Document K6yN730w90qmG8g6XJy3j7grK
TOXIC SUBSTANCES CONTROL ACT (TSCA) PL 94-469
CANDIDATE LIST OF CHEMICAL SUBSTANCES
ADDENDUM III
CHEMICAL SUBSTANCES OF UNKNOWN OR VARIABLE COMPOSITION, COMPLEX REACTION PRODUCTS AND BIOLOGICAL MATERIALS
MARCH 1978
KMX 00233
U.S. ENVIRONMENTAL PROTECTION AGENCY A OFFICE OF TOXIC SUBSTANCES WASHINGTON, D.C. 20460
TOXIC SUBSTANCES CONTROL ACT (TSCA) PL 94-469
CANDIDATE LIST OF CHEMICAL SUBSTANCES
ADDENDUM III Chemical Substances of Unknown or Variable Composition,
Complex Reaction Products and Biological Materials
March 1978
U.S. Environmental Protection Agency Office of Toxic Substances Washington, DC 20460
TABLE OF CONTENTS
Page
Introduction ................................................................................................................ 1
Section I
: Class 2 Chemical Substances Derived from Natural Fats and Oils and Synthetic Sub stitutes (An Alternate Procedure for Sub stance Identification and Reporting for the Chemical Substance Inventory) .........................
3
Section II : Coke and Selected Coal Chemicals................................ 35
Section III : Chemical Substances Common to the Iron and Steel Industry................................................................ 39
Section IV : Wood and Pulp Chemicals........................................................43
Section V
: Chemical Substances Manufactured in the Paper Industry .......................................................................... 47
Section VI : Chemical Substances Manufactured in the Fertilizer Industry .......................................................... 49
Section VII : Natural Oils and Extractives..........................................51
Section VIII: Selected Polymers .......................................................... . 63
Section IX : Chemical Substances Manufactured as Part of Mixtures..................................................................... 77
Section X : Other Class 2 Chemical Substances .......................... 81
i
INTRODUCTION
The Toxic Substances Control Act (TSCA), Public Law 94-469, re quires the U.S. Environmental Protection Agency to compile, keep cur rent, and publish a list of each chemical substance which is manufac tured, imported, or processed in the United States for commercial purposes. Under the authority of Section 8 of TSCA, EPA will compile this inventory from reports prepared and submitted by manufacturers, importers, and. processors of chemical substances in accordance with Inventory Reporting Regulations (40- CFR 710). These regulations were published in the FEDERAL REGISTER on December 23, 1977 (pages 64572 to 64596), and became effective on January 1, 1978.
In April 1977, EPA published the TSCA Candidate List of Chemical Substances, which identifies over 30,000 chemical substances. The Candidate List was prepared to assist persons in reporting chemical substances for the Inventory. In January 1978, EPA published two addenda to the Candidate List, the first identifying petroleum refinery intermediate and final process stream chemical substances, and the second identifying an additional 3,000 Class 1 chemical substances. A Class 1 chemical substance is one whose composition can be represented by a definite chemical structure diagram.
This document, addendum III to the Candidate List, identifies primarily Class 2 chemical substances, and provides a mechanism for identifying and reporting others. A Class 2 chemical substance is one whose composition cannot be represented by a definite chemical structure diagram. Some chemical substances identified in this addendum are defined, in part, in terms of the processes by which they are manufac tured. Other chemical substances are simply identified by names which are widely recognized and need no further definition.
Certain common materials of commerce, such as inorganic glasses, are defined by the Inventory Reporting Regulations as mixtures. To facilitate reporting, this addendum defines certain categories which encompass the individual chemical substances manufactured in the pro duction of these mixtures.
This addendum is organized into ten sections, listing terms de veloped by EPA in cooperation with various trade associations and other agents. They represent industries involved in the manufacture of Class 2 chemical substances which are difficult to define, either due to slight variations of process or because the composition of these sub stances is not completely known or is variable. Although this addendum identifies chemical substances which are common to specific industries, it does not include all reportable chemical substances manufactured within these industries. Furthermore, any persons who manufacture such substances may use the nomenclature presented in this addendum to report for the Inventory if this nomenclature accurately describes the chemical substances they manufacture.
All chemical substances identified in this addendum, with the ex ception of those in Section I (multi-component Class 2 substances derived from natural fats and oils or synthetic substitutes), are listed with CAS Registry Numbers and EPA Code Designations, and may be reported on Form A. The substances identified in Section I must be reported on Form C according to the procedures outlined in that section.
2
Section I
CLASS 2 CHEMICAL SUBSTANCES DERIVED FROM NATURAL FATS AND OILS AND SYNTHETIC SUBSTITUTES
An Alternate Procedure for Substance Identification and Reporting
for the Chemical Substance Inventory
General
This section presents an alternate and relatively simple procedure for identifying and reporting certain multicomponent Class 2 chemical substances derived from natural fats and oils and synthetic long-chain alkyl substitutes. The procedure was developed by The Soap and Detergent Association in conjunction with the EPA and is intended to standardize the identification of substances manufactured and used extensively in the soap and detergent industry. This standardization should provide for easier and more certain reporting and recording of information for these substances. Accordingly, the procedure may be used to report multicomponent soaps and surface active agents (and also their precur sors and derivatives) manufactured, imported, or processed for such uses as wetting agents, emulsifiers, dispersants, and penetrants. Its appli cability, however, should extend beyond the soap and detergent industry.
This procedure may not be used to report any single component Class 1 chemical substance (i.e., a substance whose composition may be repre sented by a definite chemical structure diagram) or any combination of such substances prepared by mixing without chemical reaction. Further more, it should not be used in those cases where the person reporting considers its applicability to be marginal or in question. Instead, the conventional procedures should be followed for chemical substance identi fication and reporting, as specified in the EPA publication "Reporting for the Chemical Substance Inventory" (December 1977).
The Class 2 chemical substances which may be reported following procedures specified here are complex, multicomponent materials whose individual components have a common structural feature: one or more long-chain alkyl groups to which is attached a chemically functional group or groups. These components differ from one another with respect to one or more of the following long-chain alkyl group characteristics: length (carbon number), saturation, structure (linear or branched), and/or the position of functional group attachment(s).
Before 1950, most of these substances were derived commercially from natural sources. However, synthetically-derived sources of similar composition have since been developed and are presently used interchange ably with natural sources.
3
Substance Identification
According to procedures specified in this section, certain of these Class 2 chemical substances may be identified by systematically-derived, chemically-descriptive SDA Substance Names. The proper SPA' Substance Name for each is that which most precisely describes the chemical comp osition of the substance. Each substance is reported on Inventory Report Form C and identified only by the SDA Substance Name and special SDA Reporting Number, and not in terms of source, blend, process, or reaction information. During form processing, each substance reported following this procedure will be assigned a CAS Registry Number which will appear on the Inventory with the SDA Substance Name and Reporting Number and with substance synonyms, if reported.
SDA Substance Names consist of two or, in some cases, three parts. The two parts common to all SDA Substance Names are: (1) the Alkyl Descriptor, A, which describes the long-chain alkyl groups of the substance, and (2) the Functionality Descriptor, F, which identifies the functional group(s) of the substance. A third part, the Salt Descrip tor, S, identifies the cation(s) of any salt.
SDA Substance Names are systematically constructed according to the following formats:
(A) alkyl (F),
or in the case of salts,
(A) alkyl (F)(S),
where A denotes the Alkyl Descriptor; F, the Func tionality Descriptor; and S, the Salt Descriptor.
For example, the SDA Substance Name for a fatty amine which contains predominantly C^-C^g saturated alkyl chain-lengths is:
C^Q-C^ alkyl amine
where the phrase "Cj,,-C.^g" corresponds to the Alkyl Descriptor (A), and Mamine", to the Functionality
Descriptor (F).
Similarly, the SDA Substance Name for the sodium salt of a fatty car boxylic acid comprised predominantly of C^g saturated and C^g unsatur ated alkyl chains is:
C^g and C^g unsaturated alkyl carboxylic acid sodium salt
where the phrase "C^g and C^g unsaturated" corresponds to the Alkyl Descriptor (A); "carboxylic acid", to the Functionality Descriptor (F); and "sodium salt", to the Salt Descriptor (S).
A
The Class 2 chemical substances covered by this section are limited to those whose composition may be described using the Alkyl, Function ality, and Salt Descriptors listed in Tables 1, 2, and 3, respectively. These descriptors, discussed in detail below, may be combined in the SDA Substance Name format to describe more than 5,000 multicomponent Class 2 chemical substances.
Alkyl Description
Table 1 lists the Alkyl Descriptors covered by this system of sub stance identification; assigned to each is a two-digit Alkyl Descriptor Code used in generating the SDA Reporting Numbers, described later. Each Descriptor identifies a distribution of alkyl groups in terms of carbon chainlength, saturation and/or unsaturation, and linear or branched structure. Alkyl group distributions are inclusive of both even and odd alkyl chainlengths.
The Descriptors of Table 1 were chosen to cover the predominant
long-chain alkyl group distributions actually present in most commercial
multicomponent Class 2 substances of this type, and to provide for each
as precise a description as practical. Use of this procedure is predicated
on selecting the narrowest alkyl distribution (Alkyl Descriptor) which
describes the predominant long-chain alkyl groups of the substance
.
reported. In this context, the term "predominant" means that about 80
to 100 percent of all long-chain alkyl groups are included within the
description.
In the Alkyl Descriptor, a saturated, linear long-chain alkyl group is denoted by "C " where the subscript x indicates the number of carbon atoms in the alkyl chain. Unsaturated and multiple branched alkyl groups are denoted by "Cx unsaturated" and "Cx branched", respectively.
By convention, the number of carbon atoms in a long-chain alkyl group includes all long-chain alkyl and functional group carbon atoms, other than those contained in an aromatic ring, which are connected to each other in a unbroken chain of carbon-carbon bonds. For example, the alkyl chainlength, designated by "R" in the representative structural diagrams found in Table 2, includes the acyl carbon of carboxylic acids and their derivatives, and the total number of carbon atoms in such structures as R-CH^-OH or R-CH=CH2. The alkyl group does not include, however, functional group carbon atoms which are part of a phenyl ring, or are separated from the alkyl chain by a phenyl group or an atom other than carbon, e.g., R-^ , R-N(CH3)2> or R-CKCH^^NH^.
Unless specified otherwise, the alkyl groups identified by each Alkyl Descriptor are linear, or essentially linear, hydrocarbon chains. The natural fats and oils listed below provide such alkyl groups:
5
Vegetable
Animal
Marine
Avocado Babassu Castor Coconut Corn Cottonseed Crambe Linseed Olive Oiticica Palm Palm-kernel
Peanut ' Rapeseed Rice Bran Safflower Safflower
(high oleic) Sesame Sorghum Soybean Sunflower Tung Wheat Germ
Grease Lard Neatsfoot Poultry Tallow
Herring Menhaden Salmon Sardine Sperm Body
(whale) Sperm Head
(whale) Whale
These sources provide both saturated and unsaturated alkyl groups; castor oil provides a C^g hydroxy substituted alkyl group. Alkyl groups derived from other natural sources are not covered by this procedure.
Synthetic sources can provide linear or essentially linear alkyl
groups, i.e., chain branching, if any, is limited to no more than one
secondary methyl (CH^-) or ethyl (C2H5-) group per alkyl chain. For
purposes of this section, the latter type of alkyl chain is included
within the designation "linear". Multiple branched alkyl groups, de
rived exclusively from synthetic sources, have separate Alkyl Descriptors.
Some Class 2 chemical substances covered by this procedure are comprised of components which have two or more long-chain alkyl groups, e.g., (dialkyl) amine, or (dialkyl) dimethyl ammonium chloride. This procedure may be used to identity such substances provided that each long-chain alkyl group is describable, in its predominant composition, by an Alkyl Descriptor found in Table 1 and that none of these longchain alkyl groups is a single component structure describable by a definite chemical structural diagram.
i 6
Functionality Description and Substance Definition
Table 2 lists the Functionality Descriptors which may be used in this procedure of substance identification; assigned to each is a three digit Functionality Descriptor Code used in generating SDA Reporting Numbers. The partial chemical substance nomenclature (Functionality Descriptors) for each identifies a specific functional group or groups. Different Descriptors are provided for salts, and for their corresponding acids.
Associated with each Functionality Descriptor in Table 2 is a
representative structural diagram or diagrams. In many cases, these
diagrams depict only one of several possible isomers of a substance
identified by a given Functionality Descriptor. For example, a C^--C.,g
alkyl amine reported by this procedure may contain components which have
the amine functional group
attached to a terminal alkyl carbon,
as shown in Table 2 for Functionality Descriptor Code 029, or to any
other carbon atom in the alkyl chain. The applicability and limitations
of each representative structural diagram are defined by a Substance
Definition. Each Functionality Descriptor listed in Table 2 is assigned
a Substance Definition Format number ranging from 1 to 6. Through this
number, the SDA Substance Name is linked to one of six generalized
Substance Definitions appearing in Table 4. For each substance reported
by this procedure, a unique definition can be generated by inserting the
Alkyl, Functionality, and Salt Descriptor parts of its SDA Substance
Name, and the corresponding representative structural diagram found in
Table 2 into the appropriate generalized Substance Definition. Examples
contained in Table 4 illustrate how such definitions may be generated.
The Substance Definitions provide a chemical description of each sub
stance identified by an SDA Substance Name and specifies the applica
bility and limitation of the corresponding representative structural
diagram.
Note: In Table 4, the term "positional isomers", appearing in some Substance Definitions refers to substances which are otherwise similar except for the position of functional group attachment(s) on the long-chain alkyl group(s).
Salt Description
Table 3 lists the Salt Descriptors covered by this system of substance identification; assigned to each is a two-digit Salt Descriptor Code used in generating the SDA Reporting Number. SDA Substance Names for Class 2 chemical substance which are not salts contain no Salt Descriptor part; the Salt Descriptor Code for such substances is 00.
Mixed salts of monovalent anions are considered mixtures of the individual salts, each of which should be reported separately. Mixed salts of divalent anions, however, may be reported as a single substance.
7
Reporting Instructions
Class 2 chemical substances identified following this procedure may only be reported on Chemical Substance Inventory Report Form C. Although substance synonyms may also be provided, the chemical substance need only be identified by its SPA Substance Name and a systematicallyderived SPA Reporting Number. The SPA Reporting Number indicates that the substance is being reported according to the procedure described here and also serves as a redundancy check on the correctness of the reported SPA Substance Name.
The SPA Reporting Number is derived using the two- or three-digit codes associated with each Alkyl, Functionality, or Salt Pescriptor contained in Tables 1 to 3. The SPA Reporting Number is generated by systematically combining these codes for a given substance in a manner similar to that used to derive the SPA Substance Name. SPA Reporting Numbers have the following formats:
SPA aa-fff-ss
or for mixei salts of divalent anions,
SPA aa-fff-ss,s's'
where "aa" denotes the appropriate Alkyl Pescriptor Code; "fff", the appropriate Functionality Pescriptor Code; and "ss" (and "s's'") the appropriate Salt Pescriptor Code(s).
For example, the SPA Reporting Number for C^q-C^ a-^yl am*ne is:
SPA 15-029-00
This number was generated using the Pescriptor Codes found in Tables 1 to 3. Table 1 identifies the Alkyl Pescriptor Code for "CL _-C..15. Table 2 identifies the Functionality Pescriptor Code for "talkyl) amine" 029. Table 3 identifies the Salt Pescriptor Code to be used when the substance is not a salt: 00. Inserting these numbers in the standard format yields the correct SPA Reporting Number.
A seven step method, described below for a specific example, is useful in applying the nomenclature of this section to the identifica tion and reporting of particular chemical substances. Additional ex amples which further illustrate the applicability and limitations of the procedure immediately follow Table 4.
INTROPUCTORY EXAMPLE
A fatty carboxylic acid is prepared by blending acids from various sources which contain linear alkyl groups having even and odd carbon numbers. The fatty acid is then reacted with sodium hydroxide to form the sodium salt. The composition of the starting fatty acid is listed below in terms of the percent by weight of each of its components.
