Document Jr8n64MvVkrKzwaX1qXv3ynjX

+-- - - - - - - - - - ------- -- -- -- -------- -------- " -- ---- -- ---- -- -- " -- -- " -- " ~ -- + Date Printed: 08-15-1996 Page 1 LA-MAR-KA MSDS for KARL FISCHER REAGENT --------------------------------------------------------------------------------------------------------------------------------------------------------------- + 1 -PRODUCT IDENTIFICATION PRODUCT NAME: COMMON SYNONYMS: CHEMICAL FAMILY: FORMULA: FORMULA WT.: CAS NO.: NIOSH/RTECS NO. : PRODUCT USE: KARL FISCHER REAGENT N/A VOLUMETRIC SOLUTIONS AND CONCENTRATES N/A N/A N/A N/A LABORATORY REAGENT CHEMTREC # (800) 424-9300 LA-MAR-KA, INC. 10272 SOUTH PERDUE STREET BATON ROUGE, LA. 70814 EFFECTIVE: 01/29/90 REVISION #06 ISSUED: 04/14/90 REVIEWED 1-1-95 PRECAUTIONARY LABELING LA-MAR-KA LABELING SYSTEM HEALTH 3 SEVERE (LIFE) FLAMMABILITY 2 MODERATE REACTIVITY 1 SLIGHT CONTACT 3 SEVERE (LIFE) .LABORATORY PROTECTIVE EQUIPMENT GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD; PROPER GLOVES; CLASS B EXTINGUISHER U.S. PRECAUTIONARY LABELING DANGER CAUSES BURNS. COMBUSTIBLE. OVEREXPOSURE MAY CAUSE MALE OR FEMALE REPRODUCTIVE DISORDERS. EXCEPTIONAL HEALTH AND CONTACT HAZARDS: READ MATERIAL SAFETY DATA sheet KEEP AWAY FROM HEAT, SPARKS, FLAME. DO NOT GET IN EYES, ON SKIN, ON CLOTHING. AVOID BREATHING VAPOR. KEEP IN TIGHTLY CLOSED CONTAINER. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. IN CASE OF FIRE, USE WATER SPRAY, ALCOHOL FOAM, DRY CHEMICAL, OR CARBON DIOXIDE. FLUSH SPILL AREA WITH WATER SPRAY. PRECAUTIONARY LABELING (CONTINUED) INTERNATIONAL LABELING AVOID CONTACT WITH EYES. AFTER CONTACT WITH SKIN, WASH IMMEDIATELY WITH PLENTY OF WATER. KEEP CONTAINER TIGHTLY CLOSED. DO Cq,\'f A 06074 Td^Ntta; +------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------ + . Date Printed: 08-15-1996 Page 2 LA-MAR-KA MSDS for KARL FISCHER REAGENT 1 -PRODUCT IDENTIFICATION (continued) LA-MAR-KA STORAGE COLOR CODE: RED (FLAMMABLE) 2 -COMPONENTS COMPONENT 2-METHOXYETHANOL PYRIDINE METHANOL IODINE-SULFUR DIOXIDE COMPLEX CAS NO. 109-86-4 110-86-1 67-56-1 N/A WEIGHT % 25-35 10-20 25-40 20-30 OSHA/PEL 25 PPM 5 PPM 200 PPM N/E ACGIH/TLV 5 PPM 5 PPM 200 PPM N/E 3 -PHYSICAL DATA BOILING POINT: N/A VAPOR PRESSURE (MMHG): N/A MELTING POINT: N/A VAPOR DENSITY (AIR=1): N/A ''ECIFIC GRAVITY: 0.93 (H20=l) EVAPORATION RATE: N/A SOLUBILITY(H20): COMPLETE (100%) % VOLATILES BY VOLUME: 100 (21 C) PH: N/A ODOR THRESHOLD {P.P.M.): N/A PHYSICAL STATE: LIQUID COEFFICIENT WATER/OIL DISTRIBUTION: N/A APPEARANCE & ODOR: DARK BROWN LIQUI i. DISAGREEABLE ODOR. 4 -FIRE AND EXPLOSION HAZARD DATA FLASH POINT (CLOSED CUP): 37 C (100 F) AUTOIGNITION TEMPERATURE: N/A FLAMMABLE LIMITS: UPPER - N/A LOWER - N/A FIRE EXTINGUISHING MEDIA USE WATER SPRAY, ALCOHOL FOAM, DRY CHEMICAL OR CARBON DIOXIDE. D0 A 060743 confidential +----------------------- ----------------------- H Date Printed: 08-15-1996 Page 3 LA-MAR-KA MSDS for KARL FISCHER REAGENT ----------------------------------------------------------------------------------------------------------------------------------------------------------------+ 