Document JNnq8G9L0dQErpXGLzanRYMZr

: AR 226. 0730 ACUTE TOXICITY TO AQUATIC INVERTEBRATES (COROPHIUM VOLUTATOR) IesTsuestANCE 0000000 Identity: rAefmeirxrteudretocaonstPaiFnOiSng, pFeCr-f9l5u,oroorocatsanaescuolmfponoanteen,twhoficFhC-m2a0y3.al(s1o- be Octanesulfonic acid) (CAS# 2795-39-3). Remarks: is FC-203. CuTrhreent3Minpfroromdautcitoinoninldoticnautmesbeirtiwsaasminxotturneotoefd.1.3T4h%e PteFsOtSs,am3p5l%e dSiueltthoynleenfeoagmleyrc,ol3b%utysloedtihuerm,o3ct7y.l8s5u%lfawtaet,er0,.12%0%soedtihuymlelnaeurgyllycsoull,fa2te.,66an%d 0.05% tolyltriazole. cThhaerafcotlelroiwiznegd csounmcmenatrryataipopnlsioefsitmopuarmiitxiteusr.eDwaittah imnacyomnpoltetaeclcyurately reflect toxicity of the fluorochemical component of the test sample. METHOD: 000 Method: sediment ~~ ASTM E1367-90, Standard guide forconducting toxicity tests with marine and estuarine sediments. 10 day static Type: Acute static GLP: No Year completed: 2000 Species: Corophium volutator Supplier: Not given. Analytical Exposure monitoring: pH period: 10 days and dissolved oxygen Test organism age: Adults SStwaetdisitsihcaElnmviertohnomde:ntaLlCPsrovtaelcuteisoncaBlocaurldat(eVdebrysiPonRO2.B3I, T19a9n0a)l.ysiCsa,lcNualtaitoinoanl of NOEC by single-factor Test conditions: ANOVA followed by Bonferronis procedure. Dilution water: site in Byfjorden, Noauttusriadle soefaSwtaatvearng(e3r4, pNpotrswaalyin.ityS) efdriommeannt unpolluted ~~ collected at - farnacutniponololfut0e.d7s%itae.ndTahesilstefdriamcteinotnoifs0a.m8u%ddy sand an had an organic Dilution water chemistry: Not given. Lighting: Not given bSytoacdkdianngdttheesttesstolsuatmipolneptroep6a0r0atgidona:mpEascehditemsetnctoancnednt2r0a0timoLn wofasseparweaptaerr,ed then shaken for 3 an overlay of 400 mhoLurss.eawTahteerseaddidmeednttoweaaschsplaitndinatoertahtreede sub-samples, with overnight prior to study initiation. aEnxdpo4s0u0rmeLveosfsseelasw:at6e0r0 mL with gcloanstsinbueoaukseraesractoinotna.ining 200 g of test sediment 000654 Number of replicates: 3 Number Number of of organisms per replicate: concentrations: four plus 10 a blank control Water PchHemriasntgrey(d0-u1r0indgaytsh)e: study: 7.7 -8.1 (control exposure) Temper8a.t0u8re.1ra(n3g0e6:0 mg/kg exposure) 15+ 1C Dissolved oxygen range (0-10 days): 91-94% 74-97 % (control exposure) (3060 mg/kg exposure) Nominal weight). concentrations: Bk control, 91.1, 501, 1030, and 3060 mg/kg (dry Element values: 10-day 10-day LCso = NOEC >3060 = 3060 mg/kg mg/kg (sediment dry weight) (sediment dry weight) Element values based on nominal concentrations SRuebmsatraknsc:e TReesmtianrgkwsafsielcdo.ndTuhcetevadlouenstrheepmoirxtteudraepapslydetosctrhiatbemdixitnutrheeaTnedstnot the fluorochemical proportion alone. wTehieghFt)C.-2T0h3e1100--ddaayyLNCsooOwbasserdveetderEmfifneectd Ctoonbceen>t3r0at6i0onmg(/NkOgE(Cs)edwiamsen3t0d6r0y mg/kg (sediment dry weight). Validity criteria fulfilled and reference substance was in the normal range. Submitter: 3M Paul, Minnesota, Company, 55133 Environmental Laboratory, P.O. Box 33331, St. - paraguay 0000 tReesltiianbgi.litHyo:weKvieirmi,sschamrpalnekipnugri=ty2.waThsisnosttupdroypmeerleytschtahreacctreitreirziaedfoarnqduatlhietystudy lacks analytical solution. confirmation of the amount of fluorochemical proportion in the R0 EFERE0 NCES0 ~~ O ~ 0O0O0 rTeeqsutewsatsofc3onMduNcotregde,byLaRbFreRfoegraelnacnednuRemsbeearrc9h3,12of-2S,ta2v0a0n0g.er, Norway at the 000685 = Last changed: 6/27/00 000686 . 44 wo>lEiwa RRZEAERNE soTsEi2z Vno. ipso "FC-203 Light Water Brand AFFF" Toxicity tests Report RF-2000/002 CEilnanto:rve e Vee. 1T 108.01 200 Pei Frogar suorgs So The following test results were obtained with "FC-203 Light Water Brand AFFFTM : Toxicity: Skeletonema costatum Acartia tonsa Corophium volutator 72hEC, 48hLC, 10dLC,, (mgh) : 62 (mg): 200 (mg/kg dry weight): >3060 or The results relate to the producast supplied by Novatech, Toxicity, Skeletonema costatum, Acartia tonsa, Corophium volutator. re >= ~ Iorndga Andersen K(ae Nle i 000687 4 Lavo 99312-2 Fugen CONTENTS: 1 BREEN smmsmmmmmmm------------------------(} 2. TEST FOR TOXICITYWITH