8
Component Alkyl Group
% Composition
C8 saturated C10 saturated C12 saturated C14 saturated C15 saturated C16 saturated C17 saturated C18 saturated C20 saturated C16 unsaturated C18 unsaturated
0.5 1.5 7 5 5 10 10 .... 30 1.0 5 25
Step 1; Identify the Major Component Alkyl Groups
On a worksheet, list in the following format the alkyl groups which correspond to the alkyl components in the starting ingredients. Include the actual percentage by weight of each such component. As a practical consideration, components present at less than two (2) percent by weight need not be included.
Carbon Chainlength Distribution Saturated Unsaturated Branched
% Composition*
C12 --
No
C14 --
No
C15 --
No
C16 --
No
C17
--
No
C18
--
No
-- C16 No
-- C18 No
7 5 5 10 10 30 5 25
*by weight of starting fatty acid.
NOTE: The Cg, C^q, and C^q alkyl components of this example were omitted because each is present at less than two percent by weight.
9
tC'-.'kV
Step 2: Identify the Most Appropriate Alkyl Descriptor
Select from Table 1 those Alkyl Descriptors which could conceivably describe the predominant alkyl groups of the substance. Eliminate by inspection those Alkyl Descriptors which are obviously inadequate for reasons of alkyl chainlength, saturation and/or unsaturation, or struc ture. In this example, the Alkyl Descriptors for solely saturated, solely unsaturated, or branched alkyl groups are clearly inappropriate and are not considered. Other Alkyl Descriptors are not considered because their chainlength distributions are not appropriate.
By such an analysis, the Alkyl Descriptors which correspond to Alkyl Descriptor Codes 01, 04, and 11 are selected as candidates.
To determine the most appropriate Alkyl Descriptor from among these candidates, construct the following table:
Alkyl Desc. Code
01 04 11
Predominant Carbon Chainlength Saturated Unsaturated Branched
Components Within Category
8-18 14-18 16-18
18 16-18
18
No No No
93% 90 75
Number
Number
of Extra of Missing
Components Components
51 11 04
The information entered under the Alkyl Descriptor Code and Predominant Carbon Chainlength headings are taken from Table 1. The entries under the other headings were calculated by the following methods:
Components Within Category: For each Alkyl Descriptor, add the percentages of each alkyl component, listed in Table 1, whose longchain alkyl group is included within the specified distribution, e.g., 90 percent of the components shown in Step 1 fall within Alkyl Descriptor Code 04.
Number of Extra Components: For each Alkyl Descriptor, subtract from the total number of long-chain alkyl groups of the specified distribution those which appear in the actual alkyl composition, .e.g., for Alkyl Descriptor Code 04, only the C.? unsaturated group is absent from the actual alkyl composition.
Number of Missing Components: For each Alkyl Descriptor, subtract
from the total number of alkyl components in the actual composition
those which are included within the alkyl distribution specified
for the Alkyl Descriptor, e.g., only the
saturated alkyl compo
nent of the actual composition is not included within Alkyl Descrip
tor Code 04.
.Analysis: By inspection of the table shown above, it is clear that the Alkyl Descriptors which correspond to Codes 01 and 04 both adequately encompass the predominant alkyl composition of the substance, i.e., greater than 80 percent of the actual alkyl composition is included within the range of each of these alkyl distributions. The Alkyl
10
Descriptor corresponding to Code ^)4 is selected, however, because this Alkyl Descriptor includes the fewest extra and missing component alkyl groups.
NOTE: This procedure for determining the most appropriate Alkyl Descriptor should be followed only once for each unique alkyl composition reported. It need not be repeated for functionality variations involving the same alkyl composition.
Step 3: Select the Appropriate Functionality Descriptor
Refer to Table 2 and select the Functionality Descriptor which identifies the functionality of the substance. In this example, the appropriate Functionality Descriptor for a salt of a fatty carboxylic acid corresponds to Code 006.
Step 4: Select the Appropriate Salt Descriptor
Refer to Table 3 and select the Salt Descriptor(s) which identifies, if appropriate, the cation(s) of the salt being reported. In this example, the Salt Descriptor, for the sodium cation, corresponds to Code 04.
Step 5: Construct the SPA Reporting Number
Using the prefix SDA, and the Alkyl, Functionality, and Salt De scriptor Codes derived from steps 2 through 4, contruct the SDA Reporting Number using the proper format:
. SDA 04-006-04
Step 6: Construct the SDA Substance Name
In the appropriate format, construct the SDA Substance Name for the chemical substance, using the nomenclature which corresponds to the appropriate Descriptor Codes found in Tables 1 through 3, respectively. In this example, the SDA Substance Name is:
C-j^-C^g and C^g-C^g unsaturated alkyl carboxylic acid sodium salt.
-
Step 7: Complete Form C
Complete Blocks I through IV of Form C following the instructions provided in the EPA publication "Reporting for the Chemical Substance Inventory" (December 1977). In Block V, as shown below, enter the SDA Substance Name in the space provided for the Specific Chemical Name. Indicate that the substance is a Class 2 substance by checking the appropriate box. Below the line labeled "Molecular Formula", enter the SDA Reporting Number. Determine whether any other chemical substances manufactured at the plant site are encompassed by this particular SDA Substance Name and Reporting Number. If so, consider them all as a single substance and enter the appropriate code digit in the box labeled
11
,v.'>
"Vvi'V/ <'>'
"Production Range" which corresponds to their combined 1977 production
volume. If any of the substances are not site limited, make no check in
the box labeled "site limited". Finally, make all necessary confidentiality
claims by checking the appropriate boxes.
.
-
SAMPLE FORM C: BLOCK V
V. CHEMICAL SUBSTANCE WHERE THE IDENTITY IS CONFIDENTIAL (AND/OR) THE CAS REGISTRY NUMBER IS UNKNOWN
CAS REGISTRY NUMBER
1 IF KNOWN)
SPECIFIC CHEMICAL
NAME
(SEPARATE MULTIPLE NAMES WITH A SEMI-COLON'
CLASS 1 g] CLAS5 2
C^-C^g and C^g-Cjg unsaturated alkyl carboxylic acid sodium salt
51
IN THE SPACE PROVIDED BELOW, PROVIDE STRUCTURAL INFORMATION,
MOLECULAR FORMULA, AND OTHER SUPPLEMENTAL INFORMATION TO
AID IN THE SPECIFIC IDENTIFICATION OF THE CHEMICAL SUBSTANCE:
SEE AnACHED SHEETS (WRITE FORM NO. ON AIL
MOLECULAR FORMULA
ATTACHMENTS
EPA USE ONLY
ig) CHEMICAL SUBSTANCE IDENTfTY IS CONFIDENTIAL (1) SUBSTANTIATION | | No. of sheets ottoched (write form number * - on oil substontiohon sheets;. (2) Proposed Generic Nome;
SDA 04-006-04
| | (3) I agree to the terms of CONFIDENTIAL CHEMICAL SUBSTANCE IDENTITY STATEMENT on the back of this form.
T.m T
12
TABLE 1 Alkyl Descriptors
Descriptor Code
01 02 03 04 05 06 07 08 09 10
11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27
Predominant Carbon Chainlength Distribution Saturated Unsaturated Branched
8-18 10-16 14-18 14-18 14-18 14-18 14-22 16-22
16 16
18 12-20 12-20 16-18 16-22 16-26 16-22
18 18 18,18*
No No No No No No No No No No
16-18 18
6-12 8-26 10-16 12-18 14-18 14-26 16-18 16-18,18* 16-22
8 9 12 11-13
18 18
10-16 14-18
No No No No No No No No No No No Yes Yes Yes Yes No No
*Hydroxy substituted alkyl group derived from Castor Oil
Alkyl Descriptor (A) Nomenclature
Cg-Cig and C^g unsaturated C1n-C1fi and C1j,-C,n unsaturated C-i/,--C1B end Ci?-C7n unsaturated C7 r and C1^-C^ R unsaturated Cli-C1R and C1(.-C,^ unsaturated C^-C^g and C^-C^g unsaturated C1/,-C7j and C1R-C7^ unsaturated C1(.-C?^ and C^g unsaturated C^g and C^g unsaturated C16 plus C^g unsaturated and
Cig hydroxy unsaturated Clfi-C1R and C^g unsaturated C18 and C^g unsaturated C6"C12 C8-C26 C10'C16 C12'C18 C14"C18 C14'C26 c16-C18 C1R-C1R and C1R hydroxy C16"C22 Cg branched Cg branched Cj^ branched C^-C^g branched Ciq-Ci6 unsaturated C^-C^g unsaturated
13
,
TABLE 2 Functionality Descriptors
Vi; *
.1`jlj ^t.^i / V i'i* Lt
i-;V \
Func. Desc. Code
Functionality Descriptor (F) Nomenclature
Common Name
Representative Structural Diagram8
Substance Definition
Format*1
001 (trialkyl) glyceride
refined fat or oil
002 (alkyl) and (dialkyl) glyceride
R-C-O-C1 H4, 0,, 0it HC-O-C-R
R-C-0-CH2
0
II
R-C-O-Ci H4, HCt OH
HOCH,
R-C-O-CI H4, 0,,
HtC-O-C-R
HOCH,
003 (alkyl) and (dialkyl) glyceride ethoxylate
004 (alkyl) glyceride
R-C-O-Ci H4
R-C-O-C H4, O,,
HC0-(CH2CH20)n-H
HC-O-C-R
H2,C0--(CH2,CH2,0)m-H
H,CO-(CH,CH,0) -H 2 2n
R-C-O-C1 H4,
HCOH
HOCH,
005 006 007 008 009 010
011
012 013 014
(alkyl) carboxylic acid
(alkyl) carboxylic acid (salt)
(alkyl) dicarboxylic acid
(alkyl) carboxylic acid 11-butyl ester
(alkyl) carboxylic acid 2ethylhexyl ester
(alkyl) carboxylic acid methyl ester
(dialkyl) carboxylic acid ethylene glycol diester
(alkyl) dicarboxylic acid 2ethylhexyl diescer
fatty acid
R-C-OH
soap
U it R-C-ONa
fatty dibasic acid
00 HO-C-R-C-OH
fatty butyl ester
u II R-C-0-(CH2)3CH3
fatty 2- ethylhexyl ester
fatty methyl ester
0 CH,CH, II t 4 J R-C-0-CH2CH(CH2)3CH3
0 It R-C-O-CH,
00
fatty ethylene glycol R-C-0-(CH2),- 0-C-R diester
fatty 2-ethylhexyl diester
9 9?2ch3 r-(c-o-ch2-ch-(CH2)3-CH3)-
(alkvl) dicarboxylic acid hexyl diester
(trialkyl) carboxylic acid trimethylolethane triester
fatty hexyl diester
R-(c-0-(CH2>5-CH3)2
O
ch3
0
r-c-o-ch2cch2-o-c-r
CH,-0-C-R 4M
015 (trialkyl) carboxylic acid trimethylolpropane triester
0 CI H4,CHJ, n0
R-C-0-CH2CCH2-0-C-R
CH,-0-C-R m
"Salts are depicted in terms of sodium cation(s). bRefer to corresponding Substance Definition Format number (1-6) in Table 4.
1 1 1 1
1 1
, i xi/Ji'!.<* Lv ih'Ll .-i Vk'.,*w. v\.*\ '. ; i. .J- . I. * ,v/.4\* >>V . i >..vfc*`' VU 'jwl'lf.ii i'.i
L u'i ,s '.J. '
016 (tetraalkyl) carboxylic acid pentaerythritol tetraester
017 (alkyl) carboxylic acid ethoxylate
018 (alkyl) carboxylic acid propoxylate
019 (alkyl) carboxylic acid ethoxylate propoxylate
020 (alkyl) carboxylic acid amide
021 (alkyl) carboxylic acid amide ethoxylate
022 (alkyl) carboxylic acid amide monoethanol
023 (alkyl) carboxylic acid amide monoisopropanol
024 (alkyl) carboxylic acid amide diethanol
025 (alkyl) carboxylic acid amide diisopropanol
026 (alkyl) carboxylic acid amide (alkyl)
027 N,N'-(dialkyl) ethylene bis amide
028 N,N'-(dialkyl) propylene bis amide
029 (alkyl) amine
030 (alkyl) amine ethoxylate
031 (alkyl) amino ethylene nitrile
ethoxylated fatty acid
propoxylated fatty acid
0H iCH*--O-C-R
R-C-O-CH CCH,-O-C-R
R-C-O-CH, it 4 0.
0
0
R-C-0-(CH2CH20)n-H
O CH ii i J R-C-0-(CHCH^O) -H
0 " TM3
'
ethoxylated propoxyl R-C-O-(CH2CH20) (CHCH20)m-H
ated fatty acid
0
fatty amide
r-c-nh2
ethoxylated fatty amide
monoethanol fatty amide
monoisopropanol fatty amide
diethanol fatty amide
/CH,CH,0) -H
R-C-N
"
S(CH,CH,0) -H zzm
,,,CH,CH OH
R-C-NH
n ,, ,CH-CH0H
R-C"NH h_
n ** ,CH CH OH R-C-N 2 2
'ch2ch2oh
diisopropanol fatty amide
C3 0 'J ,, ,CH CHOH
R-C-N
"'CHjCHOH
,, "3
1 R-C-NH-R
00
r-c-nh(ch2)2-nh-c-r
O0 it m R-C-NH(CH2)3-NH-C-R
fatty amine
R-NH2
ethoxylated fatty amine
fatty amine nitrile
(CH,CH,0) H R-n' 2 2 n
(CH,CH,0) H z zm
R-NH-(CH2)2CSN
032 N-(alkyl) propylene diamine
R-NH-(CH2)3-NH2
033 N-(alkvl) propylene diamine ethoxylate
,(CH.CH 0) H
R-N
*(CH,CH 0) H
"(CH ) -N
2 2y
(CHz,CHz,0) zH
034 (alkyl) alkoxy ethylene nitrile fatty ether nitrile r-o-(ch2)2-c-n
035 (alkyl) alkoxy propylene amine
036 (alkyl) alkoxy propylene amine ethoxylate
037 (alkyl) alkoxy ethylene amino nitrile
038 (alkyl) alkoxy propylene amine propylene amine
fatty ether amino nitrile
fatty ether diamine
R-0-(CH2)3-NH2 ,(CH,CH 0) H
R-O-(OL) -n' 2 2 n * 4 s(CH,CH,0) H z zm
R-O-(CH2)3-NH-(CH2)2-CeN
R--0-(CH2) -NH-(CH2)3-NH2
!f
2
2 2
* 2 ti
1 2
1 1 1
1
1 1 1 3 4 3 3 4
3 3 4 3 3
i: K'm4 a*. * !
*** *>*.
039 (alkyl) nitrile
fatty nitrile
R-CsN
040 (alkyl) dimethyl amine
041 (alkyl) dimethyl amine oxide
042 (dialkyl) amine
043 (dialkyl) methyl amine
044 (trialkyl) amine
045 (alkyl) trimethyl ammonium chloride
* 046 (alkyl) trimethyl ammonium
bromide
047 (dialkyl) dimethyl ammonium chloride
048 (dialkyl) dimethyl ammonium bromide
049 (dialkyl) dimethyl ammonium methyl sulfate
050 (trialkvl) methyl ammonium chloride
051 (trialkyl) methyl ammonium bromide
052 (alkyl) benzyl dimethyl ammonium chloride
053 (dialkyl) benzyl methyl ammonium chloride
054 (trialkyl) benzyl ammonium chloride
fatty dimethyl amine
fatty dimethyl amine oxide
r-n-(ch3 3 2
CH, tJ R-N-->0 i
CH3
-
dialkyl amine
Rv /NH
R
dialkyl methyl amine
R
~N-CH, r' 3
-
trialkyl amine
alkyl trimethyl ammonium chloride
alkyl trimethyl ammonium bromide
dialkyl dimethyl ammonium chloride
R 'n-r
tv ` R CH +
x3
CH3 CH 3+
" R CH ;< 3
Cl" Br~
_CH3 CH 3"
4 rR CH 1
V3
r' 'ch3.
Cl"
dialkyl dimethyl ammonium bromide
dialkyl dimethyl am monium methyl sul fate
R CH," 4
V3
r' NCH3_
_L
R * sCH3,' A
R CH 3
\ ,R '
A
R CH3.
4
Br" CH SO "
J4 Cl"
R ,R ] 4
RACH3J
Br~
ro 3`|+
L R CH 3-
'Os ,R +
N
. r' 'ch 3-
.
