Document KJ8Do598NBNBgJR7ejeJq6MEr
PLAINTIFF'S EXHIBIT
NO. 45,215-A
LLOYD BRYANT, ET AL VS. U.S. GYPSUM COMPANY, ET AL
IN THE COUNTY COURT
AT LAW NUMBER TWO
SMITH COUNTY, TEXAS
1I&G-14
DEFENDANT THE HILL AND GRIFFITH COMPANY'S SECOND SUPPLEMENTAL RESPONSES TO PLAINTIFFS' REQUEST FOR PRODUCTION
TO: Plaintiffs, by and through their attorneys of record, Mr. Richard Nemeroff, BARON & BUDD, 3102 Oak Lawn Avenue, Suite 1100, Dallas, Texas 75219 and Mr. Jimmy M. Negem, NEGEM, BICKHAM & CLARK, 440 South Vine, Tyler, Texas 75702.
COMES NOW, THE HILL AND GRIFFITH COMPANY, one of the Defendants in the
above entitled and numbered cause, and pursuant to Rule 196 of the Texas Rules of Civil
Procedure and the Court's ruling on August 30, 2002, makes and files this its First Supplemental
Responses to Plaintiffs' Request for Production of Documents served upon its attorney of record,
which answers are attached hereto.
Respectfully submitted, ADAMS & COFFEY, P.C.
KENT M. ADAMS State Bar No. 00869200 PAMELA J. WILLIAMS State Bar No. 00791936 222 W. Las Colinas Boulevard Suite 1730N Irving, Texas 75039 PHONE: (972) 506-6600 FAX: (972)506-6620
ATTORNEYS FOR DEFENDANT, THE HILL AND GRIFFITH COMPANY
HILL AND GRIFFITH'S SECOND SUPPLEMENTAL RESPONSES TO PLAINTIFFS' REQUEST FOR PRODUCTION - Page 1
CERTIFICATE OF SERVICE This will certify that a true and correct copy of the above and foregoing has been forwarded to all known counsel of record in accordance with the Texas Rules of Civil Procedure on this the 11th day of September, 2002.
PAMELA J. WILLIAMS
HILL AND GRIFFITH'S SECOND SUPPLEMENTAL RESPONSES TO PLAINTIFFS' REQUEST FOR PRODUCTION - Page 2
DEFENDANT'S SECOND SUPPLEMENTAL RESPONSES TO PLAINTIFFS' REQUEST FOR PRODUCTION OF DOCUMENTS
REQUEST NO. 1; Documents reflecting the corporate structure of each of the Defendant's companies for the past seventy-five years.
RESPONSE;
See attached.
REQUEST NO. 2: Documents reflecting the names of persons having management authority in each of the Defendant's companies and the manner in which such authority is assigned functionally and/or geographically for the past seventy-five years.
RESPONSE:
See attached.
REQUEST NO. 4: All internal Memoranda of any of the Defendant's companies relating to the marketing of the product for the past seventy-five years.
RESPONSE:
None.
REQUEST NO. 5: All advertising, foreign and domestic, done by any of the Defendant's companies, relating to the product for past seventy-five years.
RESPONSE:
See attached.
REQUEST NO. 9: All catalogues, pamphlets, brochures, or any printed or published descriptions of the Defendant's product(s) made the basis of this lawsuit, prices of such products or services, or other information relating thereto.
RESPONSE:
See attached.
REQUEST NO. 12: Any and all communications, correspondence, inquiries, meetings, conversations, agreements, understandings, relations or contracts of any kind between or among Defendant and Tyler Pipe Industries, Inc., Western Foundry, and Sterling Faucet for the past seventy-five years.
RESPONSE:
None.
REQUEST NO. 16: A true and correct copy of all warnings or instructions attached to the packaging of the products processed or distributed by Defendant which contained silica. For each warning or instruction, attach the dates in which those warnings or instructions were used and the specific product upon which they were used.
RESPONSE:
See attached.
HILL AND GRIFFITH'S SECOND SUPPLEMENTAL RESPONSES TO PLAINTIFFS' REQUEST FOR PRODUCTION - Page 3
tj *o> c> oo <t7>0 oo IO `1 f- T1
ajw r*
mo M *
THE HILL AND GRIFFITH COMPANY CORPORATE ORGANIZATIONAL CHART
REPRESENTATIVES
1- 12.
om
co >
m
co
o X. iSL J a"
f
w
igi
||p
$sSli'.
Ute
'-i&fip.-* -
00
-O ;" ,C3 ia to
;!%*'. .S 1 1
-.'`;:M^e 0 0
Vfcvifi O 0 :4- '..-> **
11
O0 -.a* * .' .* '*.y* O 0
* - * JS 0
. ' 0 -c
'ttt'.; ,, / ' 'v ?
., '-' ? '
-0 -0
>> ,<XC'*> ' ,. r* #**
rr r*
:jv5 .: m *
H -4
flrf*#**'*' 4* >
I5M# *0 T3
:^i|-v>s^3e > >
'.CJr/^-C rr* rr**
j*i m *4 -t HH 'O' `.'<2 p-i r> 4 H
a* ` >
rr ,r* CS
,
0 0 .e H H ** 1
' .C 0 .u -JSI
M
i O -si
a
tt
H* H
.*.
M m ,* ! . > M. '* ' r> ,s:" ' .0 >
2, r* -i* ..
0 Cl tf . t
2 4>*
0 2E', *
4 a . *< > r*
ee *t c
t/}
-- c r* -m > </ r ti
1/1 0 Si
0 C >- Ht c0 Pi pa s -4
i .Gt fM* 4 {> i !>*
,<*
r
'-4 X
.sr O ;S*
ff PJi ? ,iiv
.0 c ISfe'
:o - cc --3 > tA r
wyy -V^' . ' y-J. -,W`v .
SR -si >- -`Sr--sIN Qt * * .O VC O O fo.,.4c O O
r C' '
cp : '>* .
-> 4 1# * > ^ ' ,c -4. C
0 0
'* '
u :u 41
fs a
.43 * cb c0
< :*sfi -W . CD lOS'.'i'.'O CD
**
,0`:' '.C O O aa^.-.c O O
:>*' v v0 ; ' v ' .
b U5
r- w :c
`e^- ,;C
O 0
4 C0 c0
-'-V
-/S is fS>
->* '> -*a . a -a)- ft) rt " * 0 c 00 .0 c 0 0
0 ^ J** HI
O 1! UJ ^ *0 hi \J * . 4 W* .t> e c0
u Ul
ft .Pa a OJ
43 C cO
Jj) i* W
O'
* * ,,
T5--nc ~as--------- 4} la i*. m -H*
INS IS >
.# .0 c a 0 :o . 0 0
-a >*
d1 '.C >
0
a
cO cO
3~5
;vO
a g c tg
a ^ & & a ^ at
~z*J t: ^ _v ,'>
C*.
1t
j
-
c os
x*
o
c cn
a
TC (71 33
Z y>
O
OJ5 jl
ap 3
0 1 a
* o oo
q
o O tv Ji
Ltf o5 o0i o0t
* tf
33 a
'O OI SI3
T) a c
U> Jj O r>
#
O' h
i?* ^ i'
O o
& &>o > rrt
3 55
M > 2 W
n>
.5Ho4mCrJB*A;
mo* rtCo a^
3CO3 O1 xCo<IJ
5O3oc-33i mtooo
55 Q O c o
*n vs
r>* o-*f x*-
m o r* to r*
wm
82 O T> tfo
-t a
-Q4 4O* >r-.cxCxoO
^ *Od JXov*i'
M w-*4o XO
< o o73 <n
O O **! JO
C 0 .M
{cjo
aat
'*nn
Q*
3C 3: w
m 33
m
30
ox
o
to O
tss a
x
L3 **
* *
.r4*3 VeJt\V
. <
.
oo
> ao
> 2
<
r*
3v
to -{
.
<
*
o ao
Oo
II
ooa a
> 53
4*-
>
4
Ui - Oi
* 4
8 a*-
H<
vA in *o)
o -t-
us 8 &
n x
# oo oo
O ' o o
fr &* *& o x* oooa
?<rj <
>30
m >
m*<
73
!
>*
Olit' fiin>
/-S4J
W J
*4 -s
fs f^J
rjv
CP
AO o
Q Q a o
Q I
r- o
>> tn -4 -j m
m< *tf
>8 33 *
<5
~o 2> r
03 -4
r. as< s'
5* - -
^33
DO \
uj
CO
o UI
o oo o 3 U1 o o w 14 O o ro \) O 1 to to l l ro ro l I H o ooo o o 3 -> o o o o o 3 o o o o H H* -J
o to to O O
o O' O' O 3
<3 o
*fr #
it -r* ^ *o*
it -It-
# -P* 3 it O *
-If it
It Jf-
Tl
m
o mH P3 30
mm 22
CX r* -- to :?
H 35
o *0
> r
->
r-
m r
H 30
>> r- 2
to
M --1 a3 2z
> Z to
H co P5
3>
2 05
O> > > 35 O <r> o 3 O /OTJ t) C7
in m 30.0 r> H 30 > > --<
o
O1 l C CO X
w o'
on -
cr
M o
z v < 2 *o m Tl 2
4N -i
H
H -P* ^
-4
M W --4
"I
O Q O O O O N vi o
H 3 -1 --1 >*4 ** -1
> 3>
> >2 2 >
n r* o .p* r- n o') r> r-
30 >
c3
X ?3t
to
O
M
-
4
,s *0
OJ
*>4
" o>
4
*
4 ft
4
44
4
o o o o o o o o 3 -J o o 0.0 o o o o Js
OH0* Ho* ol
ui ui
1sO sO O'
Hfr WCOD Ji
m30
-u v <r> m n
O3J 'H i_?J
CO *o o
O-i
>0?
o
`
> <r> n
r* o)
t .
O 4
-4 o
-t* o
D Z
Oo "-<>
o m
<
m fe- -I
H X m
H
35 r* m 3 TJ CO 3o
35 O 3 H 3 ~ Hi /> 2 *n h o ~n 3 4 H4
noxH /)30 05
O O X TJ
2>
-<
ui 4
*0 H* O'
4
oo oo
OJ H4 ro 44 4
*0 tn OJ H* o -t'
O' O' 45
ft
o -P* O' oao
h-
Hi- fO 4
Ul . tn ui *0 sO *0 I-*
ro . ro O' O' 4 4 4 ft
O' H4
4> 4
o o o 3 O' o o o 3 -0
003 00 3
ro
OH J)H* -s-J ofo*H4 vO vO H* O CO 05 CD . Ul
4
4
44 4
4
44
4 4 4
w oj 05 Ul 05 OJ . OJ OJ
W f\> ro O' 03 -J
-j
W H* H* O' -0 O' O O'
4
4
4 4 II
o -P' '0
OOHCDH)
4 ft m <
co >ro ^
CO O o o o o OJ Ul -0 >
o o O O <3 O o o O OJ *-4 >0 Co
%
O' CO 44
to -0 O' ro
nO '0 a*
-fc- O' oo
4>.
CD H ~g
444
-4 Ul H ro i> O' *jO O' W 44 * O' ^ ro ooO
so
4
O
o O' o o
H CO
>0 'O 44
. ^ 4
O H4 *) IM vj
o -T'
O4 '
O 4
r>
O' 4
OO 3 ooO
'0 Ul
OOO OOO
r- 3 >
IA -t H 71
jgHfecKgtffcia aastsaig ; a a ar-g s s s ;
><*mTo;
M tn 05
{
i J
i
\i
)
opi mo) bH1)
KJ\ kn
Ot n.0
O' XJOS H O CO w vn
H H
r- V" m h>
m
CP *u
>
O
l/>
!"0
rH X
o c -- K* ! C? O v ro -4 *4 j
^ O' -j l_*
O O' \J O'
\ Cj O H H* M H\ j
000 u. K-*
1i*)w1
w i
0 O' . o> ^00 }{ tv} *J\
"0 (/>
*< f~
yt
(fj *
v>
ni o?
> r-
ox
X rs>
c c-
C3 o O hl
z: o
5^ Va>.
r>
o to 3:
-0
-4 0 0
/-} CO ni rfs ?> > 0n DO
r* r~
ac kt.. 1 l
Js t> O c: *- *j\ tj 0 c;
C~) 'j5 -H sft D CS H *>V 3> >> O ~ <J'i (/>
CO
oa
OO
** 0 <5 00
'0 vO 4 * t"* * *0 ro 0 `C e 0*
M '_> -4 -4 O
i-'J
1-0 oL
fr 4 00 00
? 1* OOO 1 0 :.,
?.D 1*0
* 3C
-4
VO *> w m f' O ^ 7j r>j ** a u> .3 :j> O O *0
O' i> 0* O' O' 'O' *\f. /? u p *4 ,
iVi
-4 U|
t
0 0 0
}0-*}!i>>o *r
.tw>
v,V-4 o; *
-4 *4 4 -*
0- 4- '`'J '.0 .0 }i .1 ? ft
0> x> -i 0 'J
'}-* >-
*j\) fv>
;-4 --4 v%
.|v> ro fo
-4 -4 5 .* *
?* .1' c* j-- .0
ro
10 -1 ro
_0
I *U
!i
-
&
I
ii j i
i
i ij
j
\
,i
fi,
i 4,6 a .i.,, fdf> *-
ub bi.bi
l
I
- Hca <A'q
O OQ
,i L ;'
ii'-
mm' VN> I^-.{
'0-i 4^
~J ~IO
:'U> q>;>
If;
Ui v. i , . ;* U) u>'c .W* l* *A
i.ii
}; i
LJ ti_-jt
I . 1-
g a is--a s _. vi.'
fit'-:
-m
ssisi
if| *fii
-
fei|#
Mml'lBoii'Go III
"0
gp-..p
ISte.5, sfK`f"n
tfe? H
w***
ma r if'jc r
v m
<6.'8$O*' NH
?:'->t ->2r Si(? ;5I
'*'!$'. 6' 0 o o
H V- -* H*
Broi- 01 oi oI
Vtf' in 5-:^u5
01 vO
01
01 <0
w
I 0*
I O'
l O'
-i 05 CD OJ OJ
*V; *Vo O sl
-v oj ch -J
HHH <*<-<
rm rm rm
JO JO JO
; :; - a *0 3 *0
.
M o -
Tm3oTmU
-- -7);X
>'0 3 *-2 3
''Co
>to
o>o owr
ft-lO
o3 m JO 3
> n >to
.
r
oo
0)
*0
>x
Hm53
30 O
ms
z h
gco
o OM M| oo (0 M -4 ^
H* *
r M
o X o to ;o oo c%
*0
o H 3D oc -i 2 > t/> r
o O i-- 1 oo to to
4J. ># a>
o; c V m
33
to rM 7? JO or c o o c WM oo -i > to r to > r
4
o o >ml oo MM 0J 0J
<0
o tt M
to m > n o > r
o l JO * Q C *0 o
o H% O H >> r
i$*r**'
^-U'&.s(O>0 i-.|tMf
t'"' o
< :o
- 'B .> ; >01' 'to'.'Mto'4*
' CD >V6 '
>, tn
oi to
* o 01 * 4*
*g OJ
oo oo
o oo
44
oo o
V tV; ,,*? rviwE'
HSf;
N
/- - -r-
;:.v--`0o. o
O
O
O
O
O
O
A?,"C^ /
oo o
'J s
44
tho tho* 4
to to
44
o oo
ISjSt
is&r~P--.:!:'"Yr-!v.
S&ytoj <*?>*.. >*!!\li.'.i>,*^. v?;'
J^iS W*01Vv`>-NW >.- r.'* *COO''^-- -.`.OoJ
^:\0 ^4> -0
v-nO'5 ..'^OJ C
.;.-:--O' c
' H> 01 h w to
;
W
o 4 4*
4> OJ
B \0 OJ \Q 01 , 'OJ o O to o
rUM -J
VO to OJ
U1
4
01
to to
<0 **
oo
oc
0J 0J oo
44
oo oo oo oo
\0
44
4 MN OJ OJ
, >. ^
`S '
o
< o44st
M -04*
U1 *
' .
oc oc
O O
01
o*"n* oo
*-J *1
0J 01
CO CD
44
1-4 M >- H* 4
to to to to
01 OJ o
44
oi
10 -0 44
OJ OJ MH
jt'ggaaas
3~sTggsgs asK:a a
>
I
r i
i & v;
r
*I .
\ 1,
r*
/iS*
% s i.
*; K :* i
' r i : ':'
ri,,_rL- ;*k
1 1 ; :" i
;(
,.i
i!
i
:j i i
.{;
||l
!
i
)
!
.. !
j
. | j . T !!;? :>s' 1 !r
i j
r"
u\ to
n zc
03 O
O 0H3
o
_l
< r m 71
"0 iC
FI
M
!5S
o 3:
z im
c
03
H
II
p33j
m
05
ro N. H04\
03 S3
o
o 01
Ui !*
uiv
04 O
0+*4\
1
o o c
`^v o`n ci*; oio 0-0 oo
'6 jO !0 S jO
3:
F E 3> ` c-
rn m
S ft
n
c~tj "0 r
''CwJ i/3 jO
IiC=Or 73117 OSZ cini 1JZ
p
o oo
o , O 64 o O CO M
01 : u i. ro ro i
O o:
coo
o H*
o o*
O O O;
O O-5
r>- f*
i1
04! ` 6 o:
o o* '% $> O;
* *;
O S3! X'
1 mj
j ~ -n?
