Document JNrV39kY6O5MOw4dqzJeNwwZa

(conoco) Interoffice Communication To JGC DLD GLF GSH JRH MGJ DAP CWT JWW LNW CONFIDENTIAL J. A. DeBernardi 0ate November 11, 1980 subject Employee Information Sheets Attached you will find the subject information in my file related to you. Please review this sheet (both sides) and make any additions, deletions, or changes you find necessary to the information shown. Please return the sheets to me by December 1, 1980, and I'll have them revised and retyped. Ignore the section shown as "Special Attention." J. A. DeBernardi is Enc 00007983A OCR Lake Charles VCM Plant CERTIFIED MAIL #316132 RETURN RECEIPT REQUESTED . .1 J Conoco Chemicals Company A Division of Conoco Inc. P.O 8ox 605 Westlake. Louisiana 70669 (318)491-521 1 November 10, 1980 Mr. Randall E. Brown Environmental Protection Agency Region VI 6 AAHAT Technical Support Section First International Building 1201 Elm Street Dallas, TX 75270 Dear Mr. Brown: Attached is the confirmation of approval of the Louisiana State Construction and Operating Permit for the Conoco VCM Plant Expansion by the Assistant Secretary of the Louisiana Environmental Control Commission. Please note that the hydrocarbons yearly total includes only non-exempt hydrocarbons. Exempt hydrocarbons such as methane and ethane constitute an additional 4.88 tons/year of hydrocarbon emissions. The following table illustrates the above: Non-exempt Hydrocarbons Exempt Hydrocarbons Total Hydrocarbons 18.51 Tons/Year 4.88 Tons/Year 23.39 Tons/Year The total hydrocarbons emission total of 23.39 tons/year is the number pro vided in the revised Section IV of the Appendix of the Prevention of Significant Air Quality Deterioration (PSD) permit application which was submitted to your office on September 8, 1980. In the revised Emission Inventory Questionnaire (EIQ) that was sent to your office on September 8, 1980, a mistake was made in totaling the methane and ethane emissions. On Page 3 of 9 under Item 4, Section B, line title alkanes/paraffins, the methane and ethane total emission should read 1.19 lbs./ hr. and 4.88 tons/year instead of 1.98 lbs./hr. and 8.12 tons/year. An EIQ showing the corrected figures is attached. This addition error constitutes the minor discrepancy that was addressed by us in our letter to Ms. Kathy Bell on November 6, 1980. This mistake has been corrected with the State. CC 000079835 Randall E. Brown Page 2 November 11, 1980 We hope this satisfies your request and that a statement on our PSD application will be shortly forthcoming. If there are any questions, please call Gary Foshee at (318) 491-5062 or Dick Davis at (318) 491-5035. Sincerely, J. A. DeBernardi Plant Manager is CC: Kathy Bell Barbara Brand BCC: REL-CRH-HJN-VAM-GLF-PLF-DLD-JWW-JCL-OGC CCR 000079836 FRANK A. ASHBY, JR. SECRETARY DEPARTMENT OF NATURAL RESOURCES OFFICE OF ENVIRONMENTAL AFFAIRS AIR QUALITY DIVISION October 15, 1980 B. JIM PORTER ASSISTANT SECRETARY Mr- J. A. DeBemardi Conoco Chemicals Company P. 0. Box 605 Westlake, Louisiana 70669 Attn: Mr. Gary Foshee Dear Mr. DeBemardi: Re: Conoco Chemicals Company Westlake (Calcasieu Parish) To reduce the emissions allowable to Permit No. 1424 Conoco VCM Plant to the following maximiims in Tons per Year: Part. 86.83, HC 18.51, SC>2 68.45, CO 17.73, N02 244.97, HC1 Cl 434.69. Appropriate records will be maintained and an annual report made. This is to confirm that the permit request for the above referenced project at your VCM Plant in Westlake has been approved by the Assistant Secretary of the Louisiana Environmental Control Commission under Regulation 6.1.1. The sub mittal was approved on the basis of the emissions reported and the approval in no way guarantees the design scheme presented will be capable of controlling the emissions to the types and quantities stated. A new application must be submitted if the reported emissions are exceeded after operation begins. The permit number cited below should be referenced in future correspondence regarding this subject. Date: October 15, 1980 Permit No. 1451 T Approved by: / BD . JT*5imm DPnorrtter Assistant Secretary BJP:JHS:ne cc: Mr. Joseph Withers, Southwest Regional Office CCR Q0Q079B37 P.O. BOX 60630 . NEW ORLEANS, LA. 70160 PHONE S04 568-5121 . 325 LOYOLA AVENUE L0U1S1AKA A7F CCtmOL CCWMSS10H T\ P. 0. Box 60630, K'ao O.-tearu., la. 70160 Telephone' 1504) 527-5779 EMISSION INVENTORY QUESTIONNAIRE (Revision-of 11/74) pflr* 1 of Q CONOCO CHEMICALS COMPANY CHECK OKE OF-IKE BLOCKS EELOW: OThis inventory includes only presently existing emissions. (name of company) This inventory' includes both CONOCO INC. (parent company; if above is a division) those old emissions(expected to be still existing)and those pro posed additional emissions in Submitted by company on August- 21, 1980 (date) cluded in our permit request for . ' *VCM PLANT EXPANSION (type of new facility/modification Please file a separate report for each of your plants physically located in Louisiana. This inventory covers the following plant location: which was submitted to the com mission on 2/5/80 Td^te) and which new emissions are to be existing by 11/1/82 (date). CONOCO VCM PLANT_____________WESTLAKE_______________ CALCASIEU______________ (plant's name, if any) (nearest, town) (parish of plant s_i_tej_ I^^TkUCTJQ^S: Keep the oxZgZnxt thZ* {omtt; xetnxn a photocopy to thZ* agency. Vo noz ux*Ze Zn&ohmatZon tn the top on. le^t 4t.de iraxg.in* o thi* &oxm, a* (,Ztc \oZdex binding4 may coven, the Zn^onmatZonZ ftJ have txZzd to a*k onty ^on. the Zn^oxr.atZon need, ptziz*e do youx bz*t to anitoex each qu.e*tZon* Oux cjithoxZty to 04k {.on. tliZ* bi&onnatZan Z* contained Zn R.S. 40:2201 et *ec. CopZe* 0$ thZ* too axe