOSH 77-157-A NIOSH 77-157-B NIOSH 77-157-C NIOSH 78-175 NIOSH 79-141 NIOSH 80-125 NIOSH 82-100 NIOSH 84-100 PB-274-845 PB-276-624 PB-276-838 PB-83-105-437 PB-83-105-445 PB-82-157-728 PB-83-105-452 PB-85-179-018 1st supplement to 3rd edition NIOSH 85-117 PB-86-116-266 2nd supplement to 3rd edition NIOSH 87-117 PB-88-204-722 3rd supplement to 3rd edition NIOSH 89-127 PB-90-162-470 4th supplement to 3rd edition NIOSH 90-121 PB-91-152-660 OSHA Analytical Methods Manual, 1990 & 1993 ... 4542' NIOSH Manualol Analytical Methods (NMAM), 4th edition (IV) NIOSH 94-113 017-011-00007-9" `Denotes ordering number of the American Conference of Governmental Industrial Hygienists (ACGIH), 1330 Kemper Meadow Drive, Cincinnati, OH 45240 (513-7422020). All other ordering numbers are for the National Technical Information Service (NTIS), Springfield, VA 22161 (703-487-4650). *' Printed copies of the NMAM are available from the U S. Government Printing Office, Supenntendent of Documents, Washington, DC 20402. The computerized version of the NIOSH Manual of Analytical Methods (NMAM) is available on diskette from the Canadian Centre for Occupational Health and Safety, 250 Main Street East, Hamilton, Ontario CANADA L8N 1H6; Telephone 905-570-8094, Toll Free 1-800-668-4284 and WindowChem Software, Inc., 420-F Executive Court North, Fairfield, CA 94585; Telephone 707-864-0845; Toll Free 1-800-536-0404. ABD00022707 Code Table 3. -- Personal protection and sanitation codes Definition Code Definition SKIN Prevent skin contact Frostbite................... N.R ........................... Wear appropriate personal protec tive clothing to prevent skin contact. Wear appropriate personal protective clothing to prevent the skin from becoming frozen from contact with the liquid or from contact with ves sels containing the liquid. No recommendation is made speci fying the need for personal protec tive equipment for the body. EYES Prevent eye contact. Frostbite................... N.R............................. Wear appropriate eye protection to prevent eye contact. Wear appropriate eye protection to prevent eye contact with the liquid that could result in burns or tissue damage from frostbite. No recommendation is made speci fying the need for eye protection. WASH SKIN When contam........... Daily........................... N.R ........................... The worker should immediately wash the skin when it becomes conlaminated. The worker should wash daily at the end of each work shift. No recommendation is made speci fying the need for washing the substance from the skin (either immedi ately or at the end of the work shift). REMOVE When wet or contam When wet (flamm).... N.R............................. Work clothing that becomes wet or significantly contaminated should be removed and replaced. Work clothing that becomes wet should be immediately removed due to its flammability hazard (i.e., for liq uids with a flash point <100F). No recommendation is made spedfying the need for removing clothing that becomes wet or contaminated. (Continued) xxiv ABD00022708 Code Table 3. -- Personal protection and sanitation codes (Continued) Definition Code Definition CHANGE Daily.................... .... N.R..................... ..... Workers whose clothing may have become contaminated should change into uncontaminated clothing before leaving the work premises. No recommendation is made spedfying the need for the worker to change clothing after the workshift. PROVIDE Eyewash............. ..... Eyewash fountains should be provided in areas where there is any pos sibility that workers could be exposed to the substance, this is irrespective of the recommendation involving the wearing of eye protection. Quick drench...... ..... Facilities for quickly drenching the body should be provided within the immediate work area for emergency use where there is a possibility of exposure. (Note: It is intended that these facilities provide a sufficient quantity or flow of water to quickly remove the substance from any Frostbite....... ........... body areas likely to be exposed. The actual determination of what constitutes an adequate quick drench fa cility depends on the specific circum stances. In certain instances, a del uge shower should be readily available, whereas in others, the avail ability of water from a sink or hose could be considered adequate.] Quick drench facilities and/or eyewash fountains should be provided within the immediate work area for emergency use where there is any possibility of exposure to liquids that are extremely cold or rapidly evapo rating. OTHER CODES Liq................. ... Liquid Molt............... ...Molten N.R................ ....No recommendation applies in this category Sol................. ... Solid Soln............... . ..Solution containing the contaminant Vap................ ...Vapor ABD00022709 Table 4. -- Symbols, code components, and codes used for respirator selection Item Definition Item Definition Symbol: .......... At concentrations above the NIOSH REL, or where there is no REL, at any detectable concentration .......... Emergency or planned entry into unknown con centrations or IDLH conditions *.......... Substance reported to cause eye irritation or dam age; may require eye protection ........... Substance causes eye irritation or damage; eye protection needed A........... If not present as a fume l.......... Only nonoxidizable sorbents allowed (not charcoal) t.......... End of service life indicator (ESLI) required APF..... Assigned protection factor TBAL ... To be added later Code component: CCR..... Chemical cartridge respirator D.......... Dust respirator (if an independent code); or a dust filter F......... Full facepiece Fu........ Fume filter GMF.... Air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted canister M.......... Mist filter PAPR.... Powered, air-purifying respirator SA....... Supplied-air respirator SCBA... Self-contained breathing apparatus AG...... Acid gas cartridge or canister CF....... Continuous flow mode HiE...... Air-purifying respirator with a high-efficiency par ticulate filter (if an independent code); or a highefficiency particulate filter HiEF.... Air-purifying, full-facepiece respirator with a highefficiency particulate filter OV...... Organic vapor cartridge or canister PD,PP.. Pressure-demand or other positive-pressure mode S......... Chemical cartridge or canister providing protec tion against the compound of concern T.......... Tight-fitting facepiece XS....... Except single-use respirator XSQ.... Except single-use and quarter-mask respirator Code: CCRFAGHiE (APF = 50) Any chemical cartridge respira tor with a full facepiece and acid gas cartridge(s) in combination with a high-efficiency particu- la,efil,er (Continued) XXV xxvi ABD00022710 Table 4. -- Symbols, code components, and codes used for respirator selection (Continued) Item Definition Item Definition Code (continued) CCRFOV (APF * 50)........ Any chemical cartridge respi rator with a full facepiece and organic vapor cartridge(s) CCRFOVDMFu (APF = 50) Any chemical cartridge respira tor with a full facepiece and or ganic vapor cartridge(s) in com bination with a dust, mist, and fume filter CCRFOVHiE (APF = 50)... Any chemical cartridge respira tor with a full facepiece and or ganic vapor cartridge(s) in com bination with a high-efficiency particulate filter CCRFS (APF = 50)............ Any chemical cartridge respira tor with a full facepiece and cartridge(s) providing protec tion against the compound of concern CCRFSHiE (APF =50).... Any chemical cartridge respi rator with a full facepiece and cartridge(s) providing protec tion against the compound of concern and having a highefficiency particulate filter CCROV (APF = 10).......... Any chemical cartridge respi rator with organic vapor cartridge(s) CCROVAG (APF = 10)..... Any chemical cartridge respira tor with organic vapor and acid gas cartridge(s) CCROVDM (APF = 10).... Any chemical cartridge respira tor with organic vapor cartridge(s) in combination with a dust and mist filter CCROVDMFu (APF = 10). Any chemical cartridge respira tor with organic vapor cart ridge^) in combination with a dust, mist, and fume filter CCROVHiE (APF = 10).... Any chemical cartridge respira tor with organic vapor car tridge^) in combination with a high-efficiency particulate filter OCRS (APF = 10).............. Any chemical cartridge respira tor with cartridge(s) providing protection against the com pound of concern D (APF = 5)........................ Any dust respirator DM (APF = 5)..................... Any dust and mist respirator (Continued) ABD00022711 Table 4. -- Symbols, code components, and codes used for respirator selection (Continued) Item Definition Item Definition Code (continued) DMF(APF= 10)........... DMFu (APF = 10)........ DMXSQ (APF = 10)..... DXSQ (APF = 10)........ GMFAG (APF = 50)..... GMFAGHiE (APF = 50) Any dust and mist respirator with a full facepiece Any dust, mist, and fume res pirator Any dust and mist respirator except single-use and quartermask respirators Any dust respirator except single-use and quarter-mask respirators Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or backmounted acid gas canister Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or backmounted acid gas canister having a high-efficiency par ticulate filter GMFOV (APF = 50) Any air-purifying, full- facepiece respirator (gas mask) with a chin-style, front- or back-mounted organic va por canister GMFOVAG (APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back- mounted organic vapor and acid gas canister GMFOVAGHiE (APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back- mounted organic vapor and acid gas canister having a high efficiency particulate filter GMFOVDMFu (APF = 50). Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back- mounted organic vapor canis ter in combination with a dust, mist, and fume filter (Continued) xxvii xxviii ABD00022712 Table 4. -- Symbols, code components, and codes used for respirator selection (Continued) Item Code (continued) GMFOVHiE (APF = 50) GMFS (APF = 50) GMFSHiE (APF = 50) HiE (APF = 10) Definition Any air-purifying, fullfacepiece respirator (gas mask) with a chin-style, frontor back-mounted organic va por canister having a high-ef ficiency particulate filter Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or backmounted canister providing pro tection against the compound of concern Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or backmounted canister providing pro tection against the compound of concern and having a highefficiency particulate filter Any air-purifying respirator with a high-efficiency particu late filter Item Definition HiEF (APF = 50)................. Any air-purifying, full-facepiece respirator with a high-efficiency particulate filter PAPRAG (APF = 25)......... Any powered, air-purifying respirator with acid gas cartridge(s) PAPRAGHiE (APF = 25)... Any powered, air-purifying res pirator with acid gas cart ridge^) in combination with a high-efficiency particulate filter PAPRD (APF = 25)........... Any powered, air-purifying res pirator with a dust filter PAPRDM (APF = 25)........ Any powered, air-purifying res pirator with a dust and mist filter PAPRDMFu (APF = 25).... Any powered, air-purifying res pirator with a dust, mist, and fume filter PAPRHiE (APF = 25)....... Any powered, air-purifying res pirator with a high-efficiency particulate filter PAPROV (APF = 25)......... Any powered, air-purifying respirator with organic vapor cartridge(s) (Continued) ABD00022713 Table 4. -- Symbols, code components, and codes used for respirator selection (Continued) Item Definition Item Definition Code (continued) PAPROVAG (APF = 25).... Any powered, air-purifying respirator with organic vapor and acid gas cartridge(s) PAPROVDM (APF = 25) ... Any powered, air-purifying res pirator with organic vapor cartridge(s) in combination with a dust and mist filter PAPROVDMFu (APF = 25) Any powered, air-purifying res pirator with organic vapor cartridge(s) in combination with a dust, mist, and fume filter PAPRS (APF = 25).......... Any powered, air-purifying res pirator with cartridge(s) provid ing protection against the com pound of concern PAPRTHiE (APF = 50)..... Any powered, air-purifying res pirator with a tight-fitting facepiece and a high-efficiency particulate filter PAPRTOV (APF = 50)....... Any powered, air-purifying respirator with a tight-fitting facepiece and organic vapor cartridge(s) PAPRTOVHiE (APF = 50) PAPRTS (APF = 50)..... SA (APF = 10)................ SA.CF (APF = 25)......... SAF (APF = 50).............. SAF:PD,PP (APF = 2000) Any powered, air-purifying respirator with a tight-fitting facepiece and organic vapor cartridge(s) in combination with a high-efficiency particulate fil ter Any powered, air-purifying res pirator with a tight-fitting facepiece and cartridge(s) provid ing protection against the com pound of concern Any supplied-air respirator Any supplied-air respirator op erated in a continuous-flow mode Any supplied-air respirator with a full facepiece Any supplied-air respirator that has a full facepiece and is op erated in a pressure-demand or other positive-pressure mode (Continued) xxix XXX ABD00022714 Table 4. -- Symbols, code components, and codes used for respirator selection (Continued) Item Definition Item Definition Code (continued) SAF:PD,PP:ASCBA (APF = 10,000)............ SA:PD,PP (APF = 1000).. Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing appa ratus operated in pressuredemand or other positivepressure mode Any supplied-air respirator op erated in a pressure-demand or other positive-pressure mode SAT:CF (APF = 50)..... .... SCBAE........................ .... SCBAF (APF = 50)..... .... SCBAF:PD,PP (APF = 10,000)....... .... Any supplied-air respirator that has a tight-fitting facepiece and is operated in a continuous-flow mode Any appropriate escape-type, self-contained breathing appa ratus Any self-contained breathing apparatus with a full facepiece Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure- demand or other positive-pressure mode (Continued) ABD00022715 Table 4. -- Symbols, code components, and codes used for respirator selection (Continued) SUBSTITUTION OF PART 84 RESPIRATORS FOR PART 11 RESPIRATORS ALREADY IN USE The following selection guidelines are intended for those who are currently using a Part 11 respirator that has been properly selected (see the "Recommendations for Respirator Selection" section on page xvi). In this context, a properly selected respirator means one that has been selected based on knowledge of the contaminant and its concentration in a particular work setting, the exposure limit of the contaminant, and the general principles of respirator selection. Following these recommendations is the simplest approach to making the transition from Pari 11 filters to Part 84 filters. 1. If you are currently using a D, DM or DMFu filter: In a work setting free of oil aerosols, the minimally protective filter would be an N95. In a work setting that may contain or does contain oil aerosols, the minimally protective filter would be an R95 or P95. 2. If you are currently using a HiE filter: In a work setting free of oil aerosols, an N100 filter would be protective. In a work setting that contains or may contain oil aerosols, an R100 or P100 filter would be protective. 3. If you are currently using a paint-lacquerenamel combination cartridge: In a work setting free of oil aerosols, a combination respirator consisting of an organic vapor cartridge and an N95 particulate filter with an optional prefilter (to prevent rapid clogging by paint aerosols) would be minimally protective. In a work setting that may contain or does contain oil aerosols, a combination respirator consisting of an organic vapor cartridge and an R95 or P95 particulate filter with a prefilter (to prevent rapid clogging by paint aerosols) would be minimally protective. xxxi xxxii ABD00022716 Table 4. -- Symbols, code components, and codes used for respirator selection (Continued) 4. If you are currently using a pesticide respirator for protection against a particulate and an organic vapor: A combination respirator consisting of an organic vapor cartridge and an N95 (non-oil aerosols) or an R95 or P95 particulate filter would be minimally protective. As another example, a particular pesticide may have such low vapor pressure that only a particulate filter may be needed. Thus in certain situations, there may be no need for a combination particulate filter and organic vapor cartridge as recommended above. ABD00022717 Table 5. -- Abbreviations for symptoms of exposure and target organs Abbreviation Symptom/organ Abbreviation Symptom/organ abdom ................... .. Abdominal abnor ................... .. Abnormal/Abnormahties album..................... ... Albuminuria anes .................... .. Anesthesia anor........................ ... Anorexia anos....................... ... Anosmia (loss of the sense of smell) appre...................... ... Apprehension arrhy....................... ... Arrhythmias aspir....................... ... Aspiration asphy ..................... ... Asphyxia BP.......................... . Blood pressure breath..................... .. Breathing bron ....................... Bronchitis broncopneu ............ ... Bronchopneumonia bronspas ................ . . Bronchospasm BUN ....................... ... Blood urea nitrogen [care] ..................... ... Potential occupational carcinogen card ...................... ... Cardiac chol........................ ... Cholinesterase cirr.......................... ... Cirrhosis CNS ................... ... Central nervous system cone....................... ... Concentration conf ... ..... . . Confusion conj........................ ... Conjunctivitis constip................... ... Constipation convuls.................. .. Convulsions corn........................ ... Corneal CVS........................ ... Cardiovascular system cyan................ .. Cyanosis deer....................... ... Decrease(d) depres.................... ... Depressant/Depression derm....................... ... Dermatitis diarr....................... ... Diarrhea dist......................... ... Disturbance dizz......................... ... Dizziness drow....................... ... Drowsiness dysfunc.................. ... Dysfunction dysp ... Dyspnea (breathing difficulty) emphy.................... ... Emphysema eosin...................... .. Eosinophilia epilep ..................... ... Epileptiform epis........................ ... Epistaxis (nosebleed) equi........................ ... Equilibrium eryt......................... ... Erythema (skin redness) euph....................... ... Euphoria fail.......................... ... Failure fasc........................ ... Fasiculation (Continued) xxxiv ABD00022718 Table 5. -- Abbreviations for symptoms of exposure and target organs (Continued) Abbreviation Symptom/organ Abbreviation Symptom/organ FEV........................ ... Forced expiratory volume fib .......................... ... Fibrosis fibrl......................... ... Fibrillation ftg................ ... Fatigue func........................ ... Function Gl .......................... ... Gastrointestinal gidd........................ ... Giddiness halu........................ ... Hallucinations head....................... ... Headache hema...................... ... Hematuria (blood in the urine) hemato................... ... Hematopoietic hemog.................... ... Hemoglobinuria hemorr.................... ... Hemorrhage hyperpig................. ... Hyperpigmentation hypox...................... ... Hypoxemia (reduced oxygen in the blood) inco........................ ... Incoordination incr.......................... ... Increase(d) inebri...................... ... Inebriation inflamm................... ... Inflammation inj ........................... ... Injury insom..................... ... Insomnia irreg........................ ... Irregular/Irregularities irrit.......................... ... Irritation irrity........................ . . Irritability )aun ....................... Jaundice kera........................ ... Keratitis (inflammation of the cornea) lac.......................... lacrimation (discharge of tears) lar ........................ . . Laryngeal lass........................ . . Lassitude (weakness, exhaustion) leth ........................ . . Lethargy (drowsiness or indifference) leucyt..................... ... Leukocytosis (increased blood leukocytes) leupen.................... ... Leukopenia (reduced blood leukocytes) li-head.................... ... Lightheadedness liq ......................... . . Liquid local........................ .. Localized low-wgt................... ... Weight loss mal......................... ... Malaise (vague feeling of discomfort) malnut................... ... Malnutrition methemo................ ... Methemoglobinemia monocy.................. ... Monocytosis (increased blood monocytes) molt......................... ... Molten mucmemb ...... Mucous membrane muse...................... ... Muscle narco...................... ... Narcosis nau......................... ... Nausea (Continued) ABD00022719 Table 5. -- Abbreviations for symptoms of exposure and target organs (Continued) Abbreviation Symptom/organ Abbreviation Symptom/organ nec......................... ... Necrosis neph....................... ... Nephritis ner........................... ... Nervousness numb...................... ... Numbness opac....................... ... Opacity palp........................ ... Palpitations para........................ ... Paralysis pares...................... ... Paresthesia perf.......................... ... Perforation peri neur................. ... Peripheral neuropathy penorb.................... ... Periorbital (situated around the eye) phar........................ ... Pharyngeal photo...................... ... Photophobia (abnormal visual intolerance to light) pneu....................... ... Pneumonia pneuitis .................. ... Pneumonitis PNS........................ ... Peripheral nervous system polyneur................. ... Polyneuropathy prot.......................... ... Proteinuria pulm........................ ... Pulmonary RBC ....................... ... Red blood cell repro....................... ... Reproductive resp........................ ... Respiratory restless.................. ... Restlessness retster .................... ... Retrosternal (occurring behind the sternum) rhin.......................... ... Rhinorrhea (discharge of thin nasal mucus) salv.......................... ... Salivation sens....................... ... Sensitization sez.......................... ... Seizure short....................... ... Shortness sneez ..................... ... Sneezing sol........................... .. Solid soln........................ ... Solution som........................ ... Somnolence (sleepiness, unnatural drowsiness) subs....................... ... Substernal (occurring beneath the sternum) sweat...................... ... Sweating swell ...................... ... Swelling sys.......................... ... System tacar....................... ... Tachycardia tend........................ ... Tenderness terato...................... ... Teratogenic throb....................... ... Throbbing tight ...................... ... Tightness (Continued) xxxv xxxvi ABD00022720 Table 5. -- Abbreviations for symptoms of exposure and target organs (Continued) Abbreviation Symptom/organ Abbreviation Symptom/organ trachbronc............. ... Tracheobronchitis twitch...................... .. Twitching uncon ..................... ... Unconsciousness vap......................... ... Vapor venfib..................... .. Ventricular fibrillation verti........................ ... Vertigo {an illusion of movement) vesic...................... ... Vesiculation vis dist.................... ... Visual disturbance vomit...................... ... Vomiting weak....................... ... Weakness wheez..................... ... Wheezing ABD00022721 Table 6. -- Codes for first aid data Code Definition Code Definition Eye: Irrimmed........ ....... Irr prompt...... ....... Frostbite....... ....... If this chemical contacts the eyes, immediately wash the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately. Contact lenses should not be worn when working with this chemical. If this chemical contacts the eyes, promptly wash the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medi cal attention if any discomfort contin ues. Contact lenses should not be worn when working with this chemical If eye tissue is frozen, seek medical attention immediately; if tissue is not frozen, immediately and thoroughly flush the eyes with large amounts of water for at least 15 minutes, occasionally lifting the lower and upper eyelids If irritation, pain, swelling, lacrimation, or photophobia persist, get medical attention as soon as possible. Medical attention . .. Self-explanatory Skin: Blot/brush away... .. If irritation occurs, gently blot or brush away excess. Dust off solid; water flush......... .. If this solid chemical contacts the skin, dust it off immediately and then flush the contaminated skin with water. If this chemical or liquids containing this chemical penetrate the clothing, promptly remove the clothing and flush the skin with water. Get medical attention immediately. Frostbite .............. .. If frostbite has occurred, seek medical attention immediately; do NOT rub the affected areas or flush them with water. In order to prevent further tissue damage, do NOT attempt to remove frozen clothing from frostbitten areas. If frostbite (Continued) xxxvii xxxviii ABD00022722 Table 6. -- Codes for first aid data (Continued) Code Definition Code Definition Skin (continued) Molten flush immed/sol-liq soap wash prompt....... Soap flush immed . has NOT occurred, immediately and thoroughly wash contaminated skin with soap and water. If this molten chemical contacts the skin, immediately flush the skin with large amounts of water. Get medical attention immediately. If this chemical (or liquids containing this chemical) contacts the skin, promptly wash the contaminated skin with soap and water. If this chemical or liquids containing this chemical penetrate the clothing, immediately remove the clothing and wash the skin with soap and water. If irritation persists after washing, get medical attention. If this chemical contacts the skin, immediately flush the contaminated skin with soap and water If this chemical penetrates the clothing, immediately remove the clothing and flush the skin with water. If irritation persists after washing, get medical attention. Soap flush prompt . If this chemical contacts the skin, promptly flush the contaminated skin with soap and water. If this chemical penetrates the clothing, promptly remove the clothing and flush the skin with water. If irritation persists after washing, get medical attention. Soap prompt/ molten flush immed If this solid chemical or a liquid containing this chemical contacts the skin, promptly wash the contami nated skin with soap and water. If irritation persists after washing, get medical attention. If this molten chemical contacts the skin or nonimpervious clothing, immediately flush the affected area with large amounts of water to remove heat. Get medical attention immediately. ABD00022723 Table 6. -- Codes for first aid data (Continued) Code Definition Code Definition Skin (continued) Soap wash.. If this chemical contacts the skin, wash the contaminated skin with soap and water Soap wash immed.. If this chemical contacts the skin, immediately wash the contaminated skin with soap and water. If this chemical penetrates the clothing, immediately remove the clothing, wash the skin with soap and water, and get medical attention promptly. Soap wash prompt If this chemical contacts the skin, promptly wash the contaminated skin with soap and water. If this chemical penetrates the clothing, promptly remove the clothing and wash the skin with soap and water. Get medical attention promptly. Water flush If this chemical contacts the skin, flush the contaminated skin with water. Where there is evidence of skin irritation, get medical attention. Water flush immed If this chemical contacts the skin, Water flush prompt. Water wash Water wash immed immediately flush the contaminated skin with water. If this chemical penetrates the clothing, immediately remove the clothing and flush the skin with water Get medical attention promptly. If this chemical contacts the skin, flush the contaminated skin with water promptly. If this chemical penetrates the clothing, immediately remove the clothing and flush the skin with water promptly. If irritation persists after washing, get medical attention. If this chemical contacts the skin, wash the contaminated skin with water. If this chemical contacts the skin, immediately wash the contaminated skin with water. If this chemical penetrates the clothing, immediately remove the clothing and wash the skin with water. If symptoms occur (Continued) xxxix ABD00022724 Table 6. -- Codes for first aid data (Continued) Code Definition Code Definition Skin (continued) Water wash prompt Breath: Resp support........ after washing, get medical attention immediately. If this chemical contacts the skin, promptly wash the contaminated skin with water. If this chemical penetrates the clothing, promptly remove the clothing and wash the skin with water. If irritation persists after washing, get medical attention. If a person breathes large amounts of this chemical, move the exposed person to fresh air at once. If breathing has stopped, perform mouth-to-mouth resuscitation. Keep the affected person warm and at rest. Get medical attention as soon as possible. Fresh air................ Fresh air; 100% 0? Swallow; Medical attention immed... If a person breathes large amounts of this chemical, move the exposed person to fresh air at once. Other measures are usually unnecessary. If a person breathes large amounts of this chemical, move the exposed person to fresh air at once. If breathing has stopped, perform artificial respiration. When breathing is difficult, properly trained personnel may assist the affected person by administering 100% oxygen. Keep the affected person warm and at rest. Get medical attention as soon as possible. If this chemical has been swallowed, get medical attention immediately. ABD00022725 CHEMICAL LISTING 1 Chemical name structure/formula, CAS andRTECSNos snd DOT ID snd guide Nos Synonyms trade names, and conversion factors -AcaBe aidehyde, Ethana! Ethyl aldehyde lppmi.eomg/nis " ! ,,< 64-19 7 AF1225000 2790 153(10-60% acid) 2789 132 (>80% acid) compound) Methanecarboxylic acid [Note Can be found m concentrations of 5-8% in vinegar ] 1 ppm = 2 46 mg/m3 Acetone (CH^CO 67-64 1 AL3150000 1090 127 Dimethyl ketone Ketone propane 2 Propanone 1 ppm = 2 36 mg/m3 ABD00022726 Exposure frrrts (TWA unless noted otherwise) DLH Physical description NIOSH Ca See Appendix A . See Appendix C (Aldehydet). OSHAf 200 ppm . (360 mg/m*) C* Cotorte** liquid P000,ppm) or gas (above 69*F) with a pungent, fruity odor Chemical and physical properties MW BP SOL FIR, IP Sp, Gr flammability VP FRZ UEL LEL MW 44 1 BP 69*F Sol Miscible FI P -36*F IP 10 22eV VP- 740 mm FRZ -19Q*F UEL60% LEL 4 0% Sp Gr 0 79 Cuss IA Flammable Liquid NIOSH 10 ppm (25 mg/m3) ST 15 ppm (37 mg/m3) OSHA 10 ppm (25 mg/m3) 50 ppm Colorless liquid or crystals with a sour vinegarlike odor [Note Pure com pound is a solid below 92F Often used in an aqueous solution ] MW 60 1 BP 244F Sol Miscible FI P 103 F IP 10 66 eV VP 11mm FRZ 62F UEL(200F) 199% LEL 4 0% Sp Gr 1 05 Class II Combustible Liquid NOSH 209 ppm C5ppm , ;r - ,> i, i r - - , with a strong, -r (20 mg/m jXjngenL vinegar* $l;Z MW 1021 BP 282'F Sol 12% FIP-120'F IP lOOOeV VP 4mm FRZ. -WF UEL 10 3% LEL 2 7% NIOSH 250 ppm (590 mg/m3) OSHAf 1000 ppm (2400 mg/m3) 2500 ppm [10%LEL] Colorless liquid with a fragrant mint like odor SpGr 1 08 Claw II Combustible Liquid MW 58 1 BP 133 F Sol Miscible FIP 0 F IP 9 69 eV VP 180 mm FRZ 140F UEL128% LEL 2 5% SpGr 0 79 Class IB Flammable Liquid Incompatibilities and reactivities Measursment (SeeTable 1) Strong oxidizers, XAO-2* acids bases, Toluene, alcohols ammonia & GC/FID amines, phenols IV ketones,HCN H,S [*2538] [Note Prolonged contact with air may cause formation of peroxides that may explode and burst con tainers, easily undergoes polymerization ] Strong oxidizers (especially chromic acid sodium peroxide & nitric acid) strong caustics [Note Corrosive to metals ] Char GC/FID Water, alcohoia strong oxidizers (especially chromic ' acid) amines strong caustics (Note Corrosive to iron steel & other motels Reacts with water to form acetic acid] Bub, Reagent, Via, IV 1*3506] Oxidizers acids Char GCfrlD IV [#1300 Ketones 1] Personal protection and sanitation (See Table 3) Skin Eyes. Washskn Remove. Change Provide Prevent sKin contact Prevent eye contact W/hencontam When wet (flamm) NR Eyewash Quickdrench [Acetaldehyde) Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact Whencontam (>10%) When wet or conlam (>10% NR Eyewash (>5%) Quick drench(>50%) [Acetic acid) SMn Prevent sWo contact wSahekin Prevent eye contact When contain Remove. , When wet or conlam Change:' Provide Eyewash, Quickdrench [Acetic enhydnde] Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam When wet (flamm) NR [Acetone] ABD00022727 Recommendations for respirator concentration for use (MUC) (See Table 4) NIOSH * SCBAF PO.PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Route Symptoms (See Table 5) W) Imt eyes nose, throat !Cron eye skin bums derm, conj cough CNSdepree, delayed pulm edema, In animals kidney, mm. terato effects, (care) ' NIOSH/OSHA 50 ppm SACF(PAPROVcfCCRFOV/ GMFOV/SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE inh Irrit eyes skin nose Con throat eye skin bums skin sens dental erosion black skin hyperkeratosis conj lac phar edema chronic bron Health hazards First aid (See Table 6) Target organs (See Tables) i Breath Swallow- irrimmed Water flush prompt Rasp support Medical attention immed Eyes, akin, resp ays, kidneys, CNS, reproeys [inemmals nasalcancer] s Eye Skin Breath Swallow Irrimmed Water flush immed Resp support Medical attention immed ' Eyes skin resp sys teeth NIOSH/OSHA Ml 125 ppm' 8A.CF*i/PAPRO\/* ing -200 ppm. CCRFOV/GMFOV/PAPRTOV^ Con ' SCBAF/SAF i | SCBAF'PD.PP/SAF PD.PPJtSCBA Escape' GMFOV/SCBAE Con) lac, com edema opec, photo1 nasal phar irrit: cough dyap, bran, skin buma, veMc, eece dorm NIOSH 2500 ppm CCROVVPAPROV /GMFOV/ SA /SCBAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE hh Ing Con Irrit eyes nose throat head dizz CNSdepres derm i Irrimmed Eyes, skin, fleap*]^',' Water flush Immed - Breath Reap support Swallow > Medical mention - ` t-V* i * knmed <f * -> >, Eye Skin Breath Swallow ;~f Irr immed Soap wash immed Resp Support Medical attention immed Eyes skin resp sys CNS O o Chemical name, structure/lormula CAS and RTECS Nos and DOT ID and guide Nos Synonyms trade names and conversion factors Aeaton* cyanohydrin CH,C(OH)CNCH, 75464 000276000 Cyaoohydrin-2-propanone, 2-Cyano-2-propanot, a wdroxwsowtyronJtrUo, 2-Hydfoxy-2-mthyL proptontirfla, 2-Methyllaetonilriie 18*US5(*(abfe0d) - 1ppm<348m9ftn* Acetonitrile CH CN Cyanomethane Ethyl nitrile Methyl cyanide 75-05-8 AL7700000 1648 131 2-Ac*tyiaminofluoran* 63-98-3 A69450000 1 ppm = 1 68 mg/m3 AAF 2-AAF. 2-Ac*tamlnofluorene, N-Acetyl-2-#mlnoftuorene FAA, 2-FAA, 2-Fluorenylacetamide Acetylene HCbCH 74 86 2 A09600000 1001 116 Ethine Ethyne [Note A compressed gas used m he welding S cutting of metals ] 1 ppm - 1 06 mg/m5 ABD00022728 Exposure limits (TWA unless noted otherwise) IDLH Physical description NiOSH Cl ppm (4 malm*) [16-mmJ OSHA nona -` NO Coteries# liquid with a taint odor ot Uttar almond [Nota Forma cyanidein Bta > * * > < body l 'i * Chemical and physical properties MW BP SOL FI P, IP Sp Gr, flammability VP FRZ UEL, LEL Incompatibilities and reactivities Measurement method (See Table 1) BP 203*F Sol Miscible ~ FIP-165T* IP? " FRZ.-4'F - eausttc* . 7 K-.EthyT- v'- UBL12.0* . {Note StoMjTvV' ,`-TaQatata;^ : LEL22* v - , decompoaeito GC/NPO;'/- ? , catoneiHCNat; 'IV. , rr- ^ y ?.faunjncraaaeteptfc NIOSH 20 ppm (34 mg/m3) OSHAt 40 ppm (70 mg/m5) 500 ppm NIOSH Ca See Appendix A Ca IN DJ OSHAI191010141 Sa Appendix B NIOSH L- ^t>uu ppm (2662 rng^m3) OSHA none ND Colorless liquid with an aromatic odor [Note Forms cyanide in the body ] MW 41 1 BP 179*F Sol Miscible FIP(OC) 42 F IP 12 20 eV VP 73 mm FRZ -49*F UEL 16 0% LEL 3 0% Strong oxidizers Char Benzene GC/FID IV [#1606) Sp Gr 0 70 Class IB Flammable Liquid Tan, crystaSne ' powder (* MW 2233 . 5 BP-?V ,* r ; ' Sohtmohibta/ FIP ? IP-? yp-7 1 - !MLT.38t*R' , UEIC? LEL ? , . Non* reported ' Non* " As ` 'tvadable , ,' ^ ' 4 , ' * . . * >r f, v ' -, ' ' SpQr? . Combustible Solid . -- Colorless gas with a faint ethereal odor [Note Commercial grade has a garlic like odor Shipped under pressure dissolved m acetone ] MW 26 0 BP Sublimes Sol 2% FIP NA (Gas) IP it 40eV RGasD 0 91 Flammable Gas VP 44 2 atm FRZ 119 F (Sublimes) UEL 100% LEL 2 5% Zinc oxygen & other oxidizing agents such as halogens [Note Forms explosive acetyNde compounds with copper mercury silver & brasses (containing more than 66% copper) ] Bag none GC/FID NIOSH Acetylene Cnt Doc Personal protection (See Table 3) Sldn. Prevent aldn confect , Eye*. -Prevent eyecontact/ - Washtkkv Wheneorwnr' Remove- When wet or content m. 'fjwh,<W9k*Wc6': tAcjfotw.cyanohydrio]-IC *nk. Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet (flamm) NR Quick drench [Acetonitrile] ABD00022729 Recommendations for respirator concentration for use (MUC) (See Table 4) >osh 40 ppm. SA <' 25 ppm SA.CF > t *, ,, -50 ppm SC8AF/SAF jy v 260 ppm SAF.PD.PP -* f-SCBAF-PD PP/SAF POPP-ASCSA.< Escape; GMFOV/SCBAE i' f Route Symptoms (See table 5) to tmteyee, Win, ruptyo, Abo dfzz, weak, head, com, tng qqnvula (Ivor, kidney Ink* 'Con, j>ulmedema,asphy,L j, t Health hazards First aid (See Table 6) Target organs (See Table 5) Breath Swallow Water flush Immed Reap support sMedfeal attention pitied'" >K A ` J- -! CNS;' CVS, liver. 1 kktoeya. 61 hie*' *-> - iv " . . v? &r '5n , *' \*<-v NIOSH 200 ppm CCROV/SA 500 ppm SA CF/PAPROV/CCRFOV/ GMFOV/SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Inh Irnt nose throat asphy APS nau vomit chest pain Ing weak stupor convuls Con in animals liver kidney damage Eye Skin Breath Swallow t'. Immmed Water flush immed Resp support Medical attention immed Resp sys CVS CNS liver kidneys 5 Skin Eyes Wash skin Remove Change Provide Frostbite Frostbite NR When wet (flamm) NR Frostbite [Acetylene] TBAL Inh Head dizz asphy Con liq frostbite (I'd) Eye Breath Frostbite Fresh air Chomlctl name, structure/formula CAS and RTECS Nos and DOT ID and guide Nos Synonym* trade names and conversion factors Acrtytam ttrabromidt CHPr^Hfer, 7*27-8 Ki822SODO SymmoWetl tetnbromottfuM. TBE. Tetoabremoaeatytene; Tttmbnmortarm, 1,1,2,2-TatrabromMthftffe &M 160 Acetyisalicydic acid ChjCOOCjH.COOM 50 78 2 V00700000 'l ppmT4 I4mg/m* Acelal o-Acetoxybenzoic acid 2 Acetoxybenzoic acid Aspirin Acrolein CH,-CHCHO 107-02-5 AS1050000 Acraldehyde. Acrylaldehyde, Acrylic amhyda, AByi aldehyde Propenal, 2-Propenal 1082 131P(lnhlb#a<1) Acrylamide CH =CHCONH 79 06 1 AS3325000 1 ppm 2 29 rng/mJ Acrylamide monomer Acrylic amide Properi amide 2 Propenamide 2074 153P Exposure ftmte (TWA unless noted otherwise) NIOSH Sm Appendix D OSHA <l9mgftn^ NIOSH 5 mg/m5 OSHAT none NOSH 01kTmgtot*) kT*20i 3| (0 8 See Appendix C %SSf> 0 1 ppm (025 mgfm*) NIOSH Ca 0 03 mg/ms [skin] See Appendix A OSHAt 0 3 mg/m5 [skin] ABD00022730 IDLH B ppm, ND 2 ppm- Physical description Chemical and physical properties MW BP SOL FI P, IP, Sp, Gr flammability VP FRZ UEL, LEL Incompatibilities and reactivltlas Measurement method (See Table 1) Pfcte-yeDow liquid with s pungant odor slmUar to camphor or iodoform [Note- A aolld t below 32*f 1 MW-345? VP-0.02mm BP 474*P - FR2.-32*F (Dacompoaaa) UELNA , Sol 0 07% LELrNA FIP NA 'l'. IP? ^ ?' ) f'Strqng e*uUcar' +*}. `StAab^" hqt (ron.-Jodoeing -i r. THF. `-1.. p , nSmw&ifS' > - O&FK^V atumhum.irngonksii^? IV -`V'* . r'Stfno , ,> [#20031^ , j ' ' ***`si&?}**\&,5&> Odorless colorless to while crystal line powder [aspirin] (Note Develops the vinegar like odor ot acetic acid on contact with moisture ] POr 297 s r Honconibuattoia tiquM --' ' w v. r < ' > ~ ... i-r.j.if.. MW 180 2 BP 284 F (Decomposes) VP 0 mm (approx) Solutions of alkali hydroxides or carbonates strong Sol(77 F) UEL NA oxidizers moisture 0 3% LEL NA [Note Slowly FI P NA MEC 40 g/m3 hydrolyzes in moist IP NA air to saiicyclic & acetic acids ] Sp Gr 1 35 Combustible Powder explosion hazard it dispersed m air Filter none Grav [#0500 Particulates NOR (total)] Coiorlees or yellow liquid with a piercing, disagreeable odor MW 561 BP-127'F Sol 40% FIP--1S*F -IPM013aV ''FRZ.-120*F UEL 31% LEU 28% So Or 064 Ciaes IB Plemmabte Uquk] oiMUart^aekte XAO-2`. alkalis, anyrwnte, ** r Toluene, amlrtM- GC^JPO; [Note- Potymartrear- 'IV . iwdiKrunteas ' - (#2601) .. Inhibited' usually'' - with hydroqulnone . May form shock- ` sensitive paruddaa over time ] f, A Ca White crystalline [60 mg/m3) odorless solid MW 71 1 VP 0 007 mm BP 347 572 F MLT 184 F (Decomposes) UEL 7 Sol(86 F) LEL 7 216% PI P 280 F IP 9 SOeV Sp Gr 1 12 Combustible Solid (may also be dissolved in flammable liquids) Strong oxidizers [Note May polymerize violently upon melting ) Filter/ Si gel Methanol GC/NPD OSHA (421] Personal protection (See Tcble 3) Skm, > Prevent tldn contact Eyes. " Prevent eye contact wash akin. Whencontam Remove' When wet or contam Change- NR [Acetylene tetrabromtde] Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact Whencontam NR Daily Eyewash Quick drench [Acetylsatycyhc acid] Skin. Eyes. Wash skin Remove Change Provide Prevent skin contact Preventeye contact Whencontam When wet (flamm) NR Eyewash, Quickdrench (Acrolein] Skin Eyes Wash skm Remove Change Provide Prevent skin contact Prevent eye contact When contam/Daily When wet or contam Daily Eyewash Quick drench [Acrylamide] ABD00022731 Recommendations for respirator concentration for use (MUC) (See Table 4} OSHA 6 ppm SA/SCBAF SCBAF PD.PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Route Symptoms (See Table S) Inh Irrteyes, nose, anor, , Ing nau, severe heed, abdom Con pain, Jaun, monocy, CNS TBAL im Ing Con Imteyes skin upper resp sys incr blood Clotting time nau vomit liver Kidney inj Health hazards First aid (See Table 6) Target organs (See Table S> 8ft. ^ (trimmed - .Eyes,reways t.'-aSS .. Water flush prompt-. Uver.CNS,? ' J&HE&Breath- Swallow- ' s. vS} Eye Skin Breath Swallow Irr immed Soap wash Resp support Medical attention immed Eyes skin rasp sys blood liver kidney 7 NIOSH/QSHA 2 ppm SA CF*/PAPROVfCCRFOVI GMFOV/SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE M? lrtHe)&9,.sklff,mta 9 nwmb.dacrpumfunc. Con delayed pulm edema, chronic resp disease NIOSH S SCBAF PD PP/SAF PO PP ASCBA Escape GMFOV/SCBAE Inh Abs Ing Con Imteyes skm ataxia numblimbs pares muse weak absent deep tendon reflex hand sweat ftg leth repro effects [care] Breath " Swallow- Itr Waned * * E/rt, Waterflusblramed- heart , Respsupppft Medical atten&on 'f r romed - `v V t Eye Skin Breath Swallow % . -, - ^4 irr immed Water flush rmmed Resp support Medical attention immed Eyes skin CNS PNS repro sys [in animals tumors of the lungs testes thyroid & adrenal glands] ABD00022732 Chemical name stnictureJformula, CAS and RTECSNos and DOT ID and guide Nos Synonyms, trade names and conversion (actors Exposure limits (TWA unless noted otherwise) IDLH Physical description Chemical and physical properties MW BP SOL FI P IP Sp, Gr flammabllrty VP FR2 UEL LEL Incompatibilities and reactivities Measurement method (See Table 1) Acrylic add CH,"CHCOOH 79-10.7 AS4375O00 2210 132P (inhibited) (technical grade is 94%), -Glacial acrylic acid (96% in aqueous solution), 2-Pfopenoic add ,* 1 ppm = 2 95 mg/m3 NIOSH 2 ppm (6 ma/mJ) [skin] OSHAt none NO Colorless liquid or MW 72 1 VP 3 mm Oxidizers amines XAD(2) oW (below S5"F) BP 286`F FRZ 55`F alkalis ammonium Methanol/ with a distinctive Sol Miscible UEL 8 02% hydroxide chloro- Water acnd odor FIP121*F LEL24% sulfonic acid oleum HPLC/UVD [Note Shipped with IP ? ethylene diamine. OSHA an Inhibitor ethyienefcnne (#28) (e g hydro- 2-amuioethanol qulnonejslnce [Note Corrosive to i It readily Sp Gr 1 06 many metals] polymerizes ] Class II Combustible Liquid Acrylonitrile CHj"CHCN 107-13-1 8 AT5250000 Acrylomtnle monomer AN Propenemtnle 2-Propenemtnle VCN Vinyl cyanide 1093 131P (inhibited) 1 ppm = 2 17 mg/m3 NIOSH Ca 1 ppm C 10 ppm[15 mm) [skin) See Appendix A OSHA[1910 1045] 2 ppm C lOppm [15 mm) [skin) Ca [66 ppm] Colorless to pale yellow liquid with an unpleasant odor [Note Odor can only be detected above the PEL ] MW 53 1 BP 171F Sol 7% FI P 30F IP 10 91 eV VP 83 mm FR2 116F UEL 17% LEL 3 0% Sp Gr 0 81 Class IB Flammable Liquid Strong oxidizers Char acids & alkalis Acelone/ bromine amines [Note Unless inhib GC/^IO ited (usually with IV methylhydroquinone) may polymerize spontaneously or when heated or m presence of strong alkali Attacks copper] Adlponltrile ` * tn-dw AV2625000 2206 153 , 14-Oicyanobutans Tetramethylene cyanide *v -- -, 1 ppm = 4 43 mg/ro3 NIOSH (1fmg/m*) OSHA none NO Water-white, MW- 108.2 VP 0 002 mm Oxidizers (e g Char practically BP 563'F FRZ 34*F perchlorates, Toluene odorless, oily Sol 4.5% ua_6o% nitrates) strong GC/FID liquid [Note A solid *pm ia.17% acids (e g sulfuric acid] NIOSH Nitriles below 34*F ip? [Note Decomposes Crtt Doc Forms cyanide above 194*F forming In the body] hydrogen cyanide ] Sp Gr 0 97 Class HIA Combustible Liquid Aldrin C13H,Clfl 309 00 2 102100000 2751 151 1 2 3 4 10 10-Hexachioro 1 4 4a 5 6 8a hexahydro endo-1 4-exo 5 8 dimethanonaphthaiene HHDN Octaiene NIOSH Ca 0 25 mg/m3 [skin' See Appendix A OSHA 0 25 rng/mJ [skin] Ca [25 mg/m3] Colorless lo dark Crown crystalline solid with a mild chemical odor [Note Formerly used as an insecticide ] MW 364 9 BP Decomposes Sol 0 003% FI P NA IP ~ VP 0 00008 mm MLT 219 F UEl NA lEl NA Concentrated mineral acids active metals acid catalysts acid oxidizing agents pneno Filter/Bub isooctane GC/EConD ill [#6502) Sp Gr 1 60 Noncombustible Solid but may oe dissolved n flammable liquids Personal protection (See Table 3) Skin Eyes Washskui Remove Change Provide Prevent skin contact Prevent eye contact Whencontam When wet or contam NR Eyewash Quickdreneh (Acrylic acid] Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet (flamm) NR Eyewash Quick drench [Acrylonitrile) Skin Eves Wash skin Remove Change Prevent skin contact Prevent eye contact Whencontam When wet or contam Daily [Adipomtrlle] SKin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam/DaNy When wet or contam Daily Eyewasn Quick drench [Aldnn] ABD00022733 Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table 4) TBAL Route Symptoms (See Table 5) Wi Abs Ing Con Imt eyes skin, rasp sys eye skin bums skin sens, mammals lung liver, kidney in] Health hazards First aid (See Table 6) Target organs (See Table 5) is. Breath Swallow' Irrimmed Water flush immad Rato support Medical attention immed Eyes, akin, reap aya NIOSH SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Inh AOs Ing Con Imt eyes skin asphy head sneez nau vomit weak li-head skmvesic scaling derm [care] Eye Skin Breath Swallow Irrimmed Water wash immed Reap support Medical attention immed Eyes skin CVS liver kidneys CNS (brain tumors lung & bowel cancer) NIOSH 40 ppm SA 100 ppm SA CF 200 ppm SCBAF/SAF ISO ppm SAF PO.PP SCBAF PO,PP/SAF PD PP ASCBA Escape GMFOV/SCBAE NIOSH SCBAF PD PP/SAF PD PP ASCBA Escape GMFOVHiE/SCBAE W> Abs Ing Con Inn skin rasp sys head, dis weak, gkfd, conf convuls blurred vision dysp, abdom pain, nau, vomit Eye; Sm Breath* Swallow Irrimmed Soap wash Immed Reap support Medical attention irnmed Inh ADS Ing Con Head di2z nau vomit mal myoclonic jerks of limbs clonic tome convuls coma hema azotemia (oarej >' Eye Skin Breath Swallow ' Irrimmed Soap wash immed Resp support Medical attention immed Cancer CNS liver kidneys skin [mammals tumors of the lungs liver thyroid & adrenal glands] ABD00022734 Chemical name, structure/formula CAS and RTECSNos, and DOT 10 and guidsNos Synonyms trade names, snd conversion factors A2yt tkaM QVWipH BA5Q7W00 > -wvr : ^ <\m**\ : Aliyi chloride CH,"CHCH,Cl ** 107-05-1 UC7350000 AA. -Alyfc alcohol, . -, Propertol, ' * t-PropaiKM, > 2-Propenol, 'v^flnyl paitpot `j.` +! r v*, i- ' . > r J* 'tppn}2.38mg/m* 3 Chloropropene 3 Chloropropylene 1100 131 1 ppm * 3 13 mg/m3 Exposure Imfls (TWA unless noted otherwise) NJOSH 2 ppm (ematoi5) ST 4 ppm (10 mgftn3) lWn) OSHAf 2 ppm <5 mate*) NlOSH 1 ppm (3 mg/m3) ST 2 ppm (6 mg/m3) OSHAT 1 ppm (3 mg/m3) IDLH 20 ppm Physical description Colorima Squid with a pungent, muatard-Hw odor Chemical and physical properties MW BP SOL FI P IP Sp Gr flammability VP FRZ U EL, LEL MW 581 BP 205*F Sol Miadble R P" 70'F IP 963 aV VP-17mm FRZ. -200*F UEL.180% LEL25% 250 ppm Colorless brown yellow or purple liquid with a pungent unpleasant odor SpGrOBS Cum IB Flammable Liquid MW 76 5 BP 113*F Sol 0 4% IP 10 05 eV VP 295 mm MLT 210 F DEL 11 1% Sp Gr 0 94 Class IB Flammable Liquid AfetglycfcttMfwr. /AGE. . "NOSH `-'.SO ppm 4 Colorless liquid , . 3`'-v' 'i1-A#ytoxy-2,3-tpoxypfop'a; \ 6 ppm < IvaWiaptoaABit ' ti / \ '-4GlwwylaHylether,- & -r.y ttzmg/m*)' *f, j_ v n* Aof*ieisrr ' 106-92-3 ,J? &f! .M\AM14 2 _BP- 309*F Sot 14% sWmSrjWwpFj/1:>>'r/V';'y'$$$wv,, **?i' \vv , 22J9129' <L OSKAf CIO ppm tppma,4J?flWtn#: '5'-.*' FRZ.-148V [forms glass] AJIyl propyl disulfide 4 5-Dithia 1-octene NlOSH N D Pale-yellow MW 148 3 VP 7 Onion oil 2 ppm liquid with a BP 7 FRZ 5*F HXCHCH.S,,CH.CH,CH. 2 Propenyl propyl disulfide (12 mg/m3) strong & irritating Sol Insoluble UEL ' Propyl ally! disulfide ST 3 ppm onion like odor FI P 7 LEL ' 2179-59-1 (18 mg/m3) [Note The chief IP 7 J00350000 volatile component OSHAf of onion oil) 1 ppm 6 07 mg/m3 fl^mg/m3) Sp Gr(59*F) 0 93 Combustible Liquid Incompatibilities and reactivities Measurement method (See Table 1) Strong oxidlzem acids, carbon tetrachloride [Note Polymerization may be caused by elevated tempera tures oxidizers, or paroxklesj Chan 2-Propanol/ GC/flD, IV [#1402, Alcohols III] Strong oxidizers acids amines iron & aluminum chlondes magnesium zinc Char Benzene GC/FIO J#1000] Strong oxidizers DMwl0ttr, GC/FIO, IV [92545] Oxidizers None available Personal protection and sanitation (See Table 3) Skin Eyes Wash skin Remove Change Provide Prevent skm contact Prevent eye contact When contam When wet (flamm) NR Quick drench (Allyl alcohol] Skin Eyes Wash skin Remove Change Pro de Prevent skm contact Prevenl eye contact When conlam When wet (flamm) NR Ou'CK drench [Allyi chloride] ABD00022735 Recommendations tor respirator selection -- maximum concentration for use (MUC) (See Table 4) Route Symptoms (See Table 5) NtOSH/OSHA 20 ppm SACF'/PAPROWCCRFOV/ GMFOV/SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Wi Eye imt, tissue damage Ab8 Imt upper resp sys Ing skm.pulm edema Con r NIOSH/OSHA 25 ppm SAOf 50 ppm SCBAF/SAF 250 ppm SAP PD PP | SCBAF PD PP'SAF PD PP ASCBA Escape GMFOV'SCBAE Inh Abs Ing Con Irriteyes skin nose mucmemb pulm edema mammals liver kidneymj Health hazards First aid (See Table 6) Target organs (See Table 5) Ey*. Skip Breath Swallow Irr Immed Water flush Immed Resp support Medical attention Eyas skin resp sys <" Eye Skm Breath Swaiiow - Irr immed Soap wash immed Resp support Medical attention immed Eyes skin resp sys liver kidneys 11 Skm Eyes Wash SKir Remove Change ki R Rre.e- eye contact NR When wet or contam NR [Allyl propyl diSul'ute] TBAL irh ing Con imt eyes nose resp sys lac Eye Skin Breath Swallow Irr immed Soap wash immed Resp support Medical attention immed Chemical name structureiformula CAS and RTECS Nos and DOT ID and guide Nos Synonyms trade names and conversion factors Exposure limcts (TWA unless noted otherwise) a-AJumma Al}j 1344-28-1 8D1200000 Alumina, Aluminum oxide Aluminum tnoxkle [Note a-Alumina Is the mem component o1 tech mcel grade alumina Corundum it natural AI2Oy Emery Is an mipure crystalline variety of ai2o93 NIOSH See Appendix D OSHAt ISmg/rn5 (Iota!) 5 mgfr?i* (reap) Aluminium Aluminum metal Al Aluminum powder klementaJ aluminum 7429 90 5 BD0330000 1309 170 ipowder coaled) 396 38 powder uncoated 9260 6S imoter i NIOSH 10 mg/m3 (total) 5 ing/m' OSHA 15 mg/m5 'total) 5 mgirn' l esp Aluminum (pyro powders and welding 11/me* as Al) Synonyms vary depending upon the specific aluminum comoound . NIOSH 5 mg/m5 OSHAt none ABD00022736 IDLH Physical description ND White odorless crystalline powder Chemical and physical properties MW, BP SOL FI P IP Sp Gr flammabllrty VP FRZ UEL.LEL MW 101 9 6P 5306'F Sol Insoluble FiP NA IP NA VP Omm (approx) MLT 3632*F UEL NA LEI NA SpGr 4 0 Noncombustible solid but dusts may form explosive mixtures In air N D Silvery white MW 27 0 VP 0 mm malleable ductile BP 4221 F (approx) odorless metal Sol Insoluble Fl P NA MLT 1220 F UEL NA IP NA LEL NA SpGr 2 70 Combustible Solid finely divided dust is easily ignited may cause explosions NO Appearance and odor Properties vary depending vary depending upon upon Ibe specific aluminum the specific compound aluminum compound Incompatibilities and reactivities Measurement method (See Table 1) Chlorine trifluonde hot chlorinated rubber, acids oxidizers [Note Hydrogen gas may be formed when finely divided iron contacts moisture dunng crushing & milling operations ] Filter hone, Grav, IV [Particulates NOR #0500 (total) #0600 (rep)J Strong oxidizers & Filter acids halogenated hydrocarbons HNO, faa [Note Corrodes in IV contact with acids 8 [#70131 other metals ignition (Also #7300 may occur if powders Elements] are mixed with halogens carbon disulfide or methyl chloride ] Varies Filter HNO, ICPIV [#7300 Elements] 1363 135 (powder, pyrophoric) Aiummum (soluble salts and alnyis as Al Synonyms vary depending upon the specific aluminum compound NIOSH 2 mg'm OSHAT none 3051 135 ialky's N 0 Appearance and odor Properties vary depending vary depending upon upon the specific aluminum the specific compound alummjm compound Varies Filter HNO, FAAS IV r#T0* 3 Aluminum] [Also #7300 Elemen s] Personal protection and sanitation (See Table 3) SKin Eyes Wash skirt Remove Change NR NR NR NR NR [a-Alumina] Skin Eyes Wash skin Remove Change NR NR NR NR HR ABD00022737 Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table 4) TBAL Route Symptoms (See Table S) Inh Imt eye* skin, rasp sys Inj Con TBAL - Inh imt eyes skm resp sys Con Health hazards First aid (See Table 6) E>* Skin Breath Swallow Irr immed Blot/brush away Fresh nr Medical attention Immed Target organs (See Table 5) Eyes skm, resp sys `\ Eye B'eatr - Irr immed Fresh ar Eyes skin resp sys [Aluminum] SUn Eyas Wash skm, Remove Change; NR NR. NR N R. NR.' J. > i ' - ' ' --t -\ ' TBAL ", (AJumlnurn (pyra powders and wekkng fume*, as Ai) ** Skin Eyes Wash sk n Remove Cnange Prevent skm contact Prevent eye contact When contam VVhen wet or contam Dairy TBAL (Aluminum soluble salts anc alkyis as All) Wi Irnt skin, resp sys pulm fib ' |j. , Wimmed Skin,-'resp sys Waterflush Imrped - Oon ,, ` ` Breath " Resp support ' , i' __ Swalloyr - Medical, attention - * C Immed .' i r l 'j'**, ^ ' 'ey 1 t) a "^ \ ` fr *Xl ^ , 1 *v> '! ' O1. x - h Inh Con Imt skin resp sys skin burns Eye Skm Breath Swallow Irr immed Water Push immed Resp support Medical attention immed Skin resp sys Chemical name structure/formula CAS and RTECS Nos and DOT 10 and guide Nos Synonyms trade names and conversion factors 4-Aminodiphenyl C.H.C.H.NH, 92-67-1 DU8925000 4-Amlnoblphenyl, p-Amlnoblphenyl , p-Ammodiphenyl, 4-PhenylanlIirie 2 Aminopyridme Nh C-H/l 504 29 0 US'575000 .. ' u Ammopyfidme a Pyndylamine - Exposure limns (TWA unless noted otherwise) N10SH Ca See Appendix A OSHAI101O1O111 See Appendix B ABD00022738 IDLH Physical description Ca [N D ] Colorless crystals with a floral odor (Note Turns purple on contact with air] Chemical and physical properties MW BP SOL FI P IP Sp Gr flammability VP FRZ UEL LEL MW 109 2 BP 576*F Sol Slight FIP ? IP ? VP(227*F) 1 mm MLT 127*F UEL.? LEL 7 Incompatibilities and reactivities Oxidized by air Sp Gr 1 16 Combustible Solid but must be preheated before ignition possible NIOSH/OSHA 0 5 ppm i2 mg'm > 5 oom vVhi e powder leaflets or crystals with a characteristic odor MW 94 1 BP 4H F Sol 00 o FI P 154 F IP 8 0C eV VP'7 F. 0 8 --m ml'' 37 f UEL ~ LEL " at eng dxidzers Measurement method (See Table V Filter/ Si gel 2-Propanol GC/FID, 11(4) [P&CAM TenaxGCi2i Thermal desorp Mid #S158] 2671 153 1 ppm * 3 85 mg/m3 w - 61-62-S KZ3850000 * .i" Amtnotriazole, ^ S-Amlnotriazole, - -i 2-Amino*1,3 4-tnazoIe, .. "* ** - '> Arn -- onia NH, 7664 41 7 B00875000 1005 125 (anhydrous) 2672 154 (10 35% sold j 2073 125 (>35 50%soln ) 1005 125 (>50%soln ) Anhydrous ammonia Aquaammon a Aqueous ammonia (Note Often used in an aqueous solution ] 1 ppm = 0 70 mg/m3 NOSH ' q, v Ca 0 2 mo/m3 ' Sea Appendix A ' OSHAf ' , NIOSH 25 ppm 119 ST 35 ppm (27 mg/m3) v OSHAT 50 ppm (35 rng/m1) Ca ~ [NO], - 300 ppm Colorless to white crystalline powder Ihertrlcidel (Note Odorless when purs ] Colorless gas with a pungent suffo eating oOor [Note Shipped as a liquefied compressed gas Easily liquefied under pressure ) Sp Gr 7 Combustrbie Solid MW 84 1 BP 7 SoK77*F) 28% FLP NA IP 7 VP <0000008 mm MLT 318*F UEL NA LEL NA SpGrl 14 Noncombustible Solid but may be dissolved in flammable liquids Light (decomposes) strong oxidizers [Note Corrosive to Iron, aluminum & copper] Filter; 'none Gray IV [40500, Particulates NOR (total)J MW 17 0 VP 8 5 atm St ong oxidizers S ge1 BP 28 F FRZ 108 F acids halogens Water So) 34% UEL 28% sails o) silver 8 Vis FI P NA 'Gasi LEL 15% Zinc 'V IP 10 18eV [Note Corrosive to copper & galvanized surfaces) (#601 51 [Also #6016] RGasD 0 60 (Note Although NH , does not meet the DOT definition of a Flammable Gas (tor labeling purposes) it should be treated as one ] Personal protection (See Table 3) Sian Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam/Daily When wet or contam Daily Eyewash Quiekdrench [4-Amlnodiphenyl] Skin Eyes Wash skm Remove Change Rrov ce Prevent skm contact Pievent eye contact When contam V'lheri wet or contam Can, Quick cre'ch [2 Ammopyi'I^ine' Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact Daily When wet or contam Daily Eyewash Quiekdrench [Amitrole] Skm Eyes Wash skin Remove Change Provide Prevent sk n contact Prevent eye contact When contam (soln) When wet or contam (soln) NR hyewash(-'1Q%) Quick drench i >10%) [ATfr'Oflldl ABD00022739 Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table 4) NIOSH SCBAF PD,PP/SAF PD PP ASCBA Escape HiEF/SCBA Route Symptoms (See Table 5) hh Aba Ing Con Head, dizz; lath dysp ataxia, weak. methemo, urinary tjcmmg acute hemorrhagic cystitis, {care} Health hazards First aid (See Table 6} K Breath Swallow. trrimmed Soap wash immed Rase support Medical attention Jrrmed Target organs (See Table 5} Bladder skin [bladder cancer] NIOSH/OSHA 5 ppm SA /SCBAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOVHiErSLBAB inn Abs Ing Con Irrit eyes nose throat head dizz excitement nau high BP resp distress weak convuls stupor '' , Eye Skm Breath Swailow Irr immed Water flush immed Resp support Medical attention immed CNS resp sys NfOSH Inh Irrit eyes, skin, dysp SCBAF PD PP/SAF PD PP ASCBA *. Ing muse spasms, ataxia, anor, f Escape GMFOVHIE/SCBAE Con salv, Incr body temperature lass skJn dryness depres. (thyroid, func suppression) NIOSH 2S0 ppm CCRS (SA 300 ppm SA CF/PAPRS /CCRFS/ GMFS/SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFS/SCBAE \ inn Irrit eyes nose throat ing Cysp bronspas chest (soln) pain pulm edema pink Con frothy sputum skin burns (soln; vesic liq frostbite liq) Eye; Skin - Breath, Swallow trr Immed - .Waterwash Imm^d 1 Resp support ' .Medical anantton- ^ tenart ^ w " 1 Eyes, skin,thyroM [In anlmair. liver, thyrWd & pituitafy glandtumqrsj- , j <,' A % i- - .' * 'V * k V, i - ' Eye Skin Breath Swallow Irr immeo (soln/liqj Water flush immed (soln/liq) Resp support Medical attention immed (soln) Eyes skm resp sys 16 Chemical name stcucturei'foimu/a and DOT ID and guide Nos Synony ms trade names and conversion factors Ammonium chlonde fume NH^CI Ammonium chloride Ammonium muriate fame, Sal ammoniac fame 12125-02 9 BP455O0Q0 Ann-onium su'fanate NH4OSC NH 7"3 36 C <*061253Cu Animate herCic de Ammonium amiOosj fOnate AMS Monoami 1UI IU sail of suitam c ac d Suitamate 936s ' n-Amyl acetate CHjCOOJCHjl^CH, 628-63-7 AJl925000 Amyl acetic ester Amyl acetic ether 1-Pentanol acetate Pentyl ester of acetic acid Primary amyl acetate 1104 129 sec Amy ace ale CH,COUL.Hi.H - H 625 33 . AJ2 30C30 1 ppm *6 33mg/m* Methyiputyl ace'ate 2 Pentanci acetate 2 Pert, es er o' aceiic acd i 04 129 1 ppm = 5 33 mg/m ' Exposure liras (TWA unless rioted otherwise) NIOSH lOmgAn3 ST 20 mg/m3 OSHAt none NlOSri 10 mg m to'd i C my in' nest OSHAt 5mg.m tota i 5 mg m esc NlOSH/OSHA lOOppm (525 mg/m1) ABD00022740 IDLH Physical description NO Finely divided odorless white particulate dispersed In air Chemical and physical properties MW BP SOL FI P IP Sp Gr flammability VP FRZ UEL LEL MW 53 5 BP Sublime* Sot 37% FI P NA IP NA VP(321'F) 1 mm MLT 662'F (Sublimes) UEL NA LEL NA 1 500 rg m' Co or ess to vine c-ystalln e ocoress soiid -ert cide, SpGr 153 Noncombustible Solid M.V 114 B-5 320 F (Decomposes i So 233a FI P NA JP C ~m ajproj MLT ?pe F d = l N- Lf L NA 1000 ppm Colorless liquid with a persistent banBna-llke odor Sp Gr 1 7 Nonccmpjst bits So id MW 1302 BP 301 `P Sol 0 2% FIP 77 F IP ? VP 4 mm FRZ. 95*F UEL 7 6% LH.11% N OSH CSHn ibC mg 1000 ppm Ccloriess liquic will a mild odo Sp Gr 0 86 Class 1C Flammable Liquid WA 130 2 249 So Snght FI P 89*F IP 7 2P 7 mn -RZ 135 F JL ' S-\ LEL 1 ,, Sp Gr 0 87 C ass iC Flammable L iqu>o Incompatibilities and reactivities Measurement method (See Table 1) Alkalis & their carbonates lead & silver salts strong oxidizers ammonium nitrate potassium chlorate bromine trifiuonde [Note Corrodes most metals at high (i e fire) temperatures) Filter Water 1C OSHA [tfIDiesi mc ds hot *va er Note Eie.ateu temperatures cause a t ign y exotherm u eaction vri n *ater Filter Aate IC ii 5i (#S34 81 Nitrates strong Oxidizers alkalis & acids Nitra es St ong oxidizers a kalis & acids Char CS, GCJFID, IV {*1450, Esters 1] [Also #2549 VOC* (screening)] Char CS GC?FID 1J f#145C Lste s l' Also #2549 vOCs (Screening)1 Personal protection (See Table 3) Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact Whencontam When wet or contam Daily Eyewash Quick drench [Ammonium chlonde fume] Skir Eyes Wash sun Remove Change NR NR NR NK NR [Ammoniumi suitamatei Skm Eyes Wash skin Remove Change Prevent skm contact Prevent eye contact Whencontam When wet (flamm) NR |n-Amyl acetate] Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When / ontam When wet (flamm) NR [see Amyl acetate) Recommendations for respirator concentration for use (MUC) (See Table 4) TBAl Route Symptoms (See Table 5) Inti irnt eyes skin, reap ays, Con cough, dysp puim sens Health hazards Firstald (See Table 6) Eye Skin Breath Irrlmmed Soapwashlmmed Reap support Target organs (See Table 5) Eyes,skin respsys NIOSh 50 mg m DM 100 mg mJ DMXSO/SA 250 mg/m5 SA CF/PAPRDM 500 mg'm* SAT CF/PAPRTHiE/HiEF/ SCBAF/SAF 1500 mg/mJ SA PD PP SCBAF PD PP/SAF PD PP ASCBA Escape HiEF/SCBAE inh irr t eyes nose throat Con cough dysp NIOSHOSHA 1000 ppm CCROV/GMFOV/PAPROV' SAVSCBAF SCBAF PD PP/SAF PD PPASCBA Escape GMFOV/SCBAE Inh Irrtt eyes, nose derm Ing possible CNS depres Con narco Eye SKin Breath Swallow Soap wash prompt Resp support immed Eye Skm Breath Swallow. Irrlmmed Water flush prompt Resp support Medical attention Immed CNS Eyes skinrespsys NIOSH/OSHA 1000 ppm CCROV /GMFOV/PAPROV / SA /SCBAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Inh Ing Con Irnt eyes skin nose narco derm possible kidney liver inj possible CNS depres Eye Skin Breath Irr immed Water flush prompt Resp support Medical attention immed Eyes Skin respsys kidneys liver CNS 18 Chemical name structure/formula, CAS and RTECS Nos and DOT ID and guide Nos Synonyms trade names and conversion factors Exposure limits (TWA unless noted otherwise) ABD00022742 IDLH Physical description Chemical and physical properties MW BP SOL FI P IP Sp Gr flammability VP FRZ UEL LEL Incompatibilities and reactivities Measurement method (See Table 1) Aniline (and homologs) 92-53-3 BW6850000 1547 153 Phenylamlne --,, -1ppm39lmo/m5 NIOSH Ca See Appendix A OSHAt 5 ppm (19 ma/m5) (akin] Ca [100 ppm] Colorless to brown oily liquid with anaromatlc amine- like odor (Note A solid below 21*FJ MW 93 1 BP 363'F Sol 4% FI P 1S8T IP 7 70 eV VP 0 6 mm FRZ 21*F UEL11% LEL 13% Sp Gr 1 02 Class IIIA Combustible Liquid Strong oxidizers strong acids, toluene dllsocyanate alkalis Si gel Ethanol UU/MU, [#2002 Aromatic Amines] NHt-Co.H OCHJ, 90 04 0 BZ5410000 2431 153 ortho-Aminoamsole 2 Amsidme o-Methoxyamline /Not o-Amsidine has been used as a basis for many dyes ] NIOSH Ca 0 5 mg/m3 See Appendix A OSHA C 5 mg/m3 (skin] Ca [50 mg/m3] Red or yellow oily iquid with an amine like odor 'Note A solid below 4" F J MW 123 2 BP 437F Sol(77"F) 1% Ft P(oc) 244 F IP 7 44 e' VP <-0 1 mm FRZ 41 F ULL 7 Sp Gr 1 10 Class IIIB Combustible Liquid Slrong oxidizers XAD 2 Methanol HPLC/UVD p-Anlaidine NHjCjH^OCHj _ 104-94-8 BZ5460000 ' *** , r ^ ' * >V 2431-153 1 Antimony Sb 7440 36 0 CC4025000 parsnAmlnoanlsole, ' - ' p-Methoxyanltlpe " f ' ' 1- A -S**- ' 'i V "V'"'' > - ' > , 1 - ' ' ` 1 Antimony metal Stibium NIOSH/OSHA 0 5 mg/m3 {km] - -' . 50 mg/m3 ` -' ' '' ' NI0SH70SHA 0 5 mg'm3 50 mg/m3 (as Sb> [ Note The REL and PEL also apply to other Antimony compounds (as Sb)) 1549 157(inorganic no s 3141 1 57 ^inorganic liquid compounds nosi Yellow to brown, crystalline soGd with an amine-like odor Si ver white lustrous harq brttle solid scale-like crystals or a dark gray lustrous powder MW- 123 2 8P 475*F Sol Moderate FIP 7 IP 7 44eV VP(77*F) 0 006 mm MLT 135'F UEL 7 LEL 7 - Strong oxidizers XAD-2, Methanol HPLC/UVD, IV {#2514] So Gr 1 07 Combustible Solid MW 121 8 VP 0 mm Strong oxidizers BP 2975 F lapproxi acids haiogenated Sol Insoluble MLT 1166 F acias FI P NA UEL NA [Note Stibme is IP NA LEL NA formed when antimony is exposed lo nascent (freshly Sp Gr 6 69 formed) hydrogen j Noncombustible Solid in bulk form but a moderate expioson hazard m >he form of dus when ex posed 'c flame Filte' Ac d FAAS 11(4, [P&CAM #261] Personal protection (See Table 3) Skin Eyes Wash skin Remove Change Provide Prevent skm contact Prevent eye contact Whencontam When wet or contam NR Quick drench [Aniline (and homologs)] Skir Eyes Wash skin Remove Change Provide Prevent skm contact Prevent eye contact Whencontam When wet or contam Daily t ewash Qucarench 1|o AmsiOir'* Skm Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact Whencontam When wet or contam Daily Quick drench (p-Amsidine) Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam Wl en we or contam Dai 'Antimony] ABD00022743 Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table 4) Route Symptoms (See Table 5) NIOSH * SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Mt Abs log Con Head weak, dlzz; cyan, ataxia, dysp on effort, lacar Irrtteyes, methamo cirr, (care) Health hazards First aid (See Table 6) Target organs (See Table 5) as. Breath Swallow; Inlmmed Soap wash prompt Rasp support Medical attention vrtmed Blood CVS eyes liver, kidneys resp sys [bladder cancer] NlOSH SCBAF PD PPiSAF PD PP ASCBA Escape GMFOV/SCBAE Inh Abs Ing Con Head dizz cyar RBC Heinz booies [care] r tt ' ;' Eye Skm Breath Swallow 1 r immed Soap wash immed Resp support Medical attention immed Blood kidneys liver CVS CNS [In animals tumors ot the thyroid gland biadder & kidneys1 NIOSH/OSHA Inti Head dlzz; cyan 5 mg/mJ DMXSQ/SA Abs RBC Heinz bodies [care] 12 5 mg/m1 SA.CF/PAPRDM Ing 25 mg/m5- HlEF/PAPRTHiE'/SCBAF/SAF Con 50 mg/m3- SA PD PP" | SCBAF PD PP/SAF PD PP ASCBA Escape HIEF/SCBAE S& Breath Swallow" Irrimnted Soap wash immed Reap support Medical attention immed Blood kidneys liver, CVS CNS NIOSH/OSHA 5 mg/m' DMXSQ'VSA 125 mg/m' SA CF/PAPRDM-' 25 my/mJ HiEF/SAT CF PAPRTHiE SCBAF SAF 52 - g m' SA PD PP SCBh PD PP-SAF PC PP ASCBA Escape HiEF/SCBAE Inh Ing Con Imteyes skin nose throat mouth cough dizz head nau vomit diarr stomach cramps nsom anor jnable 'o smeli property Eye Skm Breath Swallow irr immed Soap wash immed Resp support Medical attention immed Eyes skin resp sys CVS 20 Chemical name structure/formula, CAS and RTECSNos and DOT ID and guide Nos Synonyms trade names, and conversion (actors ANTU CwHrNHC(NH,)S 86-88-4 *70275000 a-Naphthyl thlocarbamkie 1-Naphthyl thiourea a-Naphthyl thiourea Exposure limits (TWA unless noted otherwise) NIOSH/OSHA 0 3 mg/m5 ABD00022744 IDLH Physical description 100 mg/m5 White crystalline or gray odorless powder jrodenticlde] Chemical and physical properties MW BP SOL FI P IP Sp Gr flammability VP FRZ UEL LEL MW- 202 3 BP Decomposes Sol 0 06% FIP NA IP ? VP Low MLT 388`F UEL NA LEL NA Incompatibilities and reactivities Strong oxidizers silver nitrate Measurement method (SeeTable t) Filter Methanol HPLC/UVD H(5) |#S276) 1661153' Arsenic (inorganic compounds as Asi As tUetai; 7440-38 2 (Metal) CG0525000 (Metal) 1558 152 imetaii 1562 152 (dust Areenfc (omanic compound^ m$Ai) V C < ,U`9 * T J - C- '7 * - Sp Gr ? Noncombuatible Solid Arsenic metal Arsenia Other synonyms vary depending upon the Specific As compound [Note OSHA considers Inorganic Arsenic to mean copper acetoarsemte & all inorganic compounds containing arsenic except Ar$me ] NIOSH Ca C C 002 mm! [1 5-min] See Appendix A OSHAI1910 10181 0 010 mg/m3 Ca (5 mg(m' ias As i] Metal Silver-gray or t n white fcnttie odorless solid MW IA q VP 0 mm Strong oxidizers BP Sublimes Sol insoluble FI P NA IP NA vapprcx MlT 1135 F iSub imes UEL NA LEL NA bromine azide [No'e Hydrogen gas can react rvith norgan/c arsenic to form the highly toxic gas arsine ] Sp Gr 5 73 (Metal) Melal Noncombustible Solid iri bulk form but a slight explosion hazard m the form of dust when exposed to flame Synonyms vary depending upon the specific organic erseniccompound NIOSH none ' OSHA 0-5 mg/m5 NO Appearance and odor Properties vary depending vary depending upon upon the specific organic the specific arsenic compound, organic arsenic compound Vanes Filter Acid HYAAS IV ,#7900) [Also #730C Elements) Filter, Reagent; IC/HYAAS IV [#5022, Arsenic, Organs-] Arsine AsHj 7784-42 ' 2188 119 Arsenic hydnde Arsenic tnhydnde Arseniuretted hydrogen Arsenous hydnde Hydrogen arsenide 1 ppm = 3 19 mg/m3 NIOSH Ca C 0 002 mg/m3 (15-mmj See Appendix A OSHA 0 05 ppm (0 2 mg/m3) Ca (3 ppm] Colorless gas with a mild garlic like odor [Note Shipped as a liquefied compressed gas J MW 78 0 BP 81 h Sol 20% FI P NA (Gasi IP 9 89 e2 RGasD 2 69 Flammable Gas VP(70 F) 14 9 atm FRZ 179 F UfcL 78% LEL 5 ' % Strong oxidizers Char chlorine nitric acia HNO, [Note Decomposes gfaAs above 446 F T nere IV S a high potential tor the generation [#6001) of arsine gas when inorganic arsenic is exposed to nascent (freshly formed) hydrogen ] Personal protection and sanitation (See Table 3) Skirt Eyes Wash skin Remove Change NR NR NR NR Daily [ANTU] Skin Eyes Wash skin Remove Change P ovide Prevenl skm conlact Prevent eye contact Ahen contam<Dail> A'he- wet c con*am Dait, Evewas- Cjicko ench (A sen c I ir-orga-i : compounds as Sl] Recommendations vary depending upon the specific compound [Arsenic (organic compounds as As] Skn Eyes Wash skin Remove Change Provide Frostbite Frostbi'e When wet (flamm) NR Frostbite [ArsineJ ABD00022745 Recommendations for respirator selection -- maximum concentration for use (MUC| (See Table 4) Route Symptoms (See Table 5) NJOSH/OSHA 3 mg/m3 CCROVDMFu/SA 7 5 mg/m1 SA CF/PAPROVOMFu 15 mg/m1 CCRFOVHiE/GMFOVHiE/ PAPRTOVHIE/SAT CF/ SCBAF/SAF 100 mg/m1 SA PD PP SCBAF PD PP/SAF PD PP ASCBA Escape GMFOVHiE/SCBAE Inh After ingestion of large Ing doses vomit, dysp cyan coarse pulm rales, liver damage NlOSH SCBAF PD PP/SAF PD PP ASCBA Escape GMFAGHiE/SCBAE Inh Abs Con Ing Ulceralion of nasal septum derm Gl disturbances pen neur resp irnt hyperpig of skin [care] Health hazards First aid (See Table S) Target organs (See Table 5) Eye Skm Breath Swallow Irrimmed Soap wash prompt Resp support Medical attention immed Resp ays blood liver Eye Skm Breath Swallow Irr immed Soap wash immed Resp support Medical attention immed Liver kidneys skin lungs lymphatic sys [lung & lymphatic cancer] 21 TEAL Wt In animals IrntskJn, Ing possible derm resp distress Con diarr kidney damege, muse tremor, *sz possible Gl tract terato, repro effects possible liver damage Breath Swallow Irrimmed Soap wash Immed Reap support Medical attention mmed Skin reepsys, kidneys, CNS liver Gl tract repro ays NlOSH SCBAF PD PP/SAF PO PP ASCBA Escape GMFS/SCBAE Inh Con (liq) Head mal weak dizz dysp abdom back pain nau vomit bronze skin hema jaun pen neur liq frostbite [carc| Eye Skin Breath Frostbite Frostbite Resp support [lung & lymphalic cancer] Chemical name structure/formula CAS and RTECS Nos and DOT ID and guide Nos Synonyms trade names and conversion factors Exposure (mils (TWA unless noted otherwise) ABD00022746____________________________________________________ IDLH Physical descn ption Chemical and physical properties MW BP SOL FI P IP Sp Gr flammability VP FRZ UEL LEL Incompatibilities and reactivities Measurement method (See Table 1) Asbestos Hydrated mineral silicates 1332-21-4 CI6475000 2212 171 (blue brown) 2590 171 (white) Actinotite Acbnolite asbestos Amosite (cummingtonite- grunerrte), Anthophylllte Anthophyllite asbestos, Chrysotile Crocidolite (Rlebeckile), Tremolita, Tiemolrte asbestos NIOSH Ca See Appendix A See Appendix C Ca [ND] OSHAM9101001] (19101101] See Appendix C White or greenish (chrysotile) blue (crocidolite), or gray-green (amosite) fibrous odorless solids MW Vanes 8P Decomposes Sol Insoluble FI P NA IP NA VP 0 mm MLT 1112* (Decomposes) UEL NA LEL NA None reported Sp Gr ? Noncombustible :Solids Filter Acetone/ Tnacetin PCM IV [#7400 Fibers] (Also #7402 (TEM)J Asphalt fumes 8052 42 4 C1990C00C 1955 3C Asp-at Asphalt Asphaltum Bitumen (European term) Petroleum asphalt Petroleum bitumen Road asphalt Roofing asphalt NIOSH Ca C 5 mg/m' [15 min] i3ee Appendix A OSHA none Ca [N D ] Fumes generated during the produc tion or application of asphalt (a dark Drown to black cement like sub stance manufactured by the vacuum d>s nllat.on of crude petroeum oi i Properties vary depending upon the specific asphalt formulation or mixture Aspnait Combustible Solid None reported [Note Asphalt becomes molten al about 200 F ] Filter none Grav NIOSH Asphalt Fumes Cnt Doc Atrazine c,hmcin5 1912-24-9 XY5600000 2-Chloro-4-ethyIamino-8isopropylammo-s-triazlne 6-Chloro-N-ethyl-N (1-metfiylethylVI 3 5tnazane>2 4-dlamlne - 2763 151 (tnazine pesticide) NIOSH 6 mg/m5 OSHAt nor* ND Colorless or white MW 215 7 VP 0 0000003 Strong acids strong Filter odorless crystalline powder BP Decomposes mm Sol 0 003% MIT 340*F bases none Grav (herbicide) FIP NA IP NA UEL NA LEL NA IV [#0500 Particulates SpGrl 19 NOR (total)] Noncombustible Solid but may be mixed with flammable liquids Azmpnos methyl C H OjPS n3 86 50 0 TE1925000 0 0 Dimethyl S-4 oxo 1 2 3 benzotnazm 3(4H)-ylmethyl phosphoro dithioate Guthion Methyl azmpnos [(CH30)jP(S)SCH_,(N,C H40)] NIOSH/OSHA 0 2 mg/m' [skin] 10 mg/m3 Colorless crystals or a brown waxy solid [insecticide] MW 317 3 BP Decomposes Soi 0 003% FI P NA IP 7 VP 0 X 10" mm MLT 163 F UFl NA LEL NA Sp Gr 1 44 Noncombustible 'bold S rong oxaizers acids OVS 2 Toiuere/ Acetone GC/FPD [#5600 Organic Pesticides] Personal protection (See Table 3) Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact Daily NR Daily (Asbestos) Skin Eyes Wash skn Remove Change Prevent skin contact P eve-u eye contact Da U NR Daily lAspnalt fumes Stan. Eyes Wash sfun Remove Change Provide prevent skin contact Prevent eye contact Whencontam When wet or contam Daily Eyewash, Quick drench [Atrazine] Skin Eyes Wash skin Remove Change P ovide Prevent skin contact Prevent eye contact When contam When wet or contam Daily Quick drench [Azmphos methyil ABD00022747 Recommendations for respirator concentration for use (MUC| (See Table 4) Route Symptoms (See Table S) NIOSH SCBAF PD PP/SAF PD PP ASCBA Escape HiEF/SCBAE Wi Asbestos!* (chronic Ing exposure) dysp, Con interstitial fib, restricted pulm function, finger clubbing, Irrft eyes [care] Health hazards First aid (See Table 6) Eye Breath Irr Immed Freeh air if* * 1 `t NIOSH * SCBAF PD PP'SAF PD PP ASCBA Escape GM^OVH'E/SCBAE Inh Abs Ccn Irrit eyes resp sys [carcj Eye Breath In immed Resp support Target organs (See Table 6) Resp sys, eyes [lung cancer] ( . iJ i Eyes resp sys [in animals Skin tumors] TBAL Inh irrft ayes, stan derm Ing sent skin, dysp weak Con Inco, salv hypothermia, liver lr\J ' Ur ` brimmed''''':' - iEyes,skin.respeye, Soap wpsh immed vCNS, liver 1 >; Breath' /`-Resp support v. ' - ,f; ' Swallow; Meaicaf attention, . . *-i n" NIOSH/OSHA 2 mgim5 CCROVDMFu/SA 5 mg/m3 SA CF/PAPROVDMFu 10 mg/m3 CCRFOVHiE/GMFOVHiE/ PAPRT OVHiE/SAT CF/ SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOVHiE/SCBAE Inh Abs Ing Con "' - Miosis ache eyes blurred vision lac rtiin head tight chest wheez lar spas salv cyan anor nau vomit diarr sweat twitch para convuls low BP card irreg i -wr ~ Eye Skin Breath Swallow rJpr* ' u-to'.hJ' Irr immed Soap wash immed Resp support Medical attention immed Resp sys CNS CVS blood chol Chemical name structurerformula CAS and RTECS Nos and DOT ID and guide Nos Synonyms trade names and conversion factors Banum chloride (as Ba) BaClj 10301-37-2 CQ8750000 Banum dichionde 1064 154(bariumcompound not.) Banum nitrate (3S Baj 10022 31 8 CQ9625000 Barium dmitrate Banum(ll) nitrate >, 1 ?) Banum salt ot nitric acid 1446 141 Banum sulfate BaS04 7727-43-7 Artificial bant* Barite Banum salt of sutfunc acid. Barytes (natural) 1564 154 (banumcompound, n o ) Benomyl Methyl 1 (butyicarbamoyli 2 benzimidazolecarbamate 2757 151 (carbamate pesticide solid) Exposure limits (TWA unless noted otherwise) ABD00022748 IDLH Physical description Chemical anc1 physical propenties MW BP SOL FI P IP Sp Gr flammability VP FRZ UEL LEL Incompatibilities and reactivities Measurement method (See Table 1) NJOSH'/OSHA' 0 5 mg/m3 ('Note The REL and PEL also apply to other soluble banum compounds (as Ba) except Barium sulfate ] 50 mg/m3 (as Ba) White odorless solid MW 206 2 BP 2840F SOL 38% FI P NA IP ? VP Low MLT 1/65 f UEL NA LEL NA &t> Noncombustible Solid Acids oxidizers Filter Water FAAS IV [#7056 Barium soluble empds] NIOSH /OSHA 0 s rng/m ' [ Note The Rb L and PEL also apply *o other soluble banum - yfin CH res i 3S Ba excep Banun sji'ale] 50 mg/m3 ias Ba! White odorless solid MW 261 4 VP t DW BP Decomposes Ml T 1094 F aluminum magnesium SOL 9% FIP NA ULL N^ LLl NA alloys ibamm IP - c n pus ibie " ate ia ~a, ca.se f re 1 Sp . z4 Ncr corrb^s'i' le Sc ij % i acce e ate he Pur ii, g t < p St Lk me e r S Filter Water l2 Barium sciubie empds NIOSH 10mg/m3 (total) 5 mg/m3 (resp) OSHAp 15mg/m5 (total) 5 mg/m3 (rasp) N D White or MW 233 4 VP 0 mm Phosphorus aluminum Filter yellowish odorless BP 29'2 F 'appro*) [Note Aljminumin none powder iDecoimposes' MlT 2876 F the p eserce of heat Grav Sol(64 F, LE. NA IV 0 0002'' _E_ NA explosior i [Particuiates FI P NA NOR iP NA #0500 (total) Sp Gr 4 25-4 5 Noncombustible So,id (resp)] N/OSH See Appendix D OSHAf ISmg/rn1 (total) 5 mg/m3 (resp) ND White crystalline solid wth a famt acrid odor [fungicide] [Note Decomposes without melting above 572 F) MW 290 4 BP Decomposes Sol 0 0004 /, FI P NA IP NA ,P 0'jcC. mn MLT 6 7? F l Decomposes' UEl NA LEL NA Sp Gr -> NoncombusliWc '-olid IV #0500 (total) (-esp)] Personal protection and sanitation (See Table 3) Skin Eyes Wash skin Remove Change Prevent sk n contact Preveri eye contact When contam When wet or contam Dai y 'Banum chlonde as Ba,] Sk r L,es \asi s iRe-v e "lte cut sia- i.nta.i i- re ent eye _v i act / ** v~n a~ .he vet . .of a" La Bar i m r 1 ate is Hai Skin Eyes Wash skin Remove Change P ovids Prevent skin contact Prevent eye contact Daily NR NR Eyewasn Quick drench [Barium sulfate, Smi _,es A a s "i s i Remove na ige Pitt s. n .o a" "re er c,t cor ta: \ i r o< am K ''K. we Ot wOMld n Ca ABD00022749 Recommendations for respirator selection - maximum concentration for use (MUC) (See Table 4) Roijte Symptoms iSee Table 5) NIOSH/OSHA 5 mg/m3 DMXSQ/SA 12 5 mg/m3 SACF/PAPRDM 25 mg/m3 HiEF/SAT CFiPAPRTHiEi SCBAF/SAP 50 mg/m3 SAF PD PP SC8AF PD PP/SAF PD PP ASC Escape HiEF'SCSAE Inh ing Con Imteyes skin upper espsys skin burns gastroenteritis muse spasm slow pulse extrasystoles hypokalemia Health haiards First aid 1 See Table 6) Target organs (See Table 5| IK. Breath Swallow Irrimmed Water flush immed Resp support Medical attention immed Eyes skin resp sys heart CNS TSl TV 5 'L uMx.SC S 12 l m., Sf ` PwPPDM 25 a i i Hit F SAT CF LP <tm l SCBAF SAt k'J Tl, Sk PC PP 'l SCbfm PU PP S/vk PL PP -SCB- Ls ace --<iLf S'.BAF es;- s s S" oj is gas roer e i is ~lsc spasm s >w ruike ex' avyvtoies f .pokdienia -,, S* i Great i S*alk V*. w I'rmeo Aate fush m Resp suppol Mel ca atien i nmeo Eyes ski 1 resp sys ear ONb TBAL Inh Con Imteyes nose upper resp sys benign pneumoconiosis (bantosis) IK Breath Swallow Irr Immed Soap wash Resp support Medical attention mimed Eyes resp sys I B"L Irik rit eyes sm jp,,i ing resp s s sr sens r0- ccssibe epro eta ef'euts Eye Skin B earn bwa ow Soap wasn immed Peso suppot Medical attent or Eyes skin resp Sys repro sys 26 Chemical name structure/formula CAS and RTECSNos and DOT ID and guide Nos Synonyms trade names and conversion factors 8enzena C,H, 71-43-2 CYHOOQOO 1114 130 1 Benzenethiol CASH 108 98 5 DC052500C Benzol Phenyl hydride 1 ppm "319 mg/m5 Mercaptobenzene Phenyl mercaptan Thiophenol 2337 13- Benzidine NHjCjH.CgH.NHj 92-87-5 DC6625000 1885 153 Benzoyl peroxide 1 CfiH COj Oj 94 36 0 DM8575000 1 pom =4 51 mg m Benzidine-baaed dyee 4,4'-Bianilme 4,4'-6iphenyldiamine 1,1'-BtphenyM,4 -diamine 4,4 Diammobiphenyf, p-Diaminodiphenyi [Note Benzidine has been used at a basis for many dyes] Berzoperoxide Dibenzoyl peroxide 2089 145 Exposure lim/ts (TWA unless noted otherwise) ABD00022750 IDLH Physical description niosh Ca 01 ppm ST1 ppm See Appendix A OSHA[1910 1028] Ippm ST S ppm See Appendix F Ca [500 ppm] Colorless to light-yellow liquid with an aromatic odor [Note A solid below 42F ] NIObH C 0 1 ppm lO 5 mg'rn 1 S mirij OSHA* none N D Water white liquid with an offensive garlic like odor Note A solid below 5 F ] NIOSH Ca See Appendix A See Appendix C OSHA[1910 1010] See Appendix B See Appendix C Ca [NO] Grayish-yellow reddish-gray or white crystalline powder [Note Darkens on exposure to air and light ] NIOSH/OSHm K mg/rn l500 mgrrJ Coiorless to whi'e crystals or a granular powder with a famt benzaldehyde like odor Chemical and physical properties MW BP SOL FI P IP Sp Gr flammability VP FRZ UEL LEL MW 78 1 BP 176'F Sol 0 07% FI P 12"F IP 9 24 eV VP 75 mm FRZ 42'F UEL 78% LEL 12% Sp Gr 0 88 Class IB Flammable Liquid MW 110 2 BP 336 F Soli77 Fl 0 08" Fl P 132 F IP 8 e VPi65 Fi 1 mm FRZ 5 F Uhl r LEL 7 Incompatibilities and reactivities Measurement meth od (See Table 1) Strong oxidizers many fluondes & perchlorates nitnc acid Strong acids & bases calcium hypocniorite alkali metals [Note Oxidizes on exposure to a r ] Char CS, GCfrtD IV [#1500 Hydrocarbons] [Also #3700 #1501] None available Sp G 1 03 C ass M Combes '-e L10.- MW 184 3 BP 752`F Sol(54*F) 0 04% Fl P 7 IP 7 VP Low MIT 239*F UEL 7 LEL 7 Red fuming nitre acid Filter ReagenL HPLC/UVO IV (#5509) SpGrl25 Combustible Solid but difficult to burn MW' 24' 2 BP Decomposes explosively Sol 1 % Fl P 176 F IP 7 'P 1 mm MU 2*7 F UEl 7 LEL 7 Sp Gr 1 33 Combustible Solid f.asily ignited md burns veiy rjpidly) ComtusiiDle Filter substances iwooa Diethyl paper etc 1 acids ether alkalis alcohols HPLC/UVD amines ethers IV [Note Containers may [#5009] explode when heated Extremely explosion sensitive to shock heat and friction ] Personal protection and sanitation (See Table 31 Shin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye con-act When contam When wet Tamm) NR Eyewash Quick drench [Benzene] S* n byes v'.ash sum F^emove i. nange P oide Ore ent - ccn act Pre en1 ere co- act /he-c-mam '.-ei nt or contain NP b ye*asv Qj ck ere c- Gp-.e et> 1 Skin Eves Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam'Daily When wet or contam Dai y f-yewasn Quckdrench [Benzidine] S. 1 c,es asr sf i pe- . e large r'n e i at in contact P e ei u e --mact he nian yht *et .r ; -am 11 Ber'? >y' peroi o< ABD00022751 Recommendations for respirator selection -- maximum concentration for use (MUC) tSee Table 4) NIOSH * SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Route Symptoms (See Table 5) Inh l nt eyes akin nose ADs respsys gidd head nau Jng staggered gait ftg anor Con lass derm bone marrow deprea [care] Health hazards First aid (See Table 6) iFn Breath Swallow Irrimmed Soap washimmed Resp support Medical attention immed Target organs (See Table 5] Eyes skin respsys blood CNS, bone marrow [leukemia! MObH 1 ern CCR- . SA : 5 P( m 5A CF r ttn ( CRFU uMF_ vAPKP. b'8 b` b'.8c*F pD pu sa" PD Pi- hSCBA = s-ape oWFh SCB b Inh ~bs "5 I on r t eyes skm resp s;s derm cyan co.gn wheez dysp puim ecema pneu t s "eac d zz CNSdepres rau .(jm t Kicr t_y n e speen damage Fye 5k n Breath bwall-w Ir immec Soap wash immed Pesp SupCCrt Medical at ent _r inirneu Eyes ski esp sys CNS yicneys 1 ver NIOSH V SCBAF PD PP/SAF PD PP ASCBA Escape HiEF/SCBAE inh Abs Ing Con Hema secondary anemia from hemolysis acute cystitis acute liver disorders derm painful irreg unnation [care] Skin Breath Swallow Irr immed Soap wash Immed Resp support Medical attention immed Bladder skin kidneys liver blood (liver, kidney & bladder cancer] MObh bl'rt AJ ng m DHXbo Sr V -3 .bO SA _r PaPRDM >i tF P.-PP IHip bl i.c; mg m' PD PP j SCBAF PC PP Sa PD Lsca, t* Hf r Irg -0 i L i e/es skin ^ jc nemo sens dem ^ve S* 1 Breat" bA3 0* Ir m- ec SoaD *ash prompt Med ca atten-ion ned 28 Chemical name structure/formula CAS and RTECS Nos and DOT ID and guide Nos Benzyl chloride CjHjCHjCI 100-44-7 XS8925000 ,,' inaise 'i i Beryllium & beryllium compounds 'as Be; Be iMetai, 7440-41 T (Metal) DS1750000 (Metal) 1566 i54(compourtds) 1567 134 (powden tUarriuth teBuride,'' doped with Selenium Wfflde (aa BI,Te,) i1 Bismuth te'iunde undoped Bi Te, 1304 8? 1 EB3110000 Synonyms trade names, and conversion factors Exposure Irruts (TWA unless noted otherwise) ABD00022752 IDLH Physical description Chemical and physical properties MW BP SOL FI P IP Sp Gr flammability VP FRZ UEL, LEL Incompatibilities and reactivities Measurement method (See Table 1) Chioromethylbenzene a-Chlorotoiuene i < -4 1ppm518mg/m3 Beryllium metal Beryllium Other synonyms vary depending upon the specific beryllium compound NIOSH Cl ppm (5 mg/m3} [15-min] OSHA (/mg/m3) 10 ppm NIOSH Ca Ca [4 mg/m3 Not to exceed ias Be)] 0 0005 mg/m See Appendix A OSHA 0 002 mq/m3 C 0 005 mq/m3 0 025 mg/m3 (30 min maximum peak] Cotorieea to slights vetlow Rqwd with a pungent aromatic odor U > * Metal A hard bnttle gray whrte solid MW 126 6 BP 354*F Sd 005% FLP- 153*F IP ? VP-Imm FRZ. -36*F UEL 7 LEL11% V. -< SpGrl 10 1 Clase IIIA Combustible Liquid Oxidizers, sods, copper aluminum magnesium, iron zinc tin [Note Can polymerize when in contact with all common metals ' except nideal & lead. Hydrolyzes in H,0 to benzyl alcohol] Char; CSj, GOTO, IV (*1003, Hakwenated , Hydro- ? carbons) MW 9 0 BP 4532 F Sol Insoluble Fl P NA IP NA VP 0 mm [approx i MLT 2349 F UEL NA LEL NA Acids caustics chlorinated hydrocarbons oxidizers rnollen litfmjm Sp Gr 1 85 (Metal) Metal Noncombustible Solid in bulk term but a slight explosion hazard in the form of a powder or dust Filter Acid GFAAS IV (*7102) [Also *7300 Elements) Doped bboHdti' , NIOSH ND 'H3n^ayit*ane Properties are unavailable - < Strong' oxidizers, *"*ir'FUtac^v-Vf sesouiteliuride. 5 mg/m3 : .solidthat has been but should be similar to ; - moleture < 'l'#,-none, x.a,* Doped bismuth toBunde, enhanced (doped) .. Bismuth teUuride. undoped. v Gray; . ,A,. Doped bismuth trrtetlunde, Doped leUurobjamuthlte OSHA| none wtti a smafl amount v ... of selenium sufflda - -- [*0500. h*T [Note Doped With selenium sulfide Commercial mix may contain 80% Bi,Te, 20% ,' t 1 ^Note Doping'altars /4`. \ y} s >. the condudMtv of' \- . ' "'J ,A< ' ' Particulates NOR' * . [total]]' l stannous tetlunde, plus soma tellurium.] ' - semiconductor [ SpGr? 1 Noncombustibie BoBd ' > 'S ; " , ' Irt,- Bismuth sesquitellunde Bismuth tellunoe Bismuth trrtellunde Tellurobismuthite NIOSH 10 mg'm3 (total) 5 mg/m3 irespi OSHA 15 mg/m3 (total) 5 mg/m3 (resp) ND Gray crystalline MW 600 0 VP 0 mm Strong oxidizers Filter solid BP ' (approxj leg bromine none Sol Insoluble MLT 1063 F chlorine or ftuonne) Grav FI P NA UEL NA moisture nitric acid IV IP NA LEL NA (decom poses) [Particulates NOR #0500 (total) Sp Gr 7 7 #0600 Noncombustible Solid (resp)] Personal protection and sanitation (See Table 3) Stun Eyes. Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contarn When wet or contam NR Eyewaeh, Quick drench (Benzyl chloride] r Skin Eyes Wash skm Remove Change Provide Preven' skm contact Prevent eye contact Daily When wel or contam Daily Eyewash ABD00022753 Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table 4| NIOSH/OSHA lOppm CCROVAGVGMFOVAG/ paprovagvsavscbaf SCBAFPD PP/SAFPD,PPASCBA' Escape GMFOVAG/SCBAE r Route Symptoms (See Table $( Wt Ing Con *' Irrtteyes skin nose week, fmty head skin eruption, pulm edema ?' X* ~ i t f it NIOSH * SCBAF PD PP SAF PD PP ASCBA Escape HEFSC8AE Inh Con Berylliosis chronic exposure anor low wgt weak chest pain cough duOOing ot fingers cyan pulm insufficiency irrit eyes derm [care] Health hazards First aid (See Table ( Target organs (See Table 5) S.- Breath Swallow Irr immed Soapwash mmed /Reap aupport . Medical attention skin, reap sys. - _ , -i 1 '' ' 4 >r" \ ' ' -* f' l- 4 V _ ' * > ' ^Vv^'V , , *. ` u> k rA ,, 't *r c y., Eye Breath In mmeO Fresh air Eyes skin res 'lung cancer] [Beryllium & bery lium compounds (as Bel Sttt Eyar Wash akin Remove. Change Provide ' Prevent skin contact Prevent eye contact Wtienconlam When wet or contam NR Eyewash Qolckdrench ' TBAl [Bismuth taliuride doped wfth Selenium sulfide (as BijTej)] Skm Eyes Wash skin Remove Change Provide Preven1 sum coniact Prevent eye contac* When contam WTien wet or contam NH Eyewash Quickdrench l B-vL Irriteyip/jfan upper reap eye garlic breath;* v - Inanimate pulm lesion*-. (nonflbrotlc) Irh Irrii eyes shin upper Con reso sys garlic breath .'V A-SMftjJ-' t,Soapwa*himmed, >Ds/' * .** V'"` *' ' ''MeSca'l attention' immed pi s' Fye Skin Breath Swallow Irr mmed Soap wash immeo Resp support Medical attention immeo Eres sh n resp sys [Bismuth eiiuride undoped] 30 Chemical name structure'formula CAS and RTECS Nos and DOT ID and guide Nos Synonyms trade names and conversion factors Borates tetra sodium satis (Anhydrous) N#jB407 1330-43-4 ED4S68000 Anhydrous borax Borax dehydrated Disodium salt of bone acid Disodium tetrabromate Fused borax Sodium borate (anhydrous) Sodium tetraborate Exposure limits (TWA unless noted otherwise) NIOSH 1 mg/m3 OSHAt none sod'um salts (Decahydrate) Na.B.O 10H,0 '303 96 4 VZ2275D0Q Borates tetra sodium salts (Pentahydrate) NSjB407 5HjO 12179-04-3 Borax Borax decahydrate Sodium borate decahydrate Sodium tetraborate decahydrate NIOSH 5 mg/mJ OSHAf none Borax pentahydrate Sodium borate pentahydrate Sodium tetraborate pentahydrate NIOSH 1 mg/m5 OSHAt none Boron oxide BO 1303 86 2 EDT9000CC Bone annydnde Bone oxide Bcror moxide NIOSH 0mg~ OSHAf 5 mg n ABD00022754 IDLH Physical description Chemical and physical properties MW BP SOL fl P, IP Sp Gr flammability VP FRZ UEL LEL ND While to gray MW 201 2 VP 0 mm odorless powder BP 2867F (approx) [herbicide] (Decomposes) MLT 1366 F (Note Becomes Sol 3% UEL NA opaque on exposurei Fl P NA LEL NA to air ] IP NA Sp Gr 2 37 Noncombustible Solid Incompatibilities and rcactiv les Measurement method (See Table 1) Moisture [Note Forms partial hydrate in moist air ] Filter none Grav [#0500 Particulates NOR (total)] ND White odorless MW 391 4 VP 0 mm Zirconium strong Filter crystalline solid BP 608F (approx) acids metallic salts none [herbicide] Sol 6% Grav [Note Becomes anhydrous at 608 P ] IP NA LEL NA Particulates NOR itotahj Sp Gr 1 73 Noncombustible Solid ran inherent fire retardant i ND Colorless or white MW 261 4 VP 0 mm None reported Filter odorless crystals or BP ? (approx) [Note However see none free-flowino powder SoL 4% MLT 392*F the reactivities & Grav [herbicide! Fl P NA UEL NA Incompatibilities IV [Note Begins to IP NA LEL NA reported for the [0500 lose water of related substance Particulates hydrabon a? Borax decahydrate NOR 252'F] above ] (total)] Sp Gr 1 82 Noncombustible Solfd 200C mg'm' Colorless sem ransparert umos or ha d white odor'ess cystais Mv\ 65 6 B= 3383 F Sol 3ci =1 P Na IP 13 50 eV VP 0 mm i approx i MLT 842 F UEL NA LEL NA Sp Gr 2 46 Noncombuslibie Solid Vvater [Note Reacts slowly with wale to form bor c acid ] Filter none Grav IV '#0530 Particulates NOR i total j] Personal protection and sanitation iSco Table 3) Skin Eyes Wash skin Remove Change NR NR Daily NR Daily ABD00022755 Recommendations for respirator selection -maximum concentration for use (WUC) (See Table 4) TBAL Route Symptoms (See Table 5) Inh Ing Con i mt eyes skm upper respsys derm epis cough dysp (Borates tetra sodium salts (Anhydrous)] Sm E,es '.asn sk 1 Remo e Oha ge NK NP _<3 N -h Da TBei. if n nr t e/es skin upper ir d esp s,s cer epis ough dysp [h a es ef a s u s-ii > _.e Skin Eyes Wash skin Kamova Change NR Daily Daily ate 1 TBAL infi Imt eyes skin upper Ing resp sys derm epis Con cough dysp [Borates tetra sodium salts (Pentahydrate)] S t 1 barge e, i. ' h* -,l- Id "er ji (d( '.her a or ccn am N1 N 3i Sign ' m3rn :SJ mg,,, rg _ rW>P"M H E" P-PRTHiL b-Bi[ S SU3F PD PP S/<F PC PP ASCBA Esuane HiEF SCBr*.E IT i' i e,es skm esp s,s o ig :cn Sk (i, Health hazards First aid (See Table 6) i Breath Swallow in immed Soap wash Reap support Medical attention immed Target organs (See Table 5) Eye* skin, retpsya Eye Skin Breatr '-wall' a r immed Soap wash Pesp support Medica ahen io"1 mmed Eyes s* n resp sys Eve Skin Breath Swallow Irr Immed Soap wash Resp support Medical attention enmed Eyes skin respsys -/e Breath Swallow lr mmed Vate *ijsh promp ~ esh a immec Eyes skm resp sys Chemical name structure,fonnula CAS and RTECS Nos and DOT ID and guide Nos Synonyms trade names and conversion factors Boron Inbrormde BBr, 10294 33 4 ED7400000 Boron bromide Tribromoborane 2692 167 h- 32 - D'S Bromacii CjH^BrNjO. 314 40 9 YQ9100000 1 ppm = 10 25 mgrni' "IT" ,, T ` t b. d t 1 ppr =2 "nr, n 5-Bromo-3 sec butyl 6 methyluraci 5-Bromo 6 methyl 3 (1 methylpropyljuracil b jr-me b 'T25 6 Ef-a :.c: 1 ppm = 10 68 mgym3 V; euvia I'mrine 1'44 1S4 ppm = 6 54 r g -- Exposure limits (TYVA unless noted otherwise) NIOSH C 1 ppm MO mg/nvh OSHAt nor* Ni ,,0r - jl- 1 mg m NIOSH 1 ppm (10 mg/m3j OSHAt none M.SH 2 mg m OSH-t C 1 "J lO ' m; ABD00022756 IDLH Physical description N D Colorless turn ng i qu o with a sharp ir itabng Chemical and physii al properties MW BP SOL FI P IP Sp Gr flammability VP FRZ UEL LEL MW 250 5 BP 194 F Sol Decomposes FI P NA IP S 7C eV VPi57 F 40 mm FRZ Si F UEL NA LEL NA 2- ' n, ND 3 PC- Sp Gr(65 F) 2 64 Noncombustible Liquid ( . -i ess gas r. if a vi gent Sutt. a' rig uo Note -c'ns ce se A 1 f* ' TICS t n v$ ir Shipped as a 'on q,,efip" r m obse' jas '1 3 rp 43 r .*0 1 - 1] - f r -c . N, in n,a- n , i? r 'Fi j - -N Odorless colorless to while crystalline solid nerdcide] .Note Commercially available asa wettaoe powder or in liquid formulations ] MW 261 2 BP Sublimes Sol(77 F, 0 08% Pi P NA IP i VP(212 Fj 0 0008 mm MLT 317 P (Sublimes) UEL NA LEL NA Sp Gr 1 55 Noncombustible Solid but may be dissolved m flammable liquids Dark eddis- o ;wn fuming iQ-id wi h S mg r atrng ` j~es M A 15,3 BP kc F So 4 Pi P NA |P 1' ,6i r "2 m0 FRZ '5 F UEL NLEL f ^ Sp Gr 3 *2 Noncombus i. e LiOj 2 but a.oe crates ' ie " i ring / o t SUDlCS Incom patibilities and reactivities Measurement method (See Table 1) Moisture water heat None potass urn sodium available alcohols (Note Attacks me!a,s wood & rubber Reacts water to form bone acid and hyd ogen Crom de ) -1- i etd i Cd Cl- * L (No e i `.o ci,zes 1 l lit dl u u ao e c ' n r r a<_ c "/O -gen fk.,1 le a fL r.r a.U Nor e ava idbie Strong acids .decomposes slowly) oxidizers neat sparks open flames Filter none Grav IV (80600 Particulates NOR I'otal;] Co-bus' b e orga < -s Filter sawdust wood Na S C '.t on st aw etc IC a nmin im read 1, v ..id zabie mate ais (86 1 a m i a t yd ogen acety ere j ios* k n -> potassi.-- sociur [No e Ccr odes iror s eel sta r less s eel 4 u 11 er | Personal protection and sanitation (See Table 3i Skin Eyes Washskin Remove Change Prov Ce Prevent sk n con'act Prevent eye con'act When con'am When wet c con'ai NR Eyewash 0_ick drench [Boron tribromide] bK " E,es \ash s' Remove g" NP NP J - |Bc On 1 f JO t Skjn Eyes Wash skm Remove Change Prevent skin contact Prevent eve contac' When contam When wet Of contam Daily Eyewash Qjick drench (Bromac L,es ABD00022757 Recommendations fur respirator selection -- maji concentration for use (MUC) (See Table 4) TBAL Route Symptoms (See Table S) inn irrt eyes skm resp sys mg skm eye burns dysp CCr cum edema Health hazards First aid iSee Table 6) Target organs (See Table 5) Eye Skin Breath Swaliow Irr immed Water fush mmed Resp support Medical attention mmed Eyes skm resp sys t 1 vol ' 1- 1 1 r t e/es sr i use Fve r m rnfO yes ski 1 resp s,s lv 1 esp s s "eb K f a er `lush m mid * res L( CL" b' 1- o E S " r 1 5. h-h 1 1- cpy IV [),, i an n's u e_ k ir e Es if i- >1 = S n t` t -d 33 TBAL inh Ing Con Irrit eyes skm upper resp sys in animals thyroid in; Siun Breath Swallow Immrned Soap wash immed Reso support Medical attention immed Eyes skin resp sys thyroid M i H o'l 1 | r"' Sr t I F-kPRS > " uLUl u Gf`cS Pr-PRTS b.b-F Suf 5 SCE PD "> Sr-r PD PP rs:a It UMFS S n`c i i,, head ac ep ' co-gr feel r3 u` wpprtss jr _ j m cden a ( r eu aocurn pm J a t asie i ke . i r o s c.i S' L-">' Soap was i ir imec Resp sj ,,r Medicai at enti.n imme^ ntsc s,s e,es Chemical name structure/formula CAS and RTECS Nos and DOT ID and guide Nos Synonyms trade names and conversion factors Bromine pentaffuonde BrFs 7700 30-2 EF9350000 Bromine fluoride 1745 144 1ppm"715mg/m3 Tnbromomethane PB5600000 2515 15S 1 3-Butadiene CHj-CHCHOIj 106-99-0 EI9275000 1 ppm = 'C 34 mg m Biethylene Bivmyl Butadiene Oivinyl Erythrene Vinylethylene 1010 116P (inhibited) CH3CH CHjCHj 106 97 8 EJ42000QQ 1011115 1075 115 1 ppm2 21 mg/m} normal Butane Butyl hydride Diethyl Methylethylmethdne [Note Also see specific listing for isobutane ] 1 ppm = 2 38 mg/m Exposure limits (TWA unless noted otherwise) ABD00022758 IDLH Physical description NIOSH 0 1 ppm (0 7 mg/m3) OSHAT none ND Colorless to pale yellow fuming liquid with a pungent odor [Note A colorless gas above105"F Shipped as a compressed gas NlOSH/OSHA J C ppm c nij s* )] 850 ppm Colorless to yellow liquid with a c'lio ofor " iKe cdo (Note h so id fce ov. 4' F NIOSH Ca See Appendix A OSHA(1910 1051] 1 ppm STS ppm Ca Colorless gas with [2000 ppm] a mild aromatic or [l0%LEl] gasoline like odor [Note A liquio below 24F Shippedasa liquefied compresse gas NIOSH 800 ppm (1900 mg/m') OSHAf none ND Colorless gas with a gasoline like 01 natural gas odor [Note Shipped as a liqueliec compres' d gas A liquid 1 elow 3 F) Chemical and physical properties MW BP SOL FI P IP Sp Gr flammability VP FRZ UEL LEL incompatibilities and reactivities Measurement method (See Table 1) MW 174 9 VP 328 mm Acids halogens BP 105 F Sol Reacts violently FI P NA FRZ 77F UEL NA LEL NA arsenic selenium sulfur glass organic materials water [Note Reacts with ail IP ? elements except inert gases nitrogen 5 oxygen ] Sp Gr 2 48 Noncombustible Liquid but a very powerful oxidizer None available MW 252 8 I'P -lOl F Sol 0 1 ` c F P N IP l 48 ev VF 5 mm FRZ 4" F UEL NA l LL N Sp Gr 2 89 Nor coriibus'ib e Liqj 3 L thium sodium U ldi oolass um .ale um US a>urri n jrr z nc agres'um st or * caustics ace one Note G adjaii; [#'-r3 rh .ae aeco~poses ~>alec rg yel ow ccic h ,or. a r & 1 ght acce arr 0 s era's cecompcsi icn 1 MW 54 1 VP 2 4 atm BP 24 F FRZ 164 F Sol Insoluble UEL 12 0% FI P NA (Gas) LEL 2 0% 1Q5F (Liq) IP 9 07 eV RGasO 1 88 SpGr 0 65 (Liquid at 21*F) Flammable Gas Class 1A Flammable Liquid Phenol chlonne Char(2) dioxide copper crotonaidehyde CH.CI, GC?Flb [Note May contain IV inhibitors (such as [#1024) tnbutylcatechol) to prevent se/f polymenzatJOn May form explosive peroxides upon exposure to air ] MW 58 1 BP 31 F Sol Slight IIP NA (Gas) IP 10 63 eV VP 2 05 atm FRZ 217 F UEL 8 4% LEL 1 6% KGasD 2 11 Sp Gr 0 b (Liquid at 31 Fl Flammable Gas Class IA Flammable liquid Strong oxidizers ,eg nitrates 8 perchlorates) chlorine fluorine (nickel carbonyl +oxygen) None dvdflaple Personal protection (See Table 3) Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact Whencontam When wet or contam NR Eyewash Quick drench (Bromine pantafluondej Bkm Eyes Wash skin Remove Cnange Prevent skm contact Prevent eye contact Whencontam Whe i wet or contam NR [B'cmofc -] Skm. Eye*. Wash ekjn Remove Change Provide Frostbite Frostbite NR When wet (flamm) NR Frostbite [1 3-Butadiene) 5km Eyes Wash serin Remove Change Provide F ostbi e Frostc te NR When wet iflamm NR Frostbite [n Butane] ABD00022759 Recommen Nations for respirator selection -- maximum concentration for use (MUC) (See Table 4) TBAL Route Symptoms (See Table 5) inh Ing Con Imt eyes skin resp sys corn nec skin bums cough dysp, pulm edema liver kidney mj Health hazards First aid (See Table 6) Targetorgans (See Table S) Breath Swallow Irr immed Water flush immed Resp support Medical attention immed Eyes skm rasp sys, liver, kidneys NIOSH'OSHA 12 5 ppm SA CF'/PAPRO/1 25 ppm GCRFOVfGMFOViPAPRTOV' SCBAF/SAf850 ppm SAF PD PP SCBAI- PD PP'SAF PO PP ASCBA Escape GMFOV SCBAt Inh Abs tng Con Irrit eyes skin resp sys CNSdepres liver kidney damage NIOSH U SCBAF PO PP/SAF PD PP ASCSA Escape GMFS/SCBAE Inh Con (hq) Imt eyes, nose throat, drow Inhead liq frostbite terato repro effects (care] Eye Skin Breath Swallow Irr immed Soap wash prompt Resp support Medical attention immed Eyes skin resp sys CNS liver kidneys iC. Breath Frostbite Frostbite Resp support Eves, rasp sys, CNS repro sys (hemato cancer} TB m. inn Con i liq i row rarco asphy iq frostbite Eye Skin Breatn Frostbite f rostbite Resp support CNS Chemical name structura/ioimula CAS and RTECSNos and 00T id and guide Nos Synonyms trade names and conversion factors 2-Butanone CHjCOCKjCHj 73-03*3 EIB475000 , 1193127 1232127 Ethyl methyl Ketone, MEK Methyl acetone, Methyl ethyl ketone ' ,,i 1 ppm 2 95 mg/m* 2 Bjtoxye -- a-i. 111 76-2 KJ857500C 2369 152 But,' Cehosoive Butyl oxitol fcGBE EKiasolve EB Ethylene glycol monobutyl ether Jeffersol EB 1 ppm = 4 83 mg/m' 2-Butoxyethanol acetate t- C<H90(CHJ)50C0CHj - 112-07-2 KJ8925000 2-Butoxyethyt acetate Butyl Cettosotve acetate Butg^glycol acetate, Ektaaotve EB acetate Ethylene glycol monobutyl, ether acetate n Bj*> 1 ace'ate CH COO[CH ] Lh 123 86 4 AF7350000 1 ppm * 6 56 mg/m3 Butyl acetate n Butyi ester o' ace ic acid Butyl ethanoate 1123 129 i ppm = 4 75 mg/r-1 ABD00022760 Exposure limits (TWA unless noted otherwise] IDLH Physical description Chemical and physical properties MW BP SOL FI P, IP, Sp Gr flammability VP FRZ UEL, LEL NIOSH 200 ppm (590 mg/m3) ST 300 ppm (885 mg/m3) OShtAf 200 ppm (590 mg/m3) 3p00 ppm ->4 Colorless liquid with a moderately sharp fragrant. mint- or acetonelike odor ^ 1 -{ S , 4 MW 721 BP 175`F Sol 28% FIP-IS'F IP-9 54 ev VP-78 mm FRZ.