C1
.
Cl
'Os
4
. R ' SR
Cl-
055 (alkyl) chloride
alkyl chloride
rch2-ci
056 (alkyl) bromide
alkyl bromide
RCHj-Br
057 (alkyl) alpha olefin
alpha olefin
r-ch=ch2
058 (alkyl) alkene and (alkyl) hydroxy sulfonic acid
059 (alkyl) alkene and (alkyl)
olefin sulfonate
hydroxy sulfonic acid (salts)
R(CHi.,)
A
CH-CH(CH,)
y
-S0,H J
,
R(CH 2^
CH(CH,) x, 2
-S0,H y3
OH
R(CHC,)
X
CH=CH(CH,)
l
y
-S0,Na ->
R(CH2n) x,CH(CH2~) y-SO-3Na OH
'&jk'* ^'
3 3 3 3 3 3 3 3 3 3
3 3 3 3 3 3 3 3 3
3
jir. Wiii'jLJir.- ^
060 (alkyl) alcohol
fatty alcohol
r-ch2-oh
061 (alkyl) alcohol sulfuric acid
r-ch2-oso3h
062 (alkyl) alcohol sulfuric acid (salt)
alkyl sulfate
063 (alkyl) alcohol phosphoric acid
R-CH2-OS03Na r-ch2-opo3h2
064 (alkyl) alcohol phosphoric acid alkyl phosphate ester R-CH2~OP03Na2 (salt)
065 (alkyl) alcohol ethoxylate
ethoxylated fatty alcohol
R-CH,-0-(CH-CH,0) -H n
066 (alkyl) alcohol ethoxylate sulfuric acid
R-CHz,-0-(CHZ.CHz,0) a-S0,3H
067 068
(alkyl) ethoxylate sulfuric acid (salt)
(alkyl) alcohol ethoxylate phosphoric acid
ethoxylated alkyl sulfrate
R-CH--0-(CH,CH_0) -S0,Na 4 * a II J
R-CH2-0-(CH2CH20)n-P03H2
069 (alkyl) alcohol ethoxylate phosphoric acid (salt)
070 (alkyl) alcohol ethoxylate propoxylate
ethoxylated alkyl phosphate ester
R-CH2~0-(CH2CH20)n-P03Na2
"3 ethoxyl.at-ed propoxy- R-CHo-0-(CH_^CH-0) tl (CHCHa,0) D-H
lated fatty alcohol
071 072 073 074
075 076 077 078
(alkyl) alcohol ethoxylate propoxylate sulfuric acid
(alkyl) alcohol ethoxylate pro poxylate sulfuric acid (salt)
(alkyl) alcohol ethoxylate pro poxylate phosphoric acid
(alkyl) alcohol ethoxylate pro poxylate phosphoric acid (salt)
(alkyl) glyceryl ether chloride
(alkyl) glycidyl ether
(alkyl) glyceryl ether sulfonic acid (salt)
(alkyl) epoxide
R-CHo-0**(CHoCH_0) (CHCH.0) -S0,H
2
22n
2m 3
?3
ethoxylated propoxy- R-CH_-0-(CH,CT,0) (CHCH-0) -SO.Na
. t _. _
*
^ 4n
2 qi j
lated alkyl sulfate
?H3
R-CHo-0-(CHoCH0) (CHCH-0) -P0,H-
2
22n
2m j2
ethoxylated propoxylated alkyl phos phate ester
CH,
iJ
R-CHz,-0-(CH_Cz H Z0) n(CHCHz,0)m -PO3.Na2,
Oi H
r-o-ch2chch2-ci
P\
R-0-CH2CHCH2
fatty glycerol sul fonate
Oi H
R-O-CH2.CHCH2.-SO3Na
A
r-chch2
079 (alkyl) benzene
LAB
CH3(CH2)xCH(CH2) CH3
Oy
080 (alkyl) benzene sulfonic acid
081 (alkyl) benzene sulfonic acid (salt)
LAS
CH3(CH2)xCH(CH2)yCH3
0
SSO03. H
CH3(CH2)) XxCC| HH(CH2)yCH3
o
S03Na
3 3 3 1 3
3
082 (alkyl) phenol
083 (alkyl) phenol ethoxylate
084 (alkyl) phenol ethoxylate sulfuric acid
linear alkyl phenol'
ethoxylated linear alkyl phenol
CH3(CHZ ) xC, H(CHz-) yCH J
O
OH
b yCH3(CH2)xCH(CH2) CH3 O(CH.CHoO) H 2^n
CHS,('CH2,)'x,CH(CH2,) yOH3
085 (alkyl) phenol ethoxylate sul furic acid (salt)
086 (alkyl) phenol ethoxylafjs phosphoric acid
ethoxylated linear alkyl phosphate ester
0(CH,CH,0) -SO,H 2 2n 3
CH-(CH-) CH(CH-) CH,
j z Xj
zy 2
0(CH2CH20)n-S03Na CH3(CH2)xCH(CH2)yCH3
087 (alkyl) phenol ethoxylate phos ethoxylated linear
phoric acid (salt)
alkyl phosphate
ester
0(CH-CH_0) -P0-H2 2 n 32
CH3(CH2)xCH(CH2)yCH3
0(CH2CH20)n-P03Na2
088 089 090 091 092
(alkyl) phenol ethoxylate propoxylate
ethoxylated propoxylated linear alkyl phenol
(alkyl) phenol ethoxylate pro poxylate sulfuric acid
(alkyl) phenol ethoxylate pro poxylate sulfuric acid (salt)
ethoxylated propoxylated alkyl phenol sulfate
(alkyl) phenol ethoxylate pro poxylate phosphoric acid
(alkyl) phenol ethoxylate pro poxylate phosphoric acid (salt)
ethoxylated propoxylated linear alkyl phenol phosphate ester
CH3(CH2)xCH(CH2)yCH3
Q CH,
i J
0(CH,CH,0) (CHCH-O) H
3 2n
2m
CH3(CH2)xCH(CH2)yCH3
O CH3
0(CH,CH_0) (CHCH.0) S0,H
z zn
zm j
CH3-(CH2 -)x,CH(CH2 -)y CH3_
OI cI h3
O(CH-CH-O) (CHCH-0) SO-Na
z zn
z is j
CH3(CH2)xCH(CH2)yCH3
(^5 CH3
1>
O(CH-CH-O) (CHCH-0) P0.H-
z zn
z m j *
CH,(CH-) CH(CH-) CH.
j z x1
ay j
ch3
0(CH2CH20)n(CHCH20)mP03Na2
093 (dialkyl) phenol
linear dialkyl phenol
R
1 "-R
OH
094 (dialkyl) phenol ethoxylate 095 (branched alkyl) benzene
ethoxylated linear dialkyl phenol
AB
O(CH-CH-O) H 22n
R (branched )_>>.
096 (branched alkyl) benzene sul fonic acid
097 (branched alkyl) benzene sulfonic acid (salt)
ABS
098 (branched alkyl) phenol
branched alkyl phenol
R (branched)-|j^|
SOjH
R (branched)--^ ^ SO^Na
R (branched)-^
^OH
5
5 5
099 (branched alkyl) phenol ethoxylate
ethoxylated branched alkyl phenol
R(branched)--^. >^-0(CH2CH20)nH
6
100 (branched alkyl) phenol ethoxylate sulfuric acid
R(branched
0(CH,CH,0) -S0,H 22n 3
6
101 (branched alkyl) phenol ethoxylate sulfuric acid (salt)
102 (branched alkyl) phenol ethoxylate phosphoric acid
ethoxylated branched alkyl phenol sulfate
R(branched)--j^| ''^''O^HjO^O^-SO^Na
6
R (branched )-**.
^-0(CH2CH20)n-P03H2
103 (branched alkyl) phenol ethoxylated phosphoric acid (salt)
ethoxylated branched alkyl phenol phos phate ester
R (br anched )_j^j. 1UJ-o(CH,CH,0) -P0,Na, 22n 32
104 (branched alkyl) phenol ethoxylate propoxylate
ethoxylated propoxylated branched alkyl phenol
CH, 6
R(branched)
Cl O(CH.CH.O)
t^ (CHCH.0)
H
i2n
2m
105 (branched alkyl) phenol ethoxylate propoxylate sulfuric acid
R (branched)
O(CH.CH.O) -(CH-CH.0) -SO,H
22n
2 in J
6
106 (branched alkyl) phenol ethoxylate propoxylate sulfuric acid (salt)
ethoxylated propoxylated branched alkyl phenol sulfate
R(branched).
- CI H3, 0
0(CH2,CH2,0) n-(CH-CH2,0)m-SO3.Na
107 (branched alkyl) phenol ethoxylate propoxylate phosphoric acid
R(branched).
0(CH2CH20)n- (CH-CH2-O)m-PO3-H2-
108 (branched alkyl) phenol ethoxylate propoxylate phosphoric acid (salt)
ethoxylated propoxylated branched alkyl phenol phosphate
ester
R(branched)_--%.
CH 6 i3
0(CH2CH20)n-(CH-CH20)m-P03Na2
- ' - ` '*
'**'
.J y-. 'i' -
109 (branched dialkyl) phenol
branched dialkyl phenol
R(branched)-j^j- R(branched) OH
5
110 (branched dialkyl) phenol ethoxylate
ethoxylated branched dialkyl phenol
R(branchedW%v- R(branched) Y O(CH-CH.O) H zzn
6
111 (alkyl) and (dialkyl) phenoxy benzene sulfonic acid
112 (alkyl) and (dialkyl) phenoxy benzene sulfonic acid (salt)
113 (branched alkyl) and (branched dialkyl) phenoxy benzene sulfonic acid
114 (branched alkyl) and (branched dialkyl) phenoxy benzene sulfonic acid (salt)
115 (alkyl) alpha and (alkyl) internal oletin
-
so3h r--- p * r-o--c>r
S03H
so3h
SOjNa
S03Na
R-d--p ' r-o--^r
S03Na
SO Na
R(br.
SOjH 0.^ , R(br. so3h
S03H R(br. )
so3h
5 5
S03Na
S03Na
R(br.)*P-0-p , R(br.)-p--^-R(br.)
S03Na
SOjNa
5
R-CH=CH2 , CH3(CH2)xCH-CH(CH2)yCH3
3
20
lu, 1>1 4
J 'A
th>
Salt Descriptor Code
00 01 02 03 04 05 06 07 08 09 10 11 12 13 14
TABLE 3 Salt Descriptors
Salt Descriptor (S) Nomenclature
(none)
anmonium salt
lithium salt
.
potassium salt
sodium salt
barium salt
calcium salt
magnesium salt
nickel salt
zinc salt aluminum salt
titanium salt
monoethanol amine salt
diethanol amine salt
triethanol amine salt
21
.i. ..-A . '-i.V
lx. *2*'VLX.'ClfV. X 2*
TABLE 4
Chemical Substance Identification
with Examples
Substance Definition Format
1
SDA Reporting Number
SDA 00-000-00
EXAMPLES: SDA 13-006-04
SDA 13-093-00
SDA Substance Name (A) alkyl (F) (S) or (A) alkyl (F)
Cg-C^ alkyl carboxylic acid sodium salt
^6-^12 ^^^yl phenol
Substance Definition
The combination of alkyl (F)(S) having predominantly (A) alkyl chainlengths that generally conform to the following struc tural diagram:
Insert the Representative Struc tural Diagram from Table 2 which corresponds to F; indicate pro per salt form(s), if applicable.
The combination of alkyl carboxylic acid sodium salts having predominantly C^-C^. alkyl chainlengths that generally conform to the following structural diagram:
0
R-{!-ONa
The combination of dialkyl phenols having predominantly C^-C^, alkyl chainlengths that generally conform to the following structural diagram:
R
OH
2 SDA 00-000-00
EXAMPLE: SDA 13-017-00
(A) alkyl (F) (S) or (A) alkyl (F)
C6-<'12
carboxylic
acid ethoxylate
The combination of alkyl (F)(S) having pre dominantly (A) alkyl chainlengths and ethox ylate and/or propoxylate homologues (as ap propriate) that generally conform to the following structural diagram:
Insert the Representative Struc tural Diagram from Table 2 which corresponds to F; indicate pro per salt form(s), if applicable.
The combination of alkyl carboxylic acid ethoxylates having predominantly C.-C^ alkyl chainlengths and ethoxylate nomologues that generally conform to the fol lowing structural diagram:
0
R-(!-0-(CH-CH,0) -h Z 4n
22
Substance Definition Format
3
SDA Reporting Number
SDA 00-000-00
TABLE 4 (continued)
SDA Substance Same
(A) alkyl (F) (S) or (A) alkyl (F)
EXAMPLE: SDA 13-060-00
C6_C12 alkyl alcoho1
4
SDA 00-000-00
(A) alkyl (F) (S) or
(A) alkyl (F)
EXAMPLE: SDA 13-030-00
Cg-Ci^ alkyl amine ethoxylate
It
Substance Definition
The combination of alkyl (F)(S) having predominantly (A) alkyl chainlengths that generally conform to, or are positional isomers of, the following structural dia gram:
Insert the Representative Struc tural Diagram from Table 2 which corresponds to F; indicate pro per salt form(s), if applicable.
The combination of alkyl alcohols having predominantly C^-C., alkyl chainlengths that generally conform to, or are posi tional isomers of, the following struc tural diagram:
r-ch2-oh
Tj-
-i
The combination of alkyl (F)(S) having predominantly (A) alkyl chainlengths and ethoxylate and/or propoxylate homologues (as appropriate) that generally conform to, or are positional isomers of, Che following structural diagram:
Insert the Representative Struc tural Diagram from Table 2 which corresponds to F; indicate pro per salt form(s), if applicable.
The combination of alkyl amine ethoxylates having predominantly C^-C^ alkyl chainlengths and ethoxylate homologues that generally conform to, or are positional isomers of, the following structural dia gram:
/ (CHL.CHL.0) nH
R-N
\(CHi.CHI.O) mH
23
v
Subs tance Definition Format
5
SDA Reporting Number
SDA 00-000-00
TABLE 4 (continued)
SDA Substance Name
(A) alkyl (F) (S) or (A) alkyl (F)
EXAMPLE: SDA 24-095-00
C^2 branched alkyl benzene
Substance Definition
The combination of alkyl (F)(S) posi tional isomers having predominantly (A) alkyl chainlengths that generally conform to the following structural diagram:
Insert the Representative Struc" tural Diagram from Table 2 which corresponds to F; indicate pro per salt form(s), if applicable.
The combination of alkyl benzene posi tional isomers having predominantly C.. branched alkyl chainlengths that generally conform to the following structural dia gram:
R(branched)
e.g.
(CH3)3CCH2CHCHCH2CH(CH3)2
6
6
SDA 00-000-00
(A) alkyl (F) (S) or
(A) alkyl (F)
EXAMPLE: SDA 24-099-00
C., branched alkyl phenol ethoxylate
24
The combination of alkyl (F)(S) having predominantly (A) alkyl chainlengths and ethoxylate and/or propoxylate homologues (as appropriate) that generally conform to, or are positional isomers of, the following structural diagram:
Insert the Representative Struc~ tural Diagram from Table 2 which corresponds to F; indicate pro per salt form(s), if applicable.
The combination of alkyl phenol ethoxylates having predominantly Cj_ branched alkyl chainlengths and ethoxylate homo logues that generally conform to, or are positional isomers of, the following structural diagram:
R(branched
e.g.
0(CHL,CHJ,. 0) nH CH,
(CH3)3CCH2CHCHCH2CH(CH3)2
<> O(CH.CH.O) H z zn
v'Aj* 1". l`.r.
-.1 - /V*`V^..V.Wiis.I
\V* liv.A
$'/./V..'-M v''.' ..t'.. r> IU'V^'/,( V
v . , ;. >4 \ ,, ,
ILLUSTRATIVE EXAMPLES
The examples listed below illustrate the applicability and limitations of this method. Where appropriate, the examples are treated by the seven step procedure outlined in the Reporting Instructions.
; EXAMPLE 1
A mixture of synthetically derived saturated C^ through C^g linear alcohols is reacted with ethylene oxide_to manufacture the ethoxylated alcohol.