avcUZabZe upon xeqae*t. Aax poZZutant ejnZ**Zon data. pnovZded on thZ* {otoi *hcJLL be avaZZabte to the genenat pahZZc, tcithout exception. PJUL otkex data and ZufanmatZon pxovZded on thZ* fahm and attachment* *haZZ at*o be avaZZabZe to the pabZZc, except, that upon a *kouxZng *atZ*{.actoxy to the TechnZcat' Zecxetaxy that each otkex data and Zn- fionmcZZon, Zi made pu.blZcr veouJZd dZvuZge method* ox proce**e* entZtZed to piotectZon a* txzde *ecxet*> the data mill be kept ^xom cJUL pea*on* otkex than ejnpZoyee* , on. otkex agent*, 0 the lod*iana arid qedexaZ cux poZZutZon agenda*. HI Confidentiality of all information, except the air pollutant emission rates, is requested, and our justification for this request is attached to the back of this form, (Check the block it tnts^s the case.) cextaZn qu.e*tZon* axe not appZZcabZe, ZndZcate "none" on. "not appZZcabZe" (W.A. ). Tenor,* *uch a* "not *ZgnZ{sZcant", "nZZ", "txa.ee", " negZZ.gZbZe", etc. axe not accept able. PZeaze attach addZtZonaZ *heet* Zi maxe Apace. Z* needed. An updated report should be submitted in the future when the annual emission rate of any pollutant from any stack changes more than 107. from reported*values ._________________________________________________________________________ ITHH 1 . . . ORGANIZATION ACTIVITIES A. Circle any days of the week normally not operating; ti Tu W Th F Sat Sun B. This facility, as a whole, typically operates 341 days per year. ")C. The peak production season is _N .A ______________ __________________________________ , 1. The facility normally operates Dl D 2 El 3 eight hour shifts per day, specify the hours normally worked per day.-- S. Approximate number of employees at this location is11Q. or CCR 00007983d EMISSION INVENTORY 0 IT S 710 N M11E E (Revi r e e? 11/7 .) ?ntj* 2 of 9 T. If che facility, as s whole, operates intermittently, give cetails on the lines ^ below: G Ownership of facility. Please check one of the following: corporation. partnership, or sole propr icccrshi.p CUregulated. utility [j city government state government federal government other,, specify H. Please check off, or write operation: (2 chemical industry P natural ga;s industry petroleum industry D sugar cane industry other, specify _______ below, the descriptive Clumber industry pulp & paper cement industry Cpcrticleboard : plywood name which appiico to your Uasyjhaltic concrete * fertilizer metals industry fish meal brick making I. Please give a very brief description of your operations, with emphasis on any possible sources of air pollution. Rsfgr to attachsd process description (Section 11 anH_ gjgcjiinn III) .______________________________________________ ______ - . -------- ----- ------ ----------- A '1 * '' 1 'I -- . ' " ITEM 2 . . . FUE1 USE 3Y FACILITY AS A T-TrlQLE 'Check one of the blocks below, and supply information as requested: " Ij$ this iwjwt&uj is {ox "pxvsvrtty existing" conditions ias checked {ox page M, please glue the ln{onj?.xtLon xequested bvlow jca the lotvbt 12 month pzxlod {cx uhlch you. Ivz'je dote., Vote. {on. Ike 12 months vding Month:___ Vzzjl: ({lit in) haj, oven given. {j.tuxe usv Is expected to be mctvuotty cu.{{vient [othzx than as outlined in c. cux/ivit pvuv.lt xepuzst) give detail6 on a sepaxate sheet. S3 this Inventoxy -is bving submitted'In conjunction with a pvnr.lt xequest (cla checked on page 1), please give the. anstual consumption nates expected {.on. the total plant {on. the 12 nonUis fio&Zcuibig the date the new {exility cx i:iocU.lZcatlon becomes openatiorxl. Till} date ss exsted on page 1. Type of fuel * Annual Consumption (Li = thousands') Natural ecs 52 million cubic ~eet Process as 668 million cubic feet No. 1 to 4 f ue * oil No. 5 or 6 fuel oil 3237.8 M cn''ons 1 tt rollons Bark/ wood chios t tons Coal (specify ash 7. & anthrscitc/bitumir.ous) Other Other 1 1 tons Sultur 7. He a ting value (hv vp^rhr' M origin / M8CF1 vy BTu/ V~M e f. J (1 DO p ra n/ DSC FI \rV 3TU/ M>5 f t ^ 0.25 VT* 570/ w - ->1 W\< rnv t-> cal 1________ klV/ ETU/ t on 1 1 KM BTU / ton 1 MM CT'J/ --' i ETU/ CC* 000079Q39 EMISSION TSYtNTC?.V OTEST TONKA IRE (Revised 1\/7Q__________ ____ __ _____ ?^r? 3 of Q ITEM 3 . , . MATERIALS USED, PRODUCED, STORED,- OR TRANSPORTED BY TOTAL PLANT A. Rav materials or materials being cransported Name of material n^^ Things nV ra 3. Products or bvoroduct s T - -Ol'r-fl'ii 3 -D ^ r ^1 Lli'^>'-v-'an I v- V 0 10 *'<i ! r^nalOv-'^-i'!-.*1 _ \< , n v) ^ h "i C1 'd Ouantitv used or transported Annual Houriy Hourly average average maximum (give units') <192 MM Lb750 MM Lb13.125 MM lb/hr a 9.16 / 91 .103 1.709 lb / hr 02 .002 95,552 1,792 1 Lb. t 1t i. How stored (Be specific - floating roof tank, fixed roof. etc.) Not storea Pressure Tank Not stored How moved (Pipeline, tanktruck, etc.) ripe i me Pi oe1ine/Rai1c Pipeline i , . ! i 11 528 MM Lb. 64.140 67.259 1 .653 MM 202 .033 211,894 1 lb. |i \ | 1.000 MM 121.-77i127.403 t Lb. 1 1 1 Pressure Tank Pioe1ine Nitrocen Paaaea Smo ana Fixed Roof lankS Railcar. |j Pressure Spheres bmp . rail1 i car . or Dipelf ITEM L . . . EMISSION INEOPJ'iATION ON THE ENT IRE PLANT .AS A WHOLE Tfie_ >\JtZl> QAVCn 6noLiid C'Vie*6c-:nd, in r.ott au>Z6t to tkz <uun o the. individual. av&zagz kcJlcu o -trie point 6ouncc6 LUtzd in tiie Item 5 pxgei tfo* zac.h type, otf oJjl potluXant. A. ?ARTICULATE SOLIDS O?. LIOUIDS soot freer, combustion mineral dust ocher, soecifv: -1 | other, soecifv: t other, soecif**: 1 Material name Emission rate Emission rate (if must snecifv) lbs/hr 20.33 tons/vr 86 83 !! [j 1! || 3. ORGANIC GASES C7. VAPORS * ?1'<ri!>f/ oaraffins / -i . si'cifv: And Ethane 1.19 11 alkvnes/ acetvlenes 1 1 aromatics, srecifv: 1 aiccrois, srecifv: other, soecif*-*: -a i^an^tad 1 1.2 Dicnlorcethane 1.51 other. s t-ecifv - ^1 Vinvl Chloride other, scecif*.