Document JJg0DZnYk1QY55Oy5xVXOkEQv

Beyond Safety Regulations BY ROBERT W. WESSON rhough many company records, including Union Carbide's, show that employees are safer at work than at home, as long as lives and ttmfes are feeing lost in the plant, industry cannot rest on its excellent safety records or At Union Carbide, Improving safety is a goal that everyone is constantly striving to achieve. are rated for their toxicological properties. Much of this work is done at the Carnegie* Mellon Institute of Research in Pittsburgh. Penns. Unton Carbide has long benefited from the services of this toxicology research laboratory, it was nearly 4Q years ago that Union Carbide established its Chemical Hygiene Fellowship at the Mellon Institute. This was a full year before the enactment of die Food, Drug and Cosmetic Act, which required testing of food additives and other products that might be harmful. 4,000 Compounds Tested During the ensuing four decades, the Fellowship has grown from a two-man opera tion to a staff of over 35. To date, over 4,000 compounds have been assayed to delineate It is a way of life that begins with upper man agement, In addition to a corporate safety department and its committees, each division or operating unit of the Corporation has a safe ty and health organization devoted to its own particular needs. The Chemicals &i Plastics people organized a group known as SHARE, which falls under the direction of a vicepresident, The name is derived from safety, health and affairs related to the environment SHARE further ensures that Union Carbide's Chemicals & PJasrics operations meet all aspects of the Federal Occupational Safety and Health Act. , Union Carbide is extremely cautious with newjv developed chemicals and resins. Before manufacture or use in plants, new substances their toxicological properties. Each chemical is examined to answer the following: Under what conditions can the compound be manufactured without injury to plant per sonnel? Can it be shipped without special han- 6644 VW-12239 dling procedures? if not. what procedure must be employed? And. unde1'' n-iiut condUtom can it be used safely by ihe public? Safety programs for the industry .at large are. of course, as vital as the Corporation's interna! programs. For example, results of the work done at Carnegie-MelIon by the Chemical Hygiene FeJJnw.$hip are made available to ihe scientific community through publication and sharing of information. Product literature rou tinely includes precautionary labeling informa tion. toxicological properties. FDA and EPA status where applicable, and special handling procedures when necessary. Development of MSD Sheets Another advance of which Union Carbide is proud is the development of its Material Safety Data (MSD) Program -- perhaps the largest single endeavor undertaken to provide our cus tomers and our customers' customers with per tinent safety data. In 1970, the Department of Labor mandated mat MSD sheets he Issued on all hazardous products sold to the ship repairing, ship building and shipbreaking industries (the socalled 3-S industries). These sheets were to be retained at the job site by those using the prod ucts. While safety data have always been published on Union Carbide's products, these new requirements were more detailed and were specific to these three industries. Beyond Government Programs The first Department of Labor MSD regula tion came out on July 1, 1970. Union Carbide meanwhile had outdistanced the government program both in time and in scope. By that time, the company had already devised its own modified MSD sheers -- actuary more comprehensive than required -- which the Department of Labor approved on June 20, 1970. Union Carbide's fires MSD sheet was issued a few months later. Since that time, over 600 sheets have been issued covering an enor mous variety of products going into many dif ferent industries. Eventually, an MSD sheet will be issued on every product produced -- even on those not officially considered hazard ous, This program is much too valuable to limit its use to the legal requirements of the man date. When a -request is made for a new MSD sheet by customers, distributors or Internally, a team of experts, from chemists to lawyers, col-' labrates on developing a sheet that is as clear and helpful as possible. These sheets are so carefully done -- so comprehensive and clear -- that many other companies, and even OSHA. use them as models. To gather the physical data. Union Carbide's labs do pxtensive testing in areas such as haz ardous ingredients, fire and explosion, health, reactivity, spill or leak procedures, special pro tection and special precautions. As a result, much more is included in the data sheets than is required by current OSHA regulations. On each data sheet a list of phone numbers is in cluded so that Union Carbide safety experts can provide assistance at any time, day or night. Not only is a major effort made to prepare the sheets, but also to have them widely distrib uted and used. Customers are encouraged, via direct contact, newsletters, seminars, etc., to ask for the sheets. They can be obtained either through Union Carbide s sales force or distrib utors. Special binders are provided for conve nient filing and efficient retrieval of informa tion. A comprehensive index, which lists all sheets issued to date, is also provided for ready refer ence. Holders of MSD binders automatically receive an updated index as soon as it is issued. And, of course, ali MSD sheets are systemat ically reviewed for updating and/or revisions. The MSD Program is only one of many recent efforts to make industry safer. Union Carbide is dedicated to the continued up grading of all safety programs. Our lives depend on it. Km&g, 664 r> DECEMBER 1976 ire Umita 5 15 C4 t.5 0.1 9.001 to 5 0.2 0.4 0.01 0.05 2 QS 2.9S0 0.1S 13 5.9GO 1 5 0.25 20 10 5 0.2 0.1 0.2 ess 2 4.170 *.170 32 2 Q.Q7S 5?0 oar 3 5 1.5 0.1 5 2 22 S Substance Exposure limits p.p m." mg7M* Uranium (soluble compounds} Uranium (insoluble compounds} C Vanadium: V,Os Oust ................................ V.O, fume................................ '/'*>* ?njan so Si/'r.e Vinytcyanifle, see Aoyloftithie . vinyl toluene................................ Warfarin......................... ... Xylene {xylol} ............................ Yttrium.......................................... Zinc chloride fume................... Z-rc avc* '.'re Zirconium compound* {as Zr) . -- too too $ 0.05 0.25 0.5 0.1 -- 460 0.1 435 ?5 1 1 $ 'Parts of vapor or gas per million parts of con* laminated air by volume at 25 C and 760 m ^assure. *pproximate milligrams oi particulate par cubic mater at air. {No footnote "c" Is used to avoid confusion with We "C-1 wat precedes soma materials to *ndics?e ceiling value notations.) 