Document KGVm47Ea1Ea77V8bJJYEG3M5N

i AR2R6 ~ 1234 RECEIVED... : 21 me DECEMBER 2002 FREE SURFACE WATER MONITORING REPORT FOR WASHINGTON WORKS FACILITY AND LOCAL, LETART AND DRY RUN LANDFILLS WASHINGTON, WV Dac: February 2003 ProjectNo: DEWWIAZ301 18983632.00028 18983633.00026 18983634.00026 CORPORATE REMEDIATION GROUP An Alliance between DuPont and URS Diamond Barley Mill Plaza, Building 27 Wilmington, Delaware 19805 g CONTAN aim mm, WVDEP 17201 000155 S Surface We ater Monm itoring Ref port oednowsTaTt bablleeoo offCCoonnn tteennttss : TABLE OF CONTENTS 10 INOQUCHON ovr sess | 20 C-8 Analytical Reporting... S.J 3.0 Washington Works Facility ................. ress sss 4.0 Local Landfill..ccvuveoeceirsseren ssn 6.0 DryRun Landfill. EE 70 REFETENCES...rvvvevterosse es -- 8 Table 1.0 Table 2.0 Table 3.0 Table 4.0 TABLES C-8 in Surface Water-- Washington WorksFacility C-8 in Surface Wate--r Local Landfill C-8 in Surface Wate-r Letart Landfill C-8 in Surface Wate~rDry Run Landfill Figure 1.0 Figure 11 Figure 1.2 Figure2.0 Figure 2.1 Figure22 Figure 3.0 Figure 3.1 Figure 3.2 Figure 4.0 Figure 4.1 Figure42 [na FIGURES Site Location Map -- Washington Works Facility Surface Water Sample Location Map ~ Washington WorksFacility C-8 Concentration Surface Water Map December 2002 -- Washington Works Facility Site Location Map - Local Landfill Surface Water Sample Location Map Local Landfill C-8 Concentration Map December 2002 ~ Local Landfill Outfalls Site Location Map-- Letart Landfill Surface Water Sample Location Map~ Letart Landfill C-8 Concentration Map December 200--2 Letart Landfill Outfalls Site Location Map --Dry Run Surface Water Sample Location Map Dry Run Landfill C-8 Concentration Map December 2002 - Dry Run Landfill Outfalls 000156 Surface Water Monteorneg Reeport TaTabblleoofCCoonntentss APPENDICES AAppppeennddiixx AB.- CLhaabionr-atoofr-yCuAsntaoldyytiRceacloDradtsa~RWepaosrhtisng-tWoansWhionrgktsonFacWiolritkys Facility AAppppeennddiixx CD LCahbaoirna-toofr-yCuAsntaolydtyiRceacloDradtsa~RLeopcoarltL--sanLdfoiclall Landfill AAppppeennddiixx FE LCahbaoirna-toofr-yCuAsntaoldyytiRcaelcDoartda~sReLeptoarrttsL-anLdeftialrlt Landfill AAppppeennddiixx GH LCahbaoirna-toofr-yCAunsatloydtyiRcaelcDoartda~sRDerpyorRtu~sn DLarnydfRiulln Landfill ---------------------------- S Stace We ater Mante aring RepoS rt tedeomtine Itnrtrooddun uccttion 1.0 INTRODUCTION WDAeepsmautrltVtimir-egmnietndioiafaDHceeopanalstrehtnmtaenondrtdoHefrum(EOanrvndierRroenNsmoo.eunrGtcaWelsR-~P2rBo0tu0er1cet-ai0uo1nf9o()rWwPVuaDbsEliPecn)tH,eeratelhdtehiWne(tosWtbVeDVtiHwregeinniathe WBidhPeenHtt)hiefairnedtdaheDruseePrhoianesstobofenerneNqoaunvierimemmbpeeancrtts1o5an,nd2h0ut0ma1sakn(sC1ho0enasbleetnhpteaOrrfdoerrm).ed TbhyethCeonpsaretnitesOtrodedretHeRr.mi.ne reenlveiarsoensmoefntamfmroomniDuumPopnetrfolpueorraotoicotnasnoatattehe(CW-a8s),hiCnAgtSnodnNtuhWemoberenkvrsi3rf8oacn2im5lei-tn2yt6a1an,sdattohreetshuelt of associated landfills (Local, Letart andDry Run). LeToxhtoeevnCetoronsfeseeCn-it8nvOeirnstddiergriantekisiotnnasgblawianstdheerad,cttgihvreiotCuin-eds8wtGahrtatoeruw,nildalwnbadetsecurornfIadncvueecstwteaidtgeattroioaatnssaSentsdeseatrrhioengupnTrdeestaehmnec(eGaInSdT) `Washington Works facility and the Local, Letart and Dry Run Landfills, APthonilslaupdtodarintttiioDonnioaslfchctaohremgpCeoonEnlesienmntiotnfaOttridhoeenr,CSoysnpsseteceinmfti(cOWroduVtearNlrPlesDlaEatnSeds)topouettlrhemetistW(esosautmtfpValilirlng)gianrrieeaqtuNoiartbeiemoensnaatls. In monthly for C-8 by DuPont. mpled SPauunrrdsvueevayan/ltGuratooteuAdntdbawycahttmheeernGMtIoSnAiTot,ofTrtaihsnekgsCwoAan,ssBec,notmapnOldredCte.er,dT(tahDsrukePeoAnt:ats,Gkrs2o0wu0en2rd2ew;ap2te0er0rf2obUr)sm.eedaTnabdyWDeulPlont cAosmspeislsimnegnotfohfisEtxoirsitcianlgCG-roduantdew,amtoenritaonrdinSgurafllacweelWlastaetrtMheonliatnodrlilnsgaDnadtadeivnecllsoukpdiBenrdg a oeGfvratolhuuenatdtiwaosaknt,e(tDrhueMPohoninsittt,oor2ri0cia0nl2gC)P.