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AR226 _ 0678 MULTI-CITY STUDY FIELD REPORT FOR CLEVELAND TENNESSEE AND DECATUR ALABAMA - BATTELLE DUXBURY ACTIVITIES for Project Number N100672-01 submitted to July 9, 1999 Prepared by Scott C. Macomber Battelle 397 Washington Street Duxbury, MA 02332 (781) 934-0571 00103 | orc%in | TABLE OF CONTENTS 1 LO i ----------------, I 5. PROBLEMSEXPEAR NDI RECEOMN MENC DATEIOD NS ..ccovvvsnvrreermvsnsmeessssonssessssssssssssssssssinss 12 1 LIST OF TABLES 1" `TTAABBLLEE 23 CCHHRRONOOOONLFFEEOVVOEEGNNTLTYSS OOONN MMGAAYY2Y254,, 1999... HE 1999...c.c.vscovssnsssmssmsssssmsssssssssssssssssssssssssss 2| . `TABLE S CHROONFO EVEL NTO SONGMAYY 27,1999....c.ccvrrrrvrrsnrssrsssssssssssssssssssssssssssssesssssns& 1 `TABL6E CHROON F EVOENTLS OONMGAYY28, 1999... worms "TABLE 8 COLLECTED SAMPLESFROM DECATURAL .....ccccvrrsrrmsemmnsrssssssssssrssssssssssssesssssssssis8e "TABLE 9 SAMPLINGSITEPOSIINCT LEI VELO ANDNTNS ...ccooevrrurrmermssssssssssssssssssssssssssssrssnsssseesss 11 "TABLE 10 SAMPLINGSITEPOSITIONSIN DECATURAL .c..cccevunsunsines wnmssmsesssessesssessessossnes 11 I Final Field RptClevTeNDlecaatunrAdL Space001013 I _-- e gPnue get I 1. INTRODUCTION | lTehveeloabnjaelcytsiivse ooffstpheecsifaimcplFiCngretsaisdkuailns,thois asstsuedsysissotuorcceosl,ledcitsrpeeprrseisoenntinattihveeesnavmiprloensmefnotr,traancde1 cphorunomsdaiudcneterieoxdnpof`sasuctirulediytt'iehsorroour"gclhoanrttghreeolif"nodcouidsttecrsh.iaailSn.FtCu-dTcyho'encsciiuttmiieeessrassr.eelec`coCtnoesndtirfdooelrr'esdcaimttpheolssedeocaornleolatescctwoiinottnahwiFinlClFbCe 1 `pproopduulcattiioonn soirzec,onansdumdprtiinokninfgacwialitteiressoaunrdcea.re matched to study cities based on general location, Dpfeurrromiminstghseitohmneunitinoicctioapllallepchtaagsveeanrcoiifoeusts,hemaapstptrruiodcpyerpisahotofeniesnatcemarpellssit.nwegBrseat,srmeatdaedguiepeostnowemturheneildceeivvpeelaollofapgecedon.ocpieTerhsaetrieQoqunuaelrsiettciyenigved 1 tAhsesumratarnicceesPrfoojrecctolPlleacnti(onQaAnPd)meatnhdotdhsetSourbveeuytiPlliazendcfoonrtathiinstphreocdeestsa.iled information concerning TSPcehireesnofucnlenlselpLracoobjloelcretacttsoadrmrypiln(kiMinSnggLs)wcaoptpeeerrs,iosPnanOceTcloWcmo,plllleiacnstdhfseiuldlrufasanicnedgwutartwbeaornfmaiiiecrldrsotalemaapymleser:s,,1b)aunBldakt2tw)ealtBleaetr'tsaelnDlduex'fsbinuMfraiysrhine 1 sMaSmpLleasct.iviTthiiess.report summarizes the Duxbury team effort. A separate report summarizes the i 1.1 Survey Specific Approval 1 A(pBpOrToWv)a,l mwuansicgirpaanlteddriinnkCilnegvewlaatnedr pTleannnt,esasnedeCflreovmeltahnedPFuibrleicDleypOarwtnmeedntTr(feoartamtemnotsWphoerrkisc 1 dssraaimmnppklliiennggw)aw.astPgeerrrampnlitasensdti,ionannDwdeacmsautnnuiorctiAgplraaalnbtlaeamnddaffioflorlr.staThmehpelPiDOnegTcaaWtt ut(rhiFenicmrluuendiDicneigppaaarilrtmslaaenmndpftlilidlne.gn)iP,eedmrumanicisccseiisposantlototheir } tphreopaeprptryovfaorlsatgmroasnpthederbiyc sampling. municipal dTeapbalret1mehnitgsh.lights the cities visited during this survey and I `Table 1. Municipalities Sampled and Approvals Granted During Survey 1 Ty Study or| Fire Department Control | (Air Sampling) Drinking |Municipal WaterPlant| Landfill 1 ([CDNleiAan=rtNA.oLApTpJrToeSvoaulndRyecei[vTeNdTa Tp JC [1 ww | Air sample collected | Final Field Rpt Cleveland TN Decatur AL a Balelevlale wok001020 tvods ------------------------------------ : 2. METHODS TPrhoececodlulreecsti(oSnOPo'fse)n.viTrhoenmSeOnPta'lssuasmepdlienstihsecMounldtuic-tCeidtyacSctoarddyinwgertoeSwtraintdeanrdbyOpBeartatetliloenand are . uwsheidletointtrahienfpieelrds.onTahlepsreiodrotcoumceonntdsuc,tailnogngfiwelidthacttihveiQtiAesPPan,dsaelrsvoesaesrtvheeagsuaidraefnecreedncoecudmoecnutmsenftosr "tThheeccoolllleeccttiioonnoofffpieolsditsiaomnpdlaetsa. (Tlahteitmudeetahnoddslounsgeidtufdoer)cwolalsecctoimopnlaerteesduamtmeaarcihzesdambpellionwg.location VuasliidnaagteGdabrymicnom1pa2rXiLngGPanSaucnqiutiarcecdoprodsiintgiotno BvaetrtseulsleapSoOsiPti3o-n16o4f-k01n.owInnsltorcuamteionnt.aTcchueraccolylwecatsion . | osfamaplisnagmpwlaesscwoansduccotmepdleatcecdorudsiinnggtaoGBeantteerlalle MSeOtPalMs3M-oMdCe-lF-P1S.