SKELETONEMA COSTATUM ..orssnsisios 3. TEST FOR TOXIWICTHAICATRTYIA TONSA cvs sss 10 4. TEST FOR TOXICITYWITH COROPHIUM VOLUTATOR cocoon 1S 5,DATASIEEES assis 3 000688 eis PREFACE: Ecotoxicological tests wereperformed on *FC-203 Light Water Brand AFFF" in agreement with cNoovnadtueccthe.d iTnhaecscaomrpdlaencies awictohnctheent"rHaatremtohnatisneodrmOaflflsyhowriellCbheemuisceadlinNoati3f%icastoiloutniFono.rmTaets"ts were (OSPARCOM 1995 /SFT 1998). pTehrefporromjeedctbywaRsFc-arMriilejdoloaubt.atStRudFy-dRiroegcatloarnwdasReSseenairocrhEfnogri3neMerNoIrnggee.r LAilslatAhnedteersstesnw.ere The test results arepresented in separate sections. by Novatech. The results relate to theproduct as supplied TThhiesatcecsrterdeiptoarttiion sitsastueesdtbhyatatlhaebloarbaotroartyoarcycmreeedtistetdhbeyNNAorrweqeugiiraenmeAnctcsrecdointcaetrinoinn(gNAc)o.mpetence, equipment and workingproceduresfor all the test methods contained in the accreditation. iItntaelrsnoasltqautaelsitthyactonttherollabsocrhaetmoersy,hpaasrtaicsiaptaitsifoanctionryinqtuearllitayboarsastuorryanccoempsayrsitesmo,nsw,hiacnhditnhceluusdeesof certified reference materials and secondary reference materials The testsperformed are covered by the accreditation. This test report writing by RF - may not be Miljolab. reproduced in anyform other than in full, without the permission in 000689 TEST FOR TOXICITY Marine alga: Skeletonema costatum 000650 ide" ten . TEST REPORT GROWTH INHIBITION TEST WITH THE MARINE ALGA Skeletonema costatum (o)] i = RE He RESEARCH TEST SUBSTANCE: "FC-203 Light Water Brand AFF" TEST RESULT: `The 72 hours ECso was calculated to 62 mg/l. `The test substance was supplied by Novatech, and the test results relateto this product. TEST DETAILS: METHOD: 'wNitSh-ESNkeIlSeOto1n0e2m5a3,co1s9t9a8t:umWaatnedrPqhuaacloitdyac-tMyalruinnetrailcgoarlngurtuomw.th inhibition test TEST ORGANISM: Skeletonema costatum, strain NIVA BAC 1. A stock cultureofthe test `organism is kept at RF - Rogaland Research. PREPARATIONS: INCUBATION: Natural seawater (salinity: 34 %o)froman unpolluted site in Byfjord was used as basis for the growth medium. The water was filtered through a GF/C filter, and briefly heated to about 75C prior to use. The seawater was enriched with nutrients according to ISO 10253, and recommendations from the Paris Commission. _ mTegs/tl swoalsutpiroenspawreerdebpyrsetpairrerdinfgr0o.m50a08sgtrocakmssooflutthioen.prAodusctotcikns1olluittrieonofogfr5o0w0t.h8 `medium. Other concentrations were prepared from this stock solution. Test cultures of 50 ml were incubated in 100 ml flat-bottomed flasks on an orbital shaker, 3 replicates for each concentration. Test cultures were inoculated to about 2000 cells/ml from an exponentiallygrowing inoculum culture. t`Tuhbeestoesft wunaisverrusnalunndateurraclonwthiintueoutyspel,igahtta(>te5m0peurE/amt"u*resoefk)2f0r+om2fCl.uorescent =~ `The test was run for about 72 hours, and subsamples of5 ml were taken from the test flasks each day for growth measurements. Algal growth was measured by fluorescence. pH measurements were performed as indicated on data sheet. 000631 i oLa0bs1r2e2f Page of 31 DATA ANALYSIS: y CALCULATION: Gverroswutshtirmaet,esawsedreesccrailbceudlaitnedNSb-yElNogSliOnea1r02r5e3g.ression on biomass (fluorescence) ECsy: Tcohneceinnthriabtiitoornyoefffaepcrtoodnuctthegigvrionwgth50of%Srkeedluecttoionneomfagcrooswttathumratisee(xEp,Crseos)s.edThaissthe 3 tefhfeecctomcponucteenrtrpartoigonraamnmdetTheO9X5E%DcOondfeivdeenlcoepeldimbiyt wVeKrIe(cDaelcnumlaartke)d,byastshuemuisnegoaf ltroagtairointshimnihcinbiotrimnaglgrdioswttrhibruattieon1o0f%daatna.d 9T0h%e (pEr.oCg1oraamnmdeE,aClrsoo)c.alculate concen- NOEC: fCaacltcourlaAtNioOn VofANfOoEllCow(eNdobOybBsoenrfveerdroEnfifsecptroCcoendcuernetrfaotricono)mpias rdionngeebaychsingleconcentration mean with the control mean. TESTRESULTS: Table 1. EC and NOEC values obtained with Skeletonema costaturm. COMMENTS: VALIDATION: Testowbance FBrCa-n2d0A3 FLiFght Water ECo 13 (83-18) ECp 8-8) 0ECw >100 NOEC: 32 