-l8anTdah(teGaMscePocm)opnifdolrapttaihroetnoWfrateshphoiirsnttgwatasoks,nsmWuoonbrimktiostreifdancgitloCit-tyh8.eiTGnhIgeSrTofurfsnotdrwpart WaatansdthhqeiunalgranttdeofrinllylWst,ohrebrkeesgafaftnaecrii.nliDtTyeh,ceweatmhsbiersdrubp2ma0ir0to1tf,etdahnteod ttwhaaesksG,pIdeServTfeolrompeidngmoanGthMlPy ffoorr fthoeu.r monthsater msoanmptlhilnygfaotr tfhoeurWamsohnitnhgstaonndWqourarktserflaycitlhietryebafetgear.n iTnaJsakn(uCD:aurPPylo2nu0tm0,e2,200a2n4d).waGsrcoounndduwcatteedr Identification Groundwater Assessment is ongoing. tTshhaeimspLloriceanplgo,rttLheapttraerwstae,sntapsnedtrhDfeorrryemsReudultnisonLfaDtnedhcfeeilmmlbosenrth2l0y0(2DaetctehmebWears2h0i0n2g)toCn-8Wosrurkfsacfeacwialitteyr, and WiraRgoaagnr[e102 000158 . Stace Wate Meniorng Report CC38AAnnaallyyttiiccaallRReeppoorrttiinngg 2.0 C-8 ANALYTICAL REPORTING EhhxaepveeracinmhaleaynnttgiaecladlSomtvaeettrihotonidmi,en.mWeiPtlrhimooirdngtdtoeot1ne9,c9t1Di,oenlDaulwiPamoirtne,t.apnIednrfl1oa9br9om1r,eadwtohCr-ey8nutatinhlaeilzRyesdCisfRoaArtCt-h8e Danuaplyos,is `MNDpoevntetescgttioogmraet(riGoyCn,-wAEalCsaDbc)aomnbada.uscetBdeodat,nhatlhlyaetbiascnaaullsmyeseditsahwGoaadss cCohnrtormaacttoegdrtapthhye/EClHeycMtHrionllCaLVpaetbruoirrfeiactaotriyonin from 0.1 t0 1.0 ug/L with detection limits for C-8 that ranged ; [LCaeHnacs:aesMdtHeorpl,erPcaAtoi,nodniu.ncMtTeahdrecChC.-8189a9na9an.lalyysLtiaisncacfloarswtDoeurrPkLoawnbatosriantttroantshfeerarleldotfo 1La9n9c8awstheernLtahbeorlaatboorriaetso,ry. SuosminpgleGtCed-EonCDa nfoerwDaunPaolyntticuanltimleOtchtoodbedrev2e0l0o1p,ewdhoberynieEdsxeycvogeneltnoipnRmueeesdneattroacnchd,ontIdnecus.ctit(nEgCxw6yagaensnasl;ysis aSlnpoacelacyttseridosmiinentSwrtayatt(eeLrCCoi/lnMlNSeog/evM,eS)mP.bAe)rDtuh2aP0to0u1nttialanizddeosEpLxtiyeqdguetinhdewCrhaersgoucmloaanrttourgsacertaoepfdhLytoCT/paeMrnSfd/oerMmmSMfaosrsC5 for DuPont the analyses eIEaxsbyoegrvaeatnlourrayetpreoedrptlfsiocrCa-tpe8rerrceeisssuuilltot.ns bfyorctohmeplaarbionrgattorhy frieeplldicsaatmeopfleearecshultfi0edtsheamcpolrer.esTphoensdienrgesults sIfabmoptlhe rfeosrultthsataraenalleystsetihsacnotnhseidprearcetdictaolhqauvaentpiatsastieodntlhiemiptre(cPiQsLi)on, ctrhieterreipa.licate 2 ctIhofenosPniQedLeo.rrebdottoh hraesvueltmseatrethbeeptrweeceinsioonnecraintedrifaiivftthiemtewsotrheesPulQtLs,dtihfeferrepblyiclaetses itshan Q d[iffofneererdebsuyltaivsalleuses ltehsasntthhaenPtQheLPaQnLd,tthheeortehpelriciastneotis, saanidditfothhaevtewmoertestuhlets acceptance criteria. Q mlIeefsbtsottthhhearnceosrurliettsqueiaarfrletithaotae2lre0ae%sl.tatfiTivveheepteRirmcPeeDsnttihdseitfPhfeQerLaeb,nscotelheu(tRreePpvDla)ilcubaeteoetfwitseheceonndtsihifedfeterweod rteosuhlatvseis `measurements divided by their average. renceoffw afWniheleedxnscaetmehepdlepder,eacnEidsxiy1ognbecnrreirptelepiroicraattoseutrtlheiesnuhelidsgahreberopvoorefttaehrdebe ymseattmh,pelEelxayabgonredantloarrbeyp.roerptIlfcsirctiahtteeerariveaseurlfatogeporfetchiseion EwFonhsvueilnrtootnhnmaetenritessaaullbtoDv(aeftratobhmaestPeheQ(CsLaEmDips)lreae/pnlodarbtaerrdee.prleiCpc-oartterepedasiualrst)sisaraebroevceortdheedPiQnLthaendCoornpseo,rbaetFlieonawl,lyt,he historical results. FC-143 for consistency with MAnSaalniaqluyostiosfaeraecuhsefdietlod sasasmepslseaciscuarlascoya.naTlhyezeMdSasraecmoavterriyx vsapliukee m(uMsS)t.alRlesbuelttwseoefnt7h0e to FX Winton. 