Document K6jxr1VbE6zgaxMeZOv1QaKex
Exygen. ` &RESEARCH Proven Riss
..GePT RE
a WEA 29 fi 8: 59
Attachment 2
226-- 1776%,
|
Analytical Report
Air Sampling Fluorochemical Report
|
DuPont Washington Works -- Air Sampling Program Round 4
Exygen Research Report No. L0001359
Testing Laboratory
|
Exygen Research
3058 Research Drive
|
State College, PA 16801
|
Requester
Michael D Aucoin
|
URS Corporation
Barley Mill Plaza
|
LanBcuaisltdeinrg 2i7keRoaondmR1e261401
`Wilmington, DE 19805
|
|
.
ALL DATA CONTAINED IN THIS REPORT WAS GENERATED BY EXYGEN RESEARCH
preter
SohEER, Peon, usa
000144" TacEon,
+ Summary
Seven solid media samples were received by Centre Analytical Laboratories, Inc. (dba Exygen
'
Research) (Exygen) from DuPont
OVS tubes. Please sec Table 1 for
Corporation.
a completed
The media represent samples of air
listing of samples received and field
collected on
air volumes
| collected.
| The samples were analyzed for Perfluorooctanoic Acid (C8 Acid) using liquid chromatography
' / mass spectrometry (LCMS). The method employed is entitled "Method of Analysis for the
|
Determination
Exygen Resear
of
ch,
Perfluoro
February
octanoic A
17, 2003)
ci
d
(PFOA)
in
OVS
Airtubes
by
LCMS"
(James
Miller,
|
The OVS
Fraction A
tubes were separated
consisted of the filter,
into three fractions
backing material and
for specific
plastic ring.
fluorochemical analysis.
Fraction B contained the
[first bed of XAD resin and the PUF backing. FractionC contained the second bed of XAD
| resin and PUF backing. Fractions A and B were extracted with 1 mL of methanol. Fraction C
. was not analyzed but saved for possible future analysis. Perfluorodecanoic Acid (C10 Acid)
|
was
was
naodtdeadnaalsyzaedsuarsropgearteclsipenitkeretqoueesatc.h
fraction
prior
to
extraction.
Sample
WWK-A-AMS6-E4
|
instrument instrument
operating conditions can be data is given in Appendix
found at the beginning of each analytical run. Raw A. Chain-of-custody information can be found in
| Appendix B.
ALL DATA CONTAINEIND THIS REPORT WAS GENERATED BY EXYGEN RESEARCH
|
Fussell
000145
| Results Summary
|!
SAarmVpolleudme1
CmogAmd)a
|
AWWKAAA-mASMtS1-E444A08
t114i43s%2
S<00.N0A000007
|
WAS4 Tot)
1
00007
-- WARIS 8
i1a45588
<00000000207
|
OKAAMS2E4C
S28 To)
T CC 1458 ow NA
wKaAAmNsSsIEiNAS WANS
11446688 1468
<00.000000207 NA
|
WAS)4 To)
oe
-
WAAMISSLEEEL4eS4
=T14a2t1
<Z0o.0A000000077
CARSALES Ta) Tow
|
WWKKAAAMAMSISSES44CA
1141a4335s
<Z0G.o0No0A000077
|
AASE24To) ----
<G0001%
NA- Not Analyzed. Fraction 8 was bow the quantation i, therefor backup action doas ot require analysis,
| 1. "<"is defined as not detected at or above the reported level.
|
2. Sample results have not been corrected for blank results or control spike recoveries.
| EE 3. Please note the following descriptions of the OVS sample tube fractions:
B
c8A
J|[FeHrniotaEsxottr-- abcotas oxtact (ot analyzos)
ALLDATA CONTAINEIDN THIS REPORT WAS GENERATED BY EXYGEN RESEARCH
Pugs 3017
|
000146
|
|
3
Zz
ii
| igz 53
rkif Ze gi
ior ii sf 2:g
=Be| s
| i: T
EH
?