iVVnaatlleuenesasilansdeaircceaatilnedcciuoclantcaeetdnb.eidrNahtOeiEcnsoCmgsiprveuincgapl1rc0%ou,lgar3t0aeb%mydaweniTdnO9X0tEh%eDncOhoim(bpViKui,iornDopefrrgomrgaorw)at,mhmarenaGtder9a5Up%nhcibosondfSimdalnct.e3.0. Tduhreinrgeswulhtiscahrethbeasgerdowotnhgirsocwotnhsirdaetresedfotrotbheeetxipmoenesnptainal0 i-n7t2heb,cotnhterpoelrciuoldtures (see growth curves). Tcehlel dveanlsiidtityyicnrcirteeraisaedgibvyenainfatchteorotefstmoprroetotchoalnar1e6 fiunlftihleletde,stinpetrhaitodthe control (vcaorryrbeyspmoonrdiengthtaona1g,0rounwitths rdautreiofnmg othreetetsthaannd0,t9hde"7),2 thhoeurcsonttersotlrpesHultdsidwintoht 3,5-dichlorophenol was in the range normally found. LSaabm.plreef.renco.e:ived.: Test period: Report date: 993122 20.09.99 04.07.1099 06.01.2000 Rs Nore Elin Horve Engineer Analytical technician HHilo , Age Molversm, Senior Research Scientist Quality Assurance Enclosed: Data sheets "fToismeotthrrephoartniinsfuull,dwbyiatbtoherhpaeoorrmyiusascietornediinedwbryiNnobrgywegRiFan- MAicjcoribe.tion (NA). Th report may not be reproduced any 000692 Liarbreet. Page 7os31 PRIMARY DATA: Growth inhibition test with Skeletonema costatum Test substance: "FC-203 Light Water Brand AFFF" StLaarbt.darteef:: 09943.1120-29 MeasCuornce.meunntit:: mThge biomass was measuredbyfluorescence; values in fluorescence unis fm 7 [Gow oH Concentration | 041.1400.599]| 050.9102.599]| 061.1008.099|] 071.01:04.099| | arya-te1|| Ctoartrioen- aoftteensdt 00 001115 || oasses || s7z9 || ssoe 221340|| 0o5s9s7 o0 0o1t3a || oosses || 654 || ase 220279|| 00559997 o ot | os2 | 63 | a8 206| 0599 ] 0 0.12 0.71 74 55 2.20| 1.000 032 013 | os2 | s2 | e 220 [ 1.000 032 013 0.77 96 6 2.32| 1.000 032 0.14 0.84 12.5 7 243| 0.999 oo1m4 || ooers 016 | oes o7s0 224316|| 00559969 8s & 213| oso aazz ooiw| [oossss || 781 || e=s 220152|| 00559907 32 012 06 86 50 0o116 || 0o3sss || 4e4s || e4e8 2.17 | 0.939 212729|| 0og9rsa ot | 06 | 76 | es 209 | 0994 22 0011a2 || o0ums || assa || a4s 210856|| 00995920 013 | 03 | 36 | a 179| 079 110000 00019|| 00108s || 0013 || 1o3as||| o[eoso |oser 100 0.08 0.06 0.21 13 052| 0.784 -- ReferTe5ncmeoslubs|tance01(345-|ichio0ro4p7he|nal):185 TR [05% 115smmgot | o0t1s6 || oosas || 1v4ass 111199|| 01.0s00 Mean va0lues: 0312 a1z0 1200 Reference subst] w os |sos | | 150 | ee 727355| [1.0050%0 _. o01155 || 0o7s || 170 || esss 221310|| 0os5s9s7 o01s3 || ooss || 47 || e3o 210930|| 00559818 009 | oi 0 1 039| 0917|eresiaive 0.15 |045| 16 | 85 |[7:26[1000] Swoimonarneorsnce "660693 } gLasbirae2t. Pagesofl GROWTH CURVES: Growth Inhibition test with Skeletonema costatum Test substance: "FC-203Light Water Brand AFFF Lab. rot: 990122 i Control 7s N ] <0 314 i 2M a = oF onsnton neol| omme El$l 81 Lis 2a uw = aT anionpom ' 1 mg Is i L3o al test raion (hours) "1 32 mgt 5s! of L gal A 5) test craton (ours) La] 10 mgt i2 3Ny. a= 37 tron ny Po ' 100 mon Ii3 bTaga + nan) ial 32 mgt ia I2a .= - - et ssn ous) -- 000694 Labrefro 99312:2 Page voy 31 wIinthhi:bition of the growth of Skeletonema costatum mg/L (FC-203 Light Water Brand AFFF) Experimental data: cFCo-n2c0e3ntrLiagthitonWaitner Brand AFFF Growth rate Iinnhpiebricteinotn cCoonnttrrooll 21 CCoonnttrrooll 43 i Ccoonnttrooll 5 Control mean : 00.13322 032 1.1l0000 1l00 3.32200 320 1100..0000 10.00 3322..0000 32.00 110000..0000 100.00 22.031 . - 221.2097 - -- 2.210260 -- 2.19 220.3320 00.00 2.6 00 22.3a6 00.00 2013 28 220.1025 63.35 21 ilo 21.7282 18103 .0 200 als 12..0856 156.s1 1178 183 0.0l060s 10700.30 --- 0.52 76.3 STATISTICAL PARAMETERS CALCULATED FROM CONTINUOUS RESPONSES 5 doses and 11 responses have been used during calculations. : EEC1S0o:: 6131.9353 9955 %% ccoonnffiiddeennccee lliimmiittss :: (( 488..2295 .... 1883..4160)) EC 50: 288.00 95 % confidence limits : ( 186.95 .. 