*: r,*r<>'' ms 1 oaftnaTftrS Materials R.55 0.06 4.8a 1 1 1 ! /. UP rms 0.2a C. INORGANIC CLOSES OR VAPORS sulfur dioxide hvirc?An su1'id carbon mo-ox ice rr tr'7p r '^<(05 acrr.onia lhalceens. * r a c i f v organic sulfides fexceot K-,3) ocner, s 0^ c i *.: t 5 Do 1 1 1 up] i 1 rn NfU 17.01 6.52 53.05 i 99.19 i I ! 68.45 ( 1 17.73 1 244.97 1 t 434.69 1 j OCR 000079840 EMISSION IN 'ORY QUESTIONNAIRE (Revised 1 I /7 u ) ? are c ^ NOTES TO ITEM 5 Please read all notes bef are attempting to fill out page(s) 1. Use any number you wish, but please be consistent in identifying this po the same number on calculations, maps, future correspondence, computer print 2. If the emission point Is not a vertically discharging stack, or if there clear-cut point of emission (e.g., dust from moving equipment, multiple leak valves, evaporation from storage tanks, etc.)* put a zero in this column. 3. Give the inside diameter at the top. For non-round exits, use the eauiv. smeter, equal to 1.128 times the square root of the cross-seetional area at : of discharge. Diameter, volume flow rets, and exit velocity must be consist: 4. A "boiler", for purposes of this form, is to be understood to be any corn! device which heats a fluid and is separated from such fluid by a partition. {joxz oil heate/is, t?otcfic/un heaters. etc. cxe Ineiaded. Internal combustion and incinerators are not included. Direct fired kilns are not included. 5. Enter the proper code 000 No control equipment 001 Wet scrubber, . above 95% efficiency 002 Wet scrubber, - 80% - 95% efficient 003 Wet scrubber, Vj below 807. efficiency '004 Gravity collector, above 95% efficiency 005 Gravity collector, 80% -- 95% efficient 006 Gravity collector, below 807. efficiency 007 Centrifugal collector above 95% efficiency 008 Centrifugal collector 80% - 95% efficient 009 Centrifugal collector below 80% efficie ucv number, taken from the list 010 Electrostatic Precip. above 95% efficiency 011 Electrostatic Precip. 80% - 95% efficient 012 Electrostatic Precip. below 30% efficient 013 Gss scrubber, general 014 Mist eliminator 017 Fabric filter 019 Catalytic afterburner 020 Catalytic afterburner, with heat exchanger 021 Direct flame after burner 022 Direct flame after burner with exchanger 023 Flaring 039 Catalytic oxidation - flue gas aesulfuritation below: 040 Alkalized aluminia 041 Dry limestone injec 042 Wet limestone injec 043 Sulfuric acid plant contact process 044 Sulfuric acid plant contact process 045 Sulfur recovery pis 046 Reduced emissions b changing process 047 Vapor recovery syst< 048 Activated carbon ad: tion 050 Gas absorption colur packed. 052 Spray cower for gasc 053 Venturi scrubber for 049 Liquid filtration s> 051 Gas absorption coluz tray-type 6. Give the percent by weight of uncontrolled emission removed. If unknown, blank; if there is no effective removal, enter a zero in the column. 7. Enter the number of the method used, as follows: (l)n By actual stack test (2) By material balance, provided that this method is applicable. [1. C. , method obviously cannot be used where the Inaccuracies -in measurement axe equx on greater than the absolute magnitude o& the losses. An example o& proper uJ> would be where solvent emissions one rjot directly measured, but all solvent pus Is eventually lost to the atmosphere, and therefore material bought divided by mating kouxs equals toss note.) (3) By the use of E.P.A. emission factors. (See the "Compilation of Air Pollution Emission Factors", E.P.A. publication AP-42) (4) By making a conservative estimate. (5) By the use of emission factors other than those supplied by the E.P.A CCR 0000796^1 EMISSION Ivyj-NTOSY QUESTIONNAIRE (Revised 11 /7i*^ Pace 5 of 9 NOTES 70 ITEM 5, CONTINUED (-continuing with-note 7;) (6) Use this number if and only if you are submitting this form in connection with a permit request, and the emissions referred to have no present existence, but arc simply the result of design calculations. (7) Sources ceasing emissions must be reported on one inventory document after they cease operation (see note 8). Emissions will be zero, and a number 7 should be placed in the "emission estimation method" column. 8. If this particular pollutant, from this particular stack (point source), was not included in the stack or point source information submitted on your last Emissions Inventory Questionnaire, or if this is the first Emissions Inventory Questionnaire you are submitting, . write "add" in this column. ' If this particular pollutant, from this particular point, was included on the last Emissions Inventory Questionnaire (2IQ) submitted, but the amount has been in creased or decreased (to other than zero), write "change" in this column. If a point source has ceased operation since your last EIQ, the pollutants from that point should be reported as having zero emission rates on next submitted EIQ, and you should write "delete" in this column. AFTER A DELETION HAS BEEN ONCE RE- PORTED, VO NOT REPORT THE POINT AT ALL OU ANY FUTURE EIQJ $ AND VO NOT USE~THAT POINT'S lA/DEVTIFICATrOM (ZD] M1W5ER IN THE FUTURE FOR ANY OTHER POINT. 9. Report the concentration of particulate matter only for incinerator flue gases, in grains per standard cubic foot of dry flue gas. (See Regulation 20.6.1). If this point is not an incinerator flue, write "N.A." in the column. Report SO2 concentra tions for any stack in which it is found, in PPM by volume at standard conditions. Stack exit concentrations need not be reported for other pollutants* 10. If the hydrocarbons being emitted are of unknown type or have been obtained from emission factors which do not indicate the hydrocarbon type, simply report the data requested on the line marked "hydrocarbons". If, however, you know more about the specific hydrocarbons being emitted (for example - that they are non-methane hydro carbons , or that they are paraffinic hydrocarbons, or that they are, say, 20 weight X aikenes with remainder paraffins, or if you know the specific name of the hydro-.