Step 1: The distribution of alkyl chainlengths in the starting fatty alcohol is determined to be:
Carbon Chainlength Distribution Saturated Unsat. Branched
% Composition*
C 12
No 20
C 14 No 30
C 16 No 30
C 18 No 20
* by weight of starting fatty alcohol
Step 2: The following table lists those Alkyl Descriptors which should be considered:
Alkyl Desc. Code
Predominant Carbon Chainlength Saturated Unsaturated Branched
Components Within Category
Number3 of Extra Components
Number3 of Missing Components
14
8-26
--
15 10-16 --
16 12-18 --
17 14-18 --
18 14-26 --
No 100% No 80 No 100 No 80 No 80
6 1 0 0
4
0 1 0 1
1
2
Since the alcohol contains only even chainlengths, only the possible even
chainlenths are considered.
I
i*
i
i
i
I
i
iI t
25
I jtLd ! >#i`WCiL\k*Jl
Analysis: Alkyl Descriptors 14 and 16 include the same percentage of components of the fatty alcohol (100 percent) within the range of the descriptors. However, Descriptor 16 includes the highest percentage of components with the fewest additional or missing components. Therefore, Alkyl Descriptor 16 is most representative of the alkyl composition.
Step 3: Referring to Table 2, the Functionality Descriptor for an ethoxylated fatty alcohol is 065.
Step 4: Referring to Table 3, the appropriate Salt Descriptor is 00, since the substance is not a salt.
Step 5: Construct the SDA Reporting Number by sequentially combining the codes derived in steps 2, 3 and 4:
SDA 16-065-00
Step 6:
Following the standard format, construct the SDA Substance Name using the descriptor nomenclature, found in Tables 1 through 3, which corresponds to each descriptor code:
C^2-C^g alkyl alcohol ethoxylate
Step 7:
Complete Form C, taking into account all the individual chemical substances which are encompassed by this SDA Substance Name and Reporting Number.
EXAMPLE 2
A manufacturer reacts a mixture of linear synthetic C.--C., alcohols with ethylene oxide and propylene oxide to form the ethoxylated, propoxylated alcohol.
Step 1:
The distribution of alkyl chainlengths in the starting fatty alcohol is determined to be:
Carbon Chainlength Distribution Saturated Unsat. Branched
% Composition*
C12 "
No
20
C13 " C14 " C15 "
No No No
30 30 20
by weight of starting fatty alcohol
Step 2:
The following table lists those Alkyl Descriptors which should be considered:
26
Alkyl Desc. Code
Predominant Carbon Chainlength Saturated Unsaturated Branched
Components Within Category
Number of Extra Components
Number of Missing Components
14
8-26
--
15 10-16 --
16 12-18 --
No 100 No 100 No 100
15 ` 3 3
0 0 0
Since the alcohol contains both even and odd chainlengths, all chainlengths are considered.
Analysis: All three Alkyl Descriptors (14, 15, 16) include the
same percentage of components of the starting fatty alcohol.
Alkyl Descriptors 15 and 16, however, both provide the fewest
additional or missing components. Although either descriptor
is applicable based on the previous analysis. Alkyl Descriptor
15 is preferred, since it provides a better technical descrip
tion of the alkyl composition, i.e., the fatty alcohol composi
tion is nearer the center of the range provided by Alkyl
Descriptor 15.
.
Step 3:
Referring to Table 2, the Functionality Descriptor for an ethoxylated propoxylated fatty alcohol is 070.
Step 4:
Referring to Table 3, the appropriate Salt Descriptor is 00, since the substance is not a salt.
Step 5:
Construct the SDA Reporting Number by sequentially combining the codes derived in Steps 2, 3, and 4:
SDA 15-070-00
Step 6:
Following the standard format, construct the SDA Substance Name using the descriptor nomenclature, found in Tables 1 through 3, which corresponds to each descriptor code:
alkyl alcohol ethoxylate propoxylate
Step 7: .
Complete Form C, taking into account all the individual chemical substances which are encompassed by this SDA Substance Name and Reporting Number.
EXAMPLE 3
A manufacturer blends two linear synthetic alcohol mixtures, and then reacts them with ethylene oxide and propylene oxide, forms the phosphate acid ester by reaction with polyphosphoric acid and finally neutralizes with a combination of potassium hydroxide and sodium hydroxide.
Step 1:
The distribution of alkyl chainlengths in the starting saturated, linear fatty alcohol is determined to be:
27
Ik
!
'I
i
........ -
.i.j.r.-.v'VJ.'CiuA
Alkyl Chainlength
C10 C14 Alcohol
C12-G18 Alcohol
4:1 Blend* % Composition
o o
85 0 68.0
C12
8 20
10.4
C14
6 30
10.8
C16
0 30
6.0
C18
0 20
4.0
* by weight of starting fatty alcohols
'
Step 2:
The following table lists those Alkyl Descriptors which should be considered:
Alkyl Desc. Code
Predominant Carbon Chainlength Saturated Unsaturated Branched
Components Within Category
Number of Extra Components
Number of Missing Components
13
6-12
--
14
8-26
--
15 10-16 --
No 78.4 No 99.2 No 95.2
2 5 0
3 0 1
Analysis: Alkyl Descriptors 14 and 15 include essentially the same percentage of alkyl components within the descriptor ranges. Alkyl Descriptor L5 is selected because it includes the fewest additional or missing components. -
Step 3:
Referring to Table 2, the Functionality Descriptor for ethoxylated propoxylated alkyl phosphate ester is 074.
Step 4:
Referring to Table 3, the appropriate Salt Descriptor is 03, 04, since it is a mixed potassium salt and sodium salt of the divalent alkyl phosphoric acid anion.
NOTE: Mixed salts should be reported in terms of the indivi. dual components for salts of monovalent anions. For example,
for the mixed sodium and potassium salts of a C-.--C.., alkyl carboxylic acid, report separately the sodium salt tDA 15 006-04) on Form C and the potassium salt (SDA 15-006-03) on a separate Form C.
Step 5: Step 6:
Construct the SDA Reporting Number by sequentially combining the codes derived in steps 2, 3, and 4:
SDA 15-074-03,04
Following the standard format, construct the SDA Substance Name using the descriptor nomenclature, found in Tables 1 through 3, which corresponds to each descriptor code:
C10-C16 a-*-ky-*- alcohol ethoxylate propoxylate phosphoric acid potassium and sodium salt
Step 7:
Complete Form C, taking into account all the individual chemical
substances which are encompassed by this SDA Substance Name and Reporting Number.
EXAMPLE 4
As an aid in reporting natural fats and oils, the sources covered
in the addencum are listed below, together with the Alkyl Descriptor
Codes, which, in most instances, should be appropriate:
-
Source
Alkyl Descriptor
Code
Source
Alkyl Descriptor
Code
Avocado Babassu Castor Coconut Corn Cottonseed Crambe Grease (animal) Herring Lard Linseed Menhaden Neatsfoot Olive Oiticica . Palm Palm-kernal Peanut
9 t
JL
10 1
11
11 7 4 4 4
11 5 4
11 11 11
1 8
Poultry Rapeseed Rice Bran Safflower Safflower
(high oleic) Salmon Sardine Sesame Sorghum Soybean Sperm Body Sperm Head Sunflower Tallow Tung Whale
4 11 11 11
9
5 5 11 11 11 3 2 11 4 9 5
The indicated Alkyl Descriptors may be used to describe the alkyl chainlengths of the natural sources unless they have been fractionated or combined with other materials.
EXAMPLE 5
Stearyl amine is reacted with fatty acids to form an amide.
Step 1;
The distribution of alkyl chainlengths in the fatty acids is determined to be:
Carbon Chainlength Distribution Saturated Unsat. Branched
% Composition*
C14 --
C16 -- C18 -- -- C16 --- C18
No No . No No No
weight of starting fatty acids
2.5 25.0 18.0
3.0 50.5
Step 2:
It is obvious by inspection, without generating a table, that Alkyl Descriptor Code 04 provides a perfect descriptor.
.1 Mil j* i.-I''J%iki.L:v\<i\4i^kiw'.vCittHCjr .' Li/T^J idfc'JMVXO-ii-kSL
Step 3:
Because stearyl amine (C^g saturated alkyl amine), a Class 1 chemical substance, is used as one of the reactants, the manufactured substance in this example must be reported according to the normal method for reporting Class 2 chemical substances with'no known CAS Registry Number. The SDA method may be used, however, to define the fatty acid reactant. Referring to Table 2, the Functionality Descriptor for the fatty acid is 005.
Step 4:
Referring to Table 3, the appropriate Salt Descriptor for the fatty acid is 00^, because the substance is not a salt.
Step 5:
Construct the SDA Reporting Number by sequentially combining the codes derived in steps 2, 3 and 4.
SDA 04-005-00
Step 6: -
Following the standard format, construct the SDA Substance Name using the descriptor nomenclature, found in Tables 1 through 3, which corresponds to each descriptor code.
C^-C^g and C^g-C^g unsaturated alkyl carboxylic acid
Step 7:
On Form C, in the space provided for structural and other sup plemental information, enter the following reaction description:
Stearyl amine + C,/-C-.g an<* <"16~("18 unsaturated alkyl carboxylic acid1- >
124-30-1
.
(CAS Reg. No.)
SDA 04-005-00
Note:
CX-|4.-Cl-oi0 and Cl,o. --C, o0 unsaturated alkyl stearyl amide
If the alkyl amine reactant had been a Class 2 chemical substance reportable using this method, the reaction product could could be reported using Functionality Descriptor 026: (alkyl) carboxylic acid amide (alkyl).
EXAMPLE 6
A manufacturer hydrogenates an alkyl nitrile and then alkylates it to form a dialkyl amine which is then reacted with methyl chloride to form a quaternary ammonium chemical substance.
Step 1:
The alkyl nitrile and the alkylating agents are separately described by Alkyl Descriptors found in Table 1. Hence, their alkyl compo sitions may be combined and the SDA method may be used. The distri bution of alkyl chainlengths in the linear fatty reactants is deter mined to be:
30
A 1 - * *--*
*-*- *-^-*-1-*-
*- ,jl'i
V.i\>
Alkyl Chainlength
Nitrile
Alkylating Agent
% Composition*
C12 C14 C16 , C18 C^g unsaturated
25 40 35 -- --
-- . 12.5 -- 20 40 37.5 30 15 30 15
*by weight of the combination of alkyl nitrile and alkylating agent
Step 2: The following table lists those Alkyl Descriptors which should be considered
Alkyl Desc. Code
Predominant Carbon Chainlength Saturated Unsaturated Branched
Components Within Category
Number of Extra Components
Number of Missing Components
01 8-18
18 No
100
02
10-16
12-20
No
85
03
14-18
12-20
No
87.5
04
14-18
16-18
No
87.5
05
14-18
16-22
No
87.5
06
14-18
16-26
No
87.5
07
14-22
16-22
No
87.5
08 14-22
18 No
87.5
2 5 4 1 3 5 5 2
0 1 1 1 1 1 1 2
Analysis: Alkyl Descriptor 01 includes the highest percentage of components (100 percent). Alkyl Descriptor 04 includes a somewhat lower percentage of components, but has the same total number of additional and missing components as Descriptor 01. Because of the higher precentage of components. Descriptor 01 is selected.
Step 3: Referring to Table 2, the Functionality Descriptor for dialkyl dimethyl ammonium chloride is 047.
Step 4: Referring to Table 3, the appropriate Salt Descriptor is 00, since the substance is not a salt.
Step 5: Construct the SDA Reporting Number and subsequently combining the codes derived in steps 2, 3, and 4:
SDA 01-047-00
r
31
' I* .A. V
-
'.'.X+T, *i :
w.'h>.*,iJ.U-4 V
t
Step 6:
Following the standard format, construct the SDA Substance Name using the descriptor nomenclature found in Table 1 through 3, which corresponds to each descriptor code:
Cg-Cig and C^g unsaturated dialkyl dimethyl ammonium chloride
Step 7:
Complete Form C, taking into account all the individual chemical substances which are encompassed by this SDA Substance Name and Reporting Number.
EXAMPLE 7
The still bottoms from the distillation of the alcohol described in Example 2 are sold for use in a lubricant.
. Step 1: The composition varies and is not well defined. Therefore, it cannot be represented in terms of alkyl composition, etc.
Step 2: Referring back to Example 2, Alkyl Descriptor 15^ was selected to describe the alkyl composition.
Step 3: Although this variable composition is not included in Table 2, the Functionality Descriptor for the fatty alcohol is 060.
Step 4: Although this variable composition is not included in Table 3, the Salt Descriptor is 00.
Step 5: The Reporting Number for the fatty alcohol is SDA 15-060-00.
Step 6: The Substance Name for the fatty alcohol is c -C alkyl
alcohol.
10 16
Step 7: On Form C, in the space provided for structural and other sup plemental information, enter the following description:
Still bottoms from distillation of SDA 15-060-00, ^C10-C16 alky1 alcohol).
NOTE: Since the chemical substance is distributed in com merce, it must be reported. The variable composition of this material can be reported using the appropriate pre cursors as defined by this addendum.
EXAMPLE 8
.
A manufacturer distills a blend of linear saturated fatty acids to obtain a relatively pure dodecyl (C.^) fatty acid. The fatty acid is re acted to form a methyl ester.
32
jf ^ ^
Step 1:
Since the fatty acid is a single chainlength without any isomeric variations, the Alkyl Descriptors are not appropriate. Instead, Form A, Form B, or Form C should be considered for reporting this Class 1 chemical substance, depending on whether the sub stance appears on the Candidate List or has a CAS Registry Number.
NOTE: If the fatty acid reactant had been a complex combination of chainlengths, this system would have been applicable.
Steps 2-7:
These steps are not appropriate in view of the conventional re reporting which is required.
33
SECTION II
COKE AND SELECTED COAL CHEMICALS
Developed in Conjunction with the
American Coke and Coal Chemicals Institute
Coke (Coal)
[*65996-77-2]
HOOO-OI89
The cellular carbonaceous mass resulting from the high
temperature (greater than 700cC) destructive distillation
of coal. Composed primarily of carbon. May contain varying amounts of sulfur and ash.
Coke Oven Light Oil (Coal)
[*65996-78-3]
H000-0205
Synonyms: Light Oil (Coal), Intermediate Light Oil (Coal), Crude Light Oil (Coal)
The volatile organic liquid extracted from the gas
evolved in the high temperature (greater than 700C) destructive distillation of coal. Composed primarily of benzene, toluene, and xylenes. May contain other minor hydrocarbon constituents.
Solvent Naphtha (Coal)
[*65996-79-4]
H000-0314
The distillate from either High Temperature Coal Tar, Coke Oven Light Oil, or Coal Tar Oil Alkaline Extract Residue having an approximate distillation range of 130C to 210cC. Composed primarily of indene and other polycyclic ring systems containing a single aromatic ring. May contain phenolic compounds and aromatic nitrogen bases.
Ammonia Liquor (Coal)
[*65996-80-7]
H0O0-0422
The dilute aqueous solution extracted from the gas evolved in the high temperature (greater than 700C) destructive distillation of coal. Composed primarily of ammonium carbonate
and- other ammonium salts. May contain other water-soluble substances including phenol.
35
Coke Oven Gas (Coal)
[*65996-81-8]
H000-0531
The gas evolved from the high temperature (greater than 700cC) destructive distillation of coal after the removal of High Temperature Coal Tar, Coke Oven Light Oil, and Ammonia Liquor. Composed primarily of hydrogen and methane. May contain ammonia, hydrogen sulfide, and low molecular weight hydrocarbons.
Coal Tar Oil
[*65936-82-9]
HOOO-O055
Synonyms: Chemical Oil (Coal), Tar Acid Oil (Coal) The distillate from High Temperature Coal Tar having
an approximate distillation range of lj50 to 250C. Composed primarily of naphthalene, alkylnaphthalenes, phenolic compounds, and aromatic nitrogen bases.
Coal Tar Oil Alkaline Extract
[*65996-83-0]
H000-07S1
Synonym: Chemical Oil Alkaline Extract (Coal) The extract from Coal Tar Oil produced by an alkaline
wash such as aqueous sodium hydroxide. Composed primarily of the alkali salts of various phenolic compounds.