-11.atTmhoespuhseeorifcthsiamspsleyrs.teTmhe | afolrlopwasrttihceulsaetpeamraattetecrolalnedctaiopnoloyfupraertthiacunleatfeoaanmdPvUaEpofrorphtahesevacpoomrppohuansde.s uWsaitnegrasgalmapsslefsibferrofmilter dSruirnfkaicnegwwaatteerrssaumppplleiess,wePrOeTcWo'lsle,ctaenddvliaanddSiirlelcst wseurbemecrosliloenc,tetdaapcwcaotredrinagndtodSriOnPkiMn3g-wFa-t2e.r0. 1 uSuspipnlgieeidthbeyrtahbeumcukneitcoirpaslmaplllanstawmeprleincgolbleeackteerd.viSaedaivmaelnvte ssaymstpelme,s awnedreefcfolluleencttewdasuscionlgleBcattetdelle 1 SOP M3-F-7.0. Both sludge and sediment were collected using a stainless steel spoon. 3. CHRONOLOGY 1 sTuarbvleeys.2Tthherotuigmhes6 rpercoovriddeedafdoerttahielecdolclhercotinoonloofgeyaocfhthseaemvpelnetsmatthraitxochcausrbreeednetarcahnsdcaryiboefdtfhreom 1 tthiemessahmapvlee bcoelelnecrteicoonrldoegd, ianllEoatshteerrntiSmteasndhaarvdeTbiemeer.estimated based on the events of the day. All 1 `Table 2. Chronology of Events on May 24, 1999 [0615 | BattelleDuxbury personneldepartBoston. | i a er ere AT | I `materials presnt and accounted for. 1 [1300 | D"DeArptaivnue CihnheaCntlteacvneg loloaignnadagannsddpdcrhoecccekeidontooChhlotseevmle.olParrnodcs,eaTepNdl.tion_gha_mvee_Kri_lck_eof_rfm_eee_tii_ngd_ov_feor_rTi_acnc_h.| sampler. [1500 | Arriveatfirestation and placeairsamplingunitbehindbuildingforsamplecollection. _| | [1545 | Conductcalibrationofarsamplerand startsamplingforI2hrperiod.____| re ey aHreiparlovides maps, directions, and informs the managersofthe plant of our scheduled Ir ITER shipment to Chatisnooga A Final Feld Rpt Cleveland TNDecaturAL 001021 Battle } he I 1 `Table 3. Chronology of Events on May 25, 1999 1 70 c`oAnrcivleudaetdthaet 0f7ir4e5.statCfloen,aniedssaammpplleerra4nddoptlatceodpthateePnUdFoafn1d2hfilpeerribolda.nkSsaimnptloitnhgevent Table 3 Continuesdamole2rx.shBilpamneknst.remained in sampler for ~30 seconds, they were ten placed in storage i tw swiithveMra.t MCilekveeWlaanrddUwilhioiewsasWatshteeswuapteerrviTsroeraftomretnhte Fshainftt, (nWoWsTigPn)if,icaDnitsciusssusess arapilseidn.g . HIS 1 CCpololallnleteccettmppcohlslotoycreeienn.attreiCdfouemgfpefllesutelneutdcgaoelm.lpeUlctseieovndiaattoal1nd0ls5e.sesesFiopaleillo.swpiCoonlgolncefcootriclonloasesloicsflttasnieacbeoclPnertovKiiid.eod n57] 1 ABemenpndlcroheymweaser.dkeHpdaeirstcceoodnvtetarhceetdetdaetaatmhme0eWmebWteTurPmo,ftotinhCqeou'licurimeybdeuansbg.ionuetetriengcodoerpdairmtimeesntrwohmotpropvliadnetd the K 70 cioAofnrotkrhvideeinanpgaltawneHtsiwwfaaoartsesrtrehoteeqmubwdaerlanieicenthkyrmiaanbrgq.kuw.aayCtoTlehlleepbcl,atcnotao. rwdSiupnnotakrteeeawtarieedt,hrNiCvhe3rr5iswa1Wt8ie3lra5es.n0dw"phWoosft$s5ft4ih4le1ra:mt5ai4no.na0g"er cAomlilveet asturSftaacteewaactceersasnadreaseldoicmaetendtosnamHpilwesa.ssee River. This 36065 area was ed a [450 1520 CCoolllleeccttssuurrffaacceewwaatteerraannddsseeddiimmeennttssaammpplleesattSSittee2 I. ] a [[1116330 351CCoolllleectt sSuirefacteawpawtaertendfrsoemdriomeonmt1s0a7moplfeBaatySmitoen3t,Floel | [700 Commencespikingoffieldspikesamples | n 2015 CinotlelrescetctSiiotne2oftRaopuwtaetser60roanmda7n5.Ameo