'An atmospheric concentration oi not more than 0.02 p.p.m., or personal protection may be necessary to avals headache. 'As sampled By method that does not collect vapor. *For control of general room air. Boogie monitoring is essential for personnel control. Other Materials <Sftdb4sed -weesatot .ba*.*ase .iac^es .tor J/aa J&lowingr consult referenced sections fordetails: Mi*iai *srrcs Cpa:*5<5':cr vcia:iis >n:r;>ria:.on of **** 4-NrtfCbicheoy). aiphB'NaphWYiamlne. Methyl chioromethyi ether 32'>Dichior^enzine {and Ms sails} bs-CRioromethyt ewer beta-Naphthy1 amine. Benzidine. 4'Amincdrpsnyt. Ewyi*nemk\e. beta-Pfopidactone. 2*Aoetvlaminoworene. 4.01 methyfammoaroBanzine N-Nitrcsodsmernylamine. Vrnyi chloride. Reference 1510 1001 1910 1002 1910,1003 1910.1004 1910.1006 1910.1037 1910.1006 1910.1009 1910.1019 1910.1011 1910.1912 1910.1013 1910,1014 1910.1015 1910.1016 1910.1017 Mineral Dusts . " :: Substance Mppd' Mg/M1 Silica: Crystalline: Quartz (respirable)___ Quartz (total fflssr)......... Criobatita:Use ft the * value calculated from We count or masa for* mulaa for nuartz. Tndymite: Use ft mevalue calculated irom me for* raufae ferquaftL Amorphous, including notural elatomaceeus earm ' 2K %Si, + 5 20 . 10m<VM'%SiO*-*"2 30mo/M* 968,0,4*2 Mmo/M* %S)0- Silicates {less wan t% crys* lalllre saica}: Mica ..................................... Soapstone ......................... Talc (non-asbestos-form) . Talc {fibrous), use tabes* tos limit .......................... Tremolita {see talc, fibrous} Portland eemem............... Graphite {natural;................. Coal dial (respirable fraction less than 5% StO^.......... For more than 5% 50,___ Inert or Nuisance Dust: Respirable traction........... Toiai dust .......................... 20 20 20' 50 IS 2.4mg/M" or 10 % 810,4- 2 IS Smg/M'1 50 iSmg/tf1 Note: Converaiafl fdsora -- mppcfx $5,3"million particles per cubic meter particles per c.fi. Mllliona of particles per cubic foot of air. Baaed on impinger samplescounted By ll^tt-fleld technics. ohe percentage of crystalline silica in the formula is We amount determined from eir-borna samples, ex cept in Ehoae instances in which other methods have Been shown to be applicable. "Both concentration and percent Quarts for the application of this limn are to Be determined from the fraction oaseeng a aizwsoiector with the (chewing cnaractensties: 'Containing <t% quartz: If >i% quarts, use quartz limit, 8 Hour Time Weighted Averages and Acceptable Ceiling Concentrations Acceptable maximumpea* above we acceptable celling concentre tion foran 8-hour shin. 6641 Compliance Checklist Exposure Limits pern* mg.rw'0 Substance Exposure limits p.p.m," mgVM*" Substance... ` Expo p.p.rr rtde. so 1,1- ne ................. line -- Skin ,. 20 94 t ................. 0.1 1,000 & 5 t.' -propanol) io ig IROl................ e Azinpnoamelhyi Skin........... .. ane - Skin .. mthajene -- Skin ane) 4J0 1 5W 0.5 0.5 ccco 10 0.2 T.SC8 ! a^oiJtv1 :or.si tale Skin .. . hide ................... niemj................. uce -- Skin......... xipejpoft).. .. nice ................... ite ..................... is j.e '"O' 5. :-er;:c ................. <in............. de............... d petroleum <;:* turn* Skm........... >00 SO 1 3 5 ?0 l 0.05 -- O.T *oc :CC *A tOO 25 250 -20 5 *seo 50 0.5 -'0 300 1.3 IQ 7 Tt 1.4 0.2 2 T '0 2cC rOC 000 I u ?30 S-A 12 -2M50 *''0.3 Q.lS 0.5 0.025 1.000 45 l.SCO < 15 see Methyl *np,. $ee tf:nyi ine (propyne) . me-prooadiane APS*) ............. -- $;n esnoymethaoej /' tcohpi. see utyt earocnof 200 S,0W 1.000 1.000 ?v: too 15 1,650 1400 3.100 *12 465 Methyl isobutyl caroinoi -- Skin Meihfl isobutyl ke-^ne. see wexone ................................ C Mothyf mercaptan ............... Steen.* meinncryii; Methyl propyl ketone, so 2- 25 0.02 10 S30 100 0C5 S3 Co Methyt styrene ................... C Metnyien* Miphenv iSofi/4-JM iMOif Molybdenum: Soluble compounds............... insoluble compound*............. Mpnomethyl -- Skirt , C Monme:nyi hy*j(i2ifi -- Skm wo'd^oi'rta -- S*tin Na#tuf*4 {COS! 14*}......................... Naphthalene ..................... Nickel carbonyl ......................... Nickel, metal and soluble too 002 2 02 20 too 1C 0.091 460 02 5 15 9 0 25 20 Nicotirve -- Stdn ................... Nitric acid .................................. Nitric oxide ............................. p-Nitroaniiina -- 8km............... Nitrobenzene -- Skm .......... p-Nitrocnlerobertzene -- Skin . Nivoethane.................................. Nitrogen doxJ.......................... Nitrogen tnfluorice..................... Nitrogiycenn -- sum................. N-iromethane ............................. 2.N':-;c.*i^a^e Nitroiciuone -- Skin............... Nitrotnchiorometnane, see ChlOfOPWrtrt ............... OctacnioronspnthaJon Skin -- 2 25 1 1 -- 100 5 to <3.2 100 25 5 'OsmiumOil mist, mineral................... Tat^m^................. atc add.................................. Oxygen drftuorige................. 020*9 ............................... Paraquat -- Skm....................... Parathton -- $*w....................... Pentaborane ................................ -- Skift . .Pentachioronaphthaiene -- Skin Pemecworophenoi 2-Peruanone ............................. Perehtcrometnyi mercaptan .. Perchioryt fluoride..................... " a.sv11*>q4 issrjra? 0.05 0.1 0 005 OCD 200 0,1 a 5C0 p-Pfienyiene diamine -- Skin .. Phenyl ether {vapor) ................. Phenyl etrter-Bipherty? mixture <r*por) ..................... Phenyiethyieno. see Siyrene ... Phenyl giycidyi ether (PGE) ... Phenyihydrazin -- Skin........... Phescnn (Mevinpnos't -- Sum Phosgene Phosphine Phosphoric ) Phosphorus Phosphorus Phosphorus 10 s 0.1 03 0.5 5 30 6 5 1 310 9 29 259 sc 3C 30 O.t 2.250 5 3632 1 0.1 0.2 OS S' s?8 ,a ?o;c3 0.1 7 00 22 3.1 94 0.4 ,1 0.1 1 t 3 Proeyne, see Methylacerylane , *-- Pyreihrum ........ ............. -- Pyritfne Cumene f '- - 0.1 K3X SKiix .............. f&odium. Metal -fume and . -' dusts, as fth ....................k/;v. i floienona Selenium Selenium Stiver, metal ana soluble '1 compounds ............................ ' Sodium fluerdtcetate (1060) -- Skin ........................................ Sodium hydroxide................. SHB*w........................................ ,*... Stoddard solvent ................... - O.t 500 Strychnine....... ............................. -- Sulfur dioxide ............................ 