4 -FIRE AND EXPLOSION HAZARD DATA (continued) SPECIAL FIRE-FIGHTING PROCEDURES FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE. MOVE CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK. USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL. UNUSUAL FIRE & EXPLOSION HAZARDS VAPORS MAY FLOW ALONG SURFACES TO DISTANT IGNITION SOURCES AND FLASH BACK. CLOSED CONTAINERS EXPOSED TO HEAT MAY EXPLODE. CONTACT WITH STRONG OXIDIZERS MAY CAUSE FIRE. TOXIC GASES PRODUCED SULFUR DIOXIDE, OXIDES OF NITROGEN EXPLOSION DATA-SENSITIVITY TO MECHANICAL IMPACT NONE IDENTIFIED. EXPLOSION DATA-SENSITIVITY TO STATIC DISCHARGE NONE IDENTIFIED. -HEALTH HAZARD DATA THRESHOLD LIMIT VALUE (TLV/TWA): 16 MG/M3 (5 PPM) TLV IS FOR PYRIDINE. SHORT-TERM EXPOSURE LIMIT (STEL): NOT ESTABLISHED PERMISSIBLE EXPOSURE LIMIT (PEL): 15 MG/M3 (5 PPM) PEL IS FOR PYRIDINE. TOXICITY OF COMPONENTS ORAL RAT LD50 FOR 2-METHOXYETHANOL INTRAPERITONEAL RAT LD50 FOR 2-METHOXYETHANOL SKIN RABBIT LD50 FOR 2-METHOXYETHANOL INHALATION-7HR MOUSE LC50 FOR 2-METHOXYETHANOL ORAL RAT LD50 FOR PYRIDINE INTRAPERITONEAL RAT LD50 FOR PYRIDINE SUBCUTANEOUS RAT LD50 FOR PYRIDINE SKIN RABBIT LD50 FOR PYRIDINE ORAL RAT LD50 FOR METHANOL INTRAPERITONEAL RAT LD50 FOR METHANOL SUBCUTANEOUS MOUSE LD50 FOR METHANOL SKIN RABBIT LD50 FOR METHANOL 2460 MG/KG 2500 MG/KG 1280 MG/KG 1480 PPM 891 MG/KG 866 MG/KG 1000 MG/KG 1121 MG/KG 5628 MG/KG 9540 MG/KG 9800 MG/KG 20 G/KG DO A 060744 CONFIDENTIAL ---------------------------------------------------------------------------------------------------------------------------------------------------------------------- -- LA-MAR-KA MSDS for KARL FISCHER REAGENT Date Printed: 08-15-1996 Page 4 5 -HEALTH HAZARD DATA (continued) CARCINOGENICITY: NTP:: NO IARC: NO Z LIST: NO OSHA REG: NO CARCINOGENICITY NONE IDENTIFIED. REPRODUCTIVE EFFECTS IN TESTS WITH LABORATORY ANIMALS, EXPOSURE TO 2-METHOXYETHANOL HAS RESULTED IN AN INCREASE IN BIRTH DEFECTS, ADVERSE EFFECTS ON PREGNANCY, EMBRYONIC DEATH, BLOOD DAMAGE AND DAMAGE TO MALE REPRODUCTIVE ORGANS. ACCEPTABLE MAXIMUM EXPOSURE LIMIT FOR WOMEN OF CHILDBEARING AGE = 2 PPM HR TIME-EIGHTED AVERAGE). (8 EFFECTS OF OVEREXPOSURE INHALATION: NAUSEA, VOMITING, HEADACHE, UNCONSCIOUSNESS, COUGHING, DIFFICULT BREATHING SKIN CONTACT: BURNS EYE CONTACT: BURNS SKIN ABSORPTION: NONE IDENTIFIED INGESTION: GASTROINTESTINAL IRRITATION, CONVULSIONS CHRONIC EFFECTS: KIDNEY DAMAGE, LIVER DAMAGE, DAMAGE TO BLOOD FORMING TISSUE TARGET ORGANS EYES, SKIN MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE NONE IDENTIFIED PRIMARY ROUTES OF ENTRY EYE CONTACT, SKIN CONTACT, INHALATION, INGESTION EMERGENCY AND FIRST AID PROCEDURES INGESTION: CALL A PHYSICIAN. IF SWALLOWED, DO NOT INDUCE VOMITING. IF CONSCIOUS, GIVE LARGE AMOUNTS OF WATER. INHALATION: IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. SKIN CONTACT: IN CASE OF CONTACT, IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. WASH CLOTHING BEFORE RE-USE. DO A 060745 CONFTDFNTT