X| ; 2>
C; --i
I r r* r r[
3> Z
SO* sj
nH!.
j> Z
, Ft rns 1 HHj 2>
Z
03 2>
Z\ 03 i 2>
}* CO 1z
q H H
in t>! C3i
n~4
O J1 M
.tn t* "01 q
,v. ID- 3> i o r r:
H
o C Xi O ;c r r; o
z T? < z !u m m; z
.
*. . ; --! ,!
H
5! O 'O, -i OJ
OH
5 2>
r* ` 5
1 h -n H m w: ;C3 N N-* m h; `2> Z Z! ir n <n'
--a{ 5> r
O!
5:
o o:o
.OP-i* {* 1 1 i
O O 0.0
cn u* tnicn
i:S3 !
-{0 o-
<{J ^
i'01
: co co w o o >4
1% <\ w cn
: h -i --i
= i
< r
< r
-r<-
i rn ni hi
70 73 A
l
? X '.* X
; {
!> H
H 13
o1
m n rn o
a? X
'O X P* X
IC 2> O\j>
ll? 03 O 503
H1 . m=3 *!m'd IO a> [X
tI2>!*.*>Cl -
r o co on~ Tl
" 7m.\ 2> z
!o 0,5-* - 5 1 ojo rL-o>. s[Uro,
Ti Cn IsO jH* * ICO
b iC 12 03 r. ^ iOJ UM <n! C2 PiF CM V igc
qp
3- iU!
T CTi
jO o H* [ i bo). jOUb. w :wi
io.
0 if-0
i
(03 m !l> iG l2> j1* ! sni i
a C :** 7? o
P
0.0
oo
o o
ooo ooo
o o
ooo
ooo
oo oo
o o
oo oo*cc
o o
Oo o0*o0
! jH ill ^ Phs2 In n G -4 &% JP1 %
"0 73 O O C C--3i tJ m 03 n 73
-r* *# H% ft g,
! j I1\s
" d G G -I ft 2> --1 ro *i *.* ft ;? r
w 3S O -< o
,rn-ai? 3jn
cc M
03 03 Z T? H H O "i QO H X X -{
ma? z cSo3 x
03 n xo
i*
z
<
5 -V
to x ,r_ Oz 3> -*
03 X
< * ro *. 3? *
V*>v jI
S3
CHO* CHO*w. w* O'* 6* po
S3 w {4* ^ O
cn Q c>n >o ooo
ao o o
tSA3
y
(A
r*-
& CO [5 cn KW
^K0*w>-s' l o.Ov*0
oo 9?o
rvi -vi
5GS CO
3*. >
oo oo
0* p
W o O-S N03 oO 03 P
ft g
**5> ^35
< n
~ -<.
3>-m
2>
A?
--1 t
d
or u
jr t=r >>
--f :
oS
Wf
<* 71 S
m S3 rO
'
&.*& 3
2>
C3
rn
03 <0
;i.
0"0
r r \*n,
y
--c--- 1----- *.v
*./
7.0/J.l/LQ
1
i'!!!I!
1. ! !
~I .
ID SO
a^O
kTT TkTnrWW <---
0-0 OgO 0-:0 OgO
OfiO
H.T.T.WTMn =9 TTTH
Zftst: xi'i' ees T yv.>t nt-:zT cr.TM 7.n/n/m
,-n ...
TS.X.
t W.T OTt`7 T /TO'U 7n//T//n
nso O-^t) .OsO .O:;: O' PsO 0-0 O'
Ilk
aft
fc't.r
kC
u*
,rt, -;.
m m?
.' r
$'gg3ffi,\:
iS
m-t.y.*\~* `
7?V' ;r.\
*y.
* m
' I*:, r- o
*.
2T ow ora
W U*
I o *+
** vn
Co
*;
2 g*4* 3 *>
O 2` O t*
I
97*0G
CD
>
O,
f" qm
G_
-9 m !
L*H * kM
gQ?jCwF*
CM
B.r
im
dm >z.
)/
-->i %
m. 3ft CD mo
2
3ft -<
CJ-X
on* .*;,:*PoB,C ur** m -; `?|2 gc
o. O'/' -4.0 X C*1 *, >< a "X
r.v
o
*o 'C '*U </) }. *9 1-4 jo 5
I2"5
.'i***1
o
+* w
S3
g'
W4 i 1 4.^0
s S#*"B So m
V
0*to:0a
#
0*
i*u Mi *Oa* 9o*
a co a 0
jlo oQ
'A/"-
o Q
o c?
i
*o- oVV
I
o
5o
o
ovsoonn
oo
oo oo
U> ID wu
*0 *
ft'O o , o
'n ro
a
|<0 U3
9- & >'Oo* L
i *
oo
v.*
1~ M UVWl
. N. -
^i'*i
* i U*|Ul
o> o I
I
,>4l
PlM&.
segai
oo o
*#&
* a-..
*
vn
-.o . e
*Os.-rt:. *-ogj..,sy'iffc(*;0-
Ul'- *!<b O -J O o o
'a a
a*
ss
UJ V*
-ft* o
;1'.,'S >
::!u, m>. limum>f -,.ir^!u* oa>*
# i.* l*
OvWWO' O ^'X><U)0
2JS;
rJi*^
& CD
O
\r^a-^-r^iriv^^kJL^ * -t-y* -tx-'-i--^
o 0*0 0~ 3 D QfiO OsQ O^Q
oo?
~---- -~Ja-r
;^0*0
TTO B*l
Ofe
DNIINflODDV --*
O '-D
HUdillHD 3
b
a- ,--_ -- yj i. t_- -
t t/--
% <
Os o o ::'0 Oga: Chs'C
Z8SC TVf 6S8 I XVd: IS :ZT aaw ZQ/LX/LO
/ IT / I A
*
u -VO-v Wh JrT / /n
//T / in
h MrfnVhi'i: Bti ;>
s-t ~ o'- o
RSC Tfrfc fiQfi T TVjT Tn:oT rruu
-
' ...V
'^Sfes
?8S&'3S8
IV
t/i rSxl
w,ms,,i
5g;3^tfi *-**#11 tS/i vtSve.-&?nc$W$% a o* ,.-**.-z!('i;g! if&oStit
-
;>
*1/*-A#*
m
>}>3
-ilS'ilSl
*-
o^o-
- <?. C^'/tT'o/v
. -co>? *
V` tv-' -
29
BO
nrj'U1 t/*i Ut>>> WM 11 -ul
fer 1 y Mo> 1I ifnvj
"'Ml '> i/iM
\YV*f<'A :M * y ; t
4#
1'lA
>* > -'^V
V.
Vi ; 4*.:
f$r-
VV;? */
X X*"<? -
i''
; t/< '
'' Tx''*
` ' .i jk:
k".
bO*
o >-
| *-*
O fO
'
rEiVofO
i~*!W
1
0*
%]*-* *0
-*V-v
m
i
'<s*> V`*H
hi
:i<n
3<0 *-$00
X
o
Ci'O 58 0 O:-*
r C'
o tcMf-xr*
</> 4 ,rr
n V*
>
t>H'<jOZ
-c
/Ct'JOV
V '>-*
- *<
&;,i*mML
v:i
- '-Vx" x / .
't
' tv;;
'> f.vsv
' 'M ..
"^x -"
o
oI-*
O H* : * >-* ' h
o M
ob+ bo*
'; `Is
un VlfSfcs 1 i!*M.`Si*i0'
o A0
v:Wv^.{Vi
- '# >/ o
* # f*J ^r.#
? 'iV&i;fv>x) cv^ astiS
<' , v-"
: *|f^ m > ?j6?
oo.r; .. '}-*,*-k
' o5>
r*
il-iki o33 Z_ ;-.';.33
o nr>: o a '{
cTO C;^ eo a
v:c x:TO
0*Vv
-H o
m. . . V'xx/-';i
--i O
1
3H>
r
CilJ g:6; ?V''K
H > r*
X m
o
'A!??
f'>y-
'./"J'.vi-V'Z-
'jVx;
'Hf -v
5^bs
^ !! >
4tft'8U1 0O0v oo*
1'VS'K f* 4* f
o o
o'r> it
<?-s*
o o
o.;S
H* o
M o
Anp
'4lf#
VSi,vlV>rK<'
*
im. i' :.v
H* H*
'. S;*
jy
-J Ul \A
0* O "M
> o o
:* 0:;0 'i:^;X
o
'.-kf>tzSZ
Ox o
O' * o
.u;.*S >' is*
o |n o o .-o
'X
V < .;'tr-xJ-
^ . x'.
V
.p* t;x l
VI vn
fO
tog
o *
o
:,no
H* V> fO *
<> 0**0% VUl *4*x
o
o-4;k^
ro
m
. ,*
b
o *
iO^1
U> U)
%
i*-4
M
00
tftiUl
o;.o
00 00
j'V
VI
<0 Ut
*
'
* ?* *' ;C'
il
/*5r S'hh - :';rv
.m %>.
ro
00
v0 00
*
> 0o0
v-
fO fV M'ft
*xivtfj
O'O
^1 H* l-
^ V0
<*
* o o
?--SS7 'life * V: Oil
H*
00
U> "4
H u) *^4
"'ilK .; i;K
U> l U] sl kTF
Ta3T7vT ToT> T1 7oTt
OM-*0-0 ' o r- O O " O" O ; o
-s ' oh- o-^omo^c
<n. -
u IT t/ H JU M
1/
.V
:
V,
'*5> ft. :>:
,,V ft
ft
,1 * > j
"V
'ft
,,> 5' ft*
Q obo
o O V} b VJ \>
N> \> r. 1 )v 1
-..
O o te*
O' oM
o o te-
3 D M.
D D
4f-
...
#
Q
OnA
o o 4* \>
O o * -*
6 0 4* O
,'
"0 T> T) "0
> > 3> >
.>
rT?
r r*
1
--
50 > 2
,k ,,K
nmmu *H ~rl H
/> ,D />
/) > O
'V' A4
4S
CD 33
S'w3
p> 4* -i>
*u to O >
w -T- O X r* Jsf X
ry 2
,'f.
-V-
c "O
4* 00
r
m -I
4v 3a 00
a
-4 w O ;VV M ,,
-4 > r*
V.
>r
v'
M 2 CD
-.
'?
'V, y?. if*
'<v ft
V V ;v
'0/
Aft /4 'f
-4 -b fSJ ro
-4 NJ
O
o r
4
O 0
O o
oo oo
O o
o o
O o
f\> >.' IN5
rsj
gj CO CO s - Co
co oo
4 * e 9
o -' o o O o o
o o ooo
*?
ft
4) vD ,.7
44
a? CD U1 O
o
+ 00 ' . H*
O'
-ft
O'
'
O'
#. 4
o 4-r o -f '
cc
b o <i-
o c
o
oJ..
O o
rr
>*, <`v j
ft;
v *4) . ..
43
4
r>o
4
-4>l
0 vC
vfi u U) 4 te* <X -* u;
O'
4
O'
N
4> 4
O' 4S
a cC cc c
o c O coo
%
,
f r ;y.
A'.'
s?5 ,V'
'V V.
>?.
ift J5!i
1 Vy
<L ft
f'- JJ
o v:
3&
O' o
KJ
h-*
oo OQ
J1 V* cn
pO V, bJ
O' iV'-' *>;
o # OJ 'T'
0Y 4>' n CD
-4 -<
s
mm
no.
3:
*0 2
M *o
1
m CD |5Vr
? Gf CD
C-. >*
53 O; O C
33. CD
*0
*4 O
*X7
'ptf 'j',
D O2
HV
>
r^1 3 r*
c^-
XD
A#' r?
;r^c'
net S-
|
.i r. .,y
oo oo
oo oo
,r
V.
A v| $lr .4' V?
fi`-
<-
A sS 'V }-
'Aft
'> o E?
Q h- m:
M O
1 o
hfis
r>> N>
-4 |
O' tjf; t-* 4 CD
*
o A -< 53 H. U o> 7,?i` `'s m T3 > r- %
<r> '15 ?3 c If Qo co
M >iv 2 --i GT> k?< of O >O r2 t. "O ... o 'f C -'i2
1 O -f :it-'
|
-j.
o> 3f JN iv 4* 4 tn o n o CD o.
i x.
'i
:V 'T'f
, V.-'
A
y.i. K .
1
H
i %
1
V?' %>
'' " '.ft |
ft
h'i p
ss
O O<
h- i
H
O P O o>
Pb \) ??> H r#;
w j} 1
bi f
vt O' Vf? 35?
45
i?1 J1
# o-
* o `5;' iy.
1
,j;
T1 1
%
N'.< ^1 V,
?;/
CT J*
Vtf
43
V* < i3
1
rr >
P): o*
CD r> CD >t:
5o 53
CO.
T3
3. />
I f
O
C
*TJ
S'
V o:
XJ D>
H JK O
< s? H cd.
>I
> A>'
r
n
.4
r
!>.
> S:*
T3
i1!& o
7a
'v "*v-
a
V-* H**
M H* 4 4'-r
?< O'
" ; co X)
*
Z
bJ
L0 *.
b D .* UJ
o oO
*, A J\ b x> D-
,f D 4.
<> s 3! q! w
p' 1?f 1
VtC- g a 5; fi-' i
wi
1#
1
fir&0 s D; it:
1 a 0 fe a- 0 f & -4
l s' O'
0 -f if vn ik
co 1V a.'
1$
1
m co
i-
O
2
< ***
M ii S n %s 0
Q' 53
O mp
8 0
H1 0
2
H T3 %
> O
c
ft 2 a
.v 9-%
1
M 0
1
14
1
4C 4 O 0 t:: O0
ft/
z a 1ft
%
rff 53
a i
1 4 H E
1 S O; Q
5S V*' ro 30 s q 1
s
% tel
tel D "A & 8 M ti 7
%-f
r< m > 30
*,v W'
u /'' `-r-
ftC' o o > o O oo og
'V
yk %
;
jTj -V vV
s v'-. '-%f
i Q o Vr o O O o oQ
s C IS
't' sVi* Vt'
O' Ui
O' bJ
x,-. -o'
w H* M
<4 * 4
0D U OJ
OJ lb
tn O' O'
4
h- H*
4> H M
Vr -1
-X*
5* 4 V o oO Q o b*"
Is
M iP' H b * 4 IV H O Ol n JN) o hj, ,4 4 4-:t ,P CO [\J ;g o p,
fl Ji' 'a H >H '03 O' V) # 4 4' O' - $" o O' b a vC r- 4 4 : 03 Ct: o o oo
1
'"'r 4 . T*" -4
45 45
U1 vn
4* > 4 I'v
OD
w b
qO s ob
>'
A
H* w
ls> S) ; O'
b) b
Ob
4 i i~ 4 t-
> s rb b
,43 NO J-- r*
U1 jj - vr 01
4- t {'-* 4 O O ft-'. O' 03
o o l\) !V
PW'
P
H M /cV M ir*
rv3 \J
OO
CD 09
-b
44
4 4.
U JJ ca 03
vQ 45 bJ b>
O U1
O' O
0
4
a CO
-4
oo
-s
" f ` V. ^ eft ? Oa P0
u-ft vV
yI
-
u 5; 4) 4 NN
4 OC
1Ul u
vft-
3
;v *- vs-
9
Oa
c c
rr i? ^3
if. <
3> ?
vV
y:
H a: *r1 0> y
CT1 >
<
*'N I & r > 0; --
*< rr > X
rK
m*''nj:p;\\V*v: O5*t03'PO*\h%*vV'*}*<{J'
-H V ,W{;
'' Stfr *'
a a a fc* a a a? sf-a D< M -S--
-Q O
0:g0, 0^:0 O;
c>%o; oto
^
*
.vu>twe<` ;. 3$
$
-ife J'
:-&'fe*p-4.j o
o o'ws; So w w wsKsk.m-w i
ffip^yoo .
-?;; ,;o .
w. %0 ft*-
ft# ft 0t
O c
. 30
Z>..
m
'- fOv,.
tA
>6>.
-i
M
'";: ^o*cagr
O. -O1;
-4
O
5' H
>-
.r*
,' t$g<-
wt-
c
o
m0&`
^'v^v; I
too No-:
O o
8&-.'
oo oo
-&*-
--#*fiv-<?' =
; ^V'iv."
t ' !- i _ -|i-;.p< -; ;;0 .
:`
N).'.
* H* s*
\Q o *-
iIffOO
:>
i*4
o o U1
Q O jvn
i
to.
h*
H-
ro*-s
N-t>o>J
N t*>oi .
V009' O'.
Utf1t
in in
Ui<I
f
1 t
H-.y--.-Q. w-.
OgO OrO
H .ft tO fO O *O oo
*w oU*i a to to in in GO Q>
j* . i. fc oso
M I-* Ui w Oi O'' Wto iUoJ* 0J w
to to to to . co *000*0 U) oU i oU i. `.h
to po: "4' *4-
*4 O
a o .!- tr*- *O'*O
5>vn!w'.-., - u t Vi
Oi oo
o p .. 0-0
s 5..S.
O :'0 OgO O :
o ^n.vo^n ^^ .
'"in' " fVI <
u
mi u
u
'
u ta A o
O Sl R
S
C`~ ** "^ '-tgrcr
t|
W
fcj
C 01 u
o
f Hill and Griffith Company Material Safety Data Sheet
May be used to comply with OSHA's Hazard Communication Standard, 29 CFR 1910.1200. Standard must be consulted for specific requirements.