5 Sulfur hexafluoride ................. Sutturic acid................................ Sulfur monpchioride Sulfur pewaftuorifle SullyryI uorie ... 1400 -- 1 04; S Systox. see enteton* 2.4.ST.......................... Tantalum......... .......... 7S0P -- Skin ......... Tellurium Teffurtcrm O.C; TPP -- SWn .............................. C Terphenyta ............................ 1,1.1,2-Ttranloro-2 2>difKtoro- i.t.2.2*te/acnLoro-l i-diHuwo- SOC 500 t,i.24*rracht roethane -- Tetrachtoroeihytene. see Per- cftisroetftpteNs ...__ -- Teirachiorcmesriane, see Carbon tetrachloride............. TecraeMoronaphtnaiene -- Skin Tetraethyl teaq (as Pb) -- Skin 7er;anvflrofuran Tetrameihyl lead (as Pb) -- $in ........................................... Tetramethyl sucdnonitrile--- Skin ......................................... . Tetranitromeftano ..................... Tetiyl {2,44^rinrtrophOrtyl* 2CC 04 1 methyinllrarttlne? -- Skin ,,. Thallium (soluble compound*) -- SXfrt a* Tt ........................ Thiram........... ................................ Tin (Inorganic cmpds, except ........................... Tin iorgsnlc c:*!pd5) C 'ciusr-e-J.J.-'isarysnats >?0tui*rte -- 8km................... Toxaphene. se Chlorinated eamphene ................................ Tributyi phosphate . -.:............... 00 5 = -yli '.1 1 -7?;C'ioro*'r'ar". see Methyl cn;o.-.o.*m t.i. 2-T-ichi o.-o ano -- S*-n Titan-urn 3<cx:5i .. &B4 Trrcnioromethne. see t>,{ftroft>rm........................... DECEMBER 1976 Reference: 1910.1009, OSHA General Industry Standard*. {teens (Kit apply most direcily fo ihe asnestuos in dustry appear in red. Sxposuro Limits Substance p.p m * mg7M,B --..,, Acetaldehyde .................................. Acetic SOi'J Aeeric ajwyd^ae........................... Acetone 300 iC 5 * con 40 350 '5 20 2 400 70 Acetylene dichioHde. see t. 2-0ichloroe*hyl*ne.................... Acetylene tetreoromifle............... Acrolein.............................................. Acsviamide --* Skin...................... Acrylonitrile -- saft............... Aldrtn -- Sn................................ Ailyi aKonoi -- SUn.................... AHyl chloride . ......................... Z AJIyt giyciOyi ether (AGE) Ally) propyl dlsuitide.................... ^-AmjnceL'iar'ai, $e _ 1 0.1 -- 20 _ 2 1 to 2 -- 14 0.25 3.3 45 0.25 5 3 45 12 ... 2-Ammcpyridine............................. Ammonium SviJamace ;AmmalCj n>Amyl acS'S' aec-Amyl acetwe...................... Aniline -- Skin ........................ Anrtldsne (o, p-isemers) -- Skm 0.5 oO ~ ICC 125 5 -- 2 JO i5 525 5 19 0.5 A ntiirony and -ompovnes (ss 5t>s ANTU (aipha naphthyl thiourea) Areenlc and compounds (as As) Arsine ............................... .......... Arinpnoa-fnethyf -- $k)n ,. .. BaHym (soluble compounds) . p-Sonrooumf.r'e. See Ciumone SrtTiO'i ^9'2Kt& Benzyl cniorfde........................ Biphenyl, see Diphenyl........... Bisphenci a, 3** D<9?ycu3fi effier Soron side................................ C Boron trlHuprtde..................... Bromme........................................ Brwnoform -- Skin..................... Butadiene it.3-bu{*C'ne) Sutanethiot. see fiutyf mercaptan................................ 2-Butaneno 2-Sutoxy omare? ^Suryi CeiiosoJ<#> -- Sxm 3utyi acetate acetsts) aec-Boiyi acetate .:en-Butyi aceiato BuJyf alcohol sac-Butyi aiconoi :er?-9uiyi aiCpnot C ButyWmme -- SKm............... C tert-Butyl chromate (as CrOJ -- Stun ....................... .'vRiiiyi oi.eicvi ether i^5Gc^ Butyl mercapt'an ....................... p-ien-SutyiKKuene..................... Calcium arsenate....................... Calcium oxide.............................. Camphor .................................. CsrOdiyt (5eWrt> .................... -- -- --. 005 ? d.t O.S i.OCC _ 200 50 150 300 200 too ' 5v iOO 5 __ 50 19 10 -- 2 "1... Oi 0,3 O.S 0.2 0.2 0.5 15 3 0. $ 2.2D0 .. 590 240 710 950 950 300 isO 300 t5 0 ?^C 35 50 1 5 -- 5 Subvance Exposure Limits p.p.m." tngju'1 CfOJoAaiaehycp , Cumene -- $kin Cyanide (as CN) - SUn Cydoheiano C/c:oh*aai Cy--icr **anone . .. Cyeignexee..................................... Gysippenradtene............................. 2. ................................................... ODT Skin ..............................` . DDVp. see Giesiipivoa............... Oemeton* -- Skin........................ Diacursne mccnci ^.r^c-O'y- 4"netny'-2-pantanore) i.2>^aminpethane. see-. SByfenediamJne........................ Q)e*mmtrte ................................ DiBCrane ...................................... Oicx,rfphihfi(a; ... . .. p-D^t^'oeen^ene . Die" icrootjiuofometnan .. U-0ihJord-5,5*dlmemyl hydamwn ..................................... t.i-Oiehiproeihafte ..................... 1,2-Otcnioroeihviene ................... C Diphioroethyl ether ---Skirt .. Oichforomethane. see Meth*)enechioHde ................... Oichiorpmonoffuoromfithane ,.. C-M-DiChforo-t-niiroethane ... 1,2-Chchioropfopene, see Ppyfftned)shio<ide................. Dicriiorotetrafluoroethane .......... Oicnjorvos (OOVF) -- Skm .... Dieldflrt -- Sicn......................... DietftyisrrWne............................. tOielnylsrmno etnanor -- Skin . CNaehyiemer, see 5?nyf eoier . Oifiwodfbromomethane........ c &3i,ciari etinv (D05) Othydroxytienzene, see HydroQuinooa ....................... OHsobutyl ketone..................... OnsopfOpyiam/ne -- Skirt .... CKmeBtoxymeffiane, see MeftytaJ......................... Dimethyl acetamide -- Skin .. Otmemyiamine ......................... OkneQiyiaminobenzene, see Xyj'dene.................................. Oimso*yiartlne<N -dimeihye* vaiineS Skin................... 0mg(,nyioer'7ana. see Xyiene Dimethyl l.2-di&rome-2.2*dl* cMoroethyi phosphate, lOibrom) ................................ DimefftyHormamide -- Skin 5.6-OimeOyylheplanone. see Oibobuiyl ketone................. 1.1-OimethyinyGrazine -- Skin Dimethyipmhaiate .................. Dimethyisuifaia **-- Skin........... Oimerobenaene (all Isomers) -- Skin ...,',........... :.............. OlniwjH^cresol -- Skin........... DifliuoiMuene -- Skin........... D'tume (Oietfcyiene d*o*i0l ~ Sxim.................................. &n&rr! ........................... */> 2 50 30C 50 50 300 75 ~ -- ___ --- 055 50 -- 03 0.1 _ SO 75 1.000 ___ 109 206 15 1,000 to -- 1.000 -- 25 10 too 0.5 SO $ 10 10 10 95 1 0.2 245 5V 1.050 2(JO 20C t.ots 200 : 13 1 0.3 0.1 240 -- 0.4 o.t 5 300 450 4.950 0.2 400 790 90 -- 4^00 SO -- 7.000 1 0.25 rs so 850 2i 290 20 35 13 2S 3 3C 1 0.2 1,5 350 1 Substenee gtfiyKtfioe at . Dicnio'oei N*Ethyim<Kp Ferbam ... Perrovanadii - Fluoride (re Fluorine . FluowieftK Formk. acid Furfural -- furturyi alC Gtycido) .