-123'F UEL(200*F) 114% LEU200*F) ' 'Sp GrO,8T Ctass IB Flammable Liquid NIOSH 1,24 mgtrn , (skin) OSHAT 50 ppm 1240 niim1 [skin] '3J ppm Coio'less liquid with a mild ether like odor MW 118 2 BP 339 P S01 Misobie HP 143 F IP lOOOeV /P 08' im FRZ O' F UELi275 F Uh, LEL(200 F) Sp Gr 0 90 Class jhA Combustible Liquid NIOSH ND - 5 ppm i (33 mg/m3) , , OSHA none Colorieas liquid with a pleasant, sweet, fruity odor MW 1602 BP 378F , Sot 15% FIP 71*F IP ? VP 03mm 'FRZ -82"F JJEU275*F) 088% LEL(200*F) 864% Incompatibilities and reactivities Strong oxidizers, amines, ammonia, inorganic adds, caustics isocyanates, pyridine* <5-8 i S rorg oxidizers strong caustics , Oxidizers ' - Measurement method (See Table 1) Carbon bead*, GCfrlD, IV {#2500] i< ? ' i! ^ 1 "" i V,**. * Char Methanol GC/^ IV Alcohols IV] Char. Matnanot, GC/FID, OSHA (#83] NIOSH 50 ppm, i710 mg n i ST 200 ppm (9S0 mg/mJ) OSHAf 1 50 pprn ,T10 mg m> 1 700 ppm [13%LELj Colorless 1 quid with a fruity odor So Gr 0 94 Class |B Flammable Uquid MW 116 2 BP 258 F Sol 1% Ft P 72 F IP lOOOeV VP 10mm FRZ 107 F JEL 7 6% LEL 1 7% Sp Gr 0 88 Class IB Flamm;ibie Liquid Nitra,es st ong oxidizers alkalis & acids Char uS GG/FID IV [#1450 Esters l| ABD00022761 Personal protection (See Table 3) SMI Prevent skin contact V^wthskm Prevent eye contact When contam Remove When wet (flamm) Change , N R , Prtvtae Eyewash < I'-, Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table 4) Route Symptoms (See Table 5) NIOSH/OSHA Ml Irrit eyes skin nose, 3000 ppm SA CF/PAPROW infi head dizz, vomit, derm CCRFOV/GMFOV/SCBAF/ Con SAF SCBAF PD.PP/SAF PD.PP ASCBA Escape GMFOV/SCBAE . \:r` 'r- 1 ( h Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam VWien wet or contam NR NIOSH Inh SO ppm CCROV ISA 125 ppm SA OF /PAPROV ADS Ing 250 ppm CCRFOV/GMFOV/PAPRTOV / Con SCBAF/SAF 700 ppm SAF PO PP | SCBAF PO PPfSAF PD PP ASCBA Escape GMFOV/SCBAE Imteyes skin nose throat hemolysis hemog CNSdepres head vomit J2 SutoxyethanolJ SHn&i-fvffi,Prevent *ttn wntatt/v'i1' Bn*,* uTA Prevent eye cPntept.7 5 - TT ' r. 1N50tOpSpHm CCROVTSA* -v Mi tail eyes skin, nose - - 'AM throat hemolyM ttemog, WaahsWivvlMieocorrtam ~ ^ J -126 ppm SA CFVPAPROV* Ing - CNS-depre* h*ad,vwn5 Remove,;Wt>eaml(tanmL^t, ,, ' V 250 ppm CCRFOV/GMFOV/PAPRTOW Con ChaAQaE.; N8 -t H-1 -ry.si'e VF SCBAF/8AF, V* l\f\-C TS JT^ ii;',/700 ppm SAFPD.PP . /' ' rV"i-8CSAFPO.PP/SAFM)JPASC8A . yJr t J-"Vr * /<- * v1* * V' ' y 0>eeepe,CMFpV/SCBAe * h-*j$. 't . *'* '. 'l^*' t -y, v-v-: Shir Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam When wet (flamm) NR NlOSH/OSHA 1500 ppm CCROV*/SA` 1700 ppm SA CF7PAPROV7CCRFOV/ GMFOV/SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Inn Ing Con Irnt eyes skin upper resp sys head drow narco In Butyl acetate) Health hazards First aid (See Table 6) Target organs (See Table 5) S Breath Swallow Irr Immed Water wash immed Fresh err Medical attention immed Eyes, skin, resp sys, CNS Eye Skin Breath Swallow ' - ' r, Irr immed Soap wash prompt Resp support Medical attention immed Eyes skin resp sys CNS hemato sys blood kidneys liver lymphoid sys Eye- L - Intnmed ' Skin. Soap wash prompt Breath Rasp support , Swallow- Medic*} attention ' framed., - Eyes, skin resp sys. CNS hematosys. Wood kWneys. Bvar, lymphoid *ya. ' Eye Skin Breath Swallow Irnmmed Water flush prompt Resp support Medical attention immed Eyes skin respsys CNS Chemical name structure/formula CAS and RTECS Nos and DOT ID and guide Nos Synonyms trade names and conversion factors sec-Butyt acetate CHjCOOCH(CHj)CHjCHj sec-Butyl ester of acetic acid 1-Methylpropyl acetate 105-48-4 AF73B0Q00 38 1123 129 ted Bu , a:e a'e Ch COOC Cm SaO 88 5 a-'a::::: 1122 29 Butyl acrylate CH =CHCOOC.H. * 141-32 2 UD3150000 1 ppm * 4 75 mg/m3 ert Buy es e of acet au J ppm = 4 '5 mg m n Butyl acrylate acid Butyl 2-pfopenoato 2345 129P _ 1 C 1 `i 1 C -i 1 1 ppm = 5 24 mg/m3 y (a 'c Bu ir v Bur. aicoroi ' H,cro,tutare Prop ,l .a" roi 2v <9 ppm - 3 C3 , ~ Exposure limits (TWA unless noted otherwise) ABD00022762 IDLH Physical description NIOSHOSHA 200 ppm (950 mg/m5) 1700 ppm (10%LEl] Colorless liquid with a pleasant fruity odor Chemical and physical properties MW BP SOL FI P IP Sp Gr flammability VP FR2 UEL LEL MW 116 2 BP 234"F Sol 0 8% FI P 62*F IP 9 91 eV VP 10mm FRZ -100'F UEL98% LEL1 7% NiOSh OSHm 2T pc <9 i - r, - 5C3 oom [ C nlFl ^ocriess licuid .s th a < j l, ]> Sp Gr 0 88 Class IB Flammable liquid MW 116 2 BP 2-8 <= Sc irso i. b e np'!: p; P" PZ ' UEL ' .LI 1 j NIOSH 10 ppm (55 mg/m3) OSHAT none MuCl . ^ K (SP 11 r'sp/r 1 ju ppm 3 w rng m s Sp G 0 8' Class 'B FiamrnaL e L cud ND Clear colorless MW 128 2 VP 4 mm liquid with a BP 293*F FRZ -83*F strong fruity Sol 0 1% UEL 9 0% odor [Note Highly IP ? reactive may con- tain an inhibitor to prevent spontaneous Sp Gr 0 89 polymerization ) Class li Combustible Liquid A,, ppm LEL ,, ic less l cud Mh d S for , c^aracte ist m ci, aicohc ic oJo M \ 'li BP .42 I Ow 2 rl -J 81 P P 1)rip P 0,,im FRZ 29 I I'F 11 21Ltl 4 b i ij j d Lidsb K- Ma 'mao le i -liO Incompatibilibes and reactivities Measurement method (See Table 1) Nitrates strong oxidizers alkalis & acids Char GC?FID, IV [#1450 Esters 1] N t ates s'rpng c>id zers aika is 8 ac ds Char cs GCTIO (#1453 fcs ers Strong acids & alkalis amines halogens hydrogen compounds oxidizers heat flame sunlight [Note Polymenzes readily on heating ] None available St png Old zers $ rur 9 m nerai ac ds aixal meta s laiogens Char 2 Prooanol ivb GC P D 1 '#1401 A coho s M] Personal protection and sanitation (See Table 3) Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam When wet (ftamm) NR (sec-Butyl acetate] Skr Eyes <>asr sk n Re--eve Cra'ge P e e i s> n contav P e.e't e;e c.n act /Wen contan .Nhe" r-e * ftr- tt NR I'er Butyi dvfitOlt Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet or contam NR Eyewash Quick drencn [Butyl acrylate] Sn E.es ias"sk n me'c.e v range = re tr S' r i_o~ a.l Fre ent e.e :cntav >ne' ,,nta.me' ne ` a --m N" [n Butyl alcohol] ABD00022763 Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table 4) Route Symptoms (See Table SI NIOSH/OSHA 1700ppm SA CF/PAPROVf/CCRFOV/ GMPOV/SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMPOV/SCBAE Inh Ing Con Imteyes head drew dryness upper resp sys skin narco Health hazards First aid (See Table 6) Target organs (See Table 5) Eye Skin Breath Swallow Irr immed Water flush prompt Resp support Medical attention immed Eyes skin resp sys, CNS NOSH CSHA 500 PC- 3ACC PAPRu CCR'O ' GMFCv bCBAF b-F | SCBAC PD Pd SAF PD PP ASCBA Escape GMFOv SCBAE ITT I on infla-m e,es rri' -pper esp tract head Con narco cem E,e b"in Brea t Swaiiow Ir mr-ec /aterfusr prompt Resp support Medical attention immec Resp s/s e/es skr CNS TBAL inh Abs Ing Con Irrit eyes skin, upper resp sys, sens derm dysp J Breath Swallow irr Immed Soap wash immed Reap support Medical attention Immed Eyes skin, resp sys NOSH 25C pern Sm Dc PuPRC j' 4CC pon CCRFO GMfC P"PRT_' 1 SCBmF SAF SCBAF PD PP S"F PD PP ASCBh Escape GMFCv SCB-'F 1 V"l AtS ir9 _ort nt eyes nose h oat read eli drew :o n nfamm blj'red viS'Or lac ph.to oeim possible auditor, ne-ve damage hear nj loss CNS depres E/e S< n bream bwahoA irr m-ed Wate 'lush prompt Resp supped Medica, attention nmed E/es skin resp sys CNS Chemical name structure/lormula CAS and RTECS Nos and DOT ID and guide Nos Synonyms trade names and conversion factors sec-Butyi alcohol CH,CH,OH)CH CHj 78 92 2 601750000 2 Butanol Butylene hydrate 2 Hydroxybutane Methyl ethyl caitnnol 1120 129 lCH I r '5 65 " EDI 325v_c; 1 ppm = 3 03 mg/m3 t Metn, t , ipa T imet' ,i .at J 2C ,, - n-Butylamme CHjCHjCHjCH/JHj 109 73 8 02975000 oom = - 03 q 1 Amihobutane Butylamina 1125132 ted But> ; ate [. C H CO C c. I '89-85-1 GB2939CCC 1 ppm = 2 99 mg/m3 nn -mi j, Exposure limits (TWA unless noted otherwise) NiOSH 100 ppm (305 mg/m j ST 150 ppm 455 mg/m3) OSHAT loO ppm (450 mg/m 'i ' )S H '15^PI 4 . I1/1 OShM 100 ppm NIOSH/OSHA C 5 ppm (ISirg/m') [skin] ABD00022764 IDLH Physical description 2000 ppm Colorless liquid with a strong pleasant odor Chemical and physical properties MW BP SOL FI P IP Sp Gr flammability VP FRZ UEL LEL MW 74 1 BP 211 F Sol 16"/a FIP 75 F IP 10 lOeV VP 12mm FRZ 175*F UEL(212*F) LEL(212`F) _^ 300 ppm j -r bv J r ii, J at. e i " * it ) :anv i ire ,J_r Noe . f I. 1 jSr-3 i Jj.ej.s SO 1 l- s ] Colorless liquid with a fishy ammonia like odor Sp Gr 0 81 Class 1C Flammable Liquid M, 4, 15'J t d Mis tie v -1 12 1 ' d * 42 - n, JF. t _t_ 4 dp J' - J S. id Ccm jstble 50im - ass 16 Fla- made liq- - MW 73 2 BP 172"F Sol Miscible F| P 10*F IP 8 71 ev VP 82 mm FRZ 58 F UEL 9 8% LELl 7% Incompatibilities and reactivities Measurement method (See Table 1) Strong oxidizers organic peroxides perchionc & permonosulfuric acids Char 2 Propanol/ CSjGC/fTD IV Alcohols II] o ->' s erai au -s S'r.-g t ,jrj t i acu aizers ` But rr ci _ - l_ 1 ( I.J h .r j s Strong oxidizers strong acids [Note May corrode some metals m presence of water ] Si pel* Methanol GC/FID IV [#2012) N JbH (A Jv 1 " g ^ Vi ice nppen In ,,i e poenj x ill Ca (15 tg ,, ] DS"r L - 1 mg _r n Isk.n See -r pen <\r LiQu c 1 v.te 5oi Cities at 32 23 1 Sp Gr 0 74 Class IB Flammablei Liquid M . ;3l SP ' -iOl -F^ |0 ,- ; FRZ 3 UFL =L *r bp G ' PcJu.ng agents nojso e acids aco^os tyO az re :cm j jS io e mate ia<s Fiite NaOH Na CC IC u O'604 Hexavaien* C^ro^'i J Personal protection and sanitation (See Table 3) Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact Whencontam When wet (flamm) NR (sec-Butyl alcohol) Skm eyes Aash sum Remo ve Change Prevent Skir cor ac' Preven eye contact Ahen ;ortam Vhe' NR fla n i i e But, 3 _( 'O' Skin Eye* Wash skin Remove Change Provide Prevent skin contact Prevent eye contact Whencontam When we'(flamm) NR Eyewash Quick drench [Butylamme] 5k ' Eyes Aash snr Remove ange 're.e' sr n con'act Pre er l e?e ..ontac >>hen jt tim Da 1, he *et ; _u a NR 'tt IBj, 'oma e ABD00022765 Recommendations for respirator selection maximum concentration for use (MU' iSee Table 4) Route Symptoms (See Table 5) NIOSH 1000 ppm CCROV'/SA 2000 ppm SACF'/PAPROV (CCRFOV/ GMFOV/SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Irti Ing Con Imteyes skin nose throat narco Health hazards First aid iSee Table 6) Targetorgans (See Table 5) !Tn Breath Swallow Irr Immed Water flush prompt Resp support Medical attention mmed Eget skin respsys NIOSH OSH 1600 ppm SA CF1 PARRCv1 CCRFO/ GMFO j SCBAF SAF SS'BAf-A PP SAP PD PP ASuBr* Escape GMFO SCBAfc Inh Ing Con i rt eyes s r rose inroat d'Ow narco Eye Sk n Breatn Swallow irr immed Aater Tush prompt Resp support Medical at*entior immed Eyes skin resp sys CNS 41 NIOSH/OSKA 50 ppm CCRSVSA* 125 ppm SA.CFVPAPRS* 250 ppm CCRFSlGMFS/PAPRTSV SCBAF/SAF 300 ppm SAF PD PP SCBAF PO PP/SAF PD PP ASCBA Escape GMFS/SCBAE Wl Abs Ing Con Irrtteyes skin nose throat; head, skin flush, bums NIOSH SCBAF P0 PP SAP PC PP rvSCBA Lscape OMFO/HiEOSCRAt Inh ",bs /9 rit eyes $km resp syS eye sknbj ns d ow tiusc wean skin uicers lung changes [ca c) K Breath Swaiigw Irrlmmed 1 Water flush immed Rasa support Meoioal ansntlon snmed *n Eyas, skin rasp sys -V Eye Skin Breath Swallow Irr immed Soap wash immed Resp support Medical attention immed Eyes skm resp s,s CNS 'lung cancer] 42 Chemical name structurefformula CAS and RTECSNos and DOT ID and guide Nos Synonyms trade names and conversion factors Exposure IffTVtS (TWA unless noted otherwise) n-8utyt glyddyl ether CiH^.0, 2426-08-6 TX4200000 n Butyl 'actate CM CHiOHiCwO_4H< 138 22 ' OQ4C25GC3 BGE, 1 2-Epoxy-3-birtoxypropane 1 ppm 5 33 mg/m3 Butyl es er o' 2 hydrox, propanoic acid Bj*yi es er o' lau c ac d Buty lacta'e NIOSH CSS ppm (30 mg/m3) [15-min) OSHAt 50 ppm (270 mg/m3) NIOSH 5 ppm 25 n,g in i OSHAt none 1993 128 con-DcSltle liquid 13s ppm = 5 98 mg/m-' n-6utytmarcaptan CHjCH^CHjCHjSH 109-78-5 EK6300000 2347 130 ButanathM, n-Butanethlol, 1-Mercaptobutane 1 9 1 ' 1 ppm 3 69 mg/m3 o sec Bulyipheno1 CH CH CHICH iC,h4Oh B9 72 5 SJ892300C 2 sec Butylphenol 2 11 Methylp opyilphenol 2228 153 iiqudi 2229 153 solid 1 ppm - 6 14 mg'm NIOSH CO 5 ppm M 6 mg/m3) {15-mloJ OSHAt 10 ppm 135 mg/m3) NIOSH 5 ppm 1 30 mg/ml (Skin OSHAT none ABD00022766 IDLH Physical descri ptlon 250 ppm Colorless liquid wfth an Irritating odor Chemical and physical properties MW BP SOU FI P IP Sp Gr flammability VP FRZ UEL LEL MW 130 2 BP 327 f Sol 2% FI P 130 F IP ? VP(7?F) 3mm FRZ 7 UEL 7 LEL 7 Sp Gr 0 91 Class II Combustible Liquid ND Clea cdo less M.\ 146 : = . ; ' " whi'f iq-id wi'h a bp 3'' : 4: i i d tra-s enl od Sight j-1 ' -ccr 1 P 160 >- _hL 1 1r' IP 500 ppm Colorless liquid with a strong garlic- cabbage or skunk like odor S' Gr ; 98 Class I11A Ccmbust ble l iqu d MW 90 2 BP 209*F Sol 0 06% FI P 35*F IP 9 15eV VP 35 mm FRZ -176*F UEL ? LEL 7 SpGr 0 83 Class IB Flammable Liquid N0 Colorless liquid o MW 150 2 VP Low solid 'Below 61 cl BP 227 F FR7 6 F So. Irso ubie JEl ' Fi P 225 F |P ? _El 7 Sp Gr 0 89 Class MB Combustible liqu c uO nbuslitie Soi J Incompatibilities and reactivities Measurement method (See Table 1) Strong oxidizers strong caustics Char GcfrlD IV (#1616] St ; ig a. ,,s & bases s r g -xic zers reat spi <s tli is Ncne a.ai aD e Strong oxidizers (such as dry bleaches) acids None 'eKb ttd Fitter* HC1/DCE GC/FPD (S mode) IV [42542 Mercaptans] [Also #2525] None a.a lab e Personal protection and sanitation iSee Table 5) Skin Eyes Wash skin Remove Change Prevent skm contact Prevent eye contact When comam When wet or contam NR [n-Butyl gtyodyl ether] c_.es as-' s it v e .Ka',e r'_ ^ e -[i s> ;na. P >. e e . n o -n a . " Ail. i a Nu r^Ajb1 ,, o k 1 e _ B ty a' a e Skin Eyes Wash skm Remove Change Prevent akin contact Prevent eye contact When contam When wet (flamm) NR tn-8utyi mercaptan] S ash ski i Remove Clange Rio iae re e ' s- --nti-t ne i e,e uo a: .>f en . or am Vhe ac or __ itan NR E,eAash .uica'enoh ABD00022767 Recommendations for respirator selection -- maximum concentration for use (MUCl (See Table 4j Route Symptoms (See Table 5) NIOSH Hi 56 ppm CCR0V7SA 140 ppm SACF7PAPR0V Ing Con 250 ppm CCRF0V/GMF0V/PAPRT0V7 SCBAF/SAF SCBAF PD PPfSAF PD PP ASCBA Escape GMFOV/SCBAE Irrrteye* skm nose, sens narco possible hemato effects CMS depres 5 in.'' i it eyes skin nose g Throat d Cw neac r cerres nau om Health hazards First aid (Sea Table 6) Eye Sun Breath Swallow In Immed Soap wash Immed Reap support Medical attention <nmed Target organs (See Table 5) Eyes skm retp ays CNS Wood Eye Skir Breath Swa o* Trimmed Soap wash mmed Resp support Medical attention immed CNS Eyes skinrespsys NIOSH 5 ppm CCROV/SA 12 5 ppm SACF/PAPROV 25 ppm CCRFOV/GMFOV/PAPRTOV/ SCBAF/SAF 500 ppm SA PD PP' SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Inh irrtt eyes, skin muse Ing weak mal sweat, nau Con vomit head conf, In animals narco Inco wsak, cyan pulm Irrtt, liver, kidney damage TBmL lull hOS Con irrt eyes skm resp sys skm Corns Swallow Rasp support Medical attention immed Eyes skin reap sys CNS liver kidneys Eye Skin Breath Swallow irr immed Soap flush immed Reso support Medical attention immec Eyes skin reso sys Chemical name structure/formula CASand RTECSNos and DOT IDand guide Not Synonyms trade names and conversion factors Exposure fed(ts (TWA unless noted otherwise) p-tert-Butyltofuene (CH^CC^14CH3 96-51-1 XS8400000 2667 131 n Butyronitrile CHjCHjCH cn 109 74 0 ET875000Q 4-tert-Butyltoluene, 1-MethyM-tert-butylbenzene 1 ppm 6 07 mo/m5 NIOSH 10 ppm (60 mg/m*) ST 20 ppm (120 mg/m*) OSHAt 10 ppm (60 mg/m3) Butanemtrile Butyronitrile 1 Cyanopropane Propyl cyanide n Propyl cyanide NIOSH 8 ppm (22 mg/mJ) OSHA none ABD00022768 IDLH Physical descnption 100 ppm Colorless liquid with a distinct aromatic odor somewhat like gasoline N D Colorless liquid with a sharp suffocating odor [Note Forms cyanide in the body ] Chemical and physical properties MW BP SOU FI P IP Sp Gr flammability VP FRZ UEL LEL MW 148 3 BP 379'F Sol Insoluble FIP-155'F IP 8 28 eV VP(77'F) 0 7 mm FRZ -62T UEL ? UEL ? Sp Gr 066 Class IIIA Combustible Uquld MW 69 1 BP 244 F Sol(77 r) 3% FI P 62 F IP 11 67 eV VP 14 mm FRZ 170 F UEL ? LEL 1 66 Incompatibilities and reactivities Measurement method (See Table 1) Oxidizers Char gcSfid IV [#1501 Aromatic Hydro carbons] Strong oxidizers & reducing agents strong acids & bases Char Benzene GC1FID IV (Adapt #1606] 2411 131 Cadmium dust (as Cd) Cd (Metal) 7440-43-9 (Metal) EU9800000 (Metal) 2570 154 (compounds) Cadmium fume asCd' CdO/Cd 1306 19-0 (CdO) EV1930000 (CdO) 1 ppm = 2 83 mg/m5 Cadmium metal Cadmium Other synonyms vary depending upon the tpecrfic cadmium compound CdO Cadmium monoxide Cadmium oxide lume Cd Cadmium Sp Gr 0 81 Class IB Flammable Liquid NIOSH' Ca Sea Appendix A Ca (9 mg/m* (as Cd)] OSHA'[1910 1027) 0 006 mg/m* (Note The REL and PEL eppty to ell Cadmium compounds (at Cd)] Metal Silver white blue-tinged lustrous odorless solid MW 1124 BP 1409 F Sol Insoluble FI P NA IP NA VP 0 mm (approx) MLT ilO* UEL NA LEL NA Strong oxidizers elemental sulfur seleniums tellurium Sp Gr 8 65 (Metal) Metal Noncombusbble Solid in bulk form but will bum in powder form NIOSH Ca See Appendix A Ca (9 mgirn5 ias Cd)] OSHA [1910 1027) 0 005 mg/m5 [ Note The REL and PEL apply to all Cadmium compounds (as Cd) ] Odorless yellow Drown finely divided partic ulate dispersed m air MW 1264 BP Decomposes Sol insoluble FI P NA IP NA VP 0 mm iapp cx MLT 2599 F ULl NA l! L NA Not applicable Sp Gr 8 15 (crystalline forrn)/6 95 (amorphous form) Nonuombuslihle Solid Filter Acid FAAS, IV [#7046] Filter Acid FAAS IV (#7048] Personal protection and sanitation (See Table 3) Sion Eyes Washskm Remove Change Prevent skin contact Prevent eye contact When contarn When wet or contam NR [p-terl-Soty(toluene] Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam WVien wet 'flammi NR Quick drench [n Bu'ryomtrile] Skin. ViSehekarr Removr Change. NR NR Daily NR Daily [Cadmium dust (as Cd)J Skin Eyes Wash skin Remove Change NR NR Daily NR Oa.ly [Cadmium fjme as CJ] ABD00022769 Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table 4) NIOSH/OSHA 100 ppm SACFVPAPROWCCRFOV/ GMFOV/SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Route Symptoms (See Table 5) Wi Irnteyes, skin dry nose Ing throat; head, low BP, Con tacar adnor CVS stress CNS hematodepres metallic taste liver kxiney Inj Health hazards First aid (See Table 6) Target organs (See Table 5) U Breath Swallow trrlmmad Water flush prompt Resp support Madtcal attention invned Eyes skat resp sys, CVS CNS, bone marrow, liver, kidneys NIOSH 80 ppm CCROV SA 200 ppm SA CF/PAPROV 400 ppm C-CRFOVfGMFOVJPAPRTOVi SCBAF/SAF 1000 ppm SAF PD PP SC6AF PD PP'SAF PD PP ASCBA Escape GMFOV/SCBAE mh ADs Ing Con Irnt eyes skin resp sys head dizz weak gidd conf convuis dysp atidom pain nau vomit Eye Skin Breath Swallow Soapwash immed Resp support Eyes skin resp sys CNS CVS NIOSH SCBAF PD, PP/SAF PD PPASCBA Escape HIEF/SCBAE. NIOSH 4 SCBAF PD PP'SAF PD PP ASCBA Escape HiEF/sCBAE Inh , Ing , i Pulm edema, dysp, cough,"chest tight subs pain heed, chills muse ache*, nau, vomit, diarr. anos, emphy, prot mild anerma, [caroj 'r'i , Ever , Skin Breedt Irr immed Soapweah Resp support' ' .. Resp sy*/.* 5 kidneys, , v . -prostate, blood 1 Swallow-1 , Medical attention' [prostatic * , , z'-<- immed, ,, - ` Igngea/KprJ - ^ ,'y.A 3r ' '' ' ' `` Inh Pulm edema dysp cough tight chest subs pain head chills muse aches nau vomit diarr emphy prot anos mrld anemia (care] Breath Resp support Resp sys kidneys dood [prostatic A lung cancer] Chemical nama etructure/formula CAS and RTECSNo* and DOT ID and guide Not Synonyma trade name* and conversion factors (M Aa) Ca^AeOJ, 7778-44-1 C00830000 1573151 Calcium carbonate CaCO. 1317-65-3 EV9580000 Calcium salt (2 3) of amertcadd Cucumber dust Trtcaldum arsenate, Tricalcium ortho-arsenate (Notr Am aaa specific Hating for Arsenic (inorganic compounds, MAS}] Calcium salt of carbonic acid [Note Occurs in nature as limestone cnaiK marble dotomrte aragorita calcite & oyster shells ] Calcium cyanamide CCNj 156-2-7 GS8000000 1403138 (with >01% calcium carbide) Calcium hydroxide CatOH), 1305 62 0 EW2800000 Calcium carbimids, Cyanamide. Ume nitrogen Nitrogen ama [Note Cyanamide Is also a synonym tor Hydrogen cyanamide. NHN) Calcium hydrate Caustic lime HyOrated lima Slaked lime Exposure hurts (TWA unless noted otherwise) ABD00022770 IOLH Physical description NIOSH Ca C 0 002 mg/m* [16-mm] See Appendix A OSHA|18101018] 0010 mg/m* Ca [5 mg/rn* (as As}] Colorless to white odorless solid [Insecticide/ herbicide] Chemlcaland physical properties MW BP SOL FI P, IP, Sp Gr flammability VP FRZ UEL lel MW 398 1 BP Decomposes SoK77*F) 001% FIP NA IP NA VP 0 mm (approx) MLT 7 UEL NA LEL NA Sp Gr 3 62 Noncombustible Solid Incompatibilities and reactivities Measurement method (See Table V None repotted [Note Produces toxic fumes of arsenic when heated to decomposition ] Filter Acid HYAAS IV [#7900 Arsenic] NIOSH 10 mg/m3 (total) 5 mg/m1 ,resp> OSHA 15 mg/m3 (total) 5 mg/m3 (resp) ND White odorless MW 100 1 VP 0 mm Acids alum ammonium Filter powder or colorless BP Decomposes (approx) salts mercury 8 Acid cryslals Sol 0 001% MLT 151' hydrogen fuonne FAAS FI P NA 2442 F magnpsium IV IP NA 'Decomposes! (#7020 UEl NA Calcium] LEL NA Sp Gr 2 7 2 95 Noncombustible Sond NOSH OS mg/m* OSHAt none NO Colorless, gray or MW 80 1 VP 0 mm Water Filter black crystals or BP Sublimes (approx) [Note May polymerize none powder SoL insoluble MLT 2444*F in water or alkaline Grav [fertilizer) FIP NA UEL NA solutions lo IV (Notr Commercial IP NA LEL NA dicyanamide [#0500 grades may contain Decomposes in water Particulates calcium carbide} to form acetylene NOR Sp Gr 2 29 & ammonia ] (total)) Noncombustible Solid but a fire risk if it contains calcium carbide NIOSH 5 mg/m3 OSHA 15 mg/m3 (total) 5 mg/m5 (resp) ND White odorless MW 74 1 VP 0 mm Maleic anhydride Filter powder BP Decomposes (approx) phosphorus Acid [Note Readily Sol(32 F) 0 2% MLT 1076 F mtroethane FAAS absorbs COj from FI P NA (Decomposes) mtromethane IV the air to form IP NA (Loses H-O) mtroparaffms [#7020 calcium UEL NA mtropropane Calc urn] carbonate ] LEL NA [Note Attacks some metals ) Sp Gr 2 24 Noncombustible Solid Personal protection (See Table 3) Stan Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam/Daity When wet or contain Daily Eyewash Quick drench [Calcium arsenate (as As)] SKin Eyes Wash skin Remove Change NR NR NR NR NR [Calcium carbonate] Skin Eyes. Waahskln Remove Changr Provkte Prevent stan contact Prevent eye contact Whancontam Whan wet or contam Dally Eyewash, Quick diench [Calcium cyanamide] Skin Eyes Wash skm Remove Change Provide Prevent skin contact Prevent eye contact When contamtOaily When wet or contam Daily Eyewash Quick drench [Calcium hydroxide] ABD00022771 Recommendations tor respirator selection -- maximum concentration for use (MUC) (See Table 4) Route Symptoms (See Table S) NIOSH SCBAF RO PP/SAF PD PP-ASCBA Escape HIEF/SCBAE Inh Aba Ing Con weak; Gldiat, perl neun akin hyperplg, palmar planter hyperkeratoses, derm, (care], inanimals fvardamage > TBAl Inh Imteyes skin resp Con sys cough Health hazards First aid (See Table 8) Target organs (See Table S) is, Breath Swallow Irrlmmed Soap wash prompt Rasp support Medical attention immed * Eyes, respsys. Hver.stan.CNS, lymphatic eya , [lymphatic i hmg cancer] -9 i V , V, \t A^. v v r r >V^.. ,, - * * Eye Skin Breath Irr immed Soap wash Fresh air <_ <- A** - TBAL - TBAL Mi Ing Con Imt eye* skin upper resp sys eye skin burns skin vesic cough bron pneu Eye Skin Breath Swallow Irr immed Soap flush immed Resp support Medical attention immed Eye* skin resp sys Chemical name structure/formula CAS and RTECSNos and DOT ID and guide Nos Synonyms trade names, and conversion factors Caksum oxide CaO 1305-78-8 EW3100000 Burned Nm, Burnt lime Lime Pebble lime, Quick lime, Unslaked lime 1910157 Calcium silicate CaSiO, 1344 95 2 W91SOOOO Calcium hydrosilicate Calcium metasiiicate Calcium monosilicate Calcium salt ot silicic acid Wollastonite (mineral) Calcium sulfate CaSO. 7778-19-9 WS6920000 Camphor (synthetic) c h16o 76 22 2 EX1225000 2717 133 Anhydrous calcium sulfate. Anhydrous gypsum Anhydrous sulfate of lime. Calcium salt of sulfuric acid (Note Gypsum Is the dihydrate form & Plaster of Pans is the hemihydrate form ] 2 Camphonone Gum camphor Laurel camphor Synthetic camphor Exposure limits (TWA unless noted otherwise) AWOSH 2 mg/m5 OSHA 5 mg/m5 NIOSH 10 mg/m3 (total) 5 mg/m3 OSHA 15 mg/m3 (total) 5 mg/m3 (resp) NIOSH 10 mg/ms (total) 5 mg/m} (resp) OSHA ISmgftn5 (total) 5 mg/m5 (resp) NIOSH/OSHA 2 mg/m3 ABD0Q022772 IDLH Physical description 25 mg/m5 White or gray odorless lumps or granular powder Chemical and physical properties MW, BP SOL FI P IP Sp Gr flammability VP FRZ UEL, LEL IncompatibiJibes and reactivities Measurement method (See Table 1) MW 56 1 BP 5162*F Sol Reacts FIP NA IP NA VP 0 mm (approx) MLT 4662'F UEL NA LEL NA Water (liberates heat) fluorine ethanol [Note Reacts with water to form calcium hydroxide) Filter, Acid FAAS IV (#7020 Calcium) Sp Gr 3 34 Noncombustible Solid but wiU support combustion by liberation of oxygen ND White or cream MW 116 2 VP 0 mm None reported Filter colored free BP 7 (approx) (Note After prolonged Acid flowing powder Sol 0 01% MLT 2804 F contact with water FAA.S [Note The com Fl P NA UEL NA solution reverts to IV mercial product IP NA LEL NA soluble calcium salts [#7020 is prepared from A amorphous silica} Calcium} diatomaceous earlhS lime ] Sp Gr 2 9 Noncombustible Solid ND Odorless white MW-136 1 VP 0 mm Diazomethane Filter powder or colorless BP Decomposes (approx) aluminum phosphorus none crystaffine solid Sof 0 3% MLT 2840eF water Gray- (tote May have FIP NA (Decomposes) [Note Hygroscopic IV blue, gray, or IP NA UEL NA (1 e absorbs [Particulates reddish tinge ] LEL NA moisture from the NOR air) Reacts with #0500 water to form Gypsum (total) Sp Gr 2 96 & Plaster of Pans ] 0600 Noncombustible Solid (resp)] 200 mg/mJ Colorless or white crystals with a penetrating aromatic odor MW 152 3 BP 399 F Sol insoluble FIP 150 F IP 8 76 eV VP 0 2 mm MLT 345 F UEL3 5% LEL 0 6% Sp Gr 0 99 Combustible Solid Strong Oxidizers (especially chromic anhydride & potassium permanganate) Char Methanol/ cs. GC/F1D IV [#1301 Ketones II) Personal protection and sanitation (See Table 3) SWn Eyes Wash skin Remove Change. Provide Prevent skin contact Prevent eye contact Wien contam/Daity When wet or contain Daily Eyewash Quickdrench {Calcium node] Skin yes Wash skin Remove Change NR NR NR NR NR (Calcium silicate] Skkr V&Siakln Remove; Change- NR NR. NR NR NR {Calcium suKatej Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam When wet or contam Daily [Camphor (synthetic)] ARD00022773 Recommendations tor respirator selection -- maximum concentration for use (MUC) (SeeTable 4) Route Symptoms (See Table 5) NIOSH 10 mg/m* DM 20 mg/m4 DMXSQ/SA 25 mym* SA CF/PAPRHIE/HiEF/ SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape HiEF/SCBAE Ht Imt eyas, skin, upper JJQ resp tract ulcer, pert Con nasal septum pneu derm TBAL lnh Imt eyes Skin upper Cor resp sys Health hazards First aid (SeeTable 6) Target organs (See Table 5) & Breath Swallow irr immed Water flush immed Resp support Medical attention mmed Eyes, skin rasp sys Eye Skin Breath Irr immed Soap wash Fresh air Eyes skin resp sys TBAL Hi Con Imt eyes, skin upper resp sy eon], rhinitis. spts is Breath Irr immed Soap wash Freeh air Eyes, skin resp sys NIOSH/OSHA 50 mg/m1 SA CFc/PAPROVDMc 100 mg/m5 CCRFOVHiE/GMFOVHiE/ PA PRTOVHiE`/SCBAF/SAF 200 mg/m4 SAF PD PP SCBAF PD PP/SAF PD PP ASCBA Escape GMFOVHiE/SCBAE lnh Abs Ing Con Imt eyes skin muc memb nau vomit diarr head dizz excitement epilep convuls * Ey Skin Breath Swallow Irr immed Soap wash immed Resp support Medical attention immed Eyes skin resp sys CNS 50 Chemical nama tructura/formula, CAS andRTECSNos and DOT ID and guide Nos Synonyms trade names and conversion factors Exposure frrtts (TWA unless noted otherwise) ABD0Q022774 Physical description Chemical and physical properties MW BP SOL FI P IP Sp Gr flammability VP FRZ UEL LEL Incompatibilities and reactivities Caprolactam - ios-eo-2 ' CM3075000 i.- '/v-Tv ;, - i lactam, , ___ ,_____ ____ r.>2-ona, i. 2-OJfoncxamaltiytenaimln# f ">a " fi. MOSH Oust. t mg/m5 STamgAn* ND < olzpp(n(1 ST 0 06 ppm (3 mgAn5) 'QSHAt White, ctystalilna ao&d or flakes with ahunpleasant odor [Note1 Significant vapor conccntro- ittons would ba expected only at elevated temperatures ] MW-1132 BP515T Sol 53% FI P- 282*F IP ? VP 0 00000008 Strong oxidizers mm (acetic add * MLT 196*F dinitrogen trioxtte) UEL80% lL14% SpOrlOl Combustible Solid Captafol C^HjCl^NOjS 2425 06 1 GS4900000 Captofol Difolatao N ((1 1 2 2 Tetrachloro ethyDthioM-cyciohexene 1 2-dicarboximide NIOSH Ca 0 1 mg/m3 See Appendix A OSHAT none Ca [N D ) White crystalline MW 349 1 VP 0 000008 solid with a slight BP Decomposes mir characteristic Sol 0 0001% MLT 321 F pungent odor Fl P NA (Decomposes) [fungicide] IP NA JEL NA [Note Available LEL NA commercially as a wettable powder or Sp Gr 7 in liquid form , Noncombustible Solid bu* may be dissolved in flammable liquids Acids acid vapors Strong oxidizers Measurement method (See Table i) None available Filter none Grav IV [#0 5 00 Particulates NOR \totah] Captan CtH,CijN01S 133-06-2" . QWS076000 ma^<-> >** -- ' M06H- - . Ca ' ' N-TrichJooma(hYimarcapto-'i'~'-Ca* IND-J ,, 4-cydotiaxaM-l,2- - r,i_ <j5mgA*-D' , ^ ,Ja^Appapdt<A ' -* >* 'OOHAf T H6&471 ,, ,v'` *' rtf'^ t Tr , ' - Oddton. white. J crystattne powdar (fungicide] [Note Commercial product la ayeBow powdar ,wltfi a pungent odor] `r -' i r .iW. Carbaryl CHjNHCOOClffH 63 25 2 FCS950000 a Naphthyl N methyl carbamate 1 Naphthyl N-Methyl carbamate Sevin NIOSH/OSHA 5 mg/m3 100 mg/m5 White or gray odorless solid [pesticide] 2757151 MW 3006 BP* Decomposes QtMJl'FY 0 0003% Fl P* ? IP NA VP 0mm (approx) MLT 352*F (Deoompoaes) UEL? LEL? 8p.Grl 74 Combustible Solid, may ba dissolved in flammable liquids Strong alkaline matanaisfog., hydrated lime) [Note Corrosive to metals.] MW 201 2 BP Decomposes Sol 0 01% Fl P NA IP n VP(77 F) <0 00004 mm MLT 293 F UEL NA LEL NA Strong oxidizers strongly alkaline pesticides Sp Gr 1 23 Noncombustible Solid but may be dissolved in flammable liquids Filter none, Grav; IV [#0500 Particulate* NOR (total )J Filter Reagent Vis IV [#5006] Personal protection (See Table 3) Skin Eyes Wash skin Remove. Change Prevent skin contact Prevent eye contact When content When wet or contain Daily (Caprolactam] Skin Eves Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam/Oaiiy When wet or contam Daily Eyewash Quick drench [Captatoi] SMn viashskin Remove Change. Provide Prevent skm contact Prevent skin contact When contam/Daity When wet or contam Daily Eyewaah, Quickdrench (Captan] Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam When wet or contam Daily [Carbarylj ABD00022775 Recommendations for respirator concentration for use (MUC) (See Table 4) Route Symptoms (See Table 5) Health hazards First akt (See Table 6) Target organs (See Table S) TBAl NIOSH 4 SCBAF PD PPfSAF PD PP A.SC6A Escape GMFOV/SCBAE Ml Intteyes, skm. rasp sys,epir derm, aklfi Con . serw, asthmas Irrity, ' corrf, din, head abdom cram^cfipm oad. vomit, IS Irrimmad > Eye#, skin, respay*, ' Watarwaah Immad CNS CVS, liver? Breath -Reap support ' s Jddnaya . ,. Swallow . potion ' immad <" ^ ^ ' v' ' - 'V, 'W i rfA- 'i-l'" vc ,i ? '" ? j-t/- - yr\'& \>:A * L Inh Imteyes skin resp Abs sys tferm skin sens tng conj bran wheez diarr Con vomit liver kidney mj high BP in animals terato effects [care] & 8rlh Swallow In immad Soap wash immed Reap support Medical attention immed Eyes skin resp sys CNS liver kidneys CVS [in animals tumors at many sites] 51 NtOSH # SCBAF PD PP/SAF PD,PP-ASCBA Escape GMFOV/SCBAE . - Ml ^Ij*a^a,ak6i, upper Mis map ajn, blurred vision, - `'Ey*: > Irrlmrped ' 6Wk, - . Soapwa^hlrnmed EQyIatrsa,cat,la8iv,arer,ap ays, - tCaogn..*. demVakin sans, dyap, dlair, vomitfcj >. -V yi *' I- Breath. ? -"Rasp support Jiddneya - ' Swattow -V " , *~>Mawcfl at^ntton ,. 'tf.'-Jrowr, i" ^1*4, ri J,, n;dawndroeaTMlen.u-crK3r] yi - ` Jf T - w>' * jc - ` a ' ,, ( .'V&'VtC -> \ v~ ,v." 'jf1' *'\:t^, -v^:' :i NIOSH/OSHA 50 mg/m5 SA 100 mg/m5 SACF /SCBAF/SAF SCBAF PD PP/SAF PD PP ASC6A Escape GMFOVHiE/SCBAE inh Miosis blurred vision Abs tear rhin salv sweat Ing abdom cramps nau vomit Con diarr tremor cyan convuls iml skin possible repro effects is Breath Swallow Irrimmad Soap wash prompt Resp support Medical attention vnmed Resp sys CNS CVS skin blood chol repro sys 52 Chemical name, structure/formula, CAS and RTECSNos and DOT ID and guide Nos Synonyms trade names and conversion factors Exposure Emits (TWA unless noted otherwise) ABD00022776 IDLH Physical description p*rtoofuran cyv), m *. ~ r Carbon black C 1333-86-4 FF5800000 2,i-CHhydco-2^-dimthy(-7- b*n2uranylmsthyl- carbanute; ,r -Furacaib*; . , ` W06H , Olrntfri)* OSHAt, non*. NO ui`3*~ la.-'* t _ k, , ,o , ita l>,4 * `,+U.l I'uftwMl&i'' t. J f&itl ft f-i 5] 'll '(4'' Odort***, white or greyish. crystalline olid Hnwctloidel 1 {Note May 1b* dluohwdtn*' , quid carrier] , , `" ` 1 -'/V zii'*i* 'tut; Acetylene black Channel black Furnace black Lampblack Thermal black NIOSH/OSHA 1750 mg/m3 3 5 mg/m3 NIOSH Ca 0 1 mg PAHs/m3 [Carbon black in presence of polycyclic aromatic hydrocarbons (PAHs)] See Appendix A See Appendix C Black odorless solid Chemical and physical properties MW, BP SOL FI P IP Sp Gr flammability VP FRZ UEL, LEL Incompatibilities and reactivities Measurement method (SeeTable 1) mt 2213 BP 7 007% FIP NA IP NA vpcrrry 0000003 mm MLT 304*F DEL NA LEL NA Aftallne subatartc** add strong oxidizers (e g, perchlorates, peroxides, chlorates, nitrates, permanganates) S&GrJIS < Nonoombustfekr Solid Filter. none; Grav; ' IV ' < [0600. Parheulataa NOR (total)] MW 12 0 BP Sublimes Sol Insoluble FI P NA IP NA VP 0 mm MLT Sublimes UEL NA LEL NA Strong oxidizers such as chlorates bromates & nitrates Filter Done Grav IV (#5000] Sp Gr 1 8-2 1 Combustible Solid that may contain flammable hydrocarbons Carbon disulfide Carbon bisulfide FF6650000 1 ppm = 311 mg/m3 NIOSH 500 ppm 1 ppm (3 mg/m3) St 10 ppm (30 mg/m3) [skin] OSHAt 20 ppm C 30 ppm 100 ppm (30 min max peak) Colorless to faint yellow liquid with a sweet ether-like odor [Note Reagent grades are foul Smelling ] MW 7$ 1 BP 116 F Sol 0 3% FI P 22 F IP l0 08eV VP 297 mm FR2 169 F UEL 50 0% LEL 1 3% Sp Gr 1 26 Class IB Flammable Liquid Strong oxidizers chemically active metals such as sodium potassium & zinc azides rust halogens amines [Note Vapors may be ignited by contact with ordinary light bulb ] Char/ Dry tube Toluene GC/FPD IV [#1600] Personal protection end sanitation (See Table 3) Stow Prevent atoi contact Eype. -J .Preventeye contact Vnabeldn. Whencontwn Remove: Wien wot or content CtmK Deity EyoMe&QuttdnNKh Sign Eyes Wash skin Remove Cnange -: NR Prevent eye contact Daily NR NR (Carbon black] ABD00022777 Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table 4) Route Symptoms (See table S) Health hazards First aid (Sss Table 6) Target organs (See Table 5) NlOSH/OSHA 17 5 mg/m* DM 35 mg/m5- DMXSQ/SA 87 5 mg/m5 SACF/PAPROM 175 mg7m5 HiEF/PAPRTHiE/SCBAF/SAF ITSOrro/m1 SA PO PP SCBAF PD PP/SAF PD PP ASCBA Escape H1EF/SC8AE inti Con Cougn imt eyas m presence ot polycyclic aromatic hydrocarbons (care) Eye Breatn In presence of polycyclic aromatic hydrocarbons NKjSH V SCBAF PD PP/SAF PD PP ASCBA Escape HiEF/SCBAE Irr prompt Fresh air Resp sys eyes (lymphatic cancer (in presence of Pah*)) Skin Eyes Wash $km Remove Change Prevent skin contact Prevent eye contact Whencontam When wet (flamm) NR (Carbon disulfide) NIOSH 10 ppm CCROV/SA 25 ppm SA CF/PAPROV 50 ppm CCRFOV/GMFOV/PAPRTOV/ SCBAF/SAF 500 ppm SA PD PP SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE mti Abs Ing Con Dizz head poor sleep fig ner anor low wgt psychosis pofyneur Parkinson like syndrome ocular changes coronary heart disease gastntis kidney liver mj eye skin bums derm repro effects iz Breath Swallow Irrimmtd Soap wash immed Resp support Medical attention mmed CNS PNS CVS eyes kidneys liver skin repro y 54 Chemical nams, structure/formula CAS andRTECSNos, and DOT ID and guide Nos Synonyms trade names end conversion factors Carbon monoxide CO Carbon oxide, Fluegas, Monoxide 630-08*0 F03500000 1016119 ', 1 .Ippmet.lSmg/m* Exposure Irnlts (TWA unless noted otherwise) NlOSH 35 ppm (40 mg/m1) C 200 ppm (229 mg/m1) OSHAt 50 ppm (55 mg/m1) ARDQQQ22778 IDLH Physical description Chemical and physical properties MW BP SOL FI P IP.Sp, Gr flammability VP FRZ UEL, LEL 1200 ppm Colorless, odorless gas (Note Sharped as a nonllquefled or liquefied compressed gas ] MW 28 0 BP -313'F Sol 2% FIP NA (Gas) IP 14 01 eV VP >35 atm MLT -337`F UEL 74% LEL 125% RGasO 097 Flammable Gas Carbon tetrabromide CBr4 558 13-4 FG4725000 Carbon bromide Methane tetrabromide Tetrabromomethane 2516151 1 ppm = 13 57 mg/m5 NlOSH N D Colorless to MW 331 7 VP(205 F) 0 1 ppm yellow-brown BP 374F 40 mm (1 4 mg/m3) crystals with a Sol 0 02% MLT 194 F ST 0 3 ppm (4 mg/m3) slight odor FI P NA IP 10 31 eV UEL NA LEL NA OSHAT none Sp Gr 3 42 NoncombuStible Solid Cwbon tetmchioridtL ecu . 66-23-5 ' ' FG4900000 18461S1, ' V- Carbonyl fluonde COF 353 50 4 FG6125000 2417 125 CwboiH^ . Frepgfc.10. Ha(on1D4. - Tqfrachtorpmethan^ ti-p--pmL.x-t6b.<2So9 yJrty , **' Carbon diftuonde oxide Carbon fluonde oxide Carbon oxyfluonde Carbonyl difluonde Fluoroformyi fluonde Fluorophosgene NlOSH C > ' ST 2 ppm 1 <12 6mofrn^ tWO-mlnJ . |m Appendix A SHAT ' * , Ct J200 ppm] Colorleu liquid with (character* tote after-Cke odor i' * " -1- -2-0-0 ppm'(5-mln Max peak*in any 4 hr*) NlOSH 2 ppm {5 mg/m3) ST 5 ppm (I5mg/m3) OSHAt none N D Colorless gas wrth a pungent and very irritating odor [Note Shipped as a liquefied compressed gas J 1 ppm * 2 70 mg/m3 MW 153 8 BP"t70*F SoLO 05% FIP NA IP 1147eV VP 81 mm FRZ. -9*F UEL NA LELNA SpQrl 59 Noncombustible Liquid MW 66 0 BP 118 F Sol Reacts FIP NA IP 13 02 eV VP 55 4 atm FRZ 173 F UEL NA LEL NA RGasO 2 29 Nonflammable Gas Incompatibilities and reactivities Measurement method (SeeTabie 1) Strong oxidizers, bromine trlfluonde chlorine trrfluonde lithium Bag none Sensor IV [*6604] Strong oxidizers hexacyclohexyldilead lithium None available Chemlcally-acUve metals such as sodium, potassium & magnesium fluonne siumrun (Note Forms highly toxic phosgene gas when exposed to names or welding arcs] Char; gcJfid IV i1003 Haioge* nated Hydro carbons] Heat moisture hexafluoroisopropyl ideneammo-lithium [Note Reacts with hydrogen fluonde & carbon dioxide ] Personal protection and sanitation (See Table 3] Skm Eyes Wash skin Remove Change Provide Frostbite Frostbite NR When wet(flamm) NR Frostbite ICarbon monoxide] Skin Eyes Wash skm Remove Change NR Prevent eye contact Daily NR Daily Eyewasn [Carbon tetrabromiae] Wash skin Remove. Change Provide Prevent skm contact Prevent eye contact Whencontam When wet or contarn NR Eyewash Quickdrench [Carbon tatrachlonde] Skin Eyes Wash skm Remove Change Provide Frostbite Frostbite NR NR NR Frostbite (Carbonyl tluonde] ABD00022779 Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table 4) Route Symptoms (See fable S) Health hazards First aid (Sae Table 6) NIOSH 350 ppm SA 876 ppm SA CF 1200 ppm GMFSVSCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFSf/SCBAE Mi Head.tachypnaa nau, Con weak dlzz.conf.halu. (iiq> cyan, depriwS-T aegtmntof. electrocardiogram, angina, syncope Breath J- ; w Fcoatbita~ ", Frostbite Rasp, support 4 ]* -,<-4, r. ? u? ,jc '-m*. Target organs (See Table S) CVS. I TBAL Inh ing Con Imt eyes skin resp sys lac lung liver kidney mj mammals comdamage Eye Skin Breath Swallow Irr immed Soap wash prompt Resp support Medical attention immed Eyes skin resp sys liver kidneys NIOSH SCBAF PO PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Mi Aba Ing Con TBAL Inh Con Imteyes skin muc memb resp sys eye skin bums lac cough pjlm edema dysp chronic exposure Glpain muse fib skeletal fluorosis liq frostbite Eyes skin resp sys bone Chemical name, structure/formula, CAS and RTECS Nos and DOT ID and guide Nos Synonyms, trade names and conversion (actors Catechol CtfVOH), 120-60-9 UX1050000 1,2-8eruenedioi, o-Jlenzenediol, Pyroqstechol b '- 1 Cellulose <C,H10CVP 9004 34 6 FJ5691460 1 ppm 4.50 mg/m* Hydroxycellulose Pyrocellulose Cesium hydroxide CeOH L 21351-79-1 fK98DOOOO ' 2692 157 2681' 154 (aotution) Chlordane 57 74 9 P89800000 Cesium hydrate, Cesium hydroxide dimer Chlordan Chlordano Octachioro-3a 4 7 7a tetrahydro 4 7 roethanoirvjane 2762 131 Exposure limits (TWA unless noted otherwise) NIOSH 5 ppm (20 mg/m5) (skin) OSHAf non* NIOSH 10 mg/m11 \tota ) 5 mg/m iresp) OSHA 15 mg/m3 (total) 5 mg/m3 (resp) NIOSH 2 mg/m* OSHAt none NIOSH Ca 0 5 mg/m3 [skin] See Appendix A OSHA 0 5 mg/m3 [Skin] ABD00022780 IDLH Physical description NO Colorless crystalline solid with a faint odor [Note Discolors to brown in air & light ] Chemical and physical properties MW BP, SOL FI P IP Sp Gr flammability VP FRZ UEL LEL MW 110 1 BP 474'F Sol 44% FIP261*F IP ? VP(244*F) 10nm MIT 221*F UEL 7 LEL14% Incompatibilities and reactivities Measurement method (See Table 1) Strong oxidizers rntnc aod None available ND ND Ca [100 mg/m3) Sp Gr 1 34 Combustible Solid Odorless white substance [Note The principal fiber cell wail material of vegetable tissues (wood cotton flax grass etc )) MW 160 000 560 000 BP Decomposes Sol insoluble FI P NA IP NA VP 0 mm (approxj MLT 500 518 F Decomposes > UEL NA LEL NA Water bromine pentafluonde sodium nitrate fluorine strong cxid zers Sp Gr 1 27 1 61 Combustible Solid Filler rK>ne Grav IV [Particulates NOR #0500 (total) #0600 (resp)) Colorless or ysllowish crystalline solid (Note Hygroscopic (ue eceorbs moisture from the air)} MW 149 9 BP 7 Sot(59"F) 395% FIP NA IP NA VP 0 mm (approx) MLT 522*F UEL NA LEL NA Sp Gr 3 68 Noncombustible Solid Water acids CO, metals (eg At Fro Sn Zn) oxygen None available [Note CsOH is a strong base causing the generation ol considerable heat In contact with water or moisture) Amber colored viscous liquid with a pungent chionne like odor [insecticide] MW 409 8 BP Decomposes Sol 0 0001% FI P NA IP n VP 0 00001 mm FRZ 217 228 F UEL NA LEL NA alkaline reagents Sp Gr(77 F) 1 6 Noncombustible Liquid but may be utilized in flammable solutions Filter/ Chrom 102 Toluene [#5510] Personal protection (See Table 3) Stan Eye* Wash akin Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet or contam Daily Eyewash [Catechol] 5km Eyes vVasnskin Remove Change NR NR NR NR NR [Cellulose] Star Eye* Wash akin Remove Change Provide Prevent skin contact Prevent eye contect When content When wet or contam Daily Eyewash Quick drench [Cesium hydroxide] Skin Eyes /.'ash skm Remove Change Provide Prevent skin contact Prevent eye contac' 'Vhen contam When wet or contam Daily Eyewash Quickdrench [Chlordane.l ABD00022781 Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table 4) TBAL Route Symptoms (See Table S) Irti Abs Ing Con Irriteyes akin reap sys skm sens derm lac bums eyes convuls incr BP tadney in] Health hazards First aid (See Table 6) Target organa (See Table S) I Breath Swallow 1 trimmed Water wash Immed Reap support Medical attention romed Eyes, skm, reap ays. CNS kidneys TBAL TBAL Inn rrnt eye* skn muc Con merr\t Inh Imteyes atari upper [!* reap tract eye, akin Con buma Eye Skin Breath Irr immed Soap wash Fresh air Eyes Skin resp sys 57 S Breath Swallow- Irr immed Water flush immed Reap support Medical attention aimed Eyes, skin, raspaye' NIOSH X SCBAF PD PP'SAF PD PP ASCBA Escape GMFOVHiE/SCBAE Inh A0 5 Ing Con Blurred vision coni ataxia delirium cough abdom pain nau vomit diarr irrity tremor convuls anuna in animals lung liver kxJney damage [card Eye Skin Breath Swallow Irr immed Soap wash immed Resp support Medical attention immed CNS eyes lungs liver kidneys [in animals liver cancerj 58 Chemical name, structure/formula CAS and RTECSNos and DOT ID and guide Nos Synonyms trade names and conversion factors Exposure limits (TWA unless noted otherwise) Chlorinated camphena C^CIS 8001-35-2 XW52500Q0 2761151 Chionnated diphenyl oxide Chlorocamphene, Octachlorocamphane, Polychloroeamphene Toxaphene NiOSH Ca [skin] See Appendix A OSHAT 0 5 mg/m3 [skin] Synonyms depend on the degree of chlorination of diphenyl oxide [(C6Hj)2)0] ranging from monochlorodi phenyl oxide ((C,H4CI)0{C6H5)] to decachlorodipnenyl oxide 1(C9CI4)0(C6CI5)| NlOSHrOSHA 0 5 mg/m5 ABD00022782 IDLH Physical description Ca [200 mg/m3] Amber waxy solid with a mild pmey chlorine and camphor-like odor [insecticide] Chemical and physical properties MW BP SOL FI P IP Sp Gr flammability VP FRZ UEL, LEL Incompatibilities and reactivities Measurement method (See Table 1) MW 413 8 BP Decomposes Sol 0 0003% FI P NA IP 7 VP(77F) 0 4 mm MIT 149-194'F UEL NA LEL NA Strong oxidizers [Note Slightly corrosive to metals under moist conditions) Filter Petroleum ether GC/ECD IV [#5039] 5 mg,m3 Sp Gr 1 65 Noncombustible Solid but may be dissolved in flammable liquids ppearance and odor P opehies vary depending vary depending upor jpon he specific compound the specific compound St ong oxidizers F, er isooctane GC/EConD IV [#50 2 51 ChioriM CU 7762-50-5 F02100000 1017124 Chlorine dioxide ClOj 10049-04-4 F03000000 Moiecutar chlorine 1 ppm 2 90 mg/m1 Chiorme oxide Chlorine peroxide 1 ppm = 2 76 mg/m3 NIOSH C 0 5 ppm (1 45 mg/m3) [16-minf OSHAt Cl ppm (3 mg/m3) NIOSH 0 1 ppm (0 3 mq/m3) ST 0 3 ppm (0 9 mg/m3) OSHAT 0 1 ppm (0 3 mg/m3) 10 ppm 5 ppm Greenish-yellow gas with a pungent imtating odor [Note Shipped as a liquefied compressed gas ] MW 70 9 VP 8 atm Reacts explosively BP -29 F FRZ-150"F or forms explosive Sol 0 7% UEL NA compounds with many FI P NA LEL NA common substances IP 11 48 eV such as acetylene ether turpentine ammonia fuel gas hydrogen & finely RGasD 2 47 divided metals Nonflammable Gas but a strong oxidizer Yellow to red gas or a red brown liquid (below 52 F)with an unpleasant odor similar to chlorine and nitric acid MW 67 5 VP >1 atm BP 52 F FRZ 74 F Sol(77 F) UEL 7 0 3% LEL 7 FI P NA (Gas) ?(Liq) IP 10 36 eV RGasD 2 33 Sp Gr 1 6 (Liquid at 32F) Flammable Gas/Combustible Liquid Organ,c materials heat phosphorus potassium hydroxide sulfur mercury carbon monoxide [Note Unstable in light A powerful oxidizer ] Filter Na.S.Oj, 1C IV [#6011] Bub KJ 1C OSHA [#10202] Personal protection (See Table 3) Sign Eye*. Wash skin Remove Chang* Provide Prevent skin contact Prevent eye contact When coniam/Daily When wet or contam Daily Eyewash Quickdfench [Chlorinated camphene] Skm Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam When wet or contam Da ly ABD00022783 Recommendations for respirator selection -- maximum concentration lor use (MUC) (See Table 4) Route Symptoms (See Table S) NIOSH SCBAF PD PP/SAF PD PP ASCBA Escape GMFOVHIE/SC8AE mh Abe ing Con Nau conf agitation tremor, convuis. uncon dry red skin [care] NIOSH/OSHA 5 mg/m1 SA/SCBAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOVAGH E'SCBAE Inh Ing Con Acne torm derm liver damage Health hazards First aid (See Table 6) Target organs (See Table 6) S& Breath Swallow Irrimmad Soap wash prompt Rasp support Medical attention mmed CNS skin [in animals. Avar carreer] Eye Skin Breath Swallow lr immed Soap wash prompi Resp Support Medical attention immed Skin liver [Chlorinated diphen,i oxide] SWn. vJeshskin Remove Change. Provide Frostbite Frostbite NR NR NR Frostbite [Chlorine] Skin Eyes Wash skin Remove Change Provide Prevent skin contact (liqi Prevent eye contact (liq) When contam (hq, When wet (Hamm) NR Eyewash iliq) Quick drench (liq) (Chlonne dioxide] NIOSH 5 ppm CCRS*/SA* 10 ppm SACFVPAPRSVCCRFS/ GMFS/SCBAF/SAF SCBAF PO,PP/SAF PD PP ASCBA Escape GMFS/SCBAE inh Burning of eyes, nose Con mouth,lac rtiln cough, choking, subs pam nau vomit head dizz, syncope pulmedema pneu hypox derm, itq frostbite S Breath Frostbite Frostbite Resp support Eyee, skln.respsys NIOSH OSHA 1 ppm CCRS/SA 2 5 ppm SA CF/PAPRS^ 5 ppm CCRFS-/GMFS/SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFS/SCBAE IrVi Ing (I'Q) Con irnt eyes nose throat cough wheez bron pufm edema chronic pron Eye Skin Breath Swallow irr immed (liq) Eyes resp sys Soap wash immed (liq / Resp Support Med.cai attention mmed (liq) if 0 Chemical name structure/formula CAS and RTECSNo* and DOT ID and guide Nos Synonyms trade names and conversion factors Chlorine trifluoride Chlorine fluoride Chlorotrifluoride 7790-91-2 F02600000 ,* l V-'f* 174ft. 124' v i* *** V , r*>yV ^ - 1ppra3 78mflttn Chioroacetaidehyde CICHjCHO 107 20 0 AB2450000 Chioroacetaidehyde (40% aqueous solution) 2 Chloroaeetaidehyde 2 Chloroethanal 2232 153 1 ppm = 3 21 mg/m3 i-ChlpfOacetophencne'^ Chloroacetyi chloride CICHjCOCl 79 04 9 A06475000 Chloroacetic aod chloride Chioroacetic chlonde Monochloroacetyl chlonde 1752 156 1 ppm = 4 62 mg/m3 Exposure kmits (TWA unless noted otherwise) NIOSH/OSHA COIppm (0 4 mg/m5) NIOSH/OSHA C 1 ppm (3 mg/m3) NIOSH 0 05 ppm (0 2 mg/m1) OSHAT none ABD00022784 1DLH Physical description Chemical and physical properties MW BP SOL FI P IP Sp Gr flammability VP FRZ UEL LEL Incompatibilities and reactivities 20 ppm Colorless get or a greenish-yellow liquid (below S3*F)witha somewhat sweet, suffocating odor (Note Shipper aa a liquefied compressed gaa] MW 92 6 VP 14 atm Oxidizers, water, BP S3'F FRZ.-105T adds combustible Sol Reacts UEL.NA matenala, sand, glass F! P NA LEI. NA metals (corrosive) IP 13 00eV (Note Reacts with RGasD 321 water to form SpGrl 77 (Liquid at 53*F) chlorine & hydro- Nonflammable Gas . fluoric addJ Noncombustible Liquid, but contact with organic materials may result In SPONTANEOUS igiution Measurement method (See Table 1) None available 45 ppm Colorless liquid with an acrid penetrating odor [Note Typically found as a40% aqueous solution ] MW 78 5 SP 186 F Sol Miscible FI P 190 F (40% soln ) IP 10 61 eV VP 100 mm FRZ 3 F (40% soln ) UEL ? LEL 7 Sp Gr 1 19(40%solution) Class IHA Combustible Liquid Oxidizers acids Si gel Methanol GC/ECD IV (#2015) Water, stearn,' stjprB'V.' TenaxGC ; .oxidizers a (2), >?> (Not* Slowly. ... >w. tThheemrmaali 1 . . corrodes metal* }; r; desorp; AV A GC/FIO) fe? *9' - r * < et lf l*4 '*828"1'1-'***r -v ** >* . r ` -- ^ `c rvj NO Colorless to MW 112 9 VP 19 mm Water alcohols bases None yellowish liquid BP 223 F FRZ 7'F metals (corrosive) available with a strong Sol Decomposes UEL NA amnes pungent odor FI P NA LEL NA [Note Decomposes m IP 10 30 eV water to form chloroacetic acid & hydrogen chlonde gas ] Sp Gr 1 42 Noncombustible Liquid ABD00022785 Personal protection (See Table 3} Recommendations for respirator selection--maximum concentration for use (MUC) (See Table A) Route Symptoms <Se Tftble 5} Sta Qatari Ramov*. Prevent akin contact Prevert eye contact When contam (5q) * Wtan wetorccntwn (Bq) Eyawash {liqiQu^drenctt NJOSH/OSHA 2 5 ppm SA.CF* 5 ppm SCBAF/SAF 20ppm SAFPOPP ft s<5baf PD.PP/SAF PD.PP.ASCBA Escape GMFS/SCBAE . Ml Eye, sign bum* (llq or htgh vap cone), reap Ur#, m animats lac. com rtcer;pulm*4ema (Chlorio* tr!8uoridt tv - , !>' H-' -iAA r~'tW'-, j'j Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contain When wet or cocttam NR Eyewash Quick Orench NIOSH/OSHA 10 ppm CCROV/SA* 25 ppm SACF/PAPROV 45 ppm CCRFOVJGMFOVfPAPRTOV / SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SC8AE m APS Ing Con Irrrt skin eyes muc memo skin burns eye damage pulm edema skifi resp sys sens Health hazards First aid (See Table 6) Target organs (See Table S) |R Breath Swallow Ut immed Waterflush immed Reap support Medical attention Immed {Hq) Stan, eyes, reep eye j*' 'V t5> Eye Skin Breath Swallow Irr immed Water flush immed ssupport Medical attention immed Eyes skin resp sys [Chloroacetaldehyde] CJwnot^-'OaUy SCBAF/SAF pcm44e.^><iEy*Mh ^i. * - s oSCvdBaAtF rPuD,r,Pr<PO/SAAVF.PP.Dru,P,rPr.AnSoCvo8A t , a*v3***x,r Tw* . > *'^--'1, . `f' * . Escape-GMFSHie/SCBAfc- V>,' rf &. \ u: ^ vj - -* ;l <* EWsv i 'IrrUnmetf < - Eye*i itan, reapay* T .oSwt <iSoapwaahlmmed*; -> Breath, '..Reap support - Swallow* --Medical?attention > - 4nmid> *' -`s v V -ts A Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet or contam NR Eyewash Quick drench TBAl Inh AOs Ing Con Irnteyes skm resp sys eye skin burns cough wheez dysp lac Skin Breath Swallow Iit immed Water flush immed Resp support Medical attention mmed Eyes skin resp sys [Chloroacetyl chloride] Chemical name structure/formula CAS and RTECSNoe and DOT ID and guide Nos Synonyms trade names and conversion factors Chlorobartzene W* 108*90-7 CZ017SOOO Benzene chlonde, MCB Phenyl chlonde 1194190 o Chlorobenzylidene CIC,H4CH=C(CN)j 2698-41 1 003675000 1 ppm "4 81 mg/m3 2 Chlorobenzalmaionitriie CS OCBM 74-974 PAS2SOOOO 1 ppm = 7 71 mg/m3 Bremochtoremethane ' CB. r* . ;CBk. ' - Hatanl01T, ' Mettiyl chtorobromide 1887 160 Chlorodifluoromethane CHCIF2 75-45-6 PA6390000 1 ppm 5 29 mg/m5 Difluorochloromethane Fluorocarbon 22 Freon 22 Genetron 22 Monochlorodifluoromethane Relngerant 22 1018 126 1 ppm = 3 54 mg/m3 Exposure lands |TWA unless noted otherwise) ABD00022786 IDLH Physical description NtOSH See Appendix D OSHA 75 ppm . (350 mg/m3) 1000 ppm Colorless liquid with an almondlike odor NiOSH C 0 05 pprv (0 4 mg/m3) [Skin) OSHAt 0 05 ppm (0 4 mg/m3) 2 mg/m3 /*h White crystalline solid with a pepper like odor Chemical and physical properties MW, BP, SOL FI P IP Sp Gr flammability VP FR2 UEL LEL MW 1126 BP 270*F Sol 005% FI P 82*F IP 9 07 eV VP 9 mm FRZ. -50'F UEL 9 6% LEL 1.3% Incompatibilities and reactivities Strong oxidizers Sp-Grl 11 Claes 1C Flammable Liquid MW 186 6 BP 590 599 F Sol Insoluble FI P n IP h VP 0 00003 mm MLT 203 205 F UEL 7 LEL 7 MEC 25 g/m3 Strong oxidizers Sp Gr 7 Combustible Solid Measurement (See Table 1) Char GCfrlD IV (#1003, Hydro* carbons) Filter/ Tenax GC Reagent HPLC/UVD 11(5) [P&CAM NIOSH/OSHA 200 ppm (1050 mg/m5) v NIOSH 1000 ppm (3500 mg/m3) ST 1250 ppm (4375 mg/m3) OSHAT none 2000 ppm ` CotortesS to pale- i MW- 1294 yeBowr liquid with BP-.155T A 4tileraremv8ke Sol Insoluble odor FIP NA (Note. May be used " IP-10 77ev . -as a fire : exbnguisttng VPIISntm* ' FRZ. -1247F. ' UEL NA . . -LEUNA * ? '/ > '* SpOr 193 NpncombusbMe Liquid <, Chemfceiy-ective ' .Chan. , metal*suchasy. 1 < .C8_wi' - , calcium powdered OWFJR:,: . aluminum,zinca IV* maneslum ," . 1 . ,, Vd* !Sr r " h. * ' " " r- ,,Hydro-*', -? ,j bartons) n. '* , N D Colorless gas with MW 86 5 VP 9 4 atm Alkalis alkaline earth Char(2) a famt sweetish BP -41 F FRZ 231 F metals (e g powdered Methylene Odor Sol(77 F) UEL NA aluminum sodium chloride [Note Shipped as 0 3% LEL NA potassium zinc) GC/FID a liquefied FI P NA IV compressed gas J IP 12 45 eV [#1018] RGasD 3 11 Nonflammable Gas Personal protection (See Table 31 Skm Eyes Wash skin Change Remove Prevent skm contact Prevent eye contact When contarn NR When wet (flamm) [Chlorobenzene] Skin Eyes Wash skin Change Remove Preveni skin contact Prevent eye contact When contam/Daiiy Daily When wet or contam (o ChlorobenzyNOene maionomtrile] SMn. vJashskin Change Remove Prevent skin contact Prevent eye contact When contam NR When wet or contam [Chlorobromomethanel Skin Eyes Wash skm Remove Change Provide Frostbite Frostbite NR NR NR Frostbite [Chlorodifluoromethanel ABD00022787 Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table 4) Route Symptoms (See Table 5) OSHA If* Irrtt eyes, skJn nose 1000 ppm SA CFVPAPROV^CCRFOV/ Ing drow inco, CNS depres, GMFOV/SC8AF/SAF Con mammals liver,lung, SCBAF PD PP/SAF P0 PP ASCBA kidney inj Escape GMFOV/SCBAE Health hazards First aid (See Table 6) Target organs (See Table 5) 1C, Breath Swallow- Irrknmed Soap wash prompt Reap support Medical attention tmmed Eyes, skin, reap sys CNS, liver NIOSH/OSHA 2 malm5 SA CF'fGMFSHiE/SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFSHiE/SCBAE lnh ABs Ing Con Pam burn eyes lac conj eryt eyelids blepharospasm imt throat cough chest tignt read eryt vesic skin Eye Skin Breath Swallow Irr immed Soap wash immed Resp Support Medical attention immed Eyes skin resp sys NIOSH/OSHA 2000 ppm SA-CP^PAPROWCCRFOV/ GMFOV/SCBAF/SAF SCBAF PD PP/SAF PD.PP ASCBA Escape GMFOV/SCBAE Ml Ing, Cor Inn eyes skm throat; cortf. dlzz, CNS depres, puknedema lc Breath* Swallow Irr mimed Soap wash prompt Reap support MecUcal attention immed Eyes, skm, resp sys, * Uvef kidneys CNS TBAL \ lnh Con ('iq) Irnt resp sys conf drow nngmg in ears heart palp card arrhy asphy liver kidney spleen in; iiq frostbite - Eye Skin Breath * Frostbite Frostbite Resp support -,, '- Resp sys CVS CNS liver kidneys spleen 64 Chemical name structure/formula, CAS and RTECSNos , and DOT ID and guide Nos Synonyms trade names and conversion factors Ctilorodiphanyl (42% chlorine) CH4CIC|H3CI2 (approx) Aroctor 1242, PCB, Polychlonnated biphenyl 53469-21-9 TQ1356000 2315 171 (54% chlorine) Aroclon 1254 PCB Polychlorinated biphenyl 2315 171 Chloroform CHCI, 67-66-3 FS9100000 Methane trichlonde, Tnchloromethane 1888 151 bis Chloromethyl ether (CH2CI)jO 542-88 1 KN1575000 1 ppm = 4 88 mg/m5 BCME bis CME Chloromethyl ether Dichlorodimethyl ether Dichloromethyl ether Oxybis(chloromethane) 2249 153 Exposure limits (TWA unless noted otherwise) ABD00022788 IDLH Physical description NtOSH* Ca Ca [5 mg/m3) 0 001 mg/m5 See Appendix A [Note The NIOSH REL also applies to other PCBs ] OSHA 1 mg/m3 [skin] Colorless to lightcolored viscous liquid with a mild, hydrocarbon odor NIOSH Ca Ca (5 mg/m3] See Appendix A 0 001 mg/m3 (Note The NIOSH REL also applies to other PCBs ] OSHA 0 5 mg/m [sK.n] Colorless to pale yellow viscous liquid or solid (below 50F) with a mild hydrocarbon odor NIOSH Ca See Appendix A ST 2 ppm (9 78 mg/m3) (60-mm) OSHAT C 50 ppm (240 mg/m3) Ca Colorless liquid [500 ppm] with a pleasant odor NIOSH Ca See Appendix A Ca [N D ) Colorless liquid with a suffocating odor OSHA [1910 1008] See Appendix B Chemical and physical properties MW BP SOL FI P IP Sp Gr flammability VP FRZ UEL LEL Incompatibilities and reactivities MW 258 (approx) VP 0 001 mm BP 617-68VF FR2 -2*F Sol Insoluble UEL NA FI P NA LEL NA IP 7 Strong oxidizers Sp Gr(77*F) 1 39 Nonflammable Liquid but exposure in a fire results In the formation of a black soot containing PCBs, polychlonnated dlbenzofurans & chlorinated dibenzo-p-dioxina Measurement (See Table 1) Filter/ Ftortsd, Hexane, GC/ECD, IV [05503 PCBs] MW 326(approx) VP 0 00006 mm BP 689 734 F FRZ 50 F Sol Insoluble UEL NA ri P NA LEL NA IP 7 Strong oxidizers SpGr(77 F) 1 38 Nonflammable Liquid but exposure m a fire results m the formation of a black soot containing PCBs polychlorinated dibenzoturans & chlorinated dibenzo p dioxins Filter/ Flonsil Hexane IV (#5503 MW 1194 BP 143'F Sol(77'F) 05% FIP NA IP 11 42 eV VP 160 mm FRZ. -82*F UEL NA LEL NA Sp Gr 1 48 Noncombustible Liquid Strong caustics, chemicalty-actrve Char; cs?L metals such aa GCTFID, aluminumor mag IV nesium powder [01003 sodium & potassium Halog strong oxidizers nateo [Note When heated Hydro to decomposition, carbons) forms phosgene gas] MW 1150 BP 223F Sol Reacts FI P <66 F IP 7 VP(72"F) 30 mm FRZ -43 F UEL ' LEL ' Acids water [Note Reacts with water to form hydrochloric acid & formaldehyde) Imp Reagent GC/ECD OSHA [#10] Sp Gr 1 32 Class IB Flammable Liquid Personal protection (See Table 3) Skr Eyes Wash skirt Remove Chengs Provide Prevent skin contact Prevent eye contact When contaro When wet or contain Daily Eyewash, Quick drench [Chiorodiphenyl (42% chlorine)) Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet or contam Daily Eyewash Qjickdrerch [Chiorodiphenyl i54co chic ine J Stan, Eyes. Wash skirt Remove. Ciwige Provide Prevent skin contact Prevent eye contact When contam When wet or contam NR Eyewash Quick drench [Chloroform] Skin Eyes Washskm Remove Change Provide Prevent skin contact Prevent eye contact When contam/Daily When wet (flamm) Daily Eyewash Quick drench [bis Chioromethyi ether] ABD00022789 Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table 4) NIOSH % SCBAF PD PPJSAF PD PP ASCBA Escape GMFOVHIE/SC8AE Route Symptoms (See Table 5) Inh imt eyes, chloracne Abs liver damage, repro Ing effects [care] Con Health hazards First aid (See Table 6) t Breath Swallow- Irr immed Soap wash immed Resp support Medical attention mmed Target organs (See Table S) Skin, eyes, liver, repro sys [mammal* tumors of the pituitary gland Sliver,leukemia] NIOSH SCBAF PD PP/SAF PD PP ASCBA Escape GMFOVHiE/SCBAE Inh Abs Ing Con Irrit eyes chloracne liver damage repro effects ,carc] Eye Sk n Breatn Swallow irr mmed Soap wash immed Resp suppor" Medical attention immed Skin eyes liver repro sys ,m animals tumors of the pituitary gland S liver leukemia] NIOSH V SCBAF PD PP/SAF PD PPASCBA Escape GMFOV/SCBAE ttl Imt eyes skin dizz Abs mental dullness nau conf Ing head, ftg anes enlarged Con liver [care] IS, Breath Swallow Irr immed Soap wash prompt Resp support Medical attention Immed Uver, kidneys, heart eyes, Skin CNS [in animals liver & kidney cancer] . / NIOSH V SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV'SCBAE inh Abs Ing Con Imt eyes skin mjc memb resp sys pulm congestion edema corn damage nec deer pulm function cough dysp wheez blood staned sputum bronchial secretions (care] Eye Skin Breath Swallow irr immed Soap wash immed Resp support Medical attention immed Eyes skin resp SyS [lung cancec[ ABD00022790 Chemical name structure/formula CAS and RTECSNos and DOT ID and guide Noe Synonyms trade names and conversion factors Chtoromethyl methyl ether CHpCH^CI 107-30-2 KN6650000 ' 1239131 ChJorodimethyl ether Chloromethoxymethane, CMME DimethyfchJoroether Methylchloromathyl ether Exposure Umte (TWA unless noted otherwise) IOLH NIOSH Ca See Appendix A Ca [NO] OSHA11910 1006] See Appendix B Physical description Colorless liquid with an irritating odor Chemical and physical properties MW BP SOL FI P. IP Sp Gr flammability VP FRZ UEL LEL MW 80S BP 138'F Sol Reacts FI P(oc) 32*F IP 1025 eV VP(704F) 192 mm FRZ.-154'F UEL 7 LEL ? Sp Gr 106 Claes IB Flammable Liquid 1 Ctito'o 1 mtropropane CHjCHjCHClNO; 600 25 9 TX5075000 Korax Lanstan NIOSH 2 ppm 10 mg/m1) OSHAT 20 ppm MOO mg/m3j 100 ppm ' ppm - 5 06 mg/m3 Chloropentafluoroethana FluorecarborvIlS, Freon115 CCIfjCF, Qenatren115, HakXMbonllS. 7645-3 ` MonochioropentaflUQroethane KH7977S00 V v 'i 4^ I 102Q iaf_ , / * 1 ppm^S^mg/m5 NOSH 1000 ppm (6320 mg/nP) , OSHAf none '/ -f 1 r (H '' NO 5 - Ll Chloropicnn CCl3N02 Nilrochloroform Nitrotncbloromethane Trichloromtromelhane NIOSH/OSHA 0 1 ppm (0 7 mg/m3) 2 ppm 76 06 2 PB6300000 '500 '54 1583 I54(mixture) 2629 131 (flammable mixture) 1 ppm = 6 72 mg/m3 Colorless liquid with an unpleasant odor (tungicidej MW 123 6 BP 289 F Sol 0 5% Fl P(oc' 144 F IP 9 90 eV VP'77 Fi 6 mm FRZ o UEL > -EL ? Sp Gr 1 21 Class 111A Combustible liquid Colorless gas with a alight, ethereal odor (Note Shipped as a liquated compressed gas.] MW-154 5 BP -38*F Sot(77*F); 0 006% FIP- NA IP 1296 eV VPfTO'F) 7 9 atm FRZ -223'F UEL NA LELNA ! .,i Colorless to faint yellow oily liquid with an intensely irritating odor (pesticide] RGesD`555 V NonflammableG#e MW 164 4 BP 234 F Sol 0 2% FIP NA IP 7 VP 18 mm FRZ 93 F UEL NA LEL NA Sp Gr 1 66 Noncombustible Liquid Incompatibilities and reactivities Measurement method (See Table 1) Water [Note Reacts with water to form hydrochloric acid & formaldehyde ] Imp: Hexane. GC/ECD, Scam *220] Strong oxidizers acids Chrom 108 Ethyl acetate GC/PID 11(5 j [#S211] AjkaUe alkaline earth metals (eg, aluminum powder, sodium, potaaelum, zinc) None available Strong oxidizers (Note The matenal may explode when heated under confinement) None available Personal protection (See Table 3) Skin Eyes Washskw Remove Change Provide Prevent skin contact Prevent eye contact When cortamfDaity When wet (flamm) Daily Eyewash Quickdrench (Chloromethyl methyl ether] Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam When wet or contam NR [1 Chloro 1 nitropropane) Site; ,, * Frostbite EyeK , ,/-? Frostbite WSsheWn: NR Remove, ? > MR " Change - NR Provide' Frostbite- ', < (Chloropantafluoroethane] Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet or contam NR Eyewash Quick drench [Chloropicrin| ABD00022791 Recommendations for respirator concentration for use (MUC) {See Table 4) NJOSH SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Route Symptom* (See Table 5) Hi Irrtt eyes, skin, Abs muememb.pulm Ing edema, pulm congestion, Con pneu skm bums nee cough, wheez, pulm congestion, Wood stained-sputum, low-wgt; bronchia) secretions, {care] NIOSH 20 ppm SA* 50 ppm SA CF'/PAPROV" 100 ppm CCRFOV/GMFOV/PAPRTOV'/ SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Inh Ing Con In animals irnt eyes pulm edema liver kidney heart damage Health hazards First aid (See Table 6) Iff, Breath Swallow- (trimmed Soap wash Immed Reap support Medical attention Immed Target organs (See Table 5) Eyes, skin rsspsys (irtanimsis skin Slung cancer] Eye Skin Breath Swallow - irr immed Soap wash Resp support Medical attention immed '' a' Resp sys liver kidneys CVS eyes TBAL . \ '** Hi -> DysKdia, Into, narco, Con nau, vomit; heart palp, Iff. (q) cartfarrhy, asphy; Breath llq frostbite, derm > ' - Vj ' ' _ ' % ' ^ ' 5 *^ ^ NIOSH/OSHA 2 ppm SACFe/PAPROVE/CCRFOV/ GMFOV/SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Inh Ing Con Irriteyes skin resp sys lac cough pulm edema nau vomit Iff, Breath Swallow Proitbrte'.j r','m Frostbite; Reap suppbrt, r ,i ' t'- i . ` Irr immed Soap wash immed Resp support Medical attention immed Eyes skin resp sys Chemical name structure/formula CAS and RTECSNos and DOT ID and guide Nos Synonyms trade names * factors B-Chtoroprene CHj-CCICH-CHj 126-994 EI9625000 -- Jg911131P(jfbitod) o-Chlorostyrene OC^.CHaSH 2039 87 4 WL4160000 2-Chloro-1 3-butadiene, Chloroprane <_ 1,ppm 3 62 rngAn* 2 Chiorostyrene ortho Chiorostyrene 1 Chloro-2-ethenylbenzene o-Chtofqtoiuene CtC^CH, 96-494 XS9000000 1 ppm = 5 67 mg/mJ l-Chkxo-2-methylbenzene, 2-Chlore-l-mefhvlbanzene 2-Chlorotokiene o-Toiyl chloride 2238 130 2 Chloro 6 trichloro methyl pyndine CiC5H3NCCi, 1929 82 4 US7525000 IppmeSIOrng/m* 2 Chloro 6 (trichloro methyl)pyndme Nitrapyrin N serve 2 2 2 6 Tetrachloro 2 picoline Exposure bruts (TWA unless noted otherwise) NOSH Ca See Appendix A (36 mg/m1) 8S 26 ppm szs** NIOSH 50 ppm (285 mj/m1) ST 7Sppm (428 mg/m1) OSHAT none NOSH 50 ppm (250 mg/m1) ST 75 DBm (375 mg/m1) OSHAf none NIOSH 10 mg/m1 (total) ST 20 mg/mJ (total) 5 mg/m1 (resp) OSHA 15 mg/m1 (total) 5 mg/m1 (resp) ABD00022792 IDLH Physical descnption Ca Colorless liquid (300 ppm) with a pungent, ether-like odor N D Colorless liquid NO Colorless liquid with an aromatic odor N D Colorless or whrte crystalline sold with a mild sweet odor Chemical and physical properties MW, BP SOL FI P IP Sp.Gr flammability VP FRZ UEL LEL MW 68 5 BP 139'F Sol Slight RP -4V IP 8 79aV VP 188 mm FRZ -153*F UEL 200% LL40% SpGr 096 Class 18 Flammabfa Uqufd MW 138 6 BP 372 F Sol Insoluble IP 7 VP(77 F) 0 96 mm FRZ 82*F LEL 7 Sp Gr 1 10 Class II Combustible liquid MW- 1266 BP 320*F SoHTTF) 0009% FI P 96*F IP 6 63eV VP(77*F)4mm FRZ.41*F UEL? LEL? SpGr 108 Class 1C Flammable Liquid MW 230 9 BP 7 Sol Insoluble FI P 7 IP 7 VP(73 F) 0 003 mm MLT 145 F UEL 7 LEL 7 Sp Gr 7 Combustible Solid (Explosive) Incompatibilities and reactivities Measurement method (See Table 1) Peroxides & other oxidizers (Note Polymerizes at room temperature unless Inhibited with antioxidants] Char, GCfpIO at {*1002] None reported None available Adds alkalis oxidizers, reducing materials, water Nona avaMXa Aluminum magnesium [Note Emits oxides of nitrogen ana chlonde ion when heated to decomposition ) None available Personal protection (See Table 3) SHn- V^ashskln Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet (flamm) NR Eyewash, Quicfcdmnch [ft-Chtoroprene] Skin Eye* Wash skin Remove Change Prevent skin contact Prevent eye contact When contam When wet or contam NR [o Chlorostyrene] ABD00022793 Recommendations for respirator concentration for use (MUC) (See Table 4) NIOSH SCBAF.PD PP/SAF PD.PP ASC8A Escape GMFOWSCBAE Route Symptoms (See Table 5) Mi Abs Ing Con Intt eyes, skin resp sya r>er irrfly, derm, alopeda; repro effects (oarc] Health hazards First aid (See Table 6) f Breath Swallow Irrimmed Soap wash Immed Resp support Medical attention Immed Target organs (See Table 5) Eyes, skin, resp ays, " repro sys [lung & skin cancer] TBAL rr Ing Con In animals imt eyes skin hema prot acidosis enlarged kver jaun Eye Skin Breath Swallow In immed Soap wash Resp support Medical attention immed Eyes skin liver kidneys CNS PNS Sun Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam When wet or contam Daily [2 Chloro-6 tnchloromethyl pyridine] TBAL Inti Abs Ing Con No adverse effects noted In ingestion studies with animals 1C Breath Swallow Irrimmed Soap wash immed Resp support immed Chemical name structure/formula CAS and RTECSNos and DOT ID and guide Nos Synonyms trade names and conversion factors Chlorpynfos CiH,1CI}NO}PS 2921 68-2 TF6300000 Chiorpyrifos-ethyl 0 O-Dieltiyl 0-3 5 6 trichloro 2-pyridyl phosphorothioate Dursban 2783 55 Chromic acid and chromates CrOj tacidi 1333 82 0 (CrO, GB6650000 [CrO ) 1755 60 (acid soin > 1463 42 (acid sond Chromic acid (CrO^i Chromic anhydride Chromic oxide ChromcumiVI, oxide 1 3) Chromium trioxide Synonyms of chromates u e chromium(VI) compounds) such as zinc chromate vary depending upon the specific compound Chromnjm(ll) compounds (as Cr) Synonyms vary depending upon the specific cnromlum{ll> compound (Note Chromiumill) compounds include soluble chromous sans ] Exposure limits (TWA unless noted otherwise) NIOSH 0 2 mg/m5 ST 0 6 mg/m5 (skin) OSHAf none NIOSH tas Cr Ca See Appendix A C 001 mg/m3 See Appendix C OSHA (as CrO, C 0 1 mg/mJ See Appendix C NIOSH/OSHA 0 5 mg/m5 See Appendix C ABD00022794 IDLH Physical description Chemical and physical properties MW BP, SOL FI P IP, Sp Gr flammability VP FRZ UEL LEL Incompatibilities and reactivities Measurement method (See Table 1) ND Colorless to white MW 350 0 VP 0 00002 mm Strong acids caustics OVS-2 crystalline solid BP 320'F MLT 108`F amines Toluene/ with a mild (Decomposes) UEL ? [Note Corrosive to Acetone mercaptan-like odor Sol 0 0002% LEL 7 copper & brass ] GC/FPD, [pesticide] FIP ? IV [Note Commercial IP ? [05600 formulations may Organo- De combined with phosporus combustible Sp Gr 1 40(Lquidett10'F) Pesticides] liquids ] Combustible Solid Ca CrO Car* red [15 mg,m3 odorless flakes as Cr VI i j or powder [Note Often used m an aqueous solution (H2CrOp ] MW 100 0 VP Very low Combjstible organ c BP 482 F MLT 387 P or o'her readi y Decomposes UEL NA oxidizabie materials Sol b3o LEL NA (paper wood sulfur F' P NA aiummum plastics IP NA etc l corrosive to me'ais Sp Gr 2 TO (CrO-, CrO, Noncombustible Sold Out will acceiera e the Burning of combustible materials F Her Reagent Vis IV [#7600 Chromium Hexavaient] (A so #76341 250 rng/m5 [as Cr(ll>] Appearance and odor Properties vary deisending vary depending upon upon the specific chromium(il) the specific compound chromium(ll) compound Vanes Filter Acid FAAS IV (#7024 Chromium] Chromium ill i compounds as Cr Synonyms vary depending upor the specific chromiumilll) compound (Note ChromiumOHl compounds include soluble chromic sails ] NIOSH/OSHA 0 5 mg/m3 See Appendix C 25 mg/m3 [as Crlllli] Appearance and odor Properties vary depending vary depending upon upon the specific chromium(llli the specific compound Chrormum{l)>) compound 7anes Fi ter Acid FAAS JV [#7024 Chromium] Personal protection and sanitation (See T.ble 3| Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam When wet or contam Oaily [ChlorpyrifosJ Skm Eyes Wash skin Remove Change Provide Prevent skin contact prevent eye contact When contam When wet or contam Daily Eyewash Quick drench (Chromic acid and chromates] Skin. Eyes Wash skin Remove Change. Prevent skin contact Prevent eye contact When contam When wet or contam NR [Chromlum(ll) compounds (as Cr)J Skin Eyes Wash skm Remove Change Prevenl skin contact Prevent eye contact When contam When wet or contam NR (Chromium(lll) compounds (as Cr)J ABD00022795 Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table A) TBAl Route Symptoms (See fable 5) Inh Abs Ing Con Wheez,iarspasms salv bluish Ups skin miosis, blurred vision, nau vomit, abdom cramps dlarr Health hazards First aid (See Table 6) iGn Breath Swallow irr Immed Soap wash immed Raw support Medical attention tamed Target organs (See Table 5) Reap sye CNS PNS.pUsmachoi NIOSH SCBAF PD PP/SAF PD PP ASCBA Escape HiEF/SCBAE Inh Ing Con Irrit resp sys nasal septum perf liver kidney damage leucyt leupen monocy eosm eye inj conj skin ulcer sens derm (care) Skin Breath Swallow Irr immed Soap flush immed Resp support Medical attention immed Blood resp sys liver kidneys eyes skin (lung cancer) NIOSH/OSHA 2 5 mg/m* DM' S mg/m*- DMXSQ'/SA* 12 5 mg/m*- SA CFVPAPRDM* 25 mg/m* HIEF/PAPRTHiE'/SCBAF/SAF 250 mg/m* SAF PD.PP SCBAF PD PP/SAF PD,PP.ASCBA Escape HiEF/SCBAE . Mi Ing Con ImHeyes, sans derm NIOSH/OSHA 2 5 mg/m* DM* 5 mg/m* DMXSQ /SA* 12 5 mg/m* SA CF'/PAPRDM* 25 mg/m* HiEF/PAPRTHiE*/SC0AF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape HiEF/SCBAE Inh Ing Con Imt eyes sens derm t Breath Swallow Eye Skin Breath Swallow Irr Immed - ^ Water flush prompt K support \ ml attantwn tamed Eyas, skin t * V - `p / tf rm?; iV-V ", * Irr immed Water flush prompl Resp support Medical attention immed i'-i i* a, Eyes skin t* Chemical name strvctureftormula, CAS and RTECSNos and DOT ID and guide Nos Cr 7440-47-3 QB4200000 Chromyl chloride Cr(OCU2 14977-61-8 GB5775000 1758 1 37 Cfopfdol C,JH7CIjNO 2971-90-6 UU7711500 Coal dust GF8281000 1361 133 Synonyms trade names and conversion factors Chromium Chlorochramie anhydride Chromic oxychloride Chromium chloride oxide Chromium dichionde dioxide Chromium dioxide dichionde Chromium dioxychlonde Chromium oxychlonde Dichlorodioxochromium Coytfen 3 S-Dichloro-2 6-dimathyi 4-pyndino! Anthracite coal dust Bituminous coal dust Lignite coal dust ABD00022796 Exposure limits (TWA unless noted otherwise! IDLH Physical description NIOSH 0 5 mg/m3 See Appendix C 250 mg/m3 (as Cr) OSHA* 1 mg/m3 See Appendix C [Note The PEL also Blue-white to steel-gray lustrous, brittle hard odorless solid chromium salts} Chemical and physical properties MW BP SOL FI P, IP Sp Gr, flammability VP FRZ UEL.LEl MW 52 0 BP 4788`F Sol Insoluble FIP NA IP NA S/P Omm (approx) MLT 3452 F UEL NA LEL NA incompatibilities and reactivities Strong oxidizers (such as hydrogen peroxide) alkalis Sp Gr 7 14 Noncombustible Solid in bulk form but finely divided dust burns rapidly If heated in a flame Measurement method (SeeTable 1) Filter Acid FAAS IV (#7024J NIOSH Ca Ca (NO] See Appendix A See Appendix C 0 001 mg Cr(Vlym3 OSHA none Deep red liquid with a musty burning acrid odor [Note Fumes in moist air) MW 154 9 BP 243`F Sol Reacts FI P NA IP 12 60 eV VP 20 mm FRZ 142 F UEL NA LEL NA Sp Gr(77 F) 1 91 NoncombustiDle Liquid but a powerfji oxidizer Water combustible None substances halides available phosphorus turpentine [Note Reacts violently m water forms chromic acid chromic Chloride hydrochloric acid & chlorine Corrodes common metals ] NIOSH 10 mg/m3 (total) ST 20 mg/m3 (total) 5 mg/m3 si 15 mo/m3 (total) 5 mg/m3 (rasp) ND White to tight brown crystalline solid MW 192 1 BP 7 Sol Insoluble FIP NA IP 7 VP ? MLT >0O8"F UEL NA LEL NA Sp Gr? Noncombustible Solid but dust may explode In cloud form None reported Filter none Grav; IV [Particulates NOR #0500 (total) #0600 (rasp)] NIOSH See Appendix D OSHAf See Appendix C (Mineral Dusts) ND Dark-brown to black Properties vary depending solid dispersed m upon me specific coal air type None reported Combustible Solid slightly explosive when exposed to flame Filter none Grav IV [#0600 Particulates NOR (resp) [Also #7500) Personal protection (Se Table 3} Skin Eyes Washskin Remove Change NR NR NR NR NR (Chromium metal] Skm Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contac' When contam When et or contam NR Eyewash Quick drehch [Chromyl chlonde] ABD00022797 Recommendations for respirator concentration for use (MUC) (See Table 4) Route Symptoms (See Table S) NlOSH tnh Irrit eyes, skin, kmg 2 5 mg/m* DM* fib (nWotoglc) 5 mg/m1 OMXSQVSA' Con 12 5 mg/m5- SA CFVPAPRDM* 25 mg/m1 HiEF/PAPRTHlEVSCBAF/SAF 250 mg/m5- SAF PD PP SCBAF PD.PP/SAF PD,PP ASCBA Escape HSEF/SCBAE NlOSH k SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Inh Abs Ing Con irrit eyes skin upper respsys eye skin bums Health hazards First aid (See Table 6) Target organs (See Table 5) Skin Breath Swallow Immmed Water flush immed Resp support Medical attention immed Eyes skin tesp sys (lung cancer] Skin Eyes Wash skin Remove Change NR NR NR NR NR (Coal dust) TBAL Inh Chronic bron deer pulm tunc emphy Breath Fresh air 74 Chemical name, structure/formula CAS andRTECSNos, and DOT ID and guide Nos Synonyms, trade names and conversion factors Coal Ur pitch votatltot 65986-93-2 %6fopo;; V* > > ,* -> *'? J * fume (as Co) Co 7440-48 4 GF8750000 Synonyms vary depending upon tha specific compound (e g, pyrene, phenarthrena engine, , chty*ene,anUvacane4 ^aMnar. ooal tv pKcli. ' snd^reosote to be coal v UrproduetS.] Cobalt metal dust Cobalt metal fume Exposure limits (TWA unless noted otherwise) ABD00022798 IDLH Physical description NIOSH Ca Ca Black or dark[60 mg/m3] brown amorphous 0 Img/m* residue (cydohexene-extraotable fraction) See Appendix A See Appendix C OSHA[1910,10Q2) 0 2 mitfm3 (benzene-soluble fraction) See Appendix C NIOSH 0 05 mg/m5 20 mg/m5 (as Co) Odorless silver gray to black solid OSHAt 0 1 mg/m5 Chemical and physical properties MW, BP, SOL FI P IP Sp Gr flammability VP FRZ UEL, LEL Properties vary depending upon the specific compound Combustible Solids MW 58 9 BP 5612`F Sol Insoluble Ftp NA IP NA VP 0 mm (approx) MLT 2719 F UEL NA LEL NA Incompatibilities and reactivities Strong oxidizers Strong oxidizers ammonium nrtrate Sp Gr 8 92 Noncombustible Solid m bulk form but finely divided dust will bum at high temperatures Measurement (See Table 1) Filter Benzene Grav OSHA [#58] Filter Acid FAAS IV (#7027) Cobalt hydrocarbonyl (as Co) HCo(CO), 16642 03-6 GG0900000 HydrocoOalt tetracarbonyl Tetracarbonylhydndocobalt Tetracarbonylhydrocobalt NlOSH 0 Img/m5 OSHAt non Gas with an offensive odor MW 172 0 BP ? Sol 0 05% FI P NA (Gas) IP 7 i RGasD 5 93 Flammable Gas Air (Mote Unstable gas that decomposes rapidly n air at room temperature to cobalt carbonyl & hydrogen j Personal protection and sanitation (See Table 3) Skin Eyes Wasbskm Remove Change Prevent skin contact Prevent eye contact Daily NR Daily [Coal tar pitch volatiles] Sun Eyes .'.ash skn Remove Change Pi. e i` s. r _.nTac NR vVht con a" Aner AeT - <~o"'a" 3aii 'Cooa t 3usi' d^C '-'Tit. Prevent skin contact Prevent eye contact When comam When wet or contam Daily [CobaU carbonyl (as Co)] Prevent skin cortac P e.en- eye contact When .,,ntan When wet or contarr Dai'r 'Copait hyjrocarpor y1 as Cc ] ABD00022799 Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table 4) NIOSH * SCBAF PD PP/SAF PD PP ASCBA Escape GMFOVH1E/SC8AE NIOSH 0 25 mg m DM |J b mg DMXSQ ' DM = u SA 25 mg m SA CF n^pRQki PAPRCMTu 2 i mgrim' riifc1 SCB-.P SAT 20 mg'm' SAF PC PP SCBAF PD pP SA- PD ?p ASCBA Fsuape HiEF S.BAE Route Symptoms (See Table 5) Health hazards First aid (See Table 8) Target organs (See Table 5) Wt Con I'Vi `6 Con Derm, bron [cere] * i^ 1 * ,v - sy Ey-? trrimmed 8m ' Soap wash imrrted Breath.' . Rasp auppoft , t SwalioW,., ^edicaLattention, ' \ knmed.. Reap sya, akin, bladder kidney* [lung kidney & skin cancer) `-f a A/ -- / *y f*rv'>zA iV V w:, Xi,-'*' K'f' * + " r* )r Cougn dysp wheez deer pj'm func low wgt aerrm diffuse noduiar fib esp hypersensitivity asthma Eye Skin Brea'h Swai ow Ir immed Sobp wash Resp support Medical attention imrmed , TBAL ....a eyw.ekK'mucfherrtts?,i &<r.*',7V'f "Ifrtni'roatf'feyeslatoCreepsyaT gn, decrpulmfuncjv 3 ^ 1 >- . >+J.v '?-r! .r * . ^ *r - In animals irnl resp sys dysp cough Coer pulm func pulm edema Chemical name structure/lormula CAS and RTECSNos and DOT ID and guide Nos Synonyms trade names and conversion factors Copper (dusts and mists) 7440 50 8 GL5325000 Copper metal dusts Copper metaJ mists ABD00022800 Exposure Bmtts (TWA unless noted otherwise) IDLH Physical description Chemical and physical properties MW BP SOL FI P, IP, Sp Gr flammability VP FRZ UEL LEL NtOH ' / Ca - Ca 0 6*0.7 (Tjg/m* '{N.DJ wcmanlngtewsH " u Saa^AppandU-A ~`ir See AppandlK'C^. ,, ' Emission* released during the carboni zation of bituminous ooaTfor tbi production of coto. (Note Sea C for Properties vary depending upon the constituent Incompatibilities and reactivities None reported NlOSHVOSHA 1 m^/n)3 100 mp/m' (as Cu; I Note The REL and PEL also apply to other copper compounds (as Cu) except Copper fume ] Reddish lustrous malleable odorless solid MW 63 5 BP 4703 F Sol insoluble H P NA IP NA VP 0 mm ,approxj MLT 1981 F UfcL NA IEL NA Oxidizers alkalis sodium azide acetylene SpGr 8 94 Noncombustible Solid m bulk (orm but powdered form may ignite Measurement method (See Table 1) Filter BenzeneGray, IV [5023 Coal Tar Pitch Volatiles] Filter Acid FAAS IV (#7029J Cotton dust (raw Raw cotton dust NIOSH <0 200 mg(m3 See Appendix C 100 mg/m OSHA (Z 1 AS 1910 1043] See Appendix C Colorless odorless solid MW 7 BP Decomposes Sol Insoluble FI P NA IP NA VP 0 mm (approx) MIT Decomposes UEl NA LEL NA Strong oxidizers Sp Gr 7 Combustible Sold Personal protection and sanitation (See Table 3l Skin Eyw Wash skin Remove Change Prevent sKm contact Prevent eye contact Daily NR Daily [Coke oven emissions] Shir Cyes Wash $kn Remove Change P event skm contact Pre.ent eve __ntac Whe 1 _jntam Whe- wet ur contam DaiU 'Copper n_usts a'C lists Stun Wash skin Remove Change: NR NR NR NR. NR * '* t (Copper tome (as Cu)J Skin Lyes Wash skin Remove Change NR NR NR NR NR a s< [Cotton diist raw ARDQQQ22801 Recommendations lot respirator selection -- maximum concentration for use (MUC) (See Table 4) Route Symptoms (See Table 5) Health hazards Firstald (See Table 6) Targetorgans (See Table 5) NfOSH * SCBAF PD PP/SAF PD PP ASCBA Escape GMFOVHiE/SCBAE Inti Imteyei respsys, Con cougn.dyep.wheez, [care] Eye Breath In immed Reap support Skin reap eye, unnacy aya [stun, lung 1 _ kidney 4 bledfe cancan ,,r r - * :^ <:Ai - t' -'Jr- * ' ' ' V y >k fi ;> ' f' v`, -n,''"tt ,%r''vJi.V' A ^ NIOSH/OSHA 5 mg'iTi3 DM 10 mg/mJ DMXSQ A,SA 25 mgm' SACF/PAPRDM 50 rngfm3 HiEF'PAPRTHiE 'SCBAFlSAF 100 mg/m3- SAF PD PP | SCBAF PD PP'SAF PD PP ASCBA scape HitF'SCBAE Inh Ing Con Irnteyes nose pharynx nasal perf metallic taste derm mammals lung liver Kidney damage anemia Eye Skin Breath Swallow Irr immed Soap wash prompt Resp support Medical attention immed Eyes skin resp sys liver kidneys uhcr nsk with Wilson s disease) NtOSHOSHA 1 DMFu/SA 2 5 rog/m* SA-CF/PAPRDMFu ' 5 mgrtn*- HiEF/SAT CfipAPRTH, SCBAF/SAP ' , WOma/m*- SAF PD,PR iv A J SCBAF PD.PP/SAF'PD.PpJ cepe HiEFisCBAE _ ' ' v - 1 '< 'i^'TA-v NIOSH 1 mg/mJ 0 2 mgym' DXSQ/HiE/SA S mg/m' SA CF'PAPRD Omjm' HiEf/SAT CF/PAPRTHiEi SCBAF SAF 100 mg/mJ SA PD PP SCBAF PD PP/SAF PD PP ASCBA Escape HiEF'SCBAE irfi Byjsinons chest tight cough wheez dysp deer FEV bron mal fever chills upper resp symptoms after initial exposure Breath Fresh air CVS resp sys 78 Chemical name structure/formula CAS and RTECSNos, and DOT ID and guide Nos Synonyms trade names and conversion factors Cng* hafWcxJ* Cre^g heftWde No 1, 2H-(2Z44--TDichiorophenoxy)- CjHCljOCHjCHjOSO^a ethyl sodium sulfate 138-78-7 KK4900000 ^ ' t* if *. Exposure Hmfts (TWA unless noted otherwise) NtOSH lOmg/m* (total) 5mym* SKt list -5 mg/m? CH1C(H,OH 95 48 7 G06300000 2076 153 ortho Cresol 2 Cresol o-Cresyhc acid 1 Hydroxy 2-methylbenzerve 2 Hydroxytoluene 2-Methyl phenol 1 ppm = 4 43 mg/m3 NIOSH 2 3 ppm (10 mg/m3) OSHA 5 ppm (22 mg/m3) (skin) ARD00022802 IDLH Physical description 800 mg/m5 Colorless to white crystalline odorless solid [herbicide] Chemical and physical properties MW BP SOL FI P IP Sp Gr flammability VP FRZ UEL LEL Incompatibilities and reactivities MW 3091 BP Decomposes SoJ(7TF) 26% FIR NA IP ? VP 0 1 mm MLT 473`F (Decomposes) UEL NA LEL NA Strong oxidizers acids 250 ppm White crystals with a sweet tarry odor [Note A liquid above 88 F) Sp Gr 1 70 Noncombuetlbte Solid MW 108 2 BP 376 F Sol 2% ri P 170'F IP 8 93 eV VP(77 F) 0 29 mm MLT 88 F Sp Gr 1 05 Combustible Solid Class IIIA Combustible Liquid Strong oxidizers acids Measurement method (See Table 1) Filter Water; Vis (5) [#S356] XAD 7 Methanol GC/FID IV [#2546 Cresols and Phenol] p Cresol CH3C,HpH 106-44 5 G06475000 para Cresol 4 Cresol p-Cresylic acid 1 -Hydroxy-4-methylbenzene 4 Hydroxytoluene 4 Methyl phenol 1 opm = 4 43 mj/m3 NIOSH 2 3 ppm (10 mg/m3) OSHA 5 ppm (22 mg/m3) [skin] 250 ppm Crystalline solid with a sweet tarry odor [Note A liquid above 95`F ) MW 108 2 BP 396 F Sol 2% FI P 187'F IP 8 97 eV VP(77 F) 0 11 mm MLT 95 F UEL LEU302 F Sp Gr 1 04 Combustible Solid Class IMA Combustible liquid Strong oxidizers acids XAD 7 Methanol GC/FID [#2546 Cresols Phenqi] Personal protection (See Table 3) Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact Whencontam When wet or contam Daily (Crag herbicide] Skin byes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When conlam When wet or contam Daily Eyewash Quick drench [o Cresol] Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eyto contact Whencontam When wet or contam Daily Eyewash Quick drench [m Cresol] Sk n byes Wash Sk r Remove .hange PnviOe Rreven' $* r con'aet creve" eye contact When cor'am When wet o corta--i Dai y Eyewash Qu ck d ench ,j C esol ABD00022803 Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table 4) NIOSH SO mg/m3- DM 100 mg/m*- DMXSQ/SA 250 mg/m5- SA.CF/PAPRDM 500 mg/m5- HlEF/PAPRTHiE'/SAT CP*/ SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape HiEF/SCBAE Route Symptoms (See Table 5) Inh frrtt eyas, skin liver, tng kidney damage Con in animals CNS effects, convuls NIOSH 23 ppm CCROVDM/SA 57 5 ppm SACb/PAPROVDM 115ppm CCRFOVHir/GMFOVHiE/ PAPRTHiE /SAT CF / SCBAF/SAF 250 ppm SAF PD PP SCBAF PD PP/SAF PD PP ASCBA Escape GMFOVHiE/SCBAE NIOSH 23 ppm CCROVDM/SA 57 5 ppm SA CF/PAPROVDM 115ppm CCRFOVHiE/GMFOVHlE/ PAPRTHIEVSAT CF7 SCBAF/SAF 250 ppm SAF PD PP SCBAF PD PP/SAF PD PPWSCBA Escape GMFOVHiE/SCBAE NlOSk23 ppm CCROVDM/SA 5'5 ppm SA CF PAPROVDM 115ppm CCRFCVHiE/GMFOVHiE PAPRTh E 'SAT CF ' SCBAF SAF 250 ppm SAF PD PP SCBAF PD PP SAF PD PP ASCBA Escape GMFOVHiE/SCBAE Inh Abs Ing Con Irnt eyes skin muc memb CNS effects corf depres resp fail dysp irreg rapid resp weak pulse eye skin burns derm lung liver kidney pancreas damage Hi ' Abs Ing Con lirtteyas, skin muc memb CNS effects conf, depres reap tail, dysp, Irreg rapid reap, weak pulse eye, skin bums, derm lung, liver kidney pancreas damage Inh Abs ,ng Con ) rrt eyes sk r muc memb CNS effects conf depres resp fai dysp irreg rapid resp weak pulse eye skin burns derm lung liver kidney pancreasdamage Health hazards Flrstald (See Table 6) Target organs (See Table S) Breath Swallow Irr Immed Water wash prompt Reap support Medical attention Immed Eyes skin, CNS, liver kidney* lfn Breath Swallow - Irr immed Soap wash immed Resp support Medical attention immed Eyes skin resp sys CNS liver kidneys pancreas CVS IlSi' Breath Swallow; (tf trrtmed ' Soap wash Immed Resp support Medical attention Imped Eyas, akin rasp sys, CNS, liver Kidneys, pancreas, CVS Eye Skin Breath Swallow irr immed Soap wash immed Resp support Medical attention immed Eyes skm resp sys CNS liver kidneys pancreas CVS Chemical name, structure/formula CAS andRTECS Nos and DOTIDsnd guide Nos Synonyms trade names and conversion factors Crotonaldehyde CHjCH-CHCHO 4170-30-3 GP9499Q00 2-Butenal, Wdethyl acrolein, Propylene aldehyde 80 1143 131p(mhiMd) Crufomate C,jH19CIN03P 299 86 5 TB3850000 1 ppm 2 87 mg/m* 4 ! Butyl 2 chlorophenyl methyl methylphos phoramidate Dowco '32 Rueiene Cunena 98-82*8 GR8575000 1918131 Cyanamide NHjCN 420-04 2 GS5960Q00 Cumol laopropyt benzene 2-Phenyl propane 1 ppm * 4.92 mg/m5 - Amidocyanogen Carbimida Carbodllmide Cyanogen nitride Hydrogen cyanamide (Note Cyanamide is also a synonym for Calcium cyanamide ] Exposure limits (TWA unless noted otherwise) NIOSH 2 ppm (6 mg/m5) See Appendix C (Aldehydes) OSHA 2 ppm (6 mg/m5) NIOSH 5 ma/rn3 ST 20 mg/m3 OSHAT none ABD00022804 IDLH Physical description Chemical and physical properties MW BP SOL FI P IP Sp Gr flammability VP FRZ UEL LEL 50 ppm Water white liquid with a suffocating odor [Note Turns pale- yellow on contact with air] MW 701 BP 219F Sol 18% FI P 45'F IP 9 73eV VP 19mm FRZ-1Q1T UEL1$5% LEL2.1% Sp Gr 0 87 Class IB Flammable Liquid ND White crystalline solid m pu-e form (pesticide' [Note Commercial product s a yellow o l ] MW 291 7 BP Decomposes So' in$oioble FP7 |P 0 VP(243 F' 0 01 mrr MLT 40 F UEl 7 LEL 7 NIOSH/OSHA SO ppm (245 mg/m5) [skin] 900 ppm [10%lL] Colorless liquid with a sharp penetrating aromatic odor Sf Gr 1 16 ,,ur it us i,,ie Sci c MW 120 2 BP 306*F Sol Insoluble FI P 98*F IP 8 75 V VP 8 mm FRZ.-141 aF UEL6 5% LEL 0 9% NIOSH 2 mg/m3 OSHAt none N0 Crystalline solid Sp Gr 0 88 Class 1C Flammable Liquid MW 42 1 BP 500 t (Decomposes) Sol(59 F) 73% FI P 286 F IP 10 65eV VP 7 MLT 113 F UEL ? LEL K Sp Gr 1 28 Combustible Solid Incompatibilities and reactivities Measurement method (See Table 1) Caustics ammonia strong oxidizers nitric acid amines [Note Polymerization may occur at elevated tempera tures such as in fire conditions ] Bub Reagent PLR IV [#3516] Strongly alkaline & strongly acidic media iNote unstable ove long periods m aaueous preparations o above 43 c Filter none Z'3v 1V (#U6(J0 Particu ales NOR i rotai'] Oxidizers mtnc acid sutfunc acid [Note Forms cumene hydroperoxide upon long exposure to air J Char cs, gc)fid IV [#1501 Aromatic Hydro carbons] Above 104 F Moisture acids or alkalis 1 2 phenylene diamine salts [Note Polymerization may occur on evaporation of aqueous solutions ] Filter none Grav III (#0500 Nuisance Dust (total)] Personal protection and sanitation (See Table 3) Skin Eyes Wash skin Remove Change Provide Prevent akm contact Prevent eye contact When corlam When wet (flamm) NR Eyewash Quick drench [Crotonaidehyde] Skin byes Wash skin Remove Change Prevent skin contact Prevent eye contact When contain When wet oi contam Daily iCrufoma'e Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam When wet (flamm) NR [Cumene] Skir Eyes AashsKir Rem;,e Change Piovce P e ent skin contact P even- e,e contac Aner con an A'-e" wet or contam Da E,ewash Qjickd encn [Cyargmide' ABD00022805 Recommendations (or respirator selection -- maximum concentration for use (MUC) (See Table 4) Health hazards ------------------------------------------------------------------------------------------------------------------------------- ----------------- Route Symptoms First aid Targatoroans (See Table 5) (See Table 6) (See Table 5) NIOSH/OSHA 20 ppm CCROWSA* SO ppm SA CF*fPAPROV*fCCRFOV/ GMfOV/SCBAF/SAF SCBAF PO PP/SAF PD PP ASCBA Escape GMFOV/SCBA6 Wi log Con Imt eyes reap sys mammals dyap pulm edema Smt skin |Sn Breath Swallow Irr Immed Water flush immed Reap support Medical attention immed Eyes, skin resp sys TBAL Mi Abs Ing Con trnt eyes Skin resp sys wheez dysp blurred vision lac sweat abdom cramps diarr nau anor Eye Skin Breath Swallow Irr immed Soap wash immed Resp support Medical attention immed Eyes skin resp sys blood chol 81 NIOSH/OSKA 500 ppm CCROWSA* 900 ppm SA CF'/PAPROWCCRFOV/ GMFOV/SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE HI Abs Ing Con irrtteyes skin.mucmemb, derm, head, narpo coma , `IS Breath Swallow - tmlmmed Water Rush prompt Resp support Medical attention knmod * TBAL - inh Abs ing Cor- 1 rt eyes skin resp sys eye skin buns miosis salv lac twitch An abuse like e*fects - Eye Skin Breath Swallow !- Irr immed Water flush immed Resp support Medical attenton immed " Eyes skin resp sys CNS Chemical name CAS and RTECS Nos and DOT ID and guide Nos Synonyms trade names and conversion factors Cyanogen NCCN 460-19-5 GT1925000 Carbon nitnde Dicyanogen Ethanedimtnle Oxalonltnle 82 1026 119 Cyanogen eh'onde CiCN 506 77 4 GT22'5000 1 ppm2 13 mg/m5 Cniorcyan Chlorine cyanide Chlorocyanide Cnlorocyanogen 1589 125 i m bi eJ Cyclohexane 11062-7 GU6300000 ppm = 2 52 mgrm5 Benzene hexahydnde, Hexahydrotoenzene Hexamtfhytone, Haanapfithena 1145 128 Cyclohexanelhioi Cf SH 569 69 3 GV762500C 1 ppm 3 44 mg/ms Cyclonexylmercaptan Cyciohexylthioi 3054 131 1 ppm = 4 '5mgm Exposure limits (TWA unless noted otherwise) NIOSH lOppm (20 mg/m5) OSHAf none NIOSH C 0 3 ppm (0 5 mg/mJi OSHAT rone NIOSH/OSHA 300 ppm (1050 mgim3) NIOSH C 0 5 ppm 2 4 mg,m3 5-mmi OSHA norve if ARnnnrmanfc__________________________________________________________________________ . IDLH Physical description Chemical and physical properties MW BP SOL FI P IP Sp Gr flammability VP FRZ UEL LEL Incompatibilities and reactivities Measurement (See Table 1) ND Color.ess gas with MW 52 0 VP(70 F) Acids water strong None a pungent almond BP 6`F 5 1 atm oxidizers (e g availa ble like odor Sa 1% FRZ 18 F dichlonne oxide [Note Shipped as FI P NA (Gas) UEL 32% fluorme) a liquefied compressed gas IP 13 57 eV LEL 6 6% (Note Slowly hydrolyzed in water to Forms cyanide form hydrogen cyanide m the body ] RGasD 1 82 Sp Gr 0 95 (Liquid at -6"F) oxalic acid or ammonia [ Flammable Gas ND .obness gas or liquid below 06 F wi li an irr ta ng OCCr [Note Shippec as a iqje'iec gas A scld ce ow 20 F l o -s c/ande in tne cod, MA 6 c 5ci 0 'P _1u~m LcL N-- RGasD 2 16 So Gr 1 22 'l qud a* 32 r No'-flarnmaLle Gas 7 a er anas a ka is am ror ij a cor uiS iNute -an rcac .er. None a aiiacc tor" hydrogen c,an ng Mi, be s abi iu d e er pel, *"er _ i .n 1 Colorless liquid with a sweet chloroform like odor [Note A solid below 44*F ] MW 84 2 BP 17TF Sol Insoluble FI P O'F IP 6 88 eV VP 78 mm FRZ 44 F UEL 8% LEL1 3% Sp Gr 0 78 Class IB Flammable Liquid Oxidizers Char GCfclD IV [#1500 Hydro carbons] ND Ccloress iquid wn a strong offensive ocor M.v '62 Sol nscljhle * = I'O F IP o -P 1 3 JEl __L Cud ze s educing a*er s s reng acics dkal r ( als Ncre a3 iaoie Sp o 0 98 k lass i C omt k s n Muir Personal protection {Soe Table 3) Skm Eyes Wash akin Remove Change Provide Frostbite Prevent eye contact/ Frostbite NR When wet (flamm) NR Frostbite [Cyanogen] Skin Eyes Wash skin Remove C idt Pro 'de Prevent skm contact ilie;i P event eye contact 1 q i v/tie co-'am iiiQ Anen wet o cor lam liq i NR Eyewash hq Quick d ench i iq (Cyanogen ;hio ioe, Skm Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam When wet (flamm) NR [Cyclohexane] S n B yes Wash sk n Remove Change Provide P e em skr contac P e e it eye contac Whe qntarr vVhe~ wet or oontam NR Tvewash Qjickdench (Cyclohenanethici ABD000228n7 Recommendations for respirator selection -- mnlmum concentration for use (MUC) (See Table 4) Route Symptom* (See Table 6) Health hazard* First std (See Table 6) Target organ* (See Tables) TBAL T B AL Ml trrtt eyes, noe*. upper Con respeys, lac, cherry red llpt tachypnea, hypemea bradycardia,, head, vertl, convule, dizz toss of appetite, tow-wg*. Inf frostbite liS ' Breath Frostbite Frostbite Rasp support y i > ,~ , l. * >' - , r > '' i'~ > Inh Abs iqi Con imt eyes upper resp sys cough delayed pulm edema weak head gidd dizz conf nau vomit irreg heartbeat m1 skin vliq i Eye Skin Breath Swallow Irr immed Water wash immed (hq) Reap support Medical attention unmed Evee,reepey*,; CNS CVS Eyes skin resp sys CNS CVS NIOSH/OSHA Ml 1300 ppm SA CF'VPAPROV'VCCRFOV/ Ing GMFOV/SCBAF/SAF , Con SCBAF PD PP/SAF PD,PP ASCBA Escape GMFOV/SCBAE V1 NIOSH 5 pprr- CCRGV'SA 1 2 5 ppm SACF'PAPROV 25 ppm CCRFOV/GMFOV/PAPRTOV, SCBAFiSAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV'SCBAE inh Abs Ing Con InUfyeej skin, reap ye; crow dean, narco, > < ' * eat ' *; WtfV TMA.p(Offlpi. ,CNO 2 i * ' coma v . " , ? v A*'' Bwur1! Resp'"support -- * > .. ,"*?> 'pu1, ' , Swallow i ' Mediailattention a- ~,r;. ( . A; V- _ V _ '' , -1 1 K^-.-^fcwnod.. tu, . \ rr j_i*x*n. f. ^ 1-'--;-<--t f -;> "', J -a \ I'-Wob' ' [. /. a- ' f { . iw-r1**^1' -,vv--r 1. .s>f- - , ' ' ' U* V -r Irn' eyes skm resp sys head dm weak nau vomit convuls cough woeei: laryngitis dysp Eye Skin Breath Swallow Irr immed Soap flush immed Rasp support Medical attention immed Eyes skin respsys CNS Chemical name structure/formula CAS and RTECSNo* and DOT ID and guide Nos Synonyms trade names and conversion factors Cydohexano! C^,,OH 108-93-0 QV7875000 Anol, Cyclohexyl alcohol, Haxahydrophervol, Hexatn, Hydralln, Hydroxycyctohexane 1993 128,(combustlble ' liquid, nos) Cyclohexanone CfHl;0 108 9* 1 GW1050000 1 ppm a'4.10 mg/m* Anone Cydohexyl ketone Pimehc ketone 1915 127 1 ppm = 4 02 mg/m' Cydobexena - ri^" " Benzenetatntfjydrid#,' ceHfc _ f' ' " 130*3-8 T'* v L, *'/,.< , A- x'xi-, l'` Exposure Brruts (TWA unless noted otherwise) ABD00022808 IDLH Physical doscnption NIOSH 50 ppm (200 mg/m3) [skin] OSHAt 50 ppm (200 mg/m*) 400 ppm Sticky solid or colorless to light-yellow liquid (above 77T)wltha camphor-llke odor NIOSH 25 ppm COO mg/m3, OSHAt 50 ppm 20C mg'm'l 700 ppm Water white to pale yellow liquid with a peppermint or acetone like OCOr NIOSH/QSHA300'pRm; -2000 ppm 'Colorless liquid f With a sweet odor tv .4 v p->*'V'-3-11-- ' - - w*. H-- 'U- , *- Chemical and physical properties MW BP SOL FI P IP Sp Gr flammability VP FRZ UEL LEL MW 100 2 BP 322*F Sot 4% FI P 154F IP lOOOeV VP 1 mm MLT 77`F UEL ? LEL ? Sp Gr 0 96 Claes IIIA Combustible Liquid MW 98 2 BP 312 F Sol 15% FI P 46 F IP 9 14 eV VP 5 mm FRZ -49 F UEL 9 4`. LEu212 F, " 1C0 Sp Gr 0 95 Class IIIA ComcustiOe Liquid MW 82 2 BP 181*F Sol Insoluble RP11*F IP 8 9$ eV VP 67 mm FRZ.-154'P UEL? LEL? Cyclohexytamme CeHnNH, 108-91-8 GX0700000 Sp Gr 0 81 Class IB Flammable Liquid Aminocyclohexane NIOSH N D Colorless oi yellow MW 99 2 VP 11mm Ammohexahydrobenzene 10 ppm liquid with a BP 274 F FRZ 0 F Hexahydroamline (40 mg/m3) strong fishy Sol Miscible UEL 9 4% Hexahydroberizenamine amine like odor FI P 88"F LEL 1 5% OSHAt IP 8 37 eV none 2357 132 1 ppm = 4 06 mg/m' Sp Gr 0 87 Class IC Flammable Liquid Incompatibilities and reactiv ities Measurement method (See Table 1) Strong oxidizers (such as hydrogen peroxide & nltnc acid) Char 2 Propanol/ GC/^ID IV (#1402, AJcohois III Oxidizers rutnc acid Char CS GC/FID 1V #1300 Ketones I] Strong oxidizers [Note Forms explosive peroxides with oxygen upon storage] Char CS~ GC/FID IV (#1500, Hydro carbons] Oxidizers organic compounds acid anhydrides acid chlorides acids lead (Note Corrosive to copper aluminum zinc 8 galvanized steel ] Si gel H,SO, Gt/FID II (#221] Personal protection and sanitation (See Table 3) Skin:-: - Prevent skin contact Eft: Prevent eye contact Washekin: When content Remove:- 1 When wet or contam Change:. -. - Daily ; , . ___[Cydof(exaivol], Skin Eyes. Wash skin. Remove Change Prevent skin contact Prevent eye contact When contam When wet or contam NR (Cyclohexanone) S#V l . vjwhskut flemcwe: Prevent skin contact Prevent aye contact When contam t Whenwt)t(flamm) NR i ' Skin Eyes Wash skin Remove. Change Provide Prevent skin contact Prevent eye contact When contam When wet (flamm) NR. Eyewash. Quick drench [Cyclohexytamine] ABD00022809 Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table 4) Route Symptoms (See Table 5) NIOSH/OSHA' ' * Wv. ' . Irrrt eyes: skln,.nose, 400 ppm: CCROV/PAPROVV6MFOV/ . 'Abs throaf: skin: narco.. SAVSCBAF Ing : SCBAF:PD,PP/SAF;PD.PR:ASCeA; '-: VCon ' Escape GMFOV/SCBAE Vf Ms: iteWs G'/.w, -l tVV'fe k . i... ill 1 f NIOSH 625 ppm SA CF'/PAPROV1 700 ppm CCRFOV/GMFOV/PAPRTOV/ SCBAHSAF | SCBAF PD PP/SAF PD PPASCBA Inh Abs Ing Con Irnt eyes. skin, muc memb, head: narco, coma, derm. mammals liver, kidney damage Health hazards First aid (See Table 6) Target organs (See Table 5} Eye: ; Skin: Breath:-: ..Swallow;. It-1. . A Eye Skin Breath Swallow Irr Immed Ey. skip, resp tyt. :Water.wash prpmpt Resp support-.- . > . v-~ 'V t : Meolcal .attention ' . Immed !> *r / ** irr immed Water flush prompt Resp support Medical attention immed ", Ju Eyes, skin, resp sys. TBAL Inh Abs Ing Con Irnt eyes, skm, muc memb, resp sys; eye. skin burns, skin sens, cough. pulm edema drow, li-nead, dizz: dian. nau vomit Eye Skin: Breath Swallow* Water flush immed Resp support Medical attention immed Eyes, skin, resp sys CNS 86 Chemical name structurerformula CAS and RTECS Nos and DOT ID and guide Nos Synonyms trade names and conversion factors Cyclonlte CHAOt 121-82-4 XY8450000 Cyclolrimethytenatrlni- framlne, Hexahydro-1,3 5-trinttro- a-tnazme, RDX, Trunetftylenetrtnltrafnlne 13 5-Titnltro-1,3,$- triazscyclobexane C/dopen'adiene 542 92 , gy cocoo: * 3 Cyciopeniadiene Exposure IrnMs (TWA unless noted otherwise) NIOSH 1 Smg/m1 ST 3 mg/m* {skin] OSHAf none NIOSH/OSHA 75 ppm 200 mg m3' ABD00022810 IDLH Physical description NO While crystalline powder (Note A powerful high explosive j Chemical and physical properties MW BP SOL FI P IP Sp Gr flammability VP FRZ UEL LEL MW 222 2 BP ? Sol Insoluble FI P Explodes IP ? VP(230*F) 0 0004 mm MLT 401*F UEL ? LEI 7 750 ppm Colorless iidud with an irn atmg terpene ixe odor Sp Gr 1 82 Combustible Solid [EXPLOSIVE1) MJY 66 1 BP 1C? F Sol Insoljp e FI P oc 77 e IP 9 56 eV xP 40C mm FRZ '2' F UEL " LEL 7 Cydopenlane CAo ' 287-92-3 OY2390000 1148128 Cyhexatm C.H SnQh 13121 70-5 WH015OOOO 1 ppm = 2 70 Peotametfiytene > ,, , -f * V ** U -/, * 'NOSH ' ' 800 ppm , , (1?^9mg/m,)'* / -r OSHAf - r ' none ' NO ' Colorless liquid with a mild sweet odor S' ' ' 1 ppm 2 87 mg/m1 ' - TCHh Tr cyciohexylhyd oy Stannane Tr cyclohexyihydroxylir 'ncyciohexylstaro urn hydroxide T ncyclohexyltin hydroxide NIOSH 5~,g-> OSHAT 0 32 mg/m3 (3 mg m as Sn'] - 60 mgrm3 25 ma'm3 as Sni] Colorless to white neady odor'ess ;r,stallme powder nsectic ce) Sp Gr 0 8C Class IC Fla~m;able Liquid MW- 70 2 BP-12VF Sol Insoluble FI P -35'F IP-10 52 eV VP(68*F) 400 mm FRZ -137*F UEL 8 7% IR.11% Sp Gr 0 75 Class IB Flammable Liquid MW 385 2 BP 442 F Decomooses Scl nsoljDie HP NA P NA vP 3 mm i app cx M.T 383 c UEl NA l El NA Sp Gr 7 Incompatibilities and reactivities Measurement method (See Table 1) Strong oxidizers, combustible matenals heat [Note Detonates on contact with mercury fulminate ] Filter, none Grav IV [80500 Particulates NOR (total)) Strong Cxid zers `lumng mt ic acid sj `uric acid Note Polymerizes to Jic,c opentad ere upon standing ] Chrom 1Q4 Ethyl acetate GC FID IV [**2 5 2 3] Strong oxidizers (eg chlonne bromine fluonne) None available S rong ox'Cizers j traviclet 1 ght F ter XAL. 2 CH CQOH' Utn uN HPLC GFAAS [85534 O'ganotin Personal protection and sanitation (See Table 3) Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam/Daily When wet orcontam Daily Eyewash Quick drench [Cyelonltej1 Skin Eyes Wash s>.in Remove Change Pre e*' sv n contact "rever e,e con act .