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Vapor Pressure Determination: 8-2 Telomer B Alcohol
DUPONT REPORT 12735 8-2 TELOMER B ALCOHOL, CyF;CH;COHH;: VAPOR PRESSURE
Test Guideline(s)
Authors MDaacryylPA.. CKoabisrearn,chPih,.DP.hD(s.tudy director)
Chin Ping Kao
Robert Buck, Ph.D.
1S6tuudlyyC2o0m0p2letion Date Report Date
21 March 2003
Test Facility DuPont Corporate Cte orAnalytical Sciences Experimental Siston 4025321 Wilmington, DE 19380-0402 Ana DuPont Center fo Engineering Research Experimental Saion 120 Wilnington, DE 19880-0320 Sponsor TcleoloRmaenrd RCeosrepaorrcahtiPoannel
=
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225 5 E2=5 5
2
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Vapor Pressure Determination: 8-2 Telomer B Alcohol
2 TABLE OF CONTENTS
TTaHbElePoIfEContcen.tsr.o..ttmssssssssns--m--ssssssssssesepssssssssspsms--s--s--nsoenn
1.0 Summary
--
2.0 General SOY INOTMAON
pr
------------------
vss
3.0 MAErls 0 MEtNOUS ccs
3.1 TS GUIGENES rn 3.2 ChEMCH] SYS corres
mssm-- oS
33 TES VECIE rrr 3.4 PATAMELETS OBSEIVE cosmos
3.5 3.6
RValEidSitUy ICrLiteAriBa OBFIthYe SSNIASY .v snssse ssnsn nsnsst neness oesno
4.0 Resultsand DISCUSSION... 5.0 CONGIUSIONS vss
weal wean s----------_l
6.0 7.0.
RELEDO OFRECON corso
DisOpf ToestsLeam.l ..........oc.ooee
onion pn
ees] Mc
Figures
----
Figure Figure
1 2
Scott Method APPARBIUS.......v.oro VaporPressure: 8:2 TElomer B
roosters enero AICOROL.............occccocvrrrverrrrerr rr
8
Table Tabl1e.VaporPressure Values
............c.cccuverrrerrroor
rtmsssarsnd
Appendix Appendix A Chemical Analysis
SUm ay. . . . . . . . .
rrr
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Vapor Pressure Determination: 8-2 Telomer B Alcohol
8-2 TELOMER B ALCOHOL, CgF;;CH,;CH,OH: VAPOR PRESSURE
MAutyhoAr.sKaiser, PD. (study dict) Daryl. Cobras, AD. RobCBueck,rPh Chi Ping Kao
1.0
SUMMARY
Test Sys:
h8-k2 TEerloomnetr sp Ch B Alcohol, CsF1;CH;CH;OH, was used to determine itsvapor
Findings:
The vapor pressure 1 23C is sprovimatly 3 Pa (0022 Tor
Conclusions: The vapor pressureof 2 Tlomer B alcohol ranged fom 3 Pa at 23C to
101kPaat 201C.
20
GENERAL STUDY INFORMATION
Study Objectives
c`Tohheooblj,ecCtilveosfCHth,isCsHtOudHy,wuansdetorddeetfeirnmedinceontdhietviaopnsorbpereesesunre2o5fC8-42nTde2lo0m0er B heTteetw sSyysstteemmwJuasstidfeitceatmiionned by he sprsor Study Personnel
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Vapor Pressure Determination: 8-2 Telomer B Alcohol
Management Study Director: Principle Investigator: Technical Personnel:
Marianne Marsi, Ph.D. Mary A. Kaiser, Ph.D. Daryl P. Cobranchi, Ph.D. Barry W. Wolstenholme
Study Execution Dates Study Initiation Date: Experimental Start Date: Experimental Completion Date: Study Completion Date:
15-Jun-2001 15-Jun-2001 28-June 2002 12-3uly 2002
3.0 MATERIALS AND METHODS
31 Test Guidelines
o"rThleviqaupidorspurbesstasnucree.oAftatshuebrsmtoadnycneaimsidcefeiqnueidlaisbrithuem,stahteurvaatpioornpprreessssuurree ais bonloaysvao. leid
(fPuan,ctNieowntoofn/tme'm)pe,raUtnuirtes. whTihcehShIauvneitboefepnreesmspulroeyewdhihcihstosrhiocualldlybaereus1eTdoirsrt(hemPmasHcga)l
=1.33 x 10 Pa; | atmosphere Guideline 104 (modificd) was
= 1.013 x 10 used for this
mPeaa;s|urbeamre=nt1.0
Pa.