N.A = NOT APPLICABLE
N.E. = NOT ESTABLISHED
5. PRODUCT IDENTIFICATION
PRODUCT NAME (s): Red Chief Dry Core Paste
Manufacturer: Address:
Telephone:
The Hill & Griffith Co. 1262 State Avenue Cincinnati, Ohio 45204 (513) 921-1075
Fax:
EMERGENCY TELEPHONE: (800) 424-9300
Call Chemtrec
(513) 921-9180
II. HAZARDOUS MATERIAL IDENTIFICATION SYSTEM *
CATEGORY
RATING
Flammability
1
Health
2
Reactivity
0
Personal Protection
B
These ratings are based on NFPA regulations
LEGEND l=Slight Hazard 2=Moderate Hazard 0=Minimal Hazard B=Glasses and Gloves
III. HAZARDOUS INGREDIENTS
HAZARDOUS INGREDIENTS Iron Oxide Inert Nuisance Dusts As respirable dust
CAS.NO. 1317-60-8 Mixture
ACGIH THRESHOLD LIMIT VALUE 5 mg/m3 10 mg/m3
%
5-10 50-60
OSHA PERMISSIBLE
RANGE
EXPOSURE LIMIT
NE
15 mg/m3
@ This material contains Silicon Dioxide in some form. IARC Monographs on the evaluation of the Carcinogenic Risk of Chemicals to Humans (Volume 42,1987) concludes that there is sufficient evidence for the carcinogenicity of crystalline silica to experimental animals, and that there is limited evidence ofthe carcinogenicity of crystalline silica to humans. Classified by the IARC as 2A
PRINTED IN U.S.A
Product Name: Red ChiefDry Core Paste
Page 2
IV. PHYSICAL/CHEMICAL PROPERTIES
Appearance and Odor: Red powder, sweet odor.
Water Solubility: Miscible.
Melting Point(F): NA
Boiling Range(F): NA
Specific Gravity(water=l): NE
Vapor Pressure(nunHg): NA
Percent Volatile By Weight: NA
Vapor Density(Air=l): NA TPQ: NA
Evaporation Rate(Butyl Acetate=l): NA RQ: NA
V. FIRE AND EXPLOSION INFORMATION
Flash Point(C.O.C.)(F): NA
Auto-Ignition Temperature(F): NE
Flammable Limits: LEL: NE
UEL: NE
Extinguishing Media: Alcohol foam, CO2, or chemical.
Unusual Fire or Explosion Hazards: Material may bum in the presence offlames or high heat sources.
Special Fire-Fighting Procedures: Use full facepiece with self-contained breathing apparatus when fighting fires near this product
VI. CHEMICAL REACTIVITY INFORMATION
Conditions Contributing to Instability: None. Incompatible Materials: Strong acids or oxidizers. Conditions to Avoid: None. Hazardous Decomposition Products: Various oxides of carbon and hydrogen. PRINTED IN U.S.A.
Product Name: Red ChiefDry Core Paste
VII. HEALTH HAZARDS A. Summary/Risks
Page 3
Signs and Symptoms of Overexposure: Eyes- irritation with redness and swelling; Skin- may irritate; Inhalation- may cause coughing and sneezing.
Medical Conditions Generally Aggravated by Exposure: May aggravate pre-existing medical conditions. Primary Route(s) ofEntry: Inhalation, skin contact, and ingestion. Target Organs: Eyes, lungs, and skin. Acute Health Effect: Overexposure could lead to skin irritations and lung or mucous membrane irritation. Chronic Health Effect: Overexposure could lead to severe damage to skin, eyes, lungs, or mucous membranes. Carcinogenicity: See page 1. Notes to Physician: None.
VII. HEALTH HAZARDS B. First Aid/Emergency Procedures
Inhalation: If overcome, immediately remove from exposure and seek medical attention. Skin Contact/Absorption: Wash skin thoroughly with soap and water. Ifirritation develops, seek medical attention. Eye Contact: Flush with clear flowing water for at least 15 minutes. If irritation persists, seek medical attention. Ingestion: If ingested, DO NOT induce vomiting; call a physician immediately.
VIII. SPILL, LEAK AND WASTE DISPOSAL PROCEDURES
Procedures for clean-up of spills/leaks: Stop spill as soon as possible. Scoop up or clean up using best means possible. Water may be used to clean area. Notify proper authorities if the need exists.
Waste Disposal: Waste generated during application, demolition, breakage or spillage may be hazardous wastes as defined by RCRA (40 CFR part 261). Place waste and spillage in closed containers. Dispose of in approved landfill in accordance with federal, state and local regulations.
PRINTED IN THE U.S.A.
Product Name: Red ChiefDry Core Paste
Page 4
IX. PROTECTION AND CONTROL INFORMATION
Hygienic Practices: Minimize breathing vapors, mists, fumes or dusts. Avoid prolonged or repeated contact with skin Remove contaminated clothes, launder before reuse. Remove contaminated shoes; clean before reuse.
Ventilation Requirements: Provide ventilation sufficient to prevent exceeding recommended exposure limits Respiratory Protection: Use NIOSH approved organic cartridge Type 7 respirator for vapors and/or a fine particulate filter for
dusts, ifnecessary. Eye Protection: Use safety glasses, splash goggles, or face shield when eye contact may occur. Protective Gloves: Use chemical-resistant gloves, if needed, to avoid prolonged or repeated skin contact. Other Clothing and Equipment: As required to prevent contact. Engineering Controls/Work Practices: Keep containers and storage containers closed when not in use. Special Considerations for Repair/Maintenance of Contaminated Equipment: Provide adequate respiratory, eye and skin
protection.
X. PRECAUTIONS FOR SAFE HANDLING AND USE
Storage Segregation: Always segregate materials by major hazard class. Special Handling/Storage: Do not transfer contents to unlabeled containers). Other: Comply with all federal, state and local regulations.
XL DOT SHIPPING REQUIREMENTS
Shipping Name(s): Any Packaging
Compound, Adhesive
Date Prepared:
07-28-97
Preparedly: Lori R. Yeager
Supersedes: 10-14-93
Print Date: 07-28-97
Title: Corporate Government Regulatory Manager
As of the date ofpreparation ofthis document, the forgoing information is believed to be accurate and is provided in good faith to comply with applicable federal and state law(s). However, no warranty or representation with respect to such information is intended or given.
PRINTED IN U.S.A
<C3M*
T5 >i CD 4-> TS -h
coo
*
C(OM 0o0
P LO
PdCD pdCCS xd
m wa
00
\05 =8=
CM CM
o o
LO X fPt
d CD
pm
>
o CLoOM o
o o O05'
LO
o LO COM O
o CM C(OM
oCO ooCO
p
a
?PEEC-fhHOd*l
Em CO >H X X X >H Eh ft ft ft ft ft
o H to t--o1
w
ft
oo
hp
Ed id
ft
ft
PdM
< Ed
fEHt
cEd
Pd
fEht
a
ft
PCO
<w:
PdQ
rEfdj
PdQ
pd
. |J3 CO ft 0
aM
pc ft O rfj
x ft
w
o
ID rtl ft 14) ft LO
p =#=
i--I P
a) Ed
P
=o#=
CO X
O O
> ft ft a)
d
M LO CO
d CO
w
rH .--.
CD 1-- 1 tn
d
O
o o o
*
K Eh
CO
>dH
CO
Q Ed
H 2 O Pll ft
d
ft
o o
ft
p
--
C/5
x--1
o H
p
ft Ed
p
Ed ft
oo
=8= O in
Ed Q M
in ft H H X
CO H ft ft o o
d ft <
CO O X Ed ft ft
t--l CO b ft P o
CO
CD
P
ft p
ft .U
ft
d
O o
ft ft
P
T3
dCD
* >H
d ft
3
p
Cf d
d (D CD ft Q
CD
do
00 00
oo CO
o
05
CO 05
CO rH
S >i 3P
ft
S
rH
o
ft
CM
CM
05 CM
T--1 CO
CO ft -H
o c--1 C--1 x--1 x--! rH
05 -P o CO CO CO CO KD
O
P lf-Ht
pd dd rcvc.i /d--m
o o op p
OO
o o oPa/
CD
rr\
A1
Al
O At
O
At
r\x
Ox--1 o o p
ft ft
p Ed
0)
ft ft
ft ns
CO ft
h
P
II rH
ft o
Ed ft
Ed P to
CO Go
2 *H >
CD
rfj d
EH ft
PL<
II CM
rH
Edd p4
PS3
d
d CO
M CD
d
>p
<!
(D
ft
d II
dft LPOr.
MATERIAL SAFETY DATA SHEET
May be used to comply with OSHA15 Hazard Communication Standard, S.9 CFR 1910. 10 Standard must be consulted for specific requirement s.
N. A- = MOT APPLICABLE
N. E. = NOT ESTABLISHED
I. PRODUCT IDENTIFICATION
PRODUCT NAME (s):Slik Box
Manufacturer; Hill and Griffith Co. Address: .LESS State Avenue Cincinnati, Ohio 45E04
TELEPHONE: <S00> 543-04E5
Hours: 0:00 A. M.
5: P, M.
Fax: 513~9i--0iG
II. HAZARDOUS MATERIAL IDENTIFICATION SYSTEM
CATEGORY
Flammability
Health
'
Reactivity
Personal Protection
RATING
i 0 E
III. HAZARDOUS INGREDIENTS
LEGEND
iqnt 1 iazard
--hi in i mal \ iazarei =Minima1 H tf.Scl V"' ci E--Glasses, Gloves
and Dust Re spiv'at ov
ACGIH THRESHOLD
%
HAZARDOUS INGREDIENTS CAS.NO
LIMIT VALUE
RANGE
OSHA PERMISSABLE EXPOSURE LIMIT
NOME
none
na
na
Talc
14807--96-9 (
mg/m3
j5-"6ci
3 m g / m 3
* As respirable dust
This material contains Silicon Dioxide in some form. IARC Monographs on
the evaluation of the Carcinogenic Risk of Chemicals to Humans (Volume 4.
19ST) concludes that there is sufficient evidence for the carcinogenicity of
crystalline silica to experimental animals, and that there is limited
evidence of the car'cinogenicity of crystalline silica to humans. Classified by the IARC as SA
PRINTED IN U. S. A.
FOR CHEMICAL EMERGENCY, SPILL, LEAK, EXPOSURE OR ACCIDENT CALL CHEMTREC DAY OR NIGHT AT 1-800-424-9300
Product iMame;31ik Box
Pa g e
IV. PHYSICAL/CHEMICAL PROPERTIES
fippearancs and Odor White powder, slight Fatty odor.
Water Solubility NEGLIGIBLE
iri siting t~` oint ( 0 r ) ; i 3d
Bai1ing Rang e(aF) > 65
Spec i v i c j r v i u y \ wrfc er-.t> :
Vapor Pressure (minHg) na
Percen t V a 1 at i I e E* v l*i eipht : i "i eg.
Vapor Density(Air--1) na TPQ na
Evapo'rat :L on Rate(But y1 fleet ate=l) : na RG : na
V. FIRE AND EXPLOSION INFORMATION
Flash Point <C. Q. C. ) (oF) : 37D
Aut o-Ignit ion Temperatare(oF) : na
Flammable Limits:
LEL na
UEL na
Extinguishing Media: CQ2, Dry Chemical, Foam, Water Fog.
Unusual Fire or Explosion Hazards: None
pecial Fire-Fighting Procedures: Use full facepiece with self contained reathing apparatus when fighting fires near this product
VI. CHEMICAL REACTIVITY INFORMATION
cr 01
Conditions Contributing to Instability: None.
Incompatible Materials: N. b.
Conditions to Avoid: None.
Hazardous Decomposition Products: Various oxides of carbon and possibly nitrogen.
PRINTED IN U.S.A
Product Name: Silk Box VII. HEALTH HAZARDS A. Summary/Risks
PAGE
Signs and Symptons of Overexposure: Overexposure could result in coughing, sneezing, shortness of breath or other respiratory problems. Other symptoms may result.
Medical Conditions Generally Aggravated by Exposure: May aggravate pre existing medical conditions
Primary Route(s) of Entry: Inhalation.
Target Organs: Eyes and lungs
Acute Health Effect: Overexposure could result in temporary mucous membrane or respiratory tract irritation. Chronic Health Effect:
Carcinogenicity: This product is not considered a carcinogen by the ACSIH, NTP, I ARC,, or O-GHA. Notes to Physician: None.
VII. HEALTH HAZARDS B. FIRST AID/EMERGENCY PROCEDURES
Inhalation: If overcome, immediately remove from exposure and seek medical attention
Skin Contact/Absorption: Wash skin thoroughly with soap and water'. irritation develops, seek medical attention
If
Eye Contact: Flush with clear flowing water for at least 15 minutes. If irritation persists, seek medical attention.
Ingestion: If ingested, DO NOT induce vomiting; call a physician immediately.
VIII. SPILL, LEAK AND WASTE DISPOSAL PROCEDURES
Procedures for clean-up of spi11 s/leaks;on as possible. Scoop up or clea
n up using best means possible. Water may be used to
clean area. Not
ify proper authorities if the need exists.
Contain spill
Waste Disposal: Waste generated during application, demolition, breakage
spillage are not hazardous wastes as defined by RCRA <40 CFR part 61).
Place waste and spillage in closed containers. Dispose of in approved
landfill in accordance with federal, state and local regulations.
or
PRINTED IN THE U. S.A
ProdLiet Name: 31 ik Bqk
PAUiz. 4
IX. PROTECTION AND CONTROL INFORMATION
Hygeinic Practices: Minimize breathing vapors, mists, fumes or dusts. Avoid prolonged or repeated contact with skin. Remove contaminated clothes, launder before reuse. Remove contaminated shoes; clean before 'reuse.
Ventilation Requirements: Provide ventilation sufficient to prevent exceeding recommended exposure limits.
Respiratory Protection: respirator
Use MIOSH approved organic cartridge Type 7
Eye Protection: Use safety glasses, splash goggles or face shield when eye contact may occur
Protective Sieves: Use chemical-resistant gloves, if needed, prolonged or repeated skin contact
Other Clothing and Equipment: As required to prevent contact
Engineering Controls/Work Practices: containers closed when not in use.
Keep containers and storage
Special Considerations for Repair/Maintenance of Contaminated Equipment: Provide adequate respiratory, eye and skin protection.
X. PRECAUTIONS FOR SAFE HANDLING AND USE
Storage Segregation: Always segregate materials by major hazard class.
Special Handling/Storage: Do not transfer contents to unlabeled container(s).
Other: Comply with all federal, state and local regulations.
XI. DOT SHIPPING REQUIREMENTS Shipping Marne: Foundry Core Compound, NOI Hazard Class: None. Identification Number: None Label(s) Required: None.
Date Prepared: 4--7--199
Prepared by: Steve Neltner
Title : Lab Manager
As of the date of preparation of this document, the forgoing information is believed to be accurate and is provided in good faith to comply with applicable federal and state law<s). However, no warranty or representation with respect to such information is intended or given. PRINTED IN U. S. A.
iH ^
ft
Ti >i cn o
o
cn
0 -P
*
\--1 T3 -h . f3 -p
ID id a
IT) -P <d
LO
X ft
api
CO
Cn pooo o o
CM a> cm on CO CO in CM Pm "3* r~ on on CO
rH m o o ''3* in >1 cn o o o o
-p
a
CO
Y Y
ft CO
XXX
ft EH Pm Pm Pm Pm Pm
Q
2 pi m m <<
ft
S =tt= ft Pm p p ft ft X
oo
-H 2 ft 03 P3 Ptj < 03
to CM p CO p p ft ft P
o CQ
i--1 X ft
ft p eg
ft O X 03
O 03 <1 |xj 03
ft ft
X
ft =fl=
I--1 H
Q in ft O
a) p s > CO ft 0
ft X H O
>j <r.
CO
on
P ft
c--1
p Ph p
o Pm X ft
0 o CO P ft ft
i--1 P
o o
ft
O Pm
\
o
ft
Pi
-H
T--1
O ft on
p ft
cn *H ft on O ft ft
4-> H CM O ft H
IP in
Vi--nl irnH
ft -H
p
fEht
CO
oP
to ft
P
t-H CO 1
ft ft ft
X CO
5
Xo fot
CD ft X H ft ft
Q H ft P a M
*
X3
-P
P
0
tti
n
Pm
-H
dP
M0
-P
Pi 0)
a) ft Q
Pi O
CM CM
O LO
O
cn
p o
CO rH
g >1
ft CM CM
m rH
oCnn o fPtm
p -p
ft -4H-> 4-> fi P (C /"m d/--o
O O
CM
rinH
viC--nM1
C\i-nM1
Ci--M1 VD
oT-n1 in
ft +aJ/
ft r0o)
oo
oo
o o
o o
oo
l--1 o o o
ft Pm
ft
ft ft X rf ` P Pm CO M
q
ft
h h
03
CO
|xj
c
p
rt{ ft
ft P po 3 p V-)
> rt!
p
d
0 p
Pm II rH i--1 O
ft
to pi O rH
> 0 P Pm II CM tH [x*
ft to
mP0
0
ft mr_II
Hill and Griffith Company Material Safely Data Sheet
May be used to comply with OSHA's Hazard Communication Standard, 29 CFR1910.1200. Standard must be consulted for specific requirements.