* "en -Or tam * _en Ae f an m S7 C/Coper ddier e Skin Eyes Wash skin Remove Prevent skin contact Prevent eye contact Daily When wet (flamm) [Cyclopantana] Skn E/es '/vast- skn Remove Change P even s* r contac' hR Ahe" contarr he" -vet or oontam Da , [Cyhe*a ABD00022811 Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table 4) Route Symptoms (See Table S) TBAL Inh Abs Ing Con Irrrt eyes skin head tmty ftg weak tremor, nau dizz, vomrt, insom convuls Health hazards First aid (See Table 6) S& Breath Swallow Irr immed Soap flush immed Resp support Medical attention Immed Target organs (See Table 5} Eyes skin CNS NOSH CSHA 750 ppm CCROv GMFOv PAPRCWSA SCBAf SC B^F PD PP S^F PD PP ASCBA Fsca e GM-Ov SCBAE lrVi Ing Con Irrite/es nose Eye Skin Breath Swaiio* rr immed Soap wasr prompt Resp support Medicar ahen ion rnmed Eyes espsys 87 TBAL Ing Con Imt eyes, skin nose throat, l>-heed dizz, euph inco nau vomit. stupor dry cracking skin e Skin Breath Swallow Irr immed Soap wash Rasp support Medical attention mined Ejs skin reap aye. CSHm 3 2 irjr' CCROVDM SA 8 mg SA Cr PAPROVDM 6mgull' 'CRrOvHib GMFOvHiE PAPRTOVHiE'SAT CF SCBAFSAF 8C mg,m SAF PD PP SCBAF PD PP'SAF PD PP ASCBA Escape GMFOVHiE SCBAE Inh Abs Ing Con Irnt e/es skin resp sys head vert sore hroat cojgn abdom pair vomit skin pjrns prurtus in an mals liver kidney damage E/e Skin Brea Swa h ow l r immed Soapwash immed Resp support Medical attention mnM Eyes skin respsys liver kidneys 88 Chemical name structure/formula CAS and RTECSNos and DOT ID and guide Nos Synonyms trade names and conversion factors 2 4-D CIjCjHjOCHjCOOH 94-75 7 AG6825000 Dlchkxophanoxyacetc acid 2,4 Dichlorophenoxyacetic acid Exposure limits (TWA unless noted otherwise) NIOSH/OSHA 10mg(m3 2785 162 C.M.CI' ChCC 60 2= ,, <.J332500: 2761 ' 51 Decaborane 8Hm 17702-41-0 HOHOOOOO 1866 134 i Decanethioi CH,iCh sSh 143 *0 2 p p DDT Licl-iur v phen,'I1 'he o ethane 1 1 ~r chloro 2 2 pisip cto opher, ethane N OSH L-d See -ppendu `` y JShA [si 1 Decaboron tetradacahydride 1 ppm^SOOrng/m' Decylmercaptan n Decylmercaptan ' Mercaptcdecane NIOSH 0 3 mgrm3 (0 05 ppm) ST 0 9 mo/m3 (0 15ppm) [skin] OSHAf 0 3 mo/m* (0 05 ppm) [akin] NiOSH COS ppm i3 6 mg m3 5 min OSHt lone pprr = 713 Tij/r ABD00022812 I0LH Physical description 100 mg/rn3 VVhite to yellow crystalline odorless powder [herbicide] Chemical and physical properties MW BP SOL FI P IP Sp Gr flammability VP FRZ DEL LEL MW 221 0 BP Decomposes Sol 0 05% FI P NA IP 7 VP(320"F) 0 4 mm MLT 280 F UEL NA LEL NA Incompatibilities and reactivities Strong oxidizers Measurement method (See Table 11 Filter Methanol HPLC/UVD IV [#5001] Ca mg m , Olio less _ i Sid S . wn le COr.de Alt! d S IJ- d .md'in occr l.,es f* Sp Gr 1 57 Noncombustible Solid but may be dissolved m flammable liquids M . 364 ; BP 230 F Lt.c' -- pcses S.i soluble Pi - ice l- ' ^ f MLT 22' c UEL ' LLL St eng .xiu .ers al<a is F ite sccciane GC LCD i3 |Sbc 4 15rog/m3 Colorless to white crystalline solid with an intense biter, chocolatelike odor Sp Gr 0 9s Comtus m e Sol d MW 122 2 BP 415*F Sol Slight FlP 176*F IP 9 88 eV VP 0 2 mm MLT 211-F UEL ? LEL 7 Sp Gr 0 94 Combustible Solid ND Colorless liquid wi h a strong odor MW 1 74 4 BP 465 F Sol Insoluble Fl P 209 F ip ~ ,P 7 FRZ 15 F JEL 7 LE. 7 Oxidizers water None halogenated com available pounds (especially carbon tetrachloride) (Note May ignite SPONTANEOUSLY on exposure to sir Decomposes slowly in hot water ] Oxidizers strong acics & bases alka i meta s n t ic acid None available Sp G 0 64 Class ll'B Combustible Liquid Personal protection (See TaDie 3) Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam Wien wet or contam Daily 12 4 0] S*n Eyes Aasn S'. ilemj e C"ange p 5 ce P e en sk i to a.i P e en e>e ce- a.t . ren ;o-'an Da .'he- *e t --n ar Dai , Eje^as- _ cp : e D0T Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact Wen contam/Daily When wet or contam Daily Eyewash Quick drench (OecaboraneJ Skin Eyes Wash ski i Ren ove C nange Prevent skin contact P event eve contact When -cntarr Wer wet or ccntam NR i' Decanetn o ] ABD00022813 Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table 4) Route Symptoms (See Table 5) NIOSH/OSHA 100 mg/m3 CCROVDMFu/GMFOVHiE/ PAP ROVDMFu/SA/SC BAF SC BAF PO PP/SAF PO PP ASCBA Escape GMFOVHiE/SCBAE Inh Abs tng Con Weak stupor hyporeflexia muse twitch convuls derm mammals liver kidneymj Health hazards First aid (See Table 6) Target organs (See Table 5) Eye Skin Breath Swallow Irr immed Soap wash prompt Resp support Medical attention immed Skin CNS liver kidneys NICSh SCbAF PD p=> SA- PD =>=> -,SCB>-scaje sf.'PC HiESCBmE nr /kLs ;s ir it eyes skin pares tur gue ups face 1 emcr npp e dizz ccnf mal near ttg c~n i lv pa esis a cs om ca "i Eye Skr B ear Swa, cw r immed S.ap wasn p _,mp' Resp suppu t Med -a a it - io n meo Cres skm CNS kid e,s 'i er PNS [ n ar ima S er r g S ,rnp-dl ; -me S| 89 NIOSH/OSHA 3 mg/m3 SA 7 5 mg/m3 SA CF 15 mg/m3 SAT CF/SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOVHiE/SCBAE Inh Abs Ing Con Oizz head nau li-head drow inco local muse spasm tremor convuls ftg mammals dysp weak liver kidney damage lfn Breath Swallow Irr immed Soap wash immed Resp support Medical attention immed CNS liver kidneys NIOSH 5 ppm CCROV/SA 12 5 ppm SA CF/PAPROV ?5 ppm CCRFOV'GMFOWPAPRTOV SCBAF SAF SCBAF PD PP SAF PD PP mSCBA Escape uWrO SC3AE Inh Abs Ing Ccn Irnt eyes skin resp sys conf dizz head drow nau vomil weak c orwuls Eye Skin Brea n Swal ow irr immed Medical alter t or t nr \ea Eyes skin respsys CNS Chemical name structure/formula CAS and RTECS Nos and DOT ID and guide Nos Synonyms trade names and conversion factors Demeton (C,HsO)jPSOCjH4SCjH5 8065-48-3 TF3150000 0-0-Diethyl-0(and S>-2{ethylthio)ethyl phosphorothioate mixture Systox Diacetone alcohol CH3COCHjC(CHj)jOH 123 42 2 SA9100000 Diacetone 4 Hydroxy 4 methyl 2 pentanone 2 Methyl 2 pentanol 4 one . ABD00022814. Exposure Ixnits (TWA unless noted otherwise) IDLH Physical description NIOSH/OSHA 0 1 mg/m3 [skin] 10 mg/m3 Amber oily liquid with a sulfur-like odor [insecticide] NIOSH/OSHA 50 ppm (240 mg/m') 1800 ppm [10%LEL] Colorless liquid with a faint minty odor Chemical and physical properties MW BP SOL FI P IP Sp Gr flammability VP FR2 UEL LEL MW 258 3 BP Decomposes Sol 001% RP-113'F IP ? VP 0 0003 mm FRZ. < 13`F UEL ? LEL 7 SpGrl 12 Class II Combustible Liquid MW 116 2 BP 334"F Sol Miscible FIP 125 F IP ' VP 1 mm FR2 -47"F UEL 6 9% LEL 1 8% 1148 129 2,4-Dtarmnoantsole (and Its salts) (NHjJjCjHjOCH, 615-05-4 BZ8580500 o Oiantsidine iNH C,H)OCH> 1*9 90-4 DD087500C 1 ppm = 4 75 mg/m 1 3-Dmlno-4-methoxybenzene 4-Methoxy-l 3-benzertediamme 4-Methoxy-m-phenylenediarrune Synonyms of salts vary depending upon the specific compound Diamsicine 3 3 Diamsidine 3 3 DimethoxyCenzidine NIOSH Ca Minimize occupational exposure (especially skin exposures) See Appendix A OSHA none Ca [ND] NlCSH Ca See Appendix A See Appendix C OSHA See Appendix C Ca ND ] Sp Gr 0 94 Class II Combustible Liquid Colorless solid (needles) [Note The primary use (including Its salts such ss 2 4-diaminoarusofe sulfate) is a component of hair 6 fur dye formu lations ) MW 1382 BP ? Sol ? FIP ? IP ? Sp Gr' Combustible Solid VP ? MLT 153`F UEL ? LEL 7 Colo less crystals that urn a vio>et co cr on stand ng (Note Used as a Oasis for many ayes j MW 244 3 BP 7 Sol Insoluble Fi p 403 F IP 7 VP 7 MLT 27S F UEL ' LEL 7 Sp Gr 7 Comoustible Solid Incompatibilities and reactivities Strong oxidizers alkalis water Strong oxidizers strong alkalis Strong oxidizers Oxidize's Measurement method (See Table 1) Filter/ XAD-2 Toluene GC/FPD IV (#5514] Char 2 Propanol/ CS, GC/FID IV [#1402 Alcohols HI] None available r er Aater HPiCiUVD ij l#5d 3 Dyesi Personal protection and sanitation (See Table 3) Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact Whencontam When wet or contam Daily Eyewash Quickdrench IDemeton) Skin Eyes Wash sun Remove Change Prevent skm contact Prevent e,e contact When contam Wen .vet c cor a~ NR [D ace .re a c-c-io Skin Eyes Wash skin Remove Change Provide Prevent skin comae Prevent eye contact When contarrvDaily When wet or contam Daily Eyewasn Quickdrench [2 4 Diammoanisole (and its salts)] Skin Lyes Wash skin Remove Change Provide Prevent skm contact Prevent eye contact When contam/Daily When wet or contam Daily Eyewash Quickdrench (o DiariS'C ne' ABD00022815 Recommendations tor respirator selection -- maximum concentration for use (MUC) (See Table 4) Route Symptoms (See Table 5) NIOSH/OSHA 1 mg/m3 SA 2 5 mg/m3 SA CF 5 mg/m3 SAT CF/SCBAF/SAF lOmg/m3 SA PD PP SC8AF PD PP/SAF PD PP ASCBA Escape GMFOVHiE/SCBAE Inh Abs Ing Con Jrrit eyes skin miosis acheeyes rhin head chest tight wheez lar spasm salv cyan anor nau vomit abdom cramps diarr local sweat muse tasc weak para gidd conf ataxia convuls coma low BP card irreg NIOSH/OSHA Inh IvS" ppm SA CFc PAPROV1- hg 1803 ppm CCRFOv GMFO/PrtPRTC, 1 Co SCB^-F SAF k ,CBAF PD PP SAF PD p=SCBA Ls.ape C M c 0 SCBmE Irnt eyes Skm nose throat corn damage ri a umals narc.. i er damage Health hazards First aid (See Table 6) Eye Skin Breath Swallow Irr immed Soap wash immed Resp support Medical attention immed Target organs (See Table 5) Eye9 skin respsys CVS CNS blood chol Lye Skm Breath Swahcw 1 rr immed Water flush prompt Resp support Med'ca arenticn immec Eyes skin resp S;S CNS liver 91 NIOSH SCBAF PD PP/SAF PD PP ASCBA Escape GMFOVH.E/SCBAE Inh AOs Ing Con In animals irnt skin thyroid liver changes terato effects [care] Eye Sk n Bre ath Swallow Irr immed Soap wash immed Resp support Medical attention immed Skin thyroid liver repro syS [m animals thyroid liver skm & lymphatic sys tumors) NIOSH SCBAF PD PP/SAF PD PP ASCBA Escnpe GMFOVHiE/SCBAE Inh AOs Ing Con Irnt skin in animals kidney liver damage thyroid spleen changes [can.] Eye Skin Breath Swallow Irr immed Soap wash immed Resp support Medical attention immed Skin kidneys liver thyroid spleen (mammals bladder liver stomach & mammary gland tumors] 92 Chemical name structure/formula CAS and RTECS Nos and DOT ID and guide Nos Synonyms trade names and conversion factors Otazmon# 333-41-5 TF332500C Diaztde0 O-Diethyl-O-2 isopropyl 4-methyl-6-pynmidinylphosphorothwate Spectradde 2783 1S2 Diazomethane CH N 334 88 3 PA7C00000 Azimethyiene Azomethylene Oiazinne 19287-43-7 HQ9275000 1911 119 propane CH.BrCHBrCH.CI 96 12 8 TX8750000 2872 159 1 ppm = 1 12 rog/m3 Boroethana, Boron hydrtd# Diboron naxaftydride `lppm113mg/m* 1 Chloro 2 3-dibromo propane DBCP Dibromochioropropane 1 ppm = 9 67 mg/m' Exposure ferrets (TWA unless noted otherwisel NIOSH 0 1 mg/m5 [skin] OSHAt none ABD00022816 OLH Physical description NO Colorless liquid with a faint ester-like odor Imsecticidel [Note Technical grade is pale to dark brown ] Chemical and physical properties MW BP SOI FI P IP Sp Gr flammability VP FRZ UEL LEL MW 304 4 BP Decomposes Sol 0 00484 FI P 180 F IP 7 VP 0 0001 mm FRZ ? UEL ? LEL ? SpGrl 12 Class IIIA Combustible Liquid Incompatibilities and reactivities Measurement method Strong acids & alkalis copper-containing compounds [Note Hydrolyzes slowty in water & dilute acid ] OVS 2 Toluene/ Acetone GC/FPD IV {5600 Organo- phosphorus Pestwdes] NIOSH/OSHA 0 2 ppm 0 4 mg/m i 2 ppm Yellow gas with a musty odor [Note Shipped as a liquefied compressed gas ] MW 42 1 BP 9 F Sol Reacts FI P NA ,Gas IP S 00 eV VP -1 atm FRZ 229 F UEL 7 LEL 7 RGasD 1 45 Flammable Gas [EXPLOSIVE1] Alkali metals water drying agents such as calcium arsenate [Note May explode violently on heating exposure to sunlight or contact with rough edges such as ground glass ] XAD 2 GC^FiD IV [*2515] NIOSH/OSHA (0 1 mg/m*) ISppm t Colorless gee with MW 27 7 e repulsive, sweet BP -135*F odor Sol Reacts [Note Usually Fl P NA (Gas) IP-11 38 eV pressurized cylinders diluted with hydrogen argon nitrogen, ' RGasD 0 97 . or netant.) j FlammableOae VP(82*F) 39 5 atm FRZ. -285*F UEL. 88% LEL 08% . Water halogenated Filter/ compounds aluminum Char*; kthtum oxidized surfaces acads [Note WU Ignite IV spontaneously In [6008] moist air at room tamperature Reaets ' with water to form ` hydrogen 9 boric add ] NIOSH Ca See Appendix A Ca [ND] OSHA [1910 1044] 0 001 ppm Dense yellow or amber liquid with a pungent odor at high concentre tions [pesticide] [Note A solid below 43*F ] MW 236 4 BP 364 F Sol 0 1% FI P(oc) 170 F IP ' VP 0 8 mm PRZ 43 F UEL 7 LEL 7 Sp Gr 2 05 Class IIIA Combustible Liquid Chemically active metals such as aJurrvnum magnesium & tin alloys [Note Corrosive to metals ] None available Personal protection (Se* Table 3) Stun Wash skin Remove Change Provide Prevent skin contact Prevent eye contact Wien contain When wet or contain Only Eyewash Quickdrench (OiazinonC] Sum Eyes Wash skin Remove Change Provide Frosibiie Pros oiie NR When .vet flam n i NR Prosit- te [DiazomethaneJ Stun Eyes. Weahskm Remove Change NR NR NR NR NR [Oiborane] Skir l yes Wash skin Remove Change Provide P eve i smr contact Preven eye con act Whe contam'Daily When wet or con am Eyewash OuiCk drench M 2 DiBrom o 3 ch'oropropane] ABD00022817 Recommendations torrespi rator selection -- maximum concentration tor use (MUC) (See Table 4) TBAL Route Symptoms (See Table 5) Ml Irrtt eyes miosis blurred Abs vision dizz. coni weak log convuls dysp saJv Con abdom cramps nau vomit Health hazards First aid (See Table 6) Eye Sun Breath Swallow Irr immed Soap wash immed Reap support Medical attention mmed Target organs (See Table 5) Eyes, resp sys, CNS CVS blood chol NlOSH/OSHA 2 ppm SA iSCBAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV'SOBAE hh Con liq, Irnl eyes cougn snort Drea'h head ftg flush skin fever chest pam pulrn edema pneui is asthma iiq `rostbi'e Eye Skir Breath Frostbite F rostbite Resp support Eyes resp sys NlOSH/OSHA 1 ppm SA 2 5 ppm SA CF 5 ppm SAT CF/SCBAF/SAF ISppm SAPDPP SCBAF PD PP/SAF PD PP ASCBA Escape GMFS/SCBAE NIOSH SCBAF PD PP'SAF PD PP ASCBA Escape GMFOVHiE/$CBAt Wi Chest tight precordral pam short breath non- productive cough nau head li-head verb chills fever ftp weak tremor muse late mammals liver kidney damage pulm edema hemorr Breath rr ADS Ing Con ir it eyes skn nose 'hroat drow nau vomit pulm edema liver kidney in) sterility (care) Eye Skin Breath Swallow Resp support Resp sys CNS liver kidneys ' Irr immed Soap wash immed Resp support Medical attention immed spleen repro sys digestive sys ol the nasal cavity tongue pharynx lungs stomach adrenal & mammary glands] Chemical name structure/formula CAS and RTECS Nos and DOT ID and guide Nos Synonyms trade names and conversion factors 2 N Dibutylaminoethanol (C,Hs)2NCH2CH2OH 102-61-8 KK3850000 Dibutylaminoethanol 2 Dibutylaminoelhanol 2 Di N-butylaminoethanol 2 Di N butylammoethyl alcohol N N Dibutylelhanolamme 94 2873 153 Dibutyl phosphate C<H Ol 'OHiPO 107 66 4 TB9605000 i ppm = 7 09 mg/m3 Dibuty acio o phosphate ai n Butyl hvcroger phosphate Dibutyl phosphors acid Dibutylphthalate CgH4(COOC4H9)j 84 74-2 TI0875000 ppm - 8 60 mg/mU D6P Dibutyl 1 2 benzene dicarboxylate Di-n butyl phthalate Exposure limns (TWA unless noted otherwise) NIOSH 2 ppm (14 mg/m3) [skin] OSHAt none NlCS-i i 5 mq m' ST 2 ppm 110 mq/m1 OSHAt ' ppm (5 mg/m5) NIOSH/OSHA 5 mg/m3 ABD00022818 IDLH Physical description N D Colorless liquid with a faint amine like odor 33 ppm Paleamber odorless liquid 4000 mg/m3 Colorless to faint yellow oily liquid with a slight aromatic odor Chemical and physical ____p_ro_p_er_ties_ ___ MW, BP SOL FI P IP Sp Gr flammability VP FRZ UEL LEL MW 173 3 BP 446 F Sol 0 4% FI P 195*F IP 7 VP 0 1 mm FRZ 7 UEL 7 LEL 7 incompatibilities and reactivities Oxidizers Sp Gr 0 86 Class IIIA Combustible Liquid M/v 2' C 2 BP 2'2 r (Decomposes i So Irso uDie FP ' IP 7 VP 1 mm i approx -RZ 7 UEL > -EL 7 Strong oxid zers Sp Gr 1 06 Combustible Liquid MW 278 3 BP 644`F Sol(77 F) 0001% FI P 315 F IP 7 VP 0 00007 mm FR2 31*F UEL ? LEL(456F) 05% Nitrates strong oxidizers alkalis & acids liquid chlonne Measurement method (See Table 1) Si gel Methanol/ Water GC/FID IV [#2007 Ammoethanol Compounds] Filter Cf CN GC'FPD '#501 Filter GC?F!D IV [#5020] Died oroacet/iene OCsCC '572 29 4 *P'380000 DC Dichioroeth,ne [Note Dt A s a ross bie decomposition p cduc o* rich loroeThyten e or tr chloroethane i ppm = 3 88 mg'm NiOSH Ca See Appendix A C 0 1 ppm i0 4 mg m i OSHAT none Ca N^, Class IIIB Combustible Liquid Vdatne oil with a disagreeable sweetish odo' (No e A gas aooe 90 F OCA s not producec commercially ] MW 94 9 BP 90 F (Explodesi So. 7 FP 7 IP 7 VP 7 FRZ 58 tc 8' F UE LE_ > Sp Gr 1 26 Combust'pie -lUJid Oxidizers heat spook None Personal protection and sanitation (See Table 3} Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet or contam NR Eyewash Quick drench [2-N-Dibutylaminoethanol] Skir Eyes Wash skm Remove Change Provide P even sr contact Pre.e-' eye con'act Wien con a -- 'Vie wet r cu i an NR Qu ck d ench (Qibury phosphate] Skin. Eyes Wash skin Remove Change NR Prevent eye contact NR NR NR (Diftutyl phthalate] Skm Eyes Wash skin Remove Change Provide Prevent skin contac Prevent eye contact When contam When wet iflamr-1 NR Eyewas- Quckdrencn IDichioroacetyiene' ABD00022819 Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table 4) TBAL Route Symptoms (See Table 5) Wi Abs Ihfl Con In animats imteyes skin nose derm skm com nec, low-wgt Health hazards First aid (See Table 6) Eye Skin Breath Swallow Irr immed Soap flush immed Resp support Medical attention immed Target organs (See Table 5) Eyes, skin, rasp ay* NlOSHiOSHA 1 Cppm SA 2b ppm SA CF JJ ppm SAT SCBAFiSAF SCBAf PD PP SAF PD PR ASCBA Escape GMPO'vHiE SCBAf Inh Ing Co" 1 nt eyes skin resp sys head Eye Breath Swallow rr immed Soap wash prompt Resp suppor* Medical attention mmed Eyes skin resp sys NIOSH/OSHA 50 mg/m3- OMF 125 mg/m3- SA CF/PAF'RDMt 250 mg/m1 HlEF/SCBAF/SAF 4000 mg/m1 SAF PD PP SCBAF PD PP/SAF PD PP ASCBA Escape HIEF/SCBAE Hi Ing Con Imteyes upper reap sys stomach NIOSH a SCBAF PD PPiSAFPO PP ASCBA Escape GMFOV'SCBAE mb Abs ing Con Head loss of appetite nau vomit intense jaw pain cranial nerve palsy in animals kidney 'iver brain inj low wgt [cere I Breath Swallow Eye Skin B eath Swa low Irr immed Wash regularly Rasp support Medical attention knmad Eyes rasp ays, Qi' tract " irr immed Soap flush immed Resp support Medical attention romed i- V CNS [m animals kidney tumors) 96 Chemical name Struclure formula CAS and RTECSNos and DOT ID and guide Nos Synonyms trade names and conversion factors o-Dichlorobenzene C6.H.Cl CZ4500000 o DCB 1 2 Dichlorobenzene ortho Dtchiorobenzene o Dichlorobenzol 1591 152 C M^i 1 uo 4s ' i. 245% i 1 ppm = 5 01 mgvnJ i 4 D chior z>er ze e "d d ODgn'cr u i` 3 3 3 Oichlorobenzidme (and ns salts) NH ClC.H C,H C NH 91 94 1 DD0525000 1 pom = b c g l 4 4 Diamino 3 3 dichloro biphenyl Dichlorobenzidme base oo Dichlorobenzidme 3 3 DiChlorobiphenyl-4 4 diamme 3 3 Dichloro 4 4 biphenyl diamine 3 3 Dichloro 4 4 diarrino biphenyl l'i - o <>cJifii o im.ui m e C1 f ,5/18 1 'A8 'I I'OnO L ifluor Jicnioroi (-lUOiocarbon 2 F eon* 12 GenetrorvE. 12 Halun 122 I'ropellaril 12 Refrigerant 1 2 ethane 1b-8 12b 1 ppm ~ 4 96 mg/m 1 Exposure limits (TWA unless noted otherwise) NIOSH/OSHA C 50 ppm (300 mg/m-j ABD00022820 IDLH Physical description 200 pom Colorless to paieyelio-v 'quid with apleasant aromatic oaor [herbicide Chemical and physical properties MW BP, SOL FI P IP Sp Gr flammability VP FRZ UEL LEL MW 147 0 BP 357 F So. 0 01% FI P 151 F IP 9 05 eV VP 1 mm FRZ 1F UEL 9 2% LEL 2 2% N 03-1 i. d bee -Hpe"d - OSn-T i ro~ *50 "9 m Ca = 0 ppm] .oN'iess v v.m'e cvs al me so ic ai - a mo ncai iKts y-pr [msec cde NlOSH Ca See Appendix A OSHAJ1910 1007) See Appendix B Ca [ND] Gray to purple crystalline solid Sp Gr 1 30 Class il'A Combustible Liquic M *\ 14 ' j 6 345 so : FI = ;0 - Ip 8 98 e. p 1 3 -rr- m.t :a f JC- ' -EL 2 5 SpGr 25 Combustible So lid but "'ay 'ake seme effor* to gn re MW 253 1 BP 788F Sol(59F) 0 07% FI P 7 IP 7 VP 7 MLT 271 F UEL ' LEL 7 Sp Gr 7 NlOSH OSHA 1090 ppi-n (4950 ng,m i 15 JU0 ppm Colorless gas with an other like odor at extremely high concentrations [Note Shipped as a liquefied compressed gas ] MW 120 9 BP 22 F Sol(77 F] 0 03% FI P NA IP 11 75eV JP 5 7 a.m FRZ 252 F UEL NA LEL NA RGasD 4 2 Nonflammable Gas Incompatibilities and reactivities Measurement method (See Table 1) Strong oxid.zers a urn nurr chlorides acids acid fumes Char GCVlD [#1303 Haioge nated Hydro caroons] S rorg c d ze s as c** cr re or permangarate sc: G'lar uS GC F - [ CC3 Haiogt r a e<l Hydro -amonsi None reported Filter/ Si gel Reagent HPLC/UVD IV [#5509) Chem cally active metals such as sodium po'assium calcium powdered aluminum zinc 4 maqre$<urn Chdii2 CH Cl GC?FlD IV [#1018] Personal protection and sanitation (See Table 3) Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam When wet or contam NR [o Dichlorobenzene] Skjn Eyes Wash skm Remote Change P i,vide P even skm contact Pre ent eye contact When contam Daily Whe- wet or co-i'am Ca y E ewasr 0_ic. crercr (D Cichlor;benze'e] Skm Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contarrVDaily When wet or contam Daily Eyewash Quick drench (3 3 Dichlorobenzidme (and its salts)] Skin Eyes Wash skin Remove Change Provide Frostbite Frostbite NR NR NR Frostbite (Dichiorodifluoromethanel ABD00022821 Recommendations tor respirator selection -- maximum concentration for use (MUC) (See Table 4) Route Symptoms (See Table 5) NIOSH/OSHA Inh 200 ppm CCRFOV/PAPROV<VSCBAF/SAF Abs SCBAF PD PP/SAF PD PP ASCBA Ing Escape GMFQV/SCBAE Con Irnteyes nose liver kidneydamage skin blisters Health hazards First aid (See Table 6) Target organs (See Table 5) Eye Skin Breath Swallow Irrimmed Soap wash prompt Resp support Medical attention immed Eyes skin respsys liverkidneys NIOSH SCBAF PD PP/SAF PO PP ASCBA Escape GMFOVSCBAE hr At $ 1r9 Con Eye mv swell pe ior: o ofuse rhi i hs read aror naj so it i w wq` ,aun ;i r n a'lma s i e `iu y, r, ca .] F/e Skir Brea r Swa ,cw r mmea Soap wash Resp seppo t Med ;a a te om ed L vGf resp Sy$ l es kid ne/s SKr -i anma $ It r-< & Ji e ta cer NlOSH V SCBAF PD PP/SAF PD PP ASCBA Escape HiEF/SCBAE Inh Abs Ing Con Skin sens derm head dizz caustic bums frequent urination dysuria hema Gl upset upper resp infection [care] Eye Skm Breath Swallow Irrimmed Soap wash immed Resp support Medical attention immed Bladder liver lung skin Gl tract [inanimals liver & Bladder cancer] NIOSH/OSHA 10 000 ppm SA 15 000 ppm SA CF/SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Inh Con ("q? Dizz tremor asphy uncon card arrhy card arrest hq frostbite Eye Skin Breath Frostbite Frostbite Resp support CVS PNS Chemical name structure/fonnula CAS and RTECS Nos and DOT ID and guide Nos 1 3 Oichloro-5 5 dimethylhydantoin 113-52-5 MU0700000 1 1 Dich oioethane CHCI CH KI0175000 2362 130 1,2-Oichlomethylene OCH-CHCl 540-59-0 KV9380000 1150 132P Dichloroelhyl ethe iCICHjCH j.O 111 -44-4 KNO07SOOO 19'6 152 Synonyms trade names and conversion factors actin DOH Hatane Asymmetncal dichloroethane Edyiidene chlonde 1 i Eth,hdenedichlQnde 1 ppm = 4 05 mgim1 Acetylene dchloride da-Acetylene bichloride trane-Aoetylene dichloride sym-Olchloroethylene 1 ppm = 3 97 mg/m3 Dis,2 Chloroe hybetner 2 2 Dichlorodie'hyl ether 2 2 OiChloroethyi ether 1 ppm = 5 05 mg/m1 Exposure limfc (TWA unless noted otherwise) NIOSH 0 2 mg/m3 ST 0 4 mg/m3 OSHAT 0 2 mg/m3 ABD00022822 IDLH Physical description 5 mg/m5 White powder with a cWonne-llke odor Chemical and physical properties MW BP SOL FI P IP Sp Gr flammability VP FRZ UEL LEL MW 197 0 BP ? Sol 0 2% FI R 348*F IP ? VP ? MLT 270*F UEL 7 LEL 7 NIOSH 100 ppm ,400 mo/m' See Appendix C iCh, oroethanes) OSMA 100 ppm '400 mg'm'i 3000 ppm Colorless oiy iqoid with a Ch orotorm like odor NIOSH/OSHA 200 com (790 mg/m3) 1000 ppm Colorless liquid (usually a mixture of the da & trans isomers) wfth a slightly acnd chloroform like odor NIOSH Ca Ca ' QC dom| See Appendix A 5 ppm 30 mg m i St 10 ppm 60 mgin-'i [sxin] OSHAT C 1 5 ppm '90 mg/m'l [skin Coior'ess iqud wi'h a cnionnatec so vent like ddor SpGrl 5 Combustible Solid M'A 99 0 BP 135 F Sol 0 6% F' P 2 F IP 1 06eV VP 182 im FRZ 43 F UEL 114% l tL 5 4 e Sp Gr1 '8 Class iB Flammable Liquid MW 97 0 BP- 118-140'F Sol 0 4% FI P 36-39*F IP 9 65 eV VP 180-265 wtn FRZ. -57 to IIS'F UEL128% LEL58% SpGrfTTF) 127 Class IB Flammable UquW MW '43 0 BP 352 r So 1% FI P 31 F IP 1 VP 0 7 ~m FRZ 53 F UEL ' 1 FI 2 7% Sp Gr 1 22 Class ll CombjstiDle Liquid Incompatibilities and reactivities Measurement method (See Table 1) Water, atrong adds easily oxidized matertelsauohas ammonia salts & sulfides None available Strong oxidizers s rong caust CS Char CS IV li 00 3 Haloge nated HyC'O carbons] Strong oxidizers atrong alkalis. potassium hydroxide copper [Note Usually contains inhibitors to prevent pdymerization ] Char GCfclD, IV [*1003 Halogenatec Hydrocarbons] Strong oxidizers [Note Decomposes in presence of moisture 'O form hydrochloric acid i Char CS GC'iFiD IV [#1 004] Personal protection and sanitation {See Table 3) Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact Whencontam When wet or contam Daily Eyewash [1 3-Dichloro-5 5-dimethylhydantom] Skin Eyes Wash skm Remove Change Prevent skin contact Prevent eye contact Whencontam When wet {flamml NR ]1 1 Dichloroethane] Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam When wet (flamm) NR [1 2-Dichloroethylene] Skm Eyes Wash skm Remove Change Provide Prevent skin contact Prevent eye contact Whencontam When wet or contam NR Eyewash Quickdrench iDichloroeth/l ether' ABD00022823 Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table 4) NIOSH/OSHA 2 mg/m1 SA 5 mg/m1 SA.CF/SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFSHiE/SCBAE Route Symptoms {See Table 5} Irh Ing Con Irnteyes mucmemb resp sys Health hazards First aid {See Table 6) Target organs (See Table 5) Eye Skin Breath Swallow irnmmed Soap wash prompt Resp support Medical attention immed Eyes resp sys NIOSH/OSHA 1000 ppm SA 2500 ppm SA CF 3000 ppm SC BAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Inh Ing Con Irrit skin CNS depres liver kidney lung damage bye Skin Breath Swallow Irr immed Soap flush prompt Resp Support Medical attention immed Skin liver kidneys lungs CNS NIOSH/OSHA 1000 ppm SA CF/PAPROVE/CCRFOV/ GMFOV/SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Inh Ing Con Imt eyes, reap sys CNS depres I Breath Swallow Irr immed Soap wash prompt Resp support Medical attention immed Eyes resp sys CNS NlOSH * SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Inh Abs ing Con Imt nose throat resp sys lac cough nau vomit m animals pulm edema live' damage h arc] Eye Skin Breath Swallow irr immed Soap wash Resp support Medical attention immed Eyes tespsys 1 ver (in animals liver tumors] Chemical name structure/formula CAS and RTECSNos and DOT ID and guide Nos Synonym* trade names and conversion factors Dichloromanofluoromethane CHCI.F 75-43-4 PA6400000 Dichhxofluoromethane Fluorodichloromethane Freon 21 Genetron21 HaJont12, Refrigerant 21 1029 126 1 ppm = 4 21 mg/m' 594 72 9 Kl 050000 265C 53 1 3-Dichlofopropene CIHC=CHCH Cl * 542 75-6 UC8310000 pom = 6 89 mg m 3-Chk>faHy] chlonde DCP 1 3-Oichlofo-l-propene 1 3-Dichloropropylene Telone 2047 132 2 2 D cnloroprcj i inic CH CP COOH 75 99 0 JF069000Q 1760 164 1 ppm 4 54 mg/m* 2 2 Dichioropropanoicacid mi DicMoropropionicacid 1 ppm = 5 66 mg/m Exposure Iknte (TWA unless noted otherwise) NIOSH lOppm (40 mg/m1) OSHAf 1000 ppm (4200 mg/m*) NlOSH csha 2 ppm 11 mg,m OSHAf 0 '0 ppm 160 mg m , NIOSH Ca (5 mg/m') Iskinl See Appendix A OSHAf none NIOSH 1 ppm '6 mg/m') OSHAf none ABD00022824 IDLH Physical description Chemical and physical properties MW BP SOL FI P IP Sp Gr flammability VP FRZ UEL LL 5000 ppm Colorless gas with a slight ether like odor [Note A liquid below 48*F Shipped as a liquefied compressed gas] MW 102 9 BP 48*F Sol(86*F> 07% FIP NA IP 12 39 eV VP(70*F) 16 atm FR2.-211*F UEL NA LELNA RGesD 3 57 Nonflammable Gat 25 ppm Colorless liquiu wi'h a i unpleasant odor [funigart MW 43 9 BP 255 F Sol 2 3% n P 136 F IP 7 /P 15 mm FR2 7 JEl ' ufcL > Ca (ND) ND Sp Gr 1 43 Class ll Combustible Liquid Colorless to straw colored liquid with a sharp sweet irritating chloroform like odor (insecticide] [Note Exists as mutture of CIS A trans-isomers ( MW 111 0 BP 226*F Sol 0 2% RP 77*F IP ? VP 25 mm FR-119*F UEL 14 5% LEL63% SpGrl 21 Class 1C Flammable Liquid Colorless liquid with an send odor 'Note A white to tan powder below 46 F The sodium salt s white powde is often used 1 MW 143 0 BP 374 F Sol 50% F P NA IP 7 VP 7 FR2 46 F UEL NA uEl NA Sp Gf 1 40 Noncornbustible Liquid Incompatibilities and reactivities Measurement method (See Table 1) Chemically-actwe metals such as sodium potassium calcium powdered atumnun zinc A magnesium aad acid fumes Charf2), CS, GQFID, tv {#2516] Strong oxidizers [Note Corros ve o irpn in presence of moisture ] Chart pet i CS, GCfrlD IV i#1 601] Aluminum, magnesium halogens oxidizers {Note p*chlprohydnn may be added as a stabilizer ] None avaftabia Metals None [Note Very corrosive available toaiuminum&copper 3l1oys Reacts slowly n water to form hydrochloric & pyruvic acids , Personal protection and sanitation (See Table 3) Stun Eyes. Waahakkt Remove. Change. Provide Frostbite Frostbite NR NR NR Frostbite (Oi9hk>f|9inQnof|ijoron>ett)ane) . Skin Eyes Wash skin Remove Change Prevent skm contact Prevent eye contact When contam When wet or contam NR [1 1 Dcchk>ro-i nrtroethanel SWt' -: Prevent kn contact y*K , vPreventeyecontact Skm Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet or contam NR Eyewash Quick drench [2 2-Dichloropropionic acid] ABD00022825 Recommendations for respirator selection -- maximum concentration for use (MUC| (See Table 4) NIOSH 100 ppm SA 250 ppm SA CF 600 ppm SC8AF/SAF 5000 ppm SA PD.PP SCBAF PD.PP/SAF PD,PP ASCBA Escape GMFOV/SCBAE Route Symptoms (See Table 5) W> Con (iq) Asphy cardantiy card arrest, Kq frostbite ( Health hazards First aid (See Table 6) IS. Breath Frostbite Reap support Target organs (See Table 5) Respsys CVS - NIOSH 20 ppm SA 25 ppm SACF/SCBAF/SAF SCBAF PD PP/SAF PO PP ASCBA Escape GMFOV/SCBAE Hi in animals irrit eyes Ing skin liver heart kidney Con damage pulm edema hemorr Eye Skin Breath Swallow irr immed Soap wash immed Resp support Medical attention mmed Eyes skin respsys liver kidneys CVS TBAl Hi' ' Irrit eyes, afcjn, reap -Ab#/ sya,aya knbunw.tK; E) In Immed * Sfon. SoapUtah immed- Smith. Rasp support * Swallow, > Medteal-attantion- - s - immed , > .otgv " y VV Ey**,sion respsys, Cfctt, fterJudMY* fin animats cancw.efthr'ibMdar/lvw, * -fanpAfareatemachl Inh imt eyes skin upper mg respsys eye skm bums Con lass loss of appetite diarr vomit slowing of pulse CNS depres ICn Breath Swallow lm immed Water flush immed Resp support Medical attention immed Eyes skm resp sys Gl tract CNS Chemical name structure/formula CAS andRTECSNos and DOT ID and guide Nos Synonyms trade names and conversion factors Dichlorotetraf uO'O ethane CClF CCIF 76 14 2 KM101000 1 2 Dichlorotetra Freon 114 Genetron114 Halon 242 Refrigerant 114 102 1953 126 Di_ llorvos it. H O PiOiCX H='-H 62 J ' 7Cu36jn.J0 1 ppm - 6 99 mg/m3 DDVP v 2 Dichlorovmyl dimethyl phosphate Exposure limis iTWA unless noted otherwise) NIOSH/OSHA 1000 ppm (7000 mg/m3) NIOSH/OSHA 1 mg/m3 (Skin] 2781 152 Dicrotophos c.h,6n5p 141-66 2 TC3650000 1 ppm = 9 04 mg/m1 Bidrin Carbicron 2 Dimethyl cis 2 dimethyl- carbamoyl-1-methylvinylphosphate NIOSH 0 25 mg/m3 [skin] OSHAT none Dcvci jpen'aaiene CH '3 e pr nsoou" 2j45 29 1 ppm = 9 70 mg/m3 Bicyolopen'ad'ene DCPD ' 3 Dicyclopentadiene dimer 3a 4 7 7a Te ranydro-4 7 netnaroncene (Note Exists r two stereoison er c fo ms NIOSH 5 ppm 30 mg'm i OSHA* HOrte 1 ppm = 54'mgm ABD00022826 IDLH Physical description 15 000 ppm Colorless gas with a faint ether like odor at high concentra'ions [Note A liquid below 36 F Shipped as a liquefied compressed gas] Chemical and physical properties MW BP SOL FI P IP Sp Gr flammability VP FRZ UEL LEL MW 170 9 BP 38 "F Sol 0 01% FI P NA IP 12 20 eV VP(70*F) f 9 atm FRZ 137F UEL NA LEL NA RGasD 5 93 Nonflammable Gas Incompatibilities and reactivities Measurement method (See Table 1) Chemically active metals such as sodium potassium calcium powdered aluminum zmc& magnesium acids acid fumes Char(2) CH,C1, GC?Flb IV [#1018] 100 mg'mJ Colorless to amber liquid witfi a mild chemical odoi INote Insecticide that may be absorbed on a dry earner ] MW 221 0 BP Decomposes Sol 0 5% TIF' ->175 F IP 7 VP 0 01 mm 1 RZ 7 UFL 7 LLL 7 Sp Gh?7 Ft 1 42 Class III Combustible Liquid Strong acids strong alkalis [Note Corrosive to iron a mild steel j XAO 2 Toluene GC/FPD 11(5) [P&CAM #295' ND Yellow brown liquid MW 237 2 VP 0 0001 mm Metals OVS 2 with a mild ester odor [Insecticide] BP 752 F Sol Miscible FI P >200F IP ? FRZ 7 UEL 7 LEL 7 [Note Corrosive to cast iron mild steel brass & stainless steel J Toluene/ Acetone GC/FPD IV [#5600, Organo- phosphorus Sp Gr(59*F) 1 22 Pesticides] Class 1MB Combustible Liquid ND Colorless crystal Ime solid with a disagreeable camphor like oCoi 'Note A liquid above SO F ] MW 132 2 BP 342 P Sol 0 02% H Proc 90 F IP - VP 1 4 mm FRZ 90 F UFL 6 3% LEL u e% Sp Gr 0 99 'Liquid at 95 F Class 1C Flammable5 v/OUld Combustible So^d Oxidizers None (Note Depolymenzes available at boiling point and forms two molecules of cyclopentadiene Must be inhibited and maintained jnde an men atmosphere to orevent polymerization i Personal protection and sanitation (See Tcble 3) Skin Eye*. Wash skin Remove Change Provide Frostbite Frostbite NR NR NR Frostbite (Oichlorotetrafluoroe thane) Skir Eyes Wash S'in Remc.e Change present sk r con act prevent eye comae Ahen ccn am Vhe- wet 1 rontam NR ID Chlor.os) Skin Eve* Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet or contam Daily Quick drench [Dicrotophos] Skr P,es asr sc r Remove Change Ptcw de e e xx n .on a.t i- re.li e,e uorla^ .vhen i.Lrtam Vhe i wel or contain Ja 1, Eyewash Quickdrench (Dicyclooen tadiene ABD00022827 Recommendations for respirator selection -- maximum concentration for use (MUC( (See Table 41 NIOSH/OSHA 10 000 ppm SA 15 000 ppm SA CF/SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Route Symptoms (See Table 5) inh Imt resp sys asphy Con card arrhy card arrest (I'd) liq frostbite Health hazards First aid (See Table 6) Eye Skin Breath Frostbite Frostbite Resp support Target organs (See Table S) Reap sys CVS N IOSH'GSHaa 0 mg rn ' SA 25 mg m Srt CF mq m SA. CF,SCBAF SAF tOO SA PD PP SCBAF PD PP SAF PD PP ASCBA Escape GMFOVHiE SCBAE Irih ^bs Ccn i rit eyes skin icsis acheeyes rhnr head chest tight wheez lar spasm salv cyan anor rau vomit diart Sweat muse fasc para gidd ataxia convuis low BP ca d irreg Eye Skin Brea'h Swallow i r immed Soap wash i~med Resp support Medicai alien ion immed Resp sys CVS CNS eyes skm blood cho' TBAl wi Head nau dizz anxiety Abs resUeM muse twitch ing weak tremor Inco vomit Con abdom cramps dlarr salv sweat lac, rtumUe enor, mal $km Breath Swallow Irr immed Water wash immed Resp support Medicai attention CNS, blood Choi TBAl iv ng Con ir it eyes skin r use *hroat nco head sneez cough skin blisters in animals kidney 'ung damage Eye Breatn Swallow1 r immed Soap (lush immed Resp suppor* Medical arention immed Eyes skin resp sys CNS kidneys Chemical name structureTormula LAb and K 1 fcUb NoS and DOT ID and guide Nos Synonyms trade names and conversion factors D cyCiopen ao e-/i 1 or L H, Fe 102 54 o .K.700030 b s CyUope-itadie'V o i Per ocere 1 cn d cyulopen aJit n 104 Die c ir h2 J 5" 1 - '2 2~C Diese exhaust HfOD 2 3 4 iC - He>Jiv ,, o * e> c>f 1 4 4a ; >. ~ 3 id at (pr- ' 4 (.i _u u i _ 8 dime ha icrapt tt ale e Synonyms vary depend ng upo'- the speci'ic Jiesel exhaust component Exposure limits (TWA unless noted otherwise) NlOSH 1 3 mg m (0 al - mg " resp i 10 1 gmi ito al, 5 mg m resp 1 N..I te<. i t vf 11 ' mg m ir JO"1" ,,c m:n NlOSH Ca See Appendix A OSHA none ABD00022828 IDLH Physical description ND Ora ge "/stall ne sol J Ml J .am, a i Ke ode' Chemical ana physical -------- properties --------- ---- MW BP SOL FI P IP Sp Gr VP FR2 flammability UEL LEL MW 186 1 BP 480 iS-jl nsoluDe -'FT IP 6 86 eV VP ' M.T 33 P UBL ? .El 2 (50 i g i.'less c i ,i i ta -i sals i I a i'd h_ ica 0"C sec1 ;i je Sp Gr ? Combustio e Scud f , jf. i riF' _.e.u~[ jses ..1 iu 1 = Nx* IP ~ " f J> M. 1 'El r - N~ n F Ca [N D ] Sp >r 1 ^ 0 p ~b jst 11 . u 11 Appea ance and ocor Properties vary depending vary depending upon Lpor the specfic diesel he specific diesel exhaust con-porem exhaust component incompatibilities and reactivities Measurement method (See Table 1 j Amiro iium perchlorate te ran t omethane me'cur,(l<> n 'rate Fl e H SOvH.Oy her ICP OSHA ;ID'25G iron Oxide Fume) o -ng *\z ze *> 3v`i e l ais Sucn ab v.J .i ' s'r j g a. lS e i.ls *r 1 5" v d H 'j 2 L ( 1 (s S * - 3 Vanes Filter none EGA/TOA IV 1#5Q43 Elemental Carbon] i>eu d iu. ar r h NK ` -h2 2 r Dt< i v n,onjxe(". amine 2 v D nydrox^jie rr a- ne D oiai'iine pis l H,c ox/et", am ne .2 m-.diehnn 1 NICS-i > Pfn * i g m i OoHx^t -re P P-n ' - >C mg m N L' - > is$ crys Hib Of 3 5, n l y icj-id 3oovt* 82 F *ilh a m IJ an rro 3 Iik uccr M i, ' jE BP oft f i Deco- poslsi Sol 'a5 F1P 2'u F P' p .l m Ml r 52 - jll v a LEL '> Si vi 1 iC ass MiB ,,cr oust'Cie up. 1Lumen s* 'j l >c j 5t rd 2C JS It, J <i f fC wb il -.CS N tt Reac b w > SC M r C j r [ fj suo Jr e acsjrbs * fsr. c `^fTi t *> d f L.f v$i C 'J - pper zm- i H it J m; Ft.age ) 1 1 ,o J- x- I . v rmu ..mpu M 1s Personal protection and sanitation (See Table 3) Skin Eyes Wash skin Remove Change NR NR NR NR Daily [Dicyclopentadienyl iron] Skir F/es Wash skiRemove Change Pree-it sk r comae Pre en eve con act '.he- contam Dai1, vVher wet o uonta i Dai, E,ewash Qj ck d ench ,DeOr j Skin Eyes Wash skin Remove Change NR NR NR NR NR [Diesel exhaust] Skin Lyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet or contam Daily Eyewash Quick dtench iDiethanoiammej ABD00022829 Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table 4) TBAL Route Symptoms (See Table 5) inh Ing Con Possible irnt eyes skin resp SyS mammals liver RBC testicular changes Health hazards First aid (See Table 5) Eye Skin Breath Swallow Irrimmed Soap wash Resp support Medical attention immed Target organs (See Table 5) Eyes skin resp sys liver blood repro sys NlOSH SCBAF PC PP SF PC PP nSCBA Fscape GMFCvHiE SCBE inn -vbs Ing Cor Head dizz r do vomit -ndl sweat myoc omc irTiL jefks ClO nc tonic cor vuls coma cd ] m ani nais l .e * One Garage Eye Sk n Breatn Swallow lrr immed Soao wash im-ned Resp support Medicai attention '""led CNS liver kidneys skin tm animals l jng iver thyroid & adtei al gland Ijmc s) NlOSH SCBAF PD PPfSAF PD PP ASCBA Escape GMFOVHiE/SCBAE Inh Eye imt pulm tunc Con changes [care] Breath Resp support Eyes resp sys [m animals lung tumors] TBAL Inh Ing Con Irnt eyes skin nose throat eye burns corn nee skin burns lac cough srteez Eye Skin Breath Swallow lrr immed Water flush immed Resp support Medical attention immed Eyes skin resp sys Chemical name structure/formula CAS and RTECSNos and DOT ID and guide Nos Synonyms trade names * factors Diethylamine 109-66-7 HZ8750000 Diethamme N N-Diethylamtne N-Ettiytethanamine 106 1154132 2 Diethylammoethanol (C^H^jNCHjCHjOH 100 37 6 KK5075000 1 ppm 2 99 mg/m5 Diethylammoethanol 2 Diethylaminoethyl alcohol N N Diethylethanolarmne Diethyl (2-hydroxyethyl) amine 2 Hydroxytnethylamine 2686 132 Oiefliylenstnamtne (NHjCHjCH,)jNH 111-40-0 IE1225000 1 ppm = 4 79 mg/m1 N-(2-Amlnoethyl)1 2ethanediafnine bis(2-Aminoethyl famine DETA, 2 2 -Diammodiethyiamine 2079 154 D'ethy. Ketone CHjCH COCH CM, 96 22 0 SA8050000 1 ppm 4 22 mg/m} DEK. Dimethylacetone Ethyl Ketone Metacetone 3 Pentanone Propione 1156 '27 1 ppm = 3 53 mgtm1 Exposure limits (TWA unless noted otherwise) NIOSH 10 ppm (30 mo/m3) ST 25 ppm (75 mg/m3) OSHAt 25 ppm (75 mg/m5) NIOSH/OSHA 10 ppm (50 mg/m') (shin) NIOSH Ippm (4 mg/m3) [skin] OSHAt none NIOSH 200 ppm 705 mg/m'i OSHAT none ABD00022830 IDLH Physical description 200 ppm Colorless liquid with a fishy ammoma-liKe odor Chemical and physical properties MW BP SOL FI P, IP Sp Gr flammability VP FRZ UEL LEL MW-731 BP 132*F Sol Miscible FI P 15"F IP 8 01 eV VP 192 mm FRZ -58*F UEL101% LEL 18% 100 ppm Colorless liquid with a nauseating ammonia like odor Sp Gr0 71 Class IB Flammable Liquid MW 1172 BP 325`F Sol Miscible FI P 126 F IP > VP 1 mm FRZ 94 F UEL 7 LEL > Sp Gr 0 89 Ciass II Combustible Liquid ND Colorless to yellow MW 103 2 VP 0 4 mm liquid with a BP 405'F strong ammonia-iike Sol Miscible odor FIP 208`F FRZ. -38*F UEL 6 7% LEL 2% (Note Hygroscopic IP ' (l e absorbs moisture from the air) J SpGr 0 96 Class IIIB Combustible Liquid ND Coioriess liquid MW 86 2 VP 77 F with an acetone like BP 2.5 F 35 mm ooor Sol 5% FRZ -44 F FI P(ocj 55 F UEL 6 4=o IP 9 32 eV LEL 1 6% Sp Gr 0 81 Class IB Flammable Liquid Incompatibilities and reactiv itios Measurement method (See Table 1) Strong oxidizers strong acids cellulose nitrate Si gel Methanol GC/FIO IV (#2010) Strong oxidizers strong acids Si gel Methanol/ Water GC/FID IV (F2 007 Ammo ethanol pounds I) Oxidizers strong XAD-2' acids cellulose DMF nitrate HPLC/UVD [Note May form IV explosive complexes (#2540] with silver cobalt, or chromium compounds Corrosive to aluminum copper brass & arte ] Strong oxicizers alkalis mineral acids ihydrogen peroxide * nitric acid' None available Personal protection and sanitation (See Table 3) Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet (fiamm) NR Eyewash (>0 5%) Quick drench (liq) [Dlethylamine] Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet or contam NR Eyewash i >5%/ Quickdrench (2 Diethyiaminoe'hanol] Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet or contam NR Eyewash Quickdrench [Diethylenetfiamine] Skir Eyes Wash SKir Remove Cnange NR Preve^ e^econtac1 Daii, Ahen wet flam1'NR (Diethyl ketone} ABD00022831 Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table 4) NIOSH 200 ppm SACF'VPAPRS'VCCRFS/ GMFS/SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFS/SCBAE Route Symptoms (See Table 5) Inh Abs Ing Con Irnt eyes skin resp sys m animals myocardial degeneration Health hazards First aid (See Table 6) Target organs (See Table 5) Eye Skin Breath Swallow Irr immed Water flush immed Resp support Medical attention immed Eyes skin resp sys CVS NIOSH/OSHA 100 ppm CCROV /GMFOV/PAPROV / SA /SCBAF SCBAF PD PP/SAI POPPASCBA Escape GMFOV/SCBAF Inh Abs log Con Irrit eyes skin resp sys nau vomit Eye Skin Breath Swallow Irr immed Water flush immed Resp support Medical attention immed Eyes skin resp sys 107 TBAL Inh Abs Ing Con Imteyes skin mucmemb upper resp sys derm skin sens eye skmnec cough dysp pulm sens IC Breath Swallow Irr immed Water flush immed Resp support Medical attention immed Eyes skin resp sys TBAL Inh Ing Co- nt eyes skip nucrrieTD respsys cojg^ sneez Eye Skir Breath Swallow r immed Soap wash ResD Support Medical attention immeO Eyes $k n resp Sys Chemical name structu re/formula CAS and RTECS Nos and DOT ID and guide Nos Synonyms trade names and conversion factors Diethyl phthalate CjH^COOCjHjJj 84-66-2 Tl 1050000 DGP Diethyl ester of phthalic acid, Ethyl phthalate ^108 Difluorodibromomethane CBr F Dibromodifluoromethane Freon 12B2 Halon 1202 75-61-6 PA7525000 1941 159 Olgtyddyt ether 2238-07-5 KN2350000 ' ppm = 8 58 mg/m3 DGE Dialtyt ether dioxide D)(2,3-epoxypropyl) ether; b^3^ypropyl) ether Dilsobutyl ketone [(CH^CHCHjjCO 106 83 8 MJ5775000 1ppmBS.33mg/m, DIBK sym-Dllsopropyl acetone 2 6-Dimethyl-4 heptanone Isovalerone Valerone 1157 127 1 ppm = 5 82 mg/m3 Exposure Hmfts (TWA unless noted otherwise) NIOSH 5 mg/m5 OSHAf none NIOSH/OSHA 100 ppm (860 mg/m3) NIOSH Ca See Appendix A 0 1 ppm (0 5 mg/mJ) OSHAt COSppm (2 8 mg/m*) NIOSH 25 ppm 1,150 mg/mh OSHAT 50 ppm (290 mg/m1) ABD00022832 IDLH Physical descnption ND Colorless to waterwhite oily liquid with a very slight aromatic odor [pesticide] Chemical and physical properties MW BP SOL FIP, IP Sp Gr, flammability VP FRZ UEL LEL MW 222 3 BP 563`F Soi(775F) 0.1% FIP(oc) 322`F IP ? VP(77'F) 0 002 mm FRZ -41T UEL ? LEL(368*F) 0 7% incompatibilities and reactivities Measurement method (See Table 1) Strong oxidizers strong acids nltnc acid permanganates water OVS-TenaxToluene GC/FID OSHA (#104] 2000 ppm Colorless heavy liquid or gas (above 76 F) with a characteristic odor Ca [10 ppm] Cotodeea liquid wtth a strong tmtating odor SpGrt 12 Class IIIB Combustible Liquid however ignition Is difficult MW 209 8 BP 76 F Sol Insoluble FI P NA ip ii 07 eV VP 620 mm F RZ 231 F UEl NA LEL NA Sp Gr(59 F) 2 29 Noncombustible Liquid Nonflammable Gas MW 1302 BP 500*F Sol ? FIP-147'F IP ? VP(77'F) 0 09 mm FRZ 7 UEL ? LEL 7 Chemically active metals such as sodium potassium calcium powdered aluminum zinc& magnesium Strong oxidizers Char(2) 2 Propanol GC/FID IV [#1012) None available 500 ppm Colorless liquid with a mild sweet odor SpGri 12 Class IDA Combustible Liquid MW '42 3 BP 334 F Sol 0 05% FI P 120 F IP 9 04 eV VP 2 mm FRZ -43 F UELi200 Fi 71% LEl,200 F. 0 0% Sp Gr 0 81 Class H Combustible Liquid Strong oxidizers Char CS GC)FID IV [#1300 Ketones I] Personal protection and sanitation (See Table 3) Skin wShsion RemoveChange zzzzz [Diethyl phthakate] Skin E)s Wash skin Remove Change Prevent skin contact Prevent eye contact NR When wet or contam NR [Difluorodibromomethane] SHn. Vetkin. Remove ChangeProvide Prevent aWn contact Prevent eye contact When cordam/Dady When wet or contam Daily Eyewash, Outekdrencfc PWyadyl ether) Skin Eyes Wash skin Remove Change Prevent skin contact NR When contam When wet or contam NR (Ditsobutyl ketone] ABD00022833 Recommendations for respirator concentration for use (MUC) (See Table 4) TBAL Route Symptoms (See Table 5) Inh Imteyes skin note, J"9 throat, head, dizz, nau, Con lac, possible polyneur vesttbvlaf dysfunc, pain, numb weak, spasms In arms & lags, m animals, repro effects Hearth hazards First aid (See Table 6) Breath Swallow Irr Immed Wash regularly Resp support Medical attention Immed Target organs (See Table 5) Eyes skin resp sys, CNS, PNS repro sys ' NIOSHIOSHA 1000 ppm SA 2000 ppm SA CF/SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Wi Ing Con In animals nnt resp sys CNS symptoms liver carnage Fye Skin Breath Swallow Irr immed Water flush immed Resp support Medical attention immed Resp sys CNS liver 109 NiOSH SCBAF PD PP/SAF PD.PPASCBA Escape GMFOV/SCBAE Inh In* eye#, *km, resp sys. Abe - skin bums, Q?on m awnais. hemato sys lung. 6var, kidney damage, repro effects; [carcf. , r - '/C NIOSH 500 ppm SA CF'/PAPROVVCCRFOW GMFOV/SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE 6* hh Ing Con - *<. '' Imteyes skin nose throat head dizz derm liver kidney damage Iff, Breath Swallow- Irr immed Soap wash immed Resp support Medical attention Immed Eyes, skin, respsys repro sys fin animals skm tumors] Eye Skin Breath Swallow i Irr immed Soap wash prompt Resp support Medical attention immed Eyes skin resp sys CNS liver kidneys Chemical name structure/Yonnula CAS and RTECSNos and DOT ID and guide Nos Synonyms (rade names and conversion factors DUsopropylamine [(CH,)2CH)3NH 106-18-9 JM4025000 DIPA, N (1-Methylethyl)-2- propanamme Exposure limits (TWA unless noted otherwise) _ ABD00022834 IDLH Physical description NIOSH/OSHA 5 ppm (20 mj/m1) [skin] 200 ppm Colorless liquid with an ammonia or fish like odor Chemical and physical properties MW BP SOL FI P IP Sp Gr flammabllfty VP FRZ UEL LEL MW 101 2 BP 183*F Sol Mls&ble FI P 20`F IP 7 73eV VP 70 mm FRZ 141*F UEL 71% LL11% Incompatibilities and reactivities Measurement method (See Table 11 Strong oxidizers strong acids Imp KOH GC/FID 11(4) [#S141] 110 1156132 Dimethyl acetamide CH3CON,CHj 12' *9-5 AB7700030 Dlmethylaniine (CHjJjNH 124-40-3 IP8750000 1032 11B (anhydrous) 1160 120 (solution) 4 Dimethylam no azoberzene C.H.NNCjH/viCHji 60-11 7 0X7350000 1 ppm*4 14mftfmJ N i< Dimethyl acetamide DMAC N'OSH/CSHA 1 3 ppm 135 mg/mJ (skin1 33C ppm -olcrless liquid w th a weak ammon a or fish like oJcr Sp Gr 0 72 Claes IB Flammable Liquid MW 87 BP 32S F Sol Miscibie ci P oci 158 P iP 8 61 eV .P 2 m -- FR7 -4 F O ELi J2C F i 1 5`o LEI_|212 F ' Sc Carbon 'etrachiorice other naiogenated compounds when in contact wth ror .xidizers Si gel Me'hanci gC F,D #2304] 1 ppm = 3 56 mg,m5 DtmeOrylamme (anhydrous) N-Methylmethanamwe 1 ppm*1 85 mg/m3 Butler yellow DAB p-Dimethyiaminoazo benzene N N Dimethyl-4 ammoazo benzene Methvi yeliow NIOSH/OSHA lOppm (18 mg/m}) 500 ppm NIOSH Ca See Appendix A OSHA[1910 1315 See Appendix 0 Ca [N D Colorless gas with an ammonia-or fish like odor {Note A liquid below 44*F Shipped as a liquefied compressed gas) Yellow leaf shaped crystals Sp Gr C 94 Class IMA Combust bie Liqu c MW 45 1 BP 44'F Sol(140 F) 24% FI P NA (Gas) 20'F <uq) VP 1 7 atm FRZ 134*F UEL144% LEL 2 8% Strong oxidizers chlonne mercury acraldohydo fluorides maleic enhydnde aluminum brass copper zinc IP 9 24 eV RGasD 1 56 Sp Gr 0 67 (Liquid at 44 F) Flammable GaaiClaas IA Flammable Liquid MW 225 3 9P Sublimes Soi 3 C01 * RP 7 IP 7 JP 3 0000003 Tim ies MLT 23' F UEL 7 -EL 7 Noie epcrted sp jr Si gel Hnot GC/FID IV [#2010] G cnrom P 2 Prcpanoi II 4 i [P&CAM #2841 Personal protection and sanitation (See Table 3) Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact (>5%) When contam When wet (flamm) NR Eyewash (>5%) (Dtisopropylemine] Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet or contam NR Quickdrench ABD00Q22835 Recommendations for respirator concentration for use (MUC) (See Table 4) Route Symptoms (See Tables) NIOSH/OSHA Ing 125 ppm SA CF^APROV1 Abs 200 ppm CCRFOV/GMFOV/PAPRTOVV Ing SCBAF/SAF Con SCBAF PD,PP/SAF PD,PP ASCBA Escape GMFOV/SCBAE Imteyas skin respsyt nau, vomit head, vis dist Hearth hazards First aid (See Table 6) Target organs (See Table 5) Breath Swallow Irnmmed Watarwash immed Reap .support Medical attention knmed ,, ,, X Eyes, skin, reap ays , NIOSH/OSHA 100 ppm SA 250 ppm SA CF 300 pom SCBAF/SAF SCBAF PD PP'SAF PD PP ASCBA Escape GMFOV/SCBAE Inh Abs Ing Con Imt skin jaun liver damage depres leth nalu delusions Skin Breath Swallow in immed Water flush immed Resp support Medical attention mmed Skin liver CNS [Dimethyl acetamoei Skin Prevent skin contact (liqy Frostbite Eyes Prevent eye contact (liqy Frostbite Wash skin When contam (lia) Remove. When wet (flamm) Change NR Provide Eyewash fllq) Quick drench (liqV Frostbite [Dlmethylamme] Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam/Daily When wet or contam Daily Eyewash Quickdrench [4 Dimethy'lammoazobenzene] NIOSH/OSHA 250 ppm SACFC 600 ppm SCBAF/SAF S SCBAF PD PP/SAFPO.PP ASCBA Escape GMFS/SCBAE f 4. -' " NIOSH W SCBAF PD PP/SAF PD PP ASCBA Escape HiEF/SCBAE trti Imtnoae throat; rtr burned (8aV Eyes, skin, reap tys Con sneez, cough, dysp, Frostbite (IKj) pulmedema,con), derm, , Stan: Water flush burned fiq froatbtte 1 TllqJ/Frosiblte .' .Breath*," - Reap"support V *' ^ - w ^' < , ' - / t, J * **** 1- \ V< * >- * ` * / v- , " 1 , * ' ' 1 > tl /r ' Inh ADS Ing Con Enlarged liver liver kidney dysfunc contact derm cough wheez dysp bloody sputum bronchial secretions frequent urination hems dysuna (care) Skin Breath Swallow Irr immed Soap wash immed Resp support Medical attention mmed Skin respsys liver kidneys bladder (in animals liver & bladder tumors] Chemical name structure-formula CAS and RTECSNos and OOT ID and guide Nos Synonyms trade names and conversion factors Exposure limits (TWA unless noted otherwise) ABD00022836 IDLH Physical description Dis(2 (Dimethyiamino) ethyl)ether 3033 62 3 KR94600QQ MAX A99 NIOSH/OSHA MAX Catalyst A1 See Appendix C 2 2-Oxybia(N N dimethyl (Max Catalyst ethylaminel ESN) RCHjJjNCHjCHjOCHjCH^ICHjJj] Note A component (5%) of NIAX Catalyst ESN along with dimethylammopropio- mtnle (95%i) ND Liquid Chemical and physical properties MW BP SOL PI P IP Sp Gr flamma&ifity VP FRZ UEL LEL MW 160 3 BP 372 F Sol 7 VP ? FRZ ? UEL 7 LEL 7 IP 7 112 Dimethyiamino propionilrile iCH,j NCH Ch cn 1738 25 6 UG1575000 N N-Dimethyiamline CsHsN(CN,)j 121-69-7 BX4725000 2253 153 U<meT^yl cartamo^i c'nonoe i,,H i NCCC 79 44 7 K;42O3CC0 225c - 56 3 (Dimethyiamino) propiomtrile N N Dimethyiamino 3 propiomtrile [Note A component (95%) of NIAX Catalyst ESN along with bis(2 (dimethyiamino) ethyl) ether (5%)) NIOSH/OSHA See Appendix C (Niax Catalyst ESN) ND Colorless liquid N N-Oimethyibenzeneamine N N-DImethylphenylamine [Note Also known as Dimethylamline which is a correct synonym for Xylidine ] 1 ppm = 4 96 mg/m3 Chloroformic acid dimethylamide Dimethyicarbamic chloride N N Dimethylcarbamoyl chloride DMCC NIOSH 5 ppm (25 ma/m3) ST 10 ppm (50 mg/m3) [skin] OSHAf 5 ppm (25 mg/m3) [skin] NiOSH Ca See Appendix A OSHA r>one 100 ppm Ca (NO] Pale-yellow oily liquid with an amlne-like odor [Ndte A solid below 36'F ] Clear colorless 1 quid MW 98 2 BP 342 F Sol Miscible f 1 P 147 F IP 7 VP. 135 F 10 mm FR7 48 F UEL 7 LEL 7 Sp Gr(66 fi 0 86 Class IIIA Combustible Liquid MW 121 2 BP 378T Sol 2% FI P 142*F IP 7 14eV VP 1mm FRZ 36F UEL 7 LEL 7 ijf u yo Class IIIA Combustible Liquid MW 1076 BP 329 r Sol Reacts FI P 155 F IP 7 VP 7 FRZ 27 F UEL 7 LEL " Sp Gr 1 I7 Class MIA Comquslible Liquid Incompatibilities and reactivities Measurement method (See Table 1) None reported None available Oxidizers [Note Emits toxic oxides of nitrogen and cyanide fumes when heated to decomposition ] None available Strong oxidizers strong acids benzoyl peroxide SI gel. Ethanol GC/FID IV (#2002 Aromatic Amines] Acids water [Note Rapidly hydrolyzes in water to dimethylamme carbon dioxide and hydrogen chloride 1 None available Personal protection and sanitation (See Table 3) Skjn Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact Whencontam When wet or contam NR Eyewash Quick drench [bi(2 (Dimethylemmo)ethyt>ether} Sk, i t-yes /.'ash skiRemo e tange Pro oe Prevent skin contact P e.en eye contact \ner :cn aTM /hen wet ; co'1 a"N< Eyewash ^ruiuk jrer c r [Dimelhy aiTinop op omt le Skin Eyes Wash skin Remove. Change Provide Prevent skin contact Prevent eye contact Whencontam When wet or contam NR Quickdrench [N N-Oimethytaniline] Shir Eyes Wash skn Remo.e Change Pro ide Pre ent ski l contact P e en* eye contact When .ontarr Ahe" wot oi contam NR Eyewas1 Ujckdench iDime'hyl carbarno,! chlo ice] ABD00022837 Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table 4) Route Symptoms (See Table 5) NIOSH SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Inh Possible unnary dysfunc Abs neurological disorders Ing in animals imteyes skin Con Health hazards first aid (See Table E| Target organs (See Table 5) Breath Swallow Irrimmed Water flush immed Rasp support Medical attention immed Eyes skm unnary tract PNS NIOSH SCSef PD PP S'- - PD pSCBm Escape 3MFQV SCBaE mr Abs Ing -on lr it eyes skin jnnary dysfunc reui'o ogical cisoroers p ns & need es i i nands&feet muse weak lass nau vom t cec _erve ,,nduct on m owe legs Eye Sk n Breath Swallow Irr immed Water Push mmed Resp support Medicai attention immed Eyes skin jrmary tract PNS 113 NIOSH/OSHA 50 ppm SA 100 ppm SA-CF/SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Inh Abs Ing Con Anoxia symptoms cyan weak dizz, ataxia methemo IC Breath Swallow Irrimmed Soap wash immed Resp support Medical attention immed Blood kidneys liver CVS NIOSH SCB(- PO PP SAF PD PP ASCBA Escape GMFOV/SCBAE Inh Abs ing Cor i rit eyes skm rose throat resp s/s eye skm burns coogn wheez laryngitis dysp head nau vomit 1 ver m (care Eye Skm Breath Swallow Irr immed Water flush ir-meO Resp support Meoicai attention immed Eyes skm resp Sys liver (in animals nasa> cancer, Chemical name, etructu re/formula CAS and RTECSNoa and DOT ID and guide Noe Synonym* trade name* and conversion factor* Dimethyl-1,2-dibromo- Dibrom; 2 2-dichlcrethyt 1 2-Dlbromo-2 2-dichioro- phosphate ethyl dimethyl phosphate, Naled (CH^O)jP(0)OCHBrCBfClj 300-79-6 T89450000 114 Dimethyttormamide HCON(CHjJ3 68122 LQ2100000 Dimethyl formemide N N Dimethytformamide DMF 2265 129 11-Dimeth^hydnuto (CH^NNH, 57-14-7 MV2450000 1 ppm * 2 99 mg/m3 Oimajine. DMH UDMH, Uneymmetncal dimethyl- hydrazine 1183131 Dimethyiphthaiate C8H,(COOCHy3 131 11-3 T'1575000 1 ppm 2 48 mg/m5 Dimethyl ester of 1 2 bonzenedicarboxylic acid DMP 9168 171 Exposure tkrats (TWA unless noted otherwise) NJOSH 3 mg/m5 [skin] OSHAf 3 mg/m1 NlOSH/OSHA 10 ppm (30 mg/m3) [skin] NOSH Ce See topendlx A C 006 ppm (015 mg/m5) OSrtl 0 5 ppm p m^m5) NlOSH/OSHA 5 mg/m3 ABD00022838 IDLH Physical description 200 mg/m3 Colorless to white solid or straw- colored liquid (above 80*F) with a slightly pungent odor [insecticide} 500 ppm Coiortess to pale yellow liquid with a (amt amme Irke odor Ca (IS ppm] Cotodass liquid wtthan ammorua- or fleh-Wte odor 2000 mg/m3 Colorless oily liquid with a slight aromatic odor [Note A solid Delow 42 F ] Chemical and physical properties MW BP SOL FI P IP Sp Gr flammability VP FR2 UEl LEL MW 380 9 BP Decomposes Sol Insoluble FIP NA IP 7 VP 0 0002 mm MIT 80*F uet NA LEL NA SpGr(77*F) 1 08 Noncombu*M4* :Solid Incompatibilities and reactivities Strong oxidizers acids sunlight water [Note Corrosive to metals Hydrolyzed in presence of water ] Measurement method {See Table 1) None available MW 73 1 BP 30' F Sol Miscible F P 136 F IP 9 12 e. VP 3 m-r FRZ 70 F LEL 152' = LEL,2.2 F 2 2% Carbon etrachlonde other ha,ogenated compounds when in con act with i on s rur y ,,*idizers alkylaluminums inorganic nitrates Si gel Metnano GCfcID IV #2004] Sp Gr 0 95 Class ii Comoustibie Liquid MW 60 1 BP- 147*F Sol Miscible FI P 5`F IP 6 05 aV VP 103mm FRZ -72*F UEL 95% LEL 2% So Gr 0 79 Class IB Flammable Liquid Oxidizers halogens, metallic mercury fummg nitnc acid hydrogen peroxide [Note May Ignite SPONTANEOUSLY in contact with oxidizers ] Bub Pho-acld Vis IV [#3515] MW 194 2 BP 543 F Sol 0 4% F P 295 F IP 9 64 eV VP 0 01 mm FRZ 42 F UEL 7 LEL358 Fi 0 9% Ni'rates strong oxidizers aixaiis & acids OVS Tenax Toluene GC/FlD OShA (#104) Sp Gr 1 19 Class NIB Combustible Liquid however ignition is difficult Personal protection and sanitation (SeeT*bl*3) ABD00022839 Recommendations for respirator selection -- maximum concentration tor use (I/IUC) (See Table 4) Route Symptoms (See Table 6) Skin vJashakln. Remove Change Provide Prevent skin contact Prevent eye contact Whancontam When wet or contarn Daily Eyewash NIOSH/OSHA 30 mg/m1 DMFu/HiE/SA 75mg/m SA CF/PAPRDMFu ISOmgftn5, HIEF/SAT CF/PAPRTHiE/ SCBAF/SAF 200 mg/m* SA.PD PP 8 SCBAF PD.PP/SAF PD PP ASCBA Escape HiEF/SCBAE [Dimethyt-1,2-dibrom-2 2-dlchloroethyl phosphate] Mr in* eyes, skm, miosis, Abs lac, head, chest Ught. Ing wheaz, larspasm, aatv, Con cyan anor.nau, vomit, sodom cramp, diarr week, twitch, para okfd ataxia, convuls, low BP, card irneg Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact Whancontam When wet or contam NR NIOSH 100 ppm SA 250 ppm SA CF 500 ppm SAT CF'/SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SC8AE Inh Imt eyes skin resp sys ADS nau vomit colic liver Ing damage enlarged liver Con high BP face flush derm mammals kidney heert damage Health hazards First aid (See Table 6) 1 Breath Swallow Irrimmad Soaprash immad RMaesca ks^uDatoteonrttion nmad Target organs (See Table 6) Breath Swallow ' Immmed Water flush prompt Resp support Medical attention mmed Eyes skin resp sys Irver kidneys CVS [Dimethytformarmde] Skin. Eyes. Wsshskin Remove: Change: Provide Prevem skin contact Prevem eye contact Whencontain When wet (ftamm) NR Eyewash, Quk* drench {1.1-Olmethythydrazine) Skin Eyes Wash skin Remove Change NR Prevent eye contact NR NR NR (Dimethyiphthaiate] NIOSH V SCBAF PD PP/SAF PD.PPA8CBA Escape GMF6/SCBAE , Hi Aba " CSo'*n chest pain. dytp. lath. nau.enoxla.'cohWteIMt , *** " v f Ifc, ,, ' krttmed ' " CNS,JNec,01 -.WtaiarltuihlnWiad , tract, Mood, ''Breath: 7 sys. eyes, Swellgw /<kn c i 9; (jmentmels; 1 A, ' - 1 tumors of the \ ** *T 1 - '-kings,ivsr. , btoob vessels & v*" %V Intestines] NIOSH/OSHA 50 mg/m3 DMF 125 mg/m3- SA CFVPAPRDM' 250 mg/m1 HiEF/SCBAF/SAF 2000 mg/m1 SAF PD PP 6 SCBAF PD PP/SAF PD PP ASCBA Escape HiEF/SCBAE Hi Imt eyes upper resp sys Ing stomach pain Con Eye Skm Breath Swallow Irr prompt Wash regularly Resp support Medical attention nmed Eyas resp sys Gl tract 115 Personal protection and sanitation (See Table 3) Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet or contam NR Eyewash Quick drench [Dimethyl sulfate] Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam When wet or contam Daily (Dmitolmidel Stan Eyes Wash skm Remove Chengs Provide Prevent skin contact Prevent eye contact Wien contam Wien wet or contam Deity Quick drench [o-Oimtrobenzene] Skm Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet or contam Daily Quick drench [m Dinitrobenzene] ARDQQQ2284Q Recommendations (or resptrMor selection - maximum concentration (or use (MUC) (See Table 4) Rome Symptoms (See Table 5) NIOSH SCBAF PD PP/SAF PD PP ASCBA Escape GMFS/SCBAF nh Abs Ing Lon irnt eyes hose head gidd con) photo penorb edema dysphoma aphonia dysphagia productive cough chest pain dysp cyan vomit diarr dysuna analgesia fever album hema eye Bkmbums delirium [care] T BAL Inri ing Con Contact eczema mammals methemo liver changes Health hazards Firstald (See Table S) Target organs (See Table 5) Eye Skin Breath Swallow Im immed Water flush immed Resp support Medical attention mmed Eyes skin reapsys liver kidneys CNS [In animals nasal & lung cancer) Eye Skin Breath Swallow Irr immed Soap wash immed Resp support Medical attention immed Skin liver blood 117 NIOSH/OSHA 5 mg/m3 DM 10 mg/m3 OMXSQ/HiE/SA 25 mg/m3 SA CF/PAPRDM 50 mg/m3- HiEF/SAT CF/PAPRTHIE/ SCBAF/SAF | SCBAF PD PP/SAF PD PP ASCBA Escape HiEF/SCBAE Wl Anoxia cyan vw diet Abs central scotomas bed taste bummg mouth dry Con throat thirst yetowng hair ayee,skm,anema, trver damage NIOSH/OSHA 5 mg/m3 DM 10 mg/m3 DMXSQ/HiE/SA 25 mg/m3 SA CF/PAPROM 50 mg/m5 HiEF/SAT CF/PAPRTHiE/ SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape HiEF/SCBAE Inn Abs Ing Con Anoxia cyan vis dist central scotomas bad taste burning mouth dry throat thirst yellowing hair eyes skm anemia liver damage 1ft Breath SwaMow Soap wash mmed Reap support Medical attention nmed Eyes skin Mood liver CVS CNS Skin Breath Swallow Resp support Medical attention Eyes skin blood liver CVS CNS Chemical name tructure/formula CAS and RTECSNoa, and DOT ID and guide Nos Synonyms trade names, and conversion factors Dimethyl sulfate (CH^O, 77-78-1 WS8225M0 Dimethyl ester of sulfuric aod Dimethytsutfate, Methyl sulfate 116 1896 166 1ppm*5.16mgte* Dimtolmide (NOj)jCaHj(CHj)cNHj 145-01-6 XS4200000 3 5-Oimtro-o-toluamide 2-Methyl-3 5-dmitro benzamide Zoalene <W*A 528-29-0 CZ7480QO0 1597182 m Dinrtrobenzene C*h4(NO,), 99-65-0 CZ7350000 1597152 ortho-Dimtrobenzene, 1,2-Duvtrobenzane > meta-Dinitrobenzene 1 3-Dinitrobenzene Exposure knM* (TWA unless noted otherwise) ABD00022841 OLH Physical description NIOSH Ca See Appendix A 0 1 ppm (0 [skin] i2r) Ca [7 ppm] aColorless oily liquid with faint, on/on-fike NIOSH 5 mg/m* OSHAT none N D Yellowish crystalline solid Chemical and physical properties MW, BP, SOL FI P IP Sp Gr, flammability VP, FRZ UEL, LEL MW 126 1 BP- 370*F (Decomposes) sotem 3% FIP 182`F IP? VP 01mm ?FRZ. -25*F UEL LEL ? SpGrl 33 Cleas IIIA Combustible Liquid MW 225 2 BP 2 Sol Slight FIP NA IP -> VP ? MLT 351 F UEL NA LEL NA NIOSH/OSHA Img/m* [skin] NIOSH/OSHA 1 mg/m* (skin] SO mg/m* PMe white or yeUow crystalline solid / 50 mg/m* <- Pale white or yellow crystalline soi>d Sp Gr 7 Noncombustible Solid MW 1681 BP 806T Sol 0 05% FIP 302*F IP 10.71 eV VP 7 MLT 244*F UEL? LEL? Sp-Grl 57 Combustible Solid MW 168 1 BP 572`F Sol 0 02% FIP 302*F IP 10 43 eV VP 7 MLT 192 F UEL 7 LEL ' So Gr 1 58 Combustible Solid Incompatibilities and reactivities Measurement method (See Table 1) Strong oxidizers, ammonia solutions (Nots Decomposes in aodwater to sulfuric corrosive to metals] Porapak-P Diethyl ether; GC/EConD IV (#2524} None reported Filter none Grav [40500 Particulates NOR (total)] Strong oxidizers, caustics metals such as tin & zinc (Note Prolonged exposure to Are and heat may result in an explosion due to SPONTANEOUS decomposition ] Filter/Bub, Methanol, HPLC/UVO, |^S2T4) Strong oxidizers caustics metals such as tin & zinc (Note Prolonged exposure to fire and heat may result >n an explosion due to SPONTANEOUS decomposition ] Filter/Bub Methanol HPLC/UVD 11(4) |#S214J Chemical name, structure/formula, and DOT ID and guide Nos p-Oinitrobenzene CjHJNOjJj 100-25-4 CZ7525000 1597 152 Dimtro-o-cresol CHjC#H}0H(N02)} 534-52 1 GO9625000 1595 153 DtnKrotoluene Ce^jCHjtNOj), 25321-14-6 XT1300000 1600 152 (molten) 2036 152 (solid) Dt-sec octyl phthalate 117-61-7 TI0350000 Synonyms, trade names factors para-OMtrobenzene 1,4-DWtrobenzene Exposure (TWA untfiss noted otherwise) NIOSH/OSHA Imgrtn3 (skin) 4 6-Dlmtro-o-cresol 3 S-Dinltro-2-hydroxy- toluene 4 6-Dinitro-2-mathyl phenol DNC ONOC NIOSH/OSHA 0 2 mg/m3 (skin) Dlnitrotoluoi DNT MethyM(nitrobenzene NIOSH Ca See Appendix A 1 SmcMTi3 [skin] OSHA 1 5mgftn* (sklnj DEHP NIOSH Di(2-Ethylhexyl)phthalate Ca DOP See Appendix A bls-(2-Ethylhexyl)- 5 mg/m5 phthalate ST 10 mg/m3 Octyl phthalate [CjH^COOCHjCHfCjHjJC^HjJj) OSHAf 5 mg/m3 ARDQQQ22842 IDLH Physical description 50 mg/m3 Pale white or yellow crystalline solid 5 mg/ms Yellow odorless solid [insecticide] Chemical and physical properties MW. BP, SOL FI P. IP. Sp, Or, flammabitty VP, FRZ UEL, LEL MW 1661 BP 570*F Sot 001* FI P 7 IP 10 50 eV VP ? MLT 343'F UEL ? LEL ? SpGrl 63 Combustible SoM MW 1961 BP 594*F Sol 0 01% FI P NA IP ? VP 0 00005 mm MLT 190*F UEL NA LEL NA MEC 30 g/m3 IncompaUblltttes and reactivities Measurement method (Sea Table 1) Strong oxidizers caustics metals such as ton & zinc (Nota Prolonged exposure to fire and heat mey result m an exploetondue to SPONTANEOUS decomposition ] Filter/Bub Methanol HPLC/UVD IU4) |#S214] Strong oxidizers Filter/Bub 2 Propanol HPLC/UVD "(5) [SS166] Ca [50 mg/ml Orange-yelow crystalline solid with a characterettc odor [Nota Often shipped molten) Ca (5000 mg/m5) Colorless oily liquid with a slight odor Sp Gr 1 1 (estxnated) Noncombustible Solid MW 1622 BP 572*F VP 1 mm MLT 156*F Strong oxidizers caustics metals Filter/ Tana* Sol Insoluble UEL 7 such as tin 6 zinc GC/TEA- FI P 404*F IP ? LEL. 7 (Note Commercial grades wA EAP, OSHA decompose at 462'F (#44) with self-sustaining Sp Or 1 32 decomposition at 536*F) Combustible Solid but dtfllcuk to ignite MW 390 5 BP 727*F So75*F) 0 00003% FIP(oc) 420`F IP ? VP <0 01 mm FRZ 58'F UEL ? LEL(4744F) 03% Sp Gr 0 99 Class IIIB Combustible Liquid Nitrates strong oxidizers acids & alkalis Filter oifrlD IV (S5020 di(2 Ethylhexyl) Phthalate) Personal protection (See Table 3) Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet or contam Daily Quick drench [p-DInltrobenzene] Skin Eyes Wash skin Remove Change Prevent skin conlact Prevent eye contact When contam/Daily When wet or contam Daily (Dimtro o cresol] Skm Eye* Wash skm Remove Chw^e Provide Prevent skm contact Prevent eye contact When contam/Daity When wet or contam Daily Quick drench [Dmltrotoluene] Skin Eyes Wash skin Remove Change NR NR NR NR NR [Di-sec octyl phthalate] ABD00022843 Recommendations for respirator concentration for use (MUC| (See Table 4) NIOSH/OSHA 5 mg/m3- DM tO mg/m3 DMXSQ/HlE/SA 25 mg/m3 SA CF/PAPRDM 50 mg/m3 HIEF/SAT CF/PAPRTHIE/ SC8AF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape HiEF/SCBAE Route Symptoms (See Table 5) Hi Anoxia cyan, vis dist, Abs central scotomas, bad Ing taste, burning mouth dry Con throat thirst, yslewing has eyes, skm, anemia, liver damage NIOSH/OSHA 2 mg/m3 DMF t> mg/m3 HiEF/SA CF/PAPRDM1-/ SCBAF/SAF SCBAF PD PP/SAF PO PP ASCBA Escape HiEF/SCBAE Inh Abs Ing Con Sense of well being head fever lass profuse sweat excess thirst tacar hyperpnea cough short breath coma Health hazards First akf (See Table 6) ISI Breath Swallow- irrimmed Soapwaah tmmed Rasp support Medical attention (timed Target organs (Sse Table 5) Eyes skm Mood, liver, CVS, CNS Eye Skin Breath Swallow Irrimmed Soap washimmed Resp support Medical attention immed CVS endocrine sys 119 NtOSH SCBAF PD PP/SAF PD.PP-ASCBA Escape GMFOVHIE/SCBAE Mi AnHa.^mn;iannila. Aba isun. repo effects Jjo Icarc] Con 1 Breath Swallow Irrimmed Soap washimmed Reap support MNOK MflQOn knmed Blood, Iw, CVS, leprosys (inanimals. tMr.Mdni Mdnoy Canon] NIOSH SCBAF PD PP/SAF PD PP ASCBA Escape HiEF/SCBAE Mt Imteyes mucmemb ing in animats liver damage Con terato effects [care] Eye Breath Swallow Irrimmed Resp support Medical attention timed Eyes resp sys CNS livsr repro sys Gl tract [mammals liver tumors] Chemical name, structursfformula, CAS and RTECSNoa, and DOT ID and guide Noe Synonyms, trade names, and conversion factors Doxane c4h,o, 123-91-1 JG8225000 OMhyiene dioxide. OMhyieneether Dioxan p-Dtaxane 14-0nxane 120 1165127 Dioxathion C4H#0,JSPS(0CjH4)j]3 78-34-2 TE3350000 1 ppm 3 60 mgftn3 Delna^ p-Dioxane-2 3-diyl ethyl phosphorodithioate Dtoxane phosphate 2 3-p-Dioxenethiol S S-bis- (0 O-diethyl phosphorodrthioate) Navadett Diphenyl WA 92-52-4 DU6050000 Diphenyiamine (CjHj)jNH 122 39-4 JJ7800000 Bphenyl Phenyl benzene 1pprn>631mg/m* Aruiirtobenzene DPA PhenytanOne N-Phenylaralne N-Phenyfeenzenamne [Note The carcinogen 4-Amirtodiphenyl may be present as an impurity in the commercial product ] Exposure (TWA unless noted otherwise) NIOSH Ca See Appendix A C1 ppm (3 6 mgAn*) (30-min) 100 ppm (360 mg/m3) (sklnj NIOSH 0 2 mg/mJ [skin) OSHAt none NIOSH/OSHA 1 mg/mJ (0 2 ppm) ABD00022844 CLH Physical description Ca [500 ppm) Coiortess liquid or solid (below 53*F) wKh a mHd, ether-Kke odor Chemical and physical properties MW, BP. SOL Ft P, IP, Sp, Or, flammability VP, FRZ UEL, LEL MW 661 BP 214*F Sot Miscible FI P S6T IP-913eV VP 29 mm FRZ. 63'F UEL 22% LEL 2 OS Sp Or 1 03 Class IB Flammable Liquid ND Viscous brown MW 456 6 VP 7 tan or dark-amber BP 7 FR2 -4"F liquid Sol Insoluble UEL NA [insecticide] [Note Technical FI P NA IP 7 LEL NA product is a mixture of cis & trans-isomers ] Sp Gr(79*F) 1 26 Noncombustible Liquid 100 mgAn3 Coiortess to paieyelow aoM with a pleasant charactsrMIc odor [fungicide) MW 154 2 BP 489*F Sot Insoluble FI P 236T IP 7 95eV VP 0005mm MLT 156*F ua(311T7 SOS LEL(232*F) oas Incompatibilities and reactivities Strong oxidizers. decaborane trfathynyialummum Alkalis iron or tin surfaces heat Oxidizere Measurement method (See Table 1) Char GCfrlD. IV [1602] None available TenaxGC CCL GC#ID. IV (2630, 8lphenyt) NIOSH 10 mg/m5 OSHAt none SpGrl 04 Combustible SoHd ND Coiortess tan MW 169 2 VP(227*F) Oxidizers hexechloro- Filter (2) amber or brown BP 576*F 1mm melamine tnchloro- Methanol crystalline solid Soi 0 03% MLT 127'F melamne HPLC/UV with a pleasant FI P 307*F UEL 7 OSHA floral odor IP 7 40 eV LEL 7 (#76) (fungicide] SpGrl 16 Combustible Solid explosive if a cloud of dust is exposed to a source of ignition Personal protectioi and sanitation (See Table 3) Skin Eye* Washskm Remcrre Change Provide Prevent skin contact Prevent eye contact Mtencontam 'Mien wet (ftamm) NR Eyewash Quick drench [Droxane] Skin Eyes Aasn skin Remove Change Provide Prevent Skin contact Prevent eye contact When contarn When wet or contarr NR Eyewash Quick drench [Dioxatfnon \ Skm Eye* Wash skin Remove Chang* Provide Prevent akin contact Prevent eye contact Whencontam Mien wet or content Dally Eyewash (mofl) Quick drench (molt) (Diphenyl) Skin Eyes Washskrr Remove Change Prevent skin contact Prevent eye contact Daily When wet or contam Daiiy [Oiphenylamme] ARDQQQ22845 Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table 41 Route Symptoms (See Table 5) NIOSH * SCBAF PD PP/SAF PD PP ASC0A Escape GMFOV/SCBAE Inh AOs Ing Con Irnteyes skin nose throat drew head nau vomit liver damage kidney failure (cere) Health hazards First aid (See Table 6) Target organs (See Table 5) s& Breath Swallow Immmed Water waah prompt Reap support Medical attention mmeri Eyes, skki reap ays, liver kidneys {mammals king Irver&nasal cavity tumors) TBAl im Abs Ing Con irnteyes skin head gidd verti weak rhin chest tight miosis nau vomit abdom cramps diarr salv muse fasc con) drow Eye Skin Breath Swallow in immed Soap flush immed Resp support Medical attention immed Eyes skin resp sys CNS CVS blood ehol NKQSH/OSHA 10 mg/m1 CCROVDM/SA 25 mg/m1 SA CF'/PAPROVDM* 50 mg/m CCRFOVHiE/OMFOVHiE/ PAPRTOVHiE'/SCBAF/SAF 100 mg/m1 SAF PD PP SCBAF PO PP/SAF PD PP ASCBA Escape GMFOVHiE/SCBAE Hi Imt eyes throat Abs head nau ftg numb l"fl Hmbs liver damage Con IS, Breath Swallow Iit Immed Soap wash prompt Reap support Medical attention nvned Eye*, resp sys Nver CNS TBAL Inh Abs ing Con irnteyes skin muememb eczema tacar hypertension cough sneez methemo mcr BP heart rate prot hema Diadder inj m animats terato fleets Eye Skin Breath Swallow irr immed Soap wash prompt Resp support Medical attention immed Eyes skin resp sys CVS blood bladder repro sys Chemical name, structura/formula, CAS and RTECS Nos and DOT ID and guide Nos Synonyms trade names, and conversion factors mnyi nur CkyxjipcjifiH J4S90-94-# JM1676000 122 Dipropyl ketone (CHjCHjCH,)jCO 123-19-3 MJ5600000 %w2n2no2mSm2Lwim2r(m, DowanoiG 506 1 ppm 8.06 mgfm* Butyrone DPK. 4-Heptanor>e Heptan-4-one Propyl ketone 2710 127 OlquM (OtaMt dEramda) C^Wr, IMO-T jMsaeoooo 2791 161{aoM 2782 U1 (IqufcJ) Disuffiram [(C^jjjNCSI,, 97 77-8 J01225000 1 ppm =4 67 mg/m5 ___i dbmmid# now w*pj*t ia a Gabon iyiftMzl'-WyrWyl* Hum Ion), vartoua dlquat MMaraoommarciaily avalabla.] Antabuse bis(Diethylthiocarbamoyl) disulfide Ro-Sulfiram TETD Tetraethylthiuram disulfide Exposure Into (TWA unless noted otherwise) ABD00022846 IDLH Physical description NIOSH 100 ppm (600 mg/rn*) ST 150 ppm (900 mg/m*) iskinl tar*100 ppm NIOSH 50 ppm (235 mg/m5) OSHAT none 600 ppm Colorless liquid with a mild ether-dice odor N D Colorless liquid with a pleasant odor Chemical and physical properties MW, BP. SOL FI P. IP, Sp.Gr flammability VP, FRZ UEL, LEL MW-148.2 BP 406*F Sol MSactob FIP180*F p ? VP 0 5mm FRZ.-112T UEL30% LEL(392*F). im 8p.Gr 095 Claw IIIA Combusdbte Liquid MW 114 2 BP 291 F Sol Insoluble FI P 120*F IP 9 lOeV VP 5 mm FR2 27'F UEL ' LEL ' Incompatibilities and reactivities Measurement method (See Table 1) Strong oxidizers Char GCfclD, Oxidizers Char GCfclD OSHA [Adapt #7] SpGr 0 82 Class li Combustible Liquid NIOSH 0 5mgAn' OSHAf non# NXL OferemUa Mft - MW 944.1 VP-<000001 Yalow crystMa. BP- DawnMoaai. mm IterUcMai Sot70% MLT 636*P fric* CcmtareW FLP-7 UEL. ? product ttmf ba IP ? LEL? bund In liquid, concantrata or a solutionJ SpGr 1,22-1 XT CotnbosbWa Sold, bat doas not iQnita and buma with difficulty NIOSH N D White yellowish 2 mg/m5 or light-gray [Precautions should powder with a be taken to avoid slight odor concurrent exposure [fungicide] to ethylene dibromide } OSHAf none MW 296 6 BP ? Sol 0 02% FI P NA IP ? VP ' MLT 158*F UEL NA LEL NA Sp Gr 1 30 Noncombustible Solid Altai#, UV Rght, basic solutions [Not#., ConcantnOd dlquat sotuHonr eorrode aluminum 1 avalaMa None reported None available Personal protection (See Table 3) Skin Eyes Wash skin Remove Change NR NR NR NR NR [Dipropylene glycol methyl ether] Stun Lyes Wash skin Remove Change P event skin contact P'even' eye con act Da i, Anen we o' conMm NR .Dipropy Ketone Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet or contam Daily Quick drench (Diquat (Diquat bromide)] Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam When wet or contam Daily [Disuifmam] ABD00022847 Rec ommendattons for respirator selection -- mazimum concentration for use (MUC) (See Table 4) NIOSH/OSHA 000 ppm SA/SCBAF SCBAF PD PP/SAF PD PPASCBA Escape GMFOVHiE/SCBAE Route Symptoms (See Table 5) Inh Abs Ing Con Irnteyes nose throat weak li head head Health hazards First aid ISee Table S) Target organs (See Table 5) Eye Skin Breath Swallow Irrimmed Water wash prompt Resp support Medical attention immed Eyes resp sys CNS 1 bAL TBAL TBAL Inh ing oon lr,il eyes ski i ' N s dejies diLi soir de r n eatn n animals liver r>| i i ou Skin Breath Swallow r immea Soap wash Resp support Medica attention immed -yes Skin CNS iUf 123 Inh Abs Ing Con Irnteyes skin muememb resp sys rtnn epis skin bums nau vomit diarr mal kidney liver mj cough chest pain dysp pulm edema tremor convuis delayed healing of wounds Eye Skin Breath Swallow In immed Water Rush immed Resp support Medical attention immed Eyes skin resp sys kidneys liver CNS Inh Ing Con irnt eyes skin resp sys sens derm lass ftg tremor restless head dizz metallic taste pen neur liver damage Eye Skin Breath Swallow Irr immed Soap wash immed Resp support Medical attention immed Eyes skin resp sys CNS PNS liver Chemical imim, structure/formuia, CAS and RTECSNos, and DOT ID and gulda Not Synonyms, trada names and convaralon factors DisuNoton C^eO^PS, 200*04-4 TD9279000 O.OOMhyl S-2-(ethy*hio>ethyl uhosphoitidlmioMe DLSyatonM Thtodemeton 124 2703 1S2 2 6 0< tert butyl p-cresol [CtCHjiJjCHjCjHjOH 128-37 0 G07875000 BHT Butylated hydroxytoluene Dibutylated hydroxytoluene 4 Methyl 2 6 di tert butyl phenol tVSO,NHCON<CMJ, MO-54-1 YM02SOOO 1,1-dknedtyiuree; Mu* KimWi Exposure MM (TWA unless noted otherwise) MOSH 0 Img/m* [skin] OSHAT none NOSH 10 mg/m} OSHAt none lOmg/m* OSHAt ABD00022848 DLH Physical description ND Oily colorises to yetow liquid with a characteristic, sulfur odor [Insecticide] [Note Technical product is a brawn HqukL] Chemical and physical properties MW, BP. SOL FI P IP, Sp. Gr, ftammaMtty VP FRZ UEL, LEL Incompatibilities and reactivities MW 274 4 BP ? Sol(73*F) 0.003% FIP>180*F IP 7 VP-0 0002 mm FR>-13*F UEL 7 LEL. 7 AikeBe SpGr 114 Combusdble Liquid but w not ignftt soaly NO White to pale- MW 220 4 VP 0 01 mm Oxidizers yellow crystalline BP 509"F MLT 158*F solid with a Sol 0 00004% UEL ' slight phenolic FI P 261 F LEL 7 odor (food preservative] NO (herblefde) SpGr 105 Class iliB Combustible Liquid BP-3MT* fisar1 Flp-WK VPs LB_NA, ,* Divnyt benzene CjH4(HC*CH}), 1321 74-0 (mixed isomers) CZ9370000 2049 130 Diethylbenzene DVB Vmytstyrene [Note Commercial product contains aH 3 isomers but rtHsomer predominates Usualy contains an inhibitor to prevent polymerization ] 1 ppm = 5 33 mg/m3 NIOSH 10 ppm {50 mg/mJ) OSHAt none <* ?* ... NMmJMMWW 8cM ' #* *x'* i ND Pale straw-colored MW 1302 VP 07mm None reported liquid BP 392*F FRZ -88*F Sol 0 005% UEL 6 2% FIP(oc) 169*F LB.11% IP 7 SpGr 0 93 Class II1A Combustible Liquid Measurement method (SeeTablel) OVS-2, Tokjen*/ Mam GOFF** IV (saoo, Orgeno- *3BS5 Si gel Methanol/ G^fiD IK1) [P&CAM *226] Char Toluene GC/FID OSHA |*89] Personal protection and sanitation iSee Table 3j Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact Whencontam When wet or contam Daily Eyewash Quick drench [Disulfolon] Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye < ontact Whencontam Wher wet or contain Daily (2 6 Di tert but/' p rresol] SMn SB.** Remove Change Prevent sign contact Prevent eye contact Daily NR Daily [Diuron] Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam Mien wet or contam MR Eyewash Quick drench [Oivinyl benzene] ABD00022849 Recommendations for respirator selection -maximum concentration lor use |MU>- (See Table 4, TSAI Route Symptoms iSee Table 5i Inh Abs mg t on irnteyes skin nau vomit abdom cramps diarr salv head gidd verti weak rhin chest tight blurred vision miosis card irreg muscfasc dysp eye skin burns Health hazards First aid (See Table 6j Breath Swallow Irr immad Soap flush immed Resp support Medical attention immed Target organs (See Table 5) Eyes skin respsya CNS CVS Wood chol TBAL kift tng Con Irrit eyes skm m animals deer growth rate mcr liver weight Eye Skin Breath Swallow Irr immed Soap wish Fresh air Medical attention immed Eyes skin 125 TBAL Imteyes skin nose Ing throat Con mammals anemia methemo IS, Breath Swallow- Irr immad Water flush immed Reap support Medical attention nmed Eyes skin reap sys blood TBAL mh Ing Con Imt eyes skin resp sys skin burns in animals CNS depres Eye Skin Breath Swallow irr immed Soap flush immed Resp support Medical attention immed Eyes skin resp sys CNS 126 Chemical name structure/formula, CAS and RTECS Nos, and OOT ID and guide Not Synonyms, tradenames, and conversion factors Exposure knits (TWA unless noted otherwise) 1-Oodecanethiol CH^CHj),,SH 112-660 JR31S5000 Dodecyl mercaptan 1-Dodecyl mercaptan n-Dodecyl mercaptan Leuryl mercaptan n-Laurytmercaptan 1-Marcaptododerane NIOSH COS pom (4 1 mg/m3) [15-rnln] OSHA none 1228 131 1 ppm 8.28 mg/m3 Emery AijOj 1302 74-5 (corundum) GN023100Q (corundum) Aluminum oxide Aluminum tnoxide Corundum Impure corundum Natural aluminum oxide (Note Emery is an impure variety of ALO, wtuch may contain small impurities of iron magnesium 6 silica Corundum is natural AI,Oj] NIOSH See Appendix 0 OSHAT 15mg/mJ (total) 5 mg/m5 (resp) CwawM--n ClHtClf0J3 11WB-7 RW276COO gssffiu 6,7,8,9.)0 !!--cHorc dloxafMapin-S-exide. TNodan# U06H Olnilhi* [akin) OSHAt 27B116t Endnn C,JH,ClsO 72-20-8 101575000 1 2 3 4 10 10-Hexachloro- 6 7-epoxy1 4 4a 5b 7 8 Ba- octahydro-1 4-endo endo5 6-dimethenonaphthalene Hexadrln NIOSH/OSHA 0 1 mg/m3 (skin) 2761 151 ABD00022850 IDLH Physical descnptlon N D Colorless waterwhite or paleyellow osy liquid with a mild skunklike odor [Note A sold beiowl5*F] N D Odorless white crystalline powder N.O. saUitaulftr tffrrH odor noaectidde) [Mir TochnM preduel It a-tan. wny, homer mixture) Chemical and physical properties MW BP, SOI. FI P IP Sp,Gr, flammability VP, FRZ UEL LEL MW 202 4 BP 441-478`F Sol Insoluble FI P(oc) 190*F IP ? VP(77*F) 3 mm FRZ.15*F UEL ? LEL? Incompatibilities and reactivities Measurement method (See Table i) Strong oxidizers & adds strong bases reducing agents afcaJJ metals, water, steam None avslabie SpGrOeS Class IIIA Combustible Liquid See a-Alumina for physical & chemical properties Filter none Grav IV [Particulates NOR #0500 (total) #0600 (resp)) if. mjm.w *- vrw# r* BP1 Oeooraa^o QMO&nm SotOMOO^% '- HLT.mr PIP* NA ' UGL'MA IP-7 LEL'NA Sonccmbuaible-Bold,** may b# Dfep. jgmkipto' bon.' Hydretyaa * etowty on oontad wtowrearor _____ ,, ssareMTfT to form aubur dtaddol 2 mg/m3 Coloiless to tan crystalline solid with a mild chemical odor (insecticide) MW 380 9 VP Low Strong oxidizers BP Decomposes MLT 392*F strong scads Sol Insoluble (Decomposes) paratruon FIP NA UEL NA [Note May emit IP 7 LEL NA hydrogen chloride & phosgene whan heated or burned ] Sp Gr 1 70 Noncombustible Solid but mav be dissolved In flammable liquids Filler/ Chrom-102 Toluene GC/ECD IV [#5519) Personal protection (See Table 3) Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact Whencontam When wet or contam NR Eyewash (1-Oodecanethioil Ski Eyes rtasn skin Remove Change NK NR NR NR NR [Enieryi Skm Eyes. Wash skin Remove Change Provide Prevent skin contact Prevent eye contact Whencontam When wel or contam Daily Eyewash Quick drench (Endosulfsn) Skm Eyes Wash skin Remove Change Provide Prevenl skin contact Prevent eye contact Whencontam When wet or contam Daily Eyewash Quick drench (Endnnj ABD00022851 Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table 4) NIOSH 5 ppm CCROV/SA 12 6 ppm SACF/PAPROV 25 ppm CCRFOV/GMFOV/PAPRTOV/ SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Route Symptoms (See Table 5) Inh imteyes skin reap sys Infl cough dizz cfysp weak, Con com cyan abdom pain nau skin sens Health hazards First aid (See Table 6) Eye Skm Breath Swallow Irr immed Soap wash immed Resp support Medical attention mmed Target organs (See Table 5) Eyes skin resp sys CNS blood TBAL inn mg Con irnt eyes skin resp sys Eye Breath Swallow Irr immed Fresh air Medical attention immed Eyes skin resp sys 127 TBAL Hi Abe Ing Con Irrit skin, nau conf agitation flushing dry mouth tremor convuls head in animats kidney liver inj deer tesbe weight S Breath Swallow Irr Immed Soap flush Immed Reap support Medical attention immed Skm, CNS, Ivor kktneys reproaye NIOSH/OSHA 1 mg/m5 CCROVDMFu/SA 2 mg/m3- SA CF/PAPROVDMFu/ CCRFOVHiE/GMFOVHiE/ SCBAF/SAF SCBAF PD PP/SAF PO PP ASCBA Escape GMFOVHiE/SCBAE Hi Abs Ing Con Epilep convuls stupor head dizz abdom discomfort nau vomit insom aggressiveness conf leth weak anor mammals liver damage Eye Skin Breath Swallow Irr immed Soap wash immed Resp support Medical attention immed CNS liver Chemical name structure/formula, CAS and RTECS Nos, and DOT 10 and guide Nos Synonyms, trade names, and conversion factors Exposure {TWA unless noted otherwise) ABD00022852 IDLH Physical description Enflurane CHFjOCFjCHCF 13838-16-9 KN8600000 128 Epichlorohydrin C3H5OCl 106-89 8 TX4900000 2023 131P EPN C^H^SP 2104-64-6 TB1926000 2-Chloro-1-(diftuorometftoxyjhl 1,2-tnfiuoro- ethane, 2-CWoro-1,1,2-tnfluoro- ethyl dffluoromethyl ether Ethrane* 1 ppm*7 SSrog/m3 1 Chioro-2 3-epoxypropane 2 Chloropropylene oxide y-Chloropropylene oxide 1 ppm = 3 78 mg/m3 NIOSH* N0 C 2 ppm (ISlmg/m3) [60-minl [Note REL for exposure to waste anesthetic gas] OSHA none NIOSH Ca See Appendix A OSHAT 5 ppm (19 mg/mJ) [skin] Ca (75 ppm) Ethyl p-nttrophenyl benzenethionophaephonate, O-Ethyl 0-<4-nitrophenyl) phenytohoaphonothroate EC1HsO(C(IH&)P(S)OC,H4NOj] NIOSH/OSHA 0 5 mg/m5 [skin] 5mg/ms Clear colorless liquid with a mild sweet odor (inhalation anesthetic] Colorless liquid with a slightly irritating chloroform like odor Yellow solid with an aromatic odor [pesticide] (Note A brown liquid above 97'FJ Chemical and physical properties MW BP, SOL FI P, IP, Sp Gr flammability VP, FRZ UEL, LEL MW 164 5 BP 134*F Sol Low FIP NA IP ? VP' 175 mm FRZ. ? UEL NA LEL NA Sp Gf(77*F) 1 52 Noncombustible Liquid MW 92 5 BP 242*F Sol 7% FI P 93*F IP 10 60 eV VP 13mm FRZ 54*F UEL 21 0% LEL 3 8% Sp Gr 1 18 Class 1C Flammable Liquid MW 323 3 BP ? Sol Inaoluble FIP NA IP 7 VP(212*F) 0 0003 mm MLT 97*F UEL NA LEL NA Ethanolamine NHjCHjCHjOH 141-43-5 KJ5775000 2491 153 2-Ammoethanol 6 Ammoethyl alcohol Ethylolamine 2 Kydroxyethylamine Monoethanolamine 1 ppm = 2 50 mg/mJ NIOSH 3 ppm (8 mg/m3) ST 6 ppm (15 mg/m3) OSHAt 3 ppm (6 mg/m3) 30 ppm Colorless viscous liquid or solid (below 5l*F)with an unpleasant ammonia like odor Sp.Gf{77*F) 1 27 Noneombuatlbie SoUd MW 61 1 BP 339'F Sol Miscible FI P 186*F IP 8 96eV VP 0 4 mm FRZ 51*F UEL 23 5% LEL(284*f) 3 0% Sp Gr 1 02 Class IHA Combustible Liquid Incompatibilities and Measurement method (See Table 1) None reported Anasorb GCfrlO OSHA [#103] Strong oxidizers strong acids certain salts caustics zinc aluminum water [Note May polymerize in presence of strong acids and bases particularly when hot) Char GC?FID IV (#1010) Strong oxidizers Fitter Isooctane, GC/FPD IV [#5012] Strong oxidizers strong acids iron [Note May attack copper brass and rubber] Si gel Methanol/ Water GC/FID IV [#2007 Aminoethanol Compounds] Personal protection and sanitation (See Table 3) Skin Eyes Wash skin Remove Change NR Prevent eve contact NR NR NR [Enflurane] Skin Eyes Wash skin Remove Change ov de Prevent skin contact Prevent eye contact When contam Whe" wet i'flamn-j NR Eyewash Quick arench [Ebirhicrohydrm Skin Eyes Wash skin Remove Chanae Provide Prevent skin contact Prevent eye contact When contam When wet or contam Daily Eyewash Quick drench [EPN} Skin Eyes Wash skin Remove Change Provide Prevent sk n contact Preven, eye contact When contam When wet or contam Daily Eyewash [Ethanolamme] ABD00022853 Rec ommendations for respirator selection -- maximum concentration for use (MUC) (See Table 4) TBAL Route Symptoms (See Table SI Inh imt eyes CNS aepres Ing analgesia anes sez Cor resp depres Health hazards Firstaid (See Table 6) !n Breath Swallow Irr immed Soap wash Resp support Medical attention immed Target organs (See Table S) Eyes CNS NIOSH SCBAh PD PP/SAF PD PP ASCBA Escape GMFOVAG/SCBAE Inh AOs Ing Con irrit eyes skin with deep pain nau vomit aodom pain resp distress cough cyan repro effects [care1, Eye Skm Breath Swallow Irr immed Soap wash immed Resp support Medical attentior immed Eyes skin resp sys kidneys liver repro sys [mammals nasal cancerj NIOSH/OSHA 5 mg/mJ SA/SCBAF SCBAF PD PP/SAF PD PP ASC0A Escape GMFOVHiE/SCBAE Inh Abs Ing Con Irnteyes skin miosis lac mm head chest tight wheez lar spasm salv cyan anor nau abdom cramps diarr para convuls low BP card irreg Skin Breath Swallow Irrimmed Soap wash immed Resp support Medical attention immed skin resp sys CNS blood chol NIOSH/OSHA 30 ppm C CRS'/GMFS/PAPRS'/SA / SCBAF SCBAF PD PP/SAF PO PP ASCBA Escape GMFS/SCBAF Inh lag Con Irnteyes skin resp sys leth Eye Skin Breath Swallow Irrimmed Water flush prompt Resp support Medical attention immed Eyes skin resp sys CNS Chemical name itructure/formula, CAS and RTECS Nos and DOT ID and guide Nos Synonyms trade names and conversion factors Ethton 1(CjHjO)jP(S)S]jCHj 563-12 2 TE4550000 OOO O-TetraethylSSmethylene dKphosphorodithioate) 130 2763 152 2 Ethoxyethanol CjHjOCHjCHjOH 110-80-5 KK8050000 Cellosolve EGEE Ethylene glycol monoethyl ether 1171127 2-Ethoxyethyl soetata CHjCOOCHjCHjOCjH, 1H-1S9 KK6226000 1 ppm * 3 69 mg/m3 CeOosotve* acetate EGEEA, Ethylene glycol monoethyl ether acetate Glycol monoethyl ether eoetate 117212# Ethyl acetate CM,COOCjH5 141 78-6 AH 5425000 1 ppm 6 41 mg/m3 Acetic ester Acetic ether Ethyl ester of acetic acid Ethyl ethanoate 1173 129 1 ppm * 3 60 mg/m3 Exposure limits (TWA unless noted otherwise) NOSH 0 4 mg/m3 n) OSHAt none NIOSH 0 5 ppm (1 8 mg/m3) [skin] OSHA 200 ppm (740 mg/m3) [skin] NIOSH 0 5 ppm (2 7 mg/m3) (skin) OSHA 100 ppm (640 mg/m3) (akin] NIOSH/OSHA 400 ppm (1400 mg/m3) ABD00022854 IDLH Physical description Chemical and physical properties MW BP, SOL FI P IP Sp Gr flammability VP, FR2 UEL, LEL ND Colorless to amber- MW 384 5 VP 0 0000015 colored odorless BP >302*F mm liquid (Decomposes) FRZ 10'F (insecticide] Sol 0 0001% UEL ' [Note A solid below FI P 349*F LEL 7 1Q*F The techni IP 7 cal product has a very disagreeable odor ] Sp Gr 1 22 Class 1I1B Combustible Liquid 500 ppm Colorless liquid with a sweet pleasant ether like odor MW 90 1 BP 275 F Sol Miscible FI P 110 F IP ' VP 4 mm FR2 130 F UEH200 F) 156% LEL(200 F) 17% Incompatibilities and reactivities Acids alkalis Strong oxidizers 500 ppm Colorless liquid with a mM odor Sp Gr 0 93 Class II Combustible Liquid MW 132 2 BP-313*F Sol 23% F1P124*F IP 7 VP 2mm FRZ 79*F UEL 7 LB-17% Nitrates strong oxidizers, stalls & adds 2000 ppm (10%LEL) Colorless liquid with an ether like fruity odor Sp Gr 0 98 Class II Combustible Liquid MW 88 1 BP 171 F SW(77 F) 10% FI P 24*F IP 10 01 eV VP 73 mm FRZ 117*F UeL1l5% LEL 2 0% Nitrates strong oxidizers alkai s & acids Sp Gr 0 90 Clae* 16 Flammable Liquid Measurement method (See Table 1) OVS-2 Toluene/ Acetone GC/FPO IV [95600 Organophoaphorua Pestodea Char Methanol/ CH.CL GC/tfD IV (#1403 Alcohols IV) Cher gcSfio IV [91450 Eaten 1] Char GCfclD IV (#1457) Persun .1 ( rolfi Hill Mi it Itic s. e T <1)1. 3 Mil t yes Was"- s n Remove Change Provide S C.Ci ' Rill uO 1 dot P e.ent e,e -ontac. Wr>tn contain Wie wet cr con'am Daily Eyewash Quick drench [Ethion] Ski' Lyes Wash skin Remove Change Pee* sr r contact Preven eye con'act When contam A'hen wet or conlani NR 12 Ethoxyethano' Skin Eyas Wash skin Remove Change Prevent skin contact Prevent eye contact When contam When wet or contam NR [2-6lhoxyethyt acetate) Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contain When wet Famm, NR [Ethyl acetate) ABD00022855 R c.on mi ml jtn i' fi'rnspir.itdr < li-ctioi - in uninni nntr iticiii for usi (MU' iSeo I jBIl 4i N i. oft 5fsy mpo ms i Spi , dtu. fry AOs, lng C cn ir -i,i s SR r nau .omit aDdom .ramps diari saiv ituad giod verti weak mm chest 1 gnt Diurred vision miosis card irreg muscfasc dysp Hi i u, i >j irds First Md Sei Table ei Eye Skin Breath Swallow ir- irrtmed Soap wash immed Resp support Medical attention immed t argtt organs i Set Table 5) Eyes skin resp sys CNS CVS filooo choi NlOSh 5ppm SA i2 5 ppm SA CF 25 ppm si BAF/SAF 500 ppn SA PD PP SCBAF PO PP/SAF PD PP ASCBA Escape GMFOV/SCBAE >rih AOb mg Co in animals irriteyes esp Sy5 blood ct anges .er Ridney ung damage euro terato effects UY* Skip Breath Swa iow ii immed Water flush prompt Resp suppon Mediuai attention immed Eyes resp sys blood kidneys i ve repro sys nemato sys NIOSH 5 ppm CCROV /SA 12 5 ppm $A CF'/PAPROV* 25 ppm CCROV/GMFOV/PAPRTOV / SCBAF/SAF 500 ppm SAPOPP SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Inh Abs Ing Con Imteyes nose vomit kidney damage para in animals repro terato effects NIOSH'OSHA 2000 ppm SA CFr/PAPROV/CCRFOV- GMFOV/SCBAF/SAF SCBAF PO PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Inn irriteyes skin nose Ing throat narco derm Con Breath Swallow Irr immed Water flush prompt Resp support Medical attention immed Eyes respsys Gl tract repro sys hemato sys Eye Skin Breath Swallow Irr immed Water Hush prompt Resp support Medical attention immed Eyes skin respsys Chemical name structura/formula and DOT ID and guide Noa Ethyl acrylate CH,*CHCOOCjH5 140-55-5 AT0700000 Synonyms trade names factors Ethyl acrylate (inhibited) Ethyl ester of acrybc acid Ethyl prepenoate 132 1917 129P (inhibited) Ethyl alcohol CMjCHjOH 64 17 5 KQ6300000 1 ppm = 4 09 mglrn1 Alcohol Cologne $(xnt Ethanol EtOH Grain alcohol 1170 127 Etftyfvnine CH,CHjNHj 76-04-7 KH2100000 1 ppm * 1 89 mg/m5 Amnoefiane Ethylamlna (anhydrous) Monoethytamine 1036116 Ethyl benzene CHjCHjCjHj 100-41-4 DA0700000 1 ppm 1 85 mg/m3 Ethylbenzol Phenyiethane 1175 129 1 ppm = 4 34 mgim5 Exposure fentts (TWA unless noted otherwise) ABD00022856 IDLH Physical description NIOSH Ca See Appendix A OSHAT 25 ppm (100 mg/m1) {skin] Ca Colorless liquid [300 ppm] with an acrid odor NiOSH/OSHA 1000 ppm (1900 mg/m') 3300 ppm (10%4-EL] Clear colorless liquid with a weak ethereal vinous odor Chemical and physical properties MW. BP SOL FI P IP Sp, Gr flammability VP,FRZ UEL LEL MW 1001 8P-211V Sol 2% Ft P 48*F IP 10 30 aV VP 29 mm FRZ -96*F UEL14% LEL 14% So Gr 092 Claes 18 Flammable Liquid MW 46 1 BP 173 F Sol Miscible Fl P S5'F IP 10 47eV VP 44 mm FRZ 173 F UEL 19% LEL 3 3% NOSHOSKA 10 ppm (18 mj/m3) NIOSH 100 ppm (435 mg/m5) ST 125 ppm (545 mg/m3) OSHAT 100 ppm (435 mg/m3) 600 ppm 800 ppm (10%LL] Colorless gas or water-while IquM (below 62*F) w9h snammonMhe odor [Note Shipped ee a KqueAed compreeeed ges) Colorless liquid with an aromatic odor Sp Gr 0 79 Class IB Flammable Liquid MW 45 1 BP S2*F Sol MMble FIP IT IP 8 66 aV VP-674 mm FRZ.-114T UEL.140% LB_3.5% RQaaD 161 Sp Gr 0 69 (Liquid) FlammableGaa Class tA Flammable Liquid MW 106 2 BP 277*F Sol 0 01% Fl P 55 F IP 8 76 eV VP 7 mm FRZ 139 F DEL 6 7% LEL 0 8% Sp Gr 0 87 Class 18 Flammable Liquid Incompatibilities and reactivities Measurement method (See Table 1) Oxidizers peroxides potymerizers strong eBudts moisture chlorosuHbmc add (Note Polymerizes readSy unless an InhWtor such as hydroquinone is added ] Cher GCfrlO IV [61450 Esters 1] Strong oxidi2ers potassium dioxide bromine penfafluonde acetyl bromide acetyl chlonde platinum sodium Char 2 Butanol/ GcfclD IV (61400 Alcohols 1] Sboog edde strong oxidizera copper On 6 zinc in presence of moisture oetuloee nitrate, chlorine hypochlorites }lisi44] Strong oxidizers Char GC^FID IV [61501 Aromatic Hydro carbons] Personal protection and Sanitation (See Table 3) SKm IFyes Wash skin Remove Change Provide Prevent s<m contact Prevent eye contact When contam When wet (flamm) NR Eyewash Quick drench [Ethyl acrylate) Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam When wet (flammj NR ABD00022857 Recommendations for respirator selection - maximum concentration for use (MUC (See Table 4] NKjSH SC DAT PO PP/oAF PO PP ASCBA Escape GMFOV/SCBAE Fy n< Symptoms (ace fable 5) inh Aba Ing Con nut eyes skin resp sys [tare} NIOSH/OSHA 33U0 ppm SArSCBAF k SCBAf PD PP/SAF PD PP ASCBA Escape SCBAE Inh Ing Con uriteyes skin nose need diow fig nano cough liver damage anemia repro terato effects [Ethyl alcohol) SHn tSChskin Remove Charge Provide Pravant sMn contact (Ho) Prevent aye contact (tq) When contam (Sq) When wet or contam (Kq) NR Eyewash (ttq) Qua* drench (*q) (fthytaminal Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam When wet (flamm) NR NIOSH/OSHA 260 ppm SACF^PAPRS* 500 ppm CCRFS/GMFS/SCBAF/SAf 600 ppm SAP POPP 8 SCBAF PO PP/SAF PO PP ASCBA Escape GMFS/SCBAE Inh Imt eye* akin rasp Abs ays akin bums derm (I'd) Ing Con (Hq) NIOSH/OSHA 800 ppm CCROVVGMFOV/PAPROVV SA'/SCBAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Inh Ing Con irriteyes skin inuememb head derm narco coma Health hazards First aid 'See Table 6, Eye Skin Breath Swallow immmed Water flush immed Resp support Medical attention irnmed Target organs iSce Table 5) f yes skin respsys (inaiun lals tumors of the forestornachj Eye Sxiri Breath Swallow Irr immed Water flush prompt Fresh air Medical attention immed Eyes skin respsys CNS liver blood repro sys is, Breath SwaHcw Irr anmed (Itq) Water flush anmed (i'0) Rasp support Uedtcat attention immed (bq) Eyes akin reap ays Eye Skin Breath Swallow Immmed Water flush prompt Resp support Medical attention immed Eyes skin respsys CNS 133 [Ethyl benzene} Chemical name structure/formula CAS andRTECSNos and OOTID and guide Nos Synonyms trade names, factors Ethyl bromide CHjCHjBr 74-96-4 KH6475000 Bromoethane Monobromoethane 1891 131 Ethyl botyi ketone CHjCH^COICHjJjCH 106 35 4 MJ5250000 1 ppm = 4 46 mg/m3 Butyl ethyl ketone 3 Heptanone 1224 127 Ethyl chloride 75 00-3 KH7525000 1 ppm = 4 67 mg/m3 Hydrochtonc ether Munetic ether 1037 115 Ethylene chlorohydrin CH,CICh2OH 107 07 3 KK0875000 1 ppm * 2 64 mg/m3 2 Chloroethanoi 2 Chloroethyl alcohol Ethylene ehlorhydnn 1135131 1 ppm = 3 29 mg/m3 Exposure Smite (TWA unless noted otherwise) NIOSH See Appendix D OSHAT 200 ppm (890 mg/m3) ABD00022858 IDLH Physical descnption Chemical and physical properties MW BP, SOL FI P IP Sp, Gr flammability VP FRZ UEL LEL 2000 ppm Colorless to yellow liquid with another like odor (Note A gas above 101T) MW 109 0 BP 101 *F Sol 0 9% FI P <4*F IP 10 29 eV VP 375 mm FRZ -182*F UEL80% LEL 0 8% NIOSH/OSHA 50 ppm (230 mg/m3) 1000 ppm Colorless liquid with a powerful fruity odor Sp Gr 1 46 Class IB Flammable Liquid MW 114 2 BP 298'F Sol 1% FiP(oc) 115 F IP 9 02 ev VP 4 mm FRZ 38 F UEL ' LEL 7 NIOSH Handle with caution in the workplace See Appendix C (Chloroethanes) OSHA 1000 ppm (2600 mg/m5) NIOSH C 1 ppm (3 mg/m3) [skin] OSHAT 5 ppm (16 mg/m3) [Skin) 3800 ppm [10%LEL] Cotortesa gaa or liquid (below 54*F) with a pungent ether like odor [Note Shipped as a liquefied compressed gas] 7 ppm Colorless liquid with a faint ether like odor Sp Gr 0 82 Class II Combustible Liquid MW 64 5 VP 1000mm BP 54`F Sol 0 6% FRZ -218'F UEL154% FI P NA (Gas) LEL 3 8% 58*F (Lkj) IP 10 97eV RGasD 2 23 Sp Gr 0 92 (Liquid at 32*F) Flammable Gas Class IA Flammable Liquid MW 80 5 BP 262 F Sol Miscible Fl P 140 F IP 10 90 eV VP 5 mm FRZ 90 F UEL 159% LEL 4 9% Sp Gr 1 20 Class IMA Combustible Liquid Incompatibilities and reactivities Measurement method ChemcaJ/y-active metals such aa sodium potassium calcium powdered aluminum one 8 magnmum Char 2-Propanol GC/FID IV [#1011] Oxidizers acetaldehyde perchloric acid Char Methanol/ GC/^iD IV [#1301 Ketones II] Chemicaly-ecttve metal* such a* sodium potassium calcium powdered aluminum zinc6 magnesium oxidizers water or steam [Note Reacts with water to form hydrochloric acid) Strong oxidizers strong caustics water or steam Char(2) GcSiPlD IV [#2519] Char(pet) 2 Propanol/ GC/^lD IV [#2513] Personal protection and Sanitation (See Table Skm Eyes Wash skin Remove Charge Prevent skin contact Prevent eye contact When contain When wet (ftamm) NR [Ethyl bromide] Skin Eyes Wash skm Remove Change Prevent skin contact Prevent eye contact When contam When wet or contam NR [Ethyl Duty i ketone, Skm Eyes Wash skin Remove Change Prevent skin contact lllq) Prevent eye contact (Uq) N ft When wet (flamm) NR [Ethyl chloride] Skin Eyes Wash skin Remove Change Provide Prevent skin contact Brevent eye contact When contam When wet or contam NR Eyewash Quick drench [Ethylene chtorohydnn] ABD00022859 Recommendations for respirator selection--maximum concentration for use (MUC) (See Table 4) OSKA 2000 ppm SA/SCBAF SCBAF PO PP/SAF PO PP ASCBA Escape GMFOV/SCBAE Route Symptoms (See Table 5) hh Imteyee skin respsys Ing CNSdepres pulm edema Con liver kidney disease card arthy card arrest Health hazards First aid (See Table 6) Target organs (See Table 5) 3E. Breath Swallow Irnmmed Soap flush prompt Rasp support Medical attention mmed Eyes skin reapsys liver kidneys CVS CNS NlOSH/OSHA 500 ppm CCROV /SA 1000 ppm SA CF /PAPROV'/CCRFOVr GMFOV/SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Ml Ing Con irmeyes skin mucmemb head narco coma derm Eye Skin Breath Swallow irr immed Water flush Resp support Medical attention immed Eyes skin reap sys CNS OSHA 3800 ppm SA'/SCBAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE kti Abs Ing <Hq> Con Inco mebd abdom cramps card arrhy card arrest liver kidney damage S& Breath Swaflow Irr immed (Itq) Water flush prompt 0Q) Reap support Medical attention immed (Uq) Liver kidneys resp sys CVS CNS NIOSH 7 ppm SA/SCBAF SCBAF PO PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Inh Abs Ing Con irritmucmemb nau vomit verti inco numb vis dist head thirst delinum low BP collapse shock coma Uvec kidney damage Eye Skin Breath Swallow (it immed Water flush immed Resp support Medical attention mmed Resp sys liver kidneys CNS CVS eyes Chemical name Structure/formula CAS and RTECS Nos, and DOT ID and guide Nos Synonyms, tradenames, and conversion factors Exposure limits (TWA unless noted otherwise) Ethylenerliamlne NHjCHjCHjNHj 10715-3 KH6S75000 12-Dtamnoethane 1 2-Ethanacfeamne Ethylanediamine (anhydrous) NiOSH/OSHA 10 ppm (25 mg/m*) ABD00022860 OLH Physical description 1000 ppm Colorless viscous liquid with an ammome-Uke odor (fungicide] [Note A solid below 47*F J Chemical and physical properties MW, BP, SOL FIP.IP, Sp.Gr. flammability VP, FRZ UEL LEL MW 601 BP 241'F Sol Misdbie RP 93*F IP 8 60eV VP 11 mm FR2.47*F UEl(212*F) 5 LEM212T). 25% 136 1604 132 Ethylene dtbromide BrCH,CH,Br 106 93 4 KH9275000 1605 154 Ethylene dichlonde CICHjCHjCI 107-06-2 KI0525000 1164 129 Ethylene glycol HOCHjCHjOH 107 21 1 KW297bOOO 1 ppm 2 46 mg/m3 1 2 Dibromoethane Ethylene bromide Glycol dibromide 1 ppm = 7 69 mg/m5 1 2-Dichloroethane Ethylene chloride Glycol dichloride 1 ppm 4 05 mg/m3 1 2-Dihydroxyethane 1 2 Ethanediol Glycol Glycol alcohol Monoethylene glycol SpGrOei Claw 1C Flammable Liquid NJOSH Ca Ca (100 ppm] See Appendix A 0 045 ppm C 0 13 ppm [15-min] OSHA 20 ppm C 30 ppm 50 ppm (5 min max peak] Colorless liquid or solid (below 50'F) with a sweet odor [fumigant] MW 187 9 BP 268 F Sol 0 4% FI P NA IP 9 45 eV VP 12mm FRZ 50 F UEL NA LEL NA SpGr-2 17 Noncombustible Liquid NIOSH Ca Colorless liquid Ca [50 ppm) with a pleasant, See Appendix A. C chloroform-like (Chloroethanea) odor 1 ppm (4 mgAn3) (Note Decomposes ST 2 ppm (8 mg/m3) slowly, becomes OSHAf addic & darkens 50 ppm In color] C 100 ppm 200 ppm (5-mln max peak in any 3 hrs) MW 990 BP-182*F Sot 0 9% PIP 5fl*F IP-11 05eV VP 84 mm FRZ. -32"F UEL 18% LEL 6 2% Sp Or 1 24 Claes IB Flammable Liquid NIOSH See Appendix D OSHAT none NO Clear odorless syrupy odorless liquid [antifreeze] [Note A solid below 9'F} MW 62 1 BP 388'F Sol Miscible FI P 232'F IP f VP 0 06 mm FRZ 9'F UEL153% LEL 3 2% SpGrl 11 Class I IB Combustible Liquid Incompatibilities and reactivities Measurement method (See Table 1) Strong ecids & oxidizers carbon tetrachloride 8 other chlorinated organic compounds carbon disulfide [Note Corrosive to metals ] XAD-2* DMF, HPLC/UVD IV [2540] Chemically active metals such as sodium potassium calcium hotalummum & magnesium liquid ammonia strong oxidizers Char Benzene/ Methanol GC/ECD IV 1*1008) Strong oxidizers & caustics, chemicafly- activemetals such aa magnesiumor aluminum powoer sodium 6 potassium liquid ammonia [Note Decompoeee to vinyl chloride & HO above 1112*F) Char GcfelO IV (81003 Haiogenated Hydrocarbons] Strong oxidizers chromium tnoxide potassium permanganate sodium peroxide [Note Hygroscopic (i e absorbs moisture from (he air)) OVS 7 Methanol GC/FID IV (#5523] Personal protection and samtaiion (See Table 3) Skm Eyes Waahskm Remove Change Provide Prevent skin contact Prevent eye contact When contam/Daily When wet (flamm) Daily Eyewash,>5%) Quick drench [Etftylenediamine| Skin Eyes Wash skin Remove Change Provide Prevent Sk n conlac1 P'eve ii eye contact 'When contam When wet or conlarr NR Eyewash Quick drench (Ethylene dibromide] SJdn Eyes Wash skm Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet (flamm) NR Eyewash Quick drench (Emylene dicnionde] S* n eyes Wash skm Remove Change Preve n skin contact prpvent eye contact When contam When wet oi contam Dany [Ethylene glycol] ABD00022861 Recommendations for respirator selection --maximum concentration for use |MUC) iSee Table 4) NIOSH/OSHA 250 ppm SA CFVPAPRS` 500 ppm CCRFS/GMFS/PAPRTS1' SCBAF/SAF 1000 ppm SAF PO PP SCBAF PD PP/SAF PD PP ASCHA Escape GMFSfSCBAt Route Symptoms (See Table 5) km Abs ing Con imt nose resp sy s sens derm asthma liver kidney damage Health hazards Firstatd See Table 6) Eye Swn Breath Swa'low Irr immad Water flush mmed Resp support Medical attention immed Target organs (See Table 5) Skin respays liver kidneys NIOSH * SCBAf PD PP'SAF PD PP ASC BA Escape GMFOV/SCBAE Inn Abs mg Con r nt e,ts sk n esi sys derm with vesic '.vei head spleer Kidney dan age rep o effects care] 1 /<? Skr Bre i'n "Wdl ow ' (timed Scat wash immed Rtsp supper* Medica1 atlen'ion mined hyCS Sm ' resp sys. live kith eys repro sys [viani'raiS sK n 4 lung tuTiorsj NOSH SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Wi imt eyas com opac Abs CNS dapres nau vomit Ing derm liver kidney Con CVS damage [care] fr,, Breath Swallow Irr immed Soap wash prompt Resp support Medical attention immed Eyes skin kidneys liver CNS CVS (in animals forestomach mammary gland & circulatory sys cancer] TBAL inh Ing Con irrt eyes skin nose tnroat nau vomit abdom pair weak dizz stupor convuls CNSdepres skin sens Eye Skir Bream Swallow Irr immed Water wash immed Resp support Medical attention immed Eyes Skin resp sys CNS Chemical name. structure/formuia, CAS and RTECS Nos and DOT ID and guide Nos Btiytorw glyd OjNOCHjCHjONOj 626-96-6 KW6600000 Synonyms, trade names, and conversion factors 138 Ethyieneimine C,H,N 151-56-4 KX5075000 Ethyhmrne 1185 131P{mhlbited) Aminoethylene Dimethylenermine Dimethylenimine Ethyienimine 1 ppm = 1 76 mg/m3 Ethylene thiourea CjHjNjS 96-45 7 NI9625000 1 3-Ethylene-2-ihiourea N N-Ethylenethiourea, ETU, 2-lmidazolidlrre-2 thione Exposure femfts (TWA unless noted otherwise) ABD00022862 DLH Physical description NOSH STO.In^/m1 |WBJ Wmgltn* Cotorteaa to yalow. My, odorioat Squid. [Note An *&> sive ingredient (6040ii)ln d3yfntvHnMbaoaSkTn . oertoe{4 NIOSH Ca See Appendix A OSHA[1910 1012] See Appendix B Ca Colorless UquiQ [100 ppm] with an ammonia like odor [Note Usually contains mhibitors to prevent polymerization 1 Chemical and physical properties MW. BP. SOL FI P, IP, Sp.Gr, VP, FRZ lUmmabMty UEL. LEL MW1G2.1 BP 3S7T titbwoluM P:419f IP-?