88 -- 2 000159 - 0 Sutoce Water More Report CC--88AAnnaallyyttiiccaallRReeppoorrttiingng m1a3x0%i,muunmleasmsotuhnetsaumspedletocosnpcieknetfriaetlidosnaimspaltelseaisstf5o00urutgi/mLes the amount spiked. The pAlralobovdriaadtteaodrpyiancSttkhaaengdeQasArgPdePOn.peerraRatetesidunlbgtysPoErfxocytehgdeeunirnea-srheo(urSseOevPir)eewavenidedwidnai-tnhadoiucusasatebeifltoihrtaytc,odumasptialnirgaentphcoeretcwehidetcbhkyltihset j2Eusxdyngogetedenduhsiaanbvtleheebfeioenrndtihgveeindpueuarrlaptroeesdvesiionefwctoshmuempmlpairraoinjecesec.twiAtlhltdhaetlaarbeoproarttoerdy bSyOPE,xywgiethn fheawveexbceeepntions SER Winington, DE ee eee 000160 : = SurtaceWater Monitoring Report WaWasshhiinnggttoonnWWoorrkkssFaFcaciilliittyy 3.0 WASHINGTON WORKS FACILITY osFuiitxgfuaoruletlfsa1cl.ol0lslswehceotrwepsrsotachmeesplsloewcdaattfieoorrnaConf-dtsh(et00oW1ra,msw0ha0it2ne,gr0tr0ou3nn,oWf0fo0.5r,kNs0o0f7ao,ctihlaientryd.c1h0aO5nn)g.eDsAelctloeomrfobtuehterisn9ee,. 2002, sWsaaVmmppllNiiPnnDggEpevrSeontptoe.cromMlisotnoNtroh.oltyhWeVsr0ao0mbp0sl1ei2rnv7ga9otf.itohnTsehsweeerloeouctrafteaiclolonsrsdioesfdrteihqneutsihereeodfuitbefyladltlnhsoetaCerosendssuhernoitwnngOrtihdniesr and Figure 1.1. FlTiiasgbtulerdeei1n1..0t2hpeprroteavsbieldnee,tsshittshhteeorCCi--ca8lacdnoaantlcyaetniistcraslautrmiemosnaurlmtisazpfeodrfowsriuttrhhfeatcoheuetwfmaatoleslrst. sraeFcmoeprnlteeardceshiunlsDtasemclpeilmsitbneedgrf.pirosit.nt ALpabpoernadtioxryAanaanldytBi,carlesdpaetcatirveeployr.ts and the Chain-of-Custody records are included in DECSRaoe Feb. 11.63 Wanington, DE I-- 3 000161 Surtaco Water Moritoring Report Local Landfill 4.0 LOCAL LANDFILL OSFeipgduurbseed2s.b0oyslthehoewsCstootnrhsemewlnaottcOearrtdiroeunnroaofftnf.hdeOthLneocDWaeVlceLNamnPbdfeDirlEl.S13,pMeornmitthlNyo.saWmVp0li0n7g65o3f8fi.veTohuetefsalflouiss CDDheoccsee(mmObbIeedrrY11S661,S,,22a000n02d2..00TAShn(iNsaedpwdoi)itniwoenrael spoaimnptl,eOdutfloertCM-5.1O2(0uL0te2aa,clh0a0t14e0()10,1wdwa)as,ss0ga0lm4upe(lNseeadwm)pp,olreadCnodo8non ocuhtafianlolsfacruestsohdoyw,nthiinsFpiogiunrtew2a.s1t.aisbealbeid-aLnenaucahlapteermIniltetre0q02u.ireTdhmeonliotcaotriionngspoofsetth.eseCo sr phTraeebsletenatb2el.de0 wipnricetslheutndhteess mtthoheesthCi-rs8teocareninactldydtaaittcaaaalfivrraseti.slualFbtilsgeuffroorert2.e2haecDphreelcosecemantbtisetorn ssaumrpflaecde.watTehresdamuprlewss. (fCorustthoedyuraelcosrdssaamreplperdoviindDeedcienmAbpepre.ndLiacbeosraCtoarnydaDna,lyrteiscpaelctdihavetelaCyr.8epocrotnsceanntdractiohn.maarp FWRaningion, 08 00-- 0162 5 S `Surfacew Water Me onitorine g ReportwswVewowfLe eLtetaarw rttLLaanns ddffiilll 5.0 LETART LANDFILL Figure 3.0 presents the Letart Landfill location map. Monthly sampling of Outfalls 002 and 003 (both containing stormwater runoff) and CapRunoff (which collects leachate and stormwater runoff) is required by the Consent Order. The locationofOutfall 002, Outfall 003, and the Cap Runoffsamples are shown in Figure 3.1. On December30, a2t00O2u,tfaslalmp0l0i3ngbuwtansoc-oflnodwucctoenddiattiQountsfawlelre00e2n,caonundtCeraepdRautntohfef.tiSmeaomfpslaimnpglwiansga.ttempted The C-8 results for the December surface water are presented in Table 3.0. For each sampling point listed results listed first. In tinhethSeeptatbelme,behirst2o0r0i2calmodnattahliys