Document KEZG3N3gGbnaB7DROKNvg28r

* CAS Number 754-91-6 3M Company A R226.057 7 Voluntary Use and Exposure Information Profile Perfluorooctane sulfonamide I CHEMICAL IDENTIFICATION Chemical Name: Perfluorooctane sulfonamide CAS Number: 754-916 IL COMPANY IDENTIFICATION Company Name: ~~ 3M Site Location: 10746 Innovation Road Cottage Grove, MN 55016 1400 State Docks Road Decatur, AL 35601 Technical Contact: W.A. Weppner Phone: 651/733-6374 Address: 3M Center, Building 236-1B-10 St. Paul, MN 55144 IL ON-SITE ACTIVITIES cas# Mig. (1997) Imported 754.916 0No Commercial Activity 0 Estimate the amountof subject chemical distributed off-site: % of manufacture/import If you have already provided the above information to EPA and itis stil representative please reference that submission here: CAS Number 754-916 3M Company 2 Narrative Description and Process Flow Schematic: o3rMgaCnoofmlpuoarniyneumtiolliezceuslaesp.rocIenstshiksnporwocnesass,SoirmgoanniscEfleeecdtsrtoo-cCkhseamriecadlisFpleurosreidnaitniloinqu(iEd,CFa)nhtyodsryonutshesize ohnydtrhoegmeonlfelcuuolreidteo, abendreapnlaelceecdtrwiictchufrlrueonrtinies.paTshseedprtehrdooumgihnatnhte scoolmuptioonne,nctasusoifntghethperhodyudcrtosgecrneaatteodms hbyydtrhoisgepnroacteosmsshraevpeltahceedsbaymeflcuaorribnoen. sHkeolweetavlera,rrfarnaggemmeennttataisotnhaenfdeerdesatrorcaknguseemde,ntboufttwhiethcaalrlboofnthe fsokremleedt.on cTahneadlesgoroececoufrflaunodrisniagtniifoincoafntthaemoourngtasnoicfcfleeeadvsteodc,kbirsaanlcshoeddeapnedndceynctliucpsotnrutchteursepsecmiafiycbe tchaerbloenngcthhoaifntliemnegtthhoeftprhoecefsesedisstroucn.k aIntdisppaorsasmiebtleertsoofstyhnteheEsCizFe pfrulolcyesfslusourcinhaatesdeolerctpreircfallucourroroerngtanaincd fmlouloerciunleeastowmhse.reUaslilongftthheesheypderrofglueonroaotrogmasnoifctmhoelehcyudlreoscaasrbboansifcebeudisltdoicnkghbalvoeckbse,eunnrieqpuleaccheedmbiystries can be created by further reactions with functionalized hydrocarbon molecules. p3rMocehsass.prAodbuasciecdbsuuillfdoinnygl bblaoscekdoffsluuocrohcphreomdiuccatlss acnodmmtehrechiiaglhleystfoprroovduecrt4i0onyevaorlsuumseinfglutohreocEhCeFmical i3sM1-moacntuafneascutlufroensylisfplueorrfildue:orooctanesulfony! fluoride (POSF). The starting feedstock for this reaction (Reaction 1) Reaction 1 CiHiSOF + 17 HF 1-Octanesulfonyl fluoride -- Energy ECF CoFuSOE + 17H, Perfluorooctanesulfonyl fluoride `mTihxetuerleecotfrobcihpermoidcuacltsflaunodriwnaasttioenopfruonckesnsoywineladsndabvoaurtia3bl5e%c-o4m0po%sisttriaoinghtcocmhpariins(endoormfatlh)ePfoOlSlFow,inagn;d a 1) higher and `CoF1SOsF lwohwiecrhsctoramipgrhits-cehaaibnouhtom7o%loogfst,he.p.r,onc-eCsnsFoaunt.piuStO5F, e.g, CeF13SOsF, CrF15SO4F, 2) branched-chain, output perfluoroalkylsulfonyl fluorides with various chain lengths, about 18-20%ofthe 3) straight-chain, about 20-25% branched, and of the output cyclic (non-functional) perfluoroalkanes and ethers, which comprise 