-' carbon being emitted, say, benzene or methanol or methylethvlketone. or whatever) please leave the line marked hydrocarbons blank, write in the name or partial iden tification of your specific hydrocarbons in one of the blank lines below, and give the data requested on that line. 11. Report the fuel charging rate, if any, in units of MM ft^ (million cubic feet) for gases, M gal for fuel oil, and tons for coal, bagasse, sawdust, etc. Report the process materials charging rate, if any, in units such as M Bbl. (thousand barrels), tons (of material processed or produced), "tons (air dried unbleached pulp), M gal (storage capacity of tanks; breathing losses), etc. Please telephone us and ask if unsure of what units to use. Do not list air or water as "process materials". In determining rates, do not include any recycle amount unless asked to do so, in general the rates should be determined on a "fresh'feed" basis. For storage tanks, list separately under%"Name of fuel/ process material" the two catagories of breathing losses and working losses. The "rate" of the breathing loss determinant is M gal (storage capacity) and, of the working loss, is also M gal (throughput). If any one pollutant type (i.e., SO2, particulate matter, etc.) is emitted from more than one stack (or other emission point) serving the same piece of equip ment, please explain briefly on the reverse side of the page 6 subsheet, and write "See reverse side" prominently at the bottom of the form side. OCR 0000798^2 P ITEM NO. 5 EMISSION INVENTORY QUESTIONNAIRE (Rev1scd 11/74) Page 6 of 9 (SUBPAGE NO. 1 OF 8 ) This page Is to be used to record the data from _o_n stnck (or other emission point) only. Photocopy this page as many times as there are individual emission points, and U3e one page for each point, Note that the subscripted numbers indicate explanatory notes on pages 4 and 5. Point source ID number^ II-A Descriptive name of the equipment served by this stack Cracking Furnace Stack Height of stack above grade2 119.97 ft Stack diameter^ 4.50 ft Stock gas exit temperature 550 F Stack gas flow rate at process conditions, not at standard Stack gas eVf t velocity 17,607 ft /min 18.5ft/sec If this stack serves a "boiler"^, give % of ahnual throughput of the type(s) of fuel .used and the heat pollutants through this emis- input (i.e., fviel rate x heating value) s ion point (totals 1007.) Refinery Fuel Gas - type(s) of fuel 51.7 X io*-BTU/hr 1st fuel DecFeb MarMay JuneAug SeptNov (2) 1()6 DTU/hr 2nd fuel, if any 25 7. 25 7. ,25 7. 25 7. (2) Natural Gas to be used as back-up f Jel Normal operat11 me of till 5 PO 1 (1 t h r s days wk s day v'cek yr 24 7 49 Maine of pollutant particulate matter sulfur dioxide nitrogen dioxide hydrocarbons m carbon monoxide Pollution control equipment code s 000 000 000 non Control equipment efficiency A 0 0 0 0 0 Average emission rate lbs/hr 0.93 1.09 11.9 0.155 0.88 Maximum Annual emission emission rate rate lbs/hr tons/vr 1.01 1.13 3.81 4.48 12.9 48.7 0.168 0.634 0.95 3.6 Emission estimation method y (3) (2) (3) (3) (3) Add, change or ,de lete code g * - Concentration in gases exiting the stack q N . A. p,r/std f t 3 10.8 PIM (VOL) i Fill in this column only as required by note 9. i i QO O, CCR 000079843 If this stack is from equipment which burns fuel, give the 7. of the total fuel used by the equipment which is used, either directly or indirectly, for pace heating (or cooling) at the plant. (i.e., to heat or cool the air in a room) If this stack is not from a fuel burning equipment, or if*fuel is burned but none of the heat is intended to heat or cool air in a room, enter a zero below: 0. Q7* "apace heat" Give below the fuel or process materials charging rate to the unit served by this stack.^ Annual Name of fuel/ process material rate Refinery Fuel Gas 334 MHSCF At Maximum hourly rate 44.2 MSCF /hr Ayr ______ IXL J_1S Lis hs IhL lbs. lbs /hr /hr ITEM NO. 5 EMISSION INVENTORY QUESTIONNAIRE (Revised 11/74) Page 6 of 9 (SUBPACE NO. ? OF ft) This rage Is to be used to record the data from one stack (or other emission point) only. Photocopy this page as many times ns there are individual emission pointsp and use one page for each point. Note that the subscripted numbers indicate explanatory notes on pages 4 and 5. Point source ID number] II-B Descriptive name of the equipment served by this stack Cracking Furnace Stack Height of stack above grade2 119.97 ft Stack diameter^ 4.5 ft Stack gas exit temperature 550 F Stack gas flow rate at process conditions* not at standard 17,607 ft3/mln Stack gas *xi. t velocity 18.55 t/sec If this stack serves a "boiler"^, give tlie type(s) of fuel, used and the heat input (i.e., fuel rate x heating value) Refinery Fuel Gas. __ type(s) of fuel 51.7 x 106 BTU/hr 1st fuel f 1) _________106 BTU/hr 2nd fuel, If any X of annual throughput of pollutants through this emis sion point (totals 1007.) Dec- Mar- June- Sept- Feb May Aug Nov 25 % 25 X 25 7. Normal operat ing time of this point hrs d n y s wks day week yr 24 7 49 (1) Natural gas to be used as back-up fu bl Name of pollutant particulate ni.i 11 e r sulfur dioxide nitrogen dioxide hydrocarbons in carbon monoxide Pollution control equipment code q nnn 000 000 000 000 Control equipment efficiency f, n 0 0 0 0 Average emission rate lbs/hr 0.9.9 1.09 11.9 0. 