Document K6EpMMw0wM9VK5m28G3oNZeex
Phemguard
Safety Data Sheet
T his sa fe ty data sh e e t com p lie s w ith the req uire m en ts of: 2012 OSHA Hazard Communication Standard ( 29CFR 1910.1200)
Product name CHEMGUARD 3% AFFF C306-MS-C
1. Identification
1.1. Product Identifier Product name
CHEMGUARD 3% AFFF C306-MS-C
1.2. Other means of identification Product code Synonyms Chemical Family
770810 None No information available
1.3. Recommended use of the chemical and restrictions on use
Recommended use
Fire extinguishing agent
Uses advised against
Consumer use
1.4. Details of the Supplier of the Safety Data Sheet
Company Name
Tyco Fire Protection Products
One Stanton Street
Marinette, Wl 54143-2542
Telephone: 715-735-7411
Contact point
Product Stewardship at 1-715-735-7411
E-mail address
psra@tycofp.com
1.5. Emergency Telephone Number
Emergency telephone
CHEMTREC 800-424-9300 or 703-527-3887
2. Hazards Identification
Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Serious eye damage/eye irritation - Category 1 2.2. Label Elements Signal Word DANGER
hazard statements Causes serious eye damage
Precautionary Statements Prevention Wear protective gloves/protective clothing/eye protection/face protection.
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IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician.
2.3. Hazards Not Otherwise Classified (HNOC)
Not Applicable.
2.4. OTHER INFORMATION
Unknown Acute Toxicity
9.1297% of the mixture consists of ingredient(s) of unknown toxicity
3. Composition/information on Ingredients
3.1. Mixture
The following component(s) in this product are considered hazardous under applicable OSHA(USA)
Chemical name 2-(2-Butoxyethoxy)ethanol Laurylamidopropyl betaine
Caprylcaprilyl glucoside Fluorochemical Anionic Surfactant
Polyfluorinated alkyl polyamide Octylphenoxypolyethoxyethanol
CAS No 112-34-5 4292-10-8 68515-73-1 Proprietary Proprietary 9036-19-5
weight-% 10-30 1- 5 1- 5 1- 5 1- 5 1- 5
4. First aid measures
4.1. Description of first aid measures
Eye Contact
Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids.
Consult a physician.
Skin contact
Wash skin with soap and water. Get medical attention if irritation develops and persists.
Inhalation Ingestion
Remove to fresh air. If breathing is difficult, give oxygen. (Get medical attention immediately if symptoms occur.).
Rinse mouth. Do not induce vomiting without medical advice. If swallowed, call a poison control center or physician immediately.
4.2. Most Important Symptoms and Effects. Both Acute and Delayed
Symptoms
No information available.
4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed
Note to physicians
Treat symptomatically.
5. Fire-fighting measures
5.1. Suitable Extinguishing Media Product is extinguishing agent. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
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5.2. Unsuitable Extinguishing Media None.
5.3. Specific Hazards Arising from the Chemical
None known.
Hazardous Combustion
Carbon oxides, Fluorinated oxides, Nitrogen oxides (NOx), Oxides of sulfur
Products
5.4. Explosion Data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None.
5.5. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
6. Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Personal Precautions
Ensure adequate ventilation, especially in confined areas.
For emergency responders
Use personal protection recommended in Section 8.
6.2. Environmental Precautions Environmental Precautions
Prevent further leakage or spillage if safe to do so. Prevent entry into waterways, sewers, basements or confined areas. See Section 12 for additional Ecological Information.
6.3. Methods and material for containment and cleaning up
Methods for Containment
Prevent further leakage or spillage if safe to do so.
Methods for Cleaning Up
Pick up and transfer to properly labeled containers.
7. Handling and Storage
7.1. Precautions for Safe Handling
Advice on safe handling
Avoid contact with skin and eyes. Handle in accordance with good industrial hygiene and safety practice.