` VP-006 mm FRZ. -8*F UEL? LEL? Bp, Or 14B CxpicdW Liquid MW 43 1 BP 133'F Sol Miscible FI P 12*F IP 9 20 eV VP 160mm FRZ 97*F UEL 54 8% LEL 3 3% Sp Gr 0 63 Class IB Flammable Liquid Incompatibilities and reactivities Measurement method (See Table 1) Add*, afcals TptmmOC, Ethanol; GC/ECD; IV [2S07J Polymerizes explosively in presence of acids [Note Explosive silver denvatives may be formed with silver alloys (e g silver solder)] Bub CHCI, HPLC/UVD IV [3514] ____ dfcT''1 " v'; ' i f -J-' *'|^ NIOSH Ca See Appendix A Use encapsulated form OSHA none Ca [ND] White to pale-green crystalline solid with a faint amine odor (Note Used as an accelerator In the cunng of polychloroprerte & other elastomers ] MW 102 2 BP 446-595'F Sol(86*F) 2% FI P 486'F IP 8 15eV VP 16mm MLT 392`F UEL ? LEL 7 Sp Gr 7 Combustible Solid aKwf onamn, chlorides dTKrt, mwilnumASn; [>qxMm of Iran 6l vlurn!i>um:waM > Acrolein 1 i* >4Vv Filter Water Vis IV [5011] Personal protection and sanitation (See Table 3} Skm FyeS Wash skm Remove Change Provide Prevent skm coniact Prevent eye contact When contain When wet (fammi Daily Quick drench [Ethylene glycol dimtrale] Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam/Daily When wet or contam Daily Eyewash Quick drench i'Etfv/eneimine| Skin Eyes Wash skin Remove Change Provide Prevent skm contact (iiq) Prevent eye contact (Iiq) When contam (Iiq) When wet (flamm) NR Quick drench (Iiq) [Ethylene oxide] Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam/Oaily When wet or contam Daily [Ethylene thiourea] ABD00022863 Recommendations for respirator selection -- maximum concentration for use (MUC) [See Table 4) NIOSH 1 mg/m3 SA* 2 5 mg/m3 SACF' 5 mg/m3 SAT CF7SCBAF/SAF 75 mg/m3 SAF PD PP SCBAF PD PP/SAF PD PPASCBA Escape GMFOVHiE/SCBAE Route Symptoms (See Table 5) Inh Abs ing Con Throb head dizz. nau vomit abdom pain hypotension flush palp angina methemo delirium CNS depres irnt skin m animals anemia liver kidney damage Health hazards First aid (See Table 6) Eye Skm Breath Swallow Irr immed Soap wash immed Resp support Medical attention immed Targetoroans (See Tame 5) Skin CVS blood liver kidney* NIOSH * SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Inn Abs ing Con rrtleyes skm nose throat nau vomit head dizz Dulm edema liver kidney damage eye burns skin sens [care] Eye Skin Breath Swallow irr immed Soap wash immed Resp support Medical attention immed Eyes skin resp sys liver kidneys [in animals lung & liver tumors] NIOSH 5 ppm GMFSVSCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFSf/SCBAE NIOSH * SCBAF PD PP/SAF PD PP ASCBA Escape GMFOVHiE/SCBAE Ing Oiq) Con Imteyes skin nose throat peculiar taste head nau vomit diarr dysp cyan pulm edema draw inco EKG abnor eye skin bums (llq or high vap cone), llq frostbite repro effects [care] mammals convuis liver kidney damage Inh Ing Con Irnt eyes in animals thickening of the skin goiter terato effects [care] Breath Swallow Irrimmed Resp support Medical attention immed (Iiq) liver CNS Mood (peritoneal cancer leukemia] Eye Breath Swallow Resp support Medical attention immed Eyes skin thyroid repro sys [mammals liver thyroid & lymphatic sys tumors] Personal protection and sanitation (See Table 3; Sun Eyes Wash skm Remcne Change Prevent skm contact Prevent eye contact NR When wet (Hamm) NR [Ethyl ether) Skm Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contain When wet (flamm/ NR (Ethyl formate] Stan Eyes Wash skm Remove Change Prevent stop contact Prevent eye contact Dally Wren wet or contam NR fEthyidene norbomene) Skm Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact Wien contam When wet (flamm] NR (Ethyl mercaptan) ABD00022865 Recommendations for respirator concentration for use (MUC) (See Table 4) Route Symptoms (See Tables) OSHA 1900 ppm CCROVVGMFOV/PAPROV*/ SA*/SCBAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Wi *ng Con Irrtt eyes, skin upper resp sys dizz drew head, excited narco nau vomit Health hazards First aid (See Table ) Target organ* (See Table i) % Breath SwaDow Itrtmmed Water wash prompt Reap support Medical attention Immed Eyes, skin, reap sys, NIOSH/OSHA ISOOppm SA CFL/PAPROVc/CCRFOV/ GMFOV/SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Inh Ing Con Imt eyes upper resp sys m animals narco Eye Stan Breath Swallow Irr immed Water flush immed Resp support Medical attention immed Eyes resp sys CNS TBAL Mi toft eyes, aMn, noee Aba throat, heed, cough, dysp J?S nau vomit, cfteaory Con tastechanges, chamtaaf pneu (espe *q), inanimals ftverkMney, urogenital In), bone manow effects 9 Breath SwaMmr to tmmed Soapwash fenmad &&rsa. Immed Eyes.skki reap aye. CNS, few, kidneys, ureganMsys, bone marrow NJOSH 5 ppm CCROV/SA 12 5 ppm SACF/PAPROV 25 ppm CCRFOV/GMFOV/SATCF/ PAPRTOV/SCBAF/SAF 500 ppm SA PD PP SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Inh Ing Con Imtmucmemb head nau inanimals inco weak liver kidney damage damage cyan narco Eye Skin Breath Swallow Irr immed Soap wash immed Resp support Medical attention immed Eyes resp sys, liver kidneys blood Chemical name, structura/formula, and DOT ID and guide Noa Synonyms, trade names, factors Ettyl after WC*. Oieftyf after. OMhyl ONkte, Eftar, Bhyldda Sohant after 140 , Ethyl formate CH,CH,OCHO 109-94-4 LQ8400000 1190 129 ' f ppm a.03 mgfln* Ethyl ester of formic aad Ethyl methanoate 1 ppm = 3 03 mg/m3 Ethyl mercaptan CHjCHjSH 75-08-1 K19625000 2383 130 EthanethW Ethyl sulfhydrate Mercaptoethene 1 ppm 2 54 mg/m1 Exposure Mb (TWA unless noted otherwise) NIOSH See Appendix O OSHAt 400 ppm (1200 mgrtn3) ABD00022864 Dm Physical description Chemical and physical properties MW. BP SOL FI P IP.Sp.Gr, flammability VP, FRZ UEL, LEL 1900 ppm [lOKLELj Colorless liquid witt a pungent sweetish odor [Nde. A gas above 94*F I MW- 74 1 BP 94*F Sol 8% FI P -49*F IP 9 53eV VP 440mm FRZ.-177*F UEL 36 0% LEL19% NIOSH/OSHA 100 ppm (300 mg/m3) 1500 ppm Colorless liquid with a fruity odor SpGr071 Class IA Flammable Liquid MW 74 1 BP 130*F Sol(64'F) 9% FI P -4*F IP 1081eV VP 200 mm FRZ 113*F UEL16 0% LEL 2 8% M08H CSppm $25 mg#*!*) "net* . NIOSH C 0 5 ppm (13 mg/m3) (15-minJ OSHAt C 10 ppm (25 mg/m3) SpGr 0 92 Class IB Flammable Liquid NO Cotorteas to while MW 1202 VP 4mm Squid with a BP 298*F FRZ.-112'F turpentine-wee Sol ? UEL? odor FLP^oer totr LEL? 500 ppm Colorless liquid with a strong skunk-like odor [Note A gas above 95'F ] SpGr 090 Clue 11 Combustible Liquid MW 62 1 BP 95*F Sol 07% FI P -55*F VP 442 mm FRZ -228*F UEL 180% LEL 2 8% SpGr 0 84 Class IA Flammable Liquid Incompatibilities and reactivities Measurement method (See Table f) Strong oxidizers halogens sulfur sulfur compounds (Note Tends to form explosive peroxides under influence of air and light} Char Ethyl acetatr GC/FID IV [#1610J Nitrates strong oxidizers alkalis & acids [Note Decompose* slowly in water to form ethyl alcohol and formic acid ] Char GCfrlD IV [#1452] Oxygen [Note- ENB should be storad In a nitrogen tmrropfMWdneeX reeds wltt oxygen ] Nona I'dbHe Strong oxidizers [Note Reacts violently with calcium hypochlorite) u ; sr v* Filter* HCI/DCE GC/FPD IV [#2542] Chemical name, etructure/formula, CAS and RTECSNoe. and DOT ID and guide Noe Synonyms, trade names and conversion factors N-EttiytmocphoUne C^ONCHjCH, 4-Ethytmorphokne Ethyl silicate (C^.SiO, 78-10-4 W94S0000 1292 132 Fdramlphoe C^HjjNO^S 22224-92*4 TBS474000 tpgm4.71mg#m Ethyl orthosftcate Ethyl erficate (conoenaed) Tetreethoxysilane Tetraethyl orthoeilicate Tetraethyl aibcate 1 ppm 8 52 mg/m5 etM S-mMhyM^melhytyfe)phany^1-me<h]^ NiyiJpnPVnOiVliMHt Nmiiri0. Exposure InSts (TWA unless noted otherwise) NOSH (skin) OSHAt 20 pom NIOSH 10 ppm (85 mg/ms) OSHAt 100 ppm (860 mg/m5) M06H Olmig/m* IsWnl OSHAt mne Fansultothion Ci.H.tO.PSj 115-90-2 TF3850000 Daaamt0 O-Otethyl 0-(p-methyl- *ulflnyl)phenyl>- phoaphorothioate TarracurP* ((C,HJ0^(S)OCtH<S(0)CHj NIOSH 0 1 mg/m5 OSHAt none ABD00022866 DLH Physical description 100 ppm Cdodesa liquid with an ammoniaUke odor Chemical and physical properties MW, BP, SOL FI P IP, Sp. Gr flammability VP. FRZ UEL, LEL MW1152 BP 281*F Sol Mledble FI P(oc) 90*F IP ? VP 6mm FRZ. -81 *F UEL ? LEL ? Incompatibilities and Strong acids strong oxidizers 700 ppm ND NO SpGr 090 Cleaa 1C Flammable Liquid Colorleea liquid with a sharp alcohol-like odor MW 208 3 BP 336*F Sol Reacts Fi p 99*F IP 9 77 eV VP 1 mm frz. nrp UEL t LEL ? Strong oxidizers water [Note Reacts with water to form a silicone adhesive (a milky-white mass) { SpGr 0 93 Class 1C Flammable Liquid Ottwhfte to ten. wexy sodd [fneeatfcide] [Note. Found commercially eee granular Ingradh ent(5-l6%)or ranemuWMrte eonoenMe (400 grt).] MW 3034 BP 7 Sorf 603% RP? IP 7 SpOrl 14 VP 000006 mm MLT 121V UEL 7 LEL 7 None reported conditions] Brown liquid or yellow oil {pesticide] MW 308 4 BP 7 Sol(77*F) 0 2% FIP ? IP ? VP ? FRZ 7 UEL 7 LEL ? Alkalis Sp Gr 1 20 Combustible Liquid Measurement method (See Table 1) Si gel 11(3) [9S146] XAD 2 GC$FID [lis^ea] OVS-2 Toluene/ Aoaame; GC/FIO, tv (#6400 Orgenophoaphorue reetfcideel None available Personal protection (See Table 3| Skin Eye* Wash skin Remove Change Provide Prevent skin contact Prevent eye contact Whenconlam When wet (fiamm) NR Eyewash(>15%) Quick drench IN Ethylmorphokne) Skin Eyes Wash skin Remove Change Prevent skm contact Prevent eye contact Whenconlam When wet (fiamm, NR [Ethyl silicate) Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact Wien contam/Oaity Wien wet or contain Daily Quick drench (Fenamiphosj Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet or contam NR Eyewash Quick drench [Fensutfothion) ABD00022867 Recommendations for respirator concentration for use (MUC) (See Table 4) NIOSH 50 ppm CCROV/SA* 100 ppm SA CF7PAPR0V/CCRF0V/ GMFOV/SCBAF/SAF SCBAF PD PP/SAF PD PPASCBA Escape GMFOV/SCBAE Route Symptoms (See Table 5) Inh IrrH eyes, noae throat; Aba via dial com edema Ing blue-gray vision, colored Con haloea Health hazards Flmtakt (Saa Table 6) Target organa (See Table 5) K Breath. Owafciw Irr tamed Watir flush prompt Reap support wnHi imM tamed Eyes, reap ays NIOSH 100 ppm SA 250 ppm SACF* 500 ppm SCBAF/SAF 700 ppm SAF PD PP SCBAF PD PP/SAF PO PP ASCBA Escape GMFOV/SCBAE mr> imteyes noae (ng in animals tac dysp Con pulm edema tremor narco liver kidney damage anema Eye Skn Breath Swallow lrr mimed Soap wash prompt Reap support Medical Mention firmed Eyes reap ays Eyes liver kidneys Wood stun TBAL TBAL Wi Nau vWsi.aBdotacrania, Aba Otar, aatr, heed, gtdd, 1C?on vertt, en; iMt, cnaat dk MunwtvMon, iwoal;canHrag;inuaG - _ ftac, dyap 5fc BvrMMr tamed BOOO GnOI - Abs Ing Con iml skin nau vomit abdom cramps diarr aalv head gidd vert) weak rhm chest tight Nutred vision miosis card ttreg muaetaac dyap Eye Skm Breath Swallow Irr immed Soap flush immed Reap support Medical attention immed Skin reap ays CNS CVS blood chol Chemical nama, structure/formula and DOT ID and guide Not Fanthion CH,0,PS 68-36- TF0626000 144 Ferbam 1(CHj)jNCSj1jF 14464-64 1 N06750000 Famwanadlum duet FaV 12804-M- LK2900000 Fibrous glass dusl LK3651000 Synonyms trade names, factors tsar O,O-0tme(hyT 0-3-methyF4melhyMhiflpjhenyf Exposure brtts (TWA unless noted otherwise) MOSH SaaAppandtxO 06HAf none ABD0Q022868 IDLH Physical description NO Colortsss to brown liquid with a slight garlic-1Ike [Insecticide] Chemical and physical properties MW, BP, SOL FI P, IP, Sp. Gr, flammability VP, FRZ UEL, LEL Incompatibilities and reactivities MW 278 3 BP ? Sol 0006% FIF NA IP ? VP 000003 mm Oxidizers FRZ. 43*F UEL NA LEL NA Measurement method (See Table 1) None available {ri*(Drmefhy*dithio carbamato)iron Feme dimethyl dithiocarbamate FatTovawdium Fiber giastt Fiberglass Glass fibers Glass wool (Note Usually produced from borotilicate & low alkali silicate glasses ] NIOSH 10 mg/m3 OSHAt 15mg/m3 600 mg/mi Dark brown to black odorless solid [fungicide] MOSH* 800 mg/m* Img/m* STSmo/m3 [Nole The REL also applies to Vanadium metalandVanadium carbide] OSHAt Imgftrt* Dark, odorteaa particulate dmpereed in air [Note Ferrovanadksn metal le an ahoy uaually contain ing 9D60H vanadium] NIOSH 3 fibers/cm3 (fibers s 3 5 pm in diameter & i 10 pm in length) S mg/m3 (total) NO OSHA 15 mg/m3 (total) 5 mg/m3 (reap) Typically glass filaments >3 pm in diameter or glass wool with diameters down to 0 05pm&>1 pm in length Sp.Grl 25 Noncombuatibie Liquid MW 4165 BP Decomposes Sol 001% FI P ? IP 7 72 eV VP 0 mm (approx) MLT >356*F (Decomposes) UEL ' LEL 7 MEC 55 g/m3 Strong oxidizers moisture SpGr ' Combustible Solid Filler none Grav IV 1*0500 Particulates NOR (total)) MW 106 6 VP 0 mm BP ? (approx) Sol Insoluble MLT 2686- FIP NA 2766*F IP NA UEL NA LEL.NA MEC 1 3 g/m1 Sp.Gr ? Metal Noncombuatibie Solid, but dust may be an explosion hazard Strongosddtzar*Filter Acid, FAAS OSHA MD121 #101250] MW NA 8P NA Sol Insoluble FI P NA IP NA VP 0 mm (approx) MLT ? UEL NA LEL NA Sp Gr 2 5 Noncombustible fibers None reported Filter none PCM IV [7400 Asbestos and Other Fibers] Personal protection and sanitation iSee Table 3) Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact Whencontam When wet or contain Daily (Fenthton) Skin Eyes Wash skin Remove Change Prevent skm contact Prevent eye contact When contain When wet or contam daily i- erbur, Skin Eyes Weshskm Remove Change NR NR NR NR NR (Ferrovanadium dust] Skin Eyes Wash SKin Remove Change P eve i* sum contact Preveni eye con'act daily NR Daily [Fibrous glass oust] ABD00022869 Recommendations for respirator selection -- maximum concentration for use (MUCj (See Table 4) Route Symptoms (See Table 5) TBAL mn ADS Ing Con Nau vomit abdom cramps dian, salv head gidd vert weak rhm chest tight blurred vision miosis card irregularities muse fasc dyep Health hazards First aid (See Table 6) l Breath Swallow- In immed Soap flush immed Resp support Medical attention rimed Target organs (See Table 5) Resp ays CNS, CVS ptaamachol NlOSr 50 mg/m o 100 mg rrJ DXSO 'Hit 'SA 250 mg/m SACF/PAPRD 500 mg m' HiEF/SAT CF 'PAPRThiE < SCBAF'SAF 800 mg/m' SAP PO PP SCBAF PD PPfSAF PD PP ASCBA Escape HiEP/SCBAfc ml frit eyes esp ,f2J jem Gi dis ^Of NIOSMOSHA 5 mg/m1 DM* 10 mg/m1 DMXSQVSA* 25 mg/m1 SA.CF7PAPRDM' . 50 mg/m1 HIEF/SAT CF/PAPRTHiEV SCBAF/SAF 500 mg/m1 SAF PD PP SCBAF PD PP/SAF PO PP ASCBA Escape HIEF/SCBAE Irh imt eyes reaptys Con in animals bron pneuitls NIOSH 5XREL 0 10XREL DXSQ/HiE/SA 25X REL SACF/PAPRD 50X REL HiEF/PAPRTHiE/SCBAF/SAF 1000XREI SAF PD PP SCBAF r>D PP/SAF PO PP ASCBA Escape riiEF/SCBAE inr inn eyes skm nose Con throat dysp fcye Skm B ea'h Swanow rr irnn ed Soap wash pror p' Resp suppor* Meoica attention immed Eyes SHin resp s/s Gi act Eye Breath Irr Immed Reap support Eyes resp sys Eye Breath irr immed Fresh air Eyes skm resp sys Chemical nama, structure/formula, CAS and RTEC3Noa. and 00T ID and guide Noa Synonyms, trade names, and conversion factors '> ". 4 Swfc* Exposure (TWA unless noted otherwise) ABD00022870 IDLH Physical description 2*ppm r. Pels vslow to greeriehoaawRh InSSnSodto .* 146 Fluoratnchloromethane CClf 75-69-4 PB6125000 Freon* 11 Monofluorolnchloromethane Refrigsrant 11 Tncmorofluoromethene TncMoremonofluoromethane NIOSH C 1000 ppm (5600 mg/m3) OSHAt 1000 ppm (5600 mg/m3) 1 ppm * 5 62 mg/m3 2000 ppm Coiortess to water white nearly odorless liquid or gas (above75*F) Chemical and physical properties MW, BP, SOL FIP.IP.Sp.Gr, flarnmaMRy VP FRZ UEL, LEL Incompatibilities and reactivities Measurement method (See Table 1) MV* 300 BP--S07T VP-Hetot FRZ *3S3*F WMsr, ntoteadd, oiddtosre. organ* Mem svaHstti SofcReeett FLP-NA UELKA LELNA compounds (Note Resetsvioienttywith a# IP t&70V combustible matortoto, swept Ihs metal conMnsre In which It Is shipped Resets wHh HjO to torn hydrofluoric add.) MMfcUt NondenswabtsOes. but an extremely seongotodttsr MW 137 4 VP 690 mm SP ?5*F FRZ 168*F Soi(75*F) UEL NA 01% LEL NA FI P NA IP 11 77 eV Sp Qr 1 47 (liquid at 75'F) RGasD 4 74 Noncombustible Liquid Nonflammable Gas Chemically active metals such as sodium potassium calcium powdered aluminum zinc magnesium & lithium shavings granular banum Char cs. GC7FI0 IV [#1006 Trichloro fluoro methane) ctpyxb**, kSJSSw. Fonofos CH15OPSj 944-22-9 TA5950000 Dyfonate* Dyphonate O-Ethyl-S-phenyi ethyL phosphorothioate Fonophos 1 ppm 10 07 mg/m3 NIOSH 0 1 mg/m3 (skin) OSHAT none j/ ,, snesthetfc} I 6P-1MT sol-? RPC? FRZ. ? UEL.? LEL? "rv* NO Sjjfcflk* <& <: *<- to* IBBSLim Men** EXPLOSIVE!]. Light-yellow liquid with an aromatic odor (insecticide) MW 246 3 BP 7 Soi 0 001% FIP 201*F IP 7 VP(77*F) 0 0002 mm FRZ 7 UEL ? LEL ? None reported SpGrl 15 Cla& me Combuatibfc Liquid SvMsbiS OVS 2 Toluene/ Acetone GC/FPD IV (#5600 Organophosphonjs Pesticides] Personal protection and sanitation ( See Table 3) Skin Eyes Wash skin Remove Change Provide Prevent skin contact (liq) Prevent eye contact When contam (tiq) When wet or contam (kq) NR Eyewash (liq), Quick drench (liq) [Fluorine] Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact NR When wet or contam NR Eyewash Quick drench [Fluorotnchloromethane] Sion em Wash skin Remove Change NR Prevent aye contact NR NR NR ABD00022871 Recommendations tor respirator selection -- maximum concentration for use |MUC i (See Table 4) RoutP Symptoms (See Table 5) NIOSH/OSHA 1 ppm SA' 2 5 ppm SA CF' 5 ppm SCBAF/SAF 25 ppm SAF PD PP SCBAF PD PP/SAF PD PP ASCBA Escape QMFSVSCBAE Inh Con Imteyes nose respsys, lar spasm bron spasm puimedems eye skinbums mammals liver kidney damage Health hazards First aid (See Table 6| S Breath Irrimmed Water flush immed Reap support Target organs (See Table 5) Eyes skin respsys liver kidneys NIOSH/OSHA 2000 ppm SA/SCBAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Inh Ing Con Inco tremor derm card arrhy card arrest asphy liq frostbite Eye Skin Breath Swallow Irr immed Water flush immed Resp support Medical attention immed Skin resp sys CVS TBAL Inh Irht eyes, CNS dapres i!>a analgesia, anee sez. Con reap depres & Breath Swattow Irr immed Soap wash Reap support Medtcai attention armed Eyes CNS 147 [Fluroxene] Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet or contam Daily Eyewash Quickdrench (Fonofos] TBAL Inh ADS Ing Con Nau vomit abdom cramps diarr saiv head gidd verti weak rhin chest tight blurred vision miosis card irreg muse fasc dysp Eye Skin Breath Swallow Irr immed Soap flush immed Resp support Medical attention immed Respsys CNS CVS blood chol 148 Chemical name, tmetura/forntuia, CAS and RTECSNos, and DOT ID and guide Noe Synonyms, trade names, and conversion factors rnmelrtehyrte HCHO MM SSS&O Mettftdne om* V* , lppmi JOrnsMt* Et^oeure (TWA unless noted otherwise) ARnnnn??87? DLH Physical description woeH Bs.'sr*'* Ca E mi ssaer OSHAJ19101046} ' 075 ppm ST 2 ppm nfW- m- -ff---c--o -niit-f-* gwedhapurynt. lUnDGRVIO OQQl (Note OAen used manaqueous ciulton (see specific eating for FormaMn)) Chemical and physical properties MW, BP. SOL FI P, IP, Sp, Gr. ftammabMty VP, FRZ UEL, LEL MW 30.0 BP-TF Sot MUMS FtP-MA (Gat) IP' 10 88 aV VP>1S FRS-134T UEL 73% LEL 70% RGSSO104 Flammable Gaa IncompatibHMes and leectMtiee Measurement method (See Table 1) Strong oddiaere, MMto&aoids, phenols, urae (Nota: Pure formaidehydehae wti^HCito tom btihchtoramethyl ethar] FHMlMWttl none; Vie, snu Formalin (as formaldehyde) 1198 132 2209 132 Formaldehyde solution [Note Formalin is an aqueous solution that is 37% formaldehyde by weight inhibited solutions contain 6-12% methyl alcohol Also see specific listings for Formaldehyde and Methyl alcohol) NIOSH Ca See Appendix A 0 016 ppm C01 ppm [15-minJ Ca (20 ppm] OSHA[1910 1048] 0 75 ppm ST 2 ppm Colorless liquid with a pungent odor MW Vanes BP 214*F Sol Misable FI P 185*F IP ? VP 1 mm FRZ 7 UEL 73% LEL7% Sp Gr 1 06 Class ItIA Combustible Liquid Strong oxidizers alkalis & acids phenols urea oxides isocyanates caustics anhydrides Filter/lmp(2) none Vis IV [#3500] [Also #2541] Fonwanide HCONHj Ts-ia-r LOQftWMP SKSSSe s NOjH fiSr1 .v' 7'-r> '- OEMAf -none 7 HA ' CrtBHui. <% SfWi MW 46.1 8P411T (Decomposes) Sot: Mtoetoto FtP(o<310*F IP 103j eV VP(B6Tfc 01 nan FRZ 37*F UEL. 7 IEL1 Sp.Gr113 Ctaes MB Combustible Uqtdd Qxldbaie, iodine, Mrtdbte, suitor etwdrtoi capper, braes, INQM, le"nayd-o--n-M----pi--* (la. abaorbe meiatum from the*)] Hcm avetiehli Formic sad HCOOH 64-18-6 LQ4900000 1779 153 Formic aad (85-95% in aqueous solution) Hydrogen carboxylic aad Metherioic sad 1 ppm * 1 88 mg/m5 NIOSH/OSHA 5 ppm (9 mg/m5) 30 ppm Coiortess hquid with a pungent penetrating odor [Note Often used man aqueous solution ] MW 460 BP 224'F (90% soln } Sol Miscible FIP(oc) 122*F (90% soln) IP 11 05 eV VP 35 mm FRZ 20*F (90% soln) UEL 57% (90% Sdn) LEL 18% (90% soln) Strong oxidizers strong caustics concentrated sulfuric acid [Note Corrosive to metals ] Sp Gr 1 22 (90% solution) Class II Combustible Liquid (90% solution) Si gel* Water 1C IV (#2011] Personal protection (See Table 3) Sot Eyaa. Wash stun Remove Change NR Prevent eye contact NR NR NR [Formaldehyde] Skm Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet or contam NR Eyewash Quick drench [Formalin (as formaldehyde)] SUn Wash skin Remove Chengs. NR Prevent eye contact NR NR NR (Formanude] Skm Eyes Wash skm Remove Change Provide Prevent skin contact Prevent eye contact When contam Wien wet or contain NR Eyewash Quickdrench (Formic acid] ABD00022873 Recommendations tor respirator concentration for use (MUC) (See Table 4) Route Symptoms (See Table S) NIOSH * SCBAF PD PP/SAF PD PP ASCBA Escape GMFS/SCBAE Inh Irrtt eyas nose throat Con reap sys lac cough bron spasm [care] Health hazards First aid (See Table 6) Eye Breath irr immed Reap support Target organs (See Table 6} Eyaa, reap ay* [natal cancer] NIOSH SCBAF PD PP/SAI PD PP ASCBA Escape GMFS/SCBAE Inh ing Con uni pyes nose throat lespsys lac ough uron spasm derm [care] Fye Skin Breath Swallow Irr immed Water flush prompt Resp support Medical attention immed Eyes skin resp sys [nasal cancer] 149 TBAL Wi Irrtteye*, skin, muc memb jjo Con drew Bg* nau addot* Skm trupUona, in animate rapro affect* m, Breath SweMow lir immed Water wash Reap support Mn3c4anSDn tamed Eyaa, akin, napays, CHS raproaya NIOSH/OSHA 30 ppm SA'/SCBAF SCBAF PO PP/SAF PO PP ASCBA Escape GMFOVHiE/SCBAE mn irnt eyes skin throat Ing skin burns derm lac Con rtun cough dysp nau Eye Skm Breath Swallow Irr immed Water flush immed Resp support Medical attention mned Eyes skin resp sys 150 Chemical name, structure/formula, CAS and RTECS Not, andOOTIO and guide Not Synonyms, trade name*, and conversion factors Exposure Bote (TWA unless noted otherwise) Furfural <W> W-OM LT7000000 furat, 2-furancartoxaMehyds Furturaidehyde, 2-Furfuroidehyde NiOSH See Appendix D OSHAt 5ppm (20 malm5) (skin) 1186 132P 1 ppm 8 88 mgAn9 Furfuryl alcohol 98 00 0 LU9100000 2 Furylmethanol 2 Hydroxymethytfuran NIOSH 10 ppm (40 mg/m5) ST 15 ppm (60 mg/m5) (skin) 2874 153 1 ppm =4 01 mg/m5 OSHAt 50 ppm (200 mg/m5) 0--mna 8008-81-6 LX3300000 1208 128 Oermamum tetrahydnde GeH, 7762-85 2 LY4900000 2192 119 Motor fuel. Motor epMe. Natural paiolno, Petrol [Note; A oomptexmbdur* of voMBe hywoaerbena KS3uT*~*~ NIOSH Ca See Appendix A OSHAt none _1 ppm I9*m0hi*<p8iwto r Germane German*jm hydnde Garmanomethane Monogermane (Note Used chiefly for the production of high punty germanium for use in semiconductors ] NIOSH 02 ppm (0 8 mg/m5) OSHAt none 1 ppm = 3 13mg/m5 ABD00022874 DLH Physical description 100 ppm Colorless to amber liquid with an almond-like odor [Note Darkens m light and air) Chemical and phyalcal properties MW, BP, SOL FI P, IP, Sp.Gr, flammabHtty VP, FRZ UEL. LEL MW 981 BP 323*F Sot 0* FI P- 140*F IP 9 21 eV VP 2mm FRZ -34*F UEL 19 3% LEL21% 75 ppm Colorless to amber liquid with a faint Burning odor [Note Darkens on exposure to light ] Sp.Grl 16 date IliA CombueUWe Liquid MW 98 1 BP 338*F Sol Miscible FI P 149*F IP 7 VP(77*F) 0 6 mm FRZ 6 F UEL 163% LEL 1 8% Incompatibilities and reactivities Measurement method (See Table 1) Strong acids oxidizers, strong alkafis [Note May polymerize on contact with strong acids or strong akahs ] XAD-2*. Toluene GC/FID, IV [62629] Strong oxidizers 6 acids [Note Contact with organic acids may lead to polymerization) Porapak Q Acetone GC/FID IV [#2505} Ca (NO) Clear Hquld wth e chareotertede odor SpGrl 13 Class IMA Combustible Liquid Sot insoluble np -48*f IP-7 VP- 38-800 mm FRZ. 7 UEL 7 6% LEL14% Strong oxidiBere auehatparaddee nltitcecid& perchlorates Nona avMebls Claee IB Flammable Liquid - NO Colorleae gee with MW 76 6 VP >1 atm Bromine a pungent odor BP 127*F FRZ 267`F [Note Shipped ae Sol Insoluble UEL ? a compressed FI P NA (Gas) LEL 7 gas ] IP 11 34 eV RGesD 2 65 Flammable Gas (may Ignite SPONTANEOUSLY in air) None available Personal protection and sanitation iSee Table 3i Skm Eyes Wash skm Remove Change Prevent skm contact Prevent eye contact When contam When wet or contam NR {Furfural] Skin Eyes Wash skin Remove Change Provide Prevent skm contact Prevent eye contact When -onta n When wet or contam NR Qu ckdrench [Furfury1 aicchni Skm Eyes Wash skin Remove Change Provide Prevent skin contact F'revent eye contact When contam When wet (flamm) NR Eyewash Quick drench (Gasoline] Skin Eyes Wash Skin Remove Cnange NR NP NR NR NR [Germanium te'rahydnde] ABD00022875 Recommendations tor respirator selection -- maximum concentration for use (MUCi (See Table 4) Route Symptoms (See Table 5) OSHA 50 ppm CCROVVSA* lOOppm SA CFVCCRFOV/PAPROV*/ GMFOV/SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Irh Jrrrl eyes skin upper Aos respsys head derm log Con Me nth na/arns First aid i See Table 6) Target organs (See Table 5) Eye Skin Breath Swallow- Immrned Water flush prompt Rasp support Medical attention nmed Eyes, akin, reap ays NlOSH/OSHA 75 ppm CCROV iGMFOV/PAPROV SA /SCBAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE inh ADS Ing Con irnteye* mucmemD dizz nau diarr diuresis resp oody temperature depres vomi derm Eye Skm Breath Swallow Irr immed Water flush immed Resp support Medical attention immed Eyes skin resp sys CNS NKJSH SCBAF PD PP/SAF PD,PP ASCBA Escape GMFOV/SCBAE tah Imteyas, skin, muc memb Abs derm head fig blurred Ing vision dizz slurred Con speech conf convuls chemical pneu (aeprr) possible Uver kidney damage, [cvc] iu Breath Swallow- Irr immed Soap flush immed Reap support Medical attention (Timed Eyes, Won reap ays CNS liver kidneys (In animals liver 4 kidney cancer] TBAL inr Mai nead gidd fainting Oysp nau vomit Kidney mj hemolytic effects 8reatn Resp support CNS kidneys blood Chemical name structure/formula CAS and RTECSNos and DOT 10 and guide Noe Synonyms trade names, and conversion factors GlutMdehyde OCH(CH^CHO 111-30* MA2490000 Glutanc dialdehyde 1 SPentanedMI 152 Glycenn (mist) HOCHjCH(OH)CHjOH 5*61 5 MA6050000 1 ppm 4 0 mg/m* Gtycenn (anhydrous) Glycerol Glyeyi alcohol 1 2 3-Propanetriol Tnhydroxypropane Olyddol CAP, 566-62-5 UB437S00D Glycolonitrile HOCHjCN 107 16-4 AM0350000 2,3-Epoxy-l-propanoi Hydroxymethyl ethylene oxide 2-HydfQKymetfiyl radran 3-Hydroxypropylene oxide 1 ppm 3 03 mg/m5 Cyanomethanol Formaldehyde cyanohydnn Glycolic nitnle Glyconnnie Hydroxyecetonitnle 1 ppm - 2 34 mg/m3 Exposure Mts unless noted otherwise) NOSH C 02 pom (0 0 rrigfm5) See Appendix C (Aldehydes) OSHAt none NOSH See Appendix D OSHAT 15mg/m3 (total) 5 mg/m3 (resp) NOSH 25 ppm (75 mg/m3) OSHAf (leSmgfrn1) NIOSH C 2 ppm (5 mg/mJ) (15-min) OSHA none ARDQQQ22876 IDLH Physical description Chemical and physical properties MW, BP SOL FI P, IP, Sp, Gr, flammability VP FRZ UEL LEL ND Coloriess iiqutd MW 100 1 VP 17mm with a pungent odor BP 212*F FRZ 7*F Sol Miscible UEL NA FI P NA LEL NA IP ? NO 150 ppm SpGrl 10 Noncombusbble Liquid Clear colorless odorless syrupy liquid or solid (below 64*F) [Note The solid form melts above 64*F but the liq uid form freezes at a much lower temperature ] MW 92 1 BP 554*F (Decomposes) Sol Miscible FI P 320*F IP 7 VP(122"F) 0 003 mm MLT 64*F UEL ' LEL 7 Sp Gr 1 26 Class IHB Combustible Liquid Colorless liquid MW-741 BP 320*F (Decomposes) Sol Miecibie FI P 162*F IP 7 VP(77*F): 0 9 mm FRZ -49*F UEL? LEL? SpGrl 12 Class IIIA Combustible Liquid N D Colorless odorless MW 57 1 VP(145'F) oily liquid BP 361'F 1mm [Note Forms (Decomposes) FRZ < 98'F cyanide in the Sol Soluble UEL 7 body ] FIP 7 LEL 7 IP 7 SpGr<66 F) 1 10 Combustible Liquid Incompatibilities and reactivities Measurement method (See Table 1) Strong oxidizers Sit gel* strong bases Acetonitnie [Note Alkaline HPLCAJV solutions of IV glutaraldehyde [92532) (ie, activated glutsrekiehyde) react with alcohol ketones amines, hydrazines & proteins ] Strong oxidizers (e g chromium tnoxide Filter none potassium chlorate Grav potassium perman IV ganate) [Particulates (Note Hygroscopic NOR (i e absorbs moisture #0500 from the air) ] (total) #0600 (rasp)) Strong oxidizers nitrates Char THF GC/FID IV [91606] Traces of alkalis (promote violent polymerization) None available Personal protection and sanitation (See Table 3i Skin Eyes Wash sk n Remove Change Provide Prevent skin contact prevent eye contact Wnen contam When .vet or contam NR t-yewas" Jmckdrench [Glutaraidenyde] Skin Eyes Wash skin Remove Change NR NR NR >v R NR 'Giyce n mo, Skin Eyes Wash skm Remove Change Prevent skm contact Prevent eye contact When contam When wet or contam NR [Glycidol] Skm Eyes Wash skm Remove Change Provide Prevent skin contact P event eye contact When contam When wet or contam Daily Eyewash Quick drencn [Giycolonitrile] ABD00022877 Recommendations for respirator selection - maximum concentration for use (MUC) (See Table 4| Route Symptoms (See Table 5) T BA Inh ADS ing Con Irnt eyes skm resp sys derm sens sk.n oough asthma nau vomi* Health hazards First aid iSee Table 6) Target organs (See Table 5) Eye Skin Breath Swa low lr' immed Water flush immed Resp support Medical attention immed Eyes skm resp sys THAI inn Con rnt eyes skm rest, s>s oau vomii m Eye Ski B edit rr mmed Water wash F'esh dir Eyes skm resp sys idne/s 153 NIOSH 150 ppm SA /SCBAF SCBAh PO PP/SAF PD PPASCBA Escape GMFOV/SCBAE Ml Ing Con Imteyes skin nose throat narco iTn Breath Swallow t rr immed Water wash prompt Resp support Medical attention immed Eyes skin resp sys CNS NIOSH 20 ppm SA 50 ppm SA CF 100 ppm SC8AF/SAF 250 ppm SAF PD PP b SCBAF PD PP/SAF PD PPASCBA Escape GMFOV/SCBAE inh Abs Ing Con irnt eyes skm resp sys head dizz weak gidd conf eonvuls dysp abdom pain nau vomit Eye Skin Breath Swallow Irr immed Water wash immed Resp support Medical attention immed Eyes skm resp sys CNS CVS Chemical name, etructure/formula CAS and RTECSNos. and DOT ID and guide Nos Synonyms trade names and conversion factors Exposure imits (TWA unless noted otherwise) Oram duet (oat, wheat, barley) MD7900000 None (Note Gram dust consists of 60-75% organic materials (cereal grains) & 25-40% Inorganic materials (soil) and includes fertilizers pesticides ft microorganisms) NIOSH 4 mg/m5 OSHA lOmg/m3 ABD00022878 IDLH Physical descnptlon ND Mixture of gram and all the other substances asso ciated with its cultivation & harvesting Chemical and physical properties MW, BP, SOL FI P, IP, Sp, Gr, flammability VP.FRZ UEL.LEL Properties depend upon the specific component of the grain dust Incompatibilities and reactivities Measurement method (See Table 1) None reported Filter none Grav IV [0500 Particulates NOR <to(f)j 154 Graphite (natural) C 7782-42 5 MD9659600 Black lead Mineral carbon Plumbago Silver graphite Stove black [Note Also see specific listing for Graphite (synthetic)) NIOSH 2 5 mg/m3 (resp) OSHAt 15 mppcf 1250 mg/m3 Sleel gray to Mack greasy feeling odorless solid Graphite (synthetic) C 7440-44-0 FFS250100 Activated carbon [Note Aleo eee specific kstlng for Graphite (natural)] 1382 133 (cartoon activated) Gypsum CsS04*2Hj0 13397-24-5 MG2360000 Caicium(ll) sulfate dihydrale Gypsum stone Hydrated calcium sulfate Mineral white [Note Gypsum is the dihydrale form of calcium sulfate Plaster of Pans is the hemihydrale form ] NIOSH See Appendix D OSHAt ISmc^m3 (total) 5mgAn3 (resp) ND NIOSH 10 mg/m3 (total) 5 mg/m3 OSHA 15 mg/m3 (total) 5 mg/m3 (resp) ND Steel gray to black, greasy foaling odorless solid White or nearly white odorless crystalline solid MW 12 0 BP Sublimes Sol Insoluble Fl P NA IP NA VP 0 mm (approx) MLT 6602*F (Sublimes) UEl NA LEL NA Sp Gr 2 0-2 25 Combustible Solid Very strong oxidizers such as fluonne chlorine tnfluonde & potassium peroxide Filter none Grav IV [Particulates NOR 0500 (total) #0600 (reap)) flill- sW_sJ MW 120 BP Sublimes Sol Insoluble FI P- NA IP NA Sp Gr 15-1 d Combustible Solid Very strong oxidizers sucn as fluorine chtortne trifluoride ft potassium peroxide Filter none. Grav IV [Partieulatee NOR a0500 (reap)) | MW 172 2 BP 7 $ol(77*F) 0 2% FI P NA IP NA VP 0 mm (approx) MLT 262 325 F (Loses H,0) UEL NA LEL NA Aluminum (at high temperatures) diazomethane Sp Gr 2 32 Noncombuslible Solid Filter none Grav IV [Particulates NOR 0500 (total) #0600 (resp)) Personal protection and sanitation (See Table 3i Skin Eyes Wash skin Remove Change NR NR NR NR Daily [Gram dust (oal wheat barley)] Eyes Wash skin Remove Change \H NR NR NR ,Graphite inaturai'] Skin Eye* Wash skin Remove Change NR NR NR NR NR [Graphite (synthetic)] Skin Eyes Wash skin Remove Change NR NR NR NR [Gypsum] ABD00022879 Recommendations for respirator selection maximum concentration for use (MUC (See Table 4) Route Symptoms (See Tabls 5i TBAl inh Con mi eyes sK<n upper resp sys cough dysp wheez asthma bron chronic obstructive pulm disease con] derm rhinitis gram fever H\ UtP t>6i Aids First aid iSee Table S| Eye Biea'n irr immed Fresh air Target organs (See Table 5) Eyes skin resp sys NIOSH 12 5 mgim D 25 mg,m DXSQ/SA 62 5 mg/mJ PAPRD'SA CF 125mg/m3 HifcF/PAPRTHiE'SAT CF SCBAF SAF 1250 mg/m 1 SAF PU PP SC8AF PD PP'SAF PD PP ASCBA Escape HiEF/SCBAE T8AL Inh Cough dysp black Coi sputum Oecr po>n 1-nc u'-g fib inh Cough dysp black Con sputum deer pulm func lung fib cye Breath Immmed Fresh air Eye Breath Irr imroed Fresh air Resp sys CVS Resp sys CVS 155 TBAL Inh Irnteyes skin muememb Cor upper resp sys cough sneez Eye Breath irr immefl Fresh air Eyes skin resp sys Chemical name, atructura/foimgta, CAS and RTECS Not, and DOT iD and guide No* Synonym*, trade names. factor* HtfAan Hf 7440-56-6 UO40OOOOO ElementalloMum, iMttanmeM 156 8KBS&# Hdothane CF.CHBrCI * 151-67-7 KH6550000 1 Bromo-1-chloro-2 2 2 tnfluoroethane 2-Bromo-2-chloro-1 1 1 tnfluoroethane 111 Tnfluoro-2-bromo2-chloroethane 2 2 2-Trifluoro-1-bromo 1-chioroethane 1 ppm = 8 07 mg/m5 w 76-44-8 PCW0t?00^ Z7B1 WjagnccWcrtw|wetMde. ecfld) n-Heptane CHJCHJjCHj 142-82 5 MI7700000 Heptane normal-Heptane 1206 128 1 ppm * 4 10mg/m5 Exjjoaure (TWA unless noted otherwise) ABD00022880 DLH Physical description MO8HV0SHA* 0 5 mo*n5 9(m0 mmg/m1 [Note The REL and PEL also apply toetherhafnhsn compound* (ae Hf),} Highly lustrous, ductie grayiah sobd Chemical and physical properties MW. BP. SOL FI P, IP, Sp, Gr, flammaMMy VP, FRZ UEL.LEL Incompatibilities and reactivities MW 178 9 8P-8316*F Sol tnedubte FIP-NA IP NA VP-Omm Jrssii U6L.HA ia.NA Stiong oxidlaef*. chlorine Sp.Gr 13.31 Exptoalwin portlerAwn (sM)* 'tirycrwtth<36%wMiO: " byaMe Measurement method (SeeTabtel) Fitter Add. PE WS) {#8164] NIOSH* ND C 2 ppm (16 2 mg/rn1) 160-mini (`Note REl for exposure to waste anesthetic gas ] OSHA none -MOttt l*WnT ta*' >!< Av r V Clear colorless liquid with a sweetish pleasant odor [inhalation anesthetic) [Note May tie stabilized with 0 01%thymol] MW 197 4 BP 122`F Sol 0 3% FI P NA IP ? VP 243 mm FRZ 10O*F UEL NA LEL NA Sp Gr 1 87 Noncombustible Liquid wr ^jyjjwa ,/ V May attack rubber & some plastics sensitive to light Char(2) gcJfid OSHA 1*29) ttOO.IUBt m NIOSH 85 ppm (350 mg/m5) C 440 ppm (1800 mg/m5) [15-mm] OSHAT 500 ppm (2000 mg/m5) 750 ppm Colorless liquid with a gasotme- like odor iwyb* y<eritofMiwi!<|l^d#| ' -*k MW 100 2 BP 209`F Sol 0 0003% FI P 25`F IP 9 90 eV VP(72*F) 40 mm FRZ -131*F UEL 6 7% LEL 105% SpGr 0 68 Class IB Flammable Liquid Strong oxidizers Char GcfrlD IV [1500 Hydro carbons] Personal protection and sanitation iSee Table 3i Shut Ey Wash skm Remove Change Provide Prevent skm contact Prevent eye contact When contanvDaily When wet or conlam De.ty Eyewash Qutckdrench ft-Mvum] ikm Eyes Wash skm Remove Change Provide Prevent skm contact Prevent eye contact When ,,ontam Wher wet or con am NR Eyewash (Haiothane] SUn. uSehsMn Remove Chna. Provide Prevent skm contact Prevent eye contact When oontam/Dafly When wetoroortam Oaky Eyewash Quk* drench (Wept***>4 Skm Eye* Waah skin Remove Change Prevent skin contact Prevent eye contact Whencootam When wet (flamm) NR [n-Heptane] ABD00022881 Recommend a lions for respirator selection -- maximum concentration for use (MUC) (See Tab's NIOSH/OSHA 2 5 mg/m1 OM 5 mg/m1 DMXSQ/SA 12 5 mg/m* SA CF*/PAPROM* 25 mg/m1 HiEF/SAT CFVPAPRTHiE / SCBAF/SAF 50 mg/m1 SAF PD PP 5 SCBAF PD PP/SAF PD PP ASCBA Escape H<EF/SCBA Rout Symptoms (See Tab's 5) inh in animals irrrt eyes log skm mucmemb liver Con damage rpAi Ans log uijn irr t eyes sk n rest- s/S . nt clrow OiZ2 nav analgesia anes card army liver Kidney lamage deer auoio viSoai performance m animals repro effecis Health no .turds Firstaid (Sin 1 able fct Target organs tSee Table SI i Breath Swallow Irr immed Soap wash prompt Resp support Medical attention snmed Eyes skin muc memb liver Eye cskin Srealh Swailow In rm )<h Soap wash promp Resp s ipport Medical attentioi immed f-yes skin resp jts LVS CN^ ive kidneys iepro sys 157 NOSH . SCBAF PD PP/SAF PO,PPASCBA Escape GMFOVHiE/SCBAE hh In animals tremor Abs cortvuts Ivordamage lC?o8n (cere] S Breath Swallow Irr tinned Soapwesh Immed Reap support Medical attention tmad CNS fcver (manrmels Over cancer] NOSH 750 ppm CCROV/GMFOV/PAPROV/ SA/SCBAF SCBAF PD PP/SAF PO PP ASCBA Escape GMFOV/SCBAE tt\ L> head gtdd stupor vent Ing tnco loss of appetite nau Con derm chemical pneu (aspir liq] uncon Eye Skirt Breath Swallow Irr immed Soap wash prompt Resp support Medical attention turned Skin resp sys CNS Chemical name, structure/formula, CAS and RTECS Nos and OOTID and guide Nos Synonyms trade names and conversion factors 1-Haptonathrol CHJCHjlgSH 1939-00-4 MJ1400000 Heptyl mercaptan n-Heptyt mercaptan 158 1228 181 Hexachlorobutediene CljCCCICCI=CCIj 87 68-3 EJ0700000 1 ppm 5 41 mg/m3 HCB0 Hexachloro-1 3-butadiene 1 3-Hexachtorobutadiene PercnioroOutadiene 2279 151 HpeUtiMtohdlibafnMs WlQ <Ve 77-47-4 GY1225000 2846151 Hexachloroethane CI,CCCI3 87 72 1 KI4025000 1 ppm = 10 68 mg/m3 HCCP& Htxscftiofe-1,3-cydopenfadiene; 1,2.3.4,8,5-HexechtoroQ Pen 1ppm"11lemgtai* Carbon hexachlonde Ethane hexachlonde Perchloroethane 9037 151 1 ppm = 9 68 mg/m5 Exposure fritts (TWA unless noted otherwise) NOSH C 0 5 ppm 12 7 main3) [15-mln] OSHA none NIOSH Ca See Appendix A 0 02 ppm (0 24 mg/m3) [skin] OSHAf none NtOSH 0 01 ppm (01 mj^n5) OSHAf none NIOSH Ca See Appendix A See Appendix C (Chloroethanes) 1 ppm (10 mg/m3) [skin] OSHA 1 ppm (10 mg/m3) [skin] ABD00022882 IDLH Physical description NO Colorless liquid with a strong odor Ca (NO) Clear colorless liquid with a mild turpentinelike odor N.O. Paleyetow to amber-eotoced fc wth a pungent, unpleasant odor [Note' A hM below 18*F} Ca Colorless crystals [300 ppm) with a camphor- like odor Chemical and physical properties MW, BP, SOL FI P, IP, Sp. Gr. flammability VP, FRZ UEL, LEL MW 1323 BP351*F Sol Insoluble FIP115T IP ? VP ? FRZ -48'F UEL ? LEL ? Incompatibilities and reactivities Measurement method (See Table 1) Oxidizers reducing agents strong adds Abases alkaiimetals None evaiaMe SpGr 084 Class II Combustible Liquid MW 260 7 BP 419"F Sol Insoluble FI P 7 IP 7 VP 0 2 mm FRZ -6*F UEL 7 LEL 7 Oxidizers XAD-2 Hexane GCIECD IV [02543] SpGrl 55 Combustible Liquid f.2728 B.W IP-? VP(7T*Fi 0-08 tm PRZ.1B*F UEL. NA LEL.NA UquM - VMtt.Jgh! ' [Note- Read* slowly with wetor to form- hydrochloric add' - (V ik oorroda Iron k [261I moat metals In j presence of mrtggpfc.gxptolve. hydrooen gas ntiycelled In enotoaed space*Irttlto , , presence of moiatur*J - MW 236 7 BP Sublimes Sol(72*F) 0005% FI P NA IP 11 22 eV VP 0 2 mm MLT 368*F (Sublimes) UEL NA LEL NA SpGr 2 09 Noncombusllbie SollO Alkalis, metals such aszlnc cadmium aluminum hot Iron & mercury Char CS,, GC/FID IV [#1003, Haloge- nated Hydro carbons] Persoi di iiroieclioft ana samtutiuu (See Table 3i Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam Wher wet or contam NR (1 Heptarwthiot] Sk n Lyes Wasn skin Remove Change Prov de Previn' skin contac P'e ent eye contact When contam yVnen wet o wOi tarn NR Fyewash Quick drench (Hexacnicroouidoiene] Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam Wien wet or contam NR Eyewash Quick drench [Hexachlorocyclopentadiene] Skin Eyes Wash skin Remove Change Provide Prevent skm contact Prevent eye contacl When contam/Daiiy When wet or contam Daily Eyewash Quick drench [Hexachloroethane] ABD00022883 Recommendations for respirator selection -- maximum concentration tor use (MUCj (See Table 4i NIOSH 5 ppm CCROVrSA 12 5 ppm SA CF/PAPROV 25 ppm CCRFOV/GMFOWPAPRTOVi SCBAF/SAF trrw> cufnuurmc Route Symptoms (See Table 5) Inh Ing Con lint eyes skin nose throat weak cyan mcr respiration nau Grow neao vomit Health hazards First aid (See Table $) Eye Skin Breath Swallow rr immeO Soap wash Reap support Medical attention immed Target organs (See Table 5} Eyes skin resp sys CNS Diood NIOSH SCBAP PD PP SAF PD PP ASCBA Escape GMFOViSCBAL Inh ADs Ing Con In animals irnteyes skin resp sys kidney damage (care] Eye Skm Breath Swallow Irr immed Soap wash immed Resp support Medical attention mmed kidneys [in animals kidney tumors) TBAL Inh irnt eyes skin resp sys Abs eye skin bums lac sneez Ing cough dysp salv pukn Con edema nau vomit diarr in animals liver kidney inj Breath Swallow Irr immed Soap flush immed Reap support Medical attention Immed Eyes skin reap sys liver kidneys NIOSH k SCBAF PD PP/SAF PD PP ASCBA Escape GMFOViSCBAE Inn Abs Ing Con Irnteyes skin muememb in animals kidney damage (carcj Eye Skin Breath Swallow Irr immed Soap wash immed Resp support Medical attention immed Eyes skin resp sys kidneys [m animals liver cancer] Chemical name, structure/formula, CAS and RTECSNos and DOT ID and guide Nos Synonyms trade names and conversion factors Hexachloronaphthalene C,oHA 1335-87 1 QJ7350000 Halowax1014 160 1 Hexadecanethiol CHJCH,],,SH 2917 26 2 1228 131 (liquid) Hexafluoroacelone (CFj)jCO 684-18-2 UC2450000 2420 125 Hexamethylene dllsocyanate OCN|CHj]sNCO M01740000 2281 156 Cetyl mercaptan Hexadecanethiol 1 n Hexadecanethiol Hexadecyl mercaptan 1 ppm = 10 59 mg/m5 Bexafluoro-2-propanone 1 1 1 3,3 3-Hexafluoro- 2-propanone HFA. Periluorcecetone 1 ppm 6 79 mg/m5 1 6-Ollsocyanatofiexane HO) Hexamethylene1 6-dllsocyanate 1 6-Hexamethylene dllsocyanate HUDI 1 ppm = 6 88 mg/m5 Exposure limits (TWA unless noted otherwise) NIOSH/OSHA 0 2 mg/m3 {skin] ABD00022884 IDLH Physical description 2 mg/m3 White to lightyellow solid with an aromatic odor Chemical and physical properties MW, BP, SOL FI P, IP Sp, Or flammability VP,FRZ UEL, LEL MW 334 9 BP 650-730`F Sol Insoluble FI P NA IP ? VP <1 mm MLT 279*F UEL NA LEL NA Incompatibilities and reactivities Strong oxidizers Measurement method (See Table 1) Fitter Hexane; GC/ECO, H(2) |#S100] NlOSH C 6 5 ppm (5 3 mg/m5) (15-min) OSHA none ND NlOSH 0 1 ppm (0 1 mg/m1) [skin] OSHAt none ND NlOSH 0 005 ppm (35 ug/m5) C 0 020 ppm (140 Mg/m2) [10 min] none NO Colorless liquid or solid (below 64-68'F) with a strong odor SpGrl 78 Noncombustible Solid MW 258 5 BP ' Sol Insoluble FI P 215*F IP ' VP 0 1 mm FRZ 64 68 F UEL ? LEL ? Oxidizers strong acids & bases alkali metals reducing agents None available Sp Gr 0 85 Class IIIB Combustible Liquid Cotortass gas with a musty odor (Note Shipped as a liquefied compressed gas} MW~ 166 0 VP 5 8 atm Water aods BP -18*F FRZ. 188*F (Note Hvarosctxxc Sol Reaete UEL NA (1 a absorbs FIP NA LEL NA moisture from the IP-1181 eV aw) meets with moisture to form a highly acidic RGasD 5 76 sesquihydrate ] Nonflammable Gas but highly reactive with water & other substances releasing heat Nona avsdabie Clear colorless to slightly yellow liquid with a sharp pungent odor MW 168 2 BP 415*F Sol Low (Reacts) FIP 284`F IP? VP(77 F) 0 5mm FRZ 89*F UEL 7 LEL ? Sp Gr(77 F) 1 04 Class IIIB Combustible Liquid Water alcohols Imp strong bases amines Reagent carboxylic acids HPLC/UVD organotm catalysts IV (Note Reacts slowly with water to form [#5522 Isocv carbon dioxide Avoid anates] heating above 392 F (polymerizes) ] Personal p i,te< tion (See Table Si Skin Eyes Wash skin Remove Change Prevent swr contact Prevent eye contact When contam/Daily When wet or conlam Daily ABD00022885 Rec ommcndations tor respirator selection -- maximum concentration for use (MUU (See Table 4) NIOSH/OSHA 2 mg/m5 SA'/SCBAF SC8AF PO PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Roul:n Symptoms (See Table 5) Inn Abs Ing Oo n Acne form derm nau conf jaun coma Health hazards Firstaid iSee Table 6) Target organs (See Table 5) Skin Breath Swallow Immmed Soap wash Drompt Resp support Medical attention immed Skin liver [HexacMoronaphthalenej Skm Eyes /Vash skm Remove Change Prevent skr contact P'evei t i_>e cor ac W en woman Whe1 wet or -oi 'am Da . 'iexaaLCd Skin Eyes Wash skin Remove Change Provide Prevent skin tontacd Frostbue Prevent eye contact/ Frostbite NR NR NR Frostbite iHexafluoroacelone) Skm Eyes Wash skin Remove v-hange Provide Preve-t skin contac Prever eye contact When cuntam Wher wet vr contam NR Eyewas- Quick drennn {Hexamethylene dnsocyanate] NlOsi-i n pom 1 'n 01 Rj ,, r > iil'kj' < VjMf-r, Pr-i p' 3 v `l --f PC F Pi -Pil 11 1 J c '.M '`.'S' nr nD5 ' <-,(S smr ist i-Jd weak \ in <* ir vu - /t -> met So k Adst e au r. ^ P- /t s sk r reSC syb b*- f j TSAI )nh Abs Con irnteyes skm mucmemb respsys pulm edema liq frostbite n animals teralo repro effects kidney inj Eye Skm Breath Frostbite Frostbite Resp support Eyes skm respsys kidneys repro sys NIOSM 0 05 ppm 5A 0 125 ppm SACF 3 25 ppm SCBAFiSAF 1 ppm SAF PD PP SCBAF PD PP-SAF PD PP ASCBA Escape GMFOWSCBAE inn ing Con Irnt eyes skm resp sys cough dysp bron wheez pulm edema asthma corn damage skm blisters Eye Skin Breath Swallow Irr immed Soap flush immed Resp support Medical attention immed E,es skm resp sys 161 Chemical name, tructura/formula, CAS and RTECSNoa, and OOTID and guide Not Synonyms, tradenames factors Hexamethyl phosphbramide ({CHjJjNIjPO 880-31-8 T00875000 Hexamethy(phosphoric trtamide Hexamethylphoephorotriamide HMPA, Trie(dimethylamino)- phosphine oxide 162 n-Hexane CHJCHJ4CH, ff0-54-3 MN9275000 Hexane Hexyl hydnde normal-Hexane 1208 128 HMMlnnwi (txcfcdtoQ n-Htxm) 1208 128 n-Hexanetfuol CHJCHJjSH 111-31-8 M04550000 1 ppm * 3 53 mg/m3 Diethyimeltiylmethano Ollsobropyl 2 2-Dvnetfiylbutane, 2,3-Olmethylbutene, leohaxm. 2-Methytperitene, 3 Mathyipsntane, (Not* Also eae specific Baling fern Hexane] 1 ppm 3 53 mgfltr 1-Hexanethiol Hexyl mercaptan n-Hexyl mercaptan n-Hexylthiol 1 ppm = 4 63 mg/m3 Exposure India (TWA unless noted otherwise) NOSH Ca See Appendix A OSHA none NIOSH 50 ppm (180 mg/m3) OSHAf 500 ppm (1800 mg/m3) NOSH 100 ppm (350 mgfln*) C510ppm (1800 mgitn*) [15-min] 06HAf none NIOSH C 0 5 ppm (2 7 mg/m3) jl5-mm) OSHA none ABD00022886 IDLH Physical description Ca IN D 1 Clear colorlees liquid with an aromatic or mild amine-iika odor [Note A solid below 43*F ] 1100 ppm |10%lL) Colorless liquid with a gasoline like odor NO Cfecr liquid* w*h mW, gasoBns-Mto odors (Note Inclutfee ad the (eomero of hexaneexcept rvhewne.] NO Colorless liquid with an unpleasant odor Chemical end physical properties MW BP, SOL FI P IP.Sp.Gr, flammability VP, FRZ UEL, LEL MW 179 2 BP-4S1T Sol MJtdble FIP 222*F IP ? VP 0 03 mm FRZ 43*F UEL ? LEL? SpGrl 03 Class IIIB Combustible Liquid MW 86 2 BP 156*F Sol 0 002% FIP 7*F IP 10 16eV VP 124mm FRZ 219`F UEL 7 5% LEL 11% Sp Gr 0 66 Class IB Flammable Liquid MW 88 2 BP 122-145'F Sol Insoluble FI P- -54 to 19T IP-? VP ? FRZ. -245 to -148*F UEL ? LEL7 8pGr 085-0 65 Claes IB Flammable Liquids MW 1182 BP 304*F Sol insoluble FI P 68*F IP 7 VP ? FRZ 113*F UEL 7 LEL 7 Sp Gr 0 84 Class IB Flammable Liquid Incompatibilities and Measurement method (SeeTablel) Oxidizers None strong sods available chemically-ective metals (eg potassium sodium magnesium, zinc) Strong oxidizers Char GcfclD IV (*1500 Hydro carbons] Strong oxttsers None avaltbie Oxidizers reducing agents strong acids & bases alkali metals None available Personal pruterhon and sanitation (See Table 3j Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact Whencontam When wet or uontam NR Eyewash Quick drench [Hexamethyl phosphorarmde] Skit Eyes Wash skin Remove Change Prevent Skin contact Prevent eye contact When contam When wet (flamm; NR [n Hexane] Skin Eyee Wash skin Remove Change Prevent skin contact Prevent eye contact When contam When wet (flamm) NR [Hexane isomers (excluding n Hexane)] Skm Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam When wet (flamm) NR [n Hexanethiol] ABD00022887 SeoommenaatKins for respirator selection - maximum concentration for use (MUC (See Table 4| NIOSH SCBAF PD PP/SAF PO PP ASCBA Escape GMFOV/SCBAE >< >kl(l Symptoms (See 1 able 5) Inh Abs lug Con Frit eyes skm resp sys dysp abdom pain [care] Health hazards First aid ibee Table 6) Eye Skin Breath Swallow Irr immed Water flu9h immed Resp support Medical attention mined Target organs (See Table 51 Eyes skin resp sys CMS Gl tract (mammals cancer of the nasal cavity) NIOSH 500 ppm SA 1100 ppm SA CF /SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Inh Ing Con imteyes nose li head nau head penneur numb extremities muse weak derm gidd chemical pneu taspit liq) Eye Skm Breath Swallow Irr immed Soap wash immed Resp support Medical attention immed Eyes skin resp sys CNS PNS 163 NIOSH 1000 ppm SA* 2500 ppm SA.CF* 5000 ppm SAT CF'/SCBAF/SAF SCBAF P0 PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Inh Ing Con Irrit eyes skin resp sys head gidd dizz li-head nau ctwnical pneu (asplr liq) derm fn Breath Swallow Irr immed Soap wash immed Resp support Medical attention immed Eyes, skin reap sys CNS NIOSH 5 ppm CCROV/SA 12 5 ppm SA CF/PAPROV 25 ppm CCRFOV/GMFOV/PAPRTOV/ SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE mn Ing Con irrit eyes skin nose throat weak cyan mcr respiration nau drow head vomit Eye Skin Breath Swallow Irr immed Soap wash immed Resp support Medical attention immed Eyes skin resp sys CNS blood Chemical name structure/formula and DOT 10 and guide No* 2-Hexanone CH,COJCH,]5CM, 991-70-6 MP1400000 164 Hexone CHjCOCHjCmCHjjj 108-10-1 SA9275000 1245 127 >ec Hexylcstete W>* 10944-9 8A7S29000 Synonyms, tradenames factor* Exposure fenHs (TWA unless noted otherwise) Butyl methyl ketone MBK Methyl butyl ketone Methyl n-butyl ketone NIOSH Ippm (4 mg/m*) OSHAf 100 ppm (410 mg/m*) IppmM lOmg/m* Isobutyl methyl ketone Methyl isobutyl ketone 4 Methyl 2-pentanone MIBK 1 ppm = 4 10mg/m3 NIOSH 50 ppm (205 mg/m3) ST 75 ppm (300 mg/m3) OSHAT 100 ppm (410 mg/m3) 1 3-OknattiylDutyt acetete NIOSH/OSHA U[CdHM^SioMOnCwH^lCH^CHjChHCH^J5(300D6OTmI g/tn*) 1999 129 1ppnS.9D mourn* Hexylene glycol (CHj)jCOHCHjCHOHCHj 107-41-5 SA0810000 2 4-Dihydroxy 2 methyl pentane 2-Methyt-2 4-pentanediol 4-Methy1-2 4-pentanediol 2-Methylpentane-2 4-diol NIOSH C 25 ppm (125 mg/m1) OSHAT none 1 ppm * 4 83 mg/m3 ABD00022888 LH Physical descnptlon 1600 ppm Colorless liquid with an acetonelike odor 500 ppm Colorless liquid with a pleasant odor 800 ppm Cotortsaa Iqtid wlhamild. pMaiant, fruity odor ND Colorless liquid with a mild sweetish odor Chemical and physical properties MW, BP, SOL FI P IP.Sp Gr flammabHNy VP,FRZ UEL, LEL MW 100 2 BP 282'F Sol 2% F1P7TF IP 9S4eV VP 11 mm FRZ.-71'F UEL 8% LEL? Incompatibilities and Measurement method (See Table 1} Strong oxidizers Char gcJfid, IV *1300 Ketoneel) SpGrOSI Class 1C Flammable Liquid MW 100 2 BP 242*F Sol 2% FI P 64*F IP 9 30 eV VP 16mm FRZ 120 F UEL(200*F) 8 0% LEL(200*F) 12% Strong oxidizers potassium ten butoxide Char GCfrlD IV [1300 Ketones 1] Sp Gr 0 80 Ctass IB Flammable Liquid MW 144.2 BP-29TF 801006% RP11TF tp? VP 3 mm FRZ. -63*F UEL? LEL? Nttraloa, strong oxfdfeere, atom 4 tide i- Char; GCSfiP; fV '(91460, , EMMVQ SSi^Sfcwi WpXkjpB . , MW 118 2 VP 0 05mm BP 388*F FRZ 58'F Sol Miaobie (Seta to Ft P 209*F glass) IP 7 UEL(est) 74% LEUcaic) 13% Sp Gr 0 92 Class |||B Combustible Liquid v V * .. '-\V-SV. ,, t~ -' Strong oxidizers strong acids [Note Hygroecopic <i e absorbs moisture from the ir)) None available Personal protection and sanitation See Table 3) Stan Eyes Wash km Remove Change Prevent skin contact Prevent eye contact When contam Wten wet (flamm) NR [2-Hexenone] Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam When wet (flamm) NR [Hexonef Skin VvShskin Remove Change Prevent akm contact Prevent eye contact When contam Wen wet or contam NR [aac-Hexyl acetate] Skm Eyes Wash skin Remove Change Provide Prevent skm contact Prevent eye contact When contam When wet or contam NR Eyewash [Hexylene glycol] ABD00022889 Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table 4) NIGSH 10 ppm SA 25 ppm SA CF 50 ppm SAT CF/SCBAF/SAF 1600 ppm SAF PD PP | 5CBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Route Symptoms ISee Table 5) Abs Ing Con Imteyes nose pen neur weak pares derm head drow Health hazards First aid (See Table 6i EW Skin Breath Swallow Irr immed Soap wash immed Resp support Medical attention immed Target organs (See Table 5) Eyes skm resp sys CNS PNS NIOSH 500 ppm CCROV /GMFOV/PAPROV / SA /SCBAF SCBAF PD PP/SAF PD PP ASC8A Escape GMFOV/SCBAE tnh my Cor irrjieyes skm mucmemb head narco coma derm mammals liver kidney damage Eye Skin Breath Swallow Irr immed Water flush prompl R*sp support Medical attention mmed Eyes bkm resp sys CNS liver kidneys 165 NIOSHOSHA 500 ppm CCROV'/GMFOV/PAPROW SA7SCBAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Ml Imt eye* akjn noee Jnfl throat head Con m animals narco % Breath Swallow Irr immed Water flush prompt Raw support Medical attention mad Ejre* akin raapays TBAL mn Ing Con Imt eyes skm resp sys head dizz nau inco CNS depres derm skm sens i Breath Swallow Irr immed Water wash immed Resp support Medical attention mmed E^es skin resp sys 166 Chemical name, structure/formuia CAS and RTECS Nos and DOT 10 and guide No* Synonyms, trade names. and conversion factors Exposure limits (TWA unless noted otherwise) Hydrazine HjNNHj Oamne Hydrazine (anhydrous) Hydrazine base 302-01 2 MU7175000 2029 132 (anhydrous) 3293 152 (<37% eoln ) 2030 153 (37-64% *otn ) 2029 132 (>94%eoln) 1 ppm 1 31 mg/m3 NtOSH Ca See Appendix A (0 04 mg/m3) OSHAT Ippm (1 3 mg/m3) [skin] Hydrogenated terphenyls 61768 32 7 W26535000 Hydrogenated diphenyl benzenes Hydrogenated phenyl biphenyls Hydrogenated tnphenyis [Note Complex mixture of terphenyl isomers that are partially hydrogenated] NIOSH 0 5 ppm (5 mg/m3) OSHAT none 1 ppm *12 19 mg/m1 (40% hydfogenatsd) Hydrogen bromide HBr 10035-10-6 MW3BS0000 Anhydrous hydrogen bromide Aqueous hydrogen bromide (i a Hydrobromic acid) NIOSH C 3 ppm (10 mg/m3) OSHAT ?img/m3) 1040 125 (anhydrous) 1708 154 (solution) Hydrogen chlonde HCl 7647-01-0 MW4025000 1 ppm 3 31 mg/m3 Anhydrous hydrogen chlonde Aqueous hydrogen chlonde (i e Hydrochloric acid Munatic acid) (Note Often used in an aqueous solution ] niosh/osha C 5ppm (7 mg/m3) 1050 125 (anhydrous) 1789 157 (solution) 1 ppm a 1 49 mg/m3 ABD00022890 I0LH Ca [50 ppm) Physical description Colorless fuming oily liquid with an ammoma-ltke odor (Note A solid below 36*F ] Chemical and physical properties MW, BP SOL FI P IP, Sp.Gr, flammability VP FRZ UEL, LEL MW 321 BP 236*F Sol Miscible Ft P 99*F IP 6 93 eV VP tOmm FRZ. 36*F UEL98% LEL 2 9% SpGrl 01 Class >C Flammable Liquid Incompatibilities and reactivities Measurement method (See Table 1) Oxidizers hydrogen peroxide nibic acid metallic oxxiee aods [Note Can ignite SPONTANEOUSLY on contact with oxidizers or porous materials such as earth wood & doth ] Sub Reagent IV (#3503] ND Clear oily pale MW 298 VP(77 F) None reported None yellow liquids with (40% hydro 01 mm (40%) (Note When heatea available a famt odor genated) irritating vapors (plasticizer/heat 8P 644*F (40%) UEL ' will be released ] transfer media] Sol insoluble LEL 1 FI P 31S*F(40%) IP > Sp Gr{77 F) 1 003-1 009 (40% hydrogenated) Class IU0 Combustible Liquids 30 ppm Colorless gas with a sharp irritating odor [Note Shipped as a liquefied compressed gas Often used in an aqueous solution) MW 80 9 BP -88`F Sol 49% FIP NA IP 11 62eV VP 20 atm FRZ -124*F UEL NA LELNA RGasD 2 81 Nonflammable Gas Strong oxidizers, strong caustics motsture copper brats, zinc (Note Hydrobromic add Is highly corrosive to most metals ] Si gel, NiHCOJ IV (#7903 Inorganic Acids] 50 ppm Colorless to slightly yellow gas with a pungent irritating odor [Note Shipped as a liquefied compressed gas ] MW 36 5 BP 121'F SoK86*F) 67% FtP NA IP 12 74eV VP 40 5 atm FRZ 174'F UEL NA LEL NA RGasD 127 Nonflammable Gas Hydroxides amines alkalis copper brass zinc [Note Hydrochloric acid is highly corrosive to most metals ] Si gel NaHCOV Na2CO; 1C IV [7903 Inorganic Acids] Personal protection and sanitation (See T bk 1 Skin Eyes Wash skin Remove Change Provide Prevent sk n _onlac Prevent eye contact When contam When wet (flammi NR Eyewash Quick drench [Hydrazine] Skin Eyes Wash skin Remove Change Prevent skm comae' Prevent eye contact When contam When wet or contam Daily ABD00022891 Recommendations for respirator selection -- maximum concentration for use (MUCl (See Table 4i NlOSH * SCBAF PD PP/SAF PD PP ASCBA Escape SCBAE rt OLit < Symptoms iSee table 5` inh AOS Ing Con Inteyes skm nose throat temporary blindness dizz nac derm eye skm bums mammals oron pulm edema liver kidney damage convuls [care) Health hazards First aid iSee Table 6) Target organs ISee Table 5) Eye Skin Breath Swallow Irr immed Water flush immed Resp support Medical attention immed Eyes skin resp sys CNS liver kidneys [mammals tumors of the lungs liver blood vessels & intestine] TBAl tnh ing Con imt eyes skin resb sys iwer kidney hemato damage fcy* Skin Breath Swallow irr immed Soap wash immed Resp support Medical attention immed Eyes 9kin resp sys liver kidneys hemato sys (Hydrogenated terohenyls] Skm yw Wash skin Remove Change Provide Prevent skin contact (solnyFrostbite Prevent eye contact (solnyFrostbite When content (sotn) When wet or contarn (sotn) NR Eyewash (soln) Quick drench (soln) Frostbite NIOSH/OSHA 30 ppm SACFe/PAPRAGc/GMFAG/ SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFAG/SC8AE [Hydrogen Bromide] Skin Eyes Wash skin Remove Chanoe Provide Prevent skm contact isoln); Frostbite Prevent eye contact/Frostbite When contam (soln) When wet or contam NR Eyewash isotnj Quick drench Isolni Frostbite [Hydrogen chloride NIOSH/OSHA 50 ppm CCRS /GMFS/PAPRS / SA /SCBAF SCBAF PO PP/SAF PD PP ASCBA Escape GMFAG/SCBAE kti Irriteyes skm nose Ing throat- soln eye skin (soln) bums tlq frostbite Con Inh Irnt nose tnroat larynx Ing cough choking derm (soln) soln eye skin burns Con iiq frostbite mammals larspasm pulm edema Eye Skin Breath Swallow Irr Immed (solny Frostbite Water flush immed (solnyFrostbite Resp support Medical attention immed (sofn) Eyes, akin rasp ays Eye Skin Breath Swallow Irr immed (solny Frostbite Water flush immed (sotn (/Frostbite Reap support Medical attention immed (soln) Eyes skin respsys 167 Chemical name structure/formula, CAS and RTECS Nos and DOT ID and guide Nos Synonyms trade names, and conversion factors Exposure imtts (TWA unless noted otherwise) 168 Hydrogen cyanide HCN 74-90-8 MW682SOOO 1061117(>20%ec*>) 1061117(*%drous) 1013 1S4(20Ksoin) Formomtnle Hydrocyanic add Prussic ead 1ppm1 lOmg/m* NIOSH ST 4 7 ppm (5 mg/m1) (skin) OSHAT 10 ppm (llmg/m1) (skin) Hydrogen fluoride (asR 7664 39 3 MW7875000 10S2 125(anhvdrou) 1790 157 (solution) Anhydrous hydrogen fluonde Aqueous hydrogen fluonde (i e Hydrofluonc acid) HF A 1 ppm = 0 62 mg/m1 NIOSH 3 ppm (2 5 mg/m3) C 6 ppm (5 mg/m1) (15-min) OSHAt 3 ppm Hydrogen peroxide 7722-84-1 MX0900000 2984 140 (8-20% soin ) 2014 140 (20u60% soln ) 2016 143(>80%soln) High-strength hydrogen peroxide Hydrogen dioxide Hydrogen peroxide (aqueous) Hydroperoxide Peroxide 1 ppm 1 39 mg/m1 NIOSH/OSHA (1 4 mgrtn1) Hydrogen selemde HjSe 7783-07-5 MX1050000 Selenium dihydnde Selenium hydnde NIOSH/OSHA 0 05 ppm (0 2 mg/m5) 2202 117 (anhydrous) 1 ppm = 3 31 mg/m1 ABD00022892 tOLH Physical description 50 ppm Colorless or paleblue liquid or gas (above 78*F) with a bitter almondlike odor [Note Often used as a 96% solution in water ] Chemfcat and physical properties MW BP SOL FI R, IP, Sp.Gr, flammability VP,FRZ UEL, LEL MW 27 0 BP 78*F{96%) Sol Miscible FI P 0*F (96%) IP 13 60eV VP 630 mm FRZ 7*F(96%) UEL40 0% LELS6% Sp Gr 0 69 Class IA Flammable Liquid FlammableGaa Incompatibilities and reactivities Amines oxidizers sods sodium hydroxide calcium hydroxide sodium carbonate water caustics ammonia [Note Can polymerize at 122-140*F} Meaiurement method (See Table 1) Soda lime, Water Vis IV (86010) 30 ppm Colorless gas or fuming liquid (below 67*F) with a strong irritating odor [Note Shipped in cylinders ] MW 20 0 BP 67*F Sol Miscible Fi P NA IP 1596 eV VP 783 mm FRZ 118 F UEL NA LEL NA RGasD 1 86 Sp Gr 1 00 (Liquid at 67*F) Nonflammable Gas Metals water or steam (Note Corrosnre to metals Will attack glass and concrete ] Si gel* NaHCOy Na,COj ic IV [*7903 Inorganic Acids] [Also *7902 7906) 75 ppm Colorless liquid with a slightly sharp odor [Note The pure compound is a crystaiPne aoVd below 12*F Often used in an aqueous solution) MW 34 0 VP(86*F) OxkJlxable materials Bub BP 266*F 5mm Iron copper brass TIOSO* Sot MtacfMa FRZ 12*F bronze chromium Vis FIP NA UEL NA zinc lead silver OSHA IP 10 54eV LEL NA manganese (IMD128SG) [Note Contact with combustible material may result in SPONTANEOUS combustion ] Sp Gr 1 39 Noncombustible Liquid but a powerful oxidizer 1 ppm Colorless gas with an odor resembling decayed horse radish [Note Shipped as a liquefied compressed gas ] MW 81 0 BP -42*F Sol(73*F) 09% FIP NA (Gas) IP 9 88 eV RGasD 2 80 Flammable Gas VP(70*F) 9 5 atm FRZ 87'F UEL 7 LEL 7 Strong oxidizers acids water haiogenated hydrocarbons None available Personal protection and sanitation (Se. Table a. Skip Eyes Wash skm Remove Change Provide Prever t ski' contact Prevent pye contact When contam When wet (flammi NR Eyewash Quick drench [Hyoiogen cyanide] ,, Lyes .JSP Sk ' Ter wr ^ iange Pi'vde i-' c *. - ' p` ei ' Hi Ar t- -a e \t NR F Win" _o ' a.1 n u^'ac lig j .'ntjr iZ ,\ J'Pr ' ,0 It ` ip i Skin Eyes Wash skm Remove Change Provide Preven s*m contact Prevent eye contact Whenoontam When wet or contam NR Eyewash Quick drench (Hydrogen peroxide] Sk^ f yes Wash sk n Remove Change Provide h s,, < 1 is c't hK W^e"' wet iflar-im NR F rostbi'e Hydrogen selpr ide ABD00022893 Recommendations for respirator selection -- maximun concentration for use IMUCi (See Table 4) NIOSH 4 7 ppm SA 50 ppm SA CF/SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFS/SCBAE Rou te Symptoms (See Table 51 Irih Abs Ing Con Asphy weak head conf nau vomit mcr /ate and depth of respiration oi respiration slow and gasping thyroid blood changes Health hazards Firetaid (See Table 6j Target organs (See Table 5) Eye Skin Breath Swallow Irrimmed Water flush immed Medical attention immed CNS CVS thyroid blood \H c .'t ' -1 TS IjM s, SCb-k r Sv.Br f 1 0 PP'SA P'JFPfC' r s ape WFb At 0AF , Ads g t bC ' i e/e S* <*oa i rt eaer ^ e,. s* Oi i 1$ |C t - rfi'i q< s (e * I'Hdt < J S.A 1 "'e- bO n m \ \d\Pf 'iuSr n re<- Peso suppoh Mwrai attention " r'faa SO n NIOSH/OSHA lOoprr SA 25 ppm SAc-r' 60 ppm SCBAF/SAF 75 ppm SAF PD PP SCBAF PO PP/SAF PD PP ASC8A Escape GMFS/SCBAE im Ing Con irrit eyes nose throat com ulcer eryt vesic skin bleaching hair Skin Breach Swallow irr immad Water Rush immed Resp support mmed Eyes skin res# sys N OSH OShA - i PP n SA i pprr tsA CF (SCBAF SAF $ SI. Br PD PP SAF PD PP ASCbA Fs-aoe GMFS-rSCBAE nr uon i eyes nose throat id , vomit diarr metallic aste garlic breath dizz ass hg iiq frostbite mammals pneuils liver aamage Eye Skir Bredlh F rostoile Frostb te Eyes reso Sys liver Chemical nama, atructura/fomuiia CAS and RTECS Not, and DOT ID and guide Nos Synonyms, trade names and conversion factors Hydrogen suWds V 7763-09-4 MX1225000 Hydraaufetlc add. SulftaO hydrogen 1093117 Hydroqumone C(H<(OH)j 123-31 9 MX3500000 1 ppm "I 40 mg/m3 p-Benzenediof 1 4-Benzer*ediol Dihydroxybenzene 1 4-Dihydroxybenzene Qumol 2662 153 2-Hydroxypropyi HRA. acrylate fl-i lydroxyprapyl acrylata, Prepylane ahook CH^CHCOOCHplOHCH, monotcryfiM NM1-1 AT1928000 Indana C^, 95-13-6 NK8225000 1 ppm6.33mg/m* Indonaphlhene 1 ppm * 4 75 mg/m5 ABD00022894 Exposure (TWA unless noted otherwise) IOLH NI06H ClOppm BW 100 ppm 08HAT C 20 ppm 60 ppm (10-min maxpeak) Physical description Chemical and physical properties MW, BP, SOL Ft P. IP, Sp, Or, flammsMHty VP, FRZ UEL, LEL Cotoriass gas Ah MW 341 a strong odor of BP-77*F rattan eggs Sot 04% (Note Sanaa of FtPNA(Gae) smel becomes |P-1049aV rapWy fatigued & can NOT be rated upon to warn of the continuous praaence of KS Shipped aa a liquefied comprawed gaa) VPITOatm FRZ.-122'F UEL44.0% LEL4.0H ROaoD:119 RdmmaMe8aa Incompatibilities and reactivities 8tawtg oxidizers, strong nitric add, metals Measurement method (See Table 1) Char IV (98013) MOSH C 2 mg/m3 [15-min) OSHA 2 mg/m3 50 mg/m5 Light tan light gray or colorless crystals MW 1101 BP 545*F Sol 7% FI P 329`F (Molten) IP 7 95 eV VP 0 00001 mm MLT 338'F UEL 7 LEL 7 Strong oxidizer* alkalis Sp Gr 1 33 Combustible Solid dust cloud may explode rf ignited in an enclosed area Filter CH.COOH hplc/uvo IV [#5004] M06N SkST* OSHAt none N.D Osar teigte- MW 130.2 VP 7 Water Nona yatew laid wttt BP379T FRZ.? [Note: Canteeome awateble osweeteh, advent Sot: ? UEL? unstable at high eder FIP149T LB. 19% temperatures* IP? praaaurea or may raact 5- wRh water w*h aoma reieaae ofenergy, but not vtotanw) $pr105 OSM IRACombuetMe liquid NIOSH NO Colorless liquid MW 116 2 VP 7 None reported None lOppm [Note A solid BP 359'F FRZ 29'F (Note Polymerize* & available (45 mg/m5) below 29'F) Sol Insoluble UEL 7 oxidizes on standing OSHAt FI R 173'F IP seiev LEL 7 It has exploded dunno nitration none with (HjS04 * HNOj)) Sp Gr 0 997 Cless 1I1A Combustible Liquid Personal protection and sanitation (See Table 3) skn Eyes Wash stem Remove Change Provide Frostbile Frostbite NR When wet tflammi NR Frostbite [Hydrogen sulfide] bKir Eyes Wash skm Remove C nange Provide P event skin contact Prevent eye contact Whe contain vVhe- wet or ,ontam Daily Eyewash i>7c/t,| (Hydroquinone; Skin Eyes Wash Skin Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet or contam NR Eyewash Quick drench [2-Hydroxypropyl acrylate] Skin Eyes Wash skin Remove Charge Prevent skin contact Prevent eye contact Daily When wet or contam NR (indene| ABD00022895 Recommendations for respirator selection -- maximum concentration for use (MUCi (See Table 4) NlOSH 100 ppm PAPRS/GMFS/SA 'SCBhE SCBAF PO PP/SAF PC PP tSCbn Escape GMFS'SCBAE Routi Symptoms (See Table 5) tnr r it eyes rest- sys Cor aur ea coma convuls coni eye paid ac proto corn vesK. oizz head fig irnly insom Gl dist Health hazards First aid (See Table 6) Eye Skin Breath Frostbite Frostbite Resp support Target organs (See Table 5) Eyes resp sys CNS NIOSHrOSHA t>0 mgim PAPRD1 NiEf-rSAT CFL SCBAF SAf | SCBAF PD PP/SAF PO PP ASCBA Escape HiEf-'SCBAE inh 1 r i eyes co"i <eia CNS Ing evcitement adored urine Co' i au Oizz suffocation rapid preatn muse twiten delirium collapse sum .ml sens derm Eye Skin Bream Swailow Irr immed Water flush Resp support Medicai attention immed Eyes skip resp sys CNS TBAL Inh Irnt eyes stun resp sys Abs eye skin bums cough dysp Ing Con EW Skin Breath Swallow Immrned Soap flush jmmad Resp support Medical attention Immed Eyes skin respays TBAl Inh Ing Con in animals irriteyes skin muememb derm skin sens chemical pneu (aspir iiq) liver kidney spleen mj Ey Skin Breath Swallow Immmed Soap wash Resp support Medical attention immed Eyes skm resp sys liver kidneys spleen Chemical nama, structura/formuia. CAS and RTECSNot, and DOT 10 and guldtNos Synonyms, tradenames, and conversion factors Mum to 7440-74-B Nil060000 Munmetol 172 Iodine `i 7553-56-2 NN1575000 Iodoform CH, 7*47* PBTOOOOQO Iron oxida dust and fume (a* Fa) F*jOj 1300-37 1 N07400000 N07526000 (fuma) 1376 135 (spent) Iodine crystals Molecular iodine 1 ppm = 10 38 mg/m3 TmodcrnsMene iftmolfctOiegAn* Feme oxide Iron(lll) oxide ill li Ei^osore (TWA unless noted otherwise) ABD00022896 DLH Physical description M0GH* NO OlmQtoi* rfMe. The RB. alto Mipiae to other Indium compounds (as In).) OBHAT none Duetts, shiny, saver-while metal that it softer then lead. NIOSH/OSHA CO 1 ppm (1 mg/m3) 2 ppm Violet solid with a sharp characteristic odor Chemical and physical propertias MW, BP, SOL FI P, IP. Sp, Gr, flammaMMy VP,FR2 (/EL, LEL Incompatibleties and reactivities Measurement method (See Table 1) MW 114 8 VP-0 mm (DWtrogen tatraodde Fitter BP 37B7*F (approx) ecetonttrte), Add. Sol Inadubla MLT 314`F marcury(H) bromide FAA, R P NA UEL. NA (at 662*F), aulfur IHS) IP NA LEL NA (mixturesIgnNewhan (PaCAM heated) #173] [Note ooddizee readily SpGr731 at higher temperatures ] Noncombusttbto Sold In buk form, but may igntte In powdered or dtnt form MW 253 8 BP 365*F Sol 001% FI P NA IP 9 31 eV VP(77*F) 0 3mm MLT 236*F UEL NA LEL NA Ammonia acetylene acetaldehyde powdered aluminum active metals liquid chlonne Char* N^CC, IV (60051 NIOSH 5 mg/m1 OSHA 10 mg/m3 Sp Gr 4 93 Noncombustible Solid N.0 Vtfow to gretnith- MW 9B37 VP*? yetowjsowderor 6P-4I0T MLT 246*F eyMae told wft a pungent, ssstr-> UEL NA LB^NA dhigreitfli odor FIP-NA Iantleeptlc tor tP- ? external use] aSriLooMnGuoMorW4*ne0Dt1tuuiieHlMMe 8ottd 2500 mg/m3 Reddish-brown (as Fe) solid [Note Exposure to tome may occur during the arc-welding of iron ] MW 159 7 BP 7 Sol Insoluble FIP NA IP NA VP 0 mm JtF'SSi.-F UEL NA LEL NA Sp Gr 5 24 Noncombustible Solid Strong agddtara, mm, mafic setts (me., mercuric oxide, Nwr nfeats), strong beset cetomst. ton* Sno--n--* piUMdl Calcium hypochionte Filter Acid ICP IV (7300 Elements) Personal protection and sanitation (Sh Table 3) 8Mn NR, Emt N.R. WMttWn N.R Renoe* nr Clwpfy . MR ABD00022897 Recommendation* for respirator election--maximum concentration for us* (MUC) (See Table 4) Route Symptoms (See Table S) TBAL trrtteye**Wamp rpoMWi.* Health hazards First aid (See Table 6) brimmed Target organs (See Table S) Eyee,atoneep*ya. tw.Mdneyft heart, WwJ A) < Stun Eyes Waahskm Remove Change Provide Prevent skin contact Prevent eye contact Whencontam Wien wet or contam Daily Eyewash(>7%) Quick drench (>7%) NIOSH/OSHA 1 ppm SA* 2 ppm SA CF7SCBAF/SAF SCBAF PD PP/SAF PO PP ASCBA Escape GMFAGHiE/SCBAE Inh Imteyes skin nose Ing lac head chest tight Con skin bums rash cutaneous hypersensitivity tn Breath Swallow irnmmed Soap wash immed Rasp support Medical attention immed Eyes, skin respey* CNS CVS (Iodine] 8ttfc ' Prevent ektocanto* PgwMatoaontot VHHVMBplk h 'rWWnCpliiHlR MMOW WWIVHOrlUWI CMf**/-, IWy pinjpfn>] " Skn Eye* Wash skin Remove Change NR NR NR NR NR " [Iron oxide dust and fume (as Fe)] TSAL . NIOSH 50 mg/m DMFu/SA 125 mg/m3 SA CF/PAPRDMFu 250 mg/m3 HiEF/SAT CF/PAPRTHiE/ SCBAF/SAF 2500 mg/m3 SA PD PP SCBAF PO PP/SAF PD PP ASCBA Escape HIEF/SCBAE & Imfeyee.jkin, Wieed,' zz.oau,toe,CNS & gIwgmsMteVIgQRIMaB*V.;, -- ' Ek , Wrtoned t dWjMiMmmed waw*. b >iPprtpaipBR MW, ,1 < ** P K`i ---- _T Inh Benign pneumoconiosis with X-ray shadows indistinguishable from fibrotic pneumoconiosis (siderosis) ' >, * r i_ Rasp support ? Resp sys 173 174 Chemical name, structura/formula, CAS and RTECS Nos and DOT ID and guide Nos Synonyms tradenames, and conversion factors Exposure limits (TWA unless noted otherwise) Iron pentecarbonyt (n Fe) F*(CO), 13463-40-6 N04900000 1004131 iron caibonyt, Pantacarbonyt iron Ippm 2.28mg/m*(es Fe) NOSH 0 Ippm (0 23 mg/m*) ST 0 2 ppm (045 mg/m*) 06H4f none Iron salts (soluble as Fe) FeSO. Ferrous sulfate Iron(ll) sulfste FeCL Ferrous chlonde Iron(ll) chlonde Fe(NOJT Fentc nitrate lmn(lll) nitrate Fe(SOJv Ferric sulfate Iron(lll) sulfate FeCL Feme chlonde Iron(lii) chloride NIOSH 1 mg/m3 OSHAf none uraiwrtPMtmi^..7y> ^bo*h/osHa ~ mam* . <5wm5*T) NsSnlooM -mmom ABD00022898 IQLH Physical description Chemical and physical properties -------------------------------------------- MW, BP SOL FI P, IP, Sp, Gr, VP, FRZ flammability UEL, LEL NO Colorless to yellow MW 195 9 VP(87*F) to dark-red oily BP(749mm) 40 mm liquid 217*F FRZ -6'F Sol Insoluble UEL ? FI P 5*F LEL ? IP ? SpGr 146-1 52 Cass IB Flammable Liquid N O Appearance and odor Properties vary depending vary depending upon upon the specific soluble the specific iron salt soluble iron sail 1000 ppm Cotortesa liquid wWiabenene4fce odor Noncombustible Solids MW: 130 2 BP-28TF Sot 03% RP-77*F (P 7 VP*4mm FRZ -109*F UEL76% LEH212T): 10% Isoamyl alcohol (primary) (CHj)jCHCHjCHjOH 123-51 3 EL5425000 1105129 lppm(.3?nq)hn* Fermentation amyl alcohol Fusel oil Isobutyl cerbinol Isopentyl alcohol 3-Methyl-1 butanol Pnmary Isoamyl alcohol 1 ppm * 3 61 mg/m5 NIOSH 100 ppm (360 mo/m3) ST 125 ppm (450 mg/m3) OSHAf 100 ppm (360 mg/m*) 500 ppm Sp.Gr 007 Ctaee 1C Flammable Liquid Colorless liquid with a disagreeable odor MW 68 2 BP 270*F Sol(57*F) 2% R P 109`F IP ? VP 28 mm FRZ 179*F UEL(212*F) 90% LEL12% SpGr^'F) 0 81 Class U Combustible liquid Incompatibilities and reactivities Measurement method (SeeTable 1) Oxidizers nitrogen None oxide (zinc cobalt available haMes) [Note Pyrophoric (i e, Igmtet spontaneously m air). Decomposed by IgMoralr releasing earbon monoxide] Vanes Filter Acid ICP IV [#7300 Elements) Nitrate*, etrom euddtzars, akaw Aactda Gtrnr, GC?fio; IV (#1450 Eetara 1] Strong oxidizers Char 2-Propanol/ Gc/ho IV [#1402 Alcohols III] Personal protection and sanitation (See Table 3) Skm Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When eontam When wet (flamm) NR Quickdrench [Iron pentacarbonyi (as Fe)) Skm Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact Daily NR Daily [Iron salts (soluble as Fe)] Skin Vl)ashslan Remove Change Prevent skin contact Prevent eye contact When eontam When wet (ftamm) NR [laoamyl acetate] Skin Eyes Wash skin Remove Change Prevent skm contact Prevent eye contact When eontam When wet or eontam NR [Isoamyl alcohol (primary)] Recommendations for respirator selection -- maximum concentrationforuse(MUC) (See Table 4) TBAL Route Symptoms (See Table 5) mh Irrtteyes muememb,reap Abs sys,head,dlzz nau, vomit fever, cyan cough, Con dysp liver, kidney, lung inj^dsgeneretfve changes Health hazards Firstald (See Table 6) S' Breath Swallow' hr Immed Soaphush immed Rasp support Medical attention tamed Target organ* (See Tab's S) Eyes, resptys.CNS, tor, kidney* TBAl Irth Imleyes skm muememb Ing abdom pain diarr vomit Con possible liver damage Eye Skin Breath Swallow Irr immed Soap wash Resp support Medical attention immed Eyes Skm resp sys liver Gl tract NIOSH/OSHA inh lrrtt eyes,skin, noea 1000 ppm CCROW/PAPROV/GMFOV/ Ing throw: dam SA/SCBAF Con Inanimsls nareo SCBAF PD,PP/SAF PO PP ASCBA Escape QMFOV/SCBAE K Breath Swallow intoned Water flush prompt Rasp support Mamoal attention toned NIOSH/OSHA 500 ppm SA CF'/CCRFOV/GMFOV/ PAPROVE/$CBAF/SAF | SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Inh Irrrt eyes skin nose Ing throat head dizz cough Con dysp nau vomit diarr skin cracking mammals narco Eye Skin Breath Swallow Irr immed Water flush prompt Resp support Medical attention immed Ej^es skin resp sys Chemical name structure/formula, CAS and RTECS Nos . and DOT ID and guide Nos Synonyms, tradenames, and conversion factors Isoamyl alcohol (secondary) (CHj)jCHCH(OH)CHj 6032-29-7 3-Methyl-2-butanol, Secondary isoamyl alcohol 176 1105 126 Isobutane CHjCH(CH3)? 75 28 5 TZ430Q00Q 1075115 1969 115 Isobutyl acetste CHjCOOCH2CH(CHj)j 110-190 AI4025000 1 ppm *3 61 mg/m3 2 Methylpropane [Note Also see specific listing for n Butane ) 1 ppm = 2 38 mg/m3 Isobutyl ester of acetic acid 2-Methyipropyl acetate 2-Methylpropyl ester of acetic add R-Methytpropyl ethanoate 1213 129 Isobutyl alcohol (CHJjCHCHjOH 78-83-1 NP9625000 1 ppm * 4 75 mg/m* IBA Isobutanol Isopropylcarbinol 2-Methyl 1 propanol 1212 129 1 ppm = 3 03 mg/m5 Exposure limits (TWA unless noted otherwise) NIOSH 100 ppm (360 mg/m') ST 125 ppm (450 mg/m5) OSHA? 100 ppm (380 mg/m3) NIOSH 800 ppm (1900 mg/m3) OSHAT none NIOSH/OSHA 150 ppm (700 mg/m5) NIOSH 50 ppm (150 mg/m3) OSHAt 100 ppm (300 mg/m3) ABD00022900 IDLH Physical description 500 ppm Colorless liquid wrth a disagreeable odor Chemical and physical properties MW, BP SOL FI P, IP, Sp,Gr, flammability VP,FRZ UEL, LEL MW 88 2 BP 234*F Sol 7 FI P(oc) 95*F IP 7 VP 1 mm FRZ ' UEL ' LEL i N D Colorless gas with a gasoline-like or natural gas odor [Note Shipped as a liquefied compressed gas A liquid below 11*F] 1300 ppm (10%LEL) Colorless liquid with a fruity, floral odor SpGr 0 62 Class 1C Flammable Liquid MW 58 1 BPIl'F Sol Slight FI P NA (Gas) IP 10 74 eV VP(7QF) 3 1 atm FRZ 255F UEL 8 4% LEL 16% RGasD 2 06 Flammable Gas Class IA Flammable Liquid MW 116 2 BP 243`F Sol(77*F) 06% FiP 64*F IP 9 97 ev VP 13mm FRZ -H5*F UEL 105% LEL 13% 1600 ppm Colorless oily liquid with a sweet musty odor Sp Gr 0 87 Class IB Flammable liquid MW 74 1 BP 227'F Sol 10% FI P 82'F IP 10 12eV VP 9 mm FRZ 162*F UEL(202*F) 106% LEL(123'F) 17% Sp Gr 0 80 Class iC Flammable Liquid Incompatibilities and reactivities Strong oxidizers Strong oxidizers (e g nitrates & perchlorates) chlorine fluonne (nickel carbonyl oxygen) Nitrates strong oxidizers alkalis & acids Strong oxidizers Measurement method (See Table 1) Char 2-Propanol/ Gofio IV (#1402 Alcohols III] None available Char gcSfio IV (#1450 Esters 1] Char 2 Propanol/ GC^ID IV [#1401 Alcohols II) Personal protection and sanitation (See Table 3) Skin Eyes Wash skm Remove Change Prevent skin contact Prevent eye contact Whencontam When wet (flamm) NR [Isoamyl alcohol (secondary)] Skin Eyes Wash skin Remove Change Provide Frostbite Frostbite NR When wet (flamm) NR Frostbite (Isobutane] Skin Eyes Wash skin Remove Change Prevent skm contact Prevent eye contact When contam When wet (flamm) NR [Isobutyl acetate] Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact Whencontam When wet (flamm) NR [Isobutyl alcohol] ARDQQ022901 Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table 4] Route Symptoms (See Table 5) NIOSH/OSHA 500 ppm SA CF{/CCRFOV/GMFOV/ PAPROV*/$CBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Ml Irrrteyes skin nose Ing throat head dizz cough, Con dysp nau, vomit dlarr skm cracking mammals narco Health hazards First aid (See Table 6) Target organs (See Table 5) In Breath Swallow Immmed Water flush prompt Reap support Medical attention turned Eyes skin respsye, CNS TBAL Mi Drow narco asphy Con liq frostbite (nq) Eye Skin Breath Frostbite Frostbite Resp support CNS NIOSH/OSHA 1300 ppm SA CF'/CCRFOV/GMFOV/ PAPROWSCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Mi Irrit eyes skin upper ing raspsys head drow anes Con in animals narco Eye Skm Breath Swallow Immmed Water flush prompt Resp support Medical attention mmed Skin eyes respays. CNS NIOSH 500 ppm CCROV'/SA* 1250 com SA CF7PAPR0V' 1600 ppm CCRFOV/GMFOV/ PAPRTOV /SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Inh Ing Con Irrit eyes throat nead drow skin cracking in animals narco Eye Skin Breath Irr immed Water flush prompt mmed Chemical name structure/formula CAS and RTECSNos , and DOT 10 and guide Noa Synonyms, trade namea. and conversion factora leobutyrpnltnle (CH^CHCN 78-82-0 TZ4900000 Isopropyl cyanide, 2-Methylpropanenftnle 2-Methylproplonltrll* Exposure Ms (TWA unless noted otherwise) ______ ARD0nn?2Q02 IDLH Physical description NiOSH OSHA none NO Colorless liquid wtth an almond-like odor [Note Forme cyanide in the body ] Chemical and physical properties MW BP SOL FI P.IP.Sp, Gr, flammability VP FRZ UEL. LEL MW 691 BP 219*F Sol Slight FI P 47*F IP 7 VP(130*F) 100 mm FRZ -97*F UEL 7 LEL 7 Incompatibilities and reactivities Measurement method (See Table 1) Oxidizers reducing agents strong acne & bases Char Benzene GC/FID IV [Adapt #1808) 178 22S4 131 leooctyf alcohol CjHjjCHjOH 26952 21-6 NS7700000 leophoron* c^Mo 78-59-1 QW7700000 IMS 128(con*uUbie liquid. n.o a) laophorone dllaocyanale CH iNjOj 4098-71-9 NQ9370000 2290 156 1 ppm 2.63 mg/m* isooctanol NiOSH Oxooctyl alcohol 50 ppm (Note A mixture of closely (270 mg/m5) related isomeric primary [skin) alcohols with branched chains such as 2 Ethyl- OSHAf hexanol none CHj(CH2)jCH(CHjCHj)CH2OH ] 1 ppm 5 33 mg/m5 leoaeetophorone, 3 5,5-Trtmetftyl-2-cydo- heaenone; 3,6,5-Trim#thyL2-cyck>heiwn-1-on* NIOSH M'mufm*) OSHAf 26 ppm (140 mg/m*) 1 ppm 6.66 mplm1 IPDl 3-lsocyanatomethyl 3 5 5- tnmethyicyclohexylisocyanate 1sophorone diamine dllaocyanale 1 ppm 9 09 mg/m5 NIOSH 0 005 ppm (0 045 mg/m5) ST 0 02 ppm (0 160 mg/m5) [skin) OSHAf none Sp Gr 0 76 Class IB Flammable Liquid NO Clear colorless MW 130 3 VP 0 4 mm None reported liquid BP 367`F FRZ < 105 F Sol Insoluble UEL(es!) 57% IP 7 LEL(calc ) None available 200 ppm Colorless to white liquid with a pappermmt-liks odor Sp Gr 0 63 Class IIIA Combustible Liquid MW- 138 2 8P 419*F Sot1% FI P 184'F IP 8 07 eV VP 03mm FRZ. 17*F UEL 3 8% LEL 0 8% Oxidizer* strong alkali* ammo* Char(pet) gcSfid [2508] Sp Gr 0 92 Clsss IMA Combustible Liquid N D Colorless to MW 222 3 VP 0 0003 mm Water alcohols None slightly yellow BP 7 FRZ 76*F phenols amines available liquid with a Sol Decomposes UEL 7 mercaptans amnes pungent odor FIP 311'F LEL 7 urethanes ureas IP 7 [Note Reacts with water to form carbon dioxide ] SpGr 1 06 Class 1118 Combustible Liquid Personal protection and sanitation (See Table 3) Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet (flamm) NR Eyewash Quick drench [Isobutyromtrile] Sion Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam/Daily When wet or contam NR Eyewash [Isooctyl alcohol] Stan. Eyes. Wash skin Remove Change Provide Prevent skin contact Prevent eye contact Whencontam When wet or contam NR Eyewesh [Isophorone] Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet or contam Daily Quickdrench [Isophorone dnsocyanate] ABrffln022903 Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table 4) Symptoms (See Table 8) NIOSH SO ppm CCROV/SA 200 ppm SA.CF/PAPROV 400 ppm CCRFOV/GMFOV/PAPRTOV/ SCBAF/SAF 1000 ppm SAFPO.PP | SCBAF PD PP/SAF PD PP ASC8A Escape GMFOV/SCBAE Inh Abs Ing Con Irrft eyes skin nose throat; head, dlzz, weak, gldd corf convuls dvsp. abdom pain, nau, vomit TBAL Inh Irriteyes skin nose Abs throat eye skin bums ing Con HeaHh hazards First aid (See Table 6) IB, Breath Swallow Irr Immed Soap fiuah Immed Raw support Medical attention tanned Target organs (See Table 6) Eyee, skin, reapays, CNS.CVS ic Breath Swallow Irr immed Soap wash immed Rasp support Medical attention immed . Eyes skin respsys NIOSH kti 40 ppm CCROV/SA* 100 ppm SA.CFVPAPROV Con 200 ppm CCRFOV/GMFOV/PAPRTOV/ SAT CFV8CBAF/SAF | SCBAF PD.PP/SAF-PDPP ASCBA Escape GMFOV/SCBAE Intt.ayfa.Mee. throat; hdanCftpu, dta. ftg, mW, dmaoe NIOSH 0 05 ppm SA* 0 125 ppm SACF* 0 25 ppm SCBAF/SAF 1 ppm SAF PD PP SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Inh Imt eyes skin rasp sys Abs chest tight dysp cough Ing sore throat bron wheez Con pulm edema possible resp sens asthma Breath: Swallow-' In Breath Swallow ,*. k -x*i -">> Tf ` f - >'V * I".............--i ri! --thw------/* In immed Eyes skin respsys Water flush Immed Resp support Medical attention nmed ^ Chemical natna, etructurafformula, CAS and RTECSNoa, and DOT ID and guide Hob Synonyms, trade names, and conversion factors MMpropoxycthdnQt (CH^CHOC^Ci^OH IflMM KU0MOQ9 *&5W*V* isopropyl vMf) Isopropyl CaUoaofw*. tapropyi fltyool 180 Isopropyl acetate CHjCOOCH(CHj)2 108-21-4 AI4930000 1220 129 taproot atahol (CH^SHOK 87-83-0 NT8060000 1219-00. Isopropylamine (CHj)jCHNH2 75-31-0 NT8400000 1221 132 Isopropyl ester of acetic acid 1-Methylethyl ester of acetic aod 2-Propyl acetate 1 ppm *4 18mg/m3 Dimethyl carWnoi, IPA, SrWPpijW) seo-Propyl atoohol, Rubbing alcohol ippmaZ^Sne/tn9 2 Ammopropane Monoisopropylamina 2-Propylamine eec-Propylamine 1 ppm 2 42 mg/m5 Exposure (TWA unless noted otherwise) ARDQQ022904 OLH Physical description foai See Appendix D OSHAf nope ND Colorless liquid with a mild, ethereal odor Chemical and physical properties MW, BP, SOL FI P, IP, Sp, Gr, flammability VP, FRZ UEL, LEL MW 104 2 BP: 283`F Sot Mtsdbto FI;R(oc) 02*F iP ? VP" 3 mm FRZ, 7 UEL 7 LEL 7 IncompetMMes and reactivities Measurement method (See Table 1) Oxkfizora None avaSsble NIOSH See Appendix D OSHAf 250 ppm (950 mg/m3) 1800 ppm Colorless liquid with a fruity odor Sp Or 090 Owe )C Flammable Lquid MW 102 2 BP 194'F Sol 3% FIP 36 F IP 9 95 eV VP 42 mm FRZ 92*F UEL 8% LEL(100*F) 18% MOSH 400 ppm (880 mg/m5) ST 600 ppm (1226 rn^n5) OSHAf l&X** NIOSH See Appendix D OSHAf 5 ppm , (12 mg/m3) 2000 ppm Colorleea liquid (10KLEQ with the odor of tubbing alcohol Sp Gr 0 87 Class IB Flammable Liquid MW 001 BP-OTF St* MtsdbMi RPtWF iP-IOIOeV VP-33 mm FRZ.-127*F UL(200*F) 127% LEL20* 750 ppm Sp.Gr 0.79 Cmit IS Flammable Liquid Colorless liquid with an ammoma- like odor [Note A gas above 91*F) MW 591 BP 91*F Soi Miscible FI P(oc) -35*F IP 8 72 eV VP 460 mm FRZ 150'F UEL 7 LEL 7 Sp Gr 0 69 Class IA Flammable Liquid Nitrates strong oxidizers alkalis & acids Char GcfrlD IV [#1454] Strong oxidizers, acetaldehyde, chlorine, ethylene oxide, acids, Isocyanates Otar 2-Butanoi/ GC/?ID, IV {#1400 Alcohols i] Strong acids strong oxidizers aldehydes ketones epoxides Bub NaOH GC/FID H(3) [#S147] Personal protection and sanitation (See Table 3) SMn. Prevent skin contact Eyes. Prevent eye contact Vwahettn. Whencontain Remove: When wet (Aamm) Chwpe: NR [2-tsopropoxyethanoJ] Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact Whencontam When wet (flamm) NR (isopropyl acetate] BMK - Prevent akin contact Eta* Prevent eye COrtBCt npipvii wnwMKifn Whenwet (Hamm) OtanoK. s *'i HR Poopmpyt HeoM Sion E^s Washskm Remove Change Provide Prevent skin contact Prevent eye contact Whencontam When wet (Hamm) NR Eyewash Qutckdrench [Isopropylamine] ABD00022905 Recommendations for respirator concentration tor uaa (MUC) (Sea Table 4) Route Symptoma (Sea Table 6) TBAL Hi In animate krteyae, Abs akn.hemog,anemia, tag pulmedema Con OSHA 1800 ppm SA CF^SCBAF/SAF SCBAF PD PP/SAF PO PP ASCBA Escape GMFOV/SCBAE Inh imteyes skin nose Ing derm Con mammals narco Health hazards First aid (Sea Table 8) is Breath .omow Irr Immed Water wash prompt Reap, import Medical attention knraad Targetorgane (Sea Table 6) Eyes, akin, ran eye, blood f Breath Swallow Irrimmed Water flush prompt Rasp support Medical attention romed Eyes skin resp sys CNS NIOSHOSHA 2000 ppm SA CFWCRFOV/GMFOV/ PAPRQWSCBAF/SAF | SCBAF PO,PP/SAF PO?P ASCBA Escape GMFQV/8CBAH J* tog 181 OSHA 125 ppm SA CF/PAPRSC 250 ppm CCRFS/GMFS/PAPRTS*/ SCBAF/SAF 750 ppm SAF PD PP SCBAF PD PP/SAF PD PP ASCBA Escape GMFS/SCBAE Abs J?8 Con ."im ii' i r_________ s. Imteyes skin nose throat pulm edema vis dist eye skin bums derm Eye Stun Breath Swallow Irrimmed Water flush immed Reap support Medical attention immed Eyes skin respsys Chemical name, structure/formula, CAS andRTECSNos, and DOT ID and guide Nos Synonyms, tradenames, factors N-laopropylanillne CjHjNHCmCHj), 766-52-5 BY4190000 N-IPA IsopropyleniUne, N- (1-MettiyMhyl)- banzanamlne, N-Phenyllsopropytamlne 182 Isopropyl etlw (CHJjCHOC^CHjJj 108-20 3 TZ5425000 1 ppm 5 53 mg/m3 Dllsopropyl ether Dllsopropyl oxide 2-lsopropoxy propane 1159 127 iMjrapyl gtycfdyl 4016-14-2 T23S00000 Kaolin 1332 58 7 GF1670500 1 ppm = 4 18mg/m3 1 2-Epoxy-3-iaopropoxyigr*1 taoprepoxyroethyl onrane 1ppm4 75mg/m China clay Clay Hydrated aluminum silicate Hydnte Porcelain clay [Note Mam constituent ot Kaolin is Kaolinite (AljSijO,(OH)4) ] Exposure knits (TWA unless noted otherwise) NIOSH flSmg/m3) [skin] OSHAt none NIOSH/OSHA 500 ppm (2100 mg/m3) ABD00022906 IDLH Physical description NO Clear yellowish liquid with a sweet aromatic odor Chemical and physical properties MW, BP, SOL FI P, IP, Sp, Gr, flammability VP, FRZ UEL, LEL MW 135 2 BP 397*F Sol Insoluble FI P(oc) 190'F IP-? VP(77*F) 6 03 mm FRZ. -58*F UEL ? LEL? 1400 ppm [10%IEL) Colorless liquid with a sharp sweet ether like odor SpGrteO'F) 003 Class DIB Combustible Liquid MW 102 2 BP 154'F Sol 0 2% FI P -18*F tP 9 20 eV VP 119mm FRZ 76*F UEL 7 9% LEL14% NOSH C 50 ppm (240 mg/ht*) [15-mn] OSHAt 50 ppm (240 mg/m) NIOSH 10 mg/rn3 (total) 5 mg/m3 (resp) OSHAt 15mg/m3 (total) 5 mg/m3 (resp) 400 ppm Colorless Bquld Sp Gr 0 73 Class IB Flammable Liquid MW 115 2 BP 279*F Sot10% FI P- 02*F IP ? VPCT7V11 mm FRZ. 7 UEL ? LSL? Sp Gr 092 Cuts tC Flammable Liquid NO White to yellowish MW vanes VP 0 mm or grayish powder BP ? (approx) [Note When Sol Insoluble MIT ? moistened darkens FI P NA UEL NA & develops a IP NA LEL NA day-like odor) Sp Gr 1 8-2 6 Noncombustible Solid Incompatibilities and reactivities Measurement method (See Table 1) Norn reported Fllter*(2), Methanol HPLC/UV OSHA 1*76] Strong oxidizers acids [Note Unstable peroxides may form on long contact of isopropyl ether with air) Char GcfrlO IV [#1616] Strang oxidizera atrong eauatica [Note May form ej^tooN* peroxides upon exposure to air or Ight] Char, t?FIO, IV [#1620] None reported Filter none Grav IV [Particulates NOR #0500 (total) #0600 (rp)) Personal protection and sanitation (See Table 3) Stan WMhskin Remove; Chengr Prevwe, Prevent skin contact Prevent eye contact Wien contain Mien wet or contam NR Quickdrench {N-teoprapytaniline} Skm Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam When wet (flamm) NR [isopropyl ether] Stdrv wSahsfctp. Remove: Change: Prevent ekln contact Prevent eye contact Whencontam Whenwet (lernm) NR. (laoprapyl gtyddyl ether] Skm Eyes Wash skin Remove Change NR NR NR NR NR [Kaolin] ABD00022907 Recommendations for respirator selection -- maximum concentration for uaa (MUC) (Sat Table 4) Route Symptoms (See Table 5) TBAL Wt Ink eyes, skin heed, Abs weak, dizz: cyan, ataxia, ly dyap on effort, teear; Con methemo Health hazards First ski (See Tabls 6) Target organa (Sea Table 6) Breath Swallow trr immad Soap waPi prompt Reap support MeacaTattenbort immad Eyee sldn raepsya, blood. CV8, liver, kidneys NIOSH/OSHA 1400 ppm CCROV/PAPROV'/GMFOVf SA /SCBAF SCBAF PO PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Wi Irtg Con Imt eyes skin nose resp discomfort derm m animals drow dizz uncon narco IS, Breath Swallow Irrimmed Soap wash prompt Reap support Meoical attention mvned Eyes skin respsys CNS 183 NIOSHOSHA 400 ppm. 8A.CF4SCBAF S SCBAF PO,PP/SAF PO.PPASCBA Escape GMFOV/SCSAE Hi Ink eyes, akin, upper reapeye, akin sene, Con poiafcla hamato, rspro effects IK Breath. Bwaffowt (rr burned SoapweWi Immad 2MCnEniJm%oLnn burned Eyes. aldn. reap aye, blood, rapro aye TBAL Irh Chronic pulm fib Con stomach granuloma Eye Breath Irr immed Fresh air Resptys stomach Chemical name structure/formula and DOT ID and guide No* Kapone c,,ci10o 143-50-0 PC#575000 Kerosene 8008 20 6 184 OA5SOOOOO 1223 128 Katena CHjCO 483-51-4 OA7700000 Lead Pb 7439 92 1 OF7525000 Synonyms, trade names. and conversion factors Exposure limits (TWA unless noted otherwise) ABD00022908 IDLH Physical description Chlordacone Dacachtoroodahydro-kepone2-one, Decachloroodahydro-1 3 4 metheno-2H-cydobuta(od>pentalen-2-one, Dacachlorotetrahydro-4 7methanomdarwone. NIOSH Ca See Appendix A 0 001 mg/m3 OSHA none Ca [ND) Tan to whita crystalline odorless solid [insecticide] Fuel Oil No 1 NIOSH Range oil 100 mg/m5 [Note A refined petroleum OSHA solvent (predominantly none C.-C-) which typically is25%normalparaffins 11% branched paraffins 30% monocycloparaffins 12% dicycloparaffins i % tncycioparaffms 16% mononuclear aromatics & 5% dmuclear aromatics ] NO Colorless to yellowish oily liquid with a strong character istic odor Carbcmtfftene Ethanona, Keto-ethylene 1ppm1 72 mgfm3 Lead metal Rumbum NIOSH 0 5 ppm (0 9 mg/m1) ST1 5 ppm (3 mg/m5) OSHAf 0 5 ppm (0 9 mg/m3) 5 ppm Colortees gas with a penatratinQ odor NIOSH 0 100 mg/m3 See Appendix C OSHA'f1910 10251 0 050 mg/m3 See Appendix C 100 mo/m3 (as Pb) A heavy ductile soft gray solid ( Note The REL and PEL also apply to other lead compounds (as Pb) See Appendix C ) Chemical and physical properties MW, BP, SOL FI P, IP, Sp.Gr, flammability VP, FRZ UEL LEL MW 490 6 BP Sublimes Soi(212*F) 0 5% FIP NA IP 7 VP(77'FV <3x ICr mm MLT 662`F (Sublimes) UEL NA LEL NA Sp Gr ? Noncombustible Solid MW 170(approx) BP 347 617*F Sol Insoluble FIP 100 162'F IP > VP(IOO'F) 5 mm FRZ 50'F UEL 5% LEL 07% Sd Gr 0 81 Class II Combustible Liquid MW 42 0 BP -69*F Sd Reads HP NA (Gas) IP 9 61 eV VP >1 atm FRZ -238*F UEL ? LEL ? RGaaO 145 FlammableGm MW 207 2 BP 3164'F Sol insoluble Fl P NA IP NA VP 0 mm (approx) MLT 621 "F UEL NA LEL NA Sp Gr 11 34 Noncombustible Solid in bulk form Incompatibilities and Measurement method (See Table 1) Adds add fumes Filter/ Imp Benzene/ Methanol GC/ECO IV (#5608] Strong oxidizers Char CS, GCfriD IV (#1550 Naphthas] Water alcohols (Note Readily polymerizes Reacts with water to form acatic mod ] Bub FeCl, Vis ' SSU Strong oxidizers hydrogen peroxide acids Filter HNOJH.O, AAS1 ? J III [#7082] [Also #7105) Personal protection and sanitation (SeeTable 3) Skn. Eyes. WwheHn Remove; CtaroK Provide. Prevent skin contact Prevent eye contact Whan contanWDeily Mien wet or contam Daily Eyewash. CMdtdrench (Kepoiwi Skn Eyes Wash skin Remove Change Provide Prevent skin contact Preventeye contact Mien contam When wet or contam NR Quick drench {Kerosene] sun Eyes: Wash sldn Remove Change NR NR NR NR NR [Ketane] Skin Eyes Wash skm Remove Change Prevent skin contact Prevent eye contact Oauy When wet or contam Daily [Lead) ABD00022909 Recommendation* for respirator selection--maximum concentrationforuse(MUC) (See Table 4) Health hazards ---------------------------------------------------------------------------------------------------------------------------- Route Symptoms Flrstaid Targetorgans (See Tables) (See Table 6) (See Table!) NIOSH V SCBAF PD.PP/SAF PD.PP ASCBA Eecape QMFOVH&SCSAE Hi Head, tier tremor bver Abs kidney damage, vis diet; I?9 ataxia chest pain, skin Con eryt; teeticUar atrophy, low sperm count, (care] IS, Breath Swallow- Irr immed Soap wash immed Rasp support Mwadfttantion immed Eyes, skin, reepfye. CNS kver.lddnaye. repro eye pnvkm*. liver cancer] NIOSH 1000 mg/m5-CCROV/SA 2500 mg/m5- SA CF/PAPROV 5000 malm5 CCRFOV/GMFOV/PAPRTOV/ SCBAF/SAF SCBAF PO PP/SAF PO PP ASCBA Escape GMFOV/SCBAE Inn Con irnteyes skin nose throat burning sensation inchest head nau weak restless mco coni drow vomit diarr derm chemical pneu (aspir iiq) ln Breath Swallow Irr immed Soap flush immed Resp support Medical attention immed Eyes skin resp sys CNS NIOSH/OSHA 5 ppm SA7SCBAF 6 SCBAF PD.PP/SAF PD.PP ASC8A Eecape GMFOV/SCBAE Hi Ink eye*, akin, noee Con throet, reap eye, pulm edema Breath Reap support Eyes skin reap ays OSHA 0 5 mg/m HiE/SA 1 25 mg/m5 SA CF/PAPRHiE 2 5 mg/m1 HiEF/SAT CF/PAPRTHiE/ SC8AF/SAF 50 mg/m5 SA PD PP 100 mg/m5 SAF PD PP SCBAF PD PP/SAF PD PP ASCBA Escape HiEF/SCBAE Irft ing Con Weak lass msom facial pallor pal eye anor low-wgt malnut constip ahdom pain colic anemia gingival lead line tremor para wrist ankles encephalopathy kidney disease irnt eyes hypotension Eye Skin Breath Swallow Irr immed Soap flush prompt Resp support Medical attention immed kidneys blood gingival tissue Chemical name structure/formula, CAS and RTECS Nos, and DOT ID and guide Nos Synonyms trade names, and conversion factors Calcium carbonate, Natural calcium carbonate [Note: Calotte & 3SU Exposure (TWA unless noted otherwise) 186 lindane CgH8Cl6 58-89-9 GV4900000 2761 151 BHC HCH y Hexachlorocyclohexane gamma-isomer of 1 2 3 4 5 6Hexachlorocyclonexane NIOSH/OSHA 0 5 mg/m3 [skin] ABD00022910 OLH Physical description ND Odorless, whitato ten powder 50 mg/m5 White to yellow crystalline powder with a slight musty odor [pesticide] Chemical and physical properties MW, BP, SOL FI P IP, Sp,Gr, flammability VP, FRZ UEL.LEL tn,.,'rvv,. RP-NA #*NA \ivii yp Omm J&Sfl 2442*F StfST*' tfUNA Solid fncornpadbil/tfes ana reactivities Measurement method (See Tablel) Fluorine,magnesium, ad#,alum, emmortum alts Fitter; p.. > IV J 1 {Parfiataa# NOR: r , #050fl. ,-j* r MW 290 8 BP 614'F Sol 0 001% FI P NA IP 7 VP 0 00001 rim MLT 235*F UEL NA IEL NA Corrosive to metals Filter/Bub Isooctane GC/EConD IV [#5502] Sp Gr 185 Noncombustible Solid but may be dissolved in flammable liquids LPG CjHJCjHgTC^H x/CjH, 68476-85-7 SE7545000 1075115 Bottled gu Compressed petroleum gas Liquefied hydrocarbon gas Liquefied petroleum gas LPG [Note A fuel mixture of Kipane propylene tenes & butylenes ] 1 ppm = 1 72-2 37 mg/m3 NIOSH/OSHA 1000 ppm (1800 mg/m3) 2000 ppm [10%LEL) Colorless noncor rosive odorless ISwhen pure iote A foul smelling odorant is usually added Shipped as a liquefied compressed gas MW 42 56 BP >-44*F Sol Insoluble FI P NA (Gas) IP 10 95 eV VP >1 atm FRZ 7 UEL.95% 8.5% RGasD 1 45-2 00 Flammable Gas (Propane) 1M (Butane) Strong oxidizers chlonne dioxxle Combustible gee meter none none IU2) l#SSi93) Personal protection (See Table 3) Stan. Em. Weahskln Remove: Changr NR NR NR NR NR [Limestone] Skin Eyes Wash skin Remove Change Provide Prevent skin contact NR When contam When wet or contam Daily Quickdrench [Lindane] Stan. uSSieldn Remove Change Provide Prevent skin contact Prevent aye contact Brush (DO NOT WASH) Whan wet or contam Daily Eyewash Quick drench (>0 5 mg/m*) [UWuffl hydride] Stan Eyes wash skin Remove Change Provide Frostbite Frostbite NR When wet (flamm) NR Frostbite [IPG1 ABD00022911 Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table 4) TBAL Route Symptoms (See Table S) Irh Irrtteyas, eton, muc memb, Con oough anew, (hin, lac Health hazards Flrstaid (See Table ft) Eye Stan Breath In Immad Soap wash Fresh air Target organs (See Tables) Eyes, skin, reapays NIOSH/OSHA 5 mg/m1- CCROVDMFu/SA 12 5 mg/m5- SA CFVPAPROVDMFu 25 mg/m5 CCRFOVHiE/GMFOVHiE/ PAPRTOVHiEVSCBAF/SAF 50 mg/m5 SAF PD PP SCBAF PD PP/SAF PD PP ASCBA Escape GMFOVHiE/SCBAE Hi Imteyes skin nose Abs throat head nau dome Ing convuls rasp difficulty Con cyan aplastic anemia muse spasm mammals liver kidney damage NIOSH/OSHA 0 26 mg/m5-WE/SA 0 S mg/m1- SA.CF*/HiEF/PAPRHIEV SCBAF/SAF 5 SCBAF PD,PP/SAF PD.PP ASCBA Escape HiEF/SCBAE Hi Irrtt eyes, skin aye Jhfl skin bums mourn Con esophagus: bums (if Ingested) nau, muse twncha*. mental conf- blurred vision Eye Skin Breath Swallow In immad Soap wash prompt Rasp support Medtat attention immed Eyes skm respsys CNS blood liver kidneys E Breath Swallow In Immad Brush (DO NOT WASH) Reap support Medical attention immad NIOSH/OSHA 2000 ppm SA/SCBAF SCBAF PD PP/SAF PD PP ASCBA Escape SCBAE H Li-head drow asphy Con Itq frostbite (hq) is, Breath Frostbite Frostbite Resp support Resp sys CNS Chemical name, structura/formula, CAS and RTECS Nos , and DOT ID and guide Noe Synonyms, trade names, and conversion factors MflCO, -0 Carbonate! Hydromagoa MagriMfum carbonate. m/*&m***+ no>urs#y flctuntan town 188 Magnesium oxide fume MgO 1309-48-4 OM3850000 Magnesia fume * Malerc anhydride <W>, 108-31-6 ON3675000 2215 156 cts-Butenedioic anhydride 2 5-furanedione Maleic acid anhydride Toxilic anhydride 1 ppm 4 01 mg/m5 Exposure (TWA unices noted otherwise) NIOSH 10 gSfi Ignite5 W# (resp) NIOSH See Appendix D OSHAT 15mg/m} HaF* NIOSH/OSHA 1 mgfm3 (0 25 ppm) ABD00022912 LH Physical description ND White odorless, crystalline powder 750 mg/ms Finely divided white particulate dispersed in air [Note Exposure may occurwhen magnesium Is burned thermally cut or welded upon ] 260-thStef ^sop-broom tt ytemK ai -tS-t--SaAr.SecTfcPJIj;;. 10 mg/m5 Colorless needles wh4e lumps or pellets with an imtating choking odor Chemical and physical properties MW, BP, SOL FI P, IP, Sp.Gr, ftamrnabMy VP.FRZ UEL.LEL MW- 943 VP-Qmm BP Decomposes (approx) Sofc0.01* MLTS62`F R.P NA (Decomposes) IP NA UE^ NA LEL-NA Incompatibilities and reactivities Acids, formaldehyde Sp^ 2.86 Noncembe^Ma Solid MW 40 3 BP 6512*F Sol(86*F) 0009% FI P NA IP NA VP 0 mm (approx) MLT 5072*F UEL NA LEL NA Chlonne tnfluonde phosphorus penta- chlonde Sp Or 3 58 Noncombustible Solid mm 1 FRZtarp Oat?'