Document K6d92m4m0Q2maxNZDeBX14nLK

/ tf*--- ~ |ufJ!P.DYAL Ir 1' _____ dJ Trade Name: Uses: Chemical Name: CATE: November 10. 1971 UNIROYAL CHEMICAL Division of UNIROYAL, Inc. Elm Street Naugatuck, Connecticut 06770 203-faeeeee -113-3000 PRODUCT SAFETY DATA SHEET <g> FLEXZONE 6H An tio2 onan t/An tioxidan t N-pheny1-N1-cyclohexyl-p-phenylenediamine Chemical and Physical Properties Appearance: Purple powder Melting Point: 100C (min.) Solubility: Specific Gravity: Soluble in acetone. and hydrocarbons. 1.18 Slightly soluble in water Corrosivity: Volatility: Not corrosive Not volatile Fire and Explosion Hazard Flash Point: Autoignition Temperature: Above normal processing temperatures. Special Decomposition/Reactivity Precautions: None Fire Fighting Media and Procedures: Water spray, foam, C02 00 086P1p 00 nftofnttai PRODUCT SAFETY DATA SHEET (Cont.) FLEX2QNE 6H Health Related Data Specific Hazard: Some skin irritation potential. 2 Handling Precautions: Avoid breathing dust or vapors. Avoid skin and eye contact. Wash thoroughly after use. First Aid Procedures: If eye contact occurs, flush with plenty of water and see physician. Toxicology Background: Oral LD50 (rats) : over 2 gms./kg. Human patch testing and experience have not indi cated the material to cause irritation or sensiti zation. However, as with any phenylenediamine derivative, care should be used in handling. People sensitized to other p-phenylenediamines may encounter dermatitis problems. Storaoe and Waste Disposal Storage: Store in cool, dry place. Cleanup: Avoid creating excessive dust. Disposal: In accordance with local regulations regarding disposal of organic chemical wastes. DO 086?13 OONFIDFNTTAl Data Supplied By: R. J. DOWLING FLEXON 845 E^ON COMPANY USA A OWtSlOH O' EXXON CO*OfUT)Oft DATE ISSUED MATERIAL SAFETY DATA SHEET EXXON COMPANY, U.S.A. P.O. BOX 2180 HOUSTON, TX 77252-2180 7/1/85 A IDENTIFICATION AND EMERGENCY INFORMATION PRODUCT NAME FLEXON 845 PRODUCT CODE 346055 - 03335 CHEMICAL NAME Petroleum Process Oil CAS NUMBER 64742-54-7 or 64742-65-0 PRODUCT APPEARANCE AND ODOR j Clear liquid, yellow color | Bland petroleum odor I: i EMERGENCY TELEPHONE NUMBER | (7131 656-3424 1 1 B. COMPONENTS AND HAZARD INFORMATION ! COMPONENTS j CAS NO. OF COMPONENTS APPROXIMATE CONCENTRATION Hydrotreated heavy paraffinic i distillate, petroleum j or Solvent dewaxed heavy paraffinic > distillate, petroleum 64742-54-7 or 64742-65-0 100% |, EXPOSURE LIMIT FOR TOTAL PRODUCT 5 mg/m3 for oil mist In sir BASIS OSHA Regulation 29 CFR 1910.1000 1 C. EMERGENCY AND FIRST AID PROCEDURES 1 EYE CONTACT If splashed Into the eyes, flush with clear water for 15 minutes or until Irritation subsides. If irritation persists, call a physician. . SKIN CONTACT Ir, case of skin contact, remove any contaminated clothing ana wash snin thoroughly with soap and water INHALATION Vaoor pressure Is very low. Vapor innalatlon under ambient conditions Is normally not a problem. If overcome by vaoor from hot product, Immediately remove from exposure and call a physician. If breathing is irregular or has stopped, start resuscitation; administer oxygen, If avellaole. If overexposed to oil mist, remove from further exposure until excessive oil mist condition subsides. ! ! 1 ) 1 t | , ! 1 I I i j 1 S45-0S77IMWH001) DO 086214 CONFTDFNTIAL FLEXON 845 INGESTION If Ingested, call a physician immediately. D. FIRE AND EXPLOSION HAZARD INFORMATION FLASH POINT (MINIMUM) 205'C (400'F) ASTM D 82. Claval and Opan Cup AUTOXGNXTION TEMPERATURE Greeter than 260'C (500*F) FLAMMABLE OR EXPLOSIVE LIMITS (APPROXIMATE PERCENT BY VOLUME IN AIR) Estlntatad valuas: Lower Flammable Limit 0.9% upper Flammacia Limit 7% EXTINGUISHING MEDIA AND FIRE FIGHTING PROCEDURES Foam, watar spray (fog), dry cnamlcal, carbon dloxlda and vaporizing liquid tyoa axtlngulshing agants may all ba sultabla for axtlngulshing firas Involving this typa of procuct, dapanding on siza or potantial siza of fira and circumstancas ralatad to tna situation. Plan flra protaction and rasponsa stratagy through consultation with local firs protaction authorities or appropriate specialists. The