Document JNGGv27z5YK6JwLQ2x97GzLNv

If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material Itself does not bum or bums with difficulty.) Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved In fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment MONOCHLOROTETRAFLUOROETHANE 4904558 NONFLAMMABLE GAS UN1021 Monochiorotetrafluoroethane is a colorless odortess gas. It is shipped as a liquefied gas under its own vapor pressure. It can asphyxiate by the displacement of air. Contact with the liquid can cause frostbite. It may only be shipped in cylinders. If material Involved in fire Extinguish fire using agent suitable for type of surrounding tire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved In fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment MONOCHLOROTRIFLUOROMETHANE 4904560 NONFLAMMABLE GAS UN1022 Monochlorotrifluoromethane is a colorless odorless gas. It is shipped as a liquefied gas under its own vapor pressure. It is noncombustible. It can asphyxiate by the displacement of air. Contact with the liquid can cause frostbite. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment MONOETHANOLAMINE 4935665 CORROSIVE MATERIAL, BASIC, COMBUSTIBLE UN2491 Monoethanolamine is a clear colorless liquid with an ammonia like odor. It is combustible and has a flash point of 185 deg. F. It is soluble in water with release of heat. It is corrosive to metals and tissue. Toxic oxides of nitrogen are produced during combustion of this material If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water In flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as tar a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical April 1981 If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing MONOETHYLAMINE 4907635 FLAMMABLE LIQUID, BASIC UN1036 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Monoethylamine is a clear colorless liquid with an ammonia-like odor. It has a flash point of less than 0 deg. F. and boils at 62 deg. F. It is corrosive to the skin and eyes. It is lighter than water and soluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material. It weighs 5.7 pounds per gallon. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate tor a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface ftow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash, cement powder, sawdust, or com mercial sorbents Apply "universal" gelling agent to immobilize spill Neutralize with sodium bisulfate (nahso4) Continued on next page 353 0UCiOO'i-r:z^o If material on fire or Involved In fire Use water in flooding quantities as fog Oo not extinguish fire unless flow can be stopped Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered MORTAR STAIN, LIQUID 4915230 COMBUSTIBLE LIQUID UN1263 Mortar stain, liquid may be formulated with a flammable solvent which has a flash point between 100 and 199 deg. F. The hazard is combustibility. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gfoves. and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water MORTAR STAIN, LIQUID 4910230 FLAMMABLE LIQUIO UN1263 Mortar stain, liquid may be formulated with a flammable solvent which has a flash point below 100 deg. F. The hazard is flammability. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective 356 Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water MOTOR FUEL ANTIKNOCK COMPOUND (OR) 4921445 ANTIKNOCK COMPOUND (THESE MATERIALS MAY CONTAIN VARIOUS HAZARDOUS SUBSTANCE FOR WHICH THE APPROPRIATE RQ APPLIES) POISON B UN1649 ENVIRONMENTALLY HAZARDOUS SUBSTANCE Motor fuel antiknock compound is a variable colored liquid with a mildly pungent sweet odor. It is also a flammable or combustible liquid. It is heavier than water and insoluble in water. It is toxic by inhalation and by skin absorption. Prolonged exposure of the material to fire or heat can result in the spontaneous decomposition of the material. If the decomposition takes place inside a container, the container may violently rupture and rocket. It weighs 13.8 pounds per gallon. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash, cement powder, sawdust, or com mercial sorbents KCb OnOQn 1728, April 1981 Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph-7) Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors MOTOR FUEL, ALCOHOL. CASTOR OIL, AND 4910235 NITROMETHANE (MOTOR FUEL, N.O.S.) FLAMMABLE LIQUID NA1203 Motor fuel, alcohol, castor oil and nitromethane is nominally model airplane fuel or some blends of automobile racing fuel. It has a flash point of below 100 deg. F. It is lighter than water and partially soluble in water. It vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material, if material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in lire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Pereonnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material MOTOR FUEL, ALCOHOL, CASTOR OIL, AND 4915235 NITROMETHANE (MOTOR FUEL. N.O.S.) COMBUSTIBLE LIQUID NA1203 Motor fuel, alcohol, castor oil and nitromethane is nominally model airplane fuel or some blends of automobile racing fuel. It has a flash point between 100 and 199 deg. F. It is lighter than water and partially soluble in water, its vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind April 1981 Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material MOTOR FUEL, N.O.S. 4915236 COMBUSTIBLE LIQUID NA1203 Motor fuel, n.o.s. may be a mixture of any number of liquids. It has a flash point between 100 and 199 deg. F. Its hazard is that of combustibility. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water MOTOR FUEL, N.O.S. 4910236 FLAMMABLE LIQUID NA1203 Motor fuel, n.o.s. may be a mixture of any number of liquids. It has a flash point of less than 100 deg. F. Its hazard is that of flammability. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Pereonnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water MUD TREATING COMPOUNDS, NEC. GAS OR OIL 4915381 WELL DRILLING (COMBUSTIBLE LIQUIDS, N.O.S.) COMBUSTIBLE LIQUID NA1993 Mud treating compounds, nec, gas or oil well drilling are various col ored liquids. They have a flash point between 100 and 199 deg. F. They are generally lighter than water and soluble in water. Their vapors are heavier than air. Continued on next page 357 MOD 000017284 If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water MUD TREATING COMPOUNDS, NEC, GAS OR OIL 4910361 WELL DRILLING (FLAMMABLE LIQUID) FLAMMABLE LIQUID UN1993 Mud treating compounds, nec, gas or oil well drilling are various col ored liquids. They have a flash point of less than 100 deg. F. They are generally lighter than water and soluble in water. Their vapors are heav ier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Peraonnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water MUSTARD GAS (POISONOUS LIQUID, N.O.S.) 4920525 POISON A NA9035 Mustard gas is a clear amber colored oily liquid with a faint odor of mustard. It is not readily combustible and its vapors are heavier than classed as a poison a, and which does not contain any explosive com ponent. By inhalation. The effects from exposure to the material are not immediately noticeable. The material may only be shipped in cylinders and some of these may have to be overpacked in a wooden box. Pro longed exposure to fire or heat may cause the cylinders to violently rupture and rocket. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical 358 aaa'o -c; If material not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered N-BUTYL PEROXYDICARBONATE, (NOT MORE THAN 4919154 52% IN SOLUTION) ORGANIC PEROXIDE UN2169 N-butyl peroxydicarbonate, (not more than 52% in solution) is a col orless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite; but once ignited, it will burn with increasing rapidity as the fire progresses, if spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burn ing of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or Involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet N-ETHYL-META-TOLUIDINE (COMBUSTIBLE LIQUID, 4913189 N.O.S.) COMBUSTIBLE LIQUID NA1993 N-ethyl-meta-toluidine is a light amber colored liquid. It is used to make other chemicals, it has a flash point of 193 deg. F. It is lighter than water and insoluble in water, it vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material. April 1981 ft material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fira Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material NALED (AGRICULTURAL INSECTICIDES, NEC, 4961656 LIQUID) ORM-E NA27S3 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10/4.54) Naled is a white solid dissolved in a liquid carrier, it is used as a pesticide. It is a water emulsifiable liquid. It can cause illness by inhal ation, skin absorption and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team net work. Telephone; 800-424-9300. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates NALED (AGRICULTURAL INSECTICIDES, NEC, OTHER 4961657 THAN LIQUID) ORM-E NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RCM 0/4.54) Naled is a white solid. It is used as a pesticide. It is a wettable powder. It can cause illness by inhalation, skin absorption and/or ingestion. In case ol damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary April 1981 Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates NALEO (INSECTICIDES, OTHER THAN 4961658 AGRICULTURAL, NEC) ORM-E NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10/4.54) Naled is a white solid or the solid dissolved in a liquid carrier. It is used as a pesticide. It is a wettable powder or water emulsifiabie liquid. It can cause illness by inhalation, skin absorption and/or ingestion, in case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--Isnd spill Dig a pit, pond, lagoon, holding area to contain iiquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates NAPHTHA 4910239 FLAMMABLE LIQUID UN2553 Naphtha is clear colorless to variable colored liquid. It is a petroleum product between gasoline and kerosine. Its flash point can vary widely but it is less than 100 deg. F. It is tighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fira and not Involved in tire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Continued on next page 359 MC-D 000017286 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts oi water or soap and water NAPHTHA 4915239 COMBUSTIBLE LIQUID UN2553 Naphtha is clear colorless to variable colored liquid. It is used in some cleaning preparations, as a solvent, and as a raw material in chemical manufacture, it is a petroleum product between gasoline and kerosine in volatiltiy. Its flash point can vary widely but it is between 100 and 199 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. II material on lire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water NAPHTHA DISTILLATE 4910240 FLAMMABLE LIQUID NA126B Naphtha distillate is clear colorless to variable colored liquid, it is a petroleum product between gasoline and kerosine. its flash point can vary widely but it is less than 100 deg. F. It is lighter then water and insoluble in water. Its vapors are heavier than air. tf material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 360 NAPHTHA DISTILLATE 491524' COMBUSTIBLE LIQUID NA126 Naphtha distillate is clear colorless to variable colored liquid. It is a petroleum product between gasoline and kerosine. Its flash point can vary widely but it is between 100 and 199 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water NAPHTHA SOLVENT 4915241 COMBUSTIBLE LIQUID UN1256 Naphtha solvent is clear colorless to variable colored liquid. It is a petroleum product between gasoline and kerosine. Its flash point can vary widely but it is between 100 and 199 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water NAPHTHA SOLVENT 4910241 FLAMMABLE LIQUID UNI 256 Naphtha solvent is clear colorless to variable colored liquid. It is a petroleum product between gasoline and kerosine. Its flash point can vary widely but it is less than 100 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Coot all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical April 1981 nx> oo" o If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handie broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water NAPHTHALENE (OR) NAPHTHALIN (NAPHTHALENE 4940360 (NAPHTHALIN), CRUOE (TAR CAMPHOR, CRUDE)) ORM-A UN1334 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RG-5000/2270) Naphthalene is a white crystalline volatile solid with a strong coal-tar odor. It is used as a moth repellent, fumigant, to make other chemicals, and for many other uses. It is heavier than water and is soluble in water. It will burn though it may take some effort to ignite. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors or dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom if dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates NAPHTHALENE (OR) NAPHTHAUN (NAPHTHALENE 4940361 (NAPHTHALIN), OTHER THAN CRUDE (TAR CAMPHOR, OTHER THAN CRUDE)) ORM-A UNI 334 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Odor. It is used as a moth repellent, fumigant, to make other chemicals, and lor many other uses. It is heavier than water and is soluble in water. It will bum though it may take some effort to ignite. April 1981 If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors or dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts oi water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates NAPHTHENIC ACID 4962356 ORM-E NA9137 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (HQ-100/45.4) Naphthenic acid is a dark colored liquid with a offensive odor. It is used to make paint dryers, detergents, and solvents. It is insoluble in water. It will burn though it may take some effort to ignite, if material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors or dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Add caustic soda If dissolved, apply activated carbon at ten times the spilled amount in region oi lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors & oO o^ 361 NAPHTHYL METHYL CARBAMATE (POISONOUS 4921446 SOLID, N.O.S.) POISON B NA2811 Naphthyl methyl carbamate is a white crystalline solid. It is essentially insoluble in water. Material will bum though it may require some effort to ignite. It is toxic by inhalation (dust, etc.) toxic oxides of nitrogen are produced during combustion of this material. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300 If material on fire or Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as tog Use foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing NEO PENTANOIC ACID (COMBUSTIBLE LIQUID, 4913151 N.O.S.) COMBUSTIBLE LIQUID NA1993 Neo pentanoic acid is a clear colorless liquid. It has a flash point of 147 deg.f. and a melting point of 96 deg. F. It is used in the making of other chemicals. It is lighter than water and soluble in water. Its vapors are heavier than air. if material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water NEOHEXANE 4908250 FLAMMABLE UN1208 Neohexane is a clear colorless liquid with a petroleum like odor. It has a flash point of -54 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. H material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire 362 MCD 000017289 Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Oo not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct ilame--evacuate for a radius of 1500 feet If matenal leaking (not on fire), downwind evacuation must be considered NEON 4904563 NONFLAMMABLE GAS UN1065 Neon is a colorless odorless gas. It is noncombustibie. It is lighter than air. It may only be shipped in cylinders. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment NICKEL AMMONIUM SULFATE 4968360 ORM-E NA9138 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Nickel ammonium sulfate is a green crystalline solid. It is used for electroplating nickel. It is soluble in water. It is non-combustible. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not Involved in fire Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates April 1981 NICKEL CAR80NYL 4906050 FLAMMABLE UQUID UN1259 PYROFORIC Nickel carbonyt is a clear colorless to yellow liquid, it is used to nickel coat steel and other metals, and to make very pure nickel powder. It has a flash point of less than 0 deg. F. It is flammable over a wide range of vapor-air concentrations. It is toxic by ingestion and inhalation. It is heavier than water and insoluble in water. The vapors are heavier than air. It may be shipped only in cylinders. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cooi all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohoi" foam, carbon dioxide or dry chemical tf material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius ol 1500 feet tf materia! leaking (not on fire), downwind evacuation must be considered NICKEL CATALYST WET, (FINELY DIVIDED, SPENT) 4916226 FLAMMABLE SOLID UN1378 PYROFORIC Nickel catalyst, wet, finely divided, spent is extremely finely powdered nickel, it is used in vegetable oil and petroleum processing. Its color may range from grey to black depending on contamination. If exposed to air or moisture it may become hot enough to ignite, it is insoluble in water and does not react with water in targe volumes, if material on fire or Involved In fire Flood with water Use dry chemical, graphite, or dry earth H material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted die body with copious amounts of water or soap and water NICKEL CATALYST WET,(FINELY DIVIDED, 4916225 ACTIVATED) FLAMMABLE SOLID UN1378 PYROFORIC Nickel catalyst wet, finely divided, activated is extremely finely pow dered nickel. It is greyish colored, tf exposed to air or moisture. It may become hot enough to ignite. It is insoluble in water and does not react with larger volumes of water. If material on fire or Involved In fire Flood with water Use dry chemical, graphite, or dry earth April 1981 If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water NICKEL CHLORIDE 4966364 ORM-E NA9139 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-5000/2270) Nickel chloride is a brown or green crystalline solid. It is used for electroplating nickel and in chemical analysis. It is soluble in water. It is non-combustible. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental conalderatfona--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Add soda ash Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates NICKEL CYANIDE, SOLID 4923275 POISON B UNI 653 Nickel cyanide, solid is an apple-green powder, it is insoluble in water. It is toxic by inhalation (dust etc.) and by ingestion. Toxic oxides of nitrogen are produced in fires involving this material. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not Involved In fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing 363 oQO Ooov1 /-J ^ NICKEL HYDROXIDE 4963S63 ORM-E NA9140 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Nickel hydroxide is a black powder. It is used to make other nickel compounds. It is insoluble in water. It is non-combustible. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates NICKEL PLATING SOLUTION (CORROSIVE LIQUID, 4930278 N.O.S.) CORROSIVE MATERIAL UN1760 Nickel plating solution is usually a green colored liquid. It is soluble in water. It is corrosive to metals and tissue. It may be toxic by ingestion, skin absorption or inhalation. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible if material not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing NICKEL NITRATE 4918769 OXIDIZER UN2725 ENVIRONMENTALLY HAZARDOUS SU8STANCE (RQ-5000 2270) Nickel nitrate is a green crystalline solid. It is used in nickel plating and to make nickel catalysts for use in chemical manufacture, it is soluble in water. It is non-combustible, but it will accelerate the burning of com bustible materials. If large quantities are involved in a fire or the com bustible material is finely divided, an explosion may result. Prolonged exposure to fire or heat may result in an explosion. Toxic oxides of nitrogen are produced in fires involving this material, if material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Add soda ash Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates 364 Mcr, O' ^0 7 7* 0 7 NICKEL PLATING SOLUTION (POISONOUS LIQUID, 492347S N.O.S.) POISON B NA2810 Nickel plating solution is usually a green colored liquid. It is soluble in water. It is toxic by ingestion and may be toxic by skin absorption and by inhalation of vapors. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with (he material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing NICKEL SULFATE 4966368 ORM-E NA9141 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Nickel sulfate is a yellow green to blue green crystalline solid. It is used to make other nickel compounds, in printing and dyeing of textiles, and for other uses. It is soluble in water. It is non-combustible. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) April 1981 If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in ram or fire fighting water Environmental considerations--water spill Add soda ash Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates NICKEL SULFATE, COPPER REFINERY, CRUDE 4966372 (NICKEL SULFATE) ORM-E NA9141 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Nickel sulfate, copper refinery, crude is a yellow green to blue green solid. It is used in the manufacture of other nickel compounds and in coatings and ceramics and in other uses. It is soluble in water. It is non combustible. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does nol burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Add soda ash Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates NICOTINE HYDROCHLORIDE 4921446 POISON B UNI656 Nicotine hydrochloride is a white crystalline solid. It is soluble in water. It is combustible though it may take some effort to ignite. It is toxic by inhalation (dust, etc.) and may be absorbed through the skin. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers April 1981 Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing NICOTINE SALICYLATE 4921450 POISON B UNI657 Nicotine salicylate is a white crystalline solid. It is soluble in water and is combustible. It is toxic by inhalation (dust, etc.) and may be toxic by skin absorption. Toxic oxides of nitrogen are produced during combus tion of this material. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted tie body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this matenal If contact with the material anticipated, wear full protective clothing NICOTINE SULFATE, LIQUID 4921451 POISON B UN1658 Nicotine sulfate, liquid is the solution of the colorless crystals. It is soluble in water and Is combustible. It is toxic by inhalation and may be toxic by skin absorption, Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Use ``alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticip*ed, wear full protective clothing \<\V .0 O.'0 365 NICOTINE SULFATE, SOUD 4921452 POISON B UN1658 Nicotine sulfate, solid is a white crystalline solid. It is soluble in water and is combustible. It is toxic by inhalation (dust, etc.) and may be toxic by skin absorption. Toxic oxides of nitrogen are produced during com bustion of this material. If material on fire or Involved in fire Extinguish fire using agent suitable for type of surrounding tire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not on fire and not Involved In tire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing NICOTINE TARTRATE 4921453 POISON B UN1659 Nicotine tartrate is a reddish white crystalline solid. It is soluble in water and is combustible. It is toxic by inhalation (dust, etc.) and may be toxic by skin absorption. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodity contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing NICOTINE, LIQUID 4921449 POISON B, COMBUSTIBLE UNI 654 Nicotine, liquid is a colorless to light yellow liquid turning brown on exposure to air. It Is soluble in water. It is combustible. It is toxic by inhalation and by skin absorption. Toxic oxides of nitrogen are produced during combustion of this material. If material on firs or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered NITRATE, N.O.S. 4918732 OXIDIZER NA1477 Nitrate, n.o.s. is a variable colored crystalline compound having the following properties. The material is soluble in water. It is noncombustible but it will accelerate the burning of combustible materials. If large quan tities of the material are involved in the fire or the combustible material is finely divided an explosion may result. Toxic oxides of nitrogen are produced in fires involving this material. H material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible H material not on fire and not involved in fire Keep sparks, flames, and other sources of Ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet NITRATE, N.O.S. (NITRATE OF SODA AND POTASH) 4916731 OXIDIZER NA1477 Nitrate of soda and potash is a white crystalline solid. The material is soluble in water, it is non-combustible but it will accelerate the burning of combustible materials. If large quantities of the material are involved in the fire or the combustible material is finely divided an explosion may result. Prolonged exposure of the material to fire or heat may result in an explosion. Toxic oxides of nitrogen are produced in fires involving this material. If material on fire or Involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers 366 April 1981 0oo 3 Personnel protection Avoid breathing dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet NITRATING (MIXED) ACID 4918525 OXIDIZER, CORROSIVE NA1796 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Nitrating (mixed) acid is a mixture of sutfuric and nitric acids which is a clear colorless to a reddish brown colored liquid. It is soluble in water with release of heat. It is non-combustible, but it will accelerate the burning of combustible material. It is corrosive to metals and tissue. It weighs 14.6 pounds per gallon. If material Involved in fire Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked time), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment NITRATING ACID, SPENT 4930254 CORROSIVE MATERIAL NA1826 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/4S4) Nitrating (mixed) acid, spent is a spent mixture o( sulfuric and nitric acids which is a dark colored liquid, it is soluble in water with release of heat. It is corrosive to metals and tissue. It weighs 14.7 pounds per gallon. ff material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog April 1981 Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective ciothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment NITRIC ACID (OVER 40%) 4918528 OXIDIZER, CORROSIVE UN2031 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Nitric add is colorless to pale yellow liquid with a suffocating odor, it is used to make other chemicals, as a reagent in chemical analysis, for ore flotation, and for many other uses. Is soluble in water with release of heat. It is noncombustible but it will accelerate the burning of com bustible materials and can cause ignition by contact with combustible materials. It is corrosive to metals and tissue. It weighs 12.6 pounds per gallon. If material involved in fire Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved In fire Keep matenai out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective ciothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered Continued on next page 367 a1 Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations---water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment NITRIC ACID, FUMING 4918529 OXIDIZER, CORROSIVE UN2032 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-1000/454) Nitric acid, fuming is a pale yellow to reddish brown liquid giving off reddish brown vapors with a suffocating odor, it is soluble in water with release of heat. It is non combustible but will accelerate the burning of combustible material. Contact with combustible material can result in ignition. It is corrosive to metals and tissue. It weighs 12.5 pounds per gallon, if material involved in fire Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved In fire Use water spray to knock-dawn vapors Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation if material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural time (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment NITRIC ACID, 40% OR LESS 4930242 CORROSIVE MATERIAL, ACIDIC NA1760 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Nitric acid is a colorless to yellow or red liquid sometimes fuming reddish brown vapors with a suffocating odor. It is soluble in water with release of heat. It is corrosive to metals or tissue. It will accelerate the burning of combustible materials and it may even cause ignition of com bustible materials by contact. It weighs 10.4 pounds per gallon. 368 oooovr^- If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact wilh the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked time), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agncultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment NITRIC OXIDE 4920330 POISON A, OXIDIZING UN1660 Nitric oxide is a colorless gas. It reacts with oxygen to give nitrogen dioxide, a reddish brown gas also a poison, class a. It is non combustible but it will accelerate the burning of combustible material. Its vapor is heavier than air. It is toxic by inhalation (vapor) and skin absorption. It may only be shipped in cylinders not equipped with safety relief devices. Prolonged exposure of the cylinders to fire or heat will result in the violent rupturing and rocketing of the cylinders. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any materia! which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered April 1981 NfTROANILINE 4921530 POISON B UN1661 Nitroaniline is a yellow to reddish orange crystalline solid. In the pres ence of moisture it may react with organic materials and the heat of the reaction may be sufficient to cause spontaneous ignition. It is used in the manufacture of dyes and explosives. It is slightly soluble in water and is combustible. It is toxic by skin absorption and inhalation (dust etc). Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved In fire Do not fight fires in a cargo of explosives Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material NITROBENZOL 4921455 POISON Bt COMBUSTIBLE UN1662 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-HXW454) Nitrobenzol is a pale yellow to dark brown liquid. It has a flash point of 190 deg. F. It is very slightly soluble in water, it is toxic by inhalation and by skin absorption. Toxic oxides of nitrogen are produced during combustion of this material. It weighs 10.0 pounds per gallon. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear sell-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder April 1981 Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors NITROCELLULOSE FLAKES, WET WITH NOT LESS THAN 20% ALCOHOL OR SOLVENT 4907070 FLAMMABLE LIQUID NA2059 THERMALLY UNSTABLE Wet nitrocellulose may appear as a white fibrous, pulp like material or a amorphous powder or compressed into blocks or flakes. It is class ified as a flammable liquid because of the flammable properties of the alcohol or solvent. In a fire the material may bum with great rapidity. Prolonged exposure to heat may dry out the material; it is the subject to self-accelerating decomposition. If confined or if large quantities are involved, an explosion may result. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemicai If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Build dikes to contain flow as necessary Wet spilled material before picking it up Keep spilled material wet Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this materiel Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet NITROCELLULOSE, COLLOIDED, GRANULAR OR 4907050 FLAKE, WET WITH NOT LESS THAN 20% ALCOHOL OR SOLVENT, OR BLOCK, WET WITH NOT LESS THAN 25% ALCOHOL FLAMMABLE LIQUID NA2059 THERMALLY UNSTABLE Wet nitrocellulose may appear as a white fibrous, pulp like material or a amorphous powder or compressed into blocks or flakes. It is class ified as a flammable liquid because of the flammable properties of the alcohol or solvent. In a fire the material may burn with great rapidity. Prolonged exposure to heat may dry out the material; it is then subject to self-accelerating decomposition. If confined or if large quantities are involved, an explosion may result. Toxic oxides of nitrogen are produced during combustion of this material. Continued on next page 369 HOP 296 If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Wet spilled material before picking it up Keep spilled material wet Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet NITROCELLULOSE, COLLOIDED, GRANULAR OR 4917184 FLAKE, WET WITH NOT LESS THAN 20% WATER FLAMMABLE SOLID NA2555 Nitrocellulose, colloided, granular or fiake, wet is a white pulp. The dry material is a high explosive. Dry it is easily ignited and burns very vigorously. The wet material will also burn though it may require some effort to ignite. It is insoluble in water. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or Involved In fire Dangerously explosive Flood with water Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Do not attempt to sweep up dry material Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 5000 feet If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Do not attempt to sweep up dry material Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate tor a radius of 5000 feet NITROCELLULOSE, WET WITH NOT LESS THAN 30% 4907060 ALCOHOL OR SOLVENT FLAMMABLE LIQUID NA2556 THERMALLY UNSTABLE Wet nitrocellulose may appear as a white fibrous, pulp like material or a amorphous powder or compressed into blocks or flakes. It is class ified as a flammable liquid because of the flammable properties ot the alcohol or solvent. In a fire the material may bum with great rapidity. Prolonged exposure to heat may dry out the material; it is then subject to self-accelerating decomposition, if confined or il large quantities are involved an explosion may result. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Wet spilled material before picking it up Keep spilled material wet Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet NITROCELLULOSE, WET WITH NOT LESS THAN 20% 4917165 WATER FLAMMABLE SOLID NA2555 Nitrocellulose, wet is a white pulp. The dry material is a high explosive. Dry, it is easily ignited and bums very vigorously. The wet material will also bum. It is insoluble in water. Toxic oxides of nitrogen are also produced during combustion. H material on fire or involved in fire Dangerously explosive Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible NITROCHLOROBENZENE, META, SOLID 4921458 POISON B UNI 578 Nitrochlorobenzene, meta, solid is a yellow crystalline solid. It is used in the manufacture of chemicals, especially dyes. It is insoluble in water and is combustible, it is toxic by inhalation (dust etc.) and may be toxic by skin absorption. Toxic oxides of nitrogen are produced during com bustion of this material. H material on fire or involved In fire Extinguish fire using agent suitable for type ot surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers 370 ,C\ .O.' 0 April 1981 Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material NITROCHLOROBENZENE, ORTHO, LIQUID 4921457 POISON B UN1578 Nitrochlorobenzene, ortho, liquid is a clear yellow liquid. It will bum though it may require some effort to ignite. It is heavier than water and insoluble in water. It is toxic by inhalation and skin absorption. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered NITROCHLOROBENZENE. PARA. SOLID (PARA- 4921459 NITROCHLOROBENZENE) POISON B UN1578 Nitrochlorobenzene, para, solid is a yellow crystalline solid. It is used in the manufacture of chemicals, dyes and agricultural chemicals. It is toxic by inhalation (dust etc.) and may be toxic by skin absorption. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical if material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Pereonnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material April 1981 NITROGEN NONFLAMMABLE GAS 4904565 UN1066 Nitrogen is a colorless odorless gas. It is noncombustible, it can cause asphyxiation by displacement of air. It can be shipped in cylinders, cargo tanks, or tank cars. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Attempt to stop leak if without hazard Personnel protection Wear protective gloves and goggles Do not handle broken packages without protective equipment NITROGEN DIOXIDE. LIQUID 4920340 POISON A, OXIDIZING UN1067 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Nitrogen dioxide, liquid is a reddish brown colored gas which becomes a yellowish brown liquid on cooling or compressing. It is shipped as a liquefied gas under its vapor pressure. Its vapor is heavier than air. It dissolves in water forming nitric acid, a corrosive material. It is toxic by inhalation (vapor) and skin absorption. It is noncombustible but it will accelerate the burning of combustible materials. The cylinders and "ton container" tank cars may not be equipped with a safety relief device. Prolonged exposure to fire or heat can cause the violent rupturing and rocketing of the cylinders and tank cars. It weighs 12.1 pounds per gallon. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire) evacuate for a radius of 2500 feet Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment 371 nO$> e\^ NITROGEN FERTILIZER SOLUTION 4904275 NONFLAMMABLE GAS, CORROSIVE NA1043 Nitrogen fertilizer solution is a solution of various compounds and ammonia gas. It contains sufficient ammonia that the pressure of the product exceeds 40 psi at 70 deg. F. The solution is corrosive. Although ammonia is lighter than air, the vapors from a leak will initially tend to hug the ground. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use water spray to absorb vapors If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Evacuation If material leaking (not on fire), downwind evacuation must be considered NITROGEN PEROXIDE, LIQUID 4920350 POISON A, OXIDIZING NA1067 Nitrogen peroxide, liquid is a reddish brown colored gas which be comes a yellowish brown liquid on cooling or compressing. It is shipped as a liquefied gas under its vapor pressure in cylinders and tank cars. Its vapor is heavier than air. It dissolves in water forming nitric acid, a corrosive material. It is noncombustible, but it will accelerate the burning of combustible materials. K is toxic by inhalation and by skin absorption. The cylinders and "ton container" tank cars may not be equipped with a safety relief device. Prolonged exposure to fire or heat can cause the violent rupturing and rocketing of the cylinders and tank cars. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not involved In fire Keep sparks, ilames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear lull protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire) evacuate for a radius of 2500 feet 372 NITROGEN SALTS, AGRICULTURAL, CRUDE 4918762 (OXIDIZING MATERIAL, N.O.S.) OXIDIZER UN1479 Nitrogen salts, agricultural, crude are various colored crystalline or prilled solids. They are soluble in water and may be noncombustible but they will accelerate the burning of combustible material. The material may be found only in containers of 55-gallon capacity or smaller. Toxic oxides of nitrogen are produced in fires involving this material. If material on fire or involved in fire Flood with water Coot all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet NITROGEN TETROXIDE, LIQUID 4920360 POISON A, OXIDIZING NA1067 Nitrogen tetroxide liquid is a reddish brown colored gas which be comes a yellowish brown liquid on cooling or compressing. It is shipped as a liquefied gas under its vapor pressure. Its vapor is heavier than air. It dissolves in water forming nitric acid, a corrosive material. It is non combustible, but it will accelerate the burning of combustible materials. It is toxic by inhalation and by skin absorption. The cylinders and "ton container" tank cars may not be equipped with a safety relief device prolonged exposure to fire or heat can cause the violent rupturing and rocketing of the cylinders and ''ton container" tank cars, and the possible violent rupturing and rocketing of the single unit tank car. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation if material leaking (not on fire) evacuate for a radius of 2500 feet NITROGEN TRIFLUORIDE 4904564 NONFLAMMABLE GAS UN2451 Nitrogen trifluoride is a colorless gas having a moldy odor. It is used to make other chemicals and as an oxidizer for rocket fuels. It is slightly soluble in water. It is corrosive to tissue. April 1981 vrzS9 000^ol ` ^ If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Materiai itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved in fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment NITROGEN-HYDROGEN GAS MIXTURE 4905860 (COMPRESSED GAS. N.O.S.) FLAMMABLE GAS UN1954 Nitrogen-hydrogen gas mixture is a colorless odorless gas. it is easily ignited and may only be shipped in cylinders. Nitrogen is noncombustible and just lighter than air; hydrogen is flammable and lighter than air. A flame can flash back to the source of the leak very easily. Under fire conditions the cylinders may violently rupture and rocket. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered NITROGEN, PRESSURIZED LIQUID 4904566 NONFLAMMABLE UN1977 Nitrogen pressurized liquid is a colorless odorless liquid. It is non combustible. Contact with the liquid can cause frostbite. It may only be shipped in cylinders. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Cool all affected containers with flooding quantities of water Do not use water on material itself Apply water from as far a distance as possible If material not involved in fire Attempt to stop leak if without hazard Do not use water on material itself Personnel protection Wear protective gloves and goggles Do not handle broken packages without protective equipment NITROGUANIOINE, WET WITH NOT LESS THAN 20% 4917180 WATER FLAMMABLE SOLID UN1336 Nitroguanidine. wet is a yellow crystalline slurry or solid. The dry material is a high explosive. Dry it is easily ignited and bums very vigorously. It is slightly soluble in water. Toxic oxides of nitrogen are produced during combustion. The wet material will also burn. If material on fire or involved in fire Dangerously explosive Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Do not attempt to sweep up dry material Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 5000 feet NITROGEN-HYDROGEN GAS MIXTURE 4904567 (COMPRESSED GAS. N.O.S.) NONFLAMMABLE GAS UN1956 Nitrogen-hydrogen gas mixture is a colorless odorless gas. While nitrogen is noncombustible and hydrogen is flammable, the mixture is nonflammable. As hydrogen is lighter than air. it will tend to rise when the mixture is released in the air. It may only be shipped in cylinders. If material involved in fire Extinguish lire using agent suitable for type of surrounding tire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as tar a distance as possiDle If material not involved in fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment April 1981 NITROHYDROCHLORIC ACID 4930243 CORROSIVE MATERIAL, ACIDIC UN1798 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-IOOO/454) Nitrohydrochloric acid is a yellow liquid with a pungent odor. It is a mixture of nitric and hydrochloric acids. Its fumes are irritating to the eyes and mucous membranes. It is soluble in water with release of heat. It is corrosive to metals and to tissue. It weighs 14.7 pounds per gallon. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or lime Continued on next page 373 30 Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment NITROHYDROCHLORIC ACID, DILUTED 4930244 CORROSIVE MATERIAL, ACIDIC UN1796 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Nitrohydrochloric acid, diluted is yellow liquid with a pungent odor. It is a mixture of nitric and hydrochloric acids diluted with water. Its fumes are irritating to the eyes and mucous membranes. It is soluble in water with release of heat. It is corrosive to metals and to tissue. It weighs 14.7 pounds per gallon. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface How using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment NITROMETHANE 4907030 FLAMMABLE LIQUID UN1261 THERMALLY UNSTABLE Nitromethane is a clear colorless liquid. It has a flash point of 95 deg. F. Some contaminants may cause nitromethane to decompose violently under fire or heat conditions. It is heavier than water and slightly soluble in water. Its vapors are heavier than air. It may only be shipped in containers of 110 gallons or less. Toxic oxides of nitrogen are produced during combustion of this material. 374 If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use ` alcohol'' foam, carbon dioxide or dry chemical II material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered NITROMURIATIC ACID (See NITROHYDROCHLORIC ACID 4930243) NITROPHENOL 4963394 ORM-E UNI 663 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Nitrophenol is a yellow crystalline solid. It is used in the manufacture of other chemicals. It is slightly soluble in water, it is combustible though it may take some effort to ignite. Toxic oxides of nitrogen are produced during the combustion of this material. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire end not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors or dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate April 1991 MCD (.>00017301 Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates NITROSTARCH, WET WITH NOT LESS THAN 20% 4917190 WATER FLAMMABLE SOLID UN1337 Nitrostarch, wet is an orange crystalline slurry or sludge. The dry material is a high explosive. Dry it is easily ignited and burns very vigorously. The wet material will also burn. Toxic oxides of nitrogen are produced during combustion. It is insoluble in water. If material on fire or Involved in fire Dangerously explosive Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible tf material not on fire end not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Do not attempt to sweep up dry material Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 5000 feet NITROSTARCH, WET WITH NOT LESS THAN 30% ALCOHOL OR SOLVENT 4907080 FLAMMABLE LIQUID UN1337 THERMALLY UNSTABLE Wet nitrostarch is an amorphous white powder. It is classified as a flammable liquid because of the flammable property of the alcohol or solvent. Under fire conditions it may bum with great rapidity. If confined or if large quantities are involved an explosion may result. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use 'alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involvad In fire Keep sparks, flames, and other sources of ignition away Build dikes to contain flow as necessary Wet spilled material before picking it up Keep spilled material wet Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet April 1981 NITROSYLCHLORIDE 4904330 NONFLAMMABLE GAS, OXIDIZING UN1069 Nitrosylchloride is a yellow to yellowish red gas. The vapors are irri tating to the eyes and respiratory system. It is nonoombustible but it will accelerate the burning of combustible material in a fire. It is decomposed by water to form hydrochloric acid, a corrosive material. The vapors are heavier than air. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use water spray to absorb vapors If material not involved in fire Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or lime Do not use water on material itself Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered NITROTOLUENE 4963155 ORM-E UNI 664 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Nitrotoluene is a yellow liquid or a crystalline solid. It is used to make other chemicals. It melts varying from 14 deg. F. to 124 deg. F. It is insoluble in water. It is combustible though it may take some effort to ignite. Toxic oxides of nitrogen are produced during the combustion of this material. It weighs 9.7 pounds per gallon. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors or dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or tire fighting water Continued on next page 375 MCD 000017302 Environmental considerations---water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom Remove trapped material with suction hoses If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates NITROUS OXIDE 4904340 NONFLAMMABLE GAS, OXIDIZING UN1070 Nitrous oxide is a colorless, sweet-tasting gas. it is also known as handling the situation at hand. It is noncombustible but it will accelerate the burning of combustible material in a fire. It is soluble in water. Its vapors are heavier than air. It can only be shipped in cylinders, 'laughing gas". Continued breathing of the vapors may incapacitate one from If material involved In fire Dangerously explosive Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If material leaking (not on fire), downwind evacuation must be considered NONYL TRICHLOROSiLANE 4934260 CORROSIVE MATERIAL, ACIDIC UN1799 Nonyl trichlorosilane is a colorless liquid with a pungent odor. It is decomposed by water to hydrochloric acid with evolution of heat. It is corrosive to metals and tissue. If material on fire or Involved in fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities o! combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing NORHAUSEN ACID (See SULFURIC ACID 4930040) NITROXYLOL 4921460 POISON B NA1665 Nitroxylol is a yellow crystalline solid or liquid. It is insoluble in water and is combustible. It is toxic by inhalation and skin absorption. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in Hooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on tire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water NONFLAMMABLE GAS, N.O.S. (See COMPRESSED GAS, N.O.S., NONFLAMMABLE GAS 4904515) 376 NUCLEAR FUEL ELEMENTS, PARTS OR 4927415 CONSTITUENTS IRRADIATED REQUIRING PROTECTIVE SHIELDING (RADIOACTIVE MATERIAL, N.O.S,, FISSILE CLASS III) RADIOACTIVE MATERIALS NA2918 Nuclear fuel elements, parts or constituents are various metal rods or shapes for use in atomic power plants. Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful whereas films may be damaged by radiation from relatively low concentrations. Fissile radioactive materials are uranium 233, uranium 235, plutonium 238, plutonium 239, or plutonium 241. In addition to the radiation hazards presented by most radioactive materials, fissile materials, if improperly handled, may be critical. This means that if too large quantities of these materials are permitted in one place a very rapid nuclear reaction can occur. This would not be explosive, but large amounts of radiation would be emitted suddenly and might injure nearby personnel. In case of trou ble with these shipments all unauthorized persons should be kept as far away as possible until qualified people with proper equipment can be obtained from the local or state radiological response team, the de partment of energy, or the shipper. If material on fire or involved in fire Contact the local, state, or department of energy radiological re sponse team Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible ^03 cy: April 1981 ft material not on fire and not involved In fire Contact the local, state, or department of energy radiological re* sponse team Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Keep upwind Avoid breathing fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation Keep unnecessary people out of incident area until area declared safe by radiological response team NUCLEAR FUEL ELEMENTS, PARTS OR 4929415 CONSTITUENTS IRRADIATED, REQUIRING PROTECTIVE SHIELDING (RADIOACTIVE MATERIAL, N.O.S., FISSILE CLASS I) SHIELDING) RADIOACTIVE MATERIALS NA2918 Nuclear fuel elements, parts or constituents are various metal rods or shapes for use in atomic power plants. Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful whereas films may be damaged by radiation from relatively low concentrations. Fissile radioactive materials are uranium 233. uranium 235. plutonium 238. plutonium 239, or plutonium 241. In addition to the radiation hazards presented by most radioactive materials, fissile materials, if improperly handled, may be critical. This means that if too large quantities of these materials are permitted in one place a very rapid nuclear reaction can occur. This would not be explosive, but large amounts of radiation would be emitted suddenly and might injure nearby personnel. In case of trou ble with these shipments all unauthorized persons should be kept as far away as possible until qualified people with proper equipment can be obtained from the local or state radiological response team, the de partment of energy, or the shipper. If material on fire or Involved In fire Contact the local, state, or department of energy radiological re sponse team Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Contact the local, state, or department of energy radiological re sponse team Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Keep upwind Avoid breathing fumes from burning material Wear full protective clothing Wear seif-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation Keep unnecessary people out of incident area until area declared safe by radiological response team NUCLEAR FUEL ELEMENTS, PARTS OR 4928415 CONSTITUENTS, IRRADIATED REQUIRING PROTECTIVE SHIELDING (RADIOACTIVE MATERIAL, N O S. FISSILE CLASS II) RADIOACTIVE MATERIALS NA2918 Nuclear fuel elements, parts or constituents are various metal rods or shapes for use in atomic power plants. Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful whereas films may be damaged by radiation from relatively low concentrations. Fissile radioactive materials are uranium 233, uranium 235, plutonium 238, plutonium 239. or plutonium 241. In addition to the radiation hazards presented by most radioactive materials, fissile materials, if improperly handled, may be critical. This means that if too large quantities of these materials are permitted in one place a very rapid nuclear reaction can occur. This would not be explosive, but large amounts of radiation would be emitted suddenly and might injure nearby personnel. In case of trou ble with these shipments all unauthorized persons should be kept as far away as possible until qualified people with proper equipment can be obtained from the local or state radiological response team, the de partment of energy, or the shipper, ft material on fire or Involved in fire Contact the local, state, or department of energy radiological re sponse team Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved in fire Contact the local, state, or department of energy radiological re sponse team Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Keep upwind Avoid breathing fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation Keep unnecessary people out of incident area until area declared safe by radiological response team NUT MEAL, EDIBLE, (FLAMMABLE SOLIO, N.O.S.) 4917390 FLAMMABLE SOUD UN1325 Nut meal, edible is the ground meat of nuts. Because of the oil content it may be liable to spontaneous heating and ignition. If material on fire or Involved in fire Flood with water If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away OCTADECYl TRICHLOROSILANE 4934265 CORROSIVE MATERIAL, ACIDIC, COMBUSTIBLE UN1800 Octadecyf trichlorosilane is a colorless liquid with a pungent odor. It is used to make various silicon containing compounds. It is combustible and has a flash point of 193 deg. F. It is decomposed by water to hydrochloric acid with evolution of heat. It is corrosive to metals and tissue. Continued on next page tf material on fire or involved in fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing OCTANE 4909250 FLAMMABLE LIQUID UN1262 Octane is a clear colorless liquid with a petroleum like odor. It has a flash point of 56 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water N-OCTANOYL PEROXIDE, (TECHNICALLY PURE) 4919182 ORGANIC PEROXIDE UN2129 N-octanoyl peroxide, (technically pure) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite; but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of combustible ma terials. Under prolonged exposure to fire or heat containers of the ma terial may explode. If material on fire or involved in fire Use water in Hooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible 378 *0^ 000^ Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet OCTYL ALCOHOL, OTHER THAN PERFUMERY 4913158 GRADE (ALCOHOL, N.O.S.) COMBUSTIBLE LIQUID UNI 987 Octyl alcohol is a clear colorless liquid with a penetrating aromatic odor. It has a flash point of 178 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water OCTYL ALCOHOL, PERFUMERY GRADE (ALCOHOL, 4913159 N.O.S.) COMBUSTIBLE LIQUID UN1987 Octyl alcohol is a dear colorless liquid with a penetrating aromatic odor. It has a flash point of 178 deg. F. It is lighter than water and insoluble in water, its vapors are heavier than air. H material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors April 1961 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do rot handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water OCTYL TRICHLOROSILANE 4934270 CORROSIVE MATERIAL, ACIDIC UN1601 Octyl trichlorosilane is a colorless liquid with a pungent odor. It is decomposed by water to hydrochloric acid with evolution ol heat. It is corrosive to metals and tissue. If material on lire or Involved In fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on matehal itself Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing OIL WELL CARTRIDGE 4903325 CLASS C EXPLOSIVE Oil well cartridges are tubular devices each containing not more than 350 grains of propellant powder and having no ignition device or element. Under fire conditions they will explode. If material on fire or involved in fire Flood with water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation if fire becomes uncontrollable--evacuate for a radius of 1500 feet OIL, N.O.S., PETROLEUM OIL OR PETROLEUM OIL, 4915245 N.O.S. COMBUSTIBLE LIQUID NA1270 Oil is a clear colorless liquid to a dark brown-black tar. It has a flash point between 100 and 199 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. Pyroxylin solvent, n.o.s. is the April 1981 If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water OIL. N.O.S., PETROLEUM OIL OR PETROLUEM OIL, 4910245 N.O.S. FLAMMABLE LIQUID NA1270 Oil is a clear colorless liquid to a dark brown-black tar. It has a flash point of 100 deg. F. or less. It (slighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water OLEUM (SULFURIC ACID FUMING) 4930030 CORROSIVE MATERIAL, ACIDIC, POISONOUS NA1631 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Oleum is a colorless to black fuming liquid. It is used in the manu facture of chemicals, dyes, explosives and in petroleum refining. It is soluble in water with release of heat, it is corrosive to metals and tissue. It will char wood and most other organic matter. The heat from mis charring may be sufficient to ignite the wood or organic matter. It weighs 16.5 pounds per gallon. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Cool ah affected containers with flooding quantities of water Apply water from as far a distance as possible Continued on next page 379 0 If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--atr spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment ORGANIC PEROXIDE, LIQUID OR SOLUTION, N.O.S. 4909265 FLAMMABLE LIQUID NA1993 Organic peroxide, liquid or solution, n.o.s. are colorless to variable colored liquids. They have flash points of 100 deg. F. or less. The main hazard is that of flammability. The solution may burn with greater inten sity than the solvent atone due to the oxidizing property of the peroxide. This fire could become extremely violent. If the solvent should evaporate, the peroxide remaining may decompose violently due to heat, even 30 or 40 deg. F. Is sufficient for some. Shock may cause the dried peroxide to detonate. The dried peroxides (rom the solution are very easily ignited. If material on fire or involved In fire Do not extinguish tire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use '`alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet 380 Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet ORGANIC PEROXIDE, LIQUID, (OR) SOLUTION, N.O.S. 4919575 ORGANIC PEROXIDE NA9183 Organic peroxide, liquid, (or) solution, n.o.s. are chemicals having these properties. The solution may either be a liquid or a crystalline material dissolved in a suitable solvent. The liquid or solution may take some effort to ignite but once ignited it burns with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur, contamination with many chemical substances can cause a violent chemical reaction. It supports the burn ing of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment ORGANIC PEROXIDE, SOLID, N.O.S. 4919580 ORGANIC PEROXIDE NA9187 Organic peroxide, solid, n.o.s. are chemicals having these properties. The materials are easily ignited and burn with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided com bustible materials. It supports the burning of combustible material. Under prolonged exposure to heat or fire containers of the material may ex plode. The material is usually not water soluble. If material on tire or Involved In tire Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up April 1981 MOD O00017307 Personnel protection Avoid breathing vapors or dusts Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet ORGANIC PHOSPHATE MIXTURE, ORGANIC 4921464 PHOSPHATE COMPOUND MIXTURE, (OR) ORGANIC PHOSPHORUS MIXTURE, SOLID (OR) DRY POISON B NA2783 Organic phosphate mixture, solid consists of two or more solid ma terials or liquid absorbed on a dry carrier. The mixture may or may not be combustible, and may or may not be water soluble. It is toxic by ingestion inhalation (dusts, etc.) and by skin absorption. In case of dam age to or leaking from containers of this material contact the pesticide safety team network. Telephone- 600-424-9300. If material on fire or Involved In fire Use water in flooding quantities as fog Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ORGANIC PHOSPHATE MIXTURE, ORGANIC 4921463 PHOSPHATE COMPOUND MIXTURE, (OR) ORGANIC PHOSPHORUS COMPOUND MIXTURE, LIQUID POISON B NA2783 Organic phosphate mixture, liquid. Is a solution of a member of a family of chemicals having the following properties. The organic phos phate is combustible though it may take some effort to ignite. The solvent may supress or aid this combustibility. The organic phosphate is very toxic by inhalation and skin absorption. It may or may not be water soluble, in case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300 If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical April 1981 H material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered ORGANIC PHOSPHATE, ORGANIC PHOSPHATE 4921461 COMPOUND, (OR) ORGANIC PHOSPHORUS COMPOUND, LIQUID POISON B NA2783 Organic phosphate, liquid, is one of a family of compounds having the following properties. The material is combustible though it may require some effort to ignite. It is very toxic by skin absorption and inhalation. It may or may not be water soluble. In case of damage to. or leaking from containers of this material contact the pesticide safety team net work. Telephone; 800-424-9300 If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Use foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered ORGANIC PHOSPHATE, ORGANIC PHOSPHATE 4921465 COMPOUND, (OR) ORGANIC PHOSPHORUS COMPOUND MIXTURE, SOLID (OR) DRY POISON B NA2783 Organic phosphate, solid is one ol a family of compounds having the following properties. The material may be combustible though requiring some effort to ignite, it is toxic by ingestion, skin asorption, or inhalation (vapors, dusts, etc). It may or may not be water soluble. In case of damage to, or leaking from containers of this material contact the pes ticide safety team network. Telephone; 800-424-9300 Continued on next page 30& ,00^ O' 381 If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire {Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ORGANIC PHOSPHATE, ORGANIC PHOSPHATE 4920530 COMPOUND, OR ORGANIC PHOSPHORUS COMPOUND; MIXED WITH COMPRESSED GAS POISON A NA1955 Organic phosphates, etc. mixed with compressed gas is a liquid ma terial charged with a gas. The organic phosphate may be lethal by skin absorption and is Ithal by inhalation. The material may only be shipped in cylinders and these must be overpacked in either a wooden or fiber- board box. Prolonged exposure of the cylinders to fire or heat may result in the violent rupturing and rocketing of the cylinders, in case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 600-424-9300 If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use `'alcohol'' foam, carbon dioxide or dry chemical tf material not on fire and not involved tn lire Keep sparks, flames, and other sources of ignition away Keep materia) out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the materia) Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ORGANOCHLORINE PESTICIDE, LIQUID, N.O.S. 4921670 (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL, NEC) POISON B UN2761 Organochlorine pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The carrier may burn though it may require some effort to ignite. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800- 424-9300. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities ol water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ORGANOCHLORINE PESTICIDE, LIQUID, N.O.S. 4S21671 (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC, LIQUID) POISON B UN2761 Organochlorine pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The carrier may bum though it may require some effort to ignite. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800- 424-9300. ORGANOCHLORINE PESTICIDE, LIQUID, N.O.S. 4910542 (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC, LIQUID) FLAMMABLE LIQUID UN2762 Organochlorine pesticide is a liquid or solid dissolved in a liquid carrier, The earner is water emulsifiable. The primary hazard of this material is the flammability of the carrier. It has a flash point below 100 deg. F. It can cause illness by inhalation, skin absorption and/or ingestion, in case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. 382 April 1981 MCD 000017309 If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wear setf-contained breathing apparatus when fighting fires involv ing this material ORGANOCHLORINE PESTICIDE, LIQUID, N.O.S. 4910541 (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL, NEC) FLAMMABLE LIQUID UN2762 Organochlorine pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The primary hazard of this material is the flammability of the carrier. It has a flash point below 100 deg. F. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. H material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical H material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wear self-contained breathing apparatus when fighting fires involv ing this material ORGANOCHLORINE PESTICIDE, SOLID, N.O.S. 4921673 (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC, OTHER THAN LIQUID) POISON B UN2761 Organochlorine pesticide is a solid or a liquid absorbed on a dry carrier. It is a wettable powder. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800- 424-9300. If material on fira or involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers April 1981 Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing ORGANOCHLORINE PESTICIDE, SOLID, N.O.S. 4921672 (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL, NEC) POISON B UN2761 Organochlorine pesticide is a solid or a liquid absorbed on a dry carrier. It is a wettable powder. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800- 424-9300. If material on fire or Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing ORGANOPHOSPHORUS PESTICIDE, UQUIO, N.O.S. 4921674 (COMPOUNDS AND PREPARATIONS (INSECTICIDES, OTHER THAN AGRICULTURAL, NEC) POISON B UN2783 Organophosphorus pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The carrier may bum though it may require some effort to ignite. It is toxic by inhalation, skin ab sorption, and/or ingestion. In case of damage to, or leaking from con tainers of this material contact the pesticide safety team network. Tele phone; 800-424-9300. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Continued on next page 3l0 0000 V7 383 Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ORGANOPHOSPHORUS PESTICIDE, LIQUID. N.O.S. 4921675 (COMPOUNDS AND PREPARATIONS (AGRICULTURAL INSECTICIDES, NEC, LIQUID) POISON B UN2783 Organophosphorus pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsiftable. The earner may burn though it may require some effort to ignite. It is toxic by inhalation, skin ab sorption, and/or ingestion. In case of damage to. or leaking from con tainers of this material contact the pesticide safety team network. Tele phone: 800-424-9300 If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the matenal Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ORGANOPHOSPHORUS PESTICIDE, LIQUID, N.O.S. 4910544 (COMPOUNDS AND PREPARATIONS (INSECTICIDES, OTHER THAN AGRICULTURAL, NEC) FLAMMABLE LIQUID UN2784 Organophosphorus pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The primary hazard of this material is the flammability of the carrier. It has a flash point below 100 deg. F. It can cause illness by inhalation, skin absorption and/or inges tion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. If material on fire or involved in fire Oo not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors 384 Personnel protection Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wear self-contained breathing apparatus when fighting fires involv ing this material ORGANOPHOSPHORUS PESTICIDE, LIQUID, N.O.S. 4910545 (COMPOUNDS AND PREPARATIONS (AGRICULTURAL INSECTICIDES, NEC, LIQUID) FLAMMABLE LIQUID UN2784 Organophosphorus pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The primary hazard of this material is the flammability of the carrier, it has a flash point below 100 deg. F. It can cause illness by inhalation, skin absorption and/or inges tion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Keep upwind Wear boots, protective gloves, and goggles Oo not handle broken packages without protective equipment Wear self-contained breathing apparatus when fighting fires involv ing this material ORGANOPHOSPHORUS PESTICIDE, SOLID, N.O.S. 4921677 (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC, OTHER THAN LIQUID) POISON B UN2783 Organophosphorus pesticide is a solid or a liquid absorbed on a dry carrier. It is a wettable powder. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety learn network. Telephone; 800- 424-9300. If material on fire or Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantilies as fog Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material if contact with the material anticipated, wear lull protective clothing April 1981 ORGANOPHOSPHORUS PESTICIDE, SOLID, N.O.S. 4921676 (COMPOUNDS AND PREPARATIONS) (INSECTICIOES, OTHER THAN AGRICULTURAL, NEC) POISON B UN2783 Orgartophosrus pesticrde is a solid or a liquid absorbed on a dry carrier. It is a wettable powder. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800- 424-9300. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use '`alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing ORGANOTIN PESTICIDE, LIQUID. N.O.S. 4921679 (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC, LIQUID) POISON B UN2786 Organotin pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The carrier may bum though it may require some effort to ignite. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to. or leaking from containers of this ma terial contact the pesticide safety team network. Telephone; 800-424- 9300. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Coof al! affected containers with flooding quantities of water Apply water from as far a distance as possible Use `alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ORGANOTIN PESTICIDE, LIQUID, N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL, 4921678 NEC) POISON B UN2786 Organotin pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The carrier may bum though it may require some effort to ignite, it is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to, or leaking from containers of this ma terial contact the pesticide safety team network. Telephone; 800-424* 9300. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 ORGANOTIN PESTICIDE, LIQUID, N.O.S. 4910546 (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL, NEC) FLAMMABLE LIQUID UN2787 Organotin pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The primary hazard of this material is the flammability of the carrier, it has a flash point below 100 deg. F. it can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to, or leaking from containers of this material contact the pes ticide safety team network. Telephone; 800-424-9300. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol " foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wear self-contained breathing apparatus when fighting tires involv ing this material **Co 12 385 ORGANOTIN PESTICIDE, LIQUID, N.O.S. 4910547 (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC. LIQUID) FLAMMABLE LIQUID UN2787 Organotin pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The primary hazard of this material is the flammability of the carrier. It has a flash point below 100 deg. F. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to, or leaking from containers of this material contact the pes ticide safety team network. Telephone: 000-424-9300. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use ' alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wear self-contained breathing apparatus when fighting fires involv ing this material ORGANOTIN PESTICIDE, SOLID, N.O.S. 4921681 (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC, OTHER THAN LIQUID) POISON B UN2786 Organotin pesticide is a solid or a liquid absorbed on a dry carrier. It is a wettable powder. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to, or leaking from containers of this ma terial contact the pesticide safety team network. Telephone; 800-4249300. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not Dum or burns with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing ORGANOTIN PESTICIDE, SOLID, N.O.S. 4921680 (COMPOUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AGRICULTURAL, NEC) POISON B UN2766 Organotin pesticide is a solid or a liquid absorbed on a dry carrier. It is a wettable powder. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to. or leaking from containers of this ma terial contact the pesticide safety team network. Telephone; 800-424- 9300. If material on fire or Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing 386 ORTHO NITRO ANILINE 4921466 POISON B UNI 661 Ortho nitro aniline is an orange yellow crystalline solid. It is slightly soluble in water and is combustible, it is toxic by inhalation (vapor, dust, etc.) and skin absorption. Toxic oxides of nitrogen are produced during combustion of this material. H material on fire or involved In fire Extinguish fire using agent suitable for type of surrounding lire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as tog Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material OXIDIZER (OR) OXIDIZING MATERIAL, N.O.S. 4918733 OXIDIZER UN1479 Oxidizing material, n.o.s. is material having the property of acceler ating the burning of combustible material. The oxidizing material, n.o.s. may or may not be combustible itself. Prolonged exposure of the material to fire or heat may result in an explosion. This material may only be packaged containers of 55-gallon capacity or smaller. Try to ascertain the exact name of the material. If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible April 1981 MCI) 000017313 M material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing vapors or dusts Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet OXIDIZER, CORROSIVE, LIQUID, N.O.S. 4916545 OXIDIZER NA9193 Oxidizer, corrosive, liquid, n.o.s. is the proper shipping name for those liquid materials having the property of accelerating the burning of com bustible materials, and being corrosive to metals and/or tissue. The material may or may not be combustible itself. Prolonged exposure of the material to fire or heat may result in an explosion. This material may only be packaged in containers of 55 gallons or less. Try to ascertain the exact name of the material from the shipping papers. If material on fire or Involved in fire Flood with water Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors or dusts Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet OXIDIZER, CORROSIVE, SOLID, N.O.S. 4916546 OXIDIZER NA9194 Oxidizer, corrosive, solid, n.o.s. is the proper shipping name for those solid materials having the property of accelerating the burning of com bustible materials, and being corrosive to tissue. The material may or may not be combustible itself. Prolonged exposure of the material to fire or heat may result in an explosion. This material may only be packaged in containers of 55 gallons or less. Try to ascertain the exact name of the material from the shipping papers. If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors or dusts Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without prote Wash away any material which may have coni copious amounts of water or soap and water Wear self-contained breathing apparatus when t ing this material If contact with the material anticipated, wear full p Approach fire with caution Evacuation If fire becomes uncontrollable--evacuate for a radi CW put `ft \ocv \1' OXIDIZER, POISONOUS, LIQUID, N.O.S. OXIDIZER Oxidizer, poisonous, liquid, n.o.s. is the proper shippir, those liquid materials having the property of accelerating thi combustible materials, and being toxic by ingestion, inhalai absorption. The material may or may not be combustible itself.V exposure of the material to fire or heat may result in an expld, material may only be packaged in containers of 55 gallons or to ascertain the exact name of the material from the shipping , tf material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of watei Apply water from as far a distance as possible V If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet OXIDIZER, POISONOUS, SOLID, N.O.S. OXIDIZER 4918778 NA9200 Oxidizer, poisonous, solid, n.o.s. is the proper shipping name for those solid materials having the property of accelerating the burning of com bustible materials, and being toxic by ingestion, inhalation, or skin ab sorption. The material may or may not be combustible itself. Prolonged exposure of the material to fire or heat may result in an explosion. This material may only be packaged in containers of 55 gallons or less. Try to ascertain the exact name of (he material from the shipping papers. If material on fire or involved In fire Rood with water Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 387 MCD 000017315 OXYGEN 4904350 NONFLAMMABLE GAS, OXIDIZING UN1072 Oxygen is a colorless odorless and tasteless gas. It is noncombustible, but it will actively support the burning of combustible materials. Some materials that will not burn in air will burn in oxygen. It can be shipped in cylinders, cargo tanks, and tank cars. If material involved In fire Dangerously explosive Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep sparks, flames, and other sources of ignition away Attempt to stop leak if without hazard Personnel protection Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet OXYGEN (GAS ADMINISTERING APPARATUS, 4904370 HOSPITAL OR SURGICAL, WITH CYLINDER OF OXYGEN) NONFLAMMABLE GAS, OXtDYZING NA1072 Oxygen (gas administering apparatus, hospital or surgical with cyl inders of oxygen) consist of a stand to support the cylinder of oxygen, regulators, hoses and masks. The oxygen is a colorless odorless gas. It is non combustible but it accelerates the burning of a fire. If material Involved In fire Dangerously explosive Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved in fire Keep sparks, flames, and other sources of ignition away Attempt to stop leak if without hazard Personnel protection Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach tire with caution If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible It material not involved in lire Keep sparks, flames, and other sources of ignition away Attempt to stop leak if without hazard Personnel protection Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution OXYGEN, PRESSURIZED LIQUID 4904360 NONFLAMMABLE GAS, OXIDIZING UN1073 Oxygen, pressurized liquid is an odorless, colorless to light blue liquid. It is noncombustible but it will actively support the burning of combustible material. Contact with liquid make many normally hard to bum materials readily combustible. When the liquid contacts combustible or oxidizable materials, an explosion may result. Contact with the liquid will cause frostbite. Leaked or spilled material will readily vaporize to the gaseous slate. It may only be shipped in cylinders. If material involved in fire Dangerously explosive Cool all affected containers with flooding quantities of water Do not use water on material Itself Apply water from as far a distance as possible If material not involved in fire Keep sparks, flames, and other sources of ignition away Attempt to stop ieak if without hazard Do not use water on material itself Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet OXYGEN (LIFE SAVING APPARATUS, OXYGEN) 4904380 NONFLAMMABLE NA1072 Oxygen (life saving apparatus, oxygen) consist of boxes containing cylinder of oxygen, hoses, regulator and administering mask. Oxygen is an odorless colorless gas. it is noncombustible, but it accelerates the burning of a fire. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep sparks, flames, and other sources of ignition away Attempt to stop leak if without hazard Personnel protection Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution OXYGEN--NITROGEN GAS MIXTURE (COMPRESSED 4904440 GAS, N.O.S.) NONFLAMMABLE GAS UN1956 Oxygen--nitrogen gas mixture is a colorless odorless gas. Both ox ygen and nitrogen are noncombustible; however, oxygen can accelerate the burning of a fire. It may only be shipped in cylinders. 388 P-CHLOROBENZOYL PEROXIDE, (NOT MORE THAN 4919220 52% IN SOLUTION) ORGANIC PEROXIDE UN2115 P-chlorobenzoyl peroxide, (not more than 52% in solution) is a col orless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite; but once ignited, it will bum with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burn ing of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. H material on fire or Involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up April 1981 MCD 000017316 UNUSED NUMBERS :. v' s.. '4CD 000017317 Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PACKING OR WIPING WASTE MANUFACTURING, 4917391 NEC, OILED, (FLAMMABLE SOLID, N.O.S.) FLAMMABLE SOLID UN1325 Packing or wiping waste manufacturing, nee, oiled is fabric or fiber contaminated, coated or impregnated with animal or vegetable oil. It is liable to spontaneous heating and ignition. If material on fire or involved In fire Flood with water If material not on fire and not Involved in fire Keep sparks, (lames, and other sources of ignition away PAINT (ASPHALTUM OR COAL TAR PAINT) 4910252 FLAMMABLE LIQUID UNI 263 Asphaltum or coal tar paint may contain a flammable solvent. Its flash point is 100 deg F. or lower. The hazard is flammability. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PAINT (ASPHALTUM OR COAL TAR VARNISH) 4910253 FLAMMABLE LIQUID UN1263 Asphaltum or coal tar varnish may contain a flammable solvent. Its flash point is 100 deg. F. or lower. The hazard is flammability. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical April 1981 PAINT DRIER, LIQUID FLAMMABLE LIQUID 4910250 UN1168 Paint drier, liquid may contain flammable solvents. Their flash point is below 100 deg. F. The hazard is that of flammability. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantifies as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PAINT DRIER, LIQUID 4915250 COMBUSTIBLE LIQUID UN1168 Paint drier, liquid may contain combustible solvents. Their flash point is between 100 and 199 deg. F. The hazard is that of combustibility. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool alt affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in lire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 389 MCD 000017314 PAINT OIL COMPOUNDS (COMBUSTIBLE LIQUID, 4915152 N.O.S.) COMBUSTIBLE LIQUID NA1993 Paint oil compounds are various colored liquids. They have a flash point between 100 and 199 deg. F. They are lighter than water and insoluble in water. Their vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use `'alcohol1' foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PAINT OIL COMPOUNDS (COMBUSTIBLE LIQUID, 4915255 N.O.S.) COMBUSTIBLE LIQUIO NA1993 Paint oil compounds are various colored liquids. They have a fiash point between 100 and 199 deg. F. They are generally lighter than water and insoluble in water. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gioves. and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PAINT OIL COMPOUNDS (FLAMMABLE LIQUID, 4910255 N.O.S.) FLAMMABLE LIQUID UNI 993 Paint oil compounds are various colored liquids. They have a flash point of less than 100 deg. F. They are generally lighter than water and insoluble in water. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers 390 MCI) 0Q0l a Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PAINT OILS, NEC (FLAMMABLE LIQUID, N.O.S.) 4910152 FLAMMABLE LIQUID UN1993 Paint oil compounds are various colored liquids. They have a flash point of less than 100 deg. F. They are lighter than water and insoluble in water. Their vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use '`alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PAINT, LACQUER, STAIN (OR) VARNISH, BRONZE OR 4915251 GOLD, LIQUID OR LACQUER BASE LIQUID COMBUSTIBLE LIQUID UN1263 Paint, etc, may contain a combustible solvent. Its flash point is between 100 and 199 deg. F. The hazard is combustibility. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain fiow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PAINT, LACQUER, STAIN, VARNISH, BRONZE, GOLD, 4910251 LIQUID OR LACQUER BASE LIQUID FLAMMABLE LIQUID UN1263 Paint, etc. may contain a flammable solvent. Its flash point is 100 deg. F. or lower. The hazard is flammability. April 1981 If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "aicohor foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PAPER STOCK, WET 4917351 FLAMMABLE SOLID NA1325 Paper stock, wet consists of rags, twine and paper, it is subject to decomposition and spontaneous ignition. It must be shipped in air tight metal or metal-lined wooden containers. If material on fire or involved in fire Flood with water If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away PARALDEHYDE 4909260 FLAMMABLE LIQUID UN1264 Paraldehyde is a clear colorless liquid with a pleasant odor. It has a flash point of 96 deg. F. and a melting point of 54 deg. F. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use ``alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing PARAFORMALDEHYDE 4941143 ORM-A UN2213 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-1000/454) Paraformaldehyde is a white solid with a light pungent odor. It is used in fungicides, bactericides, in the manufacture of adhesives, and for other uses, It is combustible though it may take some effort to ignite. It is slightly soluble in water. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Coot all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors or dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates If dissolved, apply activated carbon at ten times the spilled amount in region of fOppm or greater concentration PARAMENTHANE HYDROPEROXIDE 4919565 ORGANIC PEROXIDE UN212S Paramenthane hydroperoxide is a colorless to pale yellow liquid. It must be shipped as a 60% solution in a non-volatile solvent. The solution may take some effort to ignite but once ignited it bums with increasing rapidity as the fire progresses. It supports the burning of combustible materials. If containers of the peroxide are exposed to lire or heat for prolonged periods, they may explode. The solution may be shipped in tank car quantities, If material on fire or Involved in fire Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not Involved In fire Keep sparks, flames, and other sources of Ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Keep spilled material wet Wet spilled material before picking It up Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet April 1981 391 ^CD 0000 17^19 PARANITROANILINE, SOLID 4921467 POISON B UN1661 Paranitroaniline is a yellow crystalline solid, it is used as a corrosion inhibitor, and to make other chemicals. It is slightly soluble in water and is combustible. It is toxic by inhalation (vapor, dust, etc.) and by skin material. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material PARATHION AND COMPRESSED GAS MIXTURE POISON A 4920535 NA1967 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Parathion and compressed gas mixture is a liquid material charged with a gas. Parathion is a yellow liquid and is lethal by skin absorption and inhalation. The material may oniy be shipped in cylinders and these must be over packed in wooden or fiberboard boxes. Prolonged expo sure of the cylinders to fire or heat may result in the violent rupturing and rocketing of the cylinders. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300 If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Cool ali affected containers with flooding quantities ot water Apply water from as far a distance as possible Use '`alcohol'' foam, carbon dioxide or dry chemical If material not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered Environmental consideration*--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash, cement powder, sawdust, or com mercial sorbents Apply "universal" gelling agent to immobilize spill Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e.g. detergent, soaps, alcohols) to com press and thicken spilled material Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors PARATHION MIXTURE, DRY 4921470 POISON B NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Parathion mixture, dry is the yellow liquid absorbed on a dry carrier. Parathion itself is combustible and slightly soluble in water. It is toxic by inhalation (vapor, dust, etc.) and by skin absorption. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates PARATHION MIXTURE, LIQUID 4921471 POISON B NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Parathion mixture, liquid is a solution of parathion in a suitable solvent. Parathion itself is a yellow colored liquid and is slightly soluble in water. It is combustible though it may take some effort to ignite. It is toxic by inhalation and by skin absorption. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300 If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical Use water spray to absorb vapors 392 OOOO^-73 7.0 April 1981 It material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of fOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors PARATHION, LIQUID 4921469 POISON B NA2763 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Parathion, liquid is a yellow liquid. It is slightly soluble in water. It is combustible though it may require some effort to ignite. It is toxic by inhalation and skin absorption. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300 It weighs 10.5 pounds per gallon. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical if material not on flra and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 Evacuation If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors PEANUT CHAFF, FEED (FLAMMABLE SOLID, N.O.S.) 4917450 FLAMMABLE SOLID UN1325 Peanut chaff, feed is the ground skin from the nuts. As it contains some oil it is liable to spontaneous heating and ignition. If material on fire or Involved In fire Flood with water if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away PEANUT HULLS, CRUSHED OR GROUND, OR 4917451 PEANUT HULL BRAN OR MEAL, FEED (FLAMMABLE SOLID, N.O.S.) FLAMMABLE SOLID UNI 325 Peanut hulls, crushed or ground contains some oil and is liable to spontaneous heating and ignition. H material on fire or involved in fire Flood with water If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away PELARGONYL PEROXIDE, (TECHNICALLY PURE) 4919165 ORGANIC PEROXIDE UN2130 Pelargonyl peroxide, (technically pure) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and burns with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combustible materials. It supports the burning of combustible materials. Under prolonged ex posure to fire or heat containers of the material may explode. H material on fire or involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible. Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Continued on next page 393 MCD 000017322 Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire w<th caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet PENTABORANE 4906060 FLAMMABLE LIQUID UN1380 PYROFORIC Pentaborane is a clear, colorless liquid, and may be shipped only in cylinders. It is extremely reactive and may ignite spontaneously in con tact with moist air and many other materials. The vapors are toxic. The material is heavier than water and is slowly decomposed by water. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Do not use water Use dry chemical or carbon dioxide If material not on fire and not involved in fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered PENTACHLOROPHENOL 4961380 ORM-E NA2020 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10/4.54) Pentachlorophenol is a white crystalline solid. It is used as a fungcide, as a wood preservative, and for other uses. It is slightly soluble in water. It is noncombustible. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water 394 Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or soiid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of t Oppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates PENTANE 4908255 FLAMMABLE LIQUID UNI 265 Pentane is a clear colorless liquid with a petroleum-like odor. It has a flash point of--57 deg. F. and a boiling point of 97 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered PERACETIC ACID SOLUTION (NOT OVER 40% 4919570 PERACETIC ACID AND NOT OVER 6% HYDROGEN PEROXIDE) ORGANIC PEROXIDE NA2131 Peracetic acid solution is a clear colorless liquid with an acrid odor. It must be shipped in a solution of not more than 40% strength. Acetic add is the usual solvent. It is corrosive to metals and tissue. It may take some effort to ignite but once ignited it burns with increasing rapidity as the fire progresses. It supports the burning of combustible materials. Under prolonged exposure to heat or fire containers of the material may explode. If material on fire or involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers 8uild dikes to contain flow as necessary Use water spray to knock-down vapors April 1981 MCD 000017322 Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Approach fire with caution If contact with the material anticipated, wear full protective clothing Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet PERCHLORATE, N.O.S. 4918770 OXIDIZER NA1481 Perchlorates, n.o.s. are crystalline compounds which have the follow* ing properties. The material is soluble in water, it is noncombustible but it will accelerate the burning of combustible materials. If large quantities are involved in the fire or the combustible material is finely divided an explosion may result. Prolonged exposure of the material to fire or heat may result in an explosion. If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet PERCHLORIC ACID (EXCEEDING 50% BUT NOT 4918523 EXCEEDING 72%) OXIDIZER. CORROSIVE UNI 873 Perchloric acid is a clear colorless odorless liquid. It is soluble in water with release of heat. It will accelerate the burning of combustible ma terials. It is corrosive to metals and tissue. Under prolonged exposure of containers of the matenal to fire or heat may result in their violent rupture. if material Involved in fire Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the matenal Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the matenal anticipated, wear full protective clothing Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet April 1981 PERCHLORIC ACID, NOT OVER 50% ACID 4918522 OXIDIZER, CORROSIVE UN1602 Perchloric acid is a clear colorless liquid. It is soluble in water with release of heat. It will accelerate the burning of combustible materials and can form explosive mixtures with many organic materials. It is cor rosive to metals and tissue. Under prolonged exposure to heat or fire- containers of the material may violently rupture. If material involved in fire Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in lire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing PERCHLOROMETHYL MERCAPTAN 4921473 POISON B UNI 670 Perchloromethyl mercaptan is a yellow oily liquid with an offensive odor. It is slowly decomposed in moist air. It is insoluble in water. It is toxic by inhalation and by skin absorption. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered PERCUSSION CAP 4903160 CLASS C EXPLOSIVE Percussion caps are small copper caps containing a small charge of explosive that is readily set off by impact. These are normally used to initiate the powder charge of small-arms ammunition. H material on fire or involved In fire Flood with water Apply water from as far a distance as possible Continued on next page 395 MCD 000017323 If material not on fire and not involved In fire Keep sparks, flames, ana other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet PERCUSSION FUZE 4903250 CLASS C EXPLOSIVE Percussion fuze is a mechanism for igniting or detonating the bursting charge oi a projectile upon impact. If material on fire or involved in fire Dangerously explosive Flood with water Apply water from as far a distance as possible If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet PERFUMERY (COMBUSTIBLE LIQUID, N.O.S.) 4915422 COMBUSTIBLE LIQUIO NA1993 Perfumery is a material containing a solvent having a closed cup flash point between 100 and 199 deg. F. The hazard is combustibility. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain (low as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PERFUMERY(FLAMMABLE LIQUID, N.O.S.) 4910422 FLAMMABLE LIQUID UN1993 Perfumery is a material containing a solvent having a closed cup flash point of less than 100 deg. F. The hazard is flammability. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical 396 If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective eauipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PERMANENT HAIR WAVING SETS. OTHER THAN 4918925 ELECTRIC (OXIDIZING MATERIAL, N.O.S.) OXIDIZER UN1479 Permanent hair waving sets, other than electric are kits containing small quantities of various chemicals. All the chemicals are water sol uble. Some of them will accelerate the burning of combustible materials. If material on fire or involved in fire Flood with water If material not on fire and not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing vapors Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PERMANGANATE, N.O.S. 4916735 OXIDIZER NA1482 Permanganates, n.o.s. are compounds which have the following prop erties. They are generally purplish colored. The material is soluble in water. The materia) itself is noncombustible but it will accelerate the burning of combustible material, if the combustible material is finely divided, the mixture may be explosive. Contact with liquid combustible materials may result in spontaneous ignition. Contact with sulfuric acid may cause fire or explosion. If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet PETROLEUM ABSORPTION OIL (PETROLEUM OIL, 4910360 N.O.S.) FLAMMABLE LIQUID NA1270 Petroleum absorption oil is a clear colorless to yellow colored oil with a petroleum like odor. It has a flash point of less than tOO deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. April 1981 MCD 000017324 If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggies Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PETROLEUM ABSORPTION OIL (PETROLEUM OIL. 4915360 N.O.S.) COMBUSTIBLE LIQUID NA1993 Petroleum absorption oil is a clear colorless to yellow colored oil with a petroleum like odor. It has a flash point between 100 and 199 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PETROLEUM ALKYLATE DETERGENT 4936554 INTERMEDIATE (CORROSIVE LIQUIO, N.O.S.) CORROSIVE MATERIAL UN1760 Petroleum alkylate detergent intermediate is a variable colored ma terial. Corrosive to metals and/or tissue. It may or may not be water soluble. It may be combustible though requiring some effort to ignite. It is If material on fire or involved in fire Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical If material not on fira and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain How as necessary April 1981 Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the maienat Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear selt-contained breathing apparatus when lighting fires involv ing this material If contact with the material anticipated, wear full protective clothing PETROLEUM DISTILLATE 4910256 FLAMMABLE UOUID UNI 268 Petroleum distillate is dear colorless to variable colored liquid. It is a petroleum product between gasoline and kerosine. Its flash point can vary widely but it is less than 100 deg. F. It is lighter than water and insoluble in water, its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless How can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak If without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PETROLEUM OISTILLATE (PETROLEUM DISTILLATE 4910257 OIL, NOT FOR ILLUMINATING PURPOSES) FLAMMABLE LIQUID UN1268 Petroleum distillate fuel oil, not for illuminating purposes is clear col orless to variable colored liquid. It is used in some cleaning preparations, as a solvent, and as a raw material in chemical manufacture. It is a petroleum product between gasoline and kerosine in volatility . Its flash point can vary widely but it is less than 100 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt (o stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 397 MCD 000017325 PETROLEUM DISTILLATE FUEL OIL, NOT FOR 4915257 ILLUMINATING PURPOSES (PETROLEUM DISTILLATE) COMBUSTIBLE LIQUID UN1268 Petroleum distillate fuel oil, not for illuminating purposes is clear col orless to variable colored liquid. It is a petroleum product between gas oline and kerosine. Its flash point can vary widely but it is between 100 and 199 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PETROLEUM ETHER 4906265 FLAMMABLE LIQUID UN1271 Petroleum ether is a clear colorless liquid with a petroleum-like odor. It has a flash point of less than 0 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered PETROLEUM LUBRICATING OIL (COMBUSTIBLE 4915242 LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Petroleum lubricating oil is a variable colored liquid with a petroleum like odor, it has a flash point between 100 and 200 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PETROLEUM NAPHTHA 4910259 FLAMMABLE LIQUID UN1255 Petroleum naphtha is clear colorless to variable colored liquid. It is used in some cleaning preparations, as a solvent, and as a raw material in chemical manufacture. It is a petroleum product between gasoline and kerosine in volatility . Its flash point can vary widely but it is less than 100 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PETROLEUM NAPHTHA 4915259 COMBUSTIBLE LIQUID UNI 255 Petroleum naphtha is clean colorless to variable colored liquid. It is used in some cleaning preparations, as a solvent, and as a raw material in chemical manufacture. It is a petroleum product between gasoline and kerosine in volatiftiy. Its flash point can vary widely but it is between 100 and 199 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical 398 April 1961 000017326 tfCD ft material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PETROLEUM OIL ADDITIVE CONTAINING MORE 4915525 THAN 50 PERCENT BY WEIGHT OF PETROLEUM. (COMBUSTIBLE LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Petroleum oil additive is a various colored liquid, it has a flash point of between 100 and 200 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PETROLEUM OIL ADDITIVE, CONTAINING MORE 4910525 THAN 50 PERCENT BY WEIGHT OF PETROLEUM (FLAMMABLE LIQUID, N.O.S.) FLAMMABLE LIQUID UN1993 Petroleum oil additive is a various colored liquid. It has a flash point of less than 100 deg. F. It is lighter than water and is insoluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 PETROLEUM OIL OR PRODUCTS. MIXED LOAD 4950120 Consult the shipping papers for the exact contents of the car, con tainer, or trailer. PETROLEUM OIL RESIDUUM (PETROLEUM OIL, 4910244 N.O.S.) FLAMMABLE LIQUID NA1270 Petroleum oil residuum is a dark colored liquid with the faint odor. Characteristic of petroleum. It has a flash point of less than 100 deg. F. It is generally heavier than water and is insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PETROLEUM OIL RESIDUUM (PETROLEUM OIL, 4915244 N.O.S.) COMBUSTIBLE LIQUID NA1993 Petroleum oil residuum is a dark colored liquid with the faint odor characteristic of petroleum. It has a flash point between 100 and 199 deg. F. It is generally heavier than water and is insoluble in water. Its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PETROLEUM PARTIALLY REFINED FOR FURTHER 4915243 PROCESSING (COMBUSTIBLE LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Petroleum partially refined is a clear colorless to dark brown colored liquid with a characteristic odor. It has a flash point between 100 and 199 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. Continued on next page 399 MCD 000017327 If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PETROLEUM PROPYLENE TETRAMER 4915530 (COMBUSTIBLE LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Petroleum propylene tetramer is a clear colorless liquid with a petro- leumlike odor. It is used to make detergents, and as a lubricating oil additive. It has a flash point of 137 deg. F. it is lighter than water and is insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Oo not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PETROLEUM PROPYLENE TRIMER (FLAMMABLE LIQUID, N.O.S.) 4910520 FLAMMABLE LIQUID UN1993 Petroleum propylene trimer is a clear colorless odorless liquid. It is used to make other chemicals and as a lubricating oil additive. It has a flash point of 72 deg. F. It is lighter than water and is insoluble in water. Its vapors are heavier than air. if material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers 400 rtCD 0 Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PETROLEUM REFINERY SULFIDE WASTE 4935539 (CORROSIVE LIQUID, N.O.S.) CORROSIVE MATERIAL UN1760 Petroleum refinery sulfide waste is a dark colored liquid with an of fensive odor. It may bum though requiring some effort to ignite. It may be both lighter and heavier than water and only partially soluble in water. It is corrosive to metals and tissue. If material on fire or involved in fire Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing PETROLEUM RESIDUAL FUEL OIL OR OIESEL OIL 4915111 (FUEL OIL) COMBUSTIBLE LIQUID NA1993 Petroleum residual fuel oil or diesel oil is a heavy black liquid. It has a flash point between 100 and 199 deg. F. It weighs about the same as water and is insoluble in water. Its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Coot all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gioves. and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 328 PETROLEUM, PARTIALLY REFINED FOR FURTHER 4910243 PROCESSING (PETROLEUM OIL, N.O.S.) FLAMMABLE LIQUID NA1270 Petroleum, partially refined is a clear colorless to dark brown colored liquid with a characteristic odor. It has a flash point of below 100 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid Streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PETROLUEM DISTILLATE 49152S8 COMBUSTIBLE LIQUID UNI 268 Petroleum distillate is clear colorless to variable colored liquid. It is a petroleum product between gasoline and kerosine. Its flash point can vary widely but it is between 100 and 199 deg. F. it is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Paraonnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PHENOXY PESTICIDE, LIQUID. N.O.S. (COMPOUNDS 4921683 AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL. NEC) POISON B UN2765 Phenoxy pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The carrier may burn though it may require some effort to ignite. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to, or leaking from containers of this ma terial contact the pesticide safety team network. Telephone; 800-424- 9300. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PHENOXY PESTICIDE, LIQUID. N.O.S. (COMPOUNDS 4921692 AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC, UQUID) POISON B UN2765 Phenoxy pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The carrier may bum though it may require some effort to ignite. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to, or leaking from containers of this ma terial contact the pesticide safety team network. Telephone: 800-424- 9300. April 1981 PHENOXY PESTICIDE, LIQUID, N.O.S. (COMPOUNDS 4910574 AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL, NEC) FLAMMABLE LIQUID UN2766 Phenoxy pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The primary hazard of this material is the flammability of the carrier. It has a flash point below 100 deg. F. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to, or leaking from containers of this material contact the pes ticide safety team network. Telephone; 800-424-9300. Continued on next page 401 MCI) 00001732S If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use ` alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wear self-contained breathing apparatus when fighting fires involv ing this material PHENOXY PESTICIDE, LIQUID, N.O.S. (COMPOUNDS 4910575 AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC, LIQUID) FLAMMABLE LIQUID UN2766 Phenoxy pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiabte. The primary hazard of this material is the flammability of the carrier. It has a flash point below 100 deg. F. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to, or leaking from containers of this material contact the pes ticide safety team network. Telephone: 800-424-9300. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wear self-contained breathing apparatus when fighting fires involv ing this matenal PHENOXY PESTICIDE, SOLID, N.O.S. (COMPOUNDS 4921694 AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC, OTHER THAN LIQUID) POISON B UN2765 Phenoxy pesticide is a solid or a liquid absorbed on a dry carrier. It is a wettabie powder. It is toxic by inhalation, skin absorption, and/or ingestion. In case ol damage to. or leaking from containers of this ma terial contact the pesticide safety team network. Telephone; 800-424- 9300. If material on fire or Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Use `'alcohol" foam, carbon dioxide or dry chemical 402 If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing PHENOXY PESTICIDE, SOLID, N.O.S. (COMPOUNDS 4921693 AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL, NEC) POISON B UN2765 Phenoxy pesticide is a solid or a liquid absorbed on a dry carrier. It is a wettabie powder. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to, or leaking from containers of this ma terial contact the pesticide safety team network. Telephone; 800-424- 9300. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing PHENYL TRICHLOROSILANE 4934275 CORROSIVE MATERIAL, ACIDIC, FLAMMABLE UN1804 Phenyl trichlorosiiane is a colorless liquid with a pungent odor. It is flammable and has a flash point of 91 deg. F. It is decomposed by moisture or water to hydrochloric acid with evolution of heat. It is cor rosive to metals and tissue. If material on fire or involved in fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or iime April 1981 MCB 000017330 Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing PHENYLDICHLOROARSINE, LIQUID POISON B 4921474 NA1SS6 Phenyldichloroarsine is a clear colorless liquid. It is decomposed by water giving hydrocloric acid, a corrosive material and other materials. It is toxic by inhalation and skin absorption. If material on fire or Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered PHENYLUREA PESTICIDE, LIQUID, N.O.S. 4921685 (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES. NEC, LIQUID) POISON B UN2767 Phenylurea pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emuisifiable. The carrier may burn though it may require some effort to ignite. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800- 424-9300. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical tf material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus April 1981 Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PHENYLUREA PESTICIDE, LIQUID, N.O.S. 4921684 (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL, NEC) POISON B UN2767 Phenulurea pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emuisifiable. The carrier may burn though it may require some effort to ignite. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800- 424-9300. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PHENYLUREA PESTICIDE, LIQUID, N.O.S. 4910572 (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL, NEC) FLAMMABLE LIQUID UN2768 Phenylurea pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emuisifiable. The primary hazard of this material is the flammability of the carrier, it has a flash point below 100 deg. F. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. tf material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Continued on next page 403 3^ 000i7 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wear self-contained breathing apparatus when fighting fires involv ing this material PHENYLUREA PESTICIDE, LIQUID, N.O.S. 4910573 (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC, LIQUID) FLAMMABLE LIQUID UN2768 Phenylurea pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The primary hazard of this material is the flammability of the carrier It has a flash point below 100 deg. F. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wear self-contained breathing apparatus when fighting fires involv ing this material PHENYLUREA PESTICIDE, SOLID, N.O.S. 4921687 (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC, OTHER THAN LIQUID) POISON B UN2767 Phenylurea pesticide is a solid or a liquid absorbed on a dry carrier. It is a wettable powder. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to, or leaking from containers of this ma terial contact the pesticide safety team network. Telephone; 800-424- 9300. If material on fire or Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difliculty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical It material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing 404 PHENYLUREA PESTICIDE, SOLID.N.O.S. 4921686 (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL, NEC) POISON B UN2767 Phenylurea pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The carrier may burn though it may require some effort to ignite. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network Telephone: 800- 424-9300. If material on fire or involved in fire Extinguish fire using agent suitable lor type ol surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical tf material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material if contact with the material anticipated, wear full protective clothing PHOSGENE 4920540 POISON A UN1076 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Phosgene is a colorless liquid having a pungent odor which becomes a gas at 47 deg. F. Its vapors are irritating to the eyes and respiratory system, and it is toxic by inhalation. It is shipped as a liquid or liquefied gas in cylinders or "ton container" tank cars. The cylinders and tank cars may not be equipped with a safety relief device. Prolonged exposure of the cylinders or tank cars to fire or heat may result in their violent rupturing and rocketing. It weighs 11.6 pounds per gallon. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as tog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical tf material not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered April 1981 .0^ O0' Environmental considerations--land spill Dig a pit, pond, fagoon, holding area to contain liquid or sofid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Dilute slowly with water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--air spiff Appiy water spray or mist to knock down vapors PHOSPHATIC FERTILIZER SOLUTION (PHOSPHORIC 4930247 ACID) CORROSIVE MATERIAL UN1805 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RG-5000/2270) Phosphatic fertilizer solution is a colorless to dark brown colored liquid. It is noncombustible and is corrosive to steel and aluminum. It is heavier than water and dissolves in water. It weighs 15.6 pounds per gallon. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder vO Neutralize with agricultural lime (slaked lime), crushed limestone. 123 or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked time), crushed limestone, or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment PHOSPHINE 4920160 POISON A, FLAMMABLE UN2199 Phosphine is a colorless gas with a disagreeable garlic-like odor. It is flammable and usually will ignite spontaneously in contact with air. It is insoluble in water. It is toxic by inhalation of extremely low concen trations. It may only be shipped In cylinders which may have to be overpacked in wooden or metal containers. Prolonged exposure of the cylinders to fire or heat may result in the violent rupturing and rocketing of the cylinders. April 1981 MCP 00001733d If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered PHOSPHORIC ACID (LIQUID) OR PHOSPHORIC ACID 4930246 SOLUTION CORROSIVE MATERIAL, ACIDIC UN1805 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Phosphoric acid is a clear colorless liquid. It is used in making fertilizers and detergents, in food processing, and for many other uses. I! is soluble in water with release of heat. It is corrosive to metals and to tissue. It weighs 15.6 pounds per gallon. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph*7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment 405 PHOSPHORIC ACID TRIETHYLENEIMINE (See TRIS-(1AZIRIDIYL) PHOSPHINE OXIDE 4935520) PHOSPHORIC ANHYDRIDE 4932324 CORROSIVE MATERIAL, ACIDIC, POISONOUS NA1B07 Phosphoric anhydride is a white amorphous powder. It readily absorbs moisture from the air forming a syrup. It dissolves in water to form phosphoric acid, a corrosive material, with release of heat. This heat may be sufficient to ignite surrounding combustible materials. If mixed with organic material, heat may result which may be sufficient to ignite the organic material. It is corrosive to metals and tissue. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If material not involved In fire Keep material out of water sources and sewers Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing PHOSPHORUS BROMIDE (See PHOSPHORUS TRIBROMIOE 4932358) PHOSPHORUS CHLORIDE (See PHOSPHORUS TRICHLORIDE 4932359) Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting tires involv ing this material If contact with the material anticipated, wear full protective clothing PHOSPHORUS OXYBROMIDE 4932350 CORROSIVE MATERIAL, ACIDIC UNI 939 Phosphorus oxybromide is a colorless crystalline solid, it is used to make other chemicals. It is decomposed by water to hydrobromic and phosphoric acids with evolution of heat. It is corrosive to metals and tissue. If material involved in fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed^imestone. soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing PHOSPHORUS HEPTASULFIDE 4916315 FLAMMABLE SOLID, POISONOUS WATER REACTIVE UN1339 Phosphorus heptasulfide is a yellow crystalline solid. In the presence of moisture it may spontaneously heat and ignite. Phosphorus pentoxide and sulfur dioxide are the products of combustion. Phosphorus pentoxide reacts with water to form phosphoric acid, a corrosive material. Phos phoric heptasulfide reacts with water to form phosphoric acid and hy drogen sulfide, a toxic flammable gas with a rotten egg smell. Continued exposure to hydrogen sulfide will numb one's sense of smell to this material. If material on fire or involved In fire Do not use water Use dry chemical or carbon dioxide When fire is out, cover all suspected material with dry sand or earth, until material can be permanently disposed of If material not on fire and not Involved In fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry 406 PHOSPHORUS OXYCHLORIDE 4932352 CORROSIVE MATERIAL. ACIDIC UN1810 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Phosphorus oxychloride is colorless fuming liquid with a pungent odor. It Is decomposed by water to hydrochloric and phosphoric acids with evolution of heat. It is corrosive to metals and tissue. It weighs 14.0 pounds per gallon. If material Involved In fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material Itself if large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime MOD 000017334 April 1961 Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Adjust ph to neutral (ph-7) Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment PHOSPHORUS PENTACHLORIDE, SOLID 4932323 CORROSIVE MATERIAL, ACID, POISONOUS UN1806 Phosphorus pentachloride is a greenish-yellow crystalline solid with an irritating odor. It is decomposed by water to form hydrochloric and phosphoric acids, corrosive materials and heat. This heat may be suf ficient to ignite surrounding combustible material. It is corrosive to metals and tissue. H material involved In fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If material not involved in fire Keep material out of water sources and sewers Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodiiy contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing April 1961 PHOSPHORUS PENTASULFIDE FLAMMABLE SOLID. POISONOUS 4916320 UN1340 WATER REACTIVE ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Phosphorus pentasulfide is a light grey to greenish yellow crystalline mass having the odor of rotten eggs, it is used to make oil additives, fetation agents, and insecticides. In the presence of moisture it may spontaneously heat and ignite. Phosphorus pentoxide and sulfur dioxide, a non flammable gas, are the products of combustion. Phosphorus pen toxide reacts with water to form phosphoric acid, a corrosive material and hydrogen sulfide, a toxic flammable gas with a rotten egg smell. Continued exposure to hydrogen sulfide will numb one's sense of smell to this material. If material on fire or involved in fire Do not use water Use dry chemical or carbon dioxide When fire is out, cover all suspected material with dry sand or earth, until material can be permanently disposed of If material not on fire and not involved In fire Do not use water Keep sparks, flames, and other sources of ignition away Keep matehal out of water sources and sewers Keep material dry Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate PHOSPHORUS SESQUISULFIDE 4916330 FLAMMABLE SOLID, POISONOUS UN1341 WATER REACTIVE Phosphorus sesquisulfide is a yellow crystalline solid, it is used to make matches and in the manufacture of other chemicals. It is easily ignited by friction and when ignited gives off sulfur dioxide and phos phorus pentoxide. Phosphorus pentoxide reacts with water to form phos phoric acid, a corrosive material. It is slowly decomposed by water to give phosphoric acid and hydrogen sulfide, a toxic flammable gas smel ling of rotten eggs. Continued exposure to hydrogen sulfide will numb one's sense of smell to the material. If material on fire or Involved in fire Do not use water Use dry chemical or carbon dioxide When fire is out. cover all suspected material with dry sand or earth, until material can be permanently disposed of If material not on fire and not involved in fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Continued on next page 407 OOOO 17 03b Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self*contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing PHOSPHORUS TRIBROMIOE 4932358 CORROSIVE MATERIAL. ACIDIC UNI 808 Phosphorus tribromide is a colorless fuming liquid with a pungent odor. It is decomposed by water to hydrobromic and phosporus acids with evolution of heat. It is corrosive to metals and tissue. If material involved in fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water if contact with the material anticipated, wear full protective clothing PHOSPHORUS TRICHLORIDE 4932359 CORROSIVE MATERIAL ACIDIC UN1B09 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000'2270) Phosphorus trichloride is a colorless fuming liquid with a pungent odor. It is decomposed by water to hydrochloric and phosphorus acids with evolution of heat, ft is corrosive to metals and tissue. It weighs 13.1 pounds per gallon. If material involved in fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Coot all affected containers with flooding quantities of water Apply water from as tar a distance as possible If material not involved in fire Keep materiai out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus 408 Avoid bodily contact with the material Wear boots, protective gioves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Adjust ph to neutral (ph-7) Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment PHOSPHORUS TRISULFIDE 4916335 FLAMMABLE SOLID, POISONOUS UN1343 WATER REACTIVE Phosphorus trisulfide is a greyish yellow solid. In the presence of moisture it may spontaneously heat and ignite. Phosphorus pentoxide and sulfur dioxide are the products of combustion. Phosphorus pentoxide reacts with water to form phosphoric acid, a corrosive material. Phos phorus trisulfide reacts with water to form phosphoric acid and hydrogen sulfide, a toxic flammable gas. Continued exposure to hydrogen sulfide will numb one's sense of smell to this material. If material on fire or Involved in fire Do not use water Use dry chemical or carbon dioxide When fire is out. cover all suspected material with dry sand or earth, until material can be permanently disposed of If material not on fire and not involved in fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing PHOSPHORUS, AMORPHOUS, RED 4916725 FLAMMABLE SOLID UNI 336 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-1/0.454) Phosphorus, amorphous is a dark red powder. It is readily ignited by friction. If it is mixed with or contaminated by combustible material, it is readily ignitable. If contaminated with large quantities of combustible materials, the fire may be so intense that an explosion is possible. tf material on fire or involved in fire Flood with water If materiai not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers April 1981 MCD 000017336 Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates PHOSPHORUS, CRUDE, RED AND YELLOW, MIXED 4916142 (FLAMMABLE SOLID, N.O.S.) FLAMMABLE SOLID, POISONOUS UNI 338 PYROFORIC ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Phosphorus, crude red and yellow mixed is a yellow to red waxy amorphous solid. It may ignite spontaneously in moist air at 86 deg. F. Material may cause severe burns and may be toxic by ingestion of very small quantities. It is heavier than water and insoluble in water. If material on fire or Involved In fire Flood with water When fire is out, cover all suspected material with wet sand or earth, until material can be permanently disposed of If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Keep spilled material wet Do not attempt to sweep up dry material Personnel protection Avoid breathing fumes from burning material Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates PHOSPHORUS, WHITE OR YELLOW, ORY 4916140 FLAMMABLE SOLID, POISONOUS UNI 381 PYROFORIC ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Phosphorus, white or yellow, dry is a white to yellow colored waxy solid with a pungent sharp odor. It is shipped blanketed with an inert gas. It ignites spontaneously in moist air. The material causes severe bums to the skin and is toxic by Ingestion of very small quantities. It is heavier than water and insoluble in water. It weighs 14.5 pounds per gallon. April 1981 If material on fire or involved in fire Flood with water When fire is out. cover all suspected material with wet sand or earth, until material can be permanently disposed of If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Keep spilled material wet Do not attempt to sweep up dry material Personnel protection Avoid breathing fumes from burning material Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover with water or wet sand Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom Environmental considerations--air spill Apply water spray or mist to knock down vapors Combustion products include corrosive or toxic vapors PHOSPHORUS. WHITE OR YELLOW, IN WATER 4916141 FLAMMABLE SOLID, POISONOUS UN1381 PYROFORIC ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Phosphorus, white or yellow, in water is a white to yellow waxy solid. It is used to make phosphoric acid, pyrotechnics, and phosphorus con taining compounds. It is immersed in water for transport. It ignites spon taneously in moist air. The material causes severe bums to skin and is toxic by ingestion of very small amounts. It is heavier than water and insoluble in water. It weighs 14.5 pounds per gallon. If material on fire or Involved in fire Flood with water Wien fire is out, cover all suspected material with wet sand or earth, until material can be permanently disposed of If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Keep spilled material wet Do not attempt to sweep up dry material Personnel protection Avoid breathing fumes from burning material Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover with water or wet sand Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom Environmental considerations--air spill Apply water spray or mist to knock down vapors Combustion products include corrosive or toxic vapors 409 mod 017337 PHOSPHORYL CHLORIDE (See PHOSPHORUS OXYCHLORIDE 4932352) PHTHALIMIDE DERIVATIVE PESTICIDE, LIQUID, 4921686 N.O.S. (COMPOUNDS ANO PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL, NEC) POISON B UN2773 Phthalimide derivative pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The carrier may burn though it may require some effort to ignite. It is toxic by inhalation, skin ab sorption, and/or ingestion, in case of damage to. or leaking from con tainers of this material contact the pesticide safety team network. Tele phone; 800-424-9300. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain Mow as necessary Attempt to stop teak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PHTHALIMIDE DERIVATIVE PESTICIDE, LIQUID, 4921689 N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC, LIQUID) POISON B UN2773 Phthalimide derivative pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The carrier may burn though it may require some effort to ignite. It is toxic by inhalation, skin ab sorption, and/or ingestion. In case of damage to, or leaking from con tainers of this material contact the pesticide safety team network. Tele phone; 800-424-9300. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as rog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop teak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind 410 Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PHTHALIMIDE DERIVATIVE PESTICIDE. LIQUID, 4910570 N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL. NEC) FLAMMABLE LIQUID UN2774 Phthalimide derivate pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The primary hazard of this material is the flammability of the carrier. It has a flash point below 100 deg. F. It can cause illness by inhalation, skin absorption and/or inges tion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network, Telephone: 800-424-9300. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wear self-contained breathing apparatus when fighting fires involv ing this material PHTHALIMIDE DERIVATIVE PESTICIDE, LIQUID, 4910571 N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC, LIQUID) FLAMMABLE LIQUID UN2774 Phthafimide derivative pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The primary hazard of this material is the flammability of the carrier, it has a flash point below 100 deg. F. It can cause illness by inhalation, skin absorption and/or inges tion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be Ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical (f material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wear self-contained breathing apparatus when fighting fires involv ing this material April 1981 PHTHALIMIDE DERIVATIVE PESTICIDE, SOLID, N.O.S. 4921690 (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL, NEC) POISON B UN2773 Phthalimide derivative pesticide is a solid or a liquid absorbed on a dry carrier. It is a wettable powder. It is toxic by inhalation, skin ab sorption, and/or ingestion. In case of damage to. or leaking from con tainers of this material contact the pesticide safety team network. Tele phone; 800-424-9300. H material on fire or involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use ''alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing PHTHALIMIDE DERIVATIVE PESTICIDE, SOLID, N.O.S. 4921691 (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIOES, NEC, OTHER THAN LIQUID) POISON B UN2773 Phthalimide derivative pesticide is a solid or a liquid absorbed on a dry carrier. It is a wettable powder. It is toxic by inhalation, skin ab sorption, and/or ingestion. In case ot damage to, or leaking from con tainers of this material contact the pesticide safety team network. Tele phone; 800-424-9300. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as tog Use "alcohol" foam, carbon dioxide or dry chemical H material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing PICOLINE (COMBUSTIBLE LIQUID, N.O.S.) 4913174 COMBUSTIBLE LIQUID NA1993 Picoline is a clear colorless liquid having a strong unpleasant odor, it is used as a solvent and to make other chemicals. It has a flash point of 134 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. toxic oxides of nitrogen are produced during the com bustion of this material. April 1981 A/co OOr.>01 ^ /o3,9 If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical if material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing PICOLINE (FLAMMABLE LIQUID, N.O.S.) 4909179 FLAMMABLE LIQUID UN1993 Picoline is a clear colorless liquid having a strong unpleasant odor, it is used as a solvent and to make other chemicals. It has a flash point of 79 to 97 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. toxic oxides of nitrogen are produced during the combustion of this material. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing PICRIC ACID, WET, WITH NOT LESS THAN 10% 4917120 WATER FLAMMABLE SOLID NA1344 Picric acid, wet is a slurry of yellow crystals. The dried material is a high explosive. Once ignited it will bum very vigorously. If mixed with combustible materials and ignited the combustible materials will bum more rapidly than if by themselves due to the oxidizing properties of picric acid. Picric acid is soluble in water. Toxic oxides of nitrogen are produced during combustion of this material. Continued on next page 411 If material on fire or involved in fire Dangerously explosive Flood with water Coo! all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Do not attempt to sweep up dry material Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 5000 feet If material on fire or involved in fire Do not extinguish tire unless itow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cooi all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical H material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PINANE HYDROPEROXIDE SOLUTION (NOT OVER 4919573 45% PEROXIDE) ORGANIC PEROXIDE UN2162 Pinane hydroperoxide solution is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violeni chemical reaction. It supports the burning of combustible ma terials. Under prolonged exposure to fire or heat containers of the ma terial may explode. If material on fire or Involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet PINE OIL 4915170 COMBUSTIBLE LIQUID UNI 272 Pine oil is a clear colorless to light amber colored liquid. It has a flash point between 100 and 199 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. 412 PINE TAR (TAR, LIQUID) 4915262 COMBUSTIBLE LIQUID UN1999 Pine tar is a thick brownish black liquid with characteristic odor. It has a flash point between 100 and 199 deg. F. It is heavier than water and insoluble in water. Its vapors are heavier than air. if material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PINE TAR (TAR, LIQUID) FLAMMABLE LIQUID 4910262 UN1999 Pine tar is a thick brownish black liquid with a characteristic odor. It has a (lash point of less than 100 deg. F. It is heavier than water and insoluble in water. Its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors April 1981 vjf.p 000017340 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PINENE 4909266 FLAMMABLE LIQUID UN2368 Pinene is a clear colorless liquid with a turpentine odor. It has a flash point of 91 deg. F. It is lighter than water and is insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gioves. and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PINWHEELS (FIREWORKS OR PYROTECHNICS, NEC) 49Q3S38 CLASS C EXPLOSIVE Pinwheels are circular devices containing a small pyrotechnic charge. They spin on burning and produce a visual display. If material on fire or Involved In fire Flood with water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet PIPE LINE RUST PREVENTIVE COATING (RUST 4915182 PREVENTIVE COATING) COMBUSTIBLE LIQUID NA1142 Pipe line rust preventive coating is a thick variable colored liquid having an odor of paint. It has a flash point between 100 and 199 deg. F. II is insoluble in water and heavier than water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PIVALOYL CHLORIDE (See TRIMETHYL ACETYL CHLORIDE 4931745) PLASTIC SOLVENT, N.O.S. 4915265 COMBUSTIBLE LIQUID NA1993 Plastic solvent, n.o.s. is the proper shipping name for plastic solvents having a closed cup flash point between 100 and 199 deg. F. and not specifically mentioned in the hazardous materials regulations. The haz ard is combustibility. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gioves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PLASTIC SOLVENT, N.O.S. 4910265 FLAMMABLE LIQUID NA1993 Plastic solvent, n.o.s. is the proper shipping name for plastic solvents having a closed cup flash point of less than 100 deg. F. and not spe cifically mentioned in the hazardous materials regulations. The hazard is flammability. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool ail affected containers with flooding quantities of water Apply water from as far a distance as posable Use `'alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Continued on next page April 1981 Mod 00I734I 413 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PLASTICIZER ALCOHOL (ALCOHOL, N.O.S.) 4915406 COMBUSTIBLE LIQUID UN1987 Plasticizer aicohol is a material having a closed cup flash point be tween 100 and 199 deg. F. It is generally lighter than water and insoluble in water. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'1 foam, carbon dioxide or dry chemical if material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PLASTICIZER ALCOHOL (ALCOHOLS, N.O.S.) 4910406 FLAMMABLE LIQUID UN1967 Plasticizer alcohol, is a material having a closed cup flash point of less than 100 deg. F. The hazard is flammability. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PLASTICIZERS, PAINT, LACQUER OR VARNISH 4915410 (COMBUSTIBLE LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Plasticizers, paint, lacquer or varnish are materials containing a sol vent having a closed cup flash point between 100 and 199 deg, F. The hazard is combustibility. 414 MOD 000017342 If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical if material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PLASTICIZERS, PAINT, LACQUER OR VARNISH 4910410 (FLAMMABLE LIQUIDS, N.O.S.) FLAMMABLE LIQUID UN1993 Plasticizers, paint, lacquer or varnish are materials containing a sol vent having a closed cup flash point of less than 100 deg. F. The hazard is flammability. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be Ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical H materiel not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PLOSPHORIC CHEMICALS (OXIDIZING MATERIAL, 4918915 N.O.S.) OXIDIZER UN1479 Plosphoric chemicals is a name for two chemicals which when mixed together forms a high explosive. One is generally an oxidizer and the other a non-regulated chemical. If packages of these materials are in volved in a fire they will accelerate the burning of combustible materials. The usual shipping containers for these materials are fiberboard boxes with inside containers of not over one-gallon capacity. If material on Are or Involved In fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on tire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers April 1981 Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 5000 feet PLUTONIUM NITRATE SOLUTION 4926435 RADIOACTIVE MATERIAL NA6185 Plutonium nitrate solution is the solution of the colorless crystalline solid. Though the solution is noncombustible it will accelerate the burning of combustible material if the solution is concentrated or the water should evaporate. If large quantities are involved in the fire or the combustible material is finely divided, an explosion may result. Tocic oxides of ni trogen are produced in fires involving this material. Radioactive materiais emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful whereas films may be damaged by radiation from relatively low concentrations. If material on fire or involved in fire Contact the local, state, or department of energy radiological re sponse team Flood with water If material not on fire and not involved In fire Contact the local, state, or department of energy radiological re sponse team Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Avoid breathing dusts, and fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet Keep unnecessary people out of incident area until area declared safe by radiological response team PNEUMATIC TIRE REPAIR KITS, AUTO 4915482 (COMBUSTIBLE LIQUID, N.O.S.) COMBUSTIBLE UQUIO NA1993 Pneumatic tire repair kits, auto is a material containing a solvent having a dosed cup flash point between 100 and 199 deg. F. The hazard of this material is combustibility. If material on fire or Involved In fire Do not extinguish tire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors April 1981 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PNEUMATIC TIRE REPAIR KITS, AUTO (FLAMMABLE 4910482 LIQUID, N.O.S.) FLAMMABLE LIQUID UN1993 Pneumatic tire repair kits, auto is a material containing a solvent having a closed cup flash point of less than 100 deg. F. The hazard of this material is flammability. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water POISONED GRAIN (POISONOUS SOLID, N.O.S.) 4921591 POISON B NA2811 Poisoned grain is various types of grain that has been treated with an insecticide. It is toxic by ingestion. If material on fire or Involved In fire Flood with water H material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water POISONOUS GAS, N.O.S. POISON A 4920911 NA195S Poisonous gas. n.o.s. is a material which has the property of being lethal by skin absorption or inhalation in extremely low concentrations. The material may only be shipped in cylinders and these may have to be overpacked in wooden or metal containers. Prolonged exposure of the cylinders to fire or heat may result in the violent rupturing and rock eting of the cylinders. If material on fire or Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Continued on next pege 415 MCI) 000017343 If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered POISONOUS LIQUID, N.O.S. 4920910 POISON A NA9035 Poisonous liquid, n.o.s. is the proper shipping name for those materials having the property of being lethal by inhalation or skn absorption in extremely low concentrations. It may only be shipped in cylinders which may have to be overpacked in wooden and metal containers. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Extinguish fire using agent suitable for type of surrounding tire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered POISONOUS LIQUID, N.O.S. 4921475 POISON B UN2810 Poisonous liquid, n.o.s. are liquid or solutions of solids materials which have the property of being toxic by ingestion, inhalation, or skin ab sorption. The liquid or solution may or may not bum depending on the nature of the material and/or the solvent of the solution. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use 'alcohol" loam, carbon dioxide or dry chemical If material not on fire and not involved (n fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers 416 MCD 000017344 Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered POISONOUS SOLID, CORROSIVE, N.O.S. 4921250 POISON B, CORROSIVE UN2928 Poisonous solid, corrosive, n.o.s. Is the proper shipping name for those solids not specifically mentioned in the hazardous materials reg ulations that have the properties of being toxic by ingestion, inhalation, and skin absorbtion; and corrosive to tissue. Try to ascertain the exact name of the material from the shipping papers, if material on fire or involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing POISONOUS SOLID, N.O.S. 4921476 POISON B UN2811 Poisonous solid, n.o.s. are single material, mixtures of two or more solids, or a liquid absorbed on a dry carrier. It has the property of being toxic by ingestion, inhalation (vapor, dust, etc), or skin absorption. If material on fire or involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use '`alcohol'' foam, carbon dioxide or dry chemical H material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 POLISH OR WAX, BOAT, FURNITURE OR VEHICLE 4915386 (WAX, LIQUID) COMBUSTIBLE LIQUID NA1993 Polish or wax, boat, furniture or vehicle is a clear colorless to light cream colored liquid. It has a flash point between 100 and 199 deg. F. It is generally lighter than water and partially soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water POLISH OR WAX, FLOOR (WAX, LIQUID) 4915385 COMBUSTIBLE LIQUID NA1993 Polish or wax, floor is a clear colorless to light cream colored liquid. It has a flash point between 100 and 199 deg. F. It is generally lighter than water and partially soluble in water. Its vapors are heavier than air, If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of Ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matehal which may have contacted the body with copious amounts of water or soap and water POLISH, METAL, STOVE, FURNITURE OR WOOD, 4910270 LIQUID FLAMMABLE LIQUID NA1142 Polishes, metal, stove, furniture or wood, liquid are preparations that contain a flammable solvent. Its flash point is less than 100 deg. F. The hazard is flammability. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities a$ fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical April 1981 If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water POLISH, METAL, STOVE, FURNITURE OR WOOD, 4915270 LIQUID COMBUSTIBLE LIQUID NA1142 Polish, metal, stove, furniture or wood, liquid are preparations that contain a combustible solvent. Its flash point is between 100 and 199 deg. F. The hazard is combustibility. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fira and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water POLISHING CLOTHS, COTTON, TREATED WITH 4917475 CHEMICALS, OIL OR WAX (FLAMMABLE SOLID,N.O.S.) FLAMMABLE SOUD UN132S Polishing cloths, cotton treated with chemicals oil or wax are liable to spontaneous heating and ignition. They must be shipped in airtight metal or metal lined wooden containers. If material on fire or involved In fire Flood with water If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away POLISHING WHEEL CEMENT OR GLUE (CEMENT, 4910460 LIQUID, N.O.S.) FLAMMABLE LIQUID NA1133 Polishing wheel cement or glue is the solution of various gums or resins in various solvents. The liquids are generally quite thick and range from clear colorless to black "tars". The flash point depends on the solvent used but it will be below 100 deg. F. The hazard of these ma terials is flammability. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Continued on next page 417 MCD 000017345 If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material opt of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves. and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water POLISHING WHEEL CEMENT OR GLUE (CEMENT, 4915460 LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1133 Polishing wheel cement or glue is the solution of various gums or resins in various solvents. The liquids are generally quite thick and range from clear colorless to black "tars." the flash point depends on the solvent used but it will be between 100 and 199 deg. F. The hazard of these materials is combustibility. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water POLISHING WHEEL CEMENT THINNER 4915426 (COMBUSTIBLE LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Polishing wheel cement thinner is a material containing a solvent having a closed cup flash point between 100 and 199 deg. F. The hazard is combustibility. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 418 MOD 00C017?46 POLISHING WHEEL CEMENT THINNER (FLAMMABLE 4910426 LIQUID, N.O.S.) FLAMMABLE LIQUID UN1993 Polishing wheel cement thinner is a material containing a solvent having a closed cup flash point below 100 deg. F. The hazard is flammability. tf material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water POLYCHLOR AGRICULTURAL FUNGICIDES 4921490 (POISONOUS SOLID, N.O.S.) POISON B NA2611 Polychlor agricultural fungicides are generally waxy solids insoluble in water and non combustible. They are toxic by ingestion, inhalation (vapor, dust etc.) or by skin absorption. If material on fire or involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when lighting fires involv ing this material if contact with the material anticipated, wear full protective clothing POLYCHLORINATED BIPHENYL OR PCBS 4961666 ORM-E UN2315 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10/4.54) Polychlorinate biphenyls are colorless to light colored liquids. They are used as coolants in transformers and in electrical capacitors. They are insoluble in water. They are non-volatile and non-combustible. They are extremely persistent in the environment. It weighs 12.5 pounds per gallon. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary April 1981 Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates POLYETHYLBENZENE (COMBUSTIBLE LIQUID, 4913155 N.O.S.) COMBUSTIBLE LIQUID NA1993 Polyethylbenzene in a clear colorless liquid with a petroleum like odor. It has a flash point of 160 deg.f. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Appty water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water POLYETHYLLIGROIN (PETROLEUM ETHER) 4915227 COMBUSTIBLE LIQUID NA1993 Polyethylligrom is a clear colorless liquid with a petroleum like odor. It has a flash point between 100 and 199 deg. F It is lighter than water and insoluble in water. Its vapors are heavier than air If material on fire or invoived in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors April 1981 MCD DOO017347 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water POLYETHYLLIGROIN (PETROLEUM ETHER) 4910227 FLAMMABLE LIQUID UN1271 Polyethylligrom is a clear colorless liquid with a petroleum like odor, it has flash point of less than 100 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may spread fire Coot all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water POTASSIUM ALKALI SALTS, CRUDE, DRY (OXIDIZING 4918760 MATERIALS, N.O.S) OXIDIZER UN1479 Potassium alkali salts, crude, dry are various naturally occurring ma terials which have the property of accelerating the burning of combustible material. These materials may not be combustible themselves. The mateterials may be found only in containers of 55-gallon capacity or smaller. If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet POTASSIUM ARSENATE, SOLID 4923277 POISON B UN1677 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Potassium arsenate, solid is a white crystalline solid. It is soluble m water. It is toxic by ingestion. Continued on next page 419 If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material if contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Add ferric chloride (fecl3) Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates POTASSIUM BIFLUORIDE SOLUTION ( See POTASSIUM HYDROGEN FLUORIDE SOLUTION 4932365) POTASSIUM BROMATE 4918736 OXIDIZER UNI 484 Potassium bromate is a white crystalline solid. It is soluble in water. It forms very flammable mixtures with combustible materials and this mixture may be explosive if the combustible material is very finely di vided. The mixture can be ignited by friction. Prolonged exposure to tire or heat by the material can result in an explosion. If material on fire or Involved In fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts oi water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet POTASSIUM ARSENITE, SOLID 4923278 POISON B UNI 678 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Potassium arsenite. solid is a white powder. It is soluble in water. It is toxic by ingestion, and by inhalation (dusts.etc). If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not Involved In fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear lull protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Add calcium hypochlorite Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Add ferric chloride (fecl3) Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates 420 >v<c r ooo I*? 348 POTASSIUM CHLORATE 4918722 OXIDIZER UN 1485 Potassium chlorate is a white crystalline solid, it is used to make matches, paper, explosives, and for may other uses. It is soluble in water. It forms a very flammable mixture with combustible materials and this mixture may be explosive if the combustible material is very finely divided. The mixture can be ignited by friction. Contact with strong sul furic acid can cause fires or explosions, when mixed with ammonium salts, spontaneous decomposition and ignition may result. Prolonged exposure of the material to fire or heat can result in an explosion. If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible II material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet POTASSIUM CHROMATE 4963364 ORM-E NA9142 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Potassium chromate is a yellow crystalline solid. It is used in chemical analysis, in making pigments for paints and inks, as a fungicide, and to make other chromium compounds. It is soluble in water. It is non combustible. It material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Materia) itself does not bum or bums with difficulty.) April 1981 If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Oig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Add sodium bisulfite Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates POTASSIUM CYANIDE SOLUTION 4923225 POISON B UN1660 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10/4.54) Potassium cyanide solution is the water solution of the white crystalline solid, it is used for gold and silver extraction, in chemical analysis, to make other chemicals, and as an insecticide. Has the faint odor of bitter almonds. It is slowly decomposed by water and very rapidly by acids to yield hydrogen cyanide a flammable poison gas, It is toxic by skin absorption through open wounds, by ingestion, and by inhalation of hydrogen cyanide from the decomposition of the material. Toxic oxides of nitrogen are produced in fires involving this material. If material on fire or involved In fire Extinguish fire using agent suitable for type of surrounding fire (Matehal itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Use foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Add caustic soda Add calcium hypochlorite Adjust ph to neutral (ph-7) Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment April 1981 MCI) 000017349 POTASSIUM CYANIDE, SOUD 4923226 POISON B UN1680 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10/4.54) Potassium cyanide solid is a white crystalline or lump solid having the faint odor of bitter almonds. It absorbs water from the air forming a syrup. It is slowly decomposed by water and very rapidly by acids to give off hydrogen cyanide, a flammable poison gas. It is toxic by skin absorption through open wounds, by ingestion, and by inhalation of hydrogen cy anide from the decomposition of the material. Toxic oxides of nitrogen are produced in fires involving this material. If material Involved in fire Extinguish fire using agent suitable (or type of surrounding fire (Material itself does not bum or burns with difficulty.) Use foam, carbon dioxide or dry chemical Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If material not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Use water spray to knock-down vapors Do not use water on material itself Personnel protection Avoid breathing vapors or dusts Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Add caustic soda Add calcium hypochlorite Adjust ph to neutral (ph-7) Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment POTASSIUM DICHLORO-S-TRIAZINETRIONE (DRY, 491B430 CONTAINING MORE THAN 39% AVAILABLE CHLORINE) OXIDIZER NA2465 Potassium dichloro-s-triazinetrione is a white crystalline solid with an odor of chlorine, it is used as a dry bleach in household cleaning com pounds and swimming pool disinfectants. The material itself is noncom bustible but if contaminated with a combustible material ignition can result. It will accelerate the burning of combustible materials. Contact with ammonium compounds or hydrated salts can cause a very vigorous chemical reaction. May vigorously react with small quantities of water releasing chlorine gas. Prolonged exposure to fire or heat of the material may result in the vigorous decomposition of the material and the rup turing of its containers. Material containing less than 39 percent available chlorine will undergo reactions as described above though it may take longer to initiate and the resulting reaction may not be as vigorous. If material on fire or Involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Continued on next page 421 If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Peraonnel protection Avoid breathing dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the Cody with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet POTASSIUM DICHROMATE 4941160 ORM-A NA1479 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Potassium dichromate is a yellowish red crystaline solid. It is used in the production of other chemicals, in pyrotechnics, and explosives, in dyeing and printing, in tanning leather, and in many other uses. It is non combustible. It is soluble in water. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with dilute acid or removable strong acid Add sodium bisulfite Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Adjust ph to neutral lph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates POTASSIUM FLUORIDE SOLUTION 4932363 CORROSIVE MATERIAL, ACIDIC UNI 812 Potassium fluoride solution is the white powder dissolved in water. It has a pungent odor, The liquid or mist is irritating to the eyes, mucous membranes and skin. It is corrosive to metals and tissue. H material involved in lire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible H material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, and goggles 422 Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing POTASSIUM HYDRATE (See POTASSIUM HYDROXIDE, DRY, SOLID, FLAKE, BEAD, OR GRANULAR 4935225 OR POTASSIUM HYDROXIDE, LIQUID OR SOLUTION 4935230) POTASSIUM HYDROGEN FLUORIDE SOLUTION 4932365 CORROSIVE MATERIAL, ACIDIC NA1611 Potassium hydrogen fluoride solution is the colorless crystalline solid dissolved in water, it is used to produce fluorine, and as a metallurgical flux. It is corrosive to metals and tissue. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash, or lime Peraonnel protection Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting tires involv ing this material If contact with the material anticipated, wear full protective clothing POTASSIUM HYDROXIDE, DRY, SOLID, FLAKE, 4935225 BEAO, OR GRANULAR CORROSIVE MATERIAL, BASIC UN1613 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Potassium hydroxide, dry is a white solid. It is soluble in water with the evolution of heat. It absorbs moisture from the air and dissolves. It is corrosive to metals and tissue. It material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Apply water from as far a distance as possible If material not Involved in fire Keep material out of water sources and sewers Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with dilute acid or removable strong acid April 1981 OOOOVT POTASSIUM HYDROXIDE. LIQUIO (OR) SOLUTION 4935230 CORROSIVE MATERIAL, BASIC UN1814 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Potassium hydroxide, liquid is the water solution of the white solid. It is used to make soaps, other potassium compounds, in liquid fertilizers, and for many other uses. The concentrated solution will dissolve in additional water with evolution of heat. It is corrosive to metals and tissue. It weighs 12.6 pounds per gallon. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with vinegar or other dilute acid Environmental considerations--water spill Neutralize with dilute acid or removable strong acid Environmental considerations--sir spill Apply water spray or mist to knock down vapors POTASSIUM HYPOCHLORITE SOLUTION 4936345 CORROSIVE MATERIAL NA1791 Potassium hypochlorite solution is the white crystalline solid dissolved in water having a faint odor of chlorine. It is used as an industrial bleach. It is corrosive to metals and tissue. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible if material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing April 1981 MCD 000017351 POTASSIUM NITRATE 4918737 OXIDIZER UN14S6 Potassium nitrate is a white crystalline solid. It is used in solid pro pellants, explosives, fertilizers, and for many other uses. The material is soluble in water. It is noncombustible but it will accelerate the burning of combustible materials. If large quantities of the material are involved in the fire or the combustible material is finely divided an explosion may result. Prolonged exposure to fire or heat may result in an explosion, Toxic oxides of nitrogen are produced in fires involving this material. If material on fire or Involved In fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and safety glasses Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Approach fire with caution Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet POTASSIUM NITRATE (SALTPETER), CRUDE 4918741 (OXIDIZING MATERIAL, N.O.S.) OXIDIZER UN1479 Potassium nitrate (saltpeter), crude is a white or dirty grey crystalline solid. The material is soluble in water. It is non-combustible but it will accelerate the burning of combustible materials. If large quantities are involved in fire or the combustible material is finely divided ah explosion may result. Prolonged exposure of the material to fire or heat may result in an explosion. Toxic oxides of nitrogen are produced in fires involving this material. If material on fire or Involved In fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and safety glasses Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when lighting tires involv ing this material Approach fire with caution Evacuation If fire becomes uncontrollable--evacuate for a radius of 2SOOfeet POTASSIUM NITRATE MIXED (FUSED) WITH SODIUM 4918738 NITRITE OXIDIZER UN1487 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-100/45.4) Potassium nitrate mixed (fused) with sodium nitrite is a white crys talline solid. The material is soluble in water. It is noncombustible but it will accelerate the burning of combustible material. If large quantities of the material are involved in the fire or the combustible material is finely divided an explosion may result. If the material is contaminated by ammonium compounds, spontaneous decomposition can occur and the resulting heat may ignite surrounding combustible material. Pro longed exposure of the material to fire or heat may result in an explosion. Toxic oxides of nitrogen are produced in fires involving this material. Continued on next page 423 H material on fire or involved In fire Flood with water Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and safety glasses Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Approach fire with caution Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet Environmental considerations land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations - water spill Add soda ash Add calcium hypochlorite Adjust ph to neutral (ph-7) POTASSIUM NITRITE 4918739 OXIDIZER UNI 488 Potassium nitrite is a yellowish white crystalline solid, it is used to make other chemicals and in chemical analysis. It is soluble in water, it is noncombustible but it will accelerate the burning of combustible material. If large quantities are involved in fire or if the combustible material is finely divided, an explosion may result. If the material is contaminated by ammonium compounds, spontaneous decomposition can occur and resulting heat may ignite surrounding combustible ma terial. Prolonged exposure to fire or heat may result in an explosion. Toxic oxides of nitrogen are produced in fires involving this material. If material on fire or involved in fire Rood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible if material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Pereonnei protection Avoid breathing dusts Wear boots, protective gloves, and safety glasses Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting lires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet If material on fire or Involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and safety glasses Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Approach fire with caution Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet POTASSIUM PERMANGANATE 4918740 OXIDIZER UN1490 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Potassium permanganate is a purplish colored crystalline solid, it is used to make other chemicals, as a disinfectant, and for many other uses. It is soluble in water. The material itself is noncombustible but it will accelerate the burning of combustible material, if the combustible material is finely divided the mixture may be explosive. Contact with liquid combustible materials may result in spontaneous ignition. Contact with sulfuric acid may cause fire or explosion. If material on fire or involved In fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Approach fire with caution Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Add sodium bisulfite (nahsoO) Environmental considerations--water spill Add caustic soda Add sodium bisulfite Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates POTASSIUM PERCHLORATE 4918340 OXIDIZER, THERMALLY UNSTABLE UN1489 Potassium perchlorate is a white crystalline solid- it is used in explo sives and pyrotechnics, in photography and for many other uses. It is slightly soluble in water. The material itself is difficult to bum, but if contaminated by combustible materials it will accelerate their burning. With certain combustible materials it will form explosive mixtures. Pro longed exposure of potassium perchlorate or its containers to fire or heat may result in an explosion. Xct) 424 POTASSIUM PEROXIDE 4918530 OXIDIZER, CORROSIVE UN1491 Potassium peroxide is a yellow granular solid, it is used as a bleach bleaching and oxidizing agent. It is decomposed by water to give po tassium hydroxide, a corrosive material and hydrogen peroxide, another corrosive material which normally will decompose to water and oxygen, mixtures of potassium peroxide and combustible material can be readily ignited by friction, heat or contact with moisture. Prolonged exposure of the material and/or its containers to fire or heat may result in the vigorous decomposition of the material and rupturing of the container. April 1981 52 If material on fire or involved In fire Use dry chemical, graphite, or dry earth Use water only if flooding quantities are available Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet POTASSIUM SULFIDE 4916730 FLAMMABLE SOLID UN1382 Potassium sulfide is a yeltow-red to red crystalline mass or fused solid with an odor of rotten eggs. If exposed to moist air it is liable to spon taneous heating and may cause ignition of nearby combustible material. It absorbs moisture from the air and dissolves in it. If material on fire or Involved in fire Flood with water If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material POTASSIUM PERSULFATE (OXIDIZING MATERIAL, 4918763 N.O.S.) OXIDIZER UNI 479 Potassium persulfate is a white crystalline solid. It is soluble in water and is slowly decomposed by water. It is non-combustible but it will accelerate the burning of combustible material. If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible if material not on fire and not involved in fire Keep sparks, (lames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet POTASSIUM SALTS, NEC (OXIDIZING MATERIALS, 4916761 N.O.S.) OXIDIZER UN1479 Potassium salts, nec are various colored crystalline solids. They are soluble in water. They may be non-combustible but they will accelerate the burning of combustible material. The material may be found only in containers of 55-gallon capacity or smaller. If material on fire or Involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet April 1961 POTASSIUM, METAL 4916445 FLAMMABLE SOLID UN2257 WATER REACTIVE Potassium, metal is a soft silvery metal though normally greyish white due to oxidation. It reacts vigorously with water to form potassium hy droxide. a corrosive material, and hydrogen, a flammable gas. The heat from this reaction is sufficient to ignite the hydrogen. Potassium may ignite spontaneously in contact with air. Once ignited, potassium bums quite violently. If material on fire or Involved in fire Do not use water Do not use carbon dioxide Use graphite, soda ash. powdered sodium chloride, or suitable dry powder If material not on fire and not involved In fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Do not attempt to sweep up dry material Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Avoid breathing fumes from burning material POTASSIUM, METAL LIQUID ALLOY 4916446 FLAMMABLE SOLID UN1420 WATER REACTIVE Potassium metal liquid alloy is potassium mixed with some other metal, usually sodium, it is used as a heat exchange fluid, it is a liquid under normal conditions, it reacts vigorously with water to form potas sium hydroxide, a corrosive material and hydrogen, a flammable gas. the heat from this reaction may be sufficient to ignite the hydrogen, potassium alloy may ignite spontaneously in contact with air. once ig nited, potassium bums quite violently. If material on fire or involved in fire Do not use water Do not use carbon dioxide Use graphite, soda ash, powdered sodium chloride, or suitable dry powder Continued on next page 425 MCD 000017353 If material not on fire and not involved in fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Do not attempt to sweep up dry material Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Avoid breathing fumes from burning material Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on tire), downwind evacuation must be considered PRIMARY N-AMYL ALCOHOL (ALCOHOL, N.O.S.) 4909108 FLAMMABLE LIQUID UN1987 Primary n-amyl alcohol is a colorless liquid. It has a flash point of 91 deg. F. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. if material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools ol liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 1-PROPANOL (ALCOHOL. N.O.S.) 4909267 FLAMMABLE LIQUID UN19B7 1-propanol is a clear colorless liquid with an alcohol-like odor. It has a flash point of 77 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PROPANE 4905781 FLAMMABLE GAS UN1075 Propane is a colorless gas with a faint petroleum like odor. It is shipped as a liquefied gas under its vapor pressure. For transportation it may be stenched. Contact with the liquid can cause frostbite. It is easily ignited. Its vapors are heavier than air and a flame can flash back to the source of leak very easily. This leak can be either a liquid or vapor leak. It can asphyxiate by the displacement of air. Under fire conditions the cylinders or tank cars may violently rupture and rocket. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible H material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors PROPARGITE 4961165 ORM-E NA2765 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10/4.54) Propargite is a dark colored liquid. It is used as a pesticide. It is a wettable powder or water emulsifiable liquid. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. If material involved in fira Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water 426 MCD nooo Ir April 1981 Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Personnel protection Avoid breathing dusts, and fumes from burning material Wear protective gloves and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on tire or involved in fire evacuate tor a radius of 5000 feet PROPARGYL ALCOHOL 4907440 FLAMMABLE LIQUID. POISONOUS NA1986 Propargyl alcohol is a clear colorless liquid with a geranium-like odor. It is used to make other chemicals, as a corrosion inhibitor, and as a soil fumigant. It has a flash point of 97 deg. F. It is lighter than water and is soluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing PROPELLANT EXPLOSIVE (GUN POWDER) 4901610 CLASS A EXPLOSIVE Propellant explosives (gun powder) are black or grey granular solids, the material is easily ignited and once ignited it burns with great vigor. Upon prolonged exposure to fire containers of the material will explode. If material on fire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire end not Involved in fire Keep sparks, flames, and other sources of ignition away Keep spilled material wet Wet spilled material before picking it up Do not attempt to sweep up dry material Personnel protection Avoid breathing dusts, and fumes from burning material Wear protective gloves and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet PROPELLANT EXPLOSIVE 4901602 CLASS A EXPLOSIVE Propellant explosive is a solid chemical or chemical mixture which is designed to function by rapid combustion generally producing little or no smoke. The material is easily ignited and once ignited it burns very vigorously. Upon prolonged exposure to fire containers of the material will explode. It material on fire or involved in fire Dangerously explosive Do not tight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep spilled material wet Wet spilled material before picking it up Do not attempt to sweep up dry material April 1981 PROPELLANT EXPLOSIVE IN WATER (SMOKELESS 4902430 POWDER) CLASS B EXPLOSIVE Propellant explosive in water is single chemical or chemical mixture shipped under water to decrease ease of ignition. Most propellant ex plosives are not soluble in water. The dried material is easily ignited and once ignited bums extremely vigorously. Containers of the material can explode under fire conditions. If material on fire or Involved In fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep spilled material wet Wet spilled material before picking it up Do not attempt to sweep up dry material Continued on next page 427 MCD 000017355 Personnel protection Avoid breattiing dusts, and fumes from burning material Wear protective gloves and goggles Do not handle broken packages without protective eouipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet PROPELLANT EXPLOSIVE IN WATER, UNSTABLE, 4902440 CONDEMNED OR DETERIORATED CLASS B EXPLOSIVE Propellant explosive in water unstable, condemned or deteriorated is a single chemical or chemical mixture which has undergone some de composition due to exposure or age- The material is more susceptible to ignition even to spontaneous ignition than the original material. For this reason it is shipped in water. The dry material is easily ignited and bums extremely vigorously. Containers of the material under fire con ditions can explode. If material on fire or involved In fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep spilled material wet Wet spilled material before picking it up Do not attempt to sweep up dry material Personnel protection Avoid breathing dusts, and fumes from burning material Wear protective gloves and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting tires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet PROPELLANT EXPLOSIVE SOLID 4902420 CLASS B EXPLOSIVE Propellant explosive, solid is a single chemical or chemical mixture. The material is easily ignited and burns extremely vigorously once ig nited. Containers of the material can explode under fire conditions. If material on fire or involved in fire Dangerously explosive Do not fight fires In a cargo of explosives Evacuate area and let bum If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep spilled material wet Wet spilled material before picking it up Do not attempt to sweep up dry material Personnel protection Avoid breathing dusts, and fumes from burning material Wear protective gloves and goggles Do not handle broken packages without protective equipment 428 MCC 000017356 Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet PROPELLANT EXPLOSIVE, LIQUID 4902310 CLASS B EXPLOSIVE Propellant explosive, liquid is a single chemical normally in the liquid state or a mixture of chemicals some of which are liquids. The liquid is usually thick and not very free flowing. Trie material is easily ignited by a flame and once ignited burns very vigorously. If material on fire or involved In fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep spilled material wet Wet spilled material before picking it up Do not attempt to sweep up dry material Personnel protection Avoid breathing dusts, and fumes from burning material Wear protective gloves and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this matena! Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet PROPELLANT EXPLOSIVE, SOLID (GUN POWDER) 4902410 CLASS B EXPLOSIVE Propellant explosive, solid (gun powder) is a solid chemical or chem ical mixture. The material is easily ignited and burns very rapidly once ignited. Containers of the material can explode under fire conditions. If material on fire or Involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep spilled material wet Wet spilled material before picking it up Do not attempt to sweep up dry material Personnel protection Avoid breathing dusts, and fumes from burning material Wear protective gloves and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation if the material is on fire or involved in fire evacuate for a radius of 2500 feet April 1981 PROPIONALDEHYDE 4906270 FLAMMABLE LIQUID UNI 275 Propionaldehyde is a clear colorless liquid with an overpowering fruity odor. It has a flash point of 15 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water frem as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered PROPIONIC ACID 4931448 CORROSIVE MATERIAL, ACIDIC, COMBUSTIBLE UN1648 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Propionic acid is a colorless liquid with a pungent rancid odor, it is combustible and has a flash point of 130 deg. F. It is soluble in water with release of heat. It is corrosive to metals and tissue. It weighs B.3 pounds per gallon. If material on fire or Involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing April 1981 MCI) ^00017357 Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment PROPIONIC ACID SOLUTION 4931447 CORROSIVE MATERIAL. ACIDIC UN1B48 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Propionic acid solution is the solution of propionic acid in water having a pungent rancid odor. The solution may burn though it may require some effort to ignite. It is soluble in water with release of heat. It is corrosive to metals and tissue, it weighs 8.3 pounds per gallon. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not involved In fire Keep sparks, tiames. and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash. or iime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenai which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment 429 PROPIONIC ANHYORIDE 4931449 CORROSIVE MATERIAL, ACIDIC, COMBUSTIBLE UN2496 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Propionic anhydride is a colorless liquid with a pungent odor. It is combustible and has a flash point of 165 deg. F. It is decomposed by water to propionic acid which is soluble in water with release of heat. It is corrosive to metals and tissue, it weighs 8.4 pounds per gallon. If material on fire or Involved in fire Use water in flooding quantities as fog Solid streams of water may De ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment PROPIONYL PEROXIDE. (NOT MORE THAN 28% IN 4919187 SOLUTION) ORGANIC PEROXIDE UN2132 Propionyi peroxide, (not more than 28% in solution is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite; but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of com bustible materials. Under prolonged exposure to fire or heat, containers of the materials may explode. If material on fire or Involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive 430 00, If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in tire evacuate for a radius of 2500 feet PROPYL ACETATE 4909268 FLAMMABLE LIQUID UN1276 Propyl acetate is a clear colorless liquid with a pleasant odor. It has a flash point of 58 deg. F. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. If material on fira or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PROPYL AMINE (MONO-N-PROPYLAMINE) 4908269 FLAMMABLE LIQUID UNI 277 Propyl amine is a clear colorless liquid with an ammonia-like odor, it is used in chemical analysis and to make other chemicals, it has a flash point of -35 deg.f. it is lighter than water and soluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during com bustion of this material. If material on fira or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical April 1981 if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered PROPYL CHLORIDE 490626B FLAMMABLE LIQUID UN1278 Propyl chloride is a clear colorless liquid. It has a flash point of less than 0 deg. F. It is lighter than water and very slightly soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless (low can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities o< water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If materia) leaking (not on fire), downwind evacuation must be considered PROPYL FORMATE 4909271 FLAMMABLE LIQUID UN1281 Propyl formate is a clear colorless liquid with a pleasant odor, ft has a flash point of 27 deg. F. It is very slightly soluble in water and is lighter than water. Its vapors are heavier than air. April 1981 if material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PROPYL MERCAPTAN 4909272 FLAMMABLE LIQUID UN2704 Propyl mercaptan is a clear colorless liquid with an offensive odor. It has a flash point of-5 deg. F. It is lighter than water and very slightly soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material PROPYL TRICHLOROSILANE 4934280 CORROSIVE MATERIAL, ACIDIC, COMBUSTIBLE UN1816 Propyl trichlorosilane is a colorless liquid with a pungent odor. II is combustible and has a flash point of 100 deg. F. It is decomposed by water to hydrochloric acid with evolution of heat. It is corrosive to metals and tissue. If material on Are or Involved in fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Continued on next page 431 :I) 000017 359 M(- If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing PROPYLENE 4905782 FLAMMABLE GAS UN1075 Propylene is a colorless gas with a faint petroleum like odor. It is used to make other chemicals. It is shipped as a liquefied gas under its own vapor pressure. For transportation it may be sienched. Contact with the liquid can cause frostbite. It is easily ignited. Its vapors are heavier than air. and a flame can flash back to the source of leak very easily. This leak can be either a liquid or vapor leak. It can asphyxiate by the dis placement of air. Under lire conditions the cylinders or tankcars may violently rupture and rocket. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop teak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered PROPYLENE DIAMINE 4907860 FLAMMABLE LIQUID. CORROSIVE. BASIC UN2258 Propylene diamine is a colorless liquid with an ammonia-iike odor. It has a flash point of 92 deg. F. It is corrosive to metals and tissue. It is lighter than water and soluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical Use water spray to absorb vapors 432 If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of i500 feet If material leaking (not on fire), downwind evacuation must be considered PROPYLENE DICHLORIDE 4909269 FLAMMABLE LIQUID UN1279 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Propylene dichloride is a clear colorless liquid with a chloroform-like odor. It has a flash point of 60 deg. F. It is heavier than water and insoluble in water. Its vapors are heavier than air. It weighs 9.6 pounds per gallon, if material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical tf material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash, cement powder, sawdust, or com mercial sorbents Apply fluorocarbon-water foam to diminish vapor and fire hazard Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates April 1981 MOD 000017360 Environmental considerations--air spill Apply water spray or mist to knock down vapors Combustion products include corrosive or toxic vapors Thermal decomposition to phosgene can occur PROPYLENE (MINE, INHIBITED 4907040 FLAMMABLE LIQUID, POISONOUS UN1921 THERMALLY UNSTABLE Propylene imine. inhibited is a clear colorless liquid with an ammonia like odor. It has a flash point of 25. deg. F. If it contacts an acid, it is subject to violent polymerization. It is toxic by ingestion and through skin absorption. It is lighter than water and soluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combus- tion of this material. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain fiow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered PROPYLENE OXIDE 4906620 FLAMMABLE LIQUID, CORROSIVE UN1280 THERMALLY UNSTABLE ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Propylene oxide is a clear, colorless, volatile liquid with an ethereal odor. It is used as a fumigant, in making detergents and lubricants, and to make other chemicals. It has a flash point of -35 deg.f. And boils at 95 deg. F. It is flammable over a wide range of vapor-air concentrations. If contaminated it may polymerize with evolution of heat and possible rupture of container. Vapors are irritating to eyes, skin, and respiratory system; prolonged contact with skin may result in delayed bums. It is lighter than water and soluble in water. The vapors are heavier than air. It weighs 6.9 pounds per gallon. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use ' alcohol'1 foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 5000 feet If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash, cement powder, sawdust, or com mercial sorbents Apply "universal'' gelling agent to immobilize spill Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e g. detergent, soaps, alcohols) to com press and thicken spilled material Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors PULP MILL LIQUID (COMBUSTIBLE LIQUID, N.O.S.) COMBUSTIBLE LIQUID 4915350 NA1993 Pulp mill liquid is clear colorless to milky tan colored liquid with an offensive odor. It has a flash point between 100 and 199 deg. F. It is about the same weight as water and soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 0000.17' J61 433 PULP MILL LIQUID (FLAMMABLE LIQUID, N.O.S.) 4910320 FLAMMABLE LIQUID UN1993 Pulp mill liquid is clear colorless to milky tan colored liquid with an offensive odor. It has a flash point of less than 100 deg. F. It is about the same weight as water and soluble in water. Its vapors are heavier than air. If material on fire or involved in lire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PYRETHRINS (AGRICULTURAL INSECTICIDES, NEC. 4963877 OTHER THAN LIQUID) ORM-E NA9184 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-1000/454) Pyrethrins are colorless to white liquid absorbed on a dry carrier. It is used as a pesticide. It is a wettable oowder. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates PYRETHRINS (AGRICULTURAL INSECTICIDES, NEC, LIQUID) 4963872 ORM-E NA9184 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RG-1000/454) Pyrethrins are colorless to white liquids. It is used as a pesticide. It is a water emulsifiable liquid. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to, or leaking from con tainers of this material contact the pesticide safety team network. Tele phone; 800-424-9300, If material Involved In fire Extinguish tire using agent suitable for type of surrounding tire (Material itself does not burn or burns with difficulty.) If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates 434 M OD 0 0 0 017g o PYRETHRINS (INSECTICIDES, OTHER THAN 4963868 AGRICULTURAL, NEC) ORM-E NA9184 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Pyrethrins are colorless to white liquids. It is used as a pesticide. It is a water emulsifiable liquid. It can cause illness by inhalation, skin absorption and/or ingestion, in case of damage to. or leaking from con tainers of this materia! contact the pesticide safety team network. Tele phone; 800-424-9300. if material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) H material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with tty ash or cement powder Environmental considerations--water spill if dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates April 1981 PYRETHRINS (PYRETHRUM EXTRACT, NOT LESS 4963886 THAN 25% PYRETHRUM) ORM-E NA9164 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100Q/454) Pyrethrins are colorless to white liquids. It is used as a pesticide. It is a wettable powder or water emulsifiable liquid. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dike surface fiow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of tOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates PYRIDINE 4909277 FLAMMABLE LIQUID UN1282 Pyridine is a clear colorless to light yellow liquid with a penetrating nauseating odor. It has a flash point of 68 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. Toxic, oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing PYRETHRINS (PYRETHRUM) 4963881 ORM-E NA9184 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Pyrethrins are colorless to white liquids, it is used as a pesticide. It is a wettable powder or water emulsifiable liquid. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. If material involved in fire Extinguish fire using agent suitable tor type of surrounding fire (Material itself does not bum or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates April 1981 Ken OnJ0j PYROFORIC LIQUID, N.O.S. 4906070 FLAMMABLE LIQUID UN2845 PYROFORIC Pyroforic liquids, n.o.s.. are materials whose principal property is that of igniting spontaneously in contact with moist air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Do not use water Use graphite, soda ash or powdered sodium chloride If material not on fire and not involved in fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered s&3 435 PYROLIDINE 4909280 FLAMMABLE LIQUID UN1922 Pyrolidine is a colorless to pale yellow liquid with an ammonia like odor. It has a flash point of 37 deg. F. It is lighter than water and is soluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced dunng combustion of this material. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out ot water sources and sewers Build dikes fo contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodiiy contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the materia) anticipated, wear full protective clothing PYROLIGNEOUS ACID (COMBUSTIBLE LIQUID, 4915428 N.O.S.) COMBUSTIBLE LIQUID NA1993 Pyroligneous acid is a yellow to red liquid containing methyl alcohol, acetic acid, acetone and other materials. It has a flash point between 100 and 199 deg. F. it is lighter than water and soluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with Hooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and outer sources ot ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PYROLIGNEOUS ACID (FLAMMABLE LIQUID, N.O.S.) 4910428 FLAMMABLE LIQUID UNI 993 Pyroligneous acid is a yellow to red liquid containing methyl alcohol acetic acid, acetone and other materials. It has a flash point of less than 100 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PYROSULFURYL CHLORIDE 4930250 CORROSIVE MATERIAL, ACIDIC UN1817 Pyrosulfuryl chloride is a colorless fuming liquid with a pungent odor. It reacts with water to form hydrochloric and sulfuric acids with release of heat. It is irritating to the eyes and mucous membranes. It is corrosive to metals and tissue. If material involved in fire Do not use water on material itself Use foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing PYROXYLIN PLASTIC SCRAP 4917352 FLAMMABLE SOLID NA2006 Pyroxylin plastic scrap is the waste material from the manufacture of articles from pyroxylin plastic, a form of cellulose nitrate. It is easily ignited and once ignited it bums with great rapidity. Toxic oxides of nitrogen are produced during combustion. If material on fire or involved in fire Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible 436 April 1981 MOD 000017364 If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Wear self-contained breathing apparatus when fighting fires involv ing this material PYROXYLIN PLASTICS, RODS, SHEETS, ROLLS, 4917440 TUBES FLAMMABLE SOLID NA2006 Pyroxylin plastic is a form of cellulose nitrate. It is easily ignited and once ignited it burns with great rapidity. Toxic oxides of nitrogen are produced during combustion. If material on fire or involved In fire Flood with water If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Wear self-contained breathing apparatus when fighting fires involv ing this material If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use ` alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material PYROXYLIN SOLUTION 4910275 FLAMMABLE LIQUID NA2059 Pyroxylin solution is pyroxylin plastic dissolved in a suitable solvent. It has a flash point of less than 100 deg. F. The solvent may evaporate if spilled leaving a pyroxylin plastic film. This film is easily ignited and bums very vigorously. The hazard of the solution is flammability. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessaty Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material PYROXYLIN SOLUTION 4915275 COMBUSTIBLE LIQUID NA2059 Pyroxylin solution is pyroxylin plastic dissolved in a suitable solvent. It has a flash point between 100 and 199 deg. F. The solvent may evaporate if spilled leaving a pyroxylin plastic film. This film is easily ignited and bums very vigorously. The hazard of the solution is com bustibility. Toxic oxides of nitrogen are produced during combustion of this material. PYROXYLIN SOLVENT, N.O.S. 4910276 FLAMMABLE LIQUID NA2059 Pyroxylin solvent, n.o.s. is the proper shipping name for pyroxylin solvents having a closed cup flash point of less than 100 deg. F. and not specifically mentioned in the hazardous materials regulations. The hazard is flammability. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water PYROXYLIN SOLVENT, N.O.S. 4915276 COMBUSTIBLE LIQUID NA2059 Proper shipping name for pyroxylin solvents having a closed cup flash point between 100 and 199 deg. F,, and not specifi cally mentioned in the hazardous materials regulations. The hazard is combustibility. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'1 foam, carbon dioxide or dry chemical Continued on next page April 1981 MCI) 00017365 437 If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water QUINALDINE (COMBUSTIBLE LIQUID, N.O.S.) 4913188 COMBUSTIBLE LIQUID NA1993 Quinaldine is a colorless oily liquid darkening to red-brown on ex posure to air. it is used to make dyes, pharmaceuticals and other chem icals. it has a Hash point of 175 deg. F. It is heavier than water and slightly soluble in water, its vapors are heavier than air. toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Do not extinguish tire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Appty water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing QUINOLINE 4963367 ORM-E UN2656 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Quinoline is a clear colorless liquid that may darken on exposure to light or air. It is used in the manufacture of pharmaceuticals, dyes, paints and other chemicals. It absorbs moisture from the air and is slightly soluble in cold water. It will bum though it may take some effort to ignite. Toxic oxides of nitrogen are produced during the combustion of this material. It weighs 9.7 pounds per gallon. if material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use foam, carbon dioxide or dry chemical If material not on fire and not invoivad in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors or dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Environmental considerations--land spill Digapit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Apply "universal" gelling agent to immobilize spill Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region ol lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors RADIOACTIVE ARTICLES, NEC (RADIOACTIVE 4926420 DEVICE, N.O.S.) RAOIOACTIVE MATERIAL UN2911 Radioactive articles, nec are various devices which contain smalt amounts of a radioactive material. Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful whereas films may be damaged by radiation from relatively low concentrations. If material on fire or involved In fire Contact the local, state, or department of energy radiological re sponse team Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Appty water from as far a distance as possible (f material not on fire and not invoivad in fire Contact the local, state, or department of energy radiological re sponse team Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Keep upwind Avoid breathing fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation Keep unnecessary people out of incident area until area declared safe by radiological response team 438 April 1981 000017366 mod RADIOACTIVE ARTICLES, NEC (RADIOACTIVE 4928420 DEVICE, N.O.S., FISSILE CLASS II) RADIOACTIVE MATERIAL UN2911 Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful whereas films may be damaged by radiation from relatively low concentrations. Fissile radioactive materials are uranium 233, uranium 235, plutonium 238, plutonium 239, or plutonium 241. In addition to the radiation hazards presented by most radioactive materials, fissile materials, if improperly handled, may be critical. This means that if too large quantities of these materials are permitted in one place a very rapid nuclear reaction can occur. This would not be explosive, but large amounts of radiation would be emitted suddenly and might injure nearby personnel, in case of trou ble with these shipments all unauthorized persons should be kept as far away as possible until qualified people with proper equipment can be obtained from the local or state radiological response team, the de partment of energy, or the shipper. If material on fire or involved in fire Contact the local, state, or department of energy radiological re sponse team Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Contact the local, state, or department of energy radiological re sponse team Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Keep upwind Avoid breathing fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation Keep unnecessary people out of incident area until area declared safe by radiological response team RADIOACTIVE ARTICLES. NEC (RADIOACTIVE 4927420 DEVICE, N.O.S., FISSILE CLASS III) RADIOACTIVE MATERIAL UN2911 Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful whereas films may be damaged by radiation from relatively low concentrations. Fissile radioactive materials are uranium 233, uranium 235, plutonium 238, plutonium 239, or plutonium 241. In addition to the radiation hazards presented by most radioactive materials, fissile materials, if improperly handled, may be critical. This means that if too large quantities of these materials are permitted in one place a very rapid nuclear reaction can occur. This would not be explosive, but large amounts of radiation would be emitted suddenly and might injure nearby personnel. In case of trou ble with these shipments all unauthorized persons should be kept as far away as possible until qualified people with proper equipment can be obtained from the local or state radiological response team, the de partment of energy, or the shipper. If material on fire or Involved in fire Contact the local, state, or department of energy radiological re sponse team Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) April 1981 Man oocn7 187 Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on tire and not involved In fire Contact the local, state, or department of energy radiological re sponse team Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Keep upwind Avoid breathing fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation Keep unnecessary people out of incident area until area declared safe by radiological response team RADIOACTIVE DEVICE, N.O.S., FISSILE CLASS I 4929420 (RADIOACTIVE ARTICLES, NEC) RADIOACTIVE MATERIAL UN2911 Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful whereas films may be damaged by radiation from relatively low concentrations. Fissile radioactive materials are uranium 233. uranium 235, plutonium 238, plutonium 239, or plutonium 241. In addition to the radiation hazards presented by most radioactive materials, fissile materials, if improperly handled, may be critical. This means that if too large quantities of these materials are permitted in one place a very rapid nuclear reaction can occur. This would not be explosive, but large amounts of radiation would be emitted suddenly and might injure nearby personnel. In case of trou ble with these shipments all unauthorized persons should be kept as far away as possible until qualified people with proper equipment can be obtained from the local or state radiological response team, the de partment of energy, or the shipper. If material on fire or involved in fire Contact the local, state, or department of energy radiological re sponse team Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved in fire Contact the local, state, or department of energy radiological re sponse team Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Keep upwind Avoid breathing fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation Keep unnecessary people out of incident area until area declared safe by radiological response team 439 RADIOACTIVE ISOTOPES, NEC (RADIOACTIVE 4926441 MATERIALS, N.O.S.) RADIOACTIVE MATERIAL NA9181 Radioactive isotopes, nec are various chemical compounds having following property. Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure to humans to intense radiation may be harmful whereas films may be damaged by radiation from relatively low concentrations. If material on fire or involved in fire Contact the local, state, or department of energy radiological re sponse team Extinguish fire using agent suitable tor type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Contact the local, state, or department of energy radiological re sponse team Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Keep upwind Avoid breathing dusts, and fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation Keep unnecessary people out of incident area until area declared safe by radiological response team Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful whereas films may be damaged by radiation from relatively low concentrations. If material on fire or involved In fire Use water in flooding quantities as fog Contact the local, state, or department of energy radiological re sponse team Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not on fire and not involved in fire Contact the local, state, or department of energy radiological re sponse team Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Keep upwind Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation Keep unnecessary people out of incident area until area declared safe by radiological response team RADIOACTIVE MATERIAL SHIPPING CONTAINERS, STEEL AND URANIUM METAL EMPTY 4926467 (RADIOACTIVE MATERIAL,N.O.S.) RADIOACTIVE MATERIAL NA9161 Radioactive material shipping containers, steel and uranium metal, empty are packagings for transporting those radioactive materials which require protective shielding. They consist of a steel framework and cover and are lined with depleted uranium. Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful whereas film may be damaged by radiation from relatively low concentrations. If material involved in fire Contact the local, state, or department of energy radiological re sponse team Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved In fire Contact the local, state, or department of energy radiological re sponse team Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Keep upwind RADIOACTIVE MATERIAL, LIMITED QUANTITY, N.O.S. 4926460 (RADIOACTIVE ARTICLES OR ISOTOPES, NEC) RADIOACTIVE MATERIALS UN2910 Radioactive material, limited quantity, n.o.s. is a very small quantity of radioactive material. 440 RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY 4926430 (OR) LSA., N.O.S. (RADIOACTIVE MATERIALS, ARTICLES OR ISOTOPES, NEC) RADIOACTIVE MATERIAL UN2912 Radioactive material, low specific activity, n.o.s. are items which pos sess very low levels of radioactivity. There may be such things as ores or ore concentrates, or items not normally radioactive but which have been contaminated by radioactive materials. Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful whereas films may be damaged by radiation from relatively low concentrations. If material on fire or involved in fire Contact the local, state, or department of energy radiological re sponse team Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved inirre Contact the local, state, or department of energy radiological re sponse team Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Do not approach area of incident until measurements with suitable instruments have shown that it is safe to do so Evacuation Keep unnecessary people out of incident area until area declared safe by radiological response team MCD 00 0017368 April 1981 RADIOACTIVE MATERIAL, N.O.S. 4926440 RADIOACTIVE MATERIAL NA9181 Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful whereas films may be damaged by radiation from relatively low concentrations. If material on fire or Involved in fire Contact the local, state, or department of energy radiological re sponse team Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible H material not on fire and not involved in fire Contact the local, state, or department of energy radiological re sponse team Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Keep upwind Avoid breathing dusts, and fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation Keep unnecessary people out of incident area until area declared safe by radiological response team RADIOACTIVE MATERIAL, N.O.S. FISSILE CLASS I 4929440 RADIOACTIVE MATERIAL NA9181 Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful whereas films may be damaged by radiation from relatively low concentrations, fissile radioactive materials are ura nium 233, uranium 235. plutonium 238, plutonium 239. or plutonium 241. In addition to the radiation hazards presented by most radioactive materials, fissile materials, if improperly handled, may be critical. This means that if too large quantities of these materials are permitted in one place a very rapid nuclear reaction can occur. This would not be explo sive. but large amounts of radiation would be emitted suddenly and might injure nearby personnel. In case of trouble with these shipments ail unauthorized persons, should be kept as far away as possible until qualified people with proper equipment can be obtained from the local or state radiological response team, the department of energy, or the shipper. If material on fire or Involved in fire Contact the local, state, or department of energy radiological re sponse team Extinguish fire using agent suitable tor type of surrounding fire (Material itself does not bum or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Contact the local, state, or department of energy radiological re sponse team Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Keep upwind Avoid breathing dusts, and fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation Keep unnecessary people out of incident area until area declared safe by radiological response team April 1981 MCD 000017369 RADIOACTIVE MATERIAL, N.O.S. FISSILE CLASS II 4928440 RADIOACTIVE MATERIAL NA9181 Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful whereas films may be damaged by radiation from relatively low concentrations. Fissile radioactive materials are uranium 233, uranium 235. plutonium 236. plutonium 239. or plutonium 241. In addition to the radiation hazards presented by most radioactive materials, fissile materials, if improperly handled, may be critical. This means that if too large quantities of these materials are permitted in one place a very rapid nuclear reaction can occur. This would not be explosive, but large amounts of radiation would be emitted suddenly and might injure nearby personnel. In case of trou ble with these shipments all unauthorized persons should be kept as far away as possible until qualified people with proper equipment can be obtained from the local or state radiological response team, the de partment of energy, or the shipper. If material on fire or involved In fire Contact the local, state, or department of energy radiological re sponse team Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Contact the local, state, or department of energy radiological re sponse team Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Keep upwind Avoid breathing dusts, and fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation Keep unnecessary people out of incident area until area declared safe by radiological response team RADIOACTIVE MATERIAL, N.O.S. FISSILE CLASS III 4927440 RADIOACTIVE MATERIALS NA9181 Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful whereas films may be damaged by radiation from relatively low concentrations. Fissile radioactive materials are uranium 233, uranium 235, plutonium 238. plutonium 239. or plutonium 241. In addition to the radiation hazards presented by most radioactive materials, fissile materials, if improperly handled, may be critical. This means that if too large quantities of these materials are permitted in one place a very rapid nuclear reaction can occur. This would not be explosive, but large amounts of radiation would be emitted suddenly and might injure nearby personnel, in case of trou ble with these shipments all unauthorized persons should be kept as far away as possible until qualified people with proper equipment can be obtained from the local or state radiological response team, the de partment of energy, or the shipper. Continued on next page 441 tf material on fire or Involved In fire Contact the local, state, or department of energy radiological re sponse team Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved In fire Contact the local, state, or department of energy radiological re sponse team Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Keep upwind Avoid breathing dusts, and fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation Keep unnecessary people out of incident area until area declared safe by radiological response team RADIOACTIVE MATERIAL. SPECIAL FORM. N.O.S. RADIOACTIVE MATERIAL 4926450 NA9182 Radioactive material, special form, n.o.s. is either the radioactive material existing as a solid piece of metal or encapsulated in a metal casing. In either case the minimum dimensions are approximately 0.25" in diameter by 2". Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful whereas films may be damaged by radiation from relatively low concentrations. If material on fire or involved in fire Contact the local, state, or department of energy radiological re sponse team Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Contact the local, stale, or department of energy radiological re sponse team Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Keep upwind Avoid breathing dusts, and fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation Keep unnecessary people out of Incident area until area declared safe by radiological response team RADIOACTIVE MATERIAL, SPECIAL FORM, N.O.S., 4929450 FISSILE CLASS I RADIOACTIVE MATERIAL NA9182 Radioactive material, special form, n.o.s. is either the radioactive material existing as a solid piece of metal or encapsulated in a metal casing. In either case the minimum dimensions are approximately 0.25 ' in diameter by 2". Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful whereas films may be damaged by radiation from relatively low concentrations. Fissile radioactive materials are uranium 233. uranium 235. plutonium 238. plutonium 239. or plutonium 241. In addition to the radiation hazards presented by most radioactive materials, fissile materials, if improperly handled, may be critical. This means that if too large quantities of these materials are permitted in one place a very rapid nuclear reaction can occur. This would not be explosive, but large amounts of radiation would be emitted suddenly and might injure nearby personnel. In case of trou ble with these shipments all unauthorized persons should be kept as far away as possible until qualified people with proper equipment can be obtained from the local or state radiological response team, the de partment of energy, or the shipper. If material on fire or Involved In fire Contact the local, state, or department of energy radiological re sponse team Extinguish fire using agent suitable for type of surrounding lire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved In fire Contact the local, state, or department of energy radiological re sponse team Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Keep upwind Avoid breathing dusts, and fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation Keep unnecessary people out of incident area until area declared safe by radiological response team RAOIOACTIVE MATERIAL, SPECIAL FORM, N.O.S., 4928450 FISSILE CLASS II RADIOACTIVE MATERIAL NA9182 Radioactive material, special form, n.o.s. is either the radioactive material existing as a solid piece of metal or encapsulated in a metai casing. In either case the minimum dimensions are approximately 0.25" in diameter by 2". Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful whereas films may be damaged by radiation from relatively low concentrations. Fissile radioactive materials are uranium 233. uranium 235. plutonium 238, plutonium 239, or plutonium 241. In addition to the radiation hazards presented by most radioactive materials, fissile materials, if improperly handled, may be critical. This means that if too large quantities of these materials are permitted in one place a very rapid nuclear reaction can occur. This would not be explosive, but large amounts of radiation would be emitted suddenly and might injure nearby personnel, in case of trou ble with these shipments all unauthorized persons should be kept as far away as possible until qualified people with proper equipment can be obtained from the local or state radiological response team, the de partment of energy, or the shipper. 442 April 1981 MCD 0000l?37o If material on fire or Involved in fire Contact the local, state, or department of energy radiological re sponse team Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved in fire Contact the local, state, or department o< energy radiological re sponse team Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Keep upwind Avoid breathing dusts, and fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation Keep unnecessary people out of incident area until area declared safe by radiological response team RADIOACTIVE MATERIAL. SPECIAL FORM, N.O.S., 4927450 FISSILE CLASS III RADIOACTIVE MATERIAL NA9162 Radioactive material, special form, n.o.s. is either the radioactive material existing a a solid piece of metal or encapsulated in a metal casing. In either case the minimum dimensions are approximately 0.25" in diameter by 2". Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful whereas films may be damaged by radiation from relatively low concentrations, Fissile radioactive materials are uranium 233, uranium 235, plutonium 238. plutonium 239. or plutonium 241. In addition to the radiation hazards presented by most radioactive materials, fissile materials, if improperly handled, may be critical. This means that if too large quantities of these materials are permitted in one place a very rapid nuclear reaction can occur. This would not be explosive, but large amounts of radiation would be emitted suddenly and might injure nearby personnel. In case of trou ble with these shipments all unauthorized persons should be kept as far away as possible until qualified people with proper equipment can be obtained from the local or state radiological response team, the de partment of energy, or the shipper. If material on fire or involved in fire Contact the local, state, or department of energy radiological re sponse team Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Contact the local, state, or department of energy radiological re sponse team Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Keep upwind Avoid breathing dusts, and fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation Keep unnecessary people out of incident area until area declared safe by radiological response team RADIOACTIVE WASTE MATERIAL, HAVING NO 4926470 RECLAMATION VALUE REQUIRING PROTECTIVE SHIELDING (RADIOACTIVE MATERIAL, N.O.S.) RADIOACTIVE MATERIAL NA9181 Radioactive waste material, requiring protective shielding is various material ranging from protective clothing and rags to parts of nuclear power plants. The outside package tor these materials is generally a heavy metal container. Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful whereas films may be damaged by radiation from relatively low concentrations. If material on fire or Involved In fire Contact the local, state, or department of energy radiological re sponse team Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Contact the local, state, or department of energy radiological re sponse team Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Keep upwind Avoid breathing dusts, and fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation Keep unnecessary people out of incident area until area declared safe by radiological response team RADIOACTIVE WASTE MATERIAL, HAVING NO 4927470 RECLAMATION VALUE, REQUIRING PROTECTIVE SHIELDING (RADIOACTIVE MATERIAL, N.O.S., FISSILE CLASS III) RADIOACTIVE MATERIAL NA91B1 Radioactive waste material, requiring protective shielding is various material ranging from protective clothing and rags to parts of nuclear power plants. The outside package for these materials is generally a heavy metal container. Radioactive matenals emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to mtegse radiation may be harmful whereas films may be damaged by radiation from relatively low concentrations, Fissile radioactive materials are uranium 233, uranium 235, plutonium 238. plutonium 239, or plutonium 241. In addition to the radiation hazards presented by most radioactive materials, fissile materials, if improperly handled, may be critical. This means that if too large quantities of these materials are permitted in one place a very rapid nuclear reaction can occur. This would not be explosive, but large amount^ of radiation would be emitted suddenly and might injure nearby personnel. In case of trou ble with these shipments ail unauthorized persons should be kept as far away as possible until qualified people with proper equipment can be obtained from the local or state radiological response team, the de partment of energy, or the shipper. Continued on next page April 1981 443 MCD 000017371 tt material on fire or involved in fire Conlacl the local, state, or department of energy radiological re sponse team Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible if material not on fire and not involved in fire Contact the local, state, or department of energy radiological re sponse team Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Keep upwind Avoid breathing dusts, and fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Oo not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation Keep unnecessary people out of incident area until area declared safe by radiological response team RADIOACTIVE WASTE MATERIAL, HAVING NO 4926470 RECLAMATION VALUE, REQUIRING PROTECTIVE SHIELDING (RADIOACTIVE MATERIAL, N.O.S.. FISSILE CLASS II) RADIOACTIVE MATERIAL NA9181 Radioactive waste material, requiring protective shielding is various material ranging from protective clolhing and rags to parts of nuclear power plants. The outside package for these materials is generally a heavy metal container. Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful whereas films may be damaged by radiation from relatively low concentrations. Fissile radioactive materials are uranium 233. uranium 235. plutonium 238, plutonium 239. or plutonium 241. In addition to the radiation hazards presented by most radioactive materials, fissile materials, if improperly handled, may be critical. This means that if too large quantities of these materials are permitted in one place a very rapid nuclear reaction can occur. This would not be explosive, but large amounts of radiation would be emitted suddenly and might injure nearby personnel. In case of trou ble with these shipments alt unauthorized persons should be kept as far away as possible until qualified people with proper equipment can be obtained from the local or state radiological response team, the de partment of energy, or the shipper. If material on fire or Involved In fire Contact the local, state, or department of energy radiological re sponse team Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Coot all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved In fire Contact the local, state, or department of energy radiological re sponse team Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers 444 Personnel protection Keep upwind Avoid breathing dusts, and fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation Keep unnecessary people out of incident area until area declared safe by radiological response team RADIOACTIVE WASTE MATERIAL, HAVING NO 4929470 RECLAMATION VALUE, REQUIRING PROTECTIVE SHIELDING (RADIOACTIVE MATERIAL, N.O.S., FISSILE CLASS I) RADIOACTIVE MATERIAL NA9181 Radioactive waste material, requiring protective shielding is various material ranging from protective clothing and rags to parts of nuclear power plants. The outside package for these materials is generally a heavy metal container. Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by Instruments. Exposure of humans to intense radiation may be harmful whereas films may be damaged by radiation from relatively low concentrations. Fissile radioactive materials are uranium 233, uranium 235. plutonium 238. plutonium 239, or plutonium 24f. In addition to the radiation hazards presented by most radioactive materials, fissile materials, if improperly handled, may be critical. This means that if too large quantities of these materials are permitted in one place a very rapid nuclear reaction can occur. This would not be explosive, but large amounts of radiation would be emitted suddenly and might injure nearby personnel. In case of trou ble with these shipments all unauthorized persons should be kept as far away as possible until qualified people with proper equipment can be obtained from the local or state radiological response team, the de partment of energy, or the shipper. If material on fire or involved In fire Contact the local, state, or department of energy radiological re sponse team Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Cod all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved In fire Contact the local, state, or department of energy radiological re sponse team Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Keep upwind Avoid breathing dusts, and fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation Keep unnecessary people out of incident area until area declared safe by radiological response team April 1981 MCD 3000 17372 RAGS, OILY 4917354 FLAMMABLE SOLID UNI 956 Rags, oily are rags contaminated with animal or vegetable oil. They are liable to spontaneous heating and ignition. They must be shipped in airtight metal or metal-lined wooden containers. If material on fire or involved in fire Flood with water If material not on fire and not Involved in fire Keep sparks, tiames. and other sources of ignition away RAGS, WET 4917355 FLAMMABLE SOLID NA1325 Rags, wet are liable to spontaneous heating and ignition. They must be shipped in airtight metal or metal-lined wooden containers. If material oil fire or involved in fire Flood with water If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away REFINERY CRACKING STOCK (FLAMMABLE LIQUID, 4910514 N.O.S.) FLAMMABLE LIQUID UNI 993 Refinery cracking stock is a clear colorless to dark colored liquid with a petroleum like odor. It has a flash point of less than 100 deg. F. It is generally lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water RECLAIMED RUBBER 4917363 FLAMMABLE SOLID NA1345 Reclaimed rubber as a finely divided material may be liable to spon taneous heating and ignition. If material on fire or involved in fire Flood with water If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing fumes from burning material REFINERY CRACKING STOCK {COMBUSTIBLE 4915514 LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Refinery cracking stock is a clear colorless to dark colored liquid with a petroleum like odor. It has a flash point between 100 and 199 deg. F. It is generally lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water REFRIGERANTS, NEC, LIQUID OR GAS 4904570 (COMPRESSED GAS, N.O.S.) NONFLAMMABLE GAS UN1956 Refrigerants, nec are materials which are shipped in containers under pressure. They may be mixtures consisting of a nonflammable gas(es) and flammable gas(es) with the mixture having nonflammable properties. The mixture may separate with the flammable gas settling in low areas or the nonflammable gas settling in low areas. It may asphyxiate by the displacement of air. It may only be shipped in cylinders. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material Itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved In fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment REFRIGERANTS, NEC, LIQUID, FLAMMABLE 4905775 (COMPRESSED GAS, N.O.S.) FLAMMABLE GAS UNI 954 Refrigerants, nec are colorless gases shipped as liquefied gases un der its vapor pressure. Contact with the liquid can cause frostbite. It is easily ignited. Its vapors are heavier than air and a flame can travel back to the source of leak very easily. This leak can be either a liquid or vapor leak. It can asphyxiate by the displacement of air. Under fire conditions the cylinders or tank cars may violently rupture and rocket. Continued on next page April 1981 445 MCD O017373 If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Keep upwind Wear self-contained breathing apparatus Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 250Q feet If material leaking (not on fire), downwind evacuation must be considered REFRIGERATING MACHINE (COOLING ROOMS, 4910566 COOLING BOXES OR REFRIGERATORS OTHER THAN HOUSEHOLD TYPE). FLAMMABLE LIQUID NA1993 Cooling rooms, cooling boxes or refrigerators other than household type use a flammable liquid as a coolant. The hazard is that of flamm ability if the reservoir of liquid should be ruptured or punctured. If material on fire or involved in fire Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Build dikes to contain flow as necessary If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Personnel protection Avoid breathing vapors Keep upwind REFRIGERATING MACHINE (ICE CREAM POWER 4905665 FREEZERS AND MECHANICAL REFRIGERATORS) FLAMMABLE GAS NA1954 Refrigerating machine is an apparatus which has as a part a reservoir containing a flammable gas under pressure. This is used as a part of the refrigeration system. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on tire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Approach fire with caution REFRIGERATING MACHINE (COOLING ROOMS, 4905666 COOLING BOXES OR REFRIGERATORS, OTHER THAN HOUSEHOLD TYPE) FLAMMABLE GAS NA1954 Refrigerating machine is an apparatus which has as a part a reservoir conatining a flammable gas under pressure. This is used as a part of th-> refrigeration system, if material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apoly water from as far a distance as possible If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwmd Approach fire with caution REFRIGERATING MACHINE (COOLING ROOMS, 4904666 COOLING BOXES, OR REFRIGERATORS OTHER THAN HOUSEHOLD TYPE) NONFLAMMABLE GAS UN2857 Refrigerating machine is an apparatus which has as a part a reservoir containing a nonflammeile gas under pressure. This is used as part of the refrigeration system. REFRIGERATING MACHINE (ICE CREAM POWER 4910565 FREEZERS AND MECHANICAL REFRIGERATORS). FLAMMABLE LIQUID NA1993 Refrigerating machine uses a flammable liquid as a coolant. The haz ard is that of flammability if the resovoir of liquid should be ruptured or punctured. H material on fire or Involved in fire Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Build dikes to contain fiow as necessary REFRIGERATING MACHINE (ICE CREAM POWER 4904665 FREEZERS AND MECHANICAL REFRIGERATORS) NONFLAMMABLE GAS UN2857 Refrigerating machine is an apparatus which has as a part a reservoir containing a nonflammable gas under pressure. This is used as part of the refrigeration system. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Personnel protection Avoid breathing vapors Keep upwind 446 374 MCD oooo1< April 1981 REFRIGERATING MACHINE (REFRIGERATORS, NEC) 4905867 FLAMMABLE GAS NA1954 Refrigerating machine is an apparatus which has as a part a reservoir containing a flammable gas under pressure. This is used as a part of the refrigeration system. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Approach fire with caution REFRIGERATING MACHINE (REFRIGERATORS, NEC) 4910567 FLAMMABLE LIQUID NA1993 Refrigerators nec use a flammable liquid as a coolant. The hazard is that of flammability if the resovoir of liquid should be ruptured or punctured. If material on fire or Involved in fire Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Build dikes to contain flow as necessary REFRIGERATING MACHINE (REFRIGERATORS, NEC) 4904867 NONFLAMMABLE GAS UN2857 Refrigerating machine is an apparatus which has as a part a resevoir containing nonflammable gas under pressure. This is used as a part of the refrigeration system. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Personnel protection Avoid breathing vapors Keep upwind RESIN SOLUTION (RESIN COMPOUND, LIQUID) 4910260 FLAMMABLE LIQUID UN1666 Resin solution is the solution of various gums and resins in various solvents. The liquids are generally quite thick and may range from clear colorless to black "tar". The flash point of the solution will depends on the solvent used but it will be less than 100 deg. F. The hazard is flammability. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ali affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors April 1981 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water RESIN SOLUTION (RESIN COMPOUND, LIQUID) 4915280 COMBUSTIBLE LIQUID UN2668 Resin solution is the solution of various gums and resins in various solvents. The liquids are generally quite thick and may range from clear colorless to black "tar". The flash point of the solution wiil depend on the solvent used but it will be between 100 and 199 deg. F. The hazard is combustibility. If material on fire or involved In fire Do not extinguish lire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water RESORCINOL 4966774 ORME UN2876 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Resorcinol is a white crystalline solid changing to pink on exposure to light. It is used to make plastics, pharmaceuticals, and for many other uses. It is soluble in water. It will burn though it may take some effort to ignite. If materiel on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with Hooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors or dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates 447 000017375 MOD ROAD ASPHALT OR TAR, LIQUID 4910285 FLAMMABLE LIQUID NA1999 Road asphalt or tar. liquid is a thick black liquid with the characteristic "tar" odor. It has a flash point of less than 100 deg. F. It is generally heavier than water and is insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain (low as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ROAD ASPHALT OR TAR, LIQUID (PETROLEUM 4910260 ROAD OIL) FLAMMABLE LIQUID NA1999 Road asphalt or tar, liquid is dark brown black liquid. It has a flash point of less than 100 deg. F. It is insoluble in water and its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knockdown vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ROAD ASPHALT OR TAR, LIQUID (PETROLEUM 4915260 ROAD OIL) COMBUSTIBLE LIQUID NA1999 Road asphalt or tar, liquid is dark brown black liquid. It has a flash point between 100 and 199 deg. F. It is insoluble in water and its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ROAD OIL (PETROLEUM ROAD OIL) 4915247 COMBUSTIBLE LIQUID NA1268 Road oil is a thick brownish black liquid with a characteristic tar like odor. It has a flash point between 100 and 199 deg. F. It is insoluble in water and is usually heavier than water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Wear full protective clothing Do not handle broken packages without protective equipment ROCKET AMMUNITION WITH EMPTY PROJECTILE 4902150 CLASS B EXPLOSIVE Rocket ammunition with empty projectile is fixed ammunition which is an assembled unit consisting of an igniter, a rocket motor and an empty projectile. Under prolonged exposure to fire or heat the material can explode. If material on fire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet 448 April 1981 mod oooo1?376 ROCKET AMMUNITION WITH EXPLOSIVE 4901140 PROJECTILE CLASS A EXPLOSIVE Rocket ammunition with explosive projectile is fixed ammunition which consists of an igniter, rocket motor, and projectile (warhead) containing a high explosive. It may either be shipped as an assembled unit or as the individual components in the same outside container. The projectile may be shipped either fuzed or unfuzed. The fuzed projectile may be sensitive to shock or mechanical impact. Under prolonged exposure to heat or fire it can explode. If material on fire or Involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet ROCKET AMMUNITION WITH GAS PROJECTILE 4901145 CLASS A EXPLOSIVE Rocket ammunition with gas projectile is fixed ammunition which con sists of an igniter, rocket motor, and projectile (warhead) containing a gas and a burster. It may either be shipped as an assembled unit or as the individual components in the same outside container. The projectile may be shipped either fuzed or unfuzed. The fuzed projectile may be sensitive to shock or mechanical impact. Under prolonged exposure to heat or fire it can explode. If material on fire or Involved In fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet ROCKET AMMUNITION WITH ILLUMINATING 4901150 PROJECTILE CLASS A EXPLOSIVE Rocket ammunition with illuminating projectile is fixed ammunition which consists of an igniter, rocket motor, and projectile (warhead) con taining a pyrotechnic composition and a burster. It may be shipped as an assembled unit or as the individual components in the same outside container. The projectile may be shipped either fuzed or unfuzed. The fuzed projectile may be sensitive to shock or mechanical impact. Under prolonged exposure to heat or fire it can explode. C If material on fire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away April 1981 0q 1 ?.3 y? Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation if the material is on fire or involved in fire evacuate for a radius of 5000 feet ROCKET AMMUNITION WITH INCENDIARY 4901155 PROJECTILE CLASS A EXPLOSIVE Rocket ammunition with incendiary projectile is fixed ammunition which consists of an igniter, rocket motor and projectile (warhead) con taining a pyrotechnic composition and a burster. It may either be shipped as an assembled unit or as the individual components in the same outside container. The projectile may be shipped either fuzed or unfuzed. The fuzed projectile may be sensitive to shock or mechanical impact. Under prolonged exposure to heat or fire it can explode. If material on fire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet ROCKET AMMUNITION WITH INERT LOADED 4902160 PROJECTILE CLASS B EXPLOSIVE Rocket ammunition with inert loaded projectile is fixed ammunition which is an assembled unit consisting of an igniter, a rocket motor and an inert loaded projectile. Under prolonged exposure to fire or heat the material can explode. If material on fire or Involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Pereonnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet ROCKET AMMUNITION WITH SMOKE PROJECTILE 4901160 CLASS A EXPLOSIVE Rocket ammunition with smoke projectile is fixed ammunition which consists of an igniter, rocket motor and projectile (warhead) containing a smoke producing compound and a burster. It may either be shipped as an assembled unit or as the individual components in the same outside container. The projectile may be shipped either fuzed or unfuzed. The fuze projectile may be sensitive to shock or mechanical impact. Under prolonged exposure to heat or fire it can explode. O Continued on next page 449 If material on fire or Involved In fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet ROCKET AMMUNITION WITH SOLID PROJECTILE 4902170 CLASS B EXPLOSIVE Rocket ammunition with solid projectile is fixed ammunition which is an assembled unit consisting of an igniter, a rocket motor and a solid projectile. Under prolonged exposure to fire or heat the material can explode. If material on fire or Involved In fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet ROCKET ENGINE. LIQUID 4902520 CLASS B EXPLOSIVE Rocket engine, liquid is a self contained propulsion unit containing either a liquid propellant or a fuel and oxidizer. Under fire conditions the tanks of propellant or fuel and oxidizer may violently rupture and vig orously add to the fire. If material on fire or involved In fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet ROCKET HEAD 4901257 CLASS A EXPLOSIVE Rocket head is a casing loaded with explosives or bursting charges with or without other materials. It may be shipped either fuzed or unfuzed. The fuzed head may be sensitive to shock or mechanical impact. Under prolonged exposure to heat or fire it can explode. II material on fire or Involved In fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn 450 mcd 001 ?Pi It material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet ROCKET MOTOR 4901350 CLASS 36EXPLOSIVE Rocket motors are devices containing a propelling charge and consist of one or more continuous type combustion units closed at one end (closure may be an igniter with a thrust plate) and a nozzle at the other end. The propelling charge once ignited will burn very rapidly and may even explode. If material on fire or involved in fire Dangerously explosive Do not tight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet ROCKET MOTOR 4902530 CLASS B EXPLOSIVE Rocket motors are devices containing a propelling charge and consist of one or more container type combustion units closed at one end and a nozzle at the other end. Under fire conditions propellant can ignite and burns extremely vigorously. The rocket motor will not normally be pro pelled when the propellant catches fire. If material on fire or Involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on tire or involved in fire evacuate for a radius of 2500 feet ROOF COATING, CONSISTING OF ASPHALT, PITCH, 4915548 ROSIN OR TAR BASE (COMBUSTIBLE LIQUID, N.O.S.) COMBUSTIBLE LIQUID UN1993 Roof coating is a thick brownish black liquid with a tar-iike odor. It has a flash point between 100 and 199 deg. F. It is insoluble in water and is heavier than water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical April 1981 If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ROOFING OR FELT STOCK, WOOL. CONSISTING OF 4917373 WOOL WASTE, SWEEPINGS, OR REFUSE (WATER WOOL, WET) FLAMMABLE SOLID UN1387 Roofing or felt stock, wool, consisting of wool waste, sweepings, or refuse is liable to spontaneous heating and ignition if water wet. It must be shipped in air tight metal or metal lined containers. If material on fire or Involved in fire Flood with water If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away ROSIN GLOSS OR ESTER GUM (COMBUSTIBLE 4915446 LIQUIDS, N.O.S.) COMBUSTIBLE LIQUID NA1993 Rosin gloss or ester gum are the solutions of various gums, resins etc. In various solvents. The liquids are generally quite thick and may range from clear colorless to black "tars." the flash point depends on the solvent used but it will be between 100 and 199 deg. F. The hazard of these materials is combustibility. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray lo knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ROSIN GLOSS OR ESTER GUM (FLAMMABLE 4910446 QUIDS, N.O.S.) FLAMMABLE LIQUID UN1993 Rosin gloss or ester gum are the solutions of various gums, resins etc. In various solvents. The liquids are generally quite thick and may range from clear colorless to black "tars". The flash point depends on the solvent used but it will be below 100 deg. F. The hazard of these materials is flammability. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective April 1981 Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts oi water or soap and water ROSIN LIQUOR (FLAMMABLE LIQUID, N.O.S.) 4910442 FLAMMABLE LIQUID UNI 993 Rosin liquor is the solution of various gums and resins in various solvents. The liquids are generally quite thick and range from clear colorless to black "tars". The flash point depends on the solvent used but it is below 100 deg. F. The hazard of these materials is flammability. If material on fire or involved In fire Do not extinguish fire unless flow can be slopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use `'alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of Ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ROSIN LIQUOR, CONSISTING OF ROSIN AND NOT 491S342 MORE THAN 40% ALCOHOL OR MINERAL SPIRIT (COMBUSTIBLE LIQUIDS, N.O.S.) COMBUSTIBLE LIQUID NA1993 Rosin liquor is the solution of various gums and resins in various solvents. The liquids are generally quite thick and range from clear colorless to black "tars". The flash point depends on the solvent used but it is between 100 and 199 deg. F. The hazard of these materials is combustibility. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of waler may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Continued on next page 451 MOD 000017379 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ROSIN RESIDUE (COMBUSTIBLE LIQUID, N.O.S.) 4915366 COMBUSTIBLE LIQUID NA1993 Rosin residue is a thick dark liquid. It has a flash point between 100 and 199 deg. F. It is generally heavier than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be slopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ROSIN RESIDUE (FLAMMABLE LIQUIDS, N.O.S.) 4910366 FLAMMABLE LIQUID UN1993 Rosin residue is a thick dark liquid. It has a flash point of less than 100 deg. F. It is generally heavier than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ROSIN SOLUTION (FLAMMABLE LIQUID, N.O.S.) 4910444 FLAMMABLE LIQUID UNI 993 Rosin solution is the solution of various gums or resins in various solvents. The liquids are generally quite thick and range from clear colorless to black "tars". The flash point depends on the solvent used but it will be below 100 deg. F. The hazard of these materials is flammability. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as log Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ROUGH AMMONIATE TANKAGE. 7% OR MORE 4917367 MOISTURE CONTENT FLAMMABLE SOLID NA1325 Rough ammoniate tankage is the product of rendering and then drying of materials such as hair, horns, hoofs, batter scrap, wool waste or felt waste. The tankage may be liable to decay, spontaneous heating and ignition. if material on fire or involved In fire Rood with water If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away ROSIN SOLUTION (COMBUSTIBLE LIQUID, N.O.S.) 4915344 COMBUSTIBLE LIQUID NA1993 Rosin solution is the solution of various gums or resins in various solvents. The liquids are generally quite thick and range from clear colorless to black "tars". The flash point depends on the solvent used but it will be between 100 and 199 deg. F. The hazard of these materials is combustibility. RUBBER ACCELERATORS OR SOFTENERS, OTHER 4915555 THAN PETROLEUM, NEC (COMBUSTIBLE LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Rubber accelerators or softeners are various colored liquids. They have a flash point between 100 and 199 deg. F. They are generally lighter than water and insoluble in water. Their vapors are heavier than air. 452 IICD 0000 17380 April 1981 tf material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water RUBBER ACCELERATORS OR SOFTENERS, OTHER 4910S55 THAN PETROLEUM, NEC (FLAMMABLE LIQUID, N.O.S.) FLAMMABLE LIQUID UN1993 Rubber accelerators or softeners are various colored liquids- They have a flash point of less than 100 deg. F. They are generally tighter than water and insoluble in water. Their vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water RUBBER DIPPINGS, SCRAP, TRIMMINGS OR WASTE, 4917360 LATEX FOAM, VALUE FOR GRINDING, FLAKING OR SHREDDING (RUBBER SCRAP) FLAMMABLE SOLID NA1345 Rubber clippings, scrap, trimmings or waste latex foam as a finely divided material may be liable to spontaneous heating and ignition. If material on fire or involved In fire Flood with water If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing fumes from burning material RUBBER FILLER (VEGETABLE OIL FIBER) 4917452 (FLAMMABLE SOLID, N.O.S.) FLAMMABLE SOLID UN1325 Rubber tiller (vegetable oil liber) contains some residual oil and is liable to spontaneous heating and ignition. April 1981 MCD 000017381 H material on fire or involved in fire Flood with water tf material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away RUBBER MATTING TRIMMINGS (WASTE), OTHER 4917357 THAN FOAM (RUBBER SCRAP) FLAMMABLE SOLID NA1345 Rubber matting trimmings (waste), other than foam as a finely divided material may be liable to spontaneous heating and ignition. If material on fire or involved In fire Flood with water If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Peraonnel protection Avoid breathing fumes from burning material RUBBER PRESERVATIVE, NEC (COMBUSTIBLE 4915552 LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Rubber preservatives are various colored liquids. They have a flash point between 100 and 200 deg. F. Their vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water RUBBER PRESERVATIVE, NEC (FLAMMABLE LIQUID, 4910552 N.O.S.) FLAMMABLE LIQUID UN1993 Rubber preservatives are various colored liquids. Their flash point is below 100 deg.f. Their vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Peraonnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any materiel which may have contacted the body with copious amounts of water or soap and water 453 RUBBER SCRAP OR RUBBER BUFFINGS 4917361 FLAMMABLE SOLID UN134S Rubber scrap or rubber buffings as a finely divided materia) may be liable to spontaneous heating and ignition. If material on fire or involved in fire Flood with water If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing fumes from burning material RUBBER SCRAP OR RUBBER BUFFINGS (HARD 4917359 RUBBER SHAVINGS OR TURNINGS) FLAMMABLE SOLID NA1345 Rubber scrap or rubber buffings as a finely divided material may be liable to spontaneous heating and ignition. If material on fire or involved In fire Flood with water If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing fumes from burning material RUBBER TIRE LACQUERS. PAINT, OR SHELLAC 4910254 (PAINT, LACQUER OR SHELLAC) FLAMMABLE LIQUID UNI 263 Rubber tire lacquer, paint, or shellac is a variable colored liquid. It has a flash point of less than 100 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water RUBBER SCRAP OR RUBBER BUFFINGS (RUBBER 4917358 SCRAP HARD PULVERIZED) FLAMMABLE SOLID NA1345 Rubber scrap or rubber buffings as a finely divided material may be liable to spontaneous heating and ignition. If material on fire or involved In fire Flood with water If material not on fire and not involved In fire Keep sparks, flames, and other sources of Ignition away Personnel protection Avoid breathing fumes from burning material RUBBER, SHODDY OR REGENERATED RUBBER 4917362 FLAMMABLE SOLID UN1345 Rubber, shoddy or regenerated rubber as a finely divided material may be liable to spontaneous heating and ignition. If material on fire or involved in fire Flood with water If material not on fire and not Involved in Are Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing fumes from burning material RUBBER TIRE LACQUER, PAINT, OR SHELLAC 4915254 (PAINT, LACQUER OR SHELLAC) COMBUSTIBLE LIQUID NA1993 Rubber tire lacquer, paint, or shellac is a variable colored liquid. It has a flash point between 100 and 199 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical If material not on flra and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water RUBBING ALCOHOL COMPOUNDS (ALCOHOL, 4910412 N.O.S.) FLAMMABLE LIQUID UN1987 Rubbing alcohol compounds are clear colorless to variable colored liquids with a medicinal odor. They have a flash point of less than 100 deg. F. The hazard is flammability. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as tar a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 454 April 1981 MCD 000017382 RUBBING ALCOHOL COMPOUNDS (ALCOHOL, 4915412 N.O.S.) COMBUSTIBLE LIQUID UN1987 Rubbing alcohol compounds are clear colorless to variable colored liquids with a medicinal odor. They have a flash point between 100 and 199 deg. F. The hazard is combustibility. If material on fire or Involved in fire Do not extinguish tire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding 'quantities of water Apply water from as far a distance as possible Use 'alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain llow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water RUBIDIUM METAL 4916450 FLAMMABLE SOLID UNI 423 WATER REACTIVE Rubidium, metal is a soft silvery metal though normally greyish white in color due to oxide formation, it Is used in electronics. It may ignite spontaneously in air. Once ignited nited it can burn quite violently. It reacts violently with water to form rubidium hydroxide, a corrosive ma terial and hydrogen a flammable gas. The heat of this reaction may be sufficient to ignite the hydrogen. If material on fire or Involved In fire Do not use water Do not use carbon dioxide Use graphite, soda ash, powdered sodium chloride, or suitable dry powder If material not on fire and not involved in fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Do not attempt to sweep up dry material Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Avoid breathing fumes from burning material If material not on fire and not involved In fire Do not use water Keep sparks, flames, and other sources ot ignition away Keep material out of water sources and sewers Keep material dry Do not attempt to sweep up dry material Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Avoid breathing fumes trom burning material RUM, DENATURED 4910290 FLAMMABLE LIQUID NA1966 Rum, denatured is a clear colorless to amber colored liquid. It has a flash point of less than 100 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use ``alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water SAFETY SQUIB 4903475 CLASS C EXPLOSIVE Safety squib is a small paper tube containing a quantity of black powder. One end of each tube is usually twisted and tipped with sulfur. If material on fire or involved In fire Flood with water Apply water from as far a distance as possible If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material RUBIDIUM METAL, IN CARTRIDGES 4916449 FLAMMABLE SOLID UN1423 WATER REACTIVE Rubidium metal, In cartridges is a very limited quantity of the soft silvery metal sealed in a copper tube and overpacked in a wooden box. it is used in electronics. It reacts violently with water to form rubidium hydroxide, a corrosive material and hydrogen, a flammable gas. The heat of this reaction may be sufficient to ignite the hydrogen. If material on fire or Involved in fire Do not use water Do not use carbon dioxide Use graphite, soda ash, powdered sodium chloride, or suitable dry powder April 1981 Mr'75 On. '>a'.3 SELENIC ACID, LIQUID 4930035 CORROSIVE MATERIAL, ACIDIC, POISONOUS UN1905 Seienic acid, liquid Is the solution of the white crystalline solid in water. It is soluble in water. It is corrosive to metals and tissue. It is toxic by skin absorption and by ingestion. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water In flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Continued on next page 455 If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing If material not involved in fire Keep material out of water sources and sewers Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing SELENIUM OXIDE 4923340 POISON B NA2B11 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Selenium oxide is a white to cream color lustrous crystal or crystalline powder, it is soluble in water forming selenic acid, a corrosive material, it is toxic by ingestion and inhalation (dust). If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this materia! If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Adjust ph to neutral (ph-7) If dissolved, apply sodium sulfide solution to precipitate heavy metals Allow to aerate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates SELENIUM OXYCHLORIDE (POISONOUS SOLID, 4923345 N.O.S.) POISON B NA2610 Selenium oxychloride is a colorless to yellow fuming liquid. It is de composed by water to form hydrochloric acid a corrosive material. Con tact with the skin can cause severe burns. It is toxic by skin absorption and by inhalation. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use foam, carbon dioxide or dry chemical Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog 456 SELF-LIGHTING CIGARETTE 4917468 FLAMMABLE SOLID UN1867 Self-lighting cigarette is a cigarette treated so as to light on exposure to air or to reignite after being extinguished. It is a novelty item. If material on fire or involved in fire Flood with water If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away SHELL FIREWORKS 4903539 CLASS C EXPLOSIVE Shell fireworks are manufactured articles designed to produce an audible or visual effect. They are smaller than those classed as class b explosives. If material on fire or involved in fire Flood with water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet SHELL FIREWORKS 4902815 CLASS B EXPLOSIVE Shell fireworks are manufactured articles designed to produce visual and audible effects. They are larger than those classed as class c explosives. If material on fire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet April 1981 MCD 000017384 SHELLAC, LIQUID 4915295 COMBUSTIBLE LIQUID UN1263 Shellac, liquid is a clear colorless to orange colored liquid. It is the solution of shellac gum in a suitable solvent usually alcohol. It has a flash point between 100 and 199 deg. F. It is lighter than water and partially soluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "aicohoi" foam, carbon dioxide or dry chemical if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water SHELLAC, LIQUID 4910295 FLAMMABLE LIQUID UN1263 Shellac, liquid is a clear colorless to orange colored liquid. It is the solution of shellac gum in a suitable solvent usually alcohol. It has a flash point of less than 100 deg. F. It is lighter than water and partially soluble in water. Its vapors are heavier than air. tf material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water SHIPPER ASSOCIATION TRAFFIC 4950140 Consult the shipping papers for the exact contents of the car. con tainer, or trailer. SIGNAL FLARE 4903620 CLASS C EXPLOSIVE Signal flare is a device containing a pyrotechnic composition designed to be fired into the air. It may also contain a smoke charge. H material on fire or involved in fire Flood with water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet SILICOFLUORIC ACID (See HYDROFLUOROSILICIC ACID 4930026) SILICON CHLORIDE (OR) SILICON TETRACHLORIDE 4932370 CORROSIVE MATERIAL, ACIDIC UN1816 Silicon chloride is a colorless, fuming liquid with a pungent odor. It is used in smoke screens, to make various silicon containing chemicals, and in chemical analysis. It is decomposed by water to hydrochloric acid with evolution of heat. It is corrosive to metals in the presence of moisture and. to tissue. If material involved in fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with Hooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray, to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any materia! which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing SILICON TETOAFLUORIDE 4904280 NONFLAMMABLE GAS, CORROSIVE UN1859 Silicon tetrafluoride is a colorless gas with a pungent odor like hydro chloric acid. It fumes in air and is decomposed by water to form hydro fluoric acid, a corrosive material. The vapors are irritating to the eyes and respiratory system. The vapor is heavier than air. It may only be shipped in cylinders. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Do not use water on material itself Use water spray to absorb vapors If material not involved in fire Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or lime Do not use water on material itself Continued on next page April 1981 MCD 000017385 457 Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without prc active equipment Wash away any material which may have cc "tacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered SILICON-CALCIUM ALLOY, (FLAMMABLE SOLID, 4916768 N.O.S.) FLAMMABLE SOLID UNI 325 Silicon-calcium alloy is a grey lustrous crystalline solid. It may react with water to give off hydrogen, a flammable gas. The heat of this reaction may be sufficient to ignite the hydrogen. If material on fire or Involved in fire Do not use water Use graphite, soda ash, powdered sodium chloride, or suitable dry powder If material not on fire and not involved in fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Avoid breathing fumes from burning material SILVER CYANIDE 4923473 POISON B UNI 664 Silver cyanide is a white to greyish powder darkening on exposure to light. It is insoluble in water. It is very rapidly decomposed by acids giving off hydrogen cyanide, a flammable poison gas. It is toxic by skin absorption through open wounds, by ingestion, and by inhalation of dusts or hydrogen cyanide from decomposition of the material. Toxic oxides of nitrogen are produced in fires involving this material. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use foam, carbon dioxide or dry chemical Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If material not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Use water spray to knock-down vapors Do not use water on material itself Personnel protection Avoid breathing vapors or dusts Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing 458 SILVER NITRATE OXIDIZER 4918742 UN1493 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Silver nitrate is a colorless or white crystalline solid becoming black on exposure to light or organic material. "Pie material is soluble in water. It is non-combustible but it will accelerate the burning of combustible materials. If large quantities are involved in fire or the combustible ma terial is finely divided an explosion may result. Prolonged exposure of the material to fire or heat may result in an explosion. Toxic oxides of nitrogen are produced in fires involving this material. If material on fire or involved In fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or tire fighting water Environmental considerations--water spill If dissolved, apply sodium sulfide solution to precipitate heavy metals Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates SLUDGE ACID 4930253 CORROSIVE MATERIAL UN1906 Sludge acid is a dark colored liquid. Most of the material is water soluble with release of heat. It is corrosive to metals and tissue. If material on fire or involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Use foam, carbon dioxide or dry chemical Cool all affecied containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material our of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gioves, and goggles Do not handle broken packages without protective equipment Wash away any material wnich may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing April 1961 MCD 000017386 SLUDGE, ACID, CONTAINING NOT LESS THAN 75% 4930252 WATER (SLUDGE ACID) CORROSIVE MATERIAL UN1906 Sludge acid is a dark colored liquid. Most ol the material is water soluble with release of heat. It is corrosive to metals and tissue. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use foam, carbon dioxide or dry chemical If material not on fire end not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing SLUDGE,ALKALAI, CONTAINING NOT LESS THAN 4935204 75% WATER (CORROSIVE LIQUID, N.O.S.) CORROSIVE MATERIAL, BASIC UN1760 Sludge, aikalai. is a dark colored liquid. Most of the material is water soluble. It is corrosive to metals and tissue. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved In fire Keep material out of water sources and sewers Build dikes to contain (low as necessary Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing SMALL ARMS AMMUNITION 4903170 CLASS C EXPLOSIVE Small arms ammunition is fixed ammunition consisting of a metallic plastic, composition or paper cartridge case, a primer and a propelling charge with or without bullet, projectile, shot, tracer components, or incendiary composition or mixtures. This classification is primarily re served for ammunition with incendiary, solid, inert or empty projectiles of caliber less than 20 mm. and blank cartridge containing less than 500 grains of propellant. April 1981 If material on fire or Involved In fire Flood with water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet SMALL ARMS PRIMER 4903190 CLASS C EXPLOSIVE Small arms primer is composed of a brass cup and anvil with a small amount of explosive mixture between them. It is designed to be inserted into the base of a small aims cartridge and function by means of impact to ignite the propellant. If material on fire or involved in fire Flood with water Apply water from as far a distance as possible If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet SMALL-ARMS AMMUNITION, IRRITATING (TEAR GAS) 4903190 CARTRIDGE CLASS C EXPLOSIVE Small-arms ammunition (tear gas) cartridges is fixed ammunition con sisting of a metallic, plastic, composition or paper cartridge case, a primer, propelling charge, with a projectile containing a tear gas material. If material on fire or involved In fire Flood with water Apply water from as far a distance as possible If material not on fire and not involved In fire Keep sparks, flames, and other sources o< ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet SMOKE CANDLE 4903405 CLASS C EXPLOSIVE Smoke candle is a device containing a smoke producing pyrotechnic composition. The device is designed to be held or placed on the ground while functioning. If material on fire or Involved In fire Flood with water Apply water from as far a distance as possible If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Continued on next page 7 459 Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet SMOKE FLUE CLEANING COMPOUNDS (COMPOUND, 4936514 CLEANING, LIQUID) CORROSIVE MATERIAL NA1760 Smoke due cleaning compounds are various colored liquids. They are generally water soluble. They are corrosive to metals and/or tissue. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical If material not on lire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing SMOKE FLUE CLEANING COMPOUNDS 4910143 (COMPOUNDS, CLEANING, LIQUID) FLAMMABLE LIQUID NA1993 Smoke flue cleaning compounds are variable colored liquids with a petroleum like odor. They have a flash point of less than 100 deg. F. They are lighter than water and generally insoluble in water. Their vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out ot water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 460 SMOKE FLUE CLEANING COMPOUNDS 4915143 (COMPOUNDS. CLEANING, LIQUID) COMBUSTIBLE LIQUID NA1993 Smoke flue cleaning compounds are variable colored liquids with a petroleum like odor. They have a flash point between 100 and 199 deg. F. They are lighter than water and generally insoluble in water. Their vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water SMOKE GRENADE 4903410 CLASS C EXPLOSIVE Smoke grenade is a device containing a smoke producing pyrotechnic composition, of the size that can be thrown by hand or projected from a rifle. If material on fire or involved In fire Flood with water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet SMOKE POT 4903415 CLASS C EXPLOSIVE Smoke pot is a device containing a smoke producing pyrotechnic composition. It is designed to be placed on the ground or float on water while functioning. If material on fire or Involved in fire Flood with water Apply water from as far a distance as possible If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet April 1981 MCL Of0ol 7?>QB SMOKE SIGNAL 4903630 CLASS C EXPLOSIVE Smoke signal is a device containing a pyrotechnic composition which bums without flame upon ignition to produce various colored smoke. II material on fire or Involved in fire Flood with water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing SMOKELESS POWDER FOR SMALL ARMS <100 4917369 POUNDS OR LESS) FLAMMABLE SOLID NA1325 Smokeless powder for small arms is a black grey powder. It is easily ignited and burns very vigorously once ignited. In actuality it is a limited quantity shipment of propellant explosives, solid; class b explosive. Both the material and its packaging have undergone special testing to meet this classification of flammable solid. If material on fire or involved in fire Dangerously explosive Flood with water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material SODIUM ALUMINUM HYDRIDE 4916452 FLAMMABLE SOLID UN2835 WATER REACTIVE Sodium aluminum hydride is a white crystalline solid. It reacts with water to form sodium hydroxide, a corrosive material and hydrogen, a flammable gas. The heat of reaction may be sufficient to ignite the hydrogen. If the sodium aluminum hydride is spread over a large flat combustible area, friction can ignite the material. It may react violently with heat or oxidizing materials. If material on fire or Involved in fire Do not use water Use graphite, soda ash or powdered sodium chloride If material not on fire and not involved in fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Do not attempt to sweep up dry material Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water SODA LIME, SOUD 4935250 CORROSIVE MATERIAL UN1907 Soda lime, solid is generally a white to greyish white colored solid. It is the mixture of calcium hydroxide and sodium or potassium hydroxide, both corrosive materials. It is noncombustible and soluble in water with release of heat. It is corrosive to metals and tissue. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Apply water from as far a distance as possible if material not Involved in fire Keep material out of water sources and sewers Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water SODIUM ALUMINATE, SOLUTION 4935260 CORROSIVE MATERIAL, BASIC UN1819 Sodium aluminate, solution is the water solution of the white crystalline powder. It is corrosive to metals and tissue. April 1961 MCD 000017389 SODIUM ALUMINUM SULPHATE (SODIUM ALUM) 4963306 (ALUMINUM SULFATE) ORM-E NA907B ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Sodium aluminum suiphate is a colorless crystalline solid. It ts used in textiles, in paper making, in water purification, in food processing, and in many other uses. It is soluble in water. It is non-combustible. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Continued on next pege 461 Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates SODIUM AMIDE 4916453 FLAMMABLE SOLID UNI 425 WATER REACTIVE Sodium amide is a greyish to white crystalline solid with an ammonia like odor, it is used to make other chemicals and in chemical analysis. It reacts with water to form sodium hydroxide, a corrosive material and ammonia, a nonflammable gas. The heat from this reaction may be sufficient to ignite nearby combustible materials. If material on fire or involved in fire Do not use water Use graphite, soda ash or powdered sodium chloride If material not on fire and not involved in fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material if contact with the material anticipated, wear full protective clothing SODIUM ARSENATE, SOLID 4923290 POISON B UN1685 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Sodium arsenate, solid is a colorless to white crystalline solid. It is soluble in water. It is toxic by ingestion. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved In fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water apill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Add ferric chloride (fecl3) Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates 462 .300^ SODIUM ARSENITE, LIQUID, (SOLUTION) 4923291 POISON B UN1686 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Sodium arsenite. liquid, (solution) is the white powder dissolved in water. It is used as an atiseptic. in insecticides and herbicides, and to preserve If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical if material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors or dusts Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface How using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash, cement powder, sawdust, or com mercial sorbents Environmental considerations--water spill Add calcium hypochlorite Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Add ferric chloride (fecl3) Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors SODIUM AZIDE 4923465 POISON B UN1687 Sodium azide is a colorless crystalline solid. It is soluble in water, it will bum and may explode if large quantities are involved. It may also explode if subject to shock. It is toxic by ingestion. Toxic oxides of nitrogen are produced in fires involving this material. If material on fire or Involved In fire Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet April 1981 SODIUM BIFLUORIDE SOUD CORROSIVE MATERIAL 4932355 UN2439 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Sodium bifluoride solution is a white crystalline solid, it is used as a preservative for anatomical and zooligical specimens, in metal plating and for many other uses. It is soluble in water. It is corrosive to tissue. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved in fire Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash, of lime Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Avoid breathing fumes from burning material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spilt Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Adjust ph to neutral (ph-7) SODIUM BIFLUORIDE SOLUTION 4932356 CORROSIVE MATERIAL UN2439 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Sodium biiluoride solution is the white crystalline solid dissolved in water, it is used as a preservative for anatomical and 2ooligical speci mens, in metal plating and for many other uses. It is corrosive to metals and tissue. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain fiow as necessary Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate April 1981 ^C2> 3? Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Adjust ph to neutral (ph-7) SODIUM BISULFATE, SOLUTION (See SODIUM HYDROGEN SULFATE, SOLUTION 4932377) SODIUM BISULFITE SOLUTION 4932376 CORROSIVE MATERIAL, ACIDIC NA2693 Sodium bisulfite solution is the white crystalline solid disolved in water, and has a slight odor of burning sulfur. It is used as a food preservative, in photography, in paper making, to make other chemicals and for many other uses. It is corrosive to metals. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing SODIUM BISULFITE, SOLID (See SODIUM HYDROGEN SULFITE, SOLID 4944155) SODIUM BROMATE 4918743 OXIDIZER UNI 494 Sodium bromate is a white crystalline solid, it is used in chemical analysis. It is soluble in water. It forms very flammable mixtures with combustible materials and this mixture may be explosive if the com bustible material is very finely divided. The mixture can be ignited by friction. Prolonged exposure to fire or heat by the material may result in an explosion. If material on fire or involved in fire Flood with water Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible K material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when lighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet 463 SODIUM CHLORATE 4918723 OXIDIZER UNI 495 Sodium chlorate is a white crystalline solid. It is used in paper pulping, as a herbicide, in explosives, pyrotechnics and flares, in leather proc essing and for many other uses. The material is soluble in water. It forms a very flammable mixture with combustible materials and this mixture may be explosive if the combustible material is very finely divided. The mixture can be ignited by friction. Contact with strong sulfuric acid can cause fires or explosions. When mixed with ammonium salts, sponta neous decomposition and ignition may result. Prolonged exposure of the material to fire or heat can result in an explosion. If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible H material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet SODIUM CHLORATE AND SODIUM CHLORIDE, IN 491B765 WATER SOLUTION (OXIDIZING MATERIAL, N.O.S.) OXIDIZING MATERIAL UN1479 Sodium chlorate and sodium chloride in water solution is a clear col orless liquid. Both sodium chlorate and sodium chloride are noncom bustible. But the sodium chlorate will accelerate the burning of com bustible materials. This is especially true if the material should dry out. Contact with strong sulfuric acid may cause fires or explosions. If material on fire or Involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out ot water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet SODIUM CHLORITE 4918360 OXIDIZER UNI 496 Sodium chlorite is a white crystalline solid, it is used in water purifi cation; to bleach woodpulp, textile, fats, oils; and lor many other uses. It is soluble in water. The material itself is difficult to bum, but if con taminated by combustible materials it will accelerate their burning. With certain combustible materials it will form explosive mixtures. Prolonged exposure of sodium chlorite and/or its containers to fire or heat may result in an explosion. If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible 464 0oO^ If material not on fire and not Involved In fire Keep sparks, flames, and other sources ot ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting tires involv ing this material Approach fire with caution Evacuation if fire becomes uncontrollable--evacuate for a radius of 2500 feet SODIUM CHLORITE SOLUTION (NOT EXCEEDING 4936360 42% SODIUM CHLORITE) CORROSIVE MATERIAL UN1908 Sodium chlorite solution is a colorless liquid. It consists of sodium chlorite crystals dissolved in water. The dried material in contact with combustible material may result in spontaneous ignition. It is corrosive to metals. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If materiel not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material if contact with the material anticipated, wear full protective clothing SODIUM CHROMATE SOLUTION (SODIUM 4963372 CHROMATE) ORM-E NA9145 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Sodium chromate solution is the yellow crystalline solid dissolve in water, it is used to make pigments for paints, inks, and other chemicals, and as a wood preservative. It is soluble in water, it is non-combustible. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with oopious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder April 1961 Environmental considerations--water spill Add sodium bisulfite Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates SODIUM CHROMATE, DRY (SODIUM CHROMATE) 4963369 ORM-E NA9145 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Sodium chromate, dry is a yellow crystalline solid. It is used to make pigments for paints and inks, other chemicals, and as a wood preserv ative. It is soluble in water. It is non-combustible. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Add sodium bisulfite Neutralize with agricultural lime (staked lime), crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates SODIUM CYANIDE SOLUTION 4923227 POISON B UNI 689 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10/4.54) Sodium cyanide solution is the water solution of the white solid. It has the faint odor of bitter almonds. It is slowly decomposed by water and very rapidly by acids to give off hydrogen cyanide, a flammable poison gas. It is toxic by skin absorption through open wounds, by ingestion, and by inhalation of hydrogen cyanide from the decomposition of the material. Toxic oxides of nitrogen are produced in fires involving this material. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool ail affected containers with flooding quantities of water Use foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind April 1981 MCr; 0000 1 ?393 Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Add caustic soda Add calcium hypochlorite Adjust ph to neutral (ph-7) Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment SODIUM CYANIDE, SOLID 4923228 POISON B UNI 689 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10/4.54) Sodium cyanide, solid is a white crystalline or lump solid having the faint odor of bitter almonds. It absorbs water from the air forming a syrup. It is slowly decomposed by water and very rapidly by acids to give off hydrogen cyanide, a flammable poison gas. It is toxic by skin absorption through open wounds, by ingestion, and by inhalation of hydrogen cy anide from the decomposition of the material. Toxic oxides of nitrogen are produced in fires involving this material. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use foam, carbon dioxide or dry chemical Do not use water on material Itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If material not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Use water spray to knock-down vapors Do not use water on material itself Personnel protection Avoid breathing vapors or dusts Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in ram or fire fighting water Environmental considerations--water spill Add caustic soda Add calcium hypochlorite Adjust ph to neutral (ph-7) Environmental considerations-air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment 465 SODIUM DICHLORO-S-TRIAZINETRIONE (DRY, CONTAINING MORE THAN 39% AVAILABLE CHLORINE) 4918435 OXIDIZER UN246S Sodium dichloro-s-triazinetrione is a white crystalline solid with an odor of chlorine, it is used as a dry bleach in household cleaning com pounds and swimming pool disinfectants. The material itself is non com bustible but if contaminated with a combustible material ignition can result. It will accelerate the burning of combustible materials. Contact with ammonium compounds or hydrated salts can cause a very vigorous chemical reaction. May vigorously react with small quantities of water releasing chlorine gas. Prolonged exposure to fire or heat of the material may result in the vigorous decomposition of the material and the rup turing of its containers. Material containing less than 39 percent available chlorine will undergo reactions as described above though it may be longer to initiate and the resulting reaction may not be as vigorous. If material on fire or Involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach tire with caution Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet SODIUM DICHROMATE 4941170 ORM-A NA1479 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Sodium dichromate is a red orange crystaline solid. It is used in the manufacture of other chemicals, as a corrosive inhibitor, and for many other uses. It is non-combustible. It is soluble in water. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with dilute acid or removable strong acid Add sodium bisulfite Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates SODIUM DODECYLBENZENESULFONATE 4963374 ORM-E NA9146 ENVIRONMENTALLY HAZARDOUS SU8STANCE (RQ-1000/454) Sodium dodecylbenzenesulfonate is a white to light yellow granular solid. It is used as a detergent. It is soluble in water. It will bum though it may take some effort to ignite. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates SODIUM FLUORIDE SOLUTION 4932375 CORROSIVE MATERIAL, ACIDIC UN1690 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Sodium fluoride solution is the colorless crystalline solid dissolved in water. It is corrosive to metals and tissue. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible H material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Adjust ph to neutral (ph-7) 466 April 1981 017; 94 SODIUM FLUORIDE, SOLID 4944150 ORM-B UN1690 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Sodium fluoride, is a colorless crystaline solid or white powder (when used as an insecticide it may be dyed blue). Besides its use as an insecticide it is used to fluorinate water supplies, as a wood preservative, in cleaning compounds, manufacture of glass, and for many other uses. It is soluble in water. It is non-combustible. It is corrosive to aluminum. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) H material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph-7) SODIUM HYDRATE (See SODIUM HYDROXIDE, DRY, SOLID, FLAKE, BEAD, OR GRANULAR 4935235 OR SODIUM HYDROXIDE, LIQUID OR SOLUTION 4935200) SODIUM HYDRIDE 4916454 FLAMMABLE SOLID UN1427 WATER REACTIVE Sodium hydride is a silvery to whitish powder or slurry in oil. it is used to make other chemicals. The powder may ignite spontaneously on exposure to moist air. It reacts with water to form sodium hydroxide, a corrosive material and hydrogen, a flammable gas. The heat of the reactions may be sufficient to ignite the hydrogen. It may react violently with heat or oxidizing materials. If material on fire or involved In fire Do not use water Do not use dry chemical or carbon dioxide If material not on fire and not involved in fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water SODIUM HYDROGEN SULFATE SOLUTION 4932377 CORROSIVE MATERIAL, ACIDIC UN2837 Sodium hydrogen sulfate solution is the white crystalline solid dis solved in water. It is corrosive to metals and tissue. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog April 1981 Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing SODIUM HYDROGEN SULFITE SOLUTION (See SODIUM BISULFITE SOLUTION 493237 SODIUM HYDROGEN SULFITE, SOLID 4944155 ORM-B NA2693 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Sodium hydrogen sulfite, solid is a white crystaline solid with a faint odor of burning sulfur. It is used in the manufacture of other chemicals, in food processing, in photography, and for many other uses. It is soluble in water. It is non-combustible. It is corrosive to aluminum. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Add caustic soda Add calcium hypochlorite Adjust ph to neutral (ph-7) SODIUM HYDROSULFIDE, SOLID (WITH LESS THAN 4916738 25% WATER OF CRYSTALLIZATION) FLAMMABLE SOLID UN2318 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Sodium hydrosulfide is a colorless to light yellow crystalline solid or fused mass. It is used in paper pulping, manufacturing dyes, and de- hairing hides, it may absorb moisture from the air and be liable to spon taneous heating. It is soluble in water. It is also corrosive to metals and tissue. H material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Apply water from as far a distance as possible Continued on next page 467 000017396 MCI) If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective eouipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Add soda ash Allow to aerate Use mechanical dredges or tifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Evolves flammable hydrogen sulfide gas on contact with acids SODIUM HYDROSULFIDE, SOLID (WITH NOT LESS 4935267 THAN 25% WATER OF CRYSTALLIZATION) CORROSIVE MATERIAL UN2923 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Sodium hydrosulfide is a colorless to light yellow crystalline solid or fused mass. It is used in paper pulping, manufacturing dyes, and de- hairing hides. It is soluble in water. It is corrosive to metals and tissue. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Apply water from as far a distance as possible If material not Involved In fire Keep material out of water sources and sewers Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Add soda ash Allow to aerate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Evolves flammable hydrogen sulfide gas on contact with acids SODIUM HYDROSULFIDE, SOLUTION 493526B CORROSIVE MATERIAL, BASIC NA2922 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Sodium hyrosulfide in solution is a colorless to light yellow colored liquid. It is used in paper pulping, manufacturing dyes and dehairing hides. It is soluble in water, it is corrosive to metals and tissue. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Apply water from as far a distance as possible 468 MCD 000017396 If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors or dusts Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Add soda ash Allow to aerate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Evolves flammable hydrogen sulfide gas on contact with acids SODIUM HYDROSULFITE 4916737 FLAMMABLE SOUO UN1384 Sodium hydrosulfite is a whitish to light yellow crystalline solid having a sulfur dioxide like odor, it is used in dyeing and to bleach paper pulp. It spontaneously heats on contact with air and moisture. This heat may be sufficient to ignite surrounding combustible materials. It is soluble in water, under prolonged exposure to fire or heat containers of this material may violently rupture. If material on fire or involved in fire Flood with water If material not on fire and not Involved in tire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material SODIUM HYDROXIDE AND SODIUM BOROHYDRIDE 4935273 SOLUTION N.O.S.) CORROSIVE MATERIAL, BASIC UN1B24 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Sodium hydroxide and sodium borohydride solution is a colorless liquid. It is used for bleaching wood pulp and as a blowing agent lor making plastic foams. It is soluble in water. It is corrosive to metals and tissue. It weighs 12.7 pounds per gallon. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Apply water from as far a distance as possible H material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary April 1981 Personnel protection Avoid breathing vapors or dusts Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the materia! anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with vinegar or other dilute acid Environmental considerations--water spill Neutralize with dilute acid or removable strong acid Environmental considerations--air spill Apply water spray or mist to knock down vapors SODIUM HYDROXIDE LIQUID 4935240 CORROSIVE MATERIAL. BASIC UN1624 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Sodium hydroxide liquid is the water solution of sodium hydroxide. It is used in chemical manufacturing, petroleum refining, paper making, cleaning compounds, and for many other uses. The concentrated so lutions wiii dissolve in additional water with the evolution of heat. It is corrosive to metals and tissue. It weighs 12.7 pounds per gallon. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Apply water from as far a distance as possible If material not involved in fire Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors or dusts Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with vinegar or other dilute acid Environmental considerations--water spill Neutralize with dilute acid or removable strong acid Environmental considerations--air spill Apply water spray or mist to knock down vapors Use water in flooding quantities as fog Apply water from as far a distance as possible If material not involved in fire Keep matenal out of water sources and sewers Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with dilute acid or removable strong acid SODIUM HYDROXIDE, LIQUID (OR) SOLUTION 4935243 (CAUSTIC SODIUM (SODIUM HYDROXIDE) CONTAINING NOT LESS THAN 48 PERCENT WATER BY WEIGHT IN SOLUTION) CORROSIVE MATERIAL, BASIC UN1824 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Sodium hydroxide, liquid (or) solution is a white solid dissolved in water and has a colorless to milky white appearance. It is used m chem ical manufacturing, petroleum refining, paper making, and cleaning com pounds. It will dissolve in addtional water with release of heat. It is corrosive to metal and tissue. It weighs 12.7 pounds per gallon. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors or dusts Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid matenal Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with vinegar or other dilute acid Environmental considerations--water spill Neutralize with dilute acid or removable strong acid SODIUM HYDROXIDE, DRY, SOLID, FLAKE, BEAD, OR 4935235 GRANULAR CORROSIVE MATERIAL, BASIC UNI 823 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Sodium hydroxide, dry is a white material. It is used in chemical manufacturing, petroleum refining, cleaning compounds, home drain openers, and for many other uses. It is soluble in water with release of heal. It absorbs moisture from the air and dissolves in it. It is corrosive to metals and tissue. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) April 1981 MCI) 000017397 SODIUM HYPOCHLORITE SOLUTION 4944143 (HYPOCHLORITE SOLUTION CONTAINING NOT MORE THAN 7% AVAILABLE CHLORINE (BY WEIGHT)) ORM-A NA1791 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Sodium hypochlorite solution is the white crystalline solid dissolved in water having a faint odor of chlorine. It is used as a bleach for textiles and paper pulp, for water purification, to make other chemicals, and for many other uses. It is corrosive to aluminum. Continued on next page 469 ff material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural time (staked time), crushed limestone, or sodium bicarbonate If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors SODIUM HYPOCHLORITE SOLUTION 4932378 (HYPOCHLORITESOLUTION (CONTAINING MORE THAN 7% AVAILABLE CHLORINE BY WEIGHT) CORROSIVE MATERIAL UN1791 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Sodium hypochlorite solution is a white crystalline solid dissolved in water, it has the faint odor of chlorine. It is corrosive to metals and tissue. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible if material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material ff contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate 470 If dissolved, apply activated carbon at ten times the spilled amouir in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors SODIUM METHYLATE, ALCOHOL MIXTURE 4909290 FLAMMABLE LIQUID NA1289 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Sodium methylate, alcohol mixture is a solution of sodium methylate in an alcohol solvent. It is used as a catylist in chemical manufacture, in the manufacture of pharmacueticals. and in chemical analysis It is a clear colorless to opaque white liquid. It is corrosive to tissue. Sodium methylate reacts with water to give sodium hydroxide, a corrosive ma terial and methyl alcohol, a flammable liquid. Both of these are soluble in water. The vapors of the alcohol are heavier than air. It weighs 8.3 pounds per gallon. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use "alcohol" foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Do not use water on material itself If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak it without hazard Use water spray to knock-down vapors Do not use water on material itself Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Neutralize with vinegar or other dilute acid Apply fluorocarbon-water foam to diminish vapor and fire hazard Environmental considerations--water spill Neutralize with dilute acid or removable strong acid Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment SODIUM METHYLATE, ALCOHOL MIXTURE 4913190 COMBUSTIBLE LIQUID. CORROSIVE NA1289 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Sodium methylate, alcohol mixture is a solution of sodium methylate in an alcohol solvent. It is a clear colorless to opaque white liquid. It is corrosive to tissue. Sodium methylate reacts with water to give sodium hydroxide, a corrosive material, and methyl alcohol a flammable liquid, with release of heat. Both of these are soluble in water. The vapors of the alcohol solvent are heavier than air. It weighs 9.0 pounds per gallon. April 1981 MC>D 0000l73pg If material involved In fire Use dry chemical or carbon dioxide Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Apply water from as far a distance as possible If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear lull protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Neutralize with vinegar or other dilute acid Apply fluorocarbon-water foam to diminish vapor and fire hazard Environmental considerations--water spill Neutralize with dilute acid or removable strong acid Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment SODIUM METHYLATE. ALCOHOL MIXTURE 4935264 CORROSIVE MATERIAL, BASIC NA1269 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Sodium methylate, alcohol mixture is a colorless liquid, it is used to process edible fats and oils, and to make other chemicals. It is the solution of sodium methylate, a white powder in methyl alcohol. It is soluble in water but the sodium methylate will decompose to sodium hydroxide and methyl alcohol with the evolution of heat. It is combustible though it may require some effort to ignite. It is corrosive to metals and tissue. It weighs 9.0 pounds per gallon, tf material on fire or involved In fire Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Do not use water on material itself Personnel protection Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete April 1981 mcd oooor, ^399 Absorb bulk liquid with fly ash or cement powder Neutralize with vinegar or other dilute acid Environmental considerations--water spill Neutralize with dilute acid or removable strong acid Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors SODIUM METHYLATE, DRY 4916739 FLAMMABLE SOLID UN1431 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Sodium methylate, dry is a white amorphous powder, it is used to process edible fats and oils, and to make other chemicals. It reacts with water to form sodium hydroxide, a corrosive material, and methyl alcohol, a flammable liquid. The heat from this reaction may be sufficient to ignite surrounding combustible material or the sodium methylate itself if the water is present in only very small amounts. If material on fire or involved in fire Do not use water Use dry chemical or carbon dioxide if material not on fire and not involved in fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Avoid breathing dusts, and fumes from burning matenal Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and watar If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig apit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with dilute acid or removable strong acid SODIUM MONOXIDE, SOLID 4935265 CORROSIVE MATERIAL, BASIC UN1625 Sodium monoxide, solid is a white granular material, it is used in chemical manufacture, it is decomposed by water to sodium hydroxide with the evolution of heat. It is corrosive to metals and tissue. If material involved In fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Apply water from as far a distance as possible If material not involved In fire Keep material out of water sources and sewers Keep material dry Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 471 SODIUM NITRATE 491S746 OXIDIZER UN1498 Sodium nitrate is a white crystalline solid. It is used in solid propellants, explosives, fertilizers, and for many other uses. The material is soluble in water. It is noncombustible but tt will accelerate the burning of com bustible materials. If large quantities are involved in fire or the combus tible material is finely divided an explosion may result. Prolonged ex posure of the material to fire or heat may result in an explosion. Toxic oxides of nitrogen are produced in fires involving this material, tf material on fire or involved In fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as tar a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this materia! Approach fire with caution Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet SODIUM NITRITE 491B747 OXIDIZER UNI 500 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Sodium nitrite is a yellowish white crystalline solid, it is used as a food preservative, and to make other chemicals, it is soluble in water. It is noncombustible but it will accelerate the burning of combustible material. If large quantities are Involved in fire or if the combustible material is finely divided, an explosion may result. If the material contaminated by ammonium compounds, spontaneous decomposition can occur and re sulting heat may ignite surrounding combustible material. Prolonged exposure to fire or heat may result in an explosion. Toxic oxides of nitrogen are produced in tires involving this material. If material on fire or Involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Add soda ash Add calcium hypochlorite Adjust ph to neutral (ph-7) 472 lMD OOQ01740C SODIUM NITRITE MIXTURE (SODIUM NITRATE, 4918749 SODIUM NITRITE, AND POTASSIUM NITRITE) OXIDIZER NA1487 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Sodium nitrite mixture (sodium nitrate, sodium nitrite and potassium nitrate) is a white crystalline solid. The material is soluble in water. It is non-combustibie but it will accelerate the burning of combustible ma terial. If large quantities are involved in fire or the combustible material is finely divided an explosion may result, tf the material is contaminated by ammonium compounds, spontaneous decomposition can occur and the resulting heat may ignite surrounding combustible material. Pro longed exposure to fire or heat may result in an explosion. Toxic oxides of nitrogen are produced in fires involving this material. If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible tf material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of wafer sources and sewers Personnel protection Avoid breathing dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this materia) Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Add soda ash Add calcium hypochlorite Adjust ph to neutral (ph-7) SODIUM PERBORATE (OXIDIZING MATERIAL. N.O.S.) 4918767 OXIDIZING MATERIAL UN1479 Sodium perborate is a white crystalline solid. It is used in dyeing, as a bleach, and in detergents. It is soluble in water. The material itself is non-combustible but it will accelerate the burning of combustible ma terial. If the combustible material is finely divided the mixture may be explosive. Contact with liquid combustible materials may result in Spon taneous ignition. If material on fire or Involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Approach fire with caution April 1981 SODIUM PERCHLORATE 49187S0 OXIDIZER UNI 502 Sodium perchlorate is a white crystalline solid, it is used in chemical analysis and in explosives. The material is soluble in water. It is non combustible but it will accelerate the burning of combustible materials. If large quantities are involved in fire or the combustible material is finely divided an explosion may result. Prolonged exposure of the material to fire or heat may result in an explosion. If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Approach fire with caution Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet SODIUM PERMANGANATE 4918751 OXIDIZER UNI 503 Sodium permanganate is a purplish colored crystalline solid, it is used in medicine, as a disinfectant, and tor many other uses. It is soluble in water. The material itself is noncombustible but it will accelerate the burning of combustible material, if the combustible material is finely divided the mixture may be explosive. Contact with liquid combustible materials may result in spontaneous ignition. Contact with sulfuric acid may cause fires or explosions. If material on fire or involved in fire Flood with water Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and nol involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Approach fire with caution Evacuation It fire becomes uncontrollable--evacuate for a radius of 2500 feet SODIUM PEROXIDE 4918540 OXIDIZER, CORROSIVE UNI 504 Sodium peroxide is a yellow-white to yellow granular solid, it is used as a bleaching and oxidizing agent, in chemical analysis, and for many other uses. It is decomposed by water to give sodium hydroxide, a corrosive material and hydrogen peroxide, another corrosive material which normally wifi further decompose lo water and oxygen. Mixtures of potassium peroxide and combustible material can be readily ignited by friction, heat or contact with moisture. Prolonged exposure of the material to fire or heat may result in the vigorous decomposition of the material and the rupturing of the containers. April 1981 If material on fire or involved In fire Use dry chemical, graphite, or dry earth Use water only if flooding quantities are available Apply water from as far a distance as possible If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet SODIUM PHENOLATE, SOLID 4935270 CORROSIVE MATERIAL, BASIC UN2497 Sodium phenolate, solid is a white crystalline solid. It absorbs moisture from the air and dissolves in it. It is soluble in water. The material and its solutions are corrosive to metals and tissue. If material on fire or involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing SODIUM PHOSPHATE, DIBASIC 4966380 ORM-E NA9147 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Sodium phosphate, dibasic is a colorless to white crystalline solid. It is used as a fertilizer, in pharmaceuticals, in food processing, and for many other uses. II is soluble in water. It is non-combustible. H material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Continued on next page 473 MCD 000017401 Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates SODIUM PHOSPHATE, TRIBASIC 4966383 ORM-E NA9148 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Sodium phosphate, tribasic Is a colorless crystalline solid. It is used in cleaning compounds, photography, paint remover, and for many other uses. It is non-combustible. It is soluble in water. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates SODIUM PHOSPHIDE 4916370 FLAMMABLE SOLID, POISONOUS UN1432 WATER REACTIVE Sodium phosphide is a red solid. It reacts with water to form sodium hydroxide, a corrosive material and phosphine, a flammable poison gas. Phosphine will normally ignite spontaneously in contact with air. If there is an excess of water this fire of phosphine will not normally ignite surrounding combustible material. H material on fire or Involved in fire Do not use water Use dry chemical or carbon dioxide H material not on fire and not involved In fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing 474 MCD 0017402 SODIUM PICRAMATE, WET (WITH AT LEAST 20% 4917130 WATER) FLAMMABLE SOLID UNI 349 Sodium picramate, wet is a slurry of dark red crystals. Sodium picra- mate. dry is a high explosive. The dry material when ignited burns with vigor. If large quantities are involved an explosion may result. The wet material will burn though it may require some effort to ignite. It is soluble in water. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or Involved in fire Dangerously explosive Flood witn water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Do not attempt to sweep up dry material Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 5000 feet SODIUM POTASSIUM ALLOY (LIQUID) 4916459 FLAMMABLE SOLID UN1422 WATER REACTIVE ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Sodium potassium alloys are mixtures of metallic sodium and potas sium that is a liquid under normal conditions. It is used as a heat ex change fluid and in the manufacture of other chemicals. The alloys will react vigorously with water to form sodium and potassium hydroxides, corrosive materials, and hydrogen a flammable gas. The heat from this reaction may be sufficient to ignite the hydrogen. If material on fire or involved in fire Do not use water Do not use carbon dioxide Use graphite, soda ash, powdered sodium chloride, or suitable dry powder If material not on fire and not Involved In fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Do not attempt to sweep up dry material Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Avoid breathing fumes from burning material Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover with oil Environmental considerations--water spilt Neutralize with dilute acid or removable strong acid April 1981 SODIUM POTASSIUM ALLOY (SOLID) FLAMMABLE SOLID 4916460 UNI 422 WATER REATIVE ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Sodium potassium alloys are mixtures of metallic sodium and potas sium that is a solid under normal conditions. It is used as a heat exchange fluid and in the manufacture of other chemicals. The alloys will react vigorously with water to form sodium and potassium hydroxides, cor* rosive materials, and hydrogen a flammable gas. The heat from this reaction may be sufficient to ignite the hydrogen. If material on fire or involved in fire Do not use water Do not use carbon dioxide Use graphite, soda ash. powdered sodium chloride, or suitable dry powder If material not on fire and not Involved in fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Do not attempt to sweep up dry material Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Avoid breathing fumes from burning material Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover with oil Environmental considerations--water spill Neutralize with dilute acid or removable strong acid SOOIUM RESINATE, (FLAMMABLE SOLID, N.O.S.) 4916761 FLAMMABLE SOLID UN132S Sodium resinate is a white amorphous powder. It may spontaneously heat in the presence of air and moisture. This heat may be sufficient to ignite nearby combustible material. It is soluble in water. If material on fire or involved in fire Use water in flooding quantities as tog Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water SODIUM SELENITE 4923350 POISON B NA2630 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Sodium selenite is a white crystalline solid. It is soluble in water. It is toxic by ingestion. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved In fire Keep material out of water sources and sewers April 1981 Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Adjust ph to neutral (ph-7) If dissolved, apply sodium sulfide solution to precipitate heavy metals Allow to aerate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates SODIUM SOLUTION WASTE (CORROSIVE LIQUID, 4935248 N.O.S.) CORROSIVE MATERIAL, BASIC UN1760 Sodium solution waste is a various colored liquid. It is soluble in water. It is corrosive to metals and tissue If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors or dusts Avoid bodily contact with the material Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing SODIUM SULFIDE, ANHYDROUS 4916740 FLAMMABLE SOLID UN1385 Sodium sulfide, anhydrous is a yellow to brick red crystalline mass or fused solid with an odor of rotten eggs. If exposed to moist air it is liable to spontaneous heating and may cause ignition of nearby com bustible material. It absorbs moisture from air and dissolves in it. H material on fire or involved In fire Flood with water If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material 475 ^7 403 0000 SODIUM. METAL DISPERSION IN ORGANIC SOLVENT 4916457 FLAMMABLE SOLID UN1429 WATER REACTIVE ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-IOOO/454) Sodium, metal dispersion in organic solvent is finely divided sodium in an oil. it is used to make other chemicals, in certain fight bulbs, and for may other uses. It reacts with water to form sodium hydroxide, a corrosive material and hydrogen, a flammable gas. This reaction will not be as vigorous as that of sodium alone reacting with water as the oil coating slows down the reaction. There may be sufficient heat to ignite the hydrogen. It weighs 7.7 pounds per gallon. If material on fire or involved in fire Do not use water Do not use carbon dioxide Use graphite, soda ash. powdered sodium chloride, or suitable dry powder If material not on fire and not involved in fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Keep material dry Do not attempt to sweep up dry material Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Avoid breathing fumes from burning material Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with dilute acid or removable strong acid SODIUM, METAL LIQUID ALLOY 4916458 FLAMMABLE SOLID NA1421 WATER REACTIVE ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Sodium, metal liquid alloy is sodium mixed with some other metal, usually potassium, it is used as heat exchange fluid. It is a liquid under normal conditions. It reacts vigorously with water to form sodium hy droxide, a corrosive material and hydrogen, a flammable gas. The heat from this reaction may be sufficient to ignite the hydrogen. It weighs 7.7 pounds per gallon. If material on fire or involved in fire Do not use water Do not use carbon dioxide Use graphite, soda ash, powdered sodium chloride, or suitable dry powder If material not on fire and not Involved in fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Pereonnei protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Avoid breathing fumes from burning material Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Cover with oil Environmental considerations--water spill Neutralize with dilute acid or removable strong acid 476 ,v OO' SODIUM. METALLIC 4916456 FLAMMABLE SOLID UN1428 WATER REACTIVE ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Sodium metallic is a soft, silvery metal though normally greyish white in color due to oxide formation. It is used to manufacture chemicals, sodium compounds, in certain light bulbs, and for other uses. It may ignite spontaneously in air. Once ignited it can burn quite violently, it reacts with water to form sodium hydroxide, a corrosive material, and hydrogen, a flammable gas. The heat of the reaction may be sufficient to ignite the hydrogen. It weighs 7.7 pounds per gallon. If material on fire or Involved in fire Do not use water Do not use carbon dioxide Use graphite, soda ash. powdered sodium chloride, or suitable dry powder If material not on fire and not involved in fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Do not attempt to sweep up dry material Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Avoid breathing fumes from burning material Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover with oil Environmental considerations--water spill Neutralize with dilute acid or removable strong acid SOLOERING FLUX OR SALTS. NEC, LIQUID 4936585 (CORROSIVE LIQUID, N.O.S.) CORROSIVE MATERIAL UN1760 Soldering flux or salts, nec, liquid are generally colorless to yellow liquids. Frequently these contain hydrochloric or hydrofluoric acids and zinc chloride. They are water soluble. They are corrosive to metals and tissue. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use "alcohol'' foam, carbon dioxide or dry chemical If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear fuU protective clothing SOLDERING FLUX, NEC LIQUID (FLAMMABLE 4910492 LIQUID, N.O.S.) FLAMMABLE LIQUID UN1993 Soldering flux, nec liquid is a material containing a solvent having a closed cup flash point of less than 100 deg. F. The hazard of this material is flammability. April 1981 If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water SOLDERING FLUX, NEC, LIQUID (COMBUSTIBLE 4915492 LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Soldering flux, nec liquid is a material containing a solvent having a closed cup flash point between 100 and 199 deg. F. The hazard of this material is combustibility. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water SOLUTION, COPPER PLATING (CORROSIVE LIQUID, 4930275 N.O.S.) CORROSIVE MATERIAL UN1760 Solution, copper plating is usually a blue or green colored liquid. It is soluble in water. It is corrosive to metals and/or tissue. It may be toxic by ingestion, skin absorption or inhalation. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible if material not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the matenal Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Keep upwind SOLUTION. COPPER PLATING (POISONOUS LIQUID, 4923475 N.O.S.) POISON B NA2810 Solution, copper plating is usually a blue or green colored liquid. It is soluble in water. It is toxic by ingestion and may be toxic by skin ab sorption. and by inhalation of vapors. If material involved in fire Solid streams of water may be ineffective Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the matenal anticipated, wear full protective clothing SOLVENT REFINED COAL, LIQUID (COMBUSTIBLE 4915558 LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Solvent refined coal, liquid is a dark colored liquid, it has a flash point between 100 and 199 deg. F. it is heavier than water and is insoluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water SOLVENT, N.O.S. 4910187 FLAMMABLE LIQUID NA1993 Solvent, n.o.s. is the proper shipping name for those liquids having a closed cup flash point of less than 100 deg. F. and not specifically mentioned in the hazardous materials regulations. The hazard is flammability. Continued on next page April 1981 477 MCD 00001740 it material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use `alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water SOLVENT, N.O.S. 4915187 COMBUSTIBLE LIQUID NA1993 Solvent, n.o.s. is the proper shipping name for those liquids having a closed cup flash point between 100 and 199 deg. F. and not specifically mentioned in the hazardous materials regulations. The hazard is combustibility If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing SOLVENTS, PAINT, LACQUER, VARNISH OR RESIN 491S297 (SOLVENT, N.O.S.) COMBUSTIBLE LIQUID NA1993 Solvents, paint, lacquer, varnish or resin are clear colorless to variable colored liquids. They have a closed cup flash point between 100 and 199 deg. F. They are generally lighter than water and insoluble in water. Their vapors are heavier than air. If material on fira or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical 478 MCI; oooo If material not on fire and not involved in fire Keep sparks, flames, and other sources ol ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water SOLVENTS, PAINT, LACQUER, VARNISH OR RESIN 4910297 (SOLVENT, N.O.S.) FLAMMABLE LIQUID NA1993 Solvents, paint, lacquer, varnish or resin are clear colorless to variable colored liquids. They have a closed cup flash point of less than 100 deg. F. They are generally lighter than water and insoluble in water. Their vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water SPARKLER, MATCH HEAD OR SELF-IGNITING 4917335 (FLAMMABLE SOLID, N.O.S.) FLAMMABLE SOUD UN1325 Sparklers, match head or self-igniting consist of a metal rod coated with a pyrotechnic composition and an ignition mix on the top. Ignition is by means of friction on a prepared surface. If material on fira or involved in fire Flood with water If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Pereonnel protection Avoid breathing fumes from burning material SPARKLERS, NEC (COMMON FIREWORKS) 4903536 CLASS C EXPLOSIVE Sparklers, nec consist of a rod coated with a pyrotechnic composition. The composition is more than 100 grams per sparkier or the composition contains magnesium and a chlorate or perchlorate. H material on fire or involved In fire Flood with water Apply water from as far a distance as possible H material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away April 1981 Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet SPECIAL FIREWORKS 4902620 CLASS B EXPLOSIVE Special fireworks are manufactured articles designed primarily for the purpose of producing visible or audible pyrotechnic effects by combus tion or explosion e.g., salutes, exhibition display pieces, aeroplane flares, smoke bombs fuzed or unfuzed etc. Special fireworks are distinguished from common fireworks by the amount of explosive, pyrotechnic com position and dimensions of the devices. If material on fire or Involved In fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet SPENT GRAINS, DRIED (FLAMMABLE SOLID, N.O.S.) 4917388 FLAMMABLE SOLID UN1325 Spent grains, dned may be liable to spontaneous heating and ignition. If material on fire or Involved In fire Flood with water If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away SPENT GRAINS, WET, (FLAMMABLE SOLID, N.O.S.) 4917389 FLAMMABLE SOLID UN1325 Spent grains, wet is the mash after its fermentation to produce al coholic beverages. Depending on the moisture content it can decompose with resulting spontaneous heating and possible ignition. If material on fire or Involved In fire Flood with water If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away SPIRITS OF NITROGLYCERINE 4910310 FLAMMABLE UQUIO NA1204 Spirits of nitroglycerine are solutions of nitroglycerine in acetone or ethyl alcohol of up to 10% nitroglycerine. It has a flash point of less than 100 deg. F. If the solvent is allowed to evaporate the nitroglycerine becomes a shock sensitive high explosive. Nitroglycerine can be set off by friction, mechanical impact, or shock. As a solution the hazard is flammability. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cod all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical April 1981 MCD 000017407 If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water SPIRITS OF NITROGLYCERINE, NOT EXCEEDING 1% 4910311 NITROGLYCERINE BY WEIGHT FLAMMABLE LIQUID NA1204 Spirits of nitroglycerine, not exceeding 1% nitroglycerine by weight are solutions of nitroglycerine in acetone or ethyl alcohol of up to 1% nitroglycerine, it has a flash point of less than 100 deg. F. If the solvent is allowed to evaporate the nitroglycerine becomes a shock sensitive high explosive. Nitroglycerine can be set off by friction, mechanical im pact, or shock. As a solution the hazard is flammability. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical tf material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water SPIRITS OF TURPENTINE (COMBUSTIBLE LIQUID. 4915316 N.O.S.) COMBUSTIBLE LIQUID NA1993 Spirits of turpentine is a clear colorless liquid with a characteristic odor. It has a flash point between 100 and 199 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. H material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 479 SPIRITS OF TURPENTINE (FLAMMABLE LIQUID, 4910316 N.O.S.) FLAMMABLE LIQUID UN1993 Spirits of turpentine is a clear colorless liquid with a characteristic odor. It has a flash point of less than 100 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water SPIRITS, ALCOHOLIC, WHISKIES, RUM OTHER THAN 4910308 DENATURED (ALCOHOLIC BEVERAGE) FLAMMABLE LIQUID UN1170 Spirits, alcoholic are clear colorless to amber colored liquids with characteristic odors. They have a flash point of less than 100 deg. F. They are lighter than water and are soluble in water. Their vapors are heavier than air. if material on fire or involved in fire Do not extinguish tire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water SPRITS, GRAIN. NEUTRL, IN BOND (ALCOHOLIC BEVERAGE) 4910309 FLAMMABLE LIQUIO UN1170 Spirits, gram, neutrai, in bond are clear colorless liquid with an alcohol like odor. They have a flash point of less than 100 deg. F. They are lighter than water and soluble in water. Their vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless How can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water 480 Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water SPONGE IRON BRIQUETTES OR PELLETS, VALUE 4917436 ONLY FOR MELTING PURPOSES (FLAMMABLE SOLID, N.O.S.) FLAMMABLE SOLID UN1325 Sponge iron briquettes or pellets is a greyish colored porous solid. It is liable to oxidation. The heat from the oxidation may be sufficient to ignite surrounding combustible materials. If material on fire or involved in fire Flood with water If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Peraonnel protection Wear boots, protective gloves, and goggles STANNIC PHOSPHIDE 4916340 FLAMMABLE SOLID, POISONOUS UN1433 WATER REACTIVE Stannic phosphide is a silver white mass or lump solid. It reacts with moisture to form stannic hydroxide and phosphine, a flammable poison gas. Phosphine will normally ignite spontaneously in contact with air. If there is an excess of water this fire of phosphine will not normally ignite surrounding combustible material. If material on fire or involved in fire Do not use water Use dry chemical or carbon dioxide If material not on fire and not Involved in fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing STARTER CARTRIDGE 4903430 CLASS C EXPLOSIVE Starter cartridge consists of a metal, plastic and/or rubber case, each containing a pressed cylinder block of flammable solid material and having in the top of the case a small compartment that encloses an electric squib and a small amount of black powder and/or smokeless powder which constitute an igniter. The starter cartridge is used to ac tivate a mechanical starter for jet engine. April 1981 v7 AO If material on fire or involved in fire Rood with water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet STARTER CARTRIDGE 4902560 CLASS B EXPLOSIVE Starter cartridge consists of plastic and/or rubber case containing a pressed cylindrical block of propellant explosive which is ignited by an electric squib. The starter cartridge is used to actuate a mechanical starter for a jet engine. If material on fire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet STRONTIUM ARSENITE. SOLID 4923294 POISON B UN1691 Strontium arsenite, solid is a white powder. It is slightly soluble in water. It is toxic by inhalation (dust, etc.) and by ingestion. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved In fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing STRONTIUM CHLORATE 4916753 OXIDIZER UN1506 Strontium chlorate is a white crystalline solid, it is used in pyrotechnics. It is soluble in water. It forms a very flammable mixture with combustible materials and this mixture may be explosive if the combustible material irtrery finely divided. The mixture can be ignited by friction. Contact with strftfig sulfuric acid can cause fires or explosions, when mixed with ammonium salts, spontaneous decomposition and ignition may result. Prolonged exposure of the material to fire or heat may result in an explosion. tf material on fire or Involved In fire Rood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible tf material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Peraonnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet STRONTIUM CHLORATE, WET 4918615 OXIDIZER UNI 506 Strontium chlorate, wet is a slurry or sludge of white crystals, it is used in pyrotechnics. The material is soluble in water. It forms a very flam mable mixture with combustible materials and this mixture may be ex plosive if the combustible material is very finely divided. The mixture can be ignited by friction. Contact with strong sulfuric acid can cause fires or explosions. When mixed with ammonium salts, spontaneous decom position and ignition may result. Prolonged exposure of the material to fire or heat can result in an explosion. If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Peraonnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Approach fire with caution Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet STRONTIUM CHROMATE 4963377 ORM-E NA9149 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (HQ-1000/454) Strontium chromate is a light yellow powder or granular solid. It is used as a pigment, a protective coating against corrosion, and in pyr otechnics. it is insoluble in water. It is non-combustible. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Continued on next page April 1981 MCD 000017409 481 Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or lire fighting water Environmental conaiderationa--water spill Add sodium bisulfite Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates STRONTIUM NITRATE 4916754 OXIDIZER UNI 507 Strontium nitrate Is a white crystalline solid, it is used in pyrotechnics, in medicine, and to make other chemicals. It is soluble in water. It is noncombustible but it will accelerate the burning of combustible mate rials. If large quantities are involved in fire or the combustible matenal is finely divided an explosion may result. Prolonged exposure of the matenal to fire or heat may result in an explosion. Toxic oxides of nitrogen are produced in fires involving this material. It material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible II material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet STRONTIUM PEROXIDE 4918755 OXIDIZER UN1509 Strontium peroxide is a white powder. It is insoluble in water and slowly decomposed by water, it is non-combustible but it will accelerate the burning of combustible material, if the combustible material is finely divided the mixture may be explosive. Mixtures of combustible material and the peroxide can be ignited by friction or contact with moisture. If material on fire or Involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire end not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted die body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet 482 MCD 000017410 STRYCHNINE 4921477 POISON B UNI692 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10/4.54) Strychnine is a white crystalline solid. It is very slightly soluble in water. It will burn though it may require some effort to ignite. It is toxic by ingestion. Toxic oxides of nitrogen are produced during combustion ol this material. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding tire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, appiy activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates STRYCHNINE SALT, SOLID 4921476 POISON B UNI 692 Strychnine salt, solid is usually a while crystalline solid. It is soluble in water. It will burn though it may take some effort to ignite. It is toxic by ingestion. Toxic oxides of nitrogen are produced during combustion of this material. If materiel on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Paraonnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water April 1981 Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates STYRENE MONOMER, INHIBITED 4907265 FLAMMABLE LIQUID UN2055 POLYMERIZABLE ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Styrene monomer inhibited is a clear colorless liquid with an aromatic odor. It is used to make plastics, paints, and synthetic rubber, and to make other chemicals. It has a flash point of 90 deg. F. Its vapors are irritating to the eyes and mucous membranes. If it becomes contami nated or is subjected to heat, it may polymerize. If the polymerization takes place inside a container, the container is subject to violent rupture. It is lighter than water and insoluble in water. Its vapors are heavier than air. it weighs 7.6 pounds per gallon. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash, cement powder, sawdust, or com mercial sorbents Apply ` universal" gelling agent to immobilize spill Apply fluorocarbon-water foam to diminish vapor and fire hazard Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e.g. detergent, soaps, alcohols) to com press and thicken spilled material Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors April 1981 OOO 4U SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, 4921667 N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC. LIQUID) POISON B UN2779 Substituted nitrophenol pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The carrier may burn though it may require some effort to ignite. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to. or leaking from containers of this material contact (he pesticide safety team network. Telephone; 800-424-9300. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, 4921668 N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL, NEC) POISON B UN2779 Substituted nitrophenol pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The carrier may burn though it may require some effort to ignite. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical H material not on fire end not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 483 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, 4910577 N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC, LIQUID) FLAMMABLE LIQUID UN2780 Substituted nitrophenoi pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The primary hazard of this material is the flammability of the carrier. It has a flash point below 100 deg. F. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to, or leaking from containers of this ma terial contact the pesticide safety team network. Telephone: 800-424- 9300. If material on fire or involved In fire Do not extinguish fire unless (low can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use 'alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wear self-contained breathing apparatus when fighting fires involv ing this material SUBSTITUTED NITROPHENOL PESTICIDE, SOLID, 4921662 N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL, NEC) POISON B UN2779 Substituted nitrophenoi pesticide is a solid or a liquid absorbed on a dry carrier. It is a wettable powder. It is toxic by inhalation, skin ab sorption, and/or ingestion. In case of damage to, or leaking from con tainers of this material contact the pesticide safety team network. Tele phone; 800-424-9300. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in lire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, 4910578 N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL, NEC) FLAMMABLE LIQUID UN2780 Substituted nitrophenoi pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The primary hazard of this material is the llammability of the carrier, it has a flash point below 100 deg. F. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to. or leaking from containers of this ma terial contact the pesticide safety team network. Telephone; 800-424- 9300. If material on lira or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear bools, protective gloves, and goggles Do not handle broken packages without protective equipment Wear self-contained breathing apparatus when fighting fires involv ing this material 484 SUBSTITUTED NITROPHENOL PESTICIDE, SOLID, 4921661 N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC, OTHER THAN LIQUID) POISON B UN2779 Substituted nitrophenoi pesticide is asolid or a liquid absorbed on a dry carrier, it is a wettable powder. It is toxic by inhalation, skin ab sorption, and/or ingestion. In case of damage to, or leaking from con tainers of this material contact the pesticide safety team network. Tele phone; 600-424-9300. If material on fire or Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing April 1981 SUCCINIC ACID PEROXIDE 4919170 ORGANIC PEROXIDE UN213S Succinic add peroxide is shipped either wet as a slurry or sludge of white crystals or as a white crystalline solid. Wet, it takes some effort to ignite. But once ignited it bums very rapidly. Dry. it is easily Ignited and burns very rapidly. In either condition it strongly supports the burning of combustible materials. Dry, it can form explosive mixtures with finely divided combustible materials. Under prolonged exposure to heat or fire, containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, cartoon dioxide or dry chemical Dangerously explosive If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet SULFIDE WASTE (CORROSIVE UQUID, N.O.S.) 493S27S CORROSIVE MATERIAL UN1760 Sulfide waste is a dark colored liquid with a burning sulfur to rotten egg odor. It may bum though requiring some effort to ignite. Part of the material will dissolve in water with evolution of heat. It is corrosive to metals and tissue. If material on fire or Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of Ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when lighting fires involv ing this material If contact with the material anticipated, wear full protective clothing SULFATES, MIXED ETHYL, CONSISTING OF 4933321 MONOETHYL AND DIETHYL SULFATE (CORROSIVE LIQUID, N.O.S.) CORROSIVE MATERIAL, ACIDIC UNI 760 Sulfates, mixed ethyl, consisting of monoethyl and diethyl sulfate is a clear colorless liquid with a faint ether like odor. It is non combustible. It is corrosive to metals and tissue. If material on fire or involved in fire Use dry chemical, carbon dioxide, or dry sand Do not use water on matenal itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear setf-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing April 1981 MCD 000017413 SULFUR CHLORIDE (Dl) 4932379 CORROSIVE MATERIAL, ACIDIC UNI 628 Sulfur chloride is an amber to reddish brown fuming liquid with a pungent odor. It is decomposed by water to hydrochloric acid; sulfur dioxide, a nonflammable gas; and hydrogen sulfide, a flammable poi sonous gas with the evolution of heat. It is corrosive to metals and tissue, it weighs 14.1 pounds per gallon. If material Involved In fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself ft large quantities of combustibles are involved, use water in flooding quantities as spray and tog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Continued on next page 485 Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment SULFUR CHLORIDE (MONO) 4932380 CORROSIVE MATERIAL, ACIDIC UN1628 ENVIRONMENTALLY HAZAROOUS SUBSTANCE (RO-IOOO/454) Sulfur chloride is an amber to reddish brown fuming liquid with a pungent odor. It is decomposed by water to hydrochloric acid; sulfur dioxide, a nonflammable gas; and hydrogen sulfide, a flammable poi sonous gas with the evolution of heat. It is corrosive to metals and tissue. It weighs 14.1 pounds per gallon. If material Involved In fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Use mechanical dredges or lifts to remove Immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment SULFUR DIOXIDE 4904290 NONFLAMMABLE GAS, CORROSIVE UN1079 Sulfur dioxide is a colorless gas with an irritating sulfur odor. It is used to manufacture chemicals, in paper pulping, in metal and food process ing, and for many other uses. The vapors are irritating to the eyes and mucous membranes. It is soluble in water to form sulfurous acid, a corrosive material. The vapor is heavier than air. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use water spray to absorb vapors If material not Involved in fire Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or lime Do not use water on material itself Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered SULFUR HEXAFLUORIOE 4904575 NONFLAMMABLE GAS UN1080 Sulfur hexafluoride is a colorless odorless gas. It is noncombustible. It is shipped as a liquefied gas under its own vapor pressure. Contact with the liquid can cause frostbite. It may onty be shipped in cylinders. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved in fire Attempt to stop leak if without hazard Peraonnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment SULFUR TRIOXIDE (SULFUR TRIOXIDE, 4930051 UNSTABILIZED) CORROSIVE MATERIAL, POISONOUS UN1829 Sulfur trioxide is a fuming colorless to white crystalline solid. It is used in the manufacture of chemicals, especially detergents. It reacts vigor ously with water with release of heat. Contact with combustible materials may result in ignition. It is corrosive to metals and tissue. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as log Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible 486 mod gooi?4l4 April 1981 H material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water SULFUR TRIOXIDE, STABILIZED 4930050 CORROSIVE MATERIAL, ACIDIC, POISONOUS UN1829 Sulfur trioxide, stabilized is a colorless to white crystalline solid fuming in air. It reacts with water to form sulfuric acid with release of heat. It is corrosive to metals and tissue. Contact with combustible materials may result in ignition. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water SULFURIC ACID 4930040 CORROSIVE MATERIAL, ACIDIC, POISONOUS UN1B30 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Sulfuric acid is a colorless oily liquid. It is used to make fertilizers and other chemicals, in petroleum refining, in iron and steel production, and for many other uses. It is soluble in water with release of heat. It is corrosive to metals and tissue. It will char wood and most other organic matter on contact, but is unlikely to cause a fire. It weighs 15.3 pounds per gallon. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible H material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment SULFURIC ACID, SPENT 4930042 CORROSIVE MATERIAL, ACIDIC, POISONOUS UNI 932 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Sulfuric acid, spent is a black oily liquid. It is soluble in water with release of heat. It is corrosive to metals and tissue. It will char wood and most other organic matter on contact, but is unlikely to cause a fire. It weighs 15.3 pounds per gallon. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment SULFURIC ANHYDRIDE (See SULFUR TRIOXIDE 4930050) April 1981 00001^15 tfCD 487 SULFUROUS ACID CORROSIVE MATERIAL 493025B UN1833 Sulfurous acid is a colorless liquid with a pungent burning sulfur odor. It is soluble in water with release of heat. It is corrosive to metals and tissue. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with Hooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing SULFURYL CHLORIDE 4930260 CORROSIVE MATERIAL UN1834 Sulfuryl chloride is a colorless fuming liquid with a pungent odor. Its vapors are irritating to the eyes and mucous membranes. It reacts with water to form hydrochloric and sulfuric acids with release of heat. It is corrosive to metals and tissue. If material involved in fire Extinguish fire using agent suitable for type of surrounding tire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing SULFURYL FLUORIDE 4904576 NONFLAMMABLE GAS, POISONOUS UN2191 Sulfuryl fluoride is a colorless odorless gas. It is shipped as a liquefied gas under its own vapor pressure. It is noncombustible. It is heavier than air and prolonged breathing of sulfuryl fluoride contaminated air may be fatal. Contact with the liquid can cause frostbite. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) 488 MCD ;>00017416 Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear protective gloves and goggles Do not handle broken packages without protective equipment SULPHUR, ZINC SULPHATE AND LEAD ARSENATE 4923293 (LEAD ARSENATE, SOLID) POISON B UN1617 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Sulfur, zinc sulfate and lead arsenate is a yellow colored powder. It is insoluble in water. It is toxic by skin absorption, inhalation (dust, etc.) and by ingestion. If material involved in fire Extinguish fire using agent suitable (or type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not Involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Add ferric chloride (fecl3) Adjust ph to neutral (ph-7) Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates SUPPLEMENTARY CHARGE (EXPLOSIVE) 49Q1225 CLASS A EXPLOSIVE Supplementary charge (explosive) is a casing containing high explo sive. It is used to intensify the explosion of a detonator or detonating fuze. Under fire conditions they will explode. If material on fire or involved In fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet April 1981 TALLOW ALCOHOL (ALCOHOL, N.O.S.) 4910405 FLAMMABLE LIQUID UN1987 Tallow alcohol is a malenal having a closed cup flash point of less than 100 deg. F. The hazard is flammability. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep matehal out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water TANKAGE, CRUDE. DRIED, OTHER THAN FEEDING 4917434 (GARBAGE TANKAGE (CONTAINING LESS THAN 8% MOISTURE)) FLAMMABLE SOLID NA1325 Tankage, crude, dried is various food scrap ground and cooked. If it has not been properly cooked or is too dry it is liable to spontaneous heating and ignition. If material on fire or involved in fire Flood with water If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away TANKAGE, DERIVED FROM MEAT REFUSE 4917433 (GARBAGE TANKAGE (CONTAINING LESS THAN 8% MOISTURE)) FLAMMABLE SOLID NA1325 Tankage, derived from meat refuse is a mixture of ground meat by products. if it has not been properly cooled or is too dry it is liable to spontaneous heating and ignition. If material on fire or involved in fire Flood with water If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away TALLOW ALCOHOL (ALCOHOL, N.O.S.) COMBUSTIBLE LIQUID 4915405 UNI 987 Tallow alcohol is a material having a closed cup flash point between 100 and 199 deg. F. It is generally lighter than water and insoluble in water. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical H material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matehal which may have contacted the body with copious amounts of water or soap and water TANKAGE FERTILIZER 4917345 FLAMMABLE, SOLID NA1325 Tankage fertilizer is dried waste food products. If it has not been properly cooled or is too dry it is liable to spontaneous heating and ignition. If material on fire or involved in fire Flood with water If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away April 1981 TANKAGE, ROUGH AMMONIATE 4917365 FLAMMABLE SOLID NA1325 Tankage, rough ammoniate is the dried solid material remaining after the rendering of packing plant byproducts such as hair, horns, hoofs, leather scrap, wool waste, or felt waste. The tankage may be liable to ignition. If material on fire or involved In fire Flood with water If material not on fire and not Involved In fire Keep sparks, fie Ties, and other sources of ignition away TANNER'S DIPILATORY, NEC (CORROSIVE LIQUID, 4936573 N.O.S.) CORROSIVE MATERIAL UNI 760 Tanner's depilatory, nec is a variable colored liquid having the property of being corrosive to metals and/or tissue. It may be combustible though requiring some effort to ignite. It may or may not be water soluble. If material on fire or Involved in fire Extinguish tire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear sell-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing 489 MCD 000017417 TAR OR PITCH, COAL OR PETROLEUM (TAR, LIQUID) 4910263 FLAMMABLE LIQUID UN1999 Tar or pitch coal or petroleum is a thick brownish black liquid with a characteristic odor. It has a flash point of less than 100 deg. F. It is heavier than water and insoluble in water. Its vapors are heavier than air. If material on tire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in lire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water TAR OR PITCH, COAL OR PETROLEUM (TAR, LIQUID) 4915263 COMBUSTIBLE LIQUID UN1999 Tar or pitch, coal or petroleum is a thick brownish black liquid with a characteristic odor. It has a flash point between 100 and 199 deg. F. It is heavier than water and insoluble in water. Its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish tire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use loam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handie broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water TAR, LIQUID 4915261 COMBUSTIBLE LIQUID UN1999 Tar. liquid is a thick brownish black liquid with a characteristic odor, it has a flash point between 100 and 199 deg. F. It is insoluble in water and is heavier than water. Its vapors are heavier than air. II material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with hooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical 490 If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water TAR, LIQUID 4910261 FLAMMABLE LIQUID UNI 999 Tar, liquid is a thick brownish black liquid with a characteristic odor. It has a flash point of less than 100 deg. F. It is insoluble in water and is heavier than water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water TDE (l.l-DICHLORO-BIS(P-CHLOROPHENYL)ETHANE) 4940370 ORM-A NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Tde is a colorless crystalline solid. It is used as a pesticide. It is a wettable powder or water emulsifiable liquid. It can cause Illness by inhalation, skin absorption and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain tlow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water April 1981 MCI) 000017418 Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates TEAR GAS CANDLE 4925110 IRRITATING MATERIAL UN1700 Tear gas candle is a device containing lachrymatory (tear producing) substances and mechanism for expelling the tear gas. If material on fire or involved in fire Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water H material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water TEAR GAS GRENADE 4925120 IRRITATING MATERIAL NA2017 Tear gas grenade is a small device designed to be thrown. It has a small explosive charge for expelling the lachrymatory (tear producing) substances contained in the grenade. If material on fire or involved in fire Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing TERT-AMYL PEROXYNEODECANOATE, (NOT MORE 4919107 THAN 75% WITH PHLEGMATIZER) ORGANIC PEROXIDE UN2891 Tert-amyl peroxyneodecanoate. (not more than 75% with phlegma- tizer) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite; but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spon taneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of combustible materials. Under prolonged exposure to lire or heat containers of the material may explode. The phlegmatizer is a material added to make the peroxide less reacitive. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool alt affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Pereonnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet TEAR GAS SOLUTIONS (IRRITATING AGENT, N.O.S.) 4925132 IRRITATING MATERIAL NA1693 Tear gas solutions, are liquids which have the property of being se verely irritating to the eyes and other mucous membranes when dis persed in the air. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Use water spray to knock-down vapors April 1981 TETRAETHYL DITHIO PYROPHOSPHATE AND 4920544 COMPRESSED GAS MIXTURE POISON A UN1703 Tetraethyldithiopyrophosphate and compressed gas mixture is a liquid charged with a gas. Tetraethyldithiopyrophosphate is a yellow liquid. Its vapor is heavier than air. It is lethal by skin absorption and inhalation. The material may only be shipped in cylinders and these must be ov erpacked in strong wooden or fiberboard boxes. Prolonged exposure of the cylinders to fire or heat may result in the violent rupturing and rocketing of the cylinders. In case of damage to, or leaking from con tainers of this material contact the pesticide safety team network. Tele phone; 800-424-9300 Continued on next page 491 MCI) 000017419 If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical If material not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered TETRAETHYL DITHiOPYROPHOSPHATE MIXTURE, 4921481 DRY POISON B UNI 704 Tetraethyl dithio pyrophosphate mixture, dry is a solid material on which the liquid phosphate is absorbed. The phosphate is combustible though it may take some effort to ignite. It is toxic by inhalation (dust, etc.) and by skin absorption. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300 If material on fire or involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical H material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water TETRAETHYL DITHIOPYROPHOSPHATE MIXTURE, 4921482 LIQUID POISON B UNI 704 Tetraethyl dithio pyrophosphate mixture liquid is the solution of te traethyl dithio pyrophosphate in a suitable solvent. The phosphate itself is combustible though it may take some effort to ignite. The flammable property of the mixture will also depend on the nature of the solvent. It is toxic by inhalation and skin absorption. It may or may not be water soluble. In case of damage to, or leaking from containers of this matehal contact the pesticide safety team network. Telephone; 800-424-9300 If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water 492 MCI) 000017420 Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation if material leaking (not on fire), downwind evacuation must be considered TETRAETHYL DITHIOPYROPHOSPHATE, LIQUID 4921480 POISON B UN1704 Tetraethyl dithio pyrophosphate is a yellow liquid. It is combustible though it may require some effort to ignite. It is slightly soluble in water. It is toxic by inhalation and by skin absorption. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300 If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matehal out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any matehal which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered TETRAETHYL LEAD, UQUID 4921484 POISON B NA1649 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-IOO/45.4) Tetraethyl lead is a colorless liquid and with a characteristic odor. It is insoluble in water. It is also a combustible liquid. It may only be shipped in cylinders. Prolonged exposure to fire or heat can cause the material to explode and cause the cylinders to violently rupture and rocket. It is toxic by inhalation and by skin absorption. It is insoluble in water. It weighs 13.8 pounds per gallon. April 1981 If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical Use water spray to absorb vapors Dangerously explosive tf material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered Environmental conalderatlons--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash, cement powder, sawdust, or com mercial sorbents Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Adjust ph to neutral (ph-7) Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors TETRAETHYL PYROPHOSPHATE AND COMPRESSED 4920545 GAS MIXTURE POISON A UN1705 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Tetraethylpyrophosphate and compressed gas mixture is a liquid charged with a gas. Tetraethylpyrophosphate is a colorless liquid. Its vapor is heavier than air. It is soluble in water. It is lethal by skin ab sorption and inhalation. The material may only be shipped in cylinders and these must be overpacked in strong wooden or fiberboard boxes. Prolonged exposure of the cylinders to fire or heat may result in the violent rupturing and rocketing of the cylinders. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300 If material involved In fire Extinguish tire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water April 1981 Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Appfy "universal'' gelling agent to immobilize spill Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors TETRAETHYL PYROPHOSPHATE LIQUID 4921486 POISON B NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Tetraethyl pyrophosphate liquid is a colorless liquid. It is combustible though it may take some effort to ignite, it is soluble in water and is gradually decomposed by water. It is toxic by inhalation and by skin absorption. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424- 9300 It weighs 10.0 pounds per gallon. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical Use water spray to absorb vapors tf material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Continued on next pege 493 0000^ 4*2^ Evacuation If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors TETRAETHYL PYROPHOSPHATE MIXTURE, DRY 4921487 POISON B NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-100/45.4) Tetraethyl pyrophosphate mixture, dry is a solid material on which the phosprate, a liquid is absorbed. The phosphate itself is combustible though . may take some effort to ignite. It is soluble in water and grad ually decomposed by it. It is toxic by inhalation (dust, etc.) and by skin absorption. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424- 9300 If material on fire or Involved in fire Extinguisn fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water m flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, lames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of .vater or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates TETRAETHYL PYROPHOSPHATE MIXTURE, LIQUID 4921488 POISON B NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-100/45.4) Tetraethyl pyrophosphate mixture, liquid is the solution of a solid in tetraethyl pyrophosphate or tetraethyl pyrophosphate diluted with some solvent. Tetraethyl pyrophosphate is itself combustible, but the flamm ability of the mixture will depend upon the nature of the other materials. Tetraethyl pyrophosphate is soluble in water and is slowly decomposed by water. It is toxic by inhalation and by skin absorption. In case of damage to, or leaking from containers of this material contact the pes ticide safety team network. Telephone; 800-424-9300 494 MOD >G00 '4S?9 If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors TETRAFLUOROETHYLENE, INHIBITED 4905783 FLAMMABLE GAS UN1081 Tetrafiuoroethylene, inhibited is an odorless gas. It is easily ignited and may only be shipped in cylinders. It is heavier than air and a flame can flash back to the source of leak very easily. It can asphyxiate by the displacement of air. If exposed to heat for prolonged periods, cylinders of tetrafiuoroethylene may polymerize and the polymerization may vi olently rupture the cylinders. Under fire conditions the cylinders may violently rupture and rocket. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak If without hazard Use water spray to knock-down vapors Personnel protection Keep upwind Wear self-contained breathing apparatus Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered April 1981 1,2,3,6-TETRAHYDROBENZALDEHYDE 4936370 CORROSIVE MATERIAL, COMBUSTIBLE UN249S 1,2,3,6-tetrahydrobenzaldehyde is a colorless liquid, it is used to make fabrics water resistant, and to make other chemicals. It is combustible and has a flash point of 135 deg. F. It is lighter than water and slightly soluble in water. It is corrosive to metals and tissue. H material on fire or involved In fire Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing TETRAHYDROFURAN 4908290 FLAMMABLE LIQUID UN2056 Tetrahydrofuran is a clear colorless liquid with an ethereal odor. It has a flash point of 6 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cook all affected containers with flooding quantities of water Apply water from as far a distance as possible Use ` alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direcl flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered TETRAHYDROFURFURYL ALCOHOL 4913177 COMBUSTIBLE LIQUID NA1993 Tetrahydrofurfuryl alcohol is a clear colorless liquid with a mild odor. It has a flash point of 167 deg. F. It is heavier than water and is soluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be Ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'1 foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water TETRAMETHYL AMMONIUM HYDROXIDE, LIQUID 4935660 CORROSIVE MATERIAL, BASIC UN1835 Tetramethyl ammonium hydroxide, liquid is a colorless liquid with a strong ammonia-like odor. It is soluble in water. It is corrosive to metals and tissue. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Coot all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this materia! If contact with the material anticipated, wear full protective clothing 1,1,3,3-TETRAMETHYLBUTYL HYDROPEROXIDE, 4919190 (TECHNICALLY PURE) ORGANIC PEROXIDE UN2160 1,1,3.3-tetramethylbutyl hydroperoxide, (technically pure) is a color less to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite; but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burn ing of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. H material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive Continued on next page April 1981 495 MCD 000017423 ft material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when tighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet 1,1,3,3-TETRAMETHYLBUTYL PEROXY-2- 4919191 ETHYLHEXANOATE. (TECHNICALLY PURE) ORGANIC PEROXIDE UN2161 1,1,3,3-tetramethylbutyl peroxy-2-ethylhexanoate, (technically pure) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber, it is insoluble in water. The liquid or solution may require some effort to ignite; but once ignited, it will bum with increasing rapidity as the fire progresses. If spilled on combustible materials, spon taneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction, it supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive H material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet 496 MCD 000017424 TETRANITROMETHANE 4918180 OXIDIZER, POISONOUS AND THERMALLY UNSTABLE UN1510 Tetranitromethane is a pale yellow liquid, it is a skin and respiratory irritant. It is toxic by inhalation from prolonged exposures to the vapor or for short exposures to high concentrations of the material. The material is somewhat difficult to ignite and once ignited it bums at a steady rate. If contaminated with combustible material, tetranitromethane may de compose explosively. Prolonged exposue of tetranitromethane and/or its containers to fire or heat may cause an explosion. Toxic oxides of nitrogen are produced during combustion of this material. It material on fire or involved in fire Use water in flooding quantities as fog Cool all affected containers with flooding quantities of wafer Apply water from as far a distance as possible Solid streams of water may be ineffective Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet TEXTILE TREATING COMPOUNDS MIXTURE, UQUID 4936575 CORROSIVE MATERIAL NA1760 Textile treating compound mixture, liquid is a variable colored material having the property of being corrosive to metals and/or tissue. It may be combustible though requiring some effort to ignite. It is usually water soluble. It material on fire or Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Use "alcohol'' foam, carbon dioxide or dry chemical H material not cm fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gioves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing April 1981 TEXTILE WASTE, WET 4917368 FLAMMABLE SOLID UN1857 Textile waste, wet consists of waste fibers such as cotton, flax, wool, jute or hemp water wet. These are liable to spontaneous heating and ignition. They must be shipped in air tight metal lined containers. If material on fire or Involved in fire Flood with water If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away THALLIUM SALT, SOLID. N.O.S. 4923296 POISON B NA1707 Thallium salts, solid, n.o.s. are compounds containing thallium. They are variable colored and may or may not be water soluble. They are toxic by ingestion and inhalation {dusts, etc). If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not Involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing THALLIUM SULFATE, SOLID 4923297 POISON B NA1707 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Thallium sulfate, solid is a colorless to white crystalline solid. It is soluble in water. It is toxic by skin absorption and ingestion. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not Involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire righting water Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates April 1981 THINNER FOR RUST PREVENTIVE COATING 4910154 FLAMMABLE LIQUID NA1142 Thinner for rust preventive coating is generally a clear colorless liquid. It has a flash point of less than 100 deg. F. Most of these materials are lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water In flooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water THINNER FOR RUST PREVENTIVE COATING 4915154 COMBUSTIBLE LIQUID NA1142 Thinner for rust preventive coating is generally a clear colorless liquid. It has a flash point of between 100 and 199 deg. F. Most of the matenals are lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water THIOGLYCOLIC ACID 4931460 CORROSIVE MATERIAL, ACIDIC UN1940 Thioglycolic acid is a colorless liquid with an unpleasant odor. It is soluble in water. It is corrosive to metals and tissue. If material on fire or Involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors Continued on next page mod Q00017425 497 If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing THIONYL CHLORIDE 4930060 CORROSIVE MATERIAL, ACIDIC, POISONOUS UNI 636 Thionyl chloride is a colorless fuming liquid with a suffocating pungent odor. It reacts with water to form sulfur dioxide and hydrochloric acid. It is corrosive to metals and tissue. If material Involved in fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itseif If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water THIOPHOSGENE 4923298 POISON B UN2474 Thiophosgene is a red colored liquid. It is decomposed by water to give hydrochloric acid, a corrosive material. Contact with skin can cause severe burns, It is toxic by inhalation and by skin absorption. H material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water Do not use water on material itseif If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime 498 Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water THIOPHOSPHORYL CHLORIDE 4930264 CORROSIVE MATERIAL UN1B37 Thiophosphoryl chloride is a colorless fuming liquid. It is irritating to the eyes and mucous membranes, It is decomposed by water producing hydrochloric and phosphoric acids, corrosive materials, and hydrogen sulfide, a toxic flammable gas. It is corrosive to metals and tissue. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Matehal itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on materia) itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the materia! anticipated, wear full protective clothing THORIUM METAL BARS RODS, OR SHAPES, NOT 4926443 IRRADIATED NOR REQUIRING PROTECTIVE SHIELDING (RADIOACTIVE MATERIAL, N.O.S.) RADIOACTIVE MATERIAL NA9181 Thorium metal bars, rods, or shapes are large pieces of silvery grey metal. They are used for nuclear fuel and in electronic devices. They car be ignited by friction and burn with an intense flame. Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful, whereas film may be damaged by radiation from relatively low concentrations. If material on fire or Involved in fire Contact the local, state, or department of energy radiological re sponse team Do not use water Use graphite, soda ash, powdered sodium chloride, or suitable dry powder If material not on fire and not involved in fire Contact the local, state, or department of energy radiological re sponse team Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Do not attempt to sweep up dry material April 1981 8 Personnel protection Keep upwind Avoid breathing dusts, and fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation Keep unnecessary people out of incident area until area declared safe by radiological response team THORIUM METAL BILLETS, INGOTS, PIGS OR SLABS, 4926188 NOT IRRADIATED, NOR REQUIRING PROTECTIVE SHIELDING (THORIUM METAL, PYROFORIC) RADIOACTIVE MATERIAL, PYROFORIC NA9170 Thorium metal billets, ingots, pigs, or slabs are large pieces of the silvery grey metal. It can be ignited by friction and bums with an intense flame. The powdered metal is spontaneously flammable in air. Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful whereas films may be damaged by radiation from relatively low concentrations. If material on fire or involved in fire Contact the local, state, or department of energy radiological re sponse team Do not use water Use graphite, soda ash, powdered sodium chloride, or suitable dry powder If material not on fire and not involved in fire Contact the local, state, or department of energy radiological re sponse team Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Do not attempt to sweep up dry material Personnel protection Keep upwind Avoid breathing dusts, and fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation Keep unnecessary people out of incident area until area declared safe by radiological response team THORIUM METAL SCRAP, NOT IRRADIATED NOR 4926446 REQUIRING PROTECTIVE SHIELDING (RADIOACTIVE MATERIAL, N.O.S.) RADIOACTIVE MATERIAL NA9181 Thorium metal scrap is the waste product from various machining operations of the metal. It is silvery grey colored. It can be ignited by friction and burns with an intense flame. Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful, whereas film may be damaged by radiation from relatively low concentrations. If material on fire or involved in fire Contact the local, state, or department of energy radiological re sponse team Do not use water Use graphite, soda ash. powdered sodium chloride, or suitable dry powder April 1981 f)00n *-> J1 (427 If material not on fire and not involved in fire Contact the local, state, or department of energy radiological re sponse team Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Do not attempt to sweep up dry material Personnel protection Keep upwind Avoid breathing dusts, and fumes from burning material Wear tuil protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation Keep unnecessary people out of incident area until area declared safe by radiological response team THORIUM NITRATE, SOLID 4926310 RADIOACTIVE MATERIAL, OXIDIZING NA9171 Thorium nitrate is a white crystalline mass. It is soluble in water. Thou the material is noncombustible it will accelerate the burning of combus tible materials. If large quantities are involved in the fire or the com bustible material is finely divided an explosion may result. Toxic oxides of nitrogen are produced in fires involving this material. Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful whereas films may be damaged by radiation from relatively low concentrations. If material on fire or involved in fire Contact the local, state, or department of energy radiological re sponse team Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Contact the local, state, or department of energy radiological re sponse team Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Keep upwind Avoid breathing dusts, and fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation if fire becomes uncontrollable--evacuate for a radius of 2500 feet Keep unnecessary people out of incident area until area declared safe by radiological response team THORIUM ORE (MONAZITE SANO) (RADIOACTIVE 4926439 MATERIAL, LOW SPECIFIC ACTIVITY. (OR), LSA, N.O.S.) RADIOACTIVE MATERIAL UN2912 Thorium ore (monazite sand) is a yellowish to reddish-brown solid. It is insoluble in water. Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful, whereas film may be damaged by radiation from relatively low concentrations. Continued on next page 499 tf material involved in fire Contact the local, state, or department of energy radiological re sponse team Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible W material not involved in fire Contact the local, state, or department of energy radiological re sponse team Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Keep upwind Avoid breathing fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water THORIUM OXIDE (RADIOACTIVE MATERIAL, N.O.S.) 4926447 RADIOACTIVE MATERIAL NA9181 Thorium oxide is a white powder. It is used in high temperature ce ramics, filaments of lamps and electron tubes and as a nuclear fuel. It is insoluble in water. Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful, whereas film may be damaged by radiation from relatively low concentrations. H material involved in fire Contact the local, state, or department of energy radiological re sponse team Cool ali affected containers with flooding quantities of water Apply water from as far a distance as possible ff material not Involved in fire Contact the local, state, or department of energy radiological re sponse team Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Keep upwind Avoid breathing fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water TIME FUZE CLASS C EXPLOSIVE 4903270 Time fuze is a mechanism for igniting the bursting charge of a projectile at some predetermined time after the projectile is fired. ff material on fire or involved in fire Flood with water Apply water from as far a distance as possible If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet 500 MCP 000017428 TIN CHLORIDE, FUMING (See TIN TETRACHLORIDE, ANHYDROUS 4932383) TIN PERCHLORIDE (See TIN TETRACHLORIDE, ANHYDROUS 4932383) TIN TETRACHLORIDE, ANHYDROUS 4932383 CORROSIVE MATERIAL, ACIDIC UN1627 Tin, tetrachloride anhydrous is a colorless fuming liquid with a pungent odor. It is soluble in cold water and decomposed by hot water to form hydrochloric acid with the evolution of heat. It is corrosive to metals and tissue. If materiel Involved in fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing TINNING FLUX 4932384 CORROSIVE MATERIAL UN1840 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Tinning flux is zinc chloride and hydrochloric acid dissolved in water. It is a colorless to pale yellow liquid, it is corrosive to metals and tissue. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water In flooding quantities as fog Cool ali affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing April 1981 Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Adjust ph to neutral (ph-7) TIRE PUNCTURE OR RIM SEALING, OR TIRE 491S37S BALANCING COMPOUNDS (COMBUSTIBLE LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Tire puncture or rim sealing, or tire balancing compound are thick dark colored liquids with a petroleum like odor. They have a flash point be tween 100 and 199 deg. F. They are generally lighter than water and insoluble in water. Their vapors are heavier than air. If material on fire or involved in fire Do no! extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use wafer spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water TIRE PUNCTURE OR RIM SEALING, OR TIRE 4910375 BALANCING COMPOUNDS (FLAMMABLE LIQUIDS, N.O.S.) FLAMMABLE LIQUID UN1993 Tire puncture or rim sealing, or tire balancing compound are thick dark colored liquids with a petroleum like odor. They have a flash point of less than 100 deg. F. They are generally lighter than water and insoluble in water. Their vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors April 1981 MCI) 000017429 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water TITANIUM METAL POWDER, DRY OR WET (WITH 4916795 LESS THAN 20% WATER) FLAMMABLE SOLID UN2546 Titanium metal powder, dry is a grey lustrous powder. It can be easily ignited and bums with an intense flame, The very finely powdered ma terial may be ignited by sparks. Ignited by sparks. If material on fire or involved in fire Do not use water Use graphite, soda ash, powdered sodium chloride, or suitable dry powder If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material wet Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water TITANIUM METAL POWDER, WET, WITH 20% OR 4916780 MORE WATER FLAMMABLE SOLID UN1352 Titanium metal powder, wet is a grey lustrous sludge. The dried ma terial can be easily ignited. Very finely powdered, the "dust" may be ignited by sparks. If material on fire or involved in fire Cool all affected containers with flooding quantities of water Use graphite, soda ash. powdered sodium chloride, or suitable dry powder If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material wet Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water TITANIUM SULFATE SOLUTION (CONTAINING NOT 4930265 MORE THAN 45% SULFURIC ACID) CORROSIVE MATERIAL NA1760 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Titanium sulfate solution (containing not more than 45% sulfuric acid) is a colorless or violet colored liquid, it is used to make pigments and in dyeing. The solution is soluble in water with release of heat and possible precipitation of the titanium sulfate. It is corrosive to metais and tissue. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Continued on next page 501 If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water It contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment TITANIUM TETRACHLORIDE 4932385 CORROSIVE MATERIAL, ACIDIC UN1838 Titanium tetrachloride is a colorless fuming liquid with a pungent odor. It is decomposed by water to form hydrochloric acid with the evolution of heat. It is corrosive to metals and tissue. If material involved in fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved in fire Keep material out of water sources and sewers Buikl dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material Itself Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water It contact with the material anticipated, wear full protective clothing TOLUENE 4909305 FLAMMABLE LIQUID UN1294 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-1000/454) Toluene is a clear colorless liquid with a characteristic aromatic odor. It is used in aviation and automotive fuels, as a solvent for many ma terials, and to make other chemicals. It has a flash point of 40 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. It weighs 7.2 pounds per gallon. 502 If material on Tiro or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool alt affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash, cement powder, sawdust, or com mercial sorbents Apply "universal" gelling agent to immobilize spill Apply fluorocarbon-water foam to diminish vapor and fire hazard Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e.g. detergent, soaps, alcohols) to com press and thicken spilled material Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors TOLUENE (TOLUOL), MIXED WITH ALUMINUM 4906010 ALKYLS, NOT TO EXCEED 20 PERCENT (ALUMINUM ALKYL) FLAMMABLE LIQUID UN2845 Toluene (toluol), mixed with aluminum alkyls, not to exceed 20 percent is a clear colorless liquid. It is used to make other chemicals. It ignites spontaneously on contact with air. It reacts violently with water and most chemicals. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Do not use water Use graphite, soda ash or powdered sodium chloride If material not on fire and not Involved In fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Avoid breathing vapors Keep upwind Wear sell-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 WCD 000017430 Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing TOLUENE DIISOCYANATE 4921575 POISON B UN2076 Toluene diisocyanate is a clear colorless to pale yellow liquid with a pungent odor. It is used to make polyurethane foams and paints. It will bum though it may require some effort to ignite. It can react with aniline. The heat of this reaction may be sufficient to ignite surrounding com bustibles and the material itself. Initially its vapors are irritating to the respiratory system. It is toxic upon prolonged exposure to low concen trations of the vapor or to short exposure to high concentrations of the vapor by inhalation. It is heavier than water and reacts slowly with water producing carbon dioxide. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered TOLUENESULFONIC ACID, LIQUID 4931465 CORROSIVE MATERIAL, ACIDIC UN2S84 Toluenesulfonic acid, liquid is water solution of the colorless crystals. It is corrosive to metals and tissue. If material on fire or Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind April 1981 2) On0,'O7> TOLUIDINE (COMBUSTIBLE LIQUID, N.O.S.) 4913175 COMBUSTIBLE LIQUID NA1993 Toluidine is a clear colorless or light yellow liquid, may become reddish brown on exposure to air and light. It has a flash point of 185 deg. F. It Is about the same weight as water and is very slightly soluble In water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use `alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material TORPEDO, RAILWAY 4902810 CLASS B EXPLOSIVE A railway torpedo consists of a flat envelope of about an ounce ca pacity filled with a shock sensitive explosive composition and having attached to it a means of securing it to a rail of the railroad track. The device is designed to function by explosion when run over by the wheel of an engine. The explosive used may be composed of potassium perch lorate, sulfur and antimony sulfide. K material on fire or Involved In fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet 503 TOXAPHENE (CHLORINATED CAMPHENE) 4941190 ORM-A NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Toxaphene is an amber waxy solid. It is used as a pesticide. It is a wettable powder or water emulsifiable liquid, it can cause illness by inhalation, skin absorption and/or ingestion. In case ot damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or tire fighting water Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants ana precipitates TOXAPHENE (TOXAPHENE, OTHER THAN LIQUID) 4941189 ORM-A NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.4S4) Toxaphene is an amber waxy solid. It is used as a pesticide. It is a wettable powder. It can cause illness by inhalation, skin absorption and/ or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424- 9300. If material Involved in fire Extinguish tire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) if material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or tire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates TOXAPHENE (TOXAPHENE, LIQUID) 4941188 ORM-A NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Toxaphene is an amber waxy solid dissolved in a liquid carrier. It is used as a pesticide. It is a water emutsifiable liquid. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300. If material Involved in fire Extinguish lire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion If dissolved, apply activated carbon at len times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates 504 mod 00017432 TOY PROPELLANT DEVICE 4903540 CLASS C EXPLOSIVE Toy propellant device consists of small paper or composition tubes or containers containing a small charge of slow burning propellant pow der with or without ignition element. These devices must be so designed that they will neither burst nor produce external flame on functioning. If material on fire or involved in fire Flood with water Apply water from as far a distance as possible if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach lire with caution Avoid breathing dusts, and tumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet TOY SMOKE DEVICE 4903550 CLASS C EXPLOSIVE Toy smoke device consist of small paper or composition tubes or containers containing a small quantity of smoke producing powder. If material on fire or Involved in fire Flood with water Apply water from as far a distance as possible If material not on fire and not involved (n fire Keep sparks, flames, and other sources of ignition away April 1981 Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation if fire becomes uncontrollable--evacuate for a radius of 1500 feet TOYCAPS 4903560 CLASS C EXPLOSIVE Toy caps consist of a small amount of percussion sensitive explosive either laminated between two pieces of paper or encapsulated in plastic. If material on fire or involved in fire Flood with water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet TRACER 4903275 CLASS C EXPLOSIVE Tracer is a device containing a slow burning composition which is attached to a projectile to show its flight. if material on fire or Involved in fire Flood with water Apply water from as far a distance as possible If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet TRACER FUZE 4903280 CLASS C EXPLOSIVE A tracer fuse is a combination of a compressed column of a pyro technic mixture and a conventional cannon fuse. The device is designed to be inserted into the base of an artillery shell. If material on fire or Involved in fire Flood with water Apply water from as far a distance as possible If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet April 1961 HOD 0000l74o3 TETRALIN HYDROPEROXIDE, (TECHNICALLY PURE) 4919189 ORGANIC PEROXIDE UN2136 Tetralin hydroperoxide, (technically pure) is a white solid, it is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and bums with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combustible materials. It supports the burning of combustible materials. Under prolonged ex posure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with Ihe material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet TRI-N-BUTYLAMINE (COMBUSTIBLE LIQUID, N.O.S.) 4913130 COMBUSTIBLE LIQUID NA1993 Tri-n-butylamine is a pale yellow liquid with a fish like odor. It has a flash point of 175 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material 505 TRIAZINE PESTICIDE, LIQUID, N.O.S. (COMPOUNDS 4910580 AND PERPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL, NEC) FLAMMABLE LIQUID UN2764 Triazine pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The primary hazard of this material is the flammability ol the carrier. It has a flash point below 100 deg. F. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to, or leaking from containers of this material contact the pes ticide safety team network. Telephone: 800-424-9300. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gioves. and goggles Do not handle broken packages without protective equipment Wear self-contained breathing apparatus when fighting fires involv ing this material TRIAZINE PESTICIDE, LIQUID, N.O.S. (COMPOUNDS 4921663 AND PREPARATIONS) (INSECTICIDES. OTHER THAN AGRICULTURAL, NEC) POISON B UN2763 Triazine pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The carrier may burn though it may require some effort to ignite It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to, or leaking from containers of this ma terial contact the pesticide safety team network. Telephone; 800-424- 9300 If material on fire or involved in fire Do not extinguish fire unless How can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use ' alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Bu>id dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep unwind Wear seif-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water TRIAZINE PESTICIDE, LIQUID, N.O.S. (COMPOUNDS 4921664 AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC, LIQUID) POISON B UN2763 Triaizine pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The carrier may bum though it may require some effort to ignite. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to, or leaking from containers of this ma terial contact the pesticide safety team network. Telephone; 800-424- 9300. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Pereonnei protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 506 00001^434 MOD TRIAZINE PESTICIDE. LIQUID, N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL 4910579 INSECTICIDES, NEC, LIQUID) FLAMMABLE LIQUID UN2764 Traiazine pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The primary hazard of this material is the flammability of the carrier. It has a Hash point below 100 deg. F. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to, or leaking from containers of this material contact the pes ticide safety team network. Telephone; 800-424-9300. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gioves, and goggles Do not handle broken packages without protective equipment Wear self-contained breathing apparatus when fighting fires involv ing this material April 1961 TRIAZINE PESTICIDE, SOLID, N.O.S. (COMPOUNDS 4921666 AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC, OTHER THAN LIQUID) POISON B UN2763 Triazine pesticide is a solid or a liquid absorbed on a dry carrier. It is a wettable powder. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to, or leaking from containers of this ma terial contact the pesticide safety team network. Telephone; 800-424- 9300. If materlai on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing TRIAZINE PESTICIDE, SOLID, N.O.S. (COMPOUNDS 4921665 AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL, NEC) POISON B UN2763 Triazine pesticide is a solid or a liquid absorbed on a dry carrier. It is a wettable powder. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to, or leaking from containers of this ma terial contact the pesticide safety team network. Telephone; 800-424- 9300. If material on fire or Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical It material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning matehal Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing TRICHLORFON (AGRICULTURAL INSECTICIDES, NEC, 4940375 LIQUID) ORM-A NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Trichlorfon is a white solid dissolved in a liquid carrier. It is used as a pesticide. It is a water emulsifiable liquid. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash, cement powder, sawdust, or com mercial sorbents Apply "universal" gelling agent to immobilize spill Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates TRICHLORFON (AGRICULTURAL INSECTICIDES, NEC, 4940376 OTHER THAN LIQUID) ORM-A NA27B3 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Trichlorlon is a white crystalline solid. It is used as a pesticide. It is a wettable powder. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 000- 424-9300. if material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates TRICHLORFON (INSECTICIDES, OTHER THAN 4940377 AGRICULTURAL, NEC) ORM-A NA2763 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Trichlorfon is a white crystalline solid or the solid dissolved in a liquid carrier, ft is used as a pesticide, ft is a wettable powder or water emul sifiable liquid. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to, or leaking from containers of this ma terial contact the pesticide safety team network. Telephone; 800-424- 9300. Continued on next page April 1981 507 MCD 000017435 If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash, cement powder, sawdust, or com mercial sorbents Apply "universal" gelling agent to immobilize spill Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove Immobilized masses of pollutants and precipitates TRICHLORO-S-TRIAZINETRIONE (DRY, CONTAINING MORE THAN 39 PERCENT AVAILABLE 4918445 CHLORINE) OXIDIZER UN2468 Trichloro-s-triazinetrione is a white crystalline solid with an odor of chlorine, it is used as a dry bleach in household cleaning compounds and in swimming pool disinfectants. The material itself is noncombustible but if contaminated with combustible material ignition can result. It will accelerate the burning of combustible materials. Contact with ammonium compounds or hydrated salts can cause a very vigorous chemical re action. May vigorously react with small quantities of water releasing chlorine gas. Prolonged exposure to fire or heat of the material may result in the vigorous decomposition of the material and the rupturing of its con tainer. Material containing less than 39 percent available chlor ine will undergo reactions as described above though it may take longer to initiate and the resulting reactions may not be as vigorous. If material on fire or involved in fire Flood with water Cod all affected containers with flooding quantities of water Apply water from as far a distance as possible tf material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts Wear boots, protective gloves, and goggles Do not handie broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach tire with caution Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet TRICHLOROACETIC ACID SOLUTION 4931471 CORROSIVE MATERIAL, ACIDIC UN2564 Trichloroacetic acid solution is the clear colorless crystals dissolved in water. It is corrosive to metals and tissue. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding tire (Material itself does not burn or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use water spray to absorb vapors If material not on fire and not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained-breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing TRICHLOROACETIC ACID, SOLID 4931470 CORROSIVE MATERIAL, ACIDIC UN1839 Trichloroacetic acid, solid is a colorless crystalline solid. It absorbs moisture from air and forms a syrup. It is soluble in water with release of heat. It is corrosive to metals and tissue. If material on fire or involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Cod all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep material out of water sources and sewers Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing TRICHLOROETHYLENE 4941171 ORM-A UN1710 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Trichloroethylene is a clear odorless volatile liquid having a chloro form-like odor. It is used as a solvent, fumigant, in the manufacture of other chemicals, and for many other uses. It is heavier than water and is slightly soluble in water. It is non-combustible. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water 508 MCD 000017436 April 1981 Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soii, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Combustion products include corrosive or toxic vapors TR1CHLOROPHENOL 4940325 ORM-A NA2020 ENVIRONMENTALLY HAZAROOUS SUBSTANCE (RCMO/4.54) Trichlorophenol is a variously colored solid having a strong odor of phenol. It is used as a fungicide and herbicide. It is insoluble in water. It is non-combustible, if material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates 2,4,5-TRICHLOROPHENOXYACETIC ACID (OR) 2,4,S-T 4941185 ORM-A NA2765 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) 2,4.5-trichlorophenoxyacetic acid is a light tan solid. It is used as a herbicide, defoliant, and plant growth regulator. It is insoluble in water. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear bools, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water April 1981 Hci) 0^3? Environmental considerations--water spill Remove trapped material with suction hoses If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates 2,4,5-TRICHLOROPHENOXYACETIC ACID AMINE, 4962390 ESTER, (OR) SALT (OR) 2,4,5-T AMINE, ESTER, (OR) SALT ORM-E NA2765 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) 2,4,5-trichlorophenoxyacetic acid amine, ester, (or) salt are various colored solids. They are used as herbicides, defoliants, or plant growth regulators. They are soluble in water. They will burn though they may take some effort to ignite. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates 2,4,5-TRICHLOROPHENOXYPROPlONIC ACID 4941179 ORM-A NA2765 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) 2,4,5-trichlorophenoxypropionic acid is a white crystalline solid. It is used as a herbicide and plant growth regulator. It is slightly soluble in water. It will bum though it may take some effort to ignite. tf material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates 509 2,4,5-TRICHLOROPHENOXYPROPIONIC ACID ESTERS 49621B0 ORM-E NA2765 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) 2,4,5-trichlorophenoxypropionic acid esters are white solids. They are used as herbicides and plant growth regulators. It is slightly soluble in water. They will burn though it may take some effort to ignite. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations --land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill It dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates TRICHLOROSILANE 4907675 FLAMMABLE LIQUID, CORROSIVE, ACIDIC UNI 295 Trichlorosilane is a colorless fuming liquid with a pungent odor. It has a flash point of 7 deg. F. Vapor and liquid can cause bums. It is heavier than water and is decomposed by water to form hydrochloric acid, a corrosive material. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use "alcohol" foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors (f material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on tire), downwind evacuation must be considered 510 TRICK MATCHES 4903570 CLASS C EXPLOSIVE Trick matches consist of book matches, strike anywhere matches or strike-on-box matches which have small amounts of explosive or pyr otechnic composition affixed to the match stem just below the match head. If material on fire or involved in fire Flood with water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If tire becomes uncontrollable--evacuate for a radius of 1500 feet TRICK NOISE MAKERS, EXPLOSIVE 4903580 CLASS C EXPLOSIVE Trick noise makers, explosive, consist of spheres containing a small amount of explosive composition. If material on fire or Involved in fire Flood with water Apply water from as far a distance as possible If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet TRIETHANOLAMINE OODECYLBENZENESULFONATE 4963379 ORM-E NA9151 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Triethanolamine dodecylbenzenesulfonate is a. It is used as a deter gent. It is soluble in water. It will burn though it may take some effort to ignite. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or tire fighting water Environmental considerations--water spill if dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates April 1981 00001^38 MCP TRIETHYL PHOSPHITE 4913180 COMBUSTIBLE LIQUID NA1993 Triethyl phosphite is a clear colorless liquid with a strong foul odor, It has a Hash point of 130 deg. F. It is lighter than water and is insoluble in water. Its vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical tf material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material TRIETHYLAMINE 4907877 FLAMMABLE LIQUID, CORROSIVE, BASIC UNI 296 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Triethyiamine is a clear colorless liquid with a strong ammonia to fish like odor, tt has a flash point of 20 deg. F. Its vapors are irritating to the eyes and mucous membranes. It is lighter than water and soluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material. It weighs 6.1 pounds per gallon. If materiel on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Peraonnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash, cement powder, sawdust, or com mercial sorbents Apply "universal'' gelling agent to immobilize spill Neutralize with sodium bisulfate (nahso4) Environmental considerations--water spill Add sodium bisulfate If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment TRIETHYLENETETRAMINE (CORROSIVE LIQUID, 4935632 N.O.S.) CORROSIVE MATERIAL, BASIC UNI 760 Triethylenetetramine is a yellowish liquid. It is used in detergents and in the synthesis of dyes, pharmaceuticals and other chemicals. It is lighter than water and is soluble in water. It will burn though it may take some effort to ignite. It is corrosive to metals and tissue. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combus tion of this material. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Appty water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Peraonnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing TRIFLUOROCHLOROETHYLENE. INHIBITED 4905785 FLAMMABLE GAS UN1082 Trifluorochloroethylene is a colorless gas with a faint ethereal odor, It is shipped as a liquefied gas under its vapor pressure. Contact with the liquid can cause frostbite, it is easily ignited. Its vapors are heavier than air and a flame can flash back to the source of leak very easily. This leak can either be a liquid or vapor leak. It can asphyxiate by the displacement of air. Under fire conditions the cylinders or tank car may violently rupture and rocket. Prolonged exposure of the cylinders or tank cars to fire or heat may cause the material to polymerize with possible container rupture. Continued on next page April 1981 000017439 HCD 511 if material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water In flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate lor a radius ol 2500 feet If material leaking (not on fire), downwind evacuation must be considered Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material Itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing TRIMETHYL PHOSPHITE (FLAMMABLE LIQUID. 4909381 N.O.S.) FLAMMABLE LIQUID UN1993 Trimethyl phosphite is a clear colorless liquid with a strong foul odor. It is used to make other chemicals. It has a flash point of 99 deg. F. It is heavier than water and insoluble in water. Its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use `alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material TRIMETHYLACETYL CHLORIDE 4931745 CORROSIVE MATERIAL, ACIDIC, FLAMMABLE UN2436 Trimethylacetyl chloride is a colorless fuming liquid with a pungent odor. It is flammable and has a flash point of 35 deg. F, Its fumes are irritating to the eyes and mucous membranes, ft is decomposed by water to hydrochloric acid, a corrosive material, and trimethyfacetic acid with release of heat. It is corrosive to metals and tissue. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use dry chemical or carbon dioxide Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog 512 TRIMETHYLAMINE, ANHYDROUS 4905540 FLAMMABLE GAS UNI 083 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Trimethylamine, anhydrous is a colorless gas with a fish like odor at low concentrations changing to ammonia-like odor at higher concentra tions. It is shipped as a liquefied gas under its own vapor pressure. Contact with the liquid can cause frostbite or chemical type bums. The gas itself is corrosive and it is soluble in water to form flammable, cor rosive solutions. It is easily ignited. Its vapors are heavier than air and a flame can flash back to the source of leak very easily. It can asphyxiate by the displacement of air. Under fire conditions the cylinder or tank car may violently rupture and rocket. Toxic oxides of nitrogen are produced during combustion of this material. It weighs 5.3 pounds per gallon. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet, If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash, cement powder, sawdust, or com mercial sorbents Neutralize with sodium bisuffate (nahso4) April 1981 MCD 000017440 Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (eg. detergent, soaps, alcohols) to com press and thicken spilled material Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Add sodium bisulfate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations-~air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment TRIMETHYLAMINE, AQUEOUS SOLUTION 4907880 FLAMMABLE LIQUID, CORROSIVE, BASIC UN1297 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Trimethylamine aqueous solution is the solution of trimethylamine, a gas in water. Its odor varies from fish-like to ammonia-like as the vapor concentration increases. The flash point of a 25% solution is 35 deg. F. It is corrosive to the skin and eyes. The solution is lighter than water and soluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material. II weighs 7.4 pounds per gallon. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land apill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash, cement powder, sawdust, or com mercial sorbents Apply "universal1' gelling agent to immobilize spill Neutralize with sodium bisuifate (nahso4) Environmental considerations--water spill Add sodium bisuifate If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment April 1981 MCD 000017441 TRIMETHYLCHLOROSILANE 4907680 FLAMMABLE LIQUID, CORROSIVE, ACIDIC UN129B Trimethylchlorosilane is a colorless fuming liquid with a pungent odor. It has a flash point of 7 deg. F. Vapor and liquid can cause burns. It is heavier than water and is decomposed by water to form hydrochloric acid a corrosive material. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use "alcohol" foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered TRINITROBENZENE, WET (CONTAINING AT LEAST 4917140 10% WATER) FLAMMABLE SOLID UN1354 Trinitrobenzene, wet is a light yellow crystalline sludge or slurry. Trin itrobenzene, dry is a high explosive. Dry it is easily ignited and bums very vigorously. It is insoluble in water. The wet material will bum, though it may require some effort to ignite. Toxic oxides of nitrogen are produced during combustion of this material, if material on fire or involved in fire Dangerously explosive Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Oo not attempt to sweep up dry material Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 5000 feet 513 TRlNfTROSENZOlC ACID, WET (CONTAINING AT 4917150 LEAST 10% WATER) FLAMMABLE SOLID UN1355 Trinitrobenzoic add. wet is a sludge of yellow crystals. The dry material is a high explosive. Dry. the material is easily ignited and will burn very vigorously. The wet material can burn though it may require some effort to ignite. It is insoluble in water. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved In fire Dangerously explosive Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Do not attempt to sweep up dry material Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this matenal Evacuation If fire becomes uncontrollable--evacuate for a radius of 5000 feet TRINITROTOLUENE, WET (CONTAINING AT LEAST 4917160 10% WATER) FLAMMABLE SOUO UN1356 Trinitrotoluene, wet is a yellow crystalline slurry or sludge. The dry material is a high explosive. Dry it is easily ignited and burns very vigorously. The wet material can burn though it may require some effort to ignite. It is insoluble in water. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Dangerously explosive Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Do not attempt to sweep up dry material Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius ot 5000 feet TRIS-(1 -AZIRIDINYL) PHOSPHINE OXIDE 4935520 CORROSIVE MATERIAL. BASIC, POISONOUS UN2501 Tris-(l-aziridinyl) phosphine oxide is a colorless crystalline solid. It is toxic by ingestion and skin absorption. It is soluble in water. It is corrosive to metals and tissue. Toxic oxides of nitrogen are produced during com bustion of this matenal. If material on fire or Involved In fire Do not extinguish fire uniess flow can be stopped Use water in flooding quantities as log Cool all affected containers with flooding quantities of water 514 MCI; OOQo Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing TUNDRA COOLING UNITS, CONDENSERS, EQUALIZERS OR EXCHANGERS, OIL FIELD, GAS OR LIQUID, IRON OR STEEL, PIPE TYPE, CONTAINING NOT MORE THAN 0.0125 POUNDS OF ANHYDROUS AMMONIA PER FOOT OF PIPE (LENGTH) (ANHYQROUS AMMONIA) 4904879 NONFLAMMABLE GAS UN1005 Tundra cooling units consist of a sealed steel pipe containing anhy drous ammonia. Though ammonia is classed as a nonflammable gas, it will burn within certain vapor limits and it will increase the fire hazard in the presence of oil or other combustible material. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Materia) itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use water spray to absorb vapors If material not involved in fire Keep material out of water sources and sewers Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water TUNGSTEN HEXAFLOURIDE 4932387 CORROSIVE MATERIAL UN2196 Tungsten hexaflouride is a light yellow liquid. It is used in the man ufacture of other chemicals and in the manufacture of electronics. II has a melting point of 37 deg. F. and a boiling point of 67 deg. F. it is decomposed by water giving hydrofiouric acid, another corrosive ma terial. It is non-combustible. If material Involved In fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as tar a distance as possible If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain Dow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime April 1981 Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear fuil protective clothing TURPENTINE 4915314 COMBUSTIBLE LIQUID UN1299 Turpentine is a clear colorless liquid with a characteristic odor. It has a flash point between 100 and 199 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water TURPENTINE 4910313 FLAMMABLE LIQUID UNI 299 Turpentine is a clear colorless liquid with a characteristic odor. It has a flash point of less than 100 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes lo contain flow as necessary Attempt to stop leak If without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water TURPENTINE RESIDUE, LIQUID (COMBUSTIBLE 4915318 LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Turpentine residue, liquid is a colorless to dark colored liquid with a characteristic odor. It has a flash point between 100 and 199 deg. F. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water TURPENTINE RESIDUE, LIQUID (FLAMMABLE LIQUID, 4910318 N.O.S.) FLAMMABLE LIQUID UN1993 Turpentine residue, liquid is a colorless to dark colored liquid with a characteristic odor. It has a flash point of less than 100 deg. F. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical H material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water TURPENTINE SUBSTITUTE 4910315 FLAMMABLE LIQUID UN1300 Turpentine substitute is a clear colorless liquid with a characteristic odor. It has a flash point of less than 100 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. H material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in Hooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical Continued on next page April 1981 tics 00l744 3 515 If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water TURPENTINE SUBSTITUTE 4915315 COMBUSTIBLE LIQUID UN1300 Turpentine substitute is a clear colorless liquid with a characteristic odor. It has a flash point between 100 and 199 deg. F. It is lighter than water and insoluble in water. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water URANATES NOT IRRADIATED NOR REQUIRING 4926493 PROTECTIVE SHIELDING (RADIOACTIVE MATERIAL, N.O.S.) RADIOACTIVE MATERIAL NA9161 Uranates are usually various colored solids. They are insoluble in water. Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful whereas films may be damaged by radiation from relatively low concentrations. If material involved in fire Contact the local, state, or department of energy radiological re sponse team Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved In fire Contact the local, state, or department of energy radiological re sponse team Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Keep upwind Avoid breathing dusts, and fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment 516 ttCD 000] ?<44 Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation Keep unnecessary people out of incident area until area declared sale by radiological response team URANIUM BEARING ORE (RADIOACTIVE MATERIAL, 4926437 LOW SPECIFIC ACTIVITY (OR) LSA, N.O.S.) RADIOACTIVE MATERIAL UN2912 Uranium bearing oil is a black lustrous solid, it is insoluble in water. Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful, whereas film may be damaged by radiation from relatively low concentrations. If material involved in fire Contact the local, state, or department of energy radiological re sponse team Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved In fire Contact the local, state, or department of energy radiological re sponse team Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Keep upwind Avoid breathing fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water URANIUM HEXAFLUORIDE FISSILE CLASS I 4929490 (CONTAINING MORE THAN 0.7% U-235) (URANIUM FLUORIDES, NOT IRRADIATED NOR REQUIRING PROTECTIVE SHIELDING) RADIOACTIVE MATERIAL NA9173 Uranium hexafluoride, fissile is a colorless volatile crystalline solid. It reacts with water forming hydrofluoric acid, a corrosive material. It also reacts with most metals. Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful whereas films may be damaged by radiation from relatively low concentrations. Fissile radioactive materials are uranium 233, uranium 235, plutonium 236, plutonium 239. or plutonium 241. In addition to the radiation hazards presented by most radioactive materials, fissile materials, if improperly handled, may be critical. This means that if too large quantities of these materials are permitted in one place a very rapid nuclear reaction can occur. This would not be explosive, but large amounts of radiation would be emitted suddenly and might injure nearby personnel. In case of trou ble with these shipments ail unauthorized persons should be kept as far away as possible until qualified people with proper equipment can be obtained from the local or state radiological response team, the de partment of energy, or the shipper. If material on fire or involved In fire Contact the local, state, or department of energy radiological re sponse team Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burr or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible April 1981 if material not on fire and not involved in fire Contact the local, state, or department of energy radiological re sponse team Do not use water on material itself Use water spray to knock-down vapors Do not apply water to point of leak In tank car or container Keep material out of water sources and sewers Personnel protection Keep upwind Avoid breathing dusts, and fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted Hie body with copious amounts of water or soap and water Evacuation Keep unnecessary people out of incident area until area declared safe by radiological response team URANIUM HEXAFLUORIDE, FISSILE CLASS II 4928490 (CONTAINING MORE THAN 0.7% U-235) (URANIUM FLUORIDES, NOT IRRADIATED NOR REQUIRING PROTECTIVE SHIELDING) RADIOACTIVE MATERIALS NA0173 Uranium hexafluoride, fissile is a colorless volatile crystalline solid. It reacts with water forming hydrofluoric acid, a corrosive material. It also reacts with most metals. Radioactive materials emit certain rays that may be hazardous. These rays can be detected onty by instruments. Exposure of humans to intense radiation may be hamful whereas films may be damaged by radiation from relatively low concentrations. Fissile radioactive materials are uranium 233. uranium 235, plutonium 238, plutonium 239. or plutonium 241. In addition to the radiation hazards presented by most radioactive materials, fissile materials, if improperly handled, may be critical. This means that if too large quantities of these materials are permitted in one place a very rapid nuclear reaction can occur. This would not be explosive, but large amounts of radiation would be emitted suddenly and might injure nearby personnel. In case of trou ble with these shipments all unauthorized persons should be kept as tar away as possible until qualified people with proper equipment can be obtained from the local or state radiological response team, the de partment of energy, or the shipper. If material on fire or Involved in fire Contact the local, state, or department of energy radiological re sponse team Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved In fire Contact the local, state, or department oi energy radiological re sponse team Do not use water on matehal itself Use water spray to knock-down vapors Do not apply water to point oi leak in tank car or container Keep material out of water sources and sewers Personnel protection Keep upwind Avoid breathing dusts, and fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation Keep unnecessary people out of incident area until area declared safe by radiological response team April 1981 URANIUM HEXAFLUORIDE, FISSILE CLASS III (CONTAINING MORE THAN 0.7% U-235) 4927490 (URANIUM FLUORIDES, NOT IRRADIATED NOR REQUIRING PROTECTIVE SHIELDING) RADIOACTIVE MATERIAL NA9173 Uranium hexafluoride, fissile is a colorless volatile crystalline solid. It reacts with water forming hydrofluoric acid, a corrosive material. It also reacts with most metals. Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful whereas films may be damaged by radiation from relatively low concentrations. Fissile radioactive materials are uranium 233, uranium 235, plutonium 238, plutonium 239, or plutonium 241. In addition to the radiation hazards presented by most radioactive materials, fissile materials, if improperly handled, may be critical. This means that if too large quantities of these materials are permitted in one place a very rapid nuclear reaction can occur. This would not be explosive, but large amounts of radiation would be emitted suddenly and might injure nearby personnel. In case of trou ble with these shipments all unauthorized persons should be kept as far away as possible until qualified people with proper equipment can be obtained from the local or state radiological response team, the de partment of energy, or the shipper. H material on fire or Involved In lire Contact the local, state, or department of energy radiological re sponse team Extinguish tire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Cool all affected containers with Hooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved In fire Contact the local, state, or department of energy radiological re sponse team Do not use water on material itself Use water spray to knock-down vapors Do not apply water to point of leak in tank car or container Keep material out of water sources and sewers Personnel protection Keep upwind Avoid breathing dusts, and fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation Keep unnecessary people out of incident area until area declared safe by radiological response team URANIUM HEXAFLUORIDE, LOW SPECIFIC ACTIVITY 4926490 (CONTAINING 0.7% OR LESS U-235) (URANIUM FLUORIDES, NOT IRRADIATED NOR REQUIRING PROTECTIVE SHIELDING) RADIOACTIVE MATERIAL NA9174 Uranium hexafluoride, low specific activity is a colorless volatile crys talline solid. It reacts with water forming hydrofluoric acid, a corrosive material. It also reacts with most metals. Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful whereas films may be damaged by radiation from relatively low concentrations. Continued on next page 517 MCD 000017445 If material on fire or involved in fire Contact the local, state, or department of energy radiological re sponse team Do not use water on material itself if large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Use foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved in fire Contact the local, state, or department of energy radiological re sponse team Do not use water on material itself Use water spray to knock-down vapors Do not apply water to point of leak in tank car or container Keep material out of water sources and sewers Personnel protection Keep upwind Avoid breathing dusts, and fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation Keep unnecessary people out of incident area until area declared safe by radiological response team URANIUM METAL BARS, RODS OR SHAPES, NOT 4926186 IRRADIATED, NOR REQUIRING PROT SHIELDING (URANIUM METAL PYROFORIC) RADIOACTIVE MATERIAL, PYROFORIC NA9175 Uranium metal bars, rods, or shapes are heavy silvery to grey colored metal. It is about twice as heavy as lead. The powdered metal is spon taneously flammable in air. Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful whereas films may be damaged by radiation from relatively low concentrations. If material on fire or Involved In fire Contact the local, state, or department of energy radiological re sponse team Do not use water Use graphite, soda ash, powdered sodium chloride, or suitable dry powder If material not on fire and not Involved in fire Contact the local, state, or department of energy radiological re sponse team Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Do not attempt to sweep up dry material Personnel protection Keep upwind Avoid breathing dusts, and fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation Keep unnecessary people out of incident area until area declared safe by radiological response team 518 URANIUM METAL BILLETS, INGOTS, PIGS OR SLABS 4926185 NOT IRRADIATED NOR REQUIRING PROTECTIVE SHIELDING (URANIUM METAL, PYROFORIC) RADIOACTIVE MATERIAL, PYROFORIC NA9175 Uranium metal billets, ingots, pigs or slabs are large pieces of the heavily silvery to greyish metal, it is about twice as heavy as lead. The powdered metal is spontaneously flammable. Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful whereas films may be damaged by radiation from relatively low concentrations. If material on fire or involved In fire Contact the local, state, or department of energy radiological re sponse team Do not use water Use graphite, soda ash, powdered sodium chloride, or suitable dry powder If material not on fire and not involved in fire Contact the local, state, or department of energy radiological re sponse team Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Do not attempt to sweep up dry material Personnel protection Keep upwind Avoid breathing dusts, and fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation Keep unnecessary people out of incident area until area declared safe by radiological response team URANIUM METAL SCRAP NOT IRRADIATED NOR 4926167 REQUIRING PROTECTIVE SHIELDING (URANIUM METAL PYROFORIC) RADIOACTIVE MATERIAL, PYROFORIC NA9175 Uranium metal scrap is the waste product from various machining operations on the metal. It is a heavy silvery to greyish colored metal. It is about twice as heavy as lead. Very thin or small pieces are easily ignited and bum with an intense flame. The powder is spontaneously flammable in air. Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful whereas films may be damaged by radiation from relatively low concentrations. If material on fire or Involved in fire Contact the local, state, or department of energy radiological re sponse team Do not use water Use graphite, soda ash, powdered sodium chloride, or suitable dry powder If materiel not on fire and not Involved In fire Contact the local, state, or department of energy radiological re sponse team Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Do not attempt to sweep up dry material April 1981 000017446 MCD Personnel protection Keep upwind Avoid breathing dusts, and fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation Keep unnecessary people out of incident area until area declared safe by radiological response team Personnel protection Keep upwind Avoid breathing dusts, and fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation Keep unnecessary people out of incident area until area declared safe by radiological response team URANIUM OXIDES, NOT IRRADIATED NOR 4926491 REQUIRING PROTECTIVE SHIELDING (RADIOACTIVE MATERIAL, N.O.S.) RADIOACTIVE MATERIAL NA9161 Uranium oxides are various colored powdered solids. They are in soluble in water. Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful whereas films may be damaged by radiation from relatively low concentrations. It material Involved in fire Contact the local, state, or department of energy radiological re sponse team Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) If material not Involved In fire Contact the local, state, or department of energy radiological re sponse team Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Keep upwind Avoid breathing dusts Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation Keep unnecessary people out of incident area until area declared sate by radiological response team URANIUM SALTS. NOT IRRADIATED NOR REQUIRING 4926492 PROTECTIVE SHIELDING (RADIOACTIVE MATERIAL, N.O.S.) RADIOACTIVE MATERIAL NA9181 Uranium salts are various colored crystalline or powdered materials. They are generally insoluble in water. Radioactive materials emit certain rays that may be hazardous- These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful whereas films may be damaged by radiation from relatively low concentrations. If material Involved in fire Contact the local, state, or department of energy radiological re sponse team Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) If material not Involved In fire Contact the local, state, or department of energy radiological re sponse team Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers April 1981 MOD 000017447 URANYL ACETATE 4926425 RADIOACTIVE MATERIAL NA9180 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Uranyl acetate is a yellow crystalline solid. It is soluble in water. Radioactive materials emit certain rays that may be hazardous. These rays can. be detected only by instruments. Exposure of humans to intense radiation may be harmful whereas film may be damaged by radiation from relatively low concentrations. If material on fire or involved In fire Contact the local, state, or department of energy radiological re sponse team Extinguish fire using agent suitable for type of surrounding tire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved In fire Contact the local, state, or department of energy radiological re sponse team Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing vapors Avoid breathing fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do rot handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Do not approach area of incident until measurements with suitable instruments have shown that it is safe to do so Evacuation Keep unnecessary people out of incident area until area declared safe by radiological response team URANYL NITRATE HEXAHYDRATE SOLUTION 4926325 RADIOACTIVE MATERIAL. OXIDIZING NA9176 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Uranyl nitrate hexahydrate solution is the solution in water of the yellow crystalline solid. Though the solution is noncombustible, it will accelerate the burning of combustible material if the solution is concen trated or the water should evaporate. If large quantities are involved in the fire or the combustible material is finely divided, an explosion may result. Toxic oxides of nitrogen are produced in fires invotving this material. Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful whereas films may be damaged by radiation from relatively low concentrations. Continued on next page 519 If material on fire or involved in fire Contact the local, state, or department of energy radiological re sponse team Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved in fire Contact the local, state, or department of energy radiological re sponse team Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Avoid breathing dusts, and fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet Keep unnecessary people out of incident area until area declared safe by radiological response team Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash, cement powder, sawdust, or com mercial sorbents Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates URANYL NITRATE, SOLID 4926320 RADIOACTIVE MATERIAL, OXIDIZING NA9177 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Uranyl nitrate is a yellow crystalline solid. It is soluble in water. Though the material is noncombustible, it will accelerate the burning of com bustible materials. If large quantities are involved in the fire or the com bustible material is finely divided an explosion may result. Toxic oxides of nitrogen are produced in fires involving this maierial. Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful whereas films may be damaged by radiation from relatively low concentrations. If material on fire or Involved In fire Contact the local, state, or department of energy radiological re sponse team Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Contact the local, state, or department of energy radiological re sponse team Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Keep upwind Avoid breathing dusts, and fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus 520 HOD 000017448 Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet Keep unnecessary people out of incident area until area declared safe by radiological response team Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates URANYL NITRATE, SOLID FISSILE CLASS I 4929320 RADIOACTIVE MATERIAL, OXIDIZING NA9177 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Uranyl nitrate is a yellow crystalline solid. It is soluble in water. Though the material is noncombustible, it will accelerate the burning of com bustible materials. If large quantities are involved in the fire or the com bustible material is finely divided an explosion may result. Toxic oxides of nitrogen are produced in fires involving this material. Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful whereas films may be damaged by radiation from relatively low concentrations. Fissile radioactive materials are uranium 233, uranium 235, plutonium 238, plutonium 239, or plutonium 241. In addition to the radiation hazards presented by most radioactive materials, fissile materials, if improperly handled, may be critical. This means that if too large quantities of these materials are permitted in one place a very rapid nuclear reaction can occur. This would not be explosive, but large amounts of radiation would be emitted suddenly and might injure nearby personnel. In case of trou ble with these shipments all unauthorized persons should be kept as far away as possible until qualified people with proper equipment can be obtained from the local or state radiological response team, the de partment of energy, or the shipper, tf material on fire or Involved in fire Contact the local, state, or department of energy radiological re sponse team Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible ff materiel not on fire and not involved In fire Contact the local, state, or department of energy radiological re sponse team Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Keep upwind Avoid breathing dusts, and fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet Keep unnecessary people out of incident area until area declared safe by radiological response team Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water April 1981 Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates URANYL NITRATE, SOLID FISSILE CLASS II 4928320 RADIOACTIVE MATERIAL, OXIDIZING NA9177 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-S000/2270) Uranyl nitrate is a yellow crystalline solid. It is soluble in water. Though the material is noncombustible, it will accelerate the burning of com bustible materials. If large quantities are involved in the fire or the com bustible material is finely divided an explosion may result. Toxic oxides of nitrogen are produced in fires involving this material. Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful whereas films may be damaged by radiation from relatively low concentrations. Fissile radioactive materials are uranium 233. uranium 235. plutonium 238, plutonium 239, or plutonium 241. In addition to the radiation hazards presented by most radioactive materials, fissile materials, if improperly handled, may be critical. This means that if too large quantities of these materials are permitted in one piace a very rapid nuclear reaction can occur. This would not be explosive, but large amounts of radiation would be emitted suddenly and might injure nearby personnel. In case of trou ble with these shipments all unauthorized persons should be kept as far away as possible until qualified people with proper equipment can be obtained from the local or state radiological response team, the de partment of energy, or the shipper. If material on fire or Involved In fire Contact the local, state, or department of energy radiological re sponse team Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Contact the local, state, or department of energy radiological re sponse team Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Keep upwind Avoid breathing dusts, and fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet Keep unnecessary people out of incident area until area declared safe by radiological response team Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates URANYL NITRATE, SOLID FISSILE CLASS III 4927320 RADIOACTIVE MATERIAL, OXIDIZING NA9177 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Uranyl nitrate is a yellow crystalline solid. It is soluble in water. Though the material is noncombustible, it will accelerate the burning of com bustible materials. If large quantities are involved in the fire or the com bustible material is finely divided an explosion may result. Toxic oxides of nitrogen are produced in fires involving this material. Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful whereas films may be damaged by radiation from relatively low concentrations. Fissile radioactive materials are uranium 233, uranium 235, plutonium 238, plutonium 239, or plutonium 241. In addition to the radiation hazards presented by most radioactive materials, fissile materials, if improperly handled, may be critical. This means that if too large quantities of these materials are permitted in one place a very rapid nuclear reaction can occur. This would not be explosive, but large amounts of radiation would be emitted suddenly and might injure nearby personnel. In case of trou ble with these shipments all unauthorized persons should be kept as far away as possible until qualified people with proper equipment can be obtained from the local or state radiological response team, the de partment of energy, or the shipper. If material on fire or involved In fire Contact the local, state, or department of energy radiological re sponse team Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire end not involved (n tire Contact the local, state, or department of energy radiological re sponse team Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Keep upwind Avoid breathing dusts, and fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet Keep unnecessary people out of incident area until area declared safe by radiological response team Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates UREA NITRATE, WET (WITH 10% OR MORE WATER) 4917170 FLAMMABLE SOUD UNI 357 Urea nitrate, wet is water slurry or sludge of colorless crystals. The dry material is a high explosive. Dry it is easily ignited and bums very vigorously. The wet material can burn though it may require some effort to ignite. It is slightly soluble in water. Toxic oxides of nitrogen are produced during combustion of this material. Continued on next page April 1981 mod 0l?449 521 If material on fire or involved In fire Dangerously explosive Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Do not attempt to sweep up dry material Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 5000 feet UREA PEROXIDE 4919595 ORGANIC PEROXIDE NA1511 Urea peroxide is a white crystalline solid, it is somewhat difficult to ignite and then tends to melt and only burn partway through the mass of material, it supports the burning of combustible materials, certain solvents, e.g. ethers, acetone, can leach hydrogen peroxide from urea peroxide and form exceedingly flammable solutions (more flammable than the solvent alone). Under prolonged exposure to fire or heat con tainers of the material can explode. If material on fire or involved in fire Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing vapors or dusts Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet VALERIC ACID 4931475 CORROSIVE MATERIAL, ACIDIC, COMBUSTIBLE NA1760 Valeric acid is a colorless liquid with an unpleasant odor. It is com bustible and has a flash point of 192 deg. F. It is slightly soluble in water. It is corrosive to metals and tissue. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors 522 MCT) Ol?45n If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing VALERYL CHLORIDE 4931750 CORROSIVE MATERIAL, ACIDIC, FLAMMABLE UN2502 Valeryl chloride is a colorless fuming liquid with a pungent odor. It is flammable and has a flash point of 74 deg. F. Its fumes are irritating to the eyes and mucous membranes. It is decomposed by water to hy drochloric and valeric acids, corrosive materials, with release of heat. It is corrosive to metals and tissue. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use dry chemical or carbon dioxide Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing VANADIUM OXYTRICHLORIDE 4932388 CORROSIVE MATERIAL, ACIDIC UN2443 Vanadium oxytrichioride is a lemon yellow liquid. It is decomposed by water to give hydrochloric acid with evolution of heat. It is corrosive to metals and tissue. If material involved in (ire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible April 1981 If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing VANADIUM OXYTRICHLORIDE AND TITANIUM 4932389 TETRACHLORIDE MIXTURE CORROSIVE MATERIAL NA2443 Vanadium oxytrichlonde and titanium tetrachloride mixture is a col orless to lemon yeliow fuming liquid with a pungent odor. It is used to make catalysts for chemical manufacture. It is decomposed by water giving off hydrochloric acid, another corrosive material, it is corrosive to metals and tissue. If material Involved in fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing VANADIUM PENTOXIDE 4963385 ORM-E UN2862 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-1000/454) Vanadium pentoxide is a yellow to red crystalline solid. It is used as a catalyst in chemical processes, a pigment in ceramics, in the manu facture of other vanadium compounds, and for many other uses. It is slightly soluble in water. It is non-combustible. H material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles April 1981 74.5^ OOOO^ VlCv Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Allow to aerate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates VANADIUM TETRACHLORIDE 4932390 CORROSIVE MATERIAL, ACIDIC UN2444 Vanadium tetrachloride is a red liquid with a pungent odor. It is de composed by water to form hydrochloric acid with the evolution of heat. It is corrosive to metals and tissue. If material Involved In fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing VANADYL SULFATE 4963384 ORM-E NA9152 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Vanadyl sulfate is a blue crystalline solid. It is used as a pigment in glasses and ceramics, and in chemical processes. It is soluble in water. It is non-combustible. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area lo contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Continued on next page 523 Environmental considerations--water spill Add calcium hypochlorite Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Allow to aerate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates VERMOUTH IN TANK CARS (ALCOHOLIC BEVERAGE) 4915311 COMBUSTIBLE LIQUID UN1170 Vermouth is a variable colored liquid having the odor characteristic of fermented liquors. It has a Hash point between 100 and 199 deg. F. It is soluble in water. Its vaoors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain fiow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water VERMOUTH IN TANK CARS (ALCOHOLIC BEVERAGES) 4910344 FLAMMABLE LIQUID UN1170 Vermouth is a variable colored liquid having the odor characteristic of fermented liquors. It has a Hash point between 73 and 100 deg. F. It is soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources o< ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 524 VERMOUTH, OTHER THAN IN TANK CARS 4915310 (ALCOHOLIC BEVERAGE) COMBUSTIBLE LIQUID UN1170 Vermouth is a variable colored liquid having the odor characteristic of fermented liquors. It has a flash point between 100 and 199 deg. F. It is soluble in water, tts vapors are heavier than air. tf material on fire or involved in fire Do not extinguish fire uniess flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical It material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water VERMOUTH, OTHER THAN IN TANK CARS 4910343 (ALCOHOLIC BEVERAGE) FLAMMABLE LIQUID UN1170 Vermouth is a variable colored liquid having the odor characteristic of fermented liquors. It has a flash point between 73 and 100 deg. F. It is soluble in water. Its vapors are heavier than air. tf material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water VERY SIGNAL CARTRIDGE 4903640 CLASS C EXPLOSIVE Very signal cartridge is of the configuration of fixed ammunition which consists of a cartridge case containing a propelling charge and a primer fixed to the base, and assembled as a unit with a projectile containing a pyrotechnic composition designed to produce either a flare or smoke upon functioning. if material on fire or involved In fire Flood with water Apply water from as far a distance as possible April 1981 MCD 000017452 tf material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet VINYL ACETATE 4907270 FLAMMABLE LIQUID UN1301 POLYMERIZABLE ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Vinyl acetate is a clear colorless liquid. It is used to make adhesives, paints, and plastics, it has a flash point of 18 deg. F. Its vapors are irritating to the eyes and respiratory system. If it is subjected to heat or becomes contaminated, it is subject to polymerization. If the polymeri zation takes place inside a container, the container is subject to violent rupture, ft is lighter than water and slightly soluble in water. Its vapors are heavier than air. It weighs 7.6 pounds per gallon. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash, cement powder, sawdust, or com mercial sorbents Apply "universal" gelling agent to immobilize spill Apply fluorocarbon-water foam to diminish vapor and fire hazard Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e.g. detergent, soaps, alcohols) lo com press and thicken spilled material Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Remove (rapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors April 1981 VINYL CHLORIDE 4905792 FLAMMABLE GAS UN1086 Vinyl chloride is a colorless gas with a sweet odor. It is used to make plastics and adhesives, and to make other chemicals. It is shipped as a liquefied gas under its vapor pressure. Contact with the liquid can cause frostbite. It is easily ignited, its vapors are heavier man air and a flame can flash back to the source of leak very easily. This leak may be either a liquid or vapor leak. It can asphyxiate by the displacement of air. Under fire conditions the cylinders or tank cars may violently rupture and rocket. Prolonged exposure of the cylinders or tank cars to heat or fire may cause the material to polymerize with possible container rupture. This material is a cancer suspect agent on long term exposure to low concentrations. However, this effect has not been demonstrated for single exposures to high concentrations of the material, tf material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered VINYL ETHYL ETHER, INHIBITED 4907275 FLAMMABLE LIQUID UN1302 POLYMERIZABLE Vinyl ethyl ether, inhibited is a clear colorless liquid with an ether-like odor. It has a flash point of less than -50 deg. F. If the material is subject to heat for prolonged periods or becomes contaminated, it is subject to polymerization with evolution of heat. If the polymerization takes place inside a container, the container may violently rupture. The material is lighter than water and slightly soluble in water its vapors are heavier than air. tf material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "atcohor foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Continued on next page 525 MCD OOOOI74 53 Evacuation It fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered VINYL FLUORIDE, INHIBITED 4905793 FLAMMABLE GAS UN1660 Vinyl fluoride, inhibited is a colorless gas with a faint ethereal odor. It is shipped as a liquefied gas under its vapor pressure. Contact with the liquid can cause frostbite. It is easily ignited, its vapors are heavier than air and a flame can flash back to the source of leak very easily. This leak can be either a liquid or vapor leak, it can asphyxiate by the displacement of air. Under fire conditions the cylinders or tank cars may violently rupture and rocket. Prolonged exposure of the cylinders or tank cars to heal or fire may cause the material to polymerize with possible container rupture. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered VINYL ISOBUTYL ETHER 4907267 FLAMMABLE LIQUID UN1304 POLYMERIZABLE Vinyl isobutyl ether is a clear colorless liquid. It has a flash point of 15 deg. F. If contaminated or subjected to heat, it may polymerize. If the polymerization take place inside a container, the container is subject to violent rupture. It is fighter than water and very slightly soluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use ``alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 526 OOoo 1?454 Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered VINYL METHYL ETHER 4905795 FLAMMABLE GAS UN1067 Vinyl methyl ether is a colorless gas with a sweet odor. It is shipped as a liquefied gas under its vapor pressure. Contact with the liquid can cause frostbite, ft is easily ignited, its vapors are heavier than air and a flame can flash back to the source of leak very easily. The leak can either be a liquid or vapor leak. It can asphyxiate by the displacement of air. Under fire conditions the cylinders or tankcars may violently rup ture and rocket. Prolonged exposure of the cylinders or tank cars to heat or fire may cause the material to polymerize with possible container rupture. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Coof all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered VINYL TRICHLOROSILANE 4907685 FLAMMABLE LIQUID, CORROSIVE, ACIDIC UN130S Vinyl trichiorosilane is a colorless to pale yellow fuming liquid with a pungent odor, ft has a flash point of 16 deg. F. Vapor and liquid can cause burns. It is heavier than water and is decomposed by water to form hydrochloric acid, a corrosive material. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use "alcohol" foam, carbon dioxide or dry chemical Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime April 1981 Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation (f (ire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered VINYLtDENE CHLORIDE, INHIBITED 4907280 FLAMMABLE LIQUID UNI 303 POLYMERIZABLE ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Vinylidine chloride is a clear colorless liquid with a chloroform-like odor. It has a flash point of 0 deg. F. and a boiling point of 99 deg. F. If subject to heat, it may polymerize. If the polymerization takes place in a container the container may violently rupture. Vinylidine chloride is heavier than water and insoluble in water. Its vapors are heavier than air. It weighs 10.1 pounds per gallon. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop teak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation II fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feel If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash, cement powder, sawdust, or com mercial sorbents Apply fluorocarbon-water foam to diminish vapor and fire hazard Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Combustion products include corrosive or toxic vapors April 1981 VINYLTOLUENE, INHIBITED (COMBUSTIBLE LIQUID, 4912275 N.O.S.) COMBUSTIBLE LIQUID NA1993 POLYMERIZABLE Vinyltoluene, inhibited is a clear colorless liquid with an aromatic odor. It has a flash point of 140 deg. F. if it is subject to heat for prolonged periods or becomes contaminated it is subject to polymerization with release of heat. If the polymerization takes place inside a container, the container is subject to violent rupture. The material is lighter than water and insoluble in water. The vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet WALLPAPER REMOVER, LIQUID (COMBUSTIBLE 4915480 LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Wallpaper remover, liquid is a material containing a solvent having a closed cup flash point between 100 and 199 deg. F. The hazard of this material is combustibility. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water WALLPAPER REMOVER, LIQUID (FLAMMABLE 4910480 LIQUID, N.O.S.) FLAMMABLE LIQUID UN1993 Wallpaper remover, liquid is a material containing a solvent having a dosed cup flash point of less than 100 deg. F. The hazard of this material is flammability. Continued on next page 527 000017 4555 MCD If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water WASTE ETCHANT SOLUTION. SUITABLE ONLY FOR 4936595 RECLAMATION OF METALLIC CONTENT (CORROSIVE LIQUID, N.O.S.) CORROSIVE MATERIAL UN1760 Waste etchant solution, suitable only for reclamation of metallic con tent is a variable colored liquid having the property of being corrosive to metals and/or tissue. It is soluble in water. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing WASTE LIQUOR, CONSISTING OF NOT LESS THAN 4915321 50 PERCENT BY WEIGHT OF WATER, RESULTING FROM SULPHATE OR SODA PULPING PROCESS (COMBUSTIBLE LIQUID. N.O.S.) COMBUSTIBLE LIQUID NA1993 Waste liquor is a clear colorless to milky tan colored liquid with an offensiveoclor.it has a flash point between 100 an 199 deg. F. It is about the same weight as water and soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'" foam, carbon dioxide or dry chemical 528 4&0 00001< ft material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water WASTE LIQUOR, CONSISTING OF NOT LESS THAN 4930221 50 PERCENT BY WEIGHT OF WATER, RESULTING FROM SULPHATE OR SODA PULPING PROCESS (CORROSIVE LIQUID, N.O.S.) CORROSIVE MATERIAL UN1760 Waste liquor is a clear colorless to milky tan colored liquid with an offensive odor. It is corrosive to metals and tissue. It will burn though it may require some effort to ignite. It is about the same weight as water and soluble in water. Us vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes (o contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing WASTE LIQUOR, CONSISTING OF NOT LESS THAN 4910321 SO PERCENT BY WEIGHT OF WATER, RESULTING FROM SULPHATE OR SODA PULPING PROCESS (FLAMMABLE LIQUID, N.O.S.) FLAMMABLE LIQUID UNI 993 Waste liquor is a clear colorless to milky tan colored liquid with an offensive odor.it has a flash point of less than 100 deg. F. It is about the same weight as water and soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors April 1981 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment WASTE PAPER PULP, WET (WASTE PAPER, WET) 4917470 FLAMMABLE SOLID NA1325 Waste paper pulp, wet is finely shredded waste paper that is water wet. It is liable to spontaneous heating and ignition. It must be shipped in air tight metal or metal lined containers. If material on fire or Involved in fire Flood with water If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away WASTE WOOL, WET 4917372 FLAMMABLE SOLID UN1387 Waste wool, wet is scrap wool materials that are water wet. It is liable to spontaneous heating and ignition. It must be shipped in air-tight metal or metal lined containers. If material on fire or involved in fire Flood with water if material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away WASTE PAPER, WET 4917370 FLAMMABLE SOLID NA1325 Waste paper, wet is scrap paper that is water wet. It is subject to decomposition and spontaneous ignition. It must be shipped in air tight metal or metal lined containers. If material on fire or involved in fire Flood with water If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away WASTE PHOSPHATE FILTER CAKE SLUDGE, 4930249 CONTAINING NOT MORE THAN 50% P205 (PHOSPHORIC ACID) CORROSIVE MATERIAL, ACIDIC UN1605 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Waste phosphate filter cake sludge is the byproduct of making phos phoric acid from phosphate rock, it is partially soluble in water with release of heat. It is corrosive to metals and to tissue. Phosphoric acid weighs 15.6 pounds per gallon. If material involved in fire Extinguish fire using agent suitable lor type oi surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as tog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate April 1981 MCD 000017457 WATCH DIAL ENAMEL (RADIOACTIVE MATERIAL, 4927480 N.O.S. FISSILE CLASS III) RADIOACTIVE MATERIAL NA9181 Watch dial enamel is thick liquid, usually pale green in color. It will burn though it may require some effort to ignite. Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful whereas films may be damaged by radiation from relatively low concentrations. Fissile radioactive materials are uranium 233, uranium 235, plutonium 238, plutonium 239, or plutonium 241. In addition to the radiation hazards presented by most radioactive materials, fissile materials, if improperly handled, may be critical. This means that if too large quantities of these materials are permitted in one place a very rapid nuclear reaction can occur. This would not be explosive, but large amounts of radiation would be emitted suddenly and might injure nearby personnel. In case of trou ble with these shipments all unauthorized persons should be kept as far away as possible until qualified people with proper equipment can be obtained from the local or state radiological response team, the de partment of energy, or the shipper. If material on fire or involved In fire Contact the local, state, or department of energy radiological re sponse team Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Contact the local, state, or department of energy radiological re sponse team Keep sparks, flames, and other sources of ignition away Keep material out ot water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Avoid breathing dusts, and fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation Keep unnecessary people out of incident area until area declared safe by radiological response team 529 WATCH DIAL ENAMEL (RADIOACTIVE MATERIAL, 4926480 N.O.S.) RADIOACTIVE MATERIAL NA9181 Watch dial enamel is thick liquid, usually pale green in color. It will burn though it may require some effort to ignite. Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful whereas fiims may be damaged by radiation from relatively low concentrations. If material on fire or involved In fire Contact the local, state, or department of energy radiological re sponse team Do not extinguish tire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Contact the local, state, or department of energy radiological re sponse team Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Avoid breathing dusts, and fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation Keep unnecessary people out of incident area until area declared safe by radiological response team WATCH DIAL ENAMEL (RADIOACTIVE MATERIAL, 4929480 N.O.S., FISSILE CLASS I) RADIOACTIVE MATERIAL NA9181 Watch dial enamel is thick liquid, usually pale green in color. It will burn though it may require some effort to ignite. Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful whereas films may be damaged by radiation from relatively low concentrations. Fissile radioactive materials are uranium 233, uranium 235, plutonium 238, plutonium 239. or plutonium 241. In addition to the radiation hazards presented by most radioactive materials, fissile materials, it improperly handled, may be critical. This means that if too large quantities of these materials are permitted in one place a very rapid nuclear reaction can occur. This would not be explosive, but large amounts of radiation would be emitted suddenly and might injure nearby personnel. In case of trou ble with these shipments all unauthorized persons should be kept as far away as possible until qualified people with proper equipment can be obtained from the local or state radiological response team, the de partment of energy, or the shipper. If material on fire or involved in fire Contact the local, state, or department of energy radiological re sponse team Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Contact the local, state, or department of energy radiological re sponse team Keep sparks, flames, and other sources of ignition away 530 Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Avoid breathing dusts, and fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation Keep unnecessary people out of incident area until area declared safe by radiological response team WATCH DIAL ENAMEL (RADIOACTIVE MATERIAL, 4928480 N.O.S., FISSILE CLASS II) RADIOACTIVE MATERIAL NA9181 Watch dial enamel is thick liquid, usually pale green In color. It will burn though It may require some effort to ignite. Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful whereas films may be damaged by radiation from relatively low concentrations. Fissile radioactive materials are uranium 233. uranium 235, plutonium 238. plutonium 239. or plutonium 241. In addition to the radiation hazards presented by most radioactive materials, fissile materials, if improperly handled, may be critical. This means that if too large quantities of these materials are permitted in one place a very rapid nuclear reaction can occur. This would not be explosive, but large amounts of radiation would be emitted suddenly and might injure nearby personnel. In case of trou ble with these shipments all unauthorized persons snould be kept as far away as possible until qualified people with proper equipment can be obtained from the local or state radiological response team, the de partment of energy, or the shipper, ff material on fire or involved in fire Contact the local, state, or department of energy radiological re sponse team Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Contact the local, state, or department of energy radiological re sponse team Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Avoid breathing dusts, and fumes from burning material Wear full protective clcthing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation Keep unnecessary people out of incident area until area declared safe by radiological response team WATER PUMP SYSTEM CHARGED WITH 4904B70 COMPRESSED AIR OR NITROGEN NONFLAMMABLE GAS NA1956 Water pump system tank charged with compressed air or nitrogen consists of a metal tank with a flexible bladder inside that contains the air or nitrogen. It is used to maintain water pressure. April 1961 MCU aoi7458 If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Personnel protection Wear protective gloves and goggles Do not handle broken packages without protective equipment WATER REACTIVE SOLID, N.O.S. 4916475 FLAMMABLE SOLID UN2B13 WATER REACTIVE Water reactive solid, n.o.s. is the proper shipping name for those matenals not specifically named in the list of hazardous materials having the property ot reacting with water and giving off a flammable gas. This flammable gas will usually ignite from the heat of the reaction. Try to ascertain the exact material. If material on fire or Involved in fire Do not use water Use graphite, soda ash. powdered sodium chloride, or suitable dry powder If material not on fire and not involved in fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Do not attempt to sweep up dry material Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Avoid breathing fumes from burning material WATER TREATMENT COMPOUND, LIQUID 4936580 CORROSIVE MATERIAL NA1760 Water treatment compound liquid is a variable colored liquid. It is soluble in water. It is corrosive to metals and tissue. If material on fire or Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing WAX, LIQUID 4915387 COMBUSTIBLE LIQUID NA1993 Wax liquid is a clear colorless to light cream colored liquid. It has a flash point between 100 and 199 deg. F. It is generally lighter than water and partially soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog April 1981 Solid streams of water may be Ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water WEED KILLING COMPOUND AND CHLORDANE 4960125 MIXTURE (HAZARDOUS SUBSTANCE, LIQUID (OR) SOLID) ORM-A NA9188 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Weed killing compound and chlordane mixture is the colorless liquid chlordane absorbed on a dry carrier or dissolved in a liquid carrier. It may or may not be emulsifiabie in water. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or loamed concrete Absorb bulk liquid with fly ash, cement pqwder, sawdust, or com mercial sorbents Apply "universal" gelling agent to immobilize spill Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilied amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Combustion products include corrosive or toxic vapors WHITE ACID (AMMONIUM BIFLUORIDE AND 4930270 HYDROCHLORIC ACID MIXTURE) CORROSIVE MATERIAL NA1760 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) White acid is a colorless fuming liquid with a pungent odor. It is soluble in water with release of heat. It is corrosive to metals and tissue. Contact with the fumes or short contact with small quantities of the material can cause severe painful burns. It weighs 11.0 pounds per gallon. Continued on next page 531 MCD 000017459 If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts oi water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment WINE, CHAMPAGNE OR VERMOUTH, SPOILED 4915308 (ALCOHOLIC BEVERAGE) COMBUSTIBLE LIQUID UN1170 Wine, champange or vermouth, spioled is a variable colored liquid having the odor characteristic of fermented liquors to that of spoiled food. It has a flash point between 100 and 199 deg. F. It is soluble in water. Its vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 532 WINE, CHAMPAGNE OR VERMOUTH, SPOILED 4910341 (ALCOHOLIC BEVERAGE) FLAMMABLE LIQUID UN1170 Wine, champange or vermouth, spoiled is a variable colored liquid having the odor characteristic of fermented liquors to that of spoiled food. It has a flash point between 73 and 100 deg. F. It is soluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water WINE, SPARKLING, OTHER THAN CHAMPAGNE 4915309 (ALCOHOLIC BEVERAGE) COMBUSTIBLE LIQUID UN1170 Wine, sparkling, other than champagne is a variable colored bubbling liquid having the odor characteristic of fermented liquors. It has a flash point between 100 and 199 deg. F. It is soluble in water. Its vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in Hooding quantities as fog Solid streams of water may be ineffective Coot all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water WINE, SPARKLING, OTHER THAN CHAMPANGE 4910342 (ALCOHOLIC BEVERAGE) FLAMMABLE LIQUID UN1170 Wine, sparkling, other than champange is a variable colored bubbling liquid having the odor characteristic of fermented liquors, it has a flash point between 73 and 100 deg. F. It is soluble in water. Its vapors are heavier than air. April 1981 if material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts ot water or soap and water WINES, NEC, IN TANK CARS (ALCOHOLIC 4915306 BEVERAGE) COMBUSTIBLE LIQUID UN1170 Wines, nec, are variable colored liquids having the characteristic odor of fermented liquors. They have a flash point between 100 and 200 deg. F. They are soluble in water and their vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water WINES, NEC, IN TANK CARS (ALCOHOLIC 4910306 BEVERAGE) FLAMMABLE LIQUID UN1170 Wines, nec are various colored liquids having the characteristic odor of fermented liquors. They have a flash point between 73 and 100 deg. F. They are soluble in water and their vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use `alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary April 1981 Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water WINES, NEC, OTHER THAN IN TANK CARS 4910304 (ALCOHOLIC BEVERAGE) FLAMMABLE LIQUID UN1170 Wines, nec are various colored liquids having the characteristic odor of fermented liquors. They have a flash point between 73 and 100 deg. F. They are soluble in water and their vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water WINES, NEC, OTHER THAN IN TANK CARS 4915304 (ALCOHOLIC BEVERAGE) COMBUSTIBLE LIQUID UN1170 Wines, nec, are various colored liquids having the characteristic odor of fermented liquors. They have a flash point between 100 and 200 deg. F. They are soluble in water and their vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use ''alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 533 MCD 000017461 WOOD BLEACH (CORROSIVE LIQUID, N.O.S.) CORROSIVE MATERIAL 4936590 UN1760 Wood bleach is a variable colored liquid having the property of being corrosive to metals and/or tissue. It is water soluble. If material on fire or involved in fire Extinguish lire using agent suitable for type of surrounding fire (Material itsetf does not burn or bums with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, ftames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing WOOD CHARCOAL, IN TABLETS (CHARCOAL 4917309 BRIQUETTES) FLAMMABLE SOLID NA1361 Wood charcoal, in tablets is powdered or granular charcoal mixed with a tar or starch and water binder and pressed into tablets. The hazard is that of spontaneous heating if the charcoal briquettes are not properly cooled after manufacture. If material on fire or Involved In fire Remove burning material from load if safe and practicable to do so Use dry chemical or carbon dioxide Use water only if flooding quantities are available If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material dry If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water WOOD FURNITURE FINISHING OR REFINISHING KITS 4915395 (COMBUSTIBLE LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Wood furniture finishing or refinishing kits have small containers of flammable liquids. These liquids are variable colored with a paint-like odor. They have a flash point between 100 and 199 deg. F. They are generally lighter than water and insoluble in water. Their vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water WOOD FILLER 4910590 FLAMMABLE LIQUID UN1263 Wood filler is a paste-like material containing a flammable solvent. It has a flash point of less than 100 deg. F. The hazard is flammability. If material on fire or involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Use "alcohol'' foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary WOOD FILLER 4915290 COMBUSTIBLE LIQUID UN1263 Wood filler is a paste-iike material containing a combustible solvent. It has a flash point between 100 and 199 deg. F. The hazard is combustibility. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical 534 WOOD FURNITURE FINISHING OR REFINISHING KITS 4910395 (FLAMMABLE LIQUIDS, N.O.S FLAMMABLE LIQUID UNI 993 Wood furniture finishing or refinishing kits have small containers of flammable liquids. These liquids are variable colored with a paint-like odor. They have a flash point of less than 100 deg. F. They are generally lighter than water and insoluble in water. Their vapors are heavier than air. If material on lire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 MCD 000017462 WOOD PULP CHARCOAL, NOT ACTIVATED, 4917393 (FLAMMABLE SOLID, N.O.S.) FLAMMABLE SOLID UNI 325 Wood pulp charcoal, not activated is a black solid. The hazard in transportation is that of spontaneous heating if the material is not prop erly cooled after manufacture or if It should become wet. If material on fire or involved in fire Remove burning material from load if safe and practicable to do so Use dry chemical or carbon dioxide Use water only if flooding quantities are available If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material dry WOOD PULP, CHARRED, NOT ACTIVATED, 4917392 (FLAMMABLE SOLID, N.O.S.) FLAMMABLE SOLID UNI 325 Wood pulp, charred, not activated is a black solid. The hazard in transportation is that of spontaneous heating if the material is not prop erly cooled after manufacture or if it should become wet. If material on fire or involved In fire Flood with water If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away WOOD TURPENTINE (COMBUSTIBLE LIQUID, N.O.S.) 4915317 COMBUSTIBLE LIQUID NA1993 Wood turpentine is a clear colorless liquid with a characteristic odor. It has a flash point between 100 and 199 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water WOOD TURPENTINE (FLAMMABLE LIQUID, N.O.S.) 4910317 FLAMMABLE LIQUID UN1993 Wood turpentine is a clear colorless liquid with a characteristic odor. It has a flash point of less than 100 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors April 1981 MCD Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water WOOL WASTE, NEC, OR WOOL SWEEPINGS (WASTE 4917374 WOOL, WET) FLAMMABLE SOLID UN1387 Wool waste, nec, or wool sweepings is liable to spontaneous heating and ignition if water wet. It must be shipped in air tight metal or metal lined containers. If material on fire or Involved in fire Flood with water If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away XENON 4904595 NONFLAMMABLE GAS UN2036 Xenon is a colorless odorless gas. It is noncombustible, it is heavier than air. It can asphyxiate by the displacement of air. It may only be shipped in cylinders. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Wear protective gloves and goggles Do not handle broken packages without protective equipment XYLENE 4909350 FLAMMABLE LIQUID UN1307 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Xylene is a clear colorless liquid with a characteristic aromatic odor. It is used as a solvent for paints and adhesives, and to make other chemicals. It has a flash point of 81-90 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. It weighs 7.2 pounds per gallon. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 000017463 Continued on next pege 535 Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surlace flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash, cement powder, sawdust, or com mercial sorbents Apply 'universal'' gelling agent to Immobilize spill Apply fluorocarbon-water foam to diminish vapor and fire hazard Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e.g. detergent, soaps, alcohols) to com press and thicken spilled material inject "universal'' gelling agent to solidify encircled spill and increase effectiveness of booms If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors XYLENE (PARAXYLENE) 4909351 FLAMMABLE LIQUID UN1307 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Paraxylene is a clear colorless liquid with a characteristic aromatic odor. It solidifies at 66 deg. F. and has a flash point of 61 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. It weighs 7.2 pounds per gallon. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical if material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash, cement powder, sawdust, or com mercial sorbents Apply "universal'' gelling agent to immobilize spill Apply fluorocarbon-water foam to diminish vapor and fire hazard Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e.g. detergent, soaps, alcohols) to com press and thicken spilled material Inject "universal'' gelling agent to solidify encircled spill and increase effectiveness of booms If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors 536 XYLENOL 4941193 ORM-A UN2261 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Xylenol is a white crystaline solid. It is used in disinfectants, insecti cides, and to make other chemicals. It is combustible though it may take some effort to ignite. It is slightly soluble in water. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire end not Involved In fire Keep sparks, flames, and Other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors or dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or lire fighting water Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors XYLYL BROMIDE 4925260 IRRITATING MATERIAL UN1701 Xylyt bromide is in the form of colorless crystals or a clear colorless liquid. Its vapors are extremely irritating to the eyes and mucous membranes. If material on fire or involved in fire Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water Use water spray to absorb vapors If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Evacuation If material leaking (not on fire), downwind evacuation must be considered April 1981 0000 l'T 464 M CD ZINC ACETATE 4963387 ORM-E NA9153 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10007454) Zinc acetate is a white crystalline solid. It is used to preserve wood, to make other zinc compounds, as a food and feed additive, and for many other uses. It is soluble in water, it is non-combustible. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Add soda ash Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ZINC AMMONIUM CHLORIDE 4966386 ORM-E NA9154 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-SOOO/2270) Zinc ammonium chloride is a white crystalline solid. It is used in weld ing and soldering fluxes and in galvanizing steel. It is soluble in water. It is non-combustible, If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Add soda ash Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ZINC AMMONIUM NITRITE 4916756 OXIDIZER UNI 512 Zinc ammonium nitrite is a white powder. It is soluble in water. It is combustible and may be readily ignited by a spark or flame. If contam inated with combustible materials it is readily ignited. Prolonged ex po- sure to fire or heat may result in an explosion. Toxic oxides of nitrogen are produced during combustion of this material. ZINC ARSENATE 4923490 POISON B UN1712 Zinc arsenate is a white powder. It is insoluble in water. It is toxic by inhalation (dust, etc.) and by ingestion. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting tires involv ing this material If contact with the material anticipated, wear full protective clothing ZINC ARSENITE, SOLID 4923492 POISON B UN1712 Zinc arsenite, solid is a colorless powder. It is insoluble in water, it is toxic by inhalation (dust, etc.) and by ingestion. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material Itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing ZINC BORATE 4963369 ORM-E NA9155 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Zinc borate is a white powder. It is used as a fungus and mildew inhibitor, to fire proof textiles, and for other uses. It is slightly soluble in water. It is non-combustible. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary If material on fire or Involved In fire Flood with water Cooi all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Continued on next page April 1961 000017465 MCD 537 Personnel protection Avoid breathing dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Add soda ash Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ZINC BROMIDE 4966780 ORM-E NA9156 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Zinc bromide is a white crystalline solid. It is used in medicine, in photography, and for other uses. It is soluble in water. It is non- combustible. If material involved In fire Extinguish fire using agent suitable lor type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Add soda ash Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ZINC CARBONATE 4963890 ORM-E NA9157 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-lOOO/454) Zinc carbonate is a white crystalline solid or powder. It is used in pharmaceuticals, to make other zinc compounds, as a feed additive, and for many other uses. It is insoluble in water. It is non-combustible. If material Involved In fire Extinguish fire using agent suitable lor type of surrounding fire (Material itself does not bum or bums with difficulty.) 538 If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ZINC CHLORATE 4918771 OXIDIZER UN1513 Zinc chlorate is a white crystalline solid. The material is soluble in water. It forms a very flammable mixture with combustible materials and this mixture may be explosive if the combustible material is very finely divided. The mixture can be ignited by friction. Contact with strong sul furic acid can cause fires or explosions. When mixed with ammonium salts, spontaneous decomposition and ignition may result. Prolonged exposure of the material to tire or heat can result in an explosion, if material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible if material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet ZINC CHLORIDE CHEMICAL PLANT WASTE 4932381 (CORROSIVE LIQUID, N.O.S.) CORROSIVE MATERIAL UNI 760 Zinc chloride chemical plant waste is a colorless to dark colored liquid. It is soluble in water. It is corrosive to metals and tissue. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash, or lime April 1981 MOD 000017466 Personnel protection Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing ZINC CHLORIDE SOLUTION 4932393 CORROSIVE MATERIAL, ACIDIC UN1840 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Zinc chloride solution is the white crystalline solid dissolved in water. It is corrosive to metals and tissue. It weighs 16.1 pounds per gallon. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water split Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Adjust ph to neutral (ph-7) ZINC CHLORIDE, SOLID 4966790 ORM-E UN2331 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Zinc chloride, solid is a white crystalline solid. It is used for preserving wood, in soldering fluxes, as a catalyst in chemical manufacturing, and for many other uses. It is soluble in water. It is non-combustible. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 oqooV? 46^ Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving m rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Add soda ash Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ZINC CYANIDE 4923495 POISON B UN1713 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-10/4.54) Zinc cyanide is a white powder, it is used in medicine, in metal plating, and in chemical analysis. It is insoluble in water. It is decomposed by acids giving off hydrogen cyanide, a flammable poison gas. It is toxic by inhalation (dust and the hydrogen cyanide from decomposition) and by ingestion, toxic oxides of nitrogen are produced in fires involving this material. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use foam, carbon dioxide or dry chemical Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If material not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Use water spray to knock-down vapors Do not use water on material itself Personnel protection Avoid breathing vapors or dusts Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Add calcium hypochlorite Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ZINC FLUORIDE 4963895 ORM-E NA9156 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Zinc fluoride is a white powder. It is used for galvanizing steel and making ceramics. It is slightly soluble in water. It is non-combustible. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Continued on next page 539 If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water split Add soda ash Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ZINC FORMATE 4963392 ORM-E NA91S9 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Zinc formate is a white crystalline solid. It is used as a catalyst in chemical processing and as a water proofing agent. It is soluble in water. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Add soda ash Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ZINC HYDROSULFITE 4941195 ORM-A UNI 931 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Zinc hydcosultite is a white powder. It is used to bleach wood pulp, textiles, and other naturally occuring materials. It is non-combustible. It is soluble in water. H material on fire or Involved In fire Use water only if flooding quantities are available Use dry chemical, carbon dioxide, or dry sand If material not on fire and not involved in fire Do not use water Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 540 Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Add calcium hypochlorite Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ZINC MURIATE SOLUTION (See ZINC CHLORIDE SOLUTION 4932393) ZINC NITRATE OXIDIZER 4918790 ENVIRONMENTALLY HAZARDOUS UN1514 SUBSTANCE (RQ-5000/2270) Zinc nitrate is a colorless crystalline solid. It is used as a catalyst in the manufacture of other chemicals, in medicine, and in dyeing. It is soluble in water. It is non-combustible, but it will accelerate the burning of combustible materials. If large quantities are involved in a lire or the combustible material is finely divided, an explosion may result. Pro longed exposure to fire or heat may result in an explosion. Toxic oxides of nitrogen are produced in fires involving this material, tf material on fire or involved In fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Add soda ash Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Adjust ph to neutral (ph-7) ZINC PERMANGANATE 4918757 OXIDIZER UNI 515 Zinc permanganate is a purplish colored crystalline solid. The material is soluble in water. The material itself is non-combustible but it will accelerate the burning of combustible material, if the combustible ma terial is finely divided the mixture may be explosive. Contact with liquid combustible materials may result in spontaneous ignition. Contact with sulfuric add may result in fires or explosions. If material on fire or Involved In fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible April 1981 A 7 468 OOOtf If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Personnel protection Avoid breathing dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet ZINC PEROXIDE 4918758 OXIDIZER UN1516 Zinc peroxide is a white powder. It is insoluble in water and slowly decomposed by water. It is non-combustible but it will accelerate the burning of combustible material. If the combustible material is finely divided the mixture may be explosive. Mixtures of combustible material and the peroxide can be ignited by friction or contact with moisture. If material on fire or Involved In fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible W material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Personnel protection Avoid breathing dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet ZINC PHENOLSULFONATE 4966389 ORM-E NA9160 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Zinc phenolsulfonate is a colorless to white crystalline solid which turns pink on exposure to air. It is useas an insecticide and in medicine. It is soluble in water. II isnon-combustible. If material Involved In fire Extinguish fire using agent suitable lor type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates April 1981 MCD 000017469 ZINC PHOSPHIDE 4923496 POISON B UN1714 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Zinc phosphide is a dark grey granular solid. It is used in medicine and as a rat poison. It is slowly decomposed by water giving off phos phine. a flammable poison gas. It is toxic by ingestion. If material on fire or involved in fire Do not use water Use dry chemical or carbon dioxide If material not on fire and not involved in fire Do not use water Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Keep material dry Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or tire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ZINC RESINATE. FUSED. (FLAMMABLE SOUD, 4916764 N.O.S.) FLAMMABLE SOLID UN1325 Zinc resinate, fused is a clear to amber colored solid, it is used as a drier in paints, and as a wetting agent. It may spontaneously heat in the presence of air and moisture. This heat may be sufficient to ignite sur rounding combustible materials. It is not soluble in water. If material on fire or involved In fire Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not on fire end not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ZINC SILICOFLUORIDE 4966392 ORM-E UN2855 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (R-5000/2270) Zinc silicofluoride is a white crystalline solid. It is used as a concrete hardener, as a preservative, and for other uses. It is soluble in water. It is non-combustible. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material Itself does not bum or bums with difficulty.) Continued on next page 541 It material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ZINC SULFATE 49G3786 ORM-E NA9161 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Zinc sulfate is a colorless crystalline solid. It is used in the production of rayon, as a feed supplement, and as a fertilizer ingredient. It is soluble in water. It is non-combustible. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Env ironmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, C' sodium bicarbonate Add soda ash Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ZIRCONIUM METAL BARS, PLATES, RINGS. RODS, 4916752 SHEETS, SPONGE, STRIPS, TUBING OR UNFINISHED SHAPES, (FLAMMABLE SOLID, N.O.S.) FLAMMABLE SOLID UN1325 Zirconium metal is a greyish silver colored solid. The very thin material is easily ignited and burns with an intense flame. Once ignited the ma terial can burn under water. If material on fire or involved in fire Do not use water Use graphite, soda ash. oowdered sodium chloride, or suitable dry powder If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle Droken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ZIRCONIUM METAL SCRAP (BORINGS CLIPPINGS, 4916212 SHAVINGS SHEETS, OR TURNINGS FLAMMABLE SOLID UN1932 PYROFORIC Zirconium metal scrap is a lustrous, greyish metallic solid. It may ignite spontaneously and can burn with explosive violence. It may De ignited by static electricity. Small amounts of moisture may promote the ignition of zirconium. It can bum immersed in water and does so with greater intensity than if it bums in air. If material on fire or involved In fire Do not use water Use graphite, soda ash. powdered sodium chloride, or suitable dry powder Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ZIRCONIUM HYDRIDE 4916495 FLAMMABLE SOLID UN1437 WATER REACTIVE Zirconium hydrice is a greyish black solid. It doesn't react with water under normal conations. It is easily ignited and bums with an intense flame. The addition of water will increase the intensity of the fire. If material on fire or Involved In tire Do not use water Use graphite, soda ash or powdered sodium chloride If material not on fire and not Involved In fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packcqes without protective equipment Wash away any material whrh may have contacted the body with copious amounts of water i - soap and water 542 ZIRCONIUM METAL, DRY (CHEMICALLY PRODUCED, 4916211 FINER THAN 20 MESH PAHTICLE SIZE) FLAMMABLE SOLID UN200B PYROFORIC Zirconium metal, dry is a grey amorphous powder, it is used to make corrosion-resistant alloys, in pyrotechnics, and for many other uses. It may ignite spontaneously and can bum with explosive violence. It may be ignited by static electricity. Small amounts of water may promote the ignition of zirconium. Zirconium can bum immersed in water and does so with greater intensity than if it burns in air. If material on fire or involved in fire Do not use water Use graphite, soda ash, powdered sodium chloride, or suitable dry powder Cool all affected containers with flooding quantities of water Apply water from as tar a distance as possible If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry April 1981 MCD 000017470 Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ZIRCONIUM METAL, DRY (MECHANICALLY 4916210 PRODUCED, FINER THAN 270 MESH PARTICLE SIZE) FLAMMABLE SOLID UN2008 PYROFORIC Zirconium metal, dry is a grey amorphous powder. It is used to make corrosion-resistant alloys, in pyrotechnics, and for many other uses. It may ignite spontaneously and can burn with explosive violence. It may be ignited by static electricity. Small amounts of moisture may promote the ignition of zirconium. Zirconium can burn immersed in wafer and does so with greater intensity than if it burns in air. If material on fire or involved in fire Do not use water Use graphite, soda ash, powdered sodium chloride, or suitable dry powder Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ZIRCONIUM METAL, WET (CHEMICALLY PRODUCED, 4916751 FINER THAN 20 MESH PARTICLE SIZE) FLAMMABLE SOLID UN1358 Zirconium metal, wet is a grey amorphous sludge. It may be ignited with difficulty. If it dries out it is more easily ignitable than the dry material. Zirconium metal can burn immersed in water and does so with greater intensity than if it burns in air. If material on fire or Involved in fire Use graphite, soda ash, powdered sodium chloride, or suitable dry powder If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material wet Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ZIRCONIUM METAL, WET (MECHANICALLY 4916750 PRODUCED, FINER THAN 20 MESH PARTICLE SIZE) FLAMMABLE SOLID UN1358 Zirconium metal, wet is a grey amorphous sludge. It may be ignited with difficulty, if it dries out it is more easily ignitable than the dry material. Zirconium metal can burn immersed in water and does so with greater intensity than if it bums in air. April 1981 MOD 000017471 If material on fire or involved in fire Use graphite, soda ash, powdered sodium chloride, or suitable dry powder If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material wet Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ZIRCONIUM NITRATE 4918791 OXIDIZER UN2728 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Zirconium nitrate is a white crystalline solid. It is used as a preserv ative. It is soluble in water. It is non-combustible, but it will accelerate the burning of combustible materials. If large quantities are involved in a fire or the combustible material is finely divided, an explosion may result. Prolonged exposure to fire or heat may result in an explosion. Toxic oxides of nitrogen are produced in fires involving this material. If material on fire or Involved In fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts ol water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation II fire becomes uncontrollable--evacuate for a radius of 2500 feet Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Adjust ph to neutral (ph-7) ZIRCONIUM PICRAMATE, WET, (WITH AT LEAST 20% 4917195 WATER) FLAMMABLE SOLID UNI 517 Zirconium picramate. wet is a slurry or sludge of yellow crystals. It may take some effort to ignite but once ignited the material will burn with great rapidity. It will accelerate the burning of combustible materials. If large quantities are involved in fire or if containers of the material are exposed to fire or heat for prolonged periods, an explosion may result. Toxic oxides of nitrogen are produced during combustion. If material on firs or involved In fire Dangerously explosive Flood with water Coot all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Do not attempt to sweep up dry material Continued on next page 543 Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear seif-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 5000 feet ZIRCONIUM POTASSIUM FLUORIDE 4966395 ORM-E NA9162 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-500Q/2270) Zirconium potassium fluoride is a white crystalline solid, it is used in metal processing, as a catalyst in chemical manufacture, and for other uses. It is slightly soluble in water. It is non-combustible. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ZIRCONIUM SULFATE 4944185 ORM-B NA9163 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Zirconium sulfate is a white crystalline solid, it is used in chemical analysis, as an additive tor lubricants, and for many other uses. It is soluble in water. It is non-combustible, it is corrosive to aluminum. if material involved In fire Extinguish fire using agent suitable lor type of surrounding fire (Material itself does not burn or bums with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ZIRCONIUM TETRACHLORIDE. SOLID 4932395 CORROSIVE MATERIAL. ACIDIC UN2503 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Zirconium tetrachloride solid is a white crystalline material. It is de composed by water to give hydrochloric acid with the evolution of heat. It is corrosive to metals in the presence of moisture and to tissup. If material involved in fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover soltds with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ZIRCONIUM, METALLIC, SOLUTIONS OR MIXTURES 4909390 THERE-OF, LIQUID FLAMMABLE LIQUID UN1308 Metallic zirconium, solutions or mixtures there-of. liquid is the pow dered or (inely divided metal stored under a flammable organic solvent. Metallic zirconium powder may bum and small amounts of water may greatly accelerate this combustion to "explosive" character. The dry powder resulting from the solvent evaporating is easily ignited. Even static electricity may be sufficient to ignite the powder. If material on fire or involved In fire Use graphite, soda ash or powdered sodium chloride If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Do rot use water Do not attempt to sweep up dry material Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water MOD 000017472 544 April 1901 DOT IDENTIFICATION NUMBER COMMODITY(IES)/PAGE(S) This index lists materials in DOT identification number order, giving the commodity name(s) and the page number(s) where emergency response information can be found. Note that one DOT identification number may refer to several commodities. (See, for example: 1760, 1993 and 2761) 1001 1002 1005 1005 1006 1008 1009 1010 1010 1010 1014 1015 1016 1017 1018 1020 1021 1022 1026 1027 1028 1030 1032 1033 1035 1036 1037 1039 1040 1043 1043 1043 ACETYLENE AIR. COMPRESSED ANHYDROUS AMMONIA TUNDRA COOLING UNITS. CONDENSERS. EQUALIZERS OR EXCHANGERS. OIL FIELD. GAS OR LIQUID. IRON OR STEEL PIPE TYPE, CONTAINING NOT MORE THAN 0.0125 POUNDS OF ANHYDROUS AMMONIA PER FOOT OF PIPE (LENGTH) (ANHYDROUS AMMONIA) ARGON BORON TR1FLUORIDE MONOBROMOTRIFLUOROMETHANE BUTADIENE. INHIBITED (BUTADIENE FROM ALCOHOL) BUTADIENE. INHIBITED (BUTADIENE FROM PETROLEUM)' BUTADIENE. INHIBITED (BUTADIENE, IMPURE. FOR FUR THER REFINING) CARBON DIOXIDE OXYGEN MIXTURE CARBON DIOXIDE-NITROUS OXIDE MIXTURE CARBON MONOXIDE CHLORINE MONOCHLORODIFLUOROM ETHANE MONOCHLOROPENTAFLUOROETHANE MONOCHLOROTETRAFLUOROETHANE MONOCHLOROTRIFLUOROMETHANE CYANOGEN GAS CYCLOPROPANE DICHLORODIFLUOROMETHANE DIFLUOROETHANE DIMETHYLAMINE. ANHYDROUS DIMETHYL ETHER ETHANE MONOETHYLAMINE ETHYLCHLORIDE ETHYL METHYL ETHER ETHYLENE OXIDE CRUDE NITROGEN FERTILIZER SOLUTION (MORE THAN 25.3 PSIG) FERTILIZER AMMONIATING SOLUTION (CONTAINING FREE AMMONIA) NITROGEN FERTILIZER SOLUTION 1 11 39 514 46 74 352 79 78 79 107 108 106 119 352 352 353 353 159 162 184 194 201 198 224 224 234 230 237 155 247 372 1044 1045 1046 1048 1049 1050 1051 1052 1053 1057 1056 1060 1061 1062 1063 1064 1065 1066 1067 1067 1067 1069 1070 1072 1072 1072 1073 1075 1075 1075 1075 1075 1075 FIRE EXTINGUISHER FLUORINE HELIUM HYDROGEN BROMIDE HYDROGEN HYDROGEN CHLORIDE HYDROCYANIC ACID, LIQUEFIED HYDROFLUORIC ACID. ANHYDROUS (OR) HYDROGEN FLUORIDE HYDROGEN SULFIDE CIGARETTE LIGHTER LIQUEFIED NONFLAMMABLE GASES (CHARGED WITH NI TROGEN, CARBON DIOXIDE. OR AIR) METHYLACETYLENE-PROPADIENE. STABILIZED MONOMETHYLAMINE, ANHYDROUS METHYL BROMIDE, LIQUID (INCLUDING UP TO 2% CHLOROPICRIN) METHYL CHLORIDE METHYL MERCAPTAN NEON NITROGEN NITROGEN DIOXIDE. LIQUID NITROGEN PEROXIDE, LIQUID NITROGEN TETROXIDE, LIQUID NITROSYLCHLORIDE NITROUS OXIDE OXYGEN OXYGEN (GAS ADMINISTERING APPARATUS, HOSPITAL OR SURGICAL. WITH CYLINDER OF OXYGEN) OXYGEN (LIFE SAVING APPARATUS, OXYGEN) OXYGEN. PRESSURIZED LIQUID BUTANE BUTANE (BUTANE. IMPURE, FOR FURTHER REFINING) BUTENE GAS. LIQUEFIED (LIQUEFIED PETROLEUM GAS) BUTYLENE, IMPURE. FOR FURTHER REFINING (LIQUEFIED PETROLEUM GAS) ISOBUTANE ISOBUTANE (ISOBUTANE FOR FURTHER REFINERY PROCESSING) 249 253 267 282 281 282 279 280 283 130 313 345 354 336 337 341 382 371 371 372 372 375 376 388 388 388 388 79 79 80 94 294 295 MCI) 00001747? 545 1075 1075 1075 1075 1075 1076 1079 1080 1081 1082 1083 1086 1087 1088 1089 1090 1091 1092 1093 1098 1099 1100 1104 1106 1107 1108 1109 1110 1111 1113 1114 1115 1120 1120 1120 1123 1125 1125 1126 1127 1128 1129 1130 1131 1132 1133 1133 1133 1133 1133 1133 1133 U33 1133 1133 1133 1133 1133 1133 1133 1133 5133 1134 1135 1136 1136 1136 1136 1136 1137 1137 1137 1137 1137 ISOBUTYLENE LIQUEFIED PETROLEUM GAS LIQUEFIED PETROLEUM GAS (PINTSCH GAS) PROPANE PROPYLENE PHOSGENE SULFUR DIOXIDE SULFUR HEXAFLUORIDE TETRAFLUOROETHYLENE. INHIBITED TRIFLUOROCHLOROETHYLENE. INHIBITED TRIMETHYLAMINE. ANHYDROUS VINYL CHLORIDE VINYL METHYL ETHER ACETAL ACETALDEHYDE ACETONE ACETONE OIL ACROLEIN, INHIBITED ACRYLONITRILE ALLYL ALCOHOL ALLYL BROMIDE ALLYL CHLORIDE AMYL ACETATE AMYLAMINE AMYL CHLORIDE AMYLENE AMYL FORMATE METHYL AMYL KETONE AMYL MERCAPTAN AMYL NITRITE BENZENE BENZINE 2-BUTANOL (BUTYL ALCOHOL) TERT-BUTYL ALCOHOL (BUTYL ALCOHOL) ISOBUTYL ALCOHOL (BUTYL ALCOHOL) BUTYL ACETATE BUTYLAMINE TERT-BUTYLAMINE (BUTYLAMINE) BUTYL BROMIDE (NORMAL) BUTYL CHLORIDE BUTYL FORMATE BUTYRALDEHYDE CAMPHOR OIL CARBON BISULFIDE (OH) CARBON DISULFIDE CARBON REMOVER. LIQUID ADHESIVE, N.O.S. ADHESIVE, N O S. CEMENT, CONTAINER LINOLEUM. TILE, OR WALLBOARD. LIQUID CEMENT. CORK, INSULATION, LIQUID (CEMENT, UQUID, N.O.S.) CEMENT, CORK, INSULATION. LIQUID (CEMENT, LIQUID, N.O.S.) CEMENT. LEATHER CEMENT. LIQUID, N O S CEMENT, LIQUID, N.O.S. CEMENT, PYROXYLIN CEMENT, ROOFING, LIQUID CEMENT. RUBBER EMBEDDING CEMENT. NEC (CEMENT, LIQUID, N.O.S.) EMBEDDING CEMENT. NEC (CEMENT, LIQUID, N.O.S.) INSECTICIDE ADHESIVES. LIQUID (ADHESIVE. N.O.S.) INSECTICIDE ADHESIVES. LIQUID (ADHESIVES. N.O.S.) POLISHING WHEEL CEMENT OR GLUE (CEMENT, LIQUID. N.O.S.) PUSHING WHEEL CEMENT OR GLUE (CEMENT, LIQUID. N.O.S.) CHLOROBENZOL (OR) CHLOROBENZENE ETHYLENE CHLOROHYDRIN COAL TAR DISTILLATE COAL TAR LIGHT OIL COAL TAR LIGHT OIL (CRUDE LIGHT OIL OF COAL TAR) COAL TAR OIL COAL TAR OIL (COAL TAR OIL, CRUDE. NEC) COAL TAR DISTILLATE COAL TAR LIGHT OIL COAL TAR LIGHT OIL (CRUDE LIGHT OIL OF COAL TAR) COAL TAR OIL COAL TAR OIL (COAL TAR OIL, CRUDE. NEC) 296 313 314 426 432 404 486 486 494 511 512 525 526 1 1 3 3 7 B 17 18 18 36 39 37 39 37 335 37 38 62 63 79 81 295 80 94 94 82 82 83 95 101 106 109 10 10 111 111 111 112 112 112 112 112 113 219 229 290 290 417 418 121 234 131 132 133 134 135 132 133 133 134 135 1139 1142 1142 1142 1142 1142 1142 1142 1142 1142 1142 1142 1142 1142 1142 1142 1142 1142 1142 1142 1142 1142 1142 1143 1144 1145 1146 1147 1148 1149 1150 1152 1153 1154 1155 1155 1156 1157 1158 1159 1160 1161 1162 1163 1164 1165 1166 1167 1168 1168 1170 1170 1170 1170 1170 1170 1170 1170 1170 1170 1170 1170 1170 1170 1170 1170 COATING SOLUTION ANTI-FREEZE COMPOUND. LIQUID ANTI-FREEZE PREPARATION, LIQUID ANTIFREEZE COMPOUND UQUID ANTIFREEZE PREPARATION, LIQUID COMPOUND. LACQUER, PAINT. OR VARNISH. REMOVING. REDUCING OR THINNING COMPOUND, LACQUER. PAINT, OR VARNISH, REMOVING, REDUCING OR THINNING. COMPOUND, POLISHING, UQUID COMPOUND. VULCANIZING. LIQUID COMPOUNDS, IRON OR STEEL RUST PREVENTING. OTHER THAN PETROLEUM, NEC (RUST PREVENTIVE COATING) FLOOR POLISH OR WAX (POLISH. WOOD, LIQUID) FLOOR POLISH OR WAX (POLISH. WOOD. LIQUID) LACQUER THINNING COMPOUNDS, USED (COMPOUND, LACQUER. THINNING) LACQUER THINNING COMPOUNDS, USED (COMPOUND, LACQUER, THINNING) LEATHER BLEACH LEATHER BLEACH LEATHER DRESSING LEATHER DRESSING PIPE LINE RUST PREVENTIVE COATING (RUST PREVENTIVE COATING) POLISH, METAL. STOVE, FURNITURE OR WOOD, LIQUID POLISH. METAL. STOVE, FURNITURE OR WOOD, LIQUID THINNER FOR RUST PREVENTIVE COATING THINNER FOR RUST PREVENTIVE COATING CROTONALDEHYDE CROTONYLENE CYCLOHEXANE CYCLOPENTANE DECAHYORONAPHTHALENE DIACETONE ALCOHOL BUTYL ETHER DICHLOROETHYLENE DICHLOROPENTANE ETHYLENE GLYCOL DIETHYL ETHER DIETHYLAMINE ETHER (DIETHYL ETHER. ANESTHESIA GRADE) ETHER (DIETHYL ETHER. OTHER THAN ANESTHESIA GRADE) DIETHYL KETONE DIISOBUTYL KETONE DIISOPROPYLAMINE DIISOPROPYL ETHER DIMETHYLAMINE, AQUEOUS SOLUTION DIMETHYL CARBONATE DIMETHYLOICHLOROSILANE DIMETHYL HYDRAZINE. UNSYMMETRlCAL DIMETHYL SULFIDE DIOXANE DIOXOLANE DIVINYL ETHER PAINT DRIER. LIQUID PAINT DRIER. LIQUID ALCOHOL IN BOND. FREE OF INTERNAL REVENUE TAX <Al- COHIC BEVERAGE) ALCOHOL IN BOND, FREE OF INTERNAL REVENUE TAX (AL- COHIC BEVERAGE) ALCOHOL OR SPIRITS. FRUIT, EXCEPT GRAPE, NEUTRAL, IN BOND (ALCOHOLIC BEVERAGE) ALCOHOL OR SPIRITS, FRUIT.EXCEPT GRAPE, NEUTRAL, IN BOND (ALCOHOLIC BEVERAGE) ALCOHOL OR SPIRITS. GRAPE. NEUTRAL IN BOND (ALCO HOLIC BEVERAGE) ALCOHOL OR SPIRITS. GRAPE, NEUTRAL IN BOND (ALCO HOLIC BEVERAGE) BRANDY, ALCOHOLIC (ALCOHOLIC BEVERAGE) BRANDY, ALCOHOLIC (ALCOHOLIC BEVERAGE) CHAMPAGNE (ALCOHOLIC BEVERAGE) CHAMPAGNE (ALCOHOLIC BEVERAGE) ETHYL ALCOHOL (COLOGNE SPIRITS) LIQUORS. ALCOHOLIC, NEC (ALCOHOLIC BEVERAGE) LIQUORS, ALCOHOLIC. NEC (ALCOHOLIC BEVERAGE) SPIRITS, ALCOHOLIC. WHISKIES, RUM OTHER THAN DEN ATURED (ALCOHOLIC BEVERAGE) SPIRITS, GRAIN. NEUTRAL IN BOND (ALCOHOLIC BEVERAGE) VERMOUTH IN TANK CARS (ALCOHOLIC BEVERAGE) 136 42 42 42 42 140 140 141 142 144 252 253 305 305 311 311 311 311 413 417 417 497 497 154 154 159 162 163 176 82 186 186 235 193 224 224 192 195 197 196 202 197 203 196 199 207 207 214 389 389 12 12 12 12 13 13 75 76 113 113 226 314 314 480 480 524 546 ooooi'7 47 4 MOD 1170 1170 1170 1170 1170 1170 1170 1170 1170 1170 1170 1171 1172 1173 1175 1176 1177 1178 1179 1180 1181 1182 1183 1184 1185 1188 1189 1190 1191 1192 1193 1194 1195 1196 1197 1198 1198 1198 1198 1199 1201 1203 1203 1203 1203 1203 1203 1203 1204 1204 1206 1207 1208 1208 1210 1213 1214 1216 1218 1219 1220 1221 1222 VERMOU1H IN TANK CARS (ALCOHOLIC BEVERAGES) VERMOUTH. OTHER THAN IN TANK CARS (ALCOHOLIC BEVERAGE) VERMOUTH, OTHER THAN IN TANK CARS (ALCOHOLIC BEVERAGE) WINE. CHAMPAGNE OR VERMOUTH. SPIOLED (ALCOHOLIC BEVERAGE) WINE. CHAMPAGNE OR VERMOUTH. SPOILED (ALCOHOLIC BEVERAGE) WINE. SPARKLING. OTHER THAN CHAMPAGNE (ALCOHOLIC BEVERAGE) WINE. SPARKLING. OTHER THAN CHAMPAGNE (ALCOHOLIC BEVERAGE) WINES. NEC. IN TANK CARS (ALCOHOLIC BEVERAGE) WINES, NEC. IN TANK CARS (ALCOHOLIC BEVERAGE) WINES. NEC. OTHER THAN IN TANK CARS (ALCOHOLIC BEVERAGE) WINES. NEC. OTHER THAN IN TANK CARS (ALCOHOLIC BEVERAGE) ETHYLENE GLYCOL MONOETHYL ETHER ETHYLENE GLYCOL MONOETHYL ETHER ACETATE ETHYL ACETATE ETHYL BENZENE ETHYL BORATE ETHYL BUTYL ACETATE ETHYL BUTYRALDEHYDE ETHYL BUTYL ETHER ETHYL BUTYRATE ETHYL CHLOROACETATE ETHYL CHLOROFORMATE ETHYL DICHLOROSILANE ETHYLENE DICHLORIDE ETHYLENE IMINE. INHIBITED ETHYLENE GLYCOL MONOMETHYL ETHER ETHYLENE GLYCOL MONOMETHYL ETHER ACETATE ETHYL FORMATE ETHYL HEXALDEHYDE ETHYL LACTATE METHYL ETHYL KETONE (ETHYL METHYL KETONE) ETHYL NITRITE ETHYL PROPIONATE ETHYLTRICHLOROSILANE EXTRACT. LIQUID, FLAVORING FORMALDEHYDE (OR) FORMALIN SOLUTION (IN CON TAINERS OF 110 GALLONS OR LESS) (FORMALDEHYDE. LIQUID) FORMALDEHYDE (OR) FORMALIN SOLUTION (IN CON TAINERS OF 110 GALLONS OR LESS) (FORMALDEHYDE. PASTE) FORMALDEHYOE. LIQUID (FORMALDEHYDE OR FORMALIN SOLUTION) FORMALDEHYDE. PASTE (FORMALDEHYOE OR FORMALIN SOLUTION) FURFURAL FUSEL OIL GASOLINE GASOLINE (GASOLINE NATURAL (CASING HEAD)) GASOLINE (GASOLINE, BLENDED) MOTOR FUEL. ALCOHOL. CASTOR OIL. AND NITROMETHANE (MOTOR FUEL, N.O.S.) MOTOR FUEL. ALCOHOL. CASTOR OIL. AND NITROMETHANE (MOTOR FUEL, N.O.S.) MOTOR FUEL, N.O.S. MOTOR FUEL, N.O.S. SPIRITS OF NITROGLYCERINE SPIRITS OF NITROGLYCERINE. NOT EXCEEDING 1% NITRO GLYCERINE BY WEIGHT HEPTANE HEXALDEHYDE HEXANE NEOHEXANE INK (INK. PRINTING. NEC) ISOBUTYL ACETATE ISOBUTYLAMINE ISOOCTENE 1SOPRENE ISOPROPANOL ISOPROPYL ACETATE ISOPROPYLAMINE ISOPROPYL NITRATE 524 524 524 532 532 532 532 533 533 533 ' 533 235 236 226 227 227 227 228 228 228 228 228 229 235 236 236 236 229 230 230 338 231 232 238 240 254 255 255 255 259 260 263 263 264 357 357 357 357 479 479 269 272 273 362 289 295 296 298 299 299 300 302 300 1223 1226 1226 1228 1228 1229 1230 1231 1232 1233 1234 1235 1237 1238 1239 1242 1243 1244 1246 1247 1247 1246 1249 1250 1251 1255 1255 1256 1256 1257 1259 1261 1262 1262 1263 1263 1263 1263 1263 1263 1263 1263 1263 1263 1263 1263 1263 1263 1263 1263 1263 1263 1264 1265 1265 1267 1267 1268 1268 1268 1268 1266 1268 1268 1270 1270 1270 1270 1270 1270 1271 1271 1272 KEROSENE CIGARETTE LIGHTER LIGHTER FLUID MERCAPTAN MIXTURE. ALIPHATIC MERCAPTAN MIXTURE, ALIPHATIC MESITYL OXIDE METHANOL (METHYL ALCOHOL. COLUMBIAN SPIRITS) METHYL ACETATE METHYL ACETONE METHYL AMYL ACETATE METHYLAL MONOMETHYLAMINE, AQUEOUS SOLUTION METHYL BUTYRATE METHYL CHLOROFORMATE METHYLCHLOROMETHYL ETHER. ANHYDROUS METHYLDICHLOROSILANE METHYL FORMATE METHYL HYDRAZINE METHYL ISOPROPENYL KETONE. INHIBITED METHYL METHACRYLATE MONOMER. INHIBITED METHYLMETHACRYLATE MONOMER, UNINHIBITED METHYL PROPIONATE METHYL PROPYL KETONE METHYLTRICHLOROSILANE METHYL VINYL KETONE, INHIBITED PETROLEUM NAPHTHA PETROLEUM NAPHTHA NAPHTHA SOLVENT NAPHTHA SOLVENT GASOHOL NICKEL CARBONYL NITROMETHANE ISOOCTANE OCTANE ALUMINUM LIQUID (OR PAINT) ASPHALTUM OR COAL TAR PAINT (PAINT) ASPHALTUM OR COAL TAR VARNISH (VARNISH) COMPOUND, ENAMEL ENAMEL (ENAMEL OTHER THAN WATCH DIAL) ENAMEL (ENAMEL OTHER THAN WATCH DIAL) LACQUER BASE OR LACQUER CHIPS. PLASTIC (WET WITH ALCOHOL OR SOLVENT) MORTAR STAIN, LIQUID MORTAR STAIN, LIQUID PAINT (ASPHALTUM OR COAL TAR PAINT) PAINT (ASPHALTUM OR COAL TAR VARNISH) PAINT, LACQUER, STAIN (OR) VARNISH, BRONZE OR GOLD. LIQUID OR LACQUER BASE LIQUID PAINT, LACQUER. STAIN. VARNISH, BRONZE. GOLD. LIQUID OR LACQUER BASE LIQUID RUBBER TIRE LACQUERS, PAINT, OR SHELLAC (PAINT, LAC QUER OR SHELLAC) SHELLAC. LIQUID SHELLAC. LIQUID WOOD FILLER WOOD FILLER PARALDEHYDE ISOPENTANE PENTANE CRUDE OIL, PETROLEUM CRUDE OIL. PETROLEUM NAPHTHA DISTILLATE NAPHTHA DISTILLATE PETROLEUM DISTILLATE PETROLEUM DISTILLATE (PETROLEUM DISTILLATE OIL, NOT FOR ILLUMINATING PURPOSES) PETROLEUM DISTILLATE FUEL OIL. NOT FOR ILLUMINATING PURPOSES (PETROLEUM DISTILLATE) PETROLEUM DISTILLATE ROAD OIL (PETROLEUM ROAD OIL) COAL SPRAYING OIL PETROLEUM (PETROLEUM OIL N.O.S.) OIL, N.O.S.. PETROLEUM OIL OR PETROLEUM OIL, N.O.S OIL, N.O.S., PETROLEUM OIL OR PETROLUEM OIL. N.O.S. PETROLEUM ABSORPTION OIL (PETROLEUM OIL. N.O.S.) PETROLEUM OIL RESIDUUM (PETROLEUM OIL. N.O.S.) PETROLEUM. PARTIALLY REFINED FOR FURTHER PROC ESSING (PETROLEUM OIL. N.O.S.) PETROLEUM ETHER POLYETHYLLIGROIN (PETROLEUM ETHER) PINE OIL 304 130 312 323 323 331 333 334 335 335 345 353 337 338 345 346 339 339 340 341 341 344 344 347 344 398 398 360 360 263 363 374 298 378 20 55 55 140 219 219 304 356 356 369 369 390 390 454 457 457 534 534 391 298 394 155 155 360 360 397 397 398 401 448 131 379 379 396 399 401 398 419 412 547 MCt> 000017475 1275 1276 1277 1278 1279 1280 1281 1282 1289 1289 1289 1292 1294 1295 1296 1297 1298 1299 1299 1300 1300 1301 1302 1303 1304 1305 1307 1307 1308 1310 1313 1314 1318 1324 1324 1324 1324 1325 1325 1325 1325 1325 1325 1325 1325 1325 1325 1325 1325 1325 1325 1325 1325 1325 1325 1325 1325 1325 1325 1325 1325 1325 1325 1325 1325 PROPIONAIOEHYDE PROPYL ACETATE PROPYL AMINE (MONO-N-PROPYLAMINE) PROPYL CHLORIDE PROPYLENE DICHLORIDE PROPYLENE OXIDE PROPYL FORMATE PYRIDINE SODIUM METHYLATE, ALCOHOL MIXTURE SODIUM METHYLATE, ALCOHOL MIXTURE SODIUM METHYLATE. ALCOHOL MIXTURE ETHYL SILICATE TOLUENE TR1CHLOROSILANE TRIETHYLAMINE TRIMETHYLAMINE, AQUEOUS SOLUTION TRIMETHYLCHLOROSILANE TURPENTINE TURPENTINE TURPENTINE SUBSTITUTE TURPENTINE SUBSTITUTE VINYLACETATE VINYL ETHYL ETHER, INHIBITED VINYUDENE CHLORIDE. INHIBITED VINYL ISOBUTYL ETHER VINYL TRICHLOROSILANE XYLENE XYLENE (PARAXYLENE) ZIRCONIUM. METALLIC, SOLUTIONS OR MIXTURES THERE- OF. LIQUID AMMONIUM PICRATE. WET (WITH 10% OR MORE WATER) CALCIUM RESINATE CALCIUM RESINATE. FUSED COBALT RESINATE. PRECIPITATED FILM (NITROCELLULOSE) (CELLULOSE FILM SCRAP OR WASTE) FILM (NITROCELLULOSE) (MOVING PICTURE FILM SCRAP) FILM (NITROCELLULOSE) (MOVING PICTURE FILM. EX- POSED, NEC) FILM (NITROCELLULOSE) (PHOTOGRAPHIC FILM. NEC, UNEXPOSED) ANIMAL OR POULTRY FEED CHARCOAL. CRUSHED OR GROUND. (FLAMMABLE SOLID. N.O.S.) BURNT COTTON. NOT REPICKED (COTTON. NEC. IN BALES COMPRESSED) CALCIUM-MANGANESE-SILICON ALLOYS, (FLAMMABLE SOUO. N O S.) CELLULOSE FILM, NEC, PRINTED. (FLAMMABLE SOLID, N.O.S.) CHARCOAL, CORN COB OR COTTONSEED OR RICE HULL, NOT ACTIVATED (CHARCOAL. SHELL) CHARCOAL. OTHER THAN ANIMAL OR WOOD. NEC. NOT ACTIVATED. (FLAMMABLE SOLID. N.O.S.) CHROMIUM RESINATE (FLAMMABLE SOLID. N.O.S ) COCOA BEAN SHELLS. (FLAMMABLE SOLID. N.O.S.) COMPOUNDS GAS PURIFYING (FLAMMABLE SOLID. N.O.S.) COPPER RESINATE, (FLAMMABLE SOLID. N O S.) COSMETICS. N.O.S. DRUGS OR MEDICINES. N.O.S. FEEDING TANKAGE, NEC (FLAMMABLE SOLID. N.O.S.) FISH OIL RESIDUUM. DEHYDRATED (GARBAGE TANKAGE (CONTAINING LESS THAN 8% MOISTURE) FLAMMABLE SOLID. N.O.S. FLARES. HIGHWAY SAFETY. SOLIDIFIED FUEL OTHER THAN EXPLOSIVES OR FIREWORKS. (FLAMMABLE SOLID. N.O.S.) FUSEE (RAILWAY AND HIGHWAY) FUSEE (TRUCK FLARES. STEEL. 24 GAUGE OR THICKER) GARBAGE TANKAGE (CONTAINING LESS THAN 8% MOISTURE) GARBAGE TANKAGE (CONTAINING LESS THAN 8% WATER) IRON, POWDERED. NEC (FLAMMABLE SOLID, N.O.S.) MANGANESE RESINATE. (FLAMMABLE SOLID. N.O.S.) MEDICINES. N.O.S. N-METHYL-N'-NITRO-N-NITROSOGUANIDINE NUT MEAL EDIBLE. (FLAMMABLE SOLID, N.O.S.) PACKING OR WIPING WASTE MANUFACTURING. NEC. OILED, (FLAMMABLE SOLID, N.O.S.) PAPER STOCK. WET PEANUT CHAFF. FEED (FLAMMABLE SOLID, N.O.S.) 429 430 430 431 432 433 431 435 470 471 471 232 502 510 511 513 513 515 515 515 516 525 525 527 526 526 535 536 544 31 100 100 136 248 248 248 248 41 78 100 110 114 114 129 137 142 150 151 215 243 249 261 252 260 260 261 261 294 321 321 345 377 389 391 393 548 1325 1325 1325 1325 1325 1325 1325 1325 1325 1325 1325 1325 1325 1325 1325 1325 1325 1325 1325 1325 1325 1325 1326 1331 1334 1334 1336 1337 1337 1338 1338 1339 1340 1341 1343 1344 1345 1345 1345 1345 1345 1345 1345 1349 1352 1354 1355 1356 1357 1358 1358 PEANUT HULLS. CRUSHED OR GROUNO. OR PEANUT HULL BRAN OR MEAL, FEED (FLAMMABLE SOLID. N.O.S.) POLISHING CLOTHS. COTTON. TREATED WITH CHEMICALS, OIL OR WAX (FLAMMABLE SOLID,N.O.S.) RAGS WET ROUGH AMMONIATE TANKAGE. 7% OR MORE MOISTURE CONTENT RUBBER FILLER (VEGETABLE OIL FIBER) (FLAMMABLE SOLID. N.O.S.) SILICON-CALCIUM ALLOY, (FLAMMABLE SOLID, N O S.) SMOKELESS POWDER FOR SMALL ARMS (100 POUNDS OR LESS) SODIUM RESINATE, (FLAMMABLE SOLID. N O S.) SPARKLER. MATCH HEAD OR SELF-IGNITING (FLAMMABLE SOLID. N.O.S.) SPENT GRAINS. DRIED (FLAMMABLE SOLID. N.O.S.) SPENT GRAINS. WET. (FLAMMABLE SOLID, N.O.S.) SPONGE IRON BRIQUETTES OR PELLETS, VALUE ONLY FOR MELTING PURPOSES (FLAMMABLE SOLID. N.O.S.) TANKAGE FERTILIZER TANKAGE. CRUDE. DRIED, OTHER THAN FEEDING (GAR- BAGE TANKAGE (CONTAINING LESS THAN 6% MOISTURE)) TANKAGE. DERIVED FROM MEAT REFUSE (GARBAGE TAN- KAGE (CONTAINING LESS THAN 8% MOISTURE)) TANKAGE. ROUGH AMMONIATE WASTE PAPER PULP. WET (WASTE PAPER, WET) WASTE PAPER, WET WOOD PULP CHARCOAL. NOT ACTIVATED. (FLAMMABLE SOLID. N.O.S.) WOOD PULP, CHARRED. NOT ACTIVATED, (FLAMMABLE SOLID, N.O.S.) ZINC RESINATE. FUSED. (FLAMMABLE SOLID. N O S ) ZIRCONIUM METAL BARS. PLATES. RINGS. RODS. SHEETS. SPONGE. STRIPS. TUBING OR UNFINISHED SHAPES. (FLAMMABLE SOLID. N.O.S.) HAFNIUM, METAL, WET MATCHES, STRIKE ANYWHERE NAPHTHALENE (OR) NAPHTHAUN (NAPHTHALENE (NAPHTHALIN). CRUDE (TAR CAMPHOR. CRUDE)) NAPHTHALENE (OR) NAPHTHALIN (NAPHTHALENE (NAPHTHALIN). OTHER THAN CRUDE (TAR CAMPHOR, OTHER THAN CRUDE)) NITROGUANIDINE. WET WITH NOT LESS THAN 20% WATER NITROSTARCH. WET WITH NOT LESS THAN 20% WATER NITROSTARCH. WET WITH NOT LESS THAN 30% ALCOHOL OR SOLVENT PHOSPHORUS. AMORPHOUS, RED PHOSPHORUS, CRUDE, RED AND YELLOW. MIXED (FLAM- MABLE SOLID. N.O.S.) PHOSPHORUS HEPTASULFIDE PHOSPHORUS PENTASULFIDE PHOSPHORUS SESQUISULFIDE PHOSPHORUS TRISULFID6 PICRIC ACID, WET, WITH NOT LESS THAN 10% WATER RECLAIMED RUBBER RUBBER DIPPINGS. SCRAP. TRIMMINGS OR WASTE. LATEX FOAM. VALUE FOR GRINDING. FLAKING OR SHREDDING (RUBBER SCRAP) RUBBER MATTING TRIMMINGS (WASTE). OTHER THAN FOAM (RUBBER SCRAP) RUBBER SCRAP OR RUBBER BUFFINGS RUBBER SCRAP OR RUBBER BUFFINGS (HARD RUBBER SHAVINGS OR TURNINGS) RUBBER SCRAP OR RUBBER BUFFINGS (RUBBER SCRAP HARD PULVERIZED) RUBBER. SHODDY OR REGENERATED RUBBER SODIUM PICRAMATE, WET (WITH AT LEAST 20% WATER) TITANIUM METAL POWDER. WET. WITH 20% OR MORE WATER TRINITROBENZENE, WET (CONTAINING AT LEAST 10% WATER) TRINITROBENZOIC ACID. WET (CONTAINING AT LEAST 10% WATER) TRINITROTOLUENE, WET (CONTAINING AT LEAST 10% WATER) UREA NITRATE. WET (WITH 10% OR MORE WATER) ZIRCONIUM METAL. WET (CHEMICALLY PRODUCED, FINER THAN 20 MESH PARTICLE SIZE) ZIRCONIUM METAL WET (MECHANICALLY PRODUCED. FINER THAN 20 MESH PARTICLE SIZE) 393 417 445 452 453 458 461 475 478 479 479 480 489 489 489 489 529 529 535 535 541 542 266 321 361 361 373 375 375 408 409 406 407 407 408 411 445 453 453 454 454 454 454 474 501 513 514 514 521 543 543 MCD 000017476 1359 1360 1361 1361 1361 1361 1361 1361 1361 1361 1361 1361 1362 1364 1372 1372 1373 1374 1374 1374 1374 1374 1374 1376 1378 1378 1380 1381 1361 1382 1383 1384 1385 1387 1387 1387 1396 1396 1397 1401 1401 1402 1407 1410 1411 1412 1413 1414 1415 1415 1417 1419 1420 1421 1422 1422 1423 1423 1425 BAGS, SODIUM NITRATE EMPTY AND UNWASHED CALCIUM PHOSPHIDE CHARCOAL BRIQUETTES (CHARCOAL BRIQUETTES OR PELLETS, WITH PETROLEUM BINDER) CHARCOAL BRIQUETTES (CHARCOAL BRIQUETTES OR PELLETS, WITHOUT PETROLEUM BINDER) CHARCOAL BRIQUETTES (CHARCOAL BRIQUETTES, COM PRESSED. SELF-IGNITING) CHARCOAL SCREENINGS. MADE FROM PINON WOOD CHARCOAL, SHELL CHARCOAL. WOOD SCREENINGS, OTHER THAN PINON WOOD SCREENINGS CHARCOAL. WOOD, GROUND, CRUSHED, GRANULATED, (OR) PULVERIZED CHARCOAL WOOD. LUMP COAL, GROUND BITUMINOUS. SEA COAL, COAL FACINGS. ETC. WOOD CHARCOAL, IN TABLETS (CHARCOAL BRIQUETTES) CHARCOAL, ACTIVATED COTTON WASTE. OILY (WITH MORE THAN 5% ANIMAL OR VEGETABLE OIL) FIBERS. BURNT HAIR, WET FIBERS OR FABRIC. CONTAINING NOT MORE THAN 5% AN IMAL OR VEGETABLE OIL. ACID FISH SCRAP (FISH SCRAP (CONTAINING LESS THAN 6% OR MORE THAN 12% MOISTURE)) FISH MEAL CONTAINING LESS THEN 6% OR MORE THAN 12% WATER (FISH MEAL. GROUND. PULVERIZED OR SCREENED) FISH SCRAP CONTAINING LESS THAN 6% OR MORE THAN 12% WATER (FISH SCRAP, GROUND. PULVERIZED OR SCREENED) FISH SCRAP CONTAINING LESS THAN 6% OR MORE THAN 12% WATER (FISH SCRAP, NEC, DRY NOT GROUND, PUL- VERIZED NOR SCREENED) FISH SCRAP OR FISH MEAL CONTAINING LESS THAN 6% OR MORE THAN 12% WATER (FISH TANKAGE, NEC, DRY, NOT GROUND. PULVERIZED, OR SCREENED) FISH SCRAP, NEC. GREEN (FISH SCRAP (CONTAINING LESS THAN 6% OR MORE THAN 12% MOISTURE)) IRON MASS. (OR) SPONGE. SPENT (IRON SPONGE. SPENT, OR SPENT OXIDE) NICKEL CATALYST WET, IFINELY DIVIDED, SPENT) NICKEL CATALYST WET.(FINELY DIVIDED. ACTIVATED) PENTABORANE PHOSPHORUS. WHITE OR YELLOW. DRY PHOSPHORUS, WHITE OR YELLOW. IN WATER POTASSIUM SULFIDE IRON MASS OR SPONGE (NOT PROPERLY OXIDIZED) SODIUM HYDROSULFITE SODIUM SULFIDE. ANHYDROUS ROOFING OR FELT STOCK. WOOL, CONSISTING OF WOOL WASTE, SWEEPINGS. OR REFUSE (WATER WOOL, WET) WASTE WOOL. WET WOOL WASTE. NEC. OR WOOL SWEEPINGS (WASTE WOOL, WET) ALUMINUM METALLIC POWDER (POWDER. NEC. ALUMINUM) ALUMINUM, METALLIC. POWDER (POWDERS. ALUMINUM) ALUMINUM PHOSPHIDE CALCIUM METAL CALCIUM. METAL CRYSTALLINE CALCIUM CARBIDE CESIUM METAL LITHIUM ALUMINUM HYDRIDE LITHIUM ALUMINUM HYDRIDE. ETHEREAL LITHIUM AMIDE. POWDERED LITHIUM BOROHYDRIDE LITHIUM HYDRIDE LITHIUM METAL LITHIUM METAL, IN CARTRIDGES LITHIUM SILICON MAGNESIUM ALUMINUM PHOSPHIDE POTASSIUM. METAL LIQUID ALLOY SODIUM, METAL LIQUID ALLOY SODIUM POTASSIUM ALLOY (LIQUID) SODIUM POTASSIUM ALLOY (SOLID) RUBIDIUM METAL RUBIDIUM METAL. IN CARTRIDGES SODIUM AMIDE 57 100 113 113 114 114 114 114 114 114 136 534 114 153 248 266 248 6 249 250 250 250 250 293 363 363 394 409 409 425 293 466 475 451 529 535 20 22 21 99 101 97 113 315 315 315 315 316 316 317 317 319 425 476 474 475 455 455 462 MCI) 000017477 1427 1428 1429 1431 1432 1433 1437 1438 1439 1442 1445 1445 1446 1447 1446 1449 1452 1453 1454 1456 1457 1458 1459 1461 1461 1461 1463 1463 1466 1467 1469 1471 1472 1474 1475 1476 1477 1477 1479 1479 1479 1479 1479 1479 1479 1479 1479 1479 1479 1479 1479 1479 1479 1479 1479 1479 1479 1479 1479 1479 1479 1479 1481 1482 1484 1485 1486 1487 SODIUM HYDRIDE SODIUM. METALLIC SODIUM, METAL DISPERSION IN ORGANIC SOLVENT SODIUM METHYLATE. DRY SODIUM PHOSPHIDE STANNIC PHOSPHIDE ZIRCONIUM HYDRIDE ALUMINUM NITRATE AMMONIUM DICHROMATE (AMMONIUM BICHROMATE) AMMONIUM PERCHLORATE BARIUM CHLORATE BARIUM CHLORATE, WET BARIUM NITRATE BARIUM PERCHLORATE BARIUM PERMANGANATE BARIUM PEROXIDE CALCIUM CHLORATE CALCIUM CHLORITE CALCIUM NITRATE CALCIUM PERMANGANATE CALCIUM PEROXIDE CHLORATE AND BORATE MIXTURE CHLORATE AND MAGNESIUM CHLORIDE MIXTURE BLASTING CHLORATE (CHLORATE, N.O S.) CHLORATE. N.O.S. CHLORATE. N.O.S.. WET CHROMIC ACID MIXTURE. DRY CHROMIC ACID, SOLID FERRIC NITRATE GUANIDINE NITRATE LEAD NITRATE LITHIUM HYPOCHLORITE COMPOUND, DRY CONTAINING MORE THAN 39 PERCENT AVAILABLE CHLORINE LITHIUM PEROXIDE MAGNESIUM NITRATE MAGNESIUM PERCHLORATE MAGNESIUM PEROXIOE. SOLID NITRATE, N.O.S. NITRATE. N.O.S. (NITRATE OF SODA AND POTASH) AMMONIUM NITRATE, MAGNESIA AND PULP MIXTURE (OX IDIZING MATERIAL. N.O.S AMMONIUM NITRATE. SODIUM NITRATE MIXTURE (OXIDIZ ING MATERIAL, N.O.S.) COMPOUND. TREE OR WEED KILLINGS. SOLID COPPER NITRATE SOLUTION (CUPRIC NITRATE) COSMETICS. N.O.S. CUPRIC NITRATE DICHLOROISOCYANURIC ACID (OXIDIZING MATERIAL N.O.S.) DRUGS OR MEDICINES. N.O.S. FERTILIZING COMPOUNDS. NEC DRY (OXIDIZING MATE RIAL. N.O.S.) FLAME COLORING COMPOUNDS (OXIDIZING MATERIALS, N.O.S.) FLOUR BLEACHING COMPOUNDS. NEC (OXIDIZING MATE RIAL, N.O.S.) MEDICINES. N.O.S. NITROGEN SALTS. AGRICULTURAL, CRUDE (OXIDIZING MA TERIAL N.O.S.) OXIDIZER (OR) OXIDIZING MATERIAL, N.O.S. PERMANENT HAIR WAVING SETS, OTHER THAN ELECTRIC (OXIDIZING MATERIAL. N.O.S.) PLOSPHORIC CHEMICALS (OXIDIZING MATERIAL. N O S.) POTASSIUM ALKALI SALTS. CRUDE. DRY (OXIDIZING MA TERIALS, N.O.S) POTASSIUM DICHROMATE POTASSIUM NITRATE (SALTPETER). CRUDE (OXIDIZING MA TERIAL. N.O.S.) POTASSIUM PERSULFATE (OXIDIZING MATERIAL, N.O.S.) POTASSIUM SALTS, NEC (OXIDIZING MATERIALS, N.O.S.) SODIUM CHLORATE AND SODIUM CHLORIDE, IN WATER SOLUTION (OXIDIZING MATERIAL N.O.S.) SODIUM DICHROMATE SODIUM PERBORATE (OXIDIZING MATERIAL N.O.S.) PERCHLORATE. N.O.S. PERMANGANATE. N.O.S. POTASSIUM BROMATE POTASSIUM CHLORATE POTASSIUM NITRATE POTASSIUM NITRATE MIXED (FUSED) WITH SODIUM NITRITE 467 476 476 471 474 460 542 20 26 30 57 57 58 58 58 59 97 97 99 100 100 117 117 59 117 117 127 128 245 266 309 316 317 319 319 319 366 366 30 30 142 149 152 156 188 215 248 250 253 321 372 386 396 414 419 422 423 425 425 464 466 472 395 396 420 420 423 423 549 1487 1488 1489 1490 1491 1493 1494 1495 1496 1498 1500 1502 1503 1504 1506 1506 1507 1509 1510 1511 1512 1513 1514 1515 1516 1517 1541 1546 1547 1547 1549 1549 1549 1551 1553 1554 1555 1556 1556 1556 1557 1557 1557 1557 1557 1558 1559 1560 1560 1561 1562 1565 1566 1566 1566 1566 1566 1566 1569 1570 1571 1573 1573 1574 1575 1577 1578 1578 1578 1579 1580 SODIUM NITRITE MIXTURE fSODlUM NITRATE. SODIUM NI TRITE. AND POTASSIUM NITRITE) POTASSIUM NITRITE POTASSIUM PERCHLORATE POTASSIUM PERMANGANATE POTASSIUM PEROXIDE SILVER NITRATE SODIUM BROMATE SODIUM CHLORATE SODIUM CHLORITE SODIUM NITRATE SODIUM NITRITE SODIUM PERCHLORATE SODIUM PERMANGANATE SODIUM PEROXIDE STRONTIUM CHLORATE STRONTIUM CHLORATE. WET STRONTIUM NITRATE STRONTIUM PEROXIDE TETRANITROMETHANE UREA PEROXIDE ZINC AMMONIUM NITRITE ZINC CHLORATE ZINC NITRATE ZINC PERMANGANATE ZINC PEROXIDE ZIRCONIUM PICRAMATE. WET, (WITH AT LEAST 20% WATER) ACETONE CYANOHYDRIN AMMONIUM ARSENATE, SOLID ANILINE OIL LIQUID ANILINE OIL. LIQUID (ANILINE SLUDGE FOR FURNACE USE) ANTIMONY TRIBROMIDE. SOLID ANTIMONY TRIFLUORIDE SOLUTION ANTIMONY TRIFLUORIDE. SOLID ANTIMONY POTASSIUM TARTRATE SOLID ARSENIC ACID, SOLID (ARSENIC ACID FUSED) ARSENIC ACID SOLUTION (ARSENIC ACID OTHER THAN FUSED) ARSENIC BROMIDE. SOLID ARSENICAL COMPOUND, N.O.S. (OR) ARSENICAL MIXTURE, N.O.S. LIQUID METHYLDICHLOROAHSINE PHENYLDICHLOROARSINE. LIQUID ARSENIC IODIDE. SOLID ARSENIC SULFIDE. SOLID ARSENIC TRISULFIDE ARSENICAL COMPOUND. N.O.S., SOLID, (OR) ARSENICAL MIXTURE. N.O.S. SOLID ARSENICAL DIP. LIQUID (SHEEP DIP) ARSENIC, SOLID (ARSENIC METALLIC) ARSENIC PENTOXIDE. SOLID ARSENIC CHLORIDE. LIQUID ARSENIC TRICHLORIDE ARSENIC TRIOXIDE, SOLID (ARSENIC, WHITE. SOLID AR SENOUS ACID. SOLID) ARSENICAL DUST BARIUM CYANIDE. SOLID BERYLLIUM CHLORIDE BERYLLIUM COMPOUND. N.O.S. BERYLLIUM FLUORIDE BERYLLIUM HYDROXIDE (BERYLLIUM COMPOUND. N O S ) BERYLLIUM PHOSPHATE (BERYLLIUM COMPOUND. N.O.S.) BERYLLIUM SULFATE (BERYLLIUM COMPOUND. N.O.S ) BROMOACETONE. LIQUID BRUCINE, SOLID (DIMETHYL STRYCHNINE) BARIUM AZIDE, WET (50% OR MORE WATER) CALCIUM ARSENATE AND SULPHUR. DRY (CALCIUM ARSENATE) CALCIUM ARSENATE, SOLID CALCIUMARSENITE. SOLID CALCIUM CYANIDE, SOLID (OR) CALCIUM CYANIDE MIX TURE. SOLID DINITROCHLOROBENZOL. SOLID OR OINITROCHLOROBENZENE NITROCHLOROBENZENE. META, SOLID NITROCHLOROBENZENE, ORTHO, LIQUID NITROCHLOROBENZENE. PARA. SOLID (PARA- NITROCHLOROBENZENE) 4-CHLORO-O-TOLUIDINE HYDROCHLORIOE CHLOROPICRIN, LIQUID 472 424 424 424 424 458 463 464 464 472 472 473 473 473 481 481 488 482 496 522 537 538 540 540 541 543 3 24 40 40 44 45 46 43 48 48 48 51 346 403 49 49 50 51 51 51 49 49 50 50 52 57 68 69 69 69 70 70 77 78 57 96 96 101 98 205 370 371 371 120 124 1581 1582 1583 1583 1584 1585 1586 1587 1588 1589 1591 1592 1595 1597 1597 1599 1600 1600 1601 1601 1604 1605 1606 1607 1608 1611 1612 1613 1613 1616 1617 1617 1617 1617 1618 1620 1621 1622 1624 1624 1625 1626 1627 1628 1629 1629 1630 1631 1634 1634 1636 1637 1638 1638 1636 1639 1640 1641 1641 1642 1643 1644 1645 1646 1647 1648 1649 METHYL BROMIDE AND MORE THAN 2% CHLOROPICRIN MIXTURE. LIQUID CHLOROPICRIN AND METHYL CHLORIDE MIXTURE CHLOROPICRIN MIXTURE (CONTAINING NO COMPRESSED GAS OR POISON A LIQUID) CHLOROPICRIN. ABSORBED COCCULUS. SOLID COPPER ACETOARSENITE, SOLID COPPER ARSENITE, SOLID COPPER CYANIDE CYANIDE OR CYANIDE MIXTURE, DRY CYANOGEN CHLORIDE (CONTAINING LESS THAN 0.9% WATER) DICHLOROBENZENE, ORTHO. LIQUID DICHLOROBENZENE. PARA. SOLID DIMETHYL SULFATE DINITROBENZENE, SOLID OR DINITROBENZOL. SOLID DINITROBENZOL SOLUTION DINITROPHENOL SOLUTION DINITROTOLUENE, LIQUID DINITROTOLUENE. SOLID DISINFECTANT, LIQUID DISINFECTANT. SOLID ETHYLENEDIAMINE ETHYLENE DIBROMIDE (OR) 1.2-DIBROMOETHANE FERRIC ARSENATE, SOLID FERRIC ARSENITE, SOLID FERROUS ARSENATE, SOLID HEXAETHYL TETRAPHOSPHATE. LIQUID HEXAETHYLTETRAPHOSPHATE AND COMPRESSED GAS MIXTURE HYDROCYANIC ACID, SOLUTION HYDROCYANIC ACID, SOLUTION. LESS THAN 5% HYDRO CYANIC ACID LEAD ACETATE LEAD ARSENATE AND SULPHUR, DRY (LEAD ARSENATE. SOLID) LEAD ARSENATE. SOLID LEAD ARSENATE. SOLID (LEAD ARSENATE. PASTE) SULPHUR, ZINC SULPHATE AND LEAD ARSENATE (LEAD ARSENATE. SOLID) LEAD ARSENITE. SOLID LEAD CYANIDE LONDON PURPLE, SOLID MAGNESIUM ARSENATE, SOLID MERCURIC CHLORIDE MERCURIC CHLORIDE (MERCURIC CHLORIDE AND CHAR COAL CATALYST. SPENT) MERCURIC NITRATE MERCURIC-POTASSIUM CYANIDE. SOLID MERCUROUS NITRATE. SOLID MERCUROUS SULFATE, SOLID MERCURIC ACETATE MERCUROUS ACETATE, SOLID MERCURIC-AMMONIUM CHLORIDE, SOLID MERCURIC BENZOATE. SOLID MERCURIC BROMIDE. SOLID MERCUROUS BROMIDE. SOLID MERCURIC CYANIDE, SOLIO MERCUROUS GLUCONATE, SOLID MERCURIC IODIDE. SOLID MERCURIC IODIDE. SOLUTION MERCUROUS IODIDE. SOLID MERCUROL OR MERCURY NUCLEATE. SOLID MERCURIC OLEATE. SOLID MERCURIC OXIDE. SOLID MERCUROUS OXIDE, BLACK. SOLID MERCURIC OXYCYANIDE, SOLID (DESENSITIZED) MERCURIC-POTASSIUM IODIDE. SOLID MERCURIC SALICYLATE. SOLID MERCURIC SULFATE. SOLID MERCURIC SULFO CYANATE. SOLID (OR) MERCURIC THIOCYANATE METHYL BROMIDE AND ETHYLENE DIBROMIDE MIXTURE. LIQUID ACETONITRILE MOTOR FUEL ANTIKNOCK COMPOUND (OR) ANTIKNOCK COMPOUND (THESE MATERIALS MAY CONTAIN VARIOUS HAZARDOUS SUBSTANCE FOR WHICH THE APPROPRI ATE RQ APPLIES) 336 123 124 124 137 147 147 149 158 158 182 182 198 205 205 206 206 206 209 210 237 235 243 243 246 271 271 279 280 306 306 307 307 468 307 308 317 319 324 324 325 327 329 329 324 328 327 324 324 328 325 328 325 325 328 328 326 326 329 326 328 326 327 327 335 3 356 550 MCD 000017478 1649 1653 1654 1656 1657 1656 1656 1659 1660 1661 1661 1661 1662 1663 1664 1665 1670 1671 1677 1678 1680 1680 1684 1685 1686 1687 1689 1689 1690 1690 1691 1692 1692 1693 1693 1693 1693 1695 1697 1698 1700 1701 1703 1704 1704 1704 1705 1707 1707 1710 1712 1712 1713 1714 1715 1716 1717 1716 1719 1719 1722 1724 1725 1727 1728 1729 1730 1731 1732 1733 1733 1736 1737 1738 1739 1741 TETRAETHYL LEAD, LIQUID NICKEL CYANIDE, SOLID NICOTINE, LIQUID NICOTINE HYDROCHLORIDE NICOTINE SALICYLATE NICOTINE SULFATE, LIQUID NICOTINE SULFATE, SOLID NICOTINE TARTRATE NITRIC OXIDE NtTROANILINE ORTHO NITHO ANILINE PARANITROANILINE. SOLID NITROBENZOL NITROPHENOL NITROTOLUENE NITROXYLOL PERCHLOROMETHYL MERCAPTAN CARBOLIC ACID OR PHENOL POTASSIUM ARSENATE. SOLID POTASSIUM ARSENITE, SOLID POTASSIUM CYANIDE SOLUTION POTASSIUM CYANIDE, SOLID SILVER CYANIOE SODIUM ARSENATE. SOLID SODIUM ARSENITE, LIQUID, (SOLUTION) SODIUM AZIDE SODIUM CYANIDE SOLUTION SODIUM CYANIDE. SOLID SODIUM FLUORIDE SOLUTION SODIUM FLUORIDE. SOLID STRONTIUM ARSENITE, SOLID STRYCHNINE STRYCHNINE SALT, SOLID BROMBENZYL CYANIDE, LIQUID (IRRITATING AGENT, N.O.S.) DIPHENYLCHLORARSINE (IRRITATING AGENT, N.O.S.) IRRITATING AGENT. N.O.S. TEAR GAS SOLUTIONS (IRRITATING AGENT, N.O.S.) MONOCHLOROACETONE, STABILIZED OR INHIBITED CHLOROACETOPHENONE, GAS, LIQUID OR SOLID DIPHENYLAMINECHLOROARSINE TEAR GAS CANDLE XYLYL BROMIOE TETRAETHYL OITHIO PYROPHOSPHATE AND COM- PRESSED GAS MIXTURE TETRAETHYL DITHIOPYROPHOSPHATE MIXTURE, DRY TETRAETHYL DITHIOPYROPHOSPHATE MIXTURE, LIQUID TETRAETHYL DITHIOPYROPHOSPHATE. LIQUID TETRAETHYL PYROPHOSPHATE AND COMPRESSED GAS MIXTURE THALLIUM SALT, SOLID. N.O.S. THALLIUM SULFATE, SOLID TRICHLOROETHYLENE ZINC ARSENATE ZINC ARSENITE, SOLID ZINC CYANIDE ZINC PHOSPHIDE ACETIC ANHYDRIDE ACETYL BROMIDE ACETYL CHLORIDE N-BUTYL ACID PHOSPHATE ALKALINE CORROSIVE LIQUID, N.O.S. FATTY ALCOHOLS, ALIPHATIC OR CYCLIC. CYANOETHY- LATEO AND HYDROGENATED. AND DERIVATIVES THEREOF SUCH AS SALTS DIAMINES. OXYALKYLATES AND ALLYL CHLOROFORMATE (OR) ALLYL CHLOROCARBONATE ALLYL TRICHLOROSILANE ALUMINUM BROMIDE. ANHYDROUS. SOLID AMMONIUM HYDROGEN FLUORIDE, SOLID AMYL TRICHLOROSILANE ANISOYL CHLORIDE ANTIMONY PENTACHLORIDE ANTIMONY PENTACHLORIDE SOLUTION ANTIMONY PENTAFLUORIDE ANTIMONY TRICHLORIDE SOLUTION ANTIMONY TRICHLORIDE, SOLID BENZOYL CHLORIDE BENZYL BROMIDE (BROMOTOLUENE. ALPHA) BENZYL CHLORIDE BENZYL CHLOROFORMATE BORON TRICHLORIDE 492 363 366 365 365 365 366 366 368 369 366 392 369 374 375 376 395 105 419 420 421 421 458 462 462 462 465 465 466 467 481 482 482 76 208 294 491 352 120 208 491 536 491 492 492 492 493 497 497 508 537 537 539 541 2 4 5 81 17 242 16 19 19 27 39 41 42 43 43 44 45 65 68 68 68 74 1742 1744 1745 1746 1747 1746 1749 1750 1751 1752 1753 1754 1754 1755 1756 1757 1758 1759 1759 1759 1759 1759 1759 1759 1759 1759 11759 1759 1759 1759 1759 1759 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 BORON TRIFLUORIDE-ACETlC ACID COMPLEX BROMINE BROMINE PENTAFLUORIDE BROMINE TRIFLUORIDE BUTYL TRICHLOROSILANE CALCIUM HYPOCHLORITE MIXTURE (DRY. CONTAINING MORE THAN 39 PERCENT AVAILABLE CHLORINE) CHLORINE TRIFLUORIDE MONOCHLOROACETIC ACID, LIQUID CHLOROACETIC ACID, SOLID CHLOROACETYL CHLORIDE CHLOROPHENYL TRICHLOROSILANE CHLOROSULFONIC ACID CHLOROSUNFONIC ACID-SULFUR TRIOXIDE MIXTURE CHROMIC ACID SOLUTION CHROMIC FLUORIDE. SOLID CHROMIC FLUORIDE SOLUTION CHROMYL CHLORIDE (OR) CHROMIUM OXYCHLORIDE ACID, NEC, DRY, ORGANIC (CORROSIVE SOLID. N.O.S.) ACIDS. INORGANIC, NEC, DRY (CORROSIVE SOLID, N.O.S.) ALUMINUM CHLORIDE. DRY (CORROSIVE SOLID. N.O.S ) BATTERY SETS FOR WET BATTERIES (CORROSIVE SOLID. N.O.S,) BATTERY SETS IN BATTERY BOXES (CORROSIVE SOLID. N.O.S.) BUTYL PHENOL (CORROSIVE SOLID, N.O.S ) CLEANING COMPOUNDS. IRON OR STEEL, DRY (CORRO SIVE SOLID. N.O.S.) COAL TAR OIL CRUDE. NEC (CORROSIVE SOLID. N.O.S.) COMPOUNDS, STONE STENCIL. IN SHEET FORM (CORRO SIVE SOLID, N.O.S.) COMPOUNDS. WATER SYSTEM RUST OR SCALE PREVENTING. DRY (CORROSIVE SOLID, N.O.S.) CORROSIVE SOLID. N.O.S. COSMETICS, N.O.S., SOLID DRUGS. N.O.S., SOLID FERROUS CHLORIDE. SOLID LIME SALTS. NEC (CORROSIVE SOLID. N.O.S.) ACIDS, INORGANIC. NEC, LIQUID (ACIDS. LIQUID. N.O.S.) ACIDS, LIQUID. N.O.S. (ACIDS. NEC, LIQUID. ORGANIC) ALUMINUM PHOSPHATE SOLUTION ALUMINUM SULFATE SOLUTION 2-(2-AMINOETHOXY) ETHANOL AMINOETHYLETHANOLAMINE (CORROSIVE LIQUID. N.O.S.) N-AMINOPROPYL MORPHOLINE BIS-(AMINOPROPYL) PIPERAZINE AMINOPROPYLDIETHANOL AMINE AMYL PHENOL (CORROSIVE LIQUID. N.O.S.) ASPHALT ADDITIVE. ANTI-STRIPPING (CORROSIVE LIQUID, N.O.S.) BARIUM HYDROXIDE MONOHYDRATE (CORROSIVE SOLID, N.O.S.) BOILER COMPOUNDS. LIQUID CHEMICAL KIT CHEMICAL PLANT WASTE, NEC (CORROSIVE LIQUID, N.O.S.) CHLORAL (CORROSIVE LIQUID, N.O.S.) CHLORINATED LIME, LIQUID (CORROSIVE LIQUID. N.O.S.) CHROME CHLORIDE SOLUTION (CORROSIVE UQUIO, N.O.S ) CLEANING COMPOUND, IRON OR STEEL LIQUID (COM POUND. CLEANING. LIQUID) COAL TAR OIL CRUDE, NEC (CORROSIVE LIQUID, N.O.S.) COMPOUND. CLEANING. LIQUID COMPOUND. CLEANING, LIQUID (CONTAINING PHOS PHORIC OR ACETIC ACIDS) COMPOUND. CLEANING. LIQUID (CONTAINING SODIUM OR POTASSIUM HYDROXIDE) COMPOUND. LACQUER. PAINT OR VARNISH REMOVING LIQUID COMPOUND. TREE (OR) WEED KILLING. LIQUID COMPOUND, VULCANIZING, LIQUID COMPOUNDS. PETROLEUM TREATING, CRUDE. NEC (ACID, LIQUID. N.O.S.) COMPOUNDS. RUST PREVENTING (OR) COMPOUND RUST REMOVING CORROSIVE LIQUID. N.O.S. COSMETICS, N.O.S., LIQUID DE-INKING COMPOUNDS USED IN RECYCLING PAPER (COR ROSIVE LIQUID. N.O.S.) 2.2-DICHLOROPROPIONIC ACID DIETHYL SULFATE (CORROSIVE LIQUID. N.O.S.) 74 76 76 77 93 98 119 352 120 120 123 125 125 128 128 128 129 6 7 19 60 60 92 130 135 145 146 151 152 216 246 312 7 7 20 21 22 22 22 23 23 38 54 58 72 115 116 116 118 127 130 135 138 139 140 140 141 142 144 145 151 152 163 168 192 551 MCB 000017479 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1760 1761 1762 1763 1764 1765 1766 1767 1768 1769 1770 1770 1771 1773 1774 DIETHYLENETRIAMINE (CORROSIVE LIQUID. N.O.S.} DRUGS, N.O.S.. LIQUID ETHYL PHOSPHONOTHIOlC DICHLOfllOE. ANHYDROUS ETHYL PHOSPHORODICHLORIDATE FERROUS CHLORIDE, SOLUTION FERTILIZER SOLUTION. CONSISTING OF WATER, FREE AM MONIA AND SULPHUR, TOTAL AMMONIA CONTENT NOT TO EXCEED 30 PERCENT BY WEIGHT (CORROSIVE LIQ UID, N.O.S.} FIRE PROOFING COMPOUNDS. LIQUID. NEC (CORROSIVE LIQUID, N.O.S.) FLAME RETARDANT COMPOUND. LIQUID FUEL OIL TREATING COMPOUNDS (CORROSIVE LIQUID, N.O.S.) GLYCERINE. CRUDE. (SPENT LYE). CONCENTRATED (COR ROSIVE LIQUID. N.O.S.) HEXANOIC ACID HYDROXYETHYLACRYLATE (CORROSIVE UQUID.N.O.S.) HYDROXYPROPYL ACRYLATE (CORROSIVE LIQUID. N O S ) INSECTICIDE ADHESIVES, SPREADERS OR STICKERS. LIQ UID (CORROSIVE LIQUID. N.O.S.) ISOPENTANOIC ACID LACTIC ACID (HYDROXYPROPIONIC ACID) (ACID, LIQUID. N.O.S.) MEMTETRAHYDROPHTHALIC ANHYDRIDE METHACRYLIC ACID, GLACIAL (CORROSIVE LIQUID. N.O.S ) METHYL PHOSPHONOTHIOlC DICHLORIDE. ANHYDROUS MONOISOPROPANOLAMINE (CORROSIVE LIQUID. N.O.S.) MORPHOLINE. AEQUOUS MIXTURE NICKEL PLATING SOLUTION (CORROSIVE LIQUID. N.O.S.) NITRIC ACID. 40% OR LESS PETROLEUM ALKYLATE DETERGENT INTERMEDIATE (COR ROSIVE LIQUID. N.O.S.) PETROLEUM REFINERY SULFIDE WASTE (CORROSIVE LIQ UID. N.O.S ) SLUDGE.ALKALAI. CONTAINING NOT LESS THAN 75% WATER (CORROSIVE LIQUID. N.O.S.) SMOKE FLUE CLEANING COMPOUNDS (COMPOUND. CLEANING. LIQUID) SODIUM SOLUTION WASTE (CORROSIVE LIQUID. N.O.S.) SOLDERING FLUX OR SALTS. NEC. LIQUID (CORROSIVE LIQ UID. N.O.S ) SOLUTION, COPPER PLATING (CORROSIVE LIQUID. N.O.S.) SULFATES. MIXED ETHYL. CONSISTING OF MONOETHYL AND DIETHYL SULFATE (CORROSIVE LIQUID, N.O.S.) SULFIDE WASTE (CORROSIVE LIQUID. N O S.) TANNER'S DIPtLATORY. NEC (CORROSIVE LIOUID, N.O.S.) TEXTILE TREATING COMPOUNDS MIXTURE. LIQUID TITANIUM SULFATE SOLUTION (CONTAINING NOT MORE THAN 45% SULFURIC ACID) TRIETHYLENETETRAMINE (CORROSIVE LIQUID. NOS) VALERIC ACID WASTE ETCHANT SOLUTION, SUITABLE ONLY FOR RECLA MATION OFMETALLIC CONTENT (CORROSIVE LIQUID. N.O.S.) WASTE LIQUOR. CONSISTING OF NOT LESS THAN 50 PER CENT BY WEIGHT OF WATER. RESULTING FROM SUL PHATE OR SODA PULPING PROCESS (CORROSIVE LIQ UID. N.O.S-1 WATER TREATMENT COMPOUND, LIQUID WHITE ACID (AMMONIUM BIFLUORIDE AND HYDROCHLORIC ACID MIXTURE) WOOD BLEACH (CORROSIVE LIQUID, N.O.S.) ZINC CHLORIDE CHEMICAL PLANT WASTE (CORROSIVE LIQUID. N.O.S.) CUPRIETHYLENE-DIAMINE SOLUTION CYCLOHEXENYL TRICHLOROSILANE CYCLOHEXYL TRICHLOROSILANE DICHLOROACETIC ACID DICHLOROACETYL CHLORIDE DICHLOROPHENYL TRICHLOROSILANE DIETHYL DICHLOROSILANE DIFLUOROPHOSPHORIC ACID, ANYDROUS DIPHENYL DICHLOROSILANE DIPHENYL METHYL BROMIDE. SOLID DIPHENYL METHYL BROMIDE. SOLUTION DODECYL TRICHLOROSILANE FERRIC CHL0RI0E SOLIO FIRE EXTINGUISHER CHARGES CONTAINING SULFURIC ACID 193 216 231 223 246 247 249 250 257 265 274 264 285 290 299 305 323 332 343 354 355 364 368 397 400 457 460 475 476 477 485 485 489 496 501 511 522 528 528 531 531 534 538 157 161 161 182 182 187 192 194 207 207 208 214 244 249 552 MCI) ^00017^30 1775 1776 1777 1778 1779 1779 1780 1781 1782 1783 1784 1786 1787 1788 1788 1789 1789 1789 1789 1789 1790 1790 1790 1791 1791 1791 1791 1791 1792 1793 1794 1794 1794 1796 1798 1790 1799 1800 1801 1802 1804 1605 1805 1805 1806 1807 1808 1809 1810 1811 1812 1813 1814 1814 1816 1817 1818 1819 1823 1823 1824 1824 FLUOBORIC ACID MONOFLUOROPHOSPHORIC ACID. ANHYDROUS FLUOSULFONIC ACID (OR) FLUOROSULFONIC ACID HYDROFLUOSILlCIC. ACID FORMIC ACID FORMIC ACID SOLUTION FUMARYL CHLORIDE HEXADECYL TRICHLOROSILANE HEXAFLUOROPHOSPHORIC ACID HEXAMETHYLENE DIAMINE SOLUTION HEXYL TRICHLOROSILANE HYDROFLUORIC AND SULFURIC ACID MIXTURES HYDRIODIC ACID HYDROBROMIC ACID (MORE THAN 49% STRENGTH) HYDROBROMIC ACID, NOT MORE THAN 49% STRENGTH COMPOUND, CLEANING, LIQUID (CONTAINING HYDRO CHLORIC (MURIATIC) ACID) HYDROCHLORIC ACID HYDROCHLORIC ACID (MURIATIC ACID. SPENT) HYDROCHLORIC ACID MIXTURE HYDROCHLORIC ACID SOLUTION, INHIBITED COMPOUND. CLEANING. LIOUID (CONTAINING HYDRO FLUORIC ACID) ETCHING ACID. LIQUID. N.O.S. HYDROFLUORIC ACID SOLUTION HYPOCHLORITE SOLUTION (CONTAINING MORE THAN 7% AVAILABLE CHLORINE BY WEIGHT) HYPOCHLORITE SOLUTION CONTAINING NOT MORE THAN 7% AVAILABLE CHLORINE (BY WEIGHT) POTASSIUM HYPOCHLORITE SOLUTION SODIUM HYPOCHLORITE SOLUTION (HYPOCHLORITE SO LUTION CONTAINING NOT MORE THAN 7% AVAILABLE CHLORINE (BY WEIGHT)) SODIUM HYPOCHLORITE SOLUTION (HYPOCHLORITESOLUTION (CONTAINING MORE THAN 7% AVAILABLE CHLOR INE BY WEIGHT) IODINE MONOCHLORIDE ISOPROPYL ACID PHOSPHATE. SOLID LEAD SULFATE. SOLID (CONTAINING MORE THAN 3% FREE ACID) LEAD SULPHATE, CRUDE (LEAD SULFATE) LEAD SULPHATE, REFINED (LEAD SULFATE) NITRATING (MIXED) ACID NITROHYDROCHLORIC ACID NITROHYDROCHLORIC ACID. DILUTED NONYL TRICHLOROSILANE OCTADECYL TRICHLOROSILANE OCTYL TRICHLOROSILANE PERCHLORIC ACID. NOT OVER 50% ACID PHENYL TRICHLOROSILANE PHOSPHATIC FERTILIZER SOLUTION (PHOSPHORIC ACID) PHOSPHORIC ACID (UQUIDl OR PHOSPHORIC ACID SOLUTION WASTE PHOSPHATE FILTER CAKE SLUDGE. CONTAINING NOT MORE THAN 50% P205 (PHOSPHORIC ACID) PHOSPHORUS PENTACHLORIDE. SOLID PHOSPHORIC ANHYDRIDE PHOSPHORUS TRIBROMIDE PHOSPHORUS TRICHLOHIDE PHOSPHORUS OXYCHLORIDE POTASSIUM HYDROGEN FLUORIDE SOLUTION POTASSIUM FLUORIDE SOLUTION POTASSIUM HYDROXIDE. DRY. SOLID. FLAKE. BEAD. OR GRANULAR CAUSTIC SODA AND CAUSTIC POTASH. MIXED. IN SOLU TION (POTASSIUM HYDROXIDE. LIQUID (OR) SOLUTION) POTASSIUM HYDROXIDE. LIQUID (OR) SOLUTION PROPYL TRICHLOROSILANE PYROSULFURYL CHLORIDE SILICON CHLORIDE (OR) SILICON TETRACHLORIDE SODIUM ALUMINATE. SOLUTION LYE. CONCENTRATED. NEC (SODIUM HYDROXIDE, DRY. SOLID. FLAKE. BEAD OR GRANULAR) SODIUM HYDROXIDE. DRY. SOLID, FLAKE. BEAD, OR GRANULAR CAUSTIC SODA AND CAUSTIC POTASSIUM, MIXED, IN SO LUTION (SODIUM HYDROXIDE LIQUID (OR) SOLUTION) CAUSTIC SODA SOLUTION SPENT (SODIUM HYDROXIDE SOLUTION) 253 354 254 281 256 256 258 269 271 273 274 281 276 276 277 139 278 278 278 278 139 224 280 285 265 423 469 470 292 300 310 310 310 367 373 374 376 377 379 395 402 405 405 529 407 406 408 406 406 422 422 422 110 423 431 436 457 461 318 469 110 111 1324 1824 1824 1825 1826 1827 1828 1828 1829 1829 1830 1831 1832 1833 1834 1835 1836 1837 1838 1839 1840 1840 1841 1846 1848 1848 1850 1851 1851 1651 1856 1857 1858 1859 1860 1862 1863 1863 1864 1864 1866 1867 1866 1869 1869 1872 1872 1873 1885 1888 1868 1869 1698 1902 1902 1903 1905 1906 1906 1907 1906 1911 1911 1912 1917 1919 1921 1922 1928 1931 SODIUM HYDROXIDE AND SODIUM BOROHYDRIDE SOLU TION N.O.S.) SODIUM HYDROXIDE LIOUID SODIUM HYDROXIDE, LIQUID (OR) SOLUTION (CAUSTIC SO DIUM (SODIUM HYDROXIDE) CONTAINING NOT LESS THAN 48 PERCENT WATER BY WEIGHT IN SOLUTION) SODIUM MONOXIDE, SOLID NITRATING ACID, SPENT TIN TETRACHLORIDE. ANHYDROUS SULFUR CHLORIOE (Dl) SULFUR CHLORIDE (MONO) SULFUR TRIOXIDE (SULFUR TRIOXIDE, UNSTABILIZED) SULFUR TRIOXIDE. STABILIZED SULFURIC ACID OLEUM (SULFURIC ACID FUMING) SULFURIC ACID, SPENT SULFUROUS ACID SUIFURYL CHLORIDE TETRAMETHYL AMMONIUM HYDROXIDE, LIOUID THIONYL CHLORIDE THIOPHOSPHORYL CHLORIDE TITANIUM TETRACHLORIDE TRICHLOROACETIC ACID, SOLID TINNING FLUX ZINC CHLORIDE SOLUTION ACETALDEHYDE AMMONIA CARBON TETRACHLORIDE PROPIONIC ACID PROPIONIC ACID SOLUTION ERADICATOR, PAINT OR GREASE. LIQUID MEDICINES, N.O.S, MEDICINES. N.O.S., LIOUID MEDICINES, N.O.S., SOLID RAGS. OILY TEXTILE WASTE. WET HEXAFLUOROPROPYLENE SILICON TETRAFLUORIDE VINYL FLUORIDE, INHIBITED ETHYL CROTONATE FUEL, AVIATION, TURBINE ENGINE FUEL, AVIATION, TURBINE. ENGINE GAS DRIPS, HYDROCARBON GAS DRIPS, HYDROCARBON RESIN SOLUTION (RESIN COMPOUND, LIQUID) SELF-LIGHTING CIGARETTE DECABORANE MAGNESIUM SCRAP (BORINGS, CUPPINGS, SHAVINGS. SHEET, TURNINGS, OR SCALPINGS) MAGNESIUM, METAL (POWDERED, PELLETS. TURNINGS OR RIBBONS) LEAD PEROXIDE, GROUND. DRY (LEAD PEROXIDE LEAD PEROXIDE. PASTE (LEAD PEROXIDE) PERCHLORIC ACID (EXCEEDING 50% BUT NOT EXCEEDING 72%) BENZIDINE CHLOROFORM (CHLOROFORM (TRICHLORMETHANE). NEC, OTHER THAN TECHNICAL GRADE) CHLOROFORM (CHLOROFORM. NEC. TECHNICAL GRADE (TRICHLOROMETHANE)) CYANOGEN BROMIDE ACETYL IODIDE DK2-ETHYIHEXYL) PHOSPHORIC ACID DIISOOCTYL ACID PHOSPHATE DISINFECTANT, LIQUID SELENIC ACID, LIQUID SLUDGE ACID SLUDGE. ACID, CONTAINING NOT LESS THAN 75% WATER (SLUDGE ACID) SODA LIME. SOLID SODIUM CHLORITE SOLUTION (NOT EXCEEDING 42% SO DIUM CHLORITE) DIBORANE DIBORANE MIXTURES METHYL CHLORIDE-METHYLENE CHLORIDE MIXTURE ETHYL ACRYLATE. INHIBITED METHYLACRYLATE, INHIBITED PROPYLENE (MINE, INHIBITED PYROLIOINE METHYL MAGNESIUM BROMIDE IN ETHYL ETHER ZINC HYOROSULFITE 468 469 469 471 367 500 485 486 486 487 487 379 487 488 488 488 498 49B 502 510 500 539 1 109 429 429 223 322 322 323 445 497 271 457 526 229 257 257 261 266 447 456 163 320 320 309 309 395 63 122 122 158 4 167 196 209 454 458 459 461 464 178 179 337 226 345 433 436 340 540 WCI) 00174Qi 1932 1935 1938 1936 1939 1940 1942 1942 1944 1951 1954 1954 1954 1954 1954 1954 1954 1954 1954 1954 1954 1954 1954 1954 1955 1955 1955 1955 1956 1956 1956 1956 1956 1956 1956 1956 1956 1956 1956 1956 1956 1956 1956 1956 1956 1956 1956 1956 ZIRCONIUM METAL SCRAP (BORINGS CLIPPINGS, SHAV INGS SHEETS, OR TURNINGS CYANIDE SOLUTION, N.O.S. BROMOACETIC ACID SOLUTION BROMOACETIC ACID, SOLID PHOSPHORUS OXYBROMIDE THIOGLYCOLIC ACID AMMONIUM NITRATE (NO ORGANIC COATING) AMMONIUM NITRATE (ORGANIC COATING) MATCHES. SAFETY (BOOK, CARD OR STRIKE ON BOX) ARGON PRESSURIZED LIQUI0 ARGON-HYDROGEN GAS MIXTURE (COMPRESSED GAS, N.O.S.) ARGON-METHANE GAS MIXTURE (COMPRESSED GAS, N O S ) CARBON DIOXIDE-ETHYLENE OXIDE MIXTURE (COM PRESSED GAS, N.O.S.) CARBON DIOXIDE-PROPYLENE OXIDE MIXTURE (COM PRESSED GAS, N.O.S) COMPRESSED GAS, N.O.S. DISPERSANT GASES, NEC, FLAMMABLE (COMPRESSED GAS, N.O.S.) ETHYLENE OXIDE-D1CHLORODIFLUOROMETHANE MIX TURE (COMPRESSED GAS. N.O.S. HELIUM-BUTANE GAS. MIXTURE (COMPRESSED GAS. N.O.S) HELIUM-ISOBUTANE GAS MIXTURE (COMPRESSED GAS. N.O.S.) NITROGEN-HYDROGEN GAS MIXTURE (COMPRESSED GAS. N.O.S) REFRIGERANTS, NEC, LIQUID. FLAMMABLE (COMPRESSED GAS, N.O.S.) REFRIGERATING MACHINE (COOLING ROOMS. COOLING BOXES OR REFRIGERATORS. OTHER THAN HOUSEHOLD TYPE) REFRIGERATING MACHINE (ICE CREAM POWER FREEZERS AND MECHANICAL REFRIGERATORS) REFRIGERATING MACHINE (REFRIGERATORS. NEC) CHLORPICRIN AND NONFLAMMABLE. NONLIQUEFIED COM PRESSED GAS MIXTURE METHYL BROMIDE AND NONFLAMMABLE NONLIQUEFIED COMPRESSED GAS MIXTURE. LIQUID ORGANIC PHOSPHATE. ORGANIC PHOSPHATE COM POUND, OR ORGANIC PHOSPHORUS COMPOUND; MIXED WITH COMPRESSED GAS POISONOUS GAS. N.O.S. ACCUMULATOR. PRESSURIZED AMMONIACAL LIQUOR (COMPRESSED GAS, N.O.S.) ARGON OXYGEN GAS MIXTURE (COMPRESSED GAS, N.O.S.) ARGON-CARBON DIOXIDE GAS MIXTURE (COMPRESSED GAS. N.O.S.) ARGON-HYDROGEN GAS MIXTURE (COMPRESSED GAS, N.O.S.) ARGON-METHANE GAS MIXTURE (COMPRESSED GAS. N O S.) ARGON-NITROGEN GAS MIXTURE (COMPRESSED GAS. N.O.S.) CARBON OIOXIDE-AIR MIXTURE (COMPRESSED GAS, N O S.) CARBON DIOXIDE-ETHYLENE OXIDE GAS MIXTURE (COM PRESSED GAS. N.O.S.) CARBON OlOXIDE-NITHOGEN GAS MIXTURE (COMPRESSED GAS, N.O.S.) CARBON OIOXIDE-PROPYLENE OXIDE GAS MIXTURE (COM PRESSED GAS. N.O.S.) COMPRESSED GAS. N.O.S. DICHLORODIFLUOROMETHANE-DICHLOROTETRAFLUO- ROETHANE MIXTURE DICHLORODIFLUOROMETHANE-MONOCHLORODIFLUORO- METHANE MIXTURE DICHLORODIFLUOROMETHANE-MONOCHLOROTRIFLUO- ROMETHANE MIXTURE DICHLORODIFLUOROMETHANE-TRICHLOROMONOFLUOROMETHANE-MONOCHLORODIFLUORO- METHANE MIXTURE DICHLORODIFLUOROMETHANE-TRICHLOROTRIFLUOROETHANE MIXTURE DISPERSANT GASES. NEC (COMPRESSED GAS. N.O.S.) ETHYLENE OXIDE - DICHLORODIFLUOROMETHANE GAS MIXTURE (COMPRESSED GAS, N.O.S.) FLUOROETHANE GASES, NONFLAMMABLE (COMPRESSED GAS, N.O.S.) 542 156 77 77 406 497 28 28 321 46 47 47 107 108 146 210 237 268 268 373 445 446 446 447 125 336 382 415 1 24 46 47 47 47 47 107 107 108 108 146 185 185 185 185 185 210 237 25 553 1966 GAS MIXTURE. NEC. COMPRESSED. OTHER THAN POISON 1956 1956 (COMPRESSED GAS. N.O.S.) HELIUM - ARGON GAS MIXTURE (COMPRESSED GAS. N.O.S.) HELIUM-BUTANE GAS MIXTURE (COMPRESSED GAS. N.O.S ) 1956 HELIUM-CARBON DIOXIDE-NITROGEN MIXTURE ICOM- PRESSED GAS, N.O.S.) 1956 HELIUM-ISOBUTANE GAS MIXTURE (COMPRESSED GAS, NO.S) 1956 HELIUM-NITROGEN MIXTURE (COMPRESSED GAS, N.C S.) 1956 HEXAFLUOROPROPYLENE OXIDE 1956 MINE RESCUE EQUIPMENT CONTAINING CARBON DIOXIZ'E 1956 NITROGEN-HYDROGEN GAS MIXTURE (COMPRESSED GAo. N.O.S.) 1956 OXYGEN - NITROGEN GAS MIXTURE (COMPRESSED GAS. N.O.S.) 1956 REFRIGERANTS. NEC, LIQUID OR GAS (COMPRESSED GAS. N.O.S.) 1956 WATER PUMP SYSTEM CHARGED WITH COMPRESSED AIR OR NITROGEN 1960 ENGINE STARTING FLUID 1962 ETHYLENE 1964 HYDROCARBON GAS. NONLIQUEFIED 1964 HYDROCARBON GAS, NONLIQUEFIED (COAL GAS) 1965 HYDROCARBON GAS, LIQUEFIED 1966 HYDROGEN. LIQUEFIED 1967 INSECTICIDE. LIQUIEFIED GAS. CONTAINING POISON A MA- TERIAL OR POISON B MATERIAL 1967 PARATHION AND COMPRESSED GAS MIXTURE 1968 INSECTICIDE. LIQUEFIED GAS 1971 METHANE 1977 NITROGEN. PRESSURIZED LIQUID I960 HELIUM OXYGEN MIXTURE 1986 DENATURED ALCOHOL 1986 PROPARGYL ALCOHOL 1986 RUM. DENATURED 1987 ACTIVE PRIMARY AMYL ALCOHOL (ALCOHOL. N.O.S.) 1987 ACTIVE SEC-AMYL ALCOHOL (ALCOHOL. N.O.S.) 1987 ALCOHOL DISTILLATES. SYNTHETIC (ALCOHOL. N.O.S.) 1987 ALCOHOL DISTILLATES. SYNTHETIC (ALCOHOL. N O S.) 1987 ALCOHOL. CONTAMINATED, SUITABLE FOR ONLY BLEND- ING OR REDISTILLING PURPOSES (ALCOHOL. N.O.S.) 1987 ALCOHOL. N.O.S. 1987 ALCOHOL. N.O.S. 1987 ALCOHOLS. FATTY OR CYCLIC. ETHOXYLATED (ALCOHOL.N.O.S ) 1987 TERT-AMYL ALCOHOL (ALCOHOL. N.O.S.) 1987 N-SEC-AMYL ALCOHOL (ALCOHOL. N O S.) 1987 ANTI-FREEZE ALCOHOLS (ALCOHOL, N.O.S.) 1987 ANTI-FREEZE ALCOHOLS (ALCOHOL, N.O.S.) 1987 DECYL ALCOHOL OTHER THAN PERFUMERY GRADE (AL- COHOL, N.O.S.) 1987 DENATURED ALCOHOL SOLVENT, (ALCOHOL, N.O.S.) 1987 DENATURED ALCOHOL. SOLIDIFIED (ALCOHOL. N.O.S.) 1987 DENATURING ALCOHOL. NEC (ALCOHOL. N.O.S.) 1987 DENATURING ALCOHOL. NEC (ALCOHOL N.O.S.) 1987 DI1SOBUTYLCARBINOL (COMBUSTIBLE LIQUID. N.O.S.) 1987 ETHYL ALCOHOL. ANHYDROUS. DENATURED IN PART WITH GASOLINE. GASOLINE CONTENT NOT TO EXCEED 5 PER CENT (ALCOHOL. N.O.S.) 1987 FATTY ALCOHOLS. ANIMAL FAT OR ANIMAL. FISH, PETRO- LEUM, SEA-ANIMAL OR VEGETABLE OILS. NEC, WHEN BLENDED WITH EACH OTHER. LIQUID (ALCOHOL. N.O.S ) 1987 FURFURYL ALCOHOL (ALCOHOL N.O.S.) 1987 HEXYL ALCOHOL OTHER THAN PERFUMERY GRADE (AL- COHOL N.O.S.) 1987 ISO HEPTYL ALCOHOL (ALCOHOL N.O.S.) 1987 ISOAMYL ALCOHOL (ALCOHOL, N 0-S.) 1987 ISOOCTYL ALCOHOL. OTHER THAN PERFUMERY GRADE (ALCOHOL. N.O.S.) 1987 ISOOCTYL ALCOHOL, PERFUMERY GRADE (ALCOHOL N.O.S ) 1987 ISOPROPANOL AND METHANOL MIXTURE (ALCOHOL N.O.S.) 1987 METHANOL. CONTAMINATED, VALUE ONLY FOR REFINING (ALCOHOL N.O.S.) 1987 METHANOL, SOLIDIFIED (ALCOHOL N.O.S.) 1987 METHYL ISOBUTYL CARBINOL (COMBUSTIBLE LIQUIO, N O S ) 1987 OCTYL ALCOHOL. OTHER THAN PERFUMERY GRADE (AL- COHOL. N.O.S.) 1987 OCTYL ALCOHOL PERFUMERY GRADE (ALCOHOL, N.O.S.) 1987 PLASTICIZER ALCOHOL (ALCOHOL. N.O.S.) 1987 PLASTICIZER ALCOHOL (ALCOHOLS. N.O.S.) 262 267 267 268 268 268 272 351 373 388 445 30 223 23-J 277 277 277 284 292 392 291 333 373 267 165 427 455 9 9 11 11 13 13 14 14 37 37 41 41 164 165 165 166 166 195 227 242 260 274 294 294 298 298 300 333 333 339 378 378 414 414 1987 1987 1987 1987 1987 1987 1989 1991 1992 1992 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 993 1J93 1991 199( 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 PRIMARY N-AMYL ALCOHOL (ALCOHOL. N.O.S.) 1-PROPANOL (ALCOHOL. N.O.S.) RUBBING ALCOHOL COMPOUNDS (ALCOHOL, N.O.S.) RUBBING ALCOHOL COMPOUNDS (ALCOHOL, N.O.S.) TALLOW ALCOHOL (ALCOHOL, N.O.S.) TALLOW ALCOHOL (ALCOHOL N.O.S.) BENZALDEHYDE CHLOROPRENE. INHIBITED DINITROPHENOL (FLAMMABLE SOLID, POISONOUS. N.O S.) FLAMMABLE LIQUID. POISONOUS. N.O.S. ACRYLAMIDE SOLUTION (COMBUSTIBLE LIQUID. N.O.S.) ACRYLAMIDE SOLUTION (FLAMMABLE LIQUID. N.O.S.) ADDITIVES. FUEL OIL. GASOLINE OR LUBRICATING OIL. CONTAINING LESS THAN 50% BY WEIGHT PETROLEUM OIL (FLAMMABLE LIQUID. N.O.S ) ADDITIVES. FUEL OIL. GASOLINE OR LUBRICATING OIL, CONTAINING LESS THAN 50% BY WEIGHT OF PETRO LEUM (COMBUSTIBLE LIQUID, N.O.S.) AFTER SHAVE LOTIONS (COMBUSTIBLE LIQUID. N.O.S.) AFTER SHAVE LOTIONS (FLAMMABLE LIQUID. N.O.S.) ALCOHOL CONTAMINATED. SUITABLE ONLY FOR BLENDING OR REDISTILLING PURPOSES (ALCOHOL N.O.S.) ALCOHOLS. FATTY OR CYCLIC, ETHOXYLATED (ALCOHOL.N.O.S.) ALDOL (COMBUSTIBLE LIQUID. N O.S.) AMYL NITRATE (COMBUSTIBLE LIQUID. N.O.S.) AROMATIC CONCENTRATES. SUITABLE ONLY FOR FUR- THER PROCESSING (COMBUSTIBLE LIQUID. NO.S ) AROMATIC CONCENTRATES, SUITABLE ONLY FOR FUR- THER PROCESSING (FLAMMABLE LIQUID. N.O.S.) ASPHALT PAVEMENT SURFACE SEALER. ASPHALT, COAL TAR OR PETROLEUM BASE (COMBUSTIBLE LIQUID. N.O.S.) ASPHALT PAVEMENT SURFACE SEALER. ASPHALT. COAL TAR OR PETROLEUM BASE (FLAMMABLE LIQUID. N.O.S.) ASPHALT TILE. PLASTICIZER (COMBUSTIBLE LIQUID.N.O.S.) ASPHALT TILE. PLASTICIZER (FLAMMABLE LIQUID. N.O.S.) BATTERY BOX COMPOUNDS (COMBUSTIBLE LIQUID. N.O.S.) BATTERY BOX COMPOUNDS (FLAMMABLE LIQUID. N.O.S.) BAY RUM (COMBUSTIBLE LIQUID, N.O.S.) BAY RUM (FLAMMABLE LIQUID. N.O.S.) BELT DRESSING (COMBUSTIBLE LIQUID. N.O.S.) BELT DRESSING,(FLAMMABLE LIQUID. N.O.S.) BENZOL FORERUNNINGS, CRUDE, NOT BENZOL (FLAM- MABLE LIQUID, N.O.S ) BETA-PROPIOLACTONE (COMBUSTIBLE LIQUID. N.O.S.) BIPHENYL (DIPHENYL) (COMBUSTIBLE LIQUID. N.O.S ) BONl BREAKING COMPOUND. CONSISTING OF NAPHTHA PETROLEUM RESINS AND VEGETABLE OIL (COMBUSTI BLE :IQUID, N.O.S.) BOND BREAKING COMPOUND, CONSISTING OF NAPHTHA. PETROLEUM RESINS AND VEGETABLE OILS (FLAMMABLE LIQUID. N.O.S.) BRAKE OF SHOCK ABSORBER FLUID OR HYDRAULIC SYSTEM FLU D OTHER THAN PETROLEUM (COMBUSTIBLE LIQUID. N O S.) BUTYL ACRY-ATE (COMBUSTIBLE LIQUID. N.O.S.) BUTYL LACTASE (COMBUSTIBLE LIQUID. N.O.S.) BUTYRONITRILE (FLAMMABLE LIQUID, N.O.S.) CARBON BLACK OIL (COMBUSTIBLE LIQUID. N O S ) CARBON BLACK OIL (FLAMMABLE LIQUID. N.O.S.) CEMENT OR CONCRETE WATER PROOFING COMPOUNDS, LIQUID OR PASTE (COMBUSTIBLE LIQUID. N O.S.) CEMENT OR CONCRETE WATEH PROOFING COMPOUNDS. LIQUID OR PASTE (FLAMMABLE LIQUID. N.O.S.) CHEMICAL PLANT W^STE (COMBUSTIBLE LIQUID. N.O.S.) CHEMICAL PLANT WASTE. NEC (FLAMMABLE LIQUID. N.O.S.) CHLOROPENTANES (COMBUSTIBLE LIQUID. N.O.S.) CHLOROPENTANES (FLAMMABLE LIQUID. N.O.S.) COAL BRIQUETTE BINDSR (COMBUSTIBLE LIQUID. N.O.S.) COAL BRIQUETTE BINDER (FLAMMABLE LIQUID. N.O.S.) COAL SPRAYING OIL PETROLEUM (PETROLEUM OIL. N.O.S.) COAL TAR FIBRE SATURANT LIQUID (FLAMMABLE LIQUID, N.O.S.) COAL TAR FIBRE SATURANT. LIQUID (COMBUSTIBLE LIQ- UID. N.O.S.) COAL TAR NAPHTHA AND LIGHT OIL OF COAL TAR. CRUDE (COMBUSTIBLE LIQUID. N.O.S.) COAL TAR NAPHTHA AND LIGHT OIL OF COALTAR. CRUDE (FLAMMABLE LIQUID. N.O.S.) 426 426 454 455 489 489 61 124 205 251 8 8 9 10 10 11 13 14 14 38 48 48 54 54 54 54 59 59 61 61 61 61 65 70 70 73 73 75 81 84 95 106 107 110 111 115 116 122 123 130 131 131 132 132 134 134 554 MOD C)00017482 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 COAL TREATING COMPOUNDS. OTHER THAN PETROLEUM, NEC, LIQUID (COMBUSTIBLE LIQUID) COAL TREATING COMPOUNDS. OTHER THAN PETROLEUM, NEC, LIQUID (FLAMMABLE LIQUID, N.O.S.) COLLIDIENE (COMBUSTIBLE LIQUID, N.O.S.) COMBUSTIBLE LIQUID, N.O.S. COMPOUND, CLEANING, LIQUID COMPOUND. CLEANING, LIQUID COMPOUND, TREE OR WEED KILLING, LIQUID COMPOUND, TREE OR WEED KILLING, LIQUID COMPOUNDS CAULKING OR GLAZING (COMBUSTIBLE LIQ- UID, N.O.S.) COMPOUNDS CAULKING OR GLAZING (FLAMMABLE LIQUID. N.O.S.) COMPOUNDS, HECTOGRAPH (COMBUSTIBLE LIQUID. N.O.S.) COMPOUNDS, HECTOGRAPH (FLAMMABLE UQUID, N.O.S.) COMPOUNDS, LEATHER FINISHING, NEC (COMBUSTIBLE LIQUID, N.O.S.) COMPOUNDS, LEATHER FINISHING, NEC (FLAMMABLE LIO- UID, N.O.S.) COMPOUNDS, PETROLEUM TREATING. CRUDE, NEC (FLAMMABLE LIQUID, N.O.S.) COMPOUNDS, WALL OR WALL PAPER CLEANING (COMPOUND. CLEANING. LIQUID) COMPOUNDS, WALL OR WALL PAPER CLEANING (COMPOUND, CLEANING. LIQUID) COPPER NAPHTHANATE PETROLEUM SOLUTION, NOT MORE THAN 8% COPPER NAPHTHANATE (FLAMMABLE LIQUID, N.O.S.) COPPER NAPHTHANATE SOLUTION. NOT MORE THAN 8% COPPER NAPHTHANATE (COMBUSTIBLE LIQUID, N.O.S.) COSMETICS, N.O.S. COSMETICS, N.O.S. CREOSOTE, COAL TAR CUMENE (COMBUSTIBLE LIQUID, N.O.S.) CUTCH. CATECHU. OR JAPONICA EXTRACTS. LIQUID (COM- BUSTIBLE LIQUID, N.O.S.) CUTCH, CATECHU, OR JAPONICA EXTRACTS, LIQUID (FLAM- MABLE LIQUID. N O S.) CYCLOHEXANONE (COMBUSTIBLE LIQUID, N.O.S.) DEFOAMING COMPOUND. NEC. LIQUID (COMBUSTIBLE LIQ- UID. N.O.S.) DEFOAMING COMPOUND, NEC, LIQUID (FLAMMABLE LIQ- UID, N.O.S.) DEGUMMING COMPOUNDS. FABRIC OR FIBER (COMBUS- TIBLE LIQUID, N.O.S.) DEGUMMING COMPOUNDS, FABRIC OR FIBER (FLAMMABLE LIQUID. N.O.S.) DETERGENT INTERMEDIATES, OTHER THAN CYCLIC OR PETROLEUM (COMBUSTIBLE UQUID. N.O.S.) DETERGENT INTERMEDIATES. OTHER THAN CYCLIC OR PETROLEUM (FLAMMABLE LIQUID. N.O.S.) DI-N-PROPYLAMINE (FLAMMABLE LIQUID, N.O.S.) DIETHYL BENZENE (COMBUSTIBLE LIQUID, N.O.S.) DIETHYLAMINOETHANOL (COMBUSTIBLE LIQUID, N.O.S ) DIETHYLHYDROXYLAMINE (COMBUSTIBLE LIQUID, N.O.S.) DIISOBUTYLAMINE (FLAMMABLE LIQUID, N O S ) DIISOBUTYLENE (FLAMMABLE LIQUID, N.O.S ) DIMETHYLAMINIOETHYL METHACRYLATE (COMBUSTIBLE LIQUID. N.O.S.) DIMETHYLAMINOETHANOL (COMBUSTIBLE LIQUID, N.O.S.) DIMETHYLETHYLAMINE (FLAMMABLE LIQUID. N.O.S.) DISINFECTANT, LIQUID, N.O.S. DRUGS, N.O.S. DRUGS, N O SDRY CLEANER. LIQUID. OR LIQUID CLEANSER (COMPOUND. CLEANING. LIQUID) DRY CLEANER, LIQUID, OR LIQUIO CLEANSER (COMPOUND, CLEANING, UQUID) ELECTRIC WIRE SATURATING OR FINISHING COMPOUND, ASPHALT OR PITCH BASE (COMBUSTIBLE UQUID. N.O.S.) ELECTRIC WIRE SATURATING OR FINISHING COMPOUND, ASPHALT OR PITCH BASE (FLAMMABLE LIQUID. N.O.S.) ELECTRIC WIRE SATURATING OR FINISHING COMPOUND, PARAFFINE BASE [COMBUSTIBLE LIQUID, N.O.S.) ELECTRIC WIRE SATURATING OR FINISHING COMPOUND, PARAFFINE BASE (FLAMMABLE LIQUID, N.O.S.} ENAMEL WHITENING COMPOUNDS (COMBUSTIBLE LIQUID, N.O.S.) 136 136 137 138 139 139 141 141 142 142 143 143 144 144 145 145 145 149 149 152 152 153 155 157 157 159 164 164 164 165 166 166 175 191 193 194 195 196 202 202 203 209 216 216 216 217 217 217 218 218 220 MCB 000017483 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 ENAMEL WHITENING COMPOUNDS (FLAMMABLE LIQUID. N.O.S.) ETHYL NITRATE ETHYL-N-BUTYLAMINE (FLAMMABLE LIQUID, N.O.S ) ETHYL-N-CYCLOHEXYLAMINE (FLAMMABLE UQUID. N O S.) ETHYLHEXYLACRYLATE (COMBUSTIBLE LIQUID. N.O.S.) EXTRACTS, CHESTNUT OR QUEBRACHO, LIQUID (COMBUS- TIBLE LIQUID. N.O.S.) EXTRACTS, CHESTNUT OR QUEBRACHO, UQUID (FLAM- MABLE LIQUIDS, N.O.S.) EXTRACTS, FUSTIC OR LOGWOOD. LIQUID OR PASTE (COM- BUSTIBLE LIQUID, N.O.S.) EXTRACTS, FUSTIC OR LOGWOOD. LIQUID OR PASTE (FLAMMABLE LIQUID, N.O.S.) EXTRACTS, HYPERNIC LIQUID OR PASTE (COMBUSTIBLE UQUID. N.O.S.) EXTRACTS, HYPERNIC LIQUID OR PASTE (FLAMMABLE LIQ- UID. N.O.S.) EXTRACTS, TANNING, NEC LIQUID OR PASTE (COMBUSTI- BLE LIQUIO, N.O.S.) EXTRACTS, TANNING. NEC LIQUID OR PASTE(FLAMMABLE LIQUID, N.O.S.) FLAMMABLE UQUID, N.O.S. FLOOR COVERING UNDER LAYMENT COMPOUNDS, NEC (FLAMMABLE LIQUID. N.O.S.) FLOOR COVERING UNDERLAYMENT COMPOUNDS. NEC (COMBUSTIBLE LIQUIDS. N.O.S FOOT WARMER OR HOT BOTTLE CHARGES, CHEMICAL (COMBUSTIBLE LIQUID. N.O.S.) FOOT WARMER OR HOT BOTTLE CHARGES, CHEMICAL (FLAMMABLE LIQUID. N.O.S.) FUELOIL FUEL OIL, NO. 1.2,4, OR 5 FUNGICIDES, AGRICULTURAL, NEC. LIQUID (COMBUSTIBLE LIQUID, N.O.S.) FUNGICIDES. AGRICULTURAL NEC, LIQUID (FLAMMABLE UQUID. N.O.S.) GAMBIER EXTRACTS, LIQUID (COMBUSTIBLE LIQUID. N O S.) GAMBIER EXTRACTS. LIQUID (FLAMMABLE LIQUID. N.O.S.) GAS ODORANTS, NOT COMPRESSED GAS (COMBUSTIBLE LIQUID, N.O.S.) GAS ODORANTS. NOT COMPRESSED GAS (FLAMMABLE UQUID, N.O.S.) GASOLINE PRESERVATIVE. NEC, UQUID (COMBUSTIBLE LIQUID, N.O.S.) GASOLINE PRESERVATIVE, NEC. UQUID (FLAMMABLE LIQ- UID, N.O.S.) GERANIOL-NEROL MIXTURE (COMBUSTIBLE LIQUID, N.O.S.) GLUE CATALYST, NEC (COMBUSTIBLE LIQUID, N O S.) GLUE CATALYST, NEC (FLAMMABLE UQUID, N.O.S.) GLYCOL ETHERS (COMBUSTIBLE LIQUID. N.O.S.) HEATER FOR REFRIGERATOR CAR, UQUID FUEL TYPE HYDROXY ALDEHYDE WASTES (COMBUSTIBLE LIQUID, N.O.S.) HYDROXY ALDEHYDE WASTES (FLAMMABLE LIQUID, N.O.S.) INK (INK MATERIALS. NEC) INK MATERIALS. NEC (FLAMMABLE LIQUID, N.O.S.) INSECTICIDE. LIQUID, N.O.S. INSECTICIDE. LIQUID, N.O.S. INSECTICIDE. LIQUID, N.O.S. (INSECTICIDES OH FUNGI- CIDES. AGRICULTURAL NEC, UQUID) INSECTICIDE. LIQUID, N.O.S. (INSECTICIDES OR FUNGI- CIDES, AGRICULTURAL. NEC. LIQUID) ISOBUTYLACRYLATE (FLAMMABLE LIQUID, N.O.S.) ISOBUTYRALDEHYDE (FLAMMABLE LIQUID. N.O.S.) ISOBUTYRONITRILE (FLAMMABLE LIQUID, N O S.) ISOPROPYLTOLUENE (COMBUSTIBLE LIQUID, N.O.S.) KITS, PNEUMATIC TIRE CLEANING, AUTO (COMBUSTIBLE LIQUID, N.O.S.) KITS. PNEUMATIC TIRE CLEANING. AUTO (FLAMMABLE UOUID, N.O.S.) LUBRICATING OIL NEC (COMBUSTIBLE LIQUID. N.O.S.) LUBRICATING SYSTEM SIGHT FEED FLUID (COMBUSTIBLE LIQUID. N.O.S.) LUTIOENE (FLAMMABLE LIQUID.N.O.S.) MEDICINES. N.O.S. METHALLYL CHLORIDE (FLAMMABLE LIQUID. N.O.S.) METHLYLETHANOLAMINE (COMBUSTIBLE LIQUID, NOS) METHYL ACETOACETATE (COMBUSTIBLE LIQUID. N.O.S.) METHYL BUTYL KETONE (FLAMMABLE LIQUID, N.O.S.) 220 231 232 233 238 240 241 241 241 241 242 242 242 251 252 252 254 254 256 257 258 258 261 261 262 262 264 264 264 265 265 265 267 284 284 289 289 291 291 291 291 295 296 297 302 304 304 318 318 318 322 332 333 335 337 555 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 METHYL ISOBUTYL KETONE (FLAMMABLE LIQUID, N.O.S ) METHYL METHOXY PENTANONE (COMBUSTIBLE LIQUID, N.O.S.) MONO-TERT-BUTYL-META-CRESOL (COMBUSTIBLE LIQUID, N.O.S.) MUD TREATING COMPOUNDS, NEC, GAS OR OIL WELL ORILLING (COMBUSTIBLE LIQUIDS, N.O.S.) MUD TREATING COMPOUNDS. NEC. GAS OR OIL WELL DRILLING (FLAMMABLE LIQUID) N-ETHYL-META-TOLUIDINE (COMBUSTIBLE LIQUID, N.O.S.) NEO PENTANOIC ACID (COMBUSTIBLE LIQUID, N.O.S.) ORGANIC PEROXIDE, LIQUID OR SOLUTION, N.O.S. PAINT OIL COMPOUNDS (COMBUSTIBLE LIQUID, N.O.S.) PAINT OIL COMPOUNDS (COMBUSTIBLE LIQUID, N.O.S.) PAINT OIL COMPOUNDS (FLAMMABLE LIQUID, N O S.) PAINT OILS. NEC (FLAMMABLE LIQUID, N.O.S.) PERFUMERY (COMBUSTIBLE LIQUID, N.O.S.) PERFUMERY(FLAMMABLE LIQUID. N.O.S.) PETROLEUM ABSORPTION OIL (PETROLEUM OIL. N.O.S.) PETROLEUM LUBRICATING OIL (COMBUSTIBLE LIQUID, N.O.S.) PETROLEUM OIL ADDITIVE CONTAINING MORE THAN 50 PERCENT BY WEIGHT OF PETROLEUM. (COMBUSTIBLE LIQUID, N.O.S.) PETROLEUM OIL ADDITIVE, CONTAINING MORE THAN 50 PERCENT BY WEIGHT OF PETROLEUM (FLAMMABLE LIQ UID, N.O.S.) PETROLEUM OIL RESIDUUM (PETROLEUM OIL. N O S.) PETROLEUM PARTIALLY REFINED FOR FURTHER PROCESSING (COMBUSTIBLE LIQUID, N.O.S ) PETROLEUM PROPYLENE TETRAMER (COMBUSTIBLE LIQUID, N O S.) PETROLEUM PROPYLENE TRIMER (FLAMMABLE LIQUID. N.O.S.) PETROLEUM RESIDUAL FUEL OIL OR DIESEL OIL (FUEL OIL) PICOLINE (COMBUSTIBLE LIQUID, N.O.S ) PICOLINE (FLAMMABLE LIQUID. N.O.S.) PLASTIC SOLVENT. N.O.S. PLASTIC SOLVENT. N O S. PLASTICIZERS. PAINT, LACQUER OR VARNISH (COMBUSTIBLE LIQUID, N.O.S.) PLASTICIZERS. PAINT, LACQUER OR VARNISH (FLAMMABLE LIQUIDS. N O S.) PNEUMATIC TIRE REPAIR KITS, AUTO (COMBUSTIBLE LIQUID, N O S.) PNEUMATIC TIRE REPAIR KITS, AUTO (FLAMMABLE LIQUID, N.O.S.) POLISH OR WAX. BOAT. FURNITURE OR VEHICLE (WAX, LIQUID) POLISH OR WAX, FLOOR (WAX, LIQUID) POLISHING WHEEL CEMENT THINNER (COMBUSTIBLE LIQ- UID, N.O.S.) POLISHING WHEEL CEMENT THINNER (FLAMMABLE LIQUID, N.O.S.) POLYETHYLBENZENE (COMBUSTIBLE LIQUID. N.O.S.) POLYETHYLLIGROIN (PETROLEUM ETHER) PULP MILL LIQUID (COMBUSTIBLE LIQUID, N.O.S.) PULP MILL LIQUID (FLAMMABLE LIQUID, N.O.S ) PYROLIGNEOUS ACID (COMBUSTIBLE LIQUID, N.O.S.) PYROLIGNEOUS ACID (FLAMMABLE LIQUID, N.O.S.) QUINALDINE (COMBUSTIBLE LIQUID, N.O.S.) REFINERY CRACKING STOCK (COMBUSTIBLE LIQUID, N.O.S ) REFINERY CRACKING STOCK (FLAMMABLE LIQUID. N.O.S.) REFRIGERATING MACHINE (COOLING ROOMS. COOLING BOXES OR REFRIGERATORS OTHER THAN HOUSEHOLD TYPE). REFRIGERATING MACHINE (ICE CREAM POWER FREEZERS AND MECHANICAL REFRIGERATORS). REFRIGERATING MACHINE (REFRIGERATORS, NEC) ROOF COATING. CONSISTING OF ASPHALT, PITCH, ROSIN OH TAR BASE (COMBUSTIBLE LIQUID, N.O.S.) ROSIN GLOSS OR ESTER GUM (COMBUSTIBLE LIOUIDS, N.O.S.) ROSIN GLOSS OR ESTER GUM (FLAMMABLE LIOUIDS. N.O.S) 1993 1993 ROSIN LIQUOR (FLAMMABLE LIQUID. N.O.S.) ROSIN LIQUOR. CONSISTING OF ROSIN AND NOT MORE THAN 40% ALCOHOL OR MINERAL SPIRIT (COMBUSTIBLE LIQUIDS. N.O.S.) 1993 ROSIN RESIDUE (COMBUSTIBLE LIQUID, N.O.S.) 340 341 352 357 358 358 362 380 390 390 390 390 396 396 397 398 399 399 399 399 400 400 400 411 411 413 413 414 414 415 415 417 417 418 418 419 419 433 434 436 436 438 445 445 446 446 447 450 451 451 451 451 452 556 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1993 1999 1999 1999 1999 1999 1999 1999 1999 1999 1999 1999 2006 2006 2006 2008 2014 2014 2015 ROSIN RESIDUE (FLAMMABLE LIQUIDS, N.O.S.) ROSIN SOLUTION (COMBUSTIBLE LIQUID, N.O.S ) ROSIN SOLUTION (FLAMMABLE LIQUID. N.O.S.) RUBBER ACCELERATORS OR SOFTENERS, OTHER THAN PETROLEUM, NEC (COMBUSTIBLE LIQUID, N.O.S.) RUBBER ACCELERATORS OR SOFTENERS, OTHER THAN PETROLEUM, NEC (FLAMMABLE LIQUID. N.O.S.) RUBBER PRESERVATIVE. NEC (COMBUSTIBLE LIQUID. N.O.S.) RUBBER PRESERVATIVE. NEC (FLAMMABLE LIQUID, N.O.S.) RUBBER TIRE LACQUER, PAINT. OR SHELLAC (PAINT, LAC- QUER OR SHELLAC) SMOKE FLUE CLEANING COMPOUNDS (COMPOUNDS. CLEANING. LIQUID) SMOKE FLUE CLEANING COMPOUNDS (COMPOUNDS. CLEANING. LIQUID) SOLDERING FLUX, NEC LIQUID (FLAMMABLE LIQUID. N.O.S.) SOLDERING FLUX, NEC, LIQUIO (COMBUSTIBLE LIQUID, N.O.S.) SOLVENT REFINED COAL, LIQUID (COMBUSTIBLE LIQUID, N.O.S.) SOLVENT, N.O.S. SOLVENT, N.O.S. SOLVENTS, PAINT. LACQUER. VARNISH OR RESIN (SOL- VENT. N.O.S.) SOLVENTS. PAINT, LACQUER, VARNISH OR RESIN (SOL- VENT, N O S.) SPIRITS OF TURPENTINE (COMBUSTIBLE LIQUID, N.O.S.) SPIRITS OF TURPENTINE (FLAMMABLE LIQUID, N.O.S.) TETRAHYDROFURFURYL ALCOHOL TIRE PUNCTURE OR RIM SEALING. OR TIRE BALANCING COMPOUNDS (COMBUSTIBLE LIQUID, N.O.S.) TIRE PUNCTURE OR RIM SEALING. OR TIRE BALANCING COMPOUNDS (FLAMMABLE LIQUIDS. N.O.S.) TOLUIDINE (COMBUSTIBLE LIQUID. N.O.S.) TRI-N-BUTYLAMINE (COMBUSTIBLE LIQUID, N.O.S.) TRIETHYL PHOSPHITE TRIMETHYL PHOSPHITE (FLAMMABLE LIQUID. N.O.S.) TURPENTINE RESIDUE, LIQUID (COMBUSTIBLE LIQUID, N.O.S.) TURPENTINE RESIDUE, LIQUID (FLAMMABLE LIQUID, N O S.) VINYLTOLUENE. INHIBITED (COMBUSTIBLE LIQUID. N.O.S.) WALLPAPER REMOVER, LIQUID (COMBUSTIBLE LIQUID, N.O.S.) WALLPAPER REMOVER, LIQUID (FLAMMABLE LIQUID, N O S.) WASTE LIQUOR, CONSISTING OF NOT LESS THAN SO PER- CENT BY WEIGHT OF WATER, RESULTING FROM SUL PHATE OR SODA PULPING PROCESS (COMBUSTIBLE LIQ UID, NOS) WASTE LIQUOR. CONSISTING OF NOT LESS THAN 50 PERCENT BY WEIGHT OF WATER. RESULTING FROM SUL PHATE OR SODA PULPING PROCESS (FLAMMABLE LIQUID, N.O.S.) WAX, LIQUID WOOD FURNITURE FINISHING OR REFINISHING KITS (COMBUSTIBLE LIQUID, N.O.S.) WOOD FURNITURE FINISHING OR REFINISHING KITS (FLAMMABLE LIQUIDS. N.O.S WOOD TURPENTINE (COMBUSTIBLE LIQUID. N.O.S.) WOOD TURPENTINE (FLAMMABLE LIQUID, N.O.S.) ASPHALT, CUT BACK ASPHALT, CUT BACK (ASPHALT PETROLEUM. LIQUID AND TALL OIL PITCH. MIXED PINE TAR (TAR, LIQUID) PINE TAR (TAR. LIQUID) ROAD ASPHALT OR TAR. LIQUID ROAD ASPHALT OR TAR, LIQUID (PETROLEUM ROAD OIL) ROAD ASPHALT OR TAR, LIQUID (PETROLEUM ROAD OIL) TAR OR PITCH. COAL OR PETROLEUM (TAR, LIQUID) TAR OR PITCH. COAL OR PETROLEUM (TAR, LIQUID) TAR. LIQUID TAR. LIQUID PYROXYLIN PLASTIC SCRAP PYROXYLIN PLASTICS. RODS, SHEETS. ROLLS. TUBES ZIRCONIUM METAL, DRY (CHEMICALLY PRODUCED. FINER THAN 20 MESH PARTICLE SIZE) ZIRCONIUM METAL, DRY (MECHANICALLY PRODUCED, FINER THAN 270 MESH PARTICLE SIZE) HYDROGEN PEROXIDE SOLUTION (40% TO 52% PEROXIDE) HYDROGEN PEROXIDE SOLUTION (8% TO 40% PEROXIDE) HYDROGEN PEROXIDE SOLUTION (OVER 52% PEROXIDE) 452 45f 45iu 452 453 453 453 454 460 460 476 477 477 477 478 478 478 479 480 495 501 501 503 505 511 512 515 515 52 527 527 528 528 531 534 534 535 535 55 55 412 412 448 448 448 490 490 490 490 436 437 543 543 282 287 26 OOOO17 454 2016 2016 2017 2017 2020 2020 2022 2023 2025 2025 2029 2030 2031 2032 2036 2047 2047 2054 2054 2055 2056 2059 2059 2059 2059 2059 2059 2059 2059 2060 2067 2066 2069 2070 2073 2076 2078 2081 2082 2083 2064 2085 2085 2065 2087 2088 2089 2090 2091 2091 2092 2093 2094 2095 2096 CHEMICAL AMMUNITION. NONEXPLOSIVE (CONTAINING A POISON A MATERIAL) CHEMICAL AMMUNITION. NONEXPLOSIVE (CONTAINING A POISON B MATERIAL) CHEMICAL AMMUNITION, NONEXPLOSIVE (CONTAINING AN IRRITATING MATFRIAI ) TEAR GAS GRENADE PENTACHLOROPHENOL TRICHLOROPHENOL MINING REAGENT, LIQUID (CONTAINING 20% OR MORE CRESYLIC ACID) EPICHLOROHYDRIN MERCURIC SUBSULFATE. SOLID MERCURY COMPOUND, SOLID, N.O.S. HYDRAZINE, ANHYDROUS HYDRAZINE, AQUEOUS SOLUTION NITRIC ACID (OVER 40%) NITRIC ACID, FUMING XENON DICHLOROPROPENE DICHLOROPROPENE AND PROPYLENE DICHLORIDE MIXTURE MORPHOLINE MORPHOLINE. AEOUOUS MIXTURE STYRENE MONOMER. INHIBITED TETRAHYDROFURAN BOX TOE GUM COLLODION NITROCELLULOSE FLAKES, WET WITH NOT LESS THAN 20% ALCOHOL OR SOLVENT NITROCELLULOSE, COLLOIDED, GRANULAR OR FLAKE. WET WITH NOT LESS THAN 20% ALCOHOL OR SOLVENT. OR BLOCK. WET WITH NOT LESS THAN 25% ALCOHOL PYROXYLIN SOLUTION PYROXYLIN SOLUTION PYROXYLIN SOLVENT. N.O.S. PYROXYLIN SOLVENT, N O S. BOX TOE GUM AMMONIUM NITRATE FERTILIZER (CONTAINING NO MORE THAN 0.2% CARBON) AMMONIUM NITRATE-CARBONATE MIXTURE AMMONIUM NITRATE MIXED FERTILIZER AMMONIUM NITRATE-PHOSPHATE AMMONIA SOLUTION (CONTAINING MORE THAN 44% AMMONIA) CRESOL TOLUENE DIISOCYANATE ACETYL BENZOYL PEROXIDE SOLUTION (NOT OVER 40% PEROXIDE) ACETYL CYCLOHEXANESULPHONYL PEROXIDE. (NOT MORE THAN 82%, WETTED WITH NOT LESS THAN 12% WATER) ACETYL CYCLOHEXANESULPHONYL PEROXIDE, (NOT MORE THAN 32% IN SOLUTION) ACETYL PEROXIDE SOLUTION, (NOT OVER 25% PEROXIDE) BENZOYL PEROXIDE (BENZOYL PEROXIDE CRYSTALS. GRANULES OR POWDERS, WET WITH NOT LESS THAN 30% WATER) BENZOYL PEROXIDE (BENZOYL PEROXIDE.DRY OR WET WITH LESS THAN 30% WATER) BENZOYL PEROXIDE, (TECHNICALLY PURE OR) BENZOYL PEROXIDE. (MORE THAN 52% WITH INERT SOLID) BENZOYL PEROXIDE, (NOT MORE THAN 72% AS A PASTE) BENZOYL PEROXIDE, (MORE THAN 77% BUT LESS THAN 95% WITH WATER) BENZOYL PEROXIDE, (NOT LESS THAN 30% BUT NOT MORE 52% WITH INERT SOLID) BENZOYL PEROXIDE. (NOT MORE THAN 77% WITH WATER) TERT-BUTYL CUMYL PEROXIDE. (TECHNICALLY PURE OR) TERT-BUTYL CUMENE PEROXIDE. (TECHNICALLY PURE) TERT-BUTYL ISOPROPYL BENZENE HYDROPEROXIDE TERT-BUTYL HYDROPEROXIDE. (NOT MORE THAN 80% IN DI-TERT-BUTYL PEROXIDE AND SOLVENT) TERT-BUTYL HYDROPEROXIDE, (NOT MORE THAN 72% WITH WATER) TERT-BUTYL HYDROPEROXIDE, (MORE THAN 72% BUT NOT MORE THAN 90% WITH WATER) TERT-BUTYL PEROXYACETATE. (NOT MORE THAN 76% IN SOLUTION) TERT-BUTYL PEROXYACETATE, (NOT MORE THAN 52% IN SOLUTION) 13 13 13 491 394 509 351 223 326 331 276 276 367 368 535 187 108 355 355 463 495 75 138 369 369 437 437 437 437 75 28 29 29 29 23 154 503 4 5 5 6 66 66 67 67 66 67 67 82 84 83 83 82 87 86 2097 2098 2099 2100 2101 2102 2103 2104 2105 2106 2107 2108 2110 2111 2112 2112 2112 2113 2113 2114 2115 2116 2118 2119 2119 2120 2121 2121 2122 2123 2124 2125 2126 2128 2129 2129 2130 2131 2132 2133 2133 2134 2134 2135 2136 2137 2138 2139 TERT-BUTYL PEROXYBENZOATE. (TECHNICALLY PURE OR) TERT-BUTYL PEROXYBENZOATE. (MORE THAN 75% IN SOLUTION) TERT-BUTYL PEROXYBENZOATE. (NOT MORE THAN 75% IN SOLUTION) TERT-BUTYL PEROXYMALEATE, (TECHNICALLY PURE) TERT-BUTYL PEROXYMALEATE. (NOT MORE THAN 55% IN SOLUTION) TERT-BUTYL PEROXYMALEATE, (NOT MORE THAN 55% AS A PASTE) DI-TERT-BUTYL PEROXIDE, (TECHNICALLY PURE) TERT-BUTYL PEROXYISOPROPYL CARBONATE. (TECHNI- CALLY PURE) TERT-BUTYL PEROXY-3.5.5-TRIMETHYLHEXANOATE (OR) TERT-BUTYL PEROXYISONONANOATE. (TECHNICALLY PURE) TERT-BUTYL PEROXYPHTHALATE. (TECHNICALLY PURE) DI-(TERT-BUTYLPEROXY)PHTHALATE, (TECHN'CALLY PURE) OI-(TERT-BUTYLPEROXY)PHTHALATE, (NOT MORE THAN 55% IN SOLUTION) DI-(TERT-BUTYLPEROXY)PHTHALATE, (NOT MORE THAN 55% AS A PASTE) TERT-BUTYL PEROXYPIVALATE. (NOT MORE THAN 77% IN SOLUTION) 2,2-Dl-(TERT-BUTYLPEROXY)BUTANE. (NOT MORE THAN 55% IN SOLUTION) 1.3-OH2-TERT-BUTYLPEROXYISOPROPYL) BENZENE AND 1,4-DI-(2-TERT- BUTYLPEROXYISOPROPYL) BENZENE MIXTURE. (TECHNICALLY PURE OR 1,3-DI-(2-TERT-BUTYLPEROXYI SO PROPYL) BENZENE. (TECHNICALLY PURE OR MORE THAN 40% WITH INERT SOLID) 1,4-DI-(2-TERT-BUTYLPEROXYISO PROPYL) BENZENE. (TECHNICALLY PURE OR MORE THAN 40% WITH INERT SOLID) P-CHLOROBENZOYL PEROXIDE P-CHLOROBENZOYL PEROXIDE. (NOT MORE THAN 75% WITH WATER) P-CHLOROBENZOYL PEROXIDE. (NOT MORE THAN 52% AS A PASTE) THAN 52% WITH INERT SOLID) P-CHLOROBENZOYL PEROXIDE. (NOT MORE THAN 52% IN SOLUTION) CUMENE HYDROPEROXIDE CYCLOHEXANONE PEROXIDE (IN SOLUTION WITH NOT MORE THAN 9% BY WEIGHT ACTIVE OXYGEN) CYCLOHEXANONE PEROXIDE AND BIS(1-HYDR0XYCY- CLOHEXYL) PEROXIDE MIXTURE CYCLOHEXANONE PEROXIDE. (50 TO 85% PEROXIDE) DECANOYL PEROXIDE, (TECHNICALLY PURE) DICUMYL PEROXIOE (50% PEROXIDE) DICUMYL PEROXIDE. DRY DI-(2-ETHYLHEXYL) PEROXYDICARBONATE. (TECHNICALLY PURE) D!