4) h"ytadrrso"g(ehni,gwhhmioclheccuolmaprriwseeigahbtouftlu1or0o-c1h5e%moifcatlhebyopurtopduutc,ts) and other byproducts, including molecular Bpreocdauucseeodfbsylitghehteldeicftferroecnhceemsicianlprfloucoersisnactoinodnitpirooncse,ssravwarmiaetsersioamlse,whaandt efqruoimpmloetn-tt,o-ltohteamnidxtfurroem plantrtoa-tphlearnta.mTihxeopfriosdoumcetrtshaatndrehsuolmtoslforgoumese.lecTthreocchoemmmiecraclifalluiozreindatPiOonSFis dtehursivneodtparopduurcetschaermeiacamlixbtuutre ofapproximately 70% linear POSF derivatives and 30% branched POSF derived impurities. CAS Number 754-916 3M Company 3 pDeurrfilnugorpormoedtuhctainoen,,hbayvperobdeuecntsveanntdedwtaostteheparotdmuocstpshearree finortmheedp.asTt,hebuvtolpaltainlse awraestbeeipnrgodiumcptls,emseunctheads btoeecnapltaunrdefialnledddienstarhoyaztahredsoeurselweaasstees lbayndtfhilelrmianlthoexipdaastt,iobnutovaerre talhlecnuerxrtefnetlwyybeeairnsg.inTchienetraartsehdaavtean filnu-ohroiunsaeteodrweixtthemhayldrhoagzeanrdaotuosmswassitlel ipnrceisneenrta,tocra.n bTeherebcyypcrloeddubctasc,kmiantnoytohfewEhCiFchpraorceesisnocromaprleetely partially degraded treatment systems. in stabilization The treatment psrloucdegseseasssaoncdiadtiesdcwhiatrhgetdhetoEcCoFntprrololceeds,s in-house, has been wastewater either landfilled or land-incorporated 1998. in the past, but all ofthis treatment sludge is being landfilled off-site since carly sPyOntShEesiisistofseslufbastcaonmcmeerscuisaeldlyinvmiaabnlye portohdeurct3,Mbuftluiosrporcihmeamriiclaylapnriomdupcotrst.antThientmearjmoerdiitayteisinustehde to produce functionally derivatized fluorochemicals and high molecular weight polymeric products. mUonlieqcuuelechuesmiinsgtrcioensvceantnbioencarlehaytderdocbayrdbeornivraetaicztiionngs.POPSFOtShriosurgehacttheedswuilftohnymletfhlyuloroirdeetmhoyileatmyoinfethteo MpreoFduOcSeAciathnedrENF-mOeSthAylisoirsNol-aettehdyltopebrefluusoerdoaosctiannteesrumlefdoinataemsidteo (beMereFaOctSeAd toor fEoFrOmSoAt)he.r mSaotemreioalfst.he cTahrebomnaajtoerittoyoffortmheeiMtheerFNO-SmAetahnydloErtFN-OeStAhyilspneortfliusoorloaotcetdaannedssuulbfsoenqaumeindtolyetrheaancotle.d Twhitehseetahryeltehnee principal building blocksofthe 3M product lines. tChAeSrenacutmiboenorfP75O4-S916w,itphermfeltuhoyrlooocrteatnheyslualmfionnaembiedcea(uRs-eoSOf;tNhHe2p)r,esisenacseomafllausnmdaelsliraemdoubnyptroofduct of ammonia produced f(oNr Ha)coimn mtehrecmieatlhypluroproseet.hyTlhaimsincehermaiwcamlateirsiparl.esePnetrifnluvoerroyoscmtaalnle sulfonamide is amounts (0.1% not or less) in ptrheodvuacrtisoubsutPiOsScFurrbeansteldy imnotneirtmoerdeiadtoenslpyroindu3cMedFbDyA3Mr.eguIltactaedn itnhdeiorreectticfaololdy baeddpirteisveenptroindufcitnsa.l 3ItMis present at approximately 0.01% in the latter products. CAS Number 754-916 3M Company s The following block flow diagram describes the process discussed above. BLOCK FLOW DIAGRAM (OctaneEsluelcftornoy-lCfhleumoirciadel +FlHuoFri+naetlieocntrCiecalllsenergy) Perfluorooctane sulfonyl fluoride | (POSF) Secondary Reactors Perfluorooctane sulfonic acid (PSOF) Surfactants Vari, ous commercialized intermediates and surfactants Amphoteri}c (FsiurrefaFcitgahnttisng Pots) N-ethyl (and methyl) perfluorooctanesulfonamide } N-eptehryfllu(oarnodocmteatnhey-l) sulfonamido ethanol Additional Secondary Reactors PEhsotseprhsaatned Acrylate/polymers (Paper & Packaging) AcArdyilpaattee paodldyumcetrss Urethane polymers (Carpet and Textile Protection) Various commercialized intermediates and surfactants CAS IV. Number SITE 754-91-6 RELEASE AND TRANSFER 3M Company INFORMATION FOR TRI CHEMICALS 5 Not applicable. V. SITE RELEASE AND TRANSFER INFORMATION FOR NON-TRI CHEMICALS aWnhdilceomanpaoluyntidcsa,l smoetdhatoadsavhaaivlaebliempfrorovtehids orvepeorrttiimse,molsatrlgeyovfariaaqbuialliittyasttiivlleenxaitsutrse.forAlcetrhtoauinghmaltirmiicteesd menogniinteoerriinnggdcaatlacuelxaitsitosn,sm.osEtngeimniesesriionngacnadlcwulaasttieoness,tihmoawteevsearr,ehbaavseedliumpitoantipornoscewsisthmoredseplesctatnod finltueorrmoecdhieamtiecasltesp.because fluorochemical losses were not always included in the analysisofeach aTrheedaifcfciucrulatcytoofmtehaesuermeisdsuieontosqduaitcaksluybcmhiatntgeidnvgarpireoscedsusectoonsdeivteiroanls,favcetnortsi.ngBpartecshsuprreoscaensds dsiyfsftiecmulsty cinomispooluatnidngspcraoucseesstehsemtottoabkeehmaevaesudriefmfeernetnst.ly Afdrdoimticoonnavlelnyt,itohnealuncioqmupeouchnadrsa,ctaernidstpihcysosifctahlecsheemical data properties are not available for all intermediate reaction steps in the past. A. ON-SITE AIR RELEASES fArLoLm rPeaLcAtoNrsT,Sdr-uFmugmiitnigvoefepmriosdsuicotnisnmtearymeodcieautref,rfolmakviancgumuomnocmhearrg,indgryfirnogmopderruamtsi,onssa.mpling mMaatteerriiaall.s mIandyusbterihalanhdylgeidenineamomnoilttoerninogr hsoalsidbesetantec;ovnadpuocrtsedarfeorprsoodmuececdomfprooumnmdosl.teSnome. minor amountsofthese compounds industrial hygiene exposure testing. have been detected as fugitive emissions during tEhmeisfasciilointy.estFiumgaitteisvaereembiassseidonuspmoanyexhiasvtienogcpcruorcreesdsmdourdienlgssaonmde ehnagnidnleienrginsgtecpaslcbuultahtiaovnes nfortom been quantified Fugitive (non-point) Stack (point) Comments: Estimated Total Estimated % Annual (ibs) Releases ~~ Accuracy of Estimate (opions) No data available. No data available. #dayslyears release occurs CAS Number 754-91-6 3M Company 6 B. WATER RELEASES FROM SITE Decatur, AL `Tchoempdaotuandpsreosfenitnteedreisstpwaretroefnwoatstaneawlaytzeerdtiensttihneg 1co9n9d7uwcatsetdewinat1e9r98m,atseirnicaeltbhaelainndcievdiduuealto pmreotdhuocdtiaovnailleavbeillsitiyna1n9d97i,nitsiianlcpermoogsrtapmrfoodcuucs.tioTnhreem1a9i9n8eddaattashiamsilnaortlbeeveelns.adjusted for `Mmaatneurfiaacltsuirnintghoefstlhuedsgee acnodmpwoasutnedwsatoerrfmroamytrheesuhlytdrforloymsipsroofdumcotrioencloomsspelseixnmtohleecules. Water releases: AEnstniumaalteRdelTeoatsaels ~~ Estimated % Accuracy of (Ibs.) Estimate options) 370 Number of days/year