N.A. = NOT APPLICABLE
N.E. = NOT ESTABLISHED
1. PRODUCT IDENTIFICATION
PRODUCT NAME (s): Pyroseal Mudding Compound
Manufacturer: Address:
Telephone:
The Hill & Griffith Co. 1262 State Avenue Cincinnati, Ohio 45204 (513)921-1075
Fax:
(513)921-9180
EMERGENCY
TELEPHONE: (800)424-9300 Call Chemtrec
II. HAZARDOUS MATERIAL IDENTIFICATION SYSTEM *
CATEGORY
RATING
Flammability
0
Health
1
Reactivity
0
Personal Protection
B
These ratings are based on NFPAregulations
LEGEND 0=Mmimai Hazard l=SligJit Hazard Q=Minimal Hazard B=Glasses and gloves
III. HAZARDOUS INGREDIENTS
HAZARDOUS INGREDIENTS Water Silica Hydrous CalciumMagnesium
Silicate Hydrated Aluminum Silicate Clay Kerosene
CAS.NO. 7732-18-5 14808-60-7 14807-96-6
1332-58-7 1318-93-0 8008-20-6
ACG1H THRESHOLD LIMIT VALUE NA 0.1 mg/m3* 2 mg/m3*
% RANGE 25-35 30-35 15-20
2 mg/m3* 15 mg/m3** NE
5-8 3-7 <5
OSHA PERMISSIBLE EXPOSURE LIMIT NA 0.1 mg/m3* 20 mppcf
5 mg/m3* 5 mg/m3* NE
-Respirable Dust; ** - Total Dust This material contains Silicon Dioxide in some form. IARC Monographs on the evaluation ofthe Carcinogenic Risk of Chemicals to Humans (Volume 42,1987) concludes that there is sufficient evidence for the carcinogenicity ofcrystalline silica to experimental Tnimals, and that there is limited evidence of the carcinogenicity of crystalline silica to humans. Classified by the IARC as 2A
PRINTED IN U.S.A
Product Name: Pyroseal Mudding Compound
PHYSSCAL/CHEMICAL PROPERTIES
Appearance and Odor: White to tan paste with earthy and slight solvent odor.
Water Solubility: Miscible
Melting Point(F): Not applicable.
Boiling Range(F): 212
Specific Gravity(water=l): 1.7
Vapor Pressure(mmHg): As for Water Percent Volatile By Weight: 25-35
Vapor Density(Air=l): NE TPQ: NA
Evaporation Rate(Butyl Acetate=l): NE RQ: NA
Page 2
V. FIRE AND EXPLOSION INFORMATION
Flash Point(C.O.C.)(0F): None.
Auto-Ignition Temperature(F): Not applicable.
Flammable Limits: LEL: Not applicable.
DEL: Not applicable.
Extinguishing Media: Does not bum.
Unusual Fire or Explosion Hazards: Not applicable.
Special Fire-Fighting Procedures: Use full facepiece with self-contained breathing apparatus when fighting fires near this product
VI. CHEMICAL REACTIVITY INFORMATION
Conditions Contributing to Instability: Not applicable. Incompatible Materials: Strong oxidizing materials. Conditions to Avoid: Not applicable. Hazardous Decomposition Products: Not applicable. PRINTED IN U.S.A
Product Name: Pyioseal Mudding Compound
VIL HEALTH HAZARDS A. Summary/Risks
Page 3
Signs and Symptoms of Overexposure: May cause eye irritation, minor skin irritation, coughing or shortness ofbreath- May cause irritation of mucous membranes of the nose, throat, and respiratory tract Gastrointestinal distress if swallowed in large amounts.
Medical Conditions Generally Aggravated by Exposure: May aggravate pre-existing medical conditions.
Primary Route(s) of Entry: Absorption, inhalation, and ingestion.
Target Organs: Eyes, skin, and mucous membranes.
Acute Health Effect: May irritate noes and throat with possible minor skin irritation. Seek medical attention if ingested, although first-aid is normally not required.
Chronic Health Effect: Exposure to dust may result in silicosis. Carcinogenicity: Seepage 1.
Notes to Physician: Gastrointestinal distress if large amounts of product are swallowed.
VII. HEALTH HAZARDS B. First Aid/Emergency Procedures
Inhalation: If overcome, immediately remove from exposure and seek medical attention if irritation or discomfort persists. Skin Contact/Absorption: Wash skin thoroughly with soap and water. If irritation develops, seek medical attention.
Eye Contact: Flush with clear flowing water for at least 15 minutes. Ifirritation persists, seek medical attention.
Ingestion: If ingested, this product is not expected to be an acute ingestion problem. First-aid is normally not required, but seek medical advice.
VIII. SPILL, LEAK AND WASTE DISPOSAL PROCEDURES
Procedures for clean-up of spills/leaks: Use respiratory protection. Apply water to spilled material to minimize dust Stop spill
as soon as possible. Scoop up or clean up using best means possible. Water may be used to clean area. Notify proper
authorities ifthe need exists.
/
Waste Disposal: Waste generated during application, demolition, breakage or spillage may be hazardous wastes as defined by RCRA (40 CFR part 261). Place waste and spillage in closed containers. Dispose in accordance with federal, state and local regulations.
PRINTED IN THE U.S.A.
Product Name: Pyroseal Mudding Compound
Page 4
PROTECTION AND CONTROL INFORMATION
Hygienic Practices: Minimize breathing vapors, mists, fumes or dusts. Avoid prolonged or repeated contact with skin. Remove contaminated clothes, launder before reuse. Remove contaminated shoes; dean before reuse.
Ventilation Requirements: Provide ventilation, such as local mechanical exhaust, suffitient to prevent exceeding recommended exposure limits.
Respiratory Protection: Use NIOSH approved respirator with a fine particulate filter or approved dust mask for dusts, if necessary.
Eye Protection: Use safety glasses with side shields. Protective Gloves: Use chemical-resistant gloves, if needed, to avoid prolonged or repeated skin contact Other Clothing and Equipment: As required to prevent contact Engineering Controls/Work Practices: Keep containers and storage containers closed when not in use. Special Considerations for Repair/Maintenance of Contaminated Equipment: Provide adequate respiratory, eye and skin
protection.
X. PRECAUTIONS FOR SAFE HANDLING AND USE
Storage Segregation: Always segregate materials by major hazard class. Special Handling/Storage: Do not transfer contents to unlabeled containers). Minimize the amount of airborne dust present in
handling and storage by using an enclosed handling system. Other: Comply with all federal, state and local regulations.
XI. DOT SHIPPING REQUIREMENTS
Shipping Name(s): Any Packaging
Caulking Compound, N.OJ.
Date Prepared: 07/23/97 Prepared by: Lori R. Yeager
Supersedes: 03/24/97
Print Date: 7/25/97
Title: Corporate Government Regulatory Manager
As of the date ofpreparation of this document, the forgoing information is believed to be accurate and is provided in good faith to comply with applicable federal and state law(s). However, no warranty or representation with respect to such information is intended or given.
PRINTED IN U.S.A.
tt
CO CO rH
CM CM
T5 >1 t--1 o o CM
O CO
CO
CD -p
o T) H
6 -P
CO CD
LO -P (0
Xd
r-~ w a
CO p
r~CM
g
tO I* pc; Q
poooOooooo
CD 00 CM 00 LO co ^ 'cr CO CO PM tO O P CM LO \--1 \--1 CD
r- CO rH O CO o o rH CM >, rH o o O CM O o o to -P a
=8= o o r- ft CO >-* X >-< X >-i X X X X
O EH ft CM CM CM ft CM CM P P
M
CO g p S PI S PQ PQ PC a
CO
CM Er< 0 E-f PI ft ft ft P P
o rf!
-H
p
g ,x PQ PQ PQ PQ PQ |<
CQ PQ
to o
CO A A i-l PI A ft ft P P
o cq
1--1 P P
ft S3
x; w H CO
o i--1 pc;
CD 2
i> P D CD
O o C--I
o CO cc; PM CO f<
X 0 CQ
w <J
ft ft <
O P CQ
Em ft
CO
ft =fl=
CO
a
o o
f=n PQ
X ft rH
00 ft =tt=
CO M H o
p o
Eh PQ =8= o
p Eh LO XM
CD o o
\ =8= LO OO
po
K
s o
o o
tn o
O o LO ____
CM O p rH
a
\--1 rf!
s
\--1
o rH
rii
PMp
CO
*H ft
o ft m <!
-p 0 cq M ft
o ft
p
r-
ft ft D ta p
* EH |2 X
r-
-rH PI o P
CO s
tot--i p CO 0 PS ft H
CO
u jcC
X M ft ft g P o
srH
CO rr? ft tf!
Eh S & W p
CO Q) >i c4 PI O PC H p M f<
ft CM o o p IS P p IS p
*
-P
n
P
* CD
flj
M
CM
* *H d
P
t?
CD
CD
a) p
P =i* ir> ft CO CM o 00 t> o
O
CO rH
ft cr\ CM o
"& >i
ft o o T--1 CM CM ^
CO p
3 4->
S CM CM CM CM CM CM CM CM co
co S -H O *--! \--1 rH rH rH rH rH rH rH
Pcrc -p o CO CO CD co CO CO CO CO CO
o
Q
P (0
tn D1 o o O o o o o o o
HPrH
A(0 /-d>
P a) o o O o o o o o o
rH o o o p p W
P
W >H
a) P C3C
P td
CO p p II p rH
i--1 so wP W
P to
d CO o idj H
> a) rf! w EH p II
Q CM
p wp p pQ 2p
to
H a) SM
>p rfl a)
P P II
Lr_O
Hill and Griffith Company Material Safely Data Sheet
Mhy be userftaaKnpiyrvithOSHA's Hazard Comnmnication Standard, 29 CFR1910.1200. Standard must be consulted for spccificrcquixemciits.
N.A "-NOTAPPLICABLE
N.E. = NOT ESTABLISHED
I. PRODUCT IDENTIFICATION
PROD!fCT NAME (s): EZ Dry Core and Mold Coating
EMERGENCY
Manufacturer The Hill & Grifiuh Co.
TELEPHONE: (800) 424-9300
Address:
1262 State Avenue
Call Chcmircc
Cincinnati, Ohio 45204
Telephone:
(513)921-1075
Fax: (513)921-9180
II. HAZARDOUS MATERIAL IDENTIFICATION SYSTEM *
CATEGORY Flammability
RATING 2
Health
I
Reactivity
o
Personal Protection
H
These ratingsate based on NFPAregulaljccts
LEGEND
2"Moderate Hazard
l=SIsght Hazard
O-Minimal Hazard H-Spladt Goggles. Gloves, Apron, vapor Respirator
HI. HAZARDOUS INGREDIENTS
HAZARDOUS INGREDIENTS
CAS.NO.
ACGIH THRESHOLD %
LIMIT VALUE
RANGE
OSHA PERMISSIBLE EXPOSURE LIMIT
Aliphatic Petroleum 8052-41-3
100 ppm or 525 mg/m3 40-50
100 ppm or 525 mg/m3
Distillate
Graphite
7782-42-5
2 mg/m3
30-40
ISmppcf
l-Hydroxetbyl-2-Tall 61791-39-7
NE
0-5 NE
Chi
This material contains crystalline silica. The International Ageiicy for Research on Cancer (IARC ) Monograph Silica. Some
Silicates and Organic Fibres (Volume 68,1997) has determined that crystalline silica in the form ofquartz or cristobalire from
occupational exposures, ifinhaled, is carcinogenic to humans (IARC Group 1). Prolonged inhalation of silica dust may result in
silicosis, a progressive, disabling, and sometimes fatal, lung disease. Avoid creating dusty conditions and use a NIOSH/MSHA
approved dost respirator when Threshold limit Values (TLVs) may be exceeded
HUNTED IN U.S.A.
A W
Product Name: EZ Dry Core and Mold Coating
IV. PHYSICAL/GHEM1CAL PROPERTIES
Appearance and Odor: Silver-black paste with petroleum aliphatic odor.
Water Solubility: Negligible.
Melting Poiitt(Tr): NA
Boiling RangeCF): 305
Specific Gravity(water=]): 1.08
Vapor PressurefmmHg): 1.5
Percent Volatile By Weight: 40-50
Vapor Density(Aii=i); 3.9 TPQ: NA
Evaporation RateCButylAcetate=l): NE R.Q; NA
Page 2
V. FIRE AND EXPLOSION INFORMATION
Flash Point(C.O.C.)(F): 141
Auto-Ignition TemperatareCT); 450-500
Flammable Limits: LEL: 0.8
UEL: NA
Extinguishing Media: Carbon Dioxide, dry chemical, foam, or water fog.
Unusual Fire or Explosion Hazards: High heat may cause spontaneous combustion.
Special Fire-Fighting Procedures: Use full facepiece with sclf-containedbreathmg apparatus when fighting fires near this product
VI. CHEMICAL REACTIVITY INFORMATION
Conditions Contributing to Instability; None. Incompatible Materials: Strong acids or oxidizers. Conditions to Avoid: Storage near extreme heat open flames, or electrical arcs. Hazardous Decomposition Products: Carbon monoxide and water vapor. May produce oxides of sulfur and nitrogen. PRINTED IN U.SA.
Product Name: EZ Dry Core andMold Coating V. HEALTH HAZARDS A. Summary/Risks
Page 3
Signs and Symptoms >s$ Overexposure: Overexposure could result in skin irritation and chapping. Inhalation ofvapors may cause headache and nausea.
Medical Conditions Generally Aggravated by Exposure: May aggravate pre-existing medical conditions. Primary Routed) ofEntry: Skin contact and inhalation, Target Organs: Eyes. lungs, and skin. Acute Health Effect: Overexposure could result in respiratory tracrand mild skin irritations that are reversible. Chronic HealthEffect: Overexposure could resuli in respiratory tract and mild sing irritations that are irreversible. Carcinogenicity: Seepage I. Notes to Physician: None.
VII. HEALTH HAZARDS B. First Aid/Emergency Procedures
Inhalation: Ifovercome, immediately remove from exposure and seek medical attention. Skin Contact/Absorption: Wash skin thoroughly with soap and water. Ifirritation develops, seek medical attention. Eye Contact: Flush with dear flowing water for at least 15 minutes. If irritation persists, seek medical attention. Ingestion: ifingested, DO NOT inducevomiting; call a physician immediately.
VIA. SPILL, LEAK AND WASTE DISPOSAL PROCEDURES
Procedures for clean-up of spills/leaks: Stop spill as soon as possible. Scoop up or clean up using best maam possible. Water may be used to clean area. Notify proper authorities ifthe need exists.
Waste Disposal: Waste generated during application, demolition, breakage or spillage rosy be hazardous wastes as defined by RCRA (40 CFRpan 261). Place waste and spillage in closed containers. Dispose ofin approved landfill in accordance with federal, state and local regulations.
PRINTED IN THE U.S.A.
Product Name: EZ Dry Core and Mold Coating
Page 4
IX PROTECTION AND CONTROL INFORMATION
Hygienic Ptacticcs: Minimize breathing vapors, mists, fames or dusts. Avoid prolonged or repeated contact with skin. Remove contaminated clothes, laundfcr before reuse. Remove contaminated shoes; clean before reuse.
Ventilation Requirements: Provide ventilation sufficient to prevent exceeding recommended exposure limits. Respiratory Protection: Use NIOSH approved organic cartridge Type 7 respirator for vapors and/or a fine paniculate filter for
dusts, if necessary. Eye Protection: Use safety glasses, splash goggles, or face shield when eye contact may occur. Protective Gloves: Use chemical-resistant gloves, if needed, to avoid prolonged or repeated skin contact Other Clothing and Equipment As required to prevent contact. Engineering Controls/Work Practices: Keep containers and storage containers closed when not in use. Special Considerations for Repair/Maimenance of Contaminated Equipment: Provide adequate respiratory, eye and skin
protection.
X. PRECAUTIONS FOR SAFE HANDLING AND USE
Storage Segregation: Always segregate materials by major hazard class. Special Handling/Storage: Do not transfer contents to tmlabclcd container^). Other: Comply with all federal, state and local regulations.
XI. DOT SHIPPING REQUIREMENTS
Shipping Namefs): >119 gallons Petroleum Distillates, N.O.S., Combustible Liquid, UN 1268, PG III <119 gallons Compound, Thermal Insulating
Date Prepared: 12/16/97 Prepared by: Lori R. Yeager
Supersedes: 10/01/93
Print Date: 12/16/97
Tide: Corporate Government Regulatory Manager
As ofthe date ofpreparation ofthis document, the forgoing information is believed to be accurate and is provided in good faith to comply with applicable federal mid state Iawfs). However, no warranty or representation with respect to such information is intended or given.
PRINTED INU.S.A.