following procedures for this typa of product are based on the recommendations in the National Fire Protection Association's "Fire Protection Guide on Hazardous Materials". Eighth | Edition (19B4): t I Usa water spray, dry cnamlcal, foam or carbon dioxide, use water to keep fire-exposed | containers cool. If a leak or spill has not Ignited, use water spray to dispe-se the ! vapors and to provide protection for men attempting to stop a leek. Water spray may l be used to flush spills away from exposures. Minimize breathing gases, vapor, fumes or i decomposition products. Usa suppilad-air breathing equipment for enclosed or conf'ineo spaces ! or as otherwise needed. I ! i ; | DECOMPOSITION PRODUCTS UNDER FX-RE CONDITIONS I Fumes, smoke, carbon monoxide, sulfur oxides, aldehydes and other decomposition products, in the case of incomplete combustion. | "EMPTY" CONTAINER WARNING 1 "Empty" containers retain residue (liquid and/or vapor) and can be dangerous. DO NOT : PRESSURIZE , CUT, WELD, BRAZE, SOLDER. DRILL, GRIND OR EXPOSE SUCH CONTAINERS TD HEAT, FLAME, SPARKS OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. Do not attempt to clean since residue is difficult to remove. "Empty" drums should be completely drained, properly bunged and promptly returned to a drum reconditioner, All other containers should be disposed of in an environmentally safe manner and in ! accordance with governmental regulations. For work on tanks refer to Occupational Safety and Health Administration regulations, ANSI Z4S.1, and other governmental and industrial references pertaining to cleaning, repairing, welding, or other contemplated ! operations. E. HEALTH AND HAZARD INFORMATION* 1 VARIABILITY AMONG INDIVIDUALS 1 Health studies nave shown that many petroleum hydrocarbons and synthetic lubricants pose ! potential human health risks which may vary from person to person. As a precaution, exposure to liquids, vapors, mists or fumes shoulo be minimized. EFFECTS OF OVEREXPOSURE (Signs and symptoms of exposure) Prolonged or repeated skin contact may cause skin Irritation. NATURE OF HAZARD , Prolonged or repeated skin contact with this product tends to remove skin oils possibly | leading to irritation and dermatitis. Product contacting the eyes may cause eye Irritation, 9f5-C217(MWH002) 86?15 C NFJOBhir -Ta/.. | TOXICITY INFORMATION I Product has a low order of acuta oral toxicity. FLEXON 845 F. PHYSICAL DATA Tha following data ana approximate or typical va ues and should not be used for precise design purposes. BOILING RANGE IBP Approximately 293'C (560*F) by ASTM D 2887 VAPOR PRESSURE Less tnan 0.01 mm Hg e 20'C i SPECIFIC GRAVITY (1S.B C/15.6 C) 0.87 VAPOR DENSITY (AIR - 1) Greater than 5 MOLECULAR WEIGHT Approx 1 mats 1y 400 PERCENT VOLATILE BY VOLUME Negligible from open container in 4 hours e 38*C (100`F) 1 pH Essentially neutral EVAPORATION RATE 1 ATM. AND 25 C (77 F) (n-BUTYL ACETATE 1) Less than 0.01 : POUR, CONGEALING OR MELTING POINT j _9"C ( 15" F ) Pour Point by ASTM D 97 SOLUBILITY IN WATER 0 1 ATM. AND 25 C (77 F) Negligible; less than 0.1*/ ! VISCOSITY 154 ssu 100*F G. REACTIVITY This product is stable and will not react violently with water. Hazardous polymerization will not occur. Avoid contact with strong oxidants such as liquid chlorine, concentrated oxygen, sodium hypochlorite or calcium hypocnlor 1te, H. SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Recover free product. Ado sand, earth, or other suitable absorbent to spill area. Minimize skin contact. Keep product out of sewers and watercourses by diKing or impounding. Aavise authorities if product has entered or may enter sewers, watercourses, or extensive land areas. Assure conformity with applicable governmental regulations. I. PROTECTION AND PRECAUTIONS VENTILATION Use local exhaust to capture vapor, mists or fumes, if necessary. Provide greater than SO feet per minute hood face velocity for confined spaces. Provide ventilation sufficient to prevent exceeding recommended exposure limit or buildup of explosive concentrations of vapor in air. Use explosion-proof eauipment. No smoking or open