562.40) Coefficient of determination :0.763 000695 LGoasb1rie J Page 100rs1 TEST FOR TOXICITY Marine herbivore: Acartia tonsa 000696 S93132 RE TEST REPORT ACUTE TOXICITY TEST WITH THE MARINE COPEPOD Acartia tonsa Qa Iii Ee RE Te RESEARCH TEST SUBSTANCE: "FC-203 Light Water Brand AFFF" TEST RESULT: ' `The 48 hours LCso was calculated to 200 mg/l. The test substance was supplied by Novatech, and the test results relate to this product. TEST DETAILS: METHOD: ISO/DIS to marine 14669 - 1997: Water qualit-y Determination copepods (Copepoda, Crustacea). ofacute lethaltoxicity TEST ORGANISM: Acartia tonsa (Dana), supplied by the Marine Biological Laboratory, Universityof Copenhagen. CULTIVATION: The test organisms were supplied as eggs, and were cultivated in accordance `with the "Paris Commission - Ring Test Protocol" (VKI). Large copepodites and adults were used in the test. PREPARATIONS: INCUBATION: prior to use. = Natural seawater (salinity: 34 %s) froman unpolluted site in Byfjord was used as basis for the dilution water. The water was filtered through a GF/C filter in ``Tmegs/tl swoalsutpiroenspawreerdebpyrsetpiarrreindgf0r.o5m01a7sgtroackmssoolfutthioen.prAodsutcotcikns1olluittrieoonfodfil1u0t0i3on `water. Other concentrations were prepared from this stock solution. `Th 25 e test was mloftest run in glass containers (28 ml rolled solution and $ animals4, replicates rim vial for each s) each contain concentration. ing The_ vials were kept undear 16l/8h light/dark photoperiod at a temperature of 201C. pH and oxygen measurements were performed as indicated on the data sheet. 000697 SL9a3b1r3i2e. rege eon DATA ANALYSIS: CALCULATIONS: Tahperoedfufcecttloetnhatlhetosu5r0vi%voaflothfeActaesrttiaanitmoanlssa (iLs Cesx)p.resTsheed casomtbhienceodncmeonrtaraltiitoyn of per test concentration were used for calculation. The 24 hours and 48 hours. LC values and the 95% confidence limit were calculated by using the standard procedure PROBIT Analysis, National Swedish Environmental Protection Board (Version 2.3, 1990). This programme also calculate test concentrations lethal to 10% and 90%ofthe test animals. NOEC: CfaacltcourlaAtNioOn VofANfOoEllCow(eNdobyObBsoenrfveerdroEfnfiecptroCcoendcuernetrfaotricoon)mpiasrdionngeebaychsingleconcentration mean with the control mean. TESTRESULTS: Table 1. LC and NOEC values obtained with "FC-203 Light Waier Brand AFFF". Acaria toma 24 bows 48 hours ice 160 (84-220) 76 2-110) Ca 340 (260-460) 200 (140-270) Lon 740 (530-1400) 510 (350-1100) NOEC: 10 100 cVReootlcetosmeipdntdbiecyartPeRo1O0Bm%IT3s0a5noayadp,h9aP0no9dde5o3rnlcy0a.oferm4eadr48 ecurrei.inUacnrle, mNgO.E Vearleuce ree reby `VALIDATION: `oTxhyegveanlicdointcyecnrtirteartiiaogniavtetnheinetnhde otfestthpertoetsotcwolasargerefaultfeirltlheda,noinrtheaqtutahletdoi4ssmogl/vle,d the percentage mortality in the controls was less than 10%, and the 48 hours LCxof3,5-dichlorophenol (reference) was in the range normally found. Lab. ref. no.: Sample received.: `Test period: Report date: 993122 20.09.99 06-08.10.99 06.01.2000 Neon Elin Horve Engineer Analytical technician < Kan Age Molversmyr Senior Research Scientist Quality Assurance Enclosed: Data sheets Toormmeathrepaornt vuel dwbhy abortporeyrSseoendw ed y Non orwyeRgFia-nMAcorhe:iion (VA). Thereporayt nb reproducnedy 000698 wiiiz PRIMARY DATA: Acute toxicity test with Acartia tonsa Testsubstance: "FC-203 Light Water Brand AFFF" MSLtaeabar.tsdueartt:eem:ent: s06s.a1r02.929 Numobfdeeard | | concentration (mon Total | Nsupmebceimreonf number | pr. vessel |Specimen| A c E | A prconc. | 8 0D F | 8 NUMBER OF DEAD 24 hours 43hours | CE DF | Tow | BADCFE LaI |i __coma { l| i I) 000001 555000 0 10 010 5 0 IE001 | ! 2i 01 i 20 7 wd =a, Reference substance(3.5dichlorophenol: 555020 1.0 mgh 555 | 100 _ 1 | The result with the reference substance is within the range normaly found. 000699 993122 - M [sa 1 "ers | | e e Come T | oooh] T mo on aT | e] n a]J oo To] [=[ew w o] [ =Tw we [ew TT LT 000700 5 993122 - TEST FOR TOXICITY | Marine Amphipode: Corophium volutator 000701 Labret i 993122 Page 16.of31 iil TEST REPORT ACUTE TOXICITY SEDIMENT TEST WITH THE 3 MARINE AMPHIPOD Corophium volutator Q RF om15sa Ke ROSALAND RESEARCH TEST SUBSTANCE: "FC-203 Light Water Brand AFFF" TEST RESULT: - The 10d LCso was calculated to >3060 mg kg" dry weight sediment. `The test substance was supplied by Novatech, and the test results relate to thisproduct. TEST DETAILS: METHOD: `ATSoxTicMityE1T3e6st7s-9w0i,thStMaanrdianred