*
CO T--l o CO 'Cf
T! >i CO o lO o O o
r- 0 4->
ro Ti -H
P -P
co P
m *
P0
XP
LO w a
X--1
CO
p =H=
O CM CM CM LO
LO >H fid 2
P CO
pooooOooo
o o LO ro o O iH O
p o O' E-- O'
CO o P CM
CO H CM
^OO
>i
p
ro
o
ooOOO
a
P
P
P CO >H >H >H
>H >H >H >H
o
S
EH P p P P p P P P
o n
p
p
p
m p
PQ P
m
p
PQ P
2 Eh
m P
pq
P
fid H
o h
rH CO 2 -x PQ PQ pq PQ PQ pq pq fid
to fid p co p P p P P P P H
o P PQ
--l p p
=8= LO P
p
a
o CO H
p
X >H . H p l--1 p 0 CM 2
LO
2
LO
P P
0 O
o 5 LO >H
CO CM
p p
w p
=8= O
'S--'
CO
0
p
M
p
H
> 0
WP
=#= =H=
p
p
CM
'M1
CO
< PQ
P 2
P
o
wO
CO LO CO
-
eg fid
=8=
P
0
o o
w 2
CO
Eh H
*P--' pq
o to
p
\
tr>
o
H O P O =#= p ffl CO M EH o o
O
t--1
Oo 1 p
o CM
p
to H LO CO W rH =8= H
p w CM s
P
cn a EH fit1 p M p P Eh
to rH
H
p
M K
S
fid 2
CM
rfj
M 0
P
0
P
CO
LO
T-1
u ra
P
H
CO
H 2
p
M
fid Eh
P Eh
P
x--1 (Y] H M w pq Eh fid P
P 0 P g o 2 fid IS Q
P
TS
0
p aJ
M -H
p
d
p
t? p
M0
0p
p r- r" rH o CM iO CM LO
o ro CO o CO
to r~ o
!>i
a o rH CM CM CM CM CM LO
ro
pp
P -H
S CM CM CM CM CM CM CM CM o rH rH rH rH rH rH rH x--
Ch -P o rH rH rH rH c--1 \--1 i--1 x--
o -U P
P
M0
&> tr* o o o o o o o o
PM
0P
r. /-M
p/v*
rn
rH /--\
rH r*\
rH r-\
rH c--*
rH
rH r->
rH r-\
rH r*\
x--1 O
o o p p
K
P W >H fid pp p fd
CO p
HH P r--1
rH
Po wP M PQ w
P3
CO O w>
fid
EH p
fid II
p CM rH
Hp
P
CQ Sp
pm
M rf! M > M-t
fid 0 P
p II p tO
Gti
:'
i*
& u m imn a jnl *j) Bun-tun
; (Approved by U. S. Department ofLabor. "Essen tio/ly Similar" to Form LSB-OOS-4) '
I. t
FSMG-72-1
I-T/A is Hot Applicable
FOR METAL CASTING SUPPLIES UKK is Unknown
SECTION 1 - SOURCE AND NOMENCLATURE
FACTUREKS NAME
EMERGENCY YEUPHONS NO,
--------
.e Hill & Griffith Company
Area Code 5T3
Number 921--107!
CSS (NUMnKR, STHKer, CITY. *TATB, 2IP CODr)
CODE NO., YRAOE NAME, SYNONYMS
62 State Avenue
SCAUNAMCS AND SYNONYMS
Cincinnati, Ohio
troleum Pitch
>DED USES (check arpropriats onbs):
I;5204
CHEMICAL FAMILY
Hydrocarbon
Ho. 1 Ebony Core Compound (Pitch)
MOLECULAR FORMULA
Complex
Binders (Curing)
Binders (Non-Curing) X
Castables anti Exothermic* '
Additives X
Others
Partings
Facings X
Metal Additives - \...
:r)AU or INGREDIENT It* PRODUCT: IN CONTAlMBfr BBPOAB US):
SECTION 2 - HAZARDOUS INGREDIENTS
... - ---------
E5TABLI5HSO
OSHA STANDARD TJLV (units) ETC.
ORAL.
^*^50
(SKIN
t-c,, INHALATION
specie * Tssret
Petroleum Pitch. Pulverized
^nk
*
(TLV - 100 ppm) - see boiling point Section 3
for Aromatic Hydrocarbon)
' >d)T)6nal [only durias use):
............
Ttfp \5rrrHuv-g J
Ho safe limits have been estat Lished
. `*
6See.Sect ion ______ -
*
63ee Section
See Sect ion 6
,RKS: (can r useo to state that entirc product i ho-hasaboous i*r 0y^DapiMmoN):
SECTION 3 - PHYSICAL DATA
ENTIRE PRODUCT
OR INGREDIENT (namb)
I Point (F.) 3 Point (F.) (Give Method) c Gravity (Water =1)
Over 850F
300--310F TteB 1-30
lity in Water (Product)
Jnits)
nil
...
ranee (Product) Black powder___
Product)
*
. . .with slight aromatic odor
.
Vapor Pressure (rnmHrj) less than 1
Vapor Density (Air = 1) above 1
Evaporation Rate { 0
.
"I)
Volatile
% Vol.
mrFTdF
% Wc.
.. .
Other:
: v
SECTION 4 - FIRE AND EXPLOSION HAZARD DATA `
POINT
50Q
0p
O/-
FLAMMABLE EXPLOSIVE LIMITS
dused) Cleveland^ Open Cup
Name:
xTiecunHma wenu: CO^ -- Water fog, --dry chemicals
>
,L nee ncnneerRoaBU: yater or foam may cause frothing and spread fire.
LOWER
35 ng/liter
UFPEH
If excessive fume
moke Is encountered* wear self contained respiratory equip.' (USBM Canister Unit)
AU AftCi eXFLOSIOH HA3AH05: Dust explosion possible-
* ... . :
Flammable limit greater than -OL oz/cu.ft. dust in air.
ssm
mm CMSSfes
Corporate Office 10SS Summer Street Gneitmatf, Ohio45204 i-800-543-0425 513-921-1075 Sax513-921-9180
WESTERN BENTONITE
Hill and Griffith offers the finest available grades ofWESTERN BENTONITE to meet the requirements offoundries producing steel and gray, ductile or malleable iron castings.
WESTERN BENTONITES provide foundry sand systems with high hot and green strength properties. Works well with fine or coarse grain synthetic sands.
Higher dry and hot strengths minimize sand erosion
Imparts higher green strengths at lower moisture content to maximize mold and reduce gas or pinhole defects
permeability
Permits use of finer sands which produce superior casting finish.
Typical Chemical Analysis
SiOz AI2O3
Fe^ HO CaO K20 Na20 T1O2 Trace Elements Moisture Uncorabined pH Value
60.00 - 62.00 20.00 - 23.00 3.00 - 4.00 1.50 - 3.00 0.50- 1.50 0.40 - 0.50 2.00 - 2.70 2.50 Max. 3.50 Max. 12.00 Max. 8.00 Min.
EB11 and Griffith WESTERN BENTONITE can be used in combination with Southern Bentonite to improve the versatility ofthe sand systems and achieve highest possible green strengths with somewhat lower dty and hot strengths.
Blend WESTERN BENTONITE with Fire Clay to develop maximum hot strength available from conventional Foundry Bonding Clays.
Hill and Griffith can provide different grades ofWESTERN BENTONITE to meet specific foundry methods using dry or slurry applications for both mechanized and non-mechanized production.
WESTERN BENTONITE is available in the following grades: Granular Grade - Dustless, Pulverized 200 Mesh Grade - Foundry Grade, *Steel Grade Bentonite Specification Sheet available on request but is not available in Hill and Griffith premixes.
0392
00020
a
BONDING CLAYS
bulletin
1-1
WESTERN BENTONITE
Hill and Griffith offers the finest available grades of Western Bentonite to meet the requirements of foundries producing steel and gray, ductile or malleable iron castings.
Western Bentonites provide foundry sand systems with high hot and green strength properties. Works well with fine or coarse grain synthetic sands.
Higher dry and hot strengths minimize sand erosion Imparts higher green strengths at lower moisture content to maximize mold
permeability and reduce gas or pinhole defects. Permits use of finer sands which produce superior casting finish.
typical chemical analysis
Si02 ai2o3 Fe203 MoO CaO
K,0 Na20 TiO, Trace Elements Moisture Uncombined pH Value
I
1 I I
| I 1 I I
60.00 - 62.00 20.00 - 23.00
3.00- 4.00 1.50- 3.00
0.50- 1.50 0.40- 0.50 2.00- 2.70 2.50 Max.
3.50 Max. 12.00 Max. 8.00 Min.
Hill and Griffith Western Bentonite can be used in combination with Southern Bentonite to improve the versatility of the sand systems and achieve highest possible green strengths with somewhat lower dry and hot strengths.
Blend Western Bentonite with Fire Clay to develop maximum hot strength available from conventional Foundry Bonding Clays.
Hill and Griffith can provide different grades of Western Bentonite to meet specific foundry methods using dry or slurry applications for both mechanized and nonmechanized production.
REV. 880
The HILL and GRIFFITH Co. Cincinnati Birmingham Chicago Burbank, Ohio
serving the CAST METAL INDUSTRY since 1896
, . :..MM fcKJAl ai-tll lJ aba:
/ ... >
-- - J "
(Approved by U. S. Department of Labor. "Essentially Simik r" to Form LSB-OOS-4J
n F^G-72-1 UNK is unknown N/A is not'applicable
FOR METAL CASTING SUPPIJES .
MrPA 704 DeSIGMAT
uf*acturers name
SECTION 1 - SOURCE AND NOMENCLATURE
EMERGENCY TELEPHONE NO.
The Hill &: Griffith Comoanv REGS- (NUMRfiR, STREET, CITY, STATE, X*** CODE)
1262 State Avenue, Cincinnati, Ohio k520k
MJCAL NAME AND SYNONYMS
...
CHEMICAL FAMILY
Area Code *5"|
Number Qpi _] fjT^
'CODE NO., TRADE NAME, SYNONYMS - '
SLIK BOX
MOLE Cl! LA IF FORMULA
Proprietary mixture-Stearic acid. Iron oxide,' .
'
:nded uses [wkk Arraowi.w ob): an'd hydrated Amorphous silica
_________
Comnlpt
Binders (Curing)
Binders (Non-Curing)
Additives
Partings X
- Facings
' . Metat Additives
Castables and Exothermics
'Others- Release Agent
y
"ERIAL. OR INGREDIENT IN PRODUCT: {as in container before usk): ,
HONE
- -
.
SECTION 2 - HAZARDOUS INGREDIENTS
ESTABLISHED
OSHA STANDARD TLV (units) ETC.
ORAL
*-=>>
SKIN
.
......
INHALATION
SPECIES TESTcD
**
A' ONAl (only DURING US.b}:
HONE
.
.
'
5
ARKS: OSHA{can se used to state that sntjrs'product is non*ha2ardoUs ay
definition):
Treat as nuisance dust with permissible exposure l-imi-hs snggpR-hPd 90 m.-p.t>.c.f.
SECTION $ - PHYSICAL DATA
ENTIRE PRODUCT
OR INOREDIENT (hams)
'
ng Point' (F.)
>- 650F
Eng Point (F.) (Give P/lethod)
fic: Gravity (Water = 1)
app. 120-15C F app. 1
bility in Water (Product)
> Units)
Negligible
iarance (Product) Pink powder
- (product)
mild fatty acid
'
"
-
----- --------
Vapor Pressure (tnmHg) Vapor Density (Air =1)-
H/A H/A
Evaporation Rate ( negligible = 1)
Volatile
% Vol. negligi"b]3fcWr..
at 70 F.
Other:
. *
SECTION 4 - FIRE AND EXPLOSION HAZARD DATA
;h point
TM op"
hod Used)
Open Cup
NGUISHING MEDIA!
Foam,
r* FIRE FIGHTING PROCEQOHE3'.
dry powder
or water
fog
Do not use. water stream- under pressure.
FLAMMABLE EXPLOSIVE LIMITS *
Name:
LOWER
UHK
Upper
Uffi
:: OBSOLETE
normal hazard only from organic dusts.
tc DEWtSK [Ufc>V EL Or PRODUCT):
IRRITANT-SKIN, ever, BE3PIRATOly
ifrlK
4
JMS oyr ORl'tlON
V
Inhalation , Eye
NAME ROUTS
NAME TOXIC INGREDIENTS
Product is considered non toxic
3SYMPTOMS OF OVEREXPOSURE: {CHEMlCAb NAMC AND COffRESf-ONOIrtC SYMPTOM J
Coughing, sneezing
oic gPFects: UNK
iRGHNCY AND FIRST AID PROCEDURES:
inhaiafjnn: ffemoV|g from area into fresh air
Ingestion: Consult Physician
Skin Contact: soap & water wash"
Other:
Eye Contact: flush, with copius quantities of water-consult Physician
~
~:
~
SECTION 6 - REACTIVITY DATA
.BIUTY {check oNitJ CONDITIONSTO AVOID:
Stable X
. -
;
Unstable
*
OMPATA3ILITY [matsaiaus to avoid):
NONE
''
:aroous DECOMPOSITION PRODUCTS:
Incomplete combustion may yield -carbon monoxide & carbon dioxide
:ARDOUS POLYMERISATION (chick one}: IDITIONS TO'AVOID:
Will Not Occur".
Might Occur,
SECTION 7 - SPILL OR LEAK PROCEDURES
Pi, .1 OS TAKEN IF MATERIAL IS RELEASED OH SPILLED;. \\
~
Dike spill area with inert material such as sand.
TE DISPOSAL METHOD;
Remove to approved waste disposal area.
. SECTION S - SPECIAL PROTECTION INFORMATION
tilatjon requirements:
,t Exhaust Recommended
Ji-nicai Exhaust Recommended h>! TEFC motors recommended r protective Equipment None required
PROTECTIVE EQUIPMENT (s^cciry
Ey Goggles-safetv type recommended Gloves n6t normally required Respiratory NIOSH aunrOVed dust masks rennmm^nri^-
SECTION 9 - SPECIAL PRECAUTIONS
;aut>ons to ae taken in handling and storage:
*
Store in cool dry area. Keep container covered to protect from-open flame or sparks.
zst, precautions:
NONE REQUIRED.
information contained herein is correct to the best of our knowledge. The recommendations or suggestions contained in this data sheet are rr
s guarantee or representation as to results. We suggest that you evaluate these recgmmijgdatran^^P^ggestions in your own laboratory p is.. Our responsibility for claims arising from breach of warranty, negligence, or otfiew'fSe is5'fimuemto the purchase price of the mate
fo'cm to use any patent owned by anyone is not to be inferred from any statement contained herein. WITH REGARD TO THE MATER!
LER MAKES NO WARRANTY OF ANYK1ND WHATEVER, EXPRESS OR IMPLIED, AND ALL IMPLIED WARRANTIES OF MERCHA '-'TV AND' FITNESS FOR A PARTICLfLAFf^PURPQSE ARE HEREBY DISCLAIMED BY SELLER. -
""7/13/83
signature:
A-<.
WIuLIM M. BALL, III
MANAGER OF TECHNICAL SERVICE'
Serving the CAST METAL INDUSTRY Since 1896
'1
of,71 FSMG-72-1
(Approved by U. S. Department of Labor. "Essentially Similar" to Form LSB-OOS-4}
FOR METAL CASTING SUPPLIES
N/A - Not applicable
UNK - Unknown
SECTION 1 - SOURCE AND NOMENCLATURE
ANUFACTURERS NAME
EMERGENCY TELEPHONE NO.
: Hie Hill and Griffith Company
ODRESS (number, STREET, CITY, STATE, ZIP CODS)
1262 State Avenue,. Cincinnati, Ohio'
45204
Area Code
513 Number 921--1075
CODE NO., TRADE NAME, SYNONYMS
Zircon #1 Core & Mold Wash
roprietory - zrrconxytn^ixicace, oxay, jaisl tol, wetHnp- and, anti-foam agents & -water
TENDED USES (check appropriate ohks):
Complex
Binders (Curing)
Binders (Non-Curing)
Additives'
Partings
, Facings
, Metal Additives
Castables and Exothermics
Others Reft3CtOry Coating
ATERIAL OR INGREDIENT IN PRODUCT: -- (as in container berors dm):
' .
--
-
:
:
SECTION 2 - HAZARDOUS INGREDIENTS
ESTABLISHED OSI^A.STANDARD
t-D30
TLV) (units) ETC. --p
ORAL
/ S
1.. t-
f'
SKIN
t.c3a INHALATION
--
1:
/
! ~
/
7
I / i /.
-- 'IONAL (only DURING USe):. Product shipped in plastic or putty form.
After use will be converted to- dry powder
form.
Consider refractories in same
classification as nuisance dust.
' lOng/Mt
^A___________________L
/ ____
/.
S' /
/
/
,/S. \
_______________
SPECIES TESTED
:MARKS: ` (can
useq to state that bnTwe product is non-hazarpouj by OSHA obhihitionJ:
SECTION 3 - PHYSICAL DATA
-
iling Point (F.) Jting Point (F.) (Give Method)
ENTIRE PRODUCT
212^
OH INGREDIENT (hams)
Water 32F - Water
scific Gravity (Water =1)
>1
ability in Water (Product),
-
ve units) pearance (Product) or (Product)
100% water miscible .
White/ Soft pUttV
Earthy/sweet
Vapor Pressure (mmHg)
N/A
Vapor Density (Air -1)
N/A
Evaporation Rate (
Volatile
NeeliaifeM W 7 0F
Other:
7 N/A
%Wt.
SECTION 4 - FIRE AND EXPLOSION HAZARD DATA
POINT
N/A
O
:thod Used)
F'
O
C~_jName; Entire product
FLAHMASLS EXPL051VS UMITS
LOWER
UPPER
UNKUNK
:TMouisHiNo media Hone required in existing form.
:-w. .-.'FIRS FIGHTING PROCEDURES:
lone required in existing form.
____________________________ ___________
JSUAL Fine AND EXPLOSION HAZARDS:
'one required in existing form.
'TOXIC DEGREE iLJSVBl. OP* PRODUCT);
T5SK t
VRltS?CPAC
ROUTES OF
ABSORBTION
).