Crude Coal Tar Bases
[*65996-84-1]
HOOO-0879
The reaction product obtained by neutralizing Coal Tar Base Extract Oil with an alkaline solution, such as aqueous sodium hydroxide, to obtain the free bases. Composed primarily of a complex combination of pyridine, quinoline, and their alkyl derivatives.
Crude Coal Tar Acids
[*65996-85-2]
HOOO-O989
The reaction product obtained by neutralizing Coal Tar Oil Alkaline Extract with an acidic solution, such as aqueous sulfuric acid, to obtain the free acids. Composed primarily of phenol, cresols, and xylenols.
Coal Tar 3ase Extract Ojl
[*65996-86-3]
H000-1073
The extract from Coal Tar Oil Alkaline Extract Residue produced by an acidic wash such as aqueous sulfuric acid after distillation to remove naphthalene. Composed primarily of the acid salts of various aromatic nitrogen bases including pyridine, quinoline, and their alkyl derivatives.
36
Coal Tar Oil Alkaline Extract Residue
[*65996-87-4]
HOOO-1197
Synonym: Chemical Oil Alkaline Extract Residue The residue obtained from Coal Tar Oil by an alkaline wash such as aqueous sodium hydroxide after the removal of Crude Coal Tar Acids. Composed primarily of naphthalenes and aromatic nitrogen bases.
Benzol Forerunnings (Coal)
[*65996-88-5]
HOOO-1213
The distillate from Coke Oven Light Oil having an approximate distillation range below 100C. Composed primarily of C4-C6 aliphatic hydrocarbons.
Coal Tar, High Temperature
[*65996-89-6]
H000-1322
The condensation product obtained by cooling, to approximately ambient temperature, the gas evolved in the high temperature (greater than 700C) destructive distillation of coal. A black viscous liquid denser than water. Composed primarily of a complex mixture of condensed ring aromatic hydrocarbons. May contain minor amounts of phenolic compounds and aromatic nitrogen bases.
Coal Tar, Low Temperature
[*65996-90-9]
H000-1430
The condensation product obtained by cooling, to approximately ambient temperature, the gas evolved in low temperature (less than
700C) destructive distillation of coal. A black viscous liquid denser than water. Composed primarily of condensed ring aromatic hydrocarbons, phenolic compounds, aromatic nitrogen bases, and their alkyl derivatives.
Coal Tar Upper Distillate
[*65996-91-0]
HOOO-15^5
The distillate from High Temperature Coal Tar having an approximate distillation range of 220C to 450C. Composed primarily of three to four membered condensed ring aromatic hydrocarbons.
Coal Tar Distillate
[*65996-92-1]
H000-loo9
The distillate from High Temperature Coal Tar having an approximate distillation range of 130C to 450C. Composed primarily of two to four membered condensed ring aromatic hydrocarbons, phenolic compounds, and aromatic nitrogen bases.
37
t'S , t
'"V/* vV i'.'lj
*1 *XLKUt>
f*.
.v >
Coal Tar Pitch
[*5536-53-2]
HOOO-1778
The residue from the distillation of High Temperature Coal Tar. A black solid with a softening point from 4oC"to l8oC. Composed primarily of a complex combination of three or more membered condensed ring aromatic hydrocarbons.
38
SECTION III
CHEMICAL SUBSTANCES COMMON
TO THE
IRON AND STEEL INDUSTRY
Developed in Conjunction
with the American Iron and Steel Institute
Iron Ore Agglomerates
[*55395-55-5]
HOOO-1886
The product of agglomerating iron ore fines, concentrates. Iron Sinter, and other iron-bearing materials. Includes pellets, nodules and briquettes.
Iron Sinter
[*55395-53-9]
HOOO-1995
The thermally agglomerated substance formed by heating a variable mixture of finely divided coke, iron ore. Blast Furnace Dust, Steelmaking Dust, Mill Scale, other miscellaneous iron-bearing materials, limestone, and dolomite at 2400F to 2700F.
Furnace Iron
[*55995-57-9]
H000-2085
The metallic substance produced in a blast furnace or direct reduction furnace which contains over 90/o iron.
Blast Furnace Gas (Ferrous Metals)
[*55395-59-1]
HOOO-2116
The off gas from blast furnaces. Composed primarily of carbon monoxide, carbon dioxide, nitrogen, and hydrogen.
Blast Furnace Slag (Ferrous Metals)
[*95995-59-2]
H000-2225
The fused substance formed by the action of a flux upon the gangue of the iron-bearing materials charged to a blast furnace and upon the oxidized impurities in the iron produced. Depending upon the particular blast furnace operation, the slag is composed primarily of oxides of aluminum, calcium, magnesium, and silicon, with varying amounts of sulfur.
39
.......................................... ..
m. M*..
J.V4 a UCW^X I
Blast Furnace Dust (Ferrous Metals) .
[*65996-70-5 ]
H000-2333
The dust generated from the initial cleaning of off gases
from a blast furnace. Composed primarily of iron and carbon. May contain varying amounts of other elements, oxides, and trace compounds.
Steelmaking Slag
f*65996-71-6]
H000-2442
The fused substance formed by the action of a flux upon the gangue of iron-bearing materials charged to a steelmaking furnace and upon the oxidized impurities in the steel produced.
Depending upon the particular steelmaking operation, the slag is composed primarily of oxides of aluminum, calcium, iron, magnesium, manganese, phosphorus, and silicon, with varying amounts of sulfur.
S-teelmaking Dust
[*65996-72-7]
HOOO-2551
The dust generated during the charging, operation, and tapping of a steelmaking furnace and from steel conditioning, including that which is recovered through the use of pollution abatement equipment. Composed primarily of iron oxides. May contain varying amounts of other metallic oxides and trace compounds.
Blast Furnace and Steelmaking Sludge
[*65996-73-8]
HOOO-2675
The wetted particulate matter recovered by wet collection techniques, including pollution abatement equipment, for the recovery of materials such as iron sinter dust. Blast Furnace Dust, Steelmaking Dust, and Mill Scale.
Mill Scale (Ferrous Metals)
[*65996-74-9]
HOOO-2764
The oxidized surface of steel produced during reheating, conditioning, hot rolling, and hot forming operations. This substance is usually removed by process waters used for descaling, roll and material cooling, and other purposes. It is subsequently recovered by gravity separation techniques. Composed primarily of high-purity iron oxides. May contain varying amounts of other oxides, elements, and trace compounds.
Spent Pickle Liquor (Ferrous Metals)
[*65996-75-0]
HOOO-2899
The solution of an appropriate pickling acid or combination
of acids containing any of the elements, oxides, or salts present in steel. Pickling acids include hydrochloric, hydrofluoric, nitric, phosphoric, and sulfuric acids.
40
Metallic Dross or Spelter (Ferrous Metals) [*65996-76-1] H000-2915
The metallic salts and oxides removed from the molten metals used to coat steel by dip processes. Composed primarily of salts and oxides of aluminum, lead, tin, and zinc.
Chemical Substances Manufactured
;
as Part of Steel
[*65997-19-5] HOOO-309^
This category includes the chemical substances which are manufactured as part of steel and alloy steels. The following list identifies those elements which may exist in steel or which may comprise compounds present in steel or alloy steels. Aluminum, Beryllium, Boron, Calcium, Carbon, Cerium, Chromium, Cobalt, Copper, Hafnium, Iron, Lanthanum, Lead, Magnesium, Manganese, Molybdenum, Nickel, Niobium, Nitrogen, Oxygen, Phosphorus, Selenium, Silicon Sulfur, Tantalum, Tin, Titanium, Tungsten, Vanadium, Yttrium, Zinc, Zirconium.
41
SECTION IV WOOD AND PULP CHEMICALS
Developed in Conjunction with the
Pulp Chemicals Association
Oil of Turpentine
[*8006-64-2]
HOOO-3119
Any of the volatile predominately terpenic fractions or distillates resulting from the solvent extraction of, gum collection from, or pulping of softwoods. Composed primarily of the CioHiq terpene hydrocarbons: a-pinene, 3-pinene, limonene, 3-carene, camphene. May contain other acyclic, monocyclic, or bicyclic terpenes, oxygenated terpenes, and anethole. Exact composition varies with refining methods and the age, location, and species of the softwood source.
Oil of Turpentine. a-Pinene Fraction [*65996-96-5]
HOOO-323^
The hydrocarbon fraction distilled from Oil of Turpentine. Contains greater than 80/o a-pinene, the remainder being other terpene hydrocarbons.
Oil of Turpentine, 3-Pinene Fraction [*65996-97-6] HOOO-33^3
The hydrocarbon fraction distilled from Oil of Turpentine
or produced by the isomerization of a-pinene. Contains
greater than 70/o 3-pinene. Other major components being
limonene, a-pinene, camphene, myrcene. May contain other acyclic,
monocyclic, and bicyclic terpenes.
.
Pine Oil
[*8002-09-3]
HOOO-3^59
A complex combination of terpenes produced by the high temperature distillation of oil of turpentine residues or by the catalytic hydration of pinenes. Composed primarily of isomeric tertiary and secondary cyclic terpene alcohols. May contain terpene hydrocarbons and ethers. Exact composition varies with production methods and turpentine source.
43
Terpenes, 80/o or greater Llmonene Fraction [*65996-98-7] HOOO-358S
A complex combination of terpenes derived from Oil of Turpentine or citrus oils by fractionation or isomerization of other terpene fractions. Contains at least 80/o limonene, the remainder being other terpene hydrocarbons. May contain trace amounts of alcohols, ethers, aldehydes, or ketones.
Oil of Turpentine. 50/o or greater Limonene Fraction [*65996-99-8] KQOO-J>68j>
A complex combination of terpenes derived from Oil of Turpentine. Contains at least 50/o limonene, the remainder being phellandrenes, terpinenes, terpinolene, cineoles.
Oil of Turpentine, 8o/o or greater Terpinolene Fraction [*65997-00-4] HOOO-3705
A complex combination of terpenes derived from Oil of Turpentine. Contains at least 80vo terpinolene, the remainder being mixed terpene hydrocarbons.
Tall Oil [*8002-26-4]
HOOO-38l8
A complex combination of tall oil rosin and fatty acids -derived from the acidulation of crude tall oil soap and including that which is further refined. Contains at least 10/o rosin.
Tall Oil, sodium salt [*65997-01-5]
HOOO-3922
Synonyms: Black Liquor Soap, Tall Oil Soap Skimmings, Crude Tall Oil Soap (Kraft Process)
The sodium salt of Tall Oil formed during the kraft process where it becomes a component cf the spent pulping liquor.
The soap separates when the pulping liquor is concentrated and can be recovered by skimming the concentrated liquor.
Spent Acid from Crude Tall Oil Soap Acidulation [*65997-02-6] H000-4015
The aqueous layer formed by acidulation of tall oil soap with sulfuric acid during the production of Tall Oil. Composed primarily of a solution of sodium sulfate, the remainder being lignin and Tall Oil.
44
Tall Oil Pitch
8016- 81-7]
H000-4122
The residue from the distillation of Tall Oil-. Composed primarily of high-boiling esters of fatty acids and rosin. May contain neutral materials, free fatty acids and rosin acids.
Tall Oil Heads
65997-03-7]
H000-4246
The low boiling fraction obtained by the distillation of Tall Oil. Contains fatty acids such as palmitic, stearic, oleic and linoleic as well as neutral materials.
Tall Oil Fatty Acids
61 790-12- 3]
HOOO-4^52
A complex combination obtained by distillation of Tall Oil. Contains at least 90/o fatty acids, primarily oleic and linoleic acids, the remainder being rosin and neutral materials.
Rosin
8050-09-7]
HOOO-446^
A complex combination derived from wood, especially pine wood. Composed primarily of resin acids and modified resin acids such as dimers and decarboxylated resin acids. Includes rosin stabilized by catalytic disproportionation.
Tall Oil Fatty Acids, Sodium Salt 61790-45-2]
HOOO-4577
Tall Oil Fatty Acids. Potassium Salt
f61730-44-1]
HOOO-469S
Rosin. Glycerol Ester
f8050-31-5]
H000-4713
Rosin, Pentaerythritol Ester
[*8050-26- 8]
HOOO-4823
Rosin, Maleic Acid Adduct
[*8050-28-0]
HOOO-49^1
Rosin, Fumaric Acid Adduct
[*65997-04-8]
H000-5028
Rosin, Polymerized
[*65997-05-9]
H000- 51^0
Rosin, Hydrogenated
[*65997-06-0]
H000-5258
45
Rosin, Reaction Product with Formaldehyde [*65997-07-1] HOOO-5367
Rosin, Maleic Acid Adduct - Glycerol Ester [*65997-08-2] HOOO-5477
Rosin, Maleic Acid Adduct - Pentaerythritol Ester [*65997-09-3] HOOO-5586
Rosin, Fumaric Acid Adduct - Glycerol Ester [*65997-10-6]
HOOO-5615
Rosin, Fumaric Acid Adduct - Pentaerythritol Ester [*65997-11-7] HOOO-5724
Rosin, Polymerized - Glycerol Ester [*9006-47-7] HOOO-583I
Rosin, Polymerized - Pentaerythritol Ester
[*65997-12-8] HOOO-5949
Rosin, Hydrogenated - Glycerol Ester [*65997-13-9]
H000-60354
Rosin, Hydrogenated - Pentaerythritol Ester
[*65997-14-0] HOOO-5l49
46
SECTION V
CHEMICAL SUBSTANCES MANUFACTURED
IN THE
.
PAPER INDUSTRY
Developed in Conjunction with the
American Paper Institute
Cellulose, Chemical Pult>
[*65996-61-4]
HOOO-626^
The fibrous substance obtained from the treatment of lignocellulosic substances (wood or other agricultural fiber sources) with one or more aqueous solutions of pulping and/or bleaching chemicals. Composed of cellulose, hemi-cellulose,
lignin, and ether minor components. The relative amounts of these components depend on the extent of the pulping and bleaching processes.
Examples: bleached and unbleached kraft, sulfite and semichemical pulp and bleached mechanical pulp. Includes virgin and recycled pulps.
Starch, Oxidized
[*65996-62-5]
HOOO-6372
The substance resulting from treatment of starch in aqueous
slurry with an aqueous oxidizing agent such as hydrogen peroxide,
sodium hypochlorite, hypochlorous acid, or ammonium persulfate.
Under controlled conditions of temperature, pressure, and time,
the oxidizing agent reacts with the starch to cleave the polymeric
chains and to oxidize the end groups from aldehyde to carboxylic
acid groups.
'
Starch, Acid Hydrolyzed
[*65996-63-6]
HOOO-6481
The substance resulting from treatment of starch in aqueous slurry with small amounts of an acidifying substance, such as aluminum sulfate, generally at elevated temperature and pressure.
The process is usually continuous with the time of treatment very short. Degree of hydrolysis is usually determined by measurement of viscosity and controlled by rate of the slurry through the reactor, temperature, and acidity.
47
otarch. Enzyme Hydrolyzed
[*65996-64-7]
HOOO-6591
The substance resulting from treatment of starch in aqueous slurry with amylase or carbohydrase under controlled conditions of temperature, pressure, and time. The degree of hydrolysis is usually determined by measurement of viscosity. Enzymatic hydrolysis is terminated by destroying the enzyme by raising the temperature or adjusting the pH.
Magnesium Bisulfite
[13774-25-9]
H000-6^13
Spent pulping liquor
[*6C071-92-9J
HOOC-7855
The aqueous solution resulting from the reaction of lignocellulosic substances (wood or other agricultural fiber sources) with one or more pulping chemicals including those used in the kraft, sulfite, semichemical or other pulping processes. Composition is highly variable and includes excess pulping chemicals, dissolved and degraded cellulose, hemicellulose and lignin.
48
SECTION VI
CHEMICAL SUBSTANCES MANUFACTURED IN THE
FERTILIZER INDUSTRY
Developed in Conjunction with
The Fertilizer Institute
Phosphate Rock, Calcined
[*65996-94-3]
HOOO-0778
Substance obtained by heating naturally occurring phosphate rock to 732C to 8l6C (1350F to 1500CF) in a fluidized bed or other suitable device for oxidizing carbonaceous matter. Characterized by upgraded phosphorus content and reduced hydrocarbon levels.