-(2-ETHYLHEXYL) PEROXYDICARBONATE. (NOT MORE THAN 67% IN SOLUTION) LAUROYL PEROXIDE PARAM6NTHANE HYDROPEROXIDE METHYL ISOBUTYL KETONE PEROXIDE. (IN SOLUTION WITH NOT MORE THAN 9% BY WEIGHT ACTIVE OXYGEN) ISONONANYL PEROXIDE. (TECHNICALLY PURE)(OR) ISO- NONANYL PEROXIDE. (IN SOLUTION) CAPRYLYL PEROXIDE SOLUTION N-OCTANOYl PEROXIDE, (TECHNICALLY PURE) PELARGONYL PEROXIDE. (TECHNICALLY PURE) PERACETIC ACID SOLUTION (NOT OVER 40% PERACETIC ACID AND NOT OVER 6% HYDROGEN PEROXIDE) PROPIONYL PEROXIDE, (NOT MORE THAN 28% IN SOLUTION) ISOPROPYL PERCARBONATE. UNSTABILIZED ISOPROPYL PEROXYDICARBONATE, (TECHNICALLY PURE) ISOPROPYL PERCARBONATE. STABILIZED ISOPROPYL PEROXYOICARBONATE. (NOT MORE THAN 52% IN SOLUTION) SUCCINIC ACID PEROXIDE TETRALIN HYDROPEROXIDE, (TECHNICALLY PURE) 2,4-DICHLOROBENZOYL PEROXIDE, (NOT MORE THAN 75% WITH WATER) 2.4-DICHLOROBENZQYL PEROXIDE, (NOT MORE THAN 52% AS A PASTE) 2,4-DICHLOROBENZOYL PEROXIDE, (NOT MORE THAN 52% IN SOLUTION) 88 87 91 90 90 176 90 86 91 171 171 170 92 169 173 173 174 121 121 121 388 155 160 160 161 164 189 190 172 172 306 391 340 297 102 378 393 394 430 301 302 301 301 485 505 183 163 183 Mcd 00oo^es 557 2140 2141 2142 2143 2144 2145 2146 2147 2143 2149 2150 2151 2152 2153 2154 2155 2156 2157 2156 2159 2160 2161 2162 2163 2164 2165 2166 2167 2168 2169 2170 2171 2172 2173 2174 2174 2175 2176 2177 2178 N BUTYL-4.4-Dl-(TERT-BUmPEROXY)VALERATE, (TECH- 93 NICALIY PURE) N-BUTYL-4,4-DI-(TERT-BUTYLPEROXY)VALERATE. (NOT 93 MORE THAN 52% WITH INERT SOLID) TERT-BUTYL PEROXYISOBUTYRATE, (MORE THAN 52% BUT 69 NOT MORE THAN 77% IN SOLUTION) TERT-BUTYL PEROXY-2-ETHYLHEXANOATE, (TECHNI- 85 CALLY PURE) TERT-BUTYL PEROXYDIETHYLACETATE. (TECHNICALLY 88 PURE) U-Dl-(TERT-BUTYLPEROXY)-3.3.5-TRIMETHYL CYCLOH- 166 EXANE. (TECHNICALLY PURE) 1.1- DI-(TERT-BUTYLPEROXY)-3.3,5-TRIMETHYL CYCLOH- 168 EXANE. (NOT MORE THAN 57% IN SOLUTION) 1,1 -DI-(TERT-BUTYLPEROXY)-3.3.5-TRIMETHYL CYCLOH- 168 EXANE. (NOT MORE THAN 58% WITH INERT SOLID) DI-(I-HYDROXYCYCLOHEXYL) PEROXIDE. (TECHNICALLY 172 PURE) DIBENZYL PEROXYDICARBONATE. (NOT MORE THAN 87% 178 WITH WATER) DI-SEC-BUTYL PEROXYDICARBONATE. (TECHNICALLY PURE) 176 DI-SEC-BUTYL PEROXYDICARBONATE. (NOT MORE THAN 176 52% IN SOLUTION) DICYCLOHEXYL PEROXYDICARBONATE. (TECHNICALLY 190 PURE) DICYCLOHEXYL PEROXYDICARBONATE, (NOT MORE THAN 190 91% WITH WATER) DI-(4-TERT-BYTYLCYCLOHEXYL)PEROXYDICARBONATE, 175 (TECHNICALLY PURE) 2.5-DIMETHYL-2,5-DI-(TERT-BUTYLPEROXY) HEXANE. 200 (TECHNICALLY PURE) 2.5- DIMETHYL-2,5-DI-(TERT-BUTYLPEROXY) HEXANE, (NOT 200 MORE THAN 52% WITH INERT SOLID) 2.5- DIMETHYL-2.5-DI-(2-ETHYLHEXANOYLPEROXY) HEX- 201 ANE. (TECHNICALLY PURE) 2.5- DIMETHYL-2.5-DI-(TERT-BUTYLPEROXY)HEXYNE-3 201 (TECHNICALLY PURE) 2.5- DIMETHYL-2.5-DI-(TERT-0UTYLPEROXY)HEXYNE-3. (NOT 200 MORE THAN 52% WITH INERT SOLID) 1.1.3.3- TETRAMETHYLBUTYL HYDHOPEROXIDE, (TECHNI- 495 CALLY PURE) 1.1.3.3- TETRAMETHYLBUTYL PEROXY-2-ETHYLHEXAN- 496 OATE, (TECHNICALLY PURE) PINANE HYDROPEROXIDE SOLUTION (NOT OVER 45% 412 PEROXIDE) DIACETONE ALCOHOL PEROXIDE, (NOT MORE THAN 57% 177 IN SOLUTION WITH NOT MORE THAN 9% HYDROGEN PER OXIDE. NOT LESS THAN 26% DIACETONE ALCOHOL AND NOT LESS THAN 9% WATER; TOTAL ACTIVE OXYGEN CONTENT NOT MORE THAN 9%) DICETYL PEROXYDICARBONATE, (TECHNICALLY PURE) 3.3.6.6.9.9- HEXAMETHYL-1,2.4.5-TETRAOXOCYCLONON- 180 272 ANE. (TECNHICALLY PURE) 3.3.6.6.9.9- HEXAMETHYL-1,2,4.5-TETRAOXOCYCLONON- 272 ANE, (NOT MORE THAN 52% WITH INERT SOLID) 3.3.6.6.9.9- HEXAMETHYL-l ,2,4.5-TETRAOXOCYCLONON- 272 ANE. (NOT MORE THAN 52% IN SOLUTION) 2.2- DI-(4,4-OI-TERT-BUTYLPEROXYCYCLOHEXYL) PRO- 175 PANE. (NOT MORE THAN 42% WITH INERT SOLID) N-BUTYL PEROXYDICARBONATE. (NOT MORE THAN 52% IN 356 SOLUTION) N-BUTYL PEROXYDICARBONATE. (NOT MORE THAN 27% IN 89 SOLUTION) DIISOPROPYLBENZENE HYDROPEROXIDE SOLUTION (NOT 197 OVER 60% PEROXIDE) 2.5- DIMETHYL-2,5-DI-(BENZOYLPEROXY) HEXANE. (TECH- 199 NICALLY PURE) 2.5- DIMETHYL-2.5-DI-(BENZOYLPEROXY) HEXANE. (NOT 199 MORE THAN 82% WITH INERT SOLID) 2.5- DIMETHYL-2.5-DIHYDROPEROXY HEXANE, (NOT MORE 201 THAN 82% WITH WATER) DIMETHYLHEXANE DIHYDROPEROXIDE. (WITH 18% OR MORE 204 WATER) DIETHYL PEROXYDICARBONATE. (NOT MORE THAN 27% IN 192 SOLUTION) DI-N-PROPYL PEROXYDICARBONATE. (TECHNICALLY PURE) 175 TERT-BUTYL PEROXYNEODECANOATE. (NOT MORE THAN 91 77% IN SOLUTION) 2.2- DIHYDROPEROXY PROPANE. (NOT MORE THAN 25% 194 WITH INERT ORGANIC SOLID) 558 MCp 000017486 2179 2180 2181 2182 2183 2184 2185 2187 2158 2191 2192 2196 2199 2202 2213 2215 2215 2218 2224 2257 2258 2261 2263 2269 2280 2291 2291 2291 2291 2291 2296 2298 2299 2300 2301 2315 2318 2331 2348 2347 2357 2363 2368 2376 2389 2426 2435 2438 2439 2439 2443 2443 2444 2449 2449 2451 2456 2457 2458 2460 2461 2462 2463 2464 2465 1,1-DI-(TERT-BUTYLPEROXY)CYCLOHEXANE. (TECHNI- CALLY PURE) 1,1-DI-(TERT-BUTYLPEROXY)CYCLOHEXANE. (NOT MORE THAN 77% IN SOLUTION) 1,2-DI-(TERT-BUTYLPEROXY)CYCLOHEXANE. (NOT MORE THAN 77% IN SOLUTION) DIISOBUTYRYL PEROXIDE, (NOT MORE THAN 52% IN SOLUTION) TERT-BUTYL PEROXYCROTONATE. (NOT MORE 76% IN SOLUTION) ETHYL-3-3.DI-(TERT-BUTYLPEROXY)BUTYRATE, (TECHNI CALLY PURE) ETHYL-3.3*DI-(TERT-BUTYLPEROXY)BUTYRATE, (NOT MORE THAN 77% IN SOLUTION) CARBON DIOXIDE. LIQUEFIED ARSINE SULFURYL FLUORIDE GERMANE TUNGSTEN HEXAFLOURIDE PHOSPHINE HYDROGEN SELENIDE PARAFORMALDEHYDE MALEIC ACID MALEIC ANHYDRIDE ACRYLIC ACID BENZONITRILE POTASSIUM. METAL PROPYLENE DIAMINE XYLENOL 1,4-DIMETHYLCYCLOHEXANE IMINOBISPROPYLAMINE HEXAMETHYLENE DIAMINE. SOLID GALENA ORE, CRUDE (LEAD SULFIDE) LEAD CHLORIDE LEAD FLUOBORATE LEAD SULFIDE LEAD THIOCYANATE METHYLCYCLOHEXANE CYCLOPENTANE, METHYL METHYL DICHLOROACETATE METHYL ETHYL PYRIDINE METHYLFURAN POLYCHLORINATED BIPHENYL OR PCBS SODIUM HYDROSULFIDE, SOLID (WITH LESS THAN 25% WATER OF CRYSTALLIZATION) ZINC CHLORIDE. SOLID DIACETYL BUTYL MERCAPTAN CYCLOHEXYLAMINE ETHYL MERCAPTAN PINENE DIHYDROPYRAN FURAN AMMONIUM NITRATE. SOLUTION (CONTAINING NOT LESS THAN 15% WATER) ETHYL PHENYL DICHLOROSILANE TRIMETHYL4CETYL CHLORIDE SODIUM BIFLUORIDE SOLID SODIUM BIFLUORIDE SOLUTION VANADIUM OXYTRICHLORIDE VANADIUM OXYTRICHLORIDE AND TITANIUM TETRACHLO RIDE MIXTURE VANADIUM TETRACHLORIDE AMMONIUM OXALATE CUPRIC OXALATE NITROGEN TRIFLUORIDE 2-CHLOROPROPENE 2,3-DIMETHYLBUTANE HEXADIENE METHYL BUTENE METHYL PENTADIENE METHYL PENTANE ALUMINUM HYDRIDE BERYLLIUM NITRATE POTASSIUM DICHLORO-S-TRIAZINETRIONE (DRY. CON TAINING MORE THAN 39% AVAILABLE CHLORINE) 2465 SODIUM DICHLORO-S-TRIAZINETRIONE (DRY. CONTAINING MORE THAN 39% AVAILABLE CHLORINE) 170 169 170 196 88 233 234 108 53 488 264 514 405 283 391 320 321 8 65 425 432 536 203 286 273 261 307 308 310 311 346 16? 33t 339 348 418 467 539 177 84 162 230 415 195 259 30 231 512 463 463 522 523 523 30 156 372 124 203 269 336 343 343 20 69 421 46' 2468 2468 2474 2485 2490 2491 2493 2495 2496 2497 2498 2501 2502 2508 2505 2514 2517 2529 2530 2545 2546 2550 2551 2553 2553 2553 2553 2553 2553 2555 2555 2556 2557 2557 2562 2564 2570 2570 2570 2582 2582 2584 2564 2584 2588 2568 2593 2594 2595 2596 2597 2596 2602 2626 2630 2646 2656 2672 MONO-(TRICHLORO) TETRA-(MONOPOTASSIUM DICHLORO) PEMTA-S-TRIAZINETRIONE (DRYCONTAINING MORE THAN 39% AVAILABLE CHLORINE) TRICHLORO-S-TRIAZINETRIONE (DRY. CONTAINING MORE THAN 39 PERCENT AVAILABLE CHLORINE) THIOPHOSGENE N-BUTYL ISOCYANATE DICHLOROISOPROPYL ETHER MONOETHANOLAMINE HEXAMETHYLENE (MINE IODINE PENTAFLUORIOE PROPIONIC ANHYDRIDE SODIUM PHENOLATE. SOLID 1,2,3,6-TETRAHYDROBENZALDEHYDE TRIS-(I-AZIRIDINYL) PHOSPHINE OXIDE VALERYL CHLORIDE ZIRCONIUM TETRACHLORIDE. SOLID AMMONIUM FLUORIDE BR0M06ENZENE DIFLUOROMONOCHLOROETHANE ISOBUTYRIC ACID ISOBUTYRIC ANHYDRIDE HAFNIUM METAL, DRY TITANIUM METAL POWDER, DRY OR WET (WITH LESS THAN 20% WATER) METHYL ETHYL KETONE PEROXIDE, (IN SOLUTION WITH NOT MORE THAN 9% BY WEIGHT ACTIVE OXYGEN) TERT-BUTYL PEROXYDIETHYLACETATE, (33% WITH) TERTBUTYL PEROXYBENZOATE, (33%. ANO SOLVENT) COAL TAR NAPHTHA COAL TAR NAPHTHA COAL TAR NAPHTHA (COAL TAR NAPHTHA, CRUDE) COAL TAR NAPHTHA (COAL TAR NAPHTHA, CRUDE) NAPHTHA NAPHTHA NITROCELLULOSE, COLLOIDEO. GRANULAR OR FLAKE. WET WITH NOT LESS THAN 20% WATER NITROCELLULOSE. WET WITH NOT LESS THAN 20% WATER NITROCELLULOSE, WET WITH NOT LESS THAN 30% AL- COHOL OR SOLVENT LACQUER BASE DRY LACQUER CHIPS. DRY TERT-BUTYL PEROXYISOBLTTYRATE, (NOT MORE THAN 52% IN SOLUTION) TRICHLOROACETIC ACID SOLUTION CADMIUM ACETATE CADMIUM BROMIDE CADMIUM CHLORIDE FERRIC CHLORIDE SOLUTION (IRON CHLORIDE (IRON MU- RIATE), OTHER THAN CRUDE, LIQUID) FERRIC CHLORIDE SOLUTION (IRON CHLORIDE, CRUDE. LIQUID NOT LESS THAN 50% WATER) ALKANESULFONIC ACID DODECYLBENZENESULFONIC ACID TOLUENESULFONIC ACID. LIQUID INSECTICIDE, DRY, N.O.S. (AGRICULTURAL INSECTICIDES OR FUNGICIDES, NEC, OTHER THAN LIQUID) INSECTICIDE. DRY, N.O.S. (INSECTICIDES. INSECT OR ANI- MAL REPELLENTS OR VERMIN EXTERMINATORS. NEC. OTHER THAN AGRICULTURAL) DI-(2-METHYLBENZOYL) PEROXIDE. (NOT MORE THAN 85% WITH WATER) TERT-BUTYL PEROXYNEODECANOATE. (TECHNICALLY PURE) DIMYRISTYL PEROXYDICARBONATE, (TECHNICALLY PURE) 3-TERT-BUTYL PEROXY-3-PHENYLPHTHALIDE. (TECHNICALLY PURE) DI-(3,5,5-TRIMETHYL-1,2-DIOXOLANYL-3) PEROXIDE, (NOT MORE THAN 50% AS A PASTE, WITH PHLEGMATIZER) ETHYL-3,3-DKTERT-BUTYLPEROXY)BUTYRATE. (NOT MORE THAN 50% WITH INERT INORGANIC SOLID) DICHLORODIFLUOROMETHANE AND DIFLUOROETHANE MIXTURE (CONSTANT BOILING MIXTURE) CHLORIC ACID SODIUM SELENITE HEXACHLOROCYCLOPENTADIENE QUINOLINE AMMONIUM HYDROXIDE (CONTAINING LESS THAN 12% AMMONIA) 351 508 498 83 186 353 273 293 430 473 495 514 522 544 27 77 194 296 297 266 501 338 89 133 133 134 134 359 360 370 370 370 304 305 89 508 96 96 96 244 244 17 214 503 290 290 173 91 204 86 174 233 184 118 475 269 436 27 MCD 000017487 2672 2683 2692 2693 2693 2693 2693 2693 2703 2704 2725 2726 2755 2757 2757 2757 2757 2757 2757 2757 2757 2757 2757 2757 2757 2757 2758 2758 2759 2759 2759 2759 2759 2759 2760 2760 2761 2761 2761 2761 2761 2761 2761 2761 2781 AMMONIUM HYDROXIDE (CONTAINING NOT LESS THAN 12% BUT NOT MORE THAN 44% AMMONIA) AMMONIUM SULFIDE SOLUTION BORON TRIBROMIDE AMMONIUM BISULFITE SOLUTION AMMONIUM BISULFITE. SOLID CALCIUM HYDROGEN SULFITESOLUTION (CALCIUM BISULPHITE) SODIUM BISULFITE SOLUTION SODIUM HYDROGEN SULFITE. SOLID ISOPROPYL MERCAPTAN PROPYL MERCAPTAN NICKEL NITRATE ZIRCONIUM NITRATE 3-CHLOROPEROXYBENZOIC ACID. (NOT MORE THAN 86% WITH 3-CHLOROBENZOIC ACID) CARBAMATE PESTICIDE. LIQUID. N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES. NEC. LIQUID) CARBAMATE PESTICIDE, LIQUID. N.O.S. (COUMPOUNDS ANO PREPARATIONS) (INSECTICIDES, OTHER THAN AG RICULTURAL, NEC) CARBAMATE PESTICIDE. SOLID. N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC. OTHER THAN LIQUID) CARBAMATE PESTICIDE, SOLID. N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AGRICUL TURAL, NEC) CARBARYL (AGRICULTURAL INSECTICIDES, NEC. LIQUID) CARBARYL (AGRICULTURAL INSECTICIDES. NEC. OTHER THAN LIQUID) CARBARYL (INSECTICIDES, OTHER THAN AGRICULTURAL. NEC) CARBOFURAN CARBOFURAN MIXTURE. LIQUID (AGRICULTURAL INSECTICIDES, NEC. LIQUID) MERCAPTODIMETHUR MEXACARBATE (AGRICULTURAL INSECTICIDES, NEC, LIQUID) MEXACARBATE (AGRICULTURAL INSECTICIDES, NEC. OTHER THAN LIQUID) MEXACARBATE (INSECTICIDES, OTHER THAN AGRICULTURAL, NEC) CARBAMATE PESTICIDE, LIQUID, N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AGRICUL TURAL, NEC) CARBAMATE PESTICIDE. LIQUI0, N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIOES. NEC. LIQUID) ARSENICAL PESTICIDE. LIQUID. N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES. NEC, LIQUID) ARSENICAL PESTICIDE. LIQUID. N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIOES. OTHER THAN AGRICUL TURAL, NEC) ARSENICAL PESTICIDE, SOLID. N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICUTURAL. NEC) ARSENICAL PESTICIDE. SOLID. N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC, OTHERTHAN LIQUID) BORDEAU ARSENlTE. LIQUID BORDEAUX ARSENlTE. SOLID ARSENICAL PESTICIDE. LIQUID. N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AGRICUL TURAL NEC) ARSENICAL PESTICIDE, LIQUID. N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES. NEC, LIQUID) ALDRIN ALDRIN MIXTURE, DRY (WITH MORE THAN 65% ALDRIN) ALDRIN MIXTURE, DRY. WITH 65% OR LESS ALDRIN ALDRIN. CAST SOLID DDT (OR) DICHLORODIPHENYLTRICHLOROETHANE DICHLONE (AGRICULTURAL INSECTICIDES. NEC. LIQUID) DICHLONE (AGRICULTURAL INSECTICIDES. NEC. OTHER THAN LIQUID) DICHLONE (INSECTICIDES, OTHER THAN AGRICULTURAL. NEC) DIELDRIN (AGRICULTURAL INSECTICIDES. NEC. LIQUID) 28 32 74 25 25 98 463 467 301 431 364 543 123 103 103 104 104 104 104 104 105 105 323 349 350 350 103 103 52 52 53 53 73 74 59 60 15 15 15 16 163 181 181 181 191 559 2761 2761 2761 2761 2761 2761 2761 2761 2761 2761 2761 2761 2761 2761 2761 2761 2761 2761 2761 2761 2761 2761 2761 2761 2761 2761 2761 2761 2761 2762 2762 2762 2762 2762 2762 2763 2763 2763 2763 2764 2764 DIELDRIN (AGRICULTURAL INSECTICIDES. NEC, OTHER THAN LIQUID) OIELDRIN (INSECTICIDES. OTHER THAN AGRICULTURAL, NEC) ENDOSULFAN (AGRICULTURAL INSECTICIDES. NEC. LIQUID) ENDOSULFAN (AGRICULTURAL INSECTICIDES. NEC. OTHER THAN LIQUID) ENDOSULFAN (INSECTICIDES, OTHER THAN AGRICUL TURAL, NEC) ENDOSULFAN MIXTURE, LIQUID (AGRICULTURAL INSECTI CIDES, NEC, LIQUID) ENDRIN (AGRICULTURAL INSECTICIDES, NEC. LIQUID) ENDRIN (AGRICULTURAL INSECTICIDES, NEC, OTHER THAN LIQUID) ENDRIN (INSECTICIDES, OTHER THAN AGRICULTURAL, NEC) ENDRIN MIXTURE, LIQUID (AGRICULTURAL INSECTICIDE. NEC, LIQUID) HEPTACHLOR KELTHANE (AGRICULTURAL INSECTICIDES. NEC. LIQUID) KELTHANE (AGRICULTURAL INSECTICIDES, NEC, OTHER THAN LIQUIO) KELTHANE (INSECTICIDES, OTHER THAN AGRICULTURAL, NEC) KEPONE LINDANE (AGRICULTURAL INSECTICIDES, NEC. LIQUID) UNDANE (AGRICULTURAL INSECTICIDES. NEC. OTHER THAN LIQUID) LINDANE (INSECTICIDES. OTHER THAN AGRICULTURAL, NEC) METHOXYCHLOR (AGRICULTURAL INSECTICIDES. NEC, LIQUID) METHOXYCHLOR (AGRICULTURAL INSECTICIDES, NEC, OTHER THAN LIQUID) METHOXYCHLOR (INSECTICIDES. OTHER THAN AGRICUL TURAL, NEC) ORGANOCHLORINE PESTICIDE. LIQUID, N.O.S. (COM POUNDS AND PREPARATIONS) (AGRICULTURAL INSEC TICIDES. NEC, LIQUID) ORGANOCHLORINE PESTICIDE. LIQUID. N.O S. (COM POUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AGRICULTURAL, NEC) ORGANOCHLORINE PESTICIDE. SOLID, N.O.S. (COM POUNDS AND PREPARATIONS) (AGRICULTURAL INSEC TICIDES. NEC. OTHER THAN LIQUID) ORGANOCHLORINE PESTICIDE. SOLIO NOS (COM POUNDS ANO PREPARATIONS) (INSECTICIDES. OTHER THAN AGRICULTURAL. NEC) TDE (1.1 -DICHLORO-BIS(P-CHLOROPHENYL)ETHANE) TOXAPHENE (CHLORINATED CAMPHENE) TOXAPHENE (TOXAPHENE. LIQUID) TOXAPHENE (TOXAPHENE, OTHER THAN LIQUID) ALDRIN MIXTURE, LIQUID (WITH MORE THAN 60% ALDRIN) ALDRIN MIXTURE, LIQUID. WITH 60% OR LESS ALDRIN CHLORDANE. LIQUID CHLORDANE, LIQUID ORGANOCHLORINE PESTICIDE, LIQUID, N.O.S (COM POUNDS AND PREPARATIONS) (AGRICULTURAL INSEC TICIDES. NEC. LIQUID) ORGANOCHLORINE PESTICIDE, LIQUID, N.O.S. (COM POUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AGRICULTURAL, NEC) TRIAZINE PESTICIDE, LIQUID. N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES. NEC. LIQUID) TRIAZINE PESTICIOE, LIQUID. N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICUL TURAL, NEC) TRIAZINE PESTICIOE. SOLIO. N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIOES. NEC. OTHER THAN LIQUID) TRIAZINE PESTICIDE. SOLID. N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICUL TURAL, NEC) TRIAZINE PESTICIDE, LIQUID, N.O.S. (COMPOUNDS AND PERPARATIONS) (INSECTICIDES, OTHER THAN AGRICUL TURAL, NEC) TRIAZINE PESTICIDE, LIQUID, N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC. LIQUID) 191 191 220 221 221 221 221 222 222 222 266 303 303 303 304 312 313 313 334 334 334 362 362 383 383 490 504 504 504 15 16 118 118 382 383 506 506 507 506 506 506 560 2765 2765 2765 2765 2765 2765 2765 2765 2765 2765 2765 2766 2766 2767 2767 2767 2767 2767 2767 2767 2768 2768 2769 2769 2769 2769 2769 2769 2769 2769 2769 2769 2770 2770 2771 2,4-DICHLOROPHENOXYACETIC ACID 2,4-DICHLOROPHENOXYACETIC ACID ESTER PHENOXY PESTICIDE, LIQUIO, N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES. NEC, LIQUID) PHENOXY PESTICIDE, LIQUID, N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICUL TURAL, NEC) PHENOXY PESTICIDE, SOLID, N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC, OTHER THAN LIQUID) PHENOXY PESTICIDE, SOLID, N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICUL TURAL. NEC) PROPARG1TE 2,4,5-TRICHLOROPHENOXYACETIC ACID (OR) 2.4.5-T 2,4,5-TRICHLOROPHENOXYACETIC ACID AMINE, ESTER, (OR) SALT (OR) 2.4.5-T AMINE, ESTER, (OR) SALT 2 4.5-TRICHLOROPHENOXYPROPIONIC ACID 2.4.5-TRICHLOROPHENOXYPROPIONIC ACID ESTERS PHENOXY PESTICIDE, LIQUID, N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICUL TURAL. NEC) PHENOXY PESTICIDE. LIQUID. N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES. NEC. LIQUID) DIURON (AGRICULTURAL INSECTICIDES, NEC. LIQUID) DIURON (AGRICULTURAL INSECTICIDES. NEC, OTHER THAN LIQUID) DIURON (INSECTICIOES, OTHER THAN AGRICULTURAL. NEC) PHENYLUREA PESTICIDE. LIQUID. N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC. LIQUID) PHENYLUREA PESTICIDE, LIQUID. N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AG RICULTURAL, NEC) PHENYLUREA PESTICIDE. SOLID. N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC, OTHER THAN LIQUID) PHENYLUREA PESTICIDE. SOLID.N O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICUL TURAL, NEC) PHENYLUREA PESTICIDE. LIQUID, N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AG RICULTURAL. NEC) PHENYLUREA PESTICIDE, LIQUID, N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES. NEC, LIQUID) BENZOIC DERIVATIVE PESTICIDE. LIQUID. N.O.S. (COUMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSEC TICIDES. NEC. LIQUID) BENZOIC DERIVATIVE PESTICIDE. SOLID. N.O.S. (COM POUNDS AND PREPARATION (AGRICULTURAL INSECTI CIDES, NEC. OTHER THAN LIQUID) BENZOIC DERIVATIVE PESTICIDE. SOLID. N.O.S. (COM POUNDS AND PREPARATION (INSECTICIDES, NEC, OTHER THAN AGRICULTURAL) BENZOIC DERIVITIVE PESTICIDE,LIQUID, N O S. (COUMPOUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AGRICULTURAL, NEC) DICAMBA (AGRICULTURAL INSECTICIDES. NEC. LIQUID) DICAMBA (AGRICULTURAL INSECTICIDES, NEC, OTHER THAN LIQUID) DICAMBA (INSECTICIDES. OTHER THAN AGRICULTURAL. NEC) DICHLOBENIL (AGRICULTURAL INSECTICIDES, NEC, LIQUID) DICHLOBENIL (AGRICULTURAL INSECTICIDES, NEC, OTHER THAN LIQUID) OICHLOBENIL (INSECTICIDES, OTHER THAN AGRICUL TURAL. NEC) BENZOIC DERIVATIVE PESTICIDE, LIQUID, N.O.S (COUM- POUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AGRICULTURAL, NEC) BENZOIC DERIVATIVE PESTICIDE, LIQUID. N.O.S. (COUM- POUNDS AND PREPARATIONS) (AGRICULTURAL INSEC TICIDES, NEC. LIQUID) DITHIOCARBAMATE PESTICIDE, LIQUID. N.O.S. (COM POUNDS AND PREPARATIONS) (AGRICULTURAL INSEC TICIDES. NEC, LIQUID) 186 187 401 401 402 402 426 509 509 509 510 401 402 213 214 214 403 403 404 404 403 404 63 64 64 64 179 179 179 180 180 181 63 64 212 2771 2771 2771 2772 2772 2773 2773 2773 2773 2774 2774 2775 2775 2775 2775 2776 2776 2777 2777 2777 2777 2778 2778 2779 2779 2779 DITHIOCARBAMATE PESTICIDE, LIQUID. N.O.S. (COM POUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AGRICULTURAL. NEC) DITHIOCARBAMATE PESTICIDE. SOLID, N.O.S. (COM POUNDS AND PREPARATIONS) (AGRICULTURAL INSEC TICIDES. NEC. OTHER THAN LIQUID) DITHIOCARBAMATE PESTICIDE. SOLID, N.O.S. (COM POUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AGRICULTURAL, NEC) DITHIOCARBAMATE PESTICIDE, LIQUID. N.O.S. (COM POUNDS AND PREPARATIONS) (AGRICULTURAL INSEC TICIDES. NEC. LIQUID) DITHIOCARBAMATE PESTICIDE. LIQUID. N.O.S. (COM POUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL. NEC) PHTHALIMIDE DERIVATIVE PESTICIDE. LIQUID, N.O.S. (COM POUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AGRICULTURAL, NEC) PHTHALIMIDE DERIVATIVE PESTICIDE. LIQUID. N.O.S. (COM POUNDS AND PREPARATIONS) (AGRICULTURAL INSEC TICIDES. NEC, LIQUID) PHTHALIMIDE DERIVATIVE PESTICIDE. SOLID, N.O.S. (COM POUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AGRICULTURAL. NEC) PHTHALIMIDE DERIVATIVE PESTICIDE. SOLID. N.O.S. (COM POUNDS AND PREPARATIONS) (AGRICULTURAL INSEC TICIDES, NEC. OTHER THAN LIQUID) PHTHALIMIDE DERIVATIVE PESTICIDE. LIQUID, N.O.S. (COM POUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AGRICULTURAL. NEC) PHTHALIMIDE DERIVATIVE PESTICIDE. LIQUID. N.O.S. (COM POUNDS AND PREPARATIONS) (AGRICULTURAL INSEC TICIDES. NEC, LIQUID) COPPER BASED PESTICIDE. LIQUID. N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AG RICULTURAL. NEC) COPPER BASED PESTICIDE, LIQUID, N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES. NEC. LIQUID) COPPER BASED PESTICIDE. SOLID, N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES. NEC. OTHER THAN LIQUID) COPPER BASED PESTICIDE. SOLID. N.O.S. (COMPOUNDS ANO PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL, NEC) COPPER BASED PESTICIDE, LIQUID. N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES. NEC. LIQUID) COPPER BASED PESTICIDE. LIQUID. N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AG RICULTURAL. NEC) MERCURY BASED PESTICIDE. LIQUID. N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AG RICULTURAL. NEC) MERCURY BASED PESTICIDE, LIQUID. N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES. NEC, LIQUID) MERCURY BASED PESTICIDE, SOLID, N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AG RICULTURAL. NEC) MERCURY BASED PESTICIDE. SOLID. N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC. OTHER THAN LIQUIO) MERCURY BASEO PESTICIDE. LIQUID. N.O.S. (COMPOUNDS ANO PREPARATIONS) (AGRICULTURAL INSECTICIDES. NEC. LIQUID) MERCURY BASED PESTICIDE, LIQUID. N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AG RICULTURAL. NEC) SUBSTITUTED NITROPHENOL PESTICIDE. LIQUID, N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICALTURAL IN SECTICIDES. NEC, LIQUID) SUBSTITUTED NITROPHENOL PESTICIDE, LIQUIO, N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL NEC) SUBSTITUTED NITROPHENOL PESTICIDE. SOLID, N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL NEC) 212 213 213 212 213 410 410 411 411 410 410 147 147 148 148 148 148 329 330 330 331 330 330 483 483 484 2779 2780 2780 2781 27B1 2781 2781 2781 2781 2781 2782 2782 2783 2783 2783 2783 2783 2783 2783 2783 2783 2783 2783 2783 2783 2783 2783 2783 2783 2783 2783 2783 2783 2783 2783 2783 2783 2783 2783 SUBSTITUTED NITROPHENOL PESTICIDE. SOLID. N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL IN SECTICIDES. NEC. OTHER THAN LIQUID) SUBSTITUTED NITROPHENOL PESTICIOE. LIQUID. N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL IN SECTICIDES. NEC. LIQUID) SUBSTITUTED NITROPHENOL PESTICIDE. LIQUID. N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AGRICULTURAL, NEC) BIPYRIDILIUM PESTICIDE. SOLIO, N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES. NEC, OTHER THAN LIQUID) BIPYRIDILIUM PESTICIDE. SOLID. N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICUL TURAL, NEC) BIPYRIDILIUM PESTICIDE. LIQUID. N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES. NEC, LIQUID) BIPYRIDILIUM PESTICIDE.LIQUID. N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AGRICUL TURAL, NEC) DIQUAT (AGRICULTURAL INSECTICIDES. NEC. LIQUID) DlQUAT (AGRICULTURAL INSECTICIDES, NEC. OTHER THAN LIQUID) DIQUAT (INSECTICIDES, OTHER THAN AGRICULTURAL NEC) BIPYRIDILIUM PESTICIDE. LIQUID, N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AGRICUL TURAL. NEC) BIPYRIDILIUM PESTICIDE. LIQUID, N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES. NEC. LIQUID) AZINPHOS METHYL (OR) GUTHION (AGRICULTURAL INSEC TICIDES. NEC, LIQUID) AZINPHOS METHYL (OR) GUTHION (AGRICULTURAL INSEC TICIDES. NEC. OTHER THAN LIQUID) AZINPHOS METHYL (OR) GUTHION (INSECTICIDES. OTHER THAN AGRICULTURAL, NEC) AZINPHOS METHYL MIXTURE. LIQUID (OR) GUTHION MIX TURE. LIQUID (AGRICULTURAL INSECTICIDES. NEC, LIQUID) CHLORPYRIFOS (AGRICULTURAL INSECTICIDES. NEC, LIQUID) CHLORPYRIFOS (AGRICULTURAL INSECTICIDES. NEC. OTHER THAN LIQUID) CHLORPYRIFOS (INSECTICIDES, OTHER THAN AGRICUL TURAL. NEC) COUMAPHOS COUMAPHOS MIXTURE. LIQUID (AGRICULTURAL INSEC- TIDES, NEC, LIQUID) DIAZINON (AGRICULTURAL INSECTICIDES, NEC. LIQUID) DIAZINON (AGRICULTURAL INSECTICIDES. NEC. OTHER THAN LIQUID) DIAZINON (INSECTICIDES. OTHER THAN AGRICULTURAL. NEC) DICHLORVOS (AGRICULTURAL INSECTICIDES. NEC, LIQUID) DICHLORVOS (AGRICULTURAL INSECTICIDES. NEC. OTHER THAN LIOUIO) DICHLORVOS (INSECTICIDES. OTHER THAN AGRICUL TURAL. NEC) DICHLORVOS MIXTURE. DRY (AGRICULTURAL INSECTI CIDES. NEC. OTHER THAN LIQUID) DISULFOTON (AGRICULTURAL INSECTICIDES. NEC. LIQUID) DISULFOTON (AGRICULTURAL INSECTICIDES. NEC. OTHER THAN LIQUID) DISULFOTON (INSECTICIDES. OTHER THAN AGRICUL TURAL. NEC) DISULFOTON MIXTURE. DRY (AGRICULTURAL INSECTI CIDES. NEC. OTHER THAN LIQUID) DISULFOTON MIXTURE. LIQUID (AGRICULTURAL INSECTI CIDES. NEC, LIQUID) ETHION (AGRICULTURAL INSECTICIDES. NEC. LIQUID) ETHION (AGRICULTURAL INSECTICIDES. NEC, OTHER THAN LIQUID) ETHION (INSECTICIDES, OTHER THAN AGRICULTURAL, NEC) ETHION MIXTURE, DRY (AGRICULTURAL INSECTICIDES. NEC. OTHER THAN DRY LIQUID) HEXAETHYl TETRAPHOSPHATE MIXTURE, DRY (CONTAING NOT MORE THAN 2% HEXAETHYL TETRAPHOSPHATE) HEXAETHYL TETRAPHOSPHATE MIXTURE, DRY (CONTAIN ING MORE THAN 2% HEXAETHYL TETRAPHOSPHATE) 484 484 484 71 71 71 72 208 208 209 70 71 55 56 56 56 126 126 126 153 153 177 178 176 168 189 189 189 210 210 211 211 211 225 225 225 226 270 270 561 0,0 001748a 2783 2783 2783 2783 2783 2783 2783 2783 2783 2783 2783 2783 2783 2783 2783 2783 2783 2783 2783 27B3 2783 2783 2783 2783 2783 2783 2783 2783 2783 27B3 2783 2783 2784 2784 2786 2786 2786 2786 2787 HEXAETHYL TETRAPHOSPHATE MIXTURE, LIQUID (CON TAINING MORE THAN 25% HEXAETHYL TETRAPHOSPHATE) HEXAETHYL TETRAPHOSPHATE MIXTURE, LIQUID (CON TAINING NOT MORE THAN 25% HEXAETHYL TETRAPHOSPHATE) MALATHION METHYL PARATHION MIXTURE, DRY METHYL PARATHION MIXTURE, LIQUID (CONTAINING 25% OR LESS METHYL PARATHION) METHYL PARATHION MIXTURE. LIQUID (CONTAINING OVER 25% METHYL PARATHION) METYL PARATHION, LIQUID MEVINPHOS (AGRICULTURAL INSECTICIDES. NEC. LIQUID) MEVINPHOS (AGRICULTURAL INSECTICIDES, NEC, OTHER THAN LIQUID) MEVINPHOS (INSECTICIOES, OTHER THAN AGRICULTURAL, NEC) MEVINPHOS MIXTURE. DRY (AGRICULTURAL INSECTI CIDES, NEC, OTHER THAN LIQUID) MEVINPHOS MIXTURE. LIOUID (AGRICULTURAL INSECT- CIDES, NEC. LIQUID) NALED (AGRICULTURAL INSECTICIDES, NEC, LIQUID) NALED (AGRICULTURAL INSECTICIDES. NEC, OTHER THAN LIQUID) NALED (INSECTICIDES, OTHER THAN AGRICULTURAL, NEC) ORGANIC PHOSPHATE MIXTURE. ORGANIC PHOSPHATE COMPOUND MIXTURE, (OR) ORGANIC PHOSPHORUS MIX TURE, SOLID (OR) DRY ORGANIC PHOSPHATE MIXTURE, ORGANIC PHOSPHATE COMPOUND MIXTURE, (OR) ORGANIC PHOSPHORUS COMPOUND MIXTURE, LIQUID ORGANIC PHOSPHATE, ORGANIC PHOSPHATE COM POUND, (OR) ORGANIC PHOSPHORUS COMPOUND, LIQUID ORGANIC PHOSPHATE, ORGANIC PHOSPHATE COM POUND, (OR) ORGANIC PHOSPHORUS COMPOUND MIX TURE, SOLID (OR) DRY ORGANOPHOSPHORUS PESTICIDE. LIQUID. N O S. (COM POUNDS AND PREPARATIONS (INSECTICIDES, OTHER THAN AGRICULTURAL, NEC) ORGANOPHOSPHORUS PESTICIDE. LIQUID, N.O.S. (COM POUNDS AND PREPARATIONS (AGRICULTURAL INSEC TICIDES. NEC. LIOUID) ORGANOPHOSPHORUS PESTICIDE. SOLID, N.O.S. (COM POUNDS AND PREPARATIONS) (AGRICULTURAL INSEC TICIDES, NEC, OTHER THAN LIQUID) ORGANOPHOSPHORUS PESTICIDE, SOLID, N.O.S, (COM POUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL, NEC) PARATHION MIXTURE, DRY PARATHION MIXTURE, LIQUID PARATHION, LIQUID TETRAETHYL PYROPHOSPHATE LIQUID TETRAETHYL PYROPHOSPHATE MIXTURE, DRY TETRAETHYL PYROPHOSPHATE MIXTURE, LIQUID TRICHLORFON (AGRICULTURAL INSECTICIDES. NEC. LIQUID) TRICHLORFON (AGRICULTURAL INSECTICIDES, NEC, OTHER THAN LIQUID) TRICHLORFON (INSECTICIDES, OTHER THAN AGRICUL TURAL. NEC) ORGANOPHOSPHORUS PESTICIDE. LIQUID. N.O.S. (COM POUNDS AND PREPARATIONS (INSECTICIDES, OTHER THAN AGRICULTURAL, NEC) ORGANOPHOSPHORUS PESTICIDE, LIQUID. N.O.S. (COM POUNDS AND PREPARATIONS (AGRICULTURAL INSEC TICIDES, NEC. LIQUID) ORGANOTIN PESTICIDE. LIQUID. N.O.S. (COMPOUNDS ANO PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICUL TURAL. NEC) ORGANOTIN PESTICIDE. LIQUID. N.O.S. (COMPOUNDS ANO PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC. LIQUID) ORGANOTIN PESTICIDE, SOLID, N.O.S (COMPOUNDS ANO PREPARATIONS) (INSECTICIDES. OTHER THAN AGRICUL TURAL, NEC) ORGANOTIN PESTICIDE. SOLID. N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES. NEC. OTHER THAN LIQUID) ORGANOTIN PESTICIDE, LIOUID, N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICUL TURAL, NEC) 270 270 320 342 342 342 347 348 348 348 349 349 359 359 359 381 381 381 361 383 384 384 385 392 392 392 493 494 494 507 507 507 384 384 385 385 386 3B6 385 562 2787 2789 2790 2791 2792 2794 2794 2794 2794 2794 2796 2797 2797 2797 2797 2797 2798 2799 2801 2801 2802 2605 2806 2810 2810 2810 2810 2810 2810 2810 2810 2810 2810 2810 2810 2810 2811 2811 2811 2811 2811 2811 2811 2811 2811 2811 2811 2811 2811 2811 2811 2811 2811 2811 2811 2811 2813 2813 2814 ORGANOTIN PESTICIDE, LIQUID, N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC, LIQUID) ACETIC ACID, GLACIAL ACETIC ACID (AQUEOUS SOLUTION) AIRCRAFT ROCKET ENGINE (COMMERCIAL) AIRCRAFT ROCKET ENGINE IGNITER (COMMERCIAL) BATTERIES, ELECTRIC STORAGE, WET. WITH AUTOMOBILE AUTO PARTS. ENGINE BATTERY CHARGER WITH ELECTROLYTE (ACID) BATTERY CHARGER WITH ELECTROLYTE (ALKALINE BAT TERY FLUID) BATTERY, ELECTRIC STORAGE, WET BATTERY. ELECTRIC STORAGE. WET. WITH CONTAINERS OF CORROSIVE BATTERY FLUID ELECTROLYTE (ACID) BATTERY. FLUID ALKALINE CORROSIVE BATTERY FLUID ALKALINE CORROSIVE BATTERY FLUID PACKED WITH BAT TERY CHARGER, RADIO CURRENT SUPPLY DEVICE OR ELECTRONIC EQUIPMENT AND ACTUATING DEVICES ALKALINE CORROSIVE BATTERY FLUID WITH EMPTY STOR AGE BATTERY ELECTROLYTE (ACID) PACKED WITH BATTERY CHARGER, RADIO CURRENT SUPPLY DEVICE OH ELECTRONIC EQUIPMENT AND ACTUATING DEVICE) ELECTROLYTE (ACID) PACKED WITH DRY STORAGE BATTERY BENZENE PHOSPHORUS DICHLORIDE BENZENE PHOSPHORUS THIODICHLORIDE COAL TAR DYE, LIQUID DYE INTERMEDIATE. LIQUID COPPER CHLORIDE LITHIUM HYDRIDE IN FUSED SOLID FORM LITHIUM NITRIDE ANIMAL OR POULTRY DIP, NEC, LIOUID (POISONOUS LIO UID. N.O.S.) ARSENOUS AND MERCURIC IODIDE SOLUTION CHEMICAL PLANT WASTE, NEC (POISONOUS LIQUID. N.O.S ) CHLORINATED PHENOL PETROLEUM SOLUTION (POISON OUS LIQUID, N.O.S.) COMPOUNDS, TREE OR WEED KILLING, LIQUID DICHLOROETHYL ETHER (POISONOUS LIQUID,N.O.S.) DRUGS OR MEDICINES. N.O.S. (LIQUID) FUNGICIDES. AGRICULTURAL, NEC, LIQUID (POISONOUS LIOUID. N.O.S.) MEDICINES. N.O.S. (LIQUID) NICKEL PLATING SOLUTION (POISONOUS LIOUID. N.O.S.) POISONOUS LIOUID, N.O.S. SELENIUM OXYCHLORIDE (POISONOUS SOLID. N.O.S.) SOLUTION. COPPER PLATING (POISONOUS LIQUID, N.O.S.) ANIMAL OR POULTRY DIP, NEC. OTHER THAN LIQUID (POI SONOUS SOLID, N.O.S.) ARSENIC, CRUDE (POISONOUS SOLIO. N.O.S.) ARSENICAL ORE, CRUDE (POISONOUS SOLID. N.O.S.) COMPOUNDS METAL PURIFYING, NEC (POISONOUS SOLID, N.O.S.) COMPOUNDS, CASE CARBURIZING OR HARDENING. NEC (POISONOUS SOLID, N.O.S.) COMPOUNDS, CASE HARDENING OR CARBURIZING. CHAR COAL. COAL. OR COKE BASE (POISONOUS SOLID. N.O.S.) DICHLOROANILINE (POISONOUS SOLID, N.O.S.) DRUGS OR MEDICINES. N.O.S. (SOLID) FUNGICIDES, AGRICULTURAL. NEC. OTHER THAN LIQUID (POISONOUSSOUD. N.O.S.) LEAD BAGHOUSE FLUE DUST (FLUE DUST. POISONOUS) LEAD FLUE DUST (FLUE DUST. POISONOUS) LEAD FLUORIDE LEM) IODIDE LEAD STEARATE MEDICINES, N.O.S. (SOLID) NAPHTHYL METHYL CARBAMATE (POISONOUS SOLID, N.O.S.) POISONED GRAIN (POISONOUS SOLID. N.O.S.) POISONOUS SOLID. N.O.S. POLYCHLOR AGRICULTURAL FUNGICIDES (POISONOUS SOLID. N.O.S.) SELENIUM OXIDE LITHIUM ACETYLIDE-ETHYLENE DIAMINE COMPLEX WATER REACTIVE SOLID, N.O.S. ETIOLOGIC AGENT, N.O S. (OR) INFECTIOUS SUBSTANCE, HUMAN, N.O.S. 386 2 2 11 11 59 60 60 60 61 218 16 16 17 218 219 62 62 132 217 148 316 317 40 53 116 119 145 185 215 259 322 364 416 456 477 41 51 52 143 143 143 162 215 259 307 308 308 309 309 322 362 415 416 418 456 314 531 239 MCD 000017490 2815 2817 2819 2820 2821 2823 2826 2830 2835 2837 2845 2845 2845 2845 2845 2854 2855 2857 2857 2857 2862 2867 2868 2876 2880 2883 2884 2885 2886 2887 2888 2889 2890 2891 2892 2893 2894 2895 2896 2896 2896 2897 2898 2902 2910 2911 N-AMINOETHYL PIPERAZINE AMMONIUM HYDROGEN FLUORIDE SOLUTION AMYL ACID PHOSPHATE BUTYRIC ACID CARBOLIC ACID. LIQUID OR PHENOL. LIQUID. (LIQUID TAR ACID CONTAINING OVER 50% BENZO-PHENOL) CROTONIC ACID ETHYL CHLOROTHIOFORMATE LITHIUM FERRO SILICON SOOIUM ALUMINUM HYDRIDE SODIUM HYDROGEN SULFATE SOLUTION ALUMINUM ALKYL ETHYL PHOSPHONOUS DICHLORIDE, ANHYDROUS METHYL PHOSPHONOUS DICHLORIDE PYROFORIC LIQUID. N.O.S. TOLUENE (TOLUOL), MIXED WITH ALUMINUM ALKYLS. NOT TO EXCEED 20 PERCENT (ALUMINUM ALKYL) AMMONIUM SILICOFLUORIDE ZINC SILICOFLUORIDE REFRIGERATING MACHINE (COOLING ROOMS. COOLING BOXES. OR REFRIGERATORS OTHER THAN HOUSEHOLD TYPE) REFRIGERATING MACHINE (ICE CREAM POWER FREEZERS AND MECHANICAL REFRIGERATORS) REFRIGERATING MACHINE (REFRIGERATORS. NEC) VANADIUM PENTOXIDE INK, PRINTING. NEC (INK) RESIN SOLUTION (RESIN COMPOUND, LIQUID) RESORCINOL CALCIUM HYPOCHLORITE, HYDRATED (MINIMUM 5.5% BUT NOT MORE THAN 10% WATER. AND CONTAINING MORE THAN 39% AVAILABLE CHLORINE) 2,2-DI-(TERT-BLrrYLPEnOXY)PnOPANE. (NOT MORE THAN 50% WITH PHLEGMATIZER) 2,2-DHTERT-BUTYLPEROXY)PROPANE. (NOT MORE THAN 40% WITH INERT INORGANIC SOLID WITH NOT LESS THAN 13% PHLEGMATIZER) 1,1 -DI-(TERT-BUTYLPEROXY)CYCLOHEXANE, (NOT MORE THAN 40% WITH INERT INORGANIC SOLID. WITH NOT LESS THAN 13% PHLEGMATIZER) TERT-BUTYL PEROXY-2-ETHYLHEXANOATE. (NOT MORE THAN 30%) WITH 2,2-DI-(TERT-BUTYLPEROXY) BUTANE. (NOT MORE THAN 35% WITH NOT LESS THAN 35% PHLEGMATIZER) TERT-BUTYL P6ROXY-2-ETHYLHEXANOATE, NOT MORE 12%) WITH 2,2-DI-(TERT-BUTYLPEROXY)BUTAN, (NOT MORE THAN 14% WITH NOT LESS THAN 14% PHLEGMATIZER AND 60% INERT INORGANIC SOLID) TERT-BUTYL PEROXY-2-ETHYLHEXANOATE, (NOT MORE THAN 50% WITH PHLEGMATIZER) DMSOTRIDECYL PEROXYOICARBONATE, (TECHNICALLY PURE) TERT-BUTYL PEROXYBENZOATE (NOT MORE THAN 50% WITH INERT INORGANIC SOUD) TERT-AMYL PEROXYNEODECANOATE, (NOT MORE THAN 75% WITH PHLEGMATIZER) DIMYRISTYL PEROXYOICARBONATE. (NOT MORE THAN 22%. STABLE DISPERSION, IN WATER) LAUROYL PEROXIDE. (NOT MORE THAN 42%.STABLE DIS- PERSION, IN WATER) DI-(4-TERT-8UTYLCYCLOHEXYL)PEROXYDICARBONATE, (NOT MORE THAN 42%. STABLE DISPERSION, IN WATER) DICETYL PEROXYOICARBONATE. (NOT MORE THAN 42%. STABLE DISPERSION. IN WATER) CYCLOHEXANONE PEROXIDE AND DI-(1-HYDROXYCY- CLOHEXYL) PEROXIDE MIXTURE CYCLOHEXANONE PEROXIDE, (AS A PASTE WITH NOT MORE THAN 9% BY WEIGHT ACTIVE OXYGEN1 CYCLOHEXANONE PEROXIDE, (NOT OVER 50% PEROXIDE) INERT INORGANIC SOLIO, WITH NOT LESS THAN 13% PHLEGMATIZER) 1,1 -OI*(TERT-BUTYLPEROXY)CYCLOHEXANE. (NOT MORE THAN 50% WITH TERT-AMYL PEROXY-2-ETHYLHEXANOATE, (TECHNICALLY PURE) INSECTICIDE. LIQUID, N.O.S. (AGRICULTURAL INSECTICIDES OR FUNGICIDES. NEC. LIQUID) RADIOACTIVE MATERIAL LIMITED QUANTITY. N.O.S. (RA- DIOACTIVE ARTICLES OR ISOTOPES, NEC) RADIOACTIVE ARTICLES, NEC (RADIOACTIVE DEVICE. N.O.S.) 22 27 36 95 106 154 229 316 461 467 19 232 344 435 502 31 441 446 446 447 523 289 447 447 99 172 171 169 84 85 85 197 87 491 204 306 174 180 160 160 161 169 38 291 440 438 2911 2911 2911 2912 2912 2912 2912 2912 2912 2918 2918 2918 2922 2922 2922 2923 2924 2924 2924 2924 2925 2926 2928 9035 9035 9035 9035 9035 9077 9078 9078 9078 9078 9079 9080 9081 9083 9084 9065 9066 9067 9068 9069 9090 9091 9092 9092 9093 9093 9094 RADIOACTIVE ARTICLES. NEC (RADIOACTIVE DEVICE. N.O.S.. FISSILE CLASS II) RADIOACTIVE ARTICLES. NEC (RADIOACTIVE DEVICE. N.O.S.. FISSILE CLASS III) RADIOACTIVE DEVICE. N.O.S.. FISSILE CLASS I (RADIOAC- TIVE ARTICLES, NEC) LIGNITE ASH. URANIUM BEARING (RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY, (OR). LSA. N.O.S.) METAL ALLOY BILLETS, BLOOMS. INGOTS, PIGS. SPONGE OR SHOT. NEC. NOT IRRAOIATED NOR REQUIRING PRO TECTIVE SHIELDING (RADIOACTIVE MATERIAL N.O.S.) METAL OR METAL ALLOY BILLETS, BLOOMS, INGOTS, PIGS, SPONGE. OR SHOT. NOT IRR1DATED NOR REQUIRING PROTECTIVE SHIELDING (RADIOACTIVE MATERIAL LOW SPECIFIC ACTIVITY OR LSA, N.O.S.) RAOIOACTIVE MATERIAL. LOW SPECIFIC ACTIVITY (OR) LSA.. N.O.S. (RADIOACTIVE MATERIALS. ARTICLES OR ISOTOPES. NEC) THORIUM ORE (MONAZITE SAND) (RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY. (OR). LSA. N.O.S.) URANIUM BEARING ORE (RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY (OR) LSA, N.O.S.) NUCLEAR FUEL ELEMENTS. PARTS OR CONSTITUENTS IR- RADIATED REQUIRING PROTECTIVE SHIELDING (RADIO ACTIVE MATERIAL. N.O.S.. FISSILE CLASS III) NUCLEAR FUEL ELEMENTS. PARTS OR CONSTITUENTS IRRADIATED. REQUIRING PROTECTIVE SHIELDING (RADIO ACTIVE MATERIAL. N.O.S.. FISSILE CLASS I) SHIELDING) NUCLEAR FUEL ELEMENTS. PARTS OR CONSTITUENTS. IRRADIATED REQUIRING PROTECTIVE SHIELDING (RADIO ACTIVE MATERIAL. N.O.S. FISSILE CLASS II) CORROSIVE LIQUID. POISONOUS. N.O.S. DIMETHYL CHLOROTHIOPHOSPHATE SODIUM HYDROSULFIDE, SOLUTION SODIUM HYDROSULFIDE, SOLID (WITH NOT LESS THAN 25% WATER OF CRYSTALLIZATION) DICHLOROBUTENE DICHLOROBUTENE FLAMMABLE LIQUID, CORROSIVE. N.O.S. MIXED CHLOROSILANES (FLAMMABLE LIQUID. CORROSIVE, N.O.S.) FLAMMABLE SOLID, CORROSIVE. N.O.S. FLAMMABLE SOLID. POISONOUS, N.O.S. POISONOUS SOLID, CORROSIVE. N.O.S. GAS IDENTIFICATION SET GAS IDENTIFICATION SET LEWISITE (POISONOUS LIQUID. N.O.S.) MUSTARD GAS (POISONOUS LIQUID. N.O.S.) POISONOUS LIQUID, N.O.S. ADIPIC ACID ALUMINUM SULFATE ALUMINUM SULPHATE FLUOSULPHATE MIXTURE, FLUO- RINE CONTENT NOT TO EXCEED 25% (ALUMINUM SULFATE) ALUMINUM SULPHATE, NOT MORE THAN 5% ACTIVATED CARBON (ALUMINUM SULFATE) SODIUM ALUMINUM SULPHATE (SODIUM ALUM) (ALUMINUM SULFATE) AMMONIUM ACETATE AMMONIUM BENZOATE AMMONIUM BICARBONATE AMMONIUM CARBAMATE AMMONIUM CARBONATE AMMONIUM CHLORIDE AMMONIUM CHROMATE AMMONIUM CITRATE. DIBASIC AMMONIUM FLUOBORATE AMMONIUM SULFAMATE AMMONIUM SULFITE AMMONIUM TARTRATE AMMONIUM THIOCYANATE CRYSTALS(AMMONIUM THIOCYANATE) AMMONIUM THIOCYANATE LIQUOR(AMMONIUM THIOCYANATE) AMMONIUM THIOSULFATE AMMONIUM THIOSULFATE SOLUTION(AMMONIUM THIOSULFATE) BENZOIC ACID 9095 N-SUTYL PHTHALATE 439 439 439 312 331 332 440 499 516 376 377 377 151 198 468 468 184 184 250 351 251 251 416 202 262 312 358 416 10 21 21 21 561 24 24 24 25 25 26 26 26 26 31 32 32 32 32 33 33 63 92 563 MCD 0000.17491 9096 9097 9099 9099 9096 9100 9100 9100 9101 9102 9102 9103 9104 9105 9106 9109 9109 9109 9110 9111 9117 911B 9119 9120 9121 9121 9121 9122 9122 9125 9125 9125 9126 9127 9134 9137 9138 9139 9140 9141 9141 9142 9145 9145 9146 9147 9146 9149 9151 9152 9153 9154 9155 9156 9157 9158 9159 9160 9161 9162 9163 9170 9171 9173 9173 CALCIUM CHROMATE CALCIUM DODECYLBENZENESULFONATE CAPTAN (AGRICULTURAL INSECTICIDES, NEC, LIQUID) CAPTAN {AGRICULTURAL INSECTICIDES, NEC. OTHER THAN LIQUID) CAPTAN (INSECTICIDES. OTHER THAN AGRICULTURAL. NEC) CHROME SULPHATE SOLUTION (CHROMIC SULFATE) CHROMIC SULFATE CHROMIUM SULPHATE. BASIC. DRY (CHROMIC SULFATE) CHROMIC ACETATE CHROME CHLORIDE SOLUTION (CHROMOUS CHLORIDE) CHROMOUS CHLORIDE COBALTOUS BROMIDE COBALTOUS FORMATE COBALTOUS SULFAMATE COPPER ACETATE (VERDIGRIS) (CUPRIC ACETATE) COPPER SULFATE AND LIME COMBINED, DRY (CUPRIC SULFATE) COPPER SULPHATE AND SULPHUR (CUPRIC SULFATE) CUPRIC SULFATE CUPRIC SULFATE, AMMONlATED CUPRIC TARTRATE ETHYLENEDIAMINETETRAACETIC ACID (OR) EDTA FERRIC AMMONIUM CITRATE FERRIC AMMONIUM OXALATE FERRIC FLUORIDE FERRIC SULPHATE SOLUTION (FERRIC SULFATE) IRON SULPHATE (FERRIC). DRY, CRUDE (FERRIC SULFATE) IRON SULPHATE (FERRIC), DRY, OTHER THAN CRUDE (FER- RIC SULFATE) FERROUS AMMONIUM SULFATE FERROUS AMMONIUM SULPHATE. FERTILIZER GRADE (IRON AMMONIUM SULPHATE) (FERROUS AMONIUM SULFATE) FERROUS SULFATE FERROUS SULPHATE, LESS THAN 40% WATER (FERROUS SULFATE) FERROUS SULPHATE, NOT LESS THAN 40% WATER (FER- ROUS SULFATE) FUMARIC ACID ISOPROPANOLAMINE DODECYLBENZENESULFONATE LITHIUM CHROMATE NAPHTHENIC ACID NICKEL AMMONIUM SULFATE NICKEL CHLORIDE NICKEL HYDROXIDE NICKEL SULFATE NICKEL SULFATE, COPPER REFINERY. CRUDE (NICKEL SULFATE) POTASSIUM CHROMATE SOOIUM CHROMATE SOLUTION (SODIUM CHROMATE) SODIUM CHROMATE. DRY (SODIUM CHROMATE) SODIUM DODECYLBENZENESULFONATE SODIUM PHOSPHATE. DIBASIC SOOIUM PHOSPHATE, TRIBASIC STRONTIUM CHROMATE TRIETHANOLAMINE DODECYLBENZENESULFONATE VANADYL SULFATE ZINC ACETATE ZINC AMMONIUM CHLORIDE ZINC BORATE ZINC BROMIDE ZINC CARBONATE ZINC FLUORIDE ZINC FORMATE ZINC PHENOLSULFONATE ZINC SULFATE ZIRCONIUM POTASSIUM FLUORIDE ZIRCONIUM SULFATE THORIUM METAL BILLETS, INGOTS, PIGS OR SLABS. NOT IRRADIATED. NOR REQUIRING PROTECTIVE SHIELDING (THORIUM METAL PYROFORIC) THORIUM NITRATE. SOLID URANIUM HEXAFLUORIDE FISSILE CLASS I (CONTAINING MORE THAN 0.7% U-235) (URANIUM FLUORIDES. NOT IR RADIATED NOR REQUIRING PROTECTIVE SHIELDING) URANIUM HEXAFLUORIDE. FISSILE CLASS II (CONTAINING MORE THAN 0 7% U-235) (URANIUM FLUORIDES. NOT IR RADIATED NOR REQUIRING PROTECTIVE SHIELDING) 97 98 102 102 102 127 129 129 127 127 129 136 137 137 146 150 150 156 156 157 238 243 243 244 245 293 293 245 245 246 247 247 257 300 315 361 362 363 364 364 365 420 464 465 466 473 474 481 510 523 537 537 537 536 536 539 540 541 542 544 544 499 499 516 517 564 9173 URANIUM HEXAFLUORIDE. FISSILE CLASS III (CONTAINING MORE THAN 0.7% U-235) (URANIUM FLUORIDES. NOT IR- RAOIATED NOR REQUIRING PROTECTIVE SHIELDING) 9174 URANIUM HEXAFLUORIDE, LOW SPECIFIC ACTIVITY (CON- TAINING 0.7% OR LESS U-235) (URANIUM FLUORIDES. NOT IRRADIATED NOR REQUIRING PROTECTIVE SHIELDING) 9175 URANIUM METAL BARS, RODS OR SHAPES, NOT IRRADIATED, NOR REQUIRING PHOT SHIELDING (URANIUM METAL PYROFORIC) 9175 URANIUM METAL BILLETS, INGOTS. PIGS OR SLABS NOT IRRADIATED NOR REQUIRING PROTECTIVE SHIELDING (URANIUM METAL, PYROFORIC) 9175 URANIUM METAL SCRAP NOT IRRADIATED NOR REQUIRING PROTECTIVE SHIELDING (URANIUM METAL PYROFORIC) 9177 URANYL NITRATE. SOLID 9177 URANYL NITRATE, SOLID FISSILECLASS I 9177URANYL NITRATE, SOLID FISSILE CLASS II 9177 URANYL NITRATE, SOLID FISSILE CLASS III 9178 URANYL NITRATE HEXAHYDRATE SOLUTION 9180URANYL ACETATE 9181 CORES OR CORE ASSEMBLIES OR FUEL BLANKET ASSEM- BLIES, NUCLEAR REACTOR, NOT IRRADIATED, WITH NONIRRADIATED FUEL (RADIOACTIVE MATERIAL. N.O.S.) 9181 RADIOACTIVE ISOTOPES, NEC (RADIOACTIVE MATERIALS, N.O.S.) 9181 RADIOACTIVE MATERIAL SHIPPING CONTAINERS. STEEL AND URANIUM METAL EMPTY (RADIOACTIVE MATERIAL, N.O.S.) 9181 RADIOACTIVE MATERIAL. N.O.S, 9181 RADIOACTIVE MATERIAL, N.O.S. FISSILE CLASS I 9181 RADIOACTIVE MATERIAL. N.O.S. FISSILE CLASS II 9181 RADIOACTIVE MATERIAL. N.O.S. FISSILE CLASS III 9181 RADIOACTIVE WASTE MATERIAL. HAVING NO RECLAMATION VALUE REQUIRING PROTECTIVE SHIELDING (RA DIOACTIVE MATERIAL. N.O.S.) 9181 RADIOACTIVE WASTE MATERIAL. HAVING NO RECLAMATION VALUE, REQUIRING PROTECTIVE SHIELDING (RA DIOACTIVE MATERIAL. N.O.S.. FISSILE CLASS III) 9181 RADIOACTIVE WASTE MATERIAL, HAVING NO RECLAMATION VALUE. REQUIRING PROTECTIVE SHIELDING (RA DIOACTIVE MATERIAL, N.O.S., FISSILE CLASS II) 9181 RADIOACTIVE WASTE MATERIAL HAVING NO RECLAMATION VALUE. REQUIRING PROTECTIVE SHIELDING (RA DIOACTIVE MATERIAL N.O.S., FISSILE CLASS I) 9181 THORIUM METAL BARS RODS. OR SHAPES. NOT IRRADIATEO NOR REQUIRING PROTECTIVE SHIELDING (RADIO ACTIVE MATERIAL. N.O.S.) 9181 THORIUM METAL SCRAP, NOT IRRADIATED NOR REQUIRING PROTECTIVE SHIELDING (RADIOACTIVE MATERIAL. N.O.S.) 9181 THORIUM OXIOE (RADIOACTIVE MATERIAL N.O.S.) 9181 URANATES NOT IRRADIATED NOR REQUIRING PROTECTIVE SHIELDING (RADIOACTIVE MATERIAL. N.O.S.) 9181 9181 9181 9181 9181 9181 9182 9182 9182 9182 URANIUM OXIDES. NOT IRRADIATED NOR REQUIRING PROTECTIVE SHIELDING (RADIOACTIVE MATERIAL N.O.S.) URANIUM SALTS, NOT IRRADIATED NOR REQUIRING PROTECTIVE SHIELDING (RADIOACTIVE MATERIAL N O S.) WATCH DIAL ENAMEL (RADIOACTIVE MATERIAL N.O.S. FISSILE CLASS III) WATCH DIAL ENAMEL (RADIOACTIVE MATERIAL. N.O.S.) WATCH DIAL ENAMEL (RADIOACTIVE MATERIAL, N.O.S . FISSILE CLASS I) WATCH DIAL ENAMEL (RADIOACTIVE MATERIAL. N.O.S , FISSILE CLASS II) RADIOACTIVE MATERIAL SPECIAL FORM, N.O.S. RADIOACTIVE MATERIAL SPECIAL FORM, N.O.S.. FISSILE CLASS I RADIOACTIVE MATERIAL SPECIAL FORM, N.O.S.. FISSILE CLASS II RADIOACTIVE MATERIAL SPECIAL FORM. N O S.. FISSILE CLASS III 9183 9184 9184 918* ORGANIC PEROXIDE. LIQUID, (OR) SOLUTION, N.O.S. PYRETHRINS (AGRICULTURAL INSECTICIDES. NEC. LIQUID) PYRETHRINS (AGRICULTURAL INSECTICIDES. NEC. OTHER THAN UQUID) PYRETHRINS (INSECTICIDES, OTHER THAN AGRICUL- TURAL NEC) 517 517 518 518 518 520 520 521 521 519 519 150 440 440 441 441 441 441 442 443 444 444 496 499 496 516 519 519 529 530 530 530 442 442 442 443 380 434 434 434 )Ci^ A.9`2* 9184 9164 9165 9167 9186 9188 9169 PYRETHRINS (PYRETHRUM EXTRACT, NOT LESS THAN 25% PYRETHRUM) PYRETHRINS (PYRETHRUM) PLUTONIUM NITRATE SOLUTION ORGANIC PEROXIDE. SOLID. N.O.S. HAZARDOUS SUBSTANCE. LIQUID (OR) SOLID. NO.S. WEED KILLING COMPOUND AND CHLORDANE MIXTURE (HAZARDOUS SUBSTANCE. LIQUID (OR) SOLID) HAZARDOUS WASTE. LIQUID (OR) SOLID. N.O.S. 435 435 415 380 267 531 267 9190 9191 9193 9194 9195 9199 9200 9201 AMMONIUM PERMANGANATE CHLORINE DIOXIDE HYDRATE. FROZEN OXIDIZER. CORROSIVE. LIQUID. N.O.S. OXIDIZER, CORROSIVE, SOLID, N.O.S. METAL ALKYL, SOLUTION, N.O.S. OXIDIZER, POISONOUS. LIQUID, N.O.S. OXIDIZER. POISONOUS, SOLID. N.O.S. ANTIMONY TRIOXIDE (ANTIMONY OXIDE) 31 119 387 387 331 387 387 46 A^3 000 565 DESCRIPTION OF STCC ORGANIZATION The information presented in the table below is designed to describe the Standard Transportation Commodity Code (STCC) organization. Listed are the major hazard classes and, where appropriate, the secondary (and sometimes, tertiary) hazards of materials. This tabfe can be used to identify basic hazards of materials when the name of the material is unknown, but the middle three digits of the 49 series STC code are known. CLASS A EXPLOSIVES 49011 Ammunition 012 Military devices other than ammunition 013 Commercial devices 014 Initiating explosives 015 High explosives 016 Propellant explosives 017 Low explosives CLASS B EXPLOSIVES 49021 Ammunition 023 Propellant explosives, liquid 024 Propellant explosives, solid 025 Explosives devices 028 Special fireworks CMSS C EXPLOSIVES 49031 Ammunition 032 Military explosive devices 033 Explosives devices, detonating 034 Explosive devices, non-detonating 035 Fireworks, toy or novelty devices 036 Signaling devices NONFLAMMABLE COMPRESSED GASES 49040 Oxidizing poisonous, corrosive 041 Poisonous 042 Corrosive 043 Oxidizing 044 Oxygen mixtures 045 048 FLAMMABLE COMPRESSED GASES 49054 Poisonous 055 Corrosive 057 058 FLAMMABLE LIQUIDS 49060 Pyroforic 062 Thermally unstable, poisonous 064 Polymerizable, poisonous 066 Thermally unstable, corrosive 068 Polymerizable, corrosive 070 Thermally unstable 072 Polymerizable 074 Poisonous 076 Corrosive, acidic 078 Corrosive, basic 001 Flash point below 20 F 091-093 101-105 COMBUSTIBLE LIQUIDS 49122 Polymerizable 131 151-155 FLAMMABLE SOLIDS 49161 Pyroforic, poisonous 162 Pyroforic 163 Poisonous, water reactive 164 Water reactive 166 Poisonous 167 171 Water wet explosives 173-174 OXIDIZERS 49181 Poisonous, thermally unstable 182 Poisonous corrosive 183 Thermally unstable, inorganic 184 Thermally unstable, organic 185 Corrosive 186 Solution or wet, inorganic 187 189 ORGANIC PEROXIDES 49191 195 POISON CLASS A 49201 Flammable 203 Oxidizing 205 209 POISON CLASS B 49212 Corrosive 214 Organic 215 231 Corrosive 232-233 234 Inorganic salt 239 -7 49 4 oooo 566 IRRITATING MATERIALS 49251 Tear Gas 252 258 ETIOLOGIC AGENT 49259 RADIOACTIVE MATERIALS 49261 Pyroforic 263 Oxidizing 264 273 Fissile Class III, oxidizing 274 Fissile Class III 283 Fissile Class II oxidizing 284 Fissile Class II 293 Fissile Class 1, oxidizing 294 Fissile Class 1 CORROSIVE MATERIALS 49300 Acidic, poisonous 302 Acidic 312 Acidic, poisonous 313 Organic acids 314 Acidic 317 Acidic 320 Acidic, poisonous 323 Acidic 330 Acidic, poisonous 333 Organic salts and esters 342 Acidic 350 Basic, poisonous 352 Basic 355 Basic, poisonous 356 Basic 360 Poisonous 361 Poisonous, oxidizing 362-363 365 Miscellaneous compounds ORM-A 49401 411 ORM-B 49441 MIXED LOAD 49501 ORM-E 49601-49699 STANDARD TRANSPORTATION COMMODITY CODE (STCC)/COMMOD1TY/PAGE This index lists hazardous materials in Standard Transportation Commodity Code (STCC) order and provides the name of the commodity and the page number on which emergency response information for that commodity can be found. 4901105 AMMUNITION FOR CANNON WITH EXPLOSIVE PROJECTILE 4901110 AMMUNITION FOR CANNON WITH GAS PROJECTILE 4901115 AMMUNmON FOR CANNON WITH ILLUMINATING PROJECTILE 4901120 AMMUNITION FOR CANNON WITH INCENDIARY PROJECTILE 4901125 AMMUNITION FOR CANNON WITH SMOKE PROJECTILE 4901127 AMMUNITION FOR CANNON WITH TEAR GAS PROJECTILE 4901130 AMMUNITION FOR SMALL ARMS WITH EXPLOSIVE PROJECTILE 4901135 AMMUNITION FOR SMALL-ARMS WITH INCENDIARY PROJECTILE 4901140 ROCKET AMMUNITION WITH EXPLOSIVE PROJECTILE 4901145 ROCKET AMMUNITION WITH GAS PROJECTILE 4901150 ROCKET AMMUNITION WITH ILLUMINATING PROJECTILE 4901155 ROCKET AMMUNITION WITH INCENDIARY PROJECTILE 4901160 ROCKET AMMUNITION WITH SMOKE PROJECTILE 4901165 AMMUNITION, CHEMICAL, EXPLOSIVE. WITH POISON A MATERIAL 4901166 AMMUNITION, CHEMICAL. EXPLOSIVE, WITH POISON 6 MATERIAL 4901167 AMMUNITION. CHEMICAL EXPLOSIVE. WITH IRRITANT 4901205 DETONATING FUZE 4901210 DETONATING FUZE. RADIOACTIVE 4901215 BOOSTER. (EXPLOSIVE)(MILITARY) 4901220 BURSTER (EXPLOSIVE) 4901225 SUPPLEMENTARY CHARGE (EXPLOSIVE) 4901230 EXPLOSIVE BOMB 4901235 EXPLOSIVE MINE 4901240 EXPLOSIVE PROJECTILE 4901245 EXPLOSIVE TORPEDO 4901250 GRENADE, HAND, EXPLOSIVE 4901257 ROCKET HEAD 4901260 DETONATING PRIMER (CAPS. BLASTING OR ELECTRIC BLASTING. EXPLOSIVE) 4901310 BOOSTER (EXPLOSIVE) (COMMERCIAL) 4901330 DETONATORS (CAPS. BLASTING OR ELECTRIC BLASTING. EXPLOSIVE) 4901340 JET THRUST UNIT (JATO) 4901350 ROCKET MOTOR 4901360 IGNITER. JET THRUST (JATO) ^ 33 33 34 34 34 35 35 35 449 449 449 449 449 36 36 35 166 167 73 76 486 239 239 240 240 268 450 167 73 167 303 450 286 4901362 IGNITER, ROCKET MOTOR 4901365 DETONATING PRIMER (CAPS. BLASTING OR ELECTRIC BLASTING. EXPLOSIVE) 4901420 INITIATING EXPLOSIVE (FULMINATE OF MERCURY. WET) 4901430 INITIATING EXPLOSIVE (DIAZODINITROPHENOL) 4901435 INITIATING EXPLOSIVE (GUANYL NITROSAMINO GUANYLI- DENE HYDRAZINE) 4901440 INITIATING EXPLOSIVE (LEAD AZIDE. DEXTRINATED TYPE ONLY) 4901445 INITIATING EXPLOSIVE (LEAD MONONITRORESORCINATE) 4901450 INITIATING EXPLOSIVE (LEAD STYPHNATE)(LEAD TRINITRORESORCINATE) 4901455 INITIATING EXPLOSIVES (NITRO MANNITE) 4901460 INITIATING EXPLOSIVE (NfTROSOGUANIDINE) 4901465 INITIATING EXPLOSIVE (PENTAERYTHRITE TETRANITRATE) 4901470 INITIATING EXPLOSIVE (TETRAZENE) (GUANYL NITRO- SOAMINO GUANYL TETRAZENE 4901502 HIGH EXPLOSIVE 4901504 HIGH EXPLOSIVE. LIQUID 4901510 HIGH EXPLOSIVE (PICRIC ACID, DRY) 4901520 HIGH EXPLOSIVE (NITROCELLULOSE, DRY) 4901530 HIGH EXPLOSIVE (NITROSTARCH, DRY) 4901540 HIGH EXPLOSIVE (TRINITROTOLUOL, DRY) 4901550 AMMONIUM PERCHLORATE 4901602 PROPELLANT EXPLOSIVE 4901610 PROPELLANT EXPLOSIVE (GUN POWDER) 4901705 LOW EXPLOSIVE 4901710 BLACK POWDER 4902110 AMMUNITION FOR CANNON WITH EMPTY PROJECTILE 4902120 AMMUNITION FOR CANNON WITH INERT LOADED PROJECTILE 4902127 AMMUNITION FOR CANNON WITH TEAR GAS PROJECTILE 4902130 AMMUNITION FOR CANNON WITH SOLID PROJECTILE 4902140 AMMUNITION FOR CANNON WITHOUT PROJECTILE 4902150 ROCKET AMMUNITION WITH EMPTY PROJECTILE 4902160 ROCKET AMMUNITION WITH INERT LOADED PROJECTILE 4902170 ROCKET AMMUNITION WITH SOLID PROJECTILE 4902310 PROPELLANT EXPLOSIVE. LIQUID 4902410 PROPELLANT EXPLOSIVE. SOLID (GUN POWDER) 286 167 287 287 287 287 287 288 289 288 288 288 274 275 275 275 275 275 30 427 427 318 72 33 34 35 34 35 448 449 450 428 428 0o0l 7<as 567 4902420 PROPELLANT EXPLOSIVE SOLID 4902430 PROPELLANT EXPLOSIVE IN WATER (SMOKELESS POWDER) 4902440 PROPELLANT EXPLOSIVE IN WATER, UNSTABLE. CON DEMNED OR DETERIORATED 4902510 JET THRUST UNIT (JATO) 4902520 ROCKET ENGINE, LIQUID 4902530 ROCKET MOTOR 4902540 IGNITER, JET THRUST (JATO) 4902550 IGNITER, ROCKET MOTOR 4902560 STARTER CARTRIDGE 4902570 EXPLOSIVE POWER DEVICE, CLASS B 4902610 TORPEDO, RAILWAY 4902615 SHELL FIREWORKS 4902820 SPECIAL FIREWORKS 4902910 AMMONIUM NITRATE-FUEL OIL MIXTURE (CONTAINING ONLY PRILLED AMMONIUM NITRATE AND FUEL OIL) 4902915 BLASTING AGENT. N.O.S. 4903110 BLACK POWDER IGNITER WITH EMPTY CARTRIDGE BAG 4903120 CANNON PRIMERS 4903140 CARTRIDGE CASES. EMPTY. PRIMED 49031S0 CARTRIDGE. PRACTICE AMMUNITION 4903160 PERCUSSION CAP 4903170 SMALL ARMS AMMUNITION 4903180 SMALL-ARMS AMMUNITION, IRRITATING (TEAR GAS) CARTRIDGE 4903190 SMALL ARMS PRIMER 4903205 COMBINATION FUZE 4903210 COMBINATION PRIMER 4903215 DETONATING FUZE. CLASS C EXPLOSIVE 4903245 GRENADE. EMPTY, PRIMED 4903250 PERCUSSION FUZE 4903270 TIME FUZE 4903275 TRACER 4903280 TRACER FUZE 4903305 ACTUATING CARTRIDGE, EXPLOSIVE (FIRE EXTINGUISHER OR VALVE) 4903310 EXPLOSIVE CABLE CUTTER 4903315 EXPLOSIVE RELEASE DEVICE 4903320 FLEXIBLE LINEAR SHAPED CHARGE, METAL CLAD 4903323 FUSE. SAFETY 4903325 OIL WELL CARTRIDGE 4903345 CORDEAU DETONANT FUSE 4903355 MILD DETONATING FUSE. METAL CLAD 4903360 DETONATORS (CAPS. BLASTING OR ELECTRIC BLASTING, EXPLOSIVE) 4903405 SMOKE CANDLE 4903410 SMOKE GRENADE 4903415 SMOKE POT 4903420 EXPLOSIVE AUTO ALARM 4903425 EXPLOSIVE RIVET 4903430 STARTER CARTRIDGE 4903435 DELAY ELECTRIC IGNITER 4903440 ELECTRIC SQUIB 4903445 FUSE IGNITER 4903450 FUSE LIGHTER 4903455 IGNITER CORD 4903460 IGNITER FUSE-METAL CLAD 4903465 IGNITER 4903470 INSTANTANEOUS FUSE 4903475 SAFETY SQUIB 4903480 EXPLOSIVE POWER DEVICE. CLASS C 4903510 CIGARETTE LOADS 4903520 COMMON FIREWORKS 4903525 FIRECRACKERS OR TORPEDOES (COMMON FIREWORKS) 4903536 SPARKLERS. NEC (COMMON FIREWORKS) 4903538 PINWHEELS (FIREWORKS OR PYROTECHNICS, NEC) 4903539 SHELL FIREWORKS 4903540 TOY PROPELLANT DEVICE 4903550 TOY SMOKE DEVICE 4903560 TOYCAPS 4903570 TRICK MATCHES 4903580 TRICK NOISE MAKERS. EXPLOSIVE 4903610 HAND SIGNAL DEVICE 4903620 SIGNAL FLARE 4903630 SMOKE SIGNAL 4903640 VERY SIGNAL CARTRIDGE 4904030 FLUORINE 4904110 BORON TRIFLUORIDE 4904120 CHLORINE 428 427 428 302 450 450 266 286 461 239 503 456 479 29 72 72 101 109 109 395 459 459 459 138 138 166 265 396 500 506 505 9 239 240 252 260 379 150 350 167 459 460 460 239 240 480 165 217 260 260 286 286 285 292 455 239 130 138 249 478 413 456 504 504 505 510 510 266 457 461 524 253 74 119 4904210 ANHYDROUS AMMONIA 4904220 AMMONIA SOLUTION (CONTAINING MORE THAN 44% AMMONIA) 4904221 AMMONIACAL LIQUOR (COMPRESSED GAS. N.O.S.) 4904240 CRUDE NITROGEN FERTILIZER SOLUTION (MORE THAN 25.3 PSIG) 4904250 FERTILIZER AMMONIATING SOLUTION (CONTAINING FREE AMMONIA) 4904260 HYDROGEN BROMIDE 4904270 HYDROGEN CHLORIDE 4904275 NITROGEN FERTILIZER SOLUTION 4904280 SILICON TETRAFLUORIDE 4904290 SULFUR DIOXIDE 4904330 NITROSYLCHLORIDE 4904340 NITROUS OXIDE 4904350 OXYGEN 4904360 OXYGEN. PRESSURIZED LIQUID 4904370 OXYGEN (GAS ADMINISTERING APPARATUS. HOSPITAL OR SURGICAL, WITH CYLINDER OF OXYGEN) 4904360 OXYGEN (LIFE SAVING APPARATUS, OXYGEN) 4904410 ARGON OXYGEN GAS MIXTURE (COMPRESSED GAS, N.O.S) 4904420 CARBON DIOXIDE OXYGEN MIXTURE 4904430 HELIUM - OXYGEN MIXTURE 4904440 OXYGEN - NITROGEN GAS MIXTURE (COMPRESSED GAS. N.O.S.) 4904501 AIR. COMPRESSED 4904502 ARGON 4904503 ARGON PRESSURIZED LIQUID 4904504 ARGON-CARBON DIOXIDE GAS MIXTURE (COMPRESSED GAS, N.O.S.) 4904505 ARGON-HYDROGEN GAS MIXTURE (COMPRESSED GAS, N.O.S.) 4904506 ARGON-METHANE GAS MIXTURE (COMPRESSED GAS, N.O.S.) 4904507 ARGON-NITROGEN GAS MIXTURE (COMPRESSED GAS, N.O.S.) 4904509 CARBON DIOXIDE, LIQUEFIED 4904510 CARSON DIOXIDE-AIR MIXTURE (COMPRESSED GAS. N.O.S.) 4904511 CARBON DIOXIDE-ETHYLENE OXIDE GAS MIXTURE (COM- PRESSED GAS. N.O.S.) 4904512 CARBON DIOXIDE-NITROGEN GAS MIXTURE (COMPRESSED GAS. N.O.S.) 4904513 CARBON DIOXIDE-NITROUS OXIDE MIXTURE 4904514 CARBON DIOXIDE-PROPYLENE OXIDE GAS MIXTURE (COMPRESSED GAS. N.O.S.) 4904515 COMPRESSED GAS. N.O.S. 4904516 DICHLORODIFLUOROMETHANE 4904519 DICHLORODIFLUOROMETHANE-OICHLOROTETRAFLUOROETHANE MIXTURE 4904522 DICHLORODIFLUOROMETHANE-MONOCHLORODIFLUOROMETHANE MIXTURE 4904525 DICHLORODIFLUOROMETHANE-TRICHLOROMONOFLUOROMETHANE-MONOCHLORODIFLUORO- METHANE MIXTURE 4904528 DICHLORODIFLUOROMETHANE-TRICHLOROTRIFLUOROE- THANE MIXTURE 4904531 DICHLORODIFLUOROMETHANE-MONOCHLOROTRIFLUOROMETHANE MIXTURE 4904534 DICHLORODIFLUOROMETHANE AND DIFLUOROETHANE MIXTURE (CONSTANT BOILING MIXTURE) 4904536 DISPERSANT GASES. NEC (COMPRESSED GAS. N.O.S.) 4904537 ETHYLENE OXIDE - DICHLORODIFLUOROMETHANE GAS MIXTURE (COMPRESSED GAS. N.O.S.) 4904538 FLUOROETHANE GASES. NONFLAMMABLE (COMPRESSED GAS. N.O.S.) 4904640 HELIUM 4904542 HELIUM - ARGON GAS MIXTURE (COMPRESSED GAS. N.O.S.) 4904543 HELIUM-BUTANE GAS MIXTURE (COMPRESSED GAS. N.O.S.) 4904544 HELIUM-ISOBUTANE GAS MIXTURE (COMPRESSED GAS, N.O.S.) 4904545 HELIUM-NITROGEN MIXTURE (COMPRESSED GAS, N.O.S.) 4904546 HEXAFLUOROPROPYLENE 4904547 HELIUM-CARBON DIOXIDE-NITROGEN MIXTURE (COM- PRESSED GAS. N.O.S.) 4904548 HEXAFLUOROPROPYLENE OXIDE 4904549 MONOBROMOTRIFLUOROMETHANE 4904552 MONOCHLORODIFLUOROMETHANE 4904555 MONOCHLOROPENTAFLUOROETHANE 4904558 MONOCHLOROTETRAFLUOROETHANE 39 23 24 155 247 282 282 372 457 486 375 376 388 386 388 388 46 107 267 366 11 46 46 47 47 47 47 106 107 107 108 108 108 146 184 185 185 185 185 185 184 210 237 253 267 267 267 268 268 271 268 272 352 352 352 353 568 Mcd 001 ?49e, 4904560 MONOCHLOROTRJFLUOROMETHANE 4904563 NEON 4904564 NITROGEN TRIFLUORIDE 4904565 NITROGEN 4904566 NITROGEN. PRESSURIZED LIQUID 4904567 NITROGEN-HYDROGEN GAS MIXTURE (COMPRESSED GAS, N.O.S.) 4904570 REFRIGERANTS, NEC, LIQUID OR GAS {COMPRESSED GAS, N.O.S,) 4904575 SULFUR HEXAFLUORIDE 4904578 SULFURYL FLUORIDE 4904580 GAS MIXTURE. NEC. COMPRESSED, OTHER THAN POISON (COMPRESSED GAS, N.O.S.) 4904595 XENON 4904820 FIRE EXTINGUISHER 4904825 ACCUMULATOR, PRESSURIZED 4904830 INSECTICIDE. LIQUEFIED GAS 4904840 LIQUEFIED NONFLAMMABLE GASES (CHARGED WITH NI TROGEN. CARBON DIOXIDE, OR AIR) 4904845 MINE RESCUE EQUIPMENT CONTAINING CARBON DIOXIDE 4904865 REFRIGERATING MACHINE (ICE CREAM POWER FREEZERS AND MECHANICAL REFRIGERATORS) 4904866 REFRIGERATING MACHINE (COOLING ROOMS, COOLING BOXES, OR REFRIGERATORS OTHER THAN HOUSEHOLD TYPE) 4904867 REFRIGERATING MACHINE (REFRIGERATORS. NEC) 4904870 WATER PUMP SYSTEM CHARGED WITH COMPRESSED AIR OR NITROGEN 4904879 TUNDRA COOLING UNITS, CONDENSERS. EQUALIZERS OR EXCHANGERS, OIL FIELD. GAS OR LIQUID. IRON OR STEEL, PIPE TYPE. CONTAINING NOT MORE THAN 0.0125 POUNDS OF ANHYDROUS AMMONIA PER FOOT OF PIPE (LENGTH) (ANHYDROUS AMMONIA) 4905410 HYDROGEN SULFIDE 4905415 HYDROGEN SELENIDE 4905420 DIBORANE 4905425 DIBORANE MIXTURES 4905510 OIMETHYLAMINE. ANHYDROUS 4905520 METHYL MERCAPTAN 4905530 MONOMETHYLAMINE, ANHYDROUS 4905540 TRIMETHYLAMINE. ANHYDROUS 4905701 ACETYLENE 4905702 BUTANE (BUTANE. IMPURE. FOR FURTHER REFINING) 4905703 BUTADIENE. INHIBITED (BUTADIENE. IMPURE. FOR FUR THER REFINING) 4905704 BUTADIENE, INHIBITED (BUTADIENE FROM PETROLEUM) 4905705 BUTADIENE. INHIBITED (BUTADIENE FROM ALCOHOL) 4905706 BUTANE 4905707 BUTENE GAS. LIQUEFIED (LIQUEFIED PETROLEUM GAS) 4905708 HYDROCARBON GAS. NONLIOUEFIED (COAL GAS) 4905709 CARBON MONOXIDE 4905710 COMPRESSED GAS, N.O.S. 4905711 BUTYLENE. IMPURE. FOR FURTHER REFINING (LIQUEFIED PETROLEUM GAS) 4905713 CYCLOPROPANE 4905716 DIFLUOROETHANE 4905719 DIFLUOROMONOCHLOROETHANE 4905725 DIMETHYL ETHER 4905726 CIGARETTE LIGHTER 4905727 DISPERSANT GASES. NEC. FLAMMABLE (COMPRESSED GAS, N.O.S.) 4905728 ENGINE STARTING FLUID 4905731 ETHANE 4905734 ETHYLENE 4905745 HYDROGEN. LIQUEFIED 4905746 HYDROGEN 4905747 tSOBUTANE 4905748 ISOBUTYLENE 4905749 HYDROCARBON GAS. LIQUEFIED 4905750 ISOBUTANE (ISOBUTANE FOR FURTHER REFINERY PROCESSING) 490S752 LfQUEREO PETROLEUM GAS 4905755 METHANE 4905758 METHYLACETYLENE-PROPADIENE, STABILIZED 4905781 METHYL CHLORIDE 4905784 METHYL CHLORIDE-METHYLENE CHLORIDE MIXTURE 4905775 REFRIGERANTS, NEC. LIQUID, FLAMMABLE (COMPRESSED GAS, N.O.S.) 4905779 HYDROCARBON GAS. NONLIOUEFIED 4905780 LIQUEFIED PETROLEUM GAS (PINTSCH GAS) 353 362 372 371 373 373 445 486 488 262 535 249 1 291 313 351 446 446 447 530 514 283 283 178 179 201 341 354 512 6 79 79 78 78 79 80 277 108 146 94 162 194 194 198 130 210 223 224 234 284 281 294 296 277 295 313 333 345 337 337 445 277 314 nan 000017437 4905781 PROPANE 4905782 PROPYLENE 4905783 TETRAFLUOROETHYLENE. INHIBITED 4905785 TRIFLUOROCHLOROETHYLENE, INHIBITED 4905792 VINYL CHLORIDE 4905793 VINYL FLUORIDE, INHIBITED 4905795 VINYL METHYL ETHER 4905805 ARGON-HYDROGEN GAS MIXTURE (COMPRESSED GAS. N.O.S.) 4905610 ARGON-METHANE GAS MIXTURE (COMPRESSED GAS. N.O.S.) 4905815 CARBON DIOXIDE-PROPYLENE OXIDE MIXTURE (COM- PRESSED GAS. N.O.S.) 4905820 CARBON DIOXIDE-ETHYLENE OXIDE MIXTURE (COMPRESSED GAS. N.O.S.) 4905830 ETHYLENE OXIDE-DICHLORODIFLUOROMETHANE MIXJURE (COMPRESSED GAS. N.O.S. 4905840 HELIUM-BUTANE GAS. MIXTURE (COMPRESSED GAS. N.O.S.) 4905842 HELIUM-ISOBl/TANE GAS MIXTURE (COMPRESSED GAS. N.O.S.) 4905860 NITROGEN-HYDROGEN GAS MIXTURE (COMPRESSED GAS. N.O.S.) 4905865 REFRIGERATING MACHINE (ICE CREAM POWER FREEZERS AND MECHANICAL REFRIGERATORS) 4905666 REFRIGERATING MACHINE (COOLING ROOMS, COOLING BOXES OR REFRIGERATORS, OTHER THAN HOUSEHOLD TYPE) 4905867 REFRIGERATING MACHINE (REFRIGERATORS. NEC) 4906010 TOLUENE (TOLUOL), MIXED WITH ALUMINUM ALKYLS, NOT TO EXCEED 20 PERCENT (ALUMINUM ALKYL) 4906011 ALUMINUM ALKYL 4906030 METAL ALKYL. SOLUTION, N.O.S. 4906050 NICKEL CARBONYL 4906060 PENTABORANE 4906070 PYROFORIC LIQUID. N.O.S. 4906210 DIMETHYL HYDRAZINE, UNSYMMETRICAL 4906220 ETHYLENE (MINE. INHIBITED 4906225 HYDRAZINE. ANHYDROUS 4906230 METHYL HYDRAZINE 4906410 ACROLEIN. INHIBITED 4906420 ACRYLONITRILE 4906610 ETHYLENE OXIDE 4906620 PROPYLENE OXIDE 4907010 ETHYL NITRATE 4907020 ETHYL NITRITE 4907030 NITROMETHANE 4907035 ISOPROPYL NITRATE 4907040 PROPYLENE (MINE, INHIBITED 4907050 NITROCELLULOSE. COLLOIDED, GRANULAR OR FLAKE, WET WITH NOT LESS THAN 20% ALCOHOL OR SOLVENT, OR BLOCK, WET WITH NOT LESS THAN 25% ALCOHOL 4907060 NITROCELLULOSE, WET WITH NOT LESS THAN 30% AL- COBOL OR SOLVENT 4907070 NITROCELLULOSE FLAKES, WET WITH NOT LESS THAN 20% ALCOHOL OR SOLVENT 4907080 NITROSTARCH, WET WITH NOT LESS THAN 30% ALCOHOL OR SOLVENT 4907210 ACETALDEHYDE 4907215 ETHYL ACRYLATE. INHIBITED 4907223 CHLOROPRENE. INHIBITED 4907230 ISOPRENE 4907240 METHYL ISOPROPENYL KETONE. INHIBITED 4907245 METHYLACRYLATE, INHIBITED 4907250 METHYL METHACRYLATE MONOMER, INHIBITED 4907255 METHYLMETHACRYLATE MONOMER. UNINHIBITED 4907260 METHYL VINYL KETONE, INHIBITED 4907263 ISOBUTYLACRYLATE (FLAMMABLE LIQUID.N.O.S.) 4907265 STYRENE MONOMER, INHIBITED 4907267 VINYL ISOBUTYL ETHER 4907270 VINYLACETATE 4907275 VINYL ETHYL ETHER. INHIBITED 4907260 VINYLIDENE CHLORIDE, INHIBITED 4907405 ACETONITRILE 4907410 ALLYL BROMIDE 4907412 ALLYL CHLORIDE 4907415 N-BUTYL ISOCYANATE 4907420 EPICHLOROHYDRIN 4907422 FLAMMABLE LIQUID. POISONOUS. N.O.S. 4907425 ALLYL ALCOHOL 4907429 METHYL CHLOROFORMATE 4907430 METHYLCHLOROMETHYL ETHER, ANHYDROUS 426 432 494 511 525 526 526 47 47 106 105 235 266 266 371 442 446 447 502 19 331 363 394 435 198 236 276 339 7 8 237 433 231 231 374 300 433 369 370 369 375 1 226 124 299 340 345 341 347 344 295 483 526 525 525 527 3 18 18 83 223 251 17 338 345 569 4907440 PROPARGYL ALCOHOL 4907601 ACETYL CHLORIDE 4907605 DICHLOROBUTENE 4907607 ALLYL CHLOROFORMATE (OR) ALLYL CHLOROCARBONATE 4907609 DIETHYL DICHLOROSILANE 4907610 DIMETHYLDICHLOROSILANE 4907615 ETHYL DICHLOROSILANE 4907617 ETHYL CHLOROFORMATE 4907620 ETHYLTRICHLOROSILANE 4907625 METHYLDICHLOROSILANE 4907630 METHYLTRICHLOROSILANE 4907636 MIXED CHLOROSILANES (FLAMMABLE LIQUID, CORROSIVE, N.O.S.) 4907640 DICHLOROPROPENE AND PROPYLENE DlCHLORIDE MIXTURE 4907675 TRICHLOROSILANE 4907680 TRIMETHYLCHLOROS1LANE 4907685 VINYL TRICHLOROSILANE 4907815 DIETHYLAMINE 4907820 DIMETHYLAMINE. AQUEOUS SOLUTION 4907825 DIMETHYLETHYLAMINE (FLAMMABLE LIQUID, N.O.S.) 4907827 GASOHOL 4907829 FLAMMABLE LIQUID, CORROSIVE. N.O.S. 4907835 MONOETHYLAMINE 4907840 MONOMETHYLAMINE, AOUEOUS SOLUTION 4907846 MORPHOLINE 4907847 MORPHOLINE. AEQUOUS MIXTURE 4907860 PROPYLENE DIAMINE 4907877 TRIETHYLAMINE 4907660 TRIMETHYLAMINE, AQUEOUS SOLUTION 4908103 ACETAL 4908105 ACETONE 4908106 ACETONE OIL 4908108 AMYLENE 4908110 BENZENE 4908112 BENZINE 4908115 BUTYL CHLORIDE 4908119 BUTYRALDEHYDE 4908120 BUTYLAMINE 490812S CARBON BISULFIDE (OR) CARBON DISULFIDE 4908128 2-CHLOROPROPENE 4908132 CYCLOHEXANE 4908135 CYCLOPENTANE 4908137 CYCLOPENTANE, METHYL 4908151 DIMETHYL SULFIDE 4908156 ETHER (DIETHYL ETHER. OTHER THAN ANESTHESIA GRADE) 4908157 ETHER (DIETHYL ETHER, ANESTHESIA GRADE) 4908162 ETHYLCHLORIDE 4908165 DIVINYL ETHER 4908167 ETHYL FORMATE 4908169 ETHYL MERCAPTAN 4908171 ETHYL METHYL ETHER 4908173 METHYL PENTADIENE 4908176 GASOLINE (GASOLINE NATURAL (CASING HEAD)) 4900177 GASOLINE (GASOLINE. BLENDED) 4908178 GASOLINE 4908183 HEXANE 4908184 HEXADIENE 4908185 ISOBUTYRALDEHYDE (FLAMMABLE LIQUID, N.O.S.) 4908186 ISOBUTYLAMINE 4908188 ISOOCTANE 4908189 ISOOCTENE 4908191 METHYL PENTANE 4908192 ISOPENTANE 4908194 ISOPROPYLAMINE 4908195 DIISOPROPYL ETHER 4908205 ISOPROPYL MERCAPTAN 4908210 METHYLFURAN 4908215 LITHIUM ALUMINUM HYDRIDE. ETHEREAL 4908220 METHYL ACETATE 4908222 METHYLAL 4908223 METHALLYL CHLORIDE (FLAMMABLE LIQUID. N.O.S.) 4908225 METHYL FORMATE 4908230 METHYL MAGNESIUM BROMIDE IN ETHYL ETHER 4908240 DIHYDROPYRAN 4908250 NEOHEXANE 4908255 PENTANE 4908265 PETROLEUM ETHER 4908268 PROPYL CHLORIDE 4908269 PROPYL AMINE (MONO-N-PROPYLAMINE) 427 5 184 16 192 203 229 228 238 346 347 351 188 510 513 528 193 202 203 263 250 353 355 355 355 432 511 513 1 3 3 39 62 63 81 95 94 106 124 159 162 162 199 224 224 234 214 229 230 230 343 263 264 263 273 269 296 296 298 298 343 298 302 196 301 346 315 334 345 332 339 340 195 362 394 398 431 430 570 4908270 PROPIONALDEHYDE 4908275 2.3-DIMETHYLBUTANE 4908290 TETRAHYDROFURAN 4909105 ALCOHOL,N.O.S. 4909106 ACTIVE SEC-AMYL ALCOHOL (ALCOHOL. N.O.S.) 4909107 N-SEC-AMYL ALCOHOL (ALCOHOL. N.O.S.) 4909108 PRIMARY N-AMYL ALCOHOL (ALCOHOL. N.O.S.) 4909110 ETHYL ALCOHOL, ANHYDROUS. DENATURED IN PART WITH GASOLINE. GASOLINE CONTENT NOT TO EXCEED 5 PER CENT (ALCOHOL. N.O.S.) 4909111 AMYL ACETATE 4909112 TERT-AMYL ALCOHOL (ALCOHOL. N.O.S.) 4909115 AMYL CHLORIDE 4909117 N-BUTYL ALCOHOL (BUTYL ALCOHOL) 4909119 AMYL MERCAPTAN 4909121 AMYL NITRITE 4909125 BUTYL ETHER 4909126 BUTYL FORMATE 4909127 BUTYL BROMIDE (NORMAL) 4909128 BUTYL ACETATE 4909129 2-BUTANOL (BUTYL ALCOHOL) 4909130 TERT-BUTYL ALCOHOL (BUTYL ALCOHOL) 4909131 ISOBUTYL ALCOHOL (BUTYL ALCOHOL) 4909132 ETHYL BUTYRATE 4909133 BUTYL MERCAPTAN 4909134 TERT-BUTYLAMINE (BUTYLAMINE) 4909136 CHLOROPENTANES (FLAMMABLE LIQUID, N.O.S.) 4909137 CROTONALDEHYOE 4909138 CROTONYLENE 4909139 CYCLOHEXYLAMINE 4909141 DENATURED ALCOHOL 4909142 DENATURED ALCOHOL SOLVENT. (ALCOHOL, N.O.S.) 4909143 DENATURING ALCOHOL, NEC (ALCOHOL, N.O.S.) 4909144 DIACETYL 4909145 DICHLOROETHYIENE 4909147 DICHLOROPENTANE 4909148 DIISOPROPYLAMINE 4909149 DIACETONE ALCOHOL 4909150 DIETHYL KETONE 4909153 CHLOROBENZOL (OR) CHLOROBENZENE 4909154 DIMETHYL CARBONATE 4909155 DIOXANE 4909156 1,4-DIMETHYLCYCLOHEXANE 4909157 DI-N-PROPYLAMINE (FLAMMABLE LIQUID. N.O.S.) 4909158 DIOXOLANE 4909159 ETHYL ALCOHOL (COLOGNE SPIRITS) 4909160 ETHYL ACETATE 4909161 ETHYL BORATE 4909162 ETHYL CROTONATE 4909163 ETHYL BENZENE 4909164 ETHYL BUTYL ETHER 4909165 ETHYL-N-CYCLOHEXYLAMINE (FLAMMABLE LIQUID, N.O.S.) 4909166 ETHYLENE OICHLORIDE 4909168 ETHYL BUTYRALDEHYDE 4909170 ETHYL PROPIONATE 4909173 ETHYL-N-BUTYLAMINE (FLAMMABLE LIQUID, N.O.S.) 4909175 FURAN 4909177 DUSOBUTYLAMINE (FLAMMABLE LIQUID. N.O.S.) 4909179 PICOLINE (FLAMMABLE LIQUID, N.O.S.) 4909181 LUTIDENE (FLAMMABLE LIOUID.N.O.S.) 4909163 ACRYLAMIDE SOLUTION (FLAMMABLE LIQUID, N.O.S.) 4909165 HEXALDEHYDE 4909190 HEPTANE 4909195 AMYLAMINE 4909205 ISOPBOPANOL 4909206 ISOPROPANOL AND METHANOL MIXTURE (ALCOHOL N.O.S.) 4909207 ISOBUTYL ACETATE 4909208 ISOBUTYRONITRILE (FLAMMABLE LIQUID, N.O.S.) 4909209 DIISOBUTYLENE (FLAMMABLE LIQUID. N.O.S.) 4909210 ISOPROPYL ACETATE 4909215 FUEL AVIATION, TURBINE ENGINE 4909216 METHYL PROPYL KETONE 4909220 MERCAPTAN MIXTURE, ALIPHATIC 4909223 MESITYL OXIDE 4909225 METHYL BUTENE 4909226 METHYL BUTYRATE 4909230 METHANOL (METHYL ALCOHOL. COLUMBIAN SPIRITS) 4909235 METHYL AMYL ACETATE 4909237 METHANOL. CONTAMINATED. VALUE ONLY FOR REFINING (ALCOHOL, N.O.S.) 429 202 495 14 9 37 426 227 36 37 37 61 37 38 62 82 81 80 79 81 295 228 84 94 123 154 154 162 165 165 166 177 186 186 197 176 192 121 197 207 203 175 207 226 226 227 229 227 228 233 235 228 232 232 259 195 411 318 8 272 269 39 299 300 295 297 196 300 257 344 323 331 336 337 333 335 333 MCD 000017498 4909238 METHYL ACETONE 4909240 METHYL PROPIONATE 4909241 BUTYRONITRILE (FLAMMABLE LIQUID. N.O.S.) 4909242 METHYL BUTYL KETONE (FLAMMABLE LIQUID. N O S.) 4909243 METHYL ETHYL KETONE (ETHYL METHYL KETONE) 4909245 METHYL ISOBLTTYL KETONE (FLAMMABLE LIQUID. N.O.S.) 4909250 OCTANE 4909255 OICHLOROPROPENE 4909260 PARALDEHYDE 4909265 ORGANIC PEROXIDE. LIQUID OR SOLUTION, N.O.S. 4909266 PINENE 4909267 1-PROPANOL (ALCOHOL, N.O.S.) 4909268 PROPYL ACETATE 4909269 PROPYLENE DICHLORIDE 4909271 PROPYL FORMATE 4909272 PROPYL MERCAPTAN 4909277 PYRIDINE 4909280 PYROLIDINE 4909290 SODIUM METHYLATE. ALCOHOL MIXTURE 4909303 AMMONIUM SULFIDE SOLUTION 4909305 TOLUENE 4909310 AMYL FORMATE 4909320 CHLORDANE. LIQUID 4909330 METHYLCYCLOHEXANE 4909350 XYLENE 4909351 XYLENE (PARAXYLENE) 4909381 TRIMETHYL PHOSPHITE (FLAMMABLE LIQUID, N.O.S.) 4909390 ZIRCONIUM, METALLIC. SOLUTIONS OR MIXTURES THEREOF, LIQUID 4910101 ALUMINUM LIQUID (OR PAINT) 4910102 ALCOHOL IN BOND, FREE OF INTERNAL REVENUE TAX (AL- COHIC BEVERAGE) 4910103 ALCOHOL OR SPIRITS. GRAPE. NEUTRAL IN BOND (ALCO- HOLIC BEVERAGE) 4910104 ALCOHOL OR SPIRITS. FRUIT,EXCEPT GRAPE. NEUTRAL JN BOND (ALCOHOLIC BEVERAGE) 4910105 ANTI-FREEZE COMPOUND. LIQUID 4910106 ANTI-FREEZE PREPARATION. LIQUID 4910107 BRANDY. ALCOHOLIC (ALCOHOLIC BEVERAGE) 4910109 BOX TOE GUM 4910110 CEMENT. LEATHER 4910111 ALCOHOLS. FATTY OR CYCLIC, ETHOXYLATED (ALCOHOL,N.O.S.) 4910112 CEMENT, CONTAINER LINOLEUM. TILE, OR WALLBOARD, LIQUID 4910114 CEMENT, LIQUID. N.O.S. 4910116 CEMENT, PYROXYLIN 4910118 CEMENT, ROOFING, LIQUID 4910120 CEMENT, RUBBER 4910125 LIGHTER FLUID 4910130 CARBON REMOVER. LIQUID 4910133 COAL TAR DISTILLATE 4910134 COAL TAR LIGHT OIL 4910135 COAL TAR LIGHT OIL (CRUDE LIGHT OIL OF COAL TAR) 4910136 COAL TAR NAPHTHA 4910137 COAL TAR NAPHTHA (COAL TAR NAPHTHA, CRUDE) 4910138 COAL TAR OIL 4910139 COAL TAR OIL (COAL TAR OIL, CRUDE, NEC) 4910142 COATING SOLUTION 4910143 SMOKE FLUE CLEANING COMPOUNDS (COMPOUNDS. CLEANING. LIQUID) 4910144 COLLODION 4910145 BOND BREAKING COMPOUND. CONSISTING OF NAPHTHA. PETROLEUM RESINS AND VEGETABLE OILS (FLAMMABLE LIQUID, N.O.S.) 4910146 DRY CLEANER. LIQUID. OR LIQUID CLEANSER (COMPOUND, CLEANING. LIQUID) 4910147 COMPOUND, CLEANING. LIQUID 4910150 COMPOUND, ENAMEL 4910152 PAINT OILS. NEC (FLAMMABLE LIQUID. N.O.S.) 4910153 COMPOUND. LACQUER. PAINT. OR VARNISH. REMOVING. REDUCING OR THINNING. 4910154 THINNER FOR RUST PREVENTIVE COATING 4910155 COMPOUND, POLISHING, LIQUID 4910157 COMPOUND, TREE OR WEED KILLING. LIQUID 4910162 COMPOUND. VULCANIZING. LIQUID 4910165 CRUDE OIL, PETROLEUM 4910176 ENAMEL (ENAMEL OTHER THAN WATCH DIAL) 4910177 ENAMEL WHITENING COMPOUNDS (FLAMMABLE LIQUID, N.O-S.) 335 344 95 337 338 340 378 187 391 380 413 426 430 432 431 431 435 436 470 32 502 37 118 346 535 536 512 544 20 12 13 12 42 42 75 75 112 14 111 112 112 1t2 113 312 109 131 132 133 133 134 134 135 136 460 138 73 216 139 140 390 140 497 141 141 142 155 219 220 4910178 ERADICATOR. PAINT OR GREASE, 4910181 EXTRACT, LIQUID, FLAVORING 4910185 FLAMMABLE LIQUID. N.O.S. 4910187 SOLVENT, N.O.S. 4910188 GAS DRIPS. HYDROCARBON LIQUID 4910191 DRUGS. N.O.S. 4910192 COSMETICS, N.O.S. 4910193 MEDICINES. N.O.S 4910195 HEATER FOR REFRIGERATOR CAR. LIQUID FUEL TYPE 4910197 INSECTICIDE. LIQUID. NOS (INSECTICIDES OR FUNGI- CIDES, AGRICULTURAL, NEC. LIQUID) 4910198 FUNGICIDES, AGRICULTURAL NEC. LIQUID (FLAMMABLE LIQUID, N.O.S.) 4910204 BENZOL FORERUNNINGS. CRUDE. NOT BENZOL (FLAM- MABLE LIQUID. N.O.S.) 4910205 INK (INK, PRINTING. NEC) 4910206 INK MATERIALS. NEC (FLAMMABLE LIQUID. N.O.S.) 4910208 DEFOAMING COMPOUND. NEC. LIQUID (FLAMMABLE LIQ- UID. N.O.S ) 4910210 INSECTICIDE. LIQUID. N.O.S. 4910217 LACQUER BASE OR LACQUER CHIPS. PLASTIC (WET WITH ALCOHOL OR SOLVENT) 4910220 ASPHALT, CUTBACK 4910222 LEATHER BLEACH 4910223 LEATHER DRESSING 4910225 LIQUORS, ALCOHOLIC. NEC (ALCOHOLIC BEVERAGE) 4910227 POLYETHYLLIGROIN (PETROLEUM ETHER) 4910230 MORTAR STAIN, LIQUID 4910235 MOTOR FUEL. ALCOHOL. CASTOR OIL. AND NITROME- THANE (MOTOR FUEL. N.O.S.) 4910236 MOTOR FUEL. N.O.S. 4910239 NAPHTHA 4910240 NAPHTHA DISTILLATE 4910241 NAPHTHA SOLVENT 4910243 PETROLEUM. PARTIALLY REFINED FOR FURTHER PROC- ESSING (PETROLEUM OIL. N O S.) 4910244 PETROLEUM OIL RESIDUUM (PETROLEUM OIL N O S.) 4910245 OIL. N.O.S . PETROLEUM OIL OR PETROLUEM OIL. N.O.S. 4910250 PAINT DRIER, LIQUID 4910251 PAINT. LACQUER, STAIN, VARNISH. BRONZE. GOLD, LIQUID OR LACQUER BASE LIQUID 4910252 PAINT (ASPHALTUM OR COAL TAR PAINT) 4910253 PAINT (ASPHALTUM OR COAL TAR VARNISH) 4910254 RUBBER TIRE LACQUERS. PAINT, OR SHELLAC (PAINT, LAC- QUER OR SHELLAC) 4910255 PAINT OIL COMPOUNDS (FLAMMABLE LIQUID. N.O.S ) 4910257 PETROLEUM DISTILLATE (PETROLEUM DISTILLATE OIL, NOT FOR ILLUMINATING PURPOSES) 4910258 PETROLEUM DISTILLATE 4910259 PETROLEUM NAPHTHA 4910260 ROAD ASPHALT OR TAR, LIQUID (PETROLEUM ROAD OIL) 4910261 TAR. LIQUID 4910262 PINE TAR (TAR, LIQUID) 4910263 TAR OR PITCH, COAL OR PETROLEUM (TAR. LIQUID) 4910265 PLASTIC SOLVENT. N.O.S. 4910270 POLISH. METAL. STOVE. FURNITURE OR WOOD. LIQUID 4910271 FLOOR POLISH OR WAX (POLISH, WOOD. LIQUID) 4910275 PYROXYLIN SOLUTION 4910276 PYROXYLIN SOLVENT. N.O.S. 4910280 RESIN SOLUTION (RESIN COMPOUND. LIQUID) 4910285 ROAD ASPHALT OR TAR. LIQUID 4910290 RUM, DENATURED 4910295 SHELLAC, LIQUID 4910297 SOLVENTS, PAINT, LACQUER, VARNISH OR RESIN (SOL- VENT. N.O.S.) 4910302 ASPHALT PAVEMENT SURFACE SEALER, ASPHALT, COAL TAR OR PETROLEUM BASE (FLAMMABLE LIQUID, N.O.S.) 4910304 WINES. NEC, OTHER THAN IN TANK CARS (ALCOHOLIC BEVERAGE) 4910306 WINES, NEC. IN TANK CARS (ALCOHOLIC BEVERAGE) 4910308 SPIRITS. ALCOHOLIC. WHISKIES. RUM OTHER THAN DENATURED (ALCOHOLIC BEVERAGE) 4910309 SPHTTS. GRAIN, NEUTBL, IN BOND (ALCOHOLIC BEVERAGE) 4910310 SPIRITS OF NITROGLYCERINE 4910311 SPIRITS OF NITROGLYCERINE, NOT EXCEEDING 1% NITRO- GLYCERINE BY WEIGHT 4910313 TURPENTINE 4910315 TURPENTINE SUBSTITUTE 4910316 SPIRITS OF TURPENTINE (FLAMMABLELIQUID, N.O.S.) 4910317 WOOD TURPENTINE (FLAMMABLE LIQUIO. N.O.S.) 223 240 251 475 262 216 152 322 267 291 258 65 289 289 164 291 304 55 311 311 314 419 356 357 357 359 360 360 401 399 379 389 390 390 389 454 389 397 397 398 448 490 412 490 413 417 252 437 437 447 448 455 457 478 54 533 533 480 480 479 479 515 515 480 535 HCl) 00Q 7 7<9q 571 4910318 TURPENTINE RESIDUE, LIQUID (FLAMMABLE LIQUID, N.O.S.) 4910320 PULP MILL LIQUID (FLAMMABLE LIQUID, N.O.S.) 4910321 WASTE LIQUOR, CONSISTING OF NOT LESS THAN 50 PER CENT BY WEIGHT OF WATER. RESULTING FROM SUL PHATE OR SODA PULPING PROCESS (FLAMMABLE LIQ UID, N.O.S.) 4910323 CARBON BLACK OIL (FLAMMABLE LIQUID, N.O.S.) 4910330 COAL TREATING COMPOUNDS, OTHER THAN PETROLEUM. NEC. LIQUID (FLAMMABLE LIQUID, N.O.S.) 4910341 WINE, CHAMPAGNE OR VERMOUTH, SPOILEO (ALCOHOLIC BEVERAGE) 4910342 WINE, SPARKLING, OTHER THAN CHAMPANGE (ALCOHOLIC BEVERAGE) 4910343 VERMOUTH, OTHER THAN IN TANK CARS (ALCOHOLIC BEVERAGE) 4910344 VERMOUTH IN TANK CARS (ALCOHOLIC BEVERAGES) 4910345 CHAMPAGNE (ALCOHOLIC BEVERAGE) 4910349 COMPOUNDS, PETROLEUM TREATING. CRUDE. NEC (FLAM MABLE LIQUID, N.O.S.) 4910360 PETROLEUM ABSORPTION OIL (PETROLEUM OIL, N.O.S.) 4910361 COAL SPRAYING OIL PETROLEUM (PETROLEUM OIL N.O.S.) 4910366 ROSIN RESIDUE (FLAMMABLE LIQUIDS. N.O.S.) 4910371 DETERGENT INTERMEDIATES. OTHER THAN CYCLIC OR PETROLEUM (FLAMMABLE LIQUID, N.O.S.) 4910375 TIRE PUNCTURE OR RIM SEALING, OR TIRE BALANCING COMPOUNDS (FLAMMABLE LIQUIDS. N.O.S ) 4910381 MUD TREATING COMPOUNDS. NEC. GAS OR OIL WELL DRILLING (FLAMMABLE LIQUID) 4910395 WOOO FURNITURE FINISHING OR REFINISHING KITS (FLAM MABLE LIQUIDS. N.O.S 4910401 ALCOHOL DISTILLATES, SYNTHETIC (ALCOHOL, N.O.S.) 4910402 ANTI-FREEZE ALCOHOLS IALCOHOL, N.O.S.) 4910403 DENATURED ALCOHOL. SOLIDIFIED (ALCOHOL. N.O.S.) 4910404 METHANOL, SOLIDIFIED (ALCOHOL. N O S.) 4910405 TALLOW ALCOHOL (ALCOHOL. N.O.S.) 4910406 PLASTICIZER ALCOHOL (ALCOHOLS. N.O.S.) 4910408 ASPHALT TILE, PLASTICIZER (FLAMMABLE LIQUID, N.O.S.) 4910410 PLASTICIZERS, PAINT, LACQUEROR VARNISH (FLAMMABLE LIQUIDS, N.O.S.) 4910412 RUBBING ALCOHOL COMPOUNDS (ALCOHOL N.O.S.) 4910414 COMPOUNDS. WALL OR WALL PAPER CLEANING (COM POUND, CLEANING. LIQUID) 4910416 BELT DRESSING.(FLAMMABLE LIQUID. N.O.S.) 4910418 ELECTRIC WIRE SATURATING OR FINISHING COMPOUND, PARAFFINE BASE (FLAMMABLE LIQUID. N.O.S.) 4910420 BAY RUM (FLAMMABLE UQUIO, N O S ) 4910422 PERFUMERY(FLAMMABLE LIQUID. N.O.S.) 4910424 AFTER SHAVE LOTIONS (FLAMMABLE LIQUID, N.O.S.) 4910425 CIGARETTE LIGHTER 4910426 POLISHING WHEEL CEMENT THINNER (FLAMMABLE LIQUIO. N.O.S.) 4910428 PYROLIGNEOUS ACID (FLAMMABLE LIQUID. N.O.S.) 4910430 EXTRACTS, CHESTNUT OR QUEBRACHO, LIQUID (FLAM MABLE LIQUIDS. N.O.S ) 4910432 CUTCH, CATECHU. OR JAPONICA EXTRACTS. LIQUID (FLAM MABLE LIQUID. N.O.S.) 4910434 EXTRACTS, FUSTIC OR IOGWOOO. LIQUID OR PASTE (FLAMMABLE LIQUID. N.O.S.) 4910436 GAMBIER EXTRACTS. LIQUID (FLAMMABLE LIQUID. N.O.S.) 4910438 EXTRACTS. HYPERNIC LIQUID OR PASTE (FLAMMABLE LIQ UID. N.O.S.) 4910440 EXTRACTS. TANNING. NEC LIQUID OR PASTE(FLAMMABLE LIQUID, N.O.S.) 4910442 ROSIN LIQUOR (FLAMMABLE LIQUID. N.O.S.) 4910444 ROSIN SOLUTION (FLAMMABLE LIQUID, N.O.S.) 4910446 ROSIN GLOSS OR ESTER GUM (FLAMMABLE LIQUIDS, N.O.S ) 4910446 EMBEDDING CEMENT, NEC (CEMENT, LIQUID, N.O.S ) 4910450 COMPOUNDS CAULKING OR GLAZING (FLAMMABLE LIQUID. N.O.S.) 4910454 GLUE CATALYST, NEC (FLAMMABLE LIQUID, N.O.S.) 4910456 FLOOR COVERING UNDER LAYMENT COMPOUNDS. NEC (FLAMMABLE LIQUID, N.O.S.) 4910458 CEMENT, CORK. INSULATION. LIQUID (CEMENT. LIQUID. N.O.S.) 4910460 POLISHING WHEEL CEMENT OR GLUE (CEMENT, LIQUID. N.O.S.) 4910462 CEMENT OR CONCRETE WATER PROOFING COMPOUNDS, LIQUID OR PASTE (FLAMMABLE LIQUID, N.O.S.) 4910466 DEGUMMING COMPOUNDS. FABRIC OR FIBER (FLAMMABLE LIQUID. N.O.S.) 515 434 528 107 136 532 532 524 524 113 145 396 131 452 166 501 356 534 11 41 165 333 489 414 54 414 454 145 61 218 1 396 11 130 418 436 241 157 241 261 242 242 451 452 451 219 142 265 252 111 417 111 165 4910468 ELECTRIC WIRE SATURATING OR FINISHING COMPOUND. ASPHALT OR PITCH BASE (FLAMMABLE LIQUID. N.O.S.) 4910470 COMPOUNDS. HECTOGRAPH (FLAMMABLE LIQUID. N.O.S.) 4910472 COMPOUNDS. LEATHER FINISHING. NEC (FLAMMABLE LIQ UID, N.O.S.) 4910474 GAS ODORANTS. NOT COMPRESSED GAS (FLAMMABLE LIQUID, N.O.S.) 4910476 FOOT WARMER OR HOT BOTTLE CHARGES. CHEMICAL (FLAMMABLE LIQUID. N.O.S.) 4910478 GASOLINE PRESERVATIVE, NEC, LIQUID (FLAMMABLE LIQ UID, N.O.S.) 4910480 WALLPAPER REMOVER. LIQUID (FLAMMABLE LIQUID. N.O.S.) 4910482 PNEUMATIC TIRE REPAIR KITS. AUTO (FLAMMABLE LIQUID. N.O.S.) 4910484 KITS. PNEUMATIC TIRE CLEANING, AUTO (FLAMMABLE LIQ UID, N.O.S.) 4910486 LACQUER THINNING COMPOUNDS, USED (COMPOUND, LACQUER. THINNING) 4910488 HYDROXY ALDEHYDE WASTES (FLAMMABLE LIQUID. N.O.S.) 4910490 AROMATIC CONCENTRATES, SUITABLE ONLY FOR FUR THER PROCESSING (FLAMMABLE LIQUID, N.O.S.) 4910492 SOLDERING FLUX. NEC LIQUID (FLAMMABLE LIQUID, N.O.S.) 4910501 ALCOHOL, CONTAMINATED, SUITABLE FOR ONLY BLEND ING OR REDISTILLING PURPOSES (ALCOHOL, N.O.S.) 4910502 INSECTICIDE ADHESIVES. LIQUID (ADHESIVES, N.O.S.) 4910504 ADHESIVE, N.O.S. 4910505 COPPER BASED PESTICIDE. LIQUID, N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AG RICULTURAL, NEC) 4910506 COPPER BASED PESTICIDE. LIQUID, N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC, LIQUID) 4910507 BENZOIC DERIVATIVE PESTICIDE, LIQUID, N.O.S (COUMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL, NEC) 4910508 BENZOIC DERIVATIVE PESTICIDE, UQUIO. N.O.S. (COUMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSEC TICIDES, NEC. LIQUID) 4910510 COAL BRIQUETTE BINDER (FLAMMABLE LIQUID, N.O.S.) 4910511 COAL TAR FIBRE SATURANT LIQUID (FLAMMABLE LIQUIO. N.O.S.) 4910512 COAL TAR NAPHTHA AND LIGHT OIL OF COAL TAR, CRUDE (FLAMMABLE LIQUIO. N O S.) 4910514 REFINERY CRACKING STOCK (FLAMMABLE LIQUID. N.O.S.) 4910516 COPPER NAPHTHANATE PETROLEUM SOLUTION, NOT MORE THAN 8% COPPER NAPHTHANATE (FLAMMABLE LIQUID, N.O.S.) 4910520 PETROLEUM PROPYLENE TRIMER (FLAMMABLE LIQUID, N.O.S.) 4910521 BIPYRIOILIUM PESTICIDE. LIQUID, N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICUL TURAL. NEC) 4910522 BIPYRIOILIUM PESTICIDE. LIQUID. N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIOES, NEC. LIQUID) 4910525 PETROLEUM OIL ADDITIVE, CONTAINING MORE THAN 50 PERCENT BY WEIGHT OF PETROLEUM (FLAMMABLE LIQ UID, N.O.S.) 4910527 CARBAMATE PESTICIDE. LIQUID. N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICUL TURAL, NEC) 4910528 CARBAMATE PESTICIDE. LIQUID. N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIOES. NEC, LIQUID) 4910531 DITHIOCARBAMATE PESTICIDE. LIQUID. N.O.S. (COM POUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL, NEC) 4910532 DITHIOCARBAMATE PESTICIDE. LIQUID. N.O.S. (COM POUNDS AND PREPARATIONS) (AGRICULTURAL INSEC TICIDES. NEC, LIQUID) 4910535 ADDITIVES. FUEL OIL, GASOLINE OR LUBRICATING OIL CONTAINING LESS THAN 50% BY WEIGHT PETROLEUM OIL (FLAMMABLE LIQUID. N.O.S.) 4910537 MERCURY BASED PESTICIDE, LIQUID, N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AG RICULTURAL. NEC) 4910538 MERCURY BASED PESTICIDE, LIQUID, N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES. NEC. LIQUID) 217 143 144 263 254 264 527 415 304 305 284 48 476 13 290 10 148 148 63 64 131 132 134 445 149 400 70 71 399 103 103 213 212 9 330 330 572 MCD 000017500 4910541 ORGANOCHLORINE PESTICIDE. LIQUID. N.O.S. (COM POUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AGRICULTURAL. NEC) 4910542 ORGANOCHLORINE PESTICIDE. LIQUID. N.O.S. (COM POUNDS AND PREPARATIONS) (AGRICULTURAL INSEC TICIDES, NEC, LIQUID) 4910544 ORGANOPHOSPHORUS PESTICIDE. LIQUID. N.O.S. (COM POUNDS AND PREPARATIONS (INSECTICIDES, OTHER THAN AGRICULTURAL. NEC) 4910545 ORGANOPHOSPHORUS PESTICIOE, LIOUID. N.O.S. (COM POUNDS AND PREPARATIONS (AGRICULTURAL INSEC TICIDES. NEC. LIQUID) 4910546 ORGANOTIN PESTICIDE, LIQUID. N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICUL TURAL. NEC) 4910547 ORGANOTIN PESTICIDE. LIQUID, N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES. NEC. LIQUID) 4910550 BATTERY BOX COMPOUNDS (FLAMMABLE LIQUID. N.O.S.) 4910552 RUBBER PRESERVATIVE. NEC (FLAMMABLE LIQUID. N.O.S.) 4910555 RUBBER ACCELERATORS OR SOFTENERS. OTHER THAN PETROLEUM. NEC (FLAMMABLE LIQUID. N.O.S.) 4910557 ARSENICAL PESTICIDE. LIQUID, N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICUL TURAL. NEC) 4910558 ARSENICAL PESTICIDE, LIQUID, N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES. NEC, LIOUID) 4910560 CHEMICAL PLANT WASTE. NEC (FLAMMABLE LIQUID. N.O.S.) 4910565 REFRIGERATING MACHINE (ICE CREAM POWER FREEZERS AND MECHANICAL REFRIGERATORS). 4910566 REFRIGERATING MACHINE (COOLING ROOMS, COOLING BOXES OR REFRIGERATORS OTHER THAN HOUSEHOLD TYPE). 