A modified OECD
321 Chemical System
3.211 TestSubstance
"The est substance was obtained fom Clariant Gribh (Germany) and was shown t be 99.2% pure via gas
`chromatography. No other alcohol or iodide is tentatively identified asCF,CF=CH;OH
impurities were detected. buscd on the mass spectral
The major impurity (0.8% fragmentation pattem
by
arcs)
Name:
82 Telomer B Alcohol
Synonym:
(PerfluorooctyDethanol
Active substance(s)
8:2 Telomer B Alcohol, 9.2%
CAS Name:
I-Decanol,
h3e3p,t4a,de4c5a,f5l6uo,r6o7-78899,10,10,10-
CAS Number(s):
678397
4Telomer Research Program
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Vay Structure:
sure Determination: 8-2 TelomerB Alcohol
F
F
OH
F
FR
F
r
F
e
F
F
F
.
F
\
F
F FF
H Number Lot Number: EMSE Sample Number Concentration, nominal Concentration, analyzed: Certificateof Analysis Date: Date Received: Solubility at 25C... Vapor pressure: Stability: Appearance/Color Storage Conditions:
H-24691 P.00001 E93386.63 99% 99.2% 03-Apr. 2001 15-June -2001 "140 gL TBD via this report Stable at ambient room temperature. `White solid Room temperature; keep tightly closed
3212 Test Vehicle `The test substance was the 8_2 TelomeBr alcohol,
33 Test Conduct
d`Tywnoamtiecchmnieqauseusrewmeernetuspedrtoo cobieabidynSutchreotevtapwohreprreestshueree.quiTlhiebrfiirusmt
method was temperature
basedon a is measured
at
a
controlled pressure. was held constant 0
0Ap.p0r1o%xi(0m.a0t1eKlkyPa3)0angdrammesaosfuarlecdothoolanwaacscuprlaaccyedoifn a0.b0o1i%l.er.ThTehaeppparreastsuusr.e
WcoAns)is7t4e0dopfreassMuernestorran(sSdaucneMr,aracnosda, HTaXr)t PScCiSen4t0i0fipcr(eAsmsuerreiccaonntrFoolrlterU,Ta)Pasrtoascckiebnatsiefiucni(tRfeodrmond,
STelomer Research Program
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Vapor Pressure Determination: 8:2 Telomer B Alcohol
atpepmapreartautsuries gmievaesnurienmFeingtu.reT2h.eTatbelmepe1rasthuorwesvathreieidndfirvoimdu8al0d0at2a00poCi.ntsA diagramof the second p`rTohceesdcucroenidspirnotceenddeudre10wcaosnbfaisremdtohen ltihneeaErPitAyoOftPheTcSugravse osabttuarianteidoanttmehtehohdi'g.heTrhis ttuebme.perGaatsu-recshrformoamtotghreaSpchoittc mgertahdoedh.elTihume(a9l9c.o9o9l9%w)asflpolwaeceddodvierrectthleypionwadegrl.assTthheerfmlooswtawtaesd gcaosncthrroomlabtlyoegadrafplho.w cDounctrotloltehreoandsaorHpetwilveettprPoapecrktairedso(fnotwheAgalicloehnotl,,LtihtelevaFpalolrs,prDeEs)surmeodweasl.$890 vcaalpcourlaptreedssfurroematwe2i1ghCt wloasssra0t.0h2eTrotrrh.an Ffirogmurt3ehegwieveisghthoeftvraapporpepdremsastuerreiaclurdvoewnosbtlraeianme.d fTrhoe.m both setsofmeasurements. 33 Parameters Observed
With the Scott apparatus, pressure and temperature are observed, With the GC/MS apparatus, peak height and peak area are observed. 34 ResultAnalysis pWairtahmethteerGCo/faMSstaapnpdaarradtcuasretfhuelpyeparkephaerigehdtionrmeartehaanioslc.ompared to the same 35 Validity Criteria of the Study cFoomrpGarCe/dM.STthhee rpeesaukltasrmeaussotfasgtraenedwairtdhsirnu5n%b.efore and after the test subsiance are
4.0
RESULTS AND Discussion
2`T1hevtaCopo1r01prkePsas:uarte 2o0f1thCe. TeThleomreeBsrus8-f2raolmctohheosvianrgileedpocionnttitnaukoeunsalty2f1roCmw3ePraea.t
tahleigSnceodttwimtehthtohde.results from the 11 points taken at elevatedtemperatures taken by
50 CONCLUSIONS
`The vapor 21C.