PHigN
:
|
B i f
23
Ean
23
gig|
i
||
55% 3
gieg CS
:z
i
i
|
|
;
3
|
||
000147
f
I Surrogates
I ASursruorgraotgeatsepsipkiekreec(oCv1e0riAecsidar)ewgaisveandidnedthteofaollllOoVwiSngttuabbelse.toTghievreeaarfienanlocsoentccernittrearitaiofnorofsu5r0ro0gpatpeb sipnitkhee extract.
recoveries. Advisory ranges are 75-125%.
[[ [s Sm er Tamenmsees ibi
| wwaAmsroikess
500
a3
|
[| |
Sesne WWK-A-AMST-E4 A
2E540S0
9=46
mess ow = | leisaans E%S
ybo
[em | a I pSibnaa |
WWK-A-AMS4-E4 B.
22E50S0
Zaaonn
I * Surrogate recovery outside of advisory range.
re22
89
bo=1o58w9"
22
9=-2o4r
ALLDATA CONTAINED INTHIS REFORT WAS GENERATED BY EXYCENRESEARCH | i reset 000148
r ;1
|
.
I
|
|
=
vvovouvvvy
i] [c 55o 5o 58c c5o8o5o 5c5e5854gl
||
5238 lToRsIoToErToAzTcIoIIoNoIoEge
.
_
|
2
] pi
Cog fn
|
o
|
=
g
g:
z:
2
000149
[7 Example Calculation
r For sample WWK-A-AMS2-E4 A C8 Acid,
:
=
[311ng/mlof C8 Acidx(I mix) (1 ug/ 1000 ng) x (1 mg/1000ug) ] 10001)
/
(1458L)x (1 m3
/
!
= 00002mg /m3
Signatures
I
2 CAN,
Paul Cooly, LGM Team Leader
-
m fi
|
fohn M. Flaherty, Vice/President
[ Orta amber ContrtnoDnagta
r
James Miller
22s)oy Date
Sh
Date
r
ALL DATA CONTAINED IN THIS REPORT WAS GENERATED BY EXYGEN RESEARCH
-
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ANALYTICAL DATA REVIEW SHEET
r r r
I
LC/MS
Tower & Miller
RRL
|
Analyst
#nature/Date
Tho; Fledeety
AU mA th
I
Reviewed by
ignature/Date
r
r
r
:
:
r
|
uo.
000153
[ Sequence: C:\HPCHEM\1\SEQUENCE\120903.S
|
Sequence Table:
[ Line Location Samplovans "Method Inj SampleType Injvolume DataFile
9 Vial 92 Solvent blank FC8-10 1 Sample
|
13 vial 11 L0001359-2
FC8-10 1 Sample
|
17 vial 18 L0001359-8 FC-10 1 Sample
| Hon SRevmR. ma 1 She
1|
3332 Vviialal56 SSTTD 7150000ppppbb FFCCBB--1100 11 CCaalliibb
[ote ten was cite mate et es
28 Vial 1 STD 50ppb
FC8-10 1 Average Average -2
||
3310 vviiaal4l3 SSTTDD 250500 ppppbb FFCC88--1100 3i AAvveerraaggee AAvveerraaggee --22
32 vial 5 STO 750 ppb FC8-10 5 Average Average -2
|
34 Vial 7 STD 1500 ppb EC8-10 7 Average Average -2
[ess 12303 siossu isuisns1on 1%) UOT.1 000158 yo,
r Method C:\HPCHEN\1\HETHODS\120903
!