gas stowcomveniencs store Tocaed a Ti n [215 Collec Sit 3 tapwaterfrom Tennessee aek's Cafe. RE `Table 4. Chronology of Events on May 26, 1999 " water). Copies made of Chain ofCustody Sheets. R' T200 u`SphaiprCslaemvpellearnsduTppNliseasmp(lfielstervsi,aPFedUeraalFnEdxp'frieeslsdsstp,iktehisrarmepslpeesc)t.ive destimaions Picked h M20 DRKeeepcmeaiCvaferoperhaDogenrceeaecudarltlofa:rlocom,nfMiadrecnitiaalNiitsyhiaogkrae.emTehnet ctheanttwoaunlddDaelclaotwurusUstlisaemsplmeanraogemrthe h| POTW andthedrinking water plant. `bCeagllinKem sCamaplrinrg twoicotnhfiithrnm sdaaym.pling approval and inform Him that we are expecting io h calibration of instrument. k Final Field Rpt Cleveland TN Decatur AL -- Baa teo te wt1.022 | - raed | (1600 Arve at hotel and begin preparing water amma bottles for the following day. Table 5. Chronology of Events on May 27,1599 | Table. ContinueCpdol4le2c"eathfoDfulrruyse.nCtrCselaeemkapnWleWunTuistPia.nngd5Cc0ool0lllmeelctstaaQmCrplssaeammpplel,es3insclaumdpinlgeasntoepxpeesd fauetdomatsiaceally mpl. | Sdiasmcphlaergweads~c5o0ll0eceteetd ifnrtootmhtehreivspeirlwlhwaeyr etthhate collector that the fay lcehdatnonethleedxiisstcsh.arge `Pipe. prortg Se The effluent is : | 1045 {HioimcavtMeieoanatrreDesceoccraodtleuldre;cWtteahdtecelorilqPlulieadcntts.iounCgotlalnfekrctwomarsoawc~o5al0nl0edcytfdiisnoafnlrtopamrnotkcheeusssisentdgd3riPnoskasmpilining eg TcoreNno GF | 05 taemcphnliecisancoolnledcutteyd idnurtihnegwaotuerrcqoulalleicttyion1a ofthe acilty Richard Blackorvoandi:yas the Collect quict wate body sample from the Northwest corer ofFiat | S$E5 fbyoca~t2e0d0s.c3r0o0s ryarodsm, the Decatur Country Club. It was north of CCoruenetrkyTCielamaens e Collect surface water and sediments at ies 1. 2, and | complex located on the Tennesse River, 3 from the Riversalc Mare `cCoomlplleecxt)tap water from Site 2 located a the Decatur Boat Harbor (within Riverwalk | 135 eovetreprttohcaeteMwdoeardsgtraoenqthuCeiorlueendatpcyrhiaLotreatnpoondaou.urncsPoruleplseeecrntvtiioinsteoedfamsnaandmapclgoeelsrl.eRtiFcohlalrodwiTnegy,twtihd3ioesst, ! 1550 DSeoclaltcutr.Site 3 tap water from a Texaco gas sttion/convenienlceeacshtoartee on Rsoampwle.s 677 HES Collected SitTeap waterfom room207oftic Harpo | sFhhieplpdisnpgike samples were processed, samples segregated, and soars packaged For Table 6. Chronologyof Events on May 28, 1999 ! [ [9T84> h 5 e]pa Amivre finoirChciatt for shipment. anoogoag,a paperw ork c omp le ed For samp SpenIt <a ol er eT o p a c k-- aged TM rdeistvienataitoFnesderal Expres and ship all samples 3nd equiTpermereeponstitng C0 TeperChsogs fran | 4. RESULTS Tihmebilnistidalesscurrivbeeyd 3 through 5 of the oifn tThaebMluelst3i-tChirtoyugShtu5dyofretshuelQteAdPiPn.thAelcsoollceocltlieocntoedf QAPP were samples for the client anda the but mnaojtomrietsyosfitnhe Tables TTehhneetfs.oalmTlpholweeisncgowleslreececttciiooolnnlsoedfcettsehcdersaienbedsapmrpolceesssterdipilnedthtehesnaummebmear notfnhiwearadrtleatrbhaoornsaedtpoaryacsnpehecifoisoea"Bdmaptbltyeetslhlteea.ken, th resultsofthe sample collection efor thas sonoreduring | `Final Field Rpt Cleveland TN Decatur AL 001023 #Batielle | -_-- - OWFes 1 N wahinitdshssaauurmtvpheleyen.tiITDca'ssb.almepsTlae7bsl,aensd78apnrdov8iddeo anoltstcoonfttahien stahmepQlueaslictoyllAescstuedrainnccelusdaimnpglseasmcpollilnegctleodcastlioonngs 4.1 Sample Matrix Availability N ciPoselsrluceescitenenodtafitinensifttirhsuhecrwtieCorlneesvcneoollalfneocdotdodrutrDeiemncsgattwuheirrsdesuucerovlteloye.hcetaeTldhtdehucrcooinlnlcgeecrstunirsov.neyBo.fotPDhuOPeTOtWoTisWncfhilenudfeulnlutiewnntagssatnnrdoetapmesrmit . iavnadiilcaabtleed tfhoartstahmepclhilnogricnoanttiaoinnepdrobcieoslsogoicccaulrshazfaorldlso.winIgn bsoetchoncdiatireys,ttrheeatsmetnta.af the facilities n CfNoleleilvtoehwleiarnnlgda,nidnTffNio.lrmlTaethaiceohnar.teeaAsnoodnriisnacgnutsahslaittoenamnawtiaitlvhteetsmhaaetmimpvaleneaswgaamesprlcoeoflwtlaheecstlenadontdffosirollutghiehntmFuaenbfirtcueiapirsaylbiratesyseudolftoend tihne.the denial of permission to collecta sample. During this discussion it was revealed that the leachate. Xy CflreovmetlhaendlaUntdifliiltlieiss the leachate as itis panumofpfeedr pumped witonastfhrmeoaPmdOtehTetoWlarnfedofmrioltlvr.eeaHatommweanentv.heorDl,uerbcieoncvgaeurssuetbhswaeteqwuhoeaundltnddoiatslcblueosewsniuogsnrsaacnwctieetsdhs to " mupnieagrtrmtaiatsiisnniagobnlferitoawmnadtshtehdeelaclnieddafecildhlattaheantpdwueemntpweerodiunlfgdraonmnoettahcreobllylaenwcdatfttiehlreistloeruaercachseao.tneeTdshaetmrhpealfteot.rhee,Wlinetoahcahltathteeernswaaotmiupvleldesintoet be n was collected. Also to be collected, but not included in the QAPP, was a sample of quiet/undisturbed surface N c1w0oatntedhrue.cptToehdni.dssIsenalemCcpltleevedeialssainandtsweanemdpewldeirnfeogrusuintsaeebalisen itatowlcoaonslgl-letoccetarttmheitdsroasnnasmppporlrietvasbtteeucpdaryuospteeharattcyic.secsAusrrwseaanmstplulynebaevwiaanisgi.able uN collected at Flint Creek in Decatur. N 4.2 Onsite Observations RB Cealsetvneolratnhde,asTtNo:fTthheepdlrainntkiinngthweaHteirwapslsaentewRiitvhedrr.awTahlellooccaattiioonniosfatphperosxuirmfaacteelwyat2emrislietse is at the deinsdploafyEeaddoens aorloEcaadlsmaropa.d. ThOenesistepeilslainsgmwalalssotbatseeravcecedsosnaarelaoclaolcastteredeattstihgenatnipdotfhetheotpheenrinsula. n `The area appeared highly utilized by the local population for recreational activiics, nN DcDoeelcclaaettcuutrre.d, TiAshLil:socaTarhteeedaRasidvajeahrciewgnahtllktyoMatachtreiivHneiamgcahorwmiapnyalec7xo2mwbphrlieedrxge,esstuehrvafetarctaerlawvpeaertoseperlseatnwhdeerTseeendoinbmesesensrtevseedwReifrviesehriinngtforom nN wuthaneskbncaoonlwklnse.cstpSeedecvifeerrsoamlwadaseraeodcbescneattrlfvyiescdhoanwtsetSrrieutceotb2e.sdeAcrotvleltdehceatlMiooonnrgpgtoahnned.sChooTurhnei.tsyApLraesnvedimioiul-sslolftyhtsesahlemelpallceehdadttpuerostnlaedmopfle K FinalFeldRptCleland TN Docamar AL 3BNaatikeatiie rk001024 Rents - Pues i a | i N || N || n r ] = B i : i i # KK pond`(TDheecpeomnbdersa1m9p9l8e)dwdausrisnugrrthoiusnsduerdvbeyy vegetation and access contained a variety of wouldhave been wildlife living in extremely difficult, and or around it. Several turtles, multitudes of insects and larvae, and various birds were observed feeding at the `Sample ID `Vo`lAupmperoCxoilmlaetcteeTdo(tLa)l or Location Collected : [[DDrriinnkkiingnWWaetiesrPPrroocecssseedd[c[MoC1la2s8 [Drinking Wate Proceed [MCT Ruiking Water Processed [DrinkingWater Processed [MCI [MC12%5 [inkingWate Processed |MCI2IK priking Wate Proceed -- [MCT RRiuikkiinngg WWaatteerr PPrrooccssieedd---- [[MMCCII2Z8KK [Drinking Wer Procssed -- BrinkingWaterProcessed [MCIZSK [MCIOIH [DDrriinnkkiinnggWWaatteerr PPrroocceesssseedd-- [[MMCCIIOaS8HH [Drinking Wate Processed -- [MCIOSH priking Wate Unprocessed [MCTISB [Drinking Wer Unprocessed [MCIITD inkingWaterUnprocessed [DrinkingWaterUnprocssed [MCSD |MCTI9B *Sediment Mass (g [17 Tr [1 [1 inane DemoWer pe] Titman Dinkins Warp] [1 [1 Tiina Dinkins war bien] inane Drink Warp] [1 [1 HiuawesDrinkingWarepion] Tiiases bons warren | [1 [1 Tvinasec Dinkapea] viuasec Dinkime waepen] [[ 1 TTHiiwuaasuseeseDrDirnnkkiinmeeWwaotreeppoin]] [1 [1 HivaseeDrinking Wate bi] vise Drnkimewaer fe] [1 [1 