4910567 REFRIGERATING MACHINE (REFRIGERATORS. NEC) 4910570 PHTHAUMIDE DERIVATIVE PESTICIDE. LIQUID. N.O.S. (COM POUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AGRICULTURAL, NEC) 4910571 PHTHAUMIDE DERIVATIVE PESTICIDE. LIQUID, N.O.S. (COM POUNDS AND PREPARATIONS) (AGRICULTURAL INSEC TICIDES. NEC. LIQUID) 4910572 PHENYLUREA PESTICIDE, LIQUID, N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AG RICULTURAL. NEC) 4910573 PHENYLUREA PESTICIDE. LIQUID. N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC. LIQUID) 4910574 PHENOXY PESTICIOE. LIQUID, N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICUL TURAL. NEC) 4910575 PHENOXY PESTICIDE. LIQUID. N.O.S. (COMPOUNDS ANO PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC. LIQUID) 4910577 SUBSTITUTED NITROPHENOL PESTICIDE. LIQUID, N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL IN SECTICIDES. NEC, LIQUID) 4910578 SUBSTITUTED NITROPHENOL PESTICIDE. LIQUID, N.O.S. (COMPOUNDS ANO PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL. NEC) 4910579 TRIAZINE PESTICIDE. LIQUID, N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES. NEC, LIOUID) 4910580 TRIAZINE PESTICIDE. LIQUID. N.O.S. (COMPOUNDS AND PERPARATIONS) (INSECTICIDES, OTHER THAN AGRICUL TURAL, NEC) 4910590 WOOD FILLER 4912215 BUTYL ACRYLATE (COMBUSTIBLE LIQUID. N.O.S.) 4912218 DIMETHYLAMINIOETHYL METHACRYLATE (COMBUSTIBLE LIQUID. N.O.S.) 4912220 ETHYLHEXYLACRYLATE (COMBUSTIBLE LIOUID, N.O.S.) 4912275 VINYLTOLUENE. INHIBITED (COMBUSTIBLE LIQUID, N.O.S.) 4913103 ALCOHOL. N.O.S. 4913105 ALDOL (COMBUSTIBLE LIOUID. N.O.S.) 4913106 ACTIVE PRIMARY AMYL ALCOHOL (ALCOHOL, N.O.S.) 4913107 AMYL NITRATE (COMBUSTIBLE LIQUID. N.O.S.) 4913108 BIPHENYL (DIPHENYL) (COMBUSTIBLE LIQUID. N.O.S.) 4913110 BETA-PROPIOLACTONE (COMBUSTIBLE LIQUID, N.O.S.) 4913111 BENZALDEHYDE 4913112 BROMOBENZENE 4913113 ETHYL BUTYL ACETATE 383 382 384 364 385 386 59 453 453 52 53 116 446 446 447 410 410 403 404 401 402 484 484 506 506 534 81 202 238 527 13 14 9 38 70 70 61 77 227 4913114 ETHYL CHLOROACETATE 4913115 ETHYLENE GLYCOL DIETHYL ETHER 4913116 ETHYLENE GLYCOL MONOETHYL ETHER 4913117 ETHYLENE GLYCOL MONOETHYL ETHER ACETATE 4913119 DIISOBUTYLCAR8INOL (COMBUSTIBLE LIQUID. N.O.S.) 4913120 MERCAPTAN MIXTURE, ALIPHATIC 4913121 DECYL ALCOHOL, OTHER THAN PERFUMERY GRADE <AL- COHOL, N.O.S.) 4913122 ISO HEPTYL ALCOHOL (ALCOHOL. N.O.S.) 4913124 FURFURYL ALCOHOL (ALCOHOL, N.O.S.) 4913125 CUMENE (COMBUSTIBLE LIQUID. N.O.S.) 4913126 HEXYL ALCOHOL, OTHER THAN PERFUMERY GRADE (AL- COHOL. N.O.S.) 4913127 ISOAMYL ALCOHOL (ALCOHOL. N.O.S.) 4913128 ISOOCTYL ALCOHOL, OTHER THAN PERFUMERY GRADE (ALCOHOL, N.O.S.) 4913129 ISOOCTYL ALCOHOL, PERFUMERY GRADE (ALCOHOL N.O.S.) 4913130 TRI-N-BUTYLAMINE (COMBUSTIBLE LIQUID. N.O.S.) 4913131 BUTYL LACTATE (COMBUSTIBLE LIQUID, N.O.S.) 4913132 METHYL AMYL KETONE 4913133 DENATURING ALCOHOL. NEC (ALCOHOL. N.O.S.) 4913134 8ENZONITRILE 4913135 DIETHYL BENZENE (COMBUSTIBLE LIQUID. N.O.S.) 4913136 CHLOROPENTANES (COMBUSTIBLE LIOUID, N.O.S.) 4913138 METHYL METHOXY PENTANONE (COMBUSTIBLE LIOUID, N.O.S.) 4913140 DIISOBUTYL KETONE 4913143 METHYL ISOBUTYL CARBINOL (COMBUSTIBLE LIQUID, N.O.S.) 4913144 FORMALDEHYDE, LIQUID (FORMALDEHYDE OR FORMALIN SOLUTION) 4913145 FORMALDEHYDE, PASTE (FORMALDEHYDE OR FORMALIN SOLUTION) 4913146 FURFURAL 4913147 ISOPROPYLTOLUENE (COMBUSTIBLE LIQUID. N.O.S.) 4913150 METHYL ACETOACETATE (COMBUSTIBLE LIQUID. N.O.S.) 4913151 NEO PENTANOIC ACID (COMBUSTIBLE LIQUID, N.O.S ) 4913153 CAMPHOR OIL 4913155 POLYETHYLBENZENE (COMBUSTIBLE LIQUID. N.O.S.) 4913158 OCTYL ALCOHOL. OTHER THAN PERFUMERY GRADE (AL- COHOL. N.O.S.) 4913159 OCTYL ALCOHOL. PERFUMERY GRADE (ALCOHOL. N.O.S.) 4913162 ETHYLENE GLYCOL MONOMETHYL ETHER 4913163 ETHYLENE GLYCOL MONOMETHYL ETHER ACETATE 4913164 ETHYL HEXALDEHYDE 4913165 ETHYL LACTATE 4913166 ETHYL SILICATE 4913167 DECAHYDRONAPHTHALENE 4913170 CHLORDANE. LIQUID 4913172 MONO-TERT-BUTYL-META-CRESOL (COMBUSTIBLE LIOUID, N.O.S.) 4913173 COLUDIENE (COMBUSTIBLE LIQUID, N.O.S.) 4913174 PICOLINE (COMBUSTIBLE LIOUID. N.O.S.) 4913175 TOLUIDINE (COMBUSTIBLE LIQUIO. N.O.S.) 4913177 TETRAHYOROFURFURYL ALCOHOL 4913179 CYCLOHEXANONE (COMBUSTIBLE LIQUID. N.O.S.) 4913180 TRIETHYL PHOSPHITE 4913182 GERANIOL-NEROL MIXTURE (COMBUSTIBLE LIQUID. N.O.S.) 4913183 METHLYLETHANOLAMINE (COMBUSTIBLE LIQUID. N.O.S.) 4913184 OIMETHYLAMINOETHANOL (COMBUSTIBLE LIOUID. N.O.S.) 4913185 DIETHYLHYDROXYLAMINE (COMBUSTIBLE LIQUID, N.O.S.) 4913186 DIETHYLAMINOETHANOL (COMBUSTIBLE LIQUID. N.O.S.) 4913187 ACRYLAMIDE SOLUTION (COMBUSTIBLE LIQUID. N.O.S.) 4913188 OUINALDINE (COMBUSTIBLE LIOUID. N.O.S.) 4913189 N-ETHYL-META-TOLUIDINE (COMBUSTIBLE LIOUID. N.O.S.) 4913190 SODIUM METHYLATE, ALCOHOL MIXTURE 4913194 GLYCOL ETHERS (COMBUSTIBLE LIQUID. N.O.S.) 4915102 ALCOHOL IN BOND. FREE OF INTERNAL REVENUE TAX (ALCOHIC BEVERAGE) 4915103 ALCOHOL OR SPIRITS. GRAPE. NEUTRAL IN BOND (ALCOHOLIC BEVERAGE) 4915104 ALCOHOL OR SPIRITS. FRUIT, EXCEPT GRAPE. NEUTRAL. IN BOND (ALCOHOLIC BEVERAGE) 4915105 ANTIFREEZE COMPOUND LIOUID 4915106 ANTIFREEZE PREPARATION. LIQUID 4915107 BRANDY. ALCOHOLIC (ALCOHOLIC BEVERAGE) 4915108 ALCOHOLS. FATTY OR CYCLIC, ETHOXYLATED (ALCOHOL.N.O.S.) 4915109 BOX TOE GUM 4915111 PETROLEUM RESIDUAL FUEL OIL OR DIESEL OIL (FUEL OIL) 4915112 FUEL OIL, NO. 1.2,4, OR 5 228 235 235 236 195 323 164 294 260 155 274 294 298 298 505 84 335 166 65 191 122 341 195 339 255 255 259 302 335 362 101 419 378 378 236 236 230 230 232 163 118 352 137 411 503 495 159 511 264 333 202 194 193 8 438 358 470 265 12 13 12 42 42 76 14 75 400 257 573 MCD 000017501 4915113 FUELOIL 4915114 CEMENT, LIQUID, N.O.S. 4915115 DISINFECTANT. LIQUID, N.O.S. 4915133 COAL TAR DISTILLATE 4915134 COAL TAR LIGHT OIL 4915135 COAL TAR LIGHT OIL (CRUDE LIGHT OIL OF COAL TAR) 4915136 COAL TAR NAPHTHA 4915137 COAL TAR NAPHTHA (COAL TAR NAPHTHA, CRUDE) 4915138 COAL TAR OIL 4915139 COAL TAR OIL (COAL TAR OIL, CRUDE, NEC) 4915143 SMOKE FLUE CLEANING COMPOUNDS (COMPOUNDS, CLEANING, LIQUID) 4915144 BONO BREAKING COMPOUND, CONSISTING OF NAPHTHA PETROLEUM RESINS AND VEGETABLE OIL (COMBUSTI BLE LIQUID, N-O.S.) 4915146 DRY CLEANER, LIQUID. OR LIQUID CLEANSER (COMPOUND, CLEANING. LIQUID) 4915147 COMPOUND, CLEANING, LIQUID 4915152 PAINT OIL COMPOUNDS (COMBUSTIBLE LIQUID, N.O.S.) 4915153 COMPOUND. LACQUER. PAINT. OR VARNISH, REMOVING, REDUCING OR THINNING 4915154 THINNER FOR RUST PREVENTIVE COATING 4915157 COMPOUND. TREE OR WEED KILLING. LIQUID 4915165 CRUDE OIL, PETROLEUM 4915167 FUEL, AVIATION. TURBINE. ENGINE 4915169 FUSEL OIL 4915170 PINE OIL 4915171 KEROSENE 4915176 ENAMEL (ENAMEL OTHER THAN WATCH DIAL) 4915177 ENAMEL WHITENING COMPOUNDS (COMBUSTIBLE LIQUID. N.O.S.) 4915182 PIPE LINE RUST PREVENTIVE COATING (RUST PREVENTIVE COATING) 4915184 COMPOUNDS. IRON OR STEEL RUST PREVENTING. OTHER THAN PETROLEUM, NEC (RUST PREVENTIVE COATING) 4915185 COMBUSTIBLE LIQUID, N O.S. 4915187 SOLVENT. N.O.S. 4915188 GAS DRIPS, HYDROCARBON 4915191 DRUGS, N.O.S. 4915192 COSMETICS. N.O.S, 4915193 MEDICINES. N.O.S. 4915197 INSECTICIDE, LIQUID, N.O.S. (INSECTICIDES OR FUNGI- CIDES. AGRICULTURAL, NEC, LIQUID) 491519B FUNGICIDES. AGRICULTURAL. NEC. LIQUID (COMBUSTIBLE LIQUID. N.O.S.) 491S205 INK, PRINTING. NEC (INK) 4915206 INK (INK MATERIALS. NEC) 4915208 OEFOAMING COMPOUND. NEC. LIQUID (COMBUSTIBLE LIQ- UID. N.O.S.) 4915210 INSECTICIDE. LIQUID, N.O.S. 4915222 LEATHER BLEACH 4915223 LEATHER DRESSING 4915225 LIQUORS. ALCOHOLIC. NEC (ALCOHOLIC BEVERAGE) 4915227 POLYETHYLClGROlN (PETROLEUM ETHER) 4915228 LUBRICATING SYSTEM SIGHT FEED FLUID (COMBUSTIBLE LIQUID. N.O.S.) 4915229 LUBRICATING OIL. NEC (COMBUSTIBLE LIQUID. N.O.S.) 4915230 MORTAR STAIN, LIQUID 4915235 MOTOR FUEL, ALCOHOL, CASTOR OIL. AND NITROME- THANE (MOTOR FUEL N.O.S.) 4915236 MOTOR FUEL, N.O.S. 4915239 NAPHTHA 4915240 NAPHTHA DISTILLATE 4915241 NAPHTHA SOLVENT 4915242 PETROLEUM LUBRICATING OIL (COMBUSTIBLE LiQUIO. N.O.S.) 4915243 PETROLEUM PARTIALLY REFINED FOR FURTHER PROCESSING (COMBUSTIBLE UQUID, N.O.S.) 4915244 PETROLEUM OIL RESIDUUM (PETROLEUM OIL N.O.S.) 4915245 OIL N.O.S., PETROLEUM OIL OR PETROLEUM OIL, N.O.S. 4915247 ROAD OIL (PETROLEUM ROAD OIL) 4915250 PAINT DRIER, LIQUID 4915251 PAINT, LACQUER, STAIN (OR) VARNISH. BRONZE OR GOLD. LIQUID OR LACQUER BASE LIQUID 4915252 ASPHALTUM OR COAL TAR PAINT (PAINT) 4915253 ASPHALTUM OR COAL TAR VARNISH (VARNISH) 4915254 RUBBER TIRE LACQUER, PAINT, OR SHELLAC (PAINT. LAC- QUER OR SHELLAC) 4915255 PAINT OIL COMPOUNDS (COMBUSTIBLE LIQUID, N.O.S.) 256 112 209 132 133 133 133 134 135 135 460 73 217 139 390 140 497 141 155 257 260 412 304 219 220 413 144 138 474 259 214 152 320 292 258 289 289 164 291 311 311 314 419 318 318 356 357 357 360 360 360 398 399 399 379 448 389 390 55 55 454 390 4915257 PETROLEUM DISTILLATE FUEL OIL. NOT FOR ILLUMINATING PURPOSES (PETROLEUM DISTILLATE) 4915258 PETROLUEM DISTILLATE 4916259 PETROLEUM NAPHTHA 4915260 ROAD ASPHALT OR TAR, LIQUID (PETROLEUM ROAD OIL) 4915261 TAR. UQUID 4915262 PINE TAR (TAR, UQUID) 4915263 TAR OR PITCH. COAL OR PETROLEUM (TAR. LIQUID) 4915265 PLASTIC SOLVENT. N.O.S. 4915270 POLISH. METAL, STOVE. FURNITURE OR WOOD, LIQUID 4915271 FLOOR POLISH OR WAX (POLISH. WOOD. UQUID) 4915275 PYROXYLIN SOLUTION 4915276 PYROXYLIN SOLVENT, N.O.S. 4915280 RESIN SOLUTION (RESIN COMPOUND, LIQUID) 4915290 WOOD FILLER 4915295 SHELLAC. LIQUID 4915297 SOLVENTS. PAINT, LACOUER, VARNISH OR RESIN (SOL- VENT. N.O.S.) 4915302 ASPHALT PAVEMENT SURFACE SEALER, ASPHALT. COAL TAR OR PETROLEUM BASE (COMBUSTIBLE LIQUID, N.O.S.) 4915304 WINES. NEC. OTHER THAN IN TANK CARS (ALCOHOLIC BEVERAGE) 4915306 WINES. NEC. IN TANK CARS (ALCOHOLIC BEVERAGE) 4915308 WINE, CHAMPANGE OR VERMOUTH, SPIOLED (ALCOHOLIC BEVERAGE) 4915309 WINE, SPARKLING. OTHER THAN CHAMPAGNE (ALCOHOLIC BEVERAGE) 4915310 VERMOUTH, OTHER THAN IN TANK CARS (ALCOHOLIC BEVERAGE) 4915311 VERMOUTH IN TANK CARS (ALCOHOLIC BEVERAGE) 4915312 CHAMPANGE (ALCOHOLIC BEVERAGE) 4915314 TURPENTINE 4915315 TURPENTINE SUBSTITUTE 4915316 SPIRITS OF TURPENTINE (COMBUSTIBLE LIQUID. N O S.) 4915317 WOOD TURPENTINE (COMBUSTIBLE LIQUID. N O S.) 4915318 TURPENTINE RESIDUE. LIQUID (COMBUSTIBLE LIQUID. N.O.S.) 4915320 ASPHALT. CUT BACK (ASPHALT PETROLEUM. LIQUID ANO TALL OIL PITCH, MIXED 4915321 WASTE LIQUOR. CONSISTING OF NOT LESS THAN 50 PER- CENT BY WEIGHT OF WATER, RESULTING FROM SUL PHATE OR SODA PULPING PROCESS (COMBUSTIBLE LIQ UID. N.O.S.) 4915323 CARBON BLACK OIL (COMBUSTIBLE LIQUID, N.O.S.) 4915330 COAL TREATING COMPOUNDS, OTHER THAN PETROLEUM, NEC. LIQUIO (COMBUSTIBLE LIQUID) 4915342 ROSIN LIQUOR. CONSISTING OF ROSIN AND NOT MORE THAN 40% ALCOHOL OR MINERAL SPIRIT (COMBUSTIBLE LIQUIDS. N.O.S.) 4915344 ROSIN SOLUTION (COMBUSTIBLE LIQUID. N.O.S.) 4915350 PULP MILL UQUID (COMBUSTIBLE LIQUID, N.O.S.) 4915360 PETROLEUM ABSORPTION OIL (PETROLEUM OIL N.O.S ) 4915361 COAL SPRAYING OIL. PETROLEUM (PETROLEUM OIL N.O.S.) 4915363 CREOSOTE. COAL TAR 4915366 ROSIN RESIDUE (COMBUSTIBLE LIQUID, N.O.S.) 4915371 DETERGENT INTERMEDIATES. OTHER THAN CYCLIC OR PETROLEUM (COMBUSTIBLE UQUID, N.O.S.) 4915375 TIRE PUNCTURE OH RIM SEALING. OR TIRE BALANCING COMPOUNDS (COMBUSTIBLE LIQUID. N.O.S.) 4915381 MUD TREATING COMPOUNDS. NEC, GAS OR OIL WELL DRILLING (COMBUSTIBLE LIQUIDS. N.O.S.) 4915365 POLISH OR WAX. FLOOR (WAX, LIQUID) 4915386 POLISH OR WAX, BOAT, FURNITURE OR VEHICLE (WAX, LIQUID) 4915387 WAX. UQUID 4915395 WOOD FURNITURE FINISHING OR REFINISHING KITS (COMBUSTIBLE UQUID. N.O.S.) 4915401 ALCOHOL DISTILLATES, SYNTHETIC (ALCOHOL. N.O.S,) 4915402 ANTI-FREEZE ALCOHOLS (ALCOHOL. N.O.S.) 4915405 TALLOW ALCOHOL (ALCOHOL. N.O.S.) 4915406 PLASTICIZER ALCOHOL (ALCOHOL N.O.S.) 4915408 ASPHALT TILE. PLASTICIZER (COMBUSTIBLE LIQUID,N.O.S.) 4915410 PLASTICIZERS, PAINT. LACQUER OR VARNISH (COMBUS- TIBLE LIQUID. N.O.S.) 4915412 RUBBING ALCOHOL COMPOUNDS (ALCOHOL, N.O.S.) 4915414 COMPOUNDS. WALL OR WALL PAPER CLEANING (COM- POUND. CLEANING. UQUID) 4915416 BELT DRESSING (COMBUSTIBLE LIQUID. N.O.S.) 4915418 ELECTRIC WIRE SATURATING OR FINISHING COMPOUND. PARAFFINE BASE (COMBUSTIBLE LIQUID. N.O.S.) 398 401 398 448 490 412 490 413 417 253 437 437 447 534 457 478 54 533 533 532 532 524 524 113 515 516 479 535 515 55 528 106 136 451 452 433 397 131 153 452 166 501 357 417 417 531 534 11 41 489 414 54 414 455 146 61 218 574 oooo a 7&nl('-i 4 4915420 BAY RUM (COMBUSTIBLE LIQUID, N.O.S.) 4915422 PERFUMERY (COMBUSTIBLE LIQUID. N.O.S.) 4915424 AFTER SHAVE LOTIONS (COMBUSTIBLE LIQUID, N.O.S.) 4915426 POLISHING WHEEL CEMENT THINNER (COMBUSTIBLE LIQ UID, N.O.S.) 4915428 PYROLIGNEOUS ACID (COMBUSTIBLE LIQUID, N.O.S.) 4915430 EXTRACTS, CHESTNUT OR QUEBRACHO. LIQUID (COMBUS TIBLE LIQUID, N.O.S.) 4915432 CUTCH. CATECHU, OR JAPONICA EXTRACTS, LIQUID (COM BUSTIBLE LIQUID. N.O.S.) 4915434 EXTRACTS. FUSTIC OR LOGWOOD, LIQUID OR PASTE (COM BUSTIBLE LIQUID, N.O.S.) 4915436 GAMBIER EXTRACTS, LIQUID (COMBUSTIBLE LIQUID. N.O.S.) 4915438 EXTRACTS, HYPERNIC LIQUID OR PASTE (COMBUSTIBLE LIQUID, N.O.S.) 4916440 EXTRACTS, TANNING, NEC LIQUID OR PASTE (COMBUSTI BLE LIQUID, N.O.S.) 4915446 ROSIN GLOSS OR ESTER GUM (COMBUSTIBLE LIQUIDS. N.O.S.) 4915448 EMBEDDING CEMENT. NEC (CEMENT, LIQUID. N.O.S.) 4915450 COMPOUNDS CAULKING OR GLAZING (COMBUSTIBLE LIQ UID, N.O.S.) 4915464 GLUE CATALYST. NEC (COMBUSTIBLE LIQUID. N.O.S.) 4915456 FLOOR COVERING UNDERLAYMENT COMPOUNDS. NEC (COMBUSTIBLE LIQUIDS, N.O.S 4915456 CEMENT, CORK, INSULATION, LIQUID (CEMENT. LIQUID. N.O.S.) 4915460 POLISHING WHEEL CEMENT OR GLUE (CEMENT. LIQUID. N.O.S.) 4915462 CEMENT OR CONCRETE WATER PROOFING COMPOUNDS. LIQUID OR PASTE (COMBUSTIBLE LIQUID. N.O.S.) 4915466 DEGUMMING COMPOUNDS. FABRIC OR FIBER (COMBUS TIBLE LIQUID. N.O.S.) 4915466 ELECTRIC WIRE SATURATING OR FINISHING COMPOUND. ASPHALT OR PITCH BASE (COMBUSTIBLE LIQUID, N.O.S.) 4915470 COMPOUNDS. HECTOGRAPH (COMBUSTIBLE LIQUID. N.O.S.) 4915472 COMPOUNDS. LEATHER FINISHING. NEC (COMBUSTIBLE LIQUID, N.O.S.) 4915474 GAS ODORANTS. NOT COMPRESSED GAS (COMBUSTIBLE LIQUID. N.O.S.) 4915476 FOOT WARMER OR HOT BOTTLE CHARGES, CHEMICAL (COMBUSTIBLE LIQUID. N.O.S.) 4916478 GASOLINE PRESERVATIVE, NEC, LIQUID (COMBUSTIBLE LIQUID, N.O.S.) 4915480 WALLPAPER REMOVER, LIQUID (COMBUSTIBLE LIQUID. N.O.S.) 4915462 PNEUMATIC TIRE REPAIR KITS. AUTO (COMBUSTIBLE LIQ UID. N.O.S.) 4915484 KITS. PNEUMATIC TIRE CLEANING. AUTO (COMBUSTIBLE LIQUID. N.O.S.) 4915466 LACQUER THINNING COMPOUNDS, USED (COMPOUNO, LACQUER, THINNING) 4915488 HYDROXY ALDEHYDE WASTES (COMBUSTIBLE LIQUID. N.O.S.) 4915490 AROMATIC CONCENTRATES. SUITABLE ONLY FOR FUR THER PROCESSING (COMBUSTIBLE LIQUID. N.O.S ) 4915492 SOLDERING FLUX. NEC, LIQUID (COMBUSTIBLE LIQUID. N.O.S.) 4915501 ALCOHOL, CONTAMINATED. SUITABLE ONLY FOR BLEND ING OR REDISTILLING PURPOSES (ALCOHOL, N.O.S.) 4916502 INSECTICIDE ADHESIVES. LIQUID (ADHESIVE. N.O.S.) 4915504 ADHESIVE. N.O.S. 4915510 COAL BRIQUETTE BINDER (COMBUSTIBLE LIQUID, N.O.S.) 4915511 COAL TAR FIBRE SATURANT, LIQUID (COMBUSTIBLE LIQ- UIO, N.O.S.) 4915512 COAL TAR NAPHTHA AND LIGHT OIL OF COAL TAR, CRUDE (COMBUSTIBLE LIQUID. N.O.S.) 4915514 REFINERY CRACKING STOCK (COMBUSTIBLE LIQUIO. N.O.S.) 4915516 COPPER NAPHTHANATE SOLUTION. NOT MORE THAN 8% COPPER NAPHTHANATE (COMBUSTIBLE LIQUID, N.O.S.) 4915525 PETROLEUM OIL ADDITIVE CONTAINING MORE THAN 50 PERCENT BY WEIGHT OF PETROLEUM. (COMBUSTIBLE LIQUID. N.O.S.) 4915530 PETROLEUM PROPYLENE TETRAMER (COMBUSTIBLE LIQ UID, N.O.S.) 4916535 ADDITIVES. FUEL OIL GASOLINE OR LUBRICATING OIL, CONTAINING LESS THAN 50% BY WEIGHT OF PETRO LEUM (COMBUSTIBLE LIQUID. N.O.S.) 61 396 10 418 436 240 157 241 261 241 242 451 219 142 265 252 111 416 110 164 217 143 144 262 254 264 527 415 304 305 284 48 477 13 290 10 130 132 134 445 149 399 400 10 4915543 BRAKE OR SHOCK ABSORBER FLUID OR HYDRAULIC SYSTEM FLUID OTHER THAN PETROLEUM (COMBUSTIBLE LIQUID. N.O.S.) 4915546 FATTY ALCOHOLS. ANIMAL FAT OR ANIMAL FISH. PETROLEUM, SEA-ANIMAL OR VEGETABLE OILS. NEC. WHEN BLENDED WITH EACH OTHER, LIQUID (ALCOHOL. N.O.S.) 4915548 ROOF COATING, CONSISTING OF ASPHALT, PITCH, ROSIN OR TAR BASE (COMBUSTIBLE LIQUID. N.O.S.) 4915550 BATTERY BOX COMPOUNDS (COMBUSTIBLE LIQUID. N.O.S.) 4915552 RUBBER PRESERVATIVE. NEC (COMBUSTIBLE LIQUID, N.O.S.) 4915555 RUBBER ACCELERATORS OR SOFTENERS, OTHER THAN PETROLEUM, NEC (COMBUSTIBLE LIQUID, N.O.S.) 4915556 SOLVENT REFINED COAL. LIQUID (COMBUSTIBLE LIQUID, N.O.S.) 4915560 CHEMICAL PLANT WASTE (COMBUSTIBLE LIQUID. N.O.S.) 4916140 PHOSPHORUS. WHITE OR YELLOW, DRY 4916141 PHOSPHORUS. WHITE OR YELLOW, IN WATER 4916142 PHOSPHORUS, CRUDE, RED AND YELLOW, MIXED (FLAM- MABLE SOLID. N.O.S.) 4916210 ZIRCONIUM METAL DRY (MECHANICALLY PRODUCED. FINER THAN 270 MESH PARTICLE SIZE) 4916211 ZIRCONIUM METAL DRY (CHEMICALLY PRODUCED, FINER THAN 20 MESH PARTICLE SIZE) 4916212 ZIRCONIUM METAL SCRAP (BORINGS CLIPPINGS. SHAV- INGS SHEETS. OR TURNINGS 4916225 NICKEL CATALYST WET,(FINELY DIVIDED. ACTIVATED) 4916226 NICKEL CATALYST WET, (FINELY DIVIDED. SPENT) 4916305 ALUMINUM PHOSPHIDE 4916310 CALCIUM PHOSPHIDE 4916315 PHOSPHORUS HEPTASULFIDE 4916320 PHOSPHORUS PENTASULFIDE 4916330 PHOSPHORUS SESQUISULFIOE 4916335 PHOSPHORUS TRISULFIDE 4916340 STANNIC PHOSPHIDE 4916370 SODIUM PHOSPHIDE 4916401 CALCIUM METAL 4916402 CALCIUM, METAL CRYSTALLINE 4916403 ALUMINUM HYDRIDE 4916405 CESIUM METAL 4916406 CALCIUM CARBIDE 4916415 LITHIUM ACETYLIDE-ETHYLENE DIAMINE COMPLEX 4916420 LITHIUM ALUMINUM HYDRIDE 4916421 LITHIUM BOROHYDRIDE 4916422 LITHIUM FERRO SILICON 4916424 LITHIUM HYDRIDE 4916425 LITHIUM HYDRIDE IN FUSED SOLID FORM 4916428 LITHIUM METAL 4916429 LITHIUM METAL, IN CARTRIDGES 4916431 LITHIUM SILICON 4916432 LITHIUM NITTHDE 4916435 MAGNESIUM. METAL (POWDERED, PELLETS, TURNINGS OR RIBBONS) 4916436 MAGNESIUM SCRAP (BORINGS, CLIPPINGS, SHAVINGS. SHEET. TURNINGS. OR SCALPINGS) 4916440 MAGNESIUM ALUMINUM PHOSPHIDE 4916445 POTASSIUM, METAL 4916446 POTASSIUM. METAL LIQUID ALLOY 4916449 RUBIDIUM METAL. IN CARTRIDGES 4916450 RUBIDIUM METAL 4916452 SODIUM ALUMINUM HYDRIDE 4916453 SODIUM AMIDE 4916454 SODIUM HYDRIDE 4916456 SOOIUM. METALLIC 4916457 SOOIUM. METAL DISPERSION IN ORGANIC SOLVENT 4916456 SODIUM. METAL LIQUID ALLOY 4916459 SODIUM POTASSIUM ALLOY (LIQUID) 4916460 SODIUM POTASSIUM ALLOY (SOLID) 4916475 WATER REACTIVE SOLID, N.O.S. 4916495 ZIRCONIUM HYDRIDE 4916610 DECABORANE 4916615 FLAMMABLE SOLID. POISONOUS. N.O.S. 4916626 DINfTOOPHENOL (FLAMMABLE SOLID. POISONOUS. N.O.S.) 4916701 AMMONIUM DICHROMATE (AMMONIUM BICHROMATE) 4916703 CALCIUM RESINATE 4916704 CALCIUM RESINATE. FUSED 4916705 COBALT RESINATE. PRECIPITATED 4916707 ALUMINUM, METALLIC. POWDER (POWDERS, ALUMINUM) 4916708 ALUMINUM METALLIC POWDER (POWDER, NEC. ALUMINUM) 4916711 HAFNIUM METAL DRY 75 242 450 59 453 452 477 115 409 409 409 543 542 542 363 363 21 100 406 407 407 408 480 474 99 101 20 113 97 314 315 315 316 316 316 316 317 317 317 320 320 319 425 425 455 455 461 462 467 476 476 476 474 475 531 542 163 251 205 26 100 100 136 22 20 266 575 HOD 000017503 4916712 HAFNIUM. METAL. WET 4916717 IRON MASS OR SPONGE (NOT PROPERLY OXIDIZED) 4916718 IRON MASS. (OR) SPONGE, SPENT (IRON SPONGE, SPENT. OR SPENT OXIDE) 4916722 LITHIUM AMIDE, POWDERED 4916723 N-METHYL-N'-NITRO-N'NITROSOGUANIDlNE 4916725 PHOSPHORUS, AMORPHOUS. RED 4916730 POTASSIUM SULFIDE 4916737 SODIUM HYDROSULFITE 4916738 SODIUM HYDROSULFIDE. SOLID (WITHLESS THAN 25% WATER OF CRYSTALLIZATION) 4916739 SODIUM METHYLATE. DRY 4916740 SODIUM SULFIDE. ANHYDROUS 4916750 ZIRCONIUM METAL, WET (MECHANICALLY PRODUCED. FINER THAN 20 MESH PARTICLE SIZE) 4916751 ZIRCONIUM METAL. WET (CHEMICALLY PRODUCED. FINER THAN 20 MESH PARTICLE SIZE) 4916752 ZIRCONIUM METAL BARS, PLATES. RINGS. RODS, SHEETS. SPONGE. STRIPS, TUBING OR UNFINISHED SHAPES. (FLAMMABLE SOLID. N.O.S.) 4916755 FLAMMABLE SOLID. CORROSIVE. N.O.S. 4916761 SODIUM RESINATE, (FLAMMABLE SOLID, N.O.S.) 4916762 COPPER RESINATE, (FLAMMABLE SOLID. N.O.S.) 4916764 ZINC RESINATE. FUSED, (FLAMMABLE SOLID. N.O.S.) 4916765 CHROMIUM RESINATE (FLAMMABLE SOLID. N.O.S.) 4916766 MANGANESE RESINATE. (FLAMMABLE SOLID, N.O.S.) 4916767 CALCIUM-MANGANESE-SILICON ALLOYS, (FLAMMABLE SOLID, N.O.S.) 4916768 SILICON-CALCIUM ALLOY, (FLAMMABLE SOLID, N.O.S.) 4916769 IRON, POWDERED, NEC (FLAMMABLE SOLID. N.O.S.) 4916780 TITANIUM METAL POWDER. WET, WITH 20% OR MORE WATER 4916785 TITANIUM METAL POWDER, DRY OR WET (WITH LESS THAN 20% WATER) 4917110 BARIUM AZIDE, WET (50% OR MORE WATER) 4917120 PICRIC ACID. WET, WITH NOT LESS THAN 10% WATER 4917125 AMMONIUM PICRATE. WET (WITH 10% OR MORE WATER) 4917130 SODIUM PICRAMATE. WET (WITH AT LEAST 20% WATER) 4917140 TRINITROBENZENE. WET (CONTAINING AT LEAST 10% WATER) 4917150 TRINITROBENZOIC ACID. WET (CONTAINING AT LEAST 10% WATER) 4917160 TRINITROTOLUENE, WET {CONTAINING AT LEAST 10% WATER) 4917170 UREA NITRATE. WET (WITH 10% OR MORE WATER) 4917180 NITROGUANIDINE, WET WITH NOT LESS THAN 20% WATER 4917184 NITROCELLULOSE, COLLOIDED, GRANULAR OR FLAKE, WET WITH NOT LESS THAN 20% WATER 4917185 NITROCELLULOSE. WET WITH NOT LESS THAN 20% WATER 4917190 NITROSTARCH. WET WITH NOT LESS THAN 20% WATER 4917195 ZIRCONIUM PICRAMATE. WET. (WITH AT LEAST 20% WATER) 4917301 BAGS. SODIUM NITRATE EMPTY AND UNWASHED 4917304 BURNT COTTON. NOT REPICKED (COTTON. NEC. IN BALES COMPRESSED) 4917307 COAL, GROUND BITUMINOUS, SEA COAL. COAL FACINGS. ETC. 4917309 WOOD CHARCOAL. IN TABLETS (CHARCOAL BRIQUETTES) 4917310 CHARCOAL, ACTIVATED 4917311 CHARCOAL BRIQUETTES (CHARCOAL BRIQUETTES OR PELLETS. WITH PETROLEUM BINDER) 4917312 CHARCOAL BRIQUETTES (CHARCOAL BRIQUETTES OR PELLETS, WITHOUT PETROLEUM BINDER) 4917313 CHARCOAL BRIQUETTES (CHARCOAL BRIQUETTES, COMPRESSED. SELF-IGNITING) 4917314 CHARCOAL. SHELL 4917316 CHARCOAL, WOOD, GROUND, CRUSHED. GRANULATED, (OR) PULVERIZED 4917318 CHARCOAL, WOOD, LUMP 4917320 CHARCOAL SCREENINGS. MADE FHOM PINON WOOD 4917322 CHARCOAL. WOOD SCREENINGS, OTHER THAN PINON WOOD SCREENINGS 4917323 LACQUER BASE DRY 4917324 LACQUER CHIPS, DRY 4917325 FIBERS. BURNT 4917327 FIBERS OR FABRIC. CONTAINING NOT MORE THAN 5% ANIMAL OR VEGETABLE OIL. 4917328 FISH MEAL CONTAINING LESS THEN 6% OR MORE THAN 12% WATER (FISH MEAL, GROUND, PULVERIZED OR SCREENED) 266 293 293 315 345 408 425 468 467 471 475 543 543 542 251 475 150 541 129 321 100 458 294 501 501 57 411 31 474 513 514 514 521 373 370 370 375 543 57 78 136 534 114 113 113 114 114 114 114 114 114 304 305 248 248 249 4917329 FISH SCRAP CONTAINING LESS THAN 6% OR MORE THAN 12% WATER (FISH SCRAP, GROUND. PULVERIZED OR SCREENED) 4917330 FISH SCRAP CONTAINING LESS THAN 6% OR MORE THAN 12% WATER (FISH SCRAP, NEC, DRY NOTGROUND, PUL VERIZED NOR SCREENEO) 4917331 FISH SCRAP OR FISH MEAL CONTAINING LESS THAN 6% OR MORE THAN 12% WATER (FISH TANKAGE, NEC, DRY, NOT GROUND, PULVERIZED, OR SCREENED) 4917332 FLAMMABLE SOLID, N.O.S. 4917333 FUSEE (RAILWAY AND HIGHWAY) 4917335 SPARKLER. MATCH HEAD OR SELF-IGNITING (FLAMMABLE SOLID. N.O.S.) 4917336 MATCHES. STRIKE ANYWHERE 4917337 FILM (NITROCELLULOSE) (MOVING PICTURE FILM, EX- POSED. NEC) 4917340 FILM (NITROCELLULOSE) (MOVING PICTURE FILM SCRAP) 4917345 TANKAGE FERTILIZER 4917346 GARBAGE TANKAGE (CONTAINING LESS THAN 8% MOISTURE) 4917351 PAPER STOCK. WET 4917352 PYROXYLIN PLASTIC SCRAP 4917354 RAGS, OILY 4917355 RAGS. WET 4917356 MATCHES. SAFETY (BOOK. CARD OR STRIKE ON BOX) 4917357 RUBBER MATTING TRIMMINGS (WASTE). OTHER THAN FOAM (RUBBER SCRAP) 4917358 RUBBER SCRAP OR RUBBER BUFFINGS (RUBBER SCRAP HARD PULVERIZED) 4917359 RUBBER SCRAP OR RUBBER BUFFINGS (HARD RUBBER SHAVINGS OR TURNINGS) 4917360 RUBBER DIPPINGS. SCRAP. TRIMMINGS OR WASTE, LATEX FOAM. VALUE FOR GRINDING, FLAKING OR SHREDDING (RUBBER SCRAP) 4917361 RUBBER SCRAP OR RUBBER BUFFINGS 4917362 RUBBER, SHODDY OR REGENERATED RUBBER 4917363 RECLAIMED RUBBER 4917364 GARBAGE TANKAGE (CONTAINING LESS THAN 8% WATER) 491736$ TANKAGE, ROUGH AMMONIATE 4917366 FUSEE (TRUCK FLARES, STEEL, 24 GAUGE OR THICKER) 4917367 ROUGH AMMONIATE TANKAGE. 7% OR MORE MOISTURE CONTENT 4917368 TEXTILE WASTE. WET 4917369 SMOKELESS POWDER FOR SMALL ARMS (100 POUNDS OR LESS) 4917370 WASTE PAPER. WET 4917372 WASTE WOOL. WET 4917373 ROOFING OR FELT STOCK, WOOL, CONSISTING OF WOOL WASTE. SWEEPINGS. OR REFUSE (WATER WOOL. WET) 4917374 WOOL WASTE. NEC, OR WOOL SWEEPINGS (WASTE WOOL. WET) 4917376 DRUGS OR MEDICINES. N.O.S. 4917377 COSMETICS. N.O.S. 4917376 MEOICINES, N.O.S. 4917382 FILM (NITROCELLULOSE) (PHOTOGRAPHIC FILM. NEC, UNEXPOSED) 4917383 FILM (NITROCELLULOSE) (CELLULOSE FILM SCRAP OR WASTE) 4917386 ANIMAL OR POULTRY FEED CHARCOAL. CRUSHED OR GROUNO. (FLAMMABLE SOLID, N O-S.) 4917387 COCOA BEAN SHELLS. (FLAMMABLE SOLID. N.O.S.) 4917366 SPENT GRAINS. DRIED (FLAMMABLE SOLID, N.O.S.) 4917369 SPENT GRAINS. WET. (FLAMMABLE SOLID. N.O.S.) 4917390 NUT MEAL EDIBLE. (FLAMMABLE SOLID. N.O.S.) 4917391 PACKING OR WIPING WASTE MANUFACTURING. NEC. OILED, (FLAMMABLE SOLID, N.O.S.) 4917392 WOOD PULP. CHARRED, NOT ACTIVATED. (FLAMMABLE SOLID. N.O.S.) 4917393 WOOD PULP CHARCOAL, NOT ACTIVATED. (FLAMMABLE SOLID. N.O.S.) 4917394 CHARCOAL. CORN COB OR COTTONSEED OR RICE HULL, NOT ACTIVATED (CHARCOAL SHELL) 4917395 CHARCOAL OTHER THAN ANIMAL OR WOOD. NEC. NOT ACTIVATED. (FLAMMABLE SOLID. N.O.S.) 4917396 COMPOUNDS GAS PURIFYING (FLAMMABLE SOLID, N O.S.) 4917397 CELLULOSE FILM, NEC, PRINTED. (FLAMMABLE SOLID, N.O.S.) 4917405 AIRCRAFT ROCKET ENGINE (COMMERCIAL) 4917*10 AIRCRAFT ROCKET ENGINE IGNITER (COMMERCIAL) 250 250 250 251 260 478 321 248 248 489 261 391 436 445 445 321 453 454 454 453 454 454 445 261 489 260 452 497 461 529 529 451 535 215 151 321 248 248 41 137 479 479 377 389 535 535 114 114 142 110 11 11 576 MOD 000017504 4917412 FEEDING TANKAGE. NEC (FLAMMABLE SOLID. N.O.S.) 243 4918704 AMMONIUM NITRATE-PHOSPHATE 29 4917415 COTTON WASTE. OILY (WITH MORE THAN 5% ANIMAL OR 153 4918705 AMMONIUM NITRATE MIXED FERTILIZER VEGETABLE OIL) 4918707 BLASTING CHLORATE (CHLORATE, N.O.S.) 4917433 TANKAGE. DERIVED FROM MEAT REFUSE (GARBAGE TAN 469 4918708 BARIUM CHLORATE KAGE (CONTAINING LESS THAN 8% MOISTURE)) 4916709 BARIUM NITRATE 29 59 57 58 4917434 TANKAGE, CRUDE. DRIED. OTHER THAN FEEDING (GAR 489 4918710 BARIUM PERCHLORATE 58 BAGE TANKAGE (CONTAINING LESS THAN 8% MOISTURE)) 4918711 BARIUM PERMANGANATE 58 4917435 HAIR. WET 4917438 SPONGE IRON BRIQUETTES OR PELLETS, VALUE ONLY FOR MELTING PURPOSES (FLAMMABLE SOLID, N.O.S.) 266 480 4918712 BARIUM PEROXIDE 4918713 CALCIUM CHLORATE 4918714 CALCIUM CHLORITE 59 97 97 4917440 PYROXYLIN PLASTICS, RODS. SHEETS, ROUS. TUBES 437 4918715 CALCIUM HYPOCHLORITE MIXTURE (DRY, CONTAINING 98 4917445 FLARES, HIGHWAY SAFETY. SOLIDIFIED FUEL. OTHER THAN 252 MORE THAN 39 PERCENT AVAILABLE CHLORINE) EXPLOSIVES OR FIREWORKS. (FLAMMABLE SOLID, N.O.S.) 4918716 CALCIUM NITRATE 99 4917450 PEANUT CHAFF. FEED (FLAMMABLE SOLID, N.O.S.) 393 4918717 CALCIUM PEROXIDE 4917451 PEANUT HUUS, CRUSHED OR GROUND. OR PEANUT HULL 393 4918718 CALCIUM PERMANGANATE 100 100 BRAN OR MEAL. FEED (FLAMMABLE SOLID, N.O.S.) 4918719 CHLORATE AND BORATE MIXTURE 117 4917452 RUBBER FILLER (VEGETABLE OIL FIBER) (FLAMMABLE SOLID. 453 4918720 CHLORATE AND MAGNESIUM CHLORIDE MIXTURE 117 N.O.S.) 4918721 CHLORATE, N.O.S. 117 4917460 FISH OIL RESIDUUM. DEHYDRATED (GARBAGE TANKAGE 249 4918722 POTASSIUM CHLORATE 420 (CONTAINING LESS THAN 8% MOISTURE) 4918723 SODIUM CHLORATE 464 4917461 ACID FISH SCRAP (FISH SCRAP (CONTAINING LESS THAN 6 4918724 DICHLOROISOCYANURIC ACID (OXIDIZING MATERIAL, N.O.S.) 186 6% OR MORE THAN 12% MOISTURE)) 4918725 FERRIC NITRATE 245 4917462 FISH SCRAP, NEC. GREEN (FISH SCRAP (CONTAINING LESS 250 4918726 LEAD NITRATE 309 THAN 6% OR MORE THAN 12% MOISTURE)) 4918727 LITHIUM HYPOCHLORITE COMPOUND, DRY CONTAINING 316 4917468 SELF-LIGHTING CIGARETTE 456 MORE THAN 39 PERCENT AVAILABLE CHLORINE 4917470 WASTE PAPER PULP, WET (WASTE PAPER, WET) 529 4918728 MAGNESIUM NITRATE 319 4917475 POLISHING CLOTHS, COTTON. TREATED WITH CHEMICALS. 417 4918729 MAGNESIUM PERCHLORATE 319 OIL OR WAX (FLAMMABLE SOLID.N.O.S.) 4918730 MAGNESIUM PEROXIDE. SOLID 319 4918110 CHLORINE DIOXIDE HYDRATE, FROZEN 119 4918731 NITRATE, N.O.S. (NITRATE OF SODA AND POTASH) 366 4918180 TETRANITROMETHANE 496 4916732 NITRATE, N.O.S. 366 4916206 CHLORIC ACID 118 4918733 OXIDIZER (OR) OXIDIZING MATERIAL N.O.S. 386 4918210 CHLORINE TRIFLUORIDE 119 4916734 AMMONIUM NITRATE-CARBONATE MIXTURE 4918215 IODINE PENTAFLUORIDE 293 4916735 PERMANGANATE. N.O.S. 4918310 AMMONIUM NITRATE FERTILIZER (CONTAINING NO MORE 2S 4918736 POTASSIUM BROMATE 29 396 420 THAN 0.2% CARBON) 4918737 POTASSIUM NITRATE 423 4918311 AMMONIUM NITRATE (NO ORGANIC COATING) 28 4918738 POTASSIUM NfTRATE MIXED (FUSED) WITH SODIUM NITRITE 423 4918312 AMMONIUM NITRATE (ORGANIC COATING) 28 4918739 POTASSIUM NITRITE 424 4918320 AMMONIUM PERCHLORATE 31 4918740 POTASSIUM PERMANGANATE 424 4918322 AMMONIUM PERMANGANATE 31 4918741 POTASSIUM NITRATE (SALTPETER). CRUDE (OXIOIZING MA 423 4918335 HYDROGEN PEROXIDE SOLUTION (OVER 52% PEROXIDE) 282 TERIAL. N.O.S.) 4918340 POTASSIUM PERCHLORATE 4918360 SODIUM CHLORITE 424 4918742 SILVER NITRATE 464 4918743 SODIUM BROMATE 458 463 4918405 COMPOUND. TREE OR WEED KILLINGS, SOLID 142 4918744 CUPRIC NITRATE 156 4918410 DRUGS OR MEDICINES, N.O.S. 215 4918745 COPPER NITRATE SOLUTION (CUPRIC NITRATE) 149 4918411 COSMETICS. N.O.S. 152 4916746 SODIUM NITRATE 472 4916412 MEDICINES, N.O.S. 321 4918747 SODIUM NITRITE 472 4918415 GUANIDINE NITRATE 266 4918749 SOOIUM NITRITE MIXTURE (SODIUM NITRATE. SODIUM NI 472 491B420 MONO-(TRICHLORO) TETRA-(MONOPOTASSIUM DICH- 351 TRITE, AND POTASSIUM NITRITE) LORO) PENTA-S-TRIAZINETRIONE (DRY CONTAINING MORE 4918750 SOOIUM PERCHLORATE 473 THAN 39% AVAILABLE CHLORINE) 4918751 SODIUM PERMANGANATE 473 4918430 POTASSIUM DICHLORO-S-TRIAZINETRIONE (DRY. CON 421 4918752 MERCUROUS NITRATE. SOLID 329 TAINING MORE THAN 39% AVAILABLE CHLORINE) 4918753 STRONTIUM CHLORATE 481 4918435 SODIUM DICHLORO-S-TRIAZINETRIONE (0RY, CONTAINING 466 4918754 STRONTIUM NITRATE 482 MORE THAN 39% AVAILABLE CHLORINE) 4918755 STRONTIUM PEROXIDE 482 4918445 TRICHLORO-S-TRIAZINETRIONE (DRY, CONTAINING MORE 508 4918756 ZINC AMMONIUM NITRITE 537 THAN 39 PERCENT AVAILABLE CHLORINE) 4918757 ZINC PERMANGANATE 640 491BS05 BROMINE PENTAFLUORIDE 76 4918758 ZINC PEROXIDE 541 4918507 BROMINE TRIFLUORIDE 4918510 CHROMIC ACID. SOLID 77 4918759 BERYUIUM NITRATE 69 128 4918760 POTASSIUM ALKALI SALTS, CRUDE, DRY (OXIDIZING MA 419 4918511 CHROMIC ACID MIXTURE, DRY 127 TERIALS. N.O.S) 4918520 LITHIUM PEROXIDE 317 4918761 POTASSIUM SALTS. NEC (OXIDIZING MATERIALS. N.O.S ) 425 4916522 PERCHLORIC ACID. NOT OVER 50% ACID 395 4918762 NITROGEN SALTS. AGRICULTURAL CRUDE (OXIDIZING MA 372 4918523 PERCHLORIC ACID (EXCEEDING 50% BUT NOT EXCEEDING 395 TERIAL. N.O.S.) 72%) 4916763 POTASSIUM PERSULFATE (OXIDIZING MATERIAL. N.O.S.) 425 4918525 NITRATING (MIXED) ACID 4918528 NITRIC ACID (OVER 40%) 367 4918765 SODIUM CHLORATE AND SODIUM CHLORIDE. IN WATER 464 367 SOLUTION (OXIDIZING MATERIAL. N.O.S.) 4918529 NITRIC ACID, FUMING 368 4918767 SODIUM PERBORATE (OXIDIZING MATERIAL N.O.S.) 472 4918530 POTASSIUM PEROXIDE 424 4918769 MERCURIC NITRATE 325 4918540 SODIUM PEROXIDE 473 4918770 PERCHLORATE. N.O.S. 395 4918545 OXIDIZER. CORROSIVE. LIQUID. N.O.S. 387 4918771 ZINC CHLORATE 538 4918546 OXIDIZER. CORROSIVE. SOLID. N.O.S. 4918605 BARIUM CHLORATE. WET 387 4918774 AMMONIUM NITRATE, SOLUTION (CONTAINING NOT LESS 57 THAN 15% WATER) 30 4918610 CHLORATE, N.O.S., WET 117 4918775 HYDROGEN PEROXIDE SOLUTION (8% TO 40% PEROXIDE) 263 4918615 STRONTIUM CHLORATE, WET 481 4918776 HYDROGEN PEROXIDE SOLUTION (40% TO 52% PEROXIDE) 282 4918701 ALUMINUM NITRATE 20 4918777 OXIDIZER, POISONOUS. LIQUID, N.O.S. 387 4918702 AMMONIUM NITRATE. SODIUM NITRATE MIXTURE (OXIDIZ 30 4918778 OXIDIZER, POISONOUS, SOLID, N.O.S. 387 ING MATERIAL. N.O.S.) 4918779 LEAD PEROXIDE, GROUND, DRY (LEAD PEROXIDE 309 4918703 AMMONIUM NITRATE, MAGNESIA AND PULP MIXTURE (OX 30 4918780 LEAD PEROXIDE. PASTE (LEAD PEROXIDE) 309 IDIZING MATERIAL, N.O.S 4916789 NICKEL NITRATE 364 577 MCD 000017505 4918790 ZINC NITRATE 4918791 ZIRCONIUM NITRATE 4918795 CALCIUM HYPOCHLORITE, HYDRATED (MINIMUM 5.5% BUT NOT MORE THAN 10% WATER, AND CONTAINING MORE THAN 39% AVAILABLE CHLORINE) 4918905 FLAME COLORING COMPOUNDS (OXIDIZING MATERIALS. N.O.S.) 4918910 FLOUR BLEACHING COMPOUNDS, NEC (OXIDIZING MATE RIAL, N.O.S.) 4918915 PLOSPHORIC CHEMICALS (OXIDIZING MATERIAL, N.O.S.) 4918920 FERTILIZING COMPOUNDS, NEC DRY (OXIDIZING MATE RIAL, N.O.S.) 4918925 PERMANENT HAIR WAVING SETS, OTHER THAN ELECTRIC (OXIDIZING MATERIAL. N.O.S.) 4919103 ACETYL CYCLOHEXANESULPHONYL PEROXIDE, (NOT MORE THAN 32% IN SOLUTION) 4919104 ACETYL CYCLOHEXANESULPHONYL PEROXIDE, (NOT MORE THAN 82%. WETTED WITH NOT LESS THAN 12% WATER) 4919107 TERT-AMYL PEROXYNEODECANOATE, (NOT MORE THAN 75% WITH PHLEGMATIZER) 4919108 TERT-AMYL PEROXY-2-ETHYLHEXANOATE, (TECHNICALLY PURE) 4919110 BENZOYL PEROXIDE (BENZOYL PEROXIDE.DRY OR WET WITH LESS THAN 30% WATER) 4919113 BENZOYL PEROXIDE. (TECHNICALLY PURE OR) BENZOYL PEROXIDE, (MORE THAN 52% WITH INERT SOLID) 4919114 BENZOYL PEROXIDE, (NOT MORE THAN 77% WITH WATER) 4919115 BENZOYL PEROXIDE (BENZOYL PEROXIDE CRYSTALS. GRANULES OH POWDERS. WET WITH NOT LESS THAN 30% WATER) 4919116 BENZOYL PEROXIDE, (NOT MORE THAN 72% AS A PASTE) 4919117 BENZOYL PEROXIDE. (NOT LESS THAN 30% BUT NOT MORE 52% WITH INERT SOLID) 4919118 BENZOYL PEROXIDE, (MORE THAN 77% BUT LESS THAN 95% WITH WATER) 4919120 P-CHLOROBENZOYL PEROXIDE 4919125 CYCLOHEXANONE PEROXIDE AND DI-(1-HYDROXYCY- 540 543 99 250 253 414 248 396 5 5 491 38 66 67 67 66 67 67 66 121 160 4919151 TERT-BUTYL PEROXYBENZOATE. (TECHNICALLY PURE OR) TERT-BUTYL PEROXYBENZOATE. (MORE THAN 75% IN SOLUTION) 4919152 TERT-BUTYL PEROXYCROTONATE. (NOT MORE 76% IN SOLUTION) 4919153 N-BUTYL PEROXYDICARBONATE, (NOT MORE THAN 27% IN SOLUTION) 4919154 N-BUTYL PEROXYDICARBONATE, (NOT MORE THAN 52% IN SOLUTION) 4919155 TERT-BUTYL PEROXYDIETHYLACETATE, (33% WITH) TERTBUTYL PEROXYBENZOATE. (33%, AND SOLVENT) 4919156 TERT-BUTYL PEROXYDIETHYLACETATE. (TECHNICALLY PURE) 4919157 TERT-BUTYL PEROXYISOBUTYRATE, (MORE THAN 52% BUT NOT MORE THAN 77% IN SOLUTION) 4919158 TERT-BUTYL PEROXYISOBUTYRATE, (NOT MORE THAN 52% IN SOLUTION) 4919159 TERT-BUTYL PEROXYISOPROPYL CARBONATE, (TECHNICALLY PURE) 4919160 TERT-BUTYL PEROXYMALEATE, (NOT MORE THAN 55% IN SOLUTION) 4919161 TERT-BUTYL PEROXYMALEATE. (NOT MORE THAN 55% AS A PASTE) 4919162 TERT-BUTYL PEROXYMALEATE. (TECHNICALLY PURE) 4919163 TERT-BUTYL PEROXYNEODECANOATE. (NOT MORE THAN 77% IN SOLUTION) 4919164 TERT-BUTYL PEROXYNEODECANOATE. (TECHNICALLY PURE) 4919165 TERT-BUTYL PEROXYPHTHALATE. (TECHNICALLY PURE) 4919166 TERT-BUTYL PEROXYPIVALATE, (NOT MORE THAN 77% IN SOLUTION) 4919167 LAUROYL PEROXIDE, (NOT MORE THAN 42%,STABLE DIS- PERSION, IN WATER) 4919168 3,3,6,6.9,9-HEXAMETHYL-1.2.4,5-TETRAOXOCYCLONON- AN6, (NOT MORE THAN 52% IN SOLUTION) 4919169 3,3,6,6.9,9-HEXAMETHYL-l ,2,4,5-TETRAOXOCYCLONON- ANE, (NOT MORE THAN 52% WITH INERT SOLID) 88 88 88 356 89 88 89 89 90 90 90 91 91 91 91 92 306 272 272 CLOHEXYL) PEROXIDE MIXTURE 4919120 DECANOYL PEROXIDE. (TECHNICALLY PURE) 4919130 OIISOPROPYLBENZENE HYDROPEROXIDE SOLUTION (NOT OVER 60% PEROXIDE) 4919133 N-BUTYL-4,4-Dt-(TERT-BUTYLPEROXY)VALERATE. (NOT MORE THAN 52% WITH INERT SOLID) 4919134 N BUTYL-4,4-DI-(TERT-BUTYLPER0XY)VALERATE. (TECH NICALLY PURE) 164 197 93 93 4919170 SUCCINIC ACID PEROXIDE 4919174 ISONONANYL PEROXIDE, (TECHNICALLY PURE)(OR) ISO- NONANYL PEROXIDE, (IN SOLUTION) 4919175 ISOPROPYL PEROXYDICARBONATE. (TECHNICALLY PURE) 4919176 ISOPROPYL PEROXYDICARBONATE, (NOT MORE THAN 52% IN SOLUTION) 4919178 METHYL ETHYL KETONE PEROXIDE. (IN SOLUTION WITH NOT MORE THAN 9% BY WEIGHT ACTIVE OXYGEN) 485 297 302 301 338 4919135 TERT-BUTYL CUMYL PEROXIDE. (TECHNICALLY PURE OR) TERT-BUTYL CUMENE PEROXIOE. (TECHNICALLY PURE) 4919136 TERT-BUTYL HYDROPEROXIDE. (MORE THAN 72% BUT NOT MORE THAN 90% WITH WATER) 82 4919180 METHYL ISOBUTYL KETONE PEROXIDE. (IN SOLUTION WITH 340 NOT MORE THAN 9% BY WEIGHT ACTIVE OXYGEN) 82 4919182 N-OCTANOYL PEROXIOE, (TECHNICALLY PURE) 378 4919185 PELARGONYL PEROXIDE, (TECHNICALLY PURE) 393 4919137 TERT-BUTYL HYDROPEROXIDE. (NOT MORE THAN 72% 83 4919187 PROPIONYL PEROXIDE, (NOT MORE THAN 28% IN SOLUTION) 430 WITH WATER) 4919138 TERT-BUTYL HYDROPEROXIDE. (NOT MORE THAN 80% IN DI-TERT-BUTYL PEROXIDE AND SOLVENT) 4919140 DIMETHYLHEXANE DIHYDROPEROXIDE. (WITH 18% OR MORE WATER) 4919141 TERT-BUTYL PEROXY-2-ETHYLHEXANOATE, (TECHNI CALLY PURE) 4919142 TERT-BUTYL PEROXY-2-ETHYLHEXANOATE. (NOT MORE THAN 30%) WITH 2.2-DI-(TERT-BUTYLPEROXY) BUTANE, (NOT MORE THAN 35% WITH NOT LESS THAN 35% PHLEGMATIZER) 4919143 TERT-BUTYL PEAOXY-2-ETHYLHEXANOATE. NOT MORE 12%) WITH 2,2-DI-{TERT-BUTYLPEROXY)BUTANE. (NOT MORE THAN 14% WITH NOT LESS THAN 14% PHLEGMATIZER AND 60% INERT INORGANIC SOLID) 4919144 TERT-BUTYL PEROXY-2-ETHYLHEXANOATE. (NOT MORE THAN 50% WITH PHLEGMATIZER) 4919145 TERT-BUTYL PEROXY-3.5.5-TRIMETHYLHEXANOATE (OR) TERT-BUTYL PEROXYISONONANOATE. (TECHNICALLY PURE) 4919146 3-TERT-BUTYL PEROXY-3-PHENYLPHTHALIDE. (TECHNI CALLY PURE) 83 204 85 84 65 85 66 86 4919189 TETRALIN HYDROPEROXIDE. (TECHNICALLY PURE) 4919190 1,1,3,3-TETRAMETHYLBUTYL HYDROPEROXIDE. (TECHNI- CALLY PURE) 4919191 1.1,3,3-TETRAMETHYLBUTYL PEROXY-2-ETHYLHEXANOATE, (TECHNICALLY PURE) 4919206 1.3-DI-(2-TERT-BUTYLPEROXYISOPROPYL) BENZENE, (TECHNICALLY PURE OR MORE THAN 40% WITH INERT SOLID) 4919207 1,3-DI-(2-TERT-BUTYLPEROXYISOPROPYL) BENZENE AND 1,4-DI-(2-TERT- BUTYLPEROXYISOPROPYL) BENZENE MIXTURE, (TECHNICALLY PURE OR 4919208 1,4-DI-(2-TERT-BUTYLPEROXYISOPROPYL) BENZENE, (TECHNICALLY PURE OR MORE THAN 40% WITH INERT SOLID) 4919210 2,2-OI-(TERT-BUTYLPEROXY)BUTANE. (NOT MORE THAN 55% IN SOLUTION) 4919213 DI-TERT-BUTYL PEROXIDE. (TECHNICALLY PURE) 4919214 DI-SEC-BUTYL PEROXYDICARBONATE, (NOT MORE THAN 52% IN SOLUTION) 4919215 DI-SEC-BUTYL PEROXYDICARBONATE, (TECHNICALLY PURE) 4919218 P-CHLOROBENZOYL PEROXIOE, (NOT MORE THAN 75% WITH WATER) 505 495 496 173 173 174 169 176 176 176 121 4919147 TERT-BUTYL PEROXYACETATE. (NOT MORE THAN 52% IN SOLUTION) 4919148 TERT-BUTYL PEROXYACETATE. (NOT MORE THAN 76% IN 86 4919219 P-CHLOROBENZOYL PEROXIDE. (NOT MORE THAN 52% AS 121 A PASTE) THAN 52% WITH INERT SOLID) 87 4919220 P-CHLOROBENZOYL PEROXIDE, (NOT MORE THAN 52% IN 123 SOLUTION) 4919149 TERT-BUTYL PEROXYBENZOATE (NOT MORE THAN 50% WITH INERT INORGANIC SOLID) 4919150 TERT-BUTYL PEROXYBENZOATE, (NOT MORE THAN 75% IN SOLUTION) SOLUTION) 87 4919223 3-CHLOROPEROXYBENZOIC ACID. (NOT MORE THAN 06% 123 WITH 3-CHLOROBENZOIC ACID) 87 4919226 1,1 -DI-(TERT-BUTYLPEROXY)CYCLOHEXANE. (TECHNI- 170 CALLY PURE) 578 7b06 4919227 1,1-DI-(TERT-BUTYLPER0XY)CYCL0HEXANE, (NOT MORE THAN 77% IN SOLUTION) 4919228 1.2-DI-(TERT-BUTYLPEROXY)CYCLOHXANE, (NOT MORE THAN 77% IN SOLUTION) 4919229 1,1*DI-(TERT*BUTYLPEROXY)CYCLOHEXANE, (NOT MORE THAN 40% WITH INERT INORGANIC SOLID, WITH NOT LESS THAN 13% PHLEGMATIZER) 4919230 1,1-DI-(TERT-BUTYLPEROXY)CYCLOHEXANE, (NOT MORE THAN 50% WITH 4919234 DIACETONE ALCOHOL PEROXIDE, (NOT MORE THAN 57% IN SOLUTION WITH NOT MORE THAN 9% HYDROGEN PER OXIDE, NOT LESS THAN 26% DIACETONE ALCOHOL AND NOT LESS THAN 9% WATER: TOTAL ACTIVE OXYGEN CONTENT NOT MORE THAN 9%) 491923S DIBENZYL PEROXYDlCARBONATE, (NOT MORE THAN 87% WITH WATER) 4919237 DICETYL PEROXYDlCARBONATE, (NOT MORE THAN 42%. STABLE DISPERSION, IN WATER) 4919238 DICETYL PEROXYDlCARBONATE, (TECHNICALLY PURE) 4919242 2,4-DICHLOROBENZOYL PEROXIDE, (NOT MORE THAN 75% WITH WATER) 4919243 2.4-DICHLOROBENZOYL PEROXIDE, (NOT MORE THAN 52% AS A PASTE) 4919244 2,4-DICHLOROBENZOYL PEROXIDE, (NOT MORE THAN 52% IN SOLUTION) 4919247 DICYCLOHEXYL PEROXYDlCARBONATE, (TECHNICALLY PURE) 4919248 DICYCLOHEXYL PEROXYDlCARBONATE, (NOT MORE THAN 91% WITH WATER) 4919251 DIETHYL PEROXYDlCARBONATE, (NOT MORE THAN 27% IN SOLUTION) 4919253 2,2-DIHYDROPEROXY PROPANE, (NOT MORE THAN 25% WITH INERT ORGANIC SOLID) 4919255 DIISOBUTYRYL PEROXIDE. (NOT MORE THAN 52% IN SOLUTION) 4919257 DIISOTRIDECYL PEROXYDlCARBONATE, (TECHNICALLY PURE) 4919258 2.5-DIMETHYL-2.5-Dl-(2-ETHYLH6XANOYLPEROXY) HEX ANE, (TECHNICALLY PURE) 4919259 2.5-DIMETHYL-2,5-DI-(8ENZOYLPEROXY) HEXANE. (TECH NICALLY PURE) 4919260 2,5-DIMETHYL-2,5-DJ-(BENZOYLPEROXY) HEXANE, (NOT MORE THAN 82% WITH INERT SOLID) 4919261 2,5-DIMETHYL-2,5-DlHYDROPEHOXY HEXANE, (NOT MORE THAN 82% WITH WATER) 4919262 2,5-DIMETHYL-2,5-DI-(TERT-BUTYLPEROXY) HEXANE, (TECHNICALLY PURE) 4919263 2.5-DIMETHYL-2.5-DI-(TERT-BUTYLPEROXY) HEXANE, (NOT MORE THAN 52% WITH INERT SOLID) 4919264 2.5-DIMETHYL*2,5-DI-(TERT-BUTYLPEROXY)HEXYNE-3, (TECHNICALLY PURE) 4919265 2.5-DIMETHYL-2,5-DI-(TERT-BUTYLPEROXY)HEXYNE-3, (NOT MORE THAN 52% WITH INERT SOLID) 4919269 DIMYRISTYL PEROXYDlCARBONATE, (TECHNICALLY PURE) 4919270 DIMYRISTYL PEROXYDlCARBONATE, (NOT MORE THAN 22%, STABLE DISPERSION, IN WATER) 4919273 ETHYL-3,3-DHTERT-BUTYLPEROXY)BUTYRATE, (NOT MORE THAN 50% WITH INERT INORGANIC SOLID) 4919274 ETHYL-3,3-DHTERT-BUTYLPEROXY)BUTYRATE, (NOT MOTE THAN 77% IN SOLUTION) 4919275 ETHYL-3-3.DI-(TERT-BUTYLPEROXY)BUTYRATE. (TECHNI CALLY PURE) 4919277 3,3,6,6,9,9-HEXAMETHYL*1,2,4,5-TETRAOXOCYCLONON- ANE, (TECNHICALLY PURE) 4919279 DI-(I-HYDROXYCYCLOHEXYL) PEROXIDE. (TECHNICALLY PURE) 4919280 DI-(2-ETHYLHEXYL) PEROXYDlCARBONATE, (TECHNICALLY PURE) 4919281 DI-(2-ETHYLHEXYL) PEROXYDlCARBONATE, (NOT MORE THAN 67% IN SOLUTION) 4919282 DH2-METHYLBENZOYL) PEROXIDE, (NOT MORE THAN 85% WITH WATER) 4919283 Dl*{3,5,5-TRIMETHYL-1,2-DIOXOLANYL-3) PEROXIDE, (NOT MORE THAN 50% AS A PASTE. WITH PHLEGMATIZER) 4919284 DI-(4-TERT-BUTYLCYCLOHEXYL)PEROXYDICARBONATE, (NOT MORE THAN 42%. STABLE DISPERSION, IN WATER) 4919285 DI-(4-TERT-BYTYLCYCLOHEXYL)PEROXYDICARBONATE, (TECHNICALLY PURE) 4919286 DI-{TERT-BUTYLPEROXY)PHTHALATE, (TECHNICALLY PURE) 169 170 169 169 177 178 180 180 163 183 183 190 190 192 194 196 197 201 199 199 201 200 201 201 200 204 204 233 234 233 272 172 172 172 173 174 174 175 171 4919287 DI-(TERT-BUTYLPEROXY)PHTHALATE, (NOT MORE THAN 55% IN SOLUTION) 4919288 DI-(TEHT-BUTYLPEROXY)PHTHALATE. (NOT MORE THAN 55% AS A PASTE) 4919290 2,2*DI*(TERT*BUTYLPEROXY)PROPAN, (NOT MORE THAN 50% WITH PHLEGMATIZER) 4919291 2,2-DI-(TERT-BUTYLPEROXY)PBOPANE, (NOT MORE THAN 40% WITH INERT INORGANIC SOLID WITH NOT LESS THAN 13% PHLEGMATIZER) 4919292 2.2-DI-(4,4-Ol-TERT-BUTYLPEROXYCYCLOHEXYL) PROPANE, (NOT MORE THAN 42% WITH INERT SOLID) 4919294 DJ-N-PROPYL PEROXYDlCARBONATE, (TECHNICALLY PURE) 4919296 1,1-DI-(TERT-BUTYLPEROXY)-3,3,5-TRIMETHYL CYCLOHEXANE, (TECHNICALLY PURE) 4919297 1,1-DI-(TERT-BUTYLPEROXY)-3.3,5-TRIMETHYL CYCLOHEXANE, (NOT MORE THAN 57% IN SOLUTION) 4919298 1,1-DI-(TERT-BUTYLPEfiOXY)-3,3,5-TRIMETHYL CYCLOHEXANE. (NOT MORE THAN 58% WITH INERT SOLID) 4919505 ACETYL BENZOYL PEROXIDE SOLUTION (NOT OVER 40% PEROXIDE) 4919510 ACETYL PEROXIDE SOLUTION. (NOT OVER 25% PEROXIDE) 4919517 CAPRYLYL PEROXIDE SOLUTION 4919525 CUMENE HYDROPEROXIDE 4919527 CYCLOHEXANONE PEROXIDE (IN SOLUTION WITH NOT MORE THAN 9% BY WEIGHT ACTIVE OXYGEN) 4919528 CYCLOHEXANONE PEROXIDE, (AS A PASTE WITH NOT MORE THAN 9% BY WEIGHT ACTIVE OXYGEN) 4919530 CYCLOHEXANONE PEROXIDE, (NOT OVER 50% PEROXIDE) 4919535 CYCLOHEXANONE PEROXIDE. (50 TO 85% PEROXIDE) 4919537 CYCLOHEXANONE PEROXIDE AND BlS(1-HYDROXYCY- CLOHEXYL) PEROXIDE MIXTURE 4919540 DICUMYL PEROXIDE. DRY 4919545 DICUMYL PEROXIDE (50% PEROXIDE) 4919550 ISOPROPYL PERCARBONATE, STABILIZED 4919551 ISOPROPYL PERCARBONATE, UNSTABIUZED 4919560 LAUROYL PEROXIDE 4919565 PARAMENTHANE HYDROPEROXIDE 4919570 PERACETIC ACID SOLUTION (NOT OVER 40% PERACETIC ACID AND NOT OVER 6% HYDROGEN PEROXIDE) 4919573 PINANE HYDROPEROXIDE SOLUTION (NOT OVER 45% PEROXIDE) 4919575 ORGANIC PEROXIDE, LIQUID, (OR) SOLUTION, N.O.S. 4919580 ORGANIC PEROXIDE. SOLID. N.O.S. 4919590 TERT-BUTYL ISOPROPYL BENZENE HYDROPEROXIDE 4919595 UREA PEROXIDE 4920101 BROMOACETONE, LIQUID 4920105 CHLOROPICRIN AND METHYL CHLORIDE MIXTURE 4920115 CYANOGEN GAS 4920120 GERMANE 4920125 HYDROCYANIC ACID. LIQUEFIED 4920130 HYDROCYANIC ACI0, SOLUTION 4920135 ARSINE 4920160 PHOSPHINE 4920330 NITRIC OXIDE 4920340 NITROGEN DIOXIOE, LIQUID 4920350 NITROGEN PEROXIDE, LIQUID 4920360 NITROGEN TETROXIDE. LIQUID 4920S0S CHLORPICRIN AND NONFLAMMABLE, NONLIQUEFIED COM- PRESSED GAS MIXTURE 4920506 CYANOGEN CHLORIDE (CONTAINING LESS THAN 0.9% WATER) 4920510 GAS IDENTIFICATION SET 4920515 HEXAETHYLTETRAPHOSPHATE AND COMPRESSED GAS MIXTURE 4920517 LEWISITE (POISONOUS LIQUID. N.O.S.) 4920520 METHYLDICHLOROARSINE 4920525 MUSTARD GAS (POISONOUS LIQUID. N.O.S.) 4920530 ORGANIC PHOSPHATE, ORGANIC PHOSPHATECOM- POUND. OR ORGANIC PHOSPHORUS COMPOUND; MIXED WITH COMPRESSED GAS 4920535 PARATHION AND COMPRESSED GAS MIXTURE 4920540 PHOSGENE 4920544 TETRAETHYL DITHIO PYROPHOSPHATE AND COM* PRESSED GAS MIXTURE 4920545 TETRAETHYL PYROPHOSPHATE AND COMPRESSED GAS MIXTURE 4920550 INSECTICIDE, LIQUEFIED GAS, CONTAINING POISON A MA- TERIAL OR POISON B MATERIAL 4920910 POISONOUS LIQUID, N.O.S. 171 170 172 .171 175 175 168 168 168 4 6 102 155 160 160 161 161 160 190 189 301 301 306 391 394 412 380 380 84 522 77 123 159 264 279 279 S3 405 368 371 372 372 125 158 262 271 312 346 356 382 392 404 491 493 292 416 579 MOD 000017507 4920911 POISONOUS GAS, N.O.S. 4920925 CHEMICAL AMMUNITION. NONEXPLOSIVE (CONTAINING A POISON A MATERIAL) 4921210 CARBOLIC ACID, LIQUID OR PHENOL, LIQUID. (LIQUID TAR ACID CONTAINING OVER 50% BENZO-PHENOL) 4921220 CARBOLIC ACID OR PHENOL 4921250 POISONOUS SOLID, CORROSIVE, N.O.S, 4921401 ACETONE CYANOHYDRIN 4921403 ALDRIN 4921406 ALDRIN MIXTURE. LIOUIO (WITH MORE THAN 60% ALDRIN) 4921407 ALDRIN MIXTURE. DRY (WITH MORE THAN 65% ALDRIN) 4921410 ANILINE OIL. LIQUID 4921411 BRUCINE, SOLID (DIMETHYL STRYCHNINE) 4921412 4-CHLORO-O-TOLUIDlNE HYDROCHLORIDE 4921414 CHLOROPICRIN. LIQUID 4921415 CHLOROPICRIN. ABSORBED 4921416 CHLOROPICRIN MIXTURE (CONTAINING NO COMPRESSED GAS OR POISON A LIQUID) 4921417 HYDROCYANIC ACIO, SOLUTION, LESS THAN 5% HYDRO CYANIC ACID 4921418 COCCULUS. SOLID 4921419 COMPOUNDS. TREE OR WEED KILLING. LIQUID 4921420 ETHYLENE CHLOROHYDRIN 4921421 DINITROBENZENE. SOLID OR DINITROBENZOL SOLID 4921422 DINITROBENZOL. SOLUTION 4921423 HEXAETHYL TETRAPHOSPHATE MIXTURE. DRY (CONTAINS NOT MORE THAN 2% HEXAETHYL TETRAPHOSPHATE) 4921424 DINITROCHLOROBENZOL. SOLID OR DINITROCHLOROBENZENE 4921425 DINITROPHENOL SOLUTION 4921426 MEDICINES, N.O.S. (LIQUID) 4921427 DRUGS OR MEDICINES, N.O.S. (LIQUID) 4921430 HEXAETHYL TETRAPHOSPHATE. LIQUID 4921431 HEXAETHYL TETRAPHOSPHATE MIXTURE, DRY (CONTAIN ING MORE THAN 2% HEXAETHYL TETRAPHOSPHATE) 4921432 HEXAETHYL TETRAPHOSPHATE MIXTURE. LIOUID (CON TAINING MORE THAN 25% HEXAETHYL TETRAPHOSPHATE) 4921434 INSECTICIDE. DRY, N O S. (INSECTICIDES. INSECT OR ANI MAL REPELLENTS OR VERMIN EXTERMINATORS, NEC. OTHER THAN AGRICULTURAL) 4921435 INSECTICIDE, DRY. N.O.S. (AGRICULTURAL INSECTICIDES OR FUNGICIDES, NEC, OTHER THAN LIOUID) 4921436 INSECTICIDE, LIQUID. N.O.S. (AGRICULTURAL INSECTI CIDES OR FUNGICIDES. NEC. LIOUID) 4921437 METHYL BROMIDE AND MORE THAN 2% CHLOROPICRIN MIXTURE. LIQUID 4921436 METHYL BROMIDE AND ETHYLENE DIBROMIDE MIXTURE. LIQUID 4921439 METHYL BROMIDE AND NONFLAMMABLE NONUQUEFIED COMPRESSED GAS MIXTURE, LIOUID 4921440 METHYL BROMIDE. LIQUID (INCLUDING UP TO 2% CHLOROPICRIN) 4921441 HEXAETHYL TETRAPHOSPHATE MIXTURE. LIQUID (CON TAINING NOT MORE THAN 25% HEXAETHYL TETRAPHOSPHATE) 4921442 METYL PARATHION. LIQUID 4921443 METHYL PARATHION MIXTURE. DRY 4921444 METHYL PARATHION MIXTURE. LIQUID (CONTAINING 25% OR LESS METHYL PARATHION) 4921445 MOTOR FUEL ANTIKNOCK COMPOUND (OR) ANTIKNOCK COMPOUND (THESE MATERIALS MAY CONTAIN VARIOUS HAZARDOUS SUBSTANCE FOR WHICH THE APPROPRI ATE RQ APPLIES) 4921446 NAPHTHYL METHYL CARBAMATE (POISONOUS SOLID. N.O.S ) 4921447 METHYL PARATHION MIXTURE. LIQUID (CONTAINING OVER 25% METHYL PARATHION) 4921448 NICOTINE HYDROCHLORIDE 4921449 NICOTINE. LIQUID 4921450 NICOTINE SALICYLATE 4921451 NICOTINE SULFATE, LIQUID 4921452 NICOTINE SULFATE, SOLID 4921453 NICOTINE TARTRATE 4921454 FUNGICIDES, AGRICULTURAL, NEC, LIOUID (POISONOUS LIOUIO. N.O.S.) 4921455 NITROBENZOL 4921456 FUNGICIDES, AGRICULTURAL. NEC, OTHER THAN LIQUID (POISONOUSSOLID. N.O.S.) 4921457 NITROCHLOROBENZENE, ORTHO, LIQUID 4921458 NITROCHLOROBENZENE. META, SOLID 415 115 106 105 416 3 15 15 15 40 78 120 124 124 124 280 137 145 234 205 205 270 205 206 322 215 271 270 270 290 290 291 336 335 336 336 270 347 342 342 356 362 342 365 366 365 365 366 366 259 369 259 371 370 4921459 NITROCHLOROBENZENE. PARA, SOLID (PARANITROCHLOROBENZENE) 4921460 NITROXYLOL 4921461 ORGANIC PHOSPHATE. ORGANIC PHOSPHATE COM- POUND. (OR) ORGANIC PHOSPHORUS COMPOUND. LIQUID 4921463 ORGANIC PHOSPHATE MIXTURE. ORGANIC PHOSPHATE COMPOUND MIXTURE, (OR) ORGANIC PHOSPHORUS COMPOUND MIXTURE. LIQUID 4921464 ORGANIC PHOSPHATE MIXTURE. ORGANIC PHOSPHATE COMPOUND MIXTURE, (OR) ORGANIC PHOSPHORUS MIX TURE. SOLID (OR) DRY 4921465 ORGANIC PHOSPHATE. ORGANIC PHOSPHATE COM- POUND, (OR) ORGANIC PHOSPHORUS COMPOUND MIX TURE. SOLID (OR) DRY 4921466 ORTHO NITRO ANILINE 4921467 PARANITROANILINE. SOLID 4921469 PARATHION, LIOUID 4921470 PARATHION MIXTURE, DRY 4921471 PARATHION MIXTURE, LIOUID 4921473 PERCHLOROMETHYL MERCAPTAN 4921474 PHENYLDICHLOROARSINE, LIQUID 4921475 POISONOUS LIQUID, N.O.S. 4921476 POISONOUS SOLID. N.O.S. 4921477 STRYCHNINE 4921478 STRYCHNINE SALT. SOLID 4921480 TETRAETHYL DITHIOPYROPHOSPHATE, LIQUID 4921481 TETRAETHYL DITHIOPYROPHOSPHATE MIXTURE. DRY 4921482 TETRAETHYL DITHIOPYROPHOSPHATE MIXTURE. LIQUID 4921484 TETFIAETHYL LEAD. LIQUID 4921486 TETRAETHYL PYROPHOSPHATE LIQUID 49214B7 TETRAETHYL PYROPHOSPHATE MIXTURE. DRY 4921488 TETRAETHYL PYROPHOSPHATE MIXTURE, LIQUID 4921490 POLYCHLOR AGRICULTURAL FUNGICIDES (POISONOUS SOLID. N.O.S ) 4921491 MEDICINES. N.O.S. (SOLID) 4921492 ANILINE OIL. LIQUID (ANILINE SLUDGE FOR FURNACE USE) 4921494 CHLORINATED PHENOL PETROLEUM SOLUTION (POISON- OUS LIQUID. N.O.S.) 4921496 DRUGS OR MEDICINES. N.O.S. (SOLID) 4921503 BENZIDINE 4921505 COUMAPHOS 4921506 COUMAPHOS MIXTURE. LIQUID (AGRICULTURAL INSEC- TIDES, NEC. LIQUID) 4921508 DISULFOTON MIXTUHE, DRY (AGRICULTURAL INSECTI- CIDES. NEC, OTHER THAN LIQUID) 4921509 DISULFOTON MIXTURE. LIOUID (AGRICULTURAL INSECTI- CIDES. NEC, LIQUID) 4921511 DISULFOTON (AGRICULTURAL INSECTICIDES. NEC, LIQUID) 4921512 OISULFOTON (AGRICULTURAL INSECTICIDES, NEC, OTHER THAN LIQUID) 4921513 DISULFOTON (INSECTICIDES, OTHER THAN AGRICUL- TURAL, NEC) 4921515 DICHLOROANILINE (POISONOUS SOLID. N.O.S.) 4921516 ENDOSULFAN (AGRICULTURAL INSECTICIDES. NEC. LIQUID) 4921517 ENDOSULFAN (AGRICULTURAL INSECTICIDES. NEC, OTHER THAN LIOUIO) 4921518 ENDOSULFAN (INSECTICIDES. OTHER THAN AGRICUL- TURAL. NEC) 4921519 ENDOSULFAN MIXTURE. LIOUID (AGRICULTURAL INSECTI- CIDES. NEC. LIQUID) 4921520 ENDRIN MIXTURE, LIQUID (AGRICULTURAL INSECTICIDE. NEC. LIQUID) 4921521 ENDRIN (AGRICULTURAL INSECTICIDES, NEC, LIQUID) 4921522 ENDRIN (AGRICULTURAL INSECTICIDES. NEC. OTHER THAN LIQUID) 4921523 ENDRIN (INSECTICIDES. OTHER THAN AGRICULTURAL. NEC) 4921524 CARBOFURAN MIXTURE. LK3U1D (AGRICULTURAL INSECTI- CIDES, NEC, LIOUID) 4921525 CARBOFURAN 4921526 AZINPHOS METHYL (OR) GUTHION (AGRICULTURAL INSEC- TICIDES, NEC, LIQUID) 4921527 AZINPHOS METHYL (OR) GUTHION (AGRICULTURAL INSEC- TICIDES. NEC, OTHER THAN LIQUID) 4921528 AZINPHOS METHYL (OR) GUTHION (INSECTICIDES, OTHER THAN AGRICULTURAL, NEC) 4921529 AZINPHOS METHYL MIXTURE. LIOUID (OR) GUTHION MIXTURE, LIQUID (AGRICULTURAL INSECTICIDES. NEC. LIQUID) 4921530 NITROANILINE 4921531 MEVINPHOS (AGRICULTURAL INSECTICIDES. NEC. LIQUID) 371 376 381 381 381 381 386 392 393 392 392 395 403 416 416 482 482 492 492 492 492 493 494 494 418 322 40 119 215 63 153 153 211 211 210 210 211 182 220 220 221 221 222 221 222 222 105 105 55 56 56 56 369 348 580 MOD 00 o 17508 4921532 MEVINPHOS (AGRICULTURAL INSECTICIDES. NEC. OTHER THAN LIQUID) 4921533 MEVINPHOS (INSECTICIDES, OTHER THAN AGRICULTURAL. NEC) 4921534 DICHLORVOS (AGRICULTURAL INSECTICIDES. NEC. LIQUID) 4921535 DICHLORVOS (AGRICULTURAL INSECTICIDES. NEC. OTHER THAN LIQUID) 4921536 DICHLORVOS (INSECTICIDES, OTHER THAN AGRICUL- TURAL NEC) 4921537 DICHLORVOS MIXTURE, DRY (AGRICULTURAL INSECTI- CIDES. NEC, OTHER THAN LIQUID) 4921538 MEVINPHOS MIXTURE. DRY (AGRICULTURAL INSECTI- CIDES. NEC, OTHER THAN LIQUID) 4921539 MEVINPHOS MIXTURE. UQUIO (AGRICULTURAL INSECT- CIDES. NEC. LIQUID) 4921540 MEXACARBATE (INSECTICIDES. OTHER THAN AGRICUL- TURAL NEC) 4921541 MEXACARBATE (AGRICULTURAL INSECTICIDES. NEC. LIQUID) 4921542 MEXACARBATE (AGRICULTURAL INSECTICIDES. NEC. OTHER THAN LIQUID) 4921550 DICHLOROETHYL ETHER (POISONOUS UQUID.N.O.S.) 4921565 ETHION (AGRICULTURAL INSECTICIDES. NEC. LIQUID) 4921566 ETHION (AGRICULTURAL INSECTICIDES. NEC. OTHER THAN LIQUID) 4921567 ETHION (INSECTICIDES. OTHER THAN AGRICULTURAL. NEC) 4921568 ETHION MIXTURE. DRY (AGRICULTURAL INSECTICIDES. NEC. OTHER THAN DRY LIQUID) 4921575 TOLUENE DIISOCYANATE 4921591 POISONED GRAIN (POISONOUS SOLID, N.O.S.) 4921608 BENZOIC DERIVITIVE PESTICIDE.LIQUID, N O S. (COUM- POUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AGRICULTURAL. NEC) 4921609 BENZOIC DERIVATIVE PESTICIDE, LIQUID. N O S. (COUMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSEC TICIDES. NEC. LIQUID) 4921610 BENZOIC DERIVATIVE PESTICIDE. SOLID. N.O.S. (COM- POUNDS AND PREPARATION (INSECTICIDES. NEC, OTHER THAN AGRICULTURAL) 4921611 BENZOIC DERIVATIVE PESTICIDE. SOLID, N.O.S. (COMPOUNDS AND PREPARATION (AGRICULTURAL INSECTI CIDES. NEC, OTHER THAN LIQUID) 4921615 BIPYR1DILIUM PESTICIDE,LIQUID, N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AGRICUL TURAL. NEC) 4921616 BIPYRIDILIUM PESTICIDE. LIQUID. N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES. NEC. LIQUID) 4921617 BIPYRIDILIUM PESTICIDE. SOLID. N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AGRICUL TURAL. NEC) 4921618 BIPYRIDILIUM PESTICIDE. SOLID. N.O S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES. NEC. OTHER THAN LIQUID) 4921624 CARBAMATE PESTICIDE, LIQUID. N O S. (COUMPOUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AG RICULTURAL, NEC) 4921625 CARBAMATE PESTICIDE, LIQUID, N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES. NEC. LIQUID) 4921626 CARBAMATE PESTICIDE. SOLID. N O S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AGRICUL TURAL. NEC) 4921627 CARBAMATE PESTICIDE. SOLID. N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES. NEC. OTHER THAN LIQUID) 4921631 DITHIOCARBAMATE PESTICIDE. LIQUID. N.O.S. (COMPOUNDS ANO PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL. NEC) 4921632 DITHIOCARBAMATE PESTICIDE, LIQUID, N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSEC TICIDES, NEC, LIQUID) 4921633 DITHIOCARBAMATE PESTICIDE. SOLID. N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL, NEC) 4921634 DITHIOCARBAMATE PESTICIDE. SOLID. N.O.S. (COM- POUNDS AND PREPARATIONS) (AGRICULTURAL INSEC TICIDES. NEC, OTHER THAN LIQUID) 4921651 MERCURY BASED PESTICIDE. LIQUID, N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AG RICULTURAL. NEC) 348 348 188 189 189 189 349 349 350 349 350 165 225 225 225 226 503 415 64 63 64 64 72 71 71 71 103 103 104 104 212 212 213 213 329 4921652 MERCURY BASED PESTICIDE, LIQUID. N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES. NEC. LIQUIO) 4921653 MERCURY BASED PESTICIDE. SOLID. N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AG RICULTURAL, NEC) 4921654 MERCURY BASED PESTICIDE. SOLID. N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES. NEC. OTHER THAN LIQUID) 4921661 SUBSTITUTED NITROPHENOL PESTICIDE. SOLID. N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL IN SECTICIDES. NEC. OTHER THAN LIQUID) 4921662 SUBSTITUTED NITROPHENOL PESTICIDE. SOLID. N.O.S (COMPOUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AGRICULTURAL. NEC) 4921663 TRIAZINE PESTICIDE, LIQUID, N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICUL TURAL. NEC) 4921664 TRIAZINE PESTICIDE. LIQUID. N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC. LIQUID) 4921665 TRIAZINE PESTICIDE. SOLID, N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AGRICUL TURAL NEC) 4921666 TRIAZINE PESTICIDE, SOLID, N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES. NEC. OTHER THAN LIQUID) 4921667 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID. N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL IN SECTICIDES. NEC. LIQUID) 4921668 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID. N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL. NEC) 4921670 ORGANOCHLORINE PESTICIDE. LIQUID, N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AGRICULTURAL. NEC) 4921671 ORGANOCHLORINE PESTICIDE. LIQUIO. N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSEC TICIDES. NEC. LIQUID) 4921672 ORGANOCHLORINE PESTICIDE. SOLID. N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL. NEC) 4921673 ORGANOCHLORINE PESTICIDE, SOLID. N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSEC TICIDES, NEC. OTHER THAN LIQUID) 4921674 ORGANOPHOSPHORUS PESTICIDE. LIQUID, N.O.S. (COMPOUNDS AND PREPARATIONS (INSECTICIDES. OTHER THAN AGRICULTURAL NEC) 4921675 ORGANOPHOSPHORUS PESTICIDE. LIQUID. N.O.S. (COMPOUNDS AND PREPARATIONS (AGRICULTURAL INSEC TICIDES. NEC. LIQUIO) 4921676 ORGANOPHOSPHORUS PESTICIDE. SOLID, N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL, NEC) 4921677 ORGANOPHOSPHORUS PESTICIDE, SOLID. N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSEC TICIDES. NEC, OTHER THAN LIQUID) 4921678 ORGANOTIN PESTICIDE, LIQUID. N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AGRICUL TURAL NEC) 4921679 ORGANOTIN PESTICIDE. LIQUID. N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC. LIQUID) 4921680 OHGANOTIN PESTICIDE. SOLID. N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AGRICUL TURAL. NEC) 4921681 ORGANOTIN PESTICIDE. SOLID. N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES. NEC. OTHER THAN UQUID) 4921683 PHENOXY PESTICIDE, LIQUID. N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AGRICUL TURAL NEC) 4921684 PHENYLUREA PESTICIDE. LIQUID, N.O.S. (COMPOUNDS ANO PREPARATIONS) (INSECTICIDES. OTHER THAN AG RICULTURAL, NEC) 4921685 PHENYLUREA PESTICIDE, LIQUID. N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES. NEC. LIQUID) 330 330 331 484 484 506 506 507 507 483 483 382 382 383 383 383 384 385 384 3B5 385 386 386 401 403 403 581 MCD G0001750S 4921686 PHENYLUREA PESTICIDE, SOLID,N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICUL TURAL, NEC) 4921687 PHENYLUREA PESTICIDE. SOLID. N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES. NEC, OTHER THAN LIQUID) 4921688 PHTHALIMIDE DERIVATIVE PESTICIDE. LIQUID, N.O.S. (COM POUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AGRICULTURAL, NEC) 4921689 PHTHALIMIDE DERIVATIVE PESTICIDE. LIQUID, N.O.S. (COM POUNDS AND PREPARATIONS) (AGRICULTURAL INSEC TICIDES, NEC, LIQUID) 4921690 PHTHALIMIDE DERIVATIVE PESTICIDE, SOLID, N.O.S. (COM POUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL. NEC) 4921691 PHTHALIMIDE DERIVATIVE PESTICIDE. SOLID. N.O.S. (COM POUNDS AND PREPARATIONS) (AGRICULTURAL INSEC TICIDES, NEC, OTHER THAN LIQUID) 4921692 PHENOXY PESTICIDE, LIQUID. N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC, LIQUID) 4921693 PHENOXY PESTICIDE, SOLID, N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICUL TURAL, NEC) 4921694 PHENOXY PESTICIDE. SOLID. N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC, OTHER THAN LIQUID) 4923105 ARSENIC ACID SOLUTION (ARSENIC AClO OTHER THAN FUSED) 4923106 ARSENIC AClO, SOHO (ARSENIC ACID FUSED) 4923112 ARSENIC PENTOXIDE, SOLID 4923115 ARSENIC TRIOXIDE, SOLID (ARSENIC. WHITE, SOLID AR SENOUS ACID, SOLID) 4923201 AMMONIUM ARSENATE. SOLID 4923202 ARSENIC BROMIDE. SOLID 4923203 ARSENIC CHLORIDE. LIQUID 4923204 ARSENIC. CRUDE (POISONOUS SOLID, N.O.S.) 492320S ARSENIC IODIOE, SOLID 4923207 ARSENIC, SOLID (ARSENIC METALLIC) 4923206 ARSENIC SULFIDE. SOLID 4923209 ARSENIC TRICHLORIDE 4923210 ARSENICAL COMPOUND, N.O.S. (OR) ARSENICAL MIXTURE, N.O.S. LIQUID 4923211 ARSENICAL COMPOUND, N O S., SOLID, (OR) ARSENICAL MIXTURE, N.O.S. SOLID 4923212 ARSENICAL 0IP. LIQUID (SHEEP DIP) 4923213 ARSENICAL DUST 4923215 ARSENOUS AND MERCURIC IODIDE SOLUTION 4923216 BERYLLIUM COMPOUND. N.O.S. 4923217 CALCIUM ARSENATE. SOLID 4923218 CALCIUM ARSENATE AND SULPHUR, DRY (CALCIUM ARSENATE) 4923219 CALCIUMARSENITE. SOLID 4923220 COPPER ACETOARSENITE, SOLID 4923221 COPPER ARSENITE. SOLID 4923222 ARSENIC TRISUIFIDE 4923223 CALCIUM CYANIDE, SOLID (OR) CALCIUM CYANIDE MIX TURE. SOLID 4923224 CYANIDE OR CYANIDE MIXTURE. DRY 4923225 POTASSIUM CYANIDE SOLUTION 4923226 POTASSIUM CYANIDE. SOLID 4923227 SODIUM CYANIDE SOLUTION 4923228 SOOIUM CYANIDE, SOLID 4923229 CYANOGEN BROMIDE 4923230 CYANIDE SOLUTION. N.O.S. 4923231 FERRIC ARSENATE. SOLID 4923232 FERRIC ARSENITE. SOLID 4923233 FERROUS ARSENATE, SOUD 4923234 LEAD ARSENATE. SOLID (LEAD ARSENATE, PASTE) 4923235 LEAD ARSENATE. SOLID 4923236 LEAD ARSENITE, SOLID 4923237 LONDON PURPLE. SOLID 4923238 MAGNESIUM ARSENATE, SOUD 4923241 MERCURIC ACETATE 4923242 MERCURIC-AMMONIUM CHLORIDE. SOUD 4923243 MERCURIC BENZOATE. SOLID 4923244 MERCURIC BROMIDE, SOLID 4923245 MERCURIC CHLORIDE 4923246 MERCURIC CYANIDE, SOLID 4923247 MERCURIC IODIDE. SOLID 404 404 410 410 411 411 401 402 402 48 48 49 50 24 48 49 51 49 51 49 50 51 51 51 52 53 69 96 96 101 146 147 50 98 158 421 421 465 465 156 156 243 243 246 307 307 307 317 319 324 327 324 324 324 325 325 582 4923249 MERCURIC IODIDE, SOLUTION 4923250 MERCURIC OLEATE. SOLID 4923251 MERCURIC OXIDE. SOLID 4923253 MERCURIC OXYCYANIDE. SOUD (DESENSITIZED) 4923254 MERCURIC-POTASSIUM CYANIDE. SOUD 4923255 MERCURIC SALICYLATE, SOLID 4923256 MERCURIC SUBSULFATE. SOLID 4923257 MERCURIC SULFATE. SOLID 4923258 MERCURIC SULFO CYANATE, SOLID (OR) MERCURIC THIOCYANATE 4923259 MERCUROL OR MERCURY NUCLEATE. SOLID 4923260 MERCUROUS BROMIDE, SOLID 4923261 MERCUROUS GLUCONATE. SOLID 4923262 MERCUROUS IODIDE. SOLID 4923264 MERCUROUS OXIDE. BLACK. SOLID 4923265 MERCUROUS SULFATE, SOLID 4923266 MERCUROUS ACETATE. SOUD 4923269 MERCURY COMPOUND. SOLID, N.O.S 4923271 MERCURIC CHLORIDE (MERCURIC CHLORIDE AND CHAR- COAL CATALYST. SPENT) 4923272 MERCURIC-POTASSIUM IODIDE, SOLID 4923275 NICKEL CYANIDE. SOLID 4923277 POTASSIUM ARSENATE. SOLID 4923278 POTASSIUM ARSENITE. SOLID 4923290 SODIUM ARSENATE. SOLID 4923291 SODIUM ARSENITE, LIQUID, (SOLUTION) 4923293 SULPHUR, ZINC SULPHATE AND LEAD ARSENATE (LEAD ARSENATE, SOLID) 4923294 STRONTIUM ARSENITE. SOUD 4923296 THALLIUM SALT, SOLID. N.O.S. 4923297 THALLIUM SULFATE. SOUD 4923298 THIOPHOSGENE 4923301 ARSENICAL PESTICIDE. LIQUID. N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES. NEC, LIQUID) 4923302 ARSENICAL PESTICIDE, SOUD. N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES. NEC, OTHERTHAN LIQUID) 4923303 ARSENICAL PESTICIDE, LIQUID, N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AGRICUL TURAL NEC) 4923304 ARSENICAL PESTICIDE. SOLID, N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AGRICU- TURAL NEC) 4923305 BERYLLIUM CHLORIDE 4923310 BERYLLIUM FLUORIDE 4923315 BERYLLIUM HYDROXIDE (BERYLLIUM COMPOUND. N.O.S.) 4923318 LEAD ARSENATE AND SULPHUR. DRY (LEAD ARSENATE. SOLID) 4923325 BERYLLIUM PHOSPHATE (BERYLLIUM COMPOUND. N.O.S.) 4923330 BERYLLIUM SULFATE (BERYLLIUM COMPOUND, N.O.S ) 4923331 COPPER BASED PESTICIOE. LIOUIO. N O S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AG RICULTURAL, NEC) 4923332 COPPER BASED PESTICIDE. LIQUID. N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIOES. NEC. LIQUID) 4923333 COPPER BASED PESTICIDE. SOLID. N.O.S. (COMPOUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AG RICULTURAL, NEC) 4923334 COPPER BASED PESTICIDE. SOLID, N.O.S. (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC. OTHER THAN LIQUID) 4923340 SELENIUM OXIDE 4923345 SELENIUM OXYCHLORIDE (POISONOUS SOUD. N.O.S.) 4923350 SOOIUM SELENITE 4923360 LEAD FLUE OUST (FLUE DUST. POISONOUS) 4923361 LEAD BAGHOUSE FLUE DUST (FLUE DUST. POISONOUS) 4923370 CHEMICAL PLANT WASTE. NEC (POISONOUS LIQUID. N.O.S.) 4923390 COMPOUNDS METAL PURIFYING. NEC (POISONOUS SOLID, N.O.S,) 4923391 COMPOUNDS. CASE CARBURIZING OR HARDENING, NEC (POISONOUS SOLID. N.O.S.) 4923392 COMPOUNDS, CASE HARDENING OR CARBURIZING. CHARCOAL, COAL. OR COKE BASE (POISONOUS SOLID. N.O.S.) 4923396 ARSENICAL ORE, CRUOE (POISONOUS SOLID. N.O.S.) 4923410 BARIUM CYANIDE. SOUD 4923415 BORDEAUX ARSENITE. SOLID 4923418 COPPER CYANIDE 4923420 BORDEAU ARSENITE. LIQUID 325 326 326 326 327 326 326 327 327 328 328 328 328 329 329 328 331 324 328 363 419 420 462 462 488 481 497 497 496 52 53 52 53 6a 69 69 306 70 70 147 147 148 148 456 456 475 308 307 116 143 143 143 52 57 74 149 73 4923447 LEAD CYANIDE 492346S SODIUM AZIDE 4923473 SILVER CYANIDE 4923475 SOLUTION, COPPER PLATING (POISONOUS LIQUID. N.O.S.) 4923478 NICKEL PLATING SOLUTION (POISONOUS LIQUID. N.O.S.) 4923490 ZINC ARSENATE 4923492 ZINC ARSENITE. SOLID 4923495 ZINC CYANIDE 4923496 ZINC PHOSPHIDE 4923905 ANIMAL OR POULTRY DIP, NEC. LIQUID (POISONOUS HQ- UID, N.O.S.) 4923906 ANIMAL OR POULTRY DIP, NEC, OTHER THAN LIQUID (POI- SONOUS SOLID. N.O.S.) 4923910 DISINFECTANT, LIQUID 4923911 DISINFECTANT. SOLID 4923915 CHEMICAL AMMUNITION, NONEXPLOSIVE (CONTAINING A POISON B MATERIAL) 4925110 TEAR GAS CANDLE 4925120 TEAR GAS GRENADE 4926132 TEAR GAS SOLUTIONS (IRRITATING AGENT. N.O.S.) 4925210 BROMBENZYL CYANIDE. LIQUID (IRRITATING AGENT. N.O.S.) 4925220 CHLOROACETOPHENONE, GAS, LIQUID OR SOLID 4925230 DIPHENYLAMINECHLOROARSINE 4925240 DIPHENYLCHLORARSINE (IRRITATING AGENT. N.O.S.) 4925250 MONOCHLOROACETONE. STABILIZED OR INHIBITED 4925260 XYLYL BROMIDE 4925830 IRRITATING AGENT. N.O.S. 4925835 GAS IDENTIFICATION SET 4925840 CHEMICAL AMMUNITION, NONEXPLOSIVE (CONTAINING AN IRRITATING MATERIAL) 4925999 ETIOLOGIC AGENT, N.O.S. (OR) INFECTIOUS SUBSTANCE. HUMAN. N.O.S. 4926185 URANIUM METAL BILLETS. INGOTS. PIGS OR SLABS NOT IRRADIATED NOR REQUIRING PROTECTIVE SHIELDING (URANIUM METAL. PYROFORIC) 4926186 URANIUM METAL BARS. RODS OR SHAPES. NOT IRRADIATED. NOR REQUIRING PROT SHIELDING (URANIUM METAL PYROFORIC) 4926187 URANIUM METAL SCRAP NOT IRRADIATED NOR REQUIRING PROTECTIVE SHIELDING (URANIUM METAL PYROFORIC) 4926188 THORIUM METAL BILLETS. INGOTS. PIGS OR SLABS, NOT IRRADIATED. NOR REQUIRING PROTECTIVE SHIELDING (THORIUM METAL. PYROFORIC) 4926310 THORIUM NITRATE, SOLID 4926320 URANYL NITRATE. SOLID 4926325 URANYL NITRATE HEXAHYDRATE SOLUTION 4926420 RADIOACTIVE ARTICLES. NEC (RADIOACTIVE DEVICE, N.O.S ) 4926425 URANYL ACETATE 4926430 RADIOACTIVE MATERIAL. LOW SPECIFIC ACTIVITY (OR) LSA-, N.O.S. (RADIOACTIVE MATERIALS. ARTICLES OR ISOTOPES, NEC) 4926435 PLUTONIUM NITRATE SOLUTION 4926437 URANIUM BEARING ORE (RADIOACTIVE MATERIAL LOW SPECIFIC ACTIVITY (OR) LSA, N.O.S.) 4926438 LIGNITE ASH. URANIUM BEARING (RAOIOACTIVE MATERIAL. LOW SPECIFIC ACTIVITY. (OR), LSA. N.O.S.) 4926439 THORIUM ORE (MONAZITE SAND) (RADIOACTIVE MATERIAL. LOW SPECIFIC ACTIVITY. (OR), LSA. N.O.S.) 4926440 RADIOACTIVE MATERIAL. N.O.S. 4926441 RADIOACTIVE ISOTOPES. NEC (RADIOACTIVE MATERIALS. N.O.S.) 4926443 THORIUM METAL BARS RODS. OR SHAPES. NOT IRRADIATED NOR REQUIRING PROTECTIVE SHIELDING (RADIO ACTIVE MATERIAL, N.O.S.) 4926445 CORES OR CORE ASSEMBLIES OR FUEL BLANKET ASSEM- BLIES. NUCLEAR REACTOR, NOT IRRADIATED. WITH NONIRRADIATED FUEL, (RADIOACTIVE MATERIAL, N.O.S.) 4926446 THORIUM METAL SCRAP. NOT IRRADIATED NOR REOUIR- ING PROTECTIVE SHIELDING (RADIOACTIVE MATERIAL N.O.S.) 4926447 THORIUM OXIDE (RADIOACTIVE MATERIAL N.O.S.) 4926450 RADIOACTIVE MATERIAL SPECIAL FORM, N.O.S. 4926460 RADIOACTIVE MATERIAL, LIMITED QUANTITY, N.O.S. (RA- DIOACTIVE ARTICLES OR ISOTOPES, NEC) 4926467 RADIOACTIVE MATERIAL SHIPPING CONTAINERS. STEEL AND URANIUM METAL EMPTY (RADIOACTIVE MATERIAL,N.O.S.) 4926470 RADIOACTIVE WASTE MATERIAL. HAVING NO RECLAMATION VALUE REQUIRING PROTECTIVE SHIELDING (RA- DIOACTIVE MATERIAL N.O.S.) 308 462 458 477 364 537 537 539 541 40 41 209 210 115 491 491 491 76 120 208 208 352 536 294 262 115 239 518 518 518 499 499 520 519 438 519 440 415 516 312 499 441 440 498 150 499 500 442 440 440 443 4926480 WATCH DIAL ENAMEL (RADIOACTIVE MATERIAL, N O S.) 530 4926488 METAL ALLOY BILLETS. BLOOMS. INGOTS. PIGS, SPONGE 331 OR SHOT, NEC. NOT IRRADIATED NOR REQUIRING PRO TECTIVE SHIELDING (RADIOACTIVE MATERIAL. N.O.S.) 4926489 METAL OR METAL ALLOY BILLETS. BLOOMS. INGOTS, PIGS, 332 SPONGE, OR SHOT. NOT IRRIDATED NOR REQUIRING PROTECTIVE SHIELDING (RADIOACTIVE MATERIAL. LOW SPECIFIC ACTIVITY OR LSA. N.O.S.) 4926490 URANIUM HEXAFLUORIDE. LOW SPECIFIC ACTIVITY (CON- 517 TAINING 0.7% OR LESS U-235) (URANIUM FLUORIDES NOT IRRADIATED NOR REQUIRING PROTECTIVE SHIELDING) 4926491 URANIUM OXIDES, NOT IRRADIATED NOR REQUIRING PRO- 519 TECTIVE SHIELDING (RADIOACTIVE MATERIAL, N.O.S.) 4926492 URANIUM SALTS, NOT IRRADIATED NOR REQUIRING PRO- 519 TECTIVE SHIELDING (RADIOACTIVE MATERIAL, N.O.S.) 4926493 URANATES NOT IRRADIATED NOR REQUIRING PROTECTIVE 516 SHIELDING (RADIOACTIVE MATERIAL. N.O.S.) 4927320 URANYL N(TRATE. SOLID FISSILE CLASS III 521 4927416 NUCLEAR FUEL ELEMENTS. PARTS OR CONSTITUENTS IR- 376 RADIATED REQUIRING PROTECTIVE SHIELDING (RADIO ACTIVE MATERIAL. N.O.S., FISSILE CLASS III) 4927420 RADIOACTIVE ARTICLES. NEC (RADIOACTIVE DEVICE. N.O S 439 FISSILE CLASS III) 4927440 RADIOACTIVE MATERIAL. N.O.S. FISSILE CLASS 111 4927450 RADIOACTIVE MATERIAL. SPECIAL FORM, N.O.S.. FISSILE CLASS III 441 443 4927470 RADIOACTIVE WASTE MATERIAL. HAVING NO RECLAMA- 443 TION VALUE. REQUIRING PROTECTIVE SHIELDING (RA DIOACTIVE MATERIAL. N.O.S.. FISSILE CLASS III) 4927480 WATCH DIAL ENAMEL (RADIOACTIVE MATERIAL, N.O.S. FIS- 529 SILE CLASS III) 4927490 URANIUM HEXAFLUORIDE, FISSILE CLASS III (CONTAINING 517 MORE THAN 0.7% U-235) (URANIUM FLUORIDES. NOT IR RADIATED NOR REQUIRING PROTECTIVE SHIELDING) 4928320 URANYL NITRATE, SOLID FISSILE CLASS II 521 4928415 NUCLEAR FUEL ELEMENTS. PARTS OR CONSTITUENTS, IR- 377 RADIATED REQUIRING PROTECTIVE SHIELDING (RADIO ACTIVE MATERIAL, N.O.S. FISSILE CLASS II) 4928420 RADIOACTIVE ARTICLES. NEC (RADIOACTIVE DEVICE. N.O.S.. 437 FISSILE CLASS II) 4928440 RAOIOACTIVE MATERIAL. N.O.S. FISSILE CLASS II 4928450 RADIOACTIVE MATERIAL. SPECIAL FORM. N.O.S.. FISSILE CLASS II 441 442 4928470 RADIOACTIVE WASTE MATERIAL. HAVING NO RECLAMA- 444 TION VALUE. REQUIRING PROTECTIVE SHIELDING (RA DIOACTIVE MATERIAL. N.O.S.. FISSILE CLASS II) 4928480 WATCH DIAL ENAMEL (RADIOACTIVE MATERIAL. N.O.S., FIS- 530 SILE CLASS II) 4928490 URANIUM HEXAFLUORIDE. FISSILE CLASS II (CONTAINING 517 MORE THAN 0.7% U-235) (URANIUM FLUORIDES, NOT IR RADIATED NOR REQUIRING PROTECTIVE SHIELDING) 4926320 URANYL NITRATE. SOLID FISSILE CLASS I 520 4929415 NUCLEAR FUEL ELEMENTS, PARTS OR CONSTITUENTS IR- 377 RADIATED. REQUIRING PROTECTIVE SHIELDING (RADIO ACTIVE MATERIAL. N.O.S.. FISSILE CLASS I) SHIELDING) 4929420 RADIOACTIVE DEVICE. N.O.S.. FISSILE CLASS I (RADIOAC- 439 TIVE ARTICLES. NEC) 4929440 RADIOACTIVE MATERIAL. N.O.S. FISSILE CLASS I 441 4929450 RADIOACTIVE MATERIAL. SPECIAL FORM. N.O.S.. FISSILE 442 CLASS I 4929470 RADIOACTIVE WASTE MATERIAL. HAVING NO RECLAMA- 444 TION VALUE. REQUIRING PROTECTIVE SHIELDING (RA DIOACTIVE MATERIAL. N.O.S., FISSILE CLASS () 4929480 WATCH DIAL ENAMEL (RADIOACTIVE MATERIAL. N.O.S.. FIS- 529 SILE CLASS I) 4929490 URANIUM HEXAFLUORIDE FISSILE CLASS I (CONTAINING 516 MORE THAN 0.7% U-235) (URANIUM FLUORIDES, NOT IR RADIATED NOR REQUIRING PROTECTIVE SHIELDING) 4930005 ETCHING ACID, LIQUID, N.O.S. 224 4930010 FLUOSULFONIC ACID (OR) FLUOROSULFONICACID 254 4930015 HEXAFLUOROPHOSPHORIC ACID 271 4930020 HYDROFLUORIC AND SULFURIC ACID MIXTURES 261 4930022 HYDROFLUORIC ACID SOLUTION 280 4930024 HYDROFLUORIC ACID. ANHYDROUS (OR)HYDROGEN 280 FLUORIDE 4930026 HYDROFLUOSILiCIC. ACID 4930030 OLEUM (SULFURIC ACID FUMING) 281 379 4930035 SELENIC ACID, LIQUID 455 4930040 SULFURIC ACID 487 00x7 583 4930042 SULFURIC ACID, SPENT 487 4931434 HEXANOIC ACID 274 4930050 SULFUR TRIOXIDE. STABILIZED 4930051 SULFUR TRIOXIDE (SULFUR TRIOXIDE, UNSTABILIZED) 487 4931438 ISOBUTYRIC ACIO 486 *931439 ISOBUTYRIC ANHYDRIDE 296 297 4930060 THIONYL CHLORIDE 498 4931440 ISOPENTANOIC ACID 299 4930201 ACIDS, INORGANIC. NEC, LIQUID (ACIDS, LIQUID, N.O.S.) 7 4931441 MEMTETRAHYDROPHTHALIC ANHYDRIDE 323 4930202 BORON TRIFLUORIDE-ACETIC ACID COMPLEX 75 4931442 MINING REAGENT. LIQUID (CONTAINING 20% OR MORE 351 4930203 CHROMYL CHLORIDE (OR) CHROMIUM OXYCHLORIDE 129 CRESYLIC ACID) 4930204 CHLOROSULFONIC ACID 125 4931444 MONOCHLOROACETIC ACID. LIQUID 352 4930205 CHLOROSUNFONIC ACID-SULFUR TRIOXIDE MIXTURE 125 4931447 PROPIONIC ACID SOLUTION 429 4930206 CHROMIC ACID SOLUTION 128 4930209 COMPOUND. CLEANING, LIQUID (CONTAINING HYDRO 139 4931448 PROPIONIC ACID 4931449 PROPIONIC ANHYDRIDE 429 430 CHLORIC (MURIATIC) ACID) 4931455 2,2-DICHLOROPROPIONIC ACID 188 4930210 COMPOUND. CLEANING, LIQUID (CONTAINING HYDRO 139 4931460 THIOGLYCOLIC ACID 497 FLUORIC ACID) 4931465 TOLUENESULFONIC ACID. LIQUID 503 4930212 ACIDS. INORGANIC. NEC. DRY (CORROSIVE SOLID, N.O.S.) 7 4931470 TRICHLOROACETIC ACID. SOLID 506 4930214 DIFLUOROPHOSPHORIC ACID, ANYDROUS 194 4931471 TRICHLOROACETIC ACID SOLUTION 508 4930216 ELECTROLYTE (ACID) BATTERY, FLUID 218 4931475 VALERIC ACID 522 4930217 ELECTROLYTE (ACID) PACKED WITH DRY STORAGE 219 4931705 ACETYL BROMIDE 4 BATTERY 4931707 ACETYL IODIDE 4 4930219 FIRE EXTINGUISHER CHARGES CONTAINING SULFURIC 249 4931710 ANISOYL CHLORIDE 41 ACID 4931715 BENZENE PHOSPHORUS DICHLORIDE 62 4930221 WASTE LIQUOR, CONSISTING OF NOT LESS THAN 50 PER 529 4931720 BENZENE PHOSPHORUS THIODICHLORIDE 62 CENT BY WEIGHT OF WATER, RESULTING FROM SUL 4931725 BENZOYL CHLORIDE 65 PHATE OR SODA PULPING PROCESS (CORROSIVE LIQ 4931735 DICHLOROACETYL CHLORIDE 182 UID, N.O.S.) 4931740 FUMARYL CHLORIDE 258 4930222 FLUOBORIC ACID 4930226 HYDRIODIC ACID 253 4931745 TRIMETHYLACETYL CHLORIDE 276 4931750 VALERYL CHLORIDE 512 522 4930227 HYDROBROMIC ACID (MORE THAN 49% STRENGTH) 276 4931757 LACTIC ACID (HYOROXYPROPIONIC ACIO) (ACID. LIQUID, 305 4930226 HYDROCHLORIC ACID 4930229 HYDROCHLORIC ACID MIXTURE 278 N.O.S.) 278 4932005 ANTIMONY PENTAFLUORIDE 43 4930230 HYDROCHLORIC ACID SOLUTION. INHIBITED 278 4932010 BORON TRIBROMIDE 74 4930231 HYDROCHLORIC ACID (MURIATIC ACID, SPENT) 278 4932011 BORON TRICHLORIDE 74 4930232 HYDROBROMIC ACID. NOT MORE THAN 49% STRENGTH 277 4932301 ALUMINUM BROMIDE. ANHYDROUS. SOLID 19 4930237 LEAD SULFATE, SOLID (CONTAINING MORE THAN 3% FREE 310 4932302 ALUMINUM CHLORIDE. DRY (CORROSIVESOLID, N.O.S.) 19 ACID) 4932303 AMMONIUM HYDROGEN FLUORIDE. SOLID 27 4930240 MONOFLUOROPHOSPHORIC ACID, ANHYDROUS 354 4932304 ALUMINUM PHOSPHATE SOLUTION 20 4930242 NITRIC ACID. 40% OR LESS 368 4932305 ANTIMONY TRIFLUORIDE SOLUTION 45 4930243 NITROHYDROCHLORIC ACID 373 4932307 AMMONIUM HYDROGEN FLUORIDE SOLUTION 27 4930244 NITROHYDROCHLORIC ACID, DILUTED 374 4932310 ANTIMONY PENTACHLOR1DE 42 4930247 PHOSPHATIC FERTILIZER SOLUTION (PHOSPHORIC ACID) 405 4932312 ANTIMONY PENTACHLORIDE SOLUTION 43 4930246 PHOSPHORIC ACID (LIOUIO) OR PHOSPHORIC ACID 405 4932316 ANTIMONY TRICHLORIDE, SOLID 45 SOLUTION 4932317 ANTIMONY TRIBROMIDE, SOLUTION 44 4930249 WASTE PHOSPHATE FILTER CAKE SLUDGE, CONTAINING 529 4932318 ANTIMONY TRICHLORIDE SOLUTION 44 NOT MORE THAN 50% P205 (PHOSPHORIC ACID) 4932319 ANTIMONY TRIBROMIDE, SOLIO 44 4930250 PYROSULFUHYL CHLORIDE 436 4932323 PHOSPHORUS PENTACHLORIDE, SOLID 407 4930252 SLUDGE. ACID, CONTAINING NOT LESS THAN 75% WATER 459 4932324 PHOSPHORIC ANHYDRIDE 406 (SLUDGE ACID) 4932329 FERROUS CHLORIDE. SOLUTION 246 4930253 SLUDGE ACID 458 4932331 CALCIUM HYDROGEN SULFITE SOLUTION (CALCIUM 98 4930254 NITRATING ACID. SPENT 367 BISULPHITE) 4930256 SULFUROUS ACID 488 4932332 CHLORINATED LIME, LIQUID (CORROSIVE LIQUID, N.O.S.) 118 4930260 SULFURYL CHLORIDE 488 4932335 ANTIMONY TRIFLUORIDE. SOLID 46 4930264 THIOPHOSPHORYL CHLORIDE 498 4932338 CHROME CHLORIDE SOLUTION (CORROSIVE LIQUID, N.O.S.) 127 4930265 TITANIUM SULFATE SOLUTION (CONTAINING NOT MORE 501 4932339 CHROMIC FLUORIDE. SOLID 128 THAN 45% SULFURIC ACID) 4932340 CHROMIC FLUORIDE SOLUTION 128 4930270 WHITE ACID (AMMONIUM BIFLUORIDE AND HYDROCHLORIC 531 4932342 FERRIC CHLORIDE SOLUTION (IRON CHLORIDE. CRUDE. 244 ACID MIXTURE) LIQUID NOT LESS THAN 50% WATER) 4930275 SOLUTION, COPPER PLATING (CORROSIVE LIQUID, N.O.S.) 477 4932343 FERRIC CHLORIDE SOLUTION (IRON CHLORIDE (IRON MU- 244 4930278 NICKEL PLATING SOLUTION (CORROSIVE LIQUID. N.O.S.) 364 RIATE). OTHER THAN CRUDE, LIQUID) 4931210 CHLOROACETYL CHLORIDE 120 4932345 IODINE MONOCHLORIDE 292 4931303 ACETIC ACID, GLACIAL 2 4932348 AMMONIUM BISULFITE SOLUTION 25 4931304 ACETIC ANHYDRIDE 2 4932350 PHOSPHORUS OXYBROMIDE 406 4931320 FORMIC ACID 256 4932352 PHOSPHORUS OXYCHLORIDE 406 4931401 ACETIC ACIO (AQUEOUS SOLUTION) 2 4932355 SODIUM BIFLUORIDE SOLID 463 4931402 METHACRYLIC ACID. GLACIAL (CORROSIVE LIQUID. N.O.S.) 332 4932356 SODIUM BIFLUORIDE SOLUTION 463 4931403 ACID. NEC, DRY, ORGANIC (CORROSIVE SOLID, N.O.S.) 4931404 ACIDS. LIQUID. N.O-S. (ACIDS. NEC. LIQUID. ORGANIC) 6 4932356 PHOSPHORUS TRIBROMIDE 7 4932359 PHOSPHORUS TRICHLORIDE 408 408 4931405 ACRYLIC ACID 8 4932363 POTASSIUM FLUORIDE SOLUTION 422 4931406 ALKANESULFONIC ACID 17 4932365 POTASSIUM HYDROGEN FLUORIDE SOLUTION 422 4931410 BROMOACETIC ACID. SOLID 77 4932370 SILICON CHLORIDE (OR) SILICON TETRACHLORIDE 457 4931411 BROMOACETIC ACID SOLUTION 77 4932375 SODIUM FLUORIDE SOLUTION 466 4931412 COAL TAR OIL, CRUDE. NEC (CORROSIVE LIQUID. N.O.S.) 135 4932376 SODIUM BISULFITE SOLUTION 463 4931413 COAL TAR OIL, CRUDE. NEC (CORROSIVE SOLID. N.O.S.) 135 4932377 SODIUM HYDROGEN SULFATE SOLUTION 487 4931414 BUTYRIC ACID 95 4932378 SODIUM HYPOCHLORITE SOLUTION (HYPOCHLORITESO- 470 4931416 CHLOROACETIC ACID, SOLID 120 LUTION (CONTAINING MORETHAN 7% AVAILABLE CHLOR 4931417 CRESOL 154 INE BY WEIGHT) 4931418 CROTONICACID 154 4932379 SULFUR CHLORIDE (Dl) 485 4931420 DICHLOROACETIC ACID 182 4932380 SULFUR CHLORIDE (MONO) 486 4931422 DI(2-ETHYLHEXYL) PHOSPHORIC ACID 167 4932381 ZINC CHLORIDE CHEMICAL PLANT WASTE (CORROSIVE 538 4931426 DODECYLBENZENESULFONIC ACID 4931431 FORMIC ACID SOLUTION 214 LIQUID. N.O.S.) 256 4932383 TIN TETRACHLORIDE, ANHYDROUS 500 584 4932384 TINNING FLUX 493230S TITANIUM TETRACHLORIDE 4932387 TUNGSTEN HEXAFLOURIDE 4932388 VANADIUM OXYTRICHLORIDE 4932389 VANADIUM OXYTRICHLORIDE AND TITANIUM TETRACHLO RIDE MIXTURE 4932390 VANADIUM TETRACHLORIDE 4932393 ZINC CHLORIDE SOLUTION 4932395 ZIRCONIUM TETRACHLORIDE, SOLID 4933010 BENZYL CHLOROFORMATE 4933015 HEXACHLOROCYCLOPENTADIENE 4933315 N-BUTYL ACID PHOSPHATE 4933319 DIMETHYL CHLOROTHIOPHOSPHATE 4933320 DIETHYL SULFATE (CORROSIVE LIQUID. N.O.S.) 4933321 SULFATES, MIXED ETHYL. CONSISTING OF MONOETHYL AND DIETHYL SULFATE. (CORROSIVE LIQUID, N.O.S.) 4933322 DIMETHYL SULFATE 4933325 DIISOOCTYL ACID PHOSPHATE 4933327 ETHYL CHLOROTHIOFORMATE 4933332 ETHYL PHOSPHONOUS OICHLORIDE, ANHYDROUS 4933333 ETHYL PHOSPHORODICHLORIDATE 4933335 ISOPROPYL ACID PHOSPHATE, SOLID 4933336 METHYL PHOSPHONOTHIOIC DICHLORIDE, ANHYDROUS 4933337 METHYL PHOSPHONOUS DICHLORIDE 4933350 METHYL DICHLOROACETATE 4933355 ETHYL PHOSPHONOTHIOIC DICHLORIDE, ANHYDROUS 4933360 AMYL ACID PHOSPHATE 4934205 ALLYLTRICHLOROSILANE 4934210 AMYL TRICHLOROSILANE 4934215 BUTYL TRICHLOROSILANE 4934217 CYCLOHEXENYL TRICHLOROSILANE 4934218 CYCLOHEXYL TRICHLOROSILANE 4934220 CHLOROPHENYL TRICHLOROSILANE 4934225 DICHLOROPHENYL TRICHLOROSILANE 4934235 DIPHENYL DICHLOROSILANE 4934240 DODECYL TRICHLOROSILANE 4934245 ETHYL PHENYL DICHLOROSILANE 4934250 HEXADECYL TRICHLOROSILANE 4934255 HEXYL TRICHLOROSILANE 4934260 NONYL TRICHLOROSILANE 4934265 OCTADECYL TRICHLOROSILANE 4934270 OCTYL TRICHLOROSILANE 4934275 PHENYL TRICHLOROSILANE 4934280 PROPYL TRICHLOROSILANE 4935030 HYDRAZINE. AQUEOUS SOLUTION 4935204 SLUDGLALKALAI, CONTAINING NOT LESS THAN 75% WATER (CORROSIVE LIQUID. N.O.S.) 4935206 CAUSTIC SODA SOLUTION SPENT (SODIUM HYDROXIDE SOLUTION) 4935210 ALKALINE CORROSIVE BATTERY FLUID 4935215 ALKALINE CORROSIVE BATTERY FLUID WITH EMPTY STOR AGE BATTERY 4935220 ALKALINE CORROSIVE LIQUID. N.O.S. 4935223 FATTY ALCOHOLS, ALIPHATIC OR CYCLIC, CYANOETHY- LATED AND HYDROGENATED, AND DERIVATIVES THEREOF SUCH AS SALTS DIAMINES, OXYALKYLATES AND 4935225 POTASSIUM HYDROXIDE. DRY. SOLID, FLAKE. BEAD. OR GRANULAR 4935230 POTASSIUM HYDROXIDE. LIQUID (OR) SOLUTION 4935235 SODIUM HYDROXIDE. DRY, SOLID. FLAKE, BEAD, OR GRANULAR 4935238 BARIUM HYDROXIDE MONOHYDRATE (CORROSIVE SOLID, N.O.S.) 4935240 SODIUM HYDROXIDE LIQUID 4935243 SODIUM HYDROXIDE. LIQUID (OR) SOLUTION (CAUSTIC SO DIUM (SODIUM HYDROXIDE) CONTAINING NOT LESS THAN 48 PERCENT WATER BY WEIGHT IN SOLUTION) 4935244 CAUSTIC SODA AND CAUSTIC POTASH, MIXED. IN SOLU TION (POTASSIUM HYDROXIDE. LIQUID (OR) SOLUTION) 4935245 CAUSTIC SODA AND CAUSTIC POTASSIUM. MIXED. IN SOLimON (SODIUM HYDROXIDE LIQUID (OR) SOLUTION) 4935248 SODIUM SOLUTION WASTE (CORROSIVE LIQUID. N.O.S.) 4935250 SODA LIME. SOLID 4935255 LIME SALTS. NEC (CORROSIVE SOLID, N.O.S.) 4935260 SODIUM ALUMINATE, SOLUTION 4935262 LYE. CONCENTRATED. NEC (SODIUM HYDROXIDE. DRY. SOLID, FLAKE. BEAD OR GRANULAR) 4935264 SODIUM METHYLATE. ALCOHOL MIXTURE 4935265 SODIUM MONOXIDE. SOLID 500 502 514 522 523 523 539 544 68 269 80 198 192 485 198 196 229 232 232 300 343 344 338 231 36 19 39 93 161 161 123 187 207 214 231 269 274 376 377 379 402 431 276 459 110 16 17 17 242 422 423 469 56 469 469 110 110 475 561 312 461 318 471 471 4935267 SODIUM HYDROSULFIDE, SOLID (WITH NOT LESS THAN 25% WATER OF CRYSTALLIZATION) 4935268 SODIUM HYDROSULFIDE. SOLUTION 4935270 SODIUM PHENOLATE, SOLID 4935272 FERTILIZER SOLUTION. CONSISTING OF WATER. FREE AM- MONIA AND SULPHUR. TOTAL AMMONIA CONTENT NOT TO EXCEED 30 PERCENT BY WEIGHT (CORROSIVE LIQ UID, NOS.) 4935273 SODIUM HYDROXIDE AND SODIUM BOROHYDRIDE SOLU TION N.O.S.) 4935275 SULFIDE WASTE (CORROSIVE LIQUID. N.O.S.) 493S278 DE-INKING COMPOUNDS USED IN RECYCLING PAPER (COR ROSIVE LIQUID. N.O.S.) 4935280 AMMONIUM HYDROXIDE (CONTAINING NOT LESS THAN 12% BUT NOT MORE THAN 44% AMMONIA) 4935510 HYDROXYPROPYL ACRYLATE (CORROSIVE LIQUID. N.O.S.) 4935515 CHLORAL (CORROSIVE LIQUID. N.O.S.) 4935520 TRIS-(I-AZIRIDINYL) PHOSPHINE OXIDE 4935605 2-{2-AMINOETHOXY) ETHANOL 4935610 N-AMINOETHYL PIPERAZINE 4935615 AMINOPROPYLDIETHANOL AMINE 4935620 N-AMINOPROPYL MORPHOLINE 4935625 BIS-(AMINOPROPYL) PIPERAZINE 4935626 MONOISOPROPANOLAMINE (CORROSIVE LIQUID, N.O.S.) 493S627 AMYL PHENOL (CORROSIVE LIQUID, N.O.S.) 4935628 ETHYLENEDIAMINE 4935629 BUTYL PHENOL (CORROSIVE SOLID, N.O.S.) 4935630 CUPRIETHYLENE-DIAMINE SOLUTION 4935631 DIETHYLENETRIAMINE (CORROSIVE LIQUID. N.O.S.) 4935632 TRIETHYLENETETRAMINE (CORROSIVE LIQUID, N.O.S.) 4935640 HEXAMETHYLENE DIAMINE. SOLID 4935645 HEXAMETHYLENE DIAMINE SOLUTION 4935650 HEXAMETHYLENE IMINE 4935658 IMINOBISPROPYLAMINE 4935660 METHYL ETHYL PYRIDINE 4935665 MONOETHANOLAMINE 4935668 MORPHOLINE. AEQUOUS MIXTURE 4935674 AMINOETHYLETHANOLAMINE (CORROSIVE LIQUID, N.O.S.) 4935675 HYDROXYETHYLACRYLATE (CORROSIVE UQUID.N.O.S.) 4935680 TETRAMETHYL AMMONIUM HYDROXIDE, LIQUID 4936010 BENZYL BROMIDE (BROMOTOLUENE. ALPHA) 4936012 BENZYL CHLORIDE 4936015 CORROSIVE LIQUID. POISONOUS. N.O.S. 4936110 BROMINE 4936220 DIPHENYL METHYL BROMIDE. SOLID 4936225 DIPHENYL METHYL BROMIDE. SOLUTION 4936312 DICHLOROBUTENE 4936315 DICHIOROISOPROPYL ETHER 4936335 HYPOCHLORITE SOLUTION (CONTAINING MORE THAN 7% AVAILABLE CHLORINE BY WEIGHT) 4936345 POTASSIUM HYPOCHLORITE SOLUTION 4936360 SODIUM CHLORITE SOLUTION (NOT EXCEEDING 42% SO DIUM CHLORITE) 4936370 1,2,3,6-TETRAHYDROBENZALDEHYDE 4936502 BATTERIES. ELECTRIC STORAGE, WET, WITH AUTOMOBILE AUTO PARTS, ENGINE 4936503 BATTERY SETS FOR WET BATTERIES (CORROSIVE SOLID. N.O.S.) 4936504 BATTERY SETS IN BATTERY BOXES (CORROSIVE SOLID. N.O.S.) 4936505 BOILER COMPOUNDS. LIQUID 4936510 COAL TAR DYE, LIQUID 4936514 SMOKE FLUE CLEANING COMPOUNDS (COMPOUND. CLEANING, LIQUID) 4936515 COMPOUND, CLEANING, LIQUID 4936516 CLEANING COMPOUND, IRON OR STEEL. LIQUID (COM POUND. CLEANING. LIQUID) 4936517 CLEANING COMPOUNDS, IRON OR STEEL, DRY (CORRO SIVE SOLID. N.O.S.) 4936520 COMPOUND. CLEANING. LIQUID (CONTAINING PHOS PHORIC OR ACETIC ACIDS) 4936521 COMPOUND. CLEANING. LIQUID (CONTAINING SODIUM OR POTASSIUM HYDROXIDE) 4936530 COMPOUNDS. RUST PREVENTING (OR) COMPOUND RUST REMOVING 4936532 COMPOUND. TREE (OR) WEED KILLING. LIQUID 4936534 COMPOUND. VULCANIZING. LIQUID 4936535 COMPOUND. LACQUER, PAINT OR VARNISH REMOVING LIQUID 468 468 473 247 468 485 183 28 285 116 514 22 22 23 22 23 354 38 237 92 157 193 511 273 273 273 286 339 353 355 22 284 495 68 68 151 76 207 208 184 186 285 423 464 495 59 60 60 72 132 480 136 130 130 139 140 145 141 142 140 585 0qq t ?*, 4936536 FIRE PROOFING COMPOUNDS, LIQUID, NEC (CORROSIVE LIQUID. N.O.S.) 4936537 FUEL OIL TREATING COMPOUNDS (CORROSIVE LIQUID, N.O.S.) 4936538 CHEMICAL PLANT WASTE, NEC (CORROSIVE LIQUID, N.O.S,) 4936539 PETROLEUM REFINERY SULFIDE WASTE (CORROSIVE UQUID. N.O.S.) 4936540 CORROSIVE LIQUID, N.O.S. 4936541 GLYCERINE, CRUDE, (SPENT LYE), CONCENTRATED (COR- ROSIVE LIQUID. N.O.S.) 4936543 ASPHALT ADDITIVE. ANTI-STRIPPING (CORROSIVE LIQUID, N.O.S.) 4936545 CORROSIVE SOLID, N.O.S. 4936546 COMPOUNDS, WATER SYSTEM RUST OR SCALE PREVENT- ING, DRY (CORROSIVE SOLID, N.O.S.) 4936548 CHEMICAL KIT 4936551 COSMETICS. N.O.S., LIQUID 4936552 COSMETICS. N.O.S., SOLID 4936554 PETROLEUM ALKYLATE DETERGENT INTERMEDIATE (COR- ROSIVE LIQUID, N.O.S.) 4936555 DYE INTERMEDIATE. LIQUID 4936557 BATTERY. ELECTRIC STORAGE. WET. WITH CONTAINERS OF CORROSIVE BATTERY FLUID 4936558 BATTERY. ELECTRIC STORAGE, WET 4936561 DISINFECTANT, LIOUID 4936563 COMPOUNDS, PETROLEUM TREATING. CRUDE, NEC (ACID. LIOUID. N.O.S.) 4936564 ELECTROLYTE (ACID) PACKED WITH BATTERY CHARGER. RADIO CURRENT SUPPLY DEVICE OR ELECTRONIC EQUIPMENT AND ACTUATING DEVICE) 4936565 ALKALINE CORROSIVE BATTERY FLUID PACKED WITH BATTEfiY CHARGER. RADIO CURRENT SUPPLY DEVICE OR ELECTRONIC EQUIPMENT AND ACTUATING DEVICES 4936567 BATTERY CHARGER WITH ELECTROLYTE (ACID) 4936568 8ATTERY CHARGER WITH ELECTROLYTE (ALKALINE BAT- TERY FLUID) 4936570 FLAME RETAROANT COMPOUND, LIQUID 4936571 COMPOUNDS. STONE STENCIL. IN SHEET FORM (CORRO- SIVE SOLID, N.O.S ) 4936573 TANNER'S DIPILATORY, NEC (CORROSIVE LIQUID, N.O.S.) 4936576 TEXTILE TREATING COMPOUNDS MIXTURE. LIQUID 4936580 WATER TREATMENT COMPOUND, LIQUID 4936581 DRUGS. N.O.S.. LIQUID 4936562 DRUGS. N.O.S.. SOLID 4936583 MEDICINES. N.O.S.. LIQUID 4936584 MEDICINES. N.O.S.. SOLID 4936585 SOLDERING FLUX OR SALTS. NEC, LIQUID (CORROSIVE UQ- UID. N.O.S.) 4936590 WOOD BLEACH (CORROSIVE LIQUID, N.O.S.) 4936594 INSECTICIDE ADHESIVES, SPREADERS OR STICKERS. LIQ- UID (CORROSIVE LIQUID. N.O.S.) 4936595 WASTE ETCHANT SOLUTION. SUITABLE ONLY FOR RECLA- MATION OFMETALLIC CONTENT (CORROSIVE LIOUID. N.O.S.) 4940310 CHLOROFORM (CHLOROFORM (TRICHLORMETHANE), NEC. OTHER THAN TECHNICAL GRADE) 4940311 CHLOROFORM (CHLOROFORM. NEC. TECHNICAL GRADE (TRICHLOROMETHANE)) 4940320 CARBON TETRACHLORIDE 4940325 TRICHLOROPHENOL 4940335 ETHYLENE DIBROMIDE (OR) 1,2-DIBROMOETHANE 4940341 FORMALDEHYDE (OR) FORMALIN SOLUTION(IN CON- TAINERS OF 110 GALLONS OR LESS) (FORMALDEHYDE. LIQUID) 4940342 FORMALDEHYDE (OR) FORMALIN SOLUTION (IN CONTAINERS OF 110 GALLONS OR LESS) (FORMALDEHYDE, PASTE) 4940347 AMMONIUM HYDROXIDE (CONTAINING LESS THAN 12% AMMONIA) 4940350 AMMONIUM OXALATE 4940360 NAPHTHALENE (OR) NAPHTHALIN (NAPHTHALENE (NA- PHTHAUN), CRUDE (TAR CAMPHOR. CRUDE)) 4940361 NAPHTHALENE (OR) NAPHTHALIN (NAPHTHALENE (NA- PHTHAUN), OTHER THAN CRUOE (TAR CAMPHOR. OTHER THAN CRUDE)) 4940370 TDE (l.t-DICHLORO-BIS(P-CHLOROPHENYL)ETHANE) 4940375 TRtCHLORFON (AGRICULTURAL INSECTICIDES. NEC, LIQUID) 4940376 TRICHLORFON (AGRICULTURAL INSECTICIDES. NEC. OTHER THAN LIQUID) 249 257 116 400 151 265 54 151 146 115 152 152 397 217 61 60 209 144 218 16 60 60 250 145 4B9 496 531 216 216 322 323 476 534 290 528 122 122 109 509 235 254 255 27 30 361 361 490 507 507 4940377 TRICHLORFON (INSECTICIDES. OTHER THAN AGRICUL- TURAL. NEC) 4941103 ACETALDEHYDE AMMONIA 4941107 ALDRIN. CAST SOLID 4941108 ALDRIN MIXTURE. LIQUID. WITH 60% OR LESS ALDRIN 4941109 ALDRIN MIXTURE. DRY, WITH 65% OR LESS ALDRIN 4941114 ANTIMONY POTASSIUM TARTRATE SOLID 4941120 CARBARYL (INSECTICIDES. OTHER THAN AGRICULTURAL NEC) 4941121 CARBARYL (AGRICULTURAHNSECTICIDES. NEC. LIOUID) 507 1 16 16 15 43 104 104 4941122 CARBARYL (AGRICULTURAL INSECTICIDES. NEC. OTHER 104 THAN LIQUID) 4941123 CHLORPYRIFOS (AGRICULTURAL INSECTICIDES. NEC. 126 LIQUID) 4941124 CHLORPYRIFOS (AGRICULTURAL INSECTICIDES. NEC. 126 OTHER THAN LIQUID) 4941125 CHLORPYRIFOS (INSECTICIDES, OTHER THAN AGRICUL- 126 TURAL, NEC) 4941126 2.4-DICHLOROPHENOXYACETIC ACID 4941127 DICHLOROBENZENE. ORTHO. LIQUID 4941128 DICHLOROBENZENE. PARA. SOLID 4941129 DDT (OR) OICHLORODIPHENYLTRICHLOROETHANE 4941131 FERROUS CHLORIDE, SOLID 4941133 DIELDRIN (INSECTICIDES, OTHER THANAGRICULTURAL, NEC) 4941134 DIELDRIN (AGRICULTURAL INSECTICIDES. NEC. LIQUID) 4941135 DIELDRIN (AGRICULTURAL INSECTICIDES. NEC. OTHER THAN LIQUID) 4941140 DIAZINON (INSECTICIDES. OTHER THAN AGRICULTURAL. NEC) 4941141 DIAZINON (AGRICULTURAL INSECTICIDES. NEC. LIQUID) 4941142 DIAZINON (AGRICULTURAL INSECTICIDES. NEC. OTHER THAN LIQUID) 4941143 PARAFORMALDEHYDE 4941145 AMMONIUM CARBAMATE 4941149 AMMONIUM CARBONATE 4941150 LINDANE (INSECTICIDES, OTHERTHAN AGRICULTURAL, NEC) 4941151 LINDANE (AGRICULTURAL INSECTICIDES. NEC. LIOUID) 4941152 LINDANE (AGRICULTURAL INSECTICIDES. NEC. OTHER THAN LIQUID) 4941155 MALEIC ACID 4941156 MALATHION 4941160 POTASSIUM DICHROMATE 4941161 MALEIC ANHYDRIDE 4941170 SODIUM DICHROMATE 4941171 TRICHLOROETHYLENE 4941179 2.4.5-TRICHLOROPHENOXYPROPIONIC ACID 4941185 2.4.5-TRICHLOROPHENOXYACETICACID (OR) 2,4.5-T 4941188 TOXAPHENE (TOXAPHENE. LIQUID) 4941189 TOXAPHENE (TOXAPHENE. OTHERTHAN LIOUID) 4941190 TOXAPHENE (CHLORINATED CAMPHENE) 4941193 XYLENOL 4941195 ZINC HYDROSULFITE 4944105 AMMONIUM FLUORIDE 4944125 AMMONIUM FLUOBORATE 4944130 LEAD CHLORIDE 4944133 LEAD FLUOBORATE 4944135 AMMONIUM SILICOFLUORIDE 4944138 FERRIC CHLORIDE SOLID 4944140 LEAD FLUORIDE 4944142 AMMONIUM BISULFITE. SOLID 4944143 SODIUM HYPOCHLORITE SOLUTION (HYPOCHLORITE SO- LUTION CONTAINING NOT MORE THAN 7% AVAILABLE CHLORINE (BY WEIGHT)) 4944145 HYPOCHLORITE SOLUTION CONTAINING NOT MORE THAN 7% AVAILABLE CHLORINE (BY WEIGHT) 4944150 SODIUM FLUORIDE. SOLID 4944155 SODIUM HYDROGEN SULFITE. SOLID 4944165 ALUMINUM SULFATE SOLUTION 4944173 COPPER CHLORIDE 4944185 ZIRCONIUM SULFATE 4950110 ACIDS. CHEMICAL AND OTHER ARTICLES, MIXED LOAD 4950120 PETROLEUM OIL OR PROOUCTS. MIXEO LOAD 4950130 FREIGHT FORWARDER TRAFFIC 4950140 SHIPPER ASSOCIATION TRAFFIC 4950150 ALL FREIGHT RATE SHIPMENTS. NEC (TOFC) 4950160 MIXED LOAD OF GROCERIES AND GROCERS SUPPLIES 186 182 182 163 246 191 191 191 178 177 178 391 25 25 313 312 313 320 320 422 321 466 508 509 509 504 504 504 536 540 27 26 307 308 31 244 308 25 469 285 467 467 21 148 $44 6 399 256 457 17 351 586 MCD 0000l7514 4960125 WEED KILLING COMPOUND AND CHLORDANE MIXTURE (HAZARDOUS SUBSTANCE. LIQUID (OR) SOLID) 4960131 HAZARDOUS WASTE. LIQUID (OR> SOLID. N.O.S. 4960132 HAZARDOUS SUBSTANCE. LIQUID (OR) SOLID. NO.S. 4960140 KEPONE 4960616 DICHLONE (AGRICULTURAL INSECTICIDES. NEC, OTHER THAN LIQUID) 4960617 DICHLONE (AGRICULTURAL INSECTICIDES. NEC. LIQUID) 4960618 DICHLONE (INSECTICIDES. OTHER THAN AGRICULTURAL, NEC) 4960630 HEPTACHLOR 4960646 METHOXYCHLOR (AGRICULTURAL INSECTICIDES, NEC, LIQUID) 4960647 METHOXYCHLOR (AGRICULTURAL INSECTICIDES. NEC, OTHER THAN LIQUID) 4960648 METHOXYCHLOR (INSECTICIDES, OTHER THAN AGRICUL- TURAL. NEC) 4961110 CAPTAN (INSECTICIDES, OTHER THAN AGRICULTURAL. NEC) 4961164 CAPTAN (AGRICULTURAL INSECTICIDES. NEC. OTHER THAN LIQUID) 4961165 PROPARGITE 4961167 CAPTAN (AGRICULTURAL INSECTICIDES. NEC. LIQUID) 4961316 CUPRIC SULFATE 4961317 COPPER SULFATE AND LIME COMBINED. DRY (CUPRIC SULFATE) 4961318 COPPER SULPHATE AND SULPHUR (CUPRIC SULFATE) 4961380 PENTACHLOROPHENOL 4961656 NALED (AGRICULTURAL INSECTICIDES. NEC, LIQUID) 4961657 NALED (AGRICULTURAL INSECTICIDES. NEC. OTHER THAN LIQUID) 4961658 NALED (INSECTICIDES. OTHER THAN AGRICULTURAL. NEC) 4961666 POLYCHLORINATED BIPHENYL OR PCBS 4962110 N-BUTYL PHTHALATE 4962130 2,4-DICHLOROPHENOXYACETIC ACID ESTER 4962145 MERCAPTODJMETHUR 4962180 2,4,5-TRICHLOROPHENOXYPROPIONIC ACID ESTERS 4962303 CADMIUM ACETATE 4962305 CADMIUM BROMIDE 4962310 COPPER ACETATE (VERDIGRIS) (CUPRIC ACETATE) 4962313 CUPRIC SULFATE. AMMONIATED 4962356 NAPHTHENIC ACID 4962390 2,4,5-TRfCHLOROPHENOXYACETIC ACID AMINE. ESTER, (OR) SALT (OR) 2.4.S-T AMINE. ESTER. (OR) SALT 4962505 CADMIUM CHLORIDE 4962610 CUPRIC OXALATE 4962614 CUPRIC TARTRATE 4962620 OIURON (AGRICULTURAL INSECTICIDES. NEC. LIQUID) 4962621 DIURON (AGRICULTURAL INSECTICIDES. NEC. OTHERTHAN UQUID) 4962622 DIURON (INSECTICIDES. OTHER THAN AGRICULTURAL, NEC) 4962626 FERRIC FLUORIDE 4963115 DINITROTOLUENE. SOLID 4963120 DINITROTOLUENE. LIQUID 4963155 NITROTOLUENE 4963302 AMMONIUM CHROMATE 4963303 ALUMINUM SULFATE 4963304 ALUMINUM SULPHATE FLUOSULPHATE MIXTURE. FLUO- RINE CONTENT NOT TO EXCEED 25% (ALUMINUM SULFATE) 4963305 ALUMINUM SULPHATE, NOT MORE THAN 5% ACTIVATED CARBON (ALUMINUM SULFATE) 4963306 SODIUM ALUMINUM SULPHATE (SODIUM ALUM) (ALUMINUM SULFATE) 4963307 CALCIUM CHROMATE 4963309 CALCIUM DOOECYLBENZENESULFONATE 4963312 CHROMIC ACETATE 4963314 CHROMIC SULFATE 4963317 CHROMIUM SULPHATE. BASIC. DRY (CHROMIC SULFATE) 4963319 CHROME SULPHATE SOLUTION (CHROMIC SULFATE) 4963322 CHROMOUS CHLORIDE 4963324 CHROME CHLORIDE SOLUTION (CHROMOUS CHLORIDE) 4963327 COBALTOUS FORMATE 4963329 COBALTOUS SULFAMATE 4963332 DICAM8A (INSECTICIDES, OTHER THAN AGRICULTURAL, NEC) 4963334 DICAMBA (AGRICULTURAL INSECTICIDES. NEC. UQUID) 4963337 DICAMBA (AGRICULTURAL INSECTICIDES. NEC. OTHER THAN LIQUID) 4963339 DIQUAT (INSECTICIDES. OTHER THAN AGRICULTURAL, NEC) 531 267 267 304 181 181 181 268 334 334 334 102 102 426 102 156 150 ISO 394 359 359 359 418 92 187 323 510 96 96 146 156 361 509 96 156 157 213 214 214 244 206 206 375 26 21 21 21 461 97 98 127 129 129 127 129 126 137 137 179 179 179 209 4963342 DIQUAT (AGRICULTURAL INSECTICIDES. NEC, LIQUID) 4963344 DIQUAT (AGRICULTURAL INSECTICIDES. NEC. OTHER THAN LIQUID) 4963349 FERRIC AMMONIUM CITRATE 4963352 FERRIC AMMONIUM OXALATE 4963354 FERROUS AMMONIUM SULFATE 4963357 FERROUS AMMONIUM SULPHATE, FERTILIZER GRADE (IRON AMMONIUM SULPHATE) (FERROUS AMONIUM SULFATE) 4963359 ISOPROPANOLAMINE DOOECYLBENZENESULFONATE 4963364 POTASSIUM CHROMATE 4963367 QUINOLINE 4963369 SODIUM CHROMATE. DRY (SODIUM CHROMATE) 4963372 SOOIUM CHROMATE SOLUTION (SODIUM CHROMATE) 4963374 SODIUM DOOECYLBENZENESULFONATE 4963377 STRONTIUM CHROMATE 4963379 TRIETHANOLAMINE DOOECYLBENZENESULFONATE 4963384 VANADYL SULFATE 4963385 VANADIUM PENTOXIDE 4963387 ZINC ACETATE 4963389 ZINC BORATE 4963392 ZINC FORMATE 4963394 NITROPHENOL 4963710 COBALTOUS BROMIDE 4963720 LITHIUM CHROMATE 4963786 ZINC SULFATE 4963805 OICHLOBENIL (INSECTICIDES. OTHER THANAGRICULTURAL. NEC) 4963809 DICHLOBENIL (AGRICULTURAL INSECTICIDES. NEC. LIQUID) 4963814 DICHLOBENIL (AGRICULTURAL INSECTICIDES, NEC. OTHER THAN UQUID) 4963818 IRON SULPHATE (FERRIC). DRY, OTHER THAN CRUDE (FERRIC SULFATE) 4963823 IRON SULPHATE (FERRIC), DRY, CRUDE (FERRIC SULFATE) 4963827 FERRIC SULPHATE SOLUTION(FERRIC SULFATE) 4963832 FERROUS SULFATE 4963836 FERROUS SULPHATE.LESS THAN 40% WATER(FERROUS SULFATE) 4963841 FERROUS SULPHATE. NOT LESS THAN 40% WATER (FER- ROUS SULFATE) 4963663 NICKEL HYDROXIDE 4963868 PYRETHRINS (INSECTICIDES. OTHER THAN AGRICUL- TURAL. NEC) 4963872 PYRETHRINS (AGRICULTURAL INSECTICIDES. NEC. LIQUID) 4963677 PYRETHRINS (AGRICULTURAL INSECTICIDES, NEC, OTHER THAN LIQUID) 4963881 PYRETHRINS (PYRETHRUM) 4963886 PYRETHRINS (PYRETHRUM EXTRACT. NOT LESS THAN 25% PYRETHRUM) 4963890 ZINC CARBONATE 4963895 ZINC FLUORIDE 4966110 ADIPIC ACID 4966304 AMMONIUM BENZOATE 4966308 AMMONIUM BICARBONATE 4966316 AMMONIUM CHLORIDE 4966320 AMMONIUM CITRATE, DIBASIC 4966332 AMMONIUM SULFITE 4966336 AMMONIUM TARTRATE 4966340 BENZOIC ACID 4966352 FUMARIC ACID 4966356 LEAD THIOCYANATE 4966360 NICKEL AMMONIUM SULFATE 4966364 NICKEL CHLORIDE 4966368 NICKEL SULFATE 4966372 NICKEL SULFATE. COPPER REFINERY, CRUDE (NICKEL SULFATE) 4966380 SODIUM PHOSPHATE. DIBASIC 4966383 SODIUM PHOSPHATE. TRIBASIC 4966386 ZINC AMMONIUM CHLORIDE 4966389 ZINC PHENOLSULFONATE 4966392 ZINC SILICOFLUORIDE 4966395 ZIRCONIUM POTASSIUM FLUORIDE 4966640 LEAD ACETATE 4966708 AMMONIUM ACETATE 4966732 AMMONIUM SULFAMATE 4966738 AMMONIUM THIOCYANATECRYSTALS (AMMONIUM THIOCYANATE) 4966744 AMMONIUM THIOCYANATE LIQUOR (AMMONIUM THIOCYANATE) 4966750 AMMONIUM THIOSULFATE 208 208 243 243 245 245 300 420 438 *65 464 466 481 510 523 523 537 537 540 374 136 315 542 181 180 180 293 293 245 246 247 247 364 434 434 434 435 435 536 539 10 24 24 26 26 32 32 63 257 311 362 363 364 365 473 474 537 541 541 544 306 24 31 32 32 33 587 Mod oooox 7515 4966756 AMMONIUM THIOSULFATE SOLUTION (AMMONIUM THIOSULFATE) 4966774 RESORCINOL 4966760 ZINC BROMIDE 4966790 ZINC CHLORIDE. SOLID 4966905 ANTIMONY TRIOXIDE (ANTIMONY OXIDE) 4966910 ETHYLENEDIAMINETETRAACETIC ACID (OR) EDTA 4966920 KELTHANE (INSECTICIDES. OTHER THAN AGRICULTURAL, NEC) 33 447 538 539 46 236 303 4966930 KELTHANE (AGRICULTURAL INSECTICIDES. NEC. LIQUID) 4966940 KELTHANE (AGRICULTURAL INSECTICIDES. NEC. OTHER THAN LIQUIO) 4966950 LEAD IODIDE 4966960 LEAD STEARATE 4966970 LEAD SULPHATE. CRUDE (LEAD SULFATE) 4966980 LEAD SULPHATE. REFINED (LEAD SULFATE) 4966987 LEAD SULFIDE 4966994 GALENA ORE, CRUDE (LEAD SULFIDE) 303 303 309 309 310 310 310 261 588 000017516 MCD AFTERWORD AND ACKNOWLEDGEMENTS Operations of the Bureau for the Safe Transportation of Explosives and Other Dangerous Articles began with the opening of the office of the Chief Inspector at 24 Park Place, New York City on June 10,1907. By the time of the first Annual Report of the Chief inspector, the Bureau had an office staff of five, a laboratory staff of two, seventeen inspectors and one special agent. That original cadre is long since gone, many of the railroads that were our first members now exist only in history and even the manufacturers on the first "Conference Committee,'' formed to discuss the regulations for the transportation of explosives, have now, largely, passed on into the mists of time. What has not changed in 75 years is the purpose behind the formation of the Bureau of Explosives. Then, as now, our goal was and is to promote the safe handling and transportation of hazardous materials; to collect, analyze and disseminate information on these materials and to provide emergency assistance for the benefit of our members. Emergency Handling ofHazardous Materials in Surface Transportation furthers all of the goals we seek. Since its first issuance, thousands of copies have been distributed throughout the transportation, production and emergency response communities and it has become a "standard" work in the field. The commodity specific emergency response information in this book, and its previous editions, also exists in the form of computer data and is widely used across the railroad industry. With this information, railroads can automatical ly print hazardous materials information on train consists, classification yards can be electronically searched for specific commodities which require special handling and, if a car is damaged, a compatible empty can be located quickly for a transfer. Because each of the hazardous materials regulated by the Department of Transportation has been assigned a unique numeric code, railroad computers specifically and exactly identify every commodity in this book, avoiding the potential dangers inherent in other systems' "generic" coding. Perhaps most important, as the list of regulated commodities increases, the railroad industry can update its emergency response information much more quickly than if the data existed only as printed material. The new edition represents far more than just a reprint of the old. Hundreds of new commodities have been added, the descriptive material about each has been expanded and, for environmentally hazardous substances, emergency response mitigation information has been included. The staff of the Bureau of Explosives has devoted many, many hours to this new edition and our special thanks goes to those in the transportation, production and shipping fraternities whose voluntary efforts, in the form of comments on earlier versions and on drafts of this one, have added to and helped shape it. In the field of hazardous materials transportation safety, where the sum of available knowledge is till expanding, no written word can be considered final. We at the Bureau anticipate that this edition will have to be superseded in time. Towards that end, the comments of all readers and users of this book are both welcome and essential. Please feel free to make them either to me or to the Editor, in care of: The Bureau of Explosives Association of American Railroads 1920 L Street, North West Washington, DC 20036 (202) 293-4048 Your contribution to the safety of people, property and the environment will be appreciated. T>omas A. Phemister Director. Bureau of Explosives Washington, D.C. September, 1981 589