lights. RESPIRATORY PROTECTION Normally not needed at ambient temperatures. in confined or enclosed spaces, if needed. Use suppllad-air respiratory protection 945-CI71(MWHgOI) DO 086216 DONFTOFNTTA!.. FLEXON 845 r PROTECTIVE GLOVES Usa cnemical-reslstant gloves, if needed, to avoid prolonged or rapaatad akin contact. EYE PROTECTION Uaa splash goggles or faca aniald whan aya contact may occur. OTHER PROTECTIVE EQUIPMENT lisa chemical-resistant apron or othar impervious clothing, if naadad. to avoid contaminating regular clothing which could result in prolongad or rapaatad akin contact. WORK PRACTICES / ENGINEERING CONTROLS Keep containers closed whan not in use. I or strong oxidants. Do not handle or store near heat, sparks, flame j PERSONAL HYGIENE Minimize Dreathing vapor, mist or fumas. Avoid prolongad or repeated contact with skin. Remove contaminated clothing; launder or dry-clean Before reuse. Remove contaminated shoes and thoroughly clean before reuse; discard if oil-soaked. Cleanse skin tnorougniy after contact, before breaks and meals, and at end of work period. Product is readily removedfrom skin by waterless hand cleaners followed by washing thoroughly with soap and water. ! ! i ; I | | J. TRANSPORTATION INFORMATION TRANSPORTATION INCIDENT INFORMATION For further information relative to spills resulting from transportat1 on incidents, refer to latest Department of Transportat1 on Emergency Response Guidebook for Hazardous Materials Incidents. DOT P 5800.3. ) The information and recommendat1ons contained herein are, to the best of Exxon's Knowledge and ' belief, accurate and reliable as of the date Issued. Exxon does net warrant or guarantee their accuracy or reliability, and Exxon shall not be liable for any loss or damage arising out of | the use thereof. 1 The Information and recommendations are offered for the user's cons 1 derat 1 on and examination, and It is the user's responsibility to satisfy itself that they are suitable and complete for Its particular use. FOR ADDITIONAL .INFORMATION ON HEALTH EFFECTS CONTACT: - DIRECTOR OF INDUSTRIAL HVGIENE EXXON COMPANY. U.S.A. P C. BOX 2180 ROOM 2737 HOUSTON, TX 77252-2180 (713) 656-2443 FOR'OTHER PRODUCT INFORMATION CONTACT; MANAGER, MARKETING TECHNICAL EXXON COMPANY. U.S.A. P. 0. BOX 2180 ROOM 2455 HOUSTON, TX 77252-2180 (713) 656-5949 SERVICES 945*0277(MWh002) DO 086217 ! CONFTDFNT IAI, i ____________ I FLEXON 680 E^ON COMPANY, USA A DIVISION Of EXXON CORPORATION DATE ISSUED 7/1/85 MATERIAL SAFETY DATA SHEET EXXON COMPANY, U.5.A. P.O. BOX 2180 HOUSTON. TX 77252-2180 A IDENTIFICATION AND EMERGENCY INFORMATION PRODUCT NAME FLEXON 680 CHEMICAL NAME Petroleum Process Oil PRODUCT APPEARANCE AND ODOR Clear, orange-red liquid Mild medicinal odor EMERGENCY TELEPHONE NUMBER (713) 656-3424 PRODUCT CODE 346039 - 03341 CAS NUMBER 64742-52-5 B. COMPONENTS AND HAZARD INFORMATION COMPONENTS Hydrotreated heavy naphthenic distillate, petroleum EXPOSURE LIMIT FOR TOTAL PRODUCT 5 mg/m3 for oil mist In air CAS NO. OF COMPONENTS 64742-52-5 APPROXIMATE CONCENTRATION 100% BASIS OSHA Regulation 29 CFR 1910.1000 C. EMERGENCY AND FIRST AID PROCEDURES EYE CONTACT If splashed Into the eyes, flush with clear water for 15 minutes or until Irritation subsides. If.irritation persists, call a physician. SKIN CONTACT In case of skin contact, remove any contaminated clothing and wash skin thoroughly with soap and water. INHALATION Vapor pressure is very low. Vapor inhalation under ambient conditions Is normally not a problem. If overcome by vapor from hot product, immediately remove from exposure and call a physician. If breathing is irregular or has stopped, start resuscltat ion; administer oxygen. If available. If overexposed to oil mist, remove from further exposure until excessive oil mist condition subsides. <- INGESTION If ingested, call a physician immediately. 94-02?7(MWH00l) fr 086?] 