Inhalation
"'
""
NAME ROUTE
m < ri4.Mn LJf-\ t M
IRRITAMT-SKIN, EYfi, RESPIRATORY
Possible eye, skin & respiratory
NAME TOXIC mCHEDIENTS
Possible fumes from acrylic resin
POSSIBLE SYMPTOMS OF OVEREXPOSURE: (CHEMICAL NAME A NO COftB6fONOING SYMPTOM*)
Harmful if ingested
-----
CHRONIC effects:
UNK
EMERGENCy AND FIRST AID PROCEDURES:
' inhalation: Remove from exposure area to feesh airJf)gest~ n. Gall physician,
siftn r.nnTant:. Soap and water wash .
other:
Eye Contact: Flush with copius' quantities of -water - call physician
' SECTION 6 - REACTIVITY DATA
STABILITV {check one) CONDITIONS TO AVOID:
Stable X
Unstable____________________
_________________________________________________________________________ _
INCOMPATABILITY Imatcdmu to avoid):
In case of fire, in or near storage area steam generation is possible.
HAZARDOUS DECOMPOSITION PRODUCTS:
UNK - Incomplete combustion might yield carbon monoxide.
HAZARDOUS POtYMERRATION IciisM oits|:
Toconditions
avoid;
V
Will Not Occur _ -ft-
Might Occur
-- SECTION 7 -SPILL OR LEAK PROCEDURES
SIBPSTO BE TAKEN IF MATERIAL Is RELEASSD OR SPILLED;
Product is shipped in plastic form. If spill occurs in use form (cut hack -with water to slurry form) dike spill area with inert material such as sand.
waste: disposal, method:
Remove- waste collection to approved land fill.
SECTION 8 - SPECIAL PROTECTION INFORMATION
tVENTlLATION REQUIREMENTS:
PROTECTIVE EQUIPMENT (specrpv Types);
i_otai Exhaust
Reccmuiended.
Eye Safety, goggles or face-shield
Rjtechanicai Exhaust Recornnended for pourofi & shake out Gloves Rubber or neoprene reccomended.
------ ------------------------- :
I
Other Protective Equipment None required.
areasr -R-e--s-p-ir-a-t-o-r-y---J-N--iU--S--t-i--a--p-p--r-o--v-e--d---i--n p*--ou--r-o--t-t---&----s-h--a--k-e-- aoruetas
SECTION 9-SPECIAL PRECAUTIONS
-flETCAl/TTONS TO BS TAKEN IN Ha^OUNG AND STORAGE-
I>3antain storage area above freezing.
THEf? precautions:
None required.
the information contained herein is correct to the best of our knowledge. The recommendations or suggestions contained in this datasheet an* mat
without guarantee or representation as to results. We suggest that you evaluate these recommendations and suggestions in your own laboratr : i
so use. Our responsibility for c!aims"'arising from breach of warranty, negligence, or otherwise'is limited to the purchase price of the n,. .ari;
-feedom to use any patent owned by anyone is not to be inferred from any statement contained herein. WITH REGARD TO THE MATERIA
ELLER MAKES NO WARRANTY OF ANY KIND WHATEVER, EXPRESS OR IMPLIED, AND ALL IMPLIED WARRANTIES OF MERCHAN'
ABILITY AND FITNESS FOR A PARTICULAR PURPOSE ARE HEREBY DISCLAIMED BY SELLER.________
*te:: ^SIGNATURE
title:
-----------
722/81
Manager of Technical Services
m Fr`RG-72-1
(Approved by U. S. Department of Labor. "Essentially Similar" to Form LSB-00S-4)
' FOR METAL CASTING SUPPLIES
M/A - Not applicable
UUK - Unknown
SECTION 1 - SOURCE AND NOMENCLATURE
'tUFACTURERS NAME
EMERGENCY TELEPHONE NO.
Che- Hill" and-Griffith Company
>RSS (NUMBKR, STBeer, CITY, STATS* *P CODE]
.262 State Avenue, Cincinnati, Ohio
45204 -
.
Area Code
513 Number 921-1075
CODE NO.* TRADE NAME* SYNONYMS
Zircon #1 Corg & Mold Wash
.f:emitiictavi- .ntaympeea.ndorsi:yoholo,ph.rywihesetotHry-np-;
z,trcormjm_sxxxca.ce, uxay, and anti-roam agents & water
~NDED USES (check arpropriath ones):
MOLECULAR. FORMULA
Complex
Binders (Curing)
Binders (Non-Curing)
Additives
Partings
' Facings
Metal Additives
Castables and Exothermics
Others Refractory Coating
rEBIAU OR INGREDIENT IN PRODUCT: (as III CONTAINBR Bcrone usa): <
i
SECTION 2 - HAZARDOUS INGREDIENTS
ESTABLISHED OSHA- STANDARD TLV (units) ETC.
ORAL
SKIN
lc30 INHALATION
SPECIES TESTED
At;
UAL (only during use);
roduct shipped in plastic or putty form.-
ter use will be converted to- dry powder
orm. Consider refractories in same
lassification as nuisance dust.-
lOng/M-1
-
ARKS: (cam be used to STATE THAT eMTIRE product is non-hazardous by OSHA oepinition):
SECTION 3 - PHYSICAL DATA
ig Point (F.) ng Point (F.) (Give Method)
ENTIRE PRODUCT
?T7F
DR INGREDIENT (name)
Water 32F - Water
fie Gravity (Water =1) lility in Water (Product),
>1 ......... -
units)
1007, water miscible
arance (Product)
(product)
White/ SOft PUttV Earthy/ sweet
Vapor Pressure (mmHg)
N/A.
Vapor Density (Air = 1)
N/A
.Evaporation Rate {
= 1)
Volatile
% Vol.
Neslieible (3 70F
Other:
Jij/A %Wt.
*
SECTION 4 - FIRE AND EXPLOSION HAZARD DATA
S~PO'NT
d)'
]>{/A
qf' ______ Oq
FLAMMABLE EXPLOSIVE LIMITS
Name: Entire product
LOWER
LINK
.GUtSHINO media: None required in existing form._____________ _
IAL FIRE FIGHTING PROCEDURES:
ne required in existing form.
'AD p"PL?C[qnh AMI lie
UPPER
UNK
UAL FIRE AND EXPLOSION HAZARDS!
ne required in existing form.
Harmful if ingested
.HRONIC effects: [JMC
IMERGENCr AND FIRST AfO PROCEDURES:
_.
Inhalation: Ranove from exposure area to fresh aSxlhgaem: Gall physician.
Skin Contact: Soap and, water "Wash
Other:
Eye contact: Flush with copius quantities of water call physician______
SECTION 6 - REACTIVITY DATA :
TABurr (cmsck ohb) conditions to avoid:
Stable X
*
.
**
Unstable____________________ _________ `______________________ ^_________ '
___________;_________________~
^COMPATABIUTY (MATeaiAts to avoid}:
--.
Cn case of fire in or near storage area steam generation is possible,
AZAROOUS DECOMPOSITION PRODUCTS:
JM. - Incomplete combustion might yield carbon monoxide. ~ ' ____________
AZARDOUS POLYMERIZATION t=K orm): ONDITIONS TO AVOID:
Will Not Occur X Will NOT UCCUF----------------------------------------------------------
Might Occur
SECTION 7 - SPILL OR LEAK PROCEDURES
rsrps TO BE TAKEN.iF MATERIAL. IS RELEASED OR SPILLED! Product is shipped in plastic form. If spill occurs in use form (cut back with water
:o slurry form) dike spill area with inert material such as sand.
XSTE DISPOSAL method:
-.enove- waste collection to approved land fill.
\ SECTION 8 -SPECIAL'PROTECTION INFORMATION
:ntilatcon requirements:
tcai Exhaust
Recuitiiended.
IreoTBCTIve EQUIPMENT (srccirT Trpcs): jEye Safety goggles or face' shield
^hanicai Exhaust Recommended for pouroff & shake out stoves Rubber or neoprene recarmended.
ecial '
her Protective Equipment
None required.
aitijcts. jRespiratory iMiOSti approved in pourotf 6c shake but - * r-------------------------- areas*:
SECTION 9 - SPECIAL PRECAUTIONS
ECAUTIQNS TO BE TAKEN IN HANDLING AND STORAGE:
sintain storage area above freezing.
3ne required.
OBhk
is information contained herein is correct to the best of our knowledge. The recommendations or suggestions contained in this data sheet are mat thout guarantee or representation as to results. We suggest that you evaluate these recommendations and suggestions in your own laborau 'it
use. Our responsibility far claims arising from breach of warranty, negligence, or otherwise is limited to the purchase price of the .
it
eedom to use any patent owned by anyone is not to be inferred from any statement contained herein. WITH-REGARD TO THE MATE: iAl :LLER MAKES NO WARRANTY OF ANY KIND WHATEVER, EXPRESS QR'IMPLIED, AND ALL IMPLIED WARRANTIES OF MERCH AN
ILITY AND FJTNESS FOR A PARTICULAR PURPOSE AREHEREBLY DISCLAIMED BY SELLER.__________
`
5/28/85
signature:
/
> (
STAFF CHEMIST
Victor S. LaFay
\
HATEK1AL SAFETY DAT& SHEET
May be used to comply with GSHA's Hazard CommunicatlVn standard, 29 CFR 1910.1200. Standard must be consulted for speciiic requirements.
N.A. = NOT APPLICABLE
N.E. = NOT ESTABLISHED
I. PRODUCT IDENTIFICATION
PRODUCT NAME (s):#l Zircon Core & Mold Wash
Manufacturer: Address:
Hill and Griffith Co. 1262 State Avenue Cincinnati, Ohio 45204
TELEPHONE: (800) 543-0425 Hours: 8:00 A. M. - 5:00 P. 11. Fax: 513-921-9180
II. HAZARDOUS MATERIAL IDENTIFICATION SYSTEM
CATEGORY Flammability Health Reactivity Personal Protection
RATING 0 1 0 B
LEGEND 0=llinimal Hazara l=Slight Hazard 0=Minimal Hazard B=Glasses and Cloves
III. HAZARDOUS INGREDIENTS
ACGIH THRESHOLD
%
HAZARDOUS INGREDIENTS CAS. NO ' " LIMIT VALUE
RANGE
OSHA PERMISSABLE EXPOSURE LIMIT
Zircon
7440-67-2
5 mg/m3
70-80
5 mg/m3
* As respirable dust @ This material contains Silicon Dioxide in some form. IaRC Monographs on the evaluation of the Carcinogenic Risk of Chemicals to Humans (Volume 42, 1987) concludes that there is sufficient evidence for the carcinogenicity of crystalline silica to experimental animals, and that there is limited evidence of the,carcinogenicity of crystalline silica to humans. Classified by the IARC as 2A PRINTED IN U.S.A.
FOR CHEMICAL EMERGENCY, SPILL, LEAK, EXPOSURE OR ACCIDENT CALL CHEMTREC DAY OR NIGHT AT 1-800-424-9300
f <1 Product Name:#l Zircon Core & Mold Wash
Page 2
IV. PHYSICAL./CHEMICAL PROPERTIES
Appearance and Odor: White-soit putty. Earthy-sweet smell.
Water Solubility: 100% misc
Melting Point(oF): 32
Boiling Range<oF): 212
Specific Gravity(water=l):
Vapor Pressure<mmHg): na
Percent Volatile By Weight: neg
Vapor Density(Air=l): na TPQ: na
Evaporation Rate(Butyl Acetate=l): na RQ: na
V. FIRE AND EXPLOSION INFORMATION
Flash Point(C.Q.C.)(oF): na
Auto-Ignition Temperature(oF): na
Flammable Limits:
LEL na
UEL na
Extinguishing Media: Product is considered non combustible.
Unusual Fire or Explosion Hazards: None
Special Fire-Fighting Procedures: Use lull facepiece with self contained breathing apparatus when fighting fires near this product
VI. CHEMICAL REACTIVITY INFORMATION
Conditions Contributing to Instability: None.
Incompatible Materials: N. E.
Conditions to Avoid: Storage in extreme cold.
Hazardous Decomposition Products: Carbon monoxide and water vapor. May produce oxides of sulfur & nitrogen. PRINTED IN U.S. A.
Product Name: #1 Zircon Core & Hold Wash
VII. HEALTH HAZARDS
A. Summary/Risks
-PAGE 3
Signs and Symptons of Overexposure: Overexposure to the skin could result in minor skin irritations .including redness or itching.
Medical Conditions Generally Aggravated by Exposure: May aggravate pre existing medical conditions
Primary Route(s) of Entry: Skin Contact.
Target Organs: Eyes and Skin.
Acute Health Effect: Overexposure could result in mild skin irritations that are reversible. Chronic Health Effect: e
Carcinogenicity: This product is not considered a carcinogen by the ACGIH, NTP, I ARC, or OSHA. Notes to Physician: None.
VII. HEALTH HAZARDS B. FIRST AID/EMERGENCY PROCEDURES
Inhalation: If overcome, immediately remove from exposure and seek medical attention"
Skin Contact/Absorption: Wash skin thoroughly with soap and water. irritation develops, seek medical attention
If
Eye Contact: Flush with clear flowing water for at least 15 minutes. If irritation persists, seek medical attention.
Ingestion: If ingested, DO NOT induce vomiting; call a physician immediately.
VIII. SPILL, LEAK AND WASTE DISPOSAL PROCEDURES
Procedures for clean-up of spills/leaks:on as possible. Scoop up or clea
n up using best means possible. Water may be used to
clean area. Not
ify proper authorities if the need exists.
Contain spill
Waste Disposal: Waste generated during application, demolition, breakage or
spillage are not hazardous wastes as defined by RCRA (40 CFR part 261).
Place waste and spillage in closed containers. Dispose of in approved
landfill in accordance with federal, state and local regulations.
PRINTED IN THE U.S.A.
t
Product Name: #1 Zircon Core & Mold Wash
fSp!QO:f, FTP
w't=^I
PACE -4
IX. PROTECTION AND CONTROL INFORMATION
Hygeinic Practices: Minimize breathing vapors; mists, fumes or dusts. Avoid prolonged or repeated contact with skin. Remove contaminated clothes launder before reuse. Remove contaminated shoes; clean before reuse.
Ventilation Requirements: Provide ventilation sufficient to prevent exceeding recommended exposure limits.
Respiratory Protection: respirator
Use NIOSH approved organic cartridge Type 7
Eye Protection: Use safety glasses, splash goggles or face shield when eye contact may occur
Protective Gloves: Use chemical-resistant gloves, if needed, to avoid prolonged or repeated skin contact
Other Clothing and Equipment: As required to prevent contact
Engineering Controls/Work Practices: containers closed when not in use.
Keep containers and storage
Special Considerations for Repair/Maintenance of Contaminated Equipment: Provide adequate respiratory, eye and skin protection.
X. PRECAUTIONS FOR SAFE HANDLING AND USE
Storage Segregation: Always segregate materials by major hazard class.
Special Handling/Storage: Do not transfer contents to unlabeled cont.ai.ner < s).
Other: Comply.with all federal, state and local regulations.
XI. DOT SHIPPING REQUIREMENTS Shipping Name: Paint Compounds Hazard Class: None. Identification Number: None Label(s) Required: None.
Date Prepared: 04-16-1990 Prepared by: Steve Neltner
Title : Lab Manager
As of the date of preparation of this document, the forgoing information is believed to be accurate and is provided in good faith to comply with applicable federal and state law(s). However, no warranty or representation with respect to such information is intended or given. PRINTED IN U.S.A.
1
Hill and Griffith Company Material Safety Data Sheet
May be used to comply with OSHA's Hazard Communication Standard, 29 CFR 1910.1200. Standard must be consulted for specific requirements.
N.A. = NOT APPLICABLE
N.E. = NOT ESTABLISHED
I. PRODUCT IDENTIFICATION
PRODUCT NAME (s): Zircon #1 Core Wash
Manufacturer: Address:
Telephone:
The Hill & Griffith Co. 1085 Summer Street Cincinnati, Ohio 45204 (513)921-1075
Fax:
EMERGENCY TELEPHONE: (800) 424-9300
Call Chemtrec
(513) 921-9180
II. HAZARDOUS MATERIAL IDENTIFICATION SYSTEM *
CATEGORY
RATING
Flammability
0
Health
1
Reactivity
0
Personal Protection
B
These ratings are based on NFPA regulations
LEGEND 0=Minimal Hazard l=Slight Hazard 0=Minimal Hazard B=Glasses and Gloves
III. HAZARDOUS INGREDIENTS
HAZARDOUS INGREDIENTS Zircon Inert Nuisance Dusts As respirable dust
CAS.NO. 7440-67-7 Mixture
ACGIH THRESHOLD LIMIT VALUE 5 mg/m3 10 mg/m3
% RANGE 70-80 1-5
OSHA PERMISSIBLE EXPOSURE LIMIT 5 mg/m3 15 mg/m3
This material contains crystalline silica. The International Agency for Research on Cancer (IARC ) Monograph Silica. Some Silicates and Organic Fibres (Volume 68, 1997) has determined that crystalline silica in the form ofquartz or cristobalite from occupational exposures, if inhaled, is carcinogenic to humans (IARC Group 1). Prolonged inhalation of silica dust may result in silicosis, a progressive, disabling, and sometimes fetal, lung disease. Avoid creating dusty conditions and use a NIOSHZMSHA approved dust respirator when Threshold limit Values (TLVs) may be exceeded.
PRINTED IN U.S.A.
Product Name: Zircon #1 Core Wash
Page 2
IV. PHYSICAL/CHEMICAL PROPERTIES
Appearance and Odor: White thick paste, low odor.
Water Solubility: Miscible.
Melting Point(F): 32
Boiling Range(F): 212
Specific Gravity(water=l): > 1
Vapor Pressure(mmHg): 760
Percent Volatile By Weight: NE
Vapor Density(Aii=l): NE TPQ: NA
Evaporation Rate(Butyl Acetate=l): <1 RQ: NA
V. FIRE AND EXPLOSION INFORMATION
Flash Point(C.O.C.)(F): NA
Auto-Ignition Temperature(F): NA
Flammable Limits: LEL: NA
UEL: NA
Extinguishing Media: Not applicable.