155 0.88 Maximum emission rate lbs/hr 1.01 1.13 12.9 0.168 . 0.95 Annual emission rate tons/vr 3.81 4.48 48.7 0.634 3.6 Emission estimation method 7 (3) (2) - _J.l)______ . f 31- _ -1 (31 Add, change or, de lete code g Concentration in gases exiting the stack g N. A. rr/std f 19 10.8 PPM (VOL) i Fill in this column only as required by note 9. CCR 000079844 If this stack is from equipment which burns fuel, give the % of the total fuel used by the equipment which is used, either directly or indirectly, for space heating (or cooling) at the plant. (i.e., to hent or cool the air in a room) If this stack is not from a fuel burning equipment, or if fuel is burned but none of the heat is intended to heat or cool air in a room, enter a zero below: 0 X "space heat" Give below the fuel or process materials charglUg rate to the unit served by this stack. Annua 1 Hax i mum Name of fuel/ process material rate hourly rate /yr /vr /vr /vr /yr /hr /hr /hr /hr Dll ..J JI J ITEM NO. 5EMISSION INVENTORY QUESTIONNAIRE (Revised 11./7')Page 6 of 9 (SUBPAGE NO. 3 OF H ) This page is to be used to record tlie data from one stack (or other emission point) only. Photocopy tills page ns many times ns there arc individual emission points, and use one page for each point. Note that the subscripted numbers Indicate explanatory notes on pages A and 5. Feint source ID numberi I V-A Descriptive name of the equipment served by this stack C-500 (Main Plant Vent Stack) Height of stack above gradc2 148 ft Stack diameter^ 3.0 ft Stock pas exit temperature F Stack gas flow rate at process conditions, not at standard Stack gas t'xlt ve locity 0 ft^/min 0 ft/sec If this stack serves a "boiler"^, give the type(s) of fuel.used and the heat input (i.e., fuel rate x heating value) MA type(s) of fuel 10^ BTU/hr 1st fuel 10b BTU/hr 2nd fuel, if any % of annual throughput of pollutants through tills emis- r. ion point (totals 1007.) Dec- Mar- June- Sept- Feb May Aug Nov % 7. 7. X Normal operati ng t i me of thl > point lies days uks day v'cek yr 0 00 Name of Pollution Control Average Maximum Annual Emission Add, change Concentration in pollutant control equipirrant emission emission emission estimation or 4 dele te gases exiting the o o equipment efficiency rate code s A lbs/hr rate lbs/hr rate tous/vr method y code g p particulate matter stack g pr/stci f t 3 sulfur dioxide FTM (VOL) nitrogen dioxide hydrocarbons in carbon monoxide 00 Delete Fill in this 0 0 b' Delete column only Q3 * required by note 9. 6V86iO 00 If this stack is from equipment which burns fuel, give the 7. of the total fuel used by the equipment which Is used, either directly or indirectly, for space heating (or cooling) at the plant. (i.c., to heat or cool the air in a room) If this stack is not from a fuel burning equipment, or ifi fuel is burned but none of the heat is intended to heat or cool air in a room, enter a zero below: 0 1, "space heat*' Give below the fuel or process materials charging rote to the unit served by this stack. Annual Maximum Name of fuel/ process material rate hourly rate ------- N . l\_________________________ .. ... ... (Yr /vr / nr /hr /vr /hr /vr /hr /vr /hr .......................... /yr . _________ Oil J Jj IIKM NO. 5 EMISSION INVENTORY (JUESTIONHAIKE (Revised 11/74) _Page__ 6 of 9 (SUBPAOH NO./) 0KH___) This page Is to be used to record the data from one stack (or other emission point) _onJ_y. I'hotocopy this page as many times as there are Individual emission points, and use one page for each point. Note that the subscripted numbers indicate explanatory notes on pages 4 and 5. Point source ID number} I V-C Ucscriptive name of the equipment served by this stack Propylene Vent (BL-501) Height of stack above grade2 148 ft Stack diameter-} 0.666 ft Stock gas exit temperature F Stack gas flow rate at process conditions, not at standard 0 f t'Vmin Stack gas xf t velocity 0 ft/sec If this stack serves a "boiler"^, give the type(s) of fuel .used and the heat input (i.c., fuel rate x heating value) N.A. _____ _typc(s) of fuel 106 BTU/hr 1st fuel 10& BTU/hr 2nd fuel, if any % of annual throughput of pollutants through tills emis nior^ point (totals 1007,) Dec- Mar- June- Sept- Feb May Aug Nov X 7. ____ X 7. Norma l ope rat ing timo of th L s point hrs days wk s day vee k yr 0 0__ 0 Name of pollutant pnjrticulnte matter sulfur dioxide nitrogen dioxide hydrocarbons ip carbon monoxide Pollution Control control equipment equipment efficiency code q _________ a Average emission rate Ibs/hr Maximum emissipn rate lbs/hr Annual emission rate tons/yr Emission estimation method Add, change or ,de le te code 8 (7) Delete Concentration in gases exiting the stack q gr/stii ft^ Pit! (VOL) Fill In tli is column only as required by note 9. CCR 0 0 0 0 7 9 8 4 6 If this stack is from equipment which burns fuel, Cive below the fuel or process materials chargirig rate to give the 7. of the total fuel used by the equipment the unit served by this stack,^ which is used, either directly or indirectly, for space heating (or cooling) at the plant. (i.e.. | Name of fuel/ process material to heat or cool the air in a room) If thi9 stack ; M ft is not from a fuel burning equipment, or if fuel is burned but none of the heat is intended to heat or cool air in a room, enter a zero below; i Annual rate /yr /vr /vr /vr Ma x1mum hourly rate /hr /hr /hr /hr * fl 7. "apace heat" /vr Us ^ /hr ITEM NO. 5 EMISSION INVENTORY QUESTIONNAIRE (Revised 11/74) _____ Page 6 of 9 (SUHPAGE NO.5 OF 8 ) TI* i a page Is to he used to record the data from one stock (or other emission point) on) y. Photocopy tills page as ninny times as there are individual emission points, and uae one page Cor each point. Note