(2. GiycW.mono 2*thaye GuiMon*/,- MiCfMUffl'..'. Heotacnior Heptane Hexacnieroe Hexeenlow Hexane (ni 2-Hexanone Hexane (Mj w*se*r* Hyanne Hydrogen 0 C Hydrogen Hydrogen d> Hydrogen pr hydrogen Kydru!no< G iodine . iron wde i Isoamy isoanyi a>o i *050?/! ac Isaouly' ** tsephorona tsou'ooyi iiocropy1 a '4sapre&y'U&r fscprapyiefr iiocrcpyi s! Kerens ... Load arson Lindane -- Lithium hyt U G. (ilejui gas .... Magnesium Walathion M*i4<c vrv C ttangane Wsi:yi si uemanethh mercapia Methoxyen: 2-Memax ' Csnosoi- Ueshy' ace Methyl acet Methyl 80S! mixture f .uainyJ so'/ Methyls) {d 853?Meir.y* sz: Methyl i* Methyl |n*r Heptane* 7.500 ICO $.100 1.5 560 10 0 2-- y ie 4, % Malaga! weighted average ce>nnj coneemration Coreamration duration Banseoe (237.4-1960) .................................. Beryllium a"d beryllium compounds (207 29*1970)................................................. Cadrr*m Sums f237.S-19701....................... Cadmium d (237.5-t97fl)....................... Carbon <$isu< !237.3-'966).................... Cj.'ocr er*scMcr.je '237 ir-'W''; Chromic acd and ehromates (237,7-1971) Ethylene Oromrde (237.0t-T970)............. E-^iese oicrs price iZ37 5'>tWJ> Fluoride as duet (237.28-19>.................... rs-naioenyce 'Z3i.!o-;90) Hydrogen fluoride (237.28*1969) ............... Hydrogen sulfide (237 2*1966) {............... TO p.p.m 2 m.IW 0.) mg./M* 0.2 mg.pi*1 20 p.pj?* TO p.p m 20 p.p.m 50?.? 2.5 3 o ya do ;.$ 4>C 'IS morgsmc compour'CS 237 V'isea. Mercury (237 9-1971) .................................... Methyl chloride (237.10*1969) ............... 0.7 m :u -- 10*0 p.p.m Vit-ys-# :r sr.oe '237 3'1965: Co om Organo (alky!) mercury (237.30*1969) .... 0.01 my./M4 3 a (23* :5-:545) :0c 5 v * Tetrachioroethytens (237.22*1967) .... do Toiuo"* ;t:' :-f 96?! 'tin o/;!n;,*:*o |Z37:3.:J6': 200 5 o m JO 25 p.p.m 50pp.ro TO minutes. Sm9-W;i 3 mg.(MJ 0.6 mgVM1 30 p.p.m 25 s o m do 30 p.p.m 100 p s? _ a p on -- 20 pp.ra 25 m9-^ _ -- 100 pp.ro SCO p pm 50p.pjm 230 p p.m 10ppm -- 50 p.p.m 30 minutes. Do, 5 mmuie* m any - hours 5 minutes. 5ra:m*t#S in Shy 3 noun*. * 3C minutes. . .*' 10 minutes once only If no cmer measur able exposure occurs. 1 mg.ftOM* 200 p.pm 1 000 p.m 0.04 mg.Ar 200 pom so 20C p nm cc -- -- 300pp.ro , 2.0M cpm -- 60C p o ta / do 500 p.o m 3C0pp m $ minutes in any 3 hours. -*_ S minutea in an? 2 hojrs 5 mwas m any 3 hours. 5 minutes In any 3 hours. id minutes 5 minutes >n anu 2 hours. E PROTECTION ed Reference re Extinguishers 1910.157 and Hose Systems 1910.158 SpririWer "Systems T9T&7T59 -hemicaf shing Systems 1910.160 oxide Extinguishing 1910.161 Alarm Signaling 1910.163 ELECTRICAL REQUIREMENTS Refonttct: 1910409 (a) The requirement contained in the follow ing articles end sections of the National Electrical Code, NFPA No. 70-1971; ANSI Cl1971 (Rev. of Cl -I960) shall apply to all electrical installations and utilization equipment: Articles; SQ0 Hazardous Locations. 501 Class i Installations (Hazardous Locations). 502 Class il Installations (Hazardous Locations). 503 Class HI Installation! (Hazardous Locations}. Sections: 230-SS equipment on Structure Mstal. 250-59 fa), (to), Portable andfer Cord Connected and and <c). Plus Connected Equipment Grounding Matted. 400-3 (*)(&). Flexible Cords and Cable. Uses. 400-4 Flexible Cords and Cable Prohibited. 400-5 Flexible Cords and Cables. Splices. 400-9 Overcurreiti Protection and Ampacities of Flexible Cords. 410-10 Pull al Joints and Terminals cl Flexible Cords and Cables. 422-0 Installation, Appliances w/RexiWe Cords 422-9 Installation, Portable Immersion Healers. 422-10 Installation, Appliances Adjacent to Com- basilWe Material. 422-11 Stands lor Portable Appliances. l/vnAA CC A Cl 422-12 Signals ter HeeledAppliances. ** * O D 4} ! 422-14 Water Heaters. 422-15 (a). (b). installation of infrared Lamp and Indus- a 2' el** -- Sk>n . aceijsr* -- form.................... xane .............. jWioI................. oe*aJWie -- Skin ;Mc^' 8 ....................... -- Skin ... 25 'A 350 500 500 3 90 120 T.S00 i?Q w~ 250 23 ! >c*e ac:c --- S*m 5 Prvil' (2'P:valyl*1.3> l iriflaoeians) ............. I PJaurtom (Soluble SaJfsl as Progeny* a<cWi -- &on............. 1 Propane............................... i.OGO rv.Pre?/' 3=!4T . 'i3y; a:csnol 200 20C jvPronyl Pt&Qylene oicf!oa............... 25 75 Propylene imme --* Sfc<n............. 2 Propylene oxide......................... 100 01 01 0.002 i no MU 12,3>TKenicrooros* i* 1.:.2>rchi(5 i.2,2-io!tuct<K ................................... TnemyUnwne ............................ TnllwofQmenoflfoenetwethsne ,. 2,4,5*TrtftitfOpftftOl, *ee PiCrtc 2,4,5-Trfnitrophenylmet.hyrniu-amm*. see Teiryl............. -- Skin............ T-.s^noc^asyS gnosest . Tf:op.ny! pfcosonara .............. Turpentine ................................ so 1,000 25 1,000 -- ...,, 100 HowTo UseThis Checklist > various sections within this chart represent as designated under the Occupational Safety i Health Act as crucial to the safe operation of jr plant. To see how your plant measures up to HA standards, evaluate conditions in each of areas that appear on this checklist. The reences Indicate the sections of the Act that ily. This checklist does not represent the comte scope of the Act. For specific situations not covered here, a thorough study of the compb OSHA Standards is recommended. An ongol subscription to the OSHA General industry Sh dards and interpretations and all changes as th are enacted can be obtained for $21.00. from I Occupational Safety and Health Subscription Ss vice, care of the Superintendent of Documeri US. Government' Printing Office, Washing!* D.C. 20402. .. iTIVE 1910.133 1910.134 . '/x 1910.135 t.i9io.V36 5S 1910.137 * HAZARDOUS MATERIALS Reference G Compressed Gas 1910.101 Acetylene 1910.102 "Hydrogen I9IU. 10c Oxygen Nitrous Oxide G Flammable and Combustible Liquids 1910.104 1910.105 1910.106 Spray Finishing Using Rammable and Combustible Liquids 1910.107 Dip Tanks Containing Rammable or Combustible Liquids 1910.108 Explosives and Blasting Agents 1910.109 Fi To 8e Chec l Portable ' Standpipi Automatic Fixed Dry Extingu Carbon D Z2 Chtoraace -- $xm..................... Chlorinated cempnens -- Skm . Chlorinated diphenyl oxide . . ................................. . Chlorine OMjzide.......................... C Chlorine trtHuonde................. C Chloreacetatdehyde............... a-CMo/oecotoohenone ipMnac^ctttortde)............... Cniorobensene {monochloro. pecrer*) . >Chiorot>enjyUdene maJoncnltriie {OCSM) ........... ChToreoromomethane................. 