TiinaseeDinkinswerpin] TiiinaseeDrnkimewate bin] 11 TT Hives brnkimewoespo] Huw Drinkin was oe] [1 luau rinkineWate pi] [Driking WaterUnprocessed [MCLE [DrinkingWaterUnprocessed |MCIEK T [1 TTinHiauansseeeDDionnkkiinnswwaaneepbien]] [inking Wer Unprocessed |MCIISH [ DrinkingWaterUnprocessed |MCIITH 11 [1 [Driking Wate Unproces HivasseeDnkine Warsban] ina DrinkineWas pi] Drinking Water Unprocessseedd[[MM OTCIOSN [1 [1 FoeVaerSien IMCs1 inaneDimewaarbe] iam Dinvtmewaepea] FopWeersient --wCim [looWaterSues [MCIasp 11aTam ymor 11 en] ------ FlopWaerSiest ---- [MCI9b1 Tamer oe ------------| Thmmennige HoeWaerSiem ------[wciagc [leWaersient [veo [reWaersien 1 11------------s gaern cons------------------ FleWaersien Tweak --Twciok [eeWaterSee1 [McK T Tii------------------J--p--apnoeotnie ogg---------- TT FloWaersiest FaeVaersiemn [MCI 1 TwCiam 1 pameeg-------- Tmanen oe (Tsp WatrSieal-- Twcimsn [1 aeons--------] Tpametiog-------- BE i} -- ##BBataifetleltele001025 I -_-- retnst I i "Sedimaesnst1 `Approximate Total Volume Collected (L) or Location Collected i `Tatbalpew7a.tCeosntein2ued [MeETo [Lapses Siz MCISK [1 -- Th= mention -- | AmocoGessaten ET -- -- -- 1 [[oTpoWpaWtaeerrSSiiee #ts3 [SauceWaterSuef [[MMOCIIR1 [1 [MCI0OB [1 TTeemmesecschcaccclacCoottet [FiveRiver | I [e[SurfwceWeersSept [SurfaceWater Sie fl h[Me CI03m0 [MCI0B h[1h [1 fiwaaseRnoveer -- | asecRiver | BB [[aF StaecelWateersStep [MMCCIIOK [1-- S [waseevRieve-- r 0 [Sh taceWaterSie b [MCIh OK [1 eh wacoRive er | |JE[ST te aceWaterST if [MB CIGKi [1--T --7 tTmarse. eRi-- v--er] E ET TTO EeTO 3SE ---- TT=-- -- =-- I [[SSS utaacceeWWaatteerrSSiieer2e ___[IMMCCII0OGGHK m [[R11h e [weaaessconRR l ivser r]| | e E i -- -- S e -- TTrTTe =-- ---- n E [SefimE eniSiesl-- [e MCI0S B 2000 EE -- -- |FimaTmeohTivSer-- FT -- | L EE TE -- -- 1T TT--n -- -- T TY-- -- -- B E [SetE imentSiess [ostimentSie 83 TMCAZE Ta00t TMCIDH [2000 FTwaeRiver-- | Times River | 0' [[FPOOTTWWEEMfMfloueennt [[MMGGIMB [BOTWEfluens --[MCttp [[[111 {|CClleevveellaannddMMuunsccpaarFrOOTTWw || ClevlaodMumcpalPOTW | E[BOS TWEfluen ---- NR [POTWflue [[MMCC13a9OKK [I 1-- [1 [CClleevvellaannddMMuummpiuarFFOOTTWW || n [[BBOOTTWWEEfftueent-- [BOTWElem I[MMCCIIIOKK 1 [1 [MC39H [1 || GCleevwllaannddMMuunniisoppaaitpPoOrTwW || ClewlandMunapOTW | uy [CPROOTTWEEiffioen [[MVCtCalHE1 [1 | CClloewwllannddMMuummiiaapPoorrww__|] u A Final Field Rpt Cleveland TN Decatur AL Bat-- eie 001026 eta vot } -_-- krResiis I Sample ID `Approximate Total Location Collected i 1 [FE[ oOOTTvWWSSleuhdugtee C vom a Dr wVo"lSuemdeimCeonltlMecaa tsesde (L3) or n Ve enereorer--| [Coat oto Cleveani amet borer--| i `Table8. Collected Samfrpoml Dee cats ur AL Sample TD | Approximate Total Volume| Location Colecied Collected (L) or *Sediment 1 i o [DDDrrriiink nnkkkiiinnngggWWWWaaaatterePFPPrrrrocoooecccssmeseeeedddd[[CC[MMoCeIaaamasEanmp---- I[ [p 1TT 1 Me ass (g)p e Tp pr] ------------| RB [[DDorriionkkivinnggeWWaaetteerrrPPsrrooeccssseeedd [TCu1 2e0p5x fr 1--_p ---- {p--en--eeeJppeepne]| [MC [p 1 ene] nN [[DDrriiekkiinnggWWaatteePPrroocceessseedd [DringWat Processed [[wMCa22aa [MC225K [DrinkingWat Procsed_[MC221 [[[pp 111 ecqe urwe iepercr tpetp] m------ [b1 ecnurwaer Booed [[rDirsiknkiinnggWWaattee PPrrooccesssseedd _[_[hGMiaCn2s0am 1[1 TpbreainmVa--rpre--an----]----| peur ---- Boom E DrinkingWVaaerrUUnpprooeceessseedE [v McCT s [e E p 1 eo un w-- aY eg pTe 1e1e71 --a 1t.