0 confidential FLEXON 680 D. FIRE AND EXPLOSION HAZARD INFORMATION FLASH POINT (MINIMUM) 221'C (430'F) ASTM D 92, Cl aval ana Open Cup AUTOIBNITION TEMPERATURE Great*)* than 260'C (500'F) FLAMMABLE OR EXPLOSIVE LIMITS (APPROXIMATE PERCENT BY VOLUME IN AIR) Estimated values: Lower Flammable Limit 0.914 Upper Flammable Limit 754 EXTINGUISHING MEDIA AND FIRE FIGHTING PROCEDURES Foam, water spray (fog), dry chemical, carbon dioxide and vaporizing liquid type extinguishing agents may all be suitable for extinguishing fires involving this type of product, depending on size or potential size of fir* and circumstances related to the situation. Plan fire protection and response strategy through consultation with local fire protection authorities or appropriate specialists. The following procedures for this type of product are based on the recommendations In the National Fire Protection Association's "Fire Protection Guide on Hazardous Materials", Eighth Edition (19B4): Use water spray, dry chemical, foam or carbon dioxide. Use water to keep fire-exposed containers cool. If a leak or spill has not Ignited, use water spray to disperse the vapors and to provide protection for men attempting to stop a leak. Water spray may be used to flush spills away from exposures. Minimize breathing gases, vapor, fumes or i decomposition products. Use supplied-alr breathing equipment for enclosed or confined spaces or as otherwise needed. DECOMPOSITION PRODUCTS UNDER FIRE CONDITIONS Fumes, smdke, carbon monoxide, sulfuh oxides, aldehydes and other decomposition products, In the case of Incomplete combustion. EMPTY" CONTAINER WARNING "Empty" containers retain residue (liquid and/or vapor) and can be dangerous. DO NOT PRESSURIZE , CUT, WELD, BRAZE. SOLDER. DRILL. GRIND OR EXPOSE SUCH CONTAINERS TO HEAT. FLAME. SPARKS OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. Do not attempt to clean since residue Is difficult to remove. "Empty" drums should be completely drained, properly bunged and promptly returned to a drum reconditioner. All other containers should be disposed of in an environmentally safe manner and In accdrdance with governmental regulations. For work on tanks refer to Occupational Safety and Health Administration regulations, ANSI Z49.1, and other governmental and industrial references pertaining to cleaning, repairing, welding, or other contemplated operations. E HEALTH AND HAZARD INFORMATION 1 VARIABILITY AMONG INDIVIDUALS Health studies have shown tnat many petroleum hydrocarbons anc synthetic lubricants pose potential human health risks which may very from person to person. As a precaution, exposure | to liquids, vapors, mists or fumes should be minimized. ; EFFECTS OF OVEREXPOSURE (Signs and symptoms of exposure) j Prolonged or repeated skin contact may cause skin irritation. { NATURE OF HAZARD ! Prolonged or repeated skin contact with this product tends to remove skin oils possibly leading to Irritation and dermatitis. | Product contacting the eyes may cause eye irritation. TOXICITY INFORMATION Product has a low order of acute oral toxicity. B45`0277(MWH002) 00 r.ONFTDFNTTAL FLEXON 680 F. PHYSICAL DATA The following data aro approximate or typical values and should not bo ussd for prociss design purposes. BOILING RANGE IBP Approximately 366'C (690*F) by A5TM 0 2BB7 VAPOR PRESSURE Less tnan 0.01 mm Hg P 20' C SPECIFIC GRAVITY (IS.6 C/1S.6 C) 0.93 VAPOR DENSITY (AIR 1) Greater than S MOLECULAR WEIGHT Approximately 4B0 PERCENT VOLATILE BY VOLUME Negligible from open container In 4 hours 38'C (100`F) pH Essentially neutral EVAPORATION RATE * 1 ATM. AND 25 C (77 F) (n-BUTYL ACETATE * 1) Less than 0.01 POUR, CONGEALING OR MELTING POINT -6'C (20"F) Pour Point by ASTM D 97 SOLUBILITY IN WATER * 1 ATM. AND 25 C (77 F) Negligible: less than 0.1% VISCOSITY 1.225 SSU P 100* F G. REACTIVITY This product is stable ano will not react violently with water. Hazardous polymerization will not occur. Avoid contact with strong oxidants such as liquid chlorine, concentrated oxygen, sodium hypochlorite or calcium hypochlorite.' H. SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Recover free product. Add sand, earth, or other suitable absorbent to spill area. Minimize skin contact. Keep product out of sewers and watercourses by diking or impounding. Advise authorities if product has entered or may enter