that the subscripted numbers indicate explanatory notes on pages 4 and 5. Point source ID number^ 1V-J Descriptive name of the equipment served by tills stack Dock EDC Tank (T-415) Height of stack above grade2 35 ft Stack diameter^ 0.83 ft Stock gas exit tempera ture 84 F Stack gas flow rate at process conditions, not at standard Stack gas *dxJ c velocity 5*28 ft3/min ft/sec If this stack serves a "boiler"^, give 7. of Annual throughput of die type(s) of fuel, used and the heat pollutants through this cmis- input (i.e., fuel rate x heating value) s ion point (totals 1007.) N.A. type(s) of fuel Dec- Mar- June- Sept- 106 BTU/hr 1st fuel Feb May Aug Nov 10& BTU/hr 2nd fuel, if any 25_7* 2SJ> 25_7* 25_x Normal operating t i me of this point hr s days vks d ay we e k yr -24- J-- 52_ CCR 000079847 Name of pollutant particulate matter sulfur dioxide nitrogen dioxide hydrocarbons m TOT carbon monoxide 1,2 Dichloroethane Other Chlorinated Hydrocarbons MCI Pollution control equipment code q ll Control equipment efficiency fi. Average Maximum emission emission rate rate lbs/lir lbs/hr Annua 1 emission rate tons/yr non 0 1.67 11.9 7.33 000 0 1.61 11.4 7.05 000 0 0.06 0.45 0.28 000 0 0.04 0.31 0.19 Emission estimation method -j (A) (A) (A) (4) Add, change or delete code g Concentration in gases exiting the stack g r.r/st<l ft^ PPM (VOL) i Fill in tiiis column only as required by note 9. If this 6tack is from equipment which burns fuel, give the 7. of the total fuel used by the equipment which ia used, either directly or indirectly, for space heating (or cooling) at the plant. (i.e., to heat or cool the air in a room) If this stack is not from a fuel burning equipment, or if fuel is burned but none of the heat is intended to heat or cool air in a room, enter a zero below: 0 _7. "space heat" Give below the fuel or process materials charging rate to the unit served by this stack.n Name of fuel/ process material Breathing Losses Working Losses Annual rate 0.67 Tons /vr /yr /vr /vr /yr Maximum hourly rate /hr /hr /hr /hr _________ Oil J ITEM NO. 5 EMISSION INVENTORY QUESTIONNAIRE (Revised 11/74) Page 6 of 9 (SUBPACK NO. 6 ()k8 ) This page is to bo used to record the data from one stack (or other emission point) only. Photocopy this page as many times ns there arc individual emission points, and use one page for each point. Note that the subscripted numbers indicate explanatory notes on pages 4 and 5. Foint source ID number} I V-K Descriptive name of the equipment served by this stack Dock VCti Vent Recovery Height of stack above grode2 148 ft Stack diameter-^ 1.0 ft Stack gas exit tempe ra t urc 75 F Stack gas flow rate at process conditions, not at standard Stack gas eVl t velocity 816 f t^/niin 6,7ft/sec If this stack serves a "boiler"^, give Che type(s) of fuel .used and tfic heat input (i.e., fuel rate x heating value) N.A. type(s) of fuel 10b BTU/hr 1st fuel 10& BTU/hr 2nd fuel, if any % of annual throughput of pollutants through this emts- sion point (totals 1007.) Dec- Mar- June- Sept- Feb May Aug Nov ro Ol 25 7. 25 % 25 X Norma 1 operating t i me of tii 1 3 point hr 3 d n ys vks day veck yr JL_ JL 52 Name of pollutant particulate matter sulfur dioxide nitrogen dioxide hydrocarbons g__ carbon monoxide Vinyl Chloride Pollution control equipment code s Control equipment efficiency 6 Average Maximum Annual emission emission emission rate rate rate lbs/hr lbs/hr tons/yr Emission estimation me t h od ~t Add, change or,delete code g (below) 048 <0.01 <0.1 TEL Concentration in gases exiting the stack g _Fr/s td f t^~ PIM (VDI) Fill In tli is column only as required by note 9. CCR 0 0 0 0 7 9 8 4 8 If this stack is from equipment which burns fuel, give the 7. of the total fuel used by the equipment which is used, either directly or indirectly, for space heating (or cooling) at the plant. (i.e., to heat or cool the air in a room) If this stock is not from a fuel burning equipment, or ifi fuel is burned but none of the heat is intended to heat or cool air in a room, enter a zero below: 0 X "space heat" Give below the fuel or process materials charging rate to the unit served by this stack. Annual Max 1 mum Nome of fuel/ process material N.A. rate /yr hourly rate /yr /hr /vr /hr / yr /hr /yr /hr fca _______ ITEM NO. 5 EMISSION INVENTORY QUESTIONNAIRE (Revised 11/74)Page 6 of 9 (SURFACE f.'0.7 OF ft ) This page Is to be used to record the data from one stack (or other emission point) only. Photocopy this page as many times ns there are individual emission points, and use one page for each point. Note that the subscripted numbers indicate explanatory notes on pages 4 and 5. Point source ID number} i ;-c Descriptive name of the equipment served by tills stack Crackinq Furnace Height of stack above grade2 119.97 ft Stack diameter^ 6.0 fC Stack gas exit temperature 550 F Stack gas flow rate at process conditions, not at standard ; 22.375 ft3/niln Stack gas t velocity 13.?ft/sec If this stack serves a "boiler"^, give the type(s) of fuel-used and the heat input (i.e., fuel rate x heating value) No. 2 Fuel Oil type(s) of fuel R1 .3 X 10*> BTU/hr 1st fuel 106 BTU/hr 2nd fuel. If any % of annual throughput of pollutants through this emis- 3 ion point (t otais Dec- Mar- June- Sept- Feb May Aug Nov 25 % 25J* 25 % 25 7. Normal operating t i mo of tills point hrs days vk s day week yr Z, jL 47.62 (1) Natural qas or Refinery off qas may be ust d as a t ackup fu ?1 . Name of pollutant particulate matter sulfur dioxide nitrogen dioxide hydrocarbons in carbon monoxide Pollution control equipment code ; 000 0 00 000 000 ` 000 Control equipment efficiency fi 0 0 0 0 0 Average emission rate lbs/hr 0.8T 14.37 5.54 Q.41 2.03 Maximum emission rate Ibs/hr 0.81 1-4.37 5.54 0.41 2.03 Annual emission rate tons/vr '3.24 57.47 22.17 1.62 8.1 Emission estimation method 7 (3) (3) (5) 3) h) Add, change or delete code g Add Add Add Add Add Concentration in gases exiting the stack g if. A. ?x f s td f t 3 123 PPM (VOL) i Fill in this column only as required by note 9. CCR 0 0 0 0 7 9 8 4 9 If thin stack is from equipment which burns fuel, Give below the fuel or process materials chargillg rate to give the 7. of the total fuel used by the equipment the unit served by this stack.