AI H---------- ------------------------------------------------------------------------------------------------------------------------------------------------------------ 1- Date Printed: 08-15-1996 Page 5 LA-MAR-KA MSDS for KARL FISCHER REAGENT ----------------------------------------------------------------------------------------------------------------------------------------------------------------+ 5 -HEALTH HAZARD DATA (continued) EYE CONTACT: IN CASE OF EYE CONTACT, IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. SARA/TITLE III HAZARD CATEGORIES AND LISTS ACUTE: YES CHRONIC: YES FLAMMABILITY: YES PRESSURE: NO REACTIVITY: NO EXTREMELY HAZARDOUS SUBSTANCE: NO CERCLA HAZARDOUS SUBSTANCE: YES CONTAINS PYRIDINE (RQ = 1000 LBS) AND METHANOL (RQ = 5000 LBS) SARA 313 TOXIC CHEMICAL,S: YES CONTAINS METHANOL, 2-METHOXYETHANOL, AND PYRIDINE GENERIC CLASS: C05, C06, Cll TSCA INVENTORY: YES STATE LISTS: FOR PRODUCTS SOLD IN THE STATE OF CALIFORNIA, THE STATE REQUIRES THAT WE PROVIDE TO USERS AND THEIR EMPLOYEES THE FOLLOWING MESSAGE: WARNING: THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE BIRTH DEFECTS AND OTHER REPRODUCTIVE HARM. -REACTIVITY DATA STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR CONDITIONS TO AVOID: HEAT, FLAME, SOURCES OF IGNITION INCOMPATIBLES: WATER, STRONG OXIDIZING AGENTS, STRONG BASES, ORGANIC MATERIALS, CAUSTICS DECOMPOSITION PRODUCTS: OXIDES OF SULFUR, OXIDES OF NITROGEN, IODINE 7 -SPILL & DISPOSAL PROCEDURES STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING. SHUT OFF IGNITION SOURCES; NO FLARES, SMOKING OR FLAMES IN AREA. STOP LEAK IF YOU CAN DO SO WITHOUT RISK. USE WATER SPRAY TO REDUCE VAPORS. TAKE UP WITH SAND OR OTHER NON-COMBUSTIBLE ABSORBENT MATERIAL AND PLACE INTO CONTAINER FOR LATER DISPOSAL. FLUSH AREA WITH WATER. DISPOSAL PROCEDURE DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL ENVIRONMENTAL REGULATIONS. Do A 060746 conftdfnttai ------------------------------------------------------------------------------------------------------------------------------------------------------------------------- Date Printed: 08-15-1996 Page 6 LA-MAR-KA MSDS for KARL FISCHER REAGENT ------------------------------------------------------------------------------------------------------------------------------------------------------------------ 7 -SPILL Sc DISPOSAL PROCEDURES (continued) EPA HAZARDOUS WASTE NUMBER: U196 (TOXIC WASTE) 8 -INDUSTRIAL PROTECTIVE EQUIPMENT VENTILATION: USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP VAPOR AND MIST LEVELS AS LOW AS POSSIBLE. RESPIRATORY PROTECTION: NONE REQUIRED WHERE ADEQUATE VENTILATION CONDITIONS EXIST. IF AIRBORNE CONCENTRATION IS HIGH, A CHEMICAL CARTRIDGE RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE IS RECOMMENDED. IF CONCENTRATION EXCEEDS CAPACITY OF CARTRIDGE RESPIRATOR, A SELF-CONTAINED BREATHING APPARATUS IS ADVISED. EYE/SKIN PROTECTION: SAFETY GOGGLES AND FACE SHIELD, UNIFORM, PROTECTIVE SUIT, BUTYL RUBBER GLOVES ARE RECOMMENDED. -STORAGE AND HANDLING PRECAUTIONS LA-MAR-KA STORAGE COLOR CODE: RED (FLAMMABLE) STORAGE REQUIREMENTS KEEP CONTAINER TIGHTLY CLOSED. STORE IN A COOL, DRY, WELL-VENTILATED, FLAMMABLE LIQUID STORAGE AREA OR CABINET. 