sewers, watercourses, or extensive land areas. Assure conformity with applicable governmental regulations. I. PROTECTION AND PRECAUTIONS VENTILATION ; Use local exhaust to capture vapor, mists or fumes, If necessary, provide greater than 60 , feet per minute hood face velocity for confined spaces. Provide ventilation sufficient to j prevent exceeding recommended exposure limit or buildup of explosive concentrations of vapor in air. Use explosion-proof equipment. No smoking or open lights. RESPIRATORY PROTECTION Normally not needed at ambient temperatures. In confined or enclosed spaces, if needed. Use supplied-air respiratory protection | PROTECTIVE GLOVES Use chemical-resistant gloves, if needed, to avoid prolonged or repeated skin contact. 945-0277(MWH002) 00 086??0 confidential FLEXON 660 EYE PROTECTION Use splash gogglss or facs shield whan aya contact may occur. OTHER PROTECTIVE EQUIPMENT Usa chemical-resistant apron or othar imparvious clothing, if needed, to avoid contaminating regular clothing which could result in prolonged or repeated skin contact. WORK PRACTICES / ENGINEERING CONTROLS Keep containers closed when not In use. or strong oxidants. Do not handle or store near heat, sparks, flame PERSONAL HYGIENE Minimize Dreatning vapor, mist or fumes. Avoid prolonged or repeated contact with skin. Remove contaminated clothing; launder or dry-clean before reuse. Remove contaminated shoes and tnorougniy clean Defore reuse; discard if oil-soaked. Cleanse skin thoroughly after contact, before breaks and meals, and at end of work period. Product Is readily removed from skin by waterless hand cleaners followed by washing thoroughly with soap and water. J. TRANSPORTATION INFORMATION TRANSPORTATION INCIDENT INFORMATION For further information relative to spills resulting from transportation Incidents, refer to latest Department of Transportation Emergency Response Guidebook for Hazardous Materials Incidents, DOT P 5B00.3. ii ; The information and recommendations contained herein are. to the best of Exxon's knowledge and belief, accurate and reliable as of the date Issued. Exxon does not warrant or guarantee their accuracy or reliability, and Exxon shall not bo liable for any loss or damage arising out of the use thereof. The information and recommendations are offered for the user's eonsiderat1 on and examination, and It Is the user's responsibility to satisfy tself that they are suitable and complete for Its particular use. FOR ADDITIONAL INFORMATION ON HEALTH EFFECTS CONTACT: DIRECTOR OF INDUSTRIAL HYGIENE EXXON COMPANY, U.S.A. P 0. BOX 21 BO ROOM 2737 HOUSTON, TX 77252-2180 (713) 656-2443 I I FOR OTHER PRODUCT INFORMATION CONTACT: MANAGER, MARKETING TECHNICAL SERVICES EXXON COMPANY, U.S.A. P. 0. BOX 21 BO ROOM 2455 HOUSTON. TX 77252-2180 (713) 656-5949 l I 94ft-0377(MWH002) 00 ^0 /yp T0FNr Tai USBORAX MATERIAL SAFETY DATA SHEET Meeting OSHA Standard 29CFR #1910.1200 (g) EFFECTIVE DATE: October 25. 1985 PRODUCT TRADE NAME FIREBRAKE ZB CHEMICAL NAME AND SYNONYMS Zinc Borate (2.3.3.5) ZB 2335 CHEMICAL FAMILY: Borate HAZARD RATING: NFPA Health 0 Flammability 0 Reactivity 0 CAS NO. 12447-61-9 FORMULA: 2 Zn0*3B203*3.5H20 Material or Component None wiu*i Material or Component "WARNING: This product contains trees amounts of arsenic, a chemical known to the State of California to cause cancer. Exposure to arsonic from this Droduct will not exceed the Federal OSHA PEL unless used in a manner that produced extremely heavy airborne ccnr.entrntranB St bntftte mfltrtfinl at levels many timoB niimvflfif? P*u'flrol OSHA limits." Specific gravity: 2.8 g/cm Appearance: White powder, odorless Negligible solubility in water below 100F Average particle size: 2-10 microns Hydrolyzes with acids and bases Molecular weight 434.66 Reportive index 1.58 , Crystal density 2.8 g/cmJ Bulk density 30-50 lbs/cubic foot Oil absorption 43 g oil/lOOg. DO 08622? conftdfntta1 CONTACT: John C. Middleton, Manager, Product Safety "The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind expressed or implied is made with respect to the information contained herein.'' UNITED STATES BORAX & CHEMICAL CORPORATION 3075 WILSHIRE BLVD , LOS ANGELES, CA 90010 Page i ....... ....... I1SB0RAX SECTION IV -- HEALTH HAZARD INFORMATION ' EFFECTS OF EXPOSURE (SYMPTOMS) INGESTION: Not an acute poison. May cause nausea. ACUTE ORAL LD^ (albino rats) greater than 10 gram/Kg body weight. EYE: (16CFR $1500.42) Nay cause slight conjunctivitis. Not an irritant. SKIN: Non -irritating. ACUTE DERMAL LDS0 (16CFR 1500.40) Greater than lOg/Kg body weight on albino rabbits. PRIMARY SKIN IRRITATION INDEX: (16CFR #1500.41) - 0 (rabbits) CORROSIVE NON CORROSIVE: - X INHALATION May be irritating to mucous tissues. ACUTE LC50 Not tested. 