^ which 1s used, either directly or indirectly, for \ Annual Maximum space heating (or cooling) at the plant, (i.e.. j Name of fuel/ process material rate hourly rate to heat or cool the air in a room) If this stack No. 2 Fuel Oil 3.238 MM Gal./vr 485.7 Gal. /hr is not from a fuel burning equipment, or if fuel /yr /hr is burned but none of the heat is intended to heat /vr /hr or cool air in a room, enter a zero below: 1 /yr /hr 7vr /hr 0 7. "space heat" Lu. /hr .M P ITEM NO. 5 EMISSION INVENTORY QUESTIONNAIRE (Revised 11./74) Pngc_ G q 9 (SUBPACK NO . 8_________________ UFf}___) Tills page Is to be used Co record the data from one stack (or other emission point) only. 1'hotocopy this page as many times ns there are individual emission points, and use one page for each point. Note chat: the subscripted numbers indicate explanatory notes on pages 4 and 5. Point source ID numberj V-A Descriptive name of the equipment served by this stack Vent Incinerator Height of stack above grade2 75__________ ft Stack diameter^ JUL ft Stock gas exit temperature IZ5F Stack gas flow rate at process conditions, not at standard Stack gas xl t velocity 28,817 ft^/min 67.9ft/sec If this stack serves a "boiler"^, give the type(s) of fuel .used and the heat input (i.e., fuel rate x heating value) N.A. tvne(s) of fuel 10^ BTU/hr 1st fuel 10*3 BTU/hr 2nd fuel, if any % of annual throughput of pollutants through this emis- sion point (t otals 1007.) Dec- Mar- June- Sept- Feb 25 7. May 25 % Aug 25 7. Nov 25 7. Normal ope rating time of tills point hr s days vks day wee k yr 24 7 52 Name of pollutant Pollution Control Average Maximum Annual control equipment emission emission emission equipment efficiency rate rate rate code : A lbo/hr lbs/hr tons/vr particulate matter sulfur dioxide n?? 022 17 8Q 0.46 17.39 ' 6.46 75 Q7 2.0? nitrogen dioxide 022 28.71 28 .'71 125.40 hydrocarbons in TOT 022 carbon monoxide 022 2.98 0.55 2.98 13.07 0.55 1 2.43 Vinyl Chloride M 022 2.54 2.54 11.08 Emission estimation method y (4) 4 (4 (4) (4) (4) Add, change or .delete code g Channft Chann* Change Chance Chanqe Chanqe * Concentration in gases exiting the stack q 0.079 ft/ std ft-1 1.78 I'I'M (VOL) i Fill in this column only as required by note 9. CCS* 0 0 0 0 7 9 8 5 0 If this 6tack is from equipment which burns fuel, give the 7. of the total fuel used by the equipment which Is used, either directly or indirectly, for space heating (or cooling) at the plant. (i.e., to heat or cool the air in a room) If this stack is not from a fuel burning equipment, or if fuel Is burned but none of the heat is intended to heat or cool air in a room, enter a zero below; 0 7, "apace heat" Give below the fuel or process materials chargili^ rate to the unit served by this stack.^ Name of fuel/ process material Annual rate Maximum hourly rate /ye /vr /vr /vr /vr _____ h* /hr /hr /hr /hr /hr Vi EMISSION' INVENTORY QUESTIONNAIRE (Revised 11 / 7 d ) ITEM A FL.iNT LOCATION FOR AIR POLLUTION DISPERSION MODELING Pace 7 of 9 Give below the Universal Transverse Mercator rone number and Universal Transverse Mercator (LTM) coordinates, to the nearest one-tench kilometer, of your facility. We must have this information since we are required to report it to the U. S. Environ mental Protection Agency for vide area dispersion modeling purposes. The coordinates can be obtained from most U. S. Geological Survey maps, scale 1:24,000 or 1:62,000 for your particular area. These maps, if not already in your possession, may be found in your local library, or can be purchased from the U. S. Geological Survey (USCS) at the address shown below for 75c each (1974 price). An index of all the maps available for Louisiana, together with prices and detailed instructions for ordering, may be obtained free by addressing a request to: U. S. Geological Survey, Distribution''Cente*r, Denver Federal Center, Eldg. 41 Denver, Colorado S0225 If the map has the Universal Transverse Mercator (UTM) coordinates listed, it will have the UTM zone number mentioned among the writing along the bottom of the map. This cone number will be either 15 or 16 for Louisiana. P-CjX4C. natz that ZaXJXadz and tong^JHido. gac. nn wkat toe need, and that the USCS maps do not show UTM grid lines as they do latitude and longitude; however, tick marks along the edges of the naps do indicate the UTM grid locations. A straight edge must be used to connect tick marks at the opposite sides of USGS maps when interpolating between UTM tick marks because the map grid is drawn on Che latitudelongitude system and, therefore, the UTM grid may appear quite skewed. For the scales mentioned, tick marks appear for every 1000 meters (1 kilometer), with every fifth tick mark and the tick marks nearest the southeast and northwest corners of the map giving the value in meters. The 1:24,000 scale is preferred to accurately locate the facility, but the 1:62,000 scale nay be used if the 1:24,000 scale map is un available for your area. For example: The' state capitol building in Baton Rouge would be: UTM zone No. _1 ^5 horizontal coordinate: ,6 1_ 4._1 Km. E vertical coordinate: 2 J3 _7 0.