Calibration Table
~ Calib. Data Modified : Friday, Janvary 09, 2004 2:13:25 PM
Based on
: Peak Area
[eArbs. Rneofeerreennccee Wwiinnddooww :: [AbResl. NNoonn--rreetf.. WWiinnddooww :
Uncalibrated peaks i ! CPoarrrteicatl CALaLlibRerta.tioTnines::
05..000000 m&in 3511000000 n8in not reported YNoe,s, onildyentfiorfieiddepnetaikfsieadrepearkescalibrated
[corm me I orweiiggihnt
ii
[ AsveecraatgsevraRteisopnonsseettings:i
. Average Retention Time
IEqgunaolred AFvleoraatgiengalAlvercaagleibrNaetwio7n5s%
|" ctinrasion nepere opeiens -
Print`CoaultiborfatrieoncaTlaibblreataifotnesrwiRtehcianliabrasteqiuoennce:
|
If tNhoermsaelquReenpcoertisafdotneer Rweictahlibbrarcakteitoinng:
Results of first cycle (ending previous bracket)
I" Ssiiggnnaalr 12:: wNSoDtL 346699,, sEiIcC--a366s8..77::346699..77
RentiTni]meSig"Lvl Apmpobu]nt Area Ant/Area Ref Grp Name
m7e03e63 e1o1er50.0n00n0 s 1.01066e e4 4.9n 47283fs n1noCe eB Acid s
-
23 21500010000000000 14..989243541dee44 55..011833707200--33
35 57050010000000000 51.02984826250e45 55..54290703909-33
57 11050000110000000000 21.15285485726655 5..361410076900--33
8.336 2 21 105001.000000000 21.14704380438e4s 33..56633873276a--33 1 C10 Surrogate
|
353 57205500011.00000000000000 161..276692347701479ee53d 334...791757288428138e6a---333
\| -
&7 1105000010000000000 23.21028615006655 44..5729877790a6--33
More conpound-spefciic settings:
|" com"TpionuendW:indcoowacia
+ From 7.291 min To 8.292 min
Com"TpioruendW:inCd1o0w Surrogate + From 8.140 nin To 8.945 min
|
TTT
ea sam abe
| e "+eo m Entriee s in tr ables
| CO0414 1/9/04 2:21:08 PM miller
evsnnaemenennesene
uo12
000155
rage 1 of 2
Hothod C:\HPCHEH\1\MBTHODS\1209043
TT
~ Wea]
- 1200000
| Reus:
| - 100000
|| sooo Le :
| of rmmer J
[ - 2| l00o00d0-
. 4
Le | sooo :
Calibration Curves
gs | CS8onAiciSdeoa,teBxrpe.eRsT:170.6496.37
7 | cRFoersoriedluraatliymoSnec:da.mlDaev:.b: 670C 80..3969169938
5
mBL s1x4s8e.m68a5n4e6
x: Amount [ppb]
oo a Coc-riroelsuartrioosna:te ac ew. m5m)9366.73536 RFeosrimduaa:l Sm ed. h pev.: 9660.28033 5m33: amasohu2an0dt6.ai3oi6wi7)97
3
| conan 1/5/04 2:21:08 ox gmiticr
0013 000156
[
LC/MS SYSTEM AND OPERATING CONDITIONS
-
|
Client: Dupont
EXYGEN STUDY: _ L0001359
|
Instrument: Hewlett-Packard 1100 LC/MSD (LC/MS 3)
APL-ES Interface - Negative SIM mode
|
Nitrogen: 10 L/min at 300C
Fragmentor: Variable; Vcap: 3500V
|
Computer:
Hewlett-Packard Kayak workstation
[
Software:
Microsoft Windows NT 4.0
Agilent ChemStation Version A.08.03
|-
HPLC Equipment: HP G1379A Solvent Degasser
HP G1311A Quaternary Pump
HP G1313A Autosampler
|
HP G1316A Column Thermostat
HP G1946A MSD
|
HPLC Column: Thermo Hypersil-Keystone Betasil C18, 30 x 2.0 mm x 3um
Column Temp.: 35C
|
Mobile Phase (A): 2mM Ammonium acetate in OmniSolv Water
Mobile Phase (B): HPLC grade Methanol
Time
HA
%B
0.0
70
30
[
6.0
10
90
10.0
10
9%
|
10.0
STOP STOP
Post Time = 4 min.
Total run time = 14 min.