aGnudidEestFuoarriCnoenSdeudcitmienntgs.10 day Static Sediment 1 TEST ORGANISM: Corophium volutator, from an unpolluted site near Trondheim. CULTIVATION: The test organisms were supplied as adults (4-8 mm in size) and were held in aerated seawater at 15C. feeding. A small amountofnatural seaweed was used for PREPARATION: INCUBATION: Natural seawater (salinity: 34 %) from an unpolluted site in Byfjorden outside a`Swntaaaslvyausnsegededrffoworraopsrrgueaspneairdcifncogorntdteiesltnutsteiadonindmwepanrttoespr.o.rTtSiheoednissmeiedtnitfmoecrnoetlaliecschtaetemdsuta,tddayn usnapnodllauntdedwasiste _ Each test concentration was prepared by adding the product in 600 grams of damp sediment in a plastic bucket. 200 mlofseawater `was added and the bucket was shaken for3 hours. The sediment was divided into three beakers, 400 ml of seawaterwas added to each, and the beakers were aerated over night. 10 animals were then randomly selected for each beaker. A sample of the damp sediment was analysedfor water calculated as mg kg" sediment dry weight. content, and all concentrations are `The test was run in glass containers (600ml) each containing 200g oftest sediment, app. 400 mlofseawater and 10 animals, 3 replicates for each concentration. The beakers were kept under continuous aeration at a itnedmipceartaetduroen otfhe15da+ta1shCe.et.pH and oxygen measurements were. performed as 000702 . Sos122 DATA ANALYSIS: (CALCULATIONS: The effect on the survival of Corophium volutator is expressed as the concen- 3 tration of a product lethal to 50%ofthe test animals (LCso). The combined `mortality per test concentration were used for calculation. The 10 day LCsy `value and the 95% confidence limit are calculated by using the standard a T 2P.R3,OB19I90T).AnaTlhyissisp,rNoagtriaomnamle SawlseodicsalhcuElnavtiertoensmtecnotnaclenPtrroatteicotnisonleBtohaalrtdo(1Ve0r%siaonnd x 90%ofthe test animals. E NOEC: Calculation of NOEC (No Observed Effect Concentration) is done by single- aE fcaocntcoerntArNatOioVnAmefaolnlwoiwtehd tbhye Bcoonntfreorlromneiasn.procedure for comparing each & TESTRESULTS: Tarblee 1. LC anTd ONORESC vialliueessosbrtiaiancetdvwiitthF"FCO-2S03ULighPt WaNterBBraandAAFTF" = Coraphium volutator 10 days 3 Lu >3060 E Lea >3060 A LCs ---- >3060 : `R NoEc: X 3060 VVGaallrueessaianpediccpmaaStleae1u03%t0,abi5d0y%PaRnOdB9I0Ta%lnetthasli.ty N after O 1r0deacyasE.lcUlntiC etdsibnymg kcgo'mpsuteerdriodgrmyyoewmeinmgshtt. i 3 VALIDATION: The validity criteria given in the testprotocol are fulfilled, in that the dissolved `Oxygen concentrationatthe endofthe test wasgreaterthan or equal to 60 %, 3 the percentage mortality in the controls were less than 15% and a test with & iFslufooruanndtetnoebe(rweiftehreinncaec)cweapsteidn ltihmeitrsanfogre onrogramnailclcyofnotuenndt.anTdhesilstefdriamcteinotn.used 3x e ee ee Table 2. Characteristicsofthe sediment used for testing -- 35 anc conten (46) 07 Sit fraction (4) 0s i eee eee 1 Lab. ref no: 93122 Qu Yon To Hepes } 3 Sample received.: 20.09.99 Elin Horve Age Molversmyr `Test period: 03-13.12.99 Engineer Senior Research Scientist Report date: 06.01.2000 Analytical technician Quality Assurance : Enclosed: Data sheets Tfoim eirhethparrinFtlewhutohrepysedrinrbsiyNgobivyeRgFioMATcntion(VA)Toreproymtbrodeny~ 000703 9312.2 PRIMARY DATA: Acute toxicity test with Corophium volutator 3 Testsubstance: ~~ "FC-203 Light Water Brand AFFF" z% LStaabr.t edta:te: ss122 02.1299 i Measurement: Numobfdeeard : Total | Nsupmecbiemreonf NUMBER OF DEAD | number | pr. vessel Says 10days [Comncecnra tyrwaetiigognhy||Sppre.ccoinmce.n| A8 GD EF | A[8B CDFE| Tol | AB CDEF| Tow i 1100 1100 1100 000000 : 5 o1.1 0 10 10 2 iI ; | oo|=] cer 10 10 10 EEE 1 | wo |=| cnr IEEE % Referencesubstance(fluoranthene): _ 5 i 10 10 10 _ 322 7 x The result with th reference substance i within the range normally found. | 000704 Laatbrset Page 19131 Test substance: "FC-203 Light Water Brand AFF" LStaabr. craet:e: s0s.s1r22929 MeasurofeoxmygeenanndtpsH. [ sm Ten Twas | moaryweiagny| ey -0- To eee i [ T C | 1TT | | EET meterence substance (tuoranthene): __ _ 12 : --. . 