2*Chio?>t,3-Sii!3<!The, #e CMoroprene ............................ ChiwodipnenyJ {<*2 percent Chlorine) --- Skin................... Chiarodiphenyi Js* percent . ^ferine) -- $*m................... 1 .Crsisra 2.3-o3*voropsna. see i:chla-hvOnn . 3'CMoroethanoi. see Ethylene iorohydrin ............................ Chioroethyiene, see vinyl chionde.................................... C Chloroform (trichtoromeOiane! 1-CWoro-1-nitropropane ........... Ciorop*crin ................................ Cfcioroprene {2*ehioro-1 .3- Butadiene) -- Skm........... 50 -- -- -- 1 0.1 0.1 1 0.05 n 0.05 NO _ --* __ -- 50 20 O.t 25 chromous salts &a Cr............. Metal and moot, salts........... Zoa- tar piicn roiatues !Pen;ar.s S0la0!4 tftkCtiah) ahtntjcen# 9flP. pheroMhiene. cr>4i),-,3 -rrv*r-* 3!.-a Cobalt, metal (vme and dust ... Copper ftjrne .............................. Ousts and Mists..................... Cotton dust {raw)....................... Crttfl* herbidtee ......................... Cresoi (ail isomers) *-- Skin -- -- --. -- -- -- -- -- 5 ai 0.5 0.5 0.5 3 03 0. 3 03 )K 0.4 1,050 1 2*0 ICO 90 1 02 0.1 t 1 15 22 3. O'propyfone glycol methyl ether -- Skn....................... 100 O'-sac, octyl phthatate 10--2- aesytnft^ipntneiaia) ... ------- Enarin -- Sk>n ......................... Epicftlorhydem -- Skin............... EPm -- SKin................................ 1.2-Eooaypropene, *eo Ptopyteso*<be....................... 2.3-Epoxy-i-propanol, m Giyetdol ................................... EtfcantMhioi. see gthyimeicaptan Eth&iojarmns ............................. 3 2-ethoayetnaaoi -- Skin........... 200 2'S:r,o*y9*ytacsi a:0 iCedo- iv acetate) -- S>n , . 5-00 Sifiyt acetate .............. 4G0 Eifiy! acrylate -- S*in 25 E;^! aiconoi (einanoi? t Ooc Stflyiaowie___ ;......................... 50 Elayl sec-amyl ketone (5* methyi-3-neptnAe) ............. 25 Ethyl Benzene ........................... 100 Ethyl bromide............................. 200 Ethyl Botyl ketone (5- -. ' Kaptanon#) ............................. 50 Ethyl chloride............................. 1.000 Ethyl ether.................................. 0 gtftyt format# ............................. ' 100 C 6hyl mercaptan .'..................'-.'-10 " Ethyl silicate ............................. 100 Ethylene chlerohydnn -- Skin . 5 Etiyienediamine......................... EiTiyiene clpromJce. see 1,2- 10 CtiBomoethane....................... *-- *nv*ane cichio'ice. see f,2> .. ` Oichioroe'har* . C Ethylene atyeoi $irtt* tnO/ot Nrtmgfycerin -- Skin <0.2 i ftylene glycol mcnomethyl ewer acetate, see Mecnyt Ceiiosoi*-e sca;?te .-- S:pyln* imin* S>.if! ... . 0.5 E'hyleitr 0i2* . . . 50 900 5 O.t 19 0.5 ?4C 5W 105 i.SOC IS 130 05 890 230 2,900 t.2CC 300 ' 9A 18 25 >ietny. a-v hejano-i Methyl C* MeSihkiynl C. ix, Methyl cm Methylcyc'i Methficyct, o-Methykr. wetnyi *'h4 w*2-S Methyl fen Methyl (pgi 1 a a yc t PERSONAL PROTI EQUIPMENT * .1 To 8 Checked ;*N v .*' . i Q Eye and Face Protection; Respiratory Protection 0^.^eupatibnaiHead'w; -A:. Protections^.'; J - .>; *;*;r.'-.. V* '^v. J.,:%j Occupaktonjti FoptPrpfcsj EtedtHcafProteWve.bWi >d Refsr&ncs .rV.V. -arriage Disposal'*-*.*.? ` .< '' i.: -1910.143 >* 5- ;-. :. ftL SERVICES AND FIRST AID 1 * shall ensure to# ready availably nel for advice and consultation on a!to. . of an infirmary, clinic, or hospital in he workplace which is used for the Jured employees, a person or perquattiy trained to render first ate pproved by tits consulting physician ailaWa. or body of any person may bo eus corrosive materials, suitable drencNng orflushing oftheeyes and ovided within the work area for jncy use. % ? 0*1? fa3*lc}. Guarding U Part. 110-18 ii0*2t Arcing Pam. Marking. 110*23 Idanliiicalion. 240*1| (a). {&). Loeailon to Premises ((or Overeurrnt <c), and (fl). Protection Devices). 240-19 (a) and Guarding of Arcing or Suddenly Moving (b), Parts of Dvercurrent Protection Devices. 250-3 (aH&5- D.C. System Grounding. 250*5 (a)-(c). A.C. Circuits * Systems To So Grounded. 250*7 Circuits Not To Be Grounded. 233*42 {aHifK P/xedBfvipmsni Grounding, Genera}, 250*43 (W1). PixeQ Equipment Grounding. Specific. 250*44 (aMe). Nonftieotricai Equipment Grounding. 250*45 (a), {&), Equipment Conneetea by .Cord and Plug, <c). and (d). Grouting. 430*142 (aHd). Stationary Motor, Grinding. 439-143 Porteble Motors, Grounding. 250*50 <aMb). Equipment Grounding Connections. 250-51 Effectfee Gnjurttfteg. 250-57 (a)*(bj. Pfrea Equipment Method of Grounding. 422-16 Appliance Grounding. 422*ir tastaftaNon of WeS-mounted Ovens end Counter-mounted Costing Units. (b) Every new electrical installation and ait new utilization equipment installed after March 15, 1972, and every replacement, modification, or repair or rehabilitation, after March 15, 1972, of any part of any electrical installation or utilization equipment in stalled before Marti) 15, 1972, shatt be in stalled or made, and maintained, in accor dance with the Provisions of the 1271 National Electrical Code, NFPA No. 70-1971; ANSI Cl1971 (Rev. of Cl-1968). (c) Notwithstanding the provisions of para graphs <s) and (bi ct tftfs seefton, the effective date of the requirement in section 210-7 of tha National Electrical Code, that tit 15- and 20-ampere receptacle outlets on tinglephase circuits for construction sites shall have approved ground-fault circuit protection for personnel, is postponed pending reconsid eration of the requirement. Louisville iCincinnaii, Ohio Sales Office) ..................... ..............................Enierpri*222S Metropolitan Area Sales Office; Hackensack, Nj. 07601......... One University Plaza.................................. 201-646-H11 Minneapolis (Chicago, ill. Sales Office)........................................ .................... 800-621 <25)0 Moorestown, NJ 08057........... 308 Haroer Drive........................................ 609-235 6200 New York (Metropolitan Area Sale* Office; Hackensack, NJ.) .................. 212-695-5054 Philadelphia fMoorestown, NJ. Sales Office) ................................................. 215-923-3200 Pittsburgh (Moorestnwn, N J. Sates Office)......................................................412-922-5700 St. Louis IChicago, 111, SaiesOffice) ............................................................... 314-726-0324 San Prancisco (Long Seacn. CaU. Sales Office).......................................... . 