smuomnmitaorriiznegdrweipotrht,thaesmaomsptleretcaeknetn on 9/27/02 for the Cap Runoffsurface water location, was inadvertently named Stormwater Runoff. monthly The incorrect name monitoring reports. was carried through the October/Q402 This data point has been moved to the and November 2002 correct chronological spot under Cap Runoff in Table 3.0. Figure 3.2 presents the C-8 concentration map for the outfall sampled in December. Appendices E and F present the Custody records, respectively. laboratory analytical data reports and the Chain-of- WooSnmog ree 0--0--0--1--63---------- SSuurbfcaocewsWaetberoMnotniooorigntgReeopoorrt DrDryyRuRnunLaLnanddffiilll 6.0 DRY RUN LANDFILL Figure 4.0 shows the locationofthe Dry Run Landfill. Monthly samplingofOutfalls 001, 003, and 004 is required by the Consent Order and WV NPDES. permit No. WV0076244. (Outfall 002is a required outfall sampling location as stated in WV NPDES permit No. WV0076244. However, it was a temporary relocationofOutfall 001 and 004 no longer exists). Outfall 001 collect stormwater only. The lcooclalteicotnssosftotrhmewastuerrfaacnedwlaetaecrhastaem.plOiuntgfaplolisn0ts03aarne d shown in Figure 4.1. On December 30, 2002, Outfall 001 was. sampled. During the monthof December, Outfalls 003 and 004 were not sampled due to no-flow conditions. `Table 4.0 presents the C-8 analytical results for the December surface water samples. For cach sampling point listed in recent results presented first. the table, historical Figure 4.2 presents data are the C-8 summarized with the most concentration map for the outfall sampled in December. Laboratory records are provided in Appendices G and analytical data reports H, respectively. and Chain-of-Custody [teMesmRereno og0o0o0l1664a 7 Surface Water Monorng Report References 7.0 REFERENCES DuPont. 20023. One-Mile Radius Survey and C-8 Sampling Report and Ohio River Public Water Supply Sampling, DuPont Washington Works (December 2001- . February 2002) January 2002. DuPont Corporate Remediation Group and URS Diamond. DuPont. 20025. Two-Mile Radius Survey and C-8 Sampling, DuPont Washington Works Facility/Local Landfill, West Virginia (March-May 2002) August 2002. DuPont Corporate Remediation Group and URS Diamond. DuPont. 2002c. CompilationofHistorical C-8 Data, DuPont Washington Works Main Plant andLandfills January 2002. DuPont Corporate Remediation Group and URS Diamond. DuPont. 2002d. Proposed Groundwater Monitoring Planfor Washington Works Facility Plant andLandfills January 2002. DuPont Corporate Remediation Group and URS Diamond. WDiEmCigSiWonM,Rd0o8c Feb. 11.03 000165 8 TABLES 000166 --- Summary ofTaAbnlaely1t.i0cal Results: DuPontCW-a8sihniSnugrtfoanceWoWartkesrFacility Washington, WV e CUTLEe T067 T inmseerT T G 0------------ 7 7 eee-- ---- -- es-- -- essmveee Tg 5a-- --f ] --aL seee--1 T -- 7 a-- ) i CUTFALL002 [ami oosoerT ---- s 5------ ser 75 1 7 mee-- ---- -- 1-- -- -- -- -- E m=e-- r T -- e o 5s-- s n ee5e 5---- Ii Lee-------- 5 ---- I m mst--e -- a -- I --1oa -- -- 7 s5e 51 -- ------r ---- e e aoe rms] OUTLET 303 [ mmee u T n a e sa7sveer---- ---- os5m-- -- --] -- em ommeeTm oi --] ------ e oswm ee T T5 om p ---- E [o7 L mee-- p -- 5 -- -- -- [mazeooetm To5n 6 --s | 0211103 fof2 ------------ 0001677 Table 1_0.doc `Summary ofTaAbnlaley1t.i0cal Results: : DuPontCW-a8sihniSnugrtfoanceWoWartkesrFacility Washington, WV [spTe T. [7Bw 7 sw CUTET 007 m [te oemee e--s+ 7Tc so e m7e---- -- esae meT T o s g --m1 e---- we -- I m -- e-- e -- [ amseea T -- o sse impe [e-- ai