7.2. Conditions for safe storage, including any incompatibilities
Storage Conditions
Keep containers tightly closed in a dry, cool and well-ventilated place.
Incompatible Materials
Strong oxidizing agents. Strong acids. Strong bases.
8. Exposure Controls/Personal Protection_______________________________________________
8.1. Control Parameters
Exposure guidelines
Chemical name
ACGIH TLV
OSHA PEL
NIOSH IDLH
2-(2-Butoxyethoxy)ethanol 112-34-5
TWA: 10 ppm inhalable fraction and vapor
"
"
ACGIH (American Conference of Governmental Industrial Hygienists) OSHA (Occupational Safety and Health Administration of the
US Department of Labor) NIOSHIDLH Immediately Dangerous to Life or Health
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8.2. Appropriate Engineering Controls
Engineering controls
Showers Eyewash stations Ventilation systems.
8.3. Individual protection measures, such as personal protective equipment
Eye/Face Protection
Avoid contact with eyes. Tight sealing safety goggles.
Skin and Body Protection
Wear protective gloves and protective clothing.
Respiratory Protection
If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations.
Ventilation
Use local exhaust or general dilution ventilation to control exposure with applicable limits
8.4. General hygiene considerations Do not eat, drink or smoke when using this product. Handle in accordance with good industrial hygiene and safety practice.
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
Physical State Odor odor threshold
Liquid No data available No data available
Color
No data available
Property PH Melting point/freezing point Boiling point / boiling range Flash Point Evaporation Rate flammability (solid, gas) Flammability limit in air
Upper flammability limit: Lower flammability limit: Vapor Pressure Vapor Density Specific gravity Water Solubility Solubility in Other Solvents Partition coefficient Autoignition Temperature Decomposition Temperature Kinematic viscosity
VALUES No data available No data available No data available No data available No data available No data available
No data available No data available No data available No data available No data available No data available No data available No data available No data available No data available No data available
Remarks Method
10. Stability and Reactivity
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10.1. Chemical Stability Stable under recommended storage conditions.
10.2. Reactivity No data available
10.3. Possibility of hazardous reactions
None under normal processing.
hazardous polymerization
Hazardous polymerization does not occur.
10.4. Conditions to Avoid Extremes of temperature and direct sunlight. 10.5. Incompatible Materials Strong oxidizing agents. Strong acids. Strong bases.
10.6. Hazardous decomposition products Carbon oxides. Nitrogen oxides (NOx). Oxides of sulfur. Fluorinated oxides.
11. Toxicological Information____________________________
11.1. Information on Likely Routes of Exposure
Product information
no data available
INHALATION
no data available,
Eye Contact
no data available,
Skin contact
no data available,
INGESTION
no data available.
Acute Toxicity
Chemical name
2-(2-Butoxyethoxy)ethanol 112-34-5
Laurylamidopropyl betaine 4292-10-8
Octylphenoxypolyethoxyethanol 9036-19-5
Oral LD50
= 3384mg/kg (R a t)
> 2000 mg/kg ( Rat )
= 4190mg/kg (R a t)
dermal LD50
= 2700 mg/kg (R a b b it)
-
"
Inhalation LC50
-
-
"
11.2. Information on Toxicological Effects
Symptoms
No information available.
11.3. Delayed and immediate effects as well as chronic effects from short and long-term exposure
sensitization
No information available.
Germ Cell Mutagenicity
No information available
carcinogenicity
No information available.
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Reproductive Toxicity STOT - Single Exposure STOT - Repeated Exposure Aspiration Hazard
No information available. No information available. No information available. No information available.