000705 . si page 200731 z DATA SHEETS | | | l E23 _ i F i* x i 000706 LEabrHefros Page 210731 HNS-DATASLAD (Selse-, Miljs- og Simmernesedecanion) Dsorksucmaesnctenrz. : 10023/8101/4907 SUksrgeivtees us : 0131//1111//3988 vSiedresio|n 1 +av 0s.0e0y TjeulSe-fdoant:abl6a3de8t47e5x 0u0ta/zbTeelldeefsaxa:v M6i3lj3o4av1d3elsisngen ved 3 Norge A/S. 1 IDENTIFIKASION AV KIEMIXALIET OG ANSVARLZG Fm. Importer: u Norge A/S |1 sendelFsCn-a2v0a3: LIGHT WATER BRAND AQUEOUS FILM FORYING Fon i| Dekleoznaszj.o:ns0n0u2m6e1r4., Produksregisseres: 1 2255 13 00 Telefon, Giftinformasjonssentralen: 2 OPILYSNINGER OM KITwosk SAMMENSETNING. fnfomesion on enkeltkonponentes, faresymbol(er) og risikosecninger stormav van easnr vExz-zRosEN _ 2-((PI2E-T3YUL0EKNSGYL=YrKOOKSLYM)O-N=OTSAUNGTLYLEER/T) 3122051840s5 36sas 1,2-2FTaazepsTy0mrboler/zisikosesninger: Fazesymboles/risikosetninger: xi; xn; R36 R22 107-2101 - 20 TSFEOLSNUTTGEERRTAILASKVKYELOTODGVEAErNRzIFRSLGKAEETNTEFEALRKTUIOVREIESWTIOGFAFLEIRER TTrraaddee sSeeccrreett Trade Secret i1oss Ikke Rivas rg re -- i i 000707 hisi Page 20p31 FC-203 LIGHT WATER BRAND AQUEOUS Fri FORMING FORM Vikeisese skadevimminger ---- X23 ircicere oynene og huden. PH] sterner: . WijotSeprees:istevall. rorarssmre. : | i PH: Tiltak eyne: Saklydlel rsmserank:s oynene med rikelige mengder vann. Koncaks lege i| SKCoI--sLaLkahudreengemed sikebise messes vam. Hvis ixisassonen vecvaras, | TiltegKkBirosiinssneinndsaenysdmiiptnnteggoe:ansKeirtdcaons.etSso,lybfroirngrviesckkofmeen.deSebiosssspfmrsatomene vadvarer, TeakDfKeocsanivtseyailkngianklge:gpeersuosniedldle.tnaGcis.alaFrrsemknaelslSb3reemmkenninmgeeraknuntilsoermcibdrmeetd on 5 Tima VE smi. SametPrbordaunknzseusknaixngoatnbirddaentes Lukkingsmiddel. Tike snes. bramnsioknngamidders || Eksponezingssisixe ved bran: i[1]| romsre-nni.ngsproducser ved beam: . i | Prosedyzer ved siukking av bran: J - 000708 its Lab.refno. Page 23of 31 $m ve ores ve, [S-- e vetn-- atilea-- k andes andre punkeer desce Bs-dacabiadec, i FilsaSScknecvrkeitireerestnpleoadtmivncmeienness.lvPeSelsoatesiispeecrbSeussEteoIrnssSnseoriSnfnoRncmeIp.enLv2u0%AeE, RvieItnseSt ar | Se banks 13, Fieining av Fjerning av kjemikalieavfall: kiemtkeliosvteil-. : 7 BANDTIRING OG 0PP3ZVARING. Setingelser tor sikker oppbevscing: MnSSbeeelthsoiitakeiklaeel.reerlnaLgaTsrsuteegetsurtniicvLteooaomksre:iirdeeTmarpHsiestrhesvspvoaerrvoeepmsdreoesdsnouoenkmttmeestrdaenpkanaennnniekfnoomnCemereoneiEd kfoEonnttaa,kkte med | Utoren:etise masesiatess : --G--aphevas ansallasien oi at godt ventilers sted, ! | Sikeshesstiteak for & forhinre beam: ! SikkeTsheersescteimlouanks,for A fomhindsa ssplonjons Sikkezhetstileak for forhindze stasis sloxsrisivecs i | [BE pTSHooSrylaokdbdeLneuimktobtegaslklfaoaangssjliSregnooeysktkiedtnteigtkvotmlfepuonokrsnkkeeetrSs.ieinakgbeRseoppyFrkiooitednaugckpesfmeonrroibnkuaedantrn:bddreaUnnnnmnndeeeesr. berSeukpSuaonvikere1e0, =| = i| a|l 8 EKSZONERINGSKONTAOLL 0G PERSONLIG VEANZUTSTER. i 000709 Ce 99312-2 Page 240r31 3 /: | 7-203 L1cur waTER BRAND AQUEOUS Firs romING FON oyevern: vUnenrgnhebz&ill3erdemmpe,d svepnrsaiyieerl.ler thke i eynene. Bruk tette Hhagve2r:nu:k egnede vernehanskes ehibnedftaelreisn:g Bevucpyriodukter. Vaevhrneesnsainkseksemresasvigfolmgaetnedreialmeeevreidale(r) gumni AnnesUnhnusdtvashnudkeonnasahkien.dvesn: Andedretssvern: . oS&U7nPgnaglLndui)fscikfneoonritcnukadzjmieepnnnegssraaiodvngngdelervudafzsiiekbtelatfrrsoebvrteemiridmnsas:ecaesrmphioaaarsilttveiam.xrsiesekn3reB:avsmeeaelr/gdt7eispFsdi:le.snkoonnasvemnfotoriagsejnosneen Svelging: hpDeretondduenkndteeitek.xkteeVrasspkihsieunstd,staesrditrneigkkoeomsgridfeeolrrlserpgriruseniydnkigeg.smeudndesrdpearboegidvanmne.d Vask . || AsbefaHluoitdskjveeunnttssiulEgannsdijenodgnzs:evsetnssvialcsnsobnenyitkikees.exSteiqlstfroesxkseillissi,tenmkkeseigynec #viennitniilsatsijeosrivselinkoramtesdanosgk/oelnlseerntskeesaitornoalnieerhsoalcdaers eainideers ssiirsee.falte Adn. nome: for forurensning i srbeidsatmostare, Tebruer 1996: VAN A(m7m7e3s2k-n1i8n5ge)s: Ingen sea. osm. 2(3S--t3iUneIr0s KvSesYdS)i-TSs0ToAKm:NSOYL35 / (DIZTYLENGLYKOLNONOBUTYLETER) (112-34-3) A(aImnegzeknninnogressk: aAdmn.ezinkoamns.k grenseverdi anbefalt av produsenten. -- 12-Em8a-tiiinoenss (v1e0s7d2i10p1o)m: S-timers vesei ma/m3: L(os.tov()asev) TTaakkvveerzddit mppgm/:m:25 - ((sdeammgp)) I SYNISTAItSmKeErknDiEnTgEeRsG:ENTIEnRgen(Tarcaad.e nsoercmr:et) FLUGRAAnLmKeYrLknOiVnEgReFsL:ATIEnAgKeTnIVEadnS.TOnPoPrEmR. (Trade Sectet) RESTERS-AtVineOrRsGANvIeSrKdEi iFLUngO/RmdK:IE0W,I1KALGIrEeRn,se(vTerraddle Saencsreefta)lt av an. 000710 s59u31n3s3. Page 250731 FC-203 LIGHT WATER BRAND AQUEOUS rz romsmvG ros PPR Ge mane manasa, ss:Tilstandsform, farge, luke: Fokepunke/-ntervatl: Smeltepuake/-interval: Flamesuake: Setvantennelighes: SKeslosjonsszenses, nedze: Exszlossonsgzenser, avee: Denperykk: Loselighet 1 vana: ce. ns Klar, ravfarvet vaske. : a. 100 C (sesyanende) Ikke zelevant Ingen (Setatlesh cc) Ikke elevant Ikke zelevane Ikke zelevant avi.zon1z4e.n3semrdastuz)(Kalkutere Slander. Spesifikk vek:: Dematecshet: ca. 1.05 (vann=l) ' evi1zo2e1 (Lafond) (xetkuters Fikeise osganiske forbindelser (VO): v=i5a7s8. 4/1 sera Kaestert Fosdumpningshassignes: <1 (setylacesaza Viskositet: - Ikke kjent : - SER arT Foxhold som skal unaghs: Lo MateriIakkleesksionme.skal unnghs: 0 FarliTgsfeoaerrtvsmeepernartlmeetaslnlieoinskkgiksaepperos&ocsdirukKeklepeerrrrbe.sosnednDiteoekkosmipdo.nerwiyndgrogaeyntalruuokrsifae.cdiGyitebirgienidoanmper, cs moon sisire 00ot11 LSaibrresiar Page 260p31 FC-203 LIGHT WATER 3RAND AQUEOUS FILM FoRMENG FORM SeebilSieecdeisleo!g fraermiclcsivipvoelny:merisasion vil ikke foekomme. 11 oprLvswINGER on meiserane. SttekHHnielrudoyonyee:irzitasjons symproner kan vase redhec, hevelse, smester og Bttek#ee1r4huhtu:diesizasgon symptoms ken vere r(eedthzaetr, lhaenvgevlasretyoselKliesre:sfentest Kantake): EttekcEnenormeentska,enlttaKdoinosvgef:roeexsssioin;esing som overstiger anbefelte administrative PomAhveitz,knisnoguniasvhesre,ntmraenlgnisesnvdessysktoeomcedti:nassiyommpsoemvaesr, kemnodveerrne hodepine, rSevzikasnjvoinesreevre,, slerez tale, svimmelhet g i ekstreme tilfeller Isvzeiltsa,sjhoonsti(nsgvieo5lmuefsiivneeieer): symptoms kan vase shhes nese og SttekdBsDeeeytnrst5eelfseovnrpedslraegoikdasugpic:pteeorr,ri:csv,miesedsrloarvsghiaefrneiksvskeaermtsfoelnfufoetLxkeejveeernsttkosarolsmiierbsri,iveiisfooennss,fnimenosercsielt{onn,s BHvfUeelkilualsozesrytaktisjsite,ningii:ckbeairlniyerfseoronmhfrenhndeaamsaktboerlraokgeFisr.aseoDkemstpfoofnroeurrieisrneigsstgsevrvegspiieonhnomoiKrooiindmiesckies _ svelging kan. fore i: - Pieviirnkenning05avrrnsyszmeenrei:ess,ympromer kan vase edusert urinsengde, bled . AKShs0Bop1Pmi%Ker0IrSaSso.ipn)poe:ndsbsl|senydeLmuups0nto3gonemnteLesu.n(kgLtaeunnbnegvtaeeeibrnmeenitenelnnnseenseletilisssneoguA,esKsoeanPnuksstkCveiyevnrlaednesssiLilievearicc.tarrfibsrseeienmpimieeon,drgi.egener -- Inornasjon on allers:, ovefelsomnets ; Keetttzenkallende egenskapess - . 00p712 L9a9b3re1f2i2ro. Page 270731 FC-203 LIGHT WATER BRAND AQUEOUS FILM FORMING FOAM Aevestotfskadelige egenskaper: Reproduksjonsskadelige egenskaper: . Andre5%skraedseyvni'rknviendgreozr,endheelsper:oduktess foresporsel. giftighet er tilgjengelig ph ofDveleturtoezkljepenrngoirdkeuaklttieiedrr,,iennsncoeemhnomludsleoirngeuentnsgeenlkglesnemrealbfeslkoeyrrlebeetroersgealnloeig:sklesaogrmes i kroppen gnieednbtraytttneinegksssptoonfefreirng(emse.taDbeotlitftoerre)l,iggoeg:kainngeankkukmiuelnteereshelvseedeffekser nfdosr dmoennbersukkeesr sforna efkosrpuotnsaetrsingogovierhfeonrsolodrgtainliskveeilfeldunoirnkgj.emikalier i vsFaeossrteezkepolmulsbesleinbseefatovlksoairidsneasnneins1k9e7o0g fdulznuedoneresk.pjoepnauiulksaaslejipoeinsdeermiiosbllooomgdieatsrkbeetiidlsetcadede,nierharav este azbeidere viser ingen skadelige effekter. 