Unusual Fire or Explosion Hazards: None.
Special Fire-Fighting Procedures: Use full facepiece with self-contained breathing apparatus when fighting fires near this product.
VI. CHEMICAL REACTIVITY INFORMATION
Conditions Contributing to Instability: None. Incompatible Materials: Strong acids or oxidizers. Conditions to Avoid: None. Hazardous Decomposition Products: Possible dusts could be generated, but not likely. PRINTED IN U.S.A
Product Name: Zircon #1 Core Wash
VII. HEALTH HAZARDS A. Summary/Risks
Page 3
Signs and Symptoms of Overexposure: Eyes- irritation with redness and swelling; Skin- may irritate; Inhalation- may cause
coughing and sneezing.
Medical Conditions Generally Aggravated by Exposure: May aggravate pre-existing medical conditions.
Primary Route(s) ofEntry: Inhalation, skin contact, and ingestion.
Target Organs: Eyes, lungs, and skin.
Acute Health Effect: Overexposure could lead to skin irritations and lung or mucous membrane irritation.
Chronic Health Effect: Overexposure could lead to severe damage to skin, eyes, lungs, or mucous membranes.
Carcinogenicity: See page 1. In the report the National Toxicology Program (NTP) classified respirable crystalline silica, primarily quartz dusts occurring in industrial and occupational settings, as known to be a human carcinogen, based on sufficient evidence of carcinogenicity from studies in humans indicating a casual relationship between exposure to respirable crystalline silica dust. In addition, the American Conference of Governmental Industrial Hygienists (ACGIH) has classified crystalline' silica-quartz as an A2 Suspected Human Carcinogen.
Notes to Physician: None.
VII. HEALTH HAZARDS B. First Aid/Emergency Procedures
Inhalation: If overcome, immediately remove from exposure and seek medical attention. Skin Contact/Absorption: Wash skin thoroughly with soap and water. Ifirritation develops, seek medical attention. Eye Contact: Flush with clear flowing water for at least 15 minutes. Ifirritation persists, seek medical attention. Ingestion: Ifingested, DO NOT induce vomiting; call a physician immediately.
VIII. SPILL, LEAK AND WASTE DISPOSAL PROCEDURES
Procedures for clean-up of spills/leaks: Stop spill as soon as possible. Scoop up or clean up using best means possible. Water may be used to clean area. Notify proper authorities if the need exists.
Waste Disposal: Waste generated during application, demolition, breakage or spillage may be hazardous wastes as defined by RCRA (40 CFR part 261). Place waste and spillage in closed containers. Dispose ofin approved landfill in accordance with federal, state and local regulations.
PRINTED IN THE U.S.A.
Product Name: Zircon #1 Core Wash
Page 4
IX. PROTECTION AND CONTROL INFORMATION
Hygienic Practices: Minimize breathing vapors, mists, fiimes or dusts. Avoid prolonged or repeated contact with skin. Remove contaminated clothes, launder before reuse. Remove contaminated shoes; clean before reuse.
Ventilation Requirements: Provide ventilation sufficient to prevent exceeding recommended exposure limits. Respiratory Protection: Use NIOSH approved fine particulate respirator ifpermissible exposure limits or threshold limit values are exceeded or ifthe user deems necessary. Eye Protection: Use safety glasses, splash goggles, or face shield when eye contact may occur. Protective Gloves: Use chemical-resistant gloves, ifneeded, to avoid prolonged or repeated skin contact. Other Clothing and Equipment: As required to prevent contact. Engineering Controls/Work Practices: Keep containers and storage containers closed when not in use. Special Considerations for Repair/Maintenance of Contaminated Equipment: Provide adequate respiratory, eye and skin
protection.
X. PRECAUTIONS FOR SAFE HANDLING AND USE
Storage Segregation: Always segregate materials by major hazard class. Special Handling/Storage: Do not transfer contents to unlabeled containers). Other: Comply with all federal, state and local regulations.
XI. DOT SHIPPING REQUIREMENTS
Shipping Name(s): Any Packaging
Compound, Thermal Insulating
Date Prepared: 05/08/01 Prepared by: Lori R. Yeager
Supersedes: 11/25/97
Print Date: 05/08/01
Title: Corporate Government Regulatory Manager
As of the date ofpreparation of this document, the forgoing information is believed to be accurate and is provided in good faith to comply with applicable federal and state law(s). However, no warranty or representation with respect to such information is intended or given.
PRINTED IN U.S.A.
Serving the CAST METAL INDUSTRY Since 1896
HILL and GRIFFITH Company
Hill and Griffith Company Material Safety Data Sheet
Maybe used to comply with OSHA's Hazard Communication Standard, 29 CFR 1910.1200. Standard must be consulted for specific requirements.
N.A. = NOT APPLICABLE
N.E. = NOT ESTABLISHED
I. PRODUCT IDENTIFICATION
PRODUCT NAME (s): Concote TM 405
Manufacturer Address:
Telephone:
The Hill & Griffith Co; 1085 Summer Street Cincinnati, Ohio 45204 (513) 921-1075
Fax:
EMERGENCY TELEPHONE: (800) 424-9300
Call Chemtrec
(513) 921-9180
II. HAZARDOUS MATERIAL IDENTIFICATION SYSTEM *
CATEGORY
RATING
Flammability
0
Health
2
Reactivity
0
Personal Protection
A
These ratings are based on NFPA regulations
LEGEND 0=Minimal Hazard 2=Moderate Hazard 0=Minimal Hazard A=Safety Glasses
ill. HAZARDOUS INGREDIENTS
HAZARDOUS INGREDIENTS Olivine
CAS.NO. 1317-71-1
ACGIH THRESHOLD LIMIT VALUE 10 mg/m3
% RANGE 60-70
OSHA PERMISSIBLE EXPOSURE LIMIT 5 mg/m3
Bentonite
1302-78-9
0-10
Quartz
14808-60-7
Respirable Quartz (<l-2%) Nuisance Dust
0.05 mg/m3 10 mg/m3
0.05 mg/m3 5 mg/m3 *
* Total Dust ** Respirable Fraction
5 mg/m3 **
This material contains crystalline silica. The International Agency for Research on Cancer (IARC ) Monograph Silica. Some
Silicates and Organic Fibres (Volume 68,1997) has determined that crystalline silica in the form ofquartz or cristobalite from
occupational exposures, ifinhaled, is carcinogenic to humans (IARC Group 1). Prolonged inhalation ofsilica dust may result in
silicosis, a progressive, disabling, and sometimes fatal, lung disease. Avoid creating dusty conditions and use a NIOSH/MSHA
approved dust respirator when Threshold limit Values (ILVs) may be exceeded.
This material contains olivine, which contains small amounts ofnickel and chromium compounds. Nickel compounds are
classified by IARC as "carcinogenic to humans" (Group 1) and by NIP as "reasonably anticipated to be a carcinogen." Chromium
compounds are listed as "unclassifiable as to carcinogenicity in humans (Group 3) by IARC and "Not classifiable as a human
carcinogen" by OSHA.
PRINTED IN U.S.A.
Product Name: Concote TM 405
IV. PHYSICAL/CHEMICAL PROPERTIES
Appearance and Odor: Gray slurry, no odor.
Water Solubility: Miscible.
Melting Point(F): 32
Boiling Range(F): 212
Specific Gravity(water=l): NE
Vapor Pressure(mmHg): 760
Percent Volatile By Weight: 35-50
Vapor Density(Air=l): NE TPQ: NA
Evaporation Rate(Butyl Acetate=l): <1 RQ: NA
Page 2
V. FIRE AND EXPLOSION INFORMATION
Flash Point(C.O.C.)(F): NA
Auto-Ignition Temperature(F): NA
Flammable Limits: LEL: NA
UEL: NA
Extinguishing Media: Not applicable
Unusual Fire or Explosion Hazards: High concentrations of dust in high heat environment may cause explosions.
Special Fire-Fighting Procedures: Use full facepiece with self-contained breathing apparatus when fighting fires near product
VI. CHEMICAL REACTIVITY INFORMATION
Conditions Contributing to Instability: High concentration of dust in a high temperature environment. Incompatible Materials: NE Conditions to Avoid: Dusting. Hazardous Decomposition Products: Various oxides of carbon and hydrogen. PRINTED IN U.S.A.
Product Name: ConcoteTM405
VII. HEALTH HAZARDS A. Summary/Risks
Page 3
Signs and Symptoms of Overexposure: Overexposure could result in coughing, sneezing, shortness ofbreath, or other
respiratory problems. Other symptoms may result.
Medical Conditions Generally Aggravated by Exposure: May aggravate pre-existing medical conditions.
Primary Route(s) of Entry: Inhalation.
Target Organs: Eyes, and lungs.
Acute Health Effect: Overexposure could result in temporary mucous membrane or respiratory tract irritation.
Chronic Health Effect: Overexposure could result in irreversible mucous membrane or respiratory tract damage. Symptoms include cough, shortness ofbreath, and reduced pulmonary function. This product contains small amounts ofnickel and chromium compounds. Hexavalent chromium has not been detected in the olivine (detection limit 0.1%). Overexposure to nickel and chromium compounds may cause respiratory and skin sensitization.
Carcinogenicity: See page 1. In the report the National Toxicology.Program (NTP) classified respirable crystalline silica, primarily quartz dusts occurring in industrial and occupational settings, as known to be a human carcinogen, based on sufficient evidence of carcinogenicity from studies in humans indicating a casual relationship between exposure to respirable crystalline silica dust. In addition, the American Conference of Governmental Industrial Hygienists (ACGEH) has classified crystalline silica-quartz as an A2 Suspected Human Carcinogen. See page 1 for information on nickel and chromium compounds in the olivine. Olivine is not considered a carcinogen or suspected carcinogen by IARC, NTP, or OSHA.
Notes to Physician: None.
VII. HEALTH HAZARDS B. First Aid/Emergency Procedures
Inhalation: If overcome, immediately remove from exposure and seek medical attention. Skin Contact/Absorption: Wash skin thoroughly with soap and water. Ifirritation develops, seek medical attention. Eye Contact: Flush with clear flowing water for at least 15 minutes. Ifirritation persists, seek medical attention. Ingestion: Ifingested, DO NOT induce vomiting; call a physician immediately.
VIII. SPILL, LEAK AND WASTE DISPOSAL PROCEDURES
Procedures for clean up ofspills/leaks: Stop spill as soon as possible. Scoop up or clean up using best means possible. Water may be used to clean area. Notify proper authorities if the need exists.
Waste Disposal: Waste generated during application, demolition, breakage or spillage may be hazardous wastes as defined by RCRA (40 CFR part 261). Place waste and spillage in closed containers. Dispose ofin approved landfill in accordance with federal, state and local regulations.
PRINTED IN THE U.S.A.
Product Name: Concote TM 405
Page 4
IX. PROTECTION AND CONTROL INFORMATION
Hygienic Practices: Minimize breathing vapors, mists, fumes or dusts. Avoid prolonged or repeated contact with skin Remove contaminated clothes, launder before reuse. Remove contaminated shoes; clean before reuse.
Ventilation Requirements: Provide ventilation sufficient to prevent exceeding recommended exposure limits. Respiratory Protection: Use NIOSH approved respirator for fine particulate filter for dusts, ifPermissible Exposure Limits or
Threshold Limit Values are exceeded or if the user deems necessary. Eye Protection: Use safety glasses, splash goggles, or face shield when eye contact may occur. Protective Gloves: Use chemical-resistant gloves, ifneeded, to avoid prolonged or repeated skin contact. Other Clothing and Equipment: As required to prevent contact. Engineering Controls/Work Practices: Keep containers and storage containers closed when not in use. Special Considerations for Repair/Maintenance of Contaminated Equipment: Provide adequate respiratory, eye and skin
protection.
X. PRECAUTIONS FOR SAFE HANDLING AND USE
Storage Segregation: Always segregate materials by major hazard class. Special Handling/Storage: Do not transfer contents to unlabeled container(s). Other: Comply with all federal, state and local regulations.
XI. DOT SHIPPING REQUIREMENTS
Shipping Name(s): Any Packaging
Compound, Thermal Insulating
Date Prepared: 02/11/02 Prepared by: Lori R. Yeager
Supersedes: 08/15/01
Print Date: 02/11/02
Title: Corporate Government Regulatory Specialist
As of the date ofpreparation of this document, the forgoing information is believed to be accurate and is provided in good faith to comply with applicable federal and state law(s). However, no warranty or representation with respect to such information is intended or given.
PRINTED IN U.S.A.
o'
3 *d
SELL-BbE-LlE
H1IJJIM9 awy niH
WyBB:6 3003 *0 d3S
THE HILL AND GRIFFITH COMPANY CORPORATE ORGANIZATIONAL CHART
CORP-FLOW-OOOOI Revision: 4.00 Date: 1-23-98 Author RH Approved: GEF P. lofl
CONTROLLED
liU/1 L.VJ
rnA NV. 01 I.40 I ICO
r. uo
to vn --'IIt. 'I=MtIJ-
f/5s acc
3 ssi
S
sg
ng-
,,0usls*tteo
S2gK
Eteii
0
z
=5 M
Sag
*= S|^f,,QcsmafF
_J Q
z
wS-S*
R=C cwcwgS
s Spg
bills . |fei=gS
ZjAOl-3
<
X
aggScgrC=g|-'
Sgssig lgirSi
-- CL
iSc"isW
*^SSgf>ewOoUtl3i
ScSekoSxuCEcBoX
9 <
0
5< te
1Ui*X3
i--
co
UL
2a0J0s52r
"1 =in
O
&
SCO
xtSofcS0ti-t
I
Si fel
O *JU
o Jg
jr
s
>fgU>ot*-I oxiCutO.
"i Ss --
5g
>CLOUD ozJS5z
X3CO=U0 sSic| =go
SssMuhlUOt:xoDs.s * i>=lg< tg= cc_
cCPUr*M
z
Ui DC
>-- R=!
zX oo
9 3 a
UJ LL ill -J
x CO
< o- 1-- or <^ </)
I_-- LU _
CO ^ CQ
s go O S H* O
^9 iv
S? m
ui 3
LU 5
*3
Sc tuti
a. =>
w Jb
0 CQ J O N U} e* . t h UJ
Z
<< (A
uj^X
E Sh ts a_
_ cc
-SL- CC LU
uo. ao. Ui
u . 5?
O^H-
So :s| l5iSIwS^cS
uiz;
0=
Wtfu,
5eeS0iu
0^ i*.l ;*iigg
x-*S
"J g;wS
UI 5g wgoit I* O Qcsg s~uyjS32uXiwC
o 850 <3 Cull..
2CC-
tcfcg s=ce: wgo
--x>:
2S _ 2:
uj m
0
--
0
2 >-: rglz g>-^<ii s
c-vS
QoltlJt w >-a=s
< S*s :5fi| dieSfcwSi 2 o ;
Op3
szr < o as
5=g: o=c* Q `.`"Sgji =l<ce
>Si occ=5
sis!, S Bj i1
UuUl
UJ LU 111 5^
1=22; inLr
:gg ip <iEguiEi C Gj CO * co < rrj= 3eSi
iSz: cej^ S o o -j :g *=: 1
5 8 Si5S23 oCO </c> Uq. :1
cd
uOo coQia
K,
Ui
(ft
D
0)
Z 10
H o:
T-
<0
o.
ft
h 0 J
op
S c>
Co I
t I .<3 "H U
8
s+*, a
Co
IQ S I
a JL I
CM
>A
I .*^v
U .s
a01 w
a
I I
Fhr! R QQ
sse:
i:
>f>
oIti
tj u
lii ;g j'.it
< UJ X
3Ui CC
s CFSO=
mu a iiRirrun UWLb
PAX NO. 3172487725
iX
<D IU
I rL 2t*O/ I CBC ro w XW to
co ^ JTM
P. 04
8 *-( 3s>?
s
I
42
&
s Si 6
I
N? tc?
CHl
*5
9yS 5Ss
1 |8o
cu z
3
ffigS =s
Ece5g^
Sw
5pwgSg"
O--f i5sqgEfsigo; oggBSu!
jMCCf^_i
_J Q
s S LU . 'S
sli-j<:Stu9w^= K$o3uctci
ggii! |*Sio.O
X
iIgeSl*fJe.O=
" as
_^Sui g*gg
Kbucii
^=S52SW<t iSSSS EC 3 t b lu
CC
UteJ
I d
S1
a
eg . fc= 5b
< I 52
CC u. ZS
|m
.T U- M
CO & 2: C3
DC oseo u.