086??3 OONFTDFNTTaI. UNITED STATES BORAX & CHEMICAL CORPORATION 3075 WILSHIRE BLVD., LOS ANGELES, CA 90010 Page 2 USBORAX' ' EFFECTS OF OVEREXPOSURE FIREBRAKE ZB 10/25/85 ACUTE OVEREXPOSURE/METHOD OF EXPOSURE/SYMPTOMS Eyes: As with any powder or dust, may be irritating. Inhalation: May cause sneezing and coughing. Ingestion: May cause nausea, vomiting, diarrhea. Skin: On unbroken skin no effect. Reversible CHRONIC OVEREXPOSURE/METHOD OF EXPOSURE/SYMPTOMS Eyes: May cause conjunctivitis. Reversible. Inhalation: May be irritating to mucous tissue. Ingestion: May cause nausea, vomiting, diarrhea. Skin: No effects. OSHA Permissible Exposure LIMIT (PEL) Not listed. 29CFR 1910 Subpart Z ACGIH Recommended Threshold Limit Value Not listed. NOTE: Not mutagenic when tested in the Salmonella/Microsomal Mutagenicity Plate Incorporation assay. National Toxicology Program Annual Report on Carcinogens Year 19 83 Listed Not Listed - X International Agency for Research on Cancer (IARC) Monograph Yes No - X OSHA CARCINOGEN No EMERGENCY AND FIRST AID PROCEDURES: EYES Flush with tepid water for 15 minutes. If irritation persists consult physician. SKIN Wash area with soap and water. INHALATION Remove to fresh air. DO 0S62?4 OONFIDFNTTAI, (CONT PAGE 4) UNITED STATES BORAX & CHEMICAL CORPORATION 3075 WILSHIRE BLVD., LOS ANGELES, CA 90010 --.... -- Page 3 IICDIID AV UuJiUHAa EMERGENCY AND FIRST AID PROCEDURES: ^ -------------------------------------------------------- ------------------------------------------------------------------------------ (CONT FROM PAGE 3) INGESTION Induce vomiting. Drink large amounts of milk or water. i <HliPJWS1CIAN Not an acute poison. Since product hydrolyzes on contact with acids treat for borate ingestion. Gastric lavage with 5% sodium bicarbonate solution. For severe cases intravenous Ringer's solution is suggested. Contact emergency number on Page 1 for medical consultation on further management. SECTION V - FIRE AND EXPLOSION HAZARD DATA FLASH POINT (Method used) Not applicable FLAMMABLE LIMITS Lel EXTINGUISHING MEDIA Not applicable. Product is fire retardant. Uel SPECIAL FIREFIGHTING PROCEDURES - None UNUSUAL FIRE AND EXPLOSION HAZARDS - None SECTION VI -- REACTIVITY DATA STABILITY UNSTABLE STABLE - X CONDITIONS TO AVOID INCOMPATABILITY (materials to avoid) Hydrolyzes when in contact with acids or bases. HAZARDOUS DECOMPOSITION PRODUCTS - None HAZARDOUS POLYMERIZATION MAY OCCUR WILL NOT OCCUR - X CONDITIONS TO AVOID None known. DO 086225 CONFTDFNTTAL UNITED STATES BORAX & CHEMICAL CORPORATION 3075 WILSHIRE BLVD., LOS ANGELES, CA 90010 ........ ' -------- Page 4 USBORAX FIREBRAKE ZB 10/25/85 SECTION VII -- SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Sweep or vacuum and put into sealed metal container. Rinse area with water. WASTE DISPOSAL METHOD Zinc borate is not listed as a Hazardous Waste in 40CFR 261. Check with local authorities regarding disposal requirements. SECTION VIII -- SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION (Specify type) 3M Co. model 8710 or COMFO II with particulate filler VENTILATION LOCAL EXHAUST Standard SPECIAL MECHANICAL (General) Standard OTHER PROTECTIVE GLOVES Not necessary OTHER PROTECTIVE EQUIPMENT EYE PROTECTION Dust goggles suggested ANSI Standard Z87-1-1968 Type EtjJCON 160 SECTION IX -- SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Dry indoor storage. OTHER PRECAUTIONS Note disposal procedures above. ------------------------------------------------------------------------------------------- ---------------- --------- 