8Q0'352'37S Prom Arizona, Idaho, Montana, Nevada. Oregon, Utah. ttathington, or Wyoming ........................................................................... 800-42f-3??4 Southfield, Mich. 43037 .... 26500 Northwestern Hway....................... 313-354-0800 ' Swifts 665 2 the eecepfeWe certtag cornfration foran B*hOurWtlfL j__ j Liquid psirolsum Gasss Q Anhydrous Ammonia 1910.110 1910.111 . To Be Chec<< OCCUPATIONAL NOISE EXPOSURE Reference: 1910.95 Permissible Noise Exposures' (Table G-16) Duration per day (hours) 6 .. 4 .. 3 .. 2 1%. . 1 Vi or less Sound level dBA . slow response., . 90 . 92. 97oS;r2&ci .100 .102 .105 .110 * r"' . 115 'When the daily noise exposure is composed of two or more periods of noise exposure of different levels, their combined effect should be considered, ' rather than the individual effect of each. If the sum of the following fractions: CltTi + C2/T2 . . . Cn/Tn exceeds unity, then, the mixed exposure should be considered to exceed the limit value. Cn indicates the total time of exposure at a specified noise level, and Tn indicates the total time of exposure permitted at that level. Exposure to impulsive or Impact noise should not exceed 140 dS peak sound pressure level . Reference 1910,15 (a) The employer of medical persor - matters of plate hi - V tn the absence nearproximiVto 1 . treatment of alt in .- sons'sheB be ade .First aid supples a shall be readily av ' Where the ey /exposed, to Injun facilities for quick i body shall be pi . immediate emergt Heines 12- U.S. Sates Offices Alania, Ga. 3022$..................... I? *ecud've Par* Or. Baltimore fMoorestown, N J. Ssle$Oihce).................... Boston, Mass. 02194 .................300 Firs? Ave,, NeaOham Hg. . Charlotte (Atlanta, Ga Sales OHiceI.................................................. Chicago, Ilf. 6D60B ..................... 120 South Riverside Pla?a........... Cinonnaci, Ohio 45225 .... West Street & MadijonviUc Road Ciw*lancJ. Ohio 44114............ 1300 ULaside Ave...................... Dallas, Te*as 7520?................... 2710 Scemmons Freeway.......... Octrois {Southed. Mich. Sale* Office! ....................................... Houssorv) Danas, Texes $al Oi1see)....................................... Indianapolis (Cincinnati, Ohio Saies Office) ................................ Kansas City (Chicago, Hi. Soles Office!............................. Long Beach, Calif 90S02 . . lOOOceangate. M fi . .301.944-8211 . 617-444-5400 . 704 364-1400 . 312-454.2000 . 513 272-02GG . 256-621.4200 . 254.631-0010 . 313-354-08CC 214-631-0010 fneerprise 2226 -800-621.8236 253 4350721 ^6853 1 Ptiasono'as eentasuiiias 30 tss f a -5 TrichiorOfneihane. MAUKiAL'* hHWUUntx Mil.D STORAGE To 89 Checked - Reference Q Handling Materlais-General 1910.178 Q Indoor General Storage 1910.177 2 Powered Industrial Trucks 1910.178 MACHINERY AND MACHINE GUARDING Reference Genera) Requirements To Be Checked 0 Types of Guarding 1910.212 1910.212 Q Point of Operation Guarding 1910.212 Q Barrels, Containers, Drums 1910.212 Q Exposure of Blades 1910.212 2 Anchoring of Fixed Machinery 1910.212 CarMry* UNION CARBIDE Adhesives and Sealants Materials 270 Park Avenue, New York, N.Y. 10017 PEOPLE PLANNING THE FUTURE. 1^06 6654 5 [ OiprtMy) 1 tf \ Mttftyf p1*a HSt*A0 . S.J.Kotther Publisher Adhesives Age Mary C. McMurrer sonr Adhesives Age 7kf, Occupational Safety and Health Act has far-reaching implications for all who engage in the manufacture of goods or who provide commercial services. In the adhesives industry, which is but a single segment of all U.S. industrial activity, OSHA has received a great deal of attention and has been the subject of many hours of discussion and planning within individ ual companies and by industry organizations. Nevertheless, the very scope of the Act has made its comprehension a formidable undertaking for harried manage ment In the average adhesives manufacturing company. The ev eryday concerns o? business operations, the many environmental regulations that demand compliance, and a host of hazardous material and consumer safety controls leave little of manage ment's working time for concentration on so broad and allinclusive a subject as the safety of workers in the manufacturing environment. With these considerations in mind, the staff of Adhesives Ace has undertaken to provide adhesives management with a working checklist of what is required to achieve compliance with the Occupational Safety and Health Act. In compiling this checklist, we have reviewed the provisions of the Act and have culled out those that most directly apply to such installa tions as may be found in the adhesives industry. The checklist in this fold-out insert is intended to spotlight die most common areas of safety concern for adhesives plants; it is not intended to be a complete digest of the entire Act. We strongly urge company management to obtain complete copies of the OSHA Standards, and to become familiar with them. Perhaps the best way is ro secure a subscription to the OSHA Standards service provided by the U.S. Government Prim ing Office, Washington, D.C 20402, At a one-time cost of $21.00. such a subscription furnishes a complete copy of the Act. plus all changes as they are enacted from time to time. The Adhesives Ace OSHA compliance checklist has been referenced to provide management with a guide to the sections of the Act that apply to the areas covered. With a copy of the Standards in hand, the plant manager cart tell at a glance what safety measures must be taken, and where to find the appropriate regulations. One word of caution: it is impossible to anticipate every maniifaemring .siwaiion^sad.xM&y ,p4aoi Jemx Wteca .conditions not covered by the checklist exist, a thorough search of the OSHA Standards must be carried out by plant management, in order to accurately determine specific compliance requirements. Safety in the workplace is everyone's business. We trust that this OSHA checklist will assist adhesives management in the performance of this important obligation. We at Adhesives Ace welcome the participation of the Coatings and Adhesives Materials Department of Union Carbide Corporation as the sponsor of this special fold-out OSHA com pliance checklist. The long history of devotion to high safety standards at Union Carbide makes it most appropriate for that company to join in this effort toward the achievement of higher safety standards for the entire adhesives industry. 665T> ^ . ........... _____ ____v_ , . ;jfe|S4%&A)L^bels;arepjthe-useH;s^cl^ is^Vv& ~ !*--} 2L\ 1^ ^14 tC tl&mi^killk t sj; peeled *tHiy ..................... ......