. Bttene oxteteare, ssa~ "* ffteteTcorroelye tetpateis.) tat lNS(9on^vstltte4^,bUteter|tel^uilWr)0d|te> MW- 981 VP 0 2 mm Strong oxidizers BP 396*F MLT 127*F water alkalis Sot Reacts UEL71% metals caustics & FI P 210*F LEL 14% amines above 150*F IP 9 90 eV [Note Reacts slowly with water (hydro lyzes) to form maleic acid ] Sp Gr 1 48 Combustible Solid but may be dlfflcuk to ignite Measurement method (See Tablet) finer, none, Grav, IV (Particulates NOP #0500 (total), <to Filter Acid ICP IV [#7300 Elements) OV*2. Tetuanel Acetonor GOFPO; IV (#5600. Orgarw- Bub none HPLC/UVD IV #3512] Personal protection (See Table 3) 8km. Bk Washakin. Remove Change nr NR N.R NR NR ABD00022913 Recommendations for respirator concentration for use (MlIC) (See Table 4) TBAL Route Symptoms (Sae Table 5) Inh Irrtt eyes, akin, resp Con ays, cough Health hazards First aid (See Table 6] Eye. Breath Irr immed Fresh afr Target organa (See Table 5) Eyes, akin, teepee [Magnetite] Skr Eyes Wash skin Remove Change NR NR NR NR NR [Magnesium oxide fume] SMA. v Prevent stovcented gKw 5K2SZ^0,," nNQMn;: wntooofwm film? tthenMtoroantam Change: : Pa* '. Skn Eyes Wash skm Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet or contam NR Eyewash i. OSHA ISO mg/m3 DMFu/SA 375 mg/m3 SA CF/PAPRDMFu 750 mg/m3 HiEF/PAPRTHlEV SCBAF/SAF SCBAF PO PP/SAF PD PP ASCBA Escape HiEF/SCBAE Inh Imteves nose Con metal fume fever cough chest pain flu-like fever Breath Resp support Eyes resp sys 189 MOM .C6R0VDMUSA _ a., : fg, r-ggsgfgr w %sWtC^AeXIVOVrH, -_ 'iSS'' g*wa*w' fPO,PP^AF^PPA8CiA , * ^'v - f1 " -'s/>>; OM--P--Q---V---H---i-E--^--C---f-l-M---E- ------------------------------------j- *tT ;,-ii l" *'& *..' s'JZA JxAr*^1' ^. >,'- v. &! f -l" mt' *> >' , __ j___t&jsr NIOSH/OSHA tO mg/m3 SACFVSCBAF/SAF | SCBAF PD PP/SAF PD PP ASCBA Escape GMFOVHiE/SCBAE Hi Imt nose upper resp sys Ing con) photo double vision Con bronchial asthma derm Eye Skm Breath Swallow Irr immed Soap wash Immed Reap support Medical attention immed Eyes skin resp sys [MaleK anhydride] Chemical name structurei/formula, CAS and RTECSNos and DOT ID and guide Nos Synonyms trade names and conversion factors Kelonaldehyde CHOCH^CHO 842*78-9 'DCB47SOOO Malonic aldehyde, Matonodiaidenyde PropanediH, 1,3-PropanadM [Note- Pure Matonaldehyde is unstable and may be used as Its sodium saR ] Exposure IrrJts (TWA unless noted otherwise) ABD00022914 KXH Physical description NIOSH Ca See Appendix A See Appendix C (Aldehydes) OSHA Ca [NO) Solid (needles) Chemical and physical properties MW, BP, SOL FI P IP Sp Gr flammability VP FRZ UEL.LEL MW 721 BP 7 Sol 7 FI P 7 IP 7 VP 7 MLT 161*F UEL 7 LEL 7 Sp Gr 7 190 Malononilrile NCCHjCN 109-77 3 003150000 Cyanoacetomtnle Dicyanomethane Malonic dinitnle NIOSH 3 ppm (8 mg/m5) OSHA none ND White powder or MW 66 1 VP 7 colorless crystals BP 426*F MLT 90"F (Note Melts Sol 13% UEL 7 above 90'F FIP(oc) 266'F LEL 7 Forms cyanide m IP 12 66eV the body] 2847 153 Srbbbs^ Mn (Wetel) 743M84 (Metal) 000278000 (MftaQ Manganese cyctopentadienyl tncarbonyl (as Mn) CjHjMn(CO)j 12076-65-1 009720000 1 ppm * 2 70 mg/m3 Mangeneaemetat casldelmanganese, (Mppnii0 upon alt specltomanganeee oompotatd Cydopentedienylmanganese tncarbonyl Cydopentedienyl tncarbonyl manganese MCT Sp Gr 1 16 Combustible Solid NIOSH* 800 mg/m* Metal: A hitfmus, ImaMi9 ST3mgftn* (as Mn) biWe, edvmy sold. 08HM* CBraofot3 nMK Also seespeqMc tebogs tor Mangartaaa i trtcarbonyl, Mad SPSS'S MW) 949 8*3664*1* SoLlnatduble R.P'NA P-NA VP-Omm tmnti Sp.Gr 7J2Q (MetaO Metal- Cofiwuatible:8did NIOSH 01 mg/m5 [skin] OSHAf C 5 mg/m1 ND Yellow crystalNne MW 204 1 VP 7 solid with a BP Sublimes MLT 167*F characteristic odor Sol Slight (Sublimes) [Note An antiknock FI P 7 UEL 7 additive for IP 7 LEL 7 gasoline May be found in an oil & gaseous solution ] Sp Gr 7 Combustible Solid Incompatibilities and reactivities Measurement method (See Table 1) Proteins (Note Pure compound Is stable under neutral conditions but not under addle eondtttone ] None available Strong bases [Note May polymerue violently on prolonged heating at 265rF or in contact with strong bases at lower temperatures ] Char Toluene GC/FID NIOSH Nitnlea Cnt Doc OxMbera {Note: VWI reaot ,, wttMMtaror ataam to produce hydrogen} Filter, >Aoid. C* < IV None reported <, None available Personal protection (See Table 3) Sion Eyes Wash skin Remove. Cfcraa. Provide Prevent skin contact Prevent eye contact When contam/Daily When wet or contain Daily Eyewash Quickdrench [Malonsldehyde] Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact Whencontam When wet or contain Daily Eyewash Quick drench [Malononitnle] SMn. Eye* Washakin Remove. Change NR NR NR NR NR IMenganeee compound* and fume {as Mn Skm Eyes Vvastiskin Remove Change Prevent skin contact Prevent eye contact When conlam When wet or conlam Daily ABD00022915 Recommendations for respirator concentration for use (MUC) (See Table 4) NIOSH SCBAF PD PP/SAF PD.PP ASCBA Escape GMFOV/SCBAE Route Symptoms (See Table 6) Inh trrtt eyes, skin, rasp sya, Abs cough, CNS depres, (care] Ing Con Health hazards First aid (See Table 6) Target organs (See Table 6) fieLi SwaBow- Irr Immed Water flush Immed Reap support Matncal attention Immed Ejres, skin, reap ay*. (inaramata. thyroid gland tumors] NIOSH 80 mg/m5 SA 200 mg/m5 SA CF 400 mg/m5 SCBAF/SAF 667 mg/m* SAF PD PP SC8AF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Inh Abs Ing Cor. Irnt eyes skin nose throat head dizz weak gidd conf convuls dysp abdom pain nau vomit Eye Skin Breath Swallow Irr immed Water wash immed Resp support Medical attention immed Eyes skin resp sys CNS CVS NIOSH 10 mg/m* DMXSQ'/SA 26 mg/m* SA-CF/PAPRDM* 60 mg/m1- HEF/SAT CF/PAPRTHIE/ SCBAF/8AF/ 600 mg/m* SA-PD.PP _,, | 3C&F PB.PP/SAF PO.PP AStiBA Escape HEF/SCBAE Pattwwi's.igthania. Ing intom, rpptaiconr; matalnjmaiaver dry sasr* TBAL Inh In animals imt skin Abs pulm edema convuls CNS Ing respsys kidney changes Con deer resistance to infection Breath SwsUow immed v v jv/ - . il. ' w!SV " `y 3 Breath Swallow- Irr immed Soap wash Reap support Medical attention immed Skin respsys CNS kidneys (Manganese cyctopenladienyl incarbonyl (as Mn)l Chemical name structure/formula, CAS and RTECS Nos, and DOT ID and guide Nos Synonyms trade names, and conversion factors MMatew tetrowde (Ain) Mn,04 1317-35-7 OPM96000 Manganese oxide, Manganontanganlc oxide, Trlmanganeae tetraoxide, Trtmanganasa tatroxide 192 Marble CaCO, 1317-66-3 EV9580000 Calcium carbonate Natural calcium carbonate {Note Marble is a metamorphic form of calcium carbonate ] Mercury oompounds [exoept (organo) afcy^(asHg) Hg (Metal) 7439-97-6 (Metal) OV4SSOOOO (Metal) 2809 172 Mercury (organo) alkyl compounds (as HgJ Mercury metal Colloidal mercury Elemental mercury, MetWbc mercury Quicksilver Synonyms of `other* Hg compounds vary depending upon the specific compound Synonyms vary depending upon the specific (organo) alkyl mercury compound Exposure limits (TWA unlect noted otherwise) NlOSH See Appendix 0 OSHAf CSmg/m3 ABD00022916 IDLH Physical description NO Brownish-biack powder {Note Fumes are generated whenevermanganoee oxides are heated strong^ In air] Chsmlcal and physical properties MW, BP, SOL FI P.IP.Sp, Gr, flammability VP FRZ UEL, LEL MW- 226 8 BP ? Sol Inaoluble FIP NA IP NA VP 0mm iraw UEL NA LELNA SpGr 488 Incompatibilities and reactivities Measurement method (See Table 1) Soluble m hydrochlonc aod (liberates chlorine gas) Filter Acids, ICP; IV (#7300 Elements] NlOSH 10 mg/m3 (total) 5 mg/m5 (resp) OSHA 15 mg/m5 (total) 5 mg/m3 (resp) NOSH Hg Vapor uOSmgfai5 C01 mg/m1 (akin) OSHAt C01 mg/rn1 NlOSH 0 01 mg/m1 ST 0 03 mg/m3 (skin) OSHAT 0 01 mg/m3 ND Odorless white MW 1001 VP 0 mm Ffuonne magnesium Filter powder BP Decomposes (approx) acids alum ammonium none Sol 0 001% MLT1517 salts Grav FI P NA 2442*F IV IP NA (Decomposes) UEl NA [Particulates NOR IEL NA #0500 (total) Sp Gr 2 7-2 9 Noncombustible Solid #0600 (resp)) lOmg/m1 (asHg) Metal Sitver-white MW 2008 VP 00012mm heavy, odorless BP 674*F FRZ 48*F liquid Sol Insoluble UEL NA [Note 'Other* Hg FIP NA LELNA compounds inwide IP ? at inorganic & aryl Hg compounds except (organo) ikyls) Sp.Gr 13 6 (Metal) Metal Noncombustible Liquid Acetylene ammonia, chlorine dioxide, azides, calcium (amalgam formation) odium carbide Uthlum, rubidium, copper HopesUte, Acid AA cold IV (#6009 Mercury) 2 mg/m1 (as Hg) Appearance and odor Properties vary depending vary depending upon upon the specific (organo) the specific alkyt mercury compound (organo) alkyl mercury compound Strong oxidizers such as chlorine None available Personal protection and sanitation (Saa Table 3) Skin. Eyes Weehstin. Remove: Cftenge: NR MR MR N R. Daily ABD00022917 Recommendations for respirator concentration for use (MUC) (See Table 4) TBAL Route Symptoms (See Table 5) Ini) Asthenia, msom, mental log conf low-back pam, vomit; Con mal ftg, kidney damage; pneultia Health hazards First aid (See Table <) IS, Breath Swallow Irr immed Soepweah Reap support Medcai attention knmed Target organs (See Table 5) Reap sys, CNS, blood kidneys TAHigWMM Wraxida-ttt Un)\ Skin Eyes Wash skin Remove Change NR NR NR NR NR TBAL Inti Irnteyes skin mucmemb Con upper resp sys cough sneez rhin lac tz Breath Irr immed Soap wash Fresh air Eyes skin resp sys [Marble] Sttt Eyes. Weehtkm. Remow: Cherge: Prevent skin contact MR Whenoeaim W*n wet or content Oaty See Appendix E for Respirator Recommendations tor Mercury oompound* [except (orpeno) afcylaj. Mi Aba * Con imt ayee, skin, cough, chest pWn dysp. bron pnaunr, tremor, inaoro, my indecision heed ftg waste; stomatitis, satv; Cm dist, anor kw-wgt prat IS Breath Swallow Irr immed Soep weeh prompt Reap support Medal attention fimo Eyes, skin reap eye, CN8, kidneys [Mercuiy-compounds (except (organo) Wfcyisl (aa Hoi Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet or contam Daily Eyewash Qmckdrench NIOSH/OSHA 0 1 mg/m5 SA 0 25 mg/m5 SA CF 0 5 mg/m5- SAT CF/SCBAF/SAF 2 mg/m5 SA PD PP SCBAF PD PP/SAF PD PP ASCBA Escape SC6AE [Mercury (organo) alkyl compounds (as Hg)] Inh Pares ataxia dysarthria Abs vision heanng dist Ing spasticity jerking limbs Con dizz salv lac nau vomit diarr constip skin bums emotional dist kidney inj possible terato effects Eye Skin Breath Swallow Irr immed Soap wash immed Resp support Medical attention mmed Eyes skin CNS PNS kidneys 193 Chemical name, structure/formula, and DOT ID and guide Nos Synonyms, trade names factors E^osure (TWA unless noted otherwise) Meaty oxide (CH^C-CHCOCHj MI-79-7 8B4SOOQ00 laobutanytmethyl ketone, IsopropylKteneacetore, MoihyHscibuteoyl ketone, 4-Methyl-3-panten-2-one MQSH lOppm ^ (40 mgtof*) OSHAt 25 ppm (I00mg/m*) 194 13*0 12*' Methacrylic acid CHj=C(CHj)COOH 79-41-4 OZ297SOOO 1 ppm 4.WmgffnJ Methacrylic acid (glacial) Methacrylic acid (inhibited) a -Methacrylic acid 2-Methylacrylic acid 2-Methylpropenoic acid NIOSH 20 ppm (70 mg/m3) [skin] OSHAT none 2531 153P (inhibited) 1 ppm = 3 52 mgTm3 Mathamyl LonraM, Matty NnMtyamlno>- CH^C(6CH1)N0C(O)NHCH3 ceiboty)0ty)atttanlmi- 18783-77-6 S44ed^^methy)cerbamoyt- AK2B7SOO0 cavJMaacMnddate MOSH 2 5mgfm* OSHAt none 2757 161 (carbarnla pesticide, sold, nos.) ,5 Methoxychlor (C^H^OCHjJjCHCCIj 72-43-5 KJ3675000 p p Dimethoxydiphenylln chloroethane DMDT Methoxy-DDT 2 2-bis(p Methoxyphenyl) 1 1 1-tnchtoroethane 1 1 l-Tnchloro-2 2-blS (p-methoxyphenyl)ethane NIOSH Ca See Appendix A OSHAt 15 mg/m3 2761 151 (organochlonnepesticide solid nos) ABD00022918 IDLH Physical descnption 1400 ppm Orty, colorless to Ilght-yeBow liquid wtth a peppermint- or noney-liIce odor Chemical and physical properties MW, BP, SOL FI P.IP.Sp, Or, flammability VP, FRZ UEL, LEL MW- 98.2 BP-268V SoJ.SH FiP-eTV IP; 9 06 eV VP 9mm FRZ -52V UEL72% IB. 1.4% ' SP.Ori59*P) 0 86 CtssslC Flammable Liquid ND Colorless liquid MW 86 1 VP 0 7 mm or solid (below BP 325'F FRZ 61V 61 V)withan Sol(77V) 9% UEL 7 send repulsive FI P(oc) 171V LEL 7 odor IP 7 Sp Gr 1 02 (Liquid) Class IIIA Combustible Liquid NO White, oystattw MW 162.2 VP(77Vy eoHdwMia BP 7 000006 mm sUgM, sulfur- So^77V):e% MLT172V Ifcs odor UEL. HA (Insecticide} IP? LELNA Incompatibilities and reactivities Measurement method (See Table 1) Cbtkflrers, eeto Chir Methsnbi/ ", PH301, ` Ketones IQ - Oxidizers elevated Anasorb(2) temperatures Methanol/ hydrochlonc acid Water [Note Typically HPIC/UV contains 100 ppm OSHA of the monomethyi (#28] ether of hydroquinone to prevent polymerization ] Strang-bases None Mlbtli Ca (5000 mg/m3] Colorless to light- yellow crystals with a slight fruity odor [insecticide] but mayM 1 ~ ' dNsotvad kvflammaMs Btyds MW 345 7 BP Decomposes Sol 0 00001% FI P 7 IP 7 VP Very low MLT 171V UEL 7 LEL 7 Oxidizers 'v _ ** Filter Isooctane GC/ECD 11(4) [#S371] SpGr 1 41 Combustible Solid but difficult to bum Personal protection (See Table 3) Sldn Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet (flamm) NR Quick drench [Meetty! oxide] Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet or contam Daily Eyewash Quick drench ABD00022919 Recommendations for respirator concentration for use (MUC) (See Table 4} Route Symptoms (See Table 5) NIOSH 250 ppm SA CFVPAPROV* 500 ppm. CCRFOV/GMFOV/PAPRTOV1/ SCBAF/SAF 1400 ppm SAF PD PP SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Wi Ing Con Imteyes *kin,nvac memo narco coma in animals liver kidney damage CNS effects TBAL Inh Irriteyes skin muememb Abs eye skin bums Ing Con (Methacrylic aod] eV;*Wnpentad vifS*-1. V-TB*L': tnh Jn QW Health hazards First aid (See Table 6) Target organs (See Table S) i Breath Swallow Irrtmmed Water flush immed Resp support Medical attention mmed Eyes, skin, reap sys CNS liver, kidneys U,, Breath Swallow Irr immed Water flush immed Resp support Medical attention immed > Eyes skin resp sys ' tome* Sion Eyes Wash skin Remove Change Prevent skin contact NR When contam/Daily When wet or contam Daily [Methojtychlor] NIOSH * SCBAF PD PP/SAF PD PP ASCBA Escape GMFOVHiE/SCBAE tt\ In animals fasc trembling Ing convuls kidney liver damage [care] Skin Breath Swallow Soap wash Fresh air Medical attention immed CNS liver kidneys [in animals liver & ovarian cancer] ABD00022920 196 Chemical name, structure/formula and DOT ID and guide Nos Mathoxyflurane CHCIjCF2OCHj 76-33-0 KN7620000 Synonyms, trade names, and conversion factors 2.2-Dlcfik>ro-1,1 -dlfluoroethyl mdhyf attar; 2.2-Dtehloro-11-dlftuoro1-methoxyethane, MathoRurana Methoxyfluorane, Perthrane 1 ppm 6.76 mgftn* Exposure limits (TWA unless noted otherwise) IDLH NIOSH* ND C 2 ppm (13 smg/m) [60-mln| {Note REL for exposure to waste anesthetic gat] OSHA none Physical description Colorless liquid wtth a fruity odor [Inhalation anesthetic] Chemical and physical properties MW, BP, SOL FI P, IP Sp Gr flammability VP FRZ UEL LEL MW 185 0 BP 220*F Sol Slight FI P 7 IP ? VP 23 mm FRZ.-31`F UEL 7 ll<176T*7% Incompatibilities and reactivities None reported Sp Gr(77*F), 1 42 Combustible Liquid ' Measurement method (See Table 1) None avaHabM 4 Methoxyphenol CHjOCjHjOM 150-76-5 SL7700000 Hydroqumone monomethyl NIOSH ether 5 mg/m5 p-Hydroxyamsole Mequinol OSHAT p Methoxyphenol none Monomethyl ether hydroqumone NO Colorless to white MW 124 2 VP <0 01 mm Strong oxidizers None waxy solid with an BP 469 F MLT 135*F strong bases acid available odor of caramel & Sol(77 F) 4% UEL 7 chlorides acid phenol FI P(oc) 270 F LEL 7 anhydrides IP 7 50 eV Sp Gr 1 55 Combustible Solid under certain conditions a dust cloud can probably explode if ignited by a spark or Fame CH/XJOCH, 7-2Cf- AIBtOOQOO f s'. ` uwar;. Mvthyf wtarof aoette add, Methyl ethanoata ' xy?-Mi ^yy ` -1jjpnF $0ihgta* - NIOSH 200 ppm < (610 m^m') ST 290 ppm {760 mimfy 3100 ppm {10KULJ OSHAf ,v,, *! y f2f0iopmpmem. , i,, i;'-v Cotorteaa Squid adft a fragrant,, fruity odor MW-741 8ft.W*FJ 8ot2S1t - SP-14T-: Vk27nV -V^` /1' HK/J*', -*'r *, X.-5^ VPjl73mm . WSt-f-MT Wi1\ LELS.1% ' , with *aiw to V i * wkMi, Methyl acetylene CHjCeCH 74 99 7 UK4250000 Allyiene Propme Propyne 1 Propyne 1 ppm b 1 64 mg/m5 NIOSH/OSHA 1000 ppm (1650 mg/m5) 1700 ppm [10%LEL] Colorless gas with a sweet odor (Note A fuel that is shipped as a liquefied compressed gas ] MW 40 1 BP -10*F Sol Insoluble FI P NA (Gas) IP 10 36 eV VP 5 2 atm FRZ 153*F UEL 7 LEL 17% RGuO 1 41 Flammable Gas Strong oxidizers (such as chlonne) copper alloys [Note Can decompose explosively at 4 5 to 5 6 atmospheres of pressure ] Bag none GC/FID 11(5) j#S84] ABD00022921 Personal protection and sanitation (See Table 3) Recommendations for respirator concentration for use (MUC) (See Table 4) SMn. Eyaa WeaheMn Rmnova NR Prevent eye contact N.R. Wwnwatorcontam- THAI CNKSK 1 HR. I .%.< -i *. ' 'SP ,* Y` '< Route Symptoms (See Table 6] Inh Jrrtt eye*, CNS depm, Ing analgeeia.anei.eez, Con reap depree, liver, inanii repro, teeeto. effect*' Skm Eyes Wash skin Remove Chanae Provide Prevent skin contact Prevent eye contact Wien contarn When wet or con(am Daily Eyewash Quick drench TBAL Irfi Abs Ing Con tmteyes skin nose throat upper resp sys eye skin bums CNS depres Health hazards First aid (See Table 6) Eye: krimmed Sfaa Soapwash Breath, Heap-support gwNkHK Mkdc^ mention _ ( .'tented - , Target organa (Sea Table $) Eyes, CNS, liver, kidneys, repro ays. 1" >. r 1 ?-1 \. i Eye Sion Breath Swallow In immed Soap flush immed Resp support Medical attention mmed Eyes skin CNS [4-Methoxyphenol] 8lc-r /'.Prevent akincontact . Bw % ,, Prevent eye contact Skin Eyes Wash skin Remove Change Provide Frostbite Frostbite NR When wet (Hamm) NR Frostbite NIOSHfOSHA Inh 2000 ppm. CCROWSA* ta ' .3100 ppm- SA.CF*/CCRFOV/GMFOVA< Cod . I PAPROV/SCBAF/SAF c -'*!VJilBaSSB^^ , Ink eyM,akin, noee. throat; heed, drew; optic nerveJtophy, chest Ught; Inanteditrwroo* <r j\* %, , ' .' \ 'y- ',, f ,v , ' ' * * & 1' >*, ^ ' S >V' \ <\*S > NIOSH/OSHA 1700 ppm SA/SCBAF SCBAF P0 PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Inh Con (liq) Irrit resp sys tremor hyperexoitability anes liq frostbite IS. VPUwm SB* SS35BV 1-. -.**!*' * ' * * . 'V'* r* \ Vti| Jdn Eye Skin Breath Frostbite Frostbite Resp support Resp sys CNS [Methyl acetylene] Chemical name structure/formula CAS and RTECS Nos and OOT (0 and guide Nos Synonyms trade names, and conversion factors Exposure limits (TWA unless noted otherwise) 198 Methyl acetylenepropadlene mixture CH.C CH/CH,"C*CH, 59355-75-8 UK4920000 1060 115P (stabilized) Methyl acrylate 96 33 3 AT2800000 MAPP gas, Methyl acetylene-allene mixture. Methyl acetylene-propadlene mixture (stabilized), Propadlene-methyl acetylene Propyne-allene mixture Propyne-propedierte mixture 1 ppm*1 64 mg/m3 Methoxycarbonyiethylene Methyl ester of acrylic Methyl propenoate NIOSH 1000 ppm (1800 mg/m3) ST 1250 ppm (2250 mg/m3) OSKAf 1000 ppm (1800 mg/m3) NIOSH/OSHA 10 ppm (35 mg/m3) [skin] 1919 129P (inhibited) Methylacrylonltnle CHjOtCH^CN 126-96-7 UD1400000 3079 131P (InNbfted) Methylal CHpCHpCH3 109-87 5 PA8750000 1 ppm = 3 52 mg/m3 2-Cyanopropene-1, 2-Cyano-1-propene Isoprane cyanide feopropenyWtrile Methawylonttrile a-MathytaciylonJtrila 2-Mathytpropenanitrlla MOSH ippm OSKAf none 1 ppm - 2.74 mg/m3 Dimethoxymethane Formal Formaldehyde drmethyfacetal Methoxymethyl methyl ether Methylene dimethyl ether NIOSH/OSHA 1000 ppm (3100 mg/m3) 1234 127 1 ppm = 311 mg/m3 ABD00022922 IDLH Physical description Chemical and physical properties MW BP, SOL FIP.IP.Sp, Gr flammability VP, FRZ UEL, LEL 3400 ppm [10%LEL] Colorless gas with a strong characteristic foul odor [Note A fuel that ts shipped as a liquefied compressed gas} MW 401 BP -36 to -4*F Sol Insoluble FIP NA(Oas) IP ? RQasD 1 46 Flammable Gas VP >1atm FRZ -213*F UEL10 6% LEL 3 4% 250 ppm Colorless liquid with an acrid odor MW 86 1 BP 176 F Sol 6% FI P 27 F IP 9 90 eV VP 65 mm FRZ 106 F UEL 25% LEL 2 8% Sp Gr 0 96 Class IB Flammable Liquid NO Cotorlaas liquid MW 671 W^TTFf with an odor like BP 195*P 71mm bitter almonds. Sol 3% FRZ: -32'F FIP 34*F UEL 6.8% IP ? LEL2% 2200 ppm [10%LEL] Colorless liquid with a chloroformlike odor SpGr 060 Clau IB Flammable Uquld MW 76 1 BP111*F Sol 33% FI P(oc) 26*F IP lOOOeV VP 330 mm FRZ -157'F UEL 138% LEL 2 2% Sp Gr 0 86 Class IB Flammable Liquid Incompatibilities and reactivities Measurement method (See Table 1) Strong oxidizers, copper alloys [Note Forms explosive com pounds at high pressure In contact with ado containing more 67% copper | Bag. none, GC/FID, IS85] Nitrates oxidizers such as peroxides strong alkalis [Note Polymerizes easily usually contains an inhibitor such as hydro- quinone) Char CS, GC^FID IV [#1459] Strong adds, strong None oxkfizaro, aBcaA, Nght tvataMa {Note: Pulymartzabon may occur dueto elevated tampern tur*,vWMelMtit orcontactw(ma concentrated athattj Strong oxidizers acids r; Char Hexane GC/FID IV [#1611) Personal protection and sanitation (See Table 3) Stan Eyes. Wash stan Rerrme Change Provide Frostbite Frostbite NR When wet (ftamm) NR Frostbite [Methyl acetylene-propadiene mixture] Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact Whencontam When wet (flammj NR Quick drench [Methyl acrylatej Stan Eyes. Waehsktn Remove Change Prevent skin amtact Prevent eye contact Whencontam Wtien wet(ftamm) NR [Methylacrylonitrlle] Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eyecontact Whencontam When wet (flamm) NR [Methylal] ABD00022923 Recommendations for respirator concentration for use (MUC) (See Table 4) NIOSH/OSHA 3400 ppm SA/SCBAF SCBAF PD PP/SAF PO PP ASC8A Escape GMFS/SCBAE Route Symptoms (See fable 5) Hi Con (Nq) Imt resp sys, excitement, corrf enee Ihq frostbite Health hazards First aid (See Table 6) lldn Breath Frostbite Frostbite Reap support Target organs (See Table 5) Resp sys, CNS NIOSH/OSHA 100 ppm SA' 250 ppm SA CF (SCBAFISAF SC8AF PD PP/SAF PD PPASCBA Escape GMFOV/SCBAE inh Abs mg Con imt eyes skin upper resp sys - Eye Skin Breath Swailow Immmed Water flush immed Resp support Medical attention immed Eyes skin resp sys TBAL Hi Abe JjTO Con Irrft eyes, akin lac. inanimate ooiwuts, lose of motor control kt hmd bnbs NIOSH/OSHA 2200 ppm SA/SCBAF SCBAF PD PP/SAF PD PP ASC8A Escape GMFOV/SCBAE inh Ing Con Imt eyes skin upper resp sys anes is; Breath Swallow Irr immed Soapwash kroned Reao auDOort Mecucalattention immed ey*fctUn.CN9 >> / s* Eye Skin Breath Swallow Irr immed Water flush prompt Resp support Medical attention immed Eyes skin resp sys CNS Chemical name, stnicture/formula CAS andRTECSNot, and DOT 10 and guide Noa Synonyms, trade names and conversion factors Methyl alcohol CHfiH 67-66-1 PC1400000 Carbinol, Columbian spirits Methanol Pyroligneous spirit Wood alcohol Wood naphtha Wood spirit 200 1230 131 Methylamine CMjNMj 74 89 5 PF63000D0 1 ppm 1 31 mg/m1 Amrtomethane Anhydrous methylamine Aqueous methylamine Monomethyiamine 1061 118(anhydrous) 1235 132 (aqueous) Methyl (n-emyl) ketone CHjCqCHJ^CHj 110-43-0 MJ5076000 1 ppm = 1 27 mg/m5 Amyl methyl ketone, rnvnyl methyl ketone 2-Heptanone 1110127 Methyl bromide CHjBr 74 83 9 PA4900000 1 ppm 4 67 mg/m* Bromomethane Monobromomelhane 1062 123 1 ppm = 3 69 mg/mJ Exposure (TWA unless noted otherwise) NIOSH 200 ppm (260 mg/m*) ST 250 ppm OSHAf 200 ppm (260 mg/m*) NIOSH/OSHA 10 ppm (12 mg/m5) NIOSH/OSHA 100 ppm (465 mg/m*) NIOSH Ca See Appendix A OSHAT C 20 ppm (80 mg/m5) (skin) ABD00022924 IDLH Physical description 6000 ppm Colorless liquid with a character istic pungent odor Chemical and physical properties MW. BP, SOL PI P, IP, Sp, Gr, flammability VP. FRZ UEL, LEL MW 321 BP1147*F Sol Miscible FlP 52*F IP t064eV VP 96 mm FRZ -144*F UEL 36% IEL6Q% Incompatibilities and reactivities Measurement method (See Tablet) Strong oxidizers Si gel Water GC/FID IV {*2000 Methanol) Sp Gr 0 79 Class IB Flammable Liquid 100 ppm Colorless gas with a fish or ammonia like odor (Note A liquid below2l F Shipped as a liquefied compressed gas | MW 31 1 VP 3 0 atm BP 21*F FRZ 136*F Sol Soluble UEl 20 7% FI P NA (Gas) LEL 4 9% 14*F (Liq) IP 8 97 eV RGasD 1 00 Sp Gr 0 70 (Liquid at 13'F) Flammable Gas Class IA Flammable Liquid Mercury strong oxidizers nitromethane (Note Corrosive to copper & zinc alloys aluminums galvanized surfaces ] XAD 7 THF HPLC/FCU/Vis OSHA (#40] 800 ppm Colorless to white liquid with a banana Ifce fruity odor MW" 114 2 BP 305'F Sol 04% Fl P 1Q2*F IP 933eV VP 3 mm FRZ -32*F UEL(250*F) 79% taoism n% SpOrOSI Class 11 Combustible Liquid Strong acids alkalis & oxidizers [Note Will attack some forms of plastic ] Char Methanol/ GC/?ID IV [*1301 Ketones II] Ca J250 ppmj Colorless gas with a chloroform like odor at high concentrations (Note A liquid below 38'F Shipped as a liquefied compressed gas) MW 95 0 VP 1 9 atm Aluminum magnesium BP 38`F FRZ 137*F strong oxidizers Sol 2% UEL 160% [Note Attacks Fl P NA (Gas) LEL 10% aluminum to form IP 10 54eV aluminum tnmelhyl which is SPONTANE RGasD 3 36 OUSLY flammable] Sp Gr 1 73 (Liquid at 32'F) Flammable Gas but only in presence of e high energy ignition source Char(pet)(2)/ dry tube GC/FID IV (#2520] Personal protection and sanitation (See Table 3) SHn Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam When wet (ftamm) NR ABD00022925 Recommendations for respirator selection --maximum concentration for use (MUC) (See Table 4) NIOSHOSMA 2000 ppm SA 5000 ppm SA.CF 6000 Dpm. SAT CF/SCBAF/SAF | SCBAF PO,PP/SAF PO.PPASCBA Escape SCBAE Route Symptoms (See Table 5) Hi Irrtt eyes akin upper reap Aba sy head drow, dizz, vert, Ing h-head nau vomit; via Con dial optic nerve damage (blindness) derm Health hazards First aid (See Table 6) Target organs (See Table S) l: Breath Swallow Irrimmad Water flush prompt Reap support Meacet attention Immed Eyes, skin, reap tya, CNS Gl tract [Methyl alcohol] Skin Eyes Wash skin Remove Change Provide Prevent skin contact (solnyPtostbrte Prevent eye contact (solnyFrostbite When eontam (soln) When wet (flamm) NR Frostbite NIOSH/OSHA 100 ppm CCRFS/GMFS/PAPRS1/ SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFS/SCBAE Inh Imt eyes skin reap sys Abs cough skin muememb (soln) bums derm conj Ing liq frostbite (soln) Con (soln/liq) [Melhylamine] SMn Eyaa waahskln Remove' Change. Prevent sUn contact Prevent eye contact Whencomam When wet or eontam NR NIOSH/OSHA Mi irrtteye*, akin, muememb, 600 ppm CCROV*/PAPROV*/GMFOW J5 head flatroo,coma, darn SAVSCBAF Con SCBAF PD,PP/SAF TO PP ASCBA Escape GMFOV/8CBAE Eye Skin Breath Swallow Irr immed (soln)/ Frostbite Water flush immed (soln)/Frostbite Resp support Medical attention immed (soln) Eyes skin respiyt i&i. Breath} 1 Swallow ttrbwned . -Soepereah - >, (Fiieilhalr Medical ettention immed jean [Methyl (n-amyl) ketone] Skin Eyes Wash skin Remove Change Provide Prevent skin contact (liq) Prevent eye contact (liq) When eontam (liq) When wet (flamm) NR Quick drench (liq) NIOSH SCBAF PD PP/SAF P0 PP ASCBA Escape GMFOV/SCBAE -' Inh Abs (liq) Con (iiq> Inrit eyes skin reap sys muse weak inco vis dist verti nau vomit, head mat hand tremor convuls dysp skin vesic liq frostbrte [care] s& Breath r,'. , Irr Immed (liq) Water flush immed (I'q) Reep support Eyes skin respsys CNS [In animals lung kidney & forestomach tumori) [Methyl bromide] Chemical name structurs/formula, CAS and RTECSNos and DOT ID and guidaNos Synonyms, trad* names, and conversion factors Mhy< Cetioeolvs> CHpCHjCHjOH $& EGME, Bhyjane 0yooi monomatftyl Gtycd'monomethyi ether, 2-Matheaoiithand 202 1108127 Motfiyl Cellosolve acetate CHjCOOCHjCHjOCHj 110-49-6 KL5950000 1189 129 Methyl chloride CHjCI 74-S7-S PA6300Q00 1 ppm&1l mgim5 EGMEA Ethylene glycol monomethyl ether acetate Glycol monomethyl ether acetate 2-Methoxyethyl acetate 1 ppm = 4 83 mg/m5 CMonomethant, MonocMoromethane 1063116 Methyl chloroform CHjCClj 71-55-6 KJ2975000 i ppm^S-Ormo/m9 Chlorothene 1 1 1 Tnchkiroethane 1 1 1-Tnchloroethane (stabilized) 2831 160 1 ppm 5 46 mg/mJ Exposure (TWA unleet noted otherwise) ABD00022926 IDLH Physical description Chemical and physical properties MW, BP, SOL FI P, IP, Sp, Gr, flammability VP, FRZ UEL LEL NOSH 01ppm (0 3 mgtop) faWn] OSHA 25 ppm SLT* 200 ppm Colorless UquM with a mild, athar-bka odor MW 781 BP 266*F Sot Madbls FIP-102T IP-960SV VP 6 mm FRZ.-12VF UEL14% LEL 16% SpGr 096 Ctaae II ComboatWa Liquid NOSH 0 f ppm (0 5 mg/m5) (akin) OSHA 25 ppm (120 mg/m5) [skin] 200 ppm Colorless liquid with a irM ether like odor MW 1181 SP 293*F Sol Miscible FIP 120*F IP 7 VP 2 mm FRZ 45'F UEL 8 2% LEL1 7% Sp Gr 1 01 Class II Combustible Liquid NOSH Ca Cttoneea gas with Ca 12000 Mm) a faint Meet 8ee Append* A odor wNeh * not nottoeaded dangaroua OSHAt 100 ppm ooncantrationa [***. C 2w ppm 300 pom (5-raln max paak In eompraaaad gaa,) nyShre) MW 505 BP--12*F Sot0.6% FIP NA(Gas) IP-11.26 ev RGatf) 176 FMmmaMeGaa VP SOatm FR2-144*F UEL174% LB.&1% NtOSH C 350 ppm (1900 mg/m5) [15-min) See Appendix C (Chloroethanes) OSHAt 350 ppm (1900 mg/m5) 700 ppm Colorless liquid with a mild chloroform like odor MW 133 4 BP 185*F Sol 0 4% FIP 7 IP 11 00 eV VP 100mm FRZ 23*F UEL125% LEL 7 5% Sp Gr 1 34 Combustible Liquid but bums with difficulty Incompatibilities and reactivities method (See Table 1) Strong oxidizers, cavities Char; Methanol/ &Br IV 1*1403 Alcohols M Nitrates strong oxidizers alkalis Saods Char CS. GCTFID IV (*1451] Chemlcaly-active metalssuchas potassium powdarad Murrtnum,onc4 maonaalun: water ENote Reacts with water (hydrolyzes) to form hydrochloric add] Char(2). cast* gcJftB, IV (*1001] Strong caustics strong oxidizers chemically-active metals such as zinc aluminum magnesium powders sodium & potassium water [Note Reacts slowly with water to form hydrochloric acid) Char cs. GCTFID IV (*1003 Halooenateg Hydro carbons) Personal protection (See Table 3} Skm Eyes Wash skin Remove Change Provide Prevent skm contact Prevent eye contact When contain VWien wet or conlam NR Quick drench [Methyl CeOofolveO] Skm Eyes Wash skm Remove Change Prevent skin contact Prevent eye contact Whencontam When wet or contam NR [Methyl CeNosoive acetate] SMk tfshakfn Remove Change Provide Froetblle Frostbite NR When wet (flamm) NR Frostbite (Methyl chloride] Skrn Eyes Wash skm Remove Change Prevent skm contact Prevent eye contact When contam When wet or contam NR [Methyl chloroform] ABD00022927 Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table 4) NIOSH 1 ppm SA* 2 5 ppm SACF* 5 ppm SCBAF/SAF 100 ppm SA PD PP* 200 ppm SAF PD PP 5 SCBAF PD.PP/SAF PD PP ASCBA Route Symptoms (SeeTabl* 5) mh irnt eyes nose threat, Abs head drew weak, ataxia Ing tremor som anemic pallor Con m animals repre terato effects Health hazards First ski (See Tsbls ) Target organs (See Table $) Eye Skin Breath Swallow (dimmed Water flush prompt Reap support Medical attention tmmed Eyes, rasp aye CNS blood kidneys repre sys, hemato y NIOSH 1 ppm SA 2 5 ppm SA CF' 5 ppm SCBAF/SAF 100 ppm SA PD PP 200 ppm SAF PD PP SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Wl Abs ing Con irnt eyes nose throat kidney brain damage in animals narco ieo'o terato effects NIOSH V SCBAF PD,PP/SAF PD PP-ASCBA Escape SCBAE Wt Dizz, neu, vomit; vis diet, Con stageer, slurred epeeotv (lip) cornua come.ivw, kidneydamage, IW eMe. rtpro, terato edicts, JeareJ Eye Skin Breath Swallow Irrimmed Water flush prompt Resp support Medical attention immed Eyes resp sys kidneys brain CNS PNS repro sys hemato sys , CNS,B.Mryi. ' ssss*,' NIOSH/OSHA 700 ppm SA /SCBAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Inh Ing Con imteyes skm head lass CNSdepres poor equi derm card arrhy liver damage ic, Breath Swallow Irrimmed Soap waah prompt Reap support Medical attention snmad Eyes skin CNS CVS liver Chemical name, tnicture/formula, CAS and RTECSNos, and DOT ID and gulda No* Synonym*, trad* namas, and conversion factors Meth^2-cyano- CH^C(CN)COOCH, 137-0S-3 AS7000000 Mecrytate, Methyl cyenoeayieta. Methyl o-cywoecryfate, Methyl ester of 2-cytf>o- ecrylcackl 204 Methyicyclohexane CHjCjH , 108 87 2 GV61250Q0 Cydohexylmethane Hexahydrotoluene 2296 126 1 ppm = 4 02 mg/m3 Methyleyctohawmot Hexeftydrooreeol, . -HesehyCTTi*t>iylphenol -V, . 2MSM24 QumjeSoo -i m- `>vt ' * v* 2M7'l t;PPm?4?7iym* o-Methylcyclohexanone CH3C,H,0 583-60 8 GW1750000 2-Methylcyclohexanone 2297 127 1 ppm = 4 59 mg/m3 Exposure Into (TWA unless noted otherwise) NOSH 2 ppm (8 mg/ni*) ST 4 ppm (16 mg/m*) OSKAt none NIOSH 400 ppm (1600 mg/m3) OSHAT 500 ppm (2000 mg/m5) NIOSH OSHAt 100 ppm (470 mpftn^ NIOSH 50 ppm (230 mg/m3) ST 75 ppm (345 mg/m3 (skin) OSHAt 100 ppm (460 mg/m5) (skin) ABD00022928 cut Physical description NO Colories* liquid with a characteristic odor Chemical and physical properties MW, BP, SOL FI P, IP Sp, Gr, flammability VP,FRZ UEL, LEL MW1111 BP 7 Sol 30% FI P 174*F IP 7 VP(77*F) 0 2 mm FR2 ? UEL ? LEL ? 1200 ppm (10%LEL] Colorless liquid with a famt benzene like odor Sp Gr(8rF) 110 Claae IIIA Combustible Liquid MW 98 2 BP 214 F Sol Insoluble Fl P 25 F IP 9 85 eV VP 37mm FRZ 196*F UEL 6 7% LEL 12% 500 ppm Straw-colored liquid with a weak odor tike coconut oa Sp Gr 0 77 Class fB Flammable Liquid MW 1142 8P 311-356*F Sol 4% FIP 149-158*F IP S SO eV VP(86*F) 2 mm FRZ. -58'F UEL 7 LEL 7 600 ppm Colorless liquid with a weak peppermint like odor Sp Gr 0 92 Clast IIIA Combustible Liquid MW 112 2 BP 325'F Sol Insoluble FIP 118*F IP ? VP 1mm FRZ 7 F UEL ' LEL ? Sp Gr 0 93 Class II Combustible Liquid Incompatibilities and reactivities Measurement method (See Table 1) Moisture XAD-7* [Note Contact with CH.CN/ moisture causes rapid HPLcklV polymerization} OSHA [#55J Strong oxidizers Char GC7FID IV (#1500 Hydro carbons) Strong oxidizers Cher, S&fc IV [#1404] Strong oxidizers Porapak Acetone GC/FID IV (#2521) Personal protection and sanitation (See Table 3) 8Mn vSshsfcm. Remove. Changer Provide- Prevent skin contact Prevent eye contact Daily NR NR Eyewash [Utbyl 2-cyanoacvyiate) Skm Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam When wet (flamm) NR IMethytcyclobexane] sun; vSeheWre Remove: Change Prevent akin contact Prevent eye contact Whencontain When wet or contam NR. Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam When wet or contam NR (o-Methylcyclohexanone) ARD00022929 Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table 4) Health hazards -------------------------------------------------------------------------------------------------------------------------------------- Route Symptoms First aid Target organs (See Tables) (See Table 6) (See Table 5) TBAL Ht Irritayaa, skin.noae, Ing btutred vision, lac, rhtnftt* Con : Breath, Swallow irr immed Waterwash isurss*, immed Eyaa, skin, reap sya . NIOSH 1200 ppm SA/SCBAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Inh Ing Con Imt eyes skin nose throat li head drow m animals narco Eye Skin Breath Swallow Irr immed Soap wash prompt Resp support Medical attention mimed Eyes skin resp sys CNS 205 ND6H SOO pan SA*/SCBAF | SCBAF PD,PP/SAF PD.PP-ASCBA Eeoape GMFOV/SCBAE Hi Irrteyea.jfcJr, upper reap Abe eye. head; &' in animats, narco; Her. Wdnejtdereage K , Irrnvned -Soap wash prompt sores.Breath Swallow' immed. Eyee.sMR, reap eye, CNS. kkinaye kver ' .; > NIOSH 500 ppm SA' 600 ppm SA CFVSCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE - Inh Abs Ing Con 'lS\ rt In animals imteyes eyes mucmemb narco derm Ifn Breath Swallow ` -- .. Irr immed Soap wash prompt Resp support Medical attention immed Skin resp sys liver kidneys CNS Chemical name structure/formula, CAS and RTECSNos, and DOT ID and guide Nos Synonyms, trade names, and conversion factors Exposure knits (TWA unless noted otherwise) Methyl eydopentodienylmanganese tricarbonyl (as Mn) CHjCjH^tHCO), 12108-13-3 OP1460Q00 CI-2. CocntowBon lmprover-2, Mangantaa trtaMbonyt- methytcydopantacBery^ 2-Mstnylcyotopwtta(Unyt manpanaaatricarbonyl, ^' MOSH 07 mg/m3 [skin] OSHAf CSmgfin* , 206 Methyl demeton CsHe01PSi 8022 00-2 TG1760000 Demeton methyl O O-Dimethyl 2-ethylmer captoethyl ttuophosphate Metasystox Methyl mercaptophos Methyl systox NIOSH 0 5 mg/mJ (sAinf OSHAf none 4SSsSSm^' CWV*ilk~ 101-1+4 OYIOSOOOO . J^KtyleAeW^hS?^^ Methylene bis(4-cyctohexylisocyanate) CH^CjM^NCO], 5124-30-1 NQ9250000 Dicyciohexylmethane 4 4 dllsocyanate 0MDI bis(4 Isocyanatocydohexyl) methane HMOl Hydrogenated MDI Reduced MDI Saturated MDI 1 ppm *10 73 mg/m5 NIOSH C 0 01 ppm (0 11 mg/m3) OSHAt none ABD00022930 Physical description NO Yellow to daftorange Hqutd with a faint, pleasant odor [Note A solid below 36*F] Chemical and physical properties MW, BP, SOL Fi P, IP, Sp, Or, flammability VP, FRZ UEL, LEL MW-2181 BP 449*F Sol Insoluble FIP 230*F IP ? VP(212*F): 7mm FRZ, 36*F UEL? LEL? Incompatibilities and reactivities Measurement method (See Table 1) Light (decomposes) None evaNable y. n cfaifIlIB CombustiUe Liquid ^ ' ' ^ h ? *'"'J'f* ` i z.T ND Oily colorless to MW 230 3 VP 0 0004 mm Strong oxidizers None pale-yellow liquid BP Decomposes FRZ 7 alkalis water available wrth an unpleasant Sol 0 03-0 3% UEl ' odor Fl P > LEL 7 [insecticide] IP ? [Note Technical grade consists of 2 isomers thiono & thiolo] Sp Gr 1 20 Combustible Liquid or Setaewithe . *8P-?' faint, i 1+dor. ,/ n p*r' .AP"7 mm tj^^uel'? y rl -LEL:? - ,,J ,, '^^otert^v/' Htt*rr(2), GC/EOD; h* *< - Sp^r?-44s NO Clear colorless MW 262 4 to light yellow BP 7 liquid Sol Reacts FIP >395 F IP 7 y it v ,1. *' - at /r VP(77'F) Water ethanol None 0001mmalcohols amines available FRZ <I4*F bases acids organotm UEL ' catalysts LEL 7 (Note May slowly polymenze if heated above 122 F J Sp Gr(77"F) 1 07 Class MIS Combustible Liquid Personal protection (See Table 3) Skm vSshskin Remove Change Prevent skin contact Prevent eye contact When contarn When wet or contain NR ABD00022931 Recommendations tor respirator concentration for use (MUC) (See Table 4) TBAL Route Symptoms (See Table 5) Inh Abs Ing Con Irrtteyes, gldd, nau head, tn animals tremor, severe clonic spasms, weak, slow respiration liver, kidney lit) Health hazards First sid (See Table 6) tiJv Snath Swallow Irr immed Soapwash Immed Resp support Medical attention Immed Target organs (See Table 5) Eyes. CNS, liver, kidneys [Methyl cyctopentadienyl manganese tncorbonyl (as Mn)] Skin Eyes Wash skin Remove Change Provide Prevent skrn contact Prevent eye contact When contain When wet or contam Daily Eyewash Quick drench TBAL Inh Abs Ing Con Irnteyes skin ache eyes rhm nau head dizz vomit [Methyl demeton) Skin Eyes Washekm Remove: Change- Provide Prevent skin contact Prevent eye contact When contanVDally When wet or contam Oaily Eyewash Quickdrench NiOSH SCBAF PO PP/SAF PO PP-ASC8A Escape GMFOVHIE/SCBAE Wt Ab ing Con Hema,cyan,nau methemo, kidney mtt; (care) Eye Skin Breath Swallow - Irr immed Soap wash immed Resp support Medical attention immed Eyes skin resp sys CNS CVS blood ehol 207 i&i Breath Swallow Irr immed Soap flush irtmed Reap support Medical attwitton immed Uvar blood, kidneys [In animals. War lung & bladder tumors] [4 4'*Methyienebts(2-chJoroaniline)] Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet or contam NR Quick drench [Methylene bis(4-cyclohexyli$ocyanate)] NIOSH 01 ppm SA 0 25 ppm SA CF 0 5 ppm SCBAF/SAF 1 ppm SAF PD PP SCBAF PD PP/SAF PD PP ASC0A Escape GMFQV/SCBAE Inh Ing Con Irnteyes skin resp sys skin resp sens chest tight dysp cough dry throat wheez pulm edema skin blisters Eye Skin Breath Swallow irr immed Water flush immed Resp support Medical attention immed Eyes skin resp sys 208 Chemical name, tructure/formula, CAS and RTECSNos and DOT ID and guide Nos Methylene btophenyl leocyanata CH^NCO)* joi-es-s NQ9350000 24S9 156 Metbyiene Monde 75 09 2 PA8050000 1593 160 4,4' Methylene- CHjJC^NHj), 101-77-9 BY5425000 Methyl ethyl Ketone peroKide c,h)(o4 1336 23 4 EL9450000 2550 147 Synonyms trade names, and conversion factors Exposure fcnto (TWA unless noted otherwise) ABD00022932 IOLH Physical description Chemical and physical properties MW, BP SOL FI P IP, Sp.Gr, flammability VP,FRZ UEL LEL Incompatibilities and reactivities measurement method (See Table 1) 4 4'-Dfphenytmethane dlleocyanate, MDI, Methylene bla(4-phenyl Isocyanate) Methylene oi-p-phenyiene ester of leocyanle ecid 1 ppm *10 24 mg/m3 NIOSH 0 05 mg/m3 (0 005 ppm) C 02 mg/m3 (0 020 ppm) [10-minj OSHA C 0 2 mg/ms (0 02 ppm) 75 mg/m5 White to lightyellow odorless flUtes [Note A liquid above 99'F ] MW 250 3 BP 597*F Sol 0 2% FI P 390* IP ? VP(77*F) Strong alkalis, 0 000005mm acids, alcohol MLT99'F [Note Polymerizes UEL ? at 450`F ] LEL ? Sp Gr 1 23 (Solid at 77`F) 119(Uqwdat122`F) Combustible Solid Bub Acetylata/ Methanol HPLC/UV/ ECO IV [#5521] Djchioromeihane Methylene dichloriOe 1 ppm * 3 47 mg/m3 NIOSH Ca OSHA [1910 1052] 25 ppm ST 125 ppm Ca [2300 ppm] Colorless liquid with a chloroform like odor [Note A gas above 104 F] MW 84 9 BP 104 F Sol 2% FI P > IP 11 32 eV VP 350 mm FRZ 139 F UEL 23% LEL 13% Sp Gr 1 33 Combustible Liquid Strong oxidizers caustics chemically active metals such as aluminum magnesium powders potassium & sodium concentrated nitre acid Char(2) CS, GC7FID IV 4 4-Oiamihodiphenytmethane. para. para'-Otamlnodiphenyl- DtanHnomethane 4,4'-D<phenylmethanediamlne MDA NIOSH Ca See Appendix A OSHAI191010501 0010 ppm ST 0100 ppm Ce IND] Pale-brown crystalline solid with a faint amlne-like odor MW 198 3 BP 748*F Sold* Fl P 374*F ip I0 70ev VPf7TF) 00000002 mm MLT fWF UEL? LEL ? Strong oxidizers Sp Gr 1 06 (Liquid et212*F) Combustible Solid Filter* KOH1 Methanol. HPLC/UV/ ECO IV [#5029] 2 Butanone peroxide Ethyl methyl ketone peroxide MEKP MEK peroxide Methyl ethyl ketone hydroperoxide 1 ppm *7 21 mg/m3 NIOSH ND Colorless liquid MW 176 2 VP f C 0 2 ppm with a character BP 244*F FRZ ? (1 5 mg/m3) istic odor (Decomposes) UEL ' [Note Explosive Sol Soluble LEL ? OSHAT decomposition Fl P(oc) none occurs at 230'F ) 125 200 F (60% MEKP) Sp Gr(59*F) 1 12 Combustible Liquid Organic materials Imp heat flames sunlight Reagent trace contaminants Vis [Note A strong oxidiz IV ing agent Pure MEKP (#3508] is shock sensitive Commercial product >s diluted with 40% dimethyl phthalate cyclohexane peroxide or diallyl phthalate to reduce sensitivity to shock } Personal protection and sanitation (See Table 3) Skit Weahakin Remove Change Prevent skin contact Prevent eye contact When contam When wet or contam Dally [Methylene biaphenyl Isocyanate] Skin Eyes Wash skin Remove Change Provide Prevent sk/n contact Prevent eye contact When contam When wet or contam NR Eyewash Quickdrench [Methylene chlonde) Stfn. ^Shskfct. RemoveCtange. Provide Prevent skin contact Prevent eye contact When oontarrVDaiiy When wet or contam Dally Eyewash Quickdrench (4,4'-Methytenedieniline) Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam When wel or contam NR Eyewash Quickdrench (Wethyl ethyl ketone peroxide] ABD00022933 Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table 4) Route Symptoms (See Table 5) NtOSH 0 6 mg/m5 SA* 1 25 mg/m1- SA CF* 2 5 mg/m5- SCBAF/SAF 75molms- SAF PD PP SCBAF PD PP/SAF PD PP ASCBA Escape GMFOVHIE/SCBAE Wi Irrtt eyes, note throat, Ing rasp sens, cough, pulm Con secretions, cheat pam dysp asthma Health hazards Firetaid (See Table 6) Eye Skin Breath Swallow- Irrimmed Soap wash Immed Reap support Meoical attention Immed Target organe (See Tables) Eyee, reap aye NIOSH SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE rnn Abs mg Con irnteyes skin ftg weak som It head numb tingle limbs nau [care) Eye Skin Breath Swallow Irr immed Soap wash prompt Resp support Medical attention immed Eyes skin CVS CNS [mammals lung liver salivary & mammary gland tumors] 209 NOSH SCBAF PD PP/SAF PO.PP ASCBA Escape GMFOVHIE/SCBAE kth Irr* eyee, Jaua hepatitis, Abs myocardial damage jnfl in animate, heart aver Con apleen damage, (cere] Bread) Swallow Irr immed Soapwash Immed Raw eupport Mecfteai attention Immed Eyee, Ever, CVS, apleen (inanimate bladder canoed TBAL inn Ing Con Imt eyes skin nose throat cough dysp pulm edema blurred vision blisters scars skin abdom pam vomit diarr derm mammals liver kidney damage Eye Skin Breath Swallow Irr immed Water wash immed Resp support Medical attention immed Eyes skin resp sys liver kidneys Chemical name, structure/formula, and DOT ID and guide Nos Synonyms, trade names, and conversion factors Methyl formate MCOOCHj 107-31-3 LQ8926000 Methyl ester of formic add, Methyl methanoet* 210 IMS 12* 1 ppm 2.46 mg/m1 5-Methyl-3-heptanone Amyl ethyl ketone Ethyl amyl ketone CjHjCOCHjCHlCHjlCHjCHp-Methyl-S heptanone 541-85-5 MJ7350000 Exposure limits (TWA unless noted otherwise) NtOSH 100 ppm (250 mg/m1) ST 150 ppm {375 rog/m1) OSHAT 100 ppm (250 mg/m1) NIOSH/OSHA 25 ppm (130 mg/m3) ABD00022934 IDLH Physical description Chemical and physical properties MW, BP, SOL FI P, IP, Sp, Gr, flammability VP, FRZ UEL, LEL 4500 ppm Colorless Nqurd with a pleasant odor (Note A gas above 99*F] MW 601 BP 89*F Sol 30% FIP-2T IP 10 82eV VP 476mm FRZ -148T UEL23% LL46% 100 ppm Colorless liquid with a pungent odor Sp Gr 0d8 rfsss IA Flammable Liquid MW 128 2 BP 315F Sol Insoluble Fl P 138'F IP 7 VP 2 mm FRZ 70"F UEL 7 LEL 7 2271 127 Mp**) hydrazine CtyiHNH, 80-34-4 MV6600000 1244131 Methyl iodide CHJ 74 88 4 PA9450000 2844 151 1 ppm 5 24 mg/mJ r, Monofnthytbydewin , Ippm-IBBrngfoi1 lodomethane Monoiodomethane 1 ppm = 5 80 mg/m3 Sp Gr 0 82 Class II Combustible Liquid NIOSH Ca ' , , po^weij See AppendbrA , C 0.04 ppm 1 r ^ , (0.09 mgftn*) (2-hrt i-> genn C 02 pan (033 mg/m1) > . (skin) Fuming, odorless liquid with an emmome-ftkeodor MW-461 BP 19Q*F Sol Mlsdbte FLP-17*F IP 8 00eV VP- 39 mm FRZ.-62'F UEL 92% LEL 2.6% SpGr(77*F):087 Class IB Flammable Liquid NIOSH Ca See Appendix A 2 ppm (10 mg/m3) (skin] OSMAT 5 ppm (28 mg/m3) [skin] Ca [100 ppm] Colorless liquid with a pungent ether like odor [Note Turns yellow red or brown on exposure to ligm & moisture ] MW 141 9 BP 109 F Sol 1% FI P NA IP 9 54 eV Sp Gr 2 28 Noncombustible VP 400 mm FRZ 88 F UEL NA LEL NA Liquid Incompatibilities and Measurement method Strong oxidizers (Note Reacts slowly with water to form methanol & formic acid) Carbo-B(2), Ethyl acetate, GC/FID, !8U Strong oxidizers Char Methanol/ CS, GC/FlD IV [#1301 Ketones ll] Oxides of iron, copper, manganese lead, copper alloys, porous material* such as aarth, asbestos, wood 3 doth, strong VAMOIV M fluorine & chlorine nitric edd hydrogen peroxide Bub. Pho-actd, VI*, IV (43510) Strong oxidizers [Note Decomposes at5l8 F] Char Toluene GC/FID IV [#1014] Personal protection (See Table 3) Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact Whencontam When weUflamm) NR [Methyl formate] Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam When wet or contam NR [5 Methyl 3 heptanone) Stan. vSsh atari Remove Change Provide Prevent sidn contact Prevent eye contact Wien contam When wet (flafnm) NR Eyewash Quick drench [Methyl hydrazine] Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact Whencontam When wet or contam NR Eyewash Quick drench (Methyl iodide] ABD00022935 Recommendations for respirator concentration for use (MUC) (See Table 4) Route Symptoms (See Table 5) NlOSH/OSHA 1000 ppm SA* 2600 ppm SACF' 4500 ppm SCBAF/SAF SCBAF PD PP/SAF PQ.PP ASCBA Escape GMFOV/SCBAE Inh imt eyas, note, cheat Abs tight, dyap, vis dist, Ing CNS dapret, Con In animals ptimadema, narco NlOSHJOSHA 100 ppm CCROV/PAPROV7GMFOV/ SA'/SCBAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Inh Ing Con irnteyes Skin mucmemb head narco coma derm Health hazards First aid (See Table S) % Breath: Swallow- Irrlmmad Soap wash immad Rasp support Medical attention InvnKf Target organs (See Table 6) Eyas, reap sya, CN8 S Breath Swallow In immad Water flush Resp support Medical attention mmed - Eyes skin resp sys CNS 211 NIOSH U SCBAF PD,PP/SAF PD.PP ASCBA Escape SCBAE NIOSH U SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Mi Aba *0 Con Inh APs Ing Con Irrt eyss, skin, reap sys;. vomit, disyr, tremor, ataxia, anowa, cyan; convub, [care} x- Swnr - Bmms-* ; SMtiCNT v> i, s v .1 Irnt eyes skin reap sys nau vomit verti ataxia slurred speech drow derm [care] Eye Stan Breath Swallow ^ss.srirrfrnmarT Waterfluah.linroad < jMQ|QVI VBtnDOil Mrm* l' 1 |)R animal*- funo. Uvok. blood vottsl' , & Intestine tumors) , Immmed Soap flush immed Resp support Medical attention immad Eyes skin resp sys CNS (in animals lung kidney 4 forestomach tumors] Chemical name, structure/formuta CAS and RTECSNos, and DOT ID and guide Noe Synonyms, tradenames and conversion factors Methyl taoamyl ketone CHjCOCHjCHjCHfCHjJj 110-12-3 MPU00Q00 Isoemylmethyl ketone, Isopentyl methylketone, 2-Methyt-S-hexanone, 5 Methyl 2 hexancno, MIAK 212 2302 137 IppmaefiTmgftn* Methyl isobutyl carbmoi (CHjJjCHCH2CH(OH)CH, Isobutyimethylcarbmoi Methyl amyl alcohol 4 Methyl 2 pentanoi MIBC 108-11 2 SA7350000 2053 129 Methyl isocyanate ch^co 624-63-6 NQ9450QO0 1 ppm = 4 18 mg/m3 MeOyl ester of leooyanlc MIC ' 2460 196 Methyl isopropyl Ketone CHjCOCH(CHj)j 563 80 4 EL9100000 lpptne244moAn* 2 Acetyl propane Isopropyl methyl ketone 3 Methyl 2 butanone 3-Methyi butan 2 one MlPK 2397 127 1 ppm = 3 53 mg/m3 Exposure Mb (TWA unless noted otherwise) NOSH SR** OSHAt 100 ppm (475 mgAn5) NIOSH 25 ppm (100 mg/m'i ST 40 ppm (165 mg/m3 [skin] OSHAt 25 ppm (100 mg/m3) (skin] NIOSHOSHA 002 ppm (006 mo/m*) {ekin] NIOSH 200 ppm (705 mg/m5) OSHAt none ABD00022936 IDLH Physical descnptlon NO Colorless deer liquid w*h a pleasant, fruity odor Chemical and physical properties MW, BP, SOL FI P, IP, Sp, Gr, flammability VP, FRZ UEL LEL MW 1143 BP29VF Sol 05% FIP97*F IP- 9264 eV VP 5 mm FRZ-101 *F UEL(200*F) 8 2% LEL(200*F) 10% 400 ppm Colorless liquid with a mild odor SpGrOBI Class 1C Flammable Liquid MW 102 2 BP 271 F Sol 2% FI P 106'F IP ? VP 3 mm FRZ 130 F UEL 5 5% LEL 1 0% 3 ppm ND Cotortees liquid s#th a sharp, pungent odor Colorless liquid with an acetonelike odor Sp Gr 0 81 Class II Combustible Liquid MW 571 BP 139T 3ol(59*F) fi% FIP19T IP 10.67 eV VP 348 mm FRZ. -49*F UEL 26% LB-53% cGss8p.Gr 0 96 IB FtwrmuMe Liquid MW 66 2 BP 199 F Sol Very slight FI P 7 IP 9 32 eV VP 42 mm FRZ 134 F UEL 7 LEL ' Sp Gf 0 61 Combustible Liquid Incompatibilities and Measurement method (See Table 1) Oxidizers None avaBabie Strong oxidizers Char 2 Propanol/ CS GC/flD IV (#1402 Alcohols III] Water oxidizers, ames Iron tin, copper [Note Usuefy con tains nhiMors toigrevjint poiymert- XAD-7 CHXN, HFtCiFLD; OSHA [54] Oxidizers None available Personal protection (See Table 3) Stan Eyes Washsktn Remove Change Prevent skin contact Prevent eye contact When contam When wet (Haim) NR [Methyl isoamyi ketone] Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam When wet or contam NR [Methyl isobutyl carbinoi] Stan vSJhakln Remove. Change Provide Prevent skin contact Prevent eye contact Wtien contam VM>en wet (flamm) NR Eyewash Qutckdranch [Methyl isocyanate) Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam When wet or contam NR [Methyl isopropyl ketone) ABD00022937 Recommendations for respirator selection--maximum concentration for use (MUC) (See Table 4) Route Symptoms (See Table 5) NOSH Irti 500 ppm CCROV'/SA* Ing 1250 ppm SA CFVPAPROV* Con 2500 ppm CCRFOV/GMFOV/PAPRTOV'/ SAT CF'/SCBAF/SAF 5000 ppm SAF PD PP SCBAF PD PP/SAF PO PP ASCBA Escape GMFOV/SC8AE Irrtt eyes, skin muememb head narco coma, derm, in animals liver kidney damage Health hazards First aid (See Table 6) Target organa (See Table 5) IS Breath Swallow trr Immed Soap flush prompt RMaaaSacailuoanttoenrtbon Immad Eyas, akin, reap sya, CNS, liver kidneys NIOSH/OSHA 250 ppm SA* 400 ppm SA CF /SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Hi lint eyes skin head IngAbs drow derm in animals narco Con Eye Skin Breath Swallow Irrimmed Water flush prompt Resp support Medical attention immed Eyes skin CNS NIOSH/OSHA 0 2 ppm SA* 0 5 ppm SA CF* 1 ppm SCBAF/SAF 3 ppm SAF PD PP SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Hi imteyes, Stan, nose, Abs throat; reap sens, cough, !? pulm secretions, chest pain, Con dysp asthma, eye, skin inanSais puirnedema IS Breath; Swettow trrtmmed Waterflush immad Reso support MadoriattartlM Immad Eyee, aUn, reap sys TBAL Inh Ing Con Irnteyes skin muememb resp sys cough lETn Breath Swallow Irr immed Soap wash immad Resp support Medical attention immed Eyes skin resp sys Chemical name, structure/formula CAS and RTECS Noe and DOT ID and guide Nos Synonyms, trade names and conversion factors Exposure (TWA unless noted otherwise) Methyl mercaptan CHH 74-03-1 PB4375000 214 1064117 Methyl methacrylate CHj=C(CH3)COOCH3 80 62 6 OZ5075000 Mercaptomethane, Methanethiol Methyl suffhydrate lpprn-1 87 mafrn3 NIOSH C 0 5 ppm (1 mqAn5) [15-mtn] OSHAt CIO ppm (20 mg/m3) Methacrylate monomer Methyl ester of methacrylic acid Methyl 2-methyl-2-propenoate NIOSH/OSHA 100 ppm (410 mg/m3) 1247 129P (inhibited) Methyl parethlon (CH^^SJOC^O, 200-00-0 TO0176000 1 ppm = 4 09 mg/m3 Azophos, O.O-DKnethyl-O-D-nitro- phenylphoephorothloate; Pamthionmethyl - 2703 162. Methyl silicate (CH30),Si 681-84 5 VV9800000 - Methyl orthosilicate Tetramethoxysilane Tetramethyl ester of silicic acid Tetramethyl silicate NIOSH 0.2 mg/m5 [akin] OSHAt none NIOSH 1 ppm (6 mg/m3) OSHAt none 2606 155 1 ppm = 6 23 mg/m3 ABD00022938 IDLH Physical description Chemical and physical properties MW BP SOL FI P IP, Sp, Gr, flammability VP, FRZ UEL, LEL Incompatibilities and Measurement method (See Table 1) ISO ppm Colorless gas with a disagreeable odor like garlic or rotten cabbage [Note A liquid below 43*F Shipped as a liquefied compressed gat] MW 48 1 VP 1 7 atm BP 43*F FRZ 186*F Sol 2% UEL 21 8% FI P NA (Gas) LEL 3 9% (OC) O'F (Liq) IP 9 44 eV RGasD 1 86 Sp Gr 0 90 (Liquid at 32*F) Flammable Gas Clasa IA Flammable Liquid Strong oxidt2ers bleaches copper aluminum nickelcopper alloys Filter' HCI/DCE GC/FPD IV [#2542] 1000 ppm Colorless liquid with an acrid fruity odor MW 100 1 8P 214F Sol 1 5% FI P(oc) 50F IP 9 70 eV VP 29 mm FRZ 54F UEL 8 2% LEL17% Sp Gr 0 94 Class IB Flammable Liquid Nitrates oxidizers peroxides strong alkalis moisture [Note May polymerize if subjected to heat oxidizers or ultraviolet light Usually contains an inhibitor such as hydroqumone j XAO 2 CS, GC7FIO IV [#2537] ND White to tan MW 263 2 VP 0 00001 mm Strong oxidizers, OVS-2. crystalline solid BP 289*F MLT 99`F water Toluene/ or powder with a Sd(77*F) UEL ? [Note Explosive nsk Acetone jHingent gertlc- 0 006% LEL 7 whan heated above GC/FPD, FIP ? 122*FJ IV (pesticide] IP ? (#5600 [Note Theeommer- Organo- del product in phosphorus xylene Isetan Sp Gr 1 36 Pesticides) liquid ] Combustible Solid ND Clear colorless MW 152 3 VP(77 F) Oxidizers hexa None liquid BP 250 F 12 mm fluorides of rhenium available [Note A solid Sol Soluble FRZ 28'F molybdenum & tungsten below 28 F ] FI P 205 F UEL 1 IP > LEL 7 Sp Gr 1 02 Class 1116 Combustible Liquid Personal protection and sanitation (See Table 3) $Hn /Jashskin Remove Change Provide Prevent skin contact (liqyFroatblte Prevent eye contact (ItqyFfOatblte NR When wet (flamm) NR Eyewash (liq) Quick drench (bq) Frostbite [Methyl mercaptan] Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam When wet (flamm) NR ABD00022939 Recommendations for respirator concentration for uee (MUC) (See Teble 4) Route Symptom* (See fable 6) NOSH 5 ppm CCROV/SA 125ppm.SA.CF/PAPROV 25 ppm CCRFOV/GMFOV/PAPRTOV/ SAT CF/SCBAF/SAF 150 ppm SA.PDPP 6 SCBAF PO.PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Hi Con (Hq) Irrit eyes, akin, reap ays, narco; cyan convula, liq frostbite NIOSH/OSHA 1000 ppm SA CF/CCRFOV/GMFOV/ PAPROVc/SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Inh Ing Con Imteyes skin nose throat derm Health hazards First aid (See Table 6) Target organs (See Table 6) Eye Sldn. Breath Irr Immed (Uqy FroetbHe Water flueh immed (liq)/Frostbite Reap support Eyet, akin, reap sya, CHS, blood Eye Skin Breath Swallow Irr immed Water flush prompt Resp support Medical attention immed [Methyl methacrylate] Skin Wash akin Remove Change Provide Prevent ekm contact Prevent eye contact Whan eontam/Daily Whan wet or contam Dally Eyewash Quick drench [Methyl parattuon] Skin Eyes Washskm Remove Change Provide Prevent skm contact Prevent eye contact Daily When wet or contam NR Eyewash (Methyl silicate] NOSH 2 mg/m1- CCROVDMFu/SA 5 mo/m1 SA.CF/PAPROVDMFU lOrno/m1 CCRFOVHiE/GMFOVHiE/ PAPRTOVHiE/SAT CF/ SCBAF/SAF 200 rrvg/m1- SAF PD PP SCBAF PD PP/SAF PD.PP ASCBA Escape GMFOVHIE/SCBAE TBAL Hi Abe Ing Con In* ayae.akin; nau, vomit abdom cramps, diarr, eahr hMd, gidd, verb weak; rMn. cheat bght blurred vision miosis card kreg; muse fate; dyap IK Breath Swallow In- Immatf Soapsraahfmmad Raap support Mecical attention Immad Inh Imteyes com damage Ing (following even short term Con exposure to the vapor) (vap/ lung kidney inj pulm liq) edema ______________________________________ i______________ Eye Irr immed (vap/liq) Eyes respsys Skjn Soap wash kidneys Bream Resp support Swallow Medical attention immed Chemical name, structure/formula, CAS and RTECSNoa, and DOT ID and guide Noe Synonyms trade names and conversion factors a-Meihyi styrene 08*83-9 WL6075300 AMS, isopropenyl benzene 1-Methyl-1-phenylethyiene, 2-Phenyl propylene 216 Metribuzin CjH^N.OS 21087 64 9 XZ2990000 1 ppm 4 83 mg/m3 4 Ammo-6-(1 1-dimethyl ethyl)-3-(methylthio)1 2 4 tnazin 5(4H)-one Sencor Exposure knits {TWA unless noted otherwise) NIOSH SO ppm (240 mgAn9) ST 100 ppm {486 mg/ms) OSHAt C100 ppm (480 nftn*) NIOSH 5 mg/m3 OSHAf none ABD00022940 IDLH Physical description 700 ppm Colorless liquid with a character istic odor N D Colorless crystalline solid [herbicide) Chemical and physical properties MW, BP, SOL FI P, IP, Sp, Gr, flammability VP, FRZ UEL, LEL Incompatibilities and reactivities Measurement method (See Table 1) MW 1182 BP 330*F Sol Insoluble FIP 129*F IP 8 3SeV VP 2mm FRZ -10*F UEL&1% LEL19% Sp Gr 0 91 Class 11 Combustible Liquid OxJdize's, peroxides, halogens, catalysts for vinyl or ionic polymers aluminum iron chloride copper (Note Usually con tains an inhibitor such as tert-butyl catechol] Char; gcJfid IV (#1501 Aromatic Hydro carbons] MW 214 3 BP 7 Sol 0 1% FI P NA IP ' VP 0 0000004 mm MIT 257 F UEL NA LEL NA None reported None available Mfee (eontaWno less then taquartz) 12001*26*2 W8760000 Mineral wool fiber PY8070000 Blotite, Lepidoiite Margarita, Muscovite, Phlogopfte, Roscoelite, amrmMMtte Manmade mineral fibers Rock wool Slag wool Synthetic vitreous fibers [Note Produced by blowing steam or air through molten rock (rock wool) or vanous furnace slags that are by-products of metal smelting or refining processes (slag wool) ] NIOSH 3 mg/m1 (resp) OSHAt 20 mppcf Sp Gr 1 31 Noncombustible Solid 1500 mg/m1 Colorless odorlass flakes or sheets of hydrous sibcatM ' MW- 797 (approx) VP 0 mm BP 7 Sol Insoluble (approx) MLT ? FIP NA IP NA UEL NA LEL NA NIOSH 3 fibers/cm5 (fibers S 3 5 pm diameter&zlOpm in length) 5 mg/m3 (total) ND OSHA 15 mg/m3 (total) 5 mgim3 (resp) Sp Gr 26-32 Noncombuettbie SoU Typically a mineral wool with diameters >0 5 pm &>1 Spmm length MW vanes BP NA Sol Insoluble FIP NA IP NA VP 0 mm MLT 7 UEL NA LEL NA Sp Gr 7 Noncombustible Fibers None reported Filter none. Grav IV 1*0600, NOR IV [#0500 Particulates #7400] Personal protection (See Table 3) Sion Eye# Waahakw Remove Change Prevent skin contact Prevent eye contact When eontam When wet or eontam NR (a-Methyl styrene) Skip Eyes Wasn skio Remove Change Prevent sKin contact Prevent eye contact When eontam,Daily When we' or eontam Da iy [Metribu2 n SUn &.*, Ramcwa Change NR NR NR NR NR fllttca (containing less than 1% quartz)) Skin Eyes Wash skin Remove Change Prevent skm contact Prevent eye contact Dai'y NR Da iy [Mineral Wool] ABD00022941 Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table 4) Route Symptoms (See Table 5) NIOSH 500 ppm CCROV'/SA 700 ppm SA CF'/CCRFOV/GMFOV/ PAPROV/SCBAF/SAF SCBAF PD,PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Inh imteyes skin nose Ing throat draw, derm Con Health hazards First aid (See Table 6) Target organs (See TableS) IE, Breath Swallow Irrimmed Water flush prompt Resp support Medical attention nvned CNS TBAL Inn Ing VOr in animais CNSdepres IhyrOiO hver enzyme -hanges Eye Sum Bream Swallow irr immec Soap wash Fresh air Medical attention mined CNS thyroid uver NIOSH 15 mg/ml DM 30 mg/ml DMXSQ/SA 75 mg/m5- SACF/PAPRDM 150 mg/m5- HiEF/SAT CF/PAPRTHiE/ SCBAF/SAF 1500 moftr^SA. POPP t SCBAF PO PP/SAF PD PP ASCBA cape HiEF/SCBAE Inh Irrtt eyes pneumoconiosis Con cough dysp weak low-wgt NIOSH 5X REL D 10X REL DXSQ/HiE/SA 25X REL SACF/PAPRD 50X REL HiEF/PAPRTHiE/SCBAF/SAF 1000X REL SAF PD PP SCBAF PD PP/SAF PD PP ASCBA Escape HiEF/SCBAE Inh imteyes skin resp sys Con dysp Breath Eye Skm Breath IfTimmed Fresh air Irr immed Soap wast Fresh air Chemical name, structure/formula, CAS andRTECSNos and DOT ID and guide Nos Synonyms trade names and conversion factors Molybdenum Mo 7439-98-7 QA4880000 Molybdenum metal Molybdenum (soluble compounds as Mo) Synonyms vary depending upon the specific soluble molybdenum conipound Exposure limits (TWA unless noted otherwise) ABD00022942 IDLH Physical description Chemical and physical Incompatibilities properties and ----------------------------------------------- reactivities MW BP SOL FI P, IP, Sp.Gr VP FRZ flammability UEL LEL NOSH* See Appendix D OSHAt* ISmg/m3 5000 mg/m3 Dark gray or black (as Mo) powder with e metallic luster [Note The R6L end PEL also apply to other Insoluble molybdenum compounds ( Mo)] MW- 95 9 BP 8717T Sol Insoluble FIP-NA IP NA VP 0 mm (approx) Mil 4752*F UEL NA LELNA Strong oxidizers SpGr 10-28 Combustible 8odd in form of dust or powder NIOSH See Appendix D OSHA 5 mg/m3 1000 mg/m3 Appearance and odor Properties vary depending (as Mo) vary depending upon upon the specific soluble the specific soluble molybdenum compound molybdenum compound Varies Measurement method (See Table 1) Filter And, ICP IV (#7300, Elements] Filter Acid ICP IV [#7300 Elements] Monocrotophos C/I^NOjP 6923-22-4 TC4375000 3-Hvdroxv-N-methylcfotonarrede dimathylphosphate NIOSH 0 25 mg/ms OSHAt none 2783 182 (organophoaptm* paetieida, eolld) Monomethyl aniline CjH/iHCH, 100-61 8 BY4550000 MA (Methylammo)benzene N Methyl aniline Methylphenylamme N Phenylmethylamine 2294 153 1 ppm = 4 38 mg/m3 NIOSH 0 5 ppm (2 mg/m3) [skin] OSHAT 2 ppm [skin] NO 100 ppm Colorless to reddish-brown so6d with e fnHd. ester odor [insecticide] MW 223 2 BP-257*F SoL Miscible FIP->200*F IP ? VP 0000007 mm MLT 129*F UEL? LEL? - 1, ' > " * 'K* U ' Yellow to light brown liquid with a weak ammonialike odor Sold - MW 107 2 BP 384*F Sol Insoluble FI P 175*F IP 7 32 eV VP 0 3 mm FRZ 71*F UEL ' LEL 7 Metals low moiecuiv weight alcohols 6 glycols [Note. Corrosive to black irpn, drum steel stainless steel 304 6 brass. Should be stored at 7M0*F] * OVS-2 ' ToluanW Acatona: GC/FPO. IV (#8600. , Organo- , MSS? Strong acids strong oxidizers Bub NaOH GC/FIO IV [#3511] SpGr 0 99 Class 1IIA Combustible Liquid Personal protection and sanitation (See Table 3) Skin Eyes Wash skin Remove Change NR NR NR NR NR (Molybdenum) Skin Eyes Wash skin Remove Change Pee sk r contact Prevent eye contact Whenuonta n When wet or contam NR [Molybdenumi soiub'e compounds as Moj, Sn Eyes WaahsWn Remove Change Prevent skin contact Prevent eye contact When contam When wet or contam Daily [Monocrotophos] Skin Eyes Wash skin Remove Change Prevent skm contact Prevent eye contact When contam When wet or contam NR [Monomethyl aniline] ABD00022943 Recommendations for respirator selection - maximum concentration foi use (MUC j (See Table 4) OSHA 75 mg/m3 DMA 150 mg/m* DMXSQ'/SA 375 mg/m3 SA CF/PAPRDMA 750 mg/m3 HiEF/SAT CF/PAPRTHiE/ SC6AF/SAF 5000 mg/m* SA PD PP SCBAF PD PP/SAF PO PP ASCBA Escape HiEF/SCBAE Rin it Symptoms (See Table 5) Inh Ing Con r animals imiteyes cose throat anor diarr low wgt listlessness irver kidney damage OSHA 35 mg mJ OM 50 mg,m DMXSQ ,5A 125 mg m> SA CF ,PAPRDM 250 mgmi3 HiEF/SAT CF PAPRIHiL SCBAF SAF 1000 mgim1 SAF PD PP SCBAF PD PP/SAF PD PP ASCBA Escape HiEF/SCBAE inh Ing Con in anima s r i' eyes ose tnroa anor nco aysp anemia TBAL Inh Irnt eyes miosis blurred Abs vision dizz convulj dysp Ing salv abdom cramps nau Con diatT vpmit m animals possible terato effects Health hazards First aid iSee Table 6) Eye Brea'h Swallow irr immed Resp support Medical attention immed Target organs (See Table 51 Eyes respsys iver kidneys Skin Brea'h Swallow r immed Water flush Resp support Medical attention immed E/es resp kidneys P'OOd * 219 Eye Skin Breath Swallow Irr immed Water flush immed Resp support Medical attention Immed Eves resp sys CNS CVS blood chol repro sys NIOSH 5 ppm SA 12 5 ppm SA CF 25 ppm SAT CF/SCBAF/SAF 100 ppm SAF PD PP SCBAF PD PP/SAF PO PP ASCBA Escape GMFS/SCBAE inn Abs Ing Con Weak d iZ-2 head dysp cyan methemo pulm edema liver kidney damage Eye Skin Breath Swallow Irr immed Soap wash immed Resp support Medical attention immed Re^p sys liver kidneys blood CNS Chemical name structureitormula CAS and RTECS Nos and DOT ID and guide Nos Synonyms trade names and conversion factors Morpholine C4H,ON 110*1-8 Q08475000 Diethylene imidoxide Diethylene oxlmide Tetranydro-1 4-oxazine Tetrahydro-p-oxazwe 1780 154(aqueous) 2054 132 Naphtha (coai tar) 220 8030 30 6 DE3030000 1 ppm * 3 56 mg/m3 Crude solvent coal tai naphtha High solvent naphtha Naphtha Exposure Imtts (TWA unless noted otherwise) NOSH 20 ppm (70 mg/m3) ST 30 ppm (105 mg/m3) [skin) OSHAt 20 ppm (70 mg/m3) (akin) NIOSH/OSHA 100 ppm (400 mg/m'i ABD00022944 IDLH Physical description 1400 ppm [10%LEL] Colorless liquid with a weak ammonia or fish hke odor [Note A sofed below 23*F ] 1000 ppm [10%LEL] Reddish brown mobile liquid with an aromatic odor Chemical and physical properties MW BP SOL ft P IP Sp Gr flammability VP PRZ UEL LEL MW 87 1 BP 264'F Sol Miscible FIP(oc) 98`F IP 8 68 eV VP 6mm FRZ- 23*F UEL 112% LEL 14% Sp Or 1 007 Class 1C Flemmabie Liquid MW 110(approxi BP 320-428 F Sol Insoluble FI P 100 1 09"F IP 7 VP <5 mm FRZ UEL 1 LEL 1% 1256 128isolvent, 2653 128 Naphthalene 91 20-3 QJ0525000 1334 133 (crude or refined) 2304 133 (molten) Naphthalene dllsocyanale C H6(NCO)j 3173 72 6 NQ9600000 1 ppm = 4 50 mg/m3(approx) Naphthalln Tar camphor White tar 1 ppm 5 24 mg/m* NtOSH 10 ppm (60 mg/m3) ST 15 ppm (75 mg/m3) OSHAT 10 ppm (50 mg/m3) 5-Dllsocyanatonaphtha lene 1 5-Naphthalenedllsocyanate 1 5 Naphthalene ester of isocyamc acid NDl 1 ppm = 8 60 mg/m3 NOSH 0 040 mg/m' (0 005 ppm) C 0 170 mq/mJ (0 020 ppm) [10 mm] OSHA none 250 ppm Sp Gr 0 89-0 97 Class II Combustible Liquid Colorless to brown solid with an odor of mothballs. {Note Shipped as a molten solid ] MW 128 2 BP 424*F Sol 0 003% FI P 174*F IP 8 12 aV VP 0 08 mm MLT 178*F UEL 5 9% LEL 09% Sp.Grl 15 Combustible Solid, but wi Me some effort to Ignite ND White to light MW 2102 VP(75 F) yellow crystalline BP 505 F 0 003 mm flakes Sol ' MLT 261*F FI P(oc) 311 F UEL 7 IP 7 LEL 7 Sp Gr 7 Combustible Solid Incompatibilities and reactivities Measurement method (See Table 1) Strong acids strong oxidizers metals mtro compounds [Note Corrosive to metals ] Siqai H,SO./NaOH GC/FTO `1(3) [SI 50] Strong oxidizers Char GcfrlO IV [#1550) Strong oxidoera. chronic anhydride Ctw. GC?F1D IV p1501 Aromatic Hydrocarbona) None reported None available i L Personal protection and sanitation (See Table 3) Skin Eyea Wash akin Ramove Change Provide Prevent skin contact Prevent eye contact When contam When wet (tlamm; NR Ey*waeh(>15%) Quick drench (>25%) [Morpholine] Skin Eyes Wash skin Remov* Change Prevpnt skin contact P event eye -ontact Whei -ontam When wet or contam NR (Naphtha coai tar Skin. Eyaa. Wash akin Ramova. Charts: Prevent skin contact Prevent eye contact Whencontam Wien wet or contam Daily [Naphthalan*] Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam When wet or contam Daily (Naphthalene ditsocyanate] ABD00022945 Recommends (tons tor respirator concentration for use (MUC | (See Table 4} Route Symptoms (See Table 5) NIOSH/OSHA Wi 500 ppm SA-CF^PAPROV* Abs 1000 ppm CCRFOV/GMFOV/PAPRTOV1' mg SCBAF/SAF Con 1400 ppm SAF PD PP SCBAF PD PP/SAF PO PP ASCBA Escape GMFOV/SCBAE Irrit eyas stun nose rasp sys vis dist cough mammals liver kidney damage Health hazards First aid (See Table 6) Target organs (See Table S) Eve Skin Breath Swallow irr immed Water (lush immed Resp support Medical attention timed Eyes aton respsys liver Kidneys NIOSH/OSHA 1000 ppm SA CF'/CCRFOViGMFOV' PAPROV'/SCBAF'SAF SCBAF PD PP/SAF PD PP A5CBA scape oMFOV/SCBAfc mh Ing Con Irrit eyes sKir nose Ij bead drew derm mammals iver kidney damage Fye Skin Breath Swallow irr immed Soap wash piompt Ftesp Suppor" Medical attention immed E/es sum respsys CNS l ver kidneys NIOSHOSHA 100 ppm CCROVDM'/SA* 260 ppm SA.CF*/CCRFOVHIE/ PAPROVOMVSCBAF/SAF 4 SCBAF PD.PP/SAF PD PPJtSCBA escape GMFOVH/SCBAE Irti Irrit eyas head conf ADS exemment, nut. nau Ing vomit, atodom pain imt Con btadder profuse sweat pun, hama, hamog, rsnal ahuttwn derm, optical nauritka, com damage S& Breath Swatiow Irr immed Molten flush immed/ liver kidneys CNS eoMq soap wash prompt Row support Magical attention immed NOSH 0 05 ppm SA 0 125 ppm SA CF 0 25 ppm SCBAF/SAF 1 ppm SAF PD PP SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE hh ing Con Imt eyes nose throat resp sens cough pulm secretions chest pain dysp asthma Eye Skin Breath Swallow Irr immed Soap wash immed Resp support Medical attention rrvned Eyes respsys Chemical name structure; formula CAS and RTfcCS Nos and DOT ID and guide Nos Synonyms trade luines and conversion factors a Naphthylamme C, H NH 134 32 7 QM1400000 1 Ammonaphthalene 1 Naphthytamine 2077 153 13 Naphthylamme C CH NH 91 59 8 QM2100000 2 Ammonaphthaiene 2 Naphthylamme 1650 153 NJaxCi Catalyst ESN 62765-93-9 QR3900000 Nona [Note A Mixture of 95% dimethytamlnopropto- nttrUa & 5% bls<2dmethytaminojethyl ether] Nickel carbonyl Nj(CO), 13463 39 3 QR6300000 1259 131 Nickel tetracarbonyi Tetracarbonyl nickel 1 ppm = 6 98 mg/m5 Exposure limits (TWA unless nuted otherwise) ABD00022946 IDLH Physical disi ription NIOSH Ca See Appendix A Ca [NO] OSHA[19lO 1004] See Appendix B Colorless crystals wrth an ammonia like odor [Note Darkens in air to a reddish purple color ] Chemical and physical properties MW BP SOL FI P IP Sp Gr flammability VP FRZ Ufcc LEU MW 143 2 BP 573'F Sol 0 002% FI P 31 u'F IP 7 30 eV VP(220"F) 1 mm MLT 122'F UEL 7 LEL 7 incompatibilities and reactivities Oxidizes m air Measurement method (SeeTable 11 F Iter/ Si gel CH.COOH/ 2 Pro panol GC/FID NIOSH Ca See Appendix A Ca [N D ] OSHAJ1910 1009] See Appendix B NIOSH/OSHA See Appendix C NO NIOSH Ca See Appendix A 0 001 ppm (0 007 mg/m3) OSHA 0 001 ppm (0 007 mg/m3) Ca Combustible Solid Odoness white to red crystals with a fami aromatic ooor [Note Darkens in air to a reddish purple color ] MW 143 2 BP 583 F Sol Miscible m hot water F1P 315 F IP 9 71 eV VP(226 Fi 1mm MLT 232 F UEL ' LEL 7 Sp Gr(208 F) 1 06 Combustible Solid A liquid mixture [Note Used In the past as a catalyst inthe manufacture of flexible poly- urethane foame] MW mixture BP ? SOI 7 FI P 7 IP 7 VP 7 FRZ 7 UEL 7 LEL 7 SpGr ? Colorless to yellow liquid with a musty odor [Note A gas above 110"F] MW 170 7 BP 110'F Sol 0 05% FI P <-4`F IP 8 28 eV VP 315mm FRZ 13*F UEL ' LEL 2% None reported Oxidizers Filter/ Si gel CH.COOH/ 2 Pro panol GC/FID IV [#5518] None available Nitric acid bromine chlonne & other oxidizers flammable matenals Char(low HNOv GFAAS IV [#6007] Ni) Sp Gr(63*F) 1 32 Class IB Flammable LkjukI Personal protection and sanitation (See Table 3) Skffi Eyes Wash skm Remove Change Provide Prevent skin contact Prevent eye contact When contam/Daily When wet or contarn Daily Eyewash Quick drench [a-Naphthylarmne] Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam/Daily When wet or contam Daily Eyewash Quick drench (13 Naphthylamme] Skin. Eyee Wash akin Remove Change Provide Prevent skin contact Prevent eye contact When contam Wien wet or contam Dally Eyewash Quid'drench (MAX* Catalyst ESN] Skin Eyes Wash skin Remove Change Provide Prevent skm contact Prevent eye contact When contam When wet (flamm) NR Eyewash Quick drench (Nickel carbonyl] ABD00022947 Recommendations for respirator Health hazards selection--maximum-------------------------------------------------------------------------------------------------------------------------------------- concentration for use (MUC) Route Symptoms First aid Target organs (See Table 4| (See Table 5) (See Table S) (See Table 6) NIOSH V SCBAF PD PP/SAF PO PP ASCBA Escape HiEF/SCBAE Wi Derm hemonttagic Abs cystitis dysp ataxia Ing methemo hema dysuna Con [care] l: 8reath Swallow Immmed Soap wash immed Resp support Medical attention immed Bladder, skin [bladder cancer] NIOSH SCBAF PD PP/SAF PD PP ASCBA Escape HiEF/SCBAE Inn Abs Ing Con Derm hemontiagic cystitis dysp ataxia methemo hema dysuria [care] Eye Sinn Breath Swallow Irr immed Soap wash immed Resp support Medical attention immed Bladder skm (bladder cancer] 223 NIOSH SCBAF PD,PP/SAF PD,PP:ASCBA Escape GMFOV/SCBAE NIOSH SCBAF PD PP/SAF PD PP ASCBA Escape GMFS/SCBAE Wi 1niteyee, skin, unnary Abe dyafunc, neurological Ing disorders pins & needles Con sensation in hands & feet, muse week teas rtau vomit deer nerve conduction times of lower lege Inh Abs Ing Con Head verti nau vomit epigastric pain subs pain cough hyperpnea cyan weak leucyt pneuitis delirium convuls [care] in animals repro terato effects 111 Breath Swallow IE Breath Swallow Irr Immed Soap flush Immed Resp support Medical attention Immed Eyes, skin, urinary tract, PNS Irr immed Soap wash immed Re9p support Medical attention immed Lungs paranasal sinus CNS repro sys (lung & nasal cancer] Chemical name structure/formula CAS and RTECS Nos and DOT ID and guide Nos Nickel motel and other compounds (as Ni) Nl (Metal) 7440-02*0 (Metal) 0*6850000 (Metal) 224 Nicotine C5H.NC4H/JCH, 54-11-5 OS52SOOOO Synonyms trade names, and conversion factors Nickel metal Elemental metal, Nickel catalyst Synonyms ofother nickel compounds van/ depending upon the specific compound 3 (1 Methyl-2 pyrrolidyl) pyridine Exposure limits (TWA unless noted otherwise) ABD00022948 IDLH Physical description NiOSH* Ca See Appendix A 0 015 mg/m3 Ca [10 mg/mJ (as Ni)] Metal Lustrous silvery odorless solid OSHAf 1 mg/m3 {Note The REL and PEL do not apply to Nickel carbonyl ] NIOSH/OSHA 0 5 mg/m3 [skin] 5 mg/m3 Pale yellow to dark brown liquid with a fish-like odor when warm [insecticide] Chemical and physical properties MW, BP, SOL FI P IP Sp Gr, flammability VP, FRZ UEL LEL MW 58 7 BP 5139`F Sol Insoluble FI P NA IP NA VP 0 mm (approx) MLT 2831F UEL NA LEL NA incompatibilities and reactivities Strong acids sulfur selenium, wood & other combustibles nickel nitrate Sp Or 8 90 (Metal) Metal: Combustible 8olld, nickel sponge catalyst may Ignite SPONTANEOUSLY In air MW 162 2 BP 482*F (Decomposes) Sol Miscible FI P 203F IP 8 01 eV VP 0 08 mm FRZ 110 F UEL 4 0% LEL 0 7% Strong oxidizers strong acids Measurement method (See Tablet) Filter, Acid, ICP; IV {#7300, Elements] XAD 2 Ethyl acetate GC/NPD IV [#2544] 1654 151 Nttnc add HNO, 7887-37-2 QU5775000 1780 164 (<40% sad) 2031157(>40% add) 2032 157 (fuming) Nitric oxide NO 10102 43 9 QX0525000 Aqua fortle, Engravers add Hydrogen nfeate. Red timing nitric add (RFNA) mute timing nitric acid (WFNA) 1 ppm2 SSmo/m1 Mononitrogen monoxide Nitrogen monoxide 1660 124 1 ppm = 1 23 mg/m3 Sp Gr 1 01 Class DIB Combustible Liquid NIOSH/OSHA 25 ppm 2 ppm (5 mg/m3) St 4 ppm (10 mg/m3) OSHAf 2 ppm (5 mg/m3) Colorless, yellow or red fuming Uqmd with an acrid suffocating odor (Note Often used loan aqueous solution Fuming nitric add is conoantrated nitric add that contains dlesdvad nfeogan dioxide ] MW 63 0 BP 181 *F Sol Misoble FI P NA IP-1185 eV VP 46 mm FRZ -44"F UEL NA LEL NA SpGf(77*F) 1 50 Noncombustlbia Liquid but Increases ths flammability of combusObia materials Combustible materials metallic powders hydrogen sulfide carbides alcohols (Note Reacts with water to produce heat Corrosive to metals ] Si gel N^acHCCVt IV [87903 Inorganic Acids] NIOSH/OSHA 25 ppm (30 mg/m3) 100 ppm Coloness gas (Note Snipped as a nonliquefied compressed gas ] MW 30 0 BP 241 F Sol 5% FI P NA IP 9 27 eV VP 34 2 atm FRZ 263 F UEL NA LEL NA RGasD 1 04 Nonflammable Gas but will accelerate the burning of combustible materials Fluorine combustible Mol sieve matenals ozone NH3 Reagent chlorinated hydro- Vis carbons metals IV carbon disulfide (#6014) [Note Reacts with water to form nitric acid Rapidly converted) in air to nitrogen dioxide ] Personal protection (S*e Table 3) Stai vJashskln Remove Charge Prevent skin contact NR When contam/Daily When wet or contam CWrtly ABD00022949 Recommendations for respirator concentration for use (MUC) (See Table 4) NIOSH * SCBAF PD PP/SAF PD PP ASCBA Escape HiEF/SCBAE Route Symptoms (See Table 5) Inh Sens derm aHergic asthma Ing pneurtis [care] Con Health hazards First aid (See Table 6) Target organs (See Table 5) SkinBreath Swallow- Water flush immed Resp support Medical attention (rimed Nasal cavities, lungs skin (king & nasal cancer] (Nickel metal and other compounds (as Ni}] Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet or contam NR Eyewash Quick drench [Nicotine] Skin Eyee Wash skin Remove Cherige. Provide Prevent skin contact Prevent eye contact Whencontam When wet or contam NR Eyewash (pH<2 S) Quick drench (pH<2 S) (Nitric acid] Skin Eyes Wash skin Remove Change NR NR NR NR NR [Nitric oxide] NIOSH/OSHA 5 mg/m> SA/SCBAF SCBAF PD PP/SAF PO PP ASCBA Escape GMFOv/SCBAE Inn AOS Ing Con Nau salv abdom pain vomit diarr head dizz hearing vis dist conf weak into paroxysmal atrial fibn convuis dysp m animals terato effects NIOSH/OSHA 25 ppm SA CFVCCRFSVGMFSW SCBAFISAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFSVSC8AE Mi lrrttayes,skin muememb Ing delayed pulm edema Con pneurtis bron dental erosion Eye Skin Breath Swallow Irr immed Water flush immed Resp support Medical attention immed CNS CVS lungs Gi tract repro sys 1C Breath Swallow- Irr Immed Water flush Immed Resp support Medical attention immed Eyes skin reap sys teeth 225 NIOSH/OSHA 100 ppm SA CF /CCRFSVPAPRS V GMFS`/SA /SCBAF SCBAF PD PP/SAF PO PP ASCBA Escape GMFSvSCBAE inh irnt eyes wet skm nose Breath throat drow uncon methemo Resp support Eyes skin resp sys Wood CNS Chemical name structure/formuia CAS and RTECSNos and DOT ID and guide Nos Synonyms trade names factors p-Nitroamline NO,CJH.NH, 100-01-6 8Y7000000 para Arrxnonitrobenzene 4-Nitroamhne 4-Nitrobenzenamlne ^Nitrophenylamine 1601186 Nitrobenzene C,h5NOj 98 95 3 DA6475000 Essence of mirbane Nitrobenzol Oil of mirbane 1662 152 4-Nitroblphenyl <WVVi 02-03-3 DVS600000 1 ppm = 5 04 mg/m3 p-Nitroblpheny p-Nitrodiphenyl, 4-Nltrodlphenyl D-Phenvlnitrobenzene 4-Phenytmtrobenzene PNB p Nitrochlorobenzene CIC6H4NOj 100 00 5 CZ1050000 p Chloromtrobenzene 4 Chloromtrobenzene 1 Chloro-4-mtrobenzene 4 Nitrochlorobenzene PCNB PNCB 1570 152 Exposure krrrts (TWA unless noted otherwise) NIOSH 3 mg/m5 [skin] OSHAf 6 mg/m3 (1 ppm) [skin] ABD00022950 IDLH Physical description 300 mg/m3 Bnght yeHow crystalline powder with a slight ammomarlike odor NIOSH/OSHA 1 ppm (5 mg/m5) [Skin] 200 ppm Veiiow oily liquid with a pungent odor like paste shoe polish [Note A solid below 42 F ] NIOSH Ca See Appendix A Ca [ND] OSHAflOlO 10031 See Appendix B White to yellow noodle like, crystalline solid wim a sweetish odor NIOSH Ca See Appendix A [skin] OSHA 1 mg/m5 [skin] Ca [100 mg/m3] Yellow crystalline solid with a sweet odor Chemical and physical properties MW BP SOL FI P IP Sp Gr, flammability VP FRZ DEL, LEL Incompatibilities and reactivities Measurement method (See Table 1) MW 138 1 BP 630*F Sol 0 08% FI P 390'F IP 8 85eV VP 0 00002 mm MLT 295*F UEL 7 LEL 7 Strong oxidizers strong reducers [Note May result in spontaneous heating of organic materials in the presence of moisture ] Filter 2-Propanol HPLC/UVD IV [#5033] Sp Gr 1 42 Combustible SoDd MW 123 1 BP 411"F Sol 0 2% Fi P 190 F IP 9 92 eV VP(77 F) 0 3 mm FRZ 42 F UEL 7 LEL(200 F) 1 8% Sp Gr 1 20 Class niA Combustible Liquid Concentrated nitnc acid nitrogen tetroxide caustics phosphorus penta chloride chemically active metals such as tin or zinc Si gel Methanol GC/FID IV [#2005] MW- 1992 BP 644*F Sol Insoluble FI P 290*F IP 7 VP ? MLT 237*F UEL 7 LEL? Strong reducere SpGr ? Combustible Solid Filter/ Si gel(2) 2-Propanol GC/FID 11(4) [P&CAM #273] MW 157 6 BP 468 F Sol Slight FI P 261 *F IP 9 96 eV VP(86 F) 0 2 mm MLT 182*F UEL ' LEL 7 Strong oxidizers alkalis Sp Gr 1 S2 Solid that does not burn or burns with difficulty Methanol GC/FID IV (#2005 Nitro benzenes] Personal protection and sanitation (Set Table 3) SKin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam/Daily When wet or contam Daily Quick drench [p-Nitroamlme] Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact NR When wet or contam Daily Quick drench [Nitrobenzene] Stun Eyas Wash skin Remove Change Provide Prevent stun contact Prevent eye contact When contam/Daily When wet or contam Daily Eyewash Quick drench [4-Nitroblphenyl] Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam/Daily When wet or contam Daily Eyewash Quick drench [p Nitrochlorobenzene] ABD00022951 Recommendations tor respirator selection - maximum torn.duration for use (MUC-r (See Table 4) NIOSH 30 mg/m3 SA 75 mg/m SA Ch 150 mg/m3 SCBAF/SAF 300 mg/m1 SAF PD PP SCBAF PD PP/SAF PD PP ASCBA Escape GMFOVOMFufSCBAE Route Symptoms (See Table 5) inh Abs Ing Con irrit nose throa* cyan ataxia tacar tachypnea aysp rrrity vomit diarr convuls resp arrest anemia methemo jaundice Heaitn Hazards hirst aid iSee Table 6| bye Skin Breath Swallow Irr intmed Water flush mimed Resp support Medical attention immed Target organs (See Table 5) Resp sys blood near! liver NIOSH/OSHA 10 ppm CCROV/SA 25 ppm SA CF'/PAPROV 50 ppm CCRFOV/GMFOV/PAPRTOW SCBAF/SAF 200 ppm SAF PD PP SCBAF PD PP/SAF PO PP ASCBA Escape GMFOV/SCBAE Inh Abs Ing Con Irrit eyes skin anoxia derm anemia methemo in animals liver kidney damage testicular effects Eye Skin Breath Swallow Irr immed Soap wash immed Resp support Medical attention immed Eyes skin blood liver kidneys CVS repro sys NIOSH SCBAF PD PP/SAF PD,PP ASCBA Escape HlEF/SCBAE Inh Abs Ing Con Head leth.dizz, dysp ataxia weak, methemo unnary burning scute hemorrhagic cystitis, [care] IE, Breath Swallow Irr immed Soap wash immed Resp support Medical attention immed Bladder blood finammelt bladder tumors] 227 NIOSH SCBAF PD PP/SAF PD PP ASCBA Escape HiEF/SCBAE mn Abs Ing Con Anoxia unpleasant taste anemia methemo mammals hema hemog spleen kidney bone marrow changes repro effects [care] Eye Skin Breath Swallow irr immed Soap wash immed Resp support Medical attention immed Blood liver kidneys CVS spleen bone marrow repro sys [mammals vascular & liver tumors] Chemical name structure/formula CAS and RTECS Nos and DOT ID and guide Nos Synonyms trade nameb and conversion factors Nrt/oethane CHjCHjNOj 79 24 3 K15600000 N iroetan 2642 129 Ni'rogen dioxide 228 1010? 44 u OW9BOOOOO 106' 124 Nitrogen trtfluortde NF, 7783-54-2 QX192SOOO 1 ppm 3 07 mg/m5 Dinitrogen letroxide NO, Nitrogen peroxide 1 ppm r 1 88 mgrm Nitrogen fluonde Trlfluorammonia 2491 122 Nitroglycerine CHjNOjCHNOjCHjNOj 55-63-0 QX2100000 1204 127(<1%soln m alcohol) 3064 127 (1 5%aoln in alcohol) 1 ppm * 2 90 mg/m3 Glyceryl trinitrate NG 1 2 3 Propanetnol tnnitrale Trinitroglycerine 1 ppm = 9 29 mg/m5 Exposure touts (TWA unless noted otherwise) ABD00022952 IDlr Physic al ih bC^iptlOl NIOSH/OSNA 100 ppm (310 mg/m3) 1000 ppm Colorless oily I quid with a mild fruity odor Chemical am' physn al proper! ie- MW BP SOI FI P IP Sp Gr flammability VP FRZ DEL LEI MW 7o 1 BP 237 F Sol 5% FI P 82`F IP 10 88 eV VP( 77 F) 21mm FRZ 130 F UEL ? LEI 34% Incompatibilities and reactivities Measurement method (See Table ' i Amines strong acids alkalis & oxidizers hydrocarbons combustibles metal oxides XAD 2(2) Ethyl acetate GC/FIO IV (#2526] NIOSH 5T 1 ppm 1 3 mg,m3, OSHAt C 5 ppm iS mg/m i NIOSH/OSHA 10 ppm (29 mg/m*) NIOSH ST 0 1 mg/m5 [skin] OSHAT C 0 2 ppm (2 mg/m3) (skin] Sp Gr 1 05 Class 1C Flammable Liquid 20 ppm 1000 ppm Yellowish brown liquid or reddish brown gas iabove 70 V i with a pun gent acrid odor (Note ri solid lorrn iDelOW 15 F) it is found structurally as N 0,, ) MW 46 0 BP 70 F Sol Reacts FI P NA IP 9 75eV VP /20 mm FRZ 15 F UEL NA LEL NA Combustible material water chionnated hydrocaibons carbon disulfide ammonia (Note Reacts with water to form Sp Gr 1 44 (Liquid at 68 F, nitric acid , RGasD 2 62 NoncomOustible UquidiGas but wi i accelerate the burning of combustible nalenals Moi sieve Reagent Vis IV (#6014) Colorless gee with a moldy odor (Note Shooed ae nonUquefted compressed gas] MW 71 0 BP -200*F Sol Slight FIP NA IP 12 B7eV VP >1 atm FRZ. -340*F UEL NA LEL NA RGasD 246 Nonflammable Gas Water o* grease oridttaMe materials, ammonia. carbon monoxide methane, hydrogen, hydrogen suOde acbvawd charcoal, dlborana None iVMHW 75 mg/m3 Colorless to pale yellow viscous liquid or solid (below 56*F) (Note An explosive ingredient in dynamite (20-40%) with ethylene glycol dinitrate (80-60%) ] MW 227 1 BP Begins to decompose at 122 140 F Sol 0 1% FI P Explodes IP 7 So Gr 1 60 Explosive Liquid VP 0 0003 rrm FRZ 56 F UEL 7 LEL 7 Heat ozone shock acids (Note An OSHA Class A Explosive (1910 109) ] Tenax GC Ethanol GC/ECD IV (#2507) Personal protection and sanitation (See Table 3) Skin Eye* Wash skin Remove Change Prevent ekin contact Prevent eye contact Whencontam When wet (Hamm) NR (Nttroethane) Skm Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet or contam NR Eyewash Quick drench [Nitrogen oionde] Sttl tfSshskJn Remove Change NR NR NR NR NR (NBnpgeo Hktonde] Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet (flamm) Daily Quick drench [Nitroglycerine] ABD00022953 Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table 4) NIOSH/OSHA 1000 ppm SCBAF/SAF SCBAF PD PP/SAF PO PP ASCBA Escape SCBAE Route Symptoms (See Table 5] Mi Derm Ing in animals iac dyep Con puim rales edema liver udney in) narco Health hazards First aid (See Table 6) Target organs (See Table S') I Breath Swallow Itrimmed Soap wash prompt Resp support Medical attention mmed Skin respsys CNS kidneys liver NIOSH 20 ppm SA CF'/SCBAFVSAF SCBAF PD PP/SAF PD PP ASCBA escape GMFS /SCBAE Infi ing Con irnt eyes nose throat cough mucoid frothy sputum decrpulmfunc chronic bron dysp chest pain puim edema cyan tachypnea tacar Fye Skir Breath Swallow Irrimmed Water flush immed Rasp support Medical attention immeo Eyes respsys CVS 229 NKQSrtOSHA 100 ppm CCR8/SA 250 ppm SACF/PAPRS 600 ppm CCRFS/OMFS/PAPRT8V SAT CFVSCBAF/SAF 1000 ppm SAF PD PP SCBAF PD PP/SAF PO PP.ASC6A Escape OMFS/SCBAE Ml Inanimate anoxia cyan methemo weak dizz head Hvar kidney mj NKDSH 1 mg/m3 SA 2 5 rrig/m3' SA CF 5 mg/m3- SAT CF'/SCBAF/SAF 75 mg/m3 SAF PDPP SCBAF PD PP/SAF PO PP ASCBA Escape GMFOVHiE/SCBAE Abs Ing Con Throb head dizz nau vomit abdom pain hypotension flush palp methemo delirium CNS depres angina skin imt Breath Reap support Blood liver, kidneys Skin Breath Swallow irr immed Soap wash immed Resp support Medical attention mmed CNS Chemical name structure/fonnula CASand RTECSNos , and DOT ID and guide Nos Synonyms trade names and conversion factors Nitromethane CH3NO^ 7S-52-5 PA9800000 Nitrocarbol 230 1261 129 2 Nitronaphthaiene C _H NO_, 581 89 5 QJ976QQ00 2538 133 1-Nitropropane CHjCHjCHjNOj 108-03-2 TZ5075000 2606 129 2 Nitropropane (CH3) chno 79 46 9 TZ5250000 1 ppm = 2 50 mg/m3 (l Nitronaphthaiene Nitropropane 1-NP 1 ppm = 3 64 mg/m3 Dimethylmtromethane iSO-Nitropropane 2 SP 2608 129 1 ppm = 3 64 mg/m3 Exposure limits (TWA unless noted otherwise} NIOSH See Appendix D OSHA "00 ppm (250 mg/m3) ABD00022954 IDLM Physical description 750 ppm Colorless oilv liquid with a d sagreeable odor Chemical and physical properties MW BP SOL FI P IP, Sp, Gr, flammability VP FRZ UEL, LEL MW 61 0 BP 214'F Sol 10% FI P 95 F IP 11 08eV VP 26 mm FRZ 20*F UEL 7 LEL73% NIOSH Ca ba (N D ] See Appendix A [ Note Since metabolized to fi Naphthylamme I OSHA none Colorless solid NIOSH/OSHA 25 ppm (90 mg/m3) 1000 ppm Colorless liquid with a somewhat disagreeable odor Sp Gr 1 14 Class 1C Flammable Liquid MW 178 2 BP ' Sol Insoluble FI P 7 IP 867eV VP ' MLT '74 F UEL 7 LEL 7 Sp Gr 7 Combustible Soiio MW 89 1 BP 268*F Sd 1% Fi P 96*F IP 10 81 eV VP 8 mm FRZ -162*F UEL ? LEL 2 2% NIOSH Ca See Appendix A OSHAT 25 ppm (90 mg/m3) Ca [100 ppm] Colorless liquid with a pleasant fruity odor Sp Gr 1 00 Class 1C Flammable Liquid MW 89 1 BP 249 F Sol 2% FIP 75 F ip 10 71 eV VP 13mm FRZ 135 F bEL 110% LEL 2 6% Sp Gr 0 99 Class 1C Flammable Liquid Incompatibilities and reactivities Measu rement method (SeeTable 1) Ammes strong acids alkalis & oxdizers hydrocarbons & other combustible matenals metallic oxides {Note Slowly corrodes steel & copper when wet ] Chrom 106 Ethyl acetate GC/FPD IV (#2527) For Nitrates in general Aluminum cyanides esters phosphorus tin chlorides thiocyanates sodium hypophosphite None available Amines strong acids alkalis & oxidizers hydrocarbons & other combustible materials metal oxides XAO-4 gcSnpd OSHA [*<61 Ammes strong acids alkalis & oxidizers metal oxides combustible matenals Chrom 106 Ethyl acetate CCJFID IV [#2528] Personal protection and sanitation (See Table 3) SKin. Eyes Wash skirt Remove Change Prevent skin contact Prevent eye contact When contain Wien wet (flamm) NR (Nttromethane] Skirt Eyes Wash skin Remove Cnange Provide Prevent skin contact Prevent eye contact When cortam/Daity When wet or contam Daily Eyewash Qmckdrench [2 Nitronaphthalene] Skin. ` rtSShaWn Remove. Chang* NR Prevent eye contact Wren wet (flamm) NR {1-NltropropaneJ Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam When wet (flamm] NR [2 Nrtropropane] ABD00022955 Recommendations for respirator selection--maximum concentration for use (MUC) (See Table 4) OSHA 760 ppm SA CFf/SCBAF/SAF SCBAF PD.PP/SAF PD,PP ASCBA Escape SCBAE Route Symptoms (See Table 5] hh log Con Derm mammals ifriteyes reap sys convuls, narco liver damage Health hazards First aid (See Table 6) Target organs (See Table 5) S Breath Swallow trnmnved Soap wash prompt Resp support Medical attention immed Eyes skin CMS liver NIOSH V SCBAF PD PP/SAF PD PP ASCBA Escape GMFOVHiE/SCBAE Inh Abs Ing Con Irritskm resp sys derm [care] Eye Skin Breath Swallow irr immed Soap wash immed Resp support Medical attention immed Skin resp sys [bladder cancer] NIOSH/OSHA 250 ppm SA* 825ppm SA.CF* 1000 ppm SC8AF/SAF SCBAF PD.PP/SAF PO.PP.ASCBA Escape: SCBAE Hi Irrtt met; heed, nau 'no vomit diarr, Con Inarimale. liver, kidney damage S& Breath Swallow- Irr immed Soap wash prompt Reap support Medical attention timed Eyes, CNS, liver, kidneys NIOSH U SCBAF PD PP/SAF PD PP ASCBA Escape SCBAE Inh Ing Con Imteyes skin nose resp sys head anor nau vomit diarr kidney liver damage [care] Eye Skin Breath Swallow Irr immed Soap wash prompt Resp support Medical attention immed Eyes skin resp sys CNS kidneys liver [mammals livet tumors] Chemical name structure/formula CAS and RTECS Nos and DOT ID and guide Nos Synonyms trade names and conversion factors Exposure limits (TWA unless noted otherwise) ABD00022956 IDLH Physical description N-Nttrosodirnethylamine (CHjJjNjO 62-75-9 IQ0525000 Dimethylmtrosamine N.N-Dimethylnitrosamine DMNA N-Methyl-N-mtroso- methanamine, NOMA N-NItroso-N N-dimethylamlne NIOSH Ca See Appendix A OSHA(1910 1016] See Appendix B Ca [ND] Yellow oily liquid with a famt character istic odor 232 0 Nitrotoluene NOjCcHtCH 86 72 2 XT3150000 1664 1 52 m-NItrotoluene NO,CJH,CH, XT2975000 1664 152 NOi.C,VH .CH 0 99 99 0 XT332500C 1664 152 o-Methylnitrobenzene 2-Methylmtrobenzene ortno Nitrotoluene 1 ppm = 5 61 mg/m3 m-Methylnltrobenzene 3-Methylnitrobenzene 1 ppm = 5 61 mg/m3 p MetnylmtroDenzene 4 Methylmtrobenzene para Nitrotoluene 4 Nitrotoluene 1 ppm = 5 61 mg/m3 NIOSH 2 ppm (11 mg/m-h OSHAT 5 ppm (30 mg/m') |Skm] NIOSH 2 ppm (11 mg/m5) [skin) OSHAT 5 ppm (30 mg/m3) [skin] NIOSH 2 ppm (11 mg/m3) [skin] OSHAT 5 ppm (30 mg/m3) [skin] 200 ppm Yellow liquid with a weak aromatic odor [Note A solid Delow 25 F ] 200 ppm Yellow liquid wtm a weak aromatic odor (Note A solid below 59"F ] 200 ppm Crystal.me solid with a weak aromatic odor Chemical and physical properties MW BP SOL FI P, IP, Sp Or flammability VP FRZ UEL LEL MW 74 1 BP 306F Soi Soluble FI P 7 IP 8 69 eV VP 3 mm FRZ ? UEL? LEL? Sp Or 1 005 Combustible Liquid1 MW 137 1 BP 432 F Sol 0 07% FI P 223 f- IP 9 43 eV VP 0 1 mm FRZ 25 F UEL 7 LEL 2 2% Sp Gr t 16 Class IUB Combustible Liquid MW 1371 BP 450*F Sol 0 05% FI P 223`F IP 948 eV VP 01mm FRZ 59"F UEL ? LEL 16% So On 16 Class IIIB Combustible Liquid MW 137 1 8P 460 F Sol 0 04% FI P 223 F IP 9 50 eV VP 0 1 mm MLT 126 F UEL 7 LEL 1 6% Sp Gr 112 Combustible Solid Incompatibilities and reactivities Strong oxidizers [Note Should be stored in dark bottles ] Strong oxidizers sulfuric acid Strong oxidizers sutfune ecid Strong oxidizers sulfuric acid Measurement method (See Table 1) T-Sorb, Methanol/ CHjCI,, GC/FIIJ (V [#2522] Si gel Methanol [#2005 Nitro benzenes] SI gel Methanol IV [#2005 Nitro benzenes] Si gel Methanol GC/FID IV (#2005 Nitro benzenes] Personal protection (See Table 3} Stan WsshskJn Remove Change Provide Prevent skin contact Prevent eye contact When conlam/Daily When wet or contain Oady Eyewash Quick drench (N-Nitroaodimethylamtne) Skin Eyes Mash skm Remove Change P'even1 skin contact Prevent eye contact When contam When wet or contam NR C Nitrotoi u ere, 8Wn vSSheWr. tacnovaCtangaL Prevent akin contact Prevent eye contact Whencontam When wet or contam N.R. (nvNRrototaeneJ Skin Eyes Wash skm Remove Change Prevent skm contact Prevent eye contact When contam When wet or contam Daily (p Nitrotoloenel ABD00022957 Recommendations for respirator concentration for use (MUC) (See Table 4} NIOSH V SCBAF PO,PP/SAF PD.PP ASC8A Eacape HiEF/SCBAE Route Symptoms (See Table S) Hi Nau, vomit, diarr, Abs abdomcrampa head )C"o9n fever enlarged Irver jaun, deer liver kidney, polm tone; {cere] Health hazards First aid (Sae Table 6) a; Breath Swallow Irrlmmed Soapweah immod Reap support Medical attention toned Target organs (Sae Table 6) Uver kidneys, lunge (In animats lung kidney. liverSnaeei cavty tumors) NIOSH 20 ppm SA 50 ppm SA CP 100 ppm SAT CF/SCBAF/SAF 200 ppm SAF PD PP SCBAF PD PP/SAF PD PPASCBA Escape GMFOVHiE/SCBAE inn APS inj Ccn Mnoia cyan head weak dizz ataxia dysp tarar nau vomit NOSH 20 ppm SA* SO ppm SA.CF* 104 ppm SAT CFV8CBAF/SAF 200-ppm SAF PD.PP StSCBAFPO PP/SAF'PDPPjASCBA. Eacape GMFOVHIE/SC8AE , NIOSH 20 ppm SA 50 ppm SA CF' 100 ppm SAT CF'iSCBAFfSAF 200 ppm SAF PD PP SCBAF PD PP/SAF PD PP ASCBA Escape GMFOVHiE/SCBAE Hi Arana, cyan, head Abe weak, dfea; ataxia, Jr>9 dyep, tacsr, nau, vomK Con - Inh Abs Ing Con Anoxia cyan head weak dizz ataxia dysp tacar nau vomit Eye Skin Breath Swallow Irr mmed Soap wash immed Resp support Medical attention immed Blood CNS CVS skm Gl trac' 233 IT. Breath 8wancw IrrImmed Soapwash Immed Raw aupport MfOtonStpnMrt tomad Blood, CNS CVS, Wn. Attract Eye Skin Breath Swallow irr immed Soap wash immed Resp support Medical attention immed Blood CNS CVS skm Gl tract Chemical name structure/formula CAS and RTECS Nos , and DOT ID and guide Nos Synonyms, trade names and conversion factors 234 Nitrous ode 10024-97-2 QX1350000 1070 122 (compressed) 2201 122 (refrigerated liquid) Nonane CHjiCHJ CH3 111 842 RA6115000 Dmitrooen monoxide, Hyponctroueactd anhydride, Laughing gas 1 ppm* 1 80 mg/m3 n-Nonane Nonyl hydride 1920 128 1-NorwnalNol OyCH^SH 146&21-6 1 ppm = 5 25 mg/ms 1 Mercaptohonsha, n-Nonyt mercaptan Nonyfthlol 122ft 131 Octachloronaphthalene C cC's 2234 13 1 QK0250C00 1 ppma6S6mgfms Halowax1051 1 2 3 4 5 6 7 6-Octa chloronaphthalene Perchloronaphthalene ABD00022958 Exposure kmfts (TWA unless noted otherwise) IDLH NIOSH* ND 25 ppm {48 ma/nt5) {TWA war the time exposed) {Note REL for expoture to waste anesthetic oSS} none Physical description Chemical and physical properties MW BP SOL FI P IP Sp Gr, flammability VP FRZ UEL LEL Incompatibilities and reactivities Colorless gss with a slightly sweet odor [Inhalation anesthetic] [Note Stopped ea a liquefied compressed gas) MW 44 0 BP -127*F som'Fyow Fl P- NA IP 12 89 sV VP 51 3 atm FRZ.-132*F UELNA LEL NA Aluminum, boron, hydrazine, lithium hydride phosphine, sodium RGosO 1 53 Nonflammable Gas but supports combustion at elevated temperatures Measurement method (See Table 1) Bag none, IR, IV [#6800] NIOSH 200 ppm (1050 mg/m3) OSHAT none ND Colorless liquid with a gasoline like odor MW 128 3 BP 303 F Sol Insoluble Fl P 88 F IP 10 21 eV VP 3 mm FRZ -60F UEL 2 9% LEL 0 8% Strong oxidizers (e g peroxides nitrates perchlorates) None available MOSH C 0.5 ppm 06HA none NIOSH 0 1 mg/m3 ST 0 3 mg/m3 [skin) OSHAt 0 1 mg/m3 [skin] N.0 Liquid Sp Gr 0 72 Class 1C Flammable Liquid MW- 160.3 BP ? Sol. insoluble FiPr? IP-? VP, ? FRZ ? UEL? LEL? Unknown Waxy pale yellow solid with an aromatic odor 8p<3r ? Combustible Liquid MW 403 7 BP 770 F Sol insoluble Fl P NA IP i VP <1 mm MLT 365 F UEL NA LEL NA Sp Gr 2 00 Noncombustible Solid Oxidizers, reducing None agents, strong sens & avallabia bases, alkali metal* Strong oxidizers Filter Hexane GC/FlD 11(2) [#S97] Personal protection and sanitation |See Table 3) Skin Eyes Wash skin Remove Chanqe rovide Frostbite Frostbite NR NR NR Frostbite ABD00022959 Recommendations for respirator selection -- maximum concentration for use (MUC (See Tame 4) TBAl. mutt Symptoms (See Table 5) Inn Con (lip) Oysp drow bead asphy repro effects nq frostbite Health hazards First aid (See Table 6) Eye Skin Breath Frostbite Frostbite Fresh air Target organs (See Table 5) Resp sys CNS repro sys [Nitrous oxide] S>r Eyes Was- ski Remove Change Provde NR O I 0y g Da . Vhe~ v-e ' ami NR Eyewash ---------------- Inf nq von rrnteyes Sk n rose throat heaa brow a zz ZO^* ''2Z o ftCO dySD chem ca pr-eu laspir ,q Eye Skin Bieat^ SwalLw m nmed Soap wash immed Reso support Medica1 attention immed Eyes sxir resp sys CNS inch a-ie] Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam When wet or contam NR (t-Nonanethiol] Skm Eyes Wash skin Remove Change Prevent skm contact Prevent eye contact 'When contam/Dai y When wet or contam Daily NIOSH 5 ppm CCROV/SA 12 5 ppm SACF/PAPROV 25 ppm CCRFOV/GMFOV/PAPRTOV/ SCBAF/SAF SCBAF PD PP/SAF PO PP ASCSA Escape GMFOV/SCBAE tnh Irvg Con Irrrteyes skin nose throat weak cyan mcr respiration nau drow head vomit NIOSH/OSHA ' mg/m1 SA/SC8AF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOVHiE/SCBAE Con Acne-form derm liver damage jaun Eye Skin Breath Swallow Irr Immed Soap wash Reap support Medical attention immed Eyes, skin, resp sys blood crJs Eye Stun Breatn Shallow irr immed Water flushimmed Resp support Medical attention immed Skm nver Oetachloronapnthaiene] Chemical name structure/formula, CAS and RTECSNos, and DOT ID and guide Nos Synonyms, trade names and convention factors l-Ocfedecanetruoi CH,(CH,)1,SH 2885-00-9 1 -Mercaptooctadecane Octadeeyi mercaptan Steoryi mercaptan Octane 111-65-9 RG8400000 1262 128 i-Octanethiol CH^CHjJjSH 111-6*8 1ppm=11 72/ng/m3 n Octane normal Octane 1 opm = 4 67 mg/m3 1-Merceptooctane n-Ocfyl mercaptan Octylthlot. 1-Octytthiol Oil mist (mineral) 8012 95 1 PY8030000 1 ppm * 5 98 mg/m* Heavy mineral oil mist Paraffin ail mist White mineral oil mist Exposure limits (TWA unless noted otherwise) NIOSH C 0 5 ppm (5 9 mg/m3) [15-mirt] OSHA none ABD00022960 IDLH Physical description ND Solid or liquid (above 77'F) NIOSH 1000 ppm 75 ppm I10%LL] (350 mo/m'l C 385 ppm (1800 mg/m ') (15 mm' OSHAt 500 ppm (2350 mg/mJ oOioness nquid with a gasoline like odor NIOSH COS ppm (3 0 mg/ms) 115-min] OSHA none NO Water-white liquid with a mild odor NIOSH 5 mq/mJ ST 10 mg/m1 OSHA 5 mg/m3 2500 mg/m' Colorless oily liquid aerosol dispersed in air (Note Has an odor like burned lubricating oil ] Chemical and physical properties MW BP SOL FI P IP Sp Gr flammability VP FRZ UEL LEL MW 286 6 SP ? Sol Insoluble FI P 7 IP 7 VP 7 MIT 77`F UEL 7 LEL ? Sp Gr 0 65 Combustible Solid Combustible Liquid MW 1 ,4 <. BP 250 F Scl(77 Fi 0 00007% FI H 56 F /P 1U --irri UL L 6 5"' Lf L 1 0"'o Sp Gr 0 70 Class Flammable Liquid MW- 146 3 BP 390*F Sot Insoluble FIP(oc) 11SF (P 7 VP(212*F) 3mm FRZ -67"F UEL 7 LEL 7 Sp Gr 0 84 Claes ll Combustibie Liquid MW Vanes BP 680 F Sol insoluble 1 P(oc) 380F IP ' VP -C 5 mm FR7 0 f UEL 7 LEL 7 Sp Gr 0 90 Class IIIB Combustible liquid Incompatibilities and reactivities Measurement method (See Table 1) Oxidizers reducing agents strong acids bases alkali metals None available b rung .npizers Cnai oS GC/FID IV [#1500 Hydro carbons] Oxidizers reducing agents strong acids & bases alkali metals TenaxGC Acetone GC/FPD IV [02510] None reported Filter CCI. IR IV (#5026) Personal protection and sanitation (See Table 3) Skm Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam When wet or contam Daily (1 Octadecanethioi] t yes Wash ski Remove C*onoc 'it e l skir contact i revet t eye conlac vVnen i_on|a n Ahei we' 'Irmr NR Ic/ctane Skm Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact Whencontam When wet or contain NR [1 OctanetPiol] Skm Eyes Wash skin Remove Change Preveni skmcontact NR When cuntam When wet or contam Daily (Oil mist trroneiaii) ABD00022961 Recommendations tor respirator selection -- maximum concentration for use (MUC) (See Table 4) Route Symptoms (See Table 5) NIOSH 5 ppm CCROV/SA 12 5 ppm SA CF/PAPROV 25 ppm CCRFOV/GMFOV/PAPRTOV/ SCBAF/SAF SCBAF PD PP/SAF PD PP ASC8A Escape GMFOV/SCBAE Wi Abs ing Con tmt eyes skm resp sys head dizz weak cyan nau convuls Health hazards Flrstaid (See Table 6) Eye Skin Breath Swallow Irr immed Soap wash Immed Resp support Medical attention znmed Target organs (See Table 5) Eyes skin reap sys CNS blood NlOol '5u ^pi' SA '000 ppm bALF /SCBAF'SAF SCBAF PD PP/SAF PD PP ASCBA scape ijMFOV SCtlAE icy ing or irr t eyes 1 ose arow aerm chemica precidspn Uq ri animals nar c> Eye Ski' Bseath Swaiow irnnmed Soap wash prompt Resp support Medical attertor inmeo t/es skin respsys .NS 237 NIOSH 5 ppm CCROV/SA 12 5 ppm SA CF/PAPROV 25 ppm CCRFOV/GMFOV/PAPRTOV/ SCBAF/SAF t SCBAF PD PP/SAF PD PP ASCBA scape GMFOV/SCBAE Wi Irrtt eyes skin nose Ing throat weak cyan incr Con respirabon nau draw head vomit NiOSM/OSHA 50 mg/m' HiE/SA i25mg/m' SA CF/PAPRHiE 250 mg/m-* HiEF/SAT CF/PAPRTHiE/ SCBAF/SAF 2500 mg/m SA PD PP SCBAF PD PP/SAF PD PP ASCBA Escape HiEF/SCBAE inn 'mt eyes skm reso sys Con Breath Swallow Irr Immed Soap wash immed Resp support Medical attention immed Eyes skin resp sys blood CNS Skin Breath Soap wash Fresh air Eyes sum resp sys Chemical name structure/formula CAS and RTECS Nos and DOT ID and guide Nos Synonyms trade namos and conversion actors Osmium telfoxide OsO, 20816-12-0 RN1140000 Osmic acid anhydride Osmium oxide 238 2471 164 Oxalic acia HOOCCOOH 2H 0 144 62 7 R0245000G 1 ppm b10 40 mg/m3 Ethanedioic acid Oxalic acid (aqueousi Oxalic acid dihydrate Oxygen difluonde 7783-41-7 RS2100000 2190 124 Ozone Oj 10028 15 6 RS8225000 Dlfluortne monoxide Fluorine monoxide Oxygen fluoride 1 ppm 2 21 mg/m3 Tnatomic oxygen 1 ppm = 1 96 mg/m3 Exposure limits (TWA unless noted otherwise) NIOSH 0 002 mg/m3 (0 0002 ppm) ST 0 006 mg/m3 (0 0006 ppm) OSHAt 0 002 mg/m3 NIOSH 1 mg/m ST 2 mg/m' OSHAT 1 mg/m NIOSH C 0 OS ppm (0 1 mg/m3) OSHAt 0 05 ppm (01 mgton*) NIOSH C 0 1 ppm (0 2 mg/m3) OSHAt 0 1 ppm (0 2 mg/m3) ABD00022962 IDLH Physical description 1 mg/m1 Colorless crystalline solid or pale yellow mass with an unpleasant acrid chlorine like odor [Note A liquid above105F] Chemical ana physical properties MW BP SOL FI P IP Sp, Gr flammability VP FRZ UEL LEL MW 254 2 BP 266F Sol(77'F) 6% FI P NA IP 1260 eV VP 7 mm MLT 105"F UEL NA UEL NA Sp Gr 5 10 Noncombustible Solid 500 mg/m 0 5 ppm Col iriess Odorlesx powder or granular sond (Note The annydrouS form COOH j is an oooriess white solid l MW '26 BP Sublimes Sol 14% Ftp ? IP > VP <U 00' HTTi MLT 215 f ^Sublimes UEL 7 uEL 7 Sp Gr 1 90 Combustible Solid Colorless gas with a peculiar foul odor [Note Shipped as a nonllquefled compressed gas ] MW 54 0 BP -230*F Sol 0 02% FI P NA IP 13 11eV VP >1 atm FRZ -371*F UEL NA LEL NA RGasD 1 88 Nonflammable Gas but a strong oxidizer 5 ppm Colorless to blue gas with a very pungent odor MW 48 0 8P 169F Sol(32 F) 0 001% FI P NA IP 12 52 ev VP >1 atm FRZ 315 F UEL NA LEL NA Incompatibilities and reactivities Measurement method iSee Table 1' Hydrnchlonc acid easily oxidized organic ma'erials [Note Begins to Sublime below BP Contact with other matenals may cause fire 1 None available Strong oxidizers xilve -ompounos strong aikai s chlorites [Note Gives oft water of crystallization at 215 F and begins to sublime ] None available Combustible None matenals chlorine available bromine iodine platinum metal oxides moist air hydrogen sulfide hydrocarbons water (Note Reacts very slowly with water to form hydrofluoric acid J All oxidizable materials (both organic & inorganic/ Filters (2)/ Oxidizer Water 1C OSHA [8ID21 4) RGasD 1 66 Nonflammable Gas but a powerful oxidizer Personal protection and sanitation (See Table 3) Skin Eyes Wash skin Remove Change rovide Prevent skin contact Prevent eye contact When contam When wet or contam Daily Eyewash (Osmium tetroxide] Skin Eyes Wash skm Remove Change Provide Prevent skm contact Prevent eye contact When contam When wet or contam Daily Eyewash [Oxalic acid) Skin Eyes Wash skm Remove Change NR NR NR NR NR [Oxygen difluondej Skin Eyes Washskm Remove Change NR MR NR NR MR (Ozone] ABD00022963 Recommendations forresprrator selection--maximum concentration for use (MUC) (See Table 4} NJOSH/OSHA 0 1 mg/m1 CCRFSHlE/GMFSHiE/ SCBAF/SAF 1 mg/m1 SAF PD PP SC8AF PD PP/SAF PD PP ASCBA Escape GMFSHiE/SCBAE Health hazards ------ -- ---------------------------------------------------------------------------------------------------------------------------------------- Route Symptoms Flrstald Target organ* (See Table 5) (See Table 6} (See Table 5) Inh Irnteyes resp sys lac Ing vis dist conj, head. Con cough dysp derm Eyr Sun Breath Swallow Irrlmmed Soap wash immed Resp support Medical Mention immed Eyes, akin reap ays NIOSH/OSHA 25 mg/m3 SA CF/PAPRDM 50 mg/m' HiEF/SCBAF/SAF 500 mg/m3 SAF PD PP SCBAF PD PP/SAF PD PP ASCBA Escape HiEF/SCBAE Inh lng Con Irnteyes skin mucmemb eye burns local pain cyan shock collapse convuls kidney damage Eye Skin Breath Swallow Irr immed Water flush prompt Resp support Medical attention immed Eyes skm i Kidneys 239 NIOSH/OSHA 0 5 ppm SA/SC8AF SCBAF PD PP/SAF PD PP ASCBA Escape GMFS4SC0AE Inh Con Irrft eyes, skin, resp ay*; head pulm edema, eye, skin bum* (from contact with the gas under pressure) !C Breath brimmed Eyas, skin, reap ays Water flush Immed Reap support NIOSH/OSHA , ppm CCRS`/SA 2 5 ppm SACF/PAPRS1- 5 ppm CCRFS`/GMFS`/SAT CFi SCBAF/SAF 5 SCBAF PD PP/SAF PD PP ASCBA Escape GMFS^/SCBAE inn Con Irnteyes mucmemb pulm edema chronic resp disease Eye Breath Medical attention Fresh air 100%0: Eyes resp sys 240 Chemical name atructure/formula CAS and RTECS Noe, and DOT ID and guide Not Synonyms, trade names, factors Paraffin wax fame Paraffinfume, Paraffin ecalefanK 8002-74-2 RV0360000 Exposure nets (TWA unless noted otherwise) NOSH 2 mg/m* QSHAt non* Paraquat (Paraquat dichloride) CH3(C5H4N)2CH3 2Ci 1910-42 5 DW2275000 Pamthton <WP)f{S')OCWQi 56-28-2 TF4SSQQQO 1 1 DimethyM 4 NIOSH bipyndmium dichloride 0 1 mg/m3 (resp) N N -Dimethyl 4 4 [skin] Cipyrdinium dichlonde OSHAT Paraquat chlonde 0 5 mg/m3 (resp) Paraquat dichloride [skin] (Note Paraquat is a cation (C0H14Nj" 1 t-dimethyl-44 bipyndmium tonj the commercial product is the dichloride sail of paraquat ] 0,O-0iethyi-Q(p-nitraphenyl) phottfwoWoate, OWhyff*ratw. Ett^'parathlori, ParaatorH*ttvt NIOSH 005 mo/rrr tsKinj OSHA 0 troaTn* [skin] 2783 162 Particulates not otherwise regulated Inert dusts Nuisancedusts PNOR [Note includes all inert or nuisance dusts whethermineral inorganic or organic not listed specifically in 1910 1000 ] NIOSH See Appendix D OSHA 15 mg/m3 (total) 5 mg/m3 (resp) ABD00022964 IDLH Physical description ND Paraffin wax la a white to slightly yellowish odorless solid [Note Consists of mixture of high molecular weight hydrocarbons (M. C^J Chemical and physical properties MW, BP SOL FI P IP Sp Gr, flammability VP FRZ UEL, LEL MW- 350-420 BP 7 Sol Insoluble FI P 390*F IP 7 VP 7 MLT 115-154*F UEL? LEL ? SpGr 0 88-0 92 Combustible SoM Incompatibilities and None reported Measurement method (See Table 1) None avalabte 1 mg/m3 Yellow solid with a faint ammonia like odor Iherbicide] MW 257 2 BP Decomposes Sol Miscible FI P NA IP ? VP <0 0000001 mm MLT 572 F (Decomposes) UEL NA LEL NA Strong oxidizers alkylaryl-sulfonate wetting agents (Note Corrosive to metals Decomposes in presence of ultraviolet light ] Filter Water HPLC/UVD IV [#5003] Sp Gr 1 24 Noncombustible Solid lOmg/m* Pale-yellow to dark-brown liquid with a garttoItke odor [Note A solid below 43*F Pesticide that may be absorbed on a dry carrier] MW 261 3 BP 707*F $010 001% FI P(oc) 392'F IP 7 VP 0 00004 mm FRZ 43'F UEL 7 LEL 7 Sp Gr 1 27 Class IIIB Combustible Liquid Strong oxidizers, alkaline materials OVS-2 Toluene/ Acetone GC/FPD IV ]#5600 Organophoephorus Pesticides] ND Dusts from solid Properties vary depending substances without upon the specific solid specific occupational exposure standards Vanes Filler none Grav IV [Particulates NOR #0500 (total) #0600 (resp)i Personal protection (See Table 3) Skin Eyes Wash skin Remove Charge NR Prevent eye contact NR NR NR [Paraffin wax fume) Skin Eyes Wash skin Remove Change PioviOe Prevent Skin contact Prevent eye contact When contam When wet or contam NR Quick O'ench [Paraquat] Skin vieshaWn Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet or contam Daffy Eyewash Quickdrench [Parathlon] Skin Eyes Wash skin Remove Change NR NR NR NR [Particulates not otherwise regulated] ABD00022965 Recommendations for respirator concentration for use (MUC) (See Table 4) Route Symptoms (See Table S) TBAl Inh Irrtt eyee ekm rasp ays, Con discomfort, nsu Health hazards Firetald (See Table 6) Eye Breath IrrlnvMd Reap aupport Target organs (See Table 6) Eyes, aWn, map sya NIOSH 1 mg/m3 CCROVDMFu'/PAPROVDMFu , SA /SCBAF SCBAF PO PP/SAF PD PP ASCBA Escape GMFOVHiE/SCBAE Inh Abs Ing Con irrrt eyes skin nose throat resp sys epis derm fingernail damage irrit Gl tract heart liver kidney damage Eye Skin Breath Swallow irr immed Water flush immed Resp support Medical attention jmmed Eyes skin resp sys heart liver kidneys Gl tract 241 NIOSH 0 S mg/m5- CCROVDMFu/SA 1 25 malm1 SA-CF/PAPROVOMFu 2 5 mam1 CCRFOVHiE/SAT CF/ PAPRTOVHtEJSCBAF/SAF tOmg/m1 SA.PD,PP 8 SCBAF`PD,PP/SAF,PD,PPASCBA Escape GMFOVHIE/SCBAE TBAL Inh Irrtt eyes akin, reap ays, Abs mioaia, rhin, head, chest Ing Con salv, cyan anor,nau > vomit, Axiom cramps, diere sweat, muaefaac, week para, gkW^conf, ataxia eonvu,.OQfT), lowBP; card iireg & Swallow- Irrtrained Soapwfeh Immed SUSS*. ' ,, e' i' ` i 1p ; 1 Inh Irrit eyes skin throat Con upper resp sys Eye Breath Irr immed Fresh air Eyes skin resp sys Chemical name structure/formula CAS andRTECSNos and DOT ID and guide Nos Synonyms trade names factor* Pentaborane Pentaboron nonahydrtda 19624*22-7 RY8925000 1380 138 Pentachloroethane CHCljCCi, 7$ Cl 7 KI6300000 1 ppm 2 56 mg/m5 Ethane pentachionde Pentalm 1669 151 Pentacftioronaphthalene <Ws 1321*844 QK0300000 Hatowe>f1013, 1.2,3,4,5-Psntachloro* napMitiana Exposure knits (TWA unless noted otherwise) ABD00022966 IOLH Physical description NIOSH 0005 ppm (001 mi*n*) ST 0 015 ppm (0 03 mgmi*) OSHAt 0005 ppm (0 01 mg/m1) Ippm Colorless liquid with e pungent odor like sour mdk NiOSH Handle with caution m the workplace See Appendix C (Chioroethanesi QSHA none N0 Coioriess 'iquid with a sweetish chloroform like cdoi NI08H/OSHA 0.5 mg/m* [tklnl Unknown Pile yeflow or white solid or powder wSh an aromatic odor Chemical and physical properties MW BP, SOL FI P, IP, Sp, Gr flammability VP FRZ UEL LEL Incompatibilities and reactivities Measurement method (See Table 1) MW 63 1 BP 140*F Sol Reacts FI P 86*F IP 9 90 eV VP 171 mm FRZ.