se-- ---- g-- y-- -- emeerTy asaerTg wm [ziao nomseorr T ate oog zmn ----e --]| [oI mseemee-- mTao -- m e --m| -- Emsesee-- T oo s -- -- r ] m ee oo sw ] -- 7-- ooiw s CUTET 708 [me7eo ---- e igaw-- nr eitneser T T s s --e -- -- --177-- -- ---- -- -- 1-- -- -- 7 Emaewee-- m -- 5e%m-- mteoee 5 m osee T r s s HerTom | NNoQte=: ANnoaqtluyaQtnuitacinaftliicfmaitaeibtolhne.o(dLDOceGth)ea.cntgeeddatasaocfonNcoevnetrmabteiron20a0b1ov(eseteheSeLcOtDionan2d.0bfeolrodwettahilesl)i,mitof 000168 02111103 2012 ---------------------------- Table 1_0.doc | SummaryofTAanballey2t.i0cal Results: C8 in Surface Water WaLsohcianlgLtaonndf,ilWlV J | OUTFeALL 0e04 eT m) |__TamreuesrT ----v--aptos d w --o ------]] -- I 7 rr-- -- -- r r -- -- r T-- -- | 1 am>eS -- -- ot-- o co-- -- n-- go i [w-- ee---- ie-- "CUTFALL 004 (0) ee 1m ps---- | 1 a E ee ---- S e 7 7-- e-- -- | To---- -- { Fa -- -- ve7-- ---- e-- e -- -- i a ime m 7 e ee | i -- m 7 er s -- ---- -- -- ------ | CTFALL005 oy mwweeeer -- 7------ -- {i i 0 930mS e Te -- e 2fowco-- ne at-- ons----| 7 -- 7mz-- No=7 -- orwrconditions--------] I OUTPALL BS aves |-- a tara -- me -- -- ] {! e 7 5a 7 --7 m 7 --| i r7e:7 ------ -- 7--ee--| -- S --i7aew7e-- -- e a -- <-- re -- -- -------- F 1 azemes a -- 7 A --e --| i ---- -- s [Enmaee meers 5 8] 0211103 1or2 eC -------- Table 2_0.doc 000169 ! ` `Summary ofTaAbnlaley2t.i0cal Results: C-8LIoncSaulrLfaancdefiWlalter Washington, Wv : } COTE orTe rs en T r es e -------- -- e smoer-- e i-------- : | Faree a eeT -- a -- --a -- -- ------ -- t m msee --T -------- e sr r i [oe ET |f ae eos] - Note: Asyamethodchanged sof November 2001 (eeSec2t0 oirdoeanl, o2t103 - 000170 202 Table 2_0.oc Summary ofTaAbnlaley3t.i0cal Results: C8LientaSrutrLfaancdefiWlalter Lotart, WV ----r r -- T an mmaaemeee as] LemmoLo ---- --So-- ran ---- [1 aaemen -- ----------]| -- ---- -- I amsmaoa----g -- ---- wt s-- e-- --] --] [ 030n 0 a c a TaoGm oi o-- --n --e --]] oe tefcaaey I I moo -- --| e mameorrre 7 ow s -------- -- eme ie a------ 7 oea s -- -- r1 e-- -- * e| = mwsoer a------ r a r1m1 7 aa e -- v -- -- -- e swe 1 roa m -- r] -- 7 a eee --s-- e---- --] i eammon N --ae ---- --] Note: Analytical method cha[ nged o7 m fNovemby e7r 3-- 001 (--x7 Seconr7h7 foprGeoToe)-- .n 000171 **t*ShTahemispsalmsepaslmwpelseerrweiaavskeeidnnaaatdtvtehhreteeranetbslwpyeancratimveaednsdSurtwfoearrcemewanatoteterarsRllouycaptnei.oainns.hHeowSeevpetre,mdbuersfioQ0a2 ererpoortbythecouricr, 0211103 Toft Table 3_0.oc. ee `Summary ofTaAbnalley4t.i0cal Results: C8Driyn RSuurnfaLacnedfWialtler Lueck, WV : e SET r ---- = e er e eee -- y me --e -- s =-- ae a Ere a ---- E e ewe --S r| = et7e| n seeee o rs i i 7 a.so -- mT mnr ie-- -- m ln or 7e i a 1 -- + -- h i 7m 7 ~e ~ PROPERTY SOUNORRY e o 7mn= e e "r s 7 --| F im ome ae a rmeism -- -- [esTp] ati Tor - 000172 Table 4_0.doc 5 . i `Summary Table 4.0 of Analytical Results: C8 in Surface Water . Dry Run Landfill Lubeck, WV i: r STREA SANPLNT G PORTH eThasseoe67T gy 8y -- : -- a -- -- -- he-- -- -- om ---- -- : i [ I esw as -- e- e om-- --s ---- STREAM SAMPLING PORTE | -- 1 v 5 '!i . -- I m 7 -- -- a -- m -- x-- --) me es :- E mem w -- -- [i s-- oo2 s [ -- --5-- -- -- ------ --"m7e---- -- -- -- o7me-- ---- -- --- -- geeoser ass -- "5-- s----j POND URGERGRAN -- raosw-- ae -- sg -- amme 5 -- -- ------ Note: Analytical method changed [zao--se-- -- ----] a5ofNovember 2001 (sec Secon 2.0 for demi 02111103 ee 000173 2012 Table 4_0.doc ' FIGURES ee 000174 H+ = So =: i - A . \ i. ' AT LE Loop RE i ' Coa po Ea l = N-- J fo. 117/ Tela, + WASHINGTON WORKS TT VI figvi2 La e T FACILITY oie - - - (loeI sr bleoEEma m \ t R[veEraEve o Tn . e Ia Tor = Mr mee Ibe 0 | i/ 8 CONIA CE Trae. xFeFtFX e f A Ci LEN a : WELT Be C.K SN A | SITS SS ~ ySEvFAfTE EEE xEaSssaShaCXEEUEXpCxh . =e~ eb ke So Sed gir end 7 = RC ph Calg BET eel I. amp EEruma ees| SntOmtTad | EeapTpe eeTe ee] T ee WW T rAd T i Si Hl aneor | ~ \ wma merons :- amN use | e EETEe a e ET i OE AE; Te | CON ere ' . to - J J ca 1 0j%r, 4= | el NT, : Eu | | |- a |. |: !4 5 LEGEND i WATE QUIFALL SAMPLING PONT !. i 000176 -_ /ww a a |-- sors ane ~~. : Sn, |S - LA - tT : . Q eT wf, Re o 0000! 76a 700 -- 0 700" aw [=E.EE]| Corpopruatne MResmedbieattwieonn Group [DuPoWnotshWiansghtionng,toWnestWorvikrsginFiaacilty| ERE ETT i | - Loe, pe 1i wr | 7 we, oR meh oSeae 1 } 4 : = CE [ we . 3 Pa || i CN eg So [ Fat," |r "om yo Hl | iZ RL To 4 RT L :a3 A2 rT TY NA ||: ye - IT 11 11 URES QUTFALL SAMPLING POINT i || 000177 nE e e b .= |. | o, Teg, < | | i scaie 00001774 Fe = ed 700 o 700 Ew SI Te [=| eT] CorvoratoERomTeda,tion Group [duPoVnetsmWnagsthoinng,townestWorvkesginFgacity Fem] mmmrnitnd [SeTemTmsTe [Sr =\ To A PES vk 5 tig - 0% NOE : E: R B/E JSEL.P R\.NE-E. aR ~~ my |-- T ' Ponti \ . . p << "E Ea Wel == & Li NE Tae RT TD Li = le, L [FeoAlgleT em SE s N Wi eel, PROPERTY -- swyy3 il RY or TRE LINE~=rTwNu8le,, Sur Les SE edt wt rr, ~-- Te 5 TEE eh ae SN Se re? 7 ooos7s |am Of rom | , SAE Coa . ST 08meson" EA Sc N : i, og CE nin SE A pS Te : Vl RTA AEST A PoE Ne vx4 ro SFNoER)EAe FCSi pl, KE S@NODCARLI* L~ BE2D J 5eAadp dvss PEU- RNNIDEMIIESGhTRyLELS RSE TM N" ">5i. h lN : ee ~ grlr hPE ARTTRe EiWp CFOERaEm NSNTdLE[nywe EE roe 00 ee wameny Fes TeTE rr | od ; CIE ramen | | ZC id : -- Mi| - TEee Lo [ sme noo Ss amon || LN 1 ZO | I] 7 [=PAo ZZ A 2a a fwe 200AEN NS Yif2 |7 n WW ooo T|I2 XNREI NE S ea e 2 SR2eC7 = L C | H "id Li!ll I lW Ecse e y le ssnkFrse TY C| o C= alA e))NFIE ORER ( ey TNL 000179 Se SCAL | a em |! i 3 Ew Me owv02 Em NE = i Wi a Tel Tl PAT TA] Ae "Sep SSE NOW We eo = 7 oy Ra he i 0 a7 E rN C =N Wi I [lrS N57 F VE Ss a Oo EE TT ene Cw e NrFP y Nie I R=E LESS AE NNN GE 2 a RTT 5= 3 ON NAN SYN DEAE IBN SER Sa = [ E---E_-- SSEe SE?[TeE Tom E [em [ar] | == Ned IN A LH ET Np LL ntAl ss J rA "INA ied il N ) gi : \\ T LAN[} Tif rEkLT 3 \ ' ga INE Fe] " NE| A NFE FE 2| ! i 1 [ FZ Gi FE a: T --- Rapr oYcpel T; E4) d ( iAbi(NsEA ONs Faflspia a A erE po +8& 1A-1PN6)TEARTITELREAND--EF~ E px,5dAQVoyN w oSaG se/sJan Li. EF S DYy5E i SSaE 2 JfLRSS2e40VSfs IJs es "7 i~ NiARES Hes h Y N LI * ns F DY = 4 ds pon] 0ES 2 es GL {17 S ES = EE N1\g SSoeiSU nn 3 | A LA S i TY e {Ls & F Dl f | IN Re <N ho NN / "Ean roe i ie So == T$0 aNy ayp | TnEEs &[ron we| . I [ Las 2000" REE,arom 22som oie Br 0 00151 ITE LOCATION _ i Loviz) Ske [] = 5er d a L | ANN ed Wo it P SR = = Th i =< |~|8} _ Es nL 3 So, y pl ig A a XN NN RN i 8i], NN FE (Ie = panS--ee e EN --= I 3 es "qi | 20001834 -- 1 -RAeeeeee a eeeAe i:_-Zaifi-LE { == Rico Nl EEN p E R a E sRE jdabehe LF ya a ho es SNES GA i 7 Se bE 1 h | i RNC Sime ie Re i 7 joi ik Ce (ic MNS NG Ssgrerollil AL) EF pr00 : i 1 Soe anTa OMTHE RECW,Y ;ee 1200 0 IE la Ra T Xe = "I[4 Heo a Ae a (= 5 >) Ne W A ee ee JE] G= a I \ aR CLS0(a LS Re i SEou NT> =a| oe oa oDNg R aR Si ge Wiz A& 2 Sp e e \ I B Hh3l eLA e a Vo GK ke oCCa =) Cha ia So F AHI Eo N7EaR 9a dea aE AolEeF< = 4 =~ is E aea i i DA 1Wa Ja7 Es == We WJZ dE SoA NE ah | a 1 Se a s E ll ENE. 0 TS) [A a ES Bo | @ = NE \Y oN vE icE e oaNN lnnSlee s Pae) = ODNEN 