____ nd''applied; ;Ali'. klVi4li.'vbkfc ^'t*"** f<x* f '|-- A i -- /> ? s AU. CONTENTS AUENWEST. SAN 01600. CALIFORNIA. 92111 Ha2arc3oUi> ' Thess:ihipping Ibrmfctfor$*se tfrfiSikj ' domestic and 'interRattohat;1*^nH'f? portation 'are *providedj;i__ . formal00 ,1 l^sKee^;,per^ ,.vShipped;Certificatjoncotc|^i^f -civs 'Not R' estricted'. Hte*c^S' PI'w^M, -isra OANQ*ii'6Q(S*.i*)!'!*K!'*E<X(I**T0HRVWEVMK>El.XL*lYU**(?-*1UI*MMI'"')'A**6**l . V>.y LIQUID MINIATUpfniEsYni^Tf^YPfiL"iArtR .;; ;?^o^EMSpf^ > aji Btm^a>(r^>;OlTrlb^iii$$otuf9d*:d3pgV^^S ' .VYabie in fotoittur&'fo? usgpnsrttpping pap"'--^ '' '.'documents.^ ;Y' MinaUJfa^iigs'VaVapproxrmate^^xfi^in^t r,', They are printedjn.me'me^dghttr^affcLpQ^ ';: .same pressurV&enstive.'stoCk.a'i'sia'nd^rall^^^' * -.'labets'Y'and'are' provid9<ijn5Kandv&liso$ris&r; H^.t500;iabe! V^Y^Or^as.^Uem^Ptr^pCst^. .* C'Ylithe #pe of '0.0-X*tlB^a?,8ftown|Sfg^Sj ' the ;rterh^number.^(Xjrhir^^M5jr^'' altonwgsc AIL CONTENTS 19?8 ALLEN WEST. SAN OJSOO. CALtPORNiA. 92111 ALL CONTENTS *W7* ALLENWEST, SAN DJGO,CAUfOHNIA, Ml< 5 Aiienwest'-offer5:^fiSjarge\^8eieco^5#iP4iat^afe%oyidi^^)p,^>r.a50^rol!* preSSureile^iti-^rninsfae^^||i|:|^^pgr!^^M?jp^d2,* shipping'Mtems?W(iich'-if^Uire:sdeiicMelrijig<jJpgeSf>grfic^^p|telWS|ftt|Ss|'^f.jj;ys;.^i DcJCATS SN5TSUWE-NTS eush W0*JI SDPfUcS tSEKOHESi 1 ALL CONTENTS 1975 ALLSNWEST. SAN DIEGO, CALIFORNIA, 92111 llinwit Inc. 8245 Ronson Road, San Diego, CA 92111 (714) 58S-8686 LABELING SYSTEMS for shipping Hazardous Materials PRICE LIST Effective May, 1978 Our pricing structure may change in the future, so we will update this information from time to time. If there is a pricing change at the time of your order, we wifi advise you before work is started- See Order Form for Terms &. Conditions tflenweafe ins. 2245 Ronson Road, San Diego, CA 92111 (714) 565-8666 \BELS ~*TAGS *SILKSCREEN PRICE LIST for hazardous materials MAY 1978 page 2 *METALPHOTO PHOTO ETCH D.O.T. LAB SIS ITEM NUMBER D-1 Uvu D-27 tcxcxpl 02$) 025 025 S90 12.75 LOT 1550 LOT 14.75 LOT 1M 19.75 M 27.00 M 21.7$ M 3M 13.90 M 24.50 M 1550 M SM 1145 M 19.73 M 13.70 M 12M 1039 M 13.45 M 12.78 M 24W 935 M 17.20 M 11.70 M 43M 9.40 M 10,10 M 11,43 M SHIPPING DOCUMENTS ITEM 100 STM. S02. 503 t. LOT 200 24.65 LOT (Lor price# MM on rojm&er o( sneets 100 shaew per pM,} S j 1M 44.50 LOT | $4.45 LOT 2500 144,< LOT SM 261.90 LOT 19M 433.00 LOT MINIATURE D.O.T. FLAGS (Minimum OMer: 5 Poms) ITEM DF-1 to 0?*28 5-WaOXBS'- 759 BOX OVER 19 BOXBfc 7,39 BOX D.O.T. LABEL SUPPLY BOX fTEM D-lOO-A 14 18.SS 44. CMOO-W *n0 D-1C0-R 19.6$ aa. D-100-W $ 13.20 aa. 16 95 44. 18.10 m. 10-24 14.95 64. 13.90 ea. 17.10 ea. 25-29 14.1Om. 14,95 ea. 15.95 a. 100 - UP 12.93 aa. 14.20 6ft 16.10 aa. ORM-D-A1R, STANDARD ORM, & LIMITED QUANTITY LABELS ITEM oa-l 50 Ofi-22 1M 0.95 M 2M 7.30 M 3M 6.90 M 6M 45M 12E 5.53 M SHIPPING NAME LABELS ITEM SM SN-J to SN-35 9.7$ LOT 1M 7.50 M 3U 6.60 M 6M 6.20 M 12M 5.25 U 24M 4.M ?4M 4,45 M 4GM 4.45 M 48M 3.9$ M D.O.T. PLACARD SUPPLY BOX ITEM Df-100-T (TAGS) QSMCO-L (LASSLS) i 1 1 29.00 aa. 42.60 aa . - ?4 25.90 ea. 36.45 aa. D.O.T. PLACARDS ITEM DFM-Tio DP-17-T QP-1-L to OP-17-L DP*16-L 160 ' 134 98. 29 aa. 19< aa. SW I0ea 2$eaa. I6ir*. 1M ea. 2t*s. 13* aa. MOO 6we aa. 20* as. 12*4 as, 25-99 23.35 aa 3565 aa. OVER 100 22.43 aa. 33.48 aa. 5U 7sea. 19*4 aa. 12* as. 'OM 6vr aa. 13* a il aa. 25M 66 aa. m*aa. 104 aa. S245 Ronson Road, San Diego, CA 92111 (714) 5$5-8866 'SPECIAL HANDLING'* LABELS ITFM 0*29 to 0-34; n.TT m nsvi- -i n.n 0-40 and D*44 500 1 M 78 LOT 1 3.tO LOT j 0*45 to 043 0-54 0-53 0-56 18.23 LOT | 21 13 LOT | 14.73 LOT 1 ! ................... 2*.12 LOT 1M 22 45 M 57.95 M 28.55 M 33.88 M 21.74 W 38.49 W SM 19.79 M 51.90 M 25.95 M 30.95 M 15.94 M 35.96 M for hazardous materials MAY 1978 page 3 M 18,46 M 46.1Q M 24.55 M 28.89 M 14.10 M 33.47 M MM 17.65 M 48,05 M 2120 U 28.15 M 12.98 M 31.47 M ILLUSTRATIVE ` SPECIAL HANDLING'* LABELS ITEM P-1 to P-T2 SOT 15.50 LOT 1M 24.50 M .1M 2150 M INJURIOUS SUBSTANCES LABELS ITFM ij-1 50 13-12 W0 12.73 LOT 1M 17.48 M 14.78 M SM 19.73 M M 15.52 M 1?M 13.42 M s 1?M 12.23 M 2M 17.40 U Z3U 11.40 M 4SM 18.70 M 10.88 M INTERNATIONAL SHIPPING LABELS 1TFM A0 except 5N-3 i in- IN3 and W-4 1M U'5ea. 184 tt. 2500 12W 93. _ SU 9W ea. 54 ea (CM1 9 ea. 14V)4 ea. MM Wsa. 144 ea. SOU 7\* ea. t3 ea. 100M 7e ea. 134 44. U.S. CUSTOMS LAE ELS TTFM C-i 1U 55.00 M C-2 3500 M 2C 4600 M 21.C0M SM 40.00 M 17.80 M J0M 35.50 M 15.84 M 2SM 3150 M 12.10 M SOW 29.00 M 9.97 M 1tM 27.50 M 8.S9M BLAZERS -- Not Printed {'`Blank") fTSM e-t S-2 503 8,30 LOT I 9.80 LOT B-3 12.80 LOT B-4 16.20 LOT 1M 11.70 M 13.73 M 18.20 M 22.76 M 3M 8.43 M 9.98 M 15.15 M j 19.00 M Be suretoapecifyockoiot wlun ottering. $M 7.25 M 6.45 M 14.00 M 17.53 M 12M 3,40 M 7.48 M 12,80 M 15.95 M | | [ | ! 24M 5.75 M 8.72 M 11.80 M 14 70M BLAZERS -- Custom f>rin ted 8* sun to wcctfy stock cottr and sens tfetcft Ofblack S writs an wtefi entering. ITEM B.t i 5ST.US I 28.00 3M \ \ ins 2425 M | 26 00 M | 16.COM ISM 13.20 M ! 24M 10.20 M .13 W 7.2SM e-2 28.ca 28.60 M | 2345 M j 18.SSM 1543 M 11.90 M 1 8.48 M B-3 26.00 [ 46 $0 U 34.00 M | 27.80 M 22 60 M 18.80 M 14,00 M RRRe-4 28.00 66.65 M 42 44 M | 34.39 M 26.48 M 23.52 M | 17.46 M uuo 'sllenwsst Ins. 8245 Ronson Road, San Diego', 0A 92111 (714) 565-8566 PRICE LIST for hazardous materials MAY 1978 page 4 ZIsA ....... fN ftj I ITEM NO. 1 DESCRIPTION 1 BCS | ?j >C$ i>89 *Ct JMflCsl [ S<i2 * Ttvs Door to Femem t.2S j tOO ea 1 ** $3 *a i ITSMNO. APSCfUBTIAN Safety S<$r.$ i *PCS 1 *0>rc MS 1.3Q ea 100 PCS t.00 M ITEM NO. DESCRIPTION 10M :c:v 1 3908 5000 s&cc [ 10.000 12900 20.000 24.000 48.000 5ft 0 S-tS Paci*5 I'V. EruewpM 23.00 tel 22 CO 21.00 it M lS 1S.00 1 ta.50 1200 17.50 17.00 1300 1540 M __ M 1 M_____ ___W___ _ M___ __ U____ __ M_ M i aoci <s Prices shown are tor BLUE imprinting. For priming red. green, Mac* or brown. add ick Oink dfllPFJPava LAt3ci-& charge. For 2-ceipr labels, increase set-oe and prises by 20*. 100.000 14.50 .M ITEM NO. S>t SS-2 rpRrnPTn* Shipping label* 1 ret.<>o rx* bo p ITywJ. 12.50 fPittav 1SC0 son 15.95 lot 1000 27.50 Spl 2000 24.50 M snnes 2272 M 10.009 2t.5< M isrwn 21.07 M 25.900 2040 M An,,-DT|.,wr, ( A ci c Prices are for WHITE GLOSS stock only. For other stocks, increase prices by 20%. tn Md.fMLa uMo._ts Specify stock type and ink color when ordering, if sendwtg an. piste charge is 15.00. ITEM NO. 5*3 5*4 S*5 S*6 OESCfltPTION -:v .a:*!* s>:e ; \l' AC' iSMIS S.JC ' ACv ifl'hflS Sv: V,"jj : --5 > is seis tica v:"y >' SPT-li CHARGE {Tyoey 1259 -m*i i*m (Type). 12SO fp!arv teoo (Type)' *2.50 #*% (Type)* >2.50 stTM ism 1 JfWO JtOO 33 50 3550 - 2000 25.50 M 2? 