Flow Rate:
0.3 mL/min
Injected Volume: 5 pL.
|
Page 10f2 0014
l
000157
lons monitored: [
|
Analyte C8 Acid (PFOA)
C10 Surrogate
lon (m/z) 369
469
Extraction Date: December 3, 2003
Analyst:
[
James R. ler fo Hr
Exygen Resear 3058 Research Drive, State College, PA 16801
Phone: (814) 272-1039, FAX: (814) 231-1580
[|
|
Page 2012
o00i7s5 000158
TIunestrDuecmen0t2 0: 9:L1C7N:S346 2003
|-
Mw6/z31413701Bw510.00.259
:
G1946: API_ES Negative mode
Page 1 of 3
CE \HECHEM\1\194 6TUNE\ATUNES . TON
aw/z 2620810.756pw0.00.362
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214m/5z61222353.P9u5 ma0x.73
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or
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|
|
1630 1635
2230 2235
- am {4 [2S5c5a0n1t p5e0a.k0s6 =Ba3s0e0:0.020233S.a3m5plesA:bundaTnhcrea:sh:131043S0t4ep: FR0.a1w0,Gauss 0.3
| 100
ow
|
"|
Tw aa
i
40+
|2
[oe 500
1000
1500
2000
2500
|
| |1
w1/1z3.g8f A`bsulnoodo Re1l00A.b0u0nd Ts1o14m./0z2 Iso A1b3u8n2d Iso R3a.t2i5o 10031319997 21206564s4 34353..8511 160032419988 ad4l2z801 2103..9726 21263333119935 1361o4s3s0s4z 12214504..2650 21263344..9955 263326186906 3465..9632
0076
000159
TIunestrDuemcen0t2 0 9:L1C7H:S346 2003
61946: API_ES Negative rode
Page 2 of 3
G:\HECHEN\1\1946TUNE\RTU.NTEOSN
|
Modes API-ES Polarity: NEG
"lo
|
Fragment Skfoinnszi
V6A.0R WWiiddtthhGOafifns ~V12A8R -410 MassGain-36.25
||
Lfonne
26105 MSansesrogfyts
VAR 5.0
OSppoollttnaeask 330106
..
|
Gain 3.0 Quadde 0.00
Vuovap 24106060 ASSvatemerppalsgeieszse 0.1081
',{
.:
StGaiptcuusr: 63 DeyingGas 6.0
|-
GChuaemdCuTrerp 1.0329 Gaabs Tberemsp 30200
| Fragnentor
Dynamic Parameter Ramp
| 200]
|
| | 150
100
| so
|
-
a ld
|
|
||
500 1000
1500 2000 2500
3000
1M0a0s.s00 Se6t0t.i0n0g 30M0a0s.s00 S2e5t0t.i0n0g Mass Setting
|
{
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600160
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4015S
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~
s00 1000 1500 2000 2500 2000
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wh 112.99 HEE -106.00 A 601.98 dd ~106.00 1033.99 -106.00
[ ass offset
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| -2.00
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s00
1000 1500 2000 2500
3000
~. i
wMPars3so cSvE Setting SMraWosEsrMR voru Setting JMasEsMR Setting
i|
|
vB:a
000161
~ Sample Name:STD 50 ppb
| sSaatmapleFilIenfoC:oW\auHrmpPCHENL\DA1E150A27\57GATh32e35m2\sRCE00o00r02\.D 1 | fInojjeectsitoinDotantaee:: 122/9/003 5:09:4PM7 Smeq eLine : 1:
I SnatEioen s |sEowrn ewemeonaginx
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"MSD1460,EIC=480.7:460.7 (CHEM
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|
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000162
Sample Same:57D 30 pb
|| SpaomepleFilIenfo:SC WRC VSATAAREOO00IE.D
1
[[IIanBecmEriioeneere n2l0h3g0e3 em a mCmiel
su3::
[V BEpEoSne MAmeomiLa ns L: reTwetotm soo1g20o9s0s3.s
LerHS amatysts of perfluorsoctanote acid
| wn "MSD 369,EIC=368.7:360.7(FOO00002.0) API-ES, Neg, SIM, cs Frag: Var
-
|
1400
|
0
|
[1]
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| oo
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=
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020 wserori 000163
sample tane:sTD 100 300
| bSaatmapleilIenf Co: r \RPCREI\S\BRTAF0000G3.D
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3: |
|[I pEeg. EworLseee}+ eivaan wensto z0ges t
Les anaiyeis of periuorosctancic acid.