-- -- -- un [DDrriiknikinnggWWaetrerUUnnpprroocceesssseedd_|[MCCo2oi195p [1--11 ------------p--euJr pee| ,| | ' [[DDDrrriiinnnkkkiiinnngggWWWaaatteierrUUUnnnppprrroooccceeesssssseeeddd[||MMCCC22r1169KK [[[111--[I-- pbpece usurnwuaeierprpean--------|| Bese [DrikingWaterUUnpnroocessed[TC[ vaoiso1 n -- 1p ------ e --p-- eur-- e p-- e ----| = [DDrriienkkiinnggWWaatteerrUUnnpprroocceesssseedd[|MMaCt2oInH [ [1 1 Docu p waterpian ----|| ag [ooWaerSieml Twice [1p -------- BR F[elWWaaeerrSsiieenml-- TwweCsaonp [[p 11 een-- pne-- ee----| N FFlpeWWaaeerrsSiueend Fo Waersieol [T[ waeca1k----[1------------jjnepenee ene| IME20K [1 Timon Final ieldFieldRRpptt CleClveleanldandTTNNDeeceastAL & lle Batielle 00102" n ~nF~ao:s ' Approximate Total Volume Location Collected a (en var egra Collected (L) or *Sediment Mass [TapWaterSiem cami [1 Thimpiorim | I Tabtaple8.tCeornStuienzu-- ed I[Me MCCBDT IE1 TT -- DDeecuuusrbpoonaautier | I EE c17S a Ei-- 1-- BN [[ToSpWaeterStitses fIiMCe23sH1 hi {TeexaacocGasnSaueton] WN [Seren [SurfaceWaterSte#1 [SurfaceWaterSte#1 IMC202B [1 | TennesseeRiver | h|eMCm20s38 n[h 1o oe|s Tennessep cRiver s| [SurfaceWaterSie#1 B [p[tSeuefaveceWWeaatteersrSSiuteed1#1 [MC205B [1 | TennesseeRiver] [TR MMCC2300IKK T1T H T|iTomeaecessesecectnRneeiver]| WB [[uSutrfaaceWWaatteerrSSiteem [SbeVuersen [[MMCCAI0SOKK Tver [ [1 T eTemmeeuueeI ecrriierr | aera J E [fae ceWerSie E[[ -- Me30 T -- TT= eT -- mer seshie-- r-- E[II SEue to WraterrSiewT 2-- [C MC306K --[I1 ------ T TcmeYuecrir-- -- Bowmen E[uI e ta WaterStes T[MiCeHOsK [-- T-- efm keTte e-- ] BN [[SES edtimeevni teesee n m Twl eam_ 1 [_ or[MCO rTeemeeI seeshrie0B [SedimentSite #1 BEEr -- [SedimentSte #1 |MC210K [200 R[MCo 2TI0THSa [200 -- TemmesseeRiver FT |aTemeesrsT eieRieve-- r | BB [[SemdimeentSten2 vMCoAm h a0 oo Timeseorip ir Boome [SedimenSes I MCATmHS [2007 -- wenn T TemeT esrier-- Gee I [EOE eTWEMun --[Crae s [-- 1-- S TonTCerLyeAwr-- -- ETS [POTWEfuent |MC240K [1----[byTceCeawwi-- s 0 [POTWEMMuen: n C[PPoOmTWWEEMeuenn IMC22K TIMeCa2sOH [1 bnCreekwwir | [[ 1 TTbye Cresw kwwiw r ]| n Foal Fel Rp Covelnd TNDear AL a2e#BEaatnlcehlcle..000102 PRageeniso I al 221Wil [POTWSludge CollectedM(aLs) sor (g*Sediment 7 <7 7 J [MC2a4B [200+ |DyCreskWwrr | `Table 8. Continued [MC2#H [2| 000DyCeckwwre| juet Surtace Water' [MC28aB [1 [FmCreek | [Quiet SurfaceWater [MC28ak [1 [HmCreek |" [QuiaentdSiurLfeaaccehWaateter [[MMC2e8asH [[11 [FMmorCgeansCkon_y_La_na_i_l____|| [[CCaannddffiilll LLeeaacchhaattee [[MMCC22335sKH [[11 || MMoorrggaannCCoouunntiyy LLaanndafitlill__|_| [OrbanAir(Vapor) [MiC246 [Fier | [UrSbaamnpAleisr(aPearntoicuplaateo)rf i_tc__Mu[lMt CCi2ty4S7tu_dy___[1PUF [DpCeckwWwrp | | DyCreckWwre | 43 Instrumentation Results | AMi3r-sMaCmp-lFeLs1wetrhee aciorllseacmtpeldeurscianlgibaraGteinoneriaslaMcecteaptlasbMleoidf elit iPsSw-i1thaiirns1am0p%leorf.thAececxopredcitnegdtroesSulOtPs. | Tofotdheetsetrumdiyn.eTthheeaicnciteipatlacballeibrreastuilotns caucravleibrreastuilotnedwainsacnonRd?ucvtaeludeionfD0u.x9b9u7.ry`Tphrieocraltiobtrhaetiionnitiation curves generated in Cleveland and Decatur had R? valuesof0.997 and 0.996 respectively. The } `fpoerrCcelnetvdeilfafnedreanncde 0in%retcoo6r.d5ed6%vafloureDsefcratoumr,threesipnietcitailveclayl.ibration ranged from -1.92% to 3.70% | "pTrheeselnotceadtiionnToafbelaecsh9saanmdpl1i0.ngTshitee awcacsurdaectyeromfitnheedGuPsiSngunaitGawramsivner1i2fiXedLpGriPoSr,tothdeepraersutlutrseafrreom | Duxbury by comparing a benchmark at Battelle versus the measured location determined by the instrument. The difference the true and measured coordinates was 0.01 kilometers. | Following shipment to Tennessee the instrument was reinitiaized. This was conducted at the 1 ``mBaapysmoanntd HlootcealtioonnsoMfatyhe24l%o.calWiatrheai,nwsheivecrhalinmdiincuatteeds tohfatthiet wpraoscewsosr,ktihnegupnirtopwearlsy.disTphleayriensgults