50 M 29 50 M -- sooo 12 50 u 1500 *4 -- 12.30 M 10,000 7.50 M 9.50 M -- 10.30 u 1S.0O9 350 V 6.9Q M n 7.50 U 20,000 4.90 u 610 M - 640 M 25.000 4.10 M 5.70 M -- 600 M SHIPPING TAGS liE ffUMBBK 1 Minimum 0<V&r: 5.000 May oe grouped teener, minimum of 1M o( each type j-cs^-osaienc.->i*Mot 1t mxaivmiis.*aM 8 70 M 5.80 M I' 2 9.9CM 7 CO M 3 52 6S M 825 M 4 * 13 95M 995W i 5 15.10 M 1090 M j 6 TTW l 'te:53' \ 8 24.40 W 14SSM | 14.70 M 18 05 M I750M 10.00 m I9 75M Z\M4t 22 00M 15 SOM 1" 00 M 18.30 M 20.10 M 2085 M ........ 2615 M COMPRESSED GAS LABELS AND TAGS ITEM NO. G'i thru G-17 G-19 M-P, T-2-A-P anff T.J-S-P DESCRIPTION Gas C^-nspr Lace;s 0i5ijef Laoef Co^;*essert Css Tjs$ .... H .?> SET UP ?2.50ea copy none Oort# 12.50 1000 25 00 tot 70 00 lot 35.00 tot 7500 10) nooo soon 50 00 40.00 MM --3T5T" L WXb MM 3000 M 40 00 M 2850 M 37.00 M soon 39.00 M 2700 M 36.00 M 10.000 32.00 M 51.50 M 29.00 M 3500 U 15.000 3" 00 M \W" M wooo 36.00 M " -- --- 25.000 35.00 M ti.A6 M - - For aSi special "custom/* items. piaase sene 2 skater- fiestaitng color scheme ar.fi layout (and black & white, camera-ready an if you nave j*>, and information rsgan 3 s^=. tyoe oi stock, colors. type of packaging (pieces, strips, or rolls) ana QUANTITY. We will be happy !0 can or wr.te C^c^ with a q^offihCn && 6Spy FRAGILE THIS m\ ENO wmsmmSSSilfc special: i handling;fpfoC6durci^Wacteri^^g these original Ailenwestjahei|Sj^^^^^^ ..* Printed (a'bright:coior8rcri'wh%^PreSllfe^^! .sensitive material?.';al11abe)s'fn$a^ and are provided '^)0 f?6r/oij5|^ r AH `This! End"Up;^iab>1s/hIVeTdgtt^ THIS END printed at top' to,'iricftcateiRO^tfeW^ciiig&g over, the top'carionjeJgegFJl .insure correctJ1rii$>nd u*pyor)enta^P^$ * Oiffereht styiesXWafcbe;;*grouped;'&i~...r.A for Quantity price'breato-MInlitiflj^idfSopjaWijia' THIS END i&lri F S0it2, Vi's? tTHIS ENO ..... UP...... ^5TO mVEST S^LL>6? Vi>i .All labflfef in stock' rt-j SMlSt? 00 NOT FREEZE litimediate . ^r^<#^src5 dehyef^iyiH: rfi... ^ fe'i'S*:' *<3p v,$ i Naamo^feym KEEP DRY 'SJtr- jftg Y; yvv KEEP FROM MOISTURE .................... '. l3 '-*~VW'< S iv/'L"IA irS'fVa.^. _*i:i i- .-***; :Primed In black on :^gn^e]lo*iy3ny1^e$fe.^8bJs^j^it requirehinisTor labeling'ofJOjurtbu^'Sot^taH^esf^^^ .. * LabelsmeaSure^^S'^^^ styles ahownVape stock jterns.aHdmayjbeorouped* :price KEEP FROM -iA" RUSgJ IM# ^>1IIM ?s$cts mwm mmsMMZ it(n i.i.i Titmbihihhi Cjni UMmttMBXMMtlW'at MM'UMm* *MM MM10 WDfl Maa. 3,104 XWB01M01. ;;!cu5tom'b^[s:wriie7^Wc^^;;3^V%.-k#vii vJ'C rwi <nr<>uM >* iwitM mama, MNWM Mrtcarawsnu toM 0QI080 *9*'"'* 0 r*M*. G0trcci v>1A IUMmi OtnWM Mtuumiwann uviim'"iiii Outn^iti mu B11CBC1 tli*v*uwl tmi (&(ieo.?<i> maAnw3> MumMaiBOJ H UBflBBIH nwtWMBiHm DMO'M #*)MBMairaMlMM tons ibw>M la 18 nwir. 10 mid nr J1MM0. fl*A TmoummiMoa* W*4> VtBAI MWti M*Mr <Mt1 OOBOMII *MMg"iim3,B.w>!mf n"B tfuau. ** me** ombbs 6"*UWrBMT, <1BJ*** fTM-*0 naomt. HM4 MMT "01 **0*"fl*** (wsBumnnBt Vu rMe umu mbbuoa UM W|W>H * 'MM 60UBM MV. tee ;-s WOM pdilBtl 0*MS9A< eM1 Bi*mae* U*T M i*~J ' <aJOOJ MB *J ICO-- BUI. >UV<1 MM* mv tn*1-** mom A^J UI9MM00 M ~K<M* awuewilnu^ OMOB8IV C*W*4M* MtetlMfWIIB VMMiM *M*4ir eo*4arvi m*T MiH ))U-i"l~] 6M'H* SBr UMM* sr * }&MMB0nOMiIMMUBSSnMu#f.nMBH* UHI fWA,I IMM0.IMBMMW >'^.j. tn wwuititfHn.lM. (MOAJ1 lltfnMX ..i >MBiTWnitVTvb;yinbB7m;l(Kimnlvwin'rm-ir.rH.>..... intuSMtaHlWM' >r iiMMaaUMB4,,9iMgWw0'MMitB*>v>.l<fUciime'T ------------- TO a6tnfBiMi(4Xir-Bajfft. 'S., '^wm ALL CONTENTS *1970 ALLENWEST. SAN DIEGO, CALIFORNIA. 9SH1 ><ae-I^ije>BAu>o -bom.UUAHCa11nuUofmtmMboO. fM K4te B- <I0M W W n* fti**. unnuwMM VrtMB0iaMH.*>nviC1 tMM UlTlIQK IOMVM fWBMS MIlUA f $Ki''r';a'SAS*!ciy3i/$C5' m *mi *%&& iif?.*;' :s53 rfcx 6 A%,v*i2H'? 8 ... . COMP-RESSED2GA: ';>V'*B^rComfxeb^Gas la&ais are.printedw*- * v*% ^3Q^5^MeQ3i^3^^B5CS^ieSC?K!3!53rlS*S??S?ra<i? "'"ife' '<S?v50*4i'6fB6n De*wwOJ*`*'C&oljlnoSi.'PQw1&&*aV-lC?BruMrwo W^ s****' ^Sr,*<*>* ---- gSUra.'g>`** ....,. a-- *r~ > ' >.?' ^KiSi5 um'i ,i.i( i`.;i.i' Am utmtsr. aiMoaao.e* EMPTY im&*+*to H4BMU INUSE iiObB~B1i ~IBn~~to>tnlftliBrUnBrrr FULL uMMtMiittooBi iIB*(IMUt<o m&s&. iiV-v AU CONTENTS 19"S ALLENWEST, SAN DIEGO, CALIFORNIA. 92111 *llWt Ine. : HOW TO ORDER: Please enclose full payment with all orders, OR send 5 cr< references. We may ship C.O.D. 245 Ronson Road, San Dfego, CA 92111 (714) 555-8688 NOTE: we wjn pay shipping charges on ail orders accompar by a check for payment in full. For custom or personalized items, attach a sketch with or showing exact wording and layout Specify either ALL 0/ or UpperA-Ower case tetters. ORDER FORM Indicate choice of stock and ink color where available. MINIMUM ORDER: S10.00 ' SILLING ADDRESS: " SHIPPING ADDRESS Customer Name Customer Name Sxeet Aacress Street Address C'ly. State. Zip Cose Cay:"SMtOfpCM# Pfi&ft* N. P-jrcnas* Orasr NO. Phone Kjo* Ordered by Signatured Buyer mu oflosas must as sionsoi Date Signed rsw \o 05 SC? i*?! ON STOCX ?YS tNK COLO* QUANTITY YsrS NO UNIT PRICE TOTAL FftICE plus SET-ur | | . TERMS & CONDITIONS orderStO.OO net 3D flays ount to aJf rated Others are to send heaewrene* vttf rf)|0M!QA. manceneos> *ap-eitj*Osew*e.on*C*erv*own*tea-c* s aa rut iueeniflc<Tefl- a***1"** tmremWareene oivciawp* 9i# 4 St# f#MO*hr of M puns'**' *> to* *Ares 9i tf*#*# jwpowm fftreu^ mi us# reiav.3. w>9sn 00 a* s*fl*a 10 r(Msc#n*n: oi etteMx Uito#r no eoeomcunats mu AJten#tt o# hs i$ti s > tor ret*##, dioitQM. o1Wf ortw hbwm wnst mry fty iM a* our preeuet. Proexrere may not o returns * Rn#e ixxcw from ow office. Sa#cfl&a6otu. rn are Jua**ct re cnane# mreoui notie#. Check Enclosed Q 5 Credit References Sncf (Please check creflrt) O Ship C.O.D. if necessary O? rrs\*s SUB TOTAL OF SET-UPS TAX TOTAL ORDER 3?} 66fi^ TO AVOID TEARING CATALOG. PHOTOCC TWIS PAGE OS SEND FOB ADDITION* ORDER FOAMS. PACO TEXTURES CDRP 105? COMMERCIAL ST SAN CARLOS CA 94070 C over Photograph. "S w irl T exture" , b y Ri.ee H epler -- courtesy o f th e BeJ A ire Sands H otel, U 4 6 J S unset Boulevard. L o s Angeles, CaBfomJe SWIRL TEXTURE This pattern is created by applying a heavy coat of texture material to the wall and then swirling the texture in an even pattern with a large, round floor'waxing brush. \Un&& 6671 DRYWALL INDUSTRY TRUST FUND 9800 South Sepulveda Boulevard -- Suite 722 Los Angeles, California 90045 (213)776`45$5/(415)568-4060 BOARD OF TRUSTEES: Darrell Blackwell Roger LoftBeld Charles R. Brown James Marsh Ralph Butcher John Marton David R. Capelti Raymond C. Mills Bernard Carroll Robert F. Paquette Louis E. Croy Edward Ryan Thomas Flyrm Henry J. Silva