00 086 DATF- 10/25/85 SIGNATURE: ______ CONFTDFNTTAl. UNITED STATES BORAX & CHEMICAL CORPORATION 3075 WIISHIRE BLVD., LOS AANNGLE.tLLEttSo,, COAAS9U0O01IO0 Page 5 11QQ (1Q AY UuDUnnA PAGE 1 i3 MATERIAL SAFETY DATA SHEET CIBA-GEIGY CORPORATION PLASTICS S ADDITIVES DIVISION THREE SKYLINE DRIVE HAWTHORNE, NEW YORK 10532 EMERGENCY PHONE NUMBERS) SAFETY/HEALTH) (914) 347-4700 AFTER HOURS > (800) 334-9481 SECTION I-IDENTITY INFORMATION IDENTITY (TRADENAME)t FILESTER VIOLET BA FAMILY/CHEMICAL NAME) ANTHRAQUINONE C.I. DISPERSE VIOLET 57 PRODUCT TYPE) COLORANT HAZARD STATEMENT > xxxxxxxxxxxxxxxxxxxxxxxxxxxxxx X THIS MATERIAL SAFETY DATA SHEET (MSDS) HAS BEEN X X PREPARED IN COMPLIANCE WITH THE FEDERAL OSHA HAZARD X X COMMUNICATION STANDARD 29 CFR 1910.1200. X X THIS PRODUCT IS NOT CONSIDERED TO BE A HAZARDOUS X X CHEMICAL UNDER THAT STANDARD. X xxxxxxxxxxxxxxxxxxxxxxxxxxxxxx __________________ SECTION II-HAZARDOUS INGREDIENTS _________________ NOT APPLICABLE. SECTION III-PHYSICAL DATA APPEARANCE AND ODOR) VIOLET POWDER, ODORLESS MELTING POINT) APPROX. 185C DECOMPOSITION TEMPERATURE) >300C SOLUBILITY IN WATER) INSOLUBLE. SPECIFIC GRAVITY) NOT AVAILABLE. FILESTER VIOLET BA 00 08&2P7 confidential PAGE 2 SECTION IV-FIRE AND EXPLOSION HAZARD DATA FLASH POINT. NOT APPLICABLE. FLAMMABLE LIMITS IN AIR-LOWER. NOT APPLICABLE. FLAMMABLE LIMITS IN AIR-UPPER. NOT APPLICABLE. EXTINGUISHING MEDIA. CARBON DIOXIDE, DRY CHEMICAL, FOAM, WATER. FIRE FIGHTING PROCEDURES-SPECIAL. USE SELF-CONTAINED BREATHING APPARATUS. UNUSUAL FIRE AND EXPLOSION HAZARDS. DECOMPOSITION AND COMBUSTION PRODUCTS MAY BE TOXIC. DUST CLOUDS FROM PIGMENT POWDER CAN CREATE A DUST EXPLOSION HAZARD. SECTION V-REACTIVITY DATA STABILITY. STABLE. HAZARDOUS POLYMERIZATION. WILL NOT OCCUR. SECTION VI-HEALTH HAZARD DATA PRIMARY ROUTES OF EXPOSURE. INHALATION. ORAL LD50. (RATS) >5000 MG/KG SKIN IRRITATION: (RABBITS) NON-IRRITATING. EYE IRRITATION. (RABBITS) NON-IRRITATING. SENSITIZATION. NOT AVAILABLE. INHALATION LC50. NOT AVAILABLE. OVEREXPOSURE EFFECTS. NOT AVAILABLE SIGNS AND SYMPTOMS OF EXPOSURE. NOT AVAILABLE. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE. NOT AVAILABLE. EMERGENCY AND FIRST AID PROCEDURES-EYES. IMMEDIATELY FLUSH EYES WITH WATER FOR AT LEAST 15 MINUTES. CALL A PHYSICIAN. EMERGENCY AND FIRST AID PROCEDURES-SKIN. WASH WITH MILD SOAP AND WATER. EMERGENCY AND FIRST AID PROCEDURES-INGESTION. IF CONSCIOUS, GIVE LARGE QUANTITIES OF WATER. INDUCE VOMITING. CALL A PHYSICIAN. FILESTER VIOLET BA DO 086228 CONFIDFNTIAl PAGE 3 EMERGENCY AND FIRST AID PR0CEDURE5-INHALATI0N> REMOVE TO FRESH AIR. IF BREATHING HAS STOPPED GIVE ARTIFICIAL RESPIRATION. CALL A PHYSICIAN. SECTION VII-SPILL OR LEAK PROCEDURES SPILL PROCEDURES* COLLECT AND PLACE INTO A CLOSABLE CONTAINER FOR DISPOSAL. NEAR PROTECTIVE EQUIPMENT SPECIFIED BELOW. WASTE DISPOSAL METHODS* DISPOSE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS. SECTION VIII-SPECIAL PROTECTION INFORMATION VENTILATION. USE LOCAL EXHAUST. PROTECTIVE GLOVES* WEAR IMPERVIOUS GLOVES. EYE PROTECTION. WEAR SIDE-SHIELD CHEMICAL SAFETY GLASSES. RESPIRATORY PROTECTION* USE NIOSH APPROVED DUST MASK. SECTION IX-SPECIAL PRECAUTIONS HANDLING, SHIPPING AND STORING PRECAUTIONS. NOTICE* IN ACCORDANCE WITH GOOD INDUSTRIAL PRACTICE, HANDLE WITH CARE AND AVOID PERSONAL CONTACT. AVOID BREATHING DUST, MIST, OR VAPORS. USE WITH ADEQUATE VENTILATION. WASH HANDS AND FACE THOROUGHLY AFTER HANDLING AND BEFORE EATING, DRINKING, OR USING TOBACCO PRODUCTS. KEEP CONTAINER CLOSED WHEN NOT IN USE. FOR INDUSTRIAL USE ONLY. SECTION X- REGULATORY INFORMATION DOT CLASS* NOT REGULATED. DOT NUMBER. NOT APPLICABLE. ISSUE DATE* 06/17/86 REVISION. 01C FOR FURTHER INFORMATION, PLEASE CONTACT. ALAN SCHENKEL THE INFORMATION AND RECOMMENDATIONS CONTAINED HEREIN ARE BASED UPON DATA BELIEVED TO BE CORRECT. HOWEVER, NO GUARANTEE OR WARRANTY OF ANY KIND EXPRESSED OR IMPLIED IS MADE WITH RESPECT TO THE INFORMATION CONTAINED HEREIN. FILESTER VIOLET BA DO cONF ro^rrAi. Comm r ial Ch mieal Division/3M Mat rialSaf ty Data Sh t 3M Canter St Paul, Minnesota 55144 10-.3 398-3. 