^6 Km. N Your facility: UTM zone No. 1.5- horizontal coordinate: {LZ.2--2- ^ ITEM 7 . . . COMPLIANCE STATUS vertical coordinate: 3_3_4_6_5_ Km. N Chzck one oj ihz block* bzlou), AcgasicUng yousi hacJJJAy' <$ "Compliance Schedule"' 0 Such a document has not been requested of us, so far as we know. Such a document was requested, or submitted, but we haven't yet received noti fication that it was accepted at a public hearing by the Commission. We were notified that the document was accepted at a public hearing; no schedule of actions to achieve compliance was necessary. D We were notified that the document was accepted at a public hearing; our sched ule of actions to achieve compliance by ____ (month), 197 _ (year) was approved. The most recent "increment of progress" date in our schedule of actions was achieved r- ____ (month) ____ (day) 7 _ (year). [ji'OU MUST FILL IN THE DATE BLANKS IF YOU HAVE CHECKED THIS PARAGRAPH^ CCR 000079351 EMISSION I?,V TO f i r. S . if1'.. R of 9 h -, --, V.Z7VS7. ^ , w A Amount of corpustib 1c refuse disposed of per yer.r:_ 5915 Tons (rive t;ie applicable units) B Description of refuse; check off applicable categories: " C3 Paper scrap Rubber scrap OD Wood scraps - sawdust Cl V.'et garbage cr animal wastes 29 Other, specify:__ Rubbish C. Method of refuue disposal; cheek off applicable categories i City pickup C On-site cunp G On-site incineration Cl Contractor pickup Q Cn-sicc outdoor burning On-site landfill Q Other , specify:____________________ ___________________________________________________________________ D, If disposal is by contractor pickup, give the name and address of the contractor: Browning-Ferris Industries of Louisiana Inc. Solid Waste Division-Cities Service Hicnwav - Maoiewood, Ln 70co3 ________ _ The on-site incinerate*: s S Mo on-site incinerator C Single chamber Multiple chamber a ry. has the follcv/i tj z t e r c u mors G Primary is secondary G burners installed design features: G Water scrubber installed G Waste material disposed of by burning in a boiler F. Incinerator equipment data (if applf.cabie): Manufacturer:N . A . ______________________Modal: Capacity:Installation date : Auxiliary fuel used: (type, Hot-/ used, rate of use)__________________ ITEM 9 . , , So?FLEHEMTARY IN?OELIRTION A. PZeaez iu.pp.iy a urUyi p-iot pian on. majp which ^ko\a the. Zae&tLon& o{, ztc.chz [on. otkzn. &GUA.C.1L&i, tco&cken. uittk ihz c.qujlzz ,LdenLi,oz&Lcii mjzb&u xor, Iter, Sf the. plant bou.i'j&juL<u>, a cLLizzs.' cz icszie., and tkz cUfizction kaitk. ?Zzcj:q. clao &nowt on a. separate diaonjxn i ne.c.z&an.;/f tkz -tocotton o the clout in delation to noAXCAt htg'rdJZLU6, XfUidZiVtiai oiizcj>t and icu;;z6> Kttc.ch ike map* to tkz back o tkU onm. See Figures I and II. B. Approximately how much money have you spent on air pollution control equipment and operation in the post 10 years? Equipment $.15,500,000 Operation $2,935,000 ITEM 10 . . . TOGO GASES 1 hASiR^OUS MATERIALS A. Are there any substances used or produced in your facility v;hr :h could cause im mediate injury to life or property, _if they v;ere emitted to the atmosphere, which are not already listed in this form as one which is presently being emitted to the atcospnere? (e.g., chlorine for water treatment, toxic gases, gases used as cata lysts, etc., vrhich ordinarily do not escape) Please list such substances below. If none, please so state."No- B. Does your facility use or produce asbestos, mercury (other than laboratory use), or beryllium in any amount whatsoever.-? If answer is vgs, give cerailo bn^c- r~r ''separate sheet. If anew-.r is no, please, vnte ''r.ci; be lor*: No 00007^*52 " OCR EMISSION' IVYENTCSY Ol*Z STT ON'NA IRE (Revised 11 / 7Q_______________________ izzy. )\ . . , r~RS0N'\-;:. a CESTiriCATion Q of P A. The manager of the facility, on location at the plant site, is as follows: Nnmc: Title : Name of Company: Business street address/ P. 0. Box: City or town, parish. Zip code: Business area code/ telephone No,: James A. OeSemardi . Plant Manager - VCMPTent Conoco Cnsnical s Company, A Division of Conoco. Inc. - P. 0. Box 605 Westlake, LA 70669 31S/491-5054 B. Person to contact at the site of the facility about air pollution control, if different from the above: ' . Name : Title: Business telephone No./ extension: Gary L. Foshee_________ Chief Process Engineer 318/ -+91-5062 C. If the company's air pollution control correspondence and documents are prepared at a headquarters office, at a different site, give the information on the person to be contacted below: Nana: H. J. Neeld__________________________ Title : Director of Environmental Control Name of company; or parent company: Conoco Chemicals Company______ ^Business street address/ P. 0. Box: -ty, state, Zip code: Business area code; telephone No.: P- 0- Box 727__________________ Westlake", lA ~ 70669 ~ ~ ~ 318/491-5436 D. Person who prepared this report Name: Title: Firm: (if prepared by a consultant) Company: (if prepared in-house) Street address/ P. 0. Box: City, state, Zip code: Area code, telephone #, extension: (I one of the above., just check appropriate block.:) da. as. C. Jonathan G. Cole____________________________ _________ Process Enoineer Conoco Cnemicais Company P. 0. Box 605 . _______ West 1 a,<e , LA 70669 "316/^91-005/ E. CERTIFICATION, j certify, urxteA the provisions -in LotuAla.ua and Urited States laifj tuhicn provide criminal penalties fox. [\dlse statements, that this Emission Inventory Qaestionnaine, including ail attachments thereto, contains information which is true and correct to the best of my knouledae and belief. signatureof manager, or other company agent) J. A. DsBernardi, Plant Manager - VCM Plant (printed or typed name & title of person above) / (cade signed) cca 000079853