| iN ER
anc
[| mo (| =
on]
[]
[|=
- : TT |
"WSD1 469,EIC=458.7:469.7(FCO00003.0) API-ES, Nog, SIM, Frag: Var
on crosons nd
rrogat
| || om3500:
| | m0
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|
1500
{||
|
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[|| =. |mLtom,
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80.24
7.451
21270
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} sessessssssssssssssssssssssssssssssssssssEsEEESERREERSREERSSEERERSREEREEE
. . TR ree 0021 -- cei. 5 sen 0s 03.530o0m oe iott
000164
_ Sample Names 250 ppb
| Sample Info:
1
Data File iC:\HECHEM\I\DRTA\FCO00004.D
~"IdHTnrijetteoacpritoeiomroneannttDoart|e :i| 1di2emoi/ot5aate/sr03 5:56:25PM vSn ieiqeeh Lnineel:
su:5i
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[7 Ed
02033233 om
2/45 analysis of perfluorooctancic acid.
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~
~
[=r
*** End of Report **+
or
Pri, 9. dan. 2008 03:33:53 pm
utoagze 210c1
00016:5
+ Sample amo: 500 ooh
4 Data file :C:\HPCHEM\1\DATA\FC000005.D
A I[njrecetioln Dat:eR12/S9/03 6:11:59 2 S[merqiLhine
i5i
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ii| sonoase
CT endoT f Report +r
Pei, 5. am 2004 03:26031pm
TTT 0023
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000166
[saanpmieitag-- e 750 ss : | EInijgecitimoonnDeate sin : 12/9/03 6:27:34 BM fnSeqLine 1 Ts:
| pogosmims + onion
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|[| | vo 7as2.C8
[|| end
|
[I|.=
|
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7
T
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|
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[ol -
|
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[|=
|
|=
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0024
|
000167
sate samo 000 7
| sample Info:
I
| Injection Date : 12/9/03
| sco most + season
6:B4M3:Se0qLi9ne :
1
7
I
B
-|
i-.
|] |eo
[| -
MSD1369, E1C=368.7:360.
7D) APES, Neg, SIM, anjar
| -7500
|
[
2500-
[[||:| wow\ -- : ; RnFi-- | |
"MSD 460,EIC=468.7:469.7 (FC000007.0) API-ES, Nog, SIM,Frag:Var
[| | w150l0 |-
r | o-
:
: on : s:as =
r
o
+++ End of Report +++
TTT
u025
|
000168
Sample tase: 1500 or
[ DSaatmpalefilIenfo:-Cr\HPCHEN1\DATA\FCO00R08.D
Ce Te es me
|[hRacq eoEperaatorr e: jnmildler
vWFiaorl No.
[sAcaE,eweE tehod oa +| FEontoo. ODS1B 20902E 0
Lo anatysis of pecfiuorooctanoic acid.
1
TT su!7
[
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72697(F
BD) APES, Neg, SIM, Frag: Var
rr z : race | | woo
|
[ || wo15000
[1] | I . a
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;
PR--
{ wMoSD 40, EIC=468 74637 (FOO00006.0) 0. otras PIES, Neg.SIM,Frag: Var.
| ao
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pata Eile
C:\HECHEU\1\DNTA\Chesstor\11534330\KT30368\FC00010.D
1
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|
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| * ssawmmpilee Nmaome::L0001359-20
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| TAncjaecOtpieornatDoarte |:: m12i/l9l/e0r3 Instrument 1 zco0ats
7:45:13 PU
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1
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a | ALnaasltysCihsanMgeetdhod:: C1:/\3H/0P4CHEM\L\METHODS\10220:91033:.2X5 pn Le/us analysis of perfluorooctanoic acid.