7 4/ = CY, A5 LaRLACa F rad VBN % --a ey 7 oe A BA E Z 77 ANNE ol a ~ ! [Le E > T fe || a Corporats Remediation Gro[sie LLoOcCaAtTiIOoNnwMaAeP| --a sl ~ 0000 18a5 _ Emmemevmy FeTpe=cs Twer=t vTia ESE oa CIS ps |= NN HnAo Ta(W7w )NE fii CHA 1Jpt HEN i a he LE ~~ TE ZN nM Zr iii Fd A ESh A ey yl Gr nN ay dar 3 2 NSqm/ - AH \ E is TN mn = No iy = \ N 7 pal RN VA HER IX -- I ~~ LAN ) Preset 000185 | fr-- aN are : Td| Sos NP ae Ll Cem A TE EE 3 : = rE No ocr hes GT a NN NSA SW SCAN poe = 7 Seni LW ZA TaN E Rl Sr NNR h hel) y FHASR NE: A =n ETN, 2 NSA NANG 2 U =2 2)ANNR E e ES sSE F N_ Sh Eee =C=== = PCNa D. N\Bi Ee ESN N ERA AND = ~ a NS Ah ES) Ce Lalihe] a sd Se J CaN WW | aw ------" 0000185 ll EET LE | \ Iz . LE Jj A iE e Cl I REwfal pl LL TALL I Il Il il i Il Il APPENDICES 1 [ [ | i li il il. i 000187 qd | | | 1 | 1 | | APPENDIX A | LABORATORY ANALYTICAL DATA REPORTS | WASHINGTON WORKS FACILITY | | | 1 | | A ' 000188 i 1E en Ii XYeSsRESEARCH I! l Il Avaya sits washington rksGasamping rz | oma i{ DuPont Sample Identification yq wwczowarcer [ L ` | eL cWoWKo-Z-y sOnutmfaloel r0st0d3 WZ ural dam !| WWK-K-EQBLK-1 bi APFO (ng) a0 -66S8o 0 > NO [rA oomsA : Limitof Detection (LOD) for the procedure is appoximately 10 ng/L | no<topenocion NQ - Compound detected aat level between the LOD and LOQ. Result is not quantifiable, esas ars calcite acorn th following ora [ 1 o7a0 rrstrno2. yrtteomssrgpmat,conepmmmeefl U [oo iehsrom ad co yre daso ws 2501 rtdsn sortl adttrefsos En | | 000189 I [. 5007 Xess nan SEE APPENDIX B CHAIN-OF-CUSTODY RECORDS WASHINGTON WORKS FACILITY 000190 YL zSs JE N77600T0 EESEHis Boe B------ 8TH Tr I m EfE, RFeuies TIT i plied Co2Qs B Heor a [MEe HB0lAa5s5sS a: THR FN FENIRERE : gif ZFl EE H ERERE MES H5E Sgnuoal;be lie1 s e991 | 2 a Ly dllEE SEU SHENG 8 2 1E5H i PC! oCs HRHdAEIesl d14 SU| [= BH 510409 2 FE EAH Es] : SERRE | bd Ho '''Eis Je |onditnn [Ei3=e8ela gSvlls 14] { Sm g 33 gE wii SLE ARNE 18BI:4 El B2 1 a) o z w BH Ol 17 = [3H z APPENDIX C LABORATORY ANALYTICAL DATA REPORTS LOCAL LANDFILL 000192 EXys RESEARCH Proven Results. Analytical Results Local Landfil C8 Sampling 12/02 DuPont Sample Identification APFO (ng) LOLLCCLLL:-ZZZ--OOuOututfttaaalll 000000544 NONloedwwWCWeeesnstttrSaStltrSrotaaramemam 1102750000 9510 LLCOLL-ZK-EOuQtBfLalKi-0105 Old Central Stream 381N0D0 LCLCLL-ZZ-OLuetalcehta1t0e1Inlet 002 4881570000 Limit of Detection (LOD) for the procedure is appoximately 10 nglL. Limit of Quantitation (LOG) for the procedure is 50 ng/L ND- Compound not detected NQ + Compound detected ata level bstwoen the LOD and LOG. Result is not quantiiable. ND <LOD <Na <LOQ Results are calculated according to the following criteria v(IfaAtPlhDue)siiamrlpeoplsoesrtaaendnd l2a0b,ortahteorayvdeurpalgiecavtaeluarseisgrreepaotretredt.harIf2t5h0e RnglDL,iasngdretahterrtehlaatnive20p,ertcheenhtidgihfefrerence : r2Ife0p,tohtrehtseeada.mvpelreagaendvellaubsoriatroarpyordtuepdl.icaIftethaereablseoslsutthead2i5f0erneg/nLc, iasngdrathteerabtshoalnut5e0,dtihfefehriegnhceerisvilreesss tinhan 000193 2017 Xpomtsom rek nc] APPENDIX D CHAIN-OF-CUSTODY RECORDS LOCAL LANDFILL 000194 Zs = 7 090 ee | [TLTL; oxEf 2Qs ofw > x: ll >I5:f SZzo:l NE [HHH b H >r qeireeesenl |] A3E $F0l]ay)4d]%8 WE 2 Jd FER 32 CRE ks {Fbfr H; 25SH iXi He FBiiiidsi, fMie [13f55i5e55s8 ST9 ELE i1 3E . ly asluiiiddiyi (RE da)45) E sSGiHolNlaIdUEdfyssf | me H mmi r Z 3 PEE po Fda) iF (2AD :| |[ 2k |e 1 I i: , OR 3 : 2 5 BY TY93E3 Has 2 >31 li] of TE 5 CEE dE] SEE S|. HAE EB 0 JH Hel = 22 OJfN iy E cH] 2 BH wl 7] WW: ERESE i 2 NY 3< | ww S2 = 57 = EBHB E3]y .]