of the verifications for each sampling day are presented in Table 11. || ""Tthreuer"esaunltdomfeathseurveerdifciocoartdiionnatfeosr.ClAelvtehloaungdhwtahseavedriifffiecraetniocne iosfbey0.1o1 nkdiltohmeeatcecrsepbteatnwceeecnritthereia, the. 1 pwoassitrieocneidvatiangfdoarttah,etdhaeyDewpilalrbtemecnotnsoifdDeerefdenvsaelimdibgehctahusaeveitaadpjpuestaerdedthtehastatwehlliiltee tsheeleicntsitverument availability. The instrument did not record a constant position over a five-minute period and the 1 position appeared to change in a regulated step manner. ""Tthreuer"esaunltdometahseurveerdifciocoartdiionnaitnesD.ecTahteurrerfeesruelntceed ipnoiantditfhfaetrwenacseuosfe1d.6f8orktihleomveetriefriscbateitowneweanstthheat i orefftehreendciescphoasrigteiofnorwathsetphlaatnto.f tDhuerpilnagntthoeutvfelroifwiclaotciaotnedthoenspiltaen.t Bmaasneadgeornstuhsepesucbtsetdantthiaatlthe || Final Field Rpt Cleveland TN Decatur AL Batielle_po1029 pRageeis dthiaftfetrheencpeosiintipoonsiititohnes tfeurrtmhienratiinovnesptoiignattioofntwhaesdicsocnhdaurcgteedp.ipeSulbosceaqtuedenitnltyheitrhiavserb.eeBnasdeidscoonvetrhiesd | information verification was not possible for that day. | fAecectoarpdaritn.g tThheeQfAolPlPowtihnegmriesnuiltmsuhmavdeisbteaenncecbaelctuwleaetnedsuesdiinmgentthesGamaprlmiinngGsiPtSe.s pToshietidoinsstaisnc5e0f0rom CflreovmeSliatned1SittoeS1itteo3Siist32e60i.s8"2.29.S6a"m,ptlhiendgiasttaCnlceeveflraonmdSdiited 2ntotomSeiteet3thies Q19A6P.8P" arenqduitrheemdeinsttsa.ncTehe . | distance from Decatur Site 1 to Site 2 is 951.2", the distance from Site 2 to Site 3is 754.4" and the distance from Site 1 to Site 3 is 1,148". | `Table 9. Sampling Site Positions in Cleveland TN I [FiwasseeDrinkingWaterPlant __|N3516'015" |Wed453lo" | 114ValleyRoad | [Amoco GasSion 1 [TemesseeJacksCaf [N3sIaal" |N3seli38" [Weis320" |Wedsy2e0" |Rowes60and75 | |Rowes60and7s | t [HiwasseeRiverSie"|N3520408" [Weds 31" |FadsBluffRoad | "T=Transcribed data in log ik `Table 10. Sampling Site Positions in Decatur AL i [Hampontn | N3aadlaTM [WBPOUBS |Rowe6 | [[TTeemmeessseeeeRRiivveerrSSitee 3#2 ||NN33443570770.01"" ||WWB866S558128073" ||RRiivveerrwwaallkkMMaarriinnaa __|| 1 [DryCreckWWTP(EffluentSample)|N3#57315" [Wess |Highway20 | [Dry CreekWWTP(AirSample) |N3437204TM |W8650538" |Highway20 | 0 [FinCresk | N3a3so4" |WBes7556" |Country CubRoad | 1 `Table 11. GPS Position Verification Results 1 Final Field Rpt Cleveland TN Decatur AL n 37BMaotglTeiloleook 00103 i is at---- i Fagects 44 Communications I 1 wmDueunrrieicningoptatelhde.ecmoTpmhlpeolyseeeteicsoonomormfuttnhheiecpauftbilieilocdn.ssuwreverye,csoenvdeuracltecdonbveetrwseaetinoBnastrteelglaerdsitanfgftahnedsvaamrpiloiunsg effort i cIHonomsCppliletevateleldwa.noduP,ladTuNlb,ePiCsthesintetfhdeiGraAesycstlilosyrtofafrntotmMheaCnoCalFguDemrbwuoasfsCiilnnetfvhoeerilrmaennddamtUehtai.tliaWtideeosnWmauatstiteonrentDsoiuvtriheseitSohtna.tpJtruhodives'iesdfefdort is . 1 maps to pumped the facilities and to the POTW. reiterated his offer to allow us to sample the landfill leachate as it is 1 On May 21, 1999 a call was received from Kem Carr of Decatur Ulities indicating that he would not allow the sampling tooccurat the POTW or Drinking Water Plant if he wa 1 ciaonwnfaforiredmeoneftditaohlfeittsyhietaucgalrtiieeonentm..enIFntolrrleeovswepaiolnnisgnegtthtoehecthoiendvesenirttsiuatatytiiooofnn,tihtMewaacrlsciiedanetcNwiiodsuehdlidobkybaetwhdaersacflctioeendnttaaancntddeodBfaaftesntrdeenldomlteatodtheMart.a f cClairern.t'sA icdoenntvietrysawtaisonrebveetawleeedninMsc.onfNiidsehnicoek,aaannddiMnrr.etCaurmrwreerseulatledloiwneadntaogcroelleemcetnstaimnplwehsicaht