10 -TRANSPORTATION DATA AND ADDITIONAL INFORMATION DOMESTIC (D.O.T.) PROPER SHIPPING NAME: COMBUSTIBLE LIQUID, N.O.S. HAZARD CLASS: COMBUSTIBLE LIQUID UN/NA: NA1993 LABELS: NO LABEL REQUIRED UNDER 110 GALLONS REGULATORY REFERENCES: 49CFR 172.101; 173.118A (KARL FISCHER REAGENT) INTERNATIONAL (I.M.O.) PROPER SHIPPING NAME: FLAMMABLE LIQUIDS, POISONOUS, N.O.S. (KARL FISCHER REAGENT) HAZARD CLASS: 3.2 I.M.O. PAGE: 3084 UN: UN1992 MARINE POLLUTANTS: NO PACKAGING GROUP: II 060747 DO A dfnttal CONFt `LA-MAR-KA MSDS for KARL FISCHER REAGENT Date Printed: 08-15-1996 Page 7 10 -TRANSPORTATION DATA AND ADDITIONAL INFORMATION (continued) LABELS: FLAMMABLE LIQUID, POISON REGULATORY REFERENCES: 49CFR 172.102; PART 176; IMO AIR (I.C.A.O.) PROPER SHIPPING NAME: FLAMMABLE LIQUIDS, POISONOUS, N.O.S. (KARL FISCHER REAGENT) HAZARD CLASS: 3.2 UN: UNI992 PACKAGING GROUP: II LABELS: FLAMMABLE LIQUID, POISON REGULATORY REFERENCES: 49CFR 172.101; 173.6; PART 175; ICAO/IATA U.S. CUSTOMS HARMONIZATION NUMBER: 38220000000 N/A = NOT APPLICABLE OR NOT AVAILABLE N/E = NOT ESTABLISHED THE INFORMATION IN THIS MATERIAL SAFETY DATA SHEET MEETS THE REQUIREMENTS OF THE UNITED STATES OCCUPATIONAL SAFETY AND HEALTH ACT AND REGULATIONS PROMULGATED THEREUNDER (29 CFR 1910.1200 ET. SEQ.) AND THE CANADIAN WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM. THIS DOCUMENT IS INTENDED ONLY AS A TIDE TO THE APPROPRIATE PRECAUTIONARY HANDLING OF THE MATERIAL BY A PERSON 'AINED IN, OR SUPERVISED BY A PERSON TRAINED IN, CHEMICAL HANDLING. THE USER RESPONSIBLE FOR DETERMINING THE PRECAUTIONS AND DANGERS OF THIS CHEMICAL FOR HIS OR HER PARTICULAR APPLICATION. DEPENDING ON USAGE, PROTECTIVE CLOTHING -INCLUDING EYE AND FACE GUARDS AND RESPIRATORS MUST BE USED TO AVOID CONTACT WITH MATERIAL OR BREATHING CHEMICAL VAPORS/FUMES. EXPOSURE TO THIS PRODUCT MAY HAVE SERIOUS ADVERSE HEALTH EFFECTS-- THIS CHEMICAL MAY INTERACT WITH OTHER SUBSTANCES. SINCE THE POTENTIAL USES ARE SO VARIED, LA-MAR-KA CANNOT WARN OF ALL OF THE POTENTIAL DANGERS OF USE OR INTERACTION WITH OTHER CHEMICALS OR MATERIALS. LA-MAR-KA WARRANTS THAT THE CHEMICAL MEETS THE SPECIFICATIONS SET FORTH ON THE LABEL. * LA-MAR-KA DISCLAIMS ANY OTHER WARRANTIES, EXPRESSED OR IMPLIED, WITH REGARD TO THE PRODUCT SUPPLIED HEREUNDER, ITS MERCHANTABILITY OR ITS FITNESS FOR A PARTICULAR PURPOSE. THE USER SHOULD RECOGNIZE THAT THIS PRODUCT CAN CAUSE SEVERE INJURY AND EVEN DEATH, ESPECIALLY IF IMPROPERLY HANDLED OR THE KNOWN DANGERS OF USE ARE NOT HEEDED. READ ALL PRECAUTIONARY INFORMATION. AS NEW DOCUMENTED GENERAL SAFETY INFORMATION BECOMES AVAILABLE, LA-MAR-KA WILL PERIODICALLY REVISE THIS MATERIAL SAFETY DATA SHEET. APPROVED BY LA-MAR-KA, INC. DO A 060748 CONFIDENTIAL LA-MAR-KA MSDS for KARL FISCHER REAGENT Date Printed: 08-15-1996 Page 8 10 -TRANSPORTATION DATA AND ADDITIONAL INFORMATION (continued) A 060749 CONFIDENTIAL