| (SDT360,E17348876CHE8NISTORTSSASASATOGZpSo0Fn]GdOAP0E0S,0NToTSW, Fi: Var
10
1000
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|
[| =
|
SOTE 463 C4E 6814T 637 CHE{NSSSTOHRSYI:SATa00Z5FCO0e00CT01) APES,No, SW, Fg: Var
a0
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[| =
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|
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|= [| od
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| 2000]
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Compound
z Amount (ng/ml)
| R0"aScuirdrogac d2.i5z4er
I R.T. 78..435212
Area 597510765
i
5
pe
signal
NMSDDIL 346699,, EEIICCA4366881.77::436639..77
\
| ecoos1a
"End of Report tr
Fri, 9. Jan. 2004 02:24:06 pm
TT
0029
Page 1 of 1
600172
gone Yap | ee e51e oA Sample Info: TECHE ABA hemor ISGTAATASELGNFC000012.0 1 [ - IisnfS ehcmtoiona epese":1if0 lin en awpHmeroeel edB8: |[nReqE,GseEseh t Erco-SsomR rons snzonnts
ors snatyeta of perlsoroactancte acid.
|
"MSD1369, EIC=368.7:(3C6HE9M.S7TORVI1: TATA61
120) APES, Nog, SIM, Frag:Var
-
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[I | J-
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|
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|= [: -
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Pri, 9. Jan. 2004 02:24:43 pm
we ED)
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600173
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L/S analysts of perfiuorosctanoic acid.
i" I
"MSD 369,EIC=368.7:360.7 (CHEMSTOR 1534A6T447077:
130) API-ES,Neg, SIM, Frag:Var
- |
200
|
20
|=
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Pri, 9. Jan. 2004 02:25:08 pm
we 0031
Page 1 of 1
000174
| sSaemmpilse Nmaenee::L0001359-4
1
Data file :C:\HECHEN\1\D11A53T49A98\\CA7h49a37m6\sFC0t00o01r4.\D
| AITcnnqjgetcortupimeoennrtaDattoer:: Pm1C2iO/l09l4/eL0rA3 Dilution iT
8:32:00 PM
VSIinegaq.lLiNNoon..e Ina vel.
sIunils3
[~ =ma=lysCihsaMnegtheodd:i G1:/9\/H0C8HEM\1\METHODS\102301930133.51 pm
10/5 analysis of perfluorooctanoic acid.
|
SOT SE E96 6 TCHENSTORT S338 7aTRFCO0T0aT0E)caAnPcVEeS, og SWFray Vr
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Area 490
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|
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Fri, 9. Jan. 2004
02:25:49 pm
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Page 1 of 1
900175
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| Sample Info:
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|
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TRRnjieTcotrvieAornacrD"ate
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SiEna of Report see
Fri, 9. Jan. 2004
02:27:30 pm
TTT
W004
Page 1 of 1
000177
= ~| sDaamtpalefiNlaeme::LC0:0\0H1E3C5H9E-M8\1\DATA\Chemstor\11535463\A756736\FC000017..D 1
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i+ renciom
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In. Vel.
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03:13:35 pm
Lo/S analysis of perfluorooctanoic acid.
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HEGT 758 CESTORTEA
OT APES To, SHE Far
2
= | 0
778:ca.
[ i 20
20
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| SBoohcSiuaroga: 03.507050
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| [Epp ------ eesssssssssmsssssssssssssssssssessssssssssssssssassssssssss=sssssssmass
I
| ecooara
Eri, 9. Jan. 2004 02:28:05 pm
w053
page 101 000178
|"Sasmepeldes Nsaimke::L0001359-10
1
|. bata file Ci\HICHEM\I\DTA\Cherstor\1153562\A760064\FC000018:D
|
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[oe
|
|
| | 15000
[|=
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37343718 s7e705311s wuedoi 346d9,, BiiCc-e43s6e8..77::436695..77
| |; escocnomesssunsnmrasnesan[seEnnyenrneeses-- ssses-- sensesansensesassssesnssnsontons
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Pri, 9. Jan. 2004 02:28:46 pm
u036
Page 1 of 1
600179
|~ Ssaammppllee NIanfmoe::L0001359-11 i Data file :C:\HECHEN\1\DATA\Chemstor\11535737\AT64288\FC000019.D.