tthhee POTW and the drinking water plant. The agr s1a99m9p.lLinagtetreaomnlMeaadeyr,2M6r.duCrairnrgiandciocnavteerdsathtaitoenheebmewetanwntetweeandsMtcoro.smpCpealarekrtteaodntdohnSecWcoletitdennMteadscidoreamcbytleyMr.a,yMtrh2,e6, i CMaarcrodmibreecrtliyncdoinctaatcetdetdhatthehemawnoaugledrionffotrhem ltohcealprmoajencutfamcatnuargienrg oplfatnhtefsoirtufautritohne.r iOnnforMmaatyio2n7. Mr. i dMurr.inCgaro'usr veimspitlotoyetehes faatcitlhietyP. ODTurWinignqtuhierecdalsiebvreartaiolnotfimtehseabaiorutsawmhpalterwMeiwcehraeellDooekcikn.gafnor I atshseifsatcainltitsyuhpaedrvdiisscaohtrartgheeepxlcanetedaesnkceedisfiwn ethewererceenstamppalstindguefotroMloolcaylbidnednusutmr.y iHnpeutr.evealed that 1 DfTaehcceiarlteiutwerseartnhedatnCowleeovrteehlesaranpdme,prltmeiednm.enbtDecurorsnoivfnetgrhstaheteigcoeonnuserrssauelrorpfoubuclnoidlclienicgntqtiuhniegrsceuodrlflaaebccoteuitwonatthoeefrsssaaammmppplllieenssgaeitfnftobhroett.vhaTrnious 1 each case a general answer was offered and all interested parties were satisfied 1 5. PROBLEMS EXPERIENCED ANDRECOMMENDATIONS 1 During the deviations wceolrleecetnicoonuonftesraemdples from Cleveland TN and Decatur AL the following QAPP i * sfThohriepnpeQexAdtP-odPnaytShedeceltsiiavoemnrey1"d2..a2yIsntahbtatoetsthhtechiyattiwe"essraleomgcpiolsletliseccawtlieldpl.rboeCbllseehvmiesplppaerndedvasetantmthpeeldeetnshdewoe`fsraeemapcclohelslceofclrtleoedmctobineo.inngd.ay 1 Tuesday May 25TM and shipped on Wednesday May 26%. Decatur `samples were collected on ! Fiinanl alFiFei ldRptCleveTlNDaecnatdurr AL Bailie 001031 Battelle ( . Probicns prec nd recommenPdautgioents `Thursday May 27 and shipped on Friday May 28". Battelle project leaders have indicated that samples can be chilled (on ice) overnight and shipped the following day when adequate i time is available, and that this change to protocol will be addressed in an addendum to the QAPP. | The samples collected in Decatur were shipped on Friday May 28" and were not specifically `marked foar Saturday delivery, resulting in a4-day period in transit. Samples were delivered Tuesday June 1. Prior to the next survey logistical preparations will be in place . ) for Saturday delivery to recipient laboratories. | Battelle's Sampling Task Quality Assurance Officer, Rosanna Buhl, conducted a field audit during these surveys and has prepared an internal report to improve field operations and ensure full compliance with the QAPP and SOPs. In response to Battelle's internal audit, the field crew 1 will redesign several field log forms to help facilitate timely and accurate data recording. 8 Final Field Rpt Cleveland TN Decatur AL 2petBaetolelle 001032 1 Field Report Addendum -- Cleveland, TN and Decatur, AL | emmy Atmospheric SamplingDetails. The following details are included here to completethe field record with 1 Chleeavdeqluaanrdt,erTsNl:ocaTtheed aaitr5s5a5mp.leOrcaotetehiSstsreieetwas positioned approximately 4 fect from the fire department . | enn Decatur, AL: The air sampler in Decatur was positioned approximately 3to 4 feet from the Dry Creek ` ses Surface Wat Sampling The following details are ! included here to complete the field record with respect | CS leveland,T:E The staI wtcollecteS datexch of3 within2mfshor 8,05 mdepth. Re DVeictn,mALe: sThhesfecn 0w5amedcoplliectReed fpomnthedfoscoinvoes systeme wa coletdestanchyf hhee 33ses I ARdodaidt.ioTnahlelys,aampsliengwleas"qauliseosccoelnlte"ctweadtewritshiitenw2amsosfasmhpolreed iwnitchai.n0F.l5inmt Cderpetchk.acRcee-sssuesdpefnrdoemdCbooutnttormy Club } sediments were avoided. 1 Kel andsa Doo OriJeolelsy s - 001033