-52*F UEL 7 LEL042% Sp Or 0 62 Class 1C Flammable Liquid Ondlzert halogens, None water, halogeneted available hydrocarbons [Note May ignite SPONTANEOUSLY in moist air Corrosive1 to natural rubber Hydrolyzes slowly with heat in water to form bone eod] MV1. 202 3 BP 322 F Sol 0 053c FI P 7 IP 11 28 eV VP 3 mm MLT 20 F UFL ' LEI 7 Sp Gr 1 68 Combustible uqijid Soaum potassium Porapak ailoy * Dromotormj Hexane alkalis metals water GC'ECD (Note Hydrolysis produces dichloro acetic acid Reaction with alxalis & metals IV [#2517] produces spontaneously ekplosive chloroacetylenes ] MW 3004 BP- 636*F Sol Insoluble FIP NA IP 7 VP`<1mm MLT 248*F UEL NA LEL NA Strong oxidizers Filter/Bub Isooctane GC/ECD 9IU Pentaeniorophenoi c8ci5om 87 86 5 SM6300000 PCP Penta 2 3 4 5 6 Pentaeniorophenoi NIOSH/OSHA 0 5 mg/mJ [skin] 2 5 mg/m1 Colorless to white crystalline solid with a benzene like odor [lungicide) Sp Gr 1 67 Noncombustible Solid MW 266 4 BP 588 F (Decomposes) Sol 0 001% FI P NA IP NA VP(77 F, 0 0001 mm MLT 374F UEL NA LEL NA Strong oxidizers acids alkalis Filter/Bub Methanol HPLCAJVD IV (#5512] 2020 154 Sp Gr 1 98 Noncombusttble Solid Personal protection and sanitation (See Table 3) Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet (flamm) NR Eyewash Quick drench [Pentaborane] Skin Eyes Wasn skin Remove Change Provide P t* n sun contact Rrerei' eye comae! rVner contam When wet or contam NR Eyewash Quick drench |Pentachloroethane] Skin ViShskin Remove Change Prevent akin contact Prevent eye contact When contam When wet or contam Daily [Pentechloronaphtheiene] Skin Eyes Wash skrn Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet or contam Daily Eyewasn Quick drench [Pentach loro phenol] ABnnnn?.?.967 Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table 4) Route Symptoms (See Table 5) NIOSH/OSHA 0 05 ppm SA Q 125 ppm S Cf- 0 25 ppm SAT CF/SCBAF/SAF t ppm SA PD PP SCBAF PD PP/SAF PD PP ASCBA Escape GMFS/SCBAE Inn Abs mg Con Imteyes skin diZ2 head drew li head mco t emor convuls behavioral changes tonic spasm face neck abdom limbs Health hazards First aid iSee Table S) Eye Skin Breath Swallow Irr immed Soap wash immed Rasp support Medical attention mmed Target organs (See Table 5) Eyes skin CNS TBAl inn ng Lon in animai5 irrit eyes skin weak restless irreg respiration muse mco ver kidney lung changes Eye Skin Breath Swallow Irr mmea Soap wash Resp support Medical attention immed Eyes skin resp Sys CNS nver kidneys NIOSH/OSHA 5 mg/mv SA'/SCBAF SCBAF PO PP/SAF PD PP ASCBA Escape GMFOVHiE/SCBAE Hi Aba Ing Con Head ftg, vert anor pnjntua acne-form skin eruptions jaurt tavernec US Breath Swallow Irr Immed Skirt liver CNS Soap prompt/molten Hush immed Rasp support Medical Attention mmed NIOSH/OSHA Inn 2 5 mg/mJ CCROVDMFu'/PAPROVDMFu / Abs SA /SCBAF mg SCBAF PD PP/SAF PD PP ASCBA Con Escape GMFOVHiE/SCBAE irnt eyes nose throat sneez cough weak anor low wgt sweat head dizz nau vomit dysp chest pain high 'ever derm Eye Skin Breath Swallow irr immed Soap wash immed Resp support Medical attention immed Eyes skin respsys CVS liver kidneys CNS Chemical name structure/formula CAS and RTECSNos and DOT ID and guide Noe Synonyms, trade names and conversion factors Exposure krtts (TWA unless noted othenwise) Pentaerythntol C(CHjOH), 11&-77-6 RZ2490000 244 CHJCHJ.CH, 109 66 0 RZ9450000 1265 128 1-Pentsnathio! CH^CHj)4SH 11M6-7 SA31SOOOO 2 2-b(Hydroxymethyl)1 3-propanediol, Methane tetramethytol, Monopentaerythrttol PE, Tetrahydroxymethytmethane, Tetramethytolmethane normai-Pentane 1 ppm = 2 95 mg/m3 Amyl bydrosutfide Amyl mercaptan, Amyl sutfhydrate Pentyl mercaptan NIOSH 10 mg/m3 (total) 5mgfm3 15 mg/m3 (total) 5 mg/m3 (reap) NIOSH 120 ppm (350 mg/m3) C 610 ppm (1800 mg/m3) (15-min] OSHAf 1000 ppm (2950 mg/m3) NOSH C 0 5 ppm (2 1 m#ms) (15-minJ OSHA none 1111130 2 Pentanone CH^COCHjCHjCh 107-87 9 SA787500C 1 ppm * 4 26 mg/m3 Ethyl acetone Methyl propyl Ketone MPK NIOSH 150 ppm {530 mg/m3t OSHAT 200 ppm (700 mg/m3) 124S '27 1 ppm = 3 52 mg/m3 ABD00022968 IDLH Physical description Chemical and physical properties MW BP SOL FI P IP, Sp Gr flammability VP FRZ UEL, LEL ND Colorless to white MW 136 2 VP 0mm crystalline BP Sublimes (approx) odorless powder Sol(59*F) 6% MLT 500'F (Note Technical FI P 7 (Sublimes) grade Is 88% IP 7 UEL ? monopentaerythrt- LEL ? tol & 12%dipetv taerythritol ] SpGr 1 38 Combustible Solid 1500 ppm [10%LEL] Colorless liquid with 3 gasoline like odor (Note A gas above 97 F May be utilized as a fuel ] MW 72 2 BP 97 F Sol 0 04% FI P 5/ F IP 10 34 eV VP 420 mm FRZ 202 F UEi 7 8% LEL 15% Sp Gr 0 63 Class iA Flammable 1 iquid ND Watar-wbRe to MW 1042 VP(7TF) yellowish liquid BP 260*F 14mm with a strong, Sol Insoluble FRZ.-104'F gailic-iilce odor FI P(oc) 85*F UEL 7 IP 7 LEL 7 1500 ppm Colorless lo water white Iiqiiki with a characteristic acetone like odor SpGr 0 84 Class IB Flammable Liquid MW 86 i BP 2'5 F Sol 6% FI P 45F IP 9 39 eV VP 27 mm FRZ 108 F UEL 6 2% LEL 15% Sp Gr 0 81 Class 18 Flammable Liquid Incompatibilities ano reactivities Measurement method (See Table 1) Organic acids, oxidizers (Note Explosive compound ts formed when a mixture of PE & Baophosphoryl chloride is heated) Filter none Grav IV [Particulates NOR #0500 ioeols (resp)) Stiong oxidizers Char carbonsl Oxidizers, reducing agents alkali mews, calcium hypochlorite, concentrated nitric acid Nona avertable Oxidizers oromine tnfluonde Char CS, GCfclD IV |*M300 Ketones I] Personal protection ar>d sanitation (See Table 3) Stan Eyee Weehstan Remove Change NR NR NR NR NR [Pentaerythrrtoi] iskm Eyes Wash SKm Remove Cfarvge Prevent skin contact Prevent eye contact When contarr When wet flammj NR (n Pentane Son. WeshsJun Remove Change Prevent akin contact Prevent eye contact When contern When wet (Hamm) NR [1-PentaneOxol) Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contarr When wet iflamnn NR (2 Pentanone] ABD00022969 Recommendations for respirator selection -- maximum concentrationfor use (MUC) (See Table 4) Route Symptoms (See Table 5) TBAL Wi Imteyes reap ays Ihfl Con Health hatards First aid (See Table 6) !& Breath Swallow Irr immed Water wash Fresh atr Medical attention rrvned Target organs (See Tables) Eyes, reap ays NlOSl-i 1200 ppn SA 1500 ppm SA CF/SCBAF'bAF SCBAF PC PP/SAF PO PP ASCBA t scape GMFOv.SCBAt mr mg Con irnteyes skin nose derm chemical pneu laspir liqj drow m arvmals narco Eye Skin Breath Swailow irr rmmed Water wash prompt Resp support Medical attent or rmmed Eyes skin resp sys -"NS NOSH Ml Irrtteyes akin nose 5 ppm CCRFOV/SA 12 S ppm SA CF7PAPROV ]y throat respsys heed Con nau dtzz, vomit, dlarr 26 ppm CCRFOV/GMFOV/PAPRTOV/ derm akin sens SCBAF/SAF SCBAF PD PP/SAF PO PP ASCBA Escape OMFOV/SCBAE is, Breath Swallow trrimmed Soap wash immed Raap steport Ma^caiAttention Ironed Eyes, skin resp ays CNS NIOSM iSOOppm CCROV/PAPROV 'GMFOV/ SA /SCBAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE inn mg Con Irnteyes Skin mucmemp nead derm narco coma Ey Skin Breath Swallow Irrirrtmed Water flush Resp support Medical attention immed Eyes skin respsys CNS Chemical name structure/fonnula CAS and RTECS Nos and OOT 10 and guide Nos Synonyms trade names and conversion factors Exposure limits (TWA unless noted otherwise) Perchloromethyi mercaptan CljCSCl 594 42 3 P90370000 PCM P MM Tricholoromelhane sulfenyl chloride Tnchloromethyl sulfur chloride NIOSH/OSHA 0 1 ppm (0 8 mg/m3) 246 1670 157 Percniorvi *iuo ioe CO F T6'6 S4 6 SD S25~3t JC33 24 Perlite 93763-70-3 S05254000 Petroleum d st nates inaphtha' 1255 128 1 ppm = 7 60 mg/m3 vhionne fijor je oxide Cnior ne jxytluo ide 'rnexychlorofluo ide 1 com = 4 19 rng'm Expanded perlite [Note An amorphous material consisting of fused sodium potassium aluminum silicate ] Aliphatic petroleum naphtha Petroleum naphtha Rubber solvent 1 ppm = 4 05 mg/m3(approx) NiOSH J ppm 4 vg'rr ST 6 pprr 28 -g m OSHAt 3 ppm 113 5 mg mJ NIOSH lOmgrtn5 (total) ssei5 mg/m5 ISmafm5 (total) 5mg/m3 (reap) NIOSH 350 mg m3 C 180C mg/m3 [15-mm] OSHAt 500 ppm (2000 mg/m3) ABD00022970 IDLH Physical di >< ription 10 ppm Pale yellow oily liquid with an unpearaoie acno odo. ' 30 Ppm o'crless gjs a ir j _ra sfic sweet ,,ao Note Smpoed as i qoe'ieO compiessec gds Chemical and physical - properties MW BP SOL FI P IP Sp Gr flammaOllfty VP FRZ UEL l EL nu ompatibilitus nid reartrvities MW 165 9 BP 297*F (Decomposes! Sol cnsoluBle FI P NA IP 7 VP 3 mrr FRZ 7 UcL NA LEL NA Alkalis am nes not iron water [Note Corrosive 'o most metals Forms HC Sulfur & COj or contact with water J Sp Gr 1 69 Noncombustible Liquid but will support combustion Measurement method (See Table 1) None available MA 32 5 BP *, F Sol 0 35` Fl P NA ip U60ev /P i. ha PR/ /j4 p UbL NA .Ll N* cmuistibies st<.ng cuses amines `meiy dwioed ^etais educing agents dicoho v None avaiiaoie ND 1100 ppm [10%LELJ RGasD 3 64 Nonflammable Gas Put Will SuppOfl COniDusUcn a"jS"y-Odorless light- [Note Expanded perlite Is e fluffy white particulate ] MW vanes 8P ? Sot<1% FIP NA IP NA VP 0 mm (approx) MLT >2000*F UEL NA LEL NA None reported Sp Gr 2 2-2 4 (crude) 0 05-0 3 (expanded) Noncombusbble Solid Colorless liquid with a gasoline or kerosene like odor (Note A mixture of paraffins (C, to Ca) that may contain a small amount of aromatic hydrocarbons ) MW 99 (approx, BP 86-460 F Sol Insoluble FI P -40 to 86 F IP 7 Sp Gr 0 63 0 66 Flammable Liquid VP 40 mm FRZ 99 F UEL 5 9% LEL 1 1% Strong oxidizers Filter none Grav IV (Particulates NOR *0500 (total) #0600 (rasp)) Char CS, GC^FID IV [#1550 Naphthas) Personal protection (See Table 3) Skm Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact Whencontam Wien wet or contam NR [Perchloromethy! mercaptan] Skin Eyes Wash skin Remove Change Provide Frostbite Frostbite NR NR NR Frostbite zzzzz [Perchloryl fluoride) Skin Eyes Wash skin Remove Change [Perlite] Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam When wet (flamm) NR [Petroleum distillates (naphtha)] ABD00022971 Recommendations for respirator concentration for use (MUC) (See Table 4) Route Symptoms (See Table 5) NIOSH/OSHA 1 ppm CCROV/SA* 2 S ppm SA CF'/PAPROV* 5 ppm CCRFOV/GMFOV/PAPRTOV*/ SAT CFVSCBAF/SAF 10 ppm SAFPD PP SCBAF PD PP/SAF PD.PP ASCBA Escape GMFOV/SCBAE Mr Abs Ing Con Irrit ayes, skin nose, throat lac cough dyap, deep breath pain coarse rales, vomit, pallor tacar acidosis anuria liver kidney damage NIOSH/OSHA 30 ppm SA 75 ppm SA CF" 100 ppm SC8AF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFS'-ZSCBAE Inh Con (liq) Imt resp sys liq frostbite in animals methemo cyan weak dizz head pulm edema pneuitis anoxia Health hazards First aid (See Table 6) Eye Skin Breath Swallow Irrimmed Soap wash immed Resp support Medical attention immed Target organs (See Table 6) Eyes, stun, resp sys, liver kidneys Eye Skin Breath Frostbite Frostbite Resp support Skin resp sys blood TBAL Inh irrit eyes skin, throat Con upper resp ays Eye Breath irrimmed Fresh ak Eyes, akin, resp sys NIOSH 850 ppm SA 1100 ppm SA CF/SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Inh Irnteyes nose throat Ing dizz drew head nau Con dry cracked skin chemical pneu (aspir liq) Eye Skjn Breath Swallow Irrimmed Soap wash prompt Resp support Medical Attention immed Eyes skin resp sys CNS Chemical name structure/tormula CAS andRTECSNos and DOT ID and guide Nos Synonyms trade names, and conversion factors Phenol 10S-95-2 833325000 1671 153(oM) 2312 163 (moen) 2621 153 (solution) Phenothiazine S(CsH4)3NH 92 84 2 SN5075000 Carbolic acid Hydroxybenzeoa, Monohydroxybenzene, Phenyl alcohol Phanyl hydroxide 1 ppm 3.65 mgfln* Dibenzothiazme Fenothiazine Thiodiphenytemme p-Phenylenediamm CH(NH2)} 106-50-3 SS6060000 1673 153 Phenyl ether (vapor) C9HjOCeH. 101-84 8 KN8970000 4-AmmoanBine, 14-Benanediamlne p-Diaminobanzene 1 a-Ommlnabenasna 1,4-Phenyfenediamine Diphenyl ether Diphenyl oxide Phenory benzene Phenyl oxide 1 ppm = 6 96 mg/mJ Exposure limits (TWA unless noted otherwise) NIOSH 5 ppm (10 mg/ms) C 15 6ppm (60 mg/m9) [1 (skinl NIOSH 5 mg/mJ [skin' OSHAt none ABD00022972 IDLH Physical description Chemical and physical properties MW BP, SOL FI P IP, Sp, Gr, flammability VP FRZ DEL LEL 250 ppm Colorless to light-pink crystalline solid with a sweat, acrid odor [Note Phenol liquefies by mixing wtth about 8% water) MW 94 1 BP 359'F SoH77`F)- 9% FIP 175'F IP 0 50 eV VP 0 4 mm MLT 109*F UEL 86% LEL 1 8% Sp Gr 1 06 Combustible Solid ND Grayish green to MW 99 J VP 0 mm green sn yellow BP 700 F (approx, sold Soi Insoluble MLT 365 F [insecticide] H P > UEL 7 IP 7 LEL 7 Incompatibilities and Measurement method Strong oxidizers calcium hypochlorite aluminum chloride acids XAD-7 Methanol GC/FID IV [2546 Cresols and Phenol] None reporteo None available NIOSHOSHA 01 mg/m9 (skin] 25 mg/m9 White to slightly red, crystalline solid Sp Gr 7 Combustible Sold but not a high fire risk MW 108 2 BP 513*F So75*F) 4% Rp312*F IP 6 09 eV VP`<1mm MLT 295*F UEL 7 LEL 7 Strong oxidizers Filter* EDTA HPLCAJVD OSHA [8 7) NIOSH/OSHA 1 ppm (7 mg/m3) 100 ppm Colorless crystalline solid or liquid (above 82 F) with a geranium like odor Sp Gr 7 Combustible SoUd MW 170 2 BP 496`F Sol insoluble Fl P 239*F IP 8 09 eV VP(77 Fj 0 02 mm MLT 82 F UEL 6 0% LEL 0 7% Sp Gr 1 08 Combustible Sold Class 11IB Combustible Liquid Strong oxidizers Char GC/FID IV [#1617] Personal protection (See Table 3) Skin Eyes Wash skin Remove Change Provide Prevent skirt contact Prevent eye contact Whencontam When wet or contam Daily Eyewash Quick drench (Phenol] Skm Eyes Wash skin Remove Cnange Prevent sum contact NR W'he- oontam/Daily Wien wet o contam Daily [Phenothiazine] Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam/Daily When wet or contam Daily lp-Phenytene diamine] Skm Eyes Wash skin Remove Change Prevent skm contac1 Preven eye contact Whencontam When wet or contam NR [Phenyl ether (vapor)] ABD00022973 Recommendations for respirator concentration for use (MUC) (See Table 4) Route Symptoms (See Table 5) NIOSH/OSHA 50 ppm CCROVDM/SA 125 ppm SA CF/PAPROVDM 250 ppm CCRFOVHIE/GMFOVHiE/ PAPRTOVHiE/SCBAF/SAF SCBAF PD PP/SAF PO PP ASCBA Escape GMFOVHiE/SCBAE Inh Imteyes nose throat Abs anor low-wgt weak Ing muscache pain dark Con unne cyan liver kidney damage skin burns derm ochronosis tremor convuls twitch Health hazards Firstaid (See Table 6) Breath Swallow Irr immed Soap wash Immed Resp support Medical attention immed Target organs (See Table 5) Eyes skin, resp sys liver kidneys TBAL inn Abs mg Con itching irrit reddening skin hepatitis hemolylic anemia aodom cramps lacar kidney damage skin photo sens Eye Skin Breath Swallow irr immed Soap wash prompt Resp support Medical attention immed Skin CVS liver kidneys 249 NIOSH/OSHA 2 5 mg/m* SA CFE 5 mg/m* SCBAF/SAF 25 mg/m3 SAF PD PP SCBAF PD PP/SAF PO PP ASCBA Escape GMFSHiE/SCBAE Inh AOs Ing Con Irrit pharynx larynx bronchial asthma sens derm iKfn Breath Swallow Irr immed Soap wash prompt Resp support Medical attention immed Resp sys skin NIOSH/OSHA 25 ppm SA CF/PAPROVDM 50 ppm CCRFOVHiE/GMFOVHiE/ SCBAF/SAF 100 ppm SAF PD PP SCBAF PD PP/SAF PD PP ASCBA Escape GMFOVHiE/SCBAE Inn irrit eyes nose skm nau Con Eye Skin Breath Irr immed Soap wash prompt Resp support Chemical name structure/formula, CAS and RTECSNos and DOT ID and guide Nos Phenyl ether-biphenyl mixture (vapor) cih*oc9h/c4hscbhb 8004*13-5 DV1500000 Phenyl gtycidyi ether CHmj 122-60 1 TZ3675000 Phsnytiydiazine CjHjNHNHj 100-09-0 MW8925000 2072 153 N Phenyl 6-naphthylamrne 135-88 6 QM4550000 Synonyms trade names and conversion factors Exposure limrts (TWA unless noted otherwise) ABD00022974 IDLH Physical description Chemical and physical properties MW, BP SOL FI P IP, Sp Gr, flammability VP FRZ UEL LEL Diphenyl oxide-diphenyl mixture, Dowthwm A NIOSH/OSHA 1 ppm (7 mg/m3) 1 ppm 9 79 mg/m5 (approx) 10 ppm Colorless to straw colored liquid or solid (below 54'F) with a disagreeable aromatic odor [Note A mixture typically contains 75% phenyl ether & 25% biphenyl) MW 166 (approx) VP(77"F) BP 495 F 0 06 mm Sol Insoluble FRZ 54 F FI P 239F UEL 7 IP ? LEL ? Sp Gr(77*F) 1 06 Class DIB Combustible Liquid 1 2 Epoxy 3 phenoxy propane GJycidyl phenyl ether Phenyl 2 3-epoxypropyl ether NIOSH Ca See Appendix A C 1 ppm (6 mg/m3) [15-mm] Ca [100 ppm] Coioness liquid [Note A solid below 38 F ] MW 150 . BP 473'F Sol 0 2% Fl P 248"F IP 7 VP 0 01 mm FRZ 38'F UEL ' LEL ' 1 ppm = 6 14 mg/m3 OSHAT 10 ppm (60 mg/m3) SpGrl 11 Class IMB Combustible Liquid Hydrazinobenzene Monopherrythydrazine 1 ppm 4 42 mgfm5 NIOSH Ca See Appendix A C 0 14 ppm [skin] (0 6 mgfci5) [2-hr] Ca [15 ppm) OSKAt 5 ppm (22 mo/m5) [skin] Colorless to paleyellow liquid or solid (below 67*F) with a faint, aromatic odor MW 108 1 BP 470*F (Decomposes) Sol Slight FI P 190*F IP 7 64 aV VP(77*F) 6 04 mm FRZ 67-F UEL ? LEL ? SpGrl 10 Class MIA Combustible Liquid Combustible Solid 2 Anilmonaphthalene IJ-Naphthytphenytamine PSNA 2-Phenylammonaphthalene Phenyt-B-naphthylamine NIOSH Ca Ca- [ND] See Appendix A ['Note Since metabolized to IJ-Naphlhylamme 1 OSHA none White to yellow crystals or gray to tan flakes or powder [Note Commercial product may con tain 20 30 ppm of (1 Naphthytamme ] MW 219 3 BP 743*F Sol Insoluble FIP ? IP ? VP 7 MLT 226 F UEL 7 LEL ' Sp Gr 1 24 Combustible Solid Incompatibilities and reactivities Measurement method (See Table 1) Strong oxidizers Si gel Benzene GC/FID IV [#2013] Strong oxidizers amines strong acids strong oases Char GC/FID IV [#1619] Strong oxidizers lead dioxide Bub Pho-acid Vis, IV [#3516] Oxidizers Filter HPLC/FLD OSHA [96] Personal protection and sanitation (See Table 3) Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact Whencontam When wet or contam NR (Phenyl ether-Oiphenyi mixture (vapor)] Skin Eyes Wash skm Remove Change Provide Prevent skin contact Prevent eye contact Whencontam When wet or contam NR Eyewash Qutckdrench [Phenyl glycidyl ether] Skin Eyes Wash skm Remove Change Provide Prevent skin contact Prevent eye contact When contam/Oalty When wet or contam Daily Eyewash Qutckdrench [Phenylhydrazinej Skin Eyes Wash skin Remove Change Provide Prevent skm contact Prevent eye contact When contam/Daily When wet or contam Oaily Eyewash Quick drench [N Phenyl EJ-naphthylamine] ABD00022975 Recommendations for respirator selection --maximum concentration for use (MUC) (See Table 4) NIOSH/OSHA lOppm SA CF4CCRFOVHIE/ GMFOVHiE/PAPROVDMc/ SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOVHiE/SCBAE Route Symptoms (See Table 5} Inh Irnt eyes nose skin nau Con Health hazards First aid (See Table 6) Target organs (See Table 5) IS. Breath Irnmmed Soap wash prompt Resp support Eyes skin, resp sys NIOSH < SCBAF PD PP'SAF PD PP ASCBA Escape GMFOV/SCBAE inn APS ing Con rrit eyes Skin upper resp sys skin sens narco possible hemato repro effects ]carc] Eye Skm Breath Swallow Irr immed Soap wash prompt Resp support Medical attention immed Eyes skin CNS hemato sys repro sys [mammals nasal cancer] 251 NIOSH * SCBAF PD PP/SAF PD PP ASCBA Escape SCSAE Inh Skin sens, hemolytic AOs anemia dysp cyan jaun Ing kidney damage vascular Con thrombosis [care] NIOSH V SCBAF PD PP/SAF PD PP ASCBA Escape GMFOVHiE/SCBAE Inh ADs Ing Con Irritation leucoplakia acne hypersensitivity to sunlight [care] ! Breath Swallow Irr immed Soap wash immed Resp support Medical attention mmed Blood resp sys, liver kidneys skin [Inanimals honors of the kings, fiver blood vesaaia & intestine] Eye Skin Breath Swallow Irr immed Soap wash immed Resp support Medical attention immed Eyes skm bladder (bladder cancer) Chemical name, structure/formula CAS and RTECSNos, and DOT ID and guide Noe Synonyms, trade names, factors Exposure (TWA unless notsd otherwise) 252 Phenylphosphtne Fenytfosfin, PF, Phosphanine NIOSH C 009 ppm (025 wg#n*J HSfOOOOO < r M Phorate (C,H,0),P(S)SCH,SC,Hs 298 02 2 TD9450000 3018 152(organophosphorus pesticide liquid) , w 1ppm*4 50mgfm3 0 O-Diethyl S (ethylthio) methylphosphorodithioate 0 O Diethyl S-ethylthiomethytthiothionophosphate Thimet Timet OSHAt nous 1 <v , NIOSH 0 05 mg/m3 ST 0 2 mg/m3 [skin] OSHAT none Phosdrtn C,H,,POs 77W-34-7 005290000 2783 162 Z-Carbomethoxy-I -methylvinyl dimethyl phosphate, Mevinphoa (Note Commensal preduet it a mixture ofthe cts-& trane Isomers 1 NIOSH 0 01 ppm (01 mo/m*) ST 0 03 ppm (0 3 mafrns) {skin} 1pprn*817mgftn* OSHAf 01 mafm* (eklnf Phosgene COCi 75-44 5 SYS600000 1076 125 Cart>on oxychloride Carbony chloride Carbonyl dichlonde Chloroformyl chlonde 1 ppm = 4 05 mg/m3 NIOSH 0 1 ppm (0 4 mo/m3) C 0 2 ppm (0 8 md/m1) (15-minJ OSHA 0 1 ppm (0 4 mg/m3) ABD00022976 IDCH ND * ND Physical description Clear, colorless liquid with a foul odor Clear liquid with a skunk-like odor [insecticide] Chemical and physical properties MW, BP SOL FI P.IP.Sp, Gr, flammability VP, FRZ UEL, LEL MVtMIO 1 BP 320*F Sol Insoluble FIP ? IP-7 VP" ? FRZ ? UEL ? LEL 7 Sp,Grf69,FV 1.001 Combustible Liquid Incompatibilities and Measurement method (See Table 1) None reported None (Note Spontaneously available combustible m high concentrations In air Potential exposure to gaseous phanylphosphlne when pototoephinsM are heated above 362*F ] MW 260 4 BP 7 Sol 0 005% FIP(oc) 320F IP ' VP 0 0008 mm FRZ 45F UEL 7 LEL 7 Water alkalis (Note Hydrolyzed in the presence of moisture and by alkalis ] SpGr[77 F) 1 16 Class 1118 Combustible Liquid but does not readily ignite OVS 2 Toluene/ Acetone GC/FPO IV [#5600 Organo phosphorus Pesticides] 4 ppm Pale-yeilow to orange liquid with e weak odor (Note Insecticide that may be absorbed on a dry carrier] MW1 224 2 VP 0 003 BP Decomposes mm Sot- Mwdbfe FRZ 44*F FI P(oc)- 347'F IP 7 $T' (oia-) UEL.? LEL 7 Sp Or 1.25 Clan 1118 Combustible Liquid Strong oiddixars [Note. Corrosive to cast iron, some stainlees steels & braes) OVS-2. Toluene/ Acetone GC/FPD IV {#5600, Organophosphorus Pettitides) 2 ppm Colorless gas with a suffocating odor like musty hay [Note A fuming liquid below 47 F Shipped as a liquefied compressed gas J MW 98 9 BP 47*F Sol Slight Fl P NA IP n 55 ev VP 1 6 atm FRZ 198F UEL NA LEL NA RGasD 3 48 Sp Gr 1 43 (Liquid at 32*F) Nonflammable Gas Moisture alkalis ammonia alcohols copper [Note Reacts slowly in water to form hydrochloric acid & carbon dioxide ] XAD 2 Toluene GC/NPD OSHA |#61] Personal protection and sanitation (See Table 3) Stti Eye* Wash stun Remove Change Preventskin contact Prevent eye contact Daily When wet or contam NR [Phenylphoaphine] Sxin Eyes Wash sKir Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet or contam NR Eyewash Quick drench [Phorate) SMn ttChakbL Remove. sx Prevent akin contact Preventeye contact Wven contam VWien wet or content M.R Eyewash, Quickdrench [Pttoe***) Skin Eyes Wash skin Remove Change Provide Prevent skin contact (liq) Prevent eye contact (iiqj When contam (liq) When wet or contam (liq) NR Quick drench (liq) [Phosgene] ABD00022977 Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table 4) Route Symptoms (See Table 5) TBAL Hi inentmeli Moodchenget, Ing anemia testicular Con degeneration loss of appetite dlan lec hind leg tremor derm Health hazards First aid (See Table 6) i Breath Swallow brimmed Soap wash Resp support Medical attention mmed Targetoraans (See Table 5) Wood, CNS, ekis, rapro ays TBAL NiOSH/OSHA 01 ppm SA 02$ ppm SA.CF 06 ppm: SAT CFSCaAF/SAP 4 ppm SA.PD.PP | SCBAF PD.PP/SAF^O.PPvkaCBA Escape <3MFOVHSCBAE " ;n NlOSH/OSHA 1 ppm SA' 2 ppm SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFS/SC6AE Inn Ads mg Con irrit eyes skin resp sys miosis mm head chest tight wheez lar spasm salv cyan anor nau vomit abdom cramps diarr sweat musefase weak para gidd cent ataxia convuts coma low BP card irreg Eye Skin Breath Swallow irr immed Soap flush immed Resp support Medical attention immed Eyes skin resp sys CNS CVS olood Choi 253 Hi Ink eyee, akin, reap eye. At mioait,ittn,head cheat mo tight, wheez, ler apeam, Con satv.eyan.anor.nau, vomK, abdom orempe, diarr, pKM)da,domule. low BR, card brag 1 Greeth. Swallow irr Immed Soapwash immed Reap support Medical Mention bnmed Eyes, eWn, resp eye CNS. CVS. Wood Mot > HI Con (l<q) Irnt eyes dry burning throat vomit cough foamy sputum dysp chest pain cyan liq frostbite Eye Skin Breath Irr immed (liq) Water flush immed (I'd) Resp support Eyes skin resp sys Chemical name structure/formula CAS and RTECSNos and DOT ID and guide Nos Synonyms trade names and conversion factors Phosphine ph3 7803-51-2 SY7525000 Hydrogen phosphide Phosphorated hydrogen Phosphorus hydnde Phosphorus tnhydnde 254 2199119 Phosphonc acid h3P04 7664 38 2 TB6300000 1 ppm 1 39 mg/m5 Orthophosphoric acid Phosphonc acid (aqueous) White phosphonc acid 1805 154 Phosphorus (yellow) p 7728*14-0 TH4500000 Elemental phosphorus, Wide phosphorus 1361 136 Phosphorus oicychloride POCl3 10025 87 3 TH4897000 Phosphorus Chloride Phosphorus oxytnchlonde Phosphoryl chloride 1810 137 1 ppm = 6 27 mg/m5 Exposure limits (TWA unless noted otherwise) NIOSH 0 3 ppm (0 4 mg/m-) ST 1 ppm (1 mg/m3) OSHAt 0 3 ppm (0 4 mg/m5) NIOSH 1 mq/m3 ST 3 mg/m3 OSHAt 1 mg/m3 NIOSH/OSHA 01 mg/m3 NIOSH 0 1 ppm (0 6 mg/m5) ST 0 5 ppm (3 mg/m5) OSHAt none ABD00022978 IDLH Physical iltst ription Chemicaland physical pro perties MW BP SOL FI P IP Sp Gr flammability VP FRZ UEL LEL 50 ppm r oloriesg gas with d fisn or garliclike ixloi [pes'icide] [Note Shipped as a liquefied compressed gas Pure compound is odorless ] MW 34 0 BP *26"F Sol Slight FI P NA (Gas) IP 9 96 eV RGasD 116 Flammable Gas VP 41 3 atm FRZ 209F UEL ' LEL 1 79% 1000 mg/m5 Thick colorless odorless crystalline solid (Note Often used in an aqueous solution ] MW 98 0 BP 415F Sol Miscible FI P NA IP 7 VP 0 03 mm MLT 108'F UEL NA LEL NA Sp Gr(77`F) 1 87 (pure) 1 33 (50%soln ) Noncombustible Solid 6 mg/m5 White to yellow soft, waxy solid with acrtdfumes In air [Note Usually shipped or stored In water] MW 124 0 BP S36*F Sol 0 0003% FI P ? IP ? SpGrl 82 Flammable Solid VP 0 03 mm MIT 111'F UEL 7 LEL ? ND Clear colorless MW 153 3 VP(81F) to yellow oily 8P 222F 40 mm liquid wrth a Sol Decomposes FRZ 34 F pungent 4 musty odor FI P NA IP 7 UEL NA LEL NA (Note A solid Pelow 34'F 1 Sp Gr(77'F) 1 65 Noncombustible Liquid Put may set fire to combustible materials Incompatibilities and reactivities Measurement method (See Table 11 Air oxidizers chlorine acids moisture halogenated hydrocarbons copper [Note May ionite SPONTANEOUSLY on contact with air ] Beaded carbon' HLOU buffer 1C OSHA [#10180] Strong caustics Si gel most metals NaHCOV [Note Readily reacts Na,CO, with metals to form 1C flammable hydrogen IV gas DO NOT MIX [#7903 WITH SOLUTIONS Inorganic CONTAINING BLEACH Acids] OR AMMONIA] Air, oxidizers (including elemental Xvfene. sulfur & strong caustics), halogens GC/FPO IV [Note Ignites [*7905] SPONTANEOUSLY In moist sir] Water combustible None materials carbon available disulfide dimethyl formamide metals (except nickel & lead) (Note Decomposes in water to hydrochlonc 4 phosphoric acids j Personal protection (See Table 3) Skin Eyes Wash skin Remove Change Provide Frostbite Frostbite NR When wet (flamm) NR Frostbite [Phosphine] Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet or contam Daily Eyewash(>1 6%) Quick drench(>1 6%) (Phosphoric acid] Skin Prevent skin contact* Eyes Prevent eye contact Wash skin When contam Remove When wet or contam Chengs Daily Provide Eyewash Quick drench [`Note Flame retardant personal protective equipment should be provided) [Phosphorus (yellow)] Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet or contam NR Eyewash Quick drench ABD00022979 Recommendations for respirator concentration for use (MUC) (See Table 4) NIOSH/OSHA 3 ppm SA 7 5 ppm SA.CF 15 ppm GMFS/SCBAF/SAF 50 ppm SA.PDPP SCBAF PD PP/SAF PD PP ASCBA Escape GMFS/SCBAE Route Symptoms (See Table 5) Mi Nau, vomit abdom pain Con diarr; thirst chest tight (iiq) dysp muse pain, chilis stupor or syncope puim edema itq frostbite Health hazards First aid (See Table 6) S Breath Frostbite Frostbite Resp support Target organs (See TabTe 5) Resp sys NIOSH/OSHA 25 mg/m3 SA CF 50 mg/m5 HiEF/SCBAF/SAF 1000 mg/m3- SAF PD PP SCBAF PD PP/SAF PD PP ASCBA Escape HiEF/SCBAE Inh Ing Con irriteyes skin upper resp sys eye skin burns derm Eye Skin Breath Swallow irr immed Water flush Immed Resp support Medical attention immed Eyes skin resp sys NIOSH/OSHA 1 mg/ma SA 2 5 mg/m3- SA CF4 5 mg/m3- SCBAF/SAF S SCBAF PD PP/SAF PD.PP.ASC8A Escape SCBAE Inh Irrtt eyes, reap tract, aye, Ing sldn bums, abdom pain, nau, Con jaun anemia, cachexia, dental pam satv, jaw pain, swan la Breath Swallow- Irr immed Water flush Immed Resp support Medical attention enmed Eyes, skin, resp sys, liver, kidneys, Jew, teeth, Mood TBAL Inh Ing Con Iml eyes skin resp sys eye skin burns dysp cough lung edema dizz head weak abdom pam nau vomit neph lETn Breath Swallow Immmed Water flush immed Resp support Medical attention immed Eyes skin resp sys CNS kidneys [Phosphorus oxychloride) 255 Chemical name structure(formula CAS and RTECSNos andOOT 10 and guide Nos Synonyms trade names and conversion factors Phosphorus peniachlonde PCIS 10028-13-8 TB6126000 Pentachlorophoaphorus Phosphoric chloride Phosphorus perchlortde 1806 137 Phosphorus pentasulfide Phosphorus persulfide Phosphorus sulfide Sulfur phosphide 256 1314 80 3 TH4375000 1340 1 39 Phosphorus Inchlonde PCI, 7718-12 2 TH3675000 Phosphorus chloride 1809 137 Phthalic anhydride C^H/CO^O 85 44 9 TI3150000 1 ppm 5 62 mg/m5 1 2 Benzenedicarboxylic anhydride PAN Phthalic acid anhydride 2214 156 1 ppm = 6 06 mg/m5 Exposure limits (TWA unless noted otherwise) NIOSH/OSHA 1 mg/m5 NIOSH ' mg/mJ ST 3 mgim OSHAt 1 mg/m3 NIOSH 0 2 ppm (1 Smg/m5) ST 0 5 ppm (3 mg/rrr) OSHAt 0 5 ppm (3 mg/m5) NIOSH 6 mg/m3 OSHAt 12 mg/m3 (2 ppm) ABD00022980 IDLH Physical description 70 mg/m5 White to paleyellow crystalline solid with a pungent unpleasant odor 250 mg/m3 Green sn gray to yellow crystal l ne solid with an odo of rotten 25 ppm Colorless to yellow fuming liquid with an odor like hydrochloric acid 60 mg/m3 Mute solid (flake; or a clear coioness liquid (molten) with a characteristic ae id odor Chemical and physical properties MW, BP SOL FI P IP Sp Gr flammability VP FRZ UEL LEL MW 208 3 BP Sublimes Sol Reacts FIP NA IP ? VP(132*F) 1mm MLT 324`F (Sublimes) UEL NA LEL NA SpGr 3 60 Noncombustible Solid Incompatibilities and reactivities Measurement method (See Table 1) Water magnesium Fitter/Bub oxide chemically- Reagent active metals such as Vis sodium & potassium, 11(5) alkalis amines [8S2S7] [Note Hydrolyzes in water (even in humid air) to form hydrochloric acid & phosphoric acid Corrosive to metals] MW 222 3/ BP 957 F Sol Reacts FI P 1 IP 7 VP(572 F) 1 mm MLT 550 F UEL > LEL 7 Waler aicoho>9 None strong oxidizers available acids alkalis (Note Reacts with water to form hydrogen sulfide sulfur dioxide and phosphoric acid ) SpGr 2 09 Flammable Solid which may SPONTANEOUSLY ignite m presence of moisture MW 137 4 BP 169*F Sol Reacts FIP NA IP 9 91 eV VP 100mm FRZ -170*F UEL NA LEL NA SpGr 156 Noncombustible Liquid, however a strong oxtdizar that may ignite combuetlblee upon contact Water, chemically- Bub, active metals such as Reagent sodium 6 potassium. Vis aluminum strong IV mtnc acid acetic [#6402] acid organic matter (Note Hydrolyzes r water to form hydrochloric acid and phosphoric aad] MW 148 1 BP 563 F Soi 0 6% FI P 305 F IP 10 00 eV VP 00015mm MLT 267 F UEL 10 5% lL 1 7% Strong oxidizers water [Note Convened to phthalic acid m not water ] Filter NH .OH HPLC/UVD 11(3) [#S1 79) Sp Gr 1 53(Flake) 1 20 (Molten) Combustible Solid Personal protection {See Table 3) Stan. Remove Charge Provide Prevent stan contact Prevent eye contact When contam When wet or contam Daily Eyewash. Quick drench [Phosphorus pentacMonde] SKin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam When wet or contam Daily [Phosphorus pentasulfide] SMn Eyes Wash stan. Remove. Change Provide Prevent stan contact Prevent eye contact When contam When wet or contam NR Eyewash. Quick drench [Phosphorus trichloride] Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam When wet or contam Daily (Pnthalic anhydride] ABD00022981 Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table 4) NtOSHfOSHA lOmgrtn* SA* 25 mg/m* SA CP* 50 mg/m* SCBAF/SAF 70 mo/m* SAF PD.PP SCBAF PD.PP/SAF PD.PP.ASCBA Escape GMFOVHIE/8CBAE Route Symptoms (See Table 5) Inh tmt eyes, skin reap sys, Ing bron derm Con Health hazards First aid (See Table 6) Target organs (See Table 5) ! Breath Swallow Irr immed Water flush immed Resp support Medical attention snmed Eyes skin, resp sys NIOSH/OSHA 10 mg/m3 SA 25 mg/m3 SA CF 50 mg/m3 SCBAF/SAF 250 mg/m3 SAF PD PP SCBAF PD PP/SAF PD PP ASCBA Escape GMFSHiE/SCBAE inh ing Con Irnteyes skin resp sys apnea coma convuis conj pam lac pnolo kerato conj corn vesic dizz head ftg irnty insom Gl dist Eye Skin Breath Swallow Irr immed Dust off solid water flush Resp support Medical attention immed Eyes skin resp sys CNS 257 NIOSH 10 ppm SCBAF/SAF 25 ppm SAF PD PP SCBAF PO,PP/SAF PO PP ASCBA Escape GMFS4SCBAE Mt l?9 Con Irrlt eves, skin nose throat, pidm edema eye, skin bums Breath Swallow Irr immed Water flush tainted Resp support Meaical attention tavned Eyes, skin reap sys NIOSH 30 mg/m3 DM 60 mg/m3 DMXSQ /HiEFiPAPRDM / SA /SCBAF SCBAF PD PP/SAF PD PP ASCBA Escape H1EF/SC8AE Inh Ing Con Irrit eyes skm upper resp sys con; nasal ulcer bleeding bron bronchial asthma derm mammals liver kidney damage Eye Skin Breath Swallow Irr immed Soap wash promp, Resp support Medical attention immed Eyes skin resp sys liver kidneys Chemical name structure/formula and DOT ID and guide Nos m-Phthalodin(tnle CH4(CN), 826-17-5 CZ1900000 258 Picloram cm>c'znj 1918-02 1 TJ7525000 Picric told 66-89-1 TJ7B76000 1344113(10%wetor) Pmdone CjHsOjCfOClCH,), 83 26 1 NK6300000 Synonyms trade names and conversion factors 1 3-Benzenedtcert>onltr1le m-Olcyanobenzene 1 3-Dieyanobenzene isophthalodlnitrlle, nvPON 4 Amino 3 5 6 tnchloro picoimic acid 4 Ammo 3 5 6 tnchloro 2-picoiinic acid ATCP Grazon Tordon Phenol trtnttate. 2,4 6-Tnnltrophenol [Note An OSHA Ctaas A D^Mlvo (1910109).! 1 ppm 9 37 mg/m* ten Butyl valone 1 3 Oioxo 2 pivaloy lindane Piva Pivalyl 2 Pivalyl 1 3 mdandione Exposure limits (TWA unless noted otherwise) NIOSH 5 mg/m5 OSHAf none ABD00022982 IDLH Physical description NO Needle-like color less to white crystalline flaky solid with an almond-llke odor Chemical and physical properties MW BP SOL FI P IP Sp Gr flammability VP FR2 UEL LEL MW 1281 BP Sublimes Sol Slight FIP 7 IP ? VP 001 mm MLT 324*F (Sublimes) UEL ? LEL ? Incompatibilities and reactivities Strong oxidizers (e g chlorine bromine fluonna) Measurement method (See Table 1) Nona available NIOSH See Appendix D OSHAT 15 mg/m3 (total) 5 mg/m3 (resp) NIOSH 01 mg/m* ST 0 3 mg/m* (Kin] OSHA 01 mg/m* [skin] NIOSH/OSHA 0 1 mg/m3 Sp Gr 442 Combustible Solid and a severe explosion hazard ND Colorless to white MW 241 5 VP(95 F) Hot concentrates Filter crystals with a chlorine like odor [herpicide] BP Decomposes Sol 0 04% FI P ' IP > 0 0000006 mm MLT 424 F (Decomposes) UEL ' alkali (hydrolyzes) none Grav IV {Particulates LEL ? NOR S500 (total) Sp Gr > *600 Combustible Solid (resp)] 75 mg/m* YeUow odorieu olid [Note Usual? used Han aqueous solution ] MW 2291 BP Explodes above572*F Sotl% FI P- 302*F IP 7 VP(383*F) 1mm MLT 252*F UEL ? LEL ? SpOrl 76 Combustible SoSd Copper, lead zmc 6 othermetals, salts plaster concrete, ammonta (Note Conceive to metals Anaxploatva mixture results when the aqueous solutfon crystallizes I niter Methanol/ Water KPIC/UVO; j^S226] 100 mg/m3 Bright yellow powder wrth almost no odor (rodenticide] MW 230 3 BP Decomposes Sof(77*F) 0 002% FI P ? IP ? VP Very low MLT 230 F UEL ' LEL 7 None reported None available Sp Gr 1 06 Personal protection and sanitation (See Table 3) Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact Dany When wet or contain Daily [m-Phthalodinitme) Skin Eyes Wash Skirt Remove Change Preven* skir contact Prevent eye contact When cortam NR Daly )Picloi am) Stdn Eyea Wash skin Remove Change Prevent skin contact Prevent eye contact When contam/Daity When wet or contain Daily [Picric add] Skin Eyes Wash skin Remove Change NR NR NR NR Daily [Pmdone] ABD00022983 Recommendations tor respirator selection -- maximum concentration for use IMUC) (See Table 4) T9AI Route Symptoms (See Table 5) hh Abs Ing Cor Head nau conf mammals irrrteyes skin Health hazards First aid (See Table 6) Eye Skin Breath Swallow Irrimmed Soap wash immed Reap support Medical attention immed Target organs (See Table 5) TBAL Inh Ing Con irnt e/es sk r rest sys r.au in ar msis five** changes Eye Skir Breath Swafiow Irr immed Soap wash Fresh av Medical attention immed Eyes skin re: liver kidneys NIOSH/OSHA 0 6 mg/m1 DM 1 malm1 OMXSO/SA. 2 5 mg/m1 SACF/PAPROM 5 mg/m1 HiEF/SAT CF/PAPRTHIE/ SC8AF/SAF 75 mg/m1 SAP PD PP | SCBAF PO PP/8AF PD PP ASCBA Escape HIEF/SCSAE NIOSH/OSHA 0 5 mg/m3 DM 1 mg/m3 DMXSQ/SA 2 5 mg/m3 SA CF/PAPRDM 5 mg/m3 HiEF/SAT CF/PAPRTHiE/ SCBAF/SAf 100 mg/m3 SAF PD PP SCBAF PD PP/SAF PD PP ASCBA Escape HiEF/SCBAE Mi Irrfteyes skin sens derm Abs yellow-stained hair skin weak, myatola.anvina Con polyuria bitter taste Gl diet hepatitis hema album neph inn Epis excess deeding Ing from minor cuts bruises smoky unne black tarry stools abdom back pain IS, Swallow Irrimmed Reap support Medical attention Immed liver blood Eye Breath Swallow irr immed Resp support Medical attention immed Blood prothrombin 259 Chemical name structure/formula CAS and RTECSNos guide Nos Synonyms trade names and conversion factors Piperazine dihydrgchlonde C4H10Nj*2HCI 142-64-3 T14025000 Piperazine hydrochloride [Note The monochlonde C<HnN2 HCI is also commercialty available) 260 Piaster ol Pans CaSO. 0 5H 0 26499 66 0 TP0700000 Platinum Pi 7440-06-4 TP2160000 Calcium sulfate hemihydrate Dried calcium sulfate Gypsum hemihydrate Hemihydrate qvpsuni [Note Plaster of Pans is Ihe hemihydrate form of Calcium Sulfate & Gypsum is the dihydrate Platinum black Platinum sponge Platinum (soluOie salts as Pt) Synonyms vary depending upon the specific soluble platinum salt Exposure limits (TWA unless noted otherwise) NIOSH 5 mg/m3 OSHAT none NIOSH 10 mg/m3 (total) 5 mg/m' (resp) OSHA (total) 5 mg/rn iresp> NIOSH 1 mg/m3 OSHAT none NIOSH/OSHA 0 002 mg/m3 ABD00022984 1DLH Physical description ND White to cream colored needles or powder Chemical and physical properties MW, BP SOL FI P IP Sp, Gr flammability VP,FRZ UEl.LEL MW 1561 BP 2 Sol 41% FIP ? IP ? VP ? MLT 635'F UEL ? LEL ? Incompatibilities and reactivities Measurement method Water [Note Slightly hygroscopic (1 e absorbs moisture from the air) J None available ND NO 4 mg/m3 (as Pt) Sp Gr ? Combustible Solid but does not ignite easily White or yellowish finely divided odorless powder MW 145 2 BP ' Sol(77'F) 0 3% FI P NA IP NA VP 0 mm (approx) MLT 325 F (Loses H,0) UEL NA LEu NA SpGr 2 5 Noncombustible Solid Moisture water [Note Hygroscopic (i e absorbs moisture from the air) Reacts with water to form Gypsum) Filter none Grav IV [Particulates NOR #0500 (total) #0600 (resp)] Silvery whitish- grey malleable ductile metal MW 1951 VP 0mm Aluminum ecetone, BP 692rF (approx) arsenic, ethane Sol Insoluble MLT 3222'F hydrazine hvdrooen RP NA UEL NA peroxide, lithium, IP NA LELNA phosphorus selenium tefiurium, various fluorides SpGr 21 45 Noncombustible Solid in bulk form, but finely divided powder can be dangerous to handle Filter, Acids ICP; IV [*7300 Elements] Appearance and odor Properties vary depending vary depending upon upon the specific soluble the specific platinum salt soluble platinum salt Vanes Filter Acid/ Reagent GFAAS 11(7) [#S191] Personal protection ( See Table 3) Skin Eyes Wash skin Remove Change Provide Prevent ekm contact Prevent eye contact When contam When wet or contam Daily Eyewash Quick drench IPperezfne dihydrochlortde] Skm Eyes Wash Skin Remove Change NR NR NR NR NR [Plaster of Pans) Skm. wSshskm Remow Change NR NR NR NR Dally (Platinum] Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam When wet or contam Daily [Platinum [soluble salts as Pt)] ABD00022985 Recommendations for respirator concentration for use (MUC) (See Table 4} TBAL Route Symptoms (See Table 5) Wi Abs Ing Con Imteyes skm respsys skin bums sens asthma 61 upset head nau vomit Inco muse weak Health hazards First aid (See Table 6) Target organs (See Table 5) % Breath Swallow brimmed Water flush immed Rasp support Medical attention immed IE?, TBAL inn Ing Con Irnteyes skin muememb resp sys cough Eye Breath Swallow Irr immed Resp support Medical attention immed Eyes skm resp sys TBAL Inh Irrlt eyas, skin, resp sys I?9 derm Con Breath Swallow In-immed Soap wash Reap support Medical attention immed Eyes skin reap ays NIOSH/OSHA 0 05 mg/m3 SA CFE 0 1 mg/m3 HiEF/SCBAF/SAF 4 mg/m3 SAF PD PP | SCBAF PD PP/SAF PD PP ASCBA Escape HiEF/SCBAE Inh ing Con Irriteyes nose cough dysp wheez cyan derm sens skin lymphocytosis Eye Skin Breath Swallow Irr immed Water flush immed Resp support Medical attention immed Eyes skm resp sys Chemical name structure/formula CAS andRTECSNos and DOT ID and guide Nos Synonyms, trade names and conversion factors Portland cement 65997-15-1 W8770000 Cement Hydraulic cement Portland cement silicate (Note A class of hydraulic cements containing tn and dicalcium silicate in addition to alumina tncalcium alummate, and iron oxide ] (as CN) Potassium salt of Hydrocyanic acid 262 151 50-8 TS8750000 1680 157 (Solution i KOH 1310-58-3 TT2100000 Caustic potash Potassium hyorate 1814 154 (solution) Propane CH.CHjCH 74 98 6 TX2275000 1075 115 1978 115 Bottled gas Dimethyl methane n-Propane Propyl hydride 1 ppm = 1 80 mg/m3 ABD00022986 Exposure limits (TWA unless noted otherwise) IDLH Physical description NIOSH 10 mg/m3 (total; 5 mg/m3 (reap) OSHAT 15 mg/m3 (total) 5 mg/m3 (rasp) 5000 mg/m' Gray odorless powder NIOSH C 5 mg/m3 25 mg/mJ (as CN) OSHA 5 mg/m3 ("Note The REL and PEL also apply to other cyanides (as CN) except Hydrogen cyanide ] White granular or crystalline solid with a faint almond like odor Chemical and physical properties MW, BP SOL Fl P IP Sp Gr flammability VP FRZ UEL LEL MW ' BP NA Sol Insoluble FI P NA IP NA VP 0 mm (approx) MLT NA UEL NA LEL NA Sp Gr 7 Nonnombustlble Solid Incompatibilities and reactivities Measurement method (See Table 1) None reported Filter none Grav IV (#0500 Particulates NOR (total)] MW 65 1 VP 0 mm Strong oxidizers Filter/Bub BP 2957'F Sol(77 F) 72% (approx; (such as acids acid salts chlorates & ISE FI P NA UEL NA nitrates) IV IP NA LEL NA [Note Absorbs moisture[#79Q4 from the air forming Cyanides] a syrup | [Also Sp Gr 1 55 NoncombustiDie Solid Dui contact with acids #601D Hydrogen releases highly flammable hydrogen cyanide Cyanide) NIOSH 2 mg/m3 OSHAT none N D Odorless white or MW 561 VP(1317'F) Acids water metals Fitter slightly yellow BP 2415*F 1 mm (when wet) haiogenated HCI lumps rods flakes Sol(59`F) MLT 716*F hydrocarbons maleic Titrate sticks, or pellets 107% UEL NA anhydnde (Note May be used FI P NA LEL NA (Note Heat is oener- (#7401 as an aqueous IP ? atedif KOH comes in Alkaline solution ] contact with H,0 & Ousts] So Gr 2 04 CO, from the air 1 Noncombustible Solid however may react with H,0 & other substances and generate sufficient heat to ignite combustible materials NlOSH/OSHA 1000 ppm (1800 mg/m3) 2100 ppm (10%LEL] Colorless odorless gas [Note A foul smelling odorant is often added when used for fuel purposes Shipped as a liquefied com pressed gas j MW 44 1 BP 44 F Sol 0 01% FI P NA (Gas) IP 11 07 eV RGasD 1 55 Flammable Gas VP(70 F) 8 4 atm FRZ 306F UEL 9 5% LEL2 1% Strong oxidizers Combustible gas meter none none 11(2) [#S87] Personal protection and sanitation (See Table 3) Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact Whencontam When wet or contain NR [Portland cement] Sum Eyes Wash skm Remove Change Provide Prevent skin contact Prevent eye contact Whencontam When wet or contam Daily Eyewash Quick drench [Potassium cyanide (as CN)) Skin vJtwhskm Remove Change Provide Prevent skin contact Prevent eye contact Whencontam When wet or contam Daily Eyewash Quick drench [Potassium hydroxide] Skin Eyes Wash skin Remove Change Provide Frostbite Frostbite NR When wet (flamm) NR Frostbite [Propane] ABD00022987 Recommendations for respirator selection--maximum concentration for use (MUC) [See Table 4) NIOSH 50 mg/m3- D 100 mg/m3 DXSQ/SA 250 mg/m3 SA CF/PAPRD 500 mg/m3 HiEF/SAT CF/PAPRTHiE/ SCBAF/SAF 5000 mg/m3- SA PD PP SCBAF PO PP/SAF PD PP ASCBA Escape HtEFfSCBAE Route Symptoms (See Table 5) Inh Ing Con Irrlteyes skin nose cough expectoration exertional dysp wheez chronic bron derm NIOSH/OSHA 25 mg/m3 SA/SCBAF SCBAF PD PPfSAF PD PP ASCBA Escape GMFSHiE/SCBAE Inh Abs Ing Con Irriteyes Skin upper resp sys asphy weak head conf nau vomit mcr rate resp slow gasping resp thyroid blood changes Health hazards First aid (See Table 6) Target organs (See TableS) Ew Skm Breath Swallow Irr Immed Soap wash prompt Fresh air Medical attention immed Eyes, skin reap aye Eye Skin Breath Swallow Irr immed Soap wash immed Resp support Medical attention immed Eyes skin resp sys CVS CNS thyroid blood TBAL Wt Irrlt eyes skin, resp sys, cough sneez eye skm Con bums, vomit, dtarr NIOSH/OSHA 2100 ppm SA/SCBAF SCBAF PD PP/SAF PD PP ASCBA Escape SCBAE Inh Con (iig) Dizz conf excitation asphy liq frostbite is. Breath Swallow irr Immed Water(tueb tamed Resp support MedioaF attention Immed Eyes, skm, respsys TU Eye Skin Breath Frostbite Frostbite Resp support - ""`i CNS _ dp' Chemical name structure/formula CAS and RTECS Nos and DOT ID and guide Nos Synonyms trade names, and conversion factors Propane suttone 1120-71-4 RPS425000 3-Hydroxy-l-propanesu! phonic aod suttone 1 3-Propane suttone i Propane(hic) CH,Ch?CH(SH 107 03 9 T27300000 2402 130 Propergyl alcohol HCeCCHjOH 107-19-7 UK5075000 1986 131 (1 Propioiactone Wr 57 57-8 RQ7350000 3 Mercaptoproparie Propane i thiol Propyl mercaptan n Propyl mercaptan 1 ppm = 3 12 mg/mJ 1-Propyn-3-ol 2-Propyn'l-vl 2-Propynyl alcohol 1 ppm = 2 29 mg/m5 BPL Hydroacryhe acid 13 lactone 3 Hydroxy IJ lactone 3 Hydroxy propionic acid fl Lactone 2-Oxetanone 3 Propiolacetone Exposure limits (TWA unless noted otherwise) NIOSH Ca See Appendix A OSHA none ABD00022988 IDLH Ca (NO] Physical description White crystalline solid or a colorless liquid (above 38'F) (Note Releases a foul odor as it metts ] Chemical and physical properties MW BP SOL FI P,IP,Sp, Gr, flammability VP FRZ UEL LEL MW 122 2 BP 7 Sol 10% PI P >23S*F IP 7 VP ? MLT 86`F UEL 7 LEL 7 NIOSH C 0 5 ppm 5 mgmP; [15 mm] OSHA none ND NIOSH Ippm (2 mg/ms) [sklnj OSHAt none ND NIOSH Ca See Appendix A Ca [N D] OSHA(1910 1013] See Appendix B Colorless liquid with an offensive cabbage like odor Sp Gr 1 39 Combustible Solid MW 76 2 BP 153F Sol Slight FI P SF IP 9 195eV VP(77'F) 155mm FRZ 172 F UEL 7 LEL 7 Sp Gr 0 04 Class IB Flammable Liquid Colorless to strawcolored liquid with a mild geranium odor MW 561 BP 237'F Sol Miscible Fl P(oc) 97*F IP 1051eV VP 12mm FRZ -62*F UEL ? LEL 7 Colorless liquid with a slightly sweet odor Sp Gr 0 97 Class IC Flammable Liquid MW 72 1 BP 323'F (Decomposes) Sol 37% Fl P 165 F IP ' VP(7?Fi 3mm FRZ 28 F UEL 7 LEL 2 9% Sp Gr 1 15 Class II1A Combustible Liquid Incompatibilities and reactivities Measurement method (See Table 1) None reported None available Oxidizers reducing agents strong acids & bases alkali metals calcium hypochlorite None available Phosphorus pentoxide oxidizers Char(pet) Toluene, GC/ECD OSHA 1*97] Acetates halogens thiocyanates thiosulfates [Note May polymerize upon storage J None available Personal protection and sanitation (See Table fti Skin Eyes Wash akin Remove. Charge Provide Prevent skin contact Prevent eye contact When contam/Daily When wet or contam Daily Eyewash Quick drench propane sultonej Skin Eyes Washsk/n Remove Change Provide NR Prevent eye contact NR When wet (flainm) NR Eyewash l i Propane'h o SWn Eyes Wash skin Remove* Charne. Provide Prevent skin contact Prevent eye contact When content When wet or contain NR Eyewash Quick drench JPitgargyi alcohol) Skjn Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact Wien contam/Daily Wen wet or contam Daily Eyewash Quick drench 5ft Propiolactcme] ABD00022989 Recommendations (orrespirator selection--maximum concentration for use (MUC) (See Table 4} NIOSH SCBAF PD PP/SAF PD PP ASCBA Escape GMFOVHiE/SCBAE Route Symptoms (See Table 5) Inh Abs Ing Con In animats Irrtteyes skin mucmemb [care] Health hazards First aid (See Table 6) Target organs (See Table S) 1C Breath Swallow Irrlmmed Water flush immed Reap support Medical Mention immad Eyes, slun reap eye [mammals, akin tumors bunmta, gliomas] NIOSH 5 ppm CCROV/SA 12 5 ppm SACF/PAPROV 25 ppm CCRI-OV/GMFOV/PAPRTOV/ SCBAF/SAF SCBAF PD PPiSAF PD PP ASCBA Escape GMFOV/SCBAE Inti Ing Con inn eyes skin nose throat respsys head nau dizz cyan mammals liver kidney damage Eye Skin Breath Swahow irr immed Soap wash Resp support Medical attention immed Eyes skin respsys CNS blood liver Kidneys 265 TBAL tnh Abe Jl*8 Con irrttekJn mucmemb. CNSdapree, in arerrais. Iver, kfctaey damage 9& Breath Swallow Irrknmed Water flush prompt Reap support MsKtoot uteintkxt Immed Skin, respsys, CNS, Uver Iddney* NIOSH SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SC8AE Inh Abs Ing Con Skin rmt blistering burns com opac frequent urination dysuna hema [care] Eye Skin Bieath Swallow Irr immed Soap wash immed Resp support Medical attention immed Kidneys skin lungs eyes [mammals tumors of the liver skin & stomach] Chemical name structure/formula CAS and RTECSNos and DOT 10 and guide Nos Synonyms, trade names, and conversion factors Propionic add CHjCHjCOOH 79-09-4 UE5960000 Carbaxyethane EthanecaftoxyHe add, EftylfoRMc acid Matacatontc add, Methyl acetic add, Propanoic add 266 1646 132 ProDion ime CHJCH4CN 107 12-0 UF962S000 1 ppm * 3 03 mgrtn* Cyanoethane Ethyi cyanide Propionic nitrile Propiononitrile Exposure knits (TWA unless noted otherwise) NOSH 10 ppm (30 mgftn5) STISppm (46 mom*) OSHAt NiOSH 6 ppm (14 mg/m3) OSHA none 2404 131 1 ppm = 2 25 mg/m3 Propoxur AprocarM, Baygon*. CH^COOC^CH^g^^ M06H 0.6 mgAn* ^ 11446-1 FC3150000 N-MethyF2-iaopropoxyphey1- none cwtovnate n Propyl acetate CHjCOOCHjCHXHj 109 60 4 AJ 3675000 P'opyiacetate n Propyl ester of acetic acid 1276 129 1 ppm -4 18 mgim5 NIOSH 200 ppm (940 mg/m3) ST 250 ppm (1050 mg/m3) OSHAT 200 ppm (640 mg/m3) ABD00022990 IDLH Physical description N D CotortOM oily liquid with a pungent disagree able rancid odor [Note A solid below 5*F] Chemical and physical properties MW, BP SOL FI P, IP Sp, Gr flammability VP.FR2 UEL LEL MW 74 1 BP- 2B6*F Sol Miscible R P 126*F IP 10 24eV VP 3mm FRZ.5*F UQ.12.1% LEL29% Incompatibilities and reactivities Measurement method (See Table 1) Alkalis strong oxidizers (a g, chromium trioxide) [Nod Corrosive to steel] None available SpGr 0 99 Class II Combustible Liquid ND Colorless liquid MW 55 1 VP 35 mm with a pleasant BP 207 F FR2 133 F sweetish ethereal Soil 1 9% UEL 7 odor FI P 36F LEL 3 1 % [Note Forms IP 11 94 eV cyanide m the body ] Sp Gr 0 78 Class IB Flammable Liquid NO White to ten MW- 209 3 VP 0000007 crystalline powder BP- Decompoeea mm with a feint, Sol 02% MLT 197*f dtaracterletie FI P >300*F UEL ? odor IP ? LEL? (Insecticide) 1700 ppm Colorless liquid with a mild fruity odor SpGr ? Class IIIB Combustible Liquid MW 102 2 SP 215 F Sol 2% FIP 55 F IP 10 04 ev VP 25 mm FRZ 134 F UEL 8% LEL(100 F) 1 7% Strong oxidizers & reducing agents strong acids 8 Cases [Note Hydrogen cyanide is produced when propionitnie is heated to decomposition ] Char Benzene IV (Adapt #1606) Strong oxidizers BteBt [Note Emits highly toxic methyl isocyanatefumes when heated to decomposition ] None available Nitrates strong oxidizers alkalis & acids Char CS, GCftlD IV [#1450 Esters IJ Sp Gr 0 64 Ciass IB Flammable Liquid t5i 5 Personal protection and sanitation (See Table 31 Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet or contam NR Eyewash Quick drench acid] bkr Eyes A/ash skin Remove Change Provide P'eve skm contacl Pie.ent eye contact When .ontam Wher wet or contam NR Qmckdrench fPropiomtrile) Skin Eyes Wash skm Remove Change Prevent skm contact Prevent eye contact Daily When wet or contam Daily [Propoxur] Skin Eyes Wash skin Remove Change Prevent skm contact Prevent eye contact When contam When wet (flamm) NR [n Propyl acetate] ABD00022991 Recommendations tor respirator selection -- maximum concentration for use (MUC) (See Table 4) TBAL Route Symptoms (See Table 5) Abs Ing Con Imt eyes skin nose, throat blurred vision corn burns skin bums abdom pain nau vomit Health hazards First aid (See Table 61 Target organs (See Table 5) Eye Skin Breath Swallow Irrimmed Water flush immed Resp suppent Medical attention immed Eyes skin respsys NIOSH 60 ppm CLROViSA 150 ppm SA CF/PAPROV 300 ppm CCRFOV/GMFO'//PAPRTOW SCBAF/SAF 1000 ppm SAF PD PP SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE inn Abs mg Con "it eyes skm resp s/s nau vomit chest pain weak stupor convuls in ammels liver kidney Damage Eye 6kir Breath Swallow irrimmed Water flush immed Resp support Medical attention immed Eyes skm resp sys CVS CNS liver kidneys 267 TBAL irfi Miosis blurred vision, Abs sweat, salv, abdom cramps, nau diarr vomit, haad, Con weak, mute twitch IS) Breath Swallow Irrimmed Soapwash immed Asm support Medics! attention rvrwd CNS Over, kidneys Gl tract, Mood cnol NIOSH/OSHA 1700ppm SA CF/CCRFOV/GMFOV/ PAPROVE/SC6AF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SC8AE Inh Ing Con Inanimals irnteyes nose throat derm narco - ! Breath Swallow Irrimmed Water flush prompt Resp support Medical attention immed Eyes skin respsys CNS 268 Chemical name, structure/formula, CAS and RTECS Nos. and DOT ID and guide Nos Synonyms, trade names and conversion factors rvPropyl alcohol CHjCHjCHjOH 71-23-8 UH8225000 Ethyl carbtnd 1-Propanol n-Propanol Propyl alcohol 1274 129 Propylene dicnionde CH,CHCICH?CJ 78 87 5 TX96250Q0 1 ppm 2 46 mglm* Dichloro-1 2 propane 1 2 Dichloropropane Exposure limits (TWA unless noted otherwise) NIOSH/OSHA 200 ppm (600 mg/m*) ST 260 ppm (625 mgm*) [skin) OSHAt 200 ppm (600 mg/m1) NIOSH Ca See Appendix A OSHAt 75 ppm (350 mg/m3) 1279 130 P3SS? CHjXOpHCHNOjOH 8423-43-4 TYMOOOQO., . * rf' 1 4-, s' Propylene glycol monomethyl ether CHjOCHjCHCHj 107-68 2 UB7700000 1 ppm = 4 62 mg/m5 PGDN, Dowtherm 209 1 Methoxy-2-hydroxypropane i-Methoxy-2-propanoi 2-Methoxy-l -methylethanol Propylene glycol methyl ether 1 ppm = 3 69 mg/m1 NIOSH 100 ppm (360 mo/m1) ST 150 ppm (640 mg/m3) OSHAT none ABD00022992 IDLH Physical description 800 ppm Colorless liquid with a mild alcohoMike odor Chemical and physical properties MW, BP, SOL FI PIP, Sp.Gr, flammability VP FRZ UEL, LEL MW 601 BP 207*F Sol Miscitrte FI P 72*F IP 10 15eV VP 16mm FRZ -196*F UEL137% L6L22% Ca (400 ppm] Colorless liquid with a chloroform like odor [pesticide] Sp Or 0 81 Class IB Flammable Liquid MW 113 0 BP 206 F Sol 0 3% FI P 60 F IP 10 87 eV VP 40 mm FRZ 149 F UEL 14 5% LEL 3 4% Incompatibilities and reactivities Measurement method (See Table 1) Strong oxidizers Char 2-Propanol/ CS, GC/FIO IV [#1401, Alcohols II] Strong oxidizers strong acids active metals Char(pet) Acetone/ Cyclohexane GC/ECD SpGrl 16 Class IB Flammable Liquid chloropropane] Cotorisee liquid wttl a disagreeable odor (Note: Asp** below 1S*F ] MW 1661 BP 7 Sot01% FI P-7 IP ? VP(72'F7 0 07 mm FRZ.18*F UEL 7 LEL.7 $p.Gr(77Tn 23 Combufibte Uqutt Ammonl*compounds, Nana amines, oxidizers, available comtxistaiie materials [Note: Similar to sxxg** xpipaton potedW] NO Clear colorless MW 90 1 VP(77F) Oxidizers strong None liquid with a mild BP 248*F 12mm acids available ethereal odor Sol Miscible FRZ 139*F [Note Hygroscopic Fl P 97*F (Sets to glass) (i e absorbs IP ? UEL(calc) moisture from the 138% air) May slowly LEL(calc) form reactive 19h peroxides dunng SpGr 0 96 prolonged storage ] Class 1C Flammable Liquid Personal protection and sanitation (See Table 3) Sion. Eyas Washskin. Remove. Owes Prevent skin contact Prevent eye contact Whaneomam When wet (denim) NR (n-Propyl alcohol] Stan Eyes Wasn skin Remove Change Provide Prevent sum contact Prevent eye contact When contam When wet (flamm) NR Eyewash Quickdrench Propylene dichloride] SMn. Esrea. Wash skin Remove. Change: Prevent skin contact Prevent aya contact NR NR NR. (Propylene glycol omkrete] Skin Eyes Wash skin Remove Change NR Prevent eye contact NR When wet (flamm) NR (Propylene glycol monomethyl ether) ABD00022993 Recommendations for respirator concentration for use (MUC) (See Table 4) Route Symptoms (See fable 5) NIOSHOSHA 800 ppm CCROV/PAPROVVGMFOW SV/SCBAR | SCBAF PD,PPfSAF PD.PP ASCBA Escape GMFOV/SCBAE Hi Abs mg Con Irrtteyes, nose throat, dry cracking skin, drew, head, starts, Gipain, abdom cramps, nau. vomit, vomit, dlarr; Inanimals narco Health hazards First aid (See Table 6) l(k) Breath Swallow Irrimmed Wetar flush Rasp support Madbatafaftton Immed Target organs (See Table 5) Eyes, skin, reep sys, J tract, CN8 NIOSH * SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE inh Abs Ing Con Irrit eyes skin resp sys draw i head liver kidney damage mammals GNSdepres (care] Eye Skin Breath Swallow irr immed Soap wash prompt Resp support Medical attention immed Eyes skin resp sys liver kidneys CNS [mammals liver & mammary gland tumors] TBAL TBAL Hi Abs 5* Con Irriteyes; con], methemo, head, Impaired balance, vie diet; In animats. Hirer, kidney damage Breath Swaflow trr Immed Soap wash Reep eupport Meawpl ettenSon trnrns? Eyes, CNS blood, Aver, kidneys Inh Ing Con Irnt eyes skin nose throat head nau li head drow mco vomit diarr Eye Skin Breath Swallow ,, Irr immed Water wash Resp support Medical attention immed Eyes skin resp sys CNS Chemical name structure/formuta CAS and RTECSNos and DOT ID and guide Noe Synonyms trade names and conversion factors Exposure limits (TWA unless noted otherwise) Propylene tmine 73-65-8 CMSOSOOOO 270 1921131P(lnhiMed) Propylene oxide C,H,0 75 56 9 TZ2975000 2-Methyiethylena#nine Prooytenevnine. Propylene Imine flnhlbftsd) Propyleninwne 1 ppm 2.34 mgkr? 1 2-Epoxy propane Methyl ethylene oxide Methyloxirane Propane oxide 1 2 Propylene oxide NIOSH C See Appendix A 2 ppm (5 main3) *k)nf osh* W"'' NIOSH Ca See Appendix A OSHAT 100 ppm (240 mg/mJ) 1280 127P n-Prepytnteele CHjCHjCHjCWOj 827-13-4 UK0360000 1888131 Pyrethrum C^H*OyC,,H,,o! cj,HofcX! 8003 34 7 UR4200000 1 ppm 2 38 mg/m3 Propyl aster of nttrtc aoid 1 ppm >4 30 mg/m* Cmenn 1 or II Jesmolin 1 or II Pyrethnn I or II Pvrethrum 1 or II [Note Pyrethrum is a venable mixture of Cinenn Jesmolin and Pyrethnn ] NIOSH sfe? 8T 40 ppm (170 mown QfiHAf '^ NIOSH/OSHA 5 rng/m3 ABD00022994 IDLH Physical description Ca [100 ppm) Colorless oily liquid with an ammonia like odor Chemical and physical properties MW BP SOL FI P IP Sp Gr flammability VP FRZ UEL LEL MW 57 1 BP 152*F Sol Miscible FI P 25*F IP 9 OOeV VP 112mm FRZ -85'F UEL 7 LEL 7 SpOr 080 Cues IB Flammable Liquid Ca [400 ppm) Colorless liquid with a benzene like odor [Note A gas above 94 F i MW 58 ' BP 94 F Sol 41% FI P 35 F IP 9 81 eV VP 445 mr FRZ 170 F UEL 36% LEL 2 3% 600 ppm - Coforiees to straw-colored quid with an ether-like odor 5000 rng/m3 Brown viscous oil or solid [insecticide! Sp Gr 0 83 Class IA Flammable Liquid MW 1061 BP 231T Sol SUaht FIR 68*F IP-1107eV VP 18mm FRZ -148*F UEL 100% LEL 2% SpOrl 07 Ctaaa IB Flammable Liquid MW 316 374 BP 9 Sol Insoluble IP 9 VP Low MLT 9 UEL 9 LEL 9 Sp Gr 1 (approx) Class it IA Combustible Liquid incompatibilities and reactivities Measurement method {See Table 11 Acids strong None oxidizers water available carbonyl compounds quinones sulfonyl hal/des [Note Subject to violent polymerization in contact with actds Hydrolyzes in water to form mathytethanoiamme | Anhydrous metal Char chlorides iror strong acids caustics S peroxides CS, GCtFID IV [Note Polymerization (#1612) may occur due to high temperatures or contamination with alkalis aqueous acids amines & acidic alcohols ] Strong oxidizer*, combustible materials {Note Forms explosive mixtures with combustible materials ] Char GCfrlD [ISI'227] Strong oxidizers Filter CH.CN HPCC/UVD IV (#5008) Personal protection (See Table 3) Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contarn When wet (flamm) NR Eyewash Quickdreneh [Propylene imine] Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact Whenoontam When wet i flamm j NR Quick drench 'P opyfene oxide) Sion Eyee Wash skin Remove Change Prevent skin contact Prevent eye contact Whencontam When wet (flamm) NR [n-Propyl nitrate] Skin F yes A/ash sk n Remove Change Prevent skin contact P e^ent eye contact v\hen contarr When wet or contain Daily [Pyrethrum] ABD00022995 Recommendations for respirator concentration for use (MUC) (See Table 4) Route Symptoms (See Table 6) NIOSH SCBAF PD PP/SAF PD PP ASCBA Escape GMFS/SCBAE Inh Eye skin bums, [care] Aba Con NIOSH * SC QAF PD PP/SAf PD PP ASCBA Escape GMFS/SCBAE Inn Ing Con Irrit eyes skin resp sys blisters bums [care] Hearth hazards First aid (See Table 6) Target organa (See Table 8) is Braath SwaHow Irrlmmad WMer flush tamed Rasp support Mamcil attention immad Eywa.Udn pnanmaia. nasal tumpra] liTn Breath Swallow v Irr immed Water hush immed Reap support Medical attention immed , Eyas skin resp ays [mammals nssal tumors] NKOSH/OSHA 250 ppm SA 500 ppm SA CF/SCBAF/SAF SCBAF PO PP/SAF PD.PP ASCBA Escape GMFSVSCBAE Mi Inanimate Irrtteyea, Ing akin, mathamo,anoxia, Con cyan, dyap, Weak. dlzz. head ( NlOSH/OSHA 50 mg/m3- CCROVDMFl ISA 125 mg/m3 SACF /PAPROVDMFu 250 mg/m1 CCRFOVHiE/PAPRTOVHiEV SC8AF/SAF 5000 mg/m3 SAF PD PP | SCBAF PD PP/SAF PD PP ASCBA Escape GMFOVHiE/SCBAE Inh Ing Con Erythema derm papules pruritus rtun sneez asthma tnMth Swallow- In-immad gyaa.aWn, Soap wash prompt blood Rita flUDDM hlHQ Eye Skin Breath Swallow - ^- ' Irr immed Soap wash immed Resp support Medical attention immed , Reap sy* akin CN5 Chemical name, structure/formuta, CAS and RTECSNoe, and DOT 10 and guide Nos Synonyms, trade names and conversion factors Pyndina W 110-80-1 URS400000 Aafeanzane, Aafete Exposure knits (TWA unless noted otherwise) NIOSH/OSHA 5 ppm (ISmg/m3) 272 1282 129 Quinone OCjH^O 106-51-4 DK2625000 1 ppm *> 3 24 mg/m* 1 4 Benzoquinone p-BenzoQumone 1 4-Cyclohexadiene dioxide p-Quinone NIOSH/OSHA 0 4 mg/m3 (0 1 ppm) 2587 153 RHONM 106-48-3 VOM3SOOO 2878 183 Rhodium (metal fume and insoluble compounds as Rh) Rh (Metal) 7440-16-6 (Metal) V19069000 (Metal) 1 ppm = 4 42 mg/m3 1,3 Benzeoadot. 1dpm4J0f(io8n* Rhodium metal Elemental rhodium Synonyms of other insoluble rhodium compounds vary depending upon the specific compound NIOSH 10 ppm (45 mg/m*) ST 20 ppm (90 ro^fn*) OSHAf none NIOSH/OSHA 0 1 mg/m3 ABD00022996 IDLH Physical description 1000 ppm Colorless (o yellow liquid with a nauseating, fish-like odor Chemical and physical properties MW BP, SOL FI P, IP, Sp Gr, flammability VP FRZ UEL, LEL MW 791 BP 240'F Sol Miscible FIP W'F IP 9 27eV VP 16 mm FRZ -44"F UEL 12 4% UEL18% Incompatibilities and reactivities Measurement method (See Table 1) Strong oxidizers strong acids Cher CH.CL GC7FID IV (#1613) 100 mg/m3 Pale yellow solid with an acrid chlorine like odor Sp Gr 0 98 Class IB Flammable Liquid MW 108 1 BP Sublimes Sol Slight FI P 100-200 F IP 9 68 eV VP(77 F) 01 mm MLT 240 F UEL ? LEL Strong oxidizers XAD 2 Ethanol/ Hexane HPLC/UVD M(4) [rrsiei] Sp Gr 1 32 Combustible Solid ND White needles MW 1101 VP(77*F> plates crystals BP 531 "F 0 0002 mm flakes, or powder SoM10% MLT 226*F wtth a taint odor FI P 281*F UEL ? (Note Turns pink on exposure to IP 8 83 eV LEL (392*F) 1 4% wr or tght or contact wtth SpGrl 27 iron ] Class 1118 Combustfole Liquid but may be difficult to ignite 100 mg/m3 (as Rh) Metal White hard ductile malleable solid with a pluish gray luster MW 102 9 BP 6741F Sol Insoluble Fi P NA IP NA VP 0 mm (appro*/ MLT 3571 F UEL NA LEL NA Acetanilide albumin alkalis antipyrtne camphor ferric salts menthol, epint nitrous ether strong oxidizers & bases (Note Hygroscopic (1 e absorbs moisture from the air)) Cnlonne trifluonde Oxygen difluoride None available Filter Acid AAS H(3) [S188) Sp Gr 1241 (Metal) Metal Noncombustible Solid in bulk form but flammable as Oust or powder Personal protection (See Table 3) Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet (flamm) NR Eyewash Quickdrench [Pyridine] Skir Eyes Wash skin Remove Change P'ovide Prevent skm contact Prevent eye contact When contam When wel or contam Daily E,ewash QuickC ench (Our or e Skin Eyes Wash skm Remove Change Provide Prevent skin contact Prevent eye corned When contam When wet or contam Daily Eyewash (Resorcinol) Skt Eyes Wash skin Remove Change NR NR NR NR NR 'Rhodium ,metal 'jme and inso uble compounds asRnj] ABD00022997 Recommendations for respirator concentration for use (MUC) (See Table 4) Route Symptoms (See Table 5} NIOSH/OSHA 12S ppm SA CF'VPAPROV1 250 ppm CCRFOV/GMFOV/PAPRTOV^ SCBAF/SAF 1000 ppm SAFPOPP SCBAF PD PP/SAF PD PP ASC6A Escape GMFOV/SCBAE Ml Aba ing Con Imteyes head ner dlzz, insom, nau, onor derm liver kidney damage Health hazarda First aid (See Table 6) Eva. Sun Breath Swallow Irrimmed Wafer Auahlmmad Raap support Medical atfentlon immed Target organs (See Table 6) Eyes, skin, CNS, ifcer, kidneys Gl tract NIOSH/OSHA 10 mg/m3 SA CF" 20 mg/m3 SCBAF/SAF 100 mg/m3 SAF PD PP SCBAF PD PP/SAF PD PP ASCBA Escape GMFOVHiE SCBAE Inh Eye imt conj kera ng skin imt Con E>* Skin Breath Swallow Irr immed Soap wash immed Reap support Medical attention immed TBAL Inh Irrit eyes, skin, nosa Ing throat upper reap sys Con methemo, cyan convula resttaas Mutah skin Incr heart rate dyap dlzz drew, hypothermia, hemog spleen, kidney liverchanges, derm NIOSH/OSHA 0 5 mg/m3 DM* 1 mg/m3 DMXSCT/SA 2 5 mg/m3 SA CF/PAPRDMFu 5 mg/m3 HiEF/SAT CF/PAPRTHiE/ SCBAF/SAF 100 mg/m3 SA PD PP SCBAF PD PP/SAF PD PP ASCBA (escape HiEF/SCBAE 'nn Possible resp sens iff Breath SwaHow krlmmad WMvwMhifflffMd Rmo aupport Medcai attention mvnad Eyes, akfcv reap ays CVS. CN$ Mom, aptaan, kvar, kunaya Breath Swallow Reap support Medical attention snmed Reap ays Chmical name struchjre/formula, CAS and RTECSNos, and DOT 10 and guide Nos Synonyms trade names, and conversion factors Rhodium (sotuMe compounds, a# Rh) Synonyms vatydepandfrig upon the specie soluble rhodium compound. Exposure limits (TWA unless noted otherwise) NIOSH/OSHA 0 001 mg/m3 ABD00022998 IDLH Physical description Chemical and physical properties MW BP SOL FI P IP Sp Gr, flammability VP FR2 UEL, LEL 2 mg/m3 (asRh) Appearance and odor Properties vary depending vary depending upon upon the specific soluble the specific rhodium compound soluble rhodium compound Incompatibilities and reactivities Measurement method (See Table 1) Vanes Filter Acid GFAAS M(3) [PS 189] 274 Ronnel (CH50)jP(S)OCsH2Ci3 299 84 3 TG0525000 O O-Dimethyl 0-(2 4 5 In chlorophenyl) phosphoro thioate Fencmorophos gszssts?Rotm com solder. Rosin flux pyrolysis pfoductti Rosin oors soldering flux pyrolysis products Rotenone CaHnO, 83 79 4 OJ2800000 1 2 12 12a Tetrahydro-8 9 dimethoxy 2-<1 methyl ethenyl)-[1)benzopyr8no |3 4-bftir[2 3-h)[1) benzopyran-6(6aH)-one NIOSH 10 mg/mJ OSHAt 16 mg/m3 300 mg/m' While to light tan crystalline solid [insecticide] [Note A liquid above 106 F] MW 321 6 BP Decomposes Sol(77 F) 0 004% FI P NA IP ? VP(77 F) 0 0008 mm MLT 106 F UEL NA LEL NA Strong oxidizers Sp Gr 1 49 Noncompustible Solid NIOSH' ND 0 1 mg/m5 [Note *Ca` in the presence of formaldehyde acetaldehyde or maloneldehude See Appendloee A & C (Aldehydes)! 06HAt none Pyrolysis products Properties vary depending of rosin core upon the specific rosin solder include core solder being used acetone, aliphatic aldehydes methyl alcohol methane ethane various abletlc acids (the major components of rosin) CO & COj. NIOSH/OSHA 5 mg/m5 2500 mg/m5 Colorless to red odorless crystalline solid [insecticide] MW 394 4 BP Decomposes Sol Insoluble FI P ' IP ' VP <C 00004 run MLT 330 F JEL 1 lEL ' Varies Strong oxidizers alkalis Sp Gr 1 27 Combustible Solid OVS 2 Toluene; Acetone GC/FPD IV (#5600 Organophosphorus Pesticides! Filter/ lmp(2) none Vis IV (#3500 Formalde hyde] [Also 42541] Filter CH CN HPLC/UVD IV [#5007] Personal protection and sanitation (SeeTable3) Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact Whencontam When wet or contam NR [Rhodium (soluble compounds as Rh)j Skirl Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam When wet or contam Daily ABD00022999 Recommendations forrespirator selection--maximum concentration foruse (MUC) (See Table 4) Health hazards ------------------------------- --------------------------------------------------------------------- -------------------------------------- Route Symptoms First aid Target organs (See Table 5) (See Table 6) (See Table 5) NIOSH/OSHA OOlOmg/m5 HiE'/SA* 0 025 mg/m5 SA CFVPAPRHiE 0 050 mg/m1 HiEF/PAPRTHiE'/ SCBAF/SAF 2 mg/m5 SAF PD PP SCBAF PD PP/SAF PD PP ASCBA escape HiEF/SCBAE Inh Ing Con In animals imteyes, CNS damage Breath Swallow Irrlmmed Water fluah Reap support Medical attention Immed NIOSH 100 mg/m5 CCRQVDMFu/SA 250 mg/m' SA CF/PAPROVDMFu 300 mg/mJ CCRFOVHiE/GMFOVHiE/ PAPRTOVHiE /SCBAF/SAF SC8AF PD PP/SAF PD PP ASC6A escape GMFOVHiE/SCBAE mh Ing Con mammals imteyes chol inhibition liver kidney damage IE Breath Swallow Irnmmed Soap wash prompt Resp support Medical attention immed Eyes liver kidneys blood plasma [Ronnei Skin Eyes Wash skin Remove Change NR NR NR NR NR TBAL In presence of Formaldehyde, Acetaldehyde, or Mafonatdehyde NIOSH SCBAF PD PP/SAF PD.PPAiSCBA Escape GMFOVHiE/SCBAE [Rosin core solder pyrolysis products (as formaldehyde)] Skin Eyes Wash skm Remove Change Prevent skm contact Preventeye contact When contam When wet or contam Daily [Rotenone] NIOSH/OSHA 50 mg/m1 CCROVDMFu/SA 125 mg/m* SA CF/PAPROVDMFu 250 mg/m' CCRFOVHiE/GMFOVHiE/ PAPRTOVHiE/SAT CF/ SCBAF/SAF 2500 mg/m5 SA PD PP SCBAF PD PP/SAF PO PP ASCBA Escape GMFOVHiE/SCBAE Wi Imteyat nose throat, upper rasp sys inn ing Con Imteyes skin resp sys numbmuememb nau vomit abdompain muse tremor mco clonic convuls stupor Breath Itrimmad Reap aupport E)M /aapaya [nasal oncer thyroid gland hamtalnanimaia Onpraaancapf Formaldehyde, Acetaldehyde, or ttalonaldehyde)] !fn Breath Swallow Irnmmed Soap wash prompt Resp support Medical attention mmed Eyes skin resp sys CNS 275 Chemical name, atructura/formula, CAS andRTECSNo* and OOT ID and guide Nos Synonyms, trade names, and conversion factors Roues 1V, 1309-37*1 N0740000Q lron(ill)axide, Iron oxide rad, Rad Iron adds. Red oxide Elemental selenium VS7700000 2656 152 (powder) Selenium fluoride SoF. , _ Silica amorphous Sr03 7631 86-9 W7310000 ' 1 i ppmwrssmstfm3 Diatomaceous earth Diatomaceous silica Dialomite Precipitated amorphous silica Silica get Silicon dioxide (amorphous) Exposure hntts (TWA unless noted otherwise) NOSH Sea Appendix D OSHAt ISmg/rn5 (total) 5mfl(ms (raw) ABD00023000 IDLH Physical description Chemical and physical properties MW BP SOL FI P, IP, Sp Gr flammability VP FRZ UEL LEL NO A fine red powder of feme oxide MW 159 7 BP ? VP-Omm m(.?^2B49*F (Note Usually used Sol Insotubis in cake form or FIP NA UEL NA Impregnated In IP NA LEL NA paper or cloth ] SpGr 5 24 Noncombusbbke Sobd NIOSH /OSHA 0 2 mg/m3 t ma/m3 (asSe) ['Note The RFl and PEL also apply lo other selenium compounds (as Se) except Amorphous or crystalline red to gray solid [Note Occurs as an impurity m most sulfide ores ) MW 79 0 BP 1265F Sol Insoluble FI P NA IP NA VP 0 mm (approx) MLT 392 F UFL NA LEL NA sp Gr 4 23 Combustible Solid NOSH OSHA 0 OS ppm <0.4 mgftn} 2 ppm Colorless gas MW 193 0 BP -30'F Sot insoluble FLP NA JP ? VP* >1 atm FR2 -59'F UEL NA LEL NA RGasO 6 66 Nonflammable Gas NIOSH 6 mg/m5 OSHAt See Appendix C (Mineral Ousts) 3000 ma/m5 Transparent to gray odorless powder [Note Amorphous silica is the non-crystalline form of Si02 ] MW 60 1 BP 4046 F Sol Insoluble FI P NA IP NA VP 0 mm (approx) MLT 3110F UEL NA LEL NA SpGr 2 20 Noncombustible Solid IncompaUbillties and reactivities Measurement method (See Tablel) Calcium hypochtonts carbon monoxide hydrogen peroxide Auds strong oxidizers chromium trioxide potassium bromate cadmium Fitter none, Grav, IV [Particulates NOR #0500 (total) #0600 (rasp)] Filter Acid IV Elements] [Also 11(71 #S190i Water [Note Hydrolyzes very etowty in cold water] None available Fluorine oxygen difluonde chlonne trifluoride Filter LTA XRD IV [#7501] Personal protection (See Table 3) Skin: Eyes: Wash skin ; Remove; Change: N.R. N.R. N.R. N.R. N.R. [Rouge] Skin: Eyes Wash skin Remove Change Provide Prevent skin contact NR When contam When wet or contam NR Quick drench [Selenium] Skin: V&aehskln: Remove: Change: . N.R, N.R. N.R. N.R. [Mankim hexafluoride] Skin Eyes Wash skin Remove. Change: NR N.R. N.R. N R. (Silica, amorphous] ABJD00023001 ----------- Recommendations for respirator selection--maximum concentration for use (MUC) Route Symptoms (Soe Table 4) (See Table 5) T8AL inh Irrit eyes, skin, reap sys Con Health hazards First aid (See Table 6) Eye: Breath: 1 trimmed Fresh air Target organs (See Table 5) Eyes, skin, reap ays NIOSH/OSHA 1 mg/m1 DMA,/DMFu7Hir:F/PAPRDMn*.i PAPRDMPuVSA'/SCBAt- SCBAF PD.PP/SAF PD.PP ASCBA Escape HiEF/SCBAF Inti ing Con Irrit eyes, skin, nose, thioat, vis dist. head chills, tever dysp, bron metallic taste, garlic breath, Gl dist deirrv eye. skin bums, inanimals anemia, liver nec, cirr, kidney, spleen damage Eye Skin Breath Swallow Irr immed Soap wash immed Medical attention blood, spleen 277 NIOSH/OSHA 0.5 ppm: SA 1.26ppm:SA;CF 2 ppm: SAT:CF/SCBAF/SAF ft: $CBAF:PO,PP/SAF:PD.PP:ASCBA Escape: OMF8/SCBAE NIOSH 30 mg/m3 DM 60 mg/m3 DMXSQ/SA 150 mg/m3 SA:CF/PAPRDM 300 mg/m3 HiEF/SAT:CF/PAPRTHlE/ SCBAF/SAF 3000 mg/m3- SA.PD.PP . SCBAF PD.PP/SAF,PD.PP:ASCBA Escape. HiEF/SCBAE Wl in animals: ptilm Irrit, edema / .Braafh: . Rasp support r. . r ; tilt!" -X.'rj ;m.'. *, v! * 'p'ti Inh Irrit eyes, pneumoconiosis Con Eye Irr immed Rasp eye Ilk 3 :<.? ' /' V : i Eyes, retp sys Chemical name structure/formula CAS and RTECS Nos and DOT ID and guide Nos Synonyms trade names and conversion factors (as respirable dust) SiO, 14608-60-7 W7330000 Quartz Tndymite Tripoli 278 Silicon Si 7440 21 3 VW0400000 1346 170 (amorphous powder) Silicon carbide SIC 400-21-2 VW0450000 Elemental silicon [Note Does not occur free in nature but is found in silicon dioxide (silica) & m vanous silicates ] Carbon sltickte, Carborundum^, Silicon monocarbtda Silicon tetrahyOnde SiH, 7803 62 5 VV1400000 2203 116 Monosilane Silane Silicane 1 ppm * 1 31 mg/m3 Exposure limits (TWA unless noted otherwise) Ca See Appendix A 0 05 mg/m3 OSHAT See Appendix C (Mineral Ousts) NIOSH 10 mg/m3 Uotail 5 mg/m (respj OSHAT 15 mg/m3 (total) 5 mg/m3 (resp) NIOSH 10mg/mJ (total). 5mg/m3 SSBif 15mg/m* (total) 5 mg/m1 (rasp) NIOSH 5 ppm (7 mg/m3) OSHAT none ABD00023002 IDLH Physical description Chemical and physical properties n odorless solid (Note A component of many mineral dusts j IDLHs SO mg/m3 (quartz tripoti) 25 mg/m3 (cnstobalite tndymite) MW BP SOL FI P IP Sp Gr flammability BP 4046"F Sol insoluble Fl P NA IP NA VP FRZ UEL LEL VP 0 mm (approx) MLT 31IQ'F UEL NA LEL NA SpGr 2 66 Noncombustible Solid incompatibilities and reactivities Measurement method (See Table 1) fluorine chlonne trifluoride manganese tnoxide oxygen diftuonde hydrogen peroxide etc acetylene ammonia LTA XRD IV [#7500] [Also #7601 #7602] N D Black lo gray MW 28 l JP I) mm Chlorine fluorine Filter lustrous needle BP 4271 F ,approx; oxidizers calcium none like crystals Sol Insoluble MLT 257U F cesium carbide Grav [Note The amorphous form is a dark Drown H P NA IP NA UEL NA LEL NA MEC 160 g/m3 alkaline carbonates IV [Particulates NOR powder] #0500 (totalj SpGr 2 33 #0600 Combustible Solid in powder form (resp)] NO Yellow to green to MW 40 1 VP 0 mm None reported Filter, bluish-black BP Sublimes (approx) [Note Sublimes with none, Iridescent Sol Insoluble fciLT 4892'F decomposition at Grav crystals Fl P NA (Sublimes) 4892'F 1 IV IP 9 30eV UEL NA [Particulates LEL NA NOR #0500 (total) SpGr 3 23 *0600 Noncombusbble Solid (resp)] N D Colorless gas with MW 32 1 VP >i atm Halogens (bromine None a repulsive odor BP 169 F FRZ 301 F chlorine carbonyl available Sol Decomposes UEL i chloride antimony Fl P NA (Gas) LEL ? pentachlonde tin(lV) IP 7 chlonde) water RGasD 1 11 Flammable Gas (may ignite SPONTANEOUSLY m air) Personal protection and sanitation (See Table 3) Skm Eyes Wash skin Remove Change NR NR NR NR NR (Silica crystalline (as respirable dust)] Skin Eyes Wash skin Change NR Prevent eye contact NR NR NR [Silicon] Start. Wash skin Remove Change NR NR NR NR NR [Silicon carbide] Skm Eyes Wash skin Remove Change NR NR NR NR NR [Silicon tetrahydndel ABD00023003 Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table 4) NIOSH 0 5 mg/m1 HiE 1 25 mg/m* PAPRHiE/SACF 2 5 mg/m1 HiEF/PAPRTHIE 25 mg/m1 SA.PD PP SCBAF PD PP/SAF PD PP ASCBA Escape HIEF/SC8AE Route Symptoms {See Table 5) Sr Con Cough dysp, wheez, deer pulm func, progressive resp symptoms (silicosis) Health hazards First aid (See Table 6) Eye Breath Irrimmed Fresh air imt eyes, (care] Target organs (See Tables) Eyes, resp sys [in animals lung cancer] TBAl Inh Ing Con Imt eyes skm upper resp sys cough Eye Breath Swallow Irr immed Fresh air Medical attention immd Eyes skm resp sys 279 TBAL Hi Imt eyes, skin upper rap aye, cough Con Breath. Swallow Irrimmed Freeh air Madfcal attention immed Eyes, skin, reepsy* TBAL Inh Irnteyes skm muememb nau head Breath Resp support Eyes skm resp sys CNS Chemical name structure/formula CAS andRTECSNos and OOT ID and guide Nos Silver (metal duat and soluble compounds as Ag) Ag (Metal) 7440-22-4 (Metal) VW3500000 (Metal) Soapstone (containing less than * % quartz1 3MgO 4SiO H 0 VV8'80C00 Sodium aluminum fluoride (as F) N*jAIF# 15096-52-3 WA662S000 Sodium azide NaN, 25628 22 8 '68? 153 Synonyms trade names, and conversion factors Silver metal Argentum Synonyms of soluble silver compounds such as Silver nitrate (AoNQ,) vaxv depending upon the specific compound Massive talc Soapstone silicate Steatite Cryocide Cryodust Cryolite, Sodium hexafluoroaluminate Azide Azium Sodium salt of hydrazoic acid Exposure limits (TWA unless noted otherwise) ABD00023004 IDLH Physical description NIOSH/OSHA 0 01 mg/m3 10 mg/m3 (as Ag) Metal White lustrous solid NIOBH b mg/rn3 (total) 3 mg/m (cespi OSHAT 20 mppcf 3000 mg/m3 Odorless white gray powder NtOSH'/OSHA* 2 5 mg/m3 260 mg/m3 (as F) (Note The REL and PEL also apply to other inorganic, sow fluorides (as F) j Colorless to dark odorless solid [pesticide! (Note Loses color on heating] NIOSH C 0 1 ppm (as HN,) [skin) COS mg/mJ (as NaN,) [skin] OSHAT none ND Colorless to white odorless crystalline solid [pesticide) [Note Forms hydrazoic acid (HN,; in water] Chemical and physical properties MW BP SOL FI P IP Sp,Gr, flammability VP FRZ UEL lel Incompatibilities and reactivities MW 1079 BP 3632*F Sol Insoluble FlP NA IP NA VP Omm (approx) MLT 1761'F UEL NA LEL NA Acetylene ammonia hydrogen peroxide, bromoazide, chlonne trifluoride ethylenaimlne oxalic acid tartanc acid SpGr 1049 (Metal) Metal Noncombustible Solid, but flammable in form of dust or powder Measurement method (See Table 1) Filter Acid ICP IV [#7300, Elements] MW J79 j BP ' Sol Insoluble PI P NA IP NA /P 0 min (approx) Ml T 7 UEL NA LEL NA SpGr 2 7 2 8 Noncombuslible Solid None reported Filter none Grav IV [#0500 Particulates NOR (total)] MW 209 9 BP Decomposes Sol 0 04% FI P NA IP NA VP Omm (approx) MLT 1632T UEL NA LEL NA Strong oxidizers SpGr 2 90 Noncombustible Solid Filter NaOH ISE IV [#7902, Fluorides] MW 65 0 BP Decomposes Sol(63 F) 42% FI P 7 IP 11 70eV VP 7 MLT 527'F (Decomposes) UEL " LEL 7 Sp Gr 1 85 Combustible Solid pf heated above 572 F, Si gel NaHCOy Na,CO, IC/UV VIS CSHA (#10121) Personal protection and sanitation (See Table 3) SWn Wash skin Remove. Change Provide Prevent skin contact Prevent eye contact When content When wet or content (AgNO^) Daily Eyewash ABD00023005 Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table 4) Route Symptoms (See Table 5| NIOSH/OSHA 0 26 mg/m* SA.CPVPAPRHiE 0 S mg/rrt* HiEF/SCBAF/SAF 10 mom* SAF PD.PP $ SCBAF PD.PP/SAF PD PPASCBA Escape HEF/SCBAE W* Blue-gray eyes nasal Ing septum, throat skJn Con imt ulcerabon skin Gl diet Health hazards First aid (See Table 6) IS Breath Swallow- Irrimmad Water flush Reap support Medcel attention immed Target organs (See Table 5) Nasal septum, skin eyas [Silver (metal dust and soluble compounds as Ag)] Skin Eyes Wash Skin Remove Change No NR NR NR NR (Soapstone (containing less than 1% quartz)] NlOSH 30 mg/m5 DM 60 mg/m5 DMXSQ/SA 150 mg/m5 PAPRDM 300 mg/m5 HiEF/SAT CF /PAPRTHiE / SCBAF/SAF 3000 mg/m5 SAF PD PP SCBAF PD PP/SAF PD PP ASCBA Escape HiEF/SCBAE Skin. ^CheWn: Ffrmovw Change: Prevent skin oontact Prevent eye contact Whencontam Whan w or contam Daily [SodumeJuminum fluoride (ea Ffl NIOSH/OSHA 12.9 maftn*- DM 25 rag?n> OMXSQVSA* 62.9 ma/m* SA.'CFVPAPRDM** 126 mg/m* HIEF+/SCBAF/SAF 250 rngYn* SAF-PD.PP | SC&f PD.PP/SAF POPPASCBA Eeeepa. HIEF+/8CBAE Note- May need add gas sorbent Skin Eyes Wash skm Remove Change Provide Prevent skin contact Prevent eye contact Whencontam When wet or contam Daily Eyewash Quick drench TBAl mn Con Pneumoconiosis cough dysp digital ciubbmg cyan basal crackles cor pulmonale M Irrtt ayes, rasp sys, Jnfl nau, abdont pain, diarr Con aalv, mist, sweat; stiff spine, damt. calcMcaiion of ligaments cf rt, peMe inh ADs Ing Con Irnt eyes skin head dizz weak blurred vision dysp low BP bradycardia kidney changes Eye Breath trr immed Resp support Resp sys CVS IE, Breath Swallow- trr immed Sa^waeh prompt Medical abandon knmad Eyes, skin, resp sy*. CNS skeleton, kidney* Eye Skin Breath Swallow irr immed Water flush immed Resp support Medical attention immed Eyes skin CNS CVS kidneys (Sodium azide] Chemical name, structure/formula CAS and RTECSNos, and DOT ID and guide Nos Synonyms, trade names and conversion factors Sodium bisulfite NaHSO, 7831*90-5 V22000000 Monosodium salt of tulfuroua add, Sodium acid bisulfite Sodium bisulphite, Sodium hydrogen sulfite 282 2883 154 (solution) Sodium cyanide (as CN) NaCN 143 33 9 VZ7530000 1689 157 Sodium fluoride (as F) NeF 7981-40-4 WB0360000 Sodium salt of hydrocyanic acid FloridIno, Sodium raonofluoride 1890 154 Sodium fluoroacetate FCH.COONa 62 74 8 AH9100000 SFA Sodium monofluoroacetate 2629 151 Exposure limits (TWA unless noted otherwise) NIOSH 5 mg/m5 OSHAt none ABD00023006 IDLH Physical description ND White crystals or powder with a slight odor of sulfur dioxide Chemical and physical properties MW BP, SOL FI P.IP.Sp, Gr flammability VP, FRZ UEL LEL MW-1041 BP Decomposes Sol 29% FIP NA IP NA VP 7 MLT Decomposes UEL NA LEL NA SpQr 148 Noncombustible Solid Incompatibilities and Measurement method (See Tablet) Heat (decomposes) [Note Slowly oxkteed to the sulfate on exposure to air ] Filter none, Grav IV (#0500, Particulates NOR (total)] NIOSH C 5 mg/m5 25 mg/m5 (as CN) [10 mm] OSHA 5 mq/m3 ['Note The REL and PEL also apply to other cyanides (as CN) except Hydrogen cyanide ] White granular or crystalline solid wrth a faint almond-like odor MW 49 0 VP 0 mm Strong oxidizers Filter/Bub BP 2725 F (approx) (such as acids acid KOH Sol(77'F) 58% MLT 1047'F salts chlorates & ISE FI P NA UEL NA nitrates) IV IP NA LEL NA [Note Absorbs moisture[#7904 from the air forming Cyanides) a syrup ] [Also Sp Gr 1 60 #6010 Noncombustible Solid but contact with acids Hydrogen releases highly flammable hydrogen cyanide Cyanide ] NI08H/08HA 2 5 mg/m* 29? mgmr (F) [Not. TheRElandPELelw OH IHIOnMl oWocMmtwm*!, wiriniHtv my* * v powder or ooioriM* BP: 30*F crystal* Sor.4% Ipwtteide} ?IP* NA {Note Ptttgtt* - 'fP-NA grads is often dyid M] t VP^Oiimv UELNA LELNA ~Sp43r2.ft t .NoncomWatlWp-eollcl Strong oxidizer* PadVprsFBac 1 NeQH; iML JV 1*7802. (Mao, NIOSH 0 05 mg/m5 ST 0 15 mg/m3 [skin] OSHAT 0 05 mg/m5 [skin) 2 5 mg/m3 Fluffy colorless to white (sometimes dyed black) odorless powder [rodenticide] [Note A liquid above 95lF ] MW 100 0 BP Decomposes Sot Miscible FI P NA IP ' VP Low MIT 392 F UEL NA LEL NA SpGr ? Noncombustible Solid None reported Filter Water 1C 11(5) j#S301] Personal protection and sanitation (See Table 3) Skin Eyes Wash skin Remove Change NR NR NR NR NR [Sodium bisulfite] Sum F/es v\ash ski" Re* 'd .e ,,ia'ge Provoe Drevent sk n ccntac' Prevent e>e v-oniac' A'-'e1' ;ontarr Af e~ _r,,cnian Do , E,e*as- Oj ck d e ic iSodium cyanide ,as CN)] Skin v)ashkin Remove Change Prevent skin contact Prevent eye contact When contam When wet or contam Daily [Sodium fluoride (as F)] Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet or contam Daily Quick drench [Sodium fluoroacetate) ABD00023007 Recommendations forrespirator concentration for use (MUC) (See Table 4) TBAL Route Symptoms (See Table 5) Inh Ing Con irnteyes skin mucmemb Health hazards Fmstaid (See Table 6) Eye Breath Swallow Irr immed Fresh air Medical attention Immed Target organs (See Table S) Eyes, skin resp ays MOSH Oi,HA 2b mg m SA/SCBAR SC6-F PD PP SAF PD PP ASCBA Cscape IWFSH E SCBAE inn Acs irg Con ir-ii eyes skin asphy wear. neaa cont na^ orrn' nci esp rate ,,0* gasping resp ratior i ly 01C blood cnanges Eye Skn Breat Swa'ov. irr immed Soap wash immeo Resp support Medical attentior immec Eyes Skin CVS CNS thyroid blood 283 NIOSH/OSHA 12 5 mg/m3- DM 25 mg/m3 DMXSQVSA* 62 5 mg/m3 SA CF*/PAPRDM`+ 125 mg/m3- HrEF+ZSCBAF/SAF 250 mg/m3 SAF PD PP SCBAF PD PP/SAF PD PP ASCBA Escape H1EF+/SCBAE Note May need add gas sorbent NIOSH/OSHA 0 25 mg/m3 DM 0 5 mg/m3 DMXSQ/SA 1 25 mg/m3 SA CF/PAPRDM 2 5 mg/m3 HiEF/SAT CF/PAPRTHiE/ SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape HiEF/SCBAE Ift! Ing Con Irriteyes respsys rtau abdom pain dlarr salv thirst sweat, stiff spine derm calcification of ligaments of ribs pelvis Inh Abs Ing Con Vomit appre auditory halu facial pares twitch face muse pulsus altenans ectopic heartbeat tacar venfib pulm edema nystagmus convuls liver kidney damage Eye Skm Breath Swallow Irr immed Soap waeh prompt Fresh air Medical attention Immed Eyes, skm, reap eye, CNS, skeleton kidneys Eye Skin Breath Swallow Irr immed Water flush immed Resp support Medical attention immed Resp sys CVS liver kidneys CNS Chemical name structure/formula CAS and RTECS Noe. and DOT ID and guide Nos Synonyms trade names and conversion factors Sodium hydroxide NaOH 1310-73-2 WB4900000 284 1623 154 (solid) 1824 154 (soiuOon) Sodium meiabisulfite Na,S,Os 7681 57-4 UX8225000 Caustic soda Soda lye Sodium hydrate Disod ium pyrosulfite Sodium melabisulphite Sodium pyrosulfite KVWs 9005-25-6 GM5090000 Com starch Rtce starch Sorghum gum, a-Stareh Starch gum Tapioca starch Stibme SbH3 7803 52 3 WJ0700000 2676 i IS Antimony nydride Antimony tnhydnde Hydrogen antimomde 1 ppm = 5 10 mgymJ Exposure limits (TWA unless noted otherwise) NiOSH C 2 mg/m3 OSHAf 2 mgfm3 NIOSH 5 mg/mJ OSHAt none NIOSH 10ma/m3 (totaT) 5 rngAn5 (reap) OSHA ISmg/m3 (total) 5 mg/m3 (reap) NIOSH/OSHA 0 1 ppm (0 b mg/m3) ABD00023008 IDUH Physical description 10 mg/m3 Colorless to white odorless solid (flakes Mads granular form) Chemical and physical properties MW, BP, SOL FI P IP Sp, Gr, flammability VP, FRZ UEL, LEL Incompatibilities and reactivities MW 40 0 VP 0 mm Water acids BP 2534`F (approx) flammable liquids Sc111% MIT 605*F organic halogens FI P NA UEL NA metals such as IP NA LEL NA aluminum tin & zoic nitromethane Sp Gr 2 '3 [Note Corrosive to Noncombustrble !Solid but metals ] when in contact with water may generate sufficient heat to ignite combusfcble materials Measurement method (See Table 1) Filter HCI Tltrale IV [#7401 Alkaline Duata] NO White to yellowish MW 190 1 VP 7 Heat decomposes) Filler crystals or powder BP Decomposes MIT >302 F [Note Slowly oxidized none with an odor of sulfur dioxide Soi 54% FI P NA IP NA (Decomposes) UEL NA LEL NA to the sulfate on exposure to air & moisture ] Grav IV (#0500 Particulates NOR (total)] Sp Gr 14 Noncombustible Solid ND Fine white odor- MW varies VP 0 mm Oxidizers acids Filter less powder BP Decomposes iodine alkalis none, (Note A carbohy- Sol Insoluble Grav drate polymer FIP NA Decomposes IV composed of 25% IP NA UEL NA [Particulates amytoee&75% LEL NA NOR amylpectln ] MEC 50 g/m3 #0500 Sp Gr 1 45 (total) Noncombustible Solid, but may form ilroeoo explosive mixture with air (reap)] 5 ppm Colorless gas with a disagreeable odor like hydrogen sulfide MW 124 8 BP 1 F Sol Slight FI P NA (Gas) IP 9 51 eV VP >1 atm FRZ I26F UEL ' LEL ' Acids halogenated hydrocarbons oxidizers moisture chlonne ozone ammonia Si gel HCI Vis IV [#6008] RGasD 4 31 Hammaoie Gas Personal protection and sanitation (See Table 3) Skm Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact Whencontam When wet or oontam Daily Eyewash Quick drench [Sodium hydroxide] $K.n Eyes Wash skir Remove Change Nu NR Nr N i< NR [Sodium metabiSuifite] SWn Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact Daily When wet or contam Daily [Starch] Skin Eyes Wash skin Remove Change NR NR NR NR NR [Stibine] ABD00023009 Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table 4) NIOSH/OSHA tOmg/nv1 SA CFE/HiEF/PAPRDWr/ SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape HiEF/SCBAE Route Symptoms (See Table 5) Hi mg Con Imteyes skin mucmemb pneuitis eye skin bums temporary loss of hair Health hazards First aid (See Table 6) Target organs (See Table 5) Breeth Swallow Irr immed Water flush immed Resp support Medical attention immed Eyes skm resp sys 'BA inr iint eyes skin mucmemr og Cor 'ye Breath SwaiiOw Irr m ned F'esn air Medicai attention immed E,es ski esp sys TBAL mh Ing Con Imteyes sktn mucmemb cough chest pain derm rhln IS Breath Swallow Irr immed Soap wash Fresh air Medical attention immed Eyes skin resp sys NlOSH/OSHA 1 ppm SA 2 5 ppm SA CF 5 ppm SAT CF/SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFS/SC8AE Inr Head weak nau abdom pain lumbar pain hemog hema hemolytic anemia ]aun pulm irrit Breath Resp support Blood iwer kidneys resp sys Chemical name structure/formuia CAS ana RTECS Nos and DOT ID ana guide Nos Synonyms, rade names and conversion factors Stoddard solvent 286 8052-41-3 WJ8925000 1268 126 (petroleum distillate) Strychnine C,,H.,N,0, 57 24 9 WL2275000 Dry cleaning safety solvent Mineral spints Petroleum solvent Spotting naphtha [Note A refined petroleum solvent with a flash point of 102-110"F boiling point of 309 396'F and containing >65% C ,, or higher hydrocarbons ] Nux vomica Strynchnos 1692 151 Stpene C^jCH-CHj 100-42-6 WL3676000 Etheny) benzene Phen^efiiyiene Styrene monomer Styrof Vinyl benzene 2055 128 (inhibited) 1 ppm 4 26 mg/m9 Subtilisms 1395-21 7 (BPN) 9014-01 1 (Carlsburo) C09450000 (BPN) C09550000 (Carlsburg) Bacillus subtilis Bacillus suOtilis BPN Bacillus sublilis Cansburg Proteofytic enzymes Subtilisin BPN Subtilisin Carlsburg [Note Commercial proteolytic enzymes are used m laundry detergents ] Exposure limits (TWA unless noted otherwise) ABD00023010 IDLH Physical dtsi riptioil NIOSH 350 mg/m3 C 1800 mg/m3 [15-mm] OSHAt 500 ppm (2900 mg/m5) 20 000 mg/m3 Colorless liquid with a kerosene Ike odor NlOShi/OSHA 0 15 mg/m3 3 mgmi3 Colorless to white odorless crystalline solid [pesticide] Chemical und physical properties MW BP SOL FI P, IP, Sp Gr flammability VP FRZ UEL LEL MW Varies BP 309 396*F Sol Insoluble FI P 102 110'F iP 7 VP 7 FRZ 7 UEL 7 LEL 7 Sp Gr 0 76 Class II Combustible Liquid MW 334 4 BP Decomposes Sol 0 02% HP' IP 3 VP Low MLT 514 F UEL 7 LEL 7 Inuomputibilities jnd reactivities Measurement method (See Table 11 Strong oxidizers Char GC?FID IV [#1550 Naphthas] Strong oxidizers Filter Reagent HPLC/UVD IV [#5016] NIOSH 700 ppm SO ppm (215 mg/m5) ST 100 ppm (425 malm3) OSHAt 100 ppm C 200 ppm 600 ppm (S-mln max peak in any 3 hrs) NIOSH ND ST 0 00006 mg/m3 [60 min] OSHAt none Colorless to yellow oily liquid with a sweet, floral odor Light colored free flowing powders [Note A protein containing numerous ammo acids ] Sp Gr 1 36 Combustible Solid but difficult to ignite MW 1042 BP 293`F Sol 0 03% FI P 88'F IP 8 40 eV VP 5 mm FRZ 23"F UEL 6 8% LEL 0 9% Sp Gr 0 91 Class 1C Flammable Liquid Oxidizers catalysts for vinyl polymers Char cs,, peroxides strong GC7FID acids aluminum IV chloride *1501, [Note May polymerize Aromatic tf contaminated or Hydro- subjected to heat carbons] Usually contains an inhibitor such as tert-butylcatechoi ] MW 26 000 (approx) BP 7 Sol 7 FI P NA IP NA VP 0 mm MLT 7 UEL NA LEL NA None reported None available Sp Gr 7 Personal protection (See Table 3) Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam When wet or contam NR (Stoddard solvent] Skm Eyes Wash skm Remove Change Prevent skin contact NR When contam NR Da y 'Strychnine' Skm Wash skin Reowe Change Prevent skin contact Prevent eye contact Wien contam When wet Itontm] NR (Styrene] Skin Eyes Wash skm Remove Change Prevent skin contact Prevent eye contact When contam When wet or contam Daily [Subtihsms] ABD00023011 Recommendations for respirator concentration for use (MUC) (See Table 4) NKDSH 3500 mg/m1 CCROV'/SA 8750 mg/m} SA CFVPAPROV 17 SOOmg/m1 CCRFOV/GMFOV/ PAPRTOV'/SCBAF/SAF 20 000 mg/m1 SAF PD PP SCBAFPD PP/SAF PD PPASCBA Escape GMFOV/SCBAE Route Symptoms (See table 5) inh ing Con Imt eyes nose threat dizz derm chemical pneu (asplr liq) in animals kidneydamage NiOSH/OSHA 0 75 mg/m3 DM 1 5 mg/mJ DMXSQ/SA 3 mg/m1 SA CF/PAPRDM/HiEF/ SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA (escape HiEF'SCBAE Inh Ing Con Stiff neck facial muse restless appre incr acuity of perception mcr reflex excitability cyan tetanic eonvuis with opisthotonos Health hazards First aid (See Table 6) Target organs (See Table 5) & Breath Swallow Irr immad Soap wash prompt Reso support Medical attention immad Eyes, skm resp sys CNS, kidneys Eye Skin Breath Swallow Irr immed Soap wash prompt Resp support Medical attention immed CNS 287 NIOSH 500 ppm CCROV'/SA* 700 ppm SA-CF'/CCRFOV/GMFOV/ PAPROV/SCBAF/SAF f SCBAF PD PP/SAF PD,PPASCBA Escape GMFOV/SCBAE Inh Irrit eyee, note, reap eye Abe head, fig, dirz, com mal ing drew, vmk, unsteady gait, Con narco, defattng darm, poesnie Ihwr rapro affects TBAL Inh Ing Con imt eyes skin resp sys, resp sens (enzyme asthma) sweat head chest pam flu like symptoms cough breathlessness wheez Breath Swallow Irr immad Water flush Resp support Medical attention immed Eyes, akh, rasp ays, CNS. Over, rapro aye * Eye Skin Breath Swallow Irr immed Soap wash Resp support Medical attention immed Eyes skin resp sys Chemical nima CAS and RTECSNos guide Nos Synonyms trade names and conversion factors Succinomtnle NCCH.CHXN 11061-2 WN3850000 Butanedimtnle 1 2-Dicyanoethane Ethylene cyanide Ethylene dlcyenlde Succinic dlnitnle 288 5/ 50 1 WN650000C 1 ppm 3 28 mg/mJ Beet sugar Cane sugar Granulated sugar Rock candy Saccarose Sugar Table sugar SOj 7446-09-5 WS4550000 1079 125 Sulfur hexafluoride 5F6 2551 62 4 WS4900000 1080 126 Sulfurous acid anhydride Sulfuroue oxide Sulfur oxide 1 ppm * 2 62 mg/m3 Sulfur fluoride [Note May contain higniy toxic sulfur penlafluonde as an impurity j 1 ppm = 5 98 mg/m3 Exposure limits (TWA unless noted otherwise! NIOSH 6 ppm (20 mg/m3) OSHA none NIOSH 1 u mg n itotal mg/m-* OSHA 1 5 mgmJ i total / 5 mg/m i resp NIOSH 2 ppm (5 mo/m3) ST 5 ppm (13 mg/m3) OSHAf 5 ppm (iSmg/m3) NIOSH/OSHA '000 ppm (6000 mg/m3) ABD00023012 IDLH Physical description NO Colorless waxy solid [Note Forms cyanide in the body] Chemical and physical properties MW BP SOL FI P IP Sp Or flammability VP FRZ UEL LEL MW 801 BP $09`F Sol 13% FI P 270*F IP 7 VP(212*F) 2mm MLT 134*F UEL ? LEL ? ND 100 ppm N0 SpGr 0 99 Combustible Sohd Ha'O Afi e odor ess v-rystals urnps or powder Note May have a characteristic ca a"(i odor when healed ] MW 342 3 VP 0 mm BP Decomposes .appro* 1 Fi P NA (Decomposes IP NA Utl NA LEL NA MEC 45 g/mJ SpGr 1 59 NoncomDustibie Solid but fine airborne dust may explode Colorless gas with a charactenstic irritating pungent odor (Note A liquid below 14'F Shipped as a liquefied compressed gee] MW 64 1 BP 14*F Sd 10% FIP NA IP 12 30 eV VP 3 2 atm FRZ -104*F UEL NA LEL NA RGesD 2 26 Nonflammable Gee Colorless odorless gas [Note Shipped as a liquefied compressed gas Condenses directly to a solid upon cooling ] MW 146 i BP Sublimes Sol(77 F) 0 003% FI P NA IP 19 30 eV VP 21 5 atm FRZ 83 F (Sublimes) UEL NA LEL NA RGasD 5 11 Nonflammable Gas Incompatibilities and reactivities Measurement method |See Table 1) Oxidizers Char Toluene GC/FID NIOSH Cnt Doc Oxidizers sulfuric acid nrtnc acid Filer none Grav IV [Pamcuiates #C50G (total) #0600 (resp)] Powdered alkali Fitter/pad metals(suchas sodium & potassium), NaHCOV n^co; water ammonia zinc IC aluminum brass copper IV [Note Reacts with [*6004] water to form sulfurous aod (HjSOj) ] Disilane Bag none GC portable IV [#6602] Personal protection and sanitation (See Table 3) SWn Eyes. Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contsm When wet or contam Daily Eyewash [Succinonitriie] Skin Eyes Wash skin Remove Change NR NR NR NR NR [Sucrose] SMn. Eyes: Washakkr Remove Change Provide frostbite Frostbite NR. When wet or contam (liq) NR Frostbite (Suitor dioxide] Skin Eyes Wash skin Remove Change Provide Frostbite Frostbite NR NR NR Frostbite [Sulfur hexafluoride] ABD00023013 Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table 4) NIOSH 60 ppm SA 150 ppm SACF 250 ppm SCBAF/SAF SCBAF PD.PP/SAF PD.PPASCBA Escape GMFOV/SCBAE Route Symptoms (See Table 5) Inh Abs log Con Irnteyes skin respsys. head dizz weak gidd conf convuls biurred vision, dysp abdom pain nau vomit Health hazards First aid (See Table 6) . Breath Swallow Irr unmed Medical attention immed Target organs (See Table 5) Eyes, skat, respsys, CNS CVS TBAL frV* Irnteyes Skin upper Con resc sys cough Eye Breath irr mimed Fresh air Eyes respsys 289 NIOSH 20 ppm CCRSVSA* 50 ppm SA.CF*/PAPRS* lOOppm CCRFS/GMFS/PAPRTS*/ SAT CFVSCBAF/SAF SC8AF PD.PP/SAF PD.PP-A8C0A Escape GMFS/SCBAE Wl Irriteyes, nose throat Con rhm choking cough reflex bronchoconstrtctton lig frostbite Is, Breath Frostbite Rasp support Eyas skin, rasp sys TBAL inn Asphy mcr breath rate pulse rate slight muse nco emotional upset ftg nau vomrt convuis Eye Skin Breath Frostbite Frostbite Resp support Reso sys Chemical name, structure/formula CAS and RTECSNos , and DOT ID and guide Nos Synonyms, trade names, and conversion factors 290 Sulfunc add w 7684-93-9 wsseooooo 1630 137 1631 137(fuming) 1832 137 (spent) Sulfur monoehlonde SjCl* 10025 67 9 WS4300000 Battery acid Hydrogen sulfate Oil of vitriol Sulfunc sad (aqueous) Sulfur chlonde Sulfur subchlonde Thiosulfurous dichloride 1828 137 Sulfur pentafluoride s/ia 5714-22-7 WS4460000 1 ppm = 5 52 mg/m3 Dfaulfur decafluoride Suffur tetrafluonde sf4 7783 60 0 WT4800000 1 ppm*10 39mg/m5 Tetrafluorosulfurane 2418 125 1 ppm = 4 42 mg/m1 Exposure limits (TWA unless noted otherwise) NIOSH/OSHA 1 mg/m3 NIOSH C 1 ppm OSHAt 1 ppm (6 mg/m1) NIOSH C 0 01 DDm (01 mg/m5) OSHAt 0 025 pp (0 25 mg/m5) NIOSH C 0 1 ppm (0 4 mg/m3) OSHAT none ABD00023014 IDLH 15mg/ms 5 ppm Physical description Colorless to daftbrown oily odorless liquid [Note Pure compound Is a solid below 51'F Often used in an aqueous solution ] Light-amber to yellow red oily liquid with a pungent nauseating irritating odor Chemical and physical properties MW BP SOL FI P IP, Sp, Gr flammability VP FRZ UEL, LEL MW 98 1 BP 564*F Sol Miscible FI P NA IP ? VP 0 001 mm FRZ. 51*F UEL NA LEL NA Sp Or 1 84 (96-98% acid) Noncombusobie Liquid, capable of igniting finely divided combustible mstatists MW 135 0 BP 280F Sol Decomposes FI P 245F IP 9 40 eV VP 7 mm FRZ 1Q7'F UEL n LEL ? 