11.4. Numerical Measures of Toxicity - Product information
The following values are calculated based on chapter 3.1 of the GHS document
ATEmix (oral)
12894 mg/kg
ATEmix (dermal)
14975 mg/kg
12. Ecological Information
12.1. ecotoxicitv
1.8456% of the mixture consists of components(s) of unknown hazards to the aquatic environment
Chemical name
Algae/aquatic plants
Fish
2-(2-Butoxyethoxy)ethanol
EC50 96 h > 100 mg/L
LC50 96 h = 1300 mg/L Lepomis
112-34-5
Desmodesmus subspicatus
macrochirus static
2-Methyl-2,4-pentanediol 107-41 -5
t-Butanol 75-65-0
EC50 72 h > 1000 mg/L Desmodesmus subspicatus
LC50 96 h 10500- 11000 mg/L Pimephales promelas flow-through LC50 96 h = 10000 mg/L Lepomis
macrochirus static LC50 96 h = 8690 mg/L Pimephales promelas flow-through LC50 96 h = 10700 mg/L Pimephales promelas static
LC50 96 h 61 30 -670 0 mg/L Pimephales promelas flow-through
Polyethylene Glycol 25322-68-3
Sodium chloride 7647-14-5
4,4'-bis-(sulfostyryl)-biphenyl disodium salt 27344-41-8
-
EC50 72 h = 10 mg/L Desmodesmus subspicatus EC50
96 h 1 0 .0-11 .0 mg/L Desmodesmus subspicatus
LC50 24 h > 5000 mg/L Carassius auratus
LC50 96 h 5560 - 6080 mg/L Lepomis macrochirus flow-through LC50 96 h = 12946 mg/L Lepomis macrochirus static LC50 96 h 6020 - 7070 mg/L Pimephales promelas
static LC50 96 h = 7050 mg/L Pimephales promelas semi-static
LC50 96 h 6420 - 6700 mg/L Pimephales promelas static LC50
96 h 4747 - 7824 mg/L Oncorhynchus mykiss flow-through
LC50 96 h = 76 mg/L Brachydanio rerio static
Crustacea
EC50 24 h = 2850 mg/L Daphnia magna EC50 48 h > 100 mg/L Daphnia magna EC50 48 h 2700 - 3700 mg/L Daphnia magna
EC50 48 h = 933 mg/L Daphnia magna EC50 48 h 4607 - 6577
mg/L Daphnia magna Static -
EC50 48 h = 1000 mg/L Daphnia magna EC50 48 h 340.7 - 469.2
mg/L Daphnia magna Static
EC50 48 h = 1000 mg/L Daphnia magna
12.2. Persistence and Degradability No information available.
12.3. Bioaccumulation No information available.
12.4. Other Adverse Effects No information available
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13. Disposal Considerations
13.1. Waste Treatment Methods Disposal of wastes
Contaminated Packaging
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Do not reuse container.
14. Transport Information
DOT TDG MEX ICAO (air) IATA IMDG
NOT REGULATED NOT REGULATED NOT REGULATED NOT REGULATED NOT REGULATED NOT REGULATED
15. Regulatory Information
15.1. International Inventories TSCA DSL/NDSL ENCS IECSC KECL PICCS AICS
Complies Does not comply Does not comply Does not comply Does not comply Does not comply Does not comply
Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances
15.2. US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
Chemical name
2-(2-Butoxyethoxy)ethanol -112-34-5
SARA 311/312 Hazard Categories Acute Health Hazard Chronic health hazard Fire Hazard Sudden Release of Pressure Hazard
SARA 313 - Threshold Values %
1.0
No No No
No
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Reactive Hazard
No
CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42)
CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material
15.3. US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals
U.S. State Riqht-to-Know Regulations
Chemical name
2-(2-Butoxyethoxy)ethanol 112-34-5
New Jersey X
Massachusetts "
Pennsylvania X
16. Other information, including date of preparation of the last revision
NFPA HMIS
Health Hazards 2 Health Hazards 2
flammability 0 flammability 0
Instability 0 Physical Hazards 0
Physical and chemical properties Personal Protection X
Revision date
10-0ct-2015
Revision note
No information available
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
End of Safety Data Sheet
Revision date 10-0ct-2015
Version 1 US00005558