. 2i EREEREFEI ==| H i 5if =z 5} 2 == qJ 33383303 E= Nve7 Ig] = Rd HS EER | SEE Pe S214 APPENDIX E LABORATORY ANALYTICAL DATA REPORTS LETART LANDFILL 000196 RYE ESEARCH I Analytical Results LeTart Landfil Cs Sampling 12002 DuPont Sample Identification APFO (nol) LLLTULkZZeCEOaQuptBLAKu0rT0a2l 1411750000000 no Limi of Detection (OD) for he procedure is ppoximately 10 nglL. Limit of Quantitation (LOG) forthe procedure is 50 ng. ND- Compound not detected Na- Compound detected at & level between tho LOD and LOG. Results not quantile, ND <LOD <Na <Loa Resuls are calculated accordintgo the folowing crria v{Ia1RtPlhDue)sisaimrelppoloserttaedhn.anl2a0b,oriahtorayvedruapgiceavtaelauroeigreraatpeorrehd.anIf2t5h0e RnFgD,iasngdretahteerelhaatinve2bp,ertcgenpt iefsorence r$e0p:hoenrtosedaa.mvpelreagaendvallaubeoriatroerpyordteud.pIfathare ablseoslsutheai2f5e0rannigcleL ias gnretahteerabtshoalnu5t0e,itfhereingcreetisvleersss than 000197 SSE Bon, isn 2007 T SnS APPENDIX F CHAIN-OF-CUSTODY RECORDS LETART LANDFILL 000198 C:| s | E----tca00DO0 EERREY 5 7 ---- gbHYey HHH Qs == nr Cg: 0. 44 dNCsSiiBl:IHEddg gSeilllhit: i [] CwSFRE Rrl FIMEGEReH Eg e [EER ma OLN: E: {| Toum s o Ssedib Ji EmaEa i T5E5 J g5) WEi E i T mH 3BMis fi [E[fi1gi32f22d53i83, Lriq 5184 312 Jso4 HAA1T0EEl gg [| SHE = i | PE 19Ny CEE EI Hil i2 4] wv = TE] She Af 2 Oo = 2 0 5 : : L239||| Ga He EE | 2h Sl E APPENDIX G LABORATORY ANALYTICAL DATA REPORTS DRY RUN LANDFILL 000200 Exvoen alyica RYE ESEARCH Progen, : Analytical Results Dry Run Lanfil C8 Sampling 12/02 i DuPont Sample dentifcation APFO (ng) 1 DRL-Z-Outlet 001 56900 Limit of Detection (LOD) for the procedrs is appximately 10 ng1L Limit of Quantiation (LOG) forth procedure is 50 ng. ND- Gompound not detected Na - Compound detected ata love betwasn the LOD and LOO. Result is not quanta. ND <LOD <Na <L00 Results are calcite according fo the folowing rer v(IafRltPuhDee)sisiarlmeeppssortantadnl2a0b,orhateorayvedurpalgiocavtaeluareoigrreeapterrttehanIi2i5n0a FnELD,ianrdeathveerrehlataive26p,ermceenWthiefeyrence e50p,tohrteehseda.amvpelreagaendvallaueboirtroeprordtuepdl.icaIfteheroablseossltuhtaf2e5r0enngclLe,ias gnrothteerabtshoalnut50e.dihfefemragncmetsveesss tihan ) 000201 0007 Xp Bion, usa L aEE APPENDIX H CHAIN-OF-CUSTODY RECORDS DRY RUN LANDFILL 000202 3z5 . T m =A TaTnE g ih 2 1k CE TE SL I] 5gg: o g: o HFi= H -- r H m r HEE HfE q Es [Fd :E EiE| 9: ; = i gE : JIA ar Gl SS=H:uRfiBENilEl; aSi if l: dis OSgSEiiaNlll:e:[as E| 3dGz2 == 8oG5hsEilRi lEEeo El|T: E cRt GI RRRERTRNIY gi fal] OE J :7 i !I1 i 3J YHi eEggAehL|LEE un c MHA 82 a(,31] :3 eHxfE:L 3 dE 25 EERE HEED HE7] E4%] 2wy = HHEals|||e5:8] 2 2 Md Bh HS EE: < Sjg E3 S 5 lk TE i =i S| e L :S: : Sli ; gL [UI am CiC; EEE 0 gr 90 HHHE Er CpggE tdkErr rr fe E EiE 2g:s BJS T T BffEi Baeiddi3idS wav : Nl. J SSiRIfsL]E LiEE CSOLilME : 1p i EET OG SSiEfN [EeE ly Eo Hm H :: $5 HHI 28 BE am | Jie BE g , i 9s Dsl AS HEHE EE o g Hl g =: A ER. E RINEHEE3gRe Z be] t SF< HEENIEE]EZFa x =U] firm Bed 13] 5838 | i 110g [[ 22=.01BTm= HHmHdZ BF E i, oe Eos JB TTT, tH TTT oHsE [fee 2[38:5288:235 P2 gBes [ITT HH dro 7 n FTI] 2 fBie Eig] (45585sesssdset . EL Ju] EN FEANRER 1 sik ed] CaNZSzl?H HSYEE NYdiEg2 8 - SAili: l: HE12 ]3 rk gs af 3 2 3 IH FANEIE J rEleHi OIHil egL dX8 8| = e= Hr H = i3 8 2 3 B | : :2 ESlER NIE WTEAT ell 13 iE wv 5 . 43 i z Br z g2 ill 3 SHEPEREENEE 2 2390 ov = = H4 3Es 7 =3 < g 5 = I] ] g wy |< = Hill 2 A MSs Js 12 = EZ : 2 Ld He !'2E: S ES E