Superphosphate
[*8011-76-5]
HOOO-5842
Synonyms: Normal Superphosphate, Enriched Superphosphate Substance obtained by treating phosphate rock with sulfuric acid or a mixture of sulfuric and phosphoric acids. Composed primarily of calcium phosphates and calcium sulfate.
Superphosphate, Concentrated
[*65996-95-4]
HOOO-5955
Synonyms: Double Superphosphate, Treble Superphosphate, Triple Superphosphate
Substance obtained by acidulating phosphate rock with phosphoric acid. Normally characterized as containing 40/o or more available phosphoric oxide (P2C5). Composed primarily of calcium phosphate.
Superphosphoric Acid
[*8017-16-1]
H000-7045
Synonym: Polyphosphoric Acid
-
Combination of phosphoric acids obtained by dehydration of
orthophosphoric acid or by oxidation of phosphorus in the presence
of water. Composed primarily of polyphosphoric acids whose
molecular structure, contains more than one atom of phosphorus.
49
SECTION VII
NATURAL OILS AND EXTRACTIVES
Developed in Conjunction with the
Essential Oils Association
This section identifies certain chemical substances which are primarily oils derived from botanical sources. In some instances, a substance is defined to include the oil, extractives, and physically modified deri vatives obtained from the source. In this context, "physically modified" means the application of cer tain processes not involving chemical reactions, namely: distillation, expression, filtration, drying, heating, cooling, extraction, and decolorization by adsorption.
Ajowan Oil
[*8001-99-81
H002-4966
Ptychotis ajowan or Carum ajowan, Umbelliferae
Almond Oil, Bitter
[*8013-76-11 H002-50E6
Prunus amygdalus or Prunus armeniaca, Rosaceae
Amber Oil
[*8002-67-31 H002-5160
Pinus succinifera
Ammoniac Gum [*9000-03-7] H002-5276
Extractives and their physically modified derivatives. Doreina ammoniacum, Umbelliferae
Amyris Oil
t*8015-65-4] H002-5594
Extractives and their physically modified derivatives.
Amyris balsamifera, Rutaceae
Angelica Root Oil [*80 1 5- 64- 37
H002-5414
Extractives and their physically modified derivatives.
Scot Oil, .Seed Oil. Angelica archangelica, Umbelliferae
Anise Oil [*8007-70-31 . H002-5650
Extractives and their physically modified derivatives. Pimpinella anisura, Umbelliferae
Apopin Oil
[*8022-78-4]
Cinnamonum camphora
H002-5741
Araucaria Oil
[*8013-08-71 7002-5866
Extractives and their physically modified derivatives.
Callitropsis araucarioides, Cupressaceae
Asafoetida Gum
[*9000-04-81
H002-5972
Extractives and their physically modified derivatives.
Ferula asafoe or F. asafoetida L. or F. alliacea Boiss,
Unbelliferae
Basil Oil
1*8010-73-41 HOO2-6062
.
Extractives and their physically modified derivatives.
Ocimum basilicum, Labiatae
Bergamot Oil
[*8007-73-81 H002-6175
Extractives and their physically modified derivatives.
Citrus bergamia. Citrus
52
3irch Tar Oil [*8001-88-5] H002-6288
Extractives and their physically modified derivatives.
Betula pubescens, Betulaceae
Bois de Rose Oil f*8015-77-8] HOO2-6313 Extractives and their physically modified derivatives. Aniba rosaeodora, Lauraceae
Soldo Leaf Oil
[*8022-81-9] H002-6428
Peumus boldus
''
Boronia Oil
[*8053-33-6] H002-6536
Extractives and their physically modified derivatives.
Boronia megastigma, Rutaceae
Cade Oil
1*8013-10-3] H002-6643
Extractives and their physically modified derivatives.
Juniperus oxycedrus, Cupressaceae
Cajuput Oil
1*3008-98-81 H002-6756
Melaleuca minor, Myrtaceae
Calamus Oil
<:*6C15-70-01
Acorus calamus, Araceae
H002-6873
Camphor Oil
[*8008-51-31 H002-6984
Extractives and their physically modified derivatives.
Cinnamomum camphora, Lauraceae
Canada Balsam
[*8007-47-41
H002-7074
Extractives and their physically modified derivatives.
Abies balsamea or Tsuga canadiensis, Pinaceae
Cape Oil
1*8022-45-51
Popowia capea
H002-5529
Capsicum Olecresin
[*8023-77-61
H002-7184
Extractives and their physically modified derivatives.
Capsicum annuum or Capsicum longum. Capsicum Frutescens,
or Capsicum fastigiatum, or Capsicum minimum mill, Solanaceae
Caraway Oil
[*8000-42-81
H002-7295
Extractives and their physically modified derivatives.
Carum carvi, Umbelliferae
53
Cherry Laurel Oil
[*8000-44-01 H002-866J
Prunus laurocerasus, Rosaceae
Cognac Oil, . Green [*8016-21-5] HOO2-8776
Extractives and their physically modified derivatives Wine lees oil
Coriander Oil [*8006-52-41 HOO2-8896
Extractives and their physically modified derivatives Coriandrum sativum, Umbelliferae
Costas Oil
T*8023-88-91 H002-8911
Extractives and their physically modified derivatives
Saussurea lappa, Compositae
Cubeb Oil
[*8007-87-21 H002-9CG1
Extractives and their physically modified derivatives
Piper cubeba, Piperaceae
Cumin Oil
[*8014-13-91 H002-9114
Extractives and their physically modified derivatives
Cuminum cyminum, Umbelliferae
Curcuma Oil
[*8024-37-11 H002-9225
Extractives and their physically modified derivatives
Curcuma longa, Zingiberaceae
Cypress Oil
[*8013-80-31 H002-9335
Extractives and their physically modified derivatives.
Cypressus sempervirens, Cupressaceae
Davana Oil
r*8016-03-31 H002-9^51
Artemisia pallens, Compositae
Dill Seed Oil, European
f*8016-00-61
H002-9565
Extractives and their physically modified derivatives
Anethum graveolens, Umbelliferae
Dill Weed Oil
[*8006-75-51 H002-9677
Anethum graveolens, Umbelliferae
Estragon (Tarragon) Oil
[*8016-88-41 . H002-9781
Extractives and their physically modified derivatives
Artemisia dracunculus, Compositae
Fennel Oil, Bitter
[*8006-84-61 HO02-9819
Foericulun vulgare, Umbelliferae
Cardamom Oil
1*8000-66-62 H002-7J12
Extractives and their physically modified derivatives.
Elettaria cardamomum, Zingiberaceae
Carnation Oil
f*8021-43-01 H002-7437
Extractives and their physically modified derivatives.
Dianthus caryophyllus, Caryophyllaceae
Carrot Seed Oil
c*8010-88-11
H002-7543
Daucus corota, Umbelliferae
Cascarilla Oil
r*8007-06-57 HOO2-7659
Croton eluteria, Euphorbiaceae
Cashew Nut Shell Oil
0*8007-24-71 H002-7761
Cassia Oil
f*8007-80-51 H002-7884
(Chinese Cinnamon Oil)
Extractives and their physically modified derivatives.
Cinnamonum cassia, Lauraceae
Catnip Oil
0*8022-84-51 H002-7903
Nepata cataria, Labiatae
Cedarleaf Oil
0*8007-20-31 H002-80'8l
Extractives and their physically modified, derivatives.
Thuja occidentalis, pinaceae
Cedarwood ''Atlas'* Oil 0*8000-27-91 H002-8191 Extractives and their physically modified derivatives.
Cedrus atlantica, Pinaceae
Celery Seed Oil
0*8015-90-51
H002-8219
Extractives and their physically modified derivatives.
Apium graveolens, Umbelliferae
Chamomile Oil, German
0*8002-66-21 H002-8J22
Extractives and their physically modified derivatives.
Matricaria chamomilla, Compositae
Chamomile Oil, Roman
0*8015-92-71
Anthemis nobilis, Compositae
H002-8442
Champaca Oil
0*8006-76-6j H002-8555
.Extractives and their physically modified derivatives.
Michalea champaca or Michalea longifolia, Magnoliaceae
Fennel Oil, Sweet [*8024-24-61 H002-9925 Extractives and their physically modified derivatives.
Fceniculum vulgare, var, dulce, Umbelliferae
Fir Needle Oil, Canadian
[*8021-28-11
H00"-00'62
Extractives and their physically modified derivatives.
Tsuga canadensis, Pinaceae
Fir Needle Oil, Siberian
[*8021-20-2]
HG03-0171
Extractives and their physically modified derivatives.
Abies siberica, Pinaceae
Fir Needle Oil, Silver [*8021-27-01 H003-0283 . _ Extractives and their physically modified derivatives. Abies alba, Pinaceae
' Galangal Oil
[*8024-40-61
H003-0314
Extractives and their physically modified derivatives.
Alpinia cfficinarum, Zingiberaceae
Galbanum Gum
[*9000-24-21
Ferula, Umbelliferae
HOOF-0424-
Galbanum Oil
[*8023-01-41 H003-0535
Extractives and their physically modified derivatives.
Ferula, Umbelliferae
Garlic Oil
[*8000-78-01 H003-0647
Extractives and their physically modified derivatives.
Allium sativum, Liliaceae
Geranium Oil
[*8000-40-21 H003-0755
Extractives and their physically modified derivatives.
Pelargonium graveolens, Geraniaceae
Ginger Oil
C*3007-08-71
H00>0872
Extractives and their physically modified derivatives.
Zingiber officinale, Zingiberaceae
Gi.ngergrass Oil
[*8023-92-51
H003-0989
Extractives and their physically modified derivatives.
Cymoopogon martini, var. sofia, Gramineae
Grapefruit Oil
[*8016-20-41 H003-1075
Extractives and their physically modified derivatives.
Citrus paradisi. Citrus
Guaiacwood Oil f*8016-23-71 H003-1188
Extractives and their physically modified derivatives. Bulnesia sarmienti, Zygophyllaceae
Gum Benzoin
[*9000-05-9J H003-1295
'
Extractives and their physically modified derivatives.
Styrax tonkinensis, Rosaceae
Hay Oil
r*8031-00-31 H003-1315
Extractives and their physically modified derivatives.
Hierochlea alpina
Hop Oil
C*8007-04-31 H003-1438
Extractives and their physically modified derivatives.
Humulus lupulus, Moraceae
Huon Pine Wood Oil
C*8028-76-01 H003-1547
Dacrydium franklinii
Hyssop Oil
[*8006-83-5] H003-1653
Hyssopus officinalis, Labiatae
Iva Oil
[*8026-97-9]
HOO>176l
Achillea moschata, Compositae
Juniperberry Oil
[*8012-91-7]
H003-1832
Extractives and their physically modified derivatives.
Juniperus communis, Cupressaceae
Juniper Wood Oil
[*8002-68-4J
H003-1902
Juniperus communis, Cupressaceae
Kuromc,;i Oil
[*8026-92-41
Lindera sericea
HQ03-2088
Labdanum Oil (Cistus Oil)
[*8016-26-0]
H003-2191
Extractives and their physically modified derivatives.
Cistus ladaniferus, Cistaceae
Laurel Berry Oil
[*8002-41-31
H003-2322
Extractives and their physically modified derivatives.
Laurus no'oilis, Lauraceae
Laurel Leaf Oil
[*8006-78-8] H003-2441
Extractives and their physically modified derivatives.
Laurus nobilis, Lauraceae
Lavandin Oil
[*8022-15-91
H003-2558
Extractives and their physically modified derivatives.
Lavandula hydride - Lavandula officinalis + Lavandula latifolia, Labiatae
Lavender Oil
[*8000-28-01
H003-2661
extractives and their physically modified derivatives Lanandula officinalis, Labiatae
Lawang Oil
1*8022-16-01 H003-2771
Cinnamomum culi.lawan, Lauraceae
Lemongrass Oil
1*8007-02-11
H003-289^
Extractives and their physically modified derivatives
Cymbopogon citratus, Gramineae
Lemon Oil
1*8008-56-81
H003-2916
Extractives and their physically modified derivatives
Citrus limonum. Citrus
Lime Oil
1*8008-26-21
H003-3001
Extractives and their physically modified derivatives
Citrus aurantifolia. Citrus
Mace Oil
1*8007-12-31
H003-3H5
Extractives and their physically modified derivatives
Myristica fragrans, Myristicaceae
Manaarin-Petitgrain Oil
1*8052-30-01 H003-3228
Extractives and their physically modified derivatives
Citrus reticulata. Citrus
Marjoram Oil
1*8015-01-81
H003-3338
Extractives and their physically modified derivatives
Origanum majorana, Labiatae
Marjoram Oil, Wild (Spanish) 1*8016-33-91
H003-3^58
Extractives and their physically modified derivatives
Thymus masticina, Labiatae
-
Mawan Oil
1*8000-46-21 H003-3566
Pelargonium radula, Geraniaceae
Melissa Oil
1*8014-71-91
H003-3677
Melissa officinalis, Labiatae
Milfoil Oil
[*8022-07-91
H003-3785
Achillae millefolium, Compositae
Mustard Oil
[*8007-40-7J
H003-3811
Brassica nigra, Cruciferae
Myrrh, Oleo-Gum-Resin
[*9000-45-71
Commiphora, Burseraceae
H003-3924
Myrrh Oil
[*8016-27-31 H003-4018
'
Extractives and their physically modified derivatives
Commiphora, Burseraceae
Myrtle Oil
[*8008-46-61
H003-412'4
Myrtus communis, Myrtaceae
Neroli Oil
[*8016-28-41 H003-4235
Extractives and their physically modified derivatives
Citrus aurantium. Citrus
Niaouli Oil
C*8014-68-41 H003-4344
Melaleuca viridiflora, Myrtaceae
Nutmeg Oil
[*8008-45-51 H003-4467
Extractives and their physically modified derivatives
Myristica fragrans, Myristicaceae
Olibanum Oil
f*8016-36-21 H0^3-4575
Extractives and their physically modified derivatives
Species boswellia, Burseraceae
Onion Oil
[*8002-72-01 H003-4681
Extractives and their physically modified derivatives
Allium cepa, Liliaceae
Opopanax Gum
1*9000-78-61 H003-4799
Extractives and their physically modified derivatives
Commiphora erythrea, Burseraceae
-
Opopanax Oil
[*8021-36-11
H003-4811
Extractives and their physically modified derivatives
Commiphora erythrea, 3urseraceae
Origanum Oil
[*8007-11-21 H003-4931
Extractives and their physically modified derivatives
Thymus capitatus, Labiatae
Palmarosa Oil
[*8014-19-51
H003-5023
Extractives and their physically modified derivatives.
Cymbopogon martini, Gramineae
Patchouli Oil
[*8014-09-3] H003-5131
Extractives and their physically modified derivatives.
Pogostemon ca'olin (Pogostemon patchouli), Labiatae
Pennyroyal Oil, American
C*8007-44-11
H003-5247
Extractives and their physically modified derivatives.
Helecma pulegioides, Labiatae
Pennyroyal Oil, European
[*8013-99-81
H003-5355
Extractives and their physically modified derivatives.
Mentha pulegium, Labiatae
Peppermint Oil
[*8000-90-41
H003-5474
Extractives and their physically modified derivatives.
Mentha arvensis, Labiatae
Pimenta Berry Oil
L*8006-77-71
H003-5589
Extractives and their physically modified derivatives.
Pimenta officinalis, Myrtaceae
Pimenta Leaf Oil
[*8016-45-31 H003-5697
Extractives and their physically modified derivatives.
Pimenta officinalis, Myrtaceae
Pinus Pumilio Oil
[*8000-26-81 H003-5718
Extractives and their physically modified derivatives.
Pinus pumilio (a.tc.a. Pinus montana or Pinus mugc), Pinaceae
Pinus Sylvestris Oil
[*8023-99-21 H003-5829
Extractives and their physically modified derivatives.
Pinus sylvestris, Pinaceae
Rapeseed Oil
[*8002-13-91
H003-5944
Extractives and their physically modified derivatives.
3rassica napus
Rose Oil
1*8007-01-01
H003-6032
Extractives and their physically modified derivatives.
Rosa centifolia, Rosaceae
Rosemary Oil
f*8000-25-71
H003-6142
Extractives and their physically modified derivatives.
Rosmarinum officinalis, Labiatae
Rue Oil
r*8014-29-71
HOO3-6254
Extractives and their physically modified derivatives.