12 O22LYSNINGER OM MILIGFARS. PessisDestetnes/apiroodluokgtiessk inencnbernyoslbdaerrheetn: eller flere organiske mfillujoereksjem(iekrasliisesrenstoem).meligens ikke ex nedbrytbare og forblir i Andre skadevirkningez, milje: Nedbrytbarhet: : C33O00C00 22(00Chddeaamggieecrarsls/cO(ox3pyigoe=cnhe1D,m0ei0mc.aanld)Oxy=ge1n,1Degm/agn;d) = 1,1 g/g; : Acvatisk gifeighes: pSrtoemteilsaks)9)6 t=im7e5r0smg1/5l0; for fisk (Fathead minnow (Pimephales Stacisk 96 timess 1CS0 for fisk (Rainbow trout (Oncorhyncus - mSytaktiisssk) 48= t1i3m00ersmg/1l5;0 for daphnia 1600 mg/l (1300-2100 ng/1); (ater flea (Daphnia magna)) = S1t10a0timsgk/L48 (t8i4m0e-s1s30015m0g,/l)A;nfipode (Scud (Gemmarus fasciatus) = v4i8rgtiinmiecras) C=S04,7 mZga/slter(n10O-2y3s4ternaelm)b;ro-larvae (Crassostrea 548/1tin(e1r7s00L-C3S6O0,0 Cmgo/mLm)o;n mummichog (Fundulus heteroclitus) = 2500 000713 La5b9r3e13i1na. eC Page 280731 -- (380710 many; Te1ICsCSy0m(hR2ee.n5sa.pii3nrgas-jfoonr2, KloAxencseteisinvatazrtofaetsdisueosmnlkeuinrdogneeiysdp=) > S icta1s0t01000v0imgrn/eelss;tiengen $953 for aviallshindsering ihe. gieldende forskrifeer. 13 FITNING AY RIMEKALISAVIAL. HeSodSSeoprtetsfalokaxsl-afviieealrllnlei.:ngeLneaavvenrdkjlaeivnniigakslaallniistesinvlisaelnflosroffseonecsiiisytsgiocdektj:ent innsenter, AHmObVeEfDaIlAtTeIGOeRv:ia0l7o:grAuVpEpAeLsL: FRA ORGANISKE FROSESSER. 0ZEU5eANnDcssEcoiRoeKtdrAeeiTrnEuG0gc7Os.RnIi06di0e07r3,106:sdaelsAoivgnfecaneleklrscjfeornasomr2ig8da0ln3eirsakveoffleaktsotetsmmtieoacftiferernr,., sipe, vaskevasker Avfallssofinumer: 7151 Organisk aveell sed haloges. S3esielle Komponenter: inmeholde flosiosbindalses. 14 omaLusuIvGER on Taansmons, orekiasse: siffer: Sokstav: sesgnunser [EE -nurmes: Teno-ktasse: 0G-KLasse: 0G-side: Ssenz.: | wEAG: -- : - - - 5 000714 Lab retro pase 290731 99312-2 "ae PC-203 LIGHT WATER BRAND AQUEOUS FILM FORMING FOAM ourigeTdopplcyrsannisnpgoerss:farliy gods. 15 OPILYSNINGER ON LOVER 0G FORSKAFPTER. Hezkeetikeses SymbolH(EeLnS)E:STAOILIS (Xn) . Inne2h-ol(d2e-sb:usoksyesoksy) -ezanal 35% 7 Eeylensivkel 208 ResetaFianrgleisg: ved svelging. Ken irritere eynene og huden. S-setninges: noUyeaaaneggndkee.rinvnhadznandmiaonngg Ksaocvnotfdafakem:rp/slipergoeoy.ynteneEett:dtkeers.khyulUdlnknogsndstreakkkotsn,tgarkvutansdmkiesdmedmheuddseinzseeorogeg evelnlne.: eVetdikessvteelng.ingK,unktoinltakitndulseegreieolnlghebnrduke. ogIkvkiesbdeernengenstbehtoilidebreeank som medisinsk uistys elle: legemiddel. ti-gruoppe: Koz. yrkeshys. lufchehovs @vrigeOvvaeornpenpel&vynsftnieinnegmeerpchkionpmgromdeeurxkktebeeertsiekreetnttpCehind:tifdrleimogveerre.mMeerksekfion:rgseknrivfitler og vil |CiemviiddleerrtteidmeerrskteaftotresskriafvtefrolgavendJeanmuearrki1n9g3,8. som er basert pd Symbols Ingen Inneholder: 2-(2-3utoksyetoksy)-esanol, 1,2-etandiol UKseninnzgakhisxrkoigntrteuasnkedti.gsmymendeednehsutdoeognrehuodgmeenne.ygndeeUnrnen.vsahnFnirnonmdganndKionnsgtiaokfatfvetdlaemgiep./esypnFraionryetsmeasnsikkyei.l | s5veolfginpgh, huddreink,k tvoaskgelsassstrveaknsn omgedkesnttoerketmelnesgederunisdhdpeelooagrtv.ann. Ved ati-grugoe: 000715 Li abregro Page 300731 FG-203 LIGHT WATER BRAND AQUEOUS Pik FORKING FON SpesieS31.lilkeTTkeoOrlrShosvekSeseEraidStoagsooembnnetKowrlgisaaestfmahoeierttiaitfeseoreir:rltieinegsagokgaiiemsmsirieiiabnmugsiiloanv av elses, Hilje- og ferlige Kienikalier, K53..anTFTmooOrraIaaSskkKteeEeiiLrttLesLmooiontnnjessKtilesaertveaHr.iitaaisseeiortiten.g, aesking av. so sett som En IY ---------------- wits, ravandFeitlsaedsaonnmzehnddess:skunkonsenszas for slukking av bran hydeokarbones, ii| ViktigDsatteablkaidldef(rra) 3 veGdenuetraarlbeiOdffeilcseesn, avSt.EM2Sa-udla,tabMliandneets:ota, USA. i AzsakHBeeSlie)-doipatpuedbabltuledraeidrngt:aosrtesaneenvris,derats.taTaitlepesseJsennyie mTeocrekeEotgh F---- | cIDo7inpkoeldrranaS0entsieinogrsneeoe:mndaouuspaehrbrednsuatutdetnadesdreAospSina-sotdrnammisaSnslgedlaaafcdnoeegrbthiieernaoddfd:eetEchhaeeomeiseitssasorlbdSebiotnkkileoonhvdisbLeeeannnneeirvmreaerirnenyneidsesn Podukees | CE irkeren{sksomabirnaision med andre product sites sav:e cones SEK oY | | 000f16 LaSb5rae%fsre Pege stops FC-203 LIGHT WATER BRAND AQUEOUS PII FORKING PORK i | rotamuoz [ i Er srovursza + oases av DETTE xe-0008-0217.3 aus-oATABLAGET: | u3MmATFF FC-2P0o3 dBsranjonnslukningss | 3M Ione. | ||| 3M ID-nr. i i F3iMghLtiignhgt FWoaatme,r 23c%-A20F3F,F10r0i0re + Fxi7g-Lh0t0ii0gn8hg-00WF7oeu0tn-e,5r r31c-2a0r3,r i20z0e1. # FX3iHFs-nL0ci0ig0nh8ge-00rW6oas9ts-e,8r r3e1-2A0P3F,F ri3c0e% i| i! || | } i . | | |1 | | || | i| . |