| ATcnajeOcptieornatoDrate :+ 1m2i/l9l/e0r3 IDnislturtuimoennt i rPCOALA
9:5P0M:02SVIeinqja.lLiNNnoo.ie : nl vel. :
1 12901 sw
_ LAnaaslysCihsanMgeetdhod ; C1:/9\/H0E4CHEM\L\METHODS0\2L:21039:03453 pm Le/S analysis of perfluoracctancic acid. TOT 59, EC TR CHENSTORTTESTSTATes TOO)
APES, og, SW. Fag Var
=
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|
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1
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|{810AcSiudrrogac 04.7030.73
78.342549 810230708 MNSSDD1L 346699, EEIICC-=436688..77::436699..77
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Fri, 9. Jan. 2004 02:29:23 pm
yua7Pp Page 1 of 1
000180
sanple Hane: 500 ppb
| Sample Info:
1
R | Ilaemeere mlae Lniner SFp nt e9 _ Data file :C:\HPCHEM\1\DATA\Chemstor\11535837\A767232\FC000020.D
[am
Hk
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[nEey, RmethEohdot E| BC1R 0 METHODS 1R 2090m 31
LMS anatyats of pertluorooctancis acid.
|
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1
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|
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| In "WSTO 4I69,EE IC=4O 68.7:E 469.7C(CHE EMSN TORT153O 5837STC1B) S APN NegE , SS IMS ,FrF ag, :Va" r
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|
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| nae hep rrmsesc sme eas rsu eas as aaas raas raaas asaas seSe EEn SAs AREEs EARe RRE
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0001851
" Sample Name:Solvent blank ,
| Sample Info:
1
| InjectionDate : 12/9/03 10:21:06 BM SeqLine :
21
| REEE ESR mons i2090 eJ
| [cam o
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|[|2=-0. ||=.
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|
|
MSDY 469, EIC=468.7:469.7 (CHEMSTOR\I 153807TAT70844\FC000021.0) APF-ES,Neg, SIM, Frag: Var
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l ==sszsssssssssssssssssssssssssssssssssssssssssssssssssssssssssssssssssssss
-
*** End of Report ***
k
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Fri, 9. Jan. 2004 02:30:40 pm
Page 1 of 1
000182
J
} 1
| eSamspleilIenfo: Co\HPCHEL\BATACahemssetor1360SB\ATTAL46\FC000022.D [mIteneese a 3S ws imei
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[[ Dniseclxeu,tE ioosenhoda t 1+ E1ECBS-10E. wemonsuazRasoss. n Inj. Vol. : 5 ul
Larxs analysts of pertlsarooctancic acid.
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7369.7 (CHEM:
11536058147741441
220) API-ES,Neg, SIM,Frag:Var
|]
| wd
|
(l== 1
"| m=
|
|
[\!|
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| ed
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| 10000
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= coment rooms wo2rm) Re "8 Acid 5% 0.00
E._ 4 heen TA 7.483 Eh 330
|
|
8
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---- Sots Go an. 000 (DAES I 0 0P13AN 660183
~ sample Nanes0001359-14
1
|
Sample Info:
pata file SC:
\HRCHRN\L\DATA\Chemator\
L1S36160\ATT6T04\FC000023
0
[| e ea l oe raroe r | aTJmipdHirer wen Bettis J
amLeihee move
5i su
[| sTo, RtoctLhoaoa +| CsAoCHnE METHODS\1$250093003.55 om
R Le/MS analys[ is of pea rfluorooctanoic aciS d. ESRSH
|=
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0.000
8.327
Axes
1010047
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MSD1
MSD1
369,
469,
EEIICC==436688..77::436699..77
U - na of nepert oor oisssssssssssssssz=csssssssssssssssssssss=sssssssssssssssssssssssssssEsss
|. seooare
Eri, 9. gan. 2000 02:31:40 pm
0041 Page 1 of 1
000184
| spJ aetmeieFilmeee:<--C\HPCHEIA\BATA\Chanstor\LLS36S61\ATISSOR\F.CHOD0RA.D .
