Document KJJ3jjnwjVQ8OkLjeM7YbGZV0

ABDOO104279 MATERIAL SAFETY DATA SHEET (in comDliance with 29 CFR 1910.1200 arid WHMIS) IDENTITY: Stan-ToneR VC or VCP-5082 Dark Gray **************************************************************************************** SECTION I - Preparation/Product Information **************************************************************************************** MANUFACTURED FOR AND SUPPLIED BY: EMERGENCY TELEPHONE NO.: (216) 798-9300 Harwick Chemical Corporation 6i South Seiberling Street P. 0. Box 9360 Akron, OH 44305-0360 DATE PREPARED: June 11, 1992 PREPARER: Health, Safety & Environment PRODUCT USE: Colorant **************************************************************************************** SECTION II- Ingredients/Identity Information **************************************************************************************** COMPONENTS CHEMICAL IDENTITY/CAS#/UN# ^Rlyvinyl Chloride CAS #9002-86-2 EXPOSURE LIMITS PEL TLV OTHER Not Established Diisodecyl Phthalate CAS #68515-49-1 Not Established Titanium Dioxide *10mg/m3 CAS #13463-67-7 **5mg/m3 *PEL & TLV for total nuisance dust. **PEL for respirable dust. *10mg/m3 Carbon Black CAS #1333-86-4 3.5mg/m3 3.5mg/m3 TOXICITY LD50/LC50 AMOUNT % 20-30 LD50 rat/oral 10-20 >64,000 mg/kg LD50 rat/oral 50-60 >24,000 mg/kg 1-5 **************************************************************************************** SECTION III- Physical/Chemical Characteristics **************************************************************************************** BOILING POINT: Not Applicable SPECIFIC GRAVITY (H20=1): 2.01 (calc.) FREEZING POINT: Not Applicable pH: Not Applicable VAPOR PRESSURE (mm Hg): Not Applicable ODOR THRESHOLD (ppm): Not Determined VAPOR DENSITY (AIR=1): Not Applicable COEF. WATER/OIL DIST.: Not Determined PLUBILITY IN WATER: Negligible EVAPORATION RATE: Not Applicable PEARANCE (PHYSICAL STATE) AND ODOR: Solid; Grey Odor; None ABDOO104280 *********************************************************************3 x**************** SECTION IV- Fire and Explosion Hazard Data *************************************************************************************** -'LASH POINT (Method): Not Determined EXTINGUISHING MEDIA: Chemical foam, dry chemical, CO2 SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained breathing apparatus and protective Nothing. JNUSUAL FIRE AND EXPLOSION HAZARDS: :oxic hydrogen chloride gas. Decomposition by burning in open flame may yield -IMIS RATING: 1 -"LAMMABLE LIMITS LEL: Not Applicable UEL: Not Applicable ^UTOIGNITION TEMPERATURE: Not Determined jENS. TO MECHANICAL IMPACT: Not Applicable SENS. TO STATIC DISCHARGE: Not Applicable HAZARDOUS COMBUSTION PRODUCTS: COx, HCl, small amounts of sulfur containing gases. **************************************************************************************** ***************************S**E**C**T**I*O**N*****V**-**R**e*a**c*ti*v*i*ty***D*a*ta************************** * STABILITY STABLE: X UNSTABLE: CONDITIONS TO AVOID (Cond. of Reactivity): Excessive heat for long periods of time. INCOMPATIBILITY (Materials to Avoid): Strong oxidizing agents HAZARDOUS DECOMPOSITION OR BYPRODUCTS: gases. COx, HCl, small amounts of sulfur containing HAZARDOUS POLYMERIZATION MAY OCCUR: WILL NOT OCCUR: X CONDITIONS TO AVOID: None known HMIS RATING: 0 r ABDOO104281 *t***********************************************t*t****************t****t*t***t*****t ***t*i(.**if.***t*t***t*****S**E**C**T**IO***N*****V**I*t-**H**e*a*lt*h**H**a*z*a*rd**Dt*a*ta*t**********.