pressureofthe
Telomer
B
8-2alcohol
is
3
Pa
at
21C
and
101kPaat
6.0 RETENTION OF RECORDS
ESxtpuedryidmoecnutmalenSttsatainond imnactleurdiianlgs bwiultlnboet sltiomrietdeditno:the archivesofthe DuPont study protocol; any protocol and/or report amendments or addenda or deviations;
allraw da; one original signed copyofthe final report;
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Vapor Pressure Determination: 8-2 Telomer B Alcohol
*
laboratory-specific refrigerator, and/or
or site-specific raw freezer raw data
data
suchaspersonnel
files,
instrument,
equipment,
7.0 DispOSAL OF TEST Item DAfutPeornitssGulaanscegoofwtshiet fuinntaillrietpsoerxt,pitrhaetiroenmdaaitneinagndtetshtesnubdsetsatnrcoeyweidlblybbeusmtionrged, autnltheess other amangemareenmatdse between the sponsor and the Test Facility.
8.0 REFERENCES 1. DL.iaSgcrotatm,"",DFetueirdmiPnhaatsieonEoqufilAicbtriviiutmy,C2o6e,f(f1i9c8i6e)n,tsb14y9-1A6c3c.urate Measurementof Boiling Point 2. (U7n1i0t1e)d, SOtPatPeTs SEn8v3i0r.o7n9m5e0n,taVlapPorortPercetsisounreA,geAnucgyu,stPre1v99e5n,tipoan,gePe4s,tGiacisdeSsataunrdatTiooxniMcetShuobsdt.ances.
7Telomer Research Program
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Vapor Pressure Determination: 8:2 Telomer B Alcohol Figure 1. Scott Method Apparatus
Boiler
<$ [7
[a [ =|
oe wd I
BE] fwooe
sed)1 Ed
STelomer Research Program
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Vapor Pressure Determination: 8-2 Telomer B Alcohol
Figure 2. Vapor Pressure: 8-2 Telomer B Alcohol
10 ra
lt c
sm. me 13392897 4.25926
[A]TH A]
sii
gw
I=
2i 100
pd
<82.1 4;
10? Bem he ih a eee
Temperature (C)
Table 1. Vapor Pressure Values
[Temperature (C)] Vapor Pressure (Torr) Vapor Pressure (Pa)
Method
|
21
0022
a
`Gas Saluration Method
Ta
5
en]
708
Scott Method
1
65 | ScotMethed|
"M07
21 | 214 |ScoiMethod
119 f 130
oo 37 | 4810 | ScottMeihod
62
| 8284
Scott Method
T id E bw ul bm od TSoonstao [a2
T
103
[en
Tiree | ~ ScoftMethod T2752 | ScoiMethed
|
179
Tis
388
Ts
51667
723% |
~ Scott Method
ScoliMethod
wm
755
| 100607
"Scot Method
sms Tsasnn rgn
.
000027
Vapor Pressure Determination: 8-2 Telomer 8 Alcohol
Appendix A 2-PerfluCohreoomcitcyalleAtnhaalnyosli:sCSguFm1m7aCrHy,CH2OH H-24691
Analysis Summary
msattaenrdiaarTldhcemoemstpuhrbijoesdcettdom9aa9tse.sr2ei%saslofiwtatshsceoamsnpuaoblsjiyetcziteodmna.btyeTrhigiaalss.-acnTahlhryeosmibasatlsoaghnrocaewp,ehd0y.tu8hs%ai,tntwghaaas not w0a.nh0oo2ts%he.erchFTeuermltiohcmeaerlrasnBtarlauylcsctiouhsroebli,ysoGCrC7T/eFMl1So5mseCurFg=gBeClsHotCdsiHtdOheaHat.ttaheli0mi.t8o%f iqsuaantsiitnagtlieoinmopufrity,
pCehrrfolmuoarFtoionoagcltrlyayl,psytuhl-efToSnauinbcjdeaecctmidmMaaatnesdrsipaSelprfewlcautsorroeomvoeactltruanyaot(iecLdCab/cyiMdSH/iagtMahS)PdeefortrefcotthriemoapnnrlceiesmietLniocqfeuiodf 0.1ppm. Neither material was observed to be present.
determiBnaeseadnducpoonnfitrhmesteheancaolmypsoessi,tiwoen cofonHc-l2u4d6e9t1hattombeetahsodfsolalorwes:in hand to
Material CgF17CH2CH0H 2-Perfluorooctyl ethanol
WE. % (+0.3) 99.2
C7F15CF=CHCH0H
08
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