618/733-1110________________________________ Trade Name * FC-2120 FLIIOSEL ftrjinrt Plunrnelastnaar mical Family 3M LD. Ntxnber *1 uorinated Flaitompr 1. Ingredients 98-0211-121 6-8 (5^ CAS * % Fluoroelastomer 9011-17-0 Curative (Quaternary Phosphoniura/Polyphenol) Mixture >95 <5 lb. NE NE unitl TLV ' (Unit) NE = Not Established 2. Phyaical Data Boiling Point Solubility in Water Vapor pressure NA Specific Gravity (H,0 " 1) Vapor Density (Air = 1) NA Percent Volatile Evaporation Rate NA pH Appearance and Odor -HA______________ white# rubbery solid. > and Explosion Hazard Data Flash Point (Test Method) Setaflash CC >450 F____________________________ Flammable Limits: LEL - ty J Extinguishing Media Water# Foam# CC2# Drv Chemical Special Fire Fighting Procedures Negligible -1.8 0 ___na________________ UEL- tyA Non? Known_____________________________________ Unusual Fire and Explosion Hazards Toxic bv-prorincts# including HF# may be fanned. 4. Environmental Information Spill Response Observe precautions from other sections Collect spilled material. Recommended Disposal For quantities <100 lbs.: Dispose of waste product in a sanitary landfill. Dispose of bulk product in a facility permitted to accept chemical wastes. Or: Mix with flammable material and incinerate in an industrial or commercial facility. Combustion products will include HF. Since regulations vary# consult applicable regulations or authorities before disposal. U.S. EPA Hazardous Waste No.: None Environmental Data Not determined. DO 086230 CONFIDENT TAl 1984Threshold Limit Values listed above are current to_ Because they are reviewed yearly by ACGIH and subject to change (usually to a lower value) K is necessary for the user of this Material Safety Data Sheet to maintain a list of revised TLV's and update the sheet periodically. Form 15C93-2-C NA = Not Applicable ND = Not Determined Duns No.: 00-617-3082 TrrdfName pc_212Q FLUOREL Brand Fluoroelastomer ft. Health Hazard Data Eye Contact Animal studies indicate FC-2120 crumb is practically non-irritating ocularly <FHSA score 1.7/110.0). ' , Contact Animal studies indicate FLUOREL Brand Elastomers are non-irritating demally. Persons working with the product would have a low potential for developing skin irritation,_________________________________________ Inhalation No hazard at temperatures below the thermal decomposition point. At temperatures >660 F, breakdown to HF and short chain fluorocarbons, which are irritating and toxic, begins.___________________ kigestion Not Applicable. Suggested First Aid EYE CONTACT: Immediately flush with plenty of water. SKIN CONTACT: Wash affected area with soap and water. INHALATION: Remove to fresh air. Call a physician. 6. Reactivity Data Stability Unstable Conditions To Avoid X Stable Not Aoplicable ^compatibility Materials To Avoid ftl or Hq powdei A hlah shear/temperature conditions. hazardous Polymerization May Occur Conditions To Avoid X Will Not Occur Not Applicable_____________________________________________________________________ Hazardous Decomposition Products Thermal decomposition may produce toxic materials including HF. 7. Special Protection Information Eye Protection Skin Protection Safety classes Normal Industrial Attire. Ventilation General ventilation adequate below 660 F. Local exhaust Respiratory and Special Protection If decomposition occurs, use organic vapor and acid gas recommended above cartridge mask. 660 F. 8. Precautionary Information Avoid inhalation of decomposition products. Store below 100 F. moisture contamination. Do not smoke while handling. Prevent 9. Department of Transportation " --r Proper Shipping Name DOT Hazard Class NA = Not Applicable ND = Not Determined DO 08F>23! CONFIDENT! Al- Issue Date NOV-1985 Supersedes Feb-1995 The information on this Data Sheet represents our cun-ent data and best opinion as to the proper use and handling of this product under normal conditions. Any use of the product which is not in conformance with this Data Sheet or which involves using the product in combination with any other product or any process is the responsibility of the user.