**********t** PRIMARY ROUTES OF EXPOSURE INHALATION: X SKIN ABSORPTION: SKIN CONTACT: X INGESTION: EYE CONTACT: X HEALTH HAZARDS ACUTE: Contact with skin and eyes may cause irritation. Fumes from heated material may cause nausea or respiratory tract irritation. CHRONIC: None Known NOTE: Product form should minimize exposure making health effects less likely. CARCINOGENICITY NTP: No IARC: No OSHA: No SIGNS AND SYMPTOMS OF EXPOSURE: See health hazards above MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: None known CD TEST VALUES FOR: IRRITANCY: Not Determined SENSITIZATION: Not Determined MUTAGENICITY: Not Determined REPRODUCTIVE TOXICITY: Not Determined TERATOGENICITY: Not Determined SYNERGISTIC PRODUCTS: Not Determined HMIS RATING: 1 ttt**************t****t************t**************************************************** SECTION VII- First Aid Measures tt*t***t*X****.*************X**%*****.***********-********************-********************* EMERGENCY AND FIRST AID PROCEDURES INHALATION: Move to fresh air. INGESTION: Consult a physician. SKIN CONTACT: Wash with soap and water. EYE CONTACT: physician. Flush with water for 15 minutes, If irritation persists consult a ABDOO104282 *v **************************************************************************************** SECTION VIII- Precautions for Safe Handling and Use ******* ********************************************************************************* STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Prevent additional discharge )f material. Recover spilled material and place in a suitable container for recycle or disposal. MSTE DISPOSAL METHOD: tefer to Section X. In accordance with all Federal, State and Local regulations, PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Store in a cool, dry, ventilated area 3way from heat. Avoid contact with eyes, skin and clothing. **************************************************************************************** *************************S**E**C**T**I*O**N*****I**X**-**C**o*n*t*ro**l *M**e*a*s*u*re*s************************** RESPIRATORY PROTECTION: (Specify Type) A NIOSH/MSHA approved respirator above PEL or TLV or as necessary. VENTILATION LOCAL EXHAUST: Recommended to minimize exposure. MECHANICAL (General): Recommended to minimize exposure. PROTECTIVE GLOVES: Impervious EYE PROTECTION: Safety glasses 3THER PROTECTIVE CLOTHING OR EQUIPMENT: Eyewash station WORK/HYGENIC PRACTICES: Wash thoroughly after handling. ABDOO104283 ^r************************************************************************************** SECTION X- Additional Information **************************************************************************************** SPECIAL SHIPPING INFORMATION: Not Available TSCA INVENTORY STATUS: Chemical component(s) are listed on the TSCA Inventory. SARA TITLE III: This product contains the following toxic chemical(s) subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right-to-Know Act of 1986 and of 40 CFR 372: Insoluble Barium Salt (Barium Compound) Contained in Alkaline Earth Salt Mixture CAS ^Proprietary Mixture .1-1% RCRA STATUS: The following chemical component(s) are listed under (40 CFR 261): (Ref. 261.24) D005 PVC: Vinyl Chloride Polymers may contain Vinyl Chloride Monomer below regulated limits which has been identified as a carcinogen. Under certain conditions of use, they may be covered by OSHA Standard 29 CFR 1910.1017, Vinyl Chloride. THE INFORMATION AND RECOMMENDATIONS CONTAINED HEREIN ARE BASED UPON DATA THAT IS ACCURATE AND RELIABLE TO THE BEST OF HARWICK'S KNOWLEDGE AND BELIEF. WITH RESPECT TO THE INFORMATION AND RECOMMENDATIONS,. HARWICK MAKES NO REPRESENTATIONS OR WARRANTIES OF ANY KIND OR NATURE, EXPRESS OR IMPLIED.