1 Ppm ND Sp Gr 1 68 Class 111B Combustible Liquid Colorless liquid or gas (above ee'Fjwtthan odor tike sulfur dioxide MW- 254 1 BP 84*F Sot Insoluble RP NA IP 7 VP 561 mm FRZ -134*F UEL NA LEL NA SpGrf32*F) 2 08 RGasD8 77 Noncombustible Liquid Nonflammable Gas Colorless gas with an odor like sulfur dioxide [Note Shipped as a liquefied compressed gas ] MW 108 1 BP -41 F Sol Reacts FI P NA IP 12 63 eV VP(70*F) 10 5 atm FRZ 185 F UEL NA LEL NA RGasD 3 78 Nonflammable Gas Incompatibilities and reactivities Measurement method (See Table 1) Organic materials, chlorates carbides fulminates, water powdered metals [Note Reacts violently with water with evolution of heat Corrosive to metals) Si Ml, NaHCOy NijCCL, IC^ 3 IV (#7903, Inorganic Acids] Peroxides oxides None of phosphorous available organics water [Note Decomposes violently in water to form hydrochloric acid sulfur dioxide sulfur sulfite thiosulfate and hydrogen sulfide Corrosive to metals] None reported None available Moisture concentrated sulfuric acid dioxygen difluoride (Note Readily hydrolyzed by moisture forming hydrofluoric acid & thionyl fluonde j Bub NaOH IC OSHA [#IDlt0] Personal protfction and sanitation (See Table 3) Skm Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contarn When wet or contam NR Eyewash(>l%) Quickdrench (>1%) [Sulfunc acid] Skm Eyes Wash skin Remove Change Provide Prevent sk n contact Prevent eye contact When contam When wet or contam NR Evewash Quick drench [Sulfur monochlonde] SMrr wXEheWn. Remove; CIMK pww Prevent ekin oontect Prevent eye contact NR When wet or contam HR. Eyewash,Qutefc drench [Sulfur pentefluoride] Skin Eves Wash skm Remove Change Provide Frostbite Frostbite NR NR Frostbite [Sulfur tetrafluonde] ABD00023015 Recommendations for lespirator selection -- maximum concentration for use (MUC i (See Table 4j NIOSH/OSHA 15 mg/m3 SA CF/PAPRAGHiE/ CCRFAGH1E/GMFAGH1E/ SC9AF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFAGHiE/SCBAE Route ------- ----------- --- Symptoms (See Table 5) Inh Ing Con Imteyes skm nose tnroat pulm edema bron emphy conj stomatis, dental erosion trachbronc eye skm burns derm Health hazards ---------- -------- First aid (See Table S) Eye Skin Breath Swallow Irrimmed Water flush immed Resp support Medical attention immed Target organs (See Table 5) Eyes skin resp sys teeth NIOSH/OSHA 5 ppm ccrfs/gmfs/paprs/ SC8AF/SAF SCBAF PD PP'SAF PD PP ASCBA Escape GMFS/SC8AE Irth irnteyes skm mucmemb Ing lac cough eye skin bums Cor pulm edema Eye Skin Breath Swallow Irrimmed Water flush immed Resp support Medical attention immec Eyes skin resp sys NIOSH 01 ppm SA 0.25 ppm SACF 0 5 ppm SAT CF/SCBAF/SAF 1 ppm SA.PD PP 5 SCBAF PD F'P/SAF PD PPASCBA Escape GMFAG/SCBAE Inh trrit eyes, skin, resp sys, Ing In animals pulm edema Con hemorr SSl Breath Swallow Irrimmed Soap wash Immed Resp support Medical attention immed Ej'M.ekin, respeye, TBAL Inh Con Irnteyes mucmemb eye skin burns (from SF^ releasing hydrofluoric acid on exposure to moisture) liq frostbite mammals dysp weak rtnn Eye Skin Breath Frostbite Frostbite Resp support Chemical name structure/formula CAS and RTECS Nos and DOT ID and guide Nos Synonyms, trade names and conversion factors Sulfuryl fluoride so3f3 2690-79 8 WT507600Q Sulfur difluonde dioxide Vikane 292 2191 123 Sulprofos C, m sO Pv 36400 4.1 < TE4165000 1 ppm=418mg/m3 Boistari O Ethyl O (4 methylthio) phenyl S propyl phosphorodithioate Exposu'o limits (TWA unless noted otherwise) NIOSH 5 ppm 120 mg/m3) ST 10 ppm (40 mg/m3) OSHAt 5ppm (20 mg/m3) NIOSH 1 mg/m3 OShAf none 2,4 5-T CljCgHjOCHjCOOH 93-76-5 AJ 8400000 ppm = 13 iS'rigjT 2 4 5-Trtchlorophenoxyacetic acid NtOSH/OSHA lOmgttn3 ABD00023016 IDLH 200 ppm Physical description Chemical and physical properties MW BP SOL FI P, IP, Sp Gr, flammability VP FRZ UEL LEL Colorless odorless gas (insecticide/ `umigant] [Note Shipped as a liquefied compressed gas) MW 1021 BP -68*F Sol(32`F) 02% FI P NA IP 13 04eV VP(70F) 15 8alm FRZ -212*F UEL NA LEL NA RGasD 3 72 Nonflammable Gas NU Fan-coloied liquid MW 324 5 VP <8 mm with 3 sulfide like BP / FRZ - odor Sol Low UEL ? FI P ' LEL ' IP 3 250 mg/m5 Colorless to tan odortass crystalline solid, (herbicide} Sp G 1 20 MW 255 5 BP Decompoees SoK77*F) 0 03% FI P 7 IP ? VP e-rxio* irm MLT 307*F UEL ? LEL ? Incompahbillties and reactivities Norte reported Nom eported None reported Measurement method (See Table 1) Char NaOH 1C Iv [*6012] OVS 2 Toluene/ Acetone GC/F-PO IV [#5660 Organo phosphorus Pesticides] Fitter Methanol; HPLC/UVO IV [5001] 2755 152 Talc (containing no asbestos and less than 1% quartz; Mg3Si<0,,(0H)j 14807 96-6 WW2710000 Hydrous magnesium silicate Steatite talc NIOSH 2 mg/m3 resp) OSHAT 20 mppcf 1000 mg/m3 Odorless white powder Combustible Sottct, but bums with cUfflcutty MW Vanes Sol Insoluble FIP NA IP NA VP 0 mm (approx) MLT 1652 1832 F UEL NA LEL NA None reported Sp Gr 2 70-2 80 Noncombustible Solid Filter LTA XRD III (P&CAM #355] Personal protection (See Table 3) 9tan Eyes Washakin Remove Chfnge Provide- Frostbite Frostbite NR NR. NR. Frostbite ABD00023017 Recommendations for respirator concentration for use (MUC) (See Table 4) NIOSH/OSHA 50 ppm SA* 125 ppm SA.CF* 200 ppm SCBAF/SAF SCBAF PD,PP/SAF PO, PP ASCBA Escape GMFS/SCBAE Route Symptoms (See Table 5) Ml Con (lq) Con), rhinitis pharyngitis pares, llq frostbite, in animals narco, tremor, convuts pulm edema kidney mj Health hazards First aid (See Table 6) S. Braath Frostbite Frostbite Reap support Target organs (See Table 5) Eyes, skirt, reap eye, CNS, kidneys [Buftayf fluonde] Sldn Eyes Wash skin Remove Change Prevent skin contact NR Whencontam When wet or contam NR TBAL mn Nau vomit abdom cramps Ing diarr salv head gidd verti weak rhin chest tight blurred vision miosis card irreg muse fasc dysp (Sulprofos] Sttt Eyes. MWtettt Remove: Change: zzzzz NIOSH/OSHA 60 mgtri* DM 100 mgfm*- DMXSQ/SA 260 mg/m* SA CF/HIEF/PAPRDM/ SCBAF/SAF SC8AF PD PP/SAF PD PPASCBA Escape HiEF/SCBAE [2,4,5-T] ' Skin Eyes NR Nn NIOSH 10 mg/m3 DM Wash skin N R 20 mg/m3 DMXSQ/SA Remove NR 50 mg/m' PAPRDM/SA CF Change NR 100 mg/m' HiEh/SAT CF/PAPRTHiE/ scbaf/saf 1000 mg/m3 SA PD PP SCBAF PD PP/SAF PD PP ASCBA Escape HiEF/SOBAE [Tate (containing no asbestos and less than 1% quartz)) Ht In animals, ataxia, sMn krtt acne-Ulte rash, Con Kver damage Inh hbrotic pneumoconiosis Con irnt eyes Eye Skin Breath Swallow Irr immeO Soap wash immed Resp suppon Medical attention immed Resp sys CNS CVS blood chol & Braath Swallow Irrlmmed Soap wash Rasp support Medical attention immed Skin liver, <31 tract Eye Breath frrimmed Fresh air Eyes lesp sys CVS 293 Chemical name, structure/formula CAS and RTECSNos and DOT IQ and guide Nos Synonyms trade names and conversion factors Tantalum (metal and oxide duet as Ta) Ta (Metal) 7440-25-7 (Metal) WWS505000 (Metal) Tantalum metal Tantaium-181 Synonyms of other tantalum dusts (including oxide dusts) vary depending upon the specific compound 294 TEDP IfCH ,CH,OI ,PS|,0 3689 24 5 XN4375000 1704 153 Te 13494-80-0 WY2625000 Biadafum Dithion Sulfotep Tetraethyl dithiono pyrophosphate Tetraethyl dithiopyro phosphate Thiotepp 1 ppm = 13 18 mg/m3 Aurum paradoxum, probbmatum Tellurium hexafluoride TeFe 7783 80 4 WY2800000 2195 125 Tellurium fluonde 1 ppm = 9 88 mg/m3 ABD00023018 Exposure limits (TWA unless noted otherwise) NIOSH 5 mg/m3 ST 10 mg/m3 OSHA 5 mg/m3 IDLH Physical description 2500 mg/m3 Metal Steel blue (as Ta) lo gray solid or black odorless powder Chemical and physical properties MW BP SOL FI P IP, Sp Gr, flammability VP FR2 UEL LEL incompatibilities and reactivities Measurement method (See Tablet) MW 180 9 VP 0 mm Strong oxidizers Filter BP 9707'F (approx) bromine tnfluonde none Sol Insoluble MLT 5425*F fluorine Gray FI P NA UEL NA IV IP NA LEL NA (#0500, MEC<200 g/m3 Particulates s NOR Sp Gr 16 65 (Metal) (total)] 14 40 (Powoer) Metal Combustible Solid powder ignites SPONTANEOUSLY in air NIOSH/OSHA 0 2 mg/m' [skin] 10mg/mJ Pale yellow 'iquid with a garlic like odor (Note A pesticide that may be absorbed on a solid carrier or mixed in a more flammable liquid ) MW 322 3 BP Decomposes Sol 0 0007% VP 0 0002 mm FRZ 7 UEL 7 Strong oxidizers tron (Note Corrosive to iron ) Sp Gr(77 Ft 1 2C Combustible Liquid None available NIOSH'/OSHA* QTmg/m3 25 mg/m3 (as Te) (*Note The REL and PEL also apply to other tellurium f is : 1 Tellurium hexafluoride and Bismuth taltunde 1 Odorless dark-gray MW 127 6 to brown amorphous BP 1314 F powder or grayish- Sol Insoluble white, brittle FIP NA solid IP NA VP 0mm MLT 842 F UEL NA LEL NA Sp Gr 6 24 Combustible Solid Oxidizers, chlorine cadmium Fitter, Acid, ICP IV (#7300. Elements] NIOSH/OSHA 0 02 ppm (0 2 mg/m3) 1 ppm Colorless gas with a repulsive odor MW 241 6 8P Sublimes Sol Decomposes FI P NA IP > VP >1 atm FRZ 36*F (Sublimes) UEL NA LEL NA Water [Note Hydrolyzes slowly in water to tellunc acid ] Char NaOH FAAS 11(3) (#S1 87] RGasD 6 34 Nonflammable Gas Personal protection and sanitation (See Table 3) Sion eyes Wash skin Remove Change NR NR NR NR NR [Tantalum (metal and oxide dust, as Ta)] Skin .ye* Wash skin Remove Change Provide Prevert skin contact P event eye contact Whe- contarn Wher wet of conigm NR Eyewash Quick drench ITEDP] SWn rfShsttn Remove Change NR NR NR NR NR [Tenurtum] Skin Eyes Wash skin Remove Change NR NR NR NR (Tellurium hexafluoride] ABD00023019 Recommendations for respirator selection -- maximum concentration for use (MUC) |See Table 4) NIOSH/OSHA 25 mg/m1 DM" 50 mg/m3 DMXSQ"/DMFu/SA 125 mo/rn1 SACF/PAPRDM" 260 mg/m* HiEF/SAT CF/PAPRTHIE/ SCBAF/SAF 2500 mg/m1 SAPDPP | SCBAF PD PP/SAF PO.PPASCBA Escape HIEF/SCBAE Route Symptoms (See Table 5) lnh Irrtt eyes, skin Con mammals pulmimt NIOSH/OSHA 2 mg/m5 SA 5 mq/rr' SA CF 10 mg/m' SCBAF/SAF SCBAF PD PP'SAF PD PP ASCBA Escape GMFOVHjE/SCSaE lnh Abs Ing Con Irnt eyes skin eye pain oturred vision lac him head cyan anor nau vomit diarr local sweat weak twitch para Cheyne Stokes resoiratior corvuis low BP card irreg Health hazards First aid (See Table 6) Eye Breath Irr immed Reap support Target organs (See Table 5) Eyes skin reap sy* Eye Skin Breath Swallow Irr immed Soap wash immed Resp support Medical attention immsc Eves Skin respsys CNS CVS blood chol 295 NiOSH/OSHA 0 5 mg/m1 DM* 1 mg/m3 OMXSQ*/OMFu/SA 2 5 mg/m3 SA-CF/PAPR0M" 5 mg/m3 HiEF/SAT CF/PAPRTHIE/ SCBAF/SAF 25 mg/m3 SA.P0PP f SCBAF PD PP/SAF PD,PPASCBA Escape HIEF/SCBAE NIOSH/OSHA 0 2 ppm SA 0 5 ppm SA CF 1 ppm SAT CF/SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Iscape GMFS/SCBAE Ml Ing Con GarDc breath, sweat dry mouth metallic taste, som, anor nau no sweat derm In animals CNS red Mood cell effects lnh Head dysp garlic breath mammals pulmedema Swallow- Soap wash prompt Reap support Medical attention Immed Mi, CNS, Mood Breath Resp support Resp sys Chemical name structure/fonnuld CAS and RTECS Nos and DOT ID and guide Nos Synonyms trade names, and conversion factors Temephos lC^H4OP{SKOCNj)j]j 3383-B6-8 TT09MOOO Abate Temefos 0 0 O'O -Tetramethyt 0 0 - thlodi-p-phenylene phoaphorothioate 296 TEPP |<CH,CH,0)jP0]J0 107 49 3 UX6825000 2783 152 3016 152 (liquid) o-Terphenyl M-1S-1 WZ8472000 m Terphenyl 92 06 8 WZ6470000 Ethyl pyrophosphate Tetraethyl pyrophosphate Tetron 1 ppm = 11 87 mg/m3 o-Otohenytbenzene, 12-Otphenytoen2ene, 2-Phenylbiphenyl, 1,2-Terphenyt, ortho-Terphenyl o*Ttyhenyl 1 ppm * 9 42 mg/m* m Oiphenylbenzena 1 3-Diphenylberizene isodiphenylOenzene 3 Phenytbiphenyt 1 3 Terphenyl meta-Terphenyl m Tnphenyl 1 ppm = 9 42 mg/m3 Exposure limits (TWA unless noted otherwise) NIOSH 10 mg/m3 (total) 5 mg/m3 (reap) OSHAf 15 mg/m3 (total) 6 mg/m3 (rasp) NIOSH/OSHA 0 05 mg/m3 [skin) NIOSH C 5 mg/m3 (0 5 ppm) OSHAt C9mgAi* (Ippm) NIOSH C 5 mg/m5 (0 5 ppm) OSHAt C 9 mg/m3 (1 ppm) ABD00023020 IDLH ND Physical description White crystalline solid or liquid (above 87'F) [insecticide] [Note Technical grade is a viscous brown liquid ] Chemical and physical properties MW, BP SOL FI P IP Sp,Gr flammability VP FRZ UEL LEL Incompatibilities and reactivities MW 466 5 BP 248-257'F (Decomposes) Sol Insoluble FIP ? IP ? VP(77'F) None reported 0 60000007 mm MLT 67'F UEL ? LEL ? Sp Gr 1 32 Combustible Solid 5 mg/m3 Colo/less to amber liquid with a taint fruity odor [insecticide] [Note A solid below 32'F ] MW 290 2 BP Decomposes Sol Miscible FI P NA IP 0 VP 0 00015 mm FRZ 32'F UEL NA LEL NA Strong oxidizers alkalis water [Note Hydrolyzes quickly in water to form pyrophosphonc acid ] Sp Gr 1 19 Noncombustible Liquid 500 mg/m3 Colorless or lightyeltow solid MW 230 3 BP 630*F Sol' Insoluble FIP(oc) 325*F IP 799eV VP Very low MLT 136"F UEL? LEL? None reported 500 mg/m3 Yellow solid (needles) SpGrl 1 Combustible Solid MW 230 3 BP 689 F Sol Insoluble FI P(oc) 375'F IP 8 01 eV VP Very low MLT 192'F UEL 7 LEL ' None reported Sp Gr 1 23 Combustible Solid Measurement method (See Table 1) Filter, none, Grav IV [Particulates NOR #0600 (total) #0600 (re*p Chrom 102 (2) Toluene GC/FPO IV [#2504 Tetraethyl Pyrophos phate] Filter, GcfrlO (V (#5021) Filter GcfriD IV (#5021] Personal protection and sanitation (See Table 3} Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam When wel or contam Daily [Temephosj Skid Eyes Wash skn Remove Change Provide Prevent skin contact Preven, eye contact When contam When wet or contam NR Eyewash Quickdrench (TEPP] Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet or contam Daily Eyewash Quickdrench [o-TerphenytJ Skin Eyes Wash skm Remove Change Provide Prevent skin coniact Prevent eye contact When contam Wher wet or contam Daily Eyewash Quickdrench [m Terphenyl] ABD00023021 Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table 4) TBAL Route Symptoms (See Table 6) Inh Abs Ing Con Irrit eyes blurred vision dizz conf dysp salv abdom cramps riau diarr, vomit Health hazards First aid (See Tables) Eye Skin Breath Swallow Irr immed Soap wash immed Resp support Medical attention immed Target organs (See Table 5) Eyes resp sys, CNS CVS blood chol NIOSH/OSHA 0 5 mg/m3 SA < 25 mg/m3 SA CF 2 5 mg/m3 SAT CFiSCBAF/SAF 5 mg/m3 SA PD PP SCBAF PD PP'SAF PD PP ASCBA Escape GMFOVHiF/SCBAE inn Aos Ing Cor Eye pain blumed vision iac rhm head chest tight cyan anor ndu vomit diarr weak twitch para Cheyne-Stokes respiration convuls low BP card .meg sweat Skin Breath lr immed Water flush immed Resp support Medical attention immed Eyes resp: CVS Gl tra blood chol NIOSH 25 mg/m1 DM1 50 mg/m1 DMXSQ/SAE 125 mg/m3 SA CFE/PAPRDME 250 mg/m5 H1EF/SC8AF/SAF 500 mg/m3- SAF PD PP SCBAF PD PP/SAF PD PP ASCBA Escape HiEF/SCBAE Inh Ing Con Irriteyes skin muememb thermal skin bums head sore throat in animals liver kidney damage NIOSH 25 mg/m3 DM1 50 mg/m3 DMXSQ^'SA1125 mg/m3 SA CF/PAPRDMC 250 mg/m3 HiEF/SCBAF/SAF 500 mg/m3 SAF PD PP SCBAF PD PP/SAF PD PP ASCBA Escape HiEF/SCBAE inh Ing Con Irriteyes skin muememb thermal skm burns head sore throat n animals liver kidney damage Eye Skin Breath Swallow Irrlmmed Water flush tmmed Resp support Medical attention immed Eyes skin resp sys liver kidneys Eye Skin Breath Swallow Irnmmed Water flush immed Resp support Medical attention immed liver Kidneys Chemical name structure/formula CAS and RTECS Nos and DOT ID and guide Nos Synonyms trade names and conversion (actors Exposure limits (TWA unless noted otherwise) p-Terphenyl 92-94-4 WZ9475000 2 3 7 8 Tetrachloro dibenzo-p dioxin C,.H4Ci40^ 1746 01-6 HP3500000 1112 Tetrachloro2 2-difiuoroethane CCIjCCIFj 76-11-0 K11425000 p-Diprtenyfcenzane, 14-Diphenytoenzene, 4-PhenyiWphenyt, 1,4-Tetphenyl para-Terpheryl, p-Trtphenyt NKDSH C 5 mg/m3 (0 6 ppm) QSHAT C 9 mg/m* (1 ppm) 1 ppm * 9.42 mgfm3 Dioxin Dioxine TCDBD TCDD 2 3 7 8 TCDD [Note Formed dunng past production of 2 4 5 tr chlorophenoi 2 4 5 T & 2(2 4 5 trichiorophenoxy)propionic avid ] NIOSH Ca See Appendix A OSHA none 2,2-DifluofO-1,1 1 2tetrachloroethane Frson*112a. Maloeaibon 112a Refrigerant 112a NIOSH/OSHA 500 ppm (4170 mg/m3) 1 2 2 Tetrachloro i 2 orfiuoroetnane CC jFCC r 76 12 0 KM420000 1 ppm 8 34 mg/m* 1 2 Difluoro 112 2 tetracnioroettiane Freon "2 Haiocartson 112 Refrigerant 112 NIOSH/OSHA 500 ppm i41 70 mg,mJ 1 ppm = 8 34 mg/m3 ABD00023022 IOUH Physical description 500 mg/m3 White or lightyellow solid Ca [NO] Colorless to white crystalline solid [Note Exposure may occur through contact at previously contam rated worksites ] 2000 ppm Colorless solid with a slight ether-like odor (Note A liquid above 105'F) 2000 ppm Colorless solid or liquid laDove 77 F) with a si ght ether like odor Chemical and physical properties MW, BP SOL FI P IP.Sp, Gr flammability VP FRZ UEL LEL MW 230 3 BP 761*F Sol Insoluble FI P 405*F IP 7 78eV VP Vety tow MLT 415F UEL ? LEL ? Incompatibilities and None reported Measurement method (See Table 1) Fitter ScfrlD IV [#5021] Sp Gr 1 23 Combustible Solid MW 322 0 BP Decomposes Sol 0 00000002% F'P ' IP 7 VP(77F) 0 000002 mm MLT 581 F UEL 7 LEL 7 Uv light (decomposes) None available Sp Gr 7 MW 203 8 BP 197'F Sot. 0 01% FIP NA IP 7 VP 40 mm MLT 105F UEL NA LEL NA SpGrl 65 Noncombustible Solid MW 203 8 BP 199 F Sol(77 F| C01% Ft P NA IP 1' 306V VP 40 mm MLT 77 F UEL NA uEL NA Sp Gr 1 65 Noncombustible S'olid Chemioally-active metals such as potassium beryllium powdered aluminum zmc magnesium caloum & sodium acids Char GCfriD IV {#1016] Chemically active metals such as potassium beryllium powdered aluminum zinc magnesium calcium 8 sodium acids Char GCfrlD IV (#'016] Personal protection and sanitation [See Table 3i Skin Eyes Wash skin Remove Change Provide Prevem skin contact Prevent eye contact Whencontam When wet or contarn Daily Eyewash Quick drench |p Terphenyl] S< Eyes Vashskn Remove Change Provde ~ c/ei sun contac* Pe/e- eyecontact Wher comamiDaiiy Ahe ,ei or _<yit* Da i> Eyevvasr Quick drench |2 j 7 8 Tetrachlo o dipenzo p dioxin. Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact Whencontam When wet or contarn NR [1 1 1 2'Tetrachlofo-2 2-drfluoroethane] Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact Whencontam When wet or contain NR [112 2 Tetrachloro 1 2 difluoroethane) ABD00023023 Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table 4) NIOSH 25 mg/m3 DM* 50 mg/m3 DMXSQL/$A` 125 mg/m3 SA CFVPAPRDM1 250 mg/m3 HiEF/SCBAF/SAF 500 mg/m3- SAF PD PP SC8AF PD PP/SAF PD PP ASCBA Escape MiEF/SCBAE Ru ute Symptoms (See Table 5) Inh Irriteyes skin muememb Ing thermal skin bums head Con sore throat in animals liver kidney damage NIOSH X SC3AC PD RP/SAf PD PP ASCBA Escape 3M=0VH E'SCBAE inti Ads ,ng Qon rteyes allergic derm cnioracne porphyra Gi d s possible repro erato eflects mammais liver kidney damage hemorr (care] Health hazards First aid (See Table 5) Target organs (See Table 5) is Breath Swallow Irr immed Water flush tmmed Reap support Medical attention immed Eyes skin respsys, liver kidneys Eye Skir Breath Swallow trnmmed Soap flush immed Resp support Medical attention immed Eyes skin liver Kidneys repro sys [in animals tumors at many sites] 299 NIOSH/OSHA 2000 ppm SA/SCBAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE NIOSH/OSHA 2000 ppm SA/SCBAF SCBAF PD PP/SAF PD PP ASC8A Escape GMFOV/SCBAE Inh Irrtteye# skin, CNS Ing depres, pulmedema, drew, Con dysp < Inh In animals jmteyes Ing skm conj pulmedema Con narco ft Breath Swallow* Itr immed k ' Egg. Skin. NIP sys, goap wasftprbmpt sshes*: Inroad 1 * % v JV, ^ ` / vyv ,, v -1 1 \ s: Breath Swallow Irr immed Soap wash prompt Resp support Medical attention immed Eyes skin respsys CNS Chemical name tructure/formula, CAS andRTECSNos and DOT ID and guide Nos Synonyms trade nama# and conversion factors *tfw CCI,CHjCl 630-20-6 KI8450000 1702161 i ' 2 2 Tetracnioroethane 300 79 34 5 KI8575000 1702 151 Tatrachtoroethylene CtjOCClj 127-1*4 KX9W0Q00 None Acetylene tetrachloride Symmetrical tetrachioro ethane 1 ppm = 6 87 mg/m3 PgrcMofettoftane, ParcMwoMrvIsna Per* TetrachtorsOiylene 1007 10ft Tetrachloronaphthalene C,,,H.CI. 1335-88 2 QK3700000 1(^111*0.7041)01^ Haiowax Nibren wax Seekaywax Exposure (TWA unless noted otherwise) ABD00023024 tOLH Physical description NOSH Handle with caution in the workplace See Appendix C (Chloroethanea) OSHA none ND Yellowish-red liquid Chemical and physical properties MW, BP, SOL FI P IP Sp, Gr flammability VP FRZ UEL LEL MW 167 9 BP 267*F Sol 01% FIP ? IP 7 VP(77*F) 14mm FRZ 94'F UEL ? LEL ' SpGrl 54 Incompatibilities and reactivities Measurement method (See Table 1) Potassium sodium dinitrogen telraoxide potassium hydroxide nitrogen lelroxtde sodium potassium alloy 2 4 dimtrophftnyl disulfide None available NIOSH La See Appendix A See Appendix C Chloroethanes) 1 ppm i? mg/m1' Ca (100 ppm, Colorless lo pale yellow 'iquid with a pungent chioro<orm nxe Odor OSHAT 5 ppm (35 mg/m '> [skin; NtOSH Ca Cotort**# hqutd Ca {ISO ppm] with a mud See Appendix A cWorofonn-iike Minima* workplace odor supoaure concentration# ttmit number of workers exposed OSHAf 100 pom C 200 ppm 000 ppm (5-mtn max peak in any 3 tin) NlOSH/OSHA 2 mg/m3 [skin] Unknown Colorless to pale yellow solid with an aromatic odor MW 167 9 BP 296 F Sol 0 3% FI P NA IP 1' lOeV VP 5mm FRZ 33 F l EL NA Sp Grin Fi ' 59 Noncombusibie Liquid Chemically active metals strong Rustics `uming Sulfuric acid [Note Degrades slowly when exposed to arr J MW 165 8 VP 14 mm Strong oxidizer# BP 250*F FRZ 2*F chemtcalty-ecdve Sol 0 02% UEL NA metalssuchas FIP NA LEL NA lithium beryllium & IP 9 32 *V barium caustic soda odium hydroxide potath Sp Or 1 62 Noncombustible Liquid but decompose# in a Hr* to hydrogen chloride and phosgene MW 265 9 BP 599-680 F Sol Insoluble FI P(oc) 410*F IP 7 VP <1 mm MLT 360F UEL h LEL 7 Strong oxidizers Cna pe CS [#1019] Char gcJfid IV {1003 Halog*netoo Hydrocarbonsl Filter/Bub none GC/FID H(2) (*S130) Sp Gr 1 59-1 65 Combustible Solid Personal protection and sanitation (See Table 3) Stan Eyes Wash skin Remove Qwqa Provide Prevent skin contact Prevent eye contact Whencontam Wien wet or contain NR Eyewash Qwckdrench (11 l^-TatrecNorostfiane] Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet or contam NR Eyewash Quick drench 1112 2 Tetracmoioethane] 6Mk Prevert aWn contact Eye* Preventeye contact Wfahattu VMwncortwn Rmsw. VWtanwat or contam Crtra: NR Provide- Eyiswaeh, Quick(french {tUneMNoattiyiana) _________ Skin Prevent skin contact Eyes Prevent eye contact Wash skin When contam Remove When wet or contam Change Daily [Tetrachloronaphthaienel ABD00023025 Recommendations tor respirator selection -- maximum concentration for use (MUC) (See Table 4) Route Symptoms (See Table 5) TBAL (nh Irrlt wyes, skin weak, ing restless irreg respiration, Con muscinco. In animals liverchanges Health hazards Flretaki (See Table 6) 2 Breath Swallow Irrimmait Soap wash immed Reap support Medics! attention (timed Target organs (See Table 5) Eyes, skin, CN6, liver NIOSH SC BAP PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Inf ADS Ing Con Nau vomit abdorr, pain tremor fingers |aun hepatitis liver tend derm monocy kidney damage [care] Eye Skin Breath Swallow imrnmed Soap wash prompt Resp support Medical attention immed Skin liver kidneys CNS Gl tract (mammals liver tumors) NOSH . SC8AF PO.PP/8PD^P*6CM Escape OMFOVT8CBAE M> Wteyee, twee, throat Afel nau; flushface, neok; tm. (As, too: heed., sotrt, stfe eiyt; liver *"**U# NIOSH/OSHA 20 mg/m3 SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOVHtE/SCBAE /t vK Inh Abs Ing Con * " >, ' V > V* - > Acne-form derm head fig anor verti jaun liver mj K Breath Swetkw irr immed Soap weeh prompt Resp support Mem)attention Wnatf Eyes, aldn rsepsys tfver, kidneys, &NS PnentmaN liver tumors) - l Breath Swallow Irr immed Soap wash immed Resp support Medical attention immed Liver skin CNS 302 Chemical nams stmcture/formuia CAS and RTECSNo* and DOT ID and guide Nos Synonyms tradenames, and conversion factors Exposure Imits (TWA unless noted otherwise) ABD00023026 IDLH Physical description Chemical and physical properties MW, BP SOL FI P, IP Sp, Gr flammability VP, FRZ UEL LEL Tetraethyl lead (as Pb) SSawoo Lead tetraethyl TEL TetraethyiplumtMne 1848131 NIOSHfOSHA 0S75fngjfrns [skin] iT 40 mg/m3 (arPfi) Colorless liquid (unless dyed red, orange, or blue) with a pleasant, sweet odor (Note Main usage it In anMnow additives tor gasoiins ] MW 323 5 BP 228`F (Decomposes) Sol 0 00002% FI P 200"F IP 11 IDeV VP 0 2 mm FRZ -202'F UEL 7 IEL 16% SpGr165 Class IHB Combustible Liquid Tetrehydrofuran CH(0 109-99 9 LU5950000 2056 127 Diethylene oxide 1 4-Epoxybutane Tetremethyiene oxide THF 1 ppm * 2 95 mg/m3 NIOSH (590 mg/m3) ST 250 ppm (735 mg/m3) OSHAT 200 ppm (590 mg/m3) 2000 ppm |10%LEL] Colorless liquid with an ether like odor MW 72 1 BP 151F Sol Miscible FI P 6*F IP 9 45 eV VP 132 mm UEL118% LEL 2% Sp Gr 0 89 Class IB Flammable Liquid imfty, pwch^*. 75-74-1 > TP472J5DOC 1848151 4, % ** 74 y*. t ' H" , S in IM /J' s * f~ Si I Vi i Lr, ?* s , . '> Odferteee liquid (unieet dyed red, . Of*ng,or Wu6)` ' 'with a fruity ,v. (N<** M.^. % f' -4, jj?* V'fr adcWvqefor r-`* w *1 So) 01 bp-wo*f ip a,sov PRZ.-15*F UEL? IEL 7 SpQr 280 Oa*fcll Combustible Liquid Tetramethyl sucanonrtnie (CHJjC(CN)C(CN)(CHj)} Tetramethyl succino dmitnle TMSN 3333-52-6 WN4025000 1 ppm 5 57 mg/rrv NIOSH/OSHA 3 mg/m3 (0 5 ppm) [skin] 5 ppm Colorless odorless solid [Note Forms cyanide in the body ] MW 136 2 BP Sublimes Sol Insoluble FI P 7 IP p VP 7 MLT 338 F (Sublimes) UEL 7 IEL 7 Sp Gr 1 07 Combustible Solid Incompatibilities and reactivities Measurement method (See Table 1) Strong oxidizers, sulfuryl chtonde, rust, potassium permanoaneto (Note Decompose* slowly at room temperature and more rapidly at higher tempera tures.] XAD-2, Pentane, GC/PID IV (#2533) Strong oxidizers lithium aluminum alloys (Note Peroxides may accumulate upon prolonged storage <n presence of air J Char GCfrlD [#1609] Strang oxidizer* such as suSuryl chloride or potassium permanganate PWtfanr GC/PID IV (*2634] Strong oxidizers Char GCfrlD 11(3) [#S155J Personal protection and sanitation (See Table 3) Skin Eyes Wash sxin Remove Change Provide Prevent skin contact (>0 1%) Prevent eye contact 'Mwncontam(>0 1%) Whenwetorcontam(>0 1%) Daily Quick drench (>0 1 %) [Tetraethyl lead (as Pb)J Ski" Eyes AasnsKm Remove Change P eve- s- _o-ta^* Pre.e 'evevortac A' i*rto an A^e" .vet `iami NR 'Tei ar,d a Stun Eyes Weshsktn Remove Change Provide Preventskincomact(>01%) Prevent eye contact Wvencontarrw>01%) Whenwetorconiam(>0 1%) Daily Quidcorench (t*0 1%) [Tetramethyl lead (as Pb)] Sir E,eK Wash sK n Remove Change Preve' i ski ' _o' tact P e'en- eye -jntac Whe i u man When *e( ,r co-tarr' Da i, [Tetramethyi succmcntr ie] ABD00023027 Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table 4) Route Symptoms (See Table 5) NIOSH/OSHA 0 75 mg/m1 SA 1 875 mg/m1 SA CF 3 75 mg/m1 SAT CF/SCBAF/SAF 40 mg/m1 SA PO PP SCBAF PO PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Inh Abs Ing Con Insom lass anxiety tremor hyper-reftexia spasticity bradycardia hypotension hypothermia pallor nau anor low-wgt conf disorientation halu psychosis mama convuls coma eye imt Health hazards Flrstaid (See Table Target organs (See Tab1* S) Breath Swallow Immmed Soap wash immed Resp support Medical attention unmed CNS CVS kidneys eyes NI-SH uSHm r ,,u SA CP CDR jy GMFuy ~APROV',Si-BF SmI 5 b-BA>- >" PP SF PO PP ~Sv,0A Escape oMFCV SCBAE Inh r t e/e& jooe 'tsu 5/s dL jizz heap NS <epres -.0 -!<* B eau Sa (ja r nunec Aate husn prompt Resp suopci Med'Cal attention mrnea ryes ^p *>ys -NS NlOSH/OSHA 0 75 mg/mJ SA 1 875 mg/mJ SA CF 3 75 mg/m1 SAT CF/SCBAF/SAF 40 mg/m1 SA PO PP SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Inh Abs Ing Con Insom bad dreams restless anxious hypotension nau anor delirium mama convuls coma Eye Skin Breath Swallow Irr immed Soap wash immed Resp support Medical attention immed CNS CVS kidneys MGSA/OSHA ^8 ngn' SA/SCBAf SCBAF PD PP'SAF PD PP ASCBA Escape GMFOVH E SCBAE nr Aos iny Con neao nau convjis coma liver k dney Gi effects Eye Sx " Breath Swallow lrr,m reo Soap wash prompt Resp support Medical attenton immed CNS ,ive< Kidneys Gl trac* Chemical name Structure/formula CAS and RTECS Nos and OOT ID and guide Nos Synonyms trade names and conversion factors Tetranltromethane C(NOj)4 509-14-8 PB4025000 Tetan, TNM Exposure limits (TWA unless noted otherwise) NIOSH/OSHA Ippm (8 mg/m5} 304 1510143 Telrasodium pyrophospnate Na,Pp- 7722 68-5 UX7350000 1 ppm = 8 02 mg/m3 P/ropnosphate Sodium pyrophosphate Telrasodium diphosphate Tetrasodfum pyrophosphate (anhydrous) TSPP NlOSH 5 mg/m1 oshat none Tetryl (NO^C^NOpCH, 478-45.* BY6300000 N-WethyPN,2 4 6- tatranttreenUna, NUraintne, 2.4,6-rftyi. 2 4 6-TrtnftrophenytN-methylnltramlne NIOSH/OSHA 1 5mg/m5 {skinj Thallium (soluble compounds as 11) Synonyms vary depending upon the specific soluble thallium compound NIOSH/OSHA 0 1 mg/m3 (3km] ABD00023028 IDLH Physical desc nption 4 ppm Colorless to pale- yellow liquid or solid (below 57'F) with a pungent odor Chemical and physical properties MW, BP SOL FI P IP, Sp Gr, flammability VP FRZ DEL, LEL Incompatibilities and reactivities Measurement method (See Table 1) MW 196 0 VP 8 mm Hydrocarbons Imp/Ethyl BP 259`F TR2 57'F alkalis, metals, Acetate Sol Insoluble UEL 7 oxidizers, aluminum, none FI P 7 LEL 7 toluene cotton GC/FIO IP ? (Note Combustible IV material wet with (#3513] tetramtromethane may be highly explosive ] Sp Gr 1 62 Combustible Liquid, but difficult to ignite ND Odorless <vti te MW 265 S VP 2 mn S'rong acids powder or granules SP Decomposes 'approx [Note The decahydrale Sol(77"F) 7% FI P NA MLT 1810 F UEL NA (Na.PA IOHjO) IP NA LEL NA is m the form of colorless transparent crystals ] Sp Gr 2 45 Noncombustible Solid Filter none Grav IV (#0500 Particulates NOR (total)] 750 mg/m5 Colorless to yellow odorless crystalline solid MW 287 2 BP 356-374*F (Explodes) Sol 0 02% FI P Explodes IP ? VP <1 mm MLT 268'F UEL 7 LEI 7 Oxldlzable materials, hydrazine Filter Reagent; Vie 9U., 15 mg/m3 (as Tl) Sp Gr 1 57 Combustible Solid (Class A Explosive) Appearance and odor Properties vary depending odor vary depending upon the specific soluble upon the specific thallium compound soluble thallium compound Vanes Filter Acid ICP IV [#7300 Elements) 1707 151 (compounds nos) Personal protection (See Table 3) Skin Eyes Wash skin Remove Change Provide Prevent akin contact Prevent eye contact When contain When wet (flamm) Dally Eyewash [Tetranrtromethane) Skin Eyes Wash SKin Remove Change Provioe Preven" skn contact Prevent eye comae" When con'am When wet or contam Da iy Eyewash ,soini (Tetrasodium pyrophosphate) Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam/Dally When wet or contam Daily [TetrylJ Skin Eyes Wash skin Remove Change Preven1 skin contact Prevent eye contact When contam When wet or contam Daily (Thallium (soluble compounds as Till ABD00023029 Recommendations for respirator concentration for use (MUC) (See Table 4) Route Symptoms (See Table 5) NIOSH/OSHA 4 ppm SACFWCRFS`/GMFS`/ PAPRS^SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFSVSCBAE mh mg Con Imt eyes, skin, noBe, throat, dizz, head chest pam dysp, methemo,cyan, skin bums Health hazards First aid (See Table 6) Ift Breath Swallow tit immed Soap wash prompt SVtt. knnatf Target organs (See Table S) TBAl Inh Ing Cor 'rnt eyes Skin rose tnroat derm Eye Skin Breath Swallow Irr immed Water wash prompt Resp support Medical attention immed Eyes skin resp sys 305 NIOSH/OSHA 7 5 mg/m1 DM 15 mg/m3 DMXSQ7SA* 37 5 mg/m1 SACFVPAPRDM' 75 mg/m3 HIEF/SCBAF/SAF 750 rmj/m1 SAF PD.PP SCBAF PD PP/SAF PD.PP ASCBA Escape. HIEF/SCBAE Hi Sens derm, itch, eiyt, Abs edema on nasal font, Ing cheeks nee*,kera, Con Bn*ez;anemia,ftg, cough, cotyza irrtty mal bead, toss, ineom, nau vomit; liver, kidney damage Iffi Breath. swallow IrTlmmed Eyes, skin, raspsys, i2S'25SLSpm(l CNS.W, kidneys 'tmmod NIOSH/OSHA 0 5 mgym1 DM' 1 mg/mJ DMXSQA/SA 2 5 mg/m1 SA CF/PAPRDM" 5 mg/m3 HiEF/SAT CF/PAPRTHiE/ SCBAF/SAF 15 mg/m3 SAF PD PP SCBAF PD PP/SAF PO PP ASCBA Escape HiEF/SCBAE Inh Abs Ing Con Nau diarr abdom pain vomrt ptosis strabismus per neuntis tremor retster tight chest pain oulm edema sez chorea psychosis liver kidney damage alopecia pares legs Skin Breath Swallow Irr immed Water flush prompt Resp support Medical attention immed Eyes resp sys CNS liver kidneys Gl tract Dody hair Chemical name structure/formula, CAS and RTECS Nos and DOT ID and guide Nos Synonyms trade names and conversion factors 4 4 -Thiobis(6-tertbutyl-m-cresot) [CHjtOHJCgHjClCH^S 96-69-5 QP3150000 4 4-Thiobis<3 methyl 6tort-butylphenol) 1 1' Thiobie(2-methyl4-hydroxy-5-tertbutybenzene) Thioglyconc acic HSCH COOH 306 AI5950000 1940 153 Thionyt chloAde SOCIj 77194)9-7 XM51SOOOO Acetyl mercaptan Mercap oacetaie Mercaptoacetic acid 2 Mercaptoacetic acd / ti cgiycoiu. auc Thiovamc ac d ppm = 3 7T mg m Sutflnyl chloride, Sulfur chloride oxide Sulfureus dichlorlde Sulfurous oxychloride Thkxiyl dichlorlde Exposure limits (TWA unless noted otherwise) NIOSH lOmg/m3 (total) 5 mg/m3 15mcym3 (total) 5 mg/m3 (resp) NIOSH pprr 4 mg mJ [sk n OSHA-r nore NIOSH C 1 ppm (5 mg/m3) OSHAT none 1836 137 Tr-iram CH ^S, '3' 25 6 J01400000 1 ppm 4 87 m^m3 b>s(D methyl'hiocarbamoyl) disulfide Tetramethylthiuram disulfide hCH,)jNC(S)SSC SlN(CH,),] NlOSH/OSHA 5 mg/m 277 151 _ ARnnnrmmn IDLH Physical description Chemical and physical properties MW BP SOL PIP, IP Sp, Gr flammability VP FRZ UEL LEL Incompabbilities and reactivities Measurement method (See Table 1) ND Ught-gray to tan MW 358 6 VP None reported powder with BP ? 0 0000006 mm slightly aromatic Sol 0 08% MLT 302'F odor FI P 420'F UEL NA IP ? LEL NA SpGr 1 10 Combustible Solid Filter none Gray IV [Particulates NOR *0500 (total) *0600 (r**P)] ND Colorless liquid with a strong disagreeable odor cnaractenstic of ->ercaptans Nile Olfactory tat qi e may occur at*e soon eu.csu es ] MW 92 1 BP i Sol MisciCie Tl P 230 F VP(64 F. ICmrr FRZ 7 F Ufc. " i_E^ 5 9 Sp or ' 32 Class 1 IB Comojst we l iquid A r strong oxidizers sases active metals eg sodium potassium magnesium (.aiaurr (Ncte Readily oxidizeo by air j None available NO Cotoriess to yellow MW 1190 VP(70*F) Water acids alkalis to reddish hquid BP 169*F 100 mm ammonia chlory! with a pungent Sol Reacts FRZ -156*F odor like sulfur Fl P NA UEL NA dioxide IP ? LEL NA [Note Fumes form to form sulfur when eiqioeed to moist elr) So Gr 1 64 dioxide & hydrogen chloride) Noneombusbbte Liquid 100 mg/m' Coioness to yellow crystalline solid with a characteristic odor [Note Commercial pesticiPe products may be dyed blue ] MW 240 4 BP Decomposes Sol 0 003% FI P 7 IP 7 VP 0 000008 mm MLT 312 F UEL 7 LEL 7 Sp Gr 1 29 Combustible Solid Strong oxidizers Strong acids f- Iter CH,CN [#5005] Personal protection and sanitation (See Table 3) SKin Eyes Wash skin Remove Change NR NR NR NR NR [4 4 -Thiobis(6-tert butyl-m-cre*ol)] Skin Eyes Wash skin Remove Change Provrde Prevent skin contact Prevent eye contact When contam When wet or contam NR Eyewash Quick drench [Thioglycolic acid] Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact Wien contam Wien wet or contam NR Eyewash Quick drench [Thlonyt chloride] Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam When wet or contam Daily [Thiram] ABDQQQ23Q31 Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table 4) Route Symptoms (See Table 5) TBAL Inh Irriteyes skin, rasp sys Ing Con Health hazards FlrstakJ (See Table 6) Eye Breath Swallow Ift Immed Fresh atr Medical attention Immsd . Target organs (See Table S) Eyes. Mn.naP'tfy* TBAL Inh imteyes skin nose Abs throat lac corn damage ing skin bums blisters Con m animals weak gasping respirations convuls 1C Breath Swallow Irr immed Water flush immed Resp support Medical attention immed Eyes skin rasp sys TBAL Ml kilt eyes, skin, mucmemb; i<?0 eye,sMn bums Con Con - NIOSH/OSHA 50 mg/m3 CCROVDMFuVSA' 100 mg/m3 SA CF'/CCRFOVHiE/ GMFOVHiE/PAPROVDMFu*/ SC9AF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOVHiE/SCBAE Inh Ing Con Imteyes skin mucmemb derm Antabuse like effects Breath Swallow fc Breath Swallow briumadWat*flushWmad mm iiwiiuB Immed ^yefl.eUwM^eyfl A_ 'r 1 > ? .v.5 \k *,* , irr immed Soap wash prompt Resp support Medical attention immed E^es skin resp sys Chemical name structurefformuld CAS and RTECS No* and OOT ID and guide Nos Synonyms trade names arid conversion factors Tin Sn 7440-31-6 XP7320000 Metallic tin Tm flake Tin metal Tin powder Tm (organic compounds asSm 308 Synonyms vary depending upon the specific organic tin compound [Note Also see specific listing for Cyhexatm Tir>(!!)axtie(MSn) ao 21661-104 Standout oxide. Tin protoxide [Note- AIM see apeoflc Mte tor Tta(IV) oxide (aaSn).} Tm(lV) oxide (as Sn) SnOj 18282 10-5 XQ4000000 Stannic dioxide Stannic oxide White tin oxide (Note Also see specific listing for Tm(ll) oxide (asSn)] __________________________ ABD00Q23032____________________________________________________ Exposure Ikivts (TWA unless noted otherwise) IOLH Physical dev ription Chemical and physical properties MW BP SOL FI P IP Sp Gr flammability VP FRZ UEL LEL Incompatibilities and reactivities |0>. I--0"s4?2t-U3_JJlm35 NIOSHTOSHA* 2 mg/m3 100 mg/m3 (as Sn) [Note The REL and PEL also apply to other inorganic tin compounds (as sn) except tin oxides ] Gray to almost silver-white ductile malleable lustrous solid MW 118 7 BP 4S45*F Sol Insoluble RP NA IP NA Chlorine turpentine acids alkalis Sp Gr 7 28 Noncombuabbie Solid but powdered form may ignite NIOSH 25 mg/m C 1 mg/mJ (as Sn> [skin, ' Note Tne REL applies to all organic tin .ompounas except ryhexatin ] OSHA* 0 nig. m NOSH 2 mg/m* OSHAf nom ND Appearance ana oaor Properties vary depending vary depending upon upon the specific organic the specific tin compound organic tin onipound varies Brownish-Week powder MW 134 7 BP Oecompoae* Sol Insoluble FIP- NA IP NA VP Omm None reported (approx) MLT(600 mmHg) 1976V (Decomposes) UEL NA LELNA SpGf 63 NIOSH 2 mg/m3 OSHAT none ND White or slightly MW 150 7 VP 0 mm Chionne trifluor>d gray powder BP Decomposes (approx) Sol Insoluble MLT 2966 F FI P NA (Decomposes) IP NA UEL ' LEL ' Measurement method ISee Table 1) Filter Acid ICP tv [#7300 Elements] Filter XAO 2 Acetic acid/ CH CN HPLC/GFAAS IV (#5504] Filler; Acida. CP IV I#7300, Element*] Filter Acids (CP IV [#7300 Elements] Sp Gr $95 Personal protection and sanitation (See Table 3) Skin Eyes Washskin Remove Change NR NR NR NR NR [Tin] Recommendations /ary depend ng upon tot Specific compound [Tin (organic compounds asSni Skin yJashskm Remove Change NR NR NR NR NR [Tin(ll) oxide (a* Sn)] Skin Eyes Wash skin Remove Change NR NR NR NR [Tm(IV) oxide (as Sn)] ABD00023033 Recommendations for respirator concentration for use (MUC) (See Table 4) Route Symptoms (See Table 5) NIOSH/OSHA 10 ing/m5 DM' 20 mg/m3 DMXSCr'/SA* 50 mg/m3 SA CF'/PAPRDMA' 100 mg/m5 HiEF/SCBAF/SAF SCBAF PD PP/SAF PD PP ASC8A Escape HtEF/SCBAE Inh Ccn Irril eyes, skin rasp sys in animals vomit diarr, para with muse twitch Health hazards First aid (See Table 6) Target organs (See Table 5) Eve Skin Breath Swellow In immed Soap wash immed Reap support Medical Mention Immed Eyes, skin, reap sys NiOSM'ObHA 1 mg,m' C< ROVDM/SA 2 5 mg/m SA CF/PAPROVDM 5 mg/mJ oCRFOVHiF/GMFOVHiE/ PAPRTOVHiE/SAT CF/ SCBAF/SAf25 mg/m3 SAF PO PP SCBAF PD PP/SAF PD PP ASCBA Fscape GMFOVHiE/SCBAE TBAL Inh Aus log Con Imt eyes Sk n resp SyS nead verti psycnoneurologic dist sore throat cough abdom pain vomit urine retention paresis focal anes skin bums pruritus mammals hemolysis hepatic nec kidney damage Mi Stanno** **(benign Con pneumoconfosa) dyap decrpuknfunc Eye Skin Breath Swallow Irr immed Water flush immed Resp support Medical attention immed Eyes skin resp sys CNS liver Kidneys urinary tract blood Eye. Breath Freeh air 309 TBAL Inh Con Stannosis (benign pneumoconiosis) dysp deer pulm func Eye Breath Immmed Fresh air Resp sys Chemical name structure/formuia CAS and RTECS Nos and DOT ID and guide Nos Synonyms trade names and conversion factors Titanium dioxide TiO, ` 13463-67-7 XR2275000 Rutile, Titanium oxide Titanium peroxide 310 CHN 119 93 7 DOI225000 4 4 Diamino 3 3 dimethyl Diphenyl Diaminoditolyl 3 3 Dimethylbenzidme 3 3 Dimethyl 4 4 diphenyl diamine 3 3 Tolidme Toluene 106-88-3 XS6250000 Methyl benzene. Phenyl methane, 1294 130 Toluervediamine ch3c8h3(nh2)2 25376-45-8 95-80-7 (2 4-TDA) XS9445000 XS9825000 {2 4 TDA) 1709 181 lppm3.77rog^nJ Diammotoluene Methyiphenylene diamine TDA Tolylenediamirve Exposure Xmlts (TWA unless noted otherwise) ABD00023034 IDLH Physical description NIOSH Ca See Appendix A OSHAt 15 mg/m5 Ca (5000 mg/m3) White odorless powder Chemical and physical properties ----- -------------------- - - --- MW BP SOL FI P IP Sp Gr VP FRZ flammability UEL LEL MW 79 9 8P 45325432 F Sol Insoluble FI P NA IP NA VP 0 mm (approx, MLT 3326 3362'F UEL NA LEL NA NIOSH Ca See Appendix A See Appendix C C 0 02 mg/m! (60 minj |Skm] Ca [N D 1 OSHA See Appendix C NIOSH (373 mg/m5) ST 150 ppm (560 mg/in1) 500 ppm OSHAt 200 ppm C 300 ppm 500ppm (10-mki max peak) NIOSH Ca (all isomers) See Appendix A OSHA none Ca [N D] White to eddish crystals or powder (Note Darkers on exposure to air Often used m paste nr wet cake form Used as a casis for many dyes ] Colorless liquid with a sweet pungent benzenelike odor Sp Gr 4 26 Noncombustible Solid MW 212 3 BP 572 F Sol 0 1"c VP 7 ML1 264 F UEL ' Sp Gr 7 Combus'ide Sd iC MW 92 1 BP 232 F Sol(74*F) 007% FI P 40'F IP 8 82 eV VP 21 mm FRZ 139 F UEL71% ia.11% Sp Gr 0 67 Class 18 Flammable Liquid Colorless to brown needle-shaped crystals or powder [Note Tends to darken on storage & exposure to air Properties given are for 2 4 TDA ] MW 122 2 BP 558-F Sol Soluble FI P 300F IP 7 VP(224'F) 1mm MLT 210F UEL 7 LEL 7 Sp Gr 1 05 (Liquid at 212 F) Combustible Solid Incompatibilities and reactivities None reported Strong oxidizers Strong oxidi2ers None reported Measurement method (See Table 1i Filter Acid FAAS M(3) [#S365] Filter Water HPLC'UVD 'V Dyes] Char GCfclD IV [#1500 Hydrocarbons] [Also #4000 #1501} Imp Reagent HPIC/UVD IV [#5516] Personal protection {See Table 3) Skin Eyes Wash skin Remove Change NR NR NR NR Daily [Titanium dioxide] Skin Eyes Wash skin Remove Change Provide Prevent sum contact Prevent eye contact When contam/Daiiy When wet or eontam Daily Eyewash Quick drench [o Toiidine] Skin Eyes Wash skirt Remove Change Prevent skin contact Prevent eye contact When eontam When wet (flamm) NR [Toluene] Skin Eyes Wash skin Remove Change Provide Prevent s< n contact Prevent eye contact When contam'Datly When wet or eontam Daily Eyewasn Quick drench [Toluenediamme] ABD00023035 Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table 4) NIOSH a SCBAF PD.PP/SAF PD,PP ASCBA Escape HiEF/SCBAE Route Symptoms (See Table 6} Irti Lung fib, [oarc] Health hazards First aid (See Table 6) Breath Reap support Target organs (See Table 5) Reap ays [inanlmil*' lung tumors} NIOSH SCBAF PD PP/SAF PD PP ASCBA Escape GMFOVHiE/SCBAE Inh ADs Ing Con rril eyes nose ,n animals liver kidney damage [care) Eye Skm Breath Swallow lr' tmmed Soap flush immed Resp support Medical attention immed Eyes resp sys uver kidneys [m animals liver bladder & mammary gland tumors] NIOSH 500 ppm CCROV'/PAPROVVGMFOV/ SAVSCBAF SCBAF PD PP/SAF PD.PP ASCBA Escape GMFOV/SCBAE (ft Abs Ing Con Imt eyas, nose ftg, weak, conf auph, dlzz, head, dilated pupils, lac nor muse ftg, msom, pares, derm, Nvr, kidney damage is: Breath Swallow (trimmed Soap wseb prompt Rasp support Medical attention immed Eyes, akin, resp ays, CN8, liver, kidneys NIOSH SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Inh Abs Ing Con Irrit eyes skin nose tnroat derm ataxia tacar nau vomit convuls resp depres methemo cyan head ftg dizz bluish skin liver rnj [care] Eye Skin Breath Swallow Irr immed Water flush immed Resp support Medical attention immed Eyes skin resp sys blood CVS liver CNS [m animals liver skin & mammary gland tumors] Chemical name structure/formula CAS and RTECS Nos and DOT ID and guide Nos Synonyms trade names and conversion factors Toluene-2 4dllaocyanale CH^atNCOJj 584-84-9 CZ6300000 2078 156 0 Toluidme 312 95 53-4 XU2975000 TDI 2.4-TDI, 2.4-Toluene dllaocyanate 1ppm*7I3mg/ms o-Aminotoluene 2 Ammotoluene 1-Methyl-2 ammobenzene o-Methylanilme 2-Methylaniline ortho Toluidme 1708 153 m-Toluidme CH,yyHHa 108-44-1 XU2800000 1708 153 p Toluidme CHjCjH^NHj 106 49 0 XU31 50000 1 opm - 4 38 mg'rrP 3-Amlno-1 -methylbenzana 1-Ammophenytmathane m-Anunototuene 3-Methylaniline, 3-Methytbenzenamine, 3-Tokndine m-Totylamme 4 Ammotoluene 4 Methylaniline 4 Methylbenzenam ne 4 Toluidme Toiylamme 1708 153 Exposure limns [TWA unless noted otherwise) NIOSH Ca See Appendix A OSHAT C 0 02 ppm (0 14 mg/m3) NIOSH <^a See Appendix A [skin] OSHA 5 ppm (22 mg'irP) [skin] NIOSH See Appendix D OSHAt none NIOSH Ca See Appendix A OSHAT none ABD00023036 IOLH Physical description Ca (2 5 ppm] Colorless to paleyellow solid or liquid (above 71'F)wtha sharp pungent odor Chemical and physical propsities MW BP SOL FI P IP Sp Gr flammability VP FRZ UEL LEL MW 174 2 BP 484F Sol Insoluble FI P 260'F IP? VP(77'F) 0 05 mm MLT 71 F UEL 9 5% LEL 09% Ca [50 ppm] Colorless to pale yellow liquid with an aromatic aniline like odor Sp Gr 1 22 Class IIIB Combustible Liquid MW 107 2 BP 392 F Sol 2% FI P 185 F IP 7 44 eV VP 0 3 mm FRZ 6 F UEL 7 LEL 7 NO Ca [N D ] Sp Gr 1 01 Class IIIA Combustible Liquid Colorless to tight yellow liquid with an aromatic aminellke odor {Note Used as a basis for many dyes] MW 107 2 BP 3978F Sol 2% F1FM87*F IP 7 50eV VP(106*F) 1mm FRZ -23*F UEL ? LEL ? SpGr 0 999 Class IIIA Combustible Liquid White solid with an aromatic odor 'Note Used as a basis 'or many dyes , MW '07 2 BP 393 F Sol 0 7% FI P 88`F iP 7 50 eV VP(108 F Irrrr MLT 111 F UEL 7 LEu 7 So Gi 1 05 Combustible Solid Incompatibilities and reactivities Measurement method (See Table 1) Strong oxidizers water acids bases & amines (may cause foam & spatter) alcohols [Note Reacts slowly with water to form carbon dioxide and polyureas ] Coated glass wool Methanol HPLC/UVD IV [#2535] Strong oxidizers nitric acid bases S gei Amines] Oxidizers acids Si gel Ethanol GC/FID IV (#2002 Aromatic Amines] Oxidizers acas Si gel Ethanol GC/FID .V [#2302 Aromatic Amines] Personal protection (See Table 3) Skin Eye* wash skin Remove- Change Provide Prevent skin contact Prevent eye contact Whan contam/Dally When wet or contam Daily Eyewash Quick drench [Toluene-2 4-dnsocyanateJ Skin Eyes Wash Skin Remove Change Provide Prevent sum contact p event eye contact When contam 'When wel or contam NR Eyewash Quickdrench [o Toiuidine) SMn Eyes Wash skm Remove; Change Prevent akin contact Prevent eye contact When contam When wet or contam NR [m-Tolukft] Stan Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam/Daily When wet or contam Daily Eyewash Quickdrench [p Toiuidine) ABD00023037 Recommendations for respirator concentration for use (MUC) (See Table 4| NIOSH SCBAF PD PP/SAF PD PP ASC8A Escape GMFOV/SCBAE Route Symptoms (See Table S) Inh Irrit: eyes, skin noaa Ing throat choke paroxysmal Con cough chest pain retstar soreness, nau vomit abdom pain bron bronchospesm pulm edema dysp asthma conj lac derm akin sens [care] Health hazards First aid (See Table 6) iTn Breath Swallow Irnmmed Soap wash Immed Resp support Medical attention immed Target organs (See Table 5) Eyes skin reapsys [in animals pancreas, liver mammarygland, circulatory eys & akin tumors] NIOSH SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE inh Abs Ing Con ir i eyes anoxia nead cyan weak dm drow micro hema eye burns derm tcarc] Eye Skm Breath Swallow irr immeo Soap wash immed Resp support Medical attention immed Eyes skm Oiood kidneys liver CVS (oiadder cancer) 313 TBAl Inh Imteyes, skin hema Abs mathemo, cyan, nau, vomit, Ing low BP convula, anemia Con weak as. Breath Swallow- Irr immed Soap wash immed Reap support Medical attention nimed Eyas, akin, blood CVS NIOSH SCBAF PD PP/SAF PD PP ASCBA Escape GMFOVHiE/SCBAE Irfi Abs Ing Con imt eyes skin derm hema methemo cyan nau vomit low BP convuls anemia weak (carcj Eye Stan Breath Swallow Irr immed Soap wash immed Resp support Medical attention mmed Eyes skin Oiood CVS (inanimals liver tumors] ABD00023038 314 Chemical name structure/formula CAS and RTECSNo* and OOT ID and guide Nos Synonyms trade names nd conversion factors Tribotyt phosphate.,? Bvtylphoaphitsp, ' * -r,49 - '4 v '* t *i* ? ' pnQtWOnC-IClg, 12*-7&3 , i- . Trtfvbutyt phosphtW TC7700060; f* 1 r'~ Trichloroacetic acid CCI,COOH ' i 10 tomgrtn*K TCA Tnchloroethanoic acid AJ787S000 1839 153 (solid) 2564 153 (solution) 1 ppm = 6 68 mg/m3 Exposure limits (TWA unless noted otherwise) IDLH 1*OSH 0.2 ppm i ,(2 5 mgMi*) >1 30 ppm< -t OSHAf 8 mg/m1 - -" - -e Physical description ColortM# to pits* glow, odoriesa Jid, t, : > V-', .v Chemical and physical properties MW BP, SOL FIP, IP Sp, Gr flammability VP FRZ UEL LEL MW 2fc3 VP(T7*Fr ,,> BP5S2T ' ` V 0 004 mm." (Decomposes^ wFRZM12*F , ^ Sol 06% UEL? ,, ' FIP(oc) 295*F LEL? IP- ? , ^- Incompatibilities Measurement (See Table 1) Alkalis,'oxidizers,1 ,rFiltBft",, water moist dr,' I Olsthyf _ ` . ether y >7 , -a- GC/FfcV Ci4 ' IV r_...v, [#5034]' ,> NIOSH 1 ppm (7 mg/m3! OSKAt rorve ,Sp<Gr 0 98 L Class 1IIB Combustfcle liquid ~ j_ N0 Colorless to white MW 163 4 VP{ 124 F) Moisture iron zinc None crystalline solid with a sharp pungent odor BP 388 F Sol Miscible FI P NA IP 7 1mm MIT 136 F UEL NA LEL NA aluminum strong oxidizers [Note Decomposes on heating to form available phosgene 6 hydrogen chlonde Corrosive to metals ] Sp Gr 1 62 Noncombustible Solid cHAwg V ftffiWSErv - "J beat ' v---^'v-** > v" i ** niosHi; C 5 pprrt , (AOiftigfrn9}-* f< , .OSNAt " - '' , ,#7< , --.V^ 'V >-k i, ' yP-1'mm" . '-"Ackts^ add/times, W crystalline * ^,BP'4ie*F- ; >, FR2J 83'Fr, / r<-,oxictEzefS, gmrfTA' r^ .,soltt~(betaM'W`Fl wan an aromatic SoL0003%^, - FIP 222*F / - tUELElS^-C. 6dor.' * < 86% _ v- IP*? 1 '' Sp.6M.4B - - *<\- -j rClas# fllB CombwIbta'Uqi*! , Combustible 'Solid . 1 1 2 Tnchloroethane CHCljCHjCl 79 00 5 KJ3150000 Ethane tnchlonde 0 Tnchloroethane Vinyl tnchlonde 1 ppm * 5 46 mg/m3 NIOSH Ca See Appendix A See Appendix C (Chloroethanes) 10 ppm (45 mg/m5) [skm] OSHA 10 ppm (45 mg/m5) [skin] Ca [100 ppm) Colorless liquid with a sweet chloroform like odor MW 133 4 BP 237 F Sol 0 4% FI P 7 IP 11 00 eV VP 19 mm FRZ 34 F UEL155% LEL 6% Strong oxidizers & caustics chemically active metals (such as aluminum magnesium powders sodium 5 potassium) Sp Gr 1 44 Combustible Liquid forms dense soot Char CS, Gfc/FID IV (#1003 Halogenatec Hydro carbons) Personal protection and sanitation (See Table 3i Skin Eyes Wash skin Remove Change Prevent skm contact Prevent eye contact When contam When wet or contam NR (Trtbutyl phosphate] bves a> S' r ^emo e CMange Provide -"'re e** sk f ontac -'re e~ - e a J , -e** :j a Arer u or an Dai y tyewasM Qu < kdrench i Trich lo oacehc ac Oj Skm Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam When wet or contam NR [1 2 4-Tnchtorobenzene] okrn Lye* Vas"1 Skir Remove Change Provide Prevem skit contact Jreve'N eye t.on act v* >*ier uOna,r Vher wet or contam NR Eyewash Quick drench 1 1 2 T icn.oroethanej ABD00023039 Recommendations for respirator selection -- maximum concentration for use (MUC' (See Table 4| NIOSH 2 ppm SA 5 ppm SA CF 10 ppm SCBAF/SAF 30 ppm SAF PO PP SCBAF PD PP/SAF PD PP ASCBA Escape GMFOVhiE/SCBAE R. Symptoms (See Table 5] nh Tt, Con rit eyes skm reso sys head nau Health hazards First aid (See Table 6) Target organs (See Table 5) Eye Skm Breath Swallow 'rr immed Soap wash prompt Resp support Medical attention immed Eyes skm resp sys TBAl nr nt eyes i lose ' ;a es; s,s :c-,' d.sp de a,ea Cu1''1 ejema eye skin b1, r ns ae m salv vomit diari brea n ;Wdl 0* mec d > r f us" I'l e, esp Support Med ca attention iMimed C/e 5 SM"i 9Sp 5 5 31 H v 315 T8AL Inn Abs Ing Con Imteyes skin mucmemb m animals iver kidney damage possible terato effects Eye Skin Breatn Swallow Irr immed Soap wash Resp support Medical attention immec Eyes skin resp sys liver repro sys NIOSH SCBAF PDPPSAI PDPPASCdA Escape GMFOv SC3AE Hi ALs inj Co i lr It eyes nose CNS jeo es in k dne ,,amage er-- carc Eye Ski B eat ir mmed Resp suppon 1 n a -i '-ais ABD00023040 Chemical name structure/formula, CASandRTECS Nos and DOT ID and guide Nos Synonyms trade names. and conversion factors Trichloroethylene dCH-CCt, 7*61-6 KX45S0OOO Eth^ene trichloride Trtehloroetherte, Trtene 316 1710160 Trichloronaphthalene C, H Cl, 1321 65 9 QM025000 1 ppm 5 37 mg/m3 Halowax Nibren wax Seekay wax T2W76<|fK>''; 4 GtyeenW trtohbrohydrth, Glyceryl IrWilorohyiirln, Trwhtorohydrlh V -V >x,Ytr,,, -y. rTf ^ : f.hr.Tl^'*'B'b3 mg*n3 1-i... ^ * f 1 1 2 Tnchloro-1 2 2tnfluoroetfiane CCljFCCIFj 76-13-1 KJ4000000 Chlorofluorocarbon-113 CFC-113 Freon&113 Genetron 113 Hak>carbon113 Refngeranl 113 TTE 1 ppm - 7 67 mg/m3 Exposure knits (TWA unless noted otherwise) IDLH Physical description NIOSH Ca Saa Appandlx A Sea Appendix C C* Cokxlets Squid [1000 ppm] (unleta dyed blue) wRh a ehiorofbrmlike odor OSHAf 100 ppm C 20o ppm 300 ppm (5-mm max peak in any 2 hr>) NIOSH/OSHA 5 mg/m3 [skin Unknown Colorless to pale yellow solid with an aromatic odor Chemical and physical properties MW BP SOL FI PIP, Sp, Or flammability VP FRZ UEL, LEL MW1314 BP-189*F SctOIH FI P 7 IP 946eV VP-$6 mm FRZ.-99'F UEL(77*FX *15% LL(77*F): 6% Incompatibilities reactivities Strong csuetlCs & MkaM. chemlcafly active metals (such as barium, Htmum, aotSum, magnesium, titanium & beryllium) Sp Or 146 Combustible Liquid, but bums with difficulty MW 231 5 BP 579-669 F Sol Insoluble FI P(oc) 392 F IP ? VP <1 mm MLT 199 F UEL 7 LEL 7 Strong oxidizers (See Tablet) Chw; - t ~ SW?? IV , i [#1052J X* v I- }' .* i rh=r* Filter/Bub none GC/FID 11(2) [#S 128) NIOSH1 Ca See Appendix A 10 ppm [60 mg/m*) (skin] OSHAf SO ppm (300 mg/m3) NIOSH 1000 ppm (7600 mg/m3) ST 1250 ppm |9500 mg/m3) OSHAt 1000 ppm (7600 mg/m3) Sp Gr 1 58 Combustible Solid Ca Colorless Iqufct [100 ppm] with a chfewfenfr Ska odor MW-1474, BP-3l4*F , 'Sot 01% ' FIP-HOV IP? ' , VP3mmJ; % 5 / -----vr-*j -FR2-*F.r-i;,, '-maWs, strong UEL(302*F): % - caustic* & oxttzat^-V; 126% '>, - 0 ,,l.,i.^i / Sp.Or1 33 l tea' IIIA CombustibletJquftf X 2000 ppm Colorless to water white liquid with an odor like carbon tetrachloride at high concentra tions [Note A gas above 118*F ] MW 187 4 VP 285 mm Chemically active Char BP 118"F FRZ 31*F metalssuchas CS, Sol(77'F) UEL 7 calcium powdered GC7FID 0 02% LEL 7 aluminum me IV FI P 7 magnesium S beryllium [#1020] IP 11 99 eV [Note Decomposes if m contact with alloys SpGr(77 F) 1 56 containing >2% magnesium ] Noncombustible Liquid at ordinary temperatures but the gas will ignite and bum weakly at 1256"F Personal protection and sanitation (See Table 3i SUn IChskm Remo/e: Ctan Provide Prevent skin contact Prevent eye contact When contain Wien wet or contam NR Eyewash Quick drench (Trtchloroethyiene] Skin f yes Wasn skin Remove Change Prevent skin contact Prevent eye contact When contam When wet or contam Daily (T nchloronaphthalene] SUn. ManRemove. Change Provide Prevent skin contact Prevent eye contact When contam VMien wet or oontam NR Eyewash, Quickdrench (1 2 3-TncWoropropane] Skin Eyes Wasn skin Remove Change Prevent skin contact Prevent eye contact When contam When wet or contam NR |1 1 2 Tnchloro-1 2 2 tnfluoroethane] ABD00023041 Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table 4) NIOSH * SCBAF PD PP/SAF PD PP ASC8A Escape GMFOV/SCBAE Route Symptoms |See Table 5} Inh Imteyes skin head Abs verti vis dist ftg gxtd Ing tremor som nau vomit Con derm card arrtiy pares liver inj jcarc) Health hazards First aid (See Table 6) Target organs (See Table 5) IE Breath Swallow Irr immed Soap wash prompt Reap support Medical attention immed Eyes skin resp sys, heart liver CNS [mammals liver & kidney cancer] NlOSH SnA hO nignV SCBAF SAF SCBAF PD PP/SAF PD PP ASC BA Escape GMFOVHiE/SCBAF inn Ads ing C on Aror nau erli ,aur liver m| f/e Skit B tath Swaiiow irr nmeo Soap wasr Reap support Medical attention tmn ied uver 317 NIOSH * SCBAF PD PP/SAF PO PPASC8A Escape GMFOV/SCBAE mh Imt eyes nose throat AOs CNS depres Ing in animats liver kidney Con inj [care] IS, Breath Swallow Irr tmmed Soap wash Rasp support Medical attention mmed Eyes skin resp sys CNS liver kidneys [m animals foreetomach ltver&mammary gland cancer] NIOSH/OSHA 2000 ppm SA/SCBAF SCBAF PD PP/SAF PD PP ASC8A Escape GMFOV/SCBAE km Ing Con trnt skin throat drow derm CNS depres in animals card arrtiy narco Eye Skin Breath Swallow Irr immed Soap wash prompt Resp support Medical attention immed Skin heart CNS CVS ABD00023042 318 Chemical name structure/formula CAS and RTECS Nos and DOT ID and guide Nos Synonyms trade names and conversion factors Exposure ferrite (TWA unless noted otherwise) Trtethylaminp s' TEA' 121-44-B YE0175000 -1 '-i ' ^ - - IA i2oe it* ^ w *. -t e* i * .. Trrfluorobromomethane CBrF, PA5425000 <A i f - J- ' ,,N Tppm4 Wmg/m* Bromotrifluoromethane Fluorocarbon 1301 Freon13Bi Haiocarbon 13B1 Halonl301 Monobromotrifluoromethane Refngerant 13B1 Trifluoromonobromomethane 1009 126 1 ppm = 6 09 mg/m3 NIOSH See Appendix D CtSHAf 25 ppm ,, (100 mgArp) NIOSH/OSHA 1000 ppm (6100 mg'm') IDLH 200 ppm Physical description Chemical and physical properties MW. BP, SOL FI P, IP, Sp, Gr, flammability VP FRZ UEL LEL Incompatibilities and reactivities Measurement method (SeeTable 1) Colorless , liquid, , with a strong. ` ` ` - ammonla-llke odor MW 1012 BP.tfiS'F ' So! 2% ^ ! FIP20*F IP 7 50eV VP-54 mm -FR2tW75*F . UEL80% v 'LELt.2%. Strong oxidizer* strong adds, chlorine, hypochlorite, halogeneted compounds Bub ` u NeOH OC/FID;. [4S162I Sp <3r 0 73 Class IB Flammable Liquid 40 000 ppm Colorless odorless gas [Note Shipped as a liquefied compressed gas ] MW 148 9 BP 72 F Sol 0 03% FI P NA IP 11 78 eV VP >1 atm FRZ 267 F UEL NA LEL NA *' r - ^ calcium powdered aluminum zinc& GC^FID IV RGasD 5 14 Nonflammable Gas Trimettltlc anhydrite1 " <W>, , ,, 662-3Q7 ; \ ' DC2050000J w * f J * -f Tnmethytamine (CHj)jN 75-50 3 PA0350000 1083 118 (anhydrous) 1297 132 (aqueous soln ) 12 4-8eneoetricarboxyfic anhydrite* 4-CatboxyphthaHc anhydrite; TMA. tmaM. ' TilmetHc acid anhydrite (Mote. TMA ka also svnonvm for.Trihtsthyismine ] u(|ipn 7^86 mg/m* > N N Dimethylmethanamme [Note May be used in an aqueous solution (typically 25% 30= or 40% TMA] 1 ppm = 2 42 mg/m3 NIOSH 1 ' 0005 Dpm (0 04 mg/m*) Should be handled in the workpiece as an extremely toxic substance OSHAt , none ND NIOSH 10 ppm (24 mg/m3) ST 15 ppm (36 mg/m3) OSHAt none ND Colorless solid MW 192 1 'BP 7 Sol 7. FI P NA IP 7 - VP 0 000004 Ynirt MLT 322*F UEL NA LELNA None reported , v> l 'v 7 - \ t ' t - IV. -< *Ur*\ . [#503Sf-/ - , 1. Sp Or "t Combustfcle Solid ^ - 'v j -* t t , *. 1 _ 'V f 1 Colorless gas with a fishy amine odor [Note A liquid below 37 F Shipped as a liquefied compressed gas ] MW 59 1 BP 37 F Sol(86`F) 48% FI P NA (Gas 20 F (Liq) IP 7 62 eV VP(70"F) 1454 mm FRZ 179F UEL 11 6% LEL 2 0% RGasD 2 09 FlammableGas Class IA Flammable Liquid Strong oxidizers (including bromine) ethylene oxide nrtrosatmg agents te g sodium mtnte) mercury strong acids [Note Corrosive to many metals (e g Zinc brass aluminum copper)) None available Personal protection and sanitation (See Table 3) Skin Eyes Wash skm Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet (ftamm) NR Eyewash(>l%) Quickdrench(>1%) [Tnethylamine] Skin Eyes Wash skm Remove Change Provide F .$ 3 e Fros 01 e NR NR NR f ostDite [TnfluorobromomethaneJ Sion Ey Wash skin Remove Change Prevent skin contact Prevent eye contact When contam When wet or contam Daily fTrlmellitlc anhydride) Skm Prevent Skin contact (hq/soini Eyes FrostDi'e P event eye contac hq/Sw'n),Frostb te Wash skm When contam (soinj Remove When wet (flammj Change NR Provide Eyewash (liq/solnl Quick drench ,liQ/somi Frostbite (Tnmethyiamme] ABD00023043 Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table 4) OSHA 200 ppm SA CF^SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFS/SCBAE Route Symptoms I See Table SI Inh Imt eyas skin rasp ays Abs mammals myocardial Ing kidney liver damage Con Health hazards First aid (See Table 6) 1C, Breath Swallow Irr immed Soap wash immed Resp support Medical attention immed Target organs (See Table 5) Eyes skm resp sys CVS liver kidneys N OSH'ObrlA 10 000 ppm SA 25 000 ppm SA CF 40 000 pprr SA1 CF SCBF<SAF SCBAF PD PP'SAF PD PP ASCBA Escape GMFOV SCBAE Inn ^or 1q neaa card army ,q 'rostbite Ere Skn Breatn Frostbite Frostbite Resp support CNS bean 319 TBAl hh Irrtteyes, skin noee reap Ing sys pulmedama rasp sens Con rtunitis, asthma cough wheez, dyap mat fever museecMs snaez Iff, Breath Swallow Irr immed Soap wash Rasp support Medical attention mmed Eye*, skin, reap sya TBAI_ Inh Ing soln Con Irril eyes Skin nose throat resp SyS COugn dysp delayed pulm edema blurred vision com nec skm Ourns iiq frostbite Eye Skm Breath Irr immed (liqfsolnv Frostbite Water flush immed (liq/soln)(Frostbite Resp support Eyes Skin respsys immed (soln) ABD00023044 Chemical name structure/formula CASand RTECS No* and DOT ID and guide Nos Synonyms trade names and conversion factors 1 2 3-Trtmethylbenzene 526-73-8 DC3300000 Heroellltol [Note Hetnlfnellltene is a mixture o1 the 1,2 3-teomer wtth up to 10% of related aromatic* such at the 1 2 4-Isomer) Exposure limits (TWA unless noted Otherwise) NfOSH 25 ppm (125 mg/m*) OSHAf none IDLH ND 320 1 ppm 4 92 mg/m* ' 2 4 Tnmethylhorzpne C.hjiCH, , 95 63 6 DC3325000 Assymetncal tnmethyl benzene psi Cumene Pseudocumene [Note Hemimeihtene is a mixture of the 1 2 3 isomer with up to 10% of related aromatics such as the 1 2 4 isomer ] 1 ppm = 4 92 mg/m 13 T(lmethytbenzene CeHjCCH^ 106-87-8 0X0825000 , >' '- Meeltyiene, Symmetrical trlmethyt- benzene, eym-Trlmethyibenzene t- 2M$*120 I ?1 ppm*492mg/m1 Tnmethyl phosphite fCH30'3P 121-45-9 TH1400000 Methy1 phosphite Tnmethoxyphosphine NlOSH 25 ppm 1 25 mg m i OSHAf none NtOSH 25 ppm (^mg/m*) OSHAf none NIOSH 2 ppm 110 rng/mJj OSHAf none 2329 129 1 ppm = 5 08 mg'm' ND NO ND Physical description Clear colorless liquid wtth a distinctive aromatic odor Chemical and physical properties MW BP SOL FI P IP Sp Gr flammability VP FRZ UEL LEL MW- 120 2 BP 349*F Sol Low FIP ? IP 848 eV VP(82*F) 1 mm FRi 14*F UEL 6 6% LEL 0 8% ncompatibilrbes and reactivities Oxidizers nitnc acid Measurement method (See Table 1) None available C ear colorless I quid with a distinct ve aro"natic oaor Sp Gr 0.89 Flammable Liquid MW 120 2 BP 33' F Sol 3 006% FI P 112 F iP 8 27 eV /Pr56 Fi , mm FRZ 'T F UEL 6 4% LEL 09% Oxidizers m ric acid None available Clear colorless liquid wtth a distinctive aromatic odor Sp Gr 0 88 Class 1' Flammable l auid MW 120 2 BP- 329'F Sot-0002% FIP-122'F IP 8 39aV VP- 2 mm FRZ -49*F UEL ? LEL ? Oxidizers, nitric add None available Colorless liquid with s distinctive pungent odor Sp Gr 0 86 Claes II Flammable Liquid MW 124 1 BP 232 F Sol Reacts FI P 82 F P n VP(77 F) 24 mm FRZ 108 F UEL -> LEL ' Magnesium pe'chiorate water iNote Reacts Ihydrclyzesj wrth water ] None available Sp Gr 1 05 Class 1C Flammable Liquid Personal protection and sanitation (See Table 3) Sktn Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam When wet or contam hi R (1 2 3-Tnmetfiylbenzene] Sun Eyes Wasn skm Remove Change C'revert shin cortaci Prevent eye contact When contam When wet or contam NR ['2 4 Trimetrylbenzene] Skin Eyes Wash skin Remove Change Prevent skm contact Prevent eye contact When contam When wet or contam NR [1 3 5-Tnmethylbenzene] Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet (Itamm'i NR Quick drench Tnmethy phosphite] ABD00023045 Recommendations for respirator concentration for use (MUC) (See Table 4) TBAL Route Symptoms (See Table 51 Inh Ing Con Imteyes skin, nose throat resp sys bran hypochromicanemia head draw ftg dizz nau inco vomit conf chemical pneu (aspir liq) Health hazards First aid (See Table 61 iz Breath Swallow Irr immed Soap wash Resp support Medical attention tmmed Target organs (See Table 5) Eyes skin resp sys CNS blood T84l irr ng Curi nt eyes s r nose inroat resp sys orar hypochromicanen ia head draw ftg diZ2 nau ,nco vomit conf chemical pneu {aspir liq) Lye Skin Breath Swa'iow Jrr immed Soap wash Resp support Medical attention immed Eyes skin resp sys CNo Dlood TBAL TBAL mb Ing Con Imteyes skin nose throat resp sys bran hypochromicanemia head drew ftg dizz nau inco vomit conf chemical pneu (aspir liq) IC Breath Swallow Irr immed Soap wash Resp support Medical attention mmed Eyes skin resp sys CNS blood Inh ing Con Imteyes skin upper resp sys derm m animals terato effects Eye Skin Breath Swallow Irr immed Soap flush immed Resp support Medical attention immed Eyes skin resp sys repro sys ABD00023046 Chemical name structure/formula CAS and RTECS Nos and DOT ID and guide Nos Synonyms trade names and conversion factors 2,4 6-Trlnltrotoluene CHjCjH,(N02)," ' 118-96-7 XU0175000 1-Methyl-2 4,6trinltrobenzene, TNT, ' Trinitrotoluene, sym-Trinltrotoluene, Trinitrotoluol 322 1356 113 (wet) Tnorthocresyl phosphate iCH3CeH40j PO 78 30 8 TD0350CCO 2574 1 51 Triphenylamlne W,N 603-34-9 YK2680000 TCP TOCP Tn-o-cresyl ester o* phosphoric acid Tn-o-cresyl phosphate N N-Dipherrytaniline N,N-Mphenylbenzenanlne Triphenyl phosphate 115-86-6 TC8400000 Phenyl phosphate TPP Tnphenyl ester of phosphoric acid Exposure limits (TWA unless noted otherwise) NIOSH 0 5 mg/m* [akin] OSHAt 1 Smg/m* [akin] NIOSH 0 1 mg'm1 [Sk n' OSHAT 0 1 mg/'" IDLH Physical description 500 mg/m* Colorless to paleyellow, odorless solid or crushed flakes 40 mg/m' Colorless to pale yellow odorless liquid or solid 'below 52 F) Chemical and physical properties MW BP SOL FI P IP Sp Gr flammability VP FRZ UEL LEL Incompatibilities and reactivities MW- 227 1 VP 0 0002 mm Strong oxidizers, BP 464*F MLT 176*F ammonia, strong (Explodes) UEL ? alkalis, combustible Sd(77*F) LEL 7 materials heat 0.01% [Note Rapid hearing FI P 7 will result In (Explodes) detonation ] IP I0 59ev Sp Gr 1 65 Combustible Solid (Class A Explosive) Measurement method (See Table 1) TenaxGC, Acetone, GC/TEA-EAP, OSHA [#44] MW 368 4 BP 770 F (Decomposes Sol Slight FI P 437 F IP 7 VP(77 FI 0 00002 mm FRZ 52 F UEL 7 LEL 7 Oxidizers Filter Diethyl ether GC FPD IV 50 3 7J NIOSH 5 mg/m* OSHAT none Sp Gr 20 Class MIS Compustibe Liquid NO Colorless send MW 245 3 VP 7 None reported BP 8B9*F MLT 261*F Sol Insoluble UEL 7 FI P 7 LEL? IP 7 60 eV None available NIOSH/OSHA 3 mg/m' Sp Gr 0 77 1000 mg/m' Colorless crystalline powder with a phenol like odor MW 326 3 BP 776 F So1(129 F) 0 002% FI P 428 F IP 7 VP(380 F) 1mm MLT 120 F UEL 7 LEL 7 Sp Gr 1 29 Combustible Solid None reported Filter Diethyl ether GC/FPD IV [#5038] Personal protection and sanitation (See Table 31 Skin Eyes Wash skin Remove Change Prevent skin contact P event eye contact When contam/Dai'y When wet or contam Daily [2 4 6 Tnnitrololuene] r fe& \asr' sum kenve ^-ange e S t, *-n*dC *^e -C i d \` ei wet . i o NR T ic"nocr ety -yspl ate Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact Daily Daily Tnphenylam ne] h' byes \dS" Sk,n Remove Cnar ge F F, A \' \? N [T ipnen, pnosphate, ABD00023047 Recommendations for respirator selection -- maximum concentration for use (MUC) (See Table 4) NIOSH 5 ma/iTi1 SA 12 Smjfm1 SA CP* 25 mg/m* SCBAF/SAF 500 mg/m3 SAF PO PP | SCBAF PD PP/SAF PD PP ASCBA Escape GMFOVHiE/SCBAE Route Symptoms (See Table S) Inh Abs Con Imtskin mucmemO liver damage jaun cyan sneez cough sore throat pea neur muse pain kidney damage cataract sens derm leucyt anemia cart ineg Health hazards Firstakt (See Table 6) Target organs (See Table 5) Eye Skin Breath Swallow Irnmmed Soap wash prompt Rasp support Medical attention immed Eyes skin respsy blood liver CVS CNS kidneys N'CSH/ObHA L o mg/m DM ng m DWXSCiSA p 5 mg rn SA CF PAPRDM 5 Tgr HiEF,SAT CF PAPRTHiE; SCBAF,SAF 40 mg/m' SA PD PP SCBAF PD PP'SAF =D PP ASCBA Escape MiEF'SCBAE TBAL Inn A.OS ol d St peri neur cramps m calves pares in feel cr hands weak tee *r st arop pa a Inh Ing Con In animats imt skin eye Skin B eath Swa iow r imrneo Soap wash' /m^eo Resp Supuuit Med ua a te^'io i n ned PNS CNS Skm Breath Swallow Iit immed Soap wash Reap support immed M'-SF OSt'/ 5ng P 3l ng HiE'DXSD SA -G ->C ", 5/ rrPAPRDM htis-T.r -iyrlf SCBAF S*F 10CC -g/1 SA PD PP SCBA PD PP SA' PD -J ASv BA ``sca^e h EF 'SC BAb nr Mi iO' ohangp-v r d ooc |Pl, eriryr es n an r 'ais mjsc weak ua a 3 ea f Swa o .v Rest vuppo t Medica1 atte ition rmed Chemical name CAS and RTECS Nos. guide Nos Synonyms trade names, and conversion factors Tungsten W Wolfram YO'USOOC i ijilt sOulm omp unlb is \ 324 yy iur/ms ar* fJcoe 10 > 3 upon the specific roiuble tun jste i to pounc ABD00023048 Exposure limits (TWA unless noted otherwise) IDLH NIOSH' ND [`Note The REL also applies tc other msoluDle lungsten compounds {as W)) OSHAT nor>e Nn,vl rng/'nJ Si ) mg/m5 N1 1 111* Physical description Hard brittle steei gray to tin white solid Chemical and physical properties -------- ----------------------- -------------------- ------ - FI P IP Sp, Gr flammability VP, FRZ UEL LEL MW 1839 BP 10 701F Sol insoluble FI P NA IP NA VP Omm (approx) MLT P170 F UEL NA LEL NA Incompatibilities and reactivities Bromine trifluonde chlorine trifluonde fluonne iodine pentafluonde Sp Gi 19 3 Combustible in the form of finely divided powder may ignite spontaneously PP-1 a'LL a i ^Qu< y Ji y Icp; Ml. hi J upon the sotv'i't su'ubie u er *; ouui d P upu hes .ar. oeoc tiling upon the speufic soluble tungsten compound 4 lS Measurement method (See Table 1) Filter Acid FAAS IV [#7074) F 'e Ac 0 is rc74 Tungsten carbide (cemented) WC/Co/Ni/Ti 1 11107-01-0 2 12718-69 3 3 37329-49 0 1 Y07350000 2 Y07525000 3 Y07700000 Turpentine C h,6iaoproxi 8006 64 2 Y08400000 1299 128 Cemented tungsten carbide Cemented WC HardmeUi [Note The tungsten carbide (WC) content is generally 85-95% & the cobalt content is generally 5 15% ] [1 85% WC 15% Co 2 92% WC 8% Co 3 78% WC 14% Co 8%TiJ Gumspirits Gum turpentine Spirits of turpentine Steam distilled turpentine Sulfate wood turpentine Turps Wood turpentine NIOSH Sec Appendix C OSHAT See Appendix C NlOSH/OSHA 100 ppm '560 mg/m!] 1 ppm 5 56 mg/m3 (approx) N D A mixture of Properties vary depending tungBten carbide upon the specific mixture cobalt and sometimes other metals & metal oxides or carbides 800 ppm c-olorless liquid with a characteristic odo' MW 136(approx) BP 309-338 F Sol Insoluble FI P 95 F IP ? VP 4 mm FRZ 58 to 76 F UEL > LEL 0 8% Sp Gr 0 86 Class IC Flammable Liquid Tungsten carbide Fluonne chlonne trifluonde oxides of nitrogen lead dioxide Nona available Strong oxidi2ers chlonne chromic anhydride stannic chlonde ehromyl chloride Char gcIfid IV [#1551] Personal protection and sanitation (See Table 3) Skit Eyes Wash skin Remove Change NR NR NR NR NR [Tungsten] Recommendations vary depending upon the specific compound [Tungsten <soiuD>e compounds as W)] Skin. Eyae WaaheMn. Remove. Ctwgr Prevent akin contact Prevent eye contact Whan contam/OaUy (M) Wien wet or content Deity [Tungsten carbide (cemented)] Skm Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam When wet (flanmi NR [Turpentine] ABD00023049 Recommendations forrespirator selection -- maximum concentration for use (MUC) (See Table 4) NIOSH 50 mg/m3 HiE/SA/SCBAF SCBAF PD PP/SAF PD.PP ASCBA Escape HIEF/SCBAE Health hazards ------- --------------------------------------------------------------------------------------------------------------------------------------- Route Symptoms Firstald Target organs (See Table 5) (See Table 6) (See Table 5| Inh trm eyes skin reap sys Ing diffuse pulm fib loss of Con appetite, nau cough blood changes Breath Swallow trrimmed Soap wash Fresh sir Medical attention rnmed Eyes skin reap ays blood NIOSH 10 mg/m1 HiE/SA 25 mglm3 SA CF 50 mg/m* HiEF/SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape HiEF/SCBAE inh Ing Con irnieyes skm resp sys in animals CNS disturbances Qiarr resp failure Denavior body weight piood changes Eye Skin Breath Swallow irnmmeo Water wash Resp support Medical attention immsa Eyes skin resp sys CNS Gl tract 325 NIOSH 0 25 mg Co/m DMA 0 5 mg Co/m1 DMXSQ*A/DMFu*/SA* 1 25mgCo/m SA CFVPAPRDM**/ PAPRDMFu* 2 5 mg Co/m3- HIEF/SCBAF/SAF 20 mg Co/m* SAF PD.PP SCBAF PD PP/SAF PD PP.ASCBA Eecase: HiEF/SCBAE NIOSH/OSHA 800 ppm SA CFc/PAPROVE/CCRFOV/ GMFOV/SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Inh Irrtt eye*, skin reap sys Ing possible skm sens to Con cobalt, nickel diffuse pulm fib loes of appetite neu cough blood changes ts, Breath Swallow Tungsten carbide (cemented) containing NICKEL 4 SCBAF PO PP/SAF PD.PP ASCBA Escape HiEF/SCBAE Inh Abs ing Con Imteyes skin nose throat head verb convuls skin sens nema album kidney damage abdom pain nau vomit diarr chemical pneu (aspir liq> Eye Skin Breath Swallow Irrlmmed Soap wash Freeh air Medical attention enmed Eyes skin, resp sys, blood Irrimmed Soap wash prompt Resp support Medical attention immed Eyes skm resp sys CNS kidneys 326 Chemical name structurertormula, CAS and RTECSNos and DOT ID and guide Nos Synonyms trade names and conversion factors f-Undecanelhiol CHjfCHjljjSH 5332-52 5 Undecyl mercaptan 1228 131 Uranium imsoioDle compounds as Uj U (Metal) 7440-51 1 (Metal' YR3490000 i Metal < 2979 162 (Metal Pyrophoric) Uranium (soluble compounds asU) 1 ppm = 7 71 mg/m* Uranium metal Uranium 1 Synonyms of other insoluble uranium compounds vary depending upon the specific compound Synonyms vary depending upon the specific soluble uranium compound Exposure limits ITWA unless noted otherwise) NIOSH C 0 5 ppm (3 9 mg/m5) [15-min] OSHA none NIOSH Ca See Appendix A 0 2 mg/m3 ST 0 6 mg/m3 OSHAT 3 25 mgim3 NIOSH Ca See Appendix A 0 05 mg/m5 OSHA 0 05 mg/m5 ABD00023050 IDLH Physical description NO Liquid Chemical and physical properties MW BP SOL FI P, IP Sp Gr flammability VP FRZ UEL LEL MW 188 4 BP 495*F Sol Insoluble FIP ? IP 7 VP 7 FRZ 27'F UEL 7 LEL 7 Incompatibilities and reactivities Measurement method (SeeTable 1) Oxidizers, reducing agents strong ecus &bases alkali metals None available Sp Gr 0 84 Combustible Liquid Ca (10 mg/m3 (as U)] Metai Silver white malleable ductile lustrous solid (Note Weakly radioactive ] MW 238 0 VP 0 mm Carbon dioxide BP 6895 F (approx) carpon tetrachloride Sol Insoluble fl P NA MLT 2097 F UEL NA nitric acid fluorine [Note Complete IP NA LEL NA coverage of uranium MEC 60 g/m3 metal scrap with oil is essential for prevention of fire 1 Sp Gr 19 05 (Metal) Metal Combustible Solid especially turnings and powder None available Ca [10 mg/m5 (as 0)1 Appearance and odor Properties vary depending Urertyl nitrate vary depending upon upon the specific soluble combust!tries the specific uranium compound Uranium hexafajoride soluble uranium water compound Nona avalabio n vaieraidehyde CH3(CHj)3CHO 110-62 3 YV3600000 2058 129 Amyl aldehyde Pentanaf Valeral Vaieraidehyde Valerio aldehyde 1 ppm = 3 53 mg/m' NIOSH 50 ppm (I75mg/m3) See Appendix C (Aldehydes) OSHAT none ND Colorless liquid with a strong acrid pungent odor MW 86 2 SP 217 A Sol Slight FI P 54rF IP 9 82 eV VP 26 mm FRZ 133 F UEL 7 LEL 7 None reported Sp Gr 0 81 Class IB Flammable Liquid XAD 2 ''oluene GC/FID IV (#2536) Personal prott lion and sanitation (See Tsbn o' Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam When wet (flamm) NR [1-Undcanethiol] Skin Eyes Wash sum Rerno-e change Provide Prevenl skm contact Preven' eye contact Wnei am DaiK /he wet o' .ontarr Cai Eyewash [Uranwm as U}] Skin ViSshskln Remove Change Provide Prevent skm contact Prevent eye contact When contam/Daity Wien wet or contam Daily Eyewash fUF,) Quick drench [Uranium (soluble compounds as U)] Skin Eyes Wash skin Remove Change Provide Prevent skm contact Prevent eye contact When contam When wet (flamm) NR Eyewash Quick drench [n Valeraidehyde] ABD00023051 Recommendations, for respirator selection -- maximum concentration for use |MUC) (See Table A) Route Symptoms (See Table 5) NIOSH 5 ppm CCROV/SA 12 5 ppm SA CF/PAPROV 25 ppm CCRFOV/GMFOV/PAPRTOV/ SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMfOVfSCBAE Inh Abs Ing Con Irriteyes skin reap sys conf dizz head draw nau vomit weak convuls Health hazards First aid (See Table 6) tz Breath Swallow Irr immed Resp support Medical attention immed Target organs (See Table 5) CNS NIOSH SCBAF PD PP'SAF PD PP ASCBA Escape HiEF'SCBAE NIOSH SCBAF PD PP/SAF PO PP ASCBA Escape(Haildes) GMFAGHiE/SCBAE scapa(Non halides) HIEF/SCBAE TBA, Inh Ing ( on Derm kidney damage blood changes n anmals '.ng ,mpr node damage Po'entia1 for cancer ' a esul' of alpha emitting properties & radioactive decay products (e g radon) bye Sum Bean Swa low ir immed Soap wash prompt Resp support Medical attention im fried Skm moneys Done marrow 'ympnatic sys [lung canoe ] 327 rh Lac coni short breath Ing cough cnest rales nau Con vomit, skin burns RBC casts in unne album high BUN, {care] Potential for cancer Is a result of alpha emitting properties & radioactive decay products (e g radon) inn Ing Con irriteyes skin nose throat iC Breath Swallow Immmed Water flush immed Resp support Medical attention immed Resp sys blood iivar kidneys lymphatics sys akin bone marrow [lung cancer] Eye Skin Breath Swallow irr immed Soap flush immed Resp support Medical attention immed Eyes skin resp sys Chemical name CAS and RTECS Nos and DOT ID and guide Nos Synonyms trade names and conversion factors Vanaoium dust v2o5 "1314-62 1 VW2450000 2862 151 328 1314 62 ' yw24so::c 2862 151 Vegetable oil mist 68956-66-3 YX1850000 Divanadium pentoxide Vanadic anhydride Vanadium oxide Vanadium pentaoxide Other synonyms vary depending upon the specific vanadium compound Divanadiu'" oentox de Vanad'C anhyd ide vanadium cxide Vanadium pentaoxide Other synonyms vary depending upon the specific vanadijn" compound Vegetable mist Vrnyi acetate CH =CHOOCCH 108 05 4 AK0875000 130 129P 1 Acetoxyethyiene E henyi acetate Etheny ethanoa'e VAC Vinyl acetate monomer Vinyl ethanoate 1 ppm = 3 52 mg/m1 ABD00023052 Fxposure limits (TWA unless noted otherwise) IDt H Physical d> scription NIOSH' 35 mg/m3 Yellow orange C 0 05 mg V/m3 (as V) powder or dark [15-min] gray odorless ["Note Yhe REL flaxes dispersed applies to all in atr vanadium compounds except Vanadium metal & Vanadium carbide (see Femvanadium dust) J OSHAT C 0 5 mg VjO^rn3 (resp) Chemical and physical properties MW BP SOL FI P, IP, Sp Gr, flammability VP FRZ UEL LEL Incompatibilities and reactivities MW ret 9 BP 3182'F (Decomposes) Sol 0 8% FI P NA IP NA VP 0 mm (approx) MLT 1274"F UEL NA LEL NA Littitum ctikmne trifluoride Sp Gr 3 38 Noncombusbbte Solid but may increase intensity of fire when in contact with combustible matenals Measurement method (See Table 1) Filter IV [#7504] [Also #7300 Elements] N OSu u u J: ^ j (15 mir] ~ OSHAt C 0 1 mg v Or/m3 35 mg'r 1 as - ne , d video cam-.. ate dispersed r arr MW >8 9 BP 3 82 F Decomposes/ Sol 0 8% 1 IP NA IP NA VP 0 mm app ox UEL NA LCL NA Sp Gr 3 36 NoncomDuStiDle Solid Lithium chiorine f,,c de F"er [#7504] Elements] NIOSH 10mg/m3 (total) 5 mg/m; (rasp) OSKA 15 mg/m3 (total) S mg/m3 (resp) ND An oil extracted MW varies VP ? from the seeds BP ? FRZ > fruit or nuts of So) Insoluble UEL ? vegetables or FIP 323-540*F LEL "> other plant matter IP ? Sp Gr 0 91-0 95 Combustible Liquid None reported Filter non Grav IV [Particulates NOR #0500 (total) #0600 NIOSH C 4 ppm '5 mgrm3, , IS mim OSHAT none ND Colorless liquid with a pleasant fru'ty Odor (Note Raw material tor many poly vinyl resins ] MW 86 1 BP 162 lSol 2% Fl P 18 4 IP 9 19eV VP 83 mm FRZ 136 F UEL 13 4% LEL 2 6% Sp G' 0 93 Class 10 Flammable Liquid Acids bases silica gel alumina oxidizers azo compounds ozone lNote Usually con tams a stabilizer (eg hydroquinone or diphenylaminei to prevent polymer za lion Carbon mol sieve CH CL XtelhanoJ GC/FlO IV [#1453] Personal protection (See Table Sion Eyes Wash skin Remove Change. Prevent skin contact Prevent eye contact Whencontam When wet or contam NR (Vanadium dust] Skin Eyes Wash skin Remove Change NR NR NR NR NR [Vanadium 'umej Skin Eyes Wash skin Remove Change NR NR NR NR NR [Vegetable od mist] Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact Whencontam When wet or contam NR Eyewash Quick drench [Vmyi acetate] ABD00023053 Recommendations for respirator concentration for use (MUC> (See Table 4) NIOSH (as V] 0 5 mg/m1 HjE*/SA' 1 25 mg/m1 SA.CF*/PAPRHiE* 2 5 mg/m1 HCF/PAPRTHiE'/ SCBAF/SAF 36 mg/m1 SAF PO PP f SCBAF PD.PP/SAF PD PPASCBA Escape HIEF/SCBAE Route Symptoms (See Table 5) Hi imt eyes, skin throat; Ing green tongue, metallic Con taste eczema, cough tine rales wheez, bron dysp Health hazards First aid (See Table 6) Target organs (See TabTe 5) Eye Skin Breath Swallow- Irr Homed Soap wash prompt Reap support Medical attention Immed Eyes skin resp sys NIOSH (as V'i 0 5 mg/m 1 HiE'/SA 25 mg/m1 SACF /PAPRHiE" 2 5mg/m- HicF,PAPR7HiE SCBAF'SAF 35 mg/mJ bAF PD PP SCBAF PD PP'SAF PD RPASCBA Escape HiEF'SCQAE Inh C on irrit eyes threat green tongue metallic taste .ough fine ales wheez ornn oysP eczema Breath Resp support Eyes skin resp sys TBAU Inh Imt eyes akin resp sys lac Con Eye Breath Irr Immed Fresh air Eyes skin rasp sys NIOSH 40 ppm CCROV /SA' 100 ppm SA CF7PAPR0V 200 ppm CCRFOV/GMFOV/PAPRTOV / SC8AF/SAF 4000 ppm SA PD PP | SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Inh Ing Con Irrit eyes skin nose throat hoarseness cough loss of smell eye burns skin blisters Eye Skm Breath Swallow Irr immed Soap flush immed Resp support Medical attention immed Eyes skin resp sys Chemical name, structure/formula CAS and RTECS Nos guide Nos Synonyms, trade names, and conversion factors Vinyl bromide CKj-CHBr 593-90-2 KU3400000 Bromoethyten* 330 1035 HOP nyl chloride r~H -CHCl 5-01-4 KU9625Q00 '086 'i6P Vinyl cyclohexene dioxide chco2 106-87-0 RN0640000 Vinyl fljonde CH =CHF 75 02 5 YZ7351000 1 ppm * 4.36 mfl/m* Cbforoetftene Chioroethylene Ethylene monochlonde Monochloroethene Monochloroethylene VC Vinyl chloride monomer (VCM) 1 ppm = 2 56 mg/m3 1-Epo*y*ihyt-3,4-epoxycyclohexane, A-VInyloydohaxana dlepoxWe, 4-VmyM-cyOohaxane dkudda 1 ppm 5 73 mgfm3 Fluoroethene Fluoroethylene Monofluoroethylene Vmyi fluonde monomer i860 116P l ppm = 1 89 mg/m3 ABD00023054 Exposure knits (TWA unless noted otherwise) IDLH NIOSH Cat See Appendix A OSHAf none Ce [NO] NIOSH Ca See Appendix A [Use 1910 1017) OSHA(1910 1017] 1 ppm C 5 ppm [15-min] Ca [N D ) NIOSH Ce Appendix A 10 ppm . (80 mgrtn*) [sktn] OSHAf Ce IN D ] Physical description Chemical and physical properties MW BP, SOL FI P IP, Sd, Gr flammability VP, FR2 UEL LEL Colorless flas or liquid (below 0*F) with e pleesent [Note Shipped ae a liquefied compressed ope wtth01%pbut added to prevent polymerization ] MW 1070 BP 60*P Sol fneofobte RP-NA (Gas) IP 9.80 eV VP 14atm FR2 -219F UB-15% LEL 9% RGasD 379 Sp Or 1,49JUquW atflO'F) FiammaWeGai Class IA Flammable Liquid Colorless gas or liquid (below 7*F)witha pleasant odor at high concentrations [Note Shipped as a liquefied compressed gas MW 62 5 BP 7 F Sol(77*Fj 01% HP NA (Gas) IP 9 99 eV RGasD 2 21 Flammable Gas VP 3 3 atm FRZ 256F UEL 33 0% LEL 3 6% Coteries* liquid MW 1402 BP 441*F Sol High FI P(oc) 230*F IP ? VP-01mm FRZ -184*F UEL 7 LEL? SpGrl 10 Class (1(8 Combustible Liquid NIOSH 1 ppm C 5 ppm (usel910 1017] OSHA none N0 Colorless gas with a faint ethereal odor [Note Shipped as a liquefied compressed gas ] MW 46 1 BP 98'F Sol Insoluble FIP NA (Gas) IP 10 37eV VP 25 2 atm FRZ 257 F UEL 21 7% LEL 2 6% RGasD 1 60 Flammable Gas Incompatibilities and reactivities Measurement method (See Table 1) Strong oxidizers [Note May polymenzs In umltgM ] Char, Ethanol, IV [41009] Copper oxidizers Char(2) aluminum peroxides CS iron steel [Note Polymerizes IV in air sunlight or heat unless stabilized by inhibi tors such as phenol Attacks iron & steel in presence of moisture ] Alcohols amines, water [Note Slowly hydrolyzes In water ] None None reported [Note Inhibited with 0 2% terpenes to prevent polymenza tion | None available Personal protection (See Table 3) Skm Eyes Wash skin Remove Change Prevent skin contact (liq) Prevent eye contact (liq) When contam (liq) When wet (flamm) NR [Vinyl bromide] Skin Fyes Wash skin Remove Change Provide Frostbite Frostbite NR When wet (flamm) NR crostbite [Vinyl chloride] Skbt Eye*. WeshsWn Remove. Change. Provide Prevent skm contact Prevent eye contact When contam When wet or contam NR Eyewash. Quickdrench [Vinyl cyclohexane dioxide] Skin Eyes Wash skm Remove Change Provide Frostbite Frostbite NR When wet (flamm) NR Frostbite (Vinyl fluonde] ABD00023055 Recommendations for respirator concentration for use (MUC) (See Table 4) NIOSH * SCBAF PD,PP/SAF PO PPASCBA Escape GMFOV/SCBAE Route Symptoms (See Table S) Wi Irrrt eyes, skin, dlzz, Ing conf enco, naroo, nau (liq) vomit; Hq frostbite Con (care] (hq) Health hazards First aid (See Table 6) Target organs (See Table S) i& Breath. Swallow Irr nomad (liQ) Water ftuehimroed Medical mndon immed(Bq) Evaa.Mn.CNS, liver [In animate, liver & lymphnode tumors] NIOSH X SCBAF PD PP/SAF PD PP ASCBA Escape GMFS/SCBAE \nh Con (iiq) Weak abdompain Gl bleeding enlarged liver pallor or cyan of extremities liq frostbite (care] lion Breath Frostbite Reap support lymphatic ays [liver cancer] NioSH V SCBAF PD.PP/SAF PO.PPtASCBA Escape GMFOV/SCBAE kh InanlnMsrlPteya. Abe akin, mp aye, MtaJar j"B atrophy; iaupdn, nedvtyimw;' '| Brettft. Can akin sane, (earoj . Swetfaw immed X <,r rap****. kh; ` RvwAnal&Mh ' tufiwi] NIOSH 10 ppm CCROV/SA 25 ppm SACF'PAPROV 50 ppm CCRFOV/GMFOV/PAPRTOVf SCBAF/SAF 200 ppm SAP PD PP SCBAF PD PP/SAF PD PP ASCBA scape GMFOV/SCBAE Inh Con t'lR) Head dizz conf inco narco nau vomit Iiq frostbite M ic, Breath ,. Frostbite Frostbite Resp support CNS Chemical name stnjcture/formula and DOT ID and guide Nos WryUdene chloride CH,*CC^ 75-35-4 KVB276000 1303 129P Vinylidene fluonde CH =CF^ 75 38 7 KW0560000 Synonyms trade name*, and conversion factors 11-OCE, 1,1-Olchioroethene 1 1-CHcMoroethyiene, VDC Vinylidene chloride monomer Vinylidene dichiortde Drfluoro-1 1-ethylene 1 i Difluoroethene 1 1 Drtluoroethyiene Halocartion 1132A VDF Vinylidene difluoride 1959 116P Vinyl toluene 25M3-15-4 WL5075000 2SW-130P 5 VM & P Naphtha 0032 32-4 016180000 1271 128 1 ppm * 2 62 mg/m3 Etherytmethytoenzene, Methylstyrene, To^ethjwie Ifpm 4 S3 mg/m' Ligroin Painter* naphtha Petroleum ether Petroleum spmt Refined solvent naphtha Varnish maker* & painters naphtha Exposure nits (TWA unless noted otherwise) NlOSH Ca See Appendix A OSHAt none NIOSh i ppm C 5 ppm [use '910 1017] OSHA none NtOSH/QSHA 100 ppm (480 m&in3) ABD00023056 IDLH Physical description Ca [NO) Colorless liquid or gas (above t)9`F) with a ml/d, sweet, chloroform-like odor Chemical and physical properties MW BP, SOL FI P, IP,Sp Gr, flammability VP FRZ UEL LEL MW 96 9 BP 89*F Sof 0 04% FI P -2*F IP 10 00 eV VP 500 mm FRZ 189*F UEl 155% LEL 6 5% Sp Gr 1 21 Class IA Flammable Liquid N D Coioness gas with MW 64 C VP 35 x atm a tamt ethereal BP 122 F FRZ 227 F odor Sol Insoluble UEL 21 3% [Note Shipped as Fl P NA (Gas, LEL 5 5% a liquefied iP 10 29 eV compressed gas ] 400 ppm Colorless liquid with a strong, disagreeable odor RGasD 2 21 Flammable Gas MW 1182 BP 33fl*F Sot 0 009% FIP-12TF IP 8 20V VP 1mm FRZ.-1WF UEL. 11 0% LEL 08% NlOSH 350 mg/m3 C 1800 mg/m3 |15-mm] OSHAT none ND Clear to yellowish liquid with a pleasant aromatic odor SpGr 069 Class tl Combustibte Liquid MW 87 114 (approx) BP 203 320*F Sol Insoluble FI P 20-55 F IP ' VP 2 20 mm FRZ 7 UEL60% LEL1 2% Sp Gr(60 F) 0 73 0 76 Class IB Flammable Liquid Incompatibilities and reactivities Measurement method (See Table 1) Aluminum sunlight Char air copper heat CS, [Note Polymerization GC7FID may occur if exposed IV to oxidizers [#1015] chlorosulfonic acid mine acid or oleum Inhibitors such as the monomethyl ether of hydroquinone are added to prevent polymerization ] Oxidizers alum num chloride [Note Violent reaction with hydrogen chlonde when heated under pressure) None available Oxidizers, peroxides, strong sods iron or aluminum salts [Note Uauatiy inhibited with tart-butyl catechol to prevent polymerization.} Char GC?FlO IV [#1501 Aromatic Hydro carbons] None reported Char (Note VM&P Naphtha isCS, a refined petroleum GC^FID solvent predominantly IV C7 C which is [#1550 typically 55% Naphthas] paraffins 30% mono cycloparaffins 2% dicydo- paraffins& 12%alkylbenzenes ] Personal protection (See Table 3) Skin V^ashskin Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet (flamm) NR Eyewash Quick drench [Vtnybdene chloride] Skin Eyes Wash skin Remove Change Provide Fros'O 'e Frostbite N ft When wet (flamm) NR Frostbite [Vinylidene fluoride) Skin. Eyas. WaehskJn Remove Change Prevent akin contact Prevent aye contact When contam When wet or contam NR (Vinyl totuene] Skin Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam When wet (flamm) NR [VM & P naphtha] ABD00023057 Recommendations for respirator concentration for use (MUC) (See Table 4) Route Symptoms {See Table 5) NfOSH 4 SCBAF PD PP/SAF PD,PP ASCBA Escape GMFOV/SCBAE Irtl Irrlt eyes skin, throat, Abs dlzz head nau, dysp, Ing liver kidney dysfunc Con pneultla [care] Health hazards first aid (See Table 6) Target organs (See Tables) 1C Breath Swallow Irr immed Water flush Immed Resp support Medical attention Immed Eyes skin, rasp ays, CNS, liver kidneys ftnansnals liver & kidney tumors] NIOSH 10 ppm CCROV/SA 25 ppm SA CF/PAPROV 50 ppm CCRFOV/GMFOV/PAPRTOV/ SCBAF/SAF 200 ppm SAF PD PP SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE mb Con (liq> Dizz head nau fiq frostbite NIOSH/OSHA 400 ppm CCROV/PAPROV/GMFOW SA7SCBAF SCBAiF PO.PP/SAF POPP ASCBA Escape GMFOV/SCBAE hh 5? Con Irrtt eye*, skin, upper rasp ays, drew; In anknalr narco Eye Skin Breath Frostbite Frostbite Resp support CNS 333 Breath Swallow- Irr Immed Soap flush prompt Reap support Medical Mention immed Ejres, sWn, resp sys. NIOSH 3500 mg/m5 CCROV/SA 8750 mg/m3 SA CF/PAPROV 17 500mg/m3 CCRFOV/GMFOV/ PAPRTOV/SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE Inh Ing Con Irnt eyes upper resp sys derm CNS depres chemical pneu (aspir liq) Eye Skin Breath Swallow Irr immed Soap wash prompt Resp support Medical attention immed Eyes skin resp sys CNS Chemical name tmctura/formuia, CAS and RTECSNos and DOT 10 and guide Nos Synonyms, trade names, and conversion factor* Exposure Imits (TWA unless noted otherwise) Wwtartn c*H*o4 SI-81-2 ON4MOOOO 3-(a-Aoatooyl)-b*nzyt4-tydroKycoumarfn 4-HyOroxy-3-(3-oxo-1-pbany1 butyl)-2H-1-banzopyrar>2-ons, WARP NIOSHAJSHA OlmgAn* ABD00023058 IDLH Physical description lOOmg/m3 Colorless odorless crystalline powder (rodentlcide] Chemical and physical properties MW BP, SOL FI P IP. Sd, Gr, flammability VP FRZ UEL, LEL MW- 306 3 BP Oacompoaea Sof 0 002% F(P ? IP ? VP(71*Fy 0 09 mm MLT 322`F UEL ? LEL 7 Welding fumes 334 ZC2550000 Synonyms vary depending upon the specific component of the welding fume* NIOSH Ca See Appendix A OSHAT none Ca IN D 1 Sp Gr ? Combustible Solid Fumes generated by the process of joining or cutting Pieces of metal by heat pressure or both Properties vary depending upon the specific component of the welding fumes Incompatibilities and reactivities Strong oxidizers Varies Measurement method (See Table 1) Filter Methanol HPLC/UVD IV [*S002] Filter Acid ICP IV [#7300 Elements] Wood dust ZC9M0OOO o-Xylene C^CH,), 96-47-6 ZE2450000 1307 130 Hart wood dust, $cfl wood dust. Western r*d cedar dust 1 2 Danethytbenzene ortho-Xylene 0 Xylol 1 ppm = 4 34 mg/m3 NOSH Ca See Appendix A 1 mg/m5 OSHAT ISmgfrn5 (total) Smgnn* (reap) NIOSH 100 ppm (435 mg/m3) ST 150 ppm (655 mg/m5) OSHAT 100 ppm (435 mg/m3) Ca JND) Oust from various types of wood 900 ppm Colorless liquid with an aromatic odor MW varies BP NA Sol 7 FIP NA IP NA VP Omm JlW UEL NA LEL NA Sp Gr 7 Combustible Solid MW 106 2 BP 292*F Sol 0 02% FI P 90`F IP 8 56 eV VP 7mm FRZ 13"F UEL 6 7% LEI 0 9% Sp Gr 0 66 Class IC Flammable Liquid None reported Strong oxidizers Strong acids Filter none GravIV (#0500 Particulates NOR (total)] Char GcVlD IV (#1501 Aromatic Hydro carbons] Personal protection and sanitation (See Table 31 Sion Eyes Wash skin Remove Change Prevent skin contact NR Whencontam When wet or contam Daily [Warfarin] Sk'n byes Wash skm Rt'^ove change NR N Ft NR NR NR [Weldi ig ft rues' Skin Eyes Wash skin Remove Change NR NR NR NR NR [Wood dust] Skin Eyes Wash skin Remove Change Preven1 skm contact Prevent eye contact When uontdm When wet tflamm) NA :C Xylene ABD00023059 Recommendations for respirator selection -- maximum concentration for use (MUC i (See Table 4) NIOSH/OSHA 0 5 mg/m3- DM 1 mg/m3 OMXSQ/SA 2 5 mg/m3- SA CF/PAPRDM 5 mg/m3 HiEF/SAT CF/PAPRTHiE/ SCBAF/SAF lOOmg/m3- SA PD PP SCBAF PD PP/SAF PD PP ASCBA Escape HiEF/SCBAE Route Symptoms (See Table 5) Inh Abs Ing Con Heme back pam hematoma arms legs epia, bleeding lips mucmemb hemorr abdom pain, vomit fecal blood, petechial rash, abnor hematologic indices NIOSH SCBAF PD PP/SAF PO PP ASCBA Escape GMFOVHiE/SCBAE Inh Con Symptoms vary depending upon the specific component of the welding 'umes metal rume fever flu like symptoms dysp cough muse pam fever cn lis interstitial pneu [ca c] Health hazards First aid (See Table 6) -- & Breath Swallow Irnmmed Soap wash promp Reap support Medical attention Immed Target organs (See Table S) Eye Skin Breath Irr immed Soap wash Resp support Eyes skin respsys CNS [lung cancer] NtOSH SCBAF PD PP/SAF PD PP ASCBA Escape HIEF/SCBAE hh Con Irrtteyes, opts derm reap hyperMnefllvitygranutometous pneurtfs asthma cough wheez. sinusitis, prolonged cokts, [care] Hdri Breath Irr Immed Soap wash Fresh air Eyes skm respsys [nasal cancer] 335 NlOSH,OSHA Inh 900 ppm CCROV /PAPROV'/SA /SCBAF Abs SCBAF PD PP/SAF PD PP ASC8A Ing Escape GMFOV/SCBAE Con Irrit eyes skin nose throat dizz excitement drow inco staggering gait corn vacuolization dhor nau vomit abdom pam derm Eye Skin Breath Swallow Irr immed Soap wash prompt Reap support Medical attention immed Eyes skin resp sys CNS Gl tract blood liver kidneys Chemical name, structure/formula CAS andRTECSNo*, and DOT ID and guide Nos Synonyms trada names and conversion factors Exposure hrrwts (TWA unless noted otherwise) m-Xytene 108-38-3 ZE2276OQ0 336 1307 130 p Xylene CsH^CH^j 106 42 3 ZE2625000 1307 130 m-Xytam a, a -diamine CtH4(CHjNHj)j 1477-55-0 PF6B7QOOO 1,3-Dimathylbenzena, meta-Xyiene m-Xylol 1 ppm * 4 34 mg/m3 NiOSH 100 ppm (435 mg/m5) ST 150 ppm (656 mg/m3) OSHAf 100 ppm (435 mg/m5) 1 4 Dimethylbenzene para Xylene p Xyiol NIOSH 100 ppm 435 mg;m3i ST 150 ppm (655 mg/m3) 1 ppm = 4 34 mg/m3 OSHAt 100 ppm (435 mg/m3) 1 3-bts(Aminomethyl)benzene 1,3-Baraanadimethanamine hiXDA, nvPhanylanabWmattiytamine) m-Xyfylanadiamlna NIOSH [skin] OSHAT none Xylidme (CH5),C,H,NHj 1300 73 S 2E8575DD0 1711 151 Ammodimethylbonzene Ammoxylene Dimethylaminobenzene Dimethylaniime Xylidme isomers te g 2 4 Dimelhylamlinej [Note Dimethylaniime is also used as a synonym for N N Dimethylaniime ] 1 ppm = 4 96 mg/m3 NIOSH 2 ppm (10 mg/m3) [skin] OSHAT 5 ppm (25 mg/m3' [Sk n ABD00023060 IDUH Physical description 900 ppm Colorless liquid with an aromatic odor 900 ppm Colorless uquid with an aromatic odor [Note A solid Deiow 56 F ] ND Colorless liquid 50 ppm Pale yellow to brown liquid with aweak aromatic amine like odor Chemical and physical properties MW BP. SOL PIP, IP Sp Gr flammability VP FRZ UEL, LEL MW 106 2 BP 282T Sol Slight FI P 82V IP 8 56 eV VP 9mm FRZ -54"f UEL 7 0% LEL 11% Incompatibilities and reactivities Strong oxidizers strong acids Sp Gr 0 86 Class 1C Flammable Liquid MW 106 2 BP 281 F Sol 0 02p/ FI F 81 F IP 8 44 eV VP 9 mm FRZ 56`F UEL 7 0/ *L 1 1% Strong oxidizers strong acids Sp Gr 0 86 Class 1C FlammaOle Liquid MW- 1362 BP 477*F Sol Miscible FI P 243*F IP 7 VP(77*F) 0 03 mm FRZ 58*F LEL ? None reported Sp Gr 1 032 Class Ills Combustible Liquid MW 121 2 BP 415-439 F Sol Slight FI P 206F (2 3 ) IP 7 $5 ev (2 4 i 7 30 eV (2 6) VP <1 mm FRZ 33F UEL 7 LEL 1 0% (2 3 ) Strong oxidizers hypochlorite salts Sp Gr 0 98 Ciass HIB Combustible Liquid i2 3 ) Measurement method (SeeTable 1) Char GcVlD IV I#1501 Aromatic Hydro carbons] Char GC)FID [#1501 Aromatic Hydro carbons] None available Si gel Ethanol GC/FID IV [#2002] Personal protection and sanitation (See Table 3) Skm Eyes Wash skin Remove Change Prevent skin contact Prevent eye contact When contam When wet (flamm) NR [m-Xytene] Skin Eyes Wash skm Remove Change Prevent skin contacl Prevent eye contact When contam When wet (flamm, NR [p Xylene] Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam When wet or contam NR Eyewash Quick drench [m-Xylenea a `-diamine] Skin Eyes Wash skin Remove Change Provide Prevent skin contact Prevent eye contact When contam Wher wet or contam NR Eyewash Quick drench IXylidme] ABD00023061 Recommendations for respirator concentration for use (MUCj (Sea Table 4) Route Symptoms (See Table 5) NfOSH/OSHA Mi 900 ppm CCROV*/PAPRGV*/SA*/$CBAFAbs SCBAF PD,PP/SAF PD.PP ASCBA Escape OMFOV/SCBAE Ing Con tmt eyes skm nose throat dizz, excitement, Prow inco, staggering gait com vacuolization anor nau, vomit, abdom pain, derm Health hazards First aid {See Table 6) Target organs ($se Table 6) Breath Swallow' irr waned Soap wash prompt Re> support Mealed attention immed Eyes skin reap ays, CNS, Gl tract, Mood, liver ktdneya NIOSH/OSHA Inh 900 ppm CCROV/PAPROV ISAISCBAF Abs SCBAF PD PP/SAF PD PP ASCBA Ing Escape GMFOV/SCBAE Con I rit eyes skin nose throat dizz excitement Prow inco staggering 9ait corn vacuolization anoi nau vomit abdom pain derm Eye Skin Breath Swallow Irr immed Soap wash prompt Resp support Medical attention immed Eyes skin respsys CNS Gl tract blood liver kidneys 337 TBAL Inh Abs [09 Con In animals imtayes skin livsr kidney lung damage idn Breath Swallow Irr tmmed Water flush Immad Reap support Medical attention immed Eyes Man,respsys, Hver kidneys NIOSH 20 ppm CCROV/SA 50 ppm SA CF/CCRFOV/GMFOV/ PAPRCWSCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape GMFOV/SCBAE inh Abs Ing Con Anoxia cyan methemo lung liver kidney damage Eye Skin Breath Swallow Irr immed Soap wash immed Resp support Medical attention immed Resp sys blood liver kidneys CVS Chemical name structure/formula CAS and RTECSNos and DOT ID and guide Nos Synonyms trade names and conversion factors Yttrium Y 7440-66-5 ZG2980000 Ytinum metal 338 ZnCl, 'b40 8b 7 ZH140003L ZnO 1314-13-2 ZH4810000 1516 143 Zmc stearate 557-05-' ZH52C3CDC o X o Zinc dichiorioe tune Zinc peroxide Dibasic zmc stearate Zmc distearale Zmc salt o' stearic acid Exposure Mruts (TWA unless noted otherwise) ABD00023062 IDLM Physical description NIOSHVOSHA' 1 mg/m3 600 mg/m' (as Y) (Note The REL and PEI. also apply to other yttnum compounds (as Y) ] Dark-gray to black odorless solid Chemical and physical properties MW BP SOL FI P IP Sp Gr flammability VP FRZ UEL LEL MW 68 9 BP 5301'F Sol Soluble in hot H-0 FI P NA IP NA VP 0 mm (approx) MLT 2732'F UEL NA LEL NA Incompatibilities and reactivities Oxidizers Measure ment method (See Table 1) Filter Acid ICP IV [#7300 Elements] MOSf S' 2 rngmi OSHAt mg/m 50 rrg m White par iCdate cisoersed m air NoncombustJbla Solid rn bulk tom MA 35 ~ 3P 35C F Sol '0 F j 435 ' P NA VP i, 'ir apprc ' MlT 554 = UEl NA _ti Na fVl SSSl J ^ p liter Wale OS HA ,#IC ,21 NIOSH 600 mg/m5 5 mg/m5 (fume/dusl) ST i0mg/m5(fume) C 15 mg/m3 (dust) White odorless solid OSHAT 5 mg/m5 (fume) 16 mg/m5 (total dust) 6 mg/m5 (resp dust) NIOScl 0 mg/m total 5 mg/m i resp OSHAt 1 5 mg,ml (total 5 mg/m5 Kespi n0 Sot* white powae with a sugr cnaractenstic oao Sp G 2 91 Nonco mDustibie Soi d MW 81 4 BP ? So!