release occurs: 250 days/year Receiving Water Name: Baker's Creek at Junction with Tennessee River NPDES Number: ADL004023164 Comments: Cottage Grove, MN Water releases: AEnstniumaalteRdelTeoatsaels ~~ Estimated % Accuracy of (ibs. Estimate (options) No data available. Number of days/year release occurs: Receiving Water Name: NPDES Number: Comments: CordovIaL, Water releases: Estimated Total Annual Releases ~~ ~~ Estimated % Accuracy of (Ibs) Estimate (psiona) No data available.  CAS Number 75491-6 3M Company Number of days/year release occurs: 7 Receiving Water Name: NPDES Number: Comments: 35 CAS Number C. 7O5N4--S91I-T6E LAND RELEASES 3M Company 5 Decatur,AL `tTrhaenslpaonrdtetdretaoatmneonftfosiftDeelcaantdfuirlls,luafdtgeerwpaasssidnigsctohnrtoiunguhedaitnheiacrkleyne1r99a8n.d aSlsuldugdegeisprneossw. An iusmepdoufonrdbmaecnkt-uwpasopuesraetdiionn.19L9e7vealsspoarftotfhetchoemwpaosutnedwaitnerthterselautmdegnetwoepreeradteitoenrmbiunteids nfroowmonly wastewater data Estimated Total Annual Releases (bs) (1997) Estimated % Accuracy of Estimate options Landfill SLuarnfdacTerIeamtpmoeunntd/mLeanntdsAmendment UOtnhdeerrg(rspoeucinfdy)I:njection No30data available. 0 0 Comments: Cordova, IL `dTihsecomnatniunfuaecdtureofthese compounds has been discontinued so these releases have also been wEansgtienweaetreirn.g cTalhceulaamtioounnstowefremautsereidaltodeisstcihmaartgeedthteoatmhoeusnltuodgfemawtaesridaeltedrimsicnheardgtehdrotough use of existing removal efficiency testing results from another facility. Estimated Total A(busn)ual(R1e9l97e)ases Landfill 0 SLuarnfdacTerIeamtpmoeunntd/mLeanntdsAmendment <9 0 Underground Injection 0 Other (specify): Estimated % Accuracy of Estimate (options)  CAS Number 754-91-6 3M Company 5 Comments: Cottage Grove, MN Sludge from the Cottage Grove facility is sent to an offsite industrial landsill AEnstniumaalteRdelTeoatsaels AEcsctiumraatceydo%f (bs) (1997) Estimate (opansh LLaannddsTirleatment/Land Amendment 00 SUunrdfearcgeroIumnpdouInndjemcetnitons 00 Other (specify): Comments: C. OFF-SITE TRANSFERS DL. Transfer to Publicly Owned Treatment Works (POTW) tPortohceesPsOwTasWt.ewaters are managed in an on-site wastewater treatment facility and are not sent Number of days/year the release occurs: Annual Transfer (b): Estimated % Accuracy ofTransfer Estimate (optional) (%): SPtOreTetWAdNdarmees:s: CiSttayt:e: NPDES Number: CZiopunCtordye:: Comments: D2. TRANSFERS TO OTHER OFF-SITE LOCATIONS GspeenceirfiaclrWepaosrtteinIgnafnodrmoafftsiiotne:trTahnesfreersisclainmniottedbeinrfeoardmialtyivoenribfiyedC. ARSatmhuerm,bwearsftoerscaorempound cfllausosriofciehdembiycahlalcoatgeegnorcioenst.eWn,herregeulwaatsotreyswaarsetreaccokdeeds,bpyhCysAicSalnupmrobpeerr,titehse aanmdounonnt-sspheacviefibceen included. CAS Number 754-916 3M Company Estimated Total Estimated % 10 Annual Releases (Ibs) Accuracy of Estimate (optional) Incineration: No specific CAS number data available. Wastewater Treatment (Excluding POTW) 0 Underground Injection 0 Hazardous Waste (RCRA Subtle C) landfill No specific CAS number data available. Other Landfill Recycle or Recovery Unknown or Other No specific CAS number data available. No specific CAS number data available. Comments: CAS Number 754-91-6 3M Company VI. ON-SITE WORKPLACE EXPOSURE u `This information will assist EPA in and the magnitude, frequency, and characterizing the number of workers duration of potential exposure. When potentially providing exposed monitoring data, ensure that data is linked with worker activities described in question 2. I fEosrtiemaactheotfhtehneuemxbpoesruorfewdourrkaetirosnptoitmeenst.ialIlfyaewxoprokseedr irsouitnivnoellvyedtointhmeosruebjtehcatncohnemeical activity, activity, enter only enter only his/her most his/her most typical typical activity activity in in the the table. table. Don't Don't count a count a worker worker more more than once. potentially eTxhpeosteodt.al number in the table should equal the total number of workers Hrs/day <10 10-100 Daysiyr. 100-250 >250 Cs es Cs ws r 7 7 r 2. sDaemspclriinbge,trheemroovuatlinoefwfoilrtkeerrcaakcet,ivaitnidesdtrouwmhmiicnhgthoef lwioqrukiedsr,smiannquufeascttiuorne1aanrearetixcploes,eedt:c. pFaorrtitchuelsaetea,ctoirviatieerso,sodle,scertci.b)eatnhde,pihfyisniacamlisxttautreeo,ftthheecshuebmjiecctalcshecmoinccaelnt(rlaitqiuoidn,: gas, `This material is not handled at any of the facilities. 3. sParmopvildienginmdeutsthroidalahnydgieexnpeosmuorneitsocernianrgidoamtao,niiftoarvaeidl,abe.lge.,, wdietshcraibbreitehfedesspeccriifpitciwoonrokfetrhe nacottiviintcielsudpeearnfyorpmeerdsobnyalthiedeinntdiifvieirdsuasluschmoansitaowroerdk.erF'osrnparmiveacoyr csoocnisaildesreactuirointsy,npulmeabseerdo with any data submitted to EPA. 4. Briefly describe the engineering controls used to minimize exposure to this chemical: CAS Number 754-916 3M Company 2 S. Briefly list the personal protective exposureof this chemical: equipment your workers regularly wear to prevent COMMENTS: CVIAL.S NuCmHbeErMI7C54A-L91E6ND USES 3M Company 1 A. END USE AS AN INTERMEDIATE CONSUMED TO MAKE OTHER CHEMICALS AL On-Site Use as a Intermediate: Product chemical class (IncludeoCrApSronduucmtbechreimfiacpaplropriate) 1 % of total volumeof subject chemical manufactured or imported A2. Off-Site Use as an Intermediate As reported in Part III, p.2 Product chemical class (IncludeoCrApSronduucmtbechreimfiacpaplropriate) 1 %of total volumeof subject chemical manufactured or imported As reported in Part III, p.2 ee Co CAS Number 754-91-6 3M Company 1 Use Number 1 of 1 Description of Chemical End Use: vPeorlcuemnet goofitnogtaltomtahniusfuascet:ure+d or imported Cchheemcikcaallldpuhryisnigcatlhifsoursmes:ofthe tIofuisnedidcaitneawmeiixgthutrefrcachteicokn.apApvreorpraigaete box values are acceptable: a 130% 060% 6>0-o9%0% Aerosol Dry Powder ZZ WPapetielertsoorrsloalrvgeenctr~yswtealtssolid --_ Gasorvapor Liquid solution Other (Explain) --