3a==e 3z
^ LL>
11
O UJ
t1
E2
o e* I CC
UJ 3= 5 O
2E
u-g 5E
S -- c
l in t LT3
Sec
sco VJ U,
SB
Oi
bg
sg 52
S
2 HI a:
Qs*. lid
zX
oo
LU u_
52 O
X
<o
a: I-- CO
< Hi
DC
z> LI_
aO zh
oOf Z>
o u_ n_
hi
HI
*
O z
N LU HI
DC
Ll_
o
DC
IX. DL HI HI *: 2 O
h D < O
(0 to -J
o o
N
*> h 10
Z
& 3E
g .B
g Rg
_J C/3
jotsSs Jggwg
UJCB^CO
BS
ec ec
SCv. fvhl?;WoS2p2o
03
3
a:HI
o 2
v>Stu-
Qg{
P5 3 a.L O iu
!-us-^|-gSEeo 'SfeSS
Et_SfiiU-gsmuCM*'BIPuigs
)WP <3* UecJ *cJt>jr-
;gg o g{- d-o
O^jw*
gg| gg
-UJ SUJq;
ISS<
;|iQ
~k=sapoa=ossSz-SSl`22s3ecw!srt>?5!-S` .Op>:J-OPJgi*xx olOu wS> uU|J/gaU*J
fcfc S s u CC { eIsI!
igsc rfi
33o
= "I
iiS
XCC^r
i|fc 5la
^0.3 UJ </ _j WJ<t PCS
,& Hi 0}
IN
3
ZN
rh
K
< (0
0.
%
h 0 J
-I
s
I
K} 5 cris y I
p a s
,g
Gst G -X g
i
&
I
s
a" st .8 .8 Q to 8 |
ts>
a
<3
Co c\ <>N~(
illDU
HI
e> z < Q
au>os
vOO
SE "m _ g2w Ietusi 5 ."_LS""oW
m
tu5oeSS. sSw5SsO Sel?al6 aSgS
Sogs js"e =SSx2o*jSP EaEssf^-=cZSS!SsSfsXes
S
-. u.
=3g0gH
eft
3w<
>-
==BSi SoSi-
ttl^L cecc*tc
&So9QS!2ofcSCskj3ol
SEHchu
aUUsUzJuc
tataA:c^slS<erS? ogS s5j
aS~:tEe "1
s&i
M(C
^<11.
S3e e6s0o,S0
i3gg|E
ccccfc g5
^U-O
Q~ gWB(S
<5--m
aizzixi
SwUsgb Ii
i5Ii3gs13 03 sO aSiu
' Ss!
J-?S,XoS-
? a v- 3
2/Jdq
5c
UJ<0^
(3QtUtJ5ts
1262 State Avenue Cincinnati, O H 45204 Sales Central-Cincinnati 1-800-543-0425 Sales C&ntralr-Indianapolis 1-800-428-3102
Technical Spotlight Report
Effect of Temperature Transfer During the Casting Process ...
Figure 1
For foundries using individual ingredients such as Western
Bentonite, Southern Bentonite, Seacoal and Cellulose, the . practice has been to raise or lower one or more of these ingredients based on the type casting being produced. The rationale being, the change in size and configuration bf the casting, the greater amount of burnout of one ingredient over another would result: As a
consequence, daily adjustments made for each casting
accounted for a constant turmoil in the molding sand.
Figure 2
HOW
PREMIX
WORKS. . .
To completely understand what happens during each and every casting cycle in today's recirculating sand systems, consider a typical casting as shown in Figure 1. Once the mold cavity, and companion gating system is completely filled -- a temperature transfer zone has already been initiated. Sand temperature at the mold/metal interface has violently been changed from ambient to approximately 2600F -- see PW1 in Figure 1 -- providing the molten metal is gray, ductile, or malleable iron. At some point in time the temperature at a specific distance away from the mold/metal interface will have reached 1200F. Again refer to PW1 in Figure 1. At this instant, let us acknowledge what has happened.
(a) At the interface moisture in the sand has been transformed to steam. As the cavity fills with molten metal -- steam can only move away from the interface into the cooler mass behind the interface. When the steam temperature
. reaches 212 F, it condenses to water. As additional BTU's of heat reach the condensate, water is again transformed back to steam -- and again moves further back from the interface. Ultimately, the reaction, water to steam -- steam to water, reaches an equilibrium temperature below 212 F to form the water layer found in all molds after pouring.
(b) At this 1200 F temperature line, volatile vapors and gases of the coal and other carbons within this zone back to the interface have been released. All that remains of these carbonaceous materials is essentially fixed carbon and ash. At the interface, only ash residue remains. Also,
(c) All clays present within this zone back to the interface have been calcined. That is, the water of crystallization or chemically bound water has been destroyed, reducing the clays to dead, inert, fines -- no longer capable of providing an adhesive bond between sand grains.
The temperature transfer will continue to travel some distance even further away from the interface where the temperature has diminished to 600 F. Again, let us review what further changes have occurred:
(a) The transformation of water to steam to condensate back to steam still continues as described in the previous 1200F zone as the equilibrium temperature of 212 F has not as yet been reached.
(b) Within this second zone bounded by the 1200F and 600 F temperature lines -- all remaining volatile matter in the carbonaceous materials has been evolved. No longer can carbon particles present in these two zones contribute to sand peel from the casting in succeeding cycles of the sand. Also,
(c) Within this second zone, bound within the 1200 F and 600 F lines, the Southern Bentonite continues to be calcined to an inert contaminant. The Western Bentonite and Fire Clay are. relatively unaffected.
The temperature transfer zone progresses until all available BTU's of heat energy liberated during solidification of the molten metal have been released and consumed by the surrounding molding sand. Hence, we can understand that the heat energy is non-selective in its destruction of any and all additives present in the molding sand.
This would indicate that a proportioned blend of the various additives would be heat destroyed in essentially a fixed ratio and indeed, this is precisely what occurs as molding sand continues to be recycled through the casting process. The term "sand to metal ratio" ,adequately depicts the changes in additive consumption as casting conditions change.
As pattern changes are made with a change in casting configuration and metal section, if the weight.of iron required to pour the mold (PW1), Figure i, is equal to the new pouring weight (PW2), Figure 2, and no change of sand weight in the flask, SW1 equals SW2, there has been no change in sand to metal ratio. Therefore, the weight of combined ingredients required to rebond the sand will remain unchanged.
When different patterns are used causing a change in sand to metal ratios, we must replace proportionately the clays and carbons because the molten metal is non-selective in it's destruction of clays and carbons. This is accomplished by increasing or decreasing the Premix addition.
The HILL and GRIFFITH Company
1262 State Ave. Cincinnati, Ohio 45204
the HILL & GRIFFITH Company
SERVICES FOR THE METAL CASTING INDUSTRY
Commitment To Continuous Improvement
From its founding in 1896, the Hill & Griffith Company has been recognized for many "firsts" it has contributed to the metal casting industry. With an ongoing investment in research and development, we have achieved
New Product and Processes
Our research & development staffhas introduced several new products and continues to be one ofthe sources ofproblem resolution for the foundry industry. In addition, our plant expansions and manufacturing upgrades have provided us the best in process capabilities to meet your casting requirements.
Quality Program
Our experience and the requirements of our "Hill & Griffith Quality Program" produce the industry's most consistent and highest quality products. Hill & Griffith has received substantial recognition via customer quality awards.
SPC & Certification
Hill & Griffith utilizes state-of-the-art statistical process control measures to monitor, verify and document product quality. The automotive QS 9000 certification is scheduled for 1996.
Sand Testing
Technicians in our lab facilities use the latest testing and documentation equipment to analyze your samples, report the results and assist you in achieving optimum performance of your processes.
Technical Service
Our technical service staff utilizes degreed and foundry-trained technicians to conduct on-site assistance, process surveys, casting defect investigations, product testing, machine start-ups and much more.
Warehousing Facilities
Hill & Griffith direct sales warehouse facilities are strategically located in Birmingham, Alabama; Burbank, Ohio; Chicago, Illinois; Cincinnati, Ohio; Indianapolis, Indiana; Milwaukee,
Wisconsin, and New London, Ohio. These locations allow you to take advantage of our customized and reliable on-time delivery program.
Sales Commitment
Our current staffof 11 direct sales people and 8 distributor organizations achieves complete coverage of the North American metal casting industry. You can be certain ofHill & Griffith's rapid response to meet and exceed your expectations.
Research
Hill & Griffith's aggressive, ongoing research and development effort means customers receive cost effective, innovative and environmentally sound products. Our commitment to quality and productivity is unmatched
Electronic Data Processing
Another example of our service-oriented approach to business is our EDI system. This paperless transaction capability makes on-line reordering quick, easy and economical, and is available today from Hill & Griffith.
Bar Coding
For your convenience in monitoring inventory receipts and disbursements, we offer product and/or package bar-coding programs designed to meet your specifications.
Training
Helping you succeed is our business. Our training and support programs include seminars at customer locations or. at Hill & Griffith facilities, with hands-on assistance in your foundry and access to our comprehensive video library and training aids. We are always available to work with you.
CinHceinandqatuiaCrtoerrpsoraate
Manufacturing Plant
1-800-543-0425 1262 State Avenue Cincinnati, OH 45204
Phone 513-921-1075 Fax 513-244-4199
INDIANAPOLIS FACILITY 1-800-428-3102
3637 Farnsworth Avenue Indianapolis, IN 46241
Phone 317-241-9233 Fax 317-248-7725
the HILL & GRIFFITH Company
NEW LONDON GORE FACILITY 201 North Main Street P.O. Box 71
New London, OH 44851 Phone 419-929-5008 Fax 419-929-5106
Burbank Facility
29 Depot Street Burbank, OH 44214
Phone 216-624-2583 Fax 216-624-0961
Birmingham facility
2929 7th Avenue, North Birmingham, AL 35203
Phone 205-328-4050 Fax 205-328-4811
Chicago Facility
4606-10 West 16th Street Chicago, IL 60650 Phone 312-242-2690 Fax 312-242-2692
1995 The Hill Be Griffith Company Printed in U.S.A.
%V
The HILL and GRIFFITH Company
PRODUCTS FOR THE METAL CASTING INDUSTRY SINCE 1896
AN EVER EXPANDING SOURCE OF METAL
,, in It til' ilU' ll\
$
, bv ,iu ii iK md^crm.l *>
>.i ';;^s:SfetSSS:
'Jit belter ki'tvx- the cvtfcSHaiJjiiiiji;. . ' - '!
.foiiiiijl'y iudiisirjvThf -Mil|:j'ndb^ . ;'
GFifiitltOVinj'-'wy-.pucctiJscjItflie^i - ' . tteruSL'nnrtMui.Gjnip.in^iijU.WO: . ,; ]
Lite Itk!i injj c)lt<-MSeciC;Covn^nreji\liixv^^':ivv';^;^^
Immmmi
> . I .'A. .
The Hill and Griffith Company is a pioneer in the development of the PremixTM concept and introduced its first Premix, a combination of carbons and clays, in the early 1930s under the trade name LavobondTM. Hill and Griffith's modern blending equipment permits sand additives to be mixed according to the customer's specific formula. This prescription blending method provides foundrymen with the ability to adjust and control additive requirements for a complete range of cast metal production.
Premix facilities located at Cincinnati and Burbank, Ohio; Chicago, Illinois; and Birmingham, Alabama are examples of Hill and Griffith's continuing effort to improve its production methods and provide better service for the members of the metal casting industry.
Although Premix formulations vary according to the type of castings being produced, the following quality ingredients can be used:
Seacoal
Clays
Cereals
Carbons
Cellulose
Special Additives
ift>- ^-iiX
*<* *;,
^ * ''-J
fa>''
w<*j*mi |l|n J&3g3'* ^tr-
gjgppfcs
"'
|pi|C
?&-
**<
11.;,(t. (5(
nSIhI l^ix^ *na *** *>
(>ip !s*e *Sfy sit^i
*,-'>*<*i < iiij^ifi* 4<.m -j*( v* ~i t .
j. 1 :
You'll benefit by utilizing our state-of-the-art facilities, specifically designed for high quality, cost effective manufacturing of sand cores, molds and strainer cores. In addition to real cost and efficiency savings, you'll be tapping into the knowledge and resources of our industry leading core making technology.
,xS>>\
J
3$Hs5?g5?
Hill and Griffith offers excellent capacity for nearly any of your requirements with Osborn Quikore 10A-2 machines in New London, OH, our newest facility, and Redford CB-22's in Indianapolis. A large variety of strainer and metallurgical cores are stocked for immediate delivery.
Sample cores are available on request. Cold box cores can be made the same day to meet your testing and pattern correction requirements. For "No Bake" process work. New London is equipped with a phenolic urethane work center where cores weighing up to 25 lbs. can be produced from conventional wooden boxes.
Capabilities include:
Hot Box Cores
1 Warm Box Cores
"No Bake Cores"
Cold Box Cores
Oil Sand Cores
Shell Cores
CASTING PRODUCTS AND TECHNOLOGY
Core And Mold Coatings
Refractory coatings provide molds and cores with an impervious barrier between the sand surface and the molten metal. This ensures excellent sand peel from casting with improved casting finish.
RELEASE AGENTS AND PARTINGS
A complete line ofrelease agents and partings include green sand liquid partings like Super SlikTM for high pressure molding, and Y-250TM Liquid Parting which is specifically produced for patterns difficult to draw. To overcome environmental and health factors where non-liquid releases are needed, AvonTM Non Silica Dry Parting is available. A complete line ofDow Corning Silicones are stocked along with COBRATM (Cold Box Release Agents). For no bake applications, Air SetTM Release is unmatched. AquaPart IITM - A patented, unique water-based liquid parting which provides improved odor characteristics and reduced flammability for foundry molding applications. Flammability has long been a concern in automatic molding operations, and with the water-based formula, this prpblem can be minimized or eliminated.
Die And Squeeze casting
DilucoTM - The industry's most consistent and highest quality die lubricants. Water-based formulas handle wide temperature variations and effectively control staining and soldering. Slag SetTM Slag Conditioners - A blend of materials which improve results over the single mineral slag coagulants frequently used in the foundry industry. Plunger Lube - A water-based plunger lubricant for cleaner, efficient cooling. An effective, economical oil-based lubricant for most operations.
PERMANENT MOLD CASTING
ConcoteTM - A ready to use, low pressure die casting and permanent mold coating formulated with special refractories, binders, wetting agents, and preservatives.
Adhesives And Mudding Compounds
Speed SealTM Mold Parting Seal - A uniquely engineered sealing compound in plastic form specifically designed for use in high production molding. Red ChiefTM Core Paste - A water-based adhesive with a rapid drying characteristic when applied to warm cores or dried in a conventional oven. Green HornetTM - A water based adhesive that provides good strength in a relatively short period oftime. The product has excellent storage life.
ShurstikTM Core Adhesives - A solvent-based product designed to meet the increasing demands for higher production rates and efficiency. The product exhibits excellent strength with short periods ofset time.
Mudding Compounds - Hill and Griffith offers two types. Compounds can be easily worked into core joints and smoothed without special tools or techniques, reducing grinding and cleaning of finished castings.
Core oils
Hill and Griffith offers a conventional core oil, formulated with alkyd oils, petroleum resins and drying agents, which is used in operations that require high strength and a minimum ofbaking time. Applied as a solventless binder, the consistency ofthe cores produced is very high. Applied as a solvent containing binder, the cost of the product is decreased for the user. Hill and Griffith also offers waterborne emulsified core oils for reduced hydrocarbon emissions.
Hill and Griffith, working For Your Future
J^.ft-?r^f.{?Y**; ^Hvlsvi-n-$V?$Mt!'fc' ,>* - - ?m %? AtuV
b., - {'.-'Wwr^
KsS' W1*^(^, M?Stw* WJit"o*f-fW^ScJ|W.W'1 J-
` iln 'miftit proihii ^niulitv . * t^JiJJUOO \iiu>motivc: (A'ci'ihf iirtif *') /,.
: ; ,f_''' - m-'N i-* *'
Hi ! iJ (-rrirfifl) s smk! ore 81 j'K thjriuin fil.mts sire tli.itci;uc 11}
t ](u.it(`(.l u> ptovkli maximum
S >ci,,u\ it\d ^v'/oxiiiaiut1 (O tlu
!J ine* '11 .*ctiv Mid'i.'trv *
"
BBHBSL
_____________
MINERAL PROCESSING And Warehouse Locations
Cincinnati, Ohio Burbank, Ohio Chicago, Illinois Birmingham, Alabama
Core Plant Locations
New London, Ohio Indianapolis, Indiana
Warehouse Location
Milwaukee, Wisconsin
Everyone Knows A High Quality Product is The Key To SUCCESS.
But in today s fastpaced, competitive climate, reliable service and timely deliveries are more important than ever. We recognize how critical convenient service and delivery are to the success of your operations. In response, our commitment to convenience has never been higher -- nor has our network of interregional resources ever been broader. In addition to our people resources, our plants are strategically located to provide optimum service benefits to the metal casting industry.
Today, you can count on our company to provide the most innovative products and services, designed for improved quality, efficiency and profits. Our "Partnership in Quality" philosophy will help you meet your most demanding requirements.
Helping you succeed is our business. Our training and support programs include seminars with hands-on assistance with your metal casting process and access to our comprehensive video library and training aids.
Indianapolis Facility 1-800-428-3102
3637 Farnsworth Avenue Indianapolis, IN 46241
Phone 317-241-9233 Fax 317-248-7725
Burbank Facility
29 Depot Street Burbank, OH 44214 Phone 216-624-2583 Fax 216-624-0961
Cincinnati Corporate HEADQUARTERS &
MANUFACTURING PLANT 1800-543-0425
1262 State Avenue Cincinnati, OH 45204 Phone 513-921-1075
Fax 513-921-9180
BIRMINGHAM FACILITY
2929 7th Avenue, North Birmingham, AL 35203
Phone 205-328-4050 Fax 205-328-4811
NEW LONDON CORE FACILITY
201 North Main Street P.O. Box 71
New London, OH 44851 Phone 419-929-5008 Fax 419-929-5106
Chicago facility
4606-10 West 16th Street Chicago, IL 60650 -
Phone 312-242-2690 Fax 312-242-2692