(64`F) 0 0004% FI P NA IP NA VP 0 mm (approx) MLT 3587 F UEL NA LEL NA Noncombustible Solid MW 632 4 So> insoluble F Pioc 530 F IP NA VP u m app l> Ml T 26b 1 UEi ut. 7 MEC 2C g'm Sp Or 1 '0 ,,o' 'bustcie Sn d Chlorinated rubber (at419*F) water [Note Slowly decomposed by water ] Filter r>on XRD IV [#7502] 3x l -eis J i te auCs No,e HydOl tiubit e repe s Adler j Fc nor e Urdv 1V [Paniruiales NOR #050C itotaij #C6C C resplj Personal protection and sanitation (See Table 3) Shin vSshsktn Remove Change NR NR NR NR NR [Yttrium) Skin Eyes Wash skin Remove Change NR NR NR NR NR [Zinc chloride fume) Shin Wash skin Remove Change NR NR NR. NR NR [Zinc oxide] Skin Eyes Wash skin Remove Change NR NR NR NR NR [Zinc stearate) ABD00023063 Recommendations for respirator concentration for use (MUC) (See Table 4) Route Symptoms (See Table 6) NIOSH/OSHA 5 mg/m1 DM 10 mg/m1 DMXSQ/SA 25 mg/m3- SACF/PAPROM 50 mg/m3- HiEF/SAT CF/PAPRTHIE/ SC8AF/SAF 500 mg/m1 SAPDPP SCBAF PO.PP/SAF PD.PP ASC8A Escape HiEF/SCBAE mh Intteyes In animals pulm Irrtt Con eye in), possible liver damage NIOSH/OSHA 10 mg/m3 DMFu'/SA' 25 mg/m3 SA CF*/PAPRDMFu 50 mg/m3 HiEF/PAPRTHiE*/ SCBAF/SAF SCBAF PD PP/SAF PD PP ASCBA Escape HiEF/SCBAE inn Con irrit eyes skin nose throat conj cough copious sputum dysp chest pain pulm edema Droncopneu pulm fID cor pulmonale fever cyan tachypnea skin bums Health hazards First aid (See Table 6} Target organs (See Table 6) & Breath. Swallow- Irrbnmad Soap wteh prompt rttwaSa. traned Eyea, raapeya, tsr - Breath Resp support Eyes skin resp sys CVS 339 NIOSH/OSHA 50 mgMt3- DMFu/SA 125 mg/m* SACF/PAPROMFu 250 mg/m3- HIEF/SAT CF/PAPRTHIE SCBAF/SAF 500 mg/m* SA PD PP SCBAF PO PP/SAF PD PP ASCBA IsMpa HIEF/8CBAE Inh Matal fume fever ehHIa, museache, nau,lever, dty throat oough, weak, less, metaibc taste, heed, blurred vision, low back pain, vomit fig; mat, Ugh* ehaat dysp, rales, deerpulmfuno TBAL Inh Ing Con Imt eyes skin upper resp sys cough Breath Rasp support Rasp sys Kr,, Breath Swallow irr immed Soap wash Fresh air Medical attention immed Eyes skin rsspsys Chemical name structure/formula, CAS and RTECSNos and DOT ID and guide Nos Zirconium compounds (asZr) Zr (Metal) 7440-67*7 (Metal) ZH7070000 (Metal) 1356 170 (powder wet) 1032 135 (scrap) 2006 135 (powder dry) Synonyms trade names and conversion factors Zirconium metal Zirconium Synonyms of other zirconium compounds vary depending upon the specific compound Exposure limits (TWA unless noted otherwise) ABD00023064 IDLH Physical description Chemical and physical properties MW 8P, SOL FI P IP Sp Gr flammability VP FRZ UEL LfcL Incompatibilities and reactivities Measurement method (See Table 1) NtOSH* 50 mg/m3 5 mg/m3 (as Zr) ST 10 mg/mJ [Note TheREl applies to all zirconium compounds (as Zr) except Zirconium tetrachionde J OSHAt 5 mg/m3 Metal Soft malleable ductile solid or gray to gold amorphous powder MW 91 2 VP 0 mm Potassium nitrate BP 6471*F (approx) oxidizers Sol Insoluble MLT 3375'F [Note Fine powder FI P NA UEL NA may be stored IP NA LEL NA completely immersed in water J Sp Or 6 51 (Metal) Metal Combustible but solid form difficult to ignite however powder form may ignite SPONTANEOUSLY and can continue burning under water Filter Acid ICP IV (#7300 Elements] 340 Personal protection and sanitation (See Table 3) Recommendations vary depending upon the specific compound (Zirconium compounds (as Zr)] ABD00023065 Recommendations for respirator concentration for use {MUC) (See Table 4} Route Symptoms (See Table S) NIOSH/OSHA 25 mg/m3- DM 50 mg/m3 DMXSQ/PAPRDM/HiEF/SAz SCBAF SCBAF PD PP/SAF PD PP ASCBA Escape NiEF/SCBAE Inh Con Skin lung granulomas in animals imt skin mucmemo X ray evidence of retention in lungs Health hazards First aid (See Table 6) S& Breath Swallow Irr immed Soap wash Reap support Medical attention immed Target organs (See Table 5) Skin reap ays 341 ABD00023066 APPENDICES 344 ABD00023067 APPENDIX A -- NIOSH POTENTIAL OCCUPATIONAL CARCINOGENS New Policy For the past 20 plus years NIOSH has subscribed to a carcinogen policy that was published m 1976 by Edward J Fairchild II Associate Director for Cincinnati Operations which called for nc detectable exposure levels for proven carcinogenic substances (Annals of the New York Academy of Sciences 271 200-207 1996) This was in response to a generic OSHA ruiemaking on carcino gens Because of advances m science and in approaches to risk assessment and risk management NIOSH has adopted a more inclusive policy NIOSH recommended exposure limits (RELs) will be based on risk evaluations using human or animal health effects data and on an assessment of what levels can be feasibly achieved by engineering controls and measured by analytical techniques To the extent feasible NIOSH will project not only a no-effect exposure but also exposure levels at which there may be residual risks This policy applies to all workplace hazards including carcinogens and is responsive to Section 20(a)(3) of the Occupational Safety and Health Act of 1970 which charges NIOSH to describe exposure levels that are safe for various periods of employment including but not limited to the exposure levels at which no employee will suffer impaired health or functional capacities or diminished life expectancy as a result of his work experience The effect of this new policy will be the development whenever possible of quantitative RELs that are based on human and/or animal data as well as on the consideration of technological feasibility for controlling workplace exposures to the REL Under the old policy RELs for mos* carcinogens were ABD00023068 non quantitative values labeled lowest feasible concentration (LFC) (Note There are a few exceptions to LFC RELs for carcinogens (eg RELs for asbestos formaldehyde benzene and ethylene oxide are quantitative values based primarily on analytical limits of detection or technological feasibility) Also in 1989 NIOSH adopted several quantitative RELs for carcinogens from OSHA's permissible exposure limit (PEL) update j Under the new policy NIOSH will also recommend the complete range of respirators (as deter mined by the NIOSH Respirator Decision Logic) for carcinogens with quantitative RELs In this way respirators will be consistently recommended regardless of whether a substance is a carcinogen or a non-carcinogen Old Policy In the oast NIOSH identified numerous substances that should be treated as potential occupational carcinogens even though CSHA night not have idennfied them as such In determining their carcino genicity NIOSH used the OSHA classification outlined in 29 CFR 1990 103 which states in part Potential occupational carcinogen means any substance or combination or mix ture of substances which causes an increased incidence of benign and/or malignant neoplasms or a substantial decrease in the latency period between exposure and onset of neoplasms in humans or tn one or more experimental mammalian species as the result of any oral respiratory or dermal exposure or 345 346 ABD00023069 any other exposure which results in the induction of tumors at a site other than the site of administration This definition also includes any substance which is me tabolized into one or more potential occupational carcinogens by mammals When thresholds for carcinogens that would protect 100% of the population had not been identi fied NIOSH usually recommended that occupational exposures to carcinogens be limited to the lowest feasible concentration To ensure maximum protection from carcinogens through the use of respiratory protection, NIOSH also recommended that only the most reliable and protective respira tors be used These respirators include (1) a self-contained breathing apparatus (SCBA) that has a full facepiece and is operated in a positive-pressure mode or (2) a supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary SCBA operated in a pressure-demand or other positive-pressure mode Recommendations to be Revised The RELs and respirator recommendations for carcinogens listed in this edition of the Pocket Guide still reflect the old policy This edition which contains other updated information, is long overdue, hence, it is published now rather than later Changes in the RELs and respirator recommen dations that reflect the new policy will be included in future editions ABD00023070 APPENDIX B -- THIRTEEN OSHA-REGULATED CARCINOGENS Without establishing PELs OSHA promulgated standards in 1974 to regulate the industrial use of 13 chemicals identified as potential occupational carcinogens (2-acetylaminofluorene 4-ammodiphenyl benzidine bis-chloromethyl ether 3 3 -dichlorobenzidme 4-dimethylaminoazobenzene ethyleneimme, meth-yl chloromethyl ether alpha-naphthyiamine beta-naphthylamme 4-mtrobiphenyl N-mtrosodimethylamme and beta-propiolactone) Exposures of workers to these 13 chemicals are to be controlled through the required use of engineering controls work practices, and personal protective equipment, including respirators See 29 CFR 1910 1003-1910 1016 for specific details of these requirements Respirator selections in the Pocket Guide are based on NIOSH policy, which considers the 13 chemicals to be potential occupational carcinogens 347 348 ABD00023071 APPENDIX C -- SUPPLEMENTARY EXPOSURE LIMITS Aldehydes (Low-Molecular-Weight) Exposure to acetaldehyde has produced nasal tumors in rats and laryngeal tumors in hamsters and exposure to malonaldehyde has produced thyroid gland and pancreatic islet cell tumors in rats NIOSH therefore recommends that acetaldehyde and malonaldehyde be considered potential occupational car cinogens in conformance with the OSHA carcinogen policy Testing has not been completed to determine the carcinogenicity of acrolein, butyraldehyde (CAS# 123-72-8) crotonaldehyde, glutaraldehyde glyoxal (CAS# 107-22-2) paraformaldehyde (CAS# 30525-89-4) propiolaldehyde (CAS# 624-67-9) propionaldehyde (CAS# 123-38-6), and n-valeraldehyde nine related low-molecular-weight-aldehydes However the limited studies to date indicate that these substances have chemical reactivity and mutage nicity similarto acetaldehyde and malonaldehyde Therefore, NIOSH recommends that careful consider ation should be given to reducing exposures to these nine related aldehydes Further information can be found in the NIOSH Current Intelligence Bulletin 55 Carcinogenicity ofAcetaldehyde and Malonaldehyde and Mutagenicity of Related Low-Molecular-Weight Aldehydes [DHHS (NIOSH) Publication No 91-112 ] Asbestos NIOSH considers asbestos (i e actinolite amosite anthophyllite chrysotile crocidolite andtremo- lite) to be a potential occupational carcinogen and recommends that exposures be reduced to the lowest possible concentration For asbestos fibers >5 micrometers in length NIOSH recommends a REL of 100,000 fibers per cubic meter of air (100 000 fibers/m3) which is equal to 0 1 fiber per cubic centimeter of air (0 1 fiber/cm3), as determined by a 400-liter air sample collected over 100 minutes and NIOSH Analyti cal Method #7400 ABD00023072 APPENDIX C -- SUPPLEMENTARY EXPOSURE LIMITS (Continued) As found in 29 CFR 1910 1001 the OSHA PEL for asbestos fibers (i e actinoiite asbestos amosite anthophyllite asbestos, chrysotile, crocidolite and tremolite asbestos) is an 8-hour TWA airborne concen tration of 0 1 fiber (longer than 5 micrometers and having a length-to-diameter ratio of at least 3 to 1) per cubic centimeter of air (0 1 fiber/cm3) as determined by the membrane filter method at approxi mately 400X magnification with phase contrast illumination No worker should be exposed in excess of 1 fiber/cm5 (excursion limit) as averaged over a sampling period of 30 minutes Benzidine-, o-Tolidine, and o-Diamsidine-based Dyes In December 1980, OSHA and NIOSH jointly published the Health Hazard Alert Benzidine- o-Toli- dine and o-Diamsidine-based Dyes In this Alert OSHA and NIOSH concluded that benzidine and benzidine-based dyes were potential occupational carcinogens and recommended that worker expo sure be reduced to the lowest feasible level OSHA and NIOSH further concluded that o-tolidine and o-dianisidme (and dyes based on them) may present a cancer nsk to workers and should be handled with caution and exposure minimized 350 ABD00023073 APPENDIX C -- SUPPLEMENTARY EXPOSURE LIMITS (Continued) Carbon Black NIOSH considers "Carbon Black" to be the material consisting of more than 80% elemental carbon in the form of near-sphertcai colloidal particles and coalesced particle aggregates of colloidal size that is obtained by the partial combustion or thermal decomposition of hydrocarbons The NIOSH REL (10hour TWA) for carbon black is 3 5 mg/m3 Polycyclic aromatic hydrocarbons (PAHs) particulate polycyclic organic material (PPOM) and polynuclear aromatic hydrocarbons (PNAs) are terms fre quently used to describe various petroleum-based substances that NIOSH considers to be potential occupational carcinogens Since some of these aromatic hydrocarbons may be formed during the manufacture of carbon black (and become adsorbed on the carbon black), the NIOSH REL (10-hour TWA) for carbon black in the presence of PAHs is also 0 1 mg PAHs/m5 (measured as the cyclohex ane-extractable fraction) The OSHA PEL (8-hour TWA) for carbon black is 3 5 mg/m3 Chioroethanes NIOSH considers ethylene dichloride, hexachioroethane, 1 1,2,2-tetrachioroethane and 1,1,2- tnchloroethane, to be potential occupational carcinogens Additionally NIOSH recommends that the other five chloroethane compounds 1,1 -dichloroethane ethyl chloride, methyl chloroform, pentachloroethane and 1,11 2-tetrachloroethane be treated in the workplace with caution because of their structural similanty to the four chioroethanes shown to be carcinogenic in animals ABD00023074 APPENDIX C -- SUPPLEMENTARY EXPOSURE LIMITS (Continued) Chromic Acid and Chromates (as Cr03), Chromium(ll) and Chromium(lll) Compounds (as Cr), and Chromium Metal (as Cr) TheNIOSH REL (lO-hourTWA)isO 001 mg Cr(VI)/m3forall hexavalent chromium [Cr(VI)] compounds NIOSH considers all Cr(VI) compounds (including chromic acid tert-butyl chromate zinc chromate and chromyl chloride) to be potential occupationalcarcmogens The NIOSH REL (8-hour TWA) is 0 5 mg Cr/mfor chromium metal and chromium(ll) and chromium(llt) compounds The OSHA PEL is 0 1 mg Cr03/m3 (ceiling) for chromic acid and chromates (including tert-butyl chromate witha skin designation and zinc chromate) 0 5 mg Cr/m3 (8-hour TWA)forchromium(ll) and chromium(lll) compounds and 1 mg Cr/m3 (8-hour TWA) for chromium metal and insoluble salts Coal Tar Pitch Volatiles NIOSH considers coal tar products (i e coal tar coal tar pitch or creosote) to be potential occupational carcinogens the NIOSH REL (10-hour TWA) for coal tar products is 0 1 mg/m3 (cyclohexane-extractable fraction) The OSHA PEL (8-hour TWA) for coal tar pitch volatiles is 0 2 mg/m3 (benzene-soluble fraction) OSHA defines "coal tar pitch volatiles" in 29 CFR1910 1002 as the fused polycyclic hydrocarbons that volatilize from the distillation residues of coal, petroleum (excluding asphalt) wood and other organic matter and includes substances such as anthracene benzo(a)pyrene(BaP) phenanthrene, acridine chrysene pyrene, etc 351 352 ABD00023075 APPENDIX C -- SUPPLEMENTARY EXPOSURE LIMITS (Continued) Coke Oven Emissions The production of coke by the carbonization of bituminous coal leads to the release of chemicallycomplex emissions from coke ovens that include both gases and particulate matter of varying chemical composition The emissions include coal tar pitch volatiles (e g , particulate polycyclic organic matter [PPOM] polycyclic aromatic hydrocarbons [PAHs], and polynuclear aromatic hydrocarbons [PNAs]) aromatic compounds (e g benzene and |3-naphthylamine), trace metals (e g , arsenic, beryllium cadmium chromium lead and nickel), and gases (e g , nitric oxides and sulfur dioxide) Cotton Dust (raw) NIOSH recommends reducing exposures to cotton dust to the lowest feasible concentration to reduce the prevalence and seventy of byssinosis the REL is <0 200 mg/m3 (as lint-free cotton dust) As found in OSHA Table 2-1 (29 CFR 1910 1000) the PEL for cotton dust (raw) is 1 mg/m3 for the cotton waste processing operations of waste recycling (sorting blending cleaning and willowmg) and garnettmg PELS for other sectors (as found in 29 CFR 1910 1043) are 0 200 mg/m3 for yarn manufactur ing and cotton washing operations 0 500 mg/m3 for textile mill waste house operations or for dust from lower grade washed cotton1 used during yarn manufacturing and 0 750 mg/m3 for textile slashing and weaving operations The OSHA standard in 29 CFR 1910 1043 does not appiy to cotton harvesting ginning, or the handling and processing of woven or knitted materials and washed cotton All PELS for cotton dust are mean concentrations of lint-free respirable cotton dust collected by the vertical elutnator or an equivalent method and averaged over an 8-hour period ABD00023076 APPENDIX C -- SUPPLEMENTARY EXPOSURE LIMITS (Continued) Lead NIOSH considers `Lead" to mean metallic lead, lead oxides and lead salts (including organic salts such as lead soaps but excluding lead arsenate) The NIOSH REL for lead (10-hour TWA) is 0 100 mg/m5 air concentrations should be maintained so that worker blood lead remains less than 0 060 mg Pb/100 g of whole blood OSHA considers Lead to mean metallic lead, all inorganic lead compounds (lead oxides and lead salts) and a class of organic compounds called soaps all other lead compounds are excluded from this definition The OSHA PEL (8-hour TWA) is 0 050 mg/m3 other OSHA requirements can be found in 29 CFR 1910 1025 The OSHA PEL (8-hour TWA) for lead in non-ferrous foundries with less than 20 employees is 0 075 mg/m3 Mineral Dusts These OSHA PELS for mineraldusts" listed below are from Table 2-3 of 29 CFR 1910 1000 The OSHA PEL (8-hour TWA) for crystalline silica (as respirable quartz) is either 250 mppcf divided by the value "%Si02 + 5" or 10 mg/m3 divided by the value "%Si02 + 2 The OSHA PEL (8-hour TWA) for crystalline silica (as total quartz) is 30 mg/m3 divided by the value "%SiO. + 2" The OSHA PELs (8-hour TWAs) for cnstobalite and tridymite are 'A the values calculated above using the count or mass formulae for quartz The OSHA PEL (8-hour TWA) for amorphous silica (including diatomaceous earth) is either 80 mg/m1 divided by the value %Si02' or20 mppcf The OSHA PELs (8-hour TWAs) for mica soapstone and talc (not containing asbestos) are 20 mppcf 353 354 ABD00023077 APPENDIX C -- SUPPLEMENTARY EXPOSURE LIMITS (Continued) The OSHA PEL (8-hour TWA) for Portland cement is 50 mppcf The OSHA PEL (8-hour TWA) for graphite (natural) is 15 mppcf The OSHA PEL (8-hour TWA) for coal dust (as the respirable fraction) containing less than 5% Si02 is 2 4 mg/m3 divided by the value `%Si02 + 2' The OSHA PEL (8-hour TWA) for coal dust (as the respirable fraction) containing greater than 5% SiO, is 10 mg/m3 divided by the value %SiO? + Z NIAX Catalyst ESN In May 1978, OSHA and NIOSH jointly published the Current intelligence Bulletin (CJB) 26 NIAX Catalyst ESN In this CIB OSHA and NIOSH recommended that occupational exposure to NIAX Cata lyst ESN its components, dimethyiaminopropiomtrile and bis(2-(dimethylamino)ethyl)ether as well as formulations containing either component be minimized Exposures should be limited to as few workers as possible while minimizing workplace exposure concentrations with effective work practices and engineenng controls Exposed workers should be carefully monitored for potential disorders of the nervous and genitourinary system Although substitution is a possible control measure alternatives to NIAX Catalyst ESN or its components should be carefully evaluated with regard to possible adverse health effects Trichloroethylene NIOSH considers tnchloroethylene (TCE) to be a potential occupational carcinogen and recommends a RELof 2 ppm (as a 60-minute ceiling) during the usage of TCE as an anesthetic agent and 25 ppm (as a 10-hour TWA) during all other exposures ABD00023078 APPENDIX C -- SUPPLEMENTARY EXPOSURE LIMITS (Continued) Tungsten Carbide (Cemented) "Cemented tungsten carbide or `hard metal' refers to a mixture of tungsten carbide cobalt and sometimes metal oxides or carbides and other metals (including nickel) When the cobalt (Co) content exceeds 2% its contribution to the potential hazard is judged to exceed that of tungsten carbide Therefore the NIOSH REL (10-hour TWA) for cemented tungsten carbide containing >2% Co is 0 05 mg Co/m3 the applicable OSHA PEL is 0 1 mg Co/m3 (8-hourTWA) Nickel (Ni) may sometimes be used as a binder rather than cobalt NIOSH considers cemented tungsten carbide containing nickel to be a potential occupational carcinogen and recommends a REL of 0 015 mg Ni/m3 (10-hour TWA) The OSHA PEL for Insoluble Nickel (i e a 1 mg Ni/m3 8-hour TWA) applies to mixtures of tungsten carbide and nickel 355 356 ABD00023079 APPENDIX D -- SUBSTANCES WITH NO ESTABLISHED RELs After reviewing available published literature NIOSH provided comments to OSHA on August 1 1988 regarding the "Proposed Rule on Air Contaminants" (29 CFR 1910, Docket No H-020) In these comments NIOSH questioned whether the PELs proposed (and listed below) for the following sub stances included m the Pocket Guide were adequate to protect workers from recognized health hazards acetylene tetrabromide [TWA 1 ppm] chlorobenzene (TWA 75 ppm] coal dust (<-5% Si02) [2 mg/m3 (as the respirable dust fraction)], coal dust (> 5% Si02) [0 1 mg/m3 (as the respirable quartz fiaction)] ethyl bromide [TWA 200 ppm STEL 250 ppm] ethylene glycol [Ceiling 50 ppm], ethyl ether [TWA 400 ppm STEL 500 ppm], fenthion [TWA 0 2 mg/m3 (skin)], furfural [TWA 2 ppm (skin)], 2-isopropoxyethanol [TWA 25 ppm], isopropyl acetate [TWA 250 ppm, STEL 310 ppm], isopropylamine [TWA 5 ppm STEL 10 ppm], manganese tetroxide (as Mn) [TWA 1 mg/m3], molybdenum (soluble com pounds as Mo) [TWA 5 mg/m3], mtromethane [TWA 100 ppm] m-toluidine [TWA 2 ppm (skin)] and triethylamme [TWA 10 ppm STEL 15 ppm] At that time NIOSH also conducted a limited evaluation of the literature and concluded that the documentation cited by OSHA was inadequate to support the proposed PEL (as an 8-hour TWA) of 10 mg/m3 for a-alumma benomyl emery glycerine (mist), graphite (synthetic) magnesium oxide fume, molybdenum (insoluble compounds as Mo) particulates not otherwise regulated picloram and rouge ABD00023080 APPENDIX E--RESPIRATOR RECOMMENDATIONS FOR SELECTED CHEMICALS Mercury compounds fexcept (oraano) alkvlsl Mercury vapor NIOSH 0 5 mg/m3 CCRSVSA 1 25 mg/m3 SA CF/PAPRS7(cantster) 2 5 mg/m3 CCRFS7GMFSVSATCF/ PAPRTST(camster)/ SCBAF/SAF 10 mg/m* SA PD,PP SCBAF PD PP/SAF PD PP ASCBA Escape GMFSVSCBAE Other non (organo) alkyl mercury compounds NIOSH/OSHA 1 mg/m3 CCRSVSA 2 5 mg/m3 SA CF/PAPRS^camster) 5 mg/m3 CCRFSVGMFSVSATCF/ PAPRTSf(canister)/ SCBAF/SAF 10 mg/m3 SAPD PP SCBAF PD PP/SAF PD PP ASCBA Escape GMFSVSCBAE 357 358 ABD00023081 APPENDIX F--MISCELLANEOUS NOTES Benzene The final OSHA Benzene standard m 1910 1028 applies to all occupational exposures to benzene except some subsegments of industry where exposures are consistently under the action level (i e distribution and sales of fuels sealed containers and pipelines coke production, oil and gas drilling and production natural gas processing and the percentage exclusion for liquid mixtures) for the excepted subsegments the benzene limits in Table Z-2 apply (i e an 8-hour TWA of 10 ppm, an acceptable ceiling of 25 ppm and 50 ppm for a maximum duration of 10 minutes as an acceptable maximum peak above the acceptable ceiling) ABD00023082 ^etaldehyde Acetic anhydride Acetone Acetomtnle \cetylsalicyclic acid Acrolein \crylamide Acrylic acid Allyl alcohol Ailyl chlonde Allyl glycidyl ether APPENDIX G--VACATED 1989 OSHA PELs TWA 100 ppm (180 mg/m3) ST 150 ppm (270 mg/m3) C 5 ppm (20 mg/m3) TWA 750 ppm (1800 mg/m3) ST 1000 ppm (2400 mg/m3) TWA 40 ppm (70 mg/m3) ST 60 ppm (105 mg/m3) TWA 5 mg/m3 TWA 0 1 ppm (0 25 mg/m3) ST 0 3 ppm (0 8 mg/m3) TWA 0 03 mg/m3 [skin] TWA 10 ppm (30 mg/m3) [skin] TWA 2 ppm (5 mg/m3) ST 4 ppm (10 mg/m3) [skin] TWA 1 ppm (3 mg/m3) ST 2 ppm (6 mg/m3) TWA 5 ppm (22 mg/m3) ST 10 ppm (44 mg/m3) Allyl propyl disulfide a-Alumina Aluminum (pyro powders & welding fumes asAI) Aluminum (soluble salts & alkyls as Al) Amitrole Ammonia Ammonium chlonde fume Ammonium sulfamate Aniline (and homologs) Atrazme Banum sulfate TWA2 ppm(12 mg/m3) ST 3 ppm (18 mg/m3) TWA 10 mg/m3 (total) TWA 5 mg/m3(resp) TWA 5 mg/m3 TWA 2 mg/m3 TWA 0 2 mg/m3 ST 35 ppm (27 mg/m3) TWA 10 mg/m3 ST 20 mg/m3 TWA 10 mg/m3 (total) TWA 5 mg/m3 (resp) TWA 2 ppm (8 mg/m3) [skin] TWA 5 mg/m3 TWA 10 mg/m3 (total) TWA 5 mg/m3 (resp) 359 ABD00023083 Benomyl 360 Benzenethiol Bismuth tellunde (doped with selenium sulfide as Bi?Te3) Borates tetra sodium salts (Anhydrousj Borates tetra sodium salts (Decahydratei Borates tetra sodium salts (Pentahydratei Boron oxide Boron tribromide Bromacil Bromine Bromine pentafluoride n-Butane APPENDIX G--VACATED 1989 OSHA PELs (Continued) 1WA 10 mg/m' (total) TWA 5 mg/m3 (resp) TWA 0 5 ppm (2 mg/m') TWA 5 mg/m TWA 10 mg/m TWA 10 mg/m3 TWA 10 mg/m' TWA 10 mg/m C 1 ppm (10 mg/m3) TWA 1 ppm (10 mg/mJ) TWA 0 1 ppm (0 7 mg/m3) ST 0 3 ppm (2 mg/m3) TWA 0 1 ppm (0 7 mg/m3) TWA 800 ppm (1900 mg/m3) 2-Butanone 2-Butoxyethano! n Butyl acetate Butyl acrylate n-Butyl alcohol sec-Butyl alcohol tert-Butyl alcohol n-Butyl glycidyl ether n-Butyl lactate n-Butyl mercaptan o-sec-Butylphenol p-tert-Butyltoluene Calcium cyanamide TWA 200 ppm 1590 mg/m3) ST 300 ppm (885 mg/m3) TWA 25 ppm (120 mg/m3) [skin] TWA 150 ppm (710 mg/m3) ST 200 ppm (950 mg/m') TWA 10 ppm (55 mg/m3) C 50 ppm (150 mg/m3) [skin] TWA 100 ppm (305 mg/m ) TWA 100 ppm (300 mg/m3) ST 150 ppm (450 mg/m ) TWA 25 ppm (135 mg/m3) TWA 5 ppm (25 mg/m3) TWA 0 5 ppm (1 5 mg/m3) TWA 5 ppm (30 mg/m') [skin] TWA 10 ppm (60 mg/mJ) ST 20 ppm (120 mg/m3) TWA 0 5 mg/m3 ABD00023084 Caprolactam Captafol Captan Carbofuran Carbon dioxide Carbon disulfide Carbon monoxide Carbon tetrabromide Carbon tetrachloride Carbonyl fluoride Catechol APPENDIX G--VACATED 1989 OSHA PELs (Continued) Dust TWA 1 mg/m3 ST 3 mg/m3 Vapor TWA 5 ppm (20 mg/m3) ST 10 ppm (40 mg/m3) TWA 0 1 mg/m3 TWA 5 mg/m3 TWA 0 1 mg/m-` TWA 10 000 ppm (18 000 mg/m3) ST 30 000 ppm (54 000 mg/m3) TWA4 ppm (12 mg/m3) ST 12 ppm (36 mg/m3) [skin] TWA 35 ppm (40 mg/m3) C 200 ppm (229 mg/m3) TWA 0 1 ppm (1 4 mg/m3) ST 0 3 ppm (4 mg/m3) 1WA2 ppm (12 6 mg/m') TWA ? ppm (5 mg/m3) ST 5 ppm (15 mg/m3) TWA 5 ppm (20 mg/m3) [skin] Cesium hydroxide TWA 2 mg/mJ Chlonnated camphene TWA 0 5 mg/m3 ST 1 mg/m3 [skin] Chlorine TWA 0 5 ppm (1 5 mg/mJ) ST 1 ppm (3 mg/m3) Chlorine dioxide TWA 0 1 ppm (0 3 mg/m3) ST 0 3 ppm (0 9 mg/m3) Chioroacetyl chionde TWA0 05 ppm (0 2 mg/m1) o-Chlorobenzylidene malonomtrile C 0 05 ppm (0 4 mg/m3) [skin] Chlorodifiuoromethane TWA 1000 ppm (3500 mg/m3) Chloroform TWA 2 ppm (9 78 mg/m3) 1 -Chioro-1 -mtropropane TWA 2 ppm (10 mg/m3) Chloropentafluoroethane TWA 1000 ppm (6320 mg/m3) B-Chloroprene TWA 10 ppm (35 mg/m3) [skin] o-Chlorostyrene TWA 50 ppm (285 mg/m3) ST 75 ppm (428 mg/m3) o-Chlorotoluene TWA 50 ppm (250 mg/m3) 361 ABD00023085 362 APPENDIX G--VACATED 1989 OSHA PELs (Continued) Chlorpynfos Coal dust TWA 0 2 mg/m3 [skin] TWA 2 mg/m3 (<5% SiO ) (resp dust) TWA 0 1 mg/m3 (>5% Si02) (respquartz) Cobalt metal dust & fume, as Co) TWA 0 05 mg/m3 Cobalt carbonyl (as Co) TWAO 1 mg/m3 Cobalt hydrocarbonyt (as Co) TWAO 1 mg/m3 Crag herbicide TWA 10 mg/m3 (total) TWA 5 mg/m3 (resp) Crufomate Cyanamide Cyanogen TWA 5 mg/m3 TWA 2 mg/m3 TWA 10 ppm (20 mg/m3) Cyanogen chlonde CO 3 ppm (0 6 mg/m3) Cyclohexanol TWA 50 ppm (200 mg/m3) [skin] Cyclohexanone Cyclohexylamine TWA 25 ppm (100 mg/m3) [skin] TWA 10 ppm (40 mg/m3) Cyclomte Cyclopentane TWA 1 5 mg/m3 [skin] TWA 600 ppm (1720 mg/m3) Cyhexatin Decaborane Diazinon 2-N-Dibutylammoethanol Dibutyl phosphate Oichloroacetylene p-Dichlorobenzene 1 3-Dichloro-5,5* dimethylhydantom Dichloroethyl ether Dichloromonofluoromethane 1 1-Dichloro-1-nitroethane 1,3-Dichloropropene TWA 5 mg/m3 TWA 0 3 mg/m3 (0 05 ppm) ST 0 9 mg/m3 (0 15 ppm) [skin] TWA 0 1 mg/m3 [skin] TWA 2 ppm (14 mg/m3) TWA 1 ppm (5 mg/m3) ST 2 ppm (10 mg/m3j C 0 1 ppm (0 4 mg/m3) TWA 75 ppm (450 mg/m3) ST 110 ppm (675 mg/m3) TWA 0 2 mg/m3 ST 0 4 mg/m3 TWA 5 ppm (30 mg/m3) ST 10 ppm (60 mg/m3) [skin] TWA 10 ppm (40 mg/m3) TWA 2 ppm (10 mg/m3) TWA 1 ppm (5 mg/m3) [skin] ABD00023086 2 2-Dichloropropionic acid Dicrotophos Dicyclopentadiene Dicyclopentadienyl Ton Diethanolamine Diethylamine Diethylenetnamme Diethyl ketone Diethyl phthalate Diglycidyl ether Dusobutyl ketone N N-Dimethylamlme Dimethyl-1,2-dibromo-2,2dichlorethyl phosphate APPENDIX G--VACATED 1989 OSHA PELs (Continued) TWA 1 ppm (6 mg/m3) TWA 0 26 mg/m [skin] TWA 6 ppm (dC mg/m') TWA 10 mg/m (total) TWA 5 mg/m uesp) TWA 3 ppm (15 mg/m') TWA 10 ppm (30 mg/m ) ST 25 ppm i75 mg/mD TWA 1 ppm (4 mg/m1) TWA 200 ppm (705 mg/mJ) TWA 5 mg/m3 TWA 0 1 ppm (0 5 mg/m3) TWA 25 ppm (150 mg/m3) TWA 5 ppm (25 mg/mJ) ST 10 ppm (50 mg/m3) [skin] TWA 3 mg/m3 [skin] Dimethyl sulfate Dinitolmide Di sec octyi pnthalate Dioxane Dioxatmon Diphenylamme Dipropylene glycol methyl ether Dipropyl ketone Diquat (Diquat dibromide) Disulfiram Disulfoton 2,6-Di-tert-butyl-p-cresol Diuron Divinyl benzene TWA 0 1 ppm (0 5 mg/mJ) [skin] TWA 5 mg/m1 TWA 5 mg/m' ST '0 mg/m3 TWA 25 ppm (90 mg/m3) [skin] TWA 0 2 mg/m- fskin] TWA 10 mg/mTWA 100 ppm (600 mg/m3) ST 150 ppm (900 mg/m3) [skin] TWA 50 ppm (235 mg/m3) TWA 0 5 mg/m3 TWA 2 mg/m3 TWA 0 1 mg/m3 [skin] TWA 10 mg/m3 TWA 10 mg/m3 TWA 10 ppm (50 mg/m3) 363 ABD00023087 Emery Endosulfan Epichiorohydnn Ethanolarnme 364 Ethion Ethyl acrylate Ethyl benzene Ethyl bromide Ethylene chlorohydnn Ethylene dichlonde Ethylene glycol Ethylene glycol dinitrate APPENDIX G--VACATED 1989 OSHA PELS (Continued) TWA 10 mg/m3 (total) TWA 5 mg/m3(resp) TWAO 1 mg/m3 [skin] TWA 2 ppm (8 mg/m3) [skin] TWA 3 ppm (8 mg/m3) ST 6 ppm (15 mg/m3) 0 4 mg/m3 [skin] TWA 5 ppm (20 mg/m3) ST 25 ppm (100 mg/m3) [skin] TWA 100 ppm (435 mg/m3) ST 125 ppm (545 mg/m3) TWA 200 ppm {890 mg/m3) ST 250 ppm (1110 mg/m3) C 1 ppm (3 mg/m3) [skin] TWA 1 ppm (4 mg/m3) ST 2 ppm (8 mg/m3) C 50 ppm (125 mg/m3) ST 0 1 mg/m3 [skin] Ethyl ether Ethylidene norbornene Ethyl mercaptan N-Ethylmorpholine Ethyl silicate Fenamiphos Fensulfothion Fenthion Ferbam Ferrovanadium dust Fluorotnchloromethane Fonofos Formamide Furfural TWA 400 ppm (1200 mg/nV) ST 500 ppm (1500 mg/m3) C 5 ppm (25 mg/m3) TWAO 5 ppm (1 mg/m!) TWA 5 ppm (23 mg/m3) [skin TWA 10 ppm (85 mg/m3) TWA 0 1 mg/m3 [skin] TWA 0 1 mg/m3 TWA 0 2 mg/m- [skin] TWA 10 mg/m1 TWA 1 mg/m3 ST 3 mg/m3 C 1000 ppm (5600 mg/m3) TWA 0 1 mg/m3 [skin] TWA 20 ppm (30 mg/m3) ST 30 ppm (45 mg/m3) TWA 2 ppm (8 mg/m3) [skin] ABD00023088 Furfuryl alcohol Gasoline Germanium tetrahydride Glutaraldehyde Glycerin (mist) Glycidol Graphite (natural) Graphite (synthetic) n-Heptane Hexachlorobutadiene Hexachlorocyclopentadiene Hexafluoroacetone APPENDIX G--VACATED 1989 OSHA PELs (Continued) TWA 10 ppm (40 mg/m3) ST 15 ppm (60 mg/m3) [skin] TWA 300 ppm (900 mg/mJ) ST 500 ppm (1500 mg/ms) TWA 0 2 ppm (0 6 mg/m3) C 0 2 ppm (0 8 mg/m') TWA 10 mg/m3 (total) TWA 5 mg/m3 (resp) TWA 25 ppm (75 mg/m3) TWA 2 5 mg/mJ (resp) TWA 10 mg/m3 (total) TWA 5 mg/m3 (resp) TWA 400 ppm (1600 mg/m3) ST 500 ppm (2000 mg/m3) TWA 0 02 ppm (0 24 mg/mJ) TWA 0 01 ppm(0 1 mg/m3) TWA 0 1 ppm (0 7 mg/m3) [skin] n-Hexane Hexane isomers (except n-Hexane) 2-Hexanone Hexone Hexylene glycol Hydrazine Hydrogenated terphenyls Hydrogen bromide Hydrogen cyanide Hydrogen fluonde (as F) Hydrogen sulfide 2-Hydroxypropyl acrylate Indene TWA 50 ppm (180 mg/m3) TWA 500 ppm (1800 mg/m3) ST 1000 ppm (3600 mg/m3) TWA 5 ppm (20 mg/m3) TWA 50 ppm (205 mg/m3) ST 75 ppm (300 mg/m3) C 25 ppm (125 mg/m3) TWA 0 1 ppm (0 1 mg/m3) [skin] TWA 0 5 ppm (5 mg/m3) C 3 ppm (10 mg/m3) ST 4 7 ppm (5 mg/m3) [skin] TWA 3 ppm ST 6 ppm TWA 10 ppm (14 mg/m3) ST 15 ppm (21 mg/m3) TWA 0 5 ppm (3 mg/m3) [skin] TWA 10 ppm (45 mg/m3) 365 ABD00023089 Indium Iodoform Iron pentacarbonyl (as Fe) 366 Iron salts (soluble, as Fe) Isoamyl alcohol (primary & secondary) Isobutane Isobutyl alcohol Isooctyl alcohol Isophorone Isophorone dnsocyanate 2-lsopropoxyethanol Isopropyl acetate APPENDIX G--VACATED 1989 OSHA PELS (Continued) TWA 0 1 mg/m3 TWA 0 6 ppm (10 mg/m3) TWA 0 1 ppm (0 8 mg/m3) ST 0 2 ppm (1 6 mg/m3) TWA 1 mg/m3 TWA 100 ppm (360 mg/m3) ST 125 ppm (450 mg/m3) TWA 800 ppm {1900 mg/m3) TWA 50 ppm (150 mg/m3) TWA 50 ppm (270 mg/m3) [skin] TWA 4 ppm (23 mg/m3) TWA 0 005 ppm ST 0 02 ppm [skin] TWA 25 ppm (105 mg/m3) TWA 250 ppm (950 mg/m3) ST 310 ppm (1185 mg/m3) Isopropyl alcohol Isopropylamine N-lsopropylanthne Isopropyl glyctdyl ether Kaolin Ketene Magnesium oxide fume Malathion Manganese compounds and fume (as Mn) Manganese cyclopentadienyl tricarbonyl (as Mn) TWA 400 ppm (980 mg/mJ) ST 500 ppm (1225 mg/m3) TWA 5 ppm (12 mg/m3) ST 10 ppm (24 mg/m3) TWA 2 ppm (10 mg/m3) [skin] TWA 50 ppm (240 mg/m3) ST 75 ppm (360 mg/m3) TWA 10 mg/m3 (total) TWA 5 mg/m3 (resp) TWA 0 5 ppm (0 9 mg/m3) ST 1 5 ppm (3 mg/m3) TWA 10 mg/m3 TWA 10 mg/nV [skin] Compounds C 5 mg/m3 Fume TWA1 mg/m3 ST 3 mg/m3 TWA 0 1 mg/m3 [skin] ABD00023090 Manganese tetroxide (as Mn) Mercury compounds as Hg [except(organo) alkyls] Mercury (organo) alkyl compounds (as Hg) Mesityl oxide Methacrylic acid Methomyl Methoxychlor 4-Methoxyphenol Methyl acetate Methyl acetylene-propadiene mixture APPENDIX G--VACATED 1989 OSHA PELs (Continued) TWA 1 mg/m3 Hg Vapor TWA 0 05 mg/m3 [skin] Non-alkyl compounds C 0 1 mg/m3 [skin] TWA 0 01 mg/m3 ST 0 03 mg/mJ [skin] TWA15ppm(60 mg/m3) ST25ppm(100 mg/m3) TWA 20 ppm (70 mg/m3) [skin] TWA 2 5 mg/m3 TWA 10 mg/m3 TWA 5 mg/m3 TWA 200 ppm (610 mg/m3) ST 250 ppm (760 mg/m3) TWA 1000 ppm (1800 mg/m3) ST 1250 ppm (2250 mg/m3) Methylacrylonitrile Methyl alcohol Methyl bromide Methyl chloride Methyl chloroform Methyl-2-cyanoacrylate Methylcyclohexane Methylcyclohexanol o-Methylcyclohexanone TWA 1 ppm (3 mg/m3) [skin] TWA 200 ppm (260 mg/m3) ST 250 ppm (325 mg/m3) [skin] TWA 5 ppm (20 mg/m3) [skin] TWA 50 ppm (105 mg/m3) ST 100 ppm (210 mg/m3) TWA 350 ppm (1900 mg/m3) ST 450 ppm (2450 mg/m3) TWA 2 ppm (8 mg/m3) ST 4 ppm (16 mg/m3) TWA 400 ppm (1600 mg/m3) TWA 50 ppm (235 mg/m3) TWA 50 ppm (230 mg/m3) ST 75 ppm (345 mg/m3) [skin] Methyl cyciopentadienyl manganese tncarbonyl (as Mn) TWA 0 2 mg/m3 [skin] Methyl demeton TWA 0 5 mg/m3 [skin] 367 ABD00023091 368 APPENDIX G--VACATED 1989 OSHA PELs (Continued) 4 4'-Methylenebis(2-chloroamiine) TWA 0 02 ppm (0 22 mg/m3) [skin] Methylene bis(4-cyciohexylisocyanate) C 0 01 ppm (0 11 mg/m3) [skin] Methyl ethyl ketone peroxide C 0 7 ppm (5 mg/m3) Methyl formate TWA 100 ppm (250 mg/m3) ST 150 ppm (375 mg/m3) Methyl iodide TWA 2 ppm (10 mg/m3) [skin] Methyl isoamyl ketone TWA 50 ppm (240 mg/m3) Methyl isobutyl carbmol TWA 25 ppm (100 mg/m3) ST 40 ppm (165 mg/m3) [skin] Methyl isopropyl ketone TWA 200 ppm (705 mg/m3) Methyl mercaptan TWA0 5 ppm (1 mg/m3) Methyl parathion TWA 0 2 mg/m3 [skin] Methyl silicate TWA 1 ppm (6 mg/m3) a-Methyl styrene TWA 50 ppm (240 mg/m3) ST 100 ppm (485 mg/m3) Metribuzin TWA 5 mg/m3 Mica Molybdenum (insoluble compounds as Mo) Monocrotophos Monomethyl aniline Morpholine Naphthalene Nickel metal & other compounds (as Ni) Nitric acid p-Nitroamline Nitrogen dioxide Nitroglycenne 2-Nitropropane TWA 3 mg/m3 (resp) TWA 10 mg/m3 TWA 0 25 mg/m3 TWA 0 5 ppm (2 mg/m3) [skin] TWA 20 ppm (70 mg/m3) ST 30 ppm (105 mg/m3) [skin] TWA 10 ppm t.50 mg/m3) ST 15 ppm (75 mg/m3) Metal & insoluble compounds TWA 1 mg/m3 Soluble compounds TWA 0 1 mg/m3 TWA 2 ppm (5 mg/m3) ST 4 ppm (10 mg/m3) TWA 3 mg/m3 [skin] ST 1 ppm (1 8 mg/m3) ST 0 1 mg/m3) [skin] TWA 10 ppm (35 mg/m3) ABD00023092 APPENDIX G--VACATED 1989 OSHA PELs (Continued) Nitrotoluene (o- m- p-isomers) TWA 2 ppm (11 mg/m3) [skin] Nonane TWA200 ppm (1050 mg/m3) Octachloronaphthalene TWA 0 1 mg/m3 ST 0 3 mg/m3 [skin] Octane TWA 300 ppm (1450 mg/m3) ST 375 ppm (1800 mg/m3) Osmium tetroxide (as Os) TWA 0 002 mg/m3 (0 0002 ppm) ST 0 006 mg/m3 (0 0006 ppm) Oxalic acid TWA 1 mg/m3 ST 2 mg/m3 Oxygen difluonde C 0 05 ppm (0 1 mg/m3) Ozone Paraffin wax fume TWA 0 1 ppm (0 2 mg/m3) ST 0 3 ppm (0 6 mg/m3) TWA 2 mg/m3 Paraquat TWA 0 1 mg/mJ (resp) [skin] Pentaborane TWA 0 005 ppm (0 01 mg/m3) ST 0 015 ppm (0 03 mg/m3) Pentaerythritol n-Pentane 2-Pentanone Perchloryl fluonde Petroleum distillates (naphtha) Phenothiazme Phenyl glycidyl ether Phenylhydrazme Phenylphosphine Phorate Phosdnn TWA 10 mg/m3 (total) TWA 5 mg/m3 (resp) TWA 600 ppm (1800 mg/m3) ST 750 ppm (2250 mg/m3) TWA 200 ppm (700 mg/m3) ST 250 ppm (875 mg/m3) TWA 3 ppm (14 mg/m3) ST 6 ppm (28 mg/m3) TWA 400 ppm (1600 mg/m3) TWA 5 mg/m3 [skin) TWA 1 ppm (6 mg/m3) TWA 5 ppm (20 mg/m3) ST 10 ppm (45 mg/m3) [skin] C 0 05 ppm (0 25 mg/m3) TWA 0 05 mg/m3 ST 0 2 mg/m3 [skin] TWA 0 01 ppm (0 1 mg/m3) ST 0 03 ppm (0 3 mg/m3) [skin] 369 ABD00023093 Phosphine Phosphoric acid 370 Dhosphorus oxychlonde Phosphorus pentasulfide Phosphorus tnchlonde Phthalic anhydride m-Phthalodinitnle Picioram Piperazine dihydrochlonde Platinum metal (as Pt) Portland cement Potassium hydroxide APPENDIX G--VACATED 1989 OSHA PELs (Continued) TWA 0 3 ppm (0 4 mg/m3) ST 1 ppm (1 mg/m3) TWA1 mg/m3 ST 3 mg/m3 TWA 0 1 ppm (0 6 mg/m3) TWA 1 mg/m3 ST 3 mg/m3 TWA 0 2 ppm (1 5 mg/m3) ST 0 5 ppm (3 mg/m3) TWA 6 mg/m3 {1 ppm) TWA 5 mg/m3 TWA 10 mg/m3 (total) TWA 5 mg/m3 (resp) TWA 5 mg/m3 TWA 1 mg/m3 TWA 10 mg/m3 (total) TWA 5 mg/m3 (resp) TWA 2 mg/m3 Propargyl alcohol Propionic acid Propoxur n-Propyl acetate n-Propyl alcohol Propylene dichlonde Propylene glycol dinitrate Propylene glycol monomethyl ether Propylene oxide n-Propyl nitrate Resorcinol Ronnel TWA 1 ppm (2 mg/m3) [skin] TWA 10 ppm (30 mg/m3) TWA 0 5 mg/m3 TWA 200 ppm (840 mg/m3! ST 250 ppm (1050 mg/m3) TWA 200 ppm i500 mg/m3) ST 250 ppm (625 mg/m3) TWA 75 ppm (350 mg/m3) ST 110 ppm ^10 mg/m3! TWA 0 05 ppm (0 3 mg/m3) TWA 100 ppm (360 mg/m3) ST 150 ppm (540 mg/m3) TWA 20 ppm (50 mg/m3) TWA 25 ppm (105 mg/m3) ST 40 ppm (170 mg/m3) TWA 10 ppm (45 mg/m3) ST 20 ppm (90 mg/m3) TWA 10 mg/m3 ABD00023094 APPENDIX G--VACATED 1989 OSHA PELs (Continued) Rosin core solder pyrolysis products (as formaldehyde) Rouge Silica amorphous TWA 0 1 mg/m TWA 10 mg/m3 (total) TWA 5 mg/m3 (resp) TWA 6 mg/m3 TWA 0 1 mg/mJ (fused) Silica crystalline (as respirable dust) TWA 0 05 mg/nv (cristobalite) TWA 0 05 mg/mJ (tridymite) TWA 0 1 mg/m3 (quartz) TWAO 1 mg/m3 (tripoli) Silicon Silicon carbide Silicon tetrahydride Soapstone TWA 10 mg/m3 (total) TWA 5 mg/m3 (resp) TWA 10 mg/m3 (total) TWA 5 mg/m3 (resp) TWA 5 ppm (7 mg/m3) TWA 6 mg/m3 (total) TWA 3 mg/m3 (resp) Sodium azide Sodium bisulfite Sodium fluoroacetate Sodium hydroxide Sodium metabisulfite Stoddard solvent Styrene Subtilisins Suifurdioxide Sulfur monochlonde Sulfur pentafluonde Sulfur tetrafluoride C 0 1 ppm (as HN,) [skin] C 0 3 mg/m3 (as NaN3) [skin} TWA 5 mg/m3 TWA 0 05 mg/m3 ST 0 15 mg/m3 [skin] C 2 mg/m3 TWA 5 mg/m3 TWA 525 mg/m3 (100 ppm) TWA 50 ppm (215 mg/m3) ST 100 ppm (425 mg/m3) ST 0 00006 mg/m3 [60-minute] TWA 2 ppm (5 mg/m3) ST 5 ppm (13 mg/m3) C 1 ppm (6 mg/m3) C 0 01 ppm (0 1 mg/m3) C 0 1 ppm (0 4 mg/m3) 371 ABD00023095 APPENDIX G--VACATED 1989 OSHA PELS (Continued) Sulfuryl fluoride 1WA 5 ppm (20 mg/m') ST 10 ppm (40 mg/m3) Sulprofos TWA 1 mg/m ' Talc TWA 2 mg/m1 (resp) Temephos TWA 10 mg/m' (total) TWA 5 mg/mJ(resp) Terphenyl(o- m- p-isomers) C 5 mg/m3 (0 5 ppm) 1 1 2 2-Tetrachloroethane TWA 1 ppm (7 mg/m3) [skin] Tetrachioroethylene TWA 25 ppm (170 mg/m3) Tetrahydrofuran TWA200 ppm (590 mg/m') ST 250 ppm (735 mg/m1) Tetrasodium pyrophosphate TWA 5 mg/m1 4 4'-Thiobis(6-tert-butyl-m*cresol) TWA 10 mg/m' (total) TWA 5 mg/m3 (resp) Thioglycolic acid TWA 1 ppm (4 mg/m3) {skin} Thionyl chlonde C 1 ppm (5 mg/m3) Tin (organic compounds, as Sn) TWA 0 1 mg/m3 [skin] Tin(ll) oxide (as Sn) Tm(IV) oxide (as Sn) Titanium dioxide Toluene Toluene-2 4-dnsocyanate m-Toluidine p-Toluidme Tnbutyl phosphate Tnchloroacetic acid 1 2 4-Tnchlorobenzene Trichloroethylene 1 2 3-Tnchloropropane 1 1 2-Tnchloro-1 2 2- trifluoroethane TWA 2 mg/m3 TWA 2 mg/m3 TWA 10 mg/m3 TWA 100 ppm (375 mg/m3) ST 150 ppm (560 mg/m3) TWA 0 005 ppm (0 04 mg/m3) ST 0 02 ppm (0 15 mg/m3) TWA 2 ppm (9 mg/m-) [skin) TWA 2 ppm (9 mg/m-) [skin] TWA 0 2 ppm 12 5 mg/m3) TWA 1 ppm (7 mg/m3} C 5 ppm (40 mg/m') TWA 50 ppm (270 mg/m3) ST 200 ppm (1080 mg/m3) TWA 10 ppm (60 mg/m3) TWA 1000 ppm (7600 mg/m3 ST 1250 ppm (9500 mg/m3) ABD00023096 Tnethylarnme Tnmellitic anhydride Tnmethylarnme 1 2 3-Tnmethylbenzene 1 2 4 Trimethylbenzene 1 3 5-Tnmetnylben7ene Tnmethyl phospnite 2,4 6-Tnmtrotoluene Tnorthocresyl phosphate Tnphenylamme Tungsten (insotuble compounds asW) Tungsten (soluble compounds as W) APPENDIX G--VACATED 1989 OSHA PELs (Continued) TWA 10 ppm (40 mg/m'i ST 15 ppm (60 mg/m3) TWA 0 005 ppm (0 04 mg/m3) TWA 10 ppm (24 mg/m3) ST 15 ppm (36 mg/rnJ) TWA25 ppm (125 mg/m') TWA25 ppm (125 mg/m'l TWA 25 ppm 1125 mg/m ) TWA 2 ppm (10 mg/m3) TWA 0 5 mg/m3 [skin] TWA 0 1 mg/m3 [skin] TWA 5 mg/m3 TWA 5 mg/m3 ST 10 mg/m3 TWA 1 mg/m3 ST 3 mg/m3 Tungsten carbide (cemented) Uranium (insoluble compounds asU) n-Valeraldehyde Vanadium dust Vanadium fume Vinyl acetate Vinyl bromide Vinyl cyclohexene dioxide Vinylidene chloride VM&P Naphtha Welding fumes TWA 5 mg/m3 (as W) ST 10 mg/m3 (as W) TWA 0 05 mg/m3 (as Co) TWA 1 mg/m3 (as Ni) TWA 0 2 mg/m3 ST 0 6 mg/m3 TWA 50 ppm (i 75 mg/m3) TWA 0 05 mg V.O^m3 (resp) C 0 05 mg V_,Ot/m3 TWA 10 ppm (30 mg/m3) ST 20 ppm (60 mg/m3) TWA 5 ppm (20 mg/m3) TWA 10 ppm (60 mg/m3) [skin] TWA 1 ppm (4 mg/m3) TWA 1350 mg/m3 (300 ppm) ST 1800 mg/m3 (400 ppm) TWA 5 mg/m3 373 ABD00023097 374 Wood dust taii *ood dusts except Western red cedar) Wood dust (Western red cedar) Xylene to m p-somers) m-Xyiene u <t -diamine Xytidme 2mc chloride fume APPENDIX G--VACATED 1989 OSHA PELs (Continued) TWA 5 mg/mST 10 mg/m TWA 2 5 mg/m TWA 100 ppm (435 mg/m ) ST 150 ppm tb55 rng/m' C 0 1 mg/m' [skin] TWA 2 ppm 110 mg'm3) [skin] TWA 1 mg/m ST 2 mg/m Zinc oxide Z,nc stearate Z rucmum compounds (as Zr T WA o mg/m ifume ST 10 mg/mJ ifume) TWA 10 mg/m1 (total dust) 'AA 5 mg/m irespdust' TWA 10 mg/m Total) TWA 5 mg/m iresp, TWA 5 mg/m ST 10 mg/m ABD00023098 INDICES 375 376 50-00-0 148 50-29-3 88 50-78-2 6 53-96-3 4 54-11 5 224 55 38-9 144 55 63 0 228 56-23-5 54 56-38-2 240 56-81-5 152 57-14-7 114 57-24-9 286 57-50-1 288 57-57-8 264 57-74-9 56 58-89-9 186 60-11-7 110 60-29-7 140 60-34-4 210 60-57 1 104 61-82-5 14 ABD00023099 62-53-3 18 62-73-7 102 62-74-8 282 62 75-9 232 63-25-2 50 64-17-5 132 64-18-6 148 64--9-7 2 67-56-1 200 67-63-0 180 67-64-1 2 67-66-3 64 67-72-1 158 68-11-1 306 68-12-2 114 71-23-8 268 71-36-3 38 71-43-2 26 71-55-6 202 72-20-8 126 72-43-5 194 CAS NUMBER INDEX 74-83-9 200 74-86-2 4 74-87-3 202 74-88-4 210 74-89-5 200 74-90-8 168 74-93-1 214 74-96-4 134 74-97-5 62 74-98-6 262 74-99-7 196 75-00-3 134 75-01-4 330 75-02-5 330 75-04-7 132 75-05-8 4 75-07-0 2 75-08-1 140 75-09-2 208 75-12-7 148 75-15-0 52 75 21-8 138 75-25-2 34 75-28-5 176 75-31-0 180 75-34-3 98 75-35-4 332 75-38-7 332 75-43-4 100 75-44-5 252 75-45-6 62 75-47-8 172 75-50-3 318 75-52-5 230 75-55-8 270 75-56-9 270 75-61-6 108 75-63-8 318 75-65-0 40 75-69-4 146 75-71-8 96 75-74-1 302 75-86 5 4 75-99-0 100 76-01-7 242 76-03-9 314 76-06-2 66 76-11-9 298 76-12-0 298 76-13-1 316 76-14-2 102 76-15-3 66 76-22-2 48 76-38-0 196 76-44-8 156 77_47-4 158 77-73-6 102 77-78-1 116 78-00-2 302 78-10-4 142 78-30-8 322 78-34-2 120 78-59-1 178 ABD00023100 CAS NUMBER INDEX (Continued) 78-82-0 178 78-83-1 176 78-87-5 268 78-92-2 40 78-93-3 36 79-00-5 314 79-01-6 316 79-04-9 60 79-06-1 6 79-09-4 266 79-10-7 8 79-20-9 196 79-24-3 228 79-27-6 6 79-34-5 300 79-41-4 194 79-44-7 112 79-46-9 230 80-62-6 214 81-81-2 334 83-26-1 258 83-79-4 274 84-15-1 296 84-66-2 108 84-74-2 94 85-00-7 122 85-44-9 256 86-50-0 22 86-88-4 20 87-68-3 158 87-86-5 242 88-72-2 232 88-89-1 258 89-72-5 42 90-04-0 18 91-20-3 220 91-59-8 222 91-94-1 96 92-06-8 296 92-52-4 120 92-67-1 14 92-84-2 248 92-87-5 26 92-93-3 226 92-94-4 298 93-76-5 292 94-36-0 26 94-75-7 88 95-13-6 170 95-47-6 334 95-48-7 78 95-49-8 68 95-50-1 96 95-53-4 312 95-63-6 320 95-80-7 310 96-12-8 92 96-18-4 316 96-22-0 106 96-33-3 198 96-45-7 138 96-69-5 306 97-77-8 122 377 378 98-00-0 150 98-01-1 150 98-51-1 44 98-82-8 80 98-83-9 216 98-95-3 226 99-08-1 232 99-65-0 116 99-99-0 232 100-00-5 226 100-01-6 226 100-25-4 118 100-37-8 106 lOCMI^l 132 100-42-5 286 100-44-7 28 100-61-8 218 100-63-0 250 100-74-3 142 101-14-4 206 101-68-8 208 ABD00023101 101-77-9 208 101-84-8 248 102-54-5 104 102-81-8 94 104-94-9 18 105-46-4 38 105-60-2 50 106-35-4 134 106-42-3 336 106-44-5 78 106-46-7 96 106-49-0 312 106-50-3 248 106-51-4 272 106-87-6 330 106-89-8 128 106-92-3 10 106-93-4 136 106-97-8 34 106-99-0 34 107-02-8 6 CAS NUMBER INDEX 107-03-9 264 107-05-1 10 107-06-2 136 107-07-3 134 107-12-0 266 107-13-1 8 107-15-3 136 107-16-4 152 107-18-6 10 107-19-7 264 107-20-0 60 107-21-1 136 107-22-2 345 107-30-2 66 107-31-3 210 107-41-5 164 107-49-3 296 107-66-4 94 107-87-9 244 107-98-2 268 108-03-2 230 108-05-4 328 108-10-1 164 108-11-2 212 108-18-9 110 108-20-3 182 108-21-4 180 108-24-7 2 108-31-6 188 108-38-3 336 108-39-4 78 108-44-1 312 108-46-3 272 108-67-8 320 108-83-8 108 108-84-9 164 108-87-2 204 108-88-3 310 108-90-7 62 108-91-8 84 108-93-0 84 108-94-1 84 108-95-2 248 108-98-5 26 109-59-1 180 109-60-4 266 109-66-0 244 109-73-9 40 109-74-0 44 109-77-3 190 109-79-5 42 109-86-4 202 109-87-5 198 109-89-7 106 109-94-4 140 109-99-9 302 110-12-3 212 110-19-0 176 110-43-0 200 110-49-6 202 110-54-3 162 110-61-2 288 110-62-3 326 ABD00023102 110-66-7 244 110-80-5 130 110-82-7 82 110-83-8 84 110-86-1 272 110-91-8 220 111-15-9 130 111-30-8 152 111-31-9 162 111-40-0 106 111-42-2 104 111-44-4 98 111-65-9 236 111-69-3 8 111-76-2 36 111-84-2 234 111-88-6 236 112-07-2 36 112-55-0 126 114-26-1 266 115-29-7 126 CAS NUMBER INDEX 115-77-5 244 115-86-6 322 115-90-2 142 117-81-7 118 118-52-5 98 118-96-7 322 119-90-4 90 119-93-7 310 120-80-9 56 120-82-1 314 121-44-8 318 121-45-9 320 121-69-7 112 121-75-5 188 121-82-4 86 122-39-4 120 122-60-1 250 123-19-3 122 123-31-9 170 123-38-6 345 123-42-2 90 123-51-3 174 123-72-8 345 123-86-4 36 123-91-1 120 123-92-2 174 124-38-9 52 124-40-3 110 126-73-8 314 126-98-7 198 126-99-8 68 127-18-4 300 127-19-5 110 128-37-0 124 131-11-3 114 133-06-2 50 134-32-7 222 135-88-6 250 136-78-7 78 137-05-3 204 137-26-8 306 138-22-7 42 379 380 140-88-5 132 141-32-2 38 141-43-5 128 141-66-2 102 141-78-6 130 141-79-7 194 142-64-3 260 142-82-5 156 143-10-2 88 143-33-9 282 143-50-0 184 144-62-7 238 148-01-6 116 150-76-5 196 151-50-8 262 151-56-4 138 151-67-7 156 156-62-7 46 287-92-3 86 298-00-0 214 298-02-2 252 ABD00023103 298-04-4 124 299-84-3 274 299-86-5 80 300-76-5 114 302-01-2 166 309-00-2 8 314-40-9 32 330-54-1 124 333-41-5 92 334-88-3 92 353-50-4 54 406-90-6 146 409-21-2 278 420-04-2 80 460-19-5 82 463-51-4 184 479-45-8 304 504-29-0 14 506-77-4 82 509-14-8 304 526-73-8 320 CAS NUMBER INDEX 528-29-0 116 532-27-4 60 534-52-1 118 540-59-0 98 540-88-5 38 541-85-5 210 542-75-6 1 00 542-78-9 190 542-88-1 64 542-92-7 86 546-93-0 188 552-30-7 318 556-52-5 152 557-05-1 338 558-13-4 54 563-12-2 1 30 563-80-4 212 581-89-5 230 583-60-8 204 584-84-9 312 591-78-6 164 593-60-2 330 594-42-3 246 594-72-9 100 600-25-9 66 603-34-9 322 615-05-4 90 624-67-9 345 624-83-9 212 626-17-5 258 626-38-0 16 627-13-4 270 628-63-7 16 628-96-6 138 630-08-0 54 630-20-6 300 638-21-1 252 680-31-9 162 681-84-5 214 684-16-2 160 768-52-5 182 822-06-0 160 ABD00023104 944-22-9 146 999-61 1 170 1120-71-4 264 1189-85-1 40 1300-73-8 336 1302-74-5 126 1303-86-2 30 1303-96-4 30 1304-82-1 28 1305-62-0 46 1305-78-8 48 1306-19-0 44 1309-37-1 172 276 1309-48-4 188 1310-58-3 262 1310-73-2 284 1314-13-2 338 1314-62-1 328 1314-80-3 256 1317-35-7 192 1317-38-0 76 CAS NUMBER INDEX 1317-65-3 46 186 1321-64-8 242 1321-65-9 316 1321-74-0 124 1330-43-4 30 1332-21-4 22 1332-58 7 182 1333-82-0 70 1333-86-4 52 1335-87 1 160 1335-88-2 300 1338-23-4 208 1344-28-1 12 1344-95-2 48 1395-21-7 286 1455-21 6 234 1477-55-0 336 1563-66-2 52 1569-69-3 82 1639-09-4 158 1738-25-6 112 192 1746-01-6 298 1910-42-5 240 1912-24-9 22 1918-02-1 258 1929-82-4 68 2039-87-4 68 2104-64-5 128 2179-59-1 10 2234-13-1 234 2238-07-5 108 2425-06-1 50 2426-08-6 42 2551-62-4 288 2698-41-1 62 2699-79-8 292 2885-00-9 236 2917-26-2 160 2921-88-2 70 2971-90-6 72 3033-62-3 112 3173-72-6 220 3333-52-6 302 3383-96-8 296 3689-24-5 294 4016-14-2 182 4098-71-9 178 4170-30-3 80 5124-30-1 206 5332-52-5 326 5714-22-7 290 6032-29 7 176 6423-43 4 268 6923-22 4 218 7429-90-5 12 7439-92 1 184 7439-96-5 190 7439-97-6 192 7439-98-7 218 7440-02-0 224 7440-06-4 260 7440-16-6 272 7440-21-3 278 381 382 7440-22-4 280 7440-25-7 294 7440-31-5 308 7440-33-7 324 7440-36-0 18 7440-38-2 20 7440-44-0 154 7440-41-7 28 7440-43-9 44 7440-47-3 72 7440-48-4 74 7440-50-8 76 7440-58-6 156 7440-61-1 326 7440-65-5 338 7440-67-7 340 7440-74-6 172 7446-09-5 288 7553-56-2 172 7572-29-4 94 7580-67-8 186 ABD00023105 7616-94-6 246 7631-86-9 276 7631-90-5 282 7637-07-2 32 7646-85-7 338 7647-01-0 166 7664-38-2 254 7664-39-3 168 7664-41-7 14 7664-93-9 290 7681-49-4 282 7681-57-4 284 7697-37-2 224 7719-09-7 306 7719-12-2 256 7722-84-1 168 7722-88-5 304 7723-14-0 254 7726-95-6 32 7727-43-7 24 7773-06-0 16 CAS NUMBER INDEX 7778-18-9 48 7778-44-1 46 7782-41-4 146 7782-42-5 154 7782-49-2 276 7782-50-5 58 7782-65-2 150 7783-06-4 170 7783-07-5 168 7783-41-7 238 7783-54-2 228 7783-60-0 290 7783-79-1 276 7783-80-4 294 7784-42-1 20 7786-34-7 252 7789-30-2 34 7790-91-2 60 7803-51-2 254 7803-52-3 284 7803-62-5 278 8001-35-2 58 8002-05-9 246 8002-74-2 240 8003-34-7 270 8004-13-5 250 8006-61-9 150 8006-64-2 324 8008-20-6 184 8012-95-1 236 8022-00-2 206 8030-30-6 220 8032-32-4 332 8052-41-3 286 8052-42-4 22 6065-48-3 SO 9004-34-6 56 9005-25-8 284 9014-01-1 286 10022-31-8 24 10024-97-2 234 10025-67-9 290 ABD00023106 10025-87-3 254 10026-13-8 256 10028-15-6 238 10035-10-6 166 10049-04-4 58 10102-43-9 224 10102-44-0 228 10210-68-1 74 10294-33-4 32 10361-37-2 24 11097-69-1 64 11107-01-0 324 12001-26-2 216 12079-65-1 190 12108-13-3 206 12125-02-9 16 12179-04-3 30 12604-58-9 144 12718-69-3 324 13121-70-5 86 13397-24-5 154 CAS NUMBER INDEX 13463-39-3 222 13463-40-6 174 13463-67-7 310 13494-80-9 294 13838-16-9 128 14484-64-1 144 14807-96-6 292 14808-60-7 278 14977-61-8 72 15096-52-3 280 16219-75-3 140 16752-77-5 194 16842-03-8 74 17702-41-9 88 17804-35-2 24 18282-10-5 308 19287-45-7 92 19624-22-7 242 20816-12-0 238 21087-64-9 216 21351-79-1 56 21651-19-4 308 22224-92-6 142 25013-15-4 332 25321-14-6 118 25376-45-8 310 25639-42-3 204 26499-65-0 260 26628-22-8 280 26952-21-6 178 30525-89-4 345 31242-93-0 58 34590-94-8 122 35400-43-2 292 37329-49-0 324 53469-21-9 64 59355-75-8 198 61788-32-7 166 62765-93-9 222 65996-93-2 74 65997-15-1 262 68476-85-7 186 68956-68-3 328 93763-70-3 246 383 384 1001 4 1005 14 1008 32 1009 318 1010 34 1011 34 1013 52 1016 54 1017 58 1018 62 1020 66 1026 82 1028 96 1029 100 1032 110 1036 132 1037 134 1040 138 1045 146 1048 166 1050 166 ABD00023107 DOT ID NUMBER INDEX 1051 168 1052 168 1053 170 1060 198 1061 200 1062 200 1063 202 1064 214 1067 228 1070 234 1075 176, 186, 262 1076 252 1079 288 1080 288 1083 318 1085 330 1086 330 1089 2 1090 2 1092 6 1093 8 1098 10 1100 10 1104 16 1105 174,176 1110 200 1111 244 1114 26 1120 38, 40 1123 36, 38 1125 40 1131 52 1134 62 1135 134 1143 80 1145 82 1146 86 1148 90 1150 98 1154 106 1155 140 1156 106 1157 108 1158 110 1159 182 1160 110 1163 114 1165 120 1170 132 1171 130 1172 130 1173 130 1175 132 1184 136 1185 138 1188 202 1189 202 1190 140 1193 36 1198 148 1199 150 1203 150 1204 228 1206 156 1208 162 1212 176 1213 176 1219 180 1220 180 1221 180 1223 184 1228 234, 326 1229 194 1230 200 1231 196 1232 36 1233 164 1234 198 1235 200 1239 66 1243 210 1244 210 1245 164 1247 214 ABD00023108 1249 244 1255 246 1256 220 1259 222 1261 230 1262 236 1265 244 1268 286 1271 332 1274 268 1276 266 1279 268 1280 270 1282 272 1292 142 1294 310 1296 318 1297 318 1299 324 1301 328 1303 332 DOT ID NUMBER INDEX 1307 334, 336 1326 156 1334 220 1340 256 1344 258 1346 278 1356 322 1358 340 1361 72 1362 154 1376 172 1380 242 1381 254 1403 46 1414 186 1446 24 1463 70 1510 304 1516 338 1541 4 1547 18 1558 20 1564 24 1566 28 1567 28 1573 46 1578 226 1580 66 1583 66 1589 82 1591 96 1592 96 1593 208 1595 116 1597 116 118 1598 118 1600 118 1604 136 1605 136 1613 168 1648 4 1649 302 385 386 1650 222 1651 20 1654 224 1660 224 1661 226 1662 226 1664 232 1669 242 1670 246 1671 248 1673 248 1680 262 1687 280 1689 282 1690 282 1692 286 1697 60 1702 300 1704 294 1707 304 1708 312 ABD00023109 DOT ID NUMBER INDEX 1709 310 1710 316 1711 336 1715 2 1738 28 1744 32 1745 34 1749 60 1752 60 1755 70 1758 72 1760 100, 220 224 1779 148 1788 166 1789 166 1790 168 1805 254 1806 256 1809 256 1810 254 1813 262 1814 262 1823 284 1824 284 1828 290 1830 290 1831 290 1832 290 1836 306 1839 314 1845 52 1846 54 1848 266 1860 330 1865 270 1868 88 1885 26 1887 62 1888 64 1891 134 1897 300 1910 48 1911 92 1915 84 1916 98 1917 132 1918 80 1919 198 1920 234 1921 270 1932 340 1940 306 1941 108 1958 102 1959 332 1969 176 1978 262 1986 264 1991 68 1993 42 84 178 1994 174 1999 22 2008 340 2014 168 2015 168 2020 242 2023 128 2029 166 2030 166 2031 224 2032 224 2038 118 2047 100 2048 102 2053 212 2054 220 2055 286 2056 302 2058 326 2073 14 2074 6 2076 78 2077 222 2078 312 ABD00023110 2079 106 2085 26 2086 26 2087 26 2088 26 2089 26 2090 26 2127 208 2187 52 2188 20 2190 238 2191 292 2192 150 2194 276 2195 294 2199 254 2201 234 2202 168 2203 278 2205 8 2209 148 DOT ID NUMBER INDEX 2212 22 2214 256 2215 188 2218 8 2219 10 2228 42 2229 42 2232 60 2238 68 2249 64 2253 112 2256 84 2262 112 2265 114 2271 210 2279 158 2281 160 2284 178 2290 178 2294 218 2296 204 2297 204 2302 212 2304 220 2312 248 2315 64 2321 314 2325 320 2329 320 2337 26 2347 42 2348 38 2357 84 2362 98 2363 140 2369 36 2397 212 2402 264 2404 266 2411 44 2417 54 2418 290 387 388 2420 160 2431 18 2451 228 2471 238 2480 212 2489 208 2491 128 2504 6 2515 34 2516 54 253"1 194 2538 230 2545 156 2550 208 2553 220 2564 314 2570 44 2572 250 2574 322 2587 272 2590 22 2606 214 ABD00023111 DOT ID NUMBER INDEX 2608 230 2617 204 2618 332 2629 282 2644 210 2646 158 2647 190 2650 100 2658 276 2662 170 2667 44 2671 14 2672 14 2676 284 2681 56 2682 56 2686 106 2692 32 2693 282 2710 122 2717 48 2757 24 50 52 194 2761 8 58 88, 104 126 156 186 194 2762 56 2763 22 2765 88 292 2771 306 2781 122 2782 122 2783 22 70 92 102 124, 130 1 88 214 218 240 252 296 2789 2 2790 2 2805 186 2809 192 2821 248 2831 202 2842 228 2862 328 2871 18 2872 92 2873 94 2874 150 2876 272 2929 66 2979 326 2984 168 3018 253 296 3051 12 3054 82 3064 228 3079 198 3083 246 3141 18 3155 242 3293 166 9037 158 9089 16 9188 50 114 194 9192 146 9202 54 9260 12 ABD00023112 SYNONYM AND TRADE NAME INDEX AA 10 AAF 4 2-AAF 4 Abate 296 Acetal, 6 2- Acetammofluorene 4 Acetic acid (aqueous) 2 Acetic acid anhydride 2 Acetic aldehyde 2 Acetic ester 130 Acetic ether 130 Acetic oxide 2 3- (a-Acetonyl)-Denzyl-4-hydroxycoumann 2-Acetoxybenzoic acid 6 o-Acetoxybenzoic acid 6 1 -Acetoxyethylene 328 N-Acetyl-2-ammofluorene 4 Acetylene black 52 Acetylene dichloride 98 cis-Acetylene dichloride 98 trans-Acetylene dichloride 98 Acetylene tetrachloride 300 334 Acetyl mercaptan 306 Acetyl oxide 2 2-Acetyl propane 212 Acraldehyde, 6 Acridine, 74 Acroleic acid 8 Acrylaldehyde 6 Acrylamide monomer 6 Acrylic aldehyde, 6 Acrylic amide 6 Acrylonitrile monomer 8 Actmolite 22 Actmolite asbestos 22 Activated carbon 154 AGE 10 Alcohol 132 Aliphatic petroleum naphtha 246 Allyl aldehyde 6 Allylene 196 Allylic alcohol 10 1 -Allyloxy-2,3-epoxypropane 10 Allyl trichlonde, 316 389 ABD00023113 390 SYNONYM AND TRADE NAME INDEX (Continued) Alumina 12 Aluminum 12 Aluminum metal, 12 Aluminum oxide, 12, 126 Aluminum powder, 12 Aluminum trioxide 12,126 Amidocyanogen, 80 4-Aminoanilme, 248 ortho-Aminoamsole, 18 para-Aminoamsole 18 Ammobenzene 18 4-Aminobiphenyl, 14 p-Ammobiphenyl 14 1-Aminobutane 40 Ammocaproic lactam 50 Ammocyclohexane 84 Ammodimethylbenzene, 336 4-Ammo-6-(1 1-dimethylethyl)-3-(methylthio)-1 2 4-tnazin-5(4H)-one 216 p-Ammodiphenyl, 14 Aminoethane 132 N-(2-Aminoethy!)1 2-ethanediamine 106 2-Ammoethanol 128 [i-Aminoethyl alcohol 128 bis(2-Ammoethyl)amine 106 Aminoethylene, 138 Ammohexahydrobenzene 84 Aminomethane 200 1,3-bis(Aminomethyl)benzene, 336 3-Ammo-1-methy!benzene, 312 1-Aminonaphthalene 222 2-Ammonaphthalene 222 para-Ammonitrobenzene 226 1-Aminophenylmethane 312 2-Aminopropane 180 a-Aminopyndine 14 Aminotoluene, 312 2-Ammotoluene, 312 4-Ammotoluene, 312 m-Ammotoluene 312 o-Aminotoluene 312 Aminotriazole, 14 3-Ammotnazole, 14 2-Ammo-1 3 4-tnazote 14 ABD00023114 SYNONYM AND TRADE NAME INDEX (Continued) 3- Amino-l 2 4-triazole 14 4- Amino-3,5,6-tnchloropicolimc acid 258 4-Amino-3 5 6-trichloro-2-picolimc acid 258 Aminoxylene 336 Animate herbicide 16 Ammonium amidosulfonate 16 Ammonium chloride 16 Ammonium muriate fume 16 Amosite 22 AMS 16 216 Amyl acetic ester 16 Amyl acetic ether 16 Amyl aldehyde 326 Amyl ethyl ketone, 210 Amyl hydrosulfide 244 Amyl mercaptan 244 Amyl methyl ketone 200 n-Amyl methyl ketone, 200 Amyl sulfhydrate 244 AN 8 Anhydrous ammonia 14 Anhydrous borax 30 Anhydrous calcium sulfate, 48 Anhydrous gypsum 48 Anhydrous hydrogen bromide 166 Anhydrous hydrogen chlonde 166 Anhydrous hydrogen fluoride 168 Anhydrous sulfate of lime 48 Aniline Oil 18 Amlmobenzene 120 2-Amhnonaphthalene 250 2-Anisidme 18 Anol 84 Anone 84 Antabuse 122 Anthracite coal dust 72 Anthophyllite 22 Anthophyllite asbestos 22 Anthracene, 74 Antimony hydride 284 Antimony metal 18 Antimony powder 18 Antimony trihydride 284 Aprocarb, 266 391 ABD00023115 392 SYNONYM AND TRADE NAME INDEX (Continued) Aqua ammonia 14 Aqua fortis 224 Aqueous acrylic acid 8 Aqueous ammonia 14 Aqueous hydrogen bromide 166 Aqueous hydrogen chloride 166 Aqueous hydrogen fluoride 168 Argentum 280 Aroclor 1242 64 Aroclor 1254 64 Arsema 20 Arsenic hydride 20 Arsenic metal 20 Arsenic trihydride 20 Arsemuretted hydrogen 20 Arsenous hydride 20 Artificial barite 22 Asphaltum 22 Aspinn 6 Asymmetrical dichloroethane 98 Assymetrical tnmethylbenzene, 320 ATCP 258 Aurum paradoxum 294 Azabenzene 272 Azide 280 Azimethyiene 92 Azine 272 Azirane 138 Azindme 138 Azium 280 Azodnn, 218 Azomethylene 92 Azophos 214 Bacillus subtilis, 286 Bacillus subtilis 6PN 286 Bacillus subtilis Carlsburg 286 Banana oil 174 Barite 24 Barium dichloride 24 Barium dinitrate, 24 Banum(D) nitrate (1 2) 24 Barium salt of nitric acid, 24 Barium salt of sulfuric acid 24 Barytes 24 ABD00023116 SYNONYM AND TRADE NAME INDEX (Continued) Basudin 92 Battery acid 290 Baytex 144 BCME 64 Beet sugar 288 Benzenamine 18 Benzene chloride 62 1 4-Benzenediamine 248 1 3-Benzenedicarbortitnle 258 1 2-Benzenedicarboxylic anhydride 256 1 3-Benzenedimethanamme 336 1 2-Benzenediol, 56 o-Benzenediol 56 1 3-Benzenediol 272 m-Benzenediol 272 1 4-Benzenediol 170 p-Benzenediol 170 Benzene hexahydride 82 Benzene tetrahydride 84 1 2 4-Benzenetricarboxylic anhydride 318 Benzidine-based dyes 26 Benzoepm 126 Benzol 26 Benzo(a)pyrene 74 Benzoperoxide 26 1 4-Benzoquinone 272 p-Benzoqumone 272 Beryllium metal 28 BGE 42 BHC 186 BHT 124 4 4-Biamline 24 Bidrin 102 Bicyclopentadiene Biethylene 34 Biotite 216 Biphenyl, 120 102 4 4 -Biphenyldiamme 24 1 1 Biphenyl-4 4'-diamme 24 Bismuth sesquitellunde 28 Bismuth telluride 28 Bismuth tritelluride 28 Bitumen 22 Bituminous coal dust 72 393 ABD00023117 394 SYNONYM AND TRADE NAME INDEX (Continued) Bivinyl 34 Black copper oxide fume 76 Black lead 154 Bladafum 294 Bolstar, 292 Bottled gas 186 Borax 30 Borax decahydrate 30 Borax dehydrated 30 Borax pentahydrate 30 Boroethane 92 Boron bromide 32 Boron fluoride 32 Boron hydride 92 Bottled gas 262 BPL 264 Bromine fluoride, 34 5-Bromo-3-sec-butyl-6-methyluracil 32 Bromochloromethane 62 1- Bromo-i-chloro-2 2 2-trifluoroethane 2- Bromo-2-chloro-1 1 1-trifluoroethane Bromoethane 134 156 156 Bromoethene 330 Bromoethylene 330 Bromomethane 200 5-Bromo-6-methyl-3-(1 -methylpropyljuracil Bromotrifluoromethane 318 Burned lime 48 Burnt lime 48 Butadiene 34 normal-Butane 34 Butanedmitrile 288 Butanemtnle, 44 Butanethiol, 42 1-Butanethiol 42 n-Butanethiol 42 1- Butanol 38 2- Butanol 40 n-Butanol 38 2-Butanone peroxide, 208 2-Butenal 80 cis-Butenedioic anhydride 188 2-Butoxyethyl acetate 36 Butter yellow 110 32 ABD00023118 SYNONYM AND TRADE NAME INDEX (Continued) Butyl acetate 36 n-Butyl acrylate 38 Butyl alcohol 38 Butylamine 40 Butylated hydroxytoluene 124 Butyl Cellosolve 36 Butyl Cellosolve acetate 36 4-t-Butyl-2-chlorophenylmethyl methylphosphoramidate Butylene hydrate 40 n-Butyl ester of acetic acid 36 sec-Butyl ester of acetic acid 38 tert-Butyl ester of acetic acid 38 Butyl ester of acrylic acid 38 di-tert-Butyl ester of chromic acid 40 Butyl ester of 2-hydroxypropanoic acid 42 Butyl ester of lactic acid 42 Butyl ethanoate 36 Butyl ethyl ketone 134 Butyl glycol acetate 36 Butyl hydride 36 Butyl lactate 42 Butyl methyl ketone 164 80 Butyl oxitol 36 2-sec-Butylphenol 42 Butyl phosphate, 314 Butyl 2-propenoate, 38 4-tert-Butyltoluene 44 tert-Butyl valone 258 Butyrone 122 Butyromtrile, 44 Cadmium metal 44 Cadmium monoxide, 44 Cadmium oxide fume 44 Calcium carbimide 46 Calcium carbonate 186 192 Calcium hydrate, 46 Calcium hydrosilicate 48 Calcium metasilicate 48 Calcium monosilicate, 48 Calcium salt (2 3) of arsenic acid, 46 Calcium salt of carbonic acid 46 Calcium salt of silicic acid 48 Calcium salt of sulfuric acid 48 Calcium(ll) sulfate dihydrate 154 395 ABD00023119 396 SYNONYM AND TRADE NAME INDEX (Continued) Calcium sulfate hemihydrate 260 2-Camphonone 48 Cane sugar, 288 epsilon-Caprolactam 50 Captane 50 Captofol 50 Carbamaldehyde, 148 Carbicron 102 Carbimide 80 Carbinol 200 Carbodnmide, 80 Carbolic acid 248 Carbomethene, 184 2-Carbomethoxy-l-methylvtnyl dimethyl phosphate 252 Carbonate magnesium 188 Carbon bisulfide 52 Carbon bromide, 54 Carbon chloride, 54 Carbon difluoride oxide 54 Carbon fluoride oxide 54 Carbon hexachlonde 158 Carbonic acid gas 52 Carbon nitride 82 Carbon oxide 54 Carbon oxychloride, 252 Carbon oxyfluoride 54 Carbon sihcide 278 Carbon tet 54 Carbonyl chloride 252 Carbonyl dichloride 252 Carbonyl difluonde 54 di-mu-Carbonylhexacarbonyldicobalt Carborundum 278 Carboxyethane 266 4-Carboxyphthalic anhydride 318 Caustic lime 46 Caustic soda 284 CB 62 CBM 62 Cellosolve 130 Cellosolve acetate 130 Celtium 156 Cement 202 Cemented tungsten carbide 124 74 ABD00023120 SYNONYM AND TRADE NAME INDEX (Continued) Cemented WC 324 Cesium hydrate 56 Cesium hydroxide dimer 56 Cetyl mercaptan 160 CFC 113 316 Channel black 52 China clay 182 Chlorcyan 82 Chlordan 56 Chlordano 56 Chlordecone 184 Chlorine cyanide 82 Chlorine fluoride 60 Chlorine fluoride oxide 246 Chlorine oxide 58 Chlorine oxyfluonde 246 Chlorine peroxide 58 Chloroacetaldehyde (40% aqueous solution) 60 2-Chioroacetaldehyde 60 Chloroacetic acid chloride 60 Chloroacetic chloride 60 2 Chloroacetophenone 60 3-Chloroallyl chloride, 100 2-Chlorobenzalmalomtnle, 62 Chlorobenzol, 62 Chlorobutadiene, 68 2-Chloro-l,3-butadiene, 68 Chlorocamphene 58 Chlorochromic anhydride 72 Chlorocyantde 82 Chlorocyanogen 82 1- Chloro-2 3-dibromopropane 92 2- Cnioro-1-(difluoromethoxy)-1 1 2-tnfluoroethane 128 Chlorodimethyl ether 66 1- Chloro-2 3-epoxypropane 128 Chloroethane 134 2- Chloroethanal 60 2-Chloroethanol 134 Chloroethene, 330 1- Chloro-2-ethenylbenzene 68 2- Chloroethyl alcohol 134 Chloroethylene 330 bis(2-Chloroethyl)ether 98 2-Chloro-4-ethylamino-6-isopropylamino-s-tnazine, 22 397 ABD00023121 398 SYNONYM AND TRADE NAME INDEX (Continued) Chloroethylene, 330 6-Chloro-N-ethyl-N'-(1-methylethyl)-1 3 5-tnazine-2,4-diarmne Chlorofluorocartson 113, 316 Chloroformic acid dimethylamide, 112 Chloroformyl chlonde 252 Chloromethane 202 Chloromethoxymethane, 66 Chloromethylbenzene, 28 1- Chloro-2-methylbenzene 68 2- Chloro-1-methylbenzene, 68 Chloromethyl ether, 64 Chloromethyl phenyl ketone 60 4-Chloronitrobenzene 226 p-Chloromtrobenzene 226 1-Chloro-4-nitrobenzene, 226 Chloroprene, 68 1- Chloro-2-propene, 10 3- Chloropropene, 10 3-Chloropropylene 10 2- Chloropropylene oxide 128 y-Chloropropylene oxide 128 Chlorpyrifos-ethyl 70 22 2-Chlorostyrene 68 ortho-Chlorostyrene 68 Chlorothene 202 2-Chlorotoluene, 68 a-Chlorotoluene 28 2-Chloro-6-(trichloro-methyl)pyridme 68 Chlorotrifluoride 60 2-Chloro-1 1 2-tnfluoroethyl difluoromethyl ether 128 Chrome, 72 Chromic acid (Cr03), 70 Chromic anhydride, 70 Chromic oxide, 70 Chromic oxychloride 72 Chromium, 72 Chromium chloride oxide 72 Chromium dichlonde dioxide 72, Chromium dioxide dichloride 72 Chromium dioxychloride 72 Chromium(VI) oxide (1 3) 70 Chromium trioxide 70 Chrysene 74 Chrysotile 22 ABD00023122 CI-2 206 Cmenn I or II 270 Clay 182 bis-CME 64 CMME 66 Coal tar 74 Cobalt metal Oust 74 Cobalt metal fume 74 Cobalt octacarbonyl 74 Cobalt tetracarbonyl dimer 74 Colloidal manganese 190 Colloidal mercury 192 Cologne spirit 132 Columbian spints 200 Combustion Improver-2 206 Compressed petroleum gas 186 Confectioner s sugar 288 Copper fume 76 Copper metal dusts 76 Copper metal fumes 76 Copper monoxide fume, 76 Copper(ll) oxide 76 SYNONYM AND TRADE NAME INDEX (Continued) Corn starch 284 Corundum 126 Coyden, 72 Crag herbicide No 1 73 2- Cresol 78 3- Cresoi 78 4- Cresol 78 meta-cresol 78 ortho-Cresol, 78 para-Cresol 78 Creosote 74 m-Cresylic acid 78 o-Cresyhc acid 78 p-Cresyhc acid 78 Cnstobalite 278 Crocidolite 22 Crude solvent coal tar naphtha 220 Cryocide, 280 Cryodust 280 Cryolite 280 CS 62 Cucumber dust. 46 399 ABD00023123 400 psi-Cumene, 320 Cummingtomte-grunente 22 Cumol, 80 Cupric oxide 76 Cyanamide 46 80 Cyanoacetomtnle 190 Cyanoethane, 266 Cyanoethylene 8 Cyanogen nitride, 80 Cyanohydnn-2-propanone 4 Cyanomethane 4 Cyanomethanol 152 1-Cyanopropane 44 2-Cyano-2-propane 4 2-Cyanopropene-1, 198 2-Cyano-1-propene, 198 1 4-Cyctohexadiene dioxide 272 Cyclohexyl alcohol 84 Cyclohexyl ketone, 84 Cyclohexylmercaptan 82 Cyclohexylmethane, 204 Cyclohexylthiol 82 SYNONYM AND TRADE NAME INDEX (Continued) 1 3-Cyclopentadiene 86 bis(Cyclopentadienyl)iron 104 Cyclopentadienylmanganese tricarbonyl, 190 Cyclopentadieny! tricarbonyl manganese 190 Cyclotrimethylenetnmtramine 86 DAB 110 DACPM, 206 Dactm, 98 Dalapon, 100 Dasamt 142 DBCP, 92 DBF 94 DCA 94 o-DCB 96 p-DCB, 96 1 1-DCE 332 DCP, 100 DCPD, 102 DDH 98 p,p'-DDT, 88 DDVP 102 DEA, 104 ABD00023124 SYNONYM AND TRADE NAME INDEX (Continued) Decaboron tetradecahydnde 88 Decachlorooctahydro-1,3,4-metheno-2H'Cyclobuta(cd)-pentalen-2- one 184 Decachlorooctahydro-kepone-2-one, 184 Decachlorotetrahydro-4,7-methanomdeneone, 184 Decylmercaptan, 88 n-Decylmercaptan 88 DEHP 118 DEK 106 Delnav 120 Demeton methyl 206 DEP 108 DETA 106 DGE 108 Diacetone 90 Diallyl ether dioxide 108 Diamine 166 1 4-Diammobenzene 248 p-Diaminobenzene 248 4,4'-Diaminobiphenyl 26 4,4'-Diamino-3,3,'dichlorobiphenyll 96 2 2'-Diaminodiethylamine 106 4,4'-Diammo-3,3'-dimethylbiphenyl 310 p-Diammodiphenyl, 26 4,4'-Diammodiphenylmethane, 208 para para'-Diaminodiphenyl-methane, 208 Diaminoditolyl 310 1.2- Diammoethane, 136 1.3- Diamino-4-methoxy benzene 90 Diaminotoluene 310 Diamlinomethane, 208 Diamsidme, 90 3 3'-Diamsidme, 90 Diatomaceous earth 276 Diatomaceous silica 276 Diatomite, 276 Diazide 92 Diazinne 92 Dibasic zinc stearate 338 Dibenzothiaztne 248 Dibenzoyl peroxide, 26 DIBK 108 Diboron hexahydnde, 92 Dibrom, 114 401 ABD00023125 402 SYNONYM AND TRADE NAME INDEX (Continued) 1 2-Dibromo-2 2-dichloroethyl dimethyl phosphate, 114 Dibromochloropropane 92 Dtbromodifluoromethane 108 1,2-Dibromoethane, 136 Dibutyl acid o-phosphate, 94 Dibutylaminoethanol, 94 2-Dibutylaminoethanol, 94 2-Di-N-butylaminoethanol 94 2-Di-N-butylammoethyl alcohol, 94 Dibutylated hydroxytoluene, 124 Dibutyl 1 2-benzene-dicarboxylate 94 N N-Dibutylethanolamme 94 Di-n-butyl hydrogen phosphate, 94 Dibutyl phosphoric acid 94 Di-n-butyl phthalate 96 1 2-Dichlorobenzene 94 1 4 Dichlorobenzene 96 odho-Dichlorobenzene 96 para-Dichlorobenzene 96 Dichlorobenzidine base 96 o o -Dichlorobenzidine, 96 o-Dichlorobenzol 96 3 3'-Dichlorobiphenyl-4 4'-diamine, 96 3,3'-Dichloro-4,4'-biphenyldiamine, 96 3 3`-Dichloro-4,4'-diaminobiphenyl, 96 3,3'-Dichloro-4 4'-diaminodiphenylmethane, 106 2,2'-Dichlorodiethyl ether, 98 2.2- Dichloro-1 1-dif!uoroethyl methyl ether, 196 2.2- Dichloro-1,1 -difluoro-1 -methoxyethane 196 Dichlorodimethyi ether, 64 3,5-Dichloro-2 6-dimethyl-4-pyndinol 72 Dichlorodioxochromium 72 Dichlorodiphenyltrichloroethane, 88 1.2- Dichloroethane, 136 1 1-Dichloroethene, 332 1 1-Dichloroethylene 332 sym-Dichloroethylene, 98 2,2'-Dichloroethyl ether 98 Dichloroethyne 94 Dichlorofluoromethane 100 Dichloromethane 208 Dichloromethyl ether 64 Dichloromtroethane 100 3-(3,4-Dichlorophenyl)-t 1 -dimethylurea 124 ABD00023126 SYNONYM AND TRADE NAME INDEX (Continued) Dichloropbenoxyacetic acid 88 2 4-Dichlorophenoxyacetic acid 88 2-(2,4-Dichlorophenoxy)ethyl sodium sulfate Dichloro-1 2-propane 268 1 2-Dichloropropane, 268 2 2-Dichloropropanoic acid 100 1 3-Dichloro-1-propene 100 a a-Dichloropropionic acid 100 1 3-Dichloropropylene 100 1 2-Dichlorotetrafluoroethane 102 2 2-Dichlorovmyl dimethyl phosphate 102 Dicobalt carbonyl 74 Dicobalt octacarbonyl 74 Dicyan, 82 1 3-Dicyanobenzene 258 m-Dicyanobenzene 258 1 4-Dicyanobutane 8 1,2-Dicyanoethane, 286 Dicyanogen 82 Dicyanomethane 190 Dicyclohexylmethane 4 4'-dnsocyanate 206 1 3-Dicyclopentadiene dimer 102 78 Di(2 3-epoxypropyl) ether 108 Diethamme 106 Diethyl, 34 N N-Diethylamine 106 Diethylammoethanol, 106 2-Dtethylammoethyl alcohol, 106 Diethyl benzene 124 Diethyl (dimethoxyphosphinothioylthio) succinate 188 Diethylene dioxide, 120 Diethylene ether 118 Diethylene imidoxide, 220 Diethylene oxide 302 Diethylene oximide 220 Diethyl ester of phthalic acid 108 N N-Diethylethanolamine 106 Diethyl ether, 140 O-O-Diethyl-Ofand S)-2-(ethylthio)ethyl phosphorothioate mixture 90 O O-Diethyf S-2-(ethylthio)-ethyl phosphorodithioate 124 O O-Diethyl S-(ethylthio)methylphosphorodithioate, 252 O O-Diethyl S-ethylthiomethylthiothionophosphate, 252 Diethyl-(2-hydroxyethyl)amme, 106 403 ABD00023127 404 SYNONYM AND TRADE NAME INDEX (Continued) 0 0-Diethyl-0*2-iaopropyl-4-methyl-6-pynmidinyl-phosphorothioate 92 O O-Diethyl CMp-methylsulfinyl)phenyl)phosphorothioate 142 Diethyl oxide 140 Di(2-ethylhexyl) phthalate 118 Diethylmethylmethane 162 O O-Diethyl-O(p-mtrophenyl) phosphorothioate 240 Diethyl parathion 240 bis(Diethylthiocarbamoyl) disulfide, 122 0 O-Diethyl 0*3 5 6-tnchloro-2-pyndyl phosphorothioate 70 Difluonne monoxide 238 Difluorochloromethane 62 Difluorodichloromethane 96 1 1-Difluoroethene 332 Difluoro-1 1-ethylene 332 1 1-Oifluoroethylene 332 1 2-Difluoro-1 1 2 2-tetrachloroethane 298 2 2-Difluoro-1 1 1 2-tetrachloroethane 298 Difolatan 50 2 3-Oihydro-2 2-aimethyl-7-benzofuranyl methylcarbamate 52 Dihydroxybenzene 170 1 2-Dihydroxybenzene 56 1 3-Dihydroxybenzene 272 1 4-Dihydroxybenzene 170 m-Dihydroxybenzene 272 o-Dihydroxybenzene 56 2 2 -Dihydroxydiethyamine 104 1 2-Dihydroxyethane 136 Di(2-hydroxyethyl)amme 104 2 4-Dihydroxy-2-methylpentane 164 1 6-Dnsocyanatohexane 160 1 5-Dnsocyanatonaphthalene 220 Dusopropyl 162 sym-Dnsopropyl acetone 108 Dusopropyl ether 182 Dusopropyl oxide 182 Dimazme 114 3 3-Dimethoxybenzidine 90 p p -Dimethoxydiphenyltrichloroethane Dimethoxyrnethane 198 N N-Dimethyl acetamide 110 Dimethylacetone 106 Dimethylamme (anhydrous) 110 Dimethylammobenzene 336 194 ABD00023128 SYNONYM AND TRADE NAME INDEX (Continued) p Dimethylarrunoazobenzene 110 N N-Dimethyl-4-ammoazobenzene 110 3-(Dimethylamino)propionitnle 112 N N-Dimethylamino-3-propionitnle 112 Dimethylamline 112 336 2 4-Dimethylanilme 336 1 2-Dimethylbenzene 334 1 3-Dimethylbenzene 336 1 4-Dimethylbenzene 336 N N-Dimethylbenzeneamme 112 3 3 -Oimethylbenzidme 310 1 1 -Dimethyl-4 4 bipyndinium bichloride 240 N N -Dimethyl-4 4 -bipyndinium dichlonde 240 2 2-Dimethylbutane 162 2 3-Dimethyibutane 162 1 3-DirnethylDutyl acetate 164 Dimethylcarbarmc chloride 112 N N-Dimethylcarbamoyl chloride 112 Dimethyl carpinol 180 Dimethylcnioroether 66 2-Dimethyl cis-2-dimethylcarbamoyl-l-methylvinylphosphate 3 3-Dimethyl 4 4'-diphenyidiamme 310 102 tns(Dimethyldithiocarbamato)iron 144 Dimethyleneimme 138 Dimethylene oxide 138 Dimethylentmine 138 Dimethyl ester of 1 2-benzenedicarboxylic acid 114 Dimethyl ester of sulfuric acid 116 O O-Dimethyl 2-ethylmercaptoethyl thiophosphate 206 Dimethyl formamide 114 N N-Dimethylformamide 114 2 6-Dimethyl-4-heptanone 108 Dimethylketone 2 N N-Dimethylmethanamme 318 Dimethyl methane 262 O O-Dimethyl 0-3-methyl-4-methylthiophenyl phospnorothioate 144 Dimethylmtromethane 230 O O Oimethyl-O-p-nitrophenylphosphorothioate 214 Dimethylmtrosoamine 232 N N-Dimethylmtrosamine 232 O O-Dimethyl-S-4-oxo-l 2 3-benzotriazm-3(4H)-ylmethyl phosphorodithioate 22 N N-Dimethylphenylamine 112 Dimethylsulfate 116 405 ABD00023129 406 SYNONYM AND TRADE NAME INDEX (Continued) bis(Dimethylthiocarbamoyl) disulfide 306 0 O-Dimethyl 0-{2,4,5-tnchlorophenyl) phosphorothioate 274 Dmile, 288 1 2-Dinitrobenzene 116 1 3-Dimtrobenzene 116 1,4-Dinitrobenzene 118 meta-Dimtrobenzene 116 ortho-Dmitrobenzene 116 para-Dmitrobenzene 118 4 6-Dmitro-o-cresol 118 Dinitrogen monoxide 234 Dmitrogen letroxide 228 3 5-Dmitro-2-hydroxytoluene 118 4 6-Dmitro-2-methyl phenol 118 3 5-Dinitro-o-toluamide 116 Dmitrotoluol 118 Diolamme 104 Dioxan 120 1 4-Dioxane, 120 p-Dioxane 120 p-Dioxane-2,3-diyl ethyl phosphorodithioate, 120 Dioxane phosphate, 120 2 3-p-Dioxanethiol S S-bis(0,0-diethyl phosphoro-dithioate), 120 Dioxin 298 Dioxine, 298 1 3-Dioxo-2-pivaloy-lindane, 258 DIPA, 110 N N-Diphenylanilme 322 N N-Diphenylbenzenamine, 322 1 2-Diphenylbenzene 296 1,3-Diphenylbenzene 296 1 4-Diphenylbenzene 298 m-Diphenyibenzene 296 o-Diphenylbenzene 296 p-Diphenylbenzene 298 Diphenyl ether 248 4 4'-Diphenylmethanediamine 208 4 4'-Diphenylmethane dnsocyanate 208 Diphenyl oxide 248 Diphenyl oxide-diphenyl mixture, 250 Dipropylene glycol monomethyl ether, 122 Diquat dibromide 122 Direx 124 Disodium pyrosulfite 284 ABD00023130 Disoaium 5ai* of bone acid 30 Disodium tetrabromate, 30 Oisulfur decafluoride, 290 Di-Syston 124 4 5-Dithia-1-octene 10 Dithion 294 Divanadium pentoxide dust 328 Divanadium pentoxide fume 328 Divinyl, 34 DMAC 110 DMCC 112 DMF 114 DMH 114 DMNA 232 DMP 114 DMDI 206 DMDT 194 DNC 118 DNOC 118 DNT 118 Dodecyl mercaptan 126 1-Dodecyl mercaptan 126 SYNONYM AND TRADE NAME INDEX (Continued) a Dodecyl mercaptan 126 DOP 118 Doped bismuth sesquitellunde, 28 Doped bismuth teilunde, 28 Doped bismuth tritellunde 28 Doped tellurobismuthite 28 Dowanol EB 36 Dowanol 50B, 122 Dowco 132, 80 Dowtherm 209 268 Dowtherm A 250 DPA 120 DPK 122 Dried calcium sulfate, 260 Dry cleaning safety solvent, 286 Dry ice 52 Dursban, 70 DVB 124 Dyfonate, 146 Dyphonate, 146 EGBE 36 EGBEA 36 407 ABD00023131 408 SYNONYM AND TRADE NAME INDEX (Continued) EGDN 138 EGEE 130 EGEEA 130 EGME 202 EGMEA 202 Ektasolve EB, 36 Ektasolve EB acetate 36 Elemental hafnium 156 Elemental nickel 224 Elemental phosphorus 254 Elemental rhodium 272 Elemental selenium 276 Elemental silicon 278 ENB 140 Endosulphan 126 Engravers acid 224 Entex, 144 1 4-Epoxybutane 302 1 2-Epoxy-3-butoxypropane 42 1 2-Epoxy ethane 138 1-Epoxyethyl-3 4-epoxy-cyclohexane 1 2-Epoxy-3-isopropoxypropane 182 330 1 2-Epoxy-3-phenoxy propane 250 1 2-Epoxy propane 270 2 3-Epoxy-1-propanol 152 Epoxypropyl alcohol 152 2 Epoxypropyl ether 108 bis(2 3-Epoxypropyh ether "'08 trythrene 34 Essence of mirbane 226 Ethanal 2 Ethanecarboxyhc acid, 266 1 2 Ethanediamme 136 Ethanedimtnle 82 Ethanedioic acid 238 1 2-Ethanediol 136 1 2 Ethanediol dinitrate 138 Ethane hexachlonde 158 Ethane pentachloride 242 Ethanethiol 140 Ethane trichloride 314 Ethanoicacid 2 Ethanoic anhydride 2 Ethanol 132 ABD00023132 SYNONYM AND TRADE NAME INDEX (Continued) Ethenone 184 Ethenyi acetate 328 Ethenylbenzene 286 Ethenyi ethanoate 328 Ethenylmethylbenzene 332 Ether 140 Ethine 4 S-[1 2 bis(ethoxycarbonyl) ethylJO O-dimethyl-phosphorodithioate 188 Ethrane 128 Ethyl acetone 244 Ethyl acrylate (inhibited) 132 Ethyl aldehyde 2 Ethylamme lanhydrousi 132 Ethyl amyl ketone 210 Ethylbenzol 132 Ethyl carbmol 268 Ethyl cyanide 266 1 1 Ethylene 2 2-bipyridylhum dibromide 122 Ethylene bromide 136 Ethylenecarboxylic acid 8 Ethylene chlorhydrin 134 Ethylene chloride 136 Ethylene cyanide 288 Ethylenediamme (anhydrous) 136 Ethylene dicyanide 288 Ethylene dinitrate 138 Ethylene glycol isopropyl ether 180 Ethylene glycol monobutyl ether 36 Ethylene glycol monobutyl ether acetate 36 Ethylene glycol monoethyl ether 130 Ethylene glycol monoethyl ether acetate 130 Ethylene glycol monomethyl ether 202 Ethylene glycol monomethyl ether acetate 202 Ethylene monochloride 330 Ethylene nitrate 138 1 3-Ethylene-2-thiourea 138 N N-Ethylenethiourea 138 Ethylene trichloride 316 Ethylemmine 138 Ethyl ester of acetic acid 130 Ethyl ester of acrylic acid 132 Ethyl ester of formic acid 140 N Ethylethanamme 106 409 ABD00023133 410 SYNONYM AND TRADE NAME INDEX (Continued) Ethyl ethanoate 130 Ethylformic acid 266 bis-(2-Ethylhexyl)phthalate 118 5-Ethylidenebicyclo(2 2 1 )-hept-2-ene 140 5-Ethylidene-2-norbornene 140 Ethylidene chloride 98 1 1-Ethylidene dichloride 98 Ethylimme 138 Ethyl ketone 106 Ethyl methanoate 140 Ethyl methyl ketone 36 Ethyl methyl ketone peroxide 208 Ethyl 3-methyl-4-(methylthio)phenyl-(1-methylethyl)phosphoramidate 142 O-Ethyl 0-(4-methylthio)phenyl S-propylphosphorodithioate, 292 4-Ethylmorphohne 142 Ethyl nitrile 4 Ethyl p-mtrophenyl benzenethionophosphonate 128 O-Ethyl 0-(4-mtrophenyl) phenylphosphonothioate 128 Ethylolamine 128 Ethyl orthosilicate, 142 Ethyl oxide 140 Ethyl parathion, 240 Ethyl phthalate 108 O-Ethyl-S-phenyl ethylphosphorothioate Ethyl propenoate 132 Ethyl pyrophosphate 296 Ethyl silicate (condensed), 142 Ethyl sulfhydrate, 140 Ethyne 4 EtOH 132 ETU 138 Expanded perfite 246 FAA 4 2-FAA 4 Fenothiazine, 248 Fenylfosfm 252 Fermentation amyl alcohol 174 Feme chloride 174 Ferric dimethyl dithiocarbamate 144 Ferric nitrate 174 Ferric oxide 172 Ferric sulfate, 174 Ferrocene 104 146 ABD00023134 Ferrous chloride 174 Ferrous sulfate 174 Ferrovanadium 144 Fusel oil 174 Fiber glas 144 Fiberglass 144 Floridine 282 Flue gas 54 2-Fluorenylacetamide 4 Fluorme-19 146 Fluorine monoxide 238 Fluorocarbon-12 96 Fluorocarbon-22 62 Fluorocarbon-115 66 Fluorocarbon 1011 62 Fluorocarbon 1301 318 Fluorodichloromethane 100 Fluoroethene 330 Fluoroethylene 330 Fluoroformyl fluoride 54 Fluorophosgene 54 Fonophos 146 SYNONYM AND TRADE NAME INDEX (Continued) Formal 198 Formaldehyde cyanohydrin 152 Formaldehyde dimethylacetal 198 Formaldehyde solution 148 Formic acid (85-95% in aqueous solution) 148 Formomtrile 168 Freon 10 54 Freon 11 146 Freon 12, 96 Freon 21 100 Freon 22 62 Freon 112 298 Freon 112a 298 Freon 113 316 Freon 114 102 Freon 115 66 Freon 12B2 108 Freon 13B1 318 Fuel Oil No 1 184 Furacarb 52 Furadan 52 Fural 150 411 ABD00023135 412 2-Furancarboxaldehyde 150 2 5-Furanedione 188 Furfuraldehyde 150 2-Furfuraldehyde 150 Furnace black 52 2-Furylmethanoi 150 Fused borax, 30 Genetron 12 96 Genetron 21, 100 Genetron 22, 62 Genetron 113, 316 Genetron 114, 102 Genetron 115 66 Germane 150 Germanium hydride 150 Germanomethane 150 Glacial acetic acid 2 Glacial acrylic acid 8 Glass fibers 144 Glass wool 144 Glutaric dialdehyde 152 Glycerin (anhydrous) 152 SYNONYM AND TRADE NAME INDEX (Continued) Glycerol 152 Glycerol tnchlorohydrin 316 Glyceryl tnchlorohydrin 316 Glyceryl trinitrate 228 Glycide 152 Glycidyl phenyl ether 250 Glycol 136 Glycol alcohol, 136 Glycol dibromide, 136 Glycol dichloride, 136 Glycol dinitrate, 138 Glycolic nitrile 152 Glycol monoethyl ether acetate 130 Glycol monomethyl ether 202 Glycol monomethyl ether acetate 202 Glycomtrile 152 Glycyl alcohol 152 Gram alcohol 132 Gum camphor 48 Gumspirits 324 Gum turpentine 324 Guthion 22 ABD00023136 Gypsum hemihydrate 260 Gypsum stone 154 Hafnium metal 156 Halane 98 Halocarbon 112 298 Halocarbon 112a 298 Halocarbon 113, 316 Halocarbon 1132A, 332 Halocarbon 115 66 Halocarbon 13B1 318 Halon 104 54 Halon 112 100 Halon 122 96 Halon 242 102 Halon 1011 62 Halon 1202 108 Halon 13C1 318 Haiowax SCO 3lb Halowax 1013 242 Haiowax 1014 160 Halowax 1051 234 Hard metal 324 SYNONYM AND TRADE NAME INDEX (Continued) Hard wood dust 334 HCBD 158 HCCPD 158 HCH 186 HDI 160 Heavy mineral oil mist 236 Hemellitol, 320 Hemihydrate gypsum, 260 Hemimellitene 320 HEOD, 104 1 4 5 6 7 8 8-Heptachloro-3a 4 7 7a-tetrahydro-4 7-methanoindene 156 Heptane 156 normal-Heptane 156 Heptan-4-one 122 2 Heptanone 200 3 Heptanone 134 4-Heptanone 122 Heptyi mercaptan 158 n-Heptyl mercaptan 158 Hexachloro-1,3-butadiene 158 1 3-Hexachlorobutadiene 158 413 ABD00023137 414 SYNONYM AND TRADE NAME INDEX (Continued) y-Hexachlorocyclohexane 186 1,2 3,4,5,6-Hexachlorocyclohexane, gamma isomer of 186 Hexachloro-1 3-cyclopentadiene 158 1 2 3 4 5 5-Hexachloro-1 3-cyclopentadiene 158 1 2 3 4 10 10-Hexachloro-6 7-epoxy-1,4 4a 5 6 7 8 8a-octahydro- 1 4-endo, endo-5 8-dimethanonaphthalene 126 1 2 3 4,10,10-Hexachloro-6 7-epoxy-1,4 4a 5 6,7 8,8a-octahydro- 1 4-endo exo-5 8-dimethanonaphthalene 104 6 7 8 9 10-Hexachloro-l 5 5a 6 9 9a-hexachloro-6,9-methano-2 4 3- benzo-dioxathiepm-3-oxide 126 1 2 3 4 10,10-Hexachloro-1 4 4a 5 8 8a-hexahydro-endo-1 4-exo- 5,8-dimethanonaphthalene 8 Hexadecanethiol-1 160 n-Hexadecanethiol 160 Hexadecyl mercaptan 160 Hexadrin 126 Hexafluoro-2-propanone 160 1 1 1 3 3 3-Hexafluoro-2-propanone 160 Hexahydroamline 84 Hexahydro-2H-azepin-2-one 50 Hexahydrobenzenamme 84 Hexahydrobenzene 82 Hexahydrocresol 204 Hexahydromethylphenol 204 Hexahydrophenoi 84 Hexahydrotoluene 204 Hexahydro-1 3 5-trinitro-s-tnazme 84 Hexalin 84 Hexamethylene, 82 Hexamethylene-1 6-dnsocyanate, 160 1 6-Hexamethylene diisocyanate 160 Hexamethylphosphoric triamide 162 Hexamethylphosphorotnamide 162 Hexanaphthene 82 Hexane 162 normal-Hexane 162 Hexanedimtrile 8 1-Hexanethiol 162 Hexyl hydride 162 Hexyl mercaptan 162 n-Hexyl mercaptan 162 n Hexylthiol 162 HFA 160 HF-A 168 ABD00023138 SYNONYM AND TRADE NAME INDEX (Continued) HHDN 8 High solvent naphtha, High-strength hydrogen peroxide HMDI 160 HMPA 162 HPA 170 Hydralm 84 Hydrated aluminum silicate 182 Hydrated calcium sulfate 154 Hydrated lime 46 Hydraulic cement 262 Hydrazine (anhydrous) 166 Hydrazine base 166 Hydrazmobenzene 25C Hydnte 182 Hydroacryhc acid 264 Hydrobromic acio a-lactone 16o Hydrochloric acid 166 Hydrochloric ether 134 Hydrocobalt tetracarbonyl 74 Hydrocyanic acid 168 Hydrofluoric acid 168 168 Hydrogen antimomde, 284 Hydrogen arsenide 20 Hydrogenated diphenylbenzenes 166 Hydrogenated MDI 206 Hydrogenated phenylbiphenyls 166 Hydrogenated triphenyls 166 Hydrogen carboxylic acid 148 Hydrogen cyanamide 80 Hydrogen dioxide 168 Hydrogen nitrate 224 Hydrogen peroxide (aqueous) 168 Hydrogen phosphide 254 Hydrogen sulfate 290 Hydromagnesite 188 Hydroperoxide 168 Hydroqumone monomethyl ether 196 Hydrosulfuric acid 170 Hydrous magnesium silicate 292 Hydroxyacetomtnle 152 p-Hydroxyamsole 196 Hydroxybenzene 248 1-Hydroxybutane 38 415 ABD00023139 416 SYNONYM AND TRADE NAME INDEX (Continued) 2 Hydroxybutane 40 Hydroxycellulose 56 Hydroxycyclohexane 84 2- Hydroxyethylamme 128 bis(2-Hydroxyethyl)amme 104 [3-Hydroxyethyl isopropyl ether 180 u-Hydroxyisobutyromtnie 4 3- Hydroxy-(5-lactone 264 1-Hydroxy-2-methylbenzene 78 1-Hydroxy-3-methylbenzene 78 1- Hydroxy-4-methylbenzene 78 3- Hydroxy-N-methylcrotonamide dimethylphosphate Hydroxymethyl ethylene oxide 152 2- Hydroxymethylfuran 150 218 2-Hydroxymethyl oxiran 152 4- Hydroxy-4-methyl-2-pentanone 90 2 2-bis(Hydroxymethyl)-1 3-propanediol 244 2- Hydroxy-2-methyl-propiomtnle 4 4-Hydroxy-3-(3-oxo-1-phenyl butyl )-2H-1-benzopyran-2-one 2 Hydroxyphenol 56 3- Hydroxyphenol 272 m-Hydroxyphenol 272 3-Hydroxy-1-propanesulphomc acid sultone 3-Hydroxy-propionic acid 264 [i-Hydroxypropyl acrylate 170 3-Hydroxypropylene oxide 152 2-Hydroxytoluene 78 3-Hydroxytoluene 78 4-Hydroxytoluene 78 2-Hydroxytnethylamme 106 Hyponitrous acid anhydride 234 IBA 176 IGE 182 2-lmidazolidme-2-thione 138 2 2 -Immodiethanol 104 Impure corundum 126 Indium metal 172 Indonaphthene 170 Inert dusts 240 Iodine crystals 172 lodomethane 210 N-IPA 182 IPDI 178 Iron carbonyl 174 264 ABD00023140 SYNONYM AND TRADE NAME INDEX (Continued) Iron dicyclopentadienyl 104 Iron(ll) chloride 174 Iron(llf) chloride 174 Iron(ill) nitrate 174 Iron(lll)oxide 172 276 Iron oxide red 276 Iron(tl) sulfate 174 Iron(lll) sulfate, 174 Isoacetophorone, 178 Isoamyl methyl ketone 212 Isobutanol 176 Isobutenyl methyl ketone 198 Isobutyl carbinol 174 Isobutyl ester of acetic acid 176 Isobutyimethylcarbmoi 212 Isobutyl methyl ketone 164 bis(4 IsocyanatocyclohexyDmethane 206 3-lsocyanatomethyl-3 5 5-tnmethylcyclohexyl-isocyanate Isohexane 162 Isooctanol 178 Isopentyl acetate 174 Isopentyl alcohol 174 178 Isopentyl methyl ketone 212 Isophorone diamine dnsocyanate 178 Isophthalodimtrile 258 Isoprene cyanide 198 Isopropanol 180 Isopropenyl benzene 216 Isopropenylmtrile 198 Isopropoxymethyl oxirane 182 o-lsopropoxyphenyl-N-methylcarbamate 2-lsopropoxy propane 182 Isopropyiamline 182 Isopropyl benzene 80 Isopropylcarbinol 176 Isopropyl Cellosolve 180 Isopropyl cyanide 178 Isopropyl ester of acetic acid 180 Isopropyl glycol 178 Isopropyhdeneacetone 194 Isopropyl methyl ketone 212 Isovalerone 108 Jasmolin I or II, 270 Jeffersol EB 36 266 417 ABD00023141 418 Karmex 124 Keto-ethylene 184 Ketone propane, 2 Korax 66 f3-Lactone 264 Lannate 194 Lamp black 52 Lanstan 66 Laughing gas 234 Laurel camphor 48 Lauryi mercaptan 126 n-Lauryl mercaptan 126 Lead metdi 184 Lead 'etraethyl 302 Leaa tetramethyi 3C2 Lepidohte 216 Lignite coal dust 72 Ligrom 332 Lime 48 Lime nitrogen 46 Liquefied hydrocarDon gas 186 Liquefied petroleum gas 186 SYNONYM AND TRADE NAME INDEX (Continued) Lithium monohydride 186 LPG 186 Lye 262 284 MA 218 Mace 60 Magnesium carbonate 188 Magnesium(ll) carbonate 188 Magnesia fume 188 Maleic acid anhydride 188 Malomc aldehyde 190 Malonicdimtnle 190 Malonodialdehyde 190 Manganese-55 190 Manganese metal 19C Manganese oxide 192 Manganese tricarbonylmetnylcyciopentadienyl Manganomangamc oxide 19? Manmade mineral fibers 216 MAPPgas 198 Margarite 216 Massive talc 280 MBK 164 206 ABD00023142 MBOCA 206 MCB 62 MCT 190 MDA 208 MDI 208 Mecrylate 204 MEK 36 MEKP 208 MEK peroxide 208 Mequmot 196 Mercaptoacetate 306 Mercaptoacetic acid 306 2-Mercaptoacetic acid, 306 Mercaptobenzene 26 1-Mercaptobutane 42 1-Mercaptodecane 88 1-Mercaptododecane 126 Mercaptoethane 140 Mercaptomethane 214 1-Mercaptononane 234 1-Mercaptooctadecane 236 1-Mercaptooctane 236 SYNONYM AND TRADE NAME INDEX (Continued) 3-Mercaptopropane 264 Mercury metal, 192 Mesitylene, 320 Metacetone 106 Metacetomc acid 266 Metallic mercury 192 Metallic tin 308 Metallum problematum 294 Metasystox, 206 Methacrylate monomer 214 Methacryhc acid (glacial) 194 Methacrylic acid (inhibited) 194 a-Methacryhc acid 194 Methacrylonitrile 198 Methanal 148 Methanamide 148 Methanecarboxylic acid, 2 Methane tetrabromide 54 Methane tetramethylol 244 Methanethiol 214 Methane trichloride 64 Methanoic acid 148 ABD00023143 SYNONYM AND TRADE NAME INDEX (Continued) Methanol 200 Methoflurane 196 0-Methoxyanilme 18 p-Methoxyamline 18 4-Methoxy-l 3-benzene-diamine 90 Methoxycarbonylethylene 198 Methoxy-DDT 194 420 2-Methoxyethanol 202 2-Methoxyethyl acetate 202 Methoxyfluorane 196 1-Methoxy-2-hydroxypropane, 268 2-Methoxy-1-methylethanol 268 Methoxymethyl methyl ether 198 p-Methoxyphenoi 196 4-Methoxy m-phenylene-diamme 90 2 2-bis(p-Methoxyphenyl)-l 1 1-trichloroethane 194 1-Methoxy-2-propanol 268 Methyl acetic acid 266 Methyl acetone 36 Methyl acetylene-ailene mixture 198 Methyl acetylene-propadiene mixture (stabilized) 198 I[3-Methyl acrolein 80 2-Methylacrylic acid 194 a-Methylacrylonitrile 198 Methyl aldehyde 148 Methylamine (anhydrous) 200 Methylamme (aqueous), 200 (Methylammo)benzene 218 Methyl amyl alcohol 212 1-Methy!-2-ammobenzene 312 2-Methylamlme 312 3-Methylamlme 312 4-Methylamline, 312 N-Methyl aniline 218 o-Methylaniline 312 Methyl azmpnos 22 2-Methylaziridme 270 Methyl benzene 310 3-Methylbenzenarmne 312 4-Methylbenzenamine 312 Methyl benzol 310 3-Methyl 1-butano' 174 3-Methyl-2 butanol 176 3-Methyl-1-butanol acetate 174 ABD00023144 SYNONYM AND TRADE NAME INDEX (Continued) 3-Methyl-2-butanone 212 3-Methyl butan-2-one 212 1-Methylbutyl acetate 16 1- Methyl-4-tert-butylbenzene 44 Methyl 1-(butylcarbamoyl)-2-benzimidazolecarbamate 24 3-Methylbutyl ester of acetic acid 174 3- Methylbutyl ethanoate 174 Methyl butyl ketone 164 Methyl n-butyl ketone 164 Methyl chlorobromide 62 Methylchloromethyl ether, 66 Methyl cyanide 4 Methyl cyanoacrylate 204 Methyl a-cyanoacrylate 204 2- Methylcyclohexanone 204 2-Methylcyclopentadienyl manganese tricarbonyl 206 4- Methyl-2 6-di-tert-butyl phenol 124 2-Methyl-3 5-dinitrobenzamide 116 Methyl dimtrobenzene 118 4 4 Methylenebis(o-chloro aniline) 206 4 4-Methyienebis(2-chiorobenzenamme) 206 Methylene dichloride 208 Methylene dimethyl ether, 198 Methylene di-p-phenylene ester of isocyamc acid, 208 Methylene oxide 148 Methylene bis(4-phenyl isocyanate), 208 Methyl ester of acetic acid 196 Methyl ester of acrylic acid 198 Methyl ester of 2-cyanoacrylic acid 206 Methyl ester of formic acid, 210 Methyl ester of isocyamc acid, 212 Methyl ester of methacrylic acid 214 Methyl ethanoate 196 N-(l-Methylethyl)-benzenamme 182 Methyl ethyl carbinol 40 2- Methylethyleneimme, 270 Methyl ethylene oxide 270 1- Methylethyl ester of acetic acid 180 Methyl ethyl ketone, 36 Methyl ethyl ketone hydroperoxide 208 Methylethylmethane 34 N-r 1 Methylethyl)-2-propanamine 110 3- Methy!-5-heptanone 210 2- Methyl-5-hexanone 212 421 ABD00023145 422 SYNONYM AND TRADE NAME INDEX (Continued) 5-Methyl-2-hexanone, 212 Methylisoamyl acetate 164 Methyl isobutenyi ketone 194 Methyl tsobutyl ketone, 164 N-Methyl-2-isopropoxypheny!-carbamate, 266 2-Methyllactomtrile 4 Methyl mercaptophos 206 N-Methylmethanamtne 110 Methyl methanoate 210 Methyl N-((methylamino)carbonyl)oxy)ethammidothioate S-Methyl-N-(methylcarbamoyloxy)thioacetimidate 194 Methyl-2-methyl-2-propenoate 214 2- Methylmtroben2ene 232 3- Methylmtrobenzene 232 4- Methylmtrobenzene, 232 o-Methylmtrobenzene 232 m-Methylmtrobenzene 232 p-Methylmtrobenzene 232 N-Methyl-N-nitroso-methanamme 232 Methyl orthosilicate, 214 Methyloxirane 270 2-Methylpentane 162 194 3-Methylpentane, 162 2-Methyl-2,4-pentanediol 164 4-Methyl-2,4-pentanediol 164 2-Methylpentane-2 4-diol 164 4-Methyl-2-pentanol, 212 2-Methyl-2-pentanol-4-one 90 4-Methyl 2-pentanone 164 4-Methyl-3-penten-2-one 194 2-Methyl phenol, 78 3-Methyl phenol 78 4-Methyl phenol 78 Methylphenylamme 216 Methylphenylene diamine 310 1-Methyl-i-phenylethylene 216 Methyl phosphite 320 2-Methylpropane 176 2-Methylpropanemtnle 178 2-Methyl-1-propanol 176 2-Methyl-2-propanol 40 2-Methylpropenemtrile 198 Methyl propenoate 198 2-Methylpropenoic acid 194 ABD00023146 SYNONYM AND TRADE NAME INDEX (Continued) 2-Methylpropiomtrile 178 1 Methylpropyl acetate 38 2-Methylpropyl acetate 176 2-Methylpropyl ester of acetic aud 176 (i-Methylpropyl ethanoate 176 Methyl propyl ketone 244 2- (l-Methylpropyl)phenol 42 3- (1-Methyl-2-pyrrolidyl)pyridme 224 Methylstyrene 332 Methyl sulfate 116 Methyl sulfhydrate 214 Methyl systox 206 N-Methyl-N 2 4 6-tetranitroanilme 304 Methyl tribromide 34 1-Methyl-2 4 6-trimtrobenzene 322 Methyl yellow 110 Mevinphos 252 MIAK 212 MIBC 212 MIBK 164 MIC 212 Mineral carbon 154 Mineral spirits 286 Mineral white 154 MIPK 212 MMH 210 MMT 206 MOCA 206 Molecular bromine 32 Molecular chlorine 58 Molecular iodine, 172 Molybdenum metal 218 Monoammonium salt of sulfamic acid 16 Monobromoethane 132 Monobromoethylene 330 Monobromomethane 200 Monobromotrifluoromethane 318 Monochloroacetyl chloride 60 Monochlorobenzene 62 Monochlorodifiuoromethane 62 Monochloroethane 134 Monochloroethene 330 Monochloroethylene 330 Monochloromethane 200 202 423 ABD00023147 424 SYNONYM AND TRADE NAME INDEX (Continued) Monochloropentafluoroethane 66 Monocron 218 Monoethanolamme 128 Monoethylamine 132 Monoethyleneglycol 136 Monofluoroethylene 330 Monofluorotrichloromethane 146 Monogermane 152 Monohydroxybenzene 248 Monoiodomethane, 210 Monoisopropylamme, 180 Monomethylamme 200 Monomethyl ether hydroqumone 196 Monomethylhydrazme 210 Mononitrogen monoxide 224 Monopentaerythntol, 244 Monophenylhydrazine 250 Monosilane 278 Monosodium salt of sulfurous acid 282 Monoxide, 54 Motor fuel 150 Motor spirits 150 MPK, 244 Muriatic acid 166 Muriatic ether 134 Muscovite 216 MXDA 336 Naled 114 Naphtha 220 1 5-Naphthalene dnsocyanate 220 1,5-Naphthalene ester of isocyamc acid, 220 Naphthalin 220 1- Naphthylamine, 222 2- Naphthylamme 222 1-Naphthyl N-Methyl-carbamate 50 a-Naphthyl N-methyl-carbamate 50 6-Naphthylphenylamine 250 a-Naphthyl thiocarbamide 20 1-Naphthyl thiourea 20 a-Naphthyl thiourea 20 Natural aluminum oxide 126 Natural calcium carbonate 186 192 Natural gasoline, 150 Navadel 120 ABD00023148 NDI 220 NDMA 232 Nemacun 142 NG 228 NIAX A99 112 NIAX Catalyst A1 112 Nibren wax 300 316 Nickel catalyst 224 Nickel metal 224 Nickel tetracarbonyl 222 Nitramine 304 Nitrapynn 68 4-Nitroanilme 226 4-Nitrobenzenamine 226 Nitrobenzol 226 p-Nitrobipheny 226 Nitrocarbol 230 4-Nitrochlorobenzene 226 Nitrochloroform 66 4-Nitrodiphenyl 226 p-Nitrodiphenyl 226 Nitroetan 228 SYNONYM AND TRADE NAME INDEX (Continued) Nitrogen fluoride 228 Nitrogen lime 46 Nitrogen monoxide 224 Nitrogen peroxide, 228 Nitroglycol 138 3-Nitronaphthalene 230 p-Nitrophenylamine 226 Nitropropane 230 iso-Nitropropane, 230 N-Nitroso-N N-dimethylamme 232 2-Nitrotoluene, 232 3-Nitrotoluene 232 4-Nitrotoluene 232 ortho-Nitrotoluene 232 meta-Nitrotoluene, 232 para-Nitrotoluene 232 Nitrotnchloromethane 66 n-Nonane 234 Nonyl hydride 234 n-Nonyl mercaptan 234 Nonylthiol 234 1-NP 230 425 ABD00023149 426 SYNONYM AND TRADE NAME INDEX (Continued) 2-NP 230 N-serve, 68 Nuisance dusts, 240 Nux vomica, 286 OCBM 62 Octacarbonyldicobalt 74 Octachlorocamphene 58 1 2 3 4 5 6,7 8-Octachloronaphthalene 234 1 2 4,5 6 7,8,8-Octachloro-3a 4 7 7a-tetrahydro-4,7-metnanomdane 56 Octadecyl mercaptan 236 Octalene 8 n-Octane 236 normal-Octane 236 n-Octyl mercaptan 236 Octyl phthalate 118 Octylthiol 236 1-Octylthiol 236 Oil of mirbane 226 Oil of vitriol, 290 Onion oil 10 Orthophosphonc acid 254 Osmic acid anhydride 238 Osmium oxide 238 Oxalic acid (aqueous) 238 Oxalic acid dihydrate, 238 Oxalomtrile 82 2-Oxetanone 264 Oxirane 138 2-Oxohexamethyleneimine 50 Oxooctyl alcohol, 178 Oxybis(chloromethane) 64 2 2'-OxybislN N-dimethyl ethylamine) 112 Oxygen fluoride 238 Painters naphtha 332 PAN 256 Paraffin fume, 240 Paraffin oil mist 236 Paraffin scale fume 240 Paraquat chloride 240 Paraquat dichlonde 240 Parathion-ethyl 240 Parathion methyl 214 PBNA 250 ABD00023150 SYNONYM AND TRADE NAME INDEX (Continued) PCB 64 PCM 246 PCNB 226 PCP 242 m-PDN 258 PE 244 Pebble lime 48 Penta 242 Pentaboron nonahydride 242 Pentacarbonyl iron 174 1 2,3,4,5-Pentachloronaphthalene, 242 2 3 4 5 6-Pentachlorophenol 242 Pentachlorophosphorus 256 Pentalin 242 Pentamethylene 86 Pentanal 326 Pentane 244 normal-Pentane 244 1 5-Pentanedial 152 1-Pentanol acetate 16 2-Pentanol acetate 16 3-Pentanone 106 Penthrane, 196 Pentyl ester of acetic acid 16 Pentyl mercaptan 244 Perchlorobutadiene 158 Perchlorocyclopentadiene 158 Perchloroethane 158 Perchloroethylene, 300 Perchloronaphthalene 234 Perfluoroacetone, 160 Perk 300 Peroxide 168 Petrol 150 Petroleum asphalt 22 Petroleum bitumen 22 Petroleum ether 332 Petroleum naphtha, 246 Petroleum solvent, 286 Petroleum spirit 332 PF 252 PGDN 268 PGE 250 Phenacyl chloride 60 427 ABD00023151 428 Phenamiphos 142 Phenanthrene 74 Phenol trinitrate, 258 Phenoxy benzene 248 Phenyl alcohol 248 Phenylamme 18 2-Phenylammonaphthalene 250 Phenylamline 120 4-Phenylanilme 14 N-Phenylamlme 120 N-Phenylbenzenamme 120 Phenyl benzene 120 2- Phenylbiphenyl 296 3- Phenylbiphenyl 296 4- Phenylbiphenyl 298 Phenyl chloride 62 Phenyl chloromethyl ketone 60 1 4-Phenylene diamine 248 m-Phenylenebis(methylarmne) 336 Phenyl 2,3-epoxypropyl ether 250 Phenylethane 132 Phenylethylene 286 SYNONYM AND TRADE NAME INDEX (Continued) Phenyl hydride 26 Phenyl nydroxide 248 N-Phenylisopropylamme, 182 Phenyl mercaptan 26 Phenyl methane 310 N-Phenylmethylamme 218 Phenyl-p-naphthylamme 250 4-Phenylmtrobenzene 226 p-Phenylmtrobenzene 226 Phenyl oxide 248 Phenyl phosphate 322 2-Phenyl propane 80 2-Phenyl propylene 216 Phlogopite 216 Phosphamlme 252 Phosphorated hydrogen 254 Phosphoric acid (aqueous) 254 Phosphoric chloride 256 Phosphorus chloride 254 256 Phosphorus hydride 254 Phosphorus oxytrichloride, 254 Phosphorus perchlonde 256 ABD00023152 Phosphorus persulfide 256 Phosphorus sulfide, 256 Phosphorus tnhydride 254 Phosphoryl chloride, 254 Phthalic acid anhydride 256 Pimelic ketone 84 Piperazine hydrochloride 260 Pival 258 Pivaly! 258 2-Pivalyl-1 3-mandione 258 Platinum black 260 Platinum metal 260 Platinum sponge 260 Plumbago 154 Plumbum 184 PMM 246 PNA 226 PNB 226 PNCB 22b PNOR 240 Polychlorinated biphenyl 64 Poiychlorocamphene 58 SYNONYM AND TRADE NAME INDEX (Continued) Porcelain clay, 182 Portland cement silicate, 262 Potassium hydrate 262 Potassium salt of hydrocyanic acid, 262 Precipitated amorphous silica 276 Primary amyl acetate 16 Primary isoamyl alcohol 174 Propadiene-methyl acetylene 198 n Propane 262 Propanedial 190 1 3-Propanedial 190 Propanemtrile, 266 1,3-Propane sultone, 264 Propane-1-thiol 264 1 2 3-Propanetriol 152 1 2 3-Propanetriol trinitrate 228 Propanoic acid 266 1 Propanol 268 2-Propanol 180 n-Propanol 268 2 Propanone 2 Propellant 12 96 429 ABD00023153 430 SYNONYM AND TRADE NAME INDEX (Continued) Propenal 6 2-Propenal 6 Propenamide 6 2-Propenamide 6 Propenenitnle 8 2-Propenenitnle 8 Propene oxide 270 2-Propenoic acid, 8 Propenol 10 1- Propen-3-ol 10 2- Propenol 10 f(2-Propenyloxy)methyi] oxirane 2- Propenyl propyl disulfide 10 Propine 196 3- Propiolacetone 264 Propione 106 Propionic nitrile 266 Propiononitnle 266 Propy/acetate 266 Propyl alcohol 268 2 Propyl acetate 180 sec Propyl alcohol 180 10 Propyl allyl disulfide 10 2-Propylamme 180 sec-Propylamine 180 n-Propyl carbmol 38 Propyl cyanide 44 n-Propyl cyanide 44 Propylene aldehyde 80 Propylene glycol-1 2-dmitrate 268 1 2-Propylene glycol dinitrate 268 Propylene glycol methyl ether 268 Propylene glycol monoacrylate 170 Propyleneimme 270 Propylene imme (inhibited i 270 1 2-Propylene oxide 270 Propylemmine 270 n Propyl ester of acetic acid 266 Propyl ester of nitric acid 270 Propyl hydride 262 Propyl Ketone 122 Propyl mercaptan 264 n-Propyl mercaptan 264 Propyne 196 ABD00023154 1-Propyne 196 Propyne-allene mixture 198 Propyne-propadtene mixture 1- Propyn-3-ol 264 2 Propyn-1-ol 264 2- Propynyl alcohol 264 Proteolytic enzymes 286 Prussic acid 168 Pseudocumene 320 Pyrene 74 Pyrethrin I 270 Pyrethrinll 270 Pyrethrum 1 270 Pyrethrumll 270 a-Pyridylamme 14 Pyrocatecho! 56 Pyrocellulose 56 Pyroligneous spirit 200 Pyrophosphate 304 Quartz 278 Quick lime 48 Quicksilver 192 198 SYNONYM AND TRADE NAME INDEX (Continued) Quinol, 170 p-Quinone 272 Range oil 184 Raw cotton dust 76 RDX 86 Red fuming nitric acid (RFNA) 224 Red iron oxide, 276 Red oxide 276 Reduced MDI, 206 Refined solvent naphtha 332 Refrigerant 11 146 Refrigerant 12, 96 Refrigerant 21 100 Refrigerant 22, 62 Refrigerant 112 298 Refrigerant 112a 298 Refrigerant 113 316 Refrigerant 114 102 Refrigerant 13B1 318 Rhodium metal 272 Rice starch 284 Riebeckite, 22 ABD00023155 432 SYNONYM AND TRADE NAME INDEX (Continued) Road asphalt 22 Rock candy 288 Rockwool 216 Roofing asphalt 22 Roscoehte 216 Rosin flux pyrolysis products 274 Rosin core soldering flux pyrolysis products Ro-Sulfiram 122 Rubber solvent 246 Rubbing alcohol 180 Ruelene, 80 Rutile 310 Saccarose, 288 Sal ammoniac fume 16 Saturated MDI, 206 Secondary isoamyl alcohol 176 Seekay wax 300 316 Selenium alloy 276 Selenium dihydnde 168 Selenium fluoride 278 Selenium hydride 168 Sesone 78 274 Sevin 50 Sewer gas 170 SFA 282 Silane 278 Silica gel 276 Silicane 278 Silicon dioxide (amorphous) 276 Silicon monocarbide 278 Silver graphite, 154 Silver metal 280 Silver nitrate 280 Slag wool 216 Slaked lime 46 Soapstone silicate 280 Soda lye 284 Sodium acid bisulfite 282 Sodium bisulphite 282 Sodium borate (anhydrous) 30 Sodium borate decahydrate 30 Sodium borate pentahydrate 30 Sodium hexafluoroalummate 280 Sodium hydrate 284 ABD00023156 SYNONYM AND TRADE NAME INDEX (Continued) Sodium hydrogen sulfite 282 Sodium metabisulphite, 284 Sodium monofluoride 282 Sodium monofluoroacetate 282 Sodium pyrophosphate 304 Sodium pyrosulfite 284 Sodium salt of hydrazoic acid 280 Sodium salt of hydrocyanic acid 282 Sodium tetraborate, 30 Sodium tetraborate decahydrate 30 Sodium tetraborate pentahydrate 30 Soft wood dust 334 Solvent ether 140 Sorghum gum 284 Spectracide 92 Spirits of turpentine 324 Spotting naphtha 286 Stannic oxide 308 Stannous oxide 308 a-Starch 284 Starch gum 284 Stearyl mercaptan 236 Steatite 280 Steatite talc, 292 Steam distilled turpentine, 324 Stibium, 18 Stove black 154 Styrene monomer 286 Styrol 286 Subtihsm BPN 286 Subtilism Carlsburg, 286 Succinic dimtrile 288 Sugar 288 Sulfamate 16 Sulfate wood turpentine 324 Sulfmyl chloride 306 Sulfotepp 294 Sulfur chloride 290 Sulfur chloride oxide 306 Sulfur decafluoride 290 Sulfur difluoride dioxide 290 Sulfuretted hydrogen 170 Sulfur fluoride 288 Sulfuric acid (aqueous) 290 433 ABD00023157 434 Sulfurous acid anhydride 288 Sulfurous dichlonde, 306 Sulfurous oxide 288 Sulfurous oxychloride 306 Sulfur oxide 288 Sulfur phosphide 256 Sulfur supchlonde 290 Symmetrical tetrabromoethane 6 Symmetrical tetrachloroethane 300 Symmetrical trimethylbenzene 320 Synthetic camphor 48 Synthetic vitreous fibers 216 Systox 90 Table sugar 288 Tantalum-181 294 Tantalum metal 294 Tapioca starch, 284 Tai camphor 220 TBE 6 TBP 314 TCA 314 TCDBD 298 SYNONYM AND TRADE NAME INDEX (Continued) TCDD 298 2 3.7 8-TCOD, 298 TCE, 316 TCHH 86 TCP 322 TDA 310 TDI 312 2 4-TDI 312 TEA 318 Tear gas 60 TEL 302 Tellurium fluoride 294 Tellurobismuthite 28 Telone 100 Temefos 296 Terracur P 142 1 2-Terphenyl, 296 1 3-Terphenyl 296 1 4-Terphenyl, 298 meta-Terphenyl, 296 ortho-Terphenyl 296 para-Terphenyl 298 ABD00023158 SYNONYM AND TRADE NAME INDEX (Continued) Tetan 304 TETD 122 Tetrabromoacetylene 6 Tetrabromoethane 6 112 2 Tetrabromoethane 6 Tetrabromomethane 54 Tetracarbonylhydndocobalt 74 Tetracarbonylhydrocobalt 74 Tetracarbonyl nickel 222 Tetrachlorethylene 300 N-((1 1 2 2-Tetrachloroethyl)thio)-4-cyclohexene-1 2-dicarboximide, 50 Tetrachloromethane 54 2 2 2 6-Tetrachloro-2-picolme 68 Tetraethoxy silane 142 Tetraethyl dithionopyrophosphate 294 Tetraethyl dithiopyrophosphate 294 OOO 0-Tetraethyl S S-methylene di(phosphorodithioate) 130 Tetraethyl orthosiiicate 142 Tetraethylplumbane, 302 Tetraethyl pyrophosphate 296 Tetraethyl silicate 142 Tetraethylthiuram disulfide 122 Tetrafluorosulfurane 290 Tetrahydrobenzene, 84 1 2 12 12a-Tetrahydro-6 9-dimethoxy-2-(1-methyi-ethenyl)- [IJbenzopyrano [3,4-b]furo[2,3-h][1 ] benzopyran-6(6aH)-one, 274 3a 4 7 7a-Tetrahydro-4,7-methanoindene 102 Tetrahydro-1 4-oxazme, 220 Tetrahydro-p-oxazme 220 Tetrahydroxymethylolmethane, 244 Tetramethoxysilane 214 Tetramethylene cyanide, 8 Tetramethylene oxide 302 Tetramethyl ester of silicic acid 214 Tetramethylolmethane 244 Tetramethylplumbane 302 Tetramethyl silicate 214 Tetramethyl succinodinitnle, 302 OOOO -Tetramethyl O 0 -thiodi-p-phenylene phosphorothioate, 296 Tetramethylthiuram disulfide 306 Tetrasodium diphosphate 304 Tetrasodium pyrophosphate (anhydrous), 304 Tetron 296 435 ABD00023159 436 SYNONYM AND TRADE NAME INDEX (Continued) 2,4 6-Tetryl 304 Thermal black 52 THF 302 Thimet 252 Thiodan 126 Thiodemeton 124 Thiodiphenylamine, 248 4,4'-Thiobis(3-methyl-6-tert-butyiphenol), 306 1,1'-Thiobis(2-methyl-4-hydroxy-5-tert-butylbenzene), 306 Thionyl dichlonde 306 Thiophenol 26 Thiosulfurous dichlonde 290 Thiotepp 294 Timet 252 Tin flake 308 Tm metal 308 Tin powder 308 Tin protoxide 308 Titanium oxide 310 Titanium peroxide, 310 TMA 318 TMAN, 318 TML, 302 TMSN 302 TNM 304 TNT 322 TOCP 322 3,3'-Tolidine 310 Toluenediamme isomers 310 2,4-Toluene dnsocyanate 312 3- Toluidme 312 4- Toluidine 312 ortho-Toluidine 312 Toluol 310 Tolyethylene 332 Tolylamine 312 m-Tolylamme 312 o-Tolyl chloride 68 Tolylcnediamine 310 Tordon 258 Toxaphene 58 Toxilic anhydride, 188 TPP 322 Tremolite 22 ABD00023160 SYNONYM AND TRADE NAME INDEX (Continued) Tremolite asbestos 22 Triatomic oxygen 238 Tribromoborane 32 Tnbromomethane 34 Tributyl ester of phosphoric acid 314 Tri-n-butyl phosphate 314 Tricaicium arsenate 46 Tncaicium ortho-arsenate 46 unsym-TricMoroDenzene 314 1 2 4 TncMorobenzol 314 1 1 1 Trichloro 2 2-biS(p-chlorophenyhethane 88 1 1 1-Tr'chioroethane 202 1 1 l-Tnchloroethane (stabilized) 202 |5 Tnchloroethane 314 Tnchloroethanoic acid 314 Trichloroethene 316 Trichlorofluoromethane 146 Trichlorohydrm 316 Trichloromethane 64 Tnchloromethane sulfenyl chloride 246 1 1 1 -Trich loro-2 2-bis-(p-methoxyphenyl)ethane 194 N-Tnchloromethylmercapto-4-cyclohexene-1 2-dicarboximide 50 Trichloromethyl sulfur chloride 246 Trichloromonofluoromethane, 146 Trichloronitromethane 66 2,4,5-Trichiorophenoxyacetic acid, 292 Tn-o-cresyl ester of phosphoric acid, 322 Tn-o-cresyl phosphate 322 Tricyclohexylhydroxystannane 86 Tncyclohexylhydroxytin 86 Tricyclohexylstanmum hydroxide 86 Tncyclohexyltin hydroxide 86 Tndymite 278 Tnfluoramine 228 Trifluorammonia 228 Trifluoroborane 32 1 1 1-Trifluoro-2-bromo-2-chloroethane 156 2 2 2 Tnfluoro-1-bromo-1-chloroethane 156 2 2 2-Trifluoroethoxyethene 146 2 2 2-Tnfluoroethyl vinyl ether 146 Trifluoromonobromomethane 318 Tnhydroxypropane 152 Tniodomethane 172 Tnlene 316 437 ABD00023161 438 SYNONYM AND TRADE NAME INDEX (Continued) Trimanganese tetraoxide, 192 Trimanganese tetroxide, 192 Trimellic acid anhydride, 318 Trimethoxyphosphme 320 sym-Tnmethylbenzene, 320 Trimethyl carbinol 40 3 5 5*Trimethyl'2-cyclohexenone 178 3,5 5-Trimethyl-2-cyclo-hexen-1-one, 178 Trimethylenetrinttramine, 86 Trimethyl ester of phosphorous acid 320 Tnmtroglycertne, 228 2 4 6-Trimtrophenol 258 2 4 6-Trmitrophenyl-N-methylnitramine 304 Trinitrotoluene 322 sym-Trimtrotoluene 322 Trinitrotoluol, 322 1 3 5-Trimtro-1,3,5-tnazacyclohexane 86 Trioxychlorofluoride, 246 m-Tripheny! 296 o-Tnphenyl, 296 p-Triphenyl 298 Triphenyl ester of phosphoric acid 322 Tripoli 278 Tris{dimethylamino)phosphine oxide 162 TSPP 304 TTE 316 Tungsten metal 324 Turps 324 UDMH 114 Undecyl mercaptan 326 Unslaked lime 48 Unsymmetrical dimethylhydrazme 114 Uranium I 326 Uranium metal 326 VAC 328 Valeral 326 Valeraldehyde 326 Valeric aldehyde 326 Valerone 108 Vanadic anhydride dust 328 Vanadic anhydride fume 328 Vanadium oxide dust 328 Vanadium oxide fume 328 Vanadium pentaoxide dust 328 ABD00023162 SYNONYM AND TRADE NAME INDEX (Continued) Vanadium pentaoxide fume 328 Varnish makers & painters naptha 332 VC 330 VCN 8 VDC 332 VDF 332 .getable mis* 328 Vikane 292 Vmyt acetate monomer 328 Vinyl benzene 286 Vinyl carbmol 10 Vinyl chloride monomer (VCM) 330 Vinyl cyanide 8 4-Vinylcyclohexene diepoxide 330 4-Vinyl-1-cyclohexene dioxide, 330 Vinyl ethanoate 328 Vmylethylene 34 Vinyl fluoride monomer 330 Vinylidene chloride monomer 332 Vmylidene dichloride 332 Vinylidene difluoride 332 Vmylstyrene 124 Vinyl trichloride 314 WARF 334 Western red cedar dust 334 White fuming nitric acid (WFNA) 224 White mineral oil mist 236 White phosphoric acid 254 White phosphorus 254 White tar 220 White tin oxide 308 Wolfram 324 Woilastomte 48 Wood alcohol 200 Wood naphtha 200 Wood spirit 200 Wood turpentine, 324 meta-Xylene 336 ortho-Xyiene 334 para-Xylene, 336 m-Xylol 336 o-Xylol 334 p-Xylol 336 m-Xylylenediamine 336 439 ABD00023163 440 Yttrium metal 338 Zimmwaldite 216 Zinc chromate 70 Zinc dichloride fume 338 Zinc distearate 338 Zinc peroxide 338 Zinc salt of stearic acid 338 Zoalene 116 Zirconium 340 Zirconium metal 340 SYNONYM AND TRADE NAME INDEX (Continued) i*US GOVERNMENT PRINTING OFFICE 1997J551-571 ''' "" ' \ ^ \XV _ Delivering,on the Nation's promise: ^ Safoty.ang'heaitti at werkferaSlpeppi --!''"S'v'v'^'^:''.S'S#S 'through0re8eanch and prevention.- :