Document Jez45vJabZaVqwX4vxLOyooe

Material Safety Data Sheet Emergency Medical Telephone (800) 441-3637 (conoco CLARIFIED OIL, SLURRY OIL I. MATERIAL IDENTIFICATION Name Clarified Oil, Slurry Oil CAS Registry Number Mixture; Section XI Synonyms Catalytic Cracked Clarified Oil; FCC Clarified; FCC Slurry Product Code 0585/1072 Chemical Family Petroleum Hydrocarbons Transportation Emergency Phone 1.(800) 424-9300 (Chemtrec) IL OSHA HAZARD DETERMINATION The material is hazardous as defined by OSHA's Hazard Communication Standard, 29 CFR 1910.1200. Refer to Section XI of this MSDS for federal and state regulatory information. Hazardous Ingredients CAS Registry Number Clarified Oil 64741-62-4 (Contains approximately 10% Polynuclear Aromatic Hydrocarbons) Concentration 100% Hazardous Physical Properties None HL PHYSICAL DATA Appearance and Odor Black, viscous liquid; Petroleum odor Specific Gravity (HaO * 1) 1.03 - 1.12 Distillation Range >650*F % Volatiles (by volume) Nil Vapor Pressure Nil Solubility In Water Nil Vapor Density (Air 1.0) Not Applicable Evaporation Rato Nil IV. REACTIVITY DATA Stable: X Unstable:____ Hazardous Decomposition Materials: Hazardous gases/vapors produced are oxides of carbon, sulfur and nitrogen. Conditions to Avoid: Strong oxidizing materials, heat, flame. Hazardous Polymerization: Will not occur. RESCOOIZ/February 1989 1 Conoco Inc., P.O. Box 2197, Houston, TX 77252 General Information No. (713) 293-5550 MCD 000022969 V. FIRE AND EXPLOSION HAZARD DATA Flash Point (Method used): >200F fFMCO Handle and store in accordance with NFPA procedure for Class mil Combustible Liquid. Extinguishing Media: Use water spray, dry chemical, C02 foam. Special Fire Fighting Procedures: Use water to keep fire-exposed containers cooL If leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures. Unusual Fire and Explosion Hazards: Do not heat above flash point Products of combustion may contain carbon monoxide, carbon dioxide and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratoiy protection. National Fire Protection Association fNFPAl Classification Health 0 Fire 1 Reactivity 0 HAZARD RATING Least-0 Slight-1 Moderate-2 High-3 Extreme-4 VL TRANSPORTATION AND STORAGE Storage Conditions: Store in accordance with National Fire Protection Association regulations. Shipping Information: DOT: Not Regulated IATA/IMO: Not Restricted VIL HEALTH HAZARD INFORMATION PEL: Not Established* TLV: Not Established* Du Pont AEL: Not Established Ceiling Values Not Established. Refer to Coat Tar Pitch Volatiles; 0.2 mg/m3 Primary Routes of Exposure/Entry: Skin, inhalation. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Mouse skin painting studies have shown that petroleum distillates having a boiling point above 700F, and which are similar to ingredients in this product, caused skin tumors. Rat skin painting 90-day studies have shown a clarified slurry oil to cause liver damage and death at doses as law as 8 mg/kg/day. Cabazole derivatives are thought to be the chemical component causing the liver damage. The product may cause irritation to eyes, lungs or skin after prolonged or repeated contact Intermittent or occasional skin contact with the material is not expected to have serious health effects as long as good personal hygiene measures, such as those outlined in this material safety date sheet are followed. Listed as Carcinogen or Potential Carcinogen by: Material NT? No IARC No OSHA No * Components-- Polynuclear Aromatic Hydrocarbons, i.e., benzo(a)pyrene Yes Yes No RESC0012/February 1989 2 MCD 000022970 VHL IX X EMERGENCY AND FIRST AID INFORMATION Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Call a physician. Skin: Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If irritation develops, consult a physician. If exposed to hot material, immediately cool with cold water. Do not attempt to remove material but continue to cool exposed areas and seek medical assistance immediately. Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. Ingestion: If swallowed, do not induce vomiting. Give large quantities of water. Never give anything by mouth to an unconscious person. Call a physician. If vomiting begins, lower victim's head in an effort to prevent vomitus from entering lungs. SPILL, LEAK AND DISPOSAL INFORMATION In Case of Spill or Leak: Contain spill immediately in smallest possible area. Allow hot oil to cool. Recover as much product as possible by such methods as vacuuming or, if in semisolid state, by mechanical means. Residual fluid should be recovered by using absorbent materials. Nonrecoverable product, contaminated soil, debris and other materials should be placed in proper containers for ultimate disposal. Avoid washing, draining or directing material to storm or sanitary sewers. NOTE: Review FIRE AND EXPLOSION HAZARDS before proceeding with clean up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean up. Waste Disposal Method: Recycle as much of the recoverable product as possible. Treatment, storage, transportation and disposal must be in accordance with applicable Federal, State/Provincial, and Local regulations. PRECAUTIONARY MEASURES Respiratory Protection: Select appropriate NIOSH-approved respiratory protective equipment when exposed to oil sprays or mists. Proper respirator selection should be determined by adequately trained personnel and based on the contaminant(s), the degree of potential exposure and published respirator protection factors. Ventilation: Normal ventilation. Protective Gloves: Should be worn when any potential exists for skin contact Use insulated gloves where material is being handled hot NBR or neoprene recommended. Eye Protection: Chemical goggles when exposed to oil sprays and mists or if splashing is probable. Face shield is recommended where material is handled hot and splashing may occur. Additional Protection: Coveralls if splashing is probable. Other Precautions: Skin contact should be Clean exposed skin with waterless band cleaner followed by soap and water. Complete protective clothing if material is being handled hot Launder or discard contaminated clothing. Discard extremely contaminated leather shoes.