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fmTaErEe
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lI - w= rire |
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0) APES,Neg, SIM. Var
[| =
|
|
200.
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RISO460, EIC=468 1:460.7 (CHEMSTORY!1538541AT79904FGOD00240) APES,Nog,SIM,Frag: Var
[| om
[| oo
|
; | =wd | 100007 ol
| cormmt soos cazm) BTohreer aSo4004
AT. 4 he SE amE e
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[RP smp n --
. }.
sata file <Co\HPCHBINI\DNTA\Chemstor\LLS3GBOL\NTBEE9R\ZCE00025
| Injection Dave 1 12/9/05 11:23:m2i4 Seq Line :
"25
[ame ol
mo
sud
RT ESvemoosuazosna [ LLa/sthChaannagbeydst of: p1e/r9f/l04uszoossanots aci0d2:13:25 pm
|
SOT369,
7369.7 (CHEMSTORI163680 TAT
5) APFES, Neg, SIM,Frag: Var
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[| =
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7.400:Co.
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! rounees
IR eer TT
fri. 5. oom. 2004 0239:33om
u043
sage 10cn
000186
[~ sSammpile Name:s> 500 75
:
Data file iC: \HPCHBN\I\DATA\Chemstor\LLS36590\RTBSATZAFC00026..D
[7 STneseecmntieoenrwa:|| midajivotorseotsrs [ES i
ites me
wSeaaltiNneee hv
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eneiqy, tHeathoWaathod +| CB;c\oP-C1H0EmM\1\METHODS\1209031.
|
Last Changed : 1/9/04
02:13:25 pm
Leu analysis of perfluorooctanoic acid.
| wo SOT 365,EIG-368 7363.7 (CHENSTORIT RSITAFCOG0r0oZa5r0]08APFES,Nog,SM,Frag: Var
| oo
|
re | 8000
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[lo
rom | | 0 i 4G5 HENSTST OTRS EFCOT N 0) TENoS, SH Fa ar
| ow
8342: G10
|
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|
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[7]- wd 8000
1||
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|
.
I Compound
2
amount ng/ml
RT. i
5
Area
8
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78 Acia
529.14
| 110 surrogat 530.73
7.481 8.342
88015 122470
MSD1 369, EIC=368.7:369.7 MSD1 469, EIC=468.7:469.7
I=
r
PCo0414
Ina of Reportae
Fri, 9. Jan. 2004 02:34:00 pm
0044
Page 1 of 1
0600187
[oSameple ane:Solvent blank
:
Data file iC:\HPCHEN\I\DNTA\Chomstor\ 11537038\ATT648\RC000027..D
| RfIogonorpjecreaeDtoarct|et:i1j2m/oi9l/tn0e3r 11:54:26 BM vSIeinqag LNienle i
=27:
[--sDoirlutmioocnros i+ res0.0
vel: su
~ ALnaasitysCihsangMeedthod 1| C1:/3\/H0P4GAEN\I\NETHODSA102200920531.3351 pm
I coms anniss of serervorncrante acid.
r 55, EGET CRENSTOR TOSSATET iSO OATES,SH Fa a
=
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Pris. gan. 2006 02:36:43 pm
045
Page 1 of 1
000188
|"~ sSaammpmliee NTanmee:sT 50 ppb
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Aicq. sMetheodtnod +| CFCABR-P1C0H.E0N1\WETHODS\120903 4
| Last Changed : 1/9/04
02:13:25 pm
Lous analysis of perfluorooctancic acid.
i - SDE EG 7569 (FRR OT APES. eg SF7sVr cased
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Fri, 9. Jan. 2004
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89 6001!
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.
' Data file :C:\HPCHEM\1\DATA\FC000029.D
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Fri, 9. Jan. 2004 03:17:55 pm
0047 Page 1 of 1
000190
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Le/ms analysis of perfluorooctancic acid.
I
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rei.5. gan 2008 03:19:0pm8
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600193
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Data file :C:\HICHEN\I\DATA\FCO0D034.D
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