Ruta graveolens, Rutaceae
Saffron Oil
[*8022-19-31 HOO3-636O
Extractives and their physically modified derivatives.
Crocus sativus, Iridaceae
Sage (Clary) Oil [*8016-63-51 H003-6485
Extractives and their physically modified derivatives. Salvia sclarea, Labiatae
Sage Oil, Dalmatian
[*8018-64-6] H003-6501
Extractives and their physically modified derivatives.
Salvia officinalis, Labiatae
Sage Oil, Spanish
[*8016-65-71
HOO3-6619
Extractives and their physically modified derivatives.
Salvia lavandulaefolia, Labiatae
Sandalwood Oil, East Indian
[*8006-87-9] H003-6727
Extractives and their physically modified derivatives.
Santalum album, Santalaceae
Sassafras Oil
[*8006-80-21
H003~o837
Extractives and their physically modified derivatives.
Sassafras albidum, Lauraceae
Savin Oil
1*8024-00-81
H003-6955
Juniperus sa'oina, Cupressaceae
Siam Wood Oil
[*8022-47-71
Fokiena hodginsii
H003-7041
Snakeroot (Canadian) Oil
r*8016-69-11
Asarum canadense, Aristolochiaceae
H003-7159
Spearmint Oil
[*8008-79-51 H003-7267
Extractives and their physically modified derivatives.
Mentha spicata, Labiatae
Spike Lavender Oil
[*8016-78-21
H003-7379
- Extractives and their physically modified derivatives.
Lavandula latifolia, Labiatae
61
Spikenard Oil f*8022-22-81 . H003-7495
Nardostachys jatamansi
'
Tansy Oil
[*8016-87-31
H003-75H
Tanacetum vulgare, Corapositae
Valerian Oil
[*8008-88-61
H003-7622
Extractives and their physicalljr modified derivatives.
Valerian officinalis, Valerianaceae
Verbena Oil
[*8024-12-21 H003-7733
Extractives and their physically modified derivatives.
Lippia citriodora, Verbenaceae
. Verbena Oil, Spanish
[*8022-79-51
H003-7S44
Extractives and their physically modified derivatives.
Thymus hiemalis, Verbenaceae
Vetiver Oil
[*8016-96-41
HOC3-7969
Extractives and their physically modified derivatives.
Vetiveria zizanoides, Gramineae
Wormseed Oil (American). [*8024-11-11
H003-S051
Extractives and their physically modified derivatives.
Chenopodium ambrosioides, var. anthelminthicum, Compositae
Wormwood Oil
[*8008-93-31
HOO3-8163
extractives and their physically modified derivatives.
Artemisia absinthium, Compositae
Ylang-Ylang Oil
[*8006-81-31 H003-S274
Extractives and their physically modified derivatives.
Cananga odorata, Anonaceae
62
SECTION VIII SELECTED POLYMERS
Adipic acid, phthalic anhydride, trimethylc: olpropane, neopentyl glycol, a-hydro-^-c: hyd roxypoly [oxy [ me thyl (2- phenyle thyl) c: silvlene] ], a-hydro-;x-hydroxypoly[oxyc:
(dimethylsilylene) ]polymer
r66085-51-61
HOOO-826I
Allyl alcohol, linoleic acid, maleated styrene polymer
[*66070-57-31
HOOO-6303
Azelaic acid, isophthalic acid, trimethyla olethane, trimethylolpropane, a-hydro-6u-~ hyd roxypoly [ oxy [ methyl (2- phe nyle thyl) ~ silylene]], a-hydro-w-hydroxypoly[oxyro
(dimethylsilylene) Jpolymer
[66085-54-91
HOOO-8417
Benzoic acid, isophthalic acid, pentaeryc thritol, safflower oil polymer '
[*66071-38-31
HOOO-8527
Benzoic acid, isophthalic acid, trime thylc: olethane, dehydrated castor oil fatty acids, methyl methacrylate polymer
[*66071-51-01 HOOO-8635
Benzoic acid, phthalic anhydride, trimethylo olethane, coconut oil polymer
[*66071-24-71
HOOO-8751
Bisphenol A bis(2-hydroxypropyl)ether, isophthalic acid, tall oil fatty acids, neopentyl glycol, 3-hyd roxy-2,2-dimethyl;: propyl 3-hydroxy-2,2-dimethylpropionate
polymer
[*66071-40-7] HOOO-866
Bisphenol A, dicyclopentadiene, epichlorohyd~
rin, maleic anhydride, soybean oil fatty acids
polymer
[*66071-06-51
KC00-9062
Bisphenol A, epichlorohydrin, butyl glycidyl ether, polymer acrylate
[66085-58-31
Bisphenol A, epichlorohydrin, isophthalic acid polymer
[26284-23-11
HOOO-S973 HOOO-9171
Bisphenol A, epichlorohydrin polymer stearate [59111-89-61
HOOO-9294
64
Bisphenol A, tall oil fatty acid, epichlorohydrin polymer
r*rrn?n ?<; ^7 7 CC070-75-51
H000-931;'
p-t-Butylbenzoic acid, phthalic
anhydride, pentaerythritol, soybean fatty acid polymer
'.
[*66071-26-93
P HOOO-9^8
p-t-Butylbenzoic acid, phthalic anhydride, soybean oil, trimethylolethane polymer
1 66071-^2-51
H000-9535 huuu 95-0
2-(N-3utylcarbamoyl)ethyl acrylate and acrylic acid polymer with maleated bisphenol A epichlorohydrin copolymer
[*66070-56-21
-_ H000-9o4o
Chlorendic acid, glycerin, soybean oil polymer
1-Decene 1-octene polymer
Dehydrated castor oil fatty acid, bisphenol A, epichlorohydrin polymer
Dehydrated castor oil fatty acid, dimer fatty acid, bisphenol A, epichlorohydrin polymer
Dehydrated castor oil fatty acids, maleated soybean oil, pentaerythritol, rosin polymer
Dehydrated castor oil fatty acids, maleic acid, oiticica oil, soybean oil polymer
Dehydrated castor oil fatty acids, maleic anhydride, rosin, dicyclopentadiene polymer
Dehydrated castor oil, rosin, formaldehyde, phenol polymer
Dicyclopentadiene modified linseed oil, fatty acids, dehydrated castor oil, maleic anhydride, safflower oil polymer
65
[*66070-90-4J
H000-9763
[55621-22-01
HOOO-987O
[*66070-77-71
HOOO-9985
[*66070-78-81
H001-0033
[*66071-36-11
H001-0145
[*66071-78-1]
HOOI-O265
[*66071-65-61
H001-037S
[*66071-49-61
H001-C486
[*660 71-75- 83
H001-0591
Dicyclopentadiene, modified tall oil fatty acids, bisphenol A, epichlorohydrin polymer
[*66071-39-41
H001-0617
Dicyclopentadiene, phthalic anhydride, glycerin, pentaerythritol, tall oil fatty acids, linseed oil polymer
.
[*66071-43-01
11001-0733
Dimer fatty acid, aniline, cyclohexylamine, bisphenol A, epichlorohydrin polymer
[*56071-00-81 H001-0842
Dimethyl phthlate, phthalic anhydride, benzoic acid, glycerin, soybean oil fatty acids polymer
[*,6071-52-11
H001-0954
Ethylene oxide, styrene, butadiene polymer
[31292-96-33
HOOl-lO'4"*
Fatty acids, dehydrated castor oil, maleic anhydride, rosin, dicyclopentadiene, gilsonite polymer
[*66071-61-21
1001-115?
Formaldehyde, phenol, triethylenetetramine polymer
[32610-77-81
H001-1277
Hydrogenated (l-aecene 1-octene polymer)
[*66070-54-01
H001-1388
Hydrogenated (styrene-butadiene polymer)
[*66070-58-41
HOOl-1494
2-Eydroxyethyl acrylate, styrene, butyl acrylate, methyl methacrylate polymer
[427r-7-92-01
HOOl-1512
Isophthalic acid, azeleic acid, trimethylc: olpi'opane, trimethylolethane, neopentylc: glycol, a-hydro-uJ-hydroxypoly[oxy[methylo (2-phenylethyl)silylenel ], a-hydro-o>-=: hydroxypoly[oxy(dimethylsilylene) ]pol;nner
[66085-57-71
HOOI-I825
isophthalic acid, glycerin, linseed oil, pentaerythritol polymer
[*66070-36-01 HOOl-1744
Isophthalic acid, glycerin, pentaerythricc
tol, linseed oil, styrene, vinyltoluene
polymer
[*66071-77-01 HOOl-1852
66
Isophthalic acid, glycerin, soybean oil polymer
Isophthalic acid, glycerin, tall oil fatty acid polymer
Isophthalic acid, pentaerythritol, soybean oil polymer
Isophthalic acid, pentaerythritol, tall oil fatty acid, soybean oil polymer
Isophthalic acid, trimellitic anhydride, trimethylolpropane, tall oil fatty acid polymer
Isophthalic acid, trimethylolethane, soybean oil polymer
Isophthalic acid, trimethylolethane, trimethylolpropane, a-hydro-<*-hydroxyo poly[oxy[methyl(2-phenylethyl)silylene]], a- hyd ro-ui - hyd roxypoly [ oxy (dimet hy lxo silylene) ]polymer
Itaconic acid, phthalic anhydride, glycerin, pentaerythritol, safflower oil polymer
Itaconic acid, phthalic anhydride, glycerin, pentaerythritol, safflower oil, styrene polymer
Itaconic acid, phthalic anhydride, trimethylolethane, safflower oil, tung oil polymer
Itaconic acid, phthalic anhydride, trimethylolethane, saffloiver oil, tung oil, styrene polymer
Linseed oil fatty acid, soybean oil fatty acid, bisphencl A, epichloroo hydrin polymer
67
[*66070-91-51 .
1*66071-17-8] [*66071-86-11 [*66070-94-81
[*66071-08-71 [*66070-62-11
[66085-52-81
[*66071-45-21
[*66071-48-51
[*66070-67-51
-
[*66071-54-21
[*66070-79-91
HOOl-1969 H001-2053 H001-2164 HOOl-2286 H001-230'7 H001-2416
H001-2520 HOOl-2633 HOOl-2752 rIOOl-2867 H001-2975 HOCl-3061
Linseed oil, oiticica oil, formaldehyde, phenol polymer
Linseed oil polymer with oxygen
[*66071-41-81 [*66071-03-21
dOO 1-3171 HOOl-3291
Linseed oil, tung oil modified formaldec hyde, phenol polymer
Maleated styrene, allyl alcohol, linoleic acid polymer compound with 2-(dimethylo amino) ethanol
[*66071-31-61
HOOl-3316
[*66070-81-11 ' HOOl-3421
Maleic anhydride, glycerin, pentaerythritol, polyethylene glycol, tall oil fatty acid polymer
Maleic anhydride, soya oil polymer
Maleic anhydride, styrene, allyl alcohol, linseed oil fatty acid polymer
Oiticica oil modified rosin, pentaerythritol
ester polymer
Phenol, formaldehyde, phthalic anhydride, glycerin, linseed oil fatty acids, dehydrated castor oil polymer
Phenol, formaldehyde, phthalic anhydride, glycerin, pentaerythritol, linseed oil, tall oil fatty acids polymer
Phenol, formaldehyde, phthalic anhydride, glycerin, soybean oil, tung oil polymer
1*60071-14-51 [*66071-16-71 [*66071-15-61 [*66071-23-01
[*66071-67-81
[*66071-32-71 [*66071-35-01
H001-353S HOOl-3641 H001-3760 HOOI-3S71
H001-3981
H001-4075 HOOl-4186
_g-Phenylphenol, formaldehyde, phenol, ' gilsonite, tung oil polymer
Phthalic anhydride, benzoic acid, glycerin, linseed oil, soybean oil polymer
[*66071-64-51
HOOl-4219
[*66070-72-2]
HOOl-4323
68
Fhthalic anhydride, benzoic acid, glycerin, pentaerythritol, tall oil fatty acid polymer
Phthalic anhydride, benzoic acid, glycerin, soybean oil fatty acid polymer
Phthalic anhydride, benzoic acid, pentaerythritol, tall oil fatty acid polymer
Phthalic anhydride, benzoic acid, pentaerythritol, tall oil fatty acid, tall oil polymer
Phthalic anhydride, jg-t-butylbenzoic acid, glycerin, pentaerythritol, linseed oil, dehydrated castor oil polymer
Phthalic anhydride, jg-t-butylbenzoic acid, glycerin, pentaerythritol, linseed oil, dehydrated castor oil, styrene polymer
Phthalic anhydride, p-tert-butylbenzoic acid, trimethylolethane, dehydrated castor oil polymer
Phthalic anhydride, p-tert-butylbenzoic acid, trimethylolethane, pentaerythritol, soybean oil fatty acid, castor oil polymer
Phthalic anhydride, fatty acids dehydrated castor oil, pentaerythritol, trimethylc: olethane polymer
Phthalic anhydride, glycerin, bisphenol A bis(2-hydroxypropyl)ether, safflower oil polymer
Phthalic anhydride, glycerin, castor oil polymer
r*66070-85- 71
H001-4436
(*66070-75-31
HOOl-4548
[*66070-84-61
H001-46"7
[*66070-74-41
HOOl-4779
[*66071-70-31
HOOl-4884
[*66071-60-11
H001-49O2
[*66071-44-11
11001-5084
[*66071-42-91
HOOl-5199
[*66071-02-11
HOOl-5216
[*66071-66-71
HOOl-5339
[*66070-88-01
HOOl-5448
69
Phthalic anhydride, glycerin, coconut oil polymer
Phthalic anhydride, glycerin, dehydrated castor oil polymer
Phthalic anhydride, glycerin, linseed oil polymer
[*66070-87-91
HOOl-5556
1*66071-50-91
HOOl-5669
[*66070-59-51
IiOOl-5782
Phthalic anhydride, glycerin, linseed oil, tung oil polymer
[*66071-18-91
H001-5&06
Phthalic anhydride, glycerin, linseed oil, vinyltoluene polymer
[*66071-76-91
HOOl-5919
Phthalic anhydride, glycerin, pentaerythc ritcl, cottonseed oil polymer
[*66070-92-61
HOOl-6096
Phthalic anhydride, glycerin, pentaerythc: ritcl, linseed oil polymer
[*66070-66-41
H001-6112
Phthalic anhydride, glycerin., pentaerythc: ritol, linseed oil and soybean oil polymer
[*66070-65-31
HOOl-6226
Phthalic anhydride, glycerin, pentaerythc ritol, linseed oil, styrene polymer
[*66071-63-41
K001-cj4l
Phthalic anhydride, glycerin, pentaerythc
ritol, safflower oil polymer
'
[*66071-07-61
HOOl-6455
Phthalic anhydride, glycerin, pentaerythc ritol, soybean oil and dehydrated castor oil polymer
[*66071-56-51
HOOl-0562
Phthalic anhydride, glycerin, pentaerythc ritol, soybean oil, dehydrated castor oil, styrene polymer
[*66071-57-61
HOCI-667I
Phthalic anhydride, glycerin, pentaerythc ritol, soybean oil polymer
[*66070-93-71
H001-6792
70
Phthalic anhydride, glycerin, pentaerythc
ritol, soybean oil, tall oil fatty acid
polymer
[*66070-97-1J H001-6812
Phthalic anhydride, glycerin, pentaerythc ritol, tall oil fatty acid polymer .
i. Phthalic anhydride, glycerin, pentaerythc: ritol, tall oil polymer
[*66070-62-01 H001-6922 [*66071-30-5] H001-7012
Phthalic anhydride, glycerin, pentaerythritol,
soybean fatty acid polymer
[*66070-38-2]
HOOl-7129
Phthalic anhydride, glycerin, soybean oil, oiticica oil polymer
[*66070-81-3] HOOl-7233
Phthalic anhydride, glycerin, soybean oil polymer
[*66070-61-91 HOOl-7359
Phthalic anhydride, glycerin, soybean oil, tall oil fatty acid polymer
[*66070-69-7] HOC1-7463
Phthalic anhydride, glycerin, tall oil fatty acid polymer
[*66070-71-11 H001-7579
Phthalic anhydride, glycerin, tall oil fatty acid polymer
Phthalic anhydride, linseed oil, pentaeryc thritol, dipentaerythritol polymer
[*66070-82-41 H001-76S7 [*66070-95-91 HOC1-7712
Phthalic anhydride, pentaerythritol, ethylene glycol, coconut oil polymer
[*66070-89-1] H001-782:'
Phthalic anhydride, pentaerythritol, linseed oil polymer
[*66070-64-21 H001-7935
Phthalic anhydride, pentaerythritol, soybean oil polymer
[*66070-60-81 H001-8021
Phthalic anhydride, pentaerythritol
soybean oil polymer, ester with
hydrcabietyl alcohol
71
[*66071-53-2] H001-c130
Phthalic anhydride, pentaerythritol, soybean oil, trimethylolpropane polymer
[*66071-01-01
Phthalic anhydride, pentaerythritol, trimethylolethane, soybean oil, safflower oil polymer
'
1*66071-00-91
Phthalic anhydride, pentaerythritol, tung oil, tung oil fatty acid, linseed oil fatty acid polymer
[*66071-17-41
Phthalic anhydride, trimethylolethane, cottonseed oil fatty acid polymer
[*66070-39-31
Phthalic anhydride, trimethylolethane, pentaerythritol, dehydrated castor oil, methylmethacrylate, styrene polymer
1*66071-73-61
Phthalic anhydride, trimethylolethane, tall oil fatty acid polymer
[*66070-83-51
Phthalic anhydride, trimethylolpropane, tall oil fatty acid polymer
C*66070-86-81
H001-S24S HOOl-8362 H001-S471 HOOl-6562 HOOl-8696 H001-S711 HOOI-867I
Poly[cxy[methyl(2-phenylethyl)silylene]], a-hydro-*"-hydroxy- , polymer with a-hydro--- i- hydroxypcly [oxy( dimethylsilylene ], phthalic anhydride, pentaerythritol, soybean oil polymer
[*66071-34-91
Rosin, fumaric acid, phthalic anhydride, glycerin, soybean oil, dehydrated castor oil polymer
1*66071-47-41
Rosin, isophthalic acid, pentaerythritol, linseed oil polymer
C*66071-55-41
Rosin, isophthalic acid, trimellitic anhydride, trimethylolpropane, linoleic acid polymer
1*66071-58-7]
H001-B947 H001-9032 HOOl-9143 HOOl-9256
72
Rosin, linseed oil modified gilsonite polymer
Rosin, methyl abietate, modified menhaden oil polymer
[*66071-37-21
HOOl-9377
*66071-27-01
HOOl-9485
Rosin modified phthalic anhydride, glycerin, linseed oil, oiticica oil polymer
1*66071-72-51
H001-9595
Resin modified phthalic anhydride, glycerin, safflower oil polymer
[*66071-68-91
HO01-9614
Rosin modified tung oil, linseed oil, soybean oil, glycerin polymer
[*66071-21-41
H001-9721
Rosin modified tung oil polymer
[*66071-19-01
H001-9848
Rosin, phenol, formaldehyde, phthalic anhydride, glycerin, linseed oil, tung oil polymer
[*66070-68-61
H001-9952
Rosin, phthalic anhydride, fatty acids,
dehydrated castor oil, glycerin, linseed oil polymer
[*66071-28-11
H002-0092
Rosin, phthalic anhydride, glycerin, linseed oil, soya oil, tung oil polymer
[*66070-70-01
H002-0112
Rosin, phthalic anhydride, glycerin,
pentaerythritol, tall oil fatty acids polymer
[*66071-79-21 H002-0226
Soya oil, oiticica oil modified tripentaerc: yt'nritol, dicyclopentadiene polymer
[*66071-25-81 H002-0349
Soybean oil fatty acid, bisphenol A, epichlorohydrin polymer
[*66070-76-61
H002-0453
Soybean oil fatty acid, dimer fatty acid, bisphenol A, epichlorohydrin polymer
73
[*66070-80-2]
H002-0565
Styrene, methylmethacrylate, phthalic anhydride, pentaerythritol, ethylene glycol, safflower oil polymer
1*66071-71-4] H002-0672
Sulfur, isobutylene polymer
[66085-57-2]
H002-0795
Tall oil fatty acid, oiticica oil, rosin, formaldehyde, phenol, styrene, allyl alcohol polymer
1*66071-29-2] H002-0811
Tetraethyl silicate, ethylene glycol polymer
[28742-72-21
H002-09':57
Toluene 2,4-diisocyanate, castor oil polymer
[*66071-12-31 H002-1016
Triethylenetetramine, linoleic acid dimer polymer
[66085-55-01
H002-1128
Trimellitic anhydride, adipic acid, dehydrated castor oil fatty acid,
bisphenol A, epichlorohydrin polymer
[*66071-05-41 H002-12^7
Trimellitic anhydride, adipic acid, dehydrated castor oil fatty acid, bisphenol A, epichlorohydrin polymer,
compound with ammonia
[*66071-50-8] H002-1351
Trimellitic anhydride, azelaic acid, dehydrated castor oil fatty acid, bisphenol A, epichlorohydrin polymer
[*66071-04-21 H002-1465
Trimellitic anhydride, azelaic acid, dehydrated castor oil fatty acid, bisphenol A, epichlorohydrin polymer, compound with 2- (dimethylami.no)ethanol
[*66071-62-31 H002-1577
Tung oil, m-cresol, formaldehyde polymer
[*66071-10-11 H002-1686
Tung oil, dicyclopentadiene, formaldec hyde, phenol polymer
[*66071-7^-71 H002-1715
74
Tung oil, linseed oil, maleic anhydride, phenol, formaldehyde polymer
Tung oil modified formaldehyde, phenol polymer
Tung oil, J3-phenylphenol, formaldehyde, phenol polymer
Tung oil, soybean oil, formaldehyde, phenol, dicyclopentadiene polymer
'-
[*GC07i-zz-QJ
H002-1R23 H002-1933
r*6C07l-69-01 H002-2021
[*66071-46-31 F0C2-2135
75
SECTION IX
CHEMICAL SUBSTANCES MANUFACTURED' AS PART OF MIXTURES
Developed in Conjunction with: The Portland Cement Association
The Glass Packaging Institute Corning Glass Works
Owen-Illinois, Incorporated The Porcelain Enamel Institute
Chemical Substances Manufactured in the
Production of Portland Cement [*65997-15-1]
HOOO-7151
Portland cement is a mixture of chemical substances produced by burning or sintering at high temperatures (greater than 1200C) raw materials which are predominantly calcium carbonate, aluminum oxide, silica, and iron oxide. The chemical substances which are manufactured are confined in a crystalline mass.
This category includes all of the chemical substances specified below when they are intentionally manufactured in the production of Portland cement. The primary members of the category are Ca2Si04 and Ca3Si05. Other compounds listed below may also be included in combination with these primary substances.
C aA 12 O4 CaAI4O7 C aA lx 2 Ox 9
Ca3Alg06 Cax 2A1x 4O33 Ca.0 Ca2Fe205 CaS04
Ca2Al2Si07
Ca4Al6S0xs Cax 2AI1 4CI2O32 Cax 2AI14F2O32 Ca4Al2Feg0i o Ca6Al4Fe20i 5 Ca3TiOs
K2SO4 Na2S04
77
`1*1 V a: - il; iSk/k'J Z Siirlv'if ,,>ii 1
Chemical Substances Manufactured in the
Production of High-Alumina Cement [*65997-16-2]
HOOO-7274
High-Alumina cement is a mixture of chemical substances produced by burning or sintering at high temperature (greater
than 1200C) raw materials which are predominantly calcium carbonate, aluminum oxide, silica, and iron oxide. The chemical substances which are manufactured are confined in a crystalline ma&s.
This category includes all of the chemical substances specified below when they are intentionally manufactured in the production of high-alumina cement. The primary members of
this category are CaAl204, Ca4Al2Fe20i 0> Cai2Al14033, and Ca2Si04. Other compounds listed below may also be included in the combination with these primary substances.
CaAl407
CaAli 20i 9
Ca3Al206 CaO Ca3Si05 Ca2Fe20s CaS04
Ca2Al2SiOr Ca4AleSOi 8
Cai 2A1i 4C12032
Cax 2A1i 4F2032 CasAl4Fe20i5 Ca3Ti05 K2S04
Na2S04
Chemical Substances Manufactured in the
Production of Inorganic Glass [*65997-17-3] HOOO-73S4
This category encompasses the various chemical substances manufactured in the production of inorganic glasses by the glass industry. For purposes of this category, ''glass'1 is defined as: ''An amorphous, inorganic, usually transparent or translucent substance consisting of a mixture of silicates, or sometimes, borates or phosphates, formed by a fusion of silica, or of oxides of boron or phosphorous, with a flux and a stabilizer, into a mass that cools to a rigid condition without crystallization.'' This category consists of the various chemical substances (other than byproducts or impurities)1 which are (l) formed in melting furnaces during the production of various glasses and concurrently incorporated into a glass mixture and (2) reportable for the inventory unless excluded, e.g., under section 710.4(d) of the EPA regulations. These are substances whose presence and form are, insofar as identified herein, known, assumed, or reasonably ascertainable. Any glass contains one or more of these substances, but few, if any, contain all of them. In this category description, chemical substances are generally identified in the conventional nomenclature used by the glass industry2. The elements listed below are principally present as oxides but may also be present as halides or sulfides.
78
>. .i'
in multiple oxidation states, or in more complex compounds. An oxides or other compounds (other than byproducts or im purities) which are not identified herein but which are present in some glasses are neither known nor reasonably ascertainable, and any such substances probably are present only in very small proportions, e.g., less than one percent.
The following elements are principally present as oxides but may also be present as halides (fluorides, chlorides, bromides, or iodides) or sulfides, in multiple oxidation states, or in more complex compounds. Oxides of the first seven elements listed* collectively comprise more than 95 percent, by weight, of the glass produced in the United States.
Aluminum* Boron* Calcium* Magnesium* Potassium* Silicon* Sodium* Antimony
Arsenic Barium Bismuth Cadmium Carbon Cerium Cesium Chromium Cobalt Copper Germanium Gold Holmium Iron
Lanthanum Lead Lithium Manganese
Molybdenum Neodymium ' Nickel Niobium Phosphorus Praseodymium
Rubidium Selenium Silver Strontium Tin Titanium Tungsten Uranium Vanadium Zinc Zirconium
140 C.F.R. 710.4(d) (l)-(2) (42 Federal Register 64577).
2Common references on glass composition and structure include:
(1) G.W. Morey, The Properties of Glass, 2nd edition. Reinhold Publication Corporation (193S).
(2) J.R. Hutchins and R.V. Harrington, ''Glass,1' Encyclopedia of Chemical Technology, 2nd edition, pages 535-604, John Wiley and Sons, Inc. (1968).
(5) F.V. Tooley, the Handbook of Glass Manufacture, Ogden Publication Company (Volume 1, 1974).
79
VJi
4
J-^A*
Chemical Substances Manufacture
In the Production of Frit
[*65997-18-4]
HOOO-7^95
Frit is a mixture of inorganic chemical substances produced by rapidly quenching a molten, complex combination of materials, confining the chemical substances thus manufactured as nonmigratory components of glassy solid flakes or granules.
This category includes all of the chemical substances specified below when they are intentionally manufactured in
the production of frit. The primary members of this category are oxides of some or all of the elements listed below. Fluorides of these elements may also be included in combination with these primary substances.
Ag Ca K
Nb Sn
A1 Cd La Nd Sr
As Ce Li Ni Ti
Au Co Mg P
V
Ba Cr Mn Pb W
Bi Cu Mo Sb Zn
B Fe Na Si Zr
80
SECTION X OTHER CLASS 2 CHEMICAL SUBSTANCES
Developed in Conjunction with the
Leather Tanners Council International Technical
Caramel Association Corn Refiners Association
`.Vi- i
i LV Ll v.vi.j'j.i Vi.'.
- --.5-lj.lv. wfA.
Hair and Hair Pulp [*65997-21-9]
HOOO-7512
A biological material consisting predominantly of partially
hydrolyzed keratin.
Recovered Vegetable Tannins
[*65997-20-8]
HOOO-7626
A complex combination of vegetable tanning materials recovered from the tanning of leather. It consists of natural tannins, which are predominantly polyphenolic compounds, and/or synthetic tannins, such as aromatic sulfonic acid derivatives.
Caramel (Color)
[*8028-89-5]
HOOO-77^3
Substance obtained by controlled heat treatment of food-grade carbohydrates. Food-grade acids, alkalies, and salts may be used
to assist carmelization. Food-grade antifoaming agents may be used in an amount not greater than that required to produce the
intended effect. Consists essentially of colloidal aggregates that are dispersible in water but only partly dispersible in alcohol-water solutions. Depending upon the particular carnelizing agent used, may have a positive or negative colloidal charge in solution.
Corn Gluten Meal [*66071-96-3J
HOOO-7967
The dried residue from corn after the removal of the larger
part of the starch and germ and the separation of the bran in the wet-milling manufacture of corn starch or syrup, or by enzymatic treatment of the endosperm.
Corn Steepwater
[*66071-94-11
HC00-8054
Synonym: Condensed Fermented Corn Extractives Substance obtained by the partial removal of water from the liquid resulting from steeping corn in a water and sulphur dioxide solution which is allowed to ferment by the action of naturally occurring lactic acid-producing microorganisms.
Starch Molasses
[*8052-91-37
HOOO-8163
A by-product of the manufacture of dextrose from starch derived from corn or grain sorghum. The starch is hydrolyzed by the use of enzymes and/or acid.
82
4 .X 4 J
v/
jV'.V-'.r
A
Castor oil, dehydrated
Castor oil fatty acids, diethanolc: amine salt
[*64147-40-61 [*66071-87-2]
Castor oil fatty acids, isopropylc: aminoethanol salt
r*66071-83-81
Castor oil fatty acids, monoethanon: 1amine salt
[*66071-85-01
Castor oil fatty acids, triethanolc: amine salt
[*66071-88-31
Castor oil, hydrogenated, calcium salt
[*66072-09-11
Coconut oil acids, monoethanolamine salt
[*66071-80-51
Cod oil fatty acids, ammonium salt
[*66071-97-41
Cottonseed fatty acids, potassium salt
[*66071-93-01
Cottonseed fatty acids, sodium salt
[*66071-95-21
Lard oil fatty acids, ammonium salt
[*66072-01-31
Lard oil fatty acids, diethanolamine salt
[*66071-99-61
Lard oil fatty acids, monoethanolamine salt [*66071-98-51
Lard oil fatty acids, potassium salt
[*66072-02-41
Lard oil fatty acids, sodium salt
[*66072-03-51
Lard oil fatty acids, triethanolamine salt [*66072-00-21
Naphthenic acids, petroleum, potassium salt [*66072-08-01
Palm cil fatt3r acids, diethanolamine salt
[*66072-05-71
Palm oil fatty acids, monoethanolamine salt [*66072-04-61
Palm oil fatty acids, potassium salt
[*66072-07-91
Palm oil fatty acids, triethanolamine salt [*66072-06-81
Tall oil acids, cyclohexylamine salt
[*66071-89-41
Tall oil acids, monoethanolamine salt
[*66071-90-71
Tall cil acids, triethanolamine salt
[*66071-91-81
H002-2243
H002-2368
H002-2470
H002-25S7
H002-2692 H002-2714 H002-2831 H002- 29*. 9 H002-3032 H002-3143 H002-3252 H002-3371 H002-3485 H002-3590 H002-3615 HC02-3724 H002-3842 H002-3955 11002-^044 H002-4156 H002-4262 H002-4381 H002-4404 H002-4513
83
Tallow acids, hydrogenated, calcium salt
Tallow acids, hydrogenated, lithium salt
Tallow acids, hydrogenated, trietnanol~ amine salt
[*66071-81-61 [*66071-82-71 [*66071-84-91
H002-4621 H002-4731 H002-4856
84
United States Environmental Protection Agency
Washington DC 20460
TS-788
Official Business
Penalty for Private Use $300
Bulk Bate Postage and Pees Paid EPA Permit No. G-35
3EpA78()OOl6A 02 l54l70Q000 DOnG MeRRIL PACO TENTURS
987 COMMERCE ST SAN CARLOS CA 94070
001