* RESC0012/February 1989 3 *CD oo229?1 XI. REGULATORY INFORMATION FEDERAL REGULATIONS CERCIA, 40 CFR 261 and 302 The material contains the following hazardous substance which, when released in quantities equal to or exceeding the Reportable Quantity, triggers National Response Center notification requirements. Hazardous Substance Not Applicable Reportable Quantity SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986, TITLE III SECTIONS 302, 304, 311, 312, 313 SECTION 302/304 Extremely Hazardous Substances (40 CFR 355) The material does not contain extremely hazardous substances at greater than 1.0% concentration; however, it is possible that this material may contain extremely hazardous substances at a lower concentration so that a large enough spill could warrant an Emergency Release Report under Section 304. SECTION 311/312 - MSDS and Chemical Inventory Reporting Requirements (40 CFR 370) The material should be reported under the following EPA hazard categories: x Immediate (Acute) Health Hazard x Delayed (Chronic) Health Hazard __ Fire __ Sudden Release of Pressure __ Reactive __ Not Applicable NOTE: See Section II for the concentration of any ingredients classified as hazardous by OSHA. SECTION 313 - List of Toxk Chemicals (40 CFR 372) The material contains the following chemical(s) at a level of 1.0% or greater (0.1% for carcinogens) on the list of Toxic Chemicals and is subject to toxic chemical release reporting requirements. Toxic Chemical None CAS Registry Number Approx. Concentration (Upper Bound) _ TOXIC SUBSTANCES CONTROL ACT (TSCA), 40 CFR 710 This material is a mixture as defined by TSCA. The chemical ingredients in this material are in Section 8(b) Chemical Substance Inventory and/or are otherwise in compliance with TSCA In the case of ingredients obtained from other manufacturers, Conoco relies on the assurance of responsible third parties in providing this statement RESOURCE CONSERVATION AND RECOVERY ACT (RCRA), 40 CFR 261, SUBPART C AND D The material, when discarded or disposed of, is not specifically listed as a hazardous waste in Federal regulations; however, it could be considered hazardous if it meets criteria for being toxic, corrosive, ignitable or' reactive according to U.S. EPA definitions (40 CFR 261). Additionally, it could be designated as hazardous according to state regulations. This material could also become a hazardous waste if it is mixed with or comes in contact with a listed hazardous waste. If such contact or mixing occurs, check 40 CFR 261 to determine whether it is a hazardous waste. If it is a hazardous waste. Regulations 40 CFR 262, 263, 264 and 268 may apply. RESC0012/Februaiy 1989 4 MCD 000022972 V FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15, 40 CFR 110 The material contains the following ingredients) which is considered hazardous if spilled in navigable waters. Ingredient Petroleum Hydrocarbon Reportable Quantity Film or sheen upon or discoloration of the water surface or adjoining shoreline HAZARDOUS MATERIALS TRANSPORTATION ACT, 49 CFR 172 The material contains the following ingredient(s) which is considered hazardous if spilled while being transported in commerce. Ingredient Not Applicable Reportable Quantity STATE REGULATIONS CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1984 ('PROPOSITION 65") The material contains ingredient(s) known to the State of California to cause cancer, birth defects or other reproductive harm. Read and follow label directions and use care when handling or using all petroleum products. Ingredient Polynuclear Aromatic Hydrocarbons, Le., Benzo(a)pyrene PENNSYLVANIA WORKER AND COMMUNITY RIGHT TO KNOW ACT To the best of our knowledge the material is not sold or produced in Pennsylvania. Please notify us at the telephone number noted below if the material results in Pennsylvania commerce. MSDS Code: RESC0012 DATE OF LATEST REVISION/REVIEW: DEPARTMENT RESPONSIBLE FOR MSDS: PRODUCT INFORMATION CONTACT: 2/89 - Replaces MSDS dated 8/88 Environmental and Occupational Health Services MSDS Analyst Conoco Inc. (713) 293-5550 The above data are based on tests, experience, and other information which Conoco believes reliable and are supplied for informational purposes only. However, some ingredients may have been purchased or obtained from third-party manufacturers. In these Conoco, in good faith relies on information provided by those third parties. Since conditions of use are outside our control, CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA. NOTHING CONTAINED HEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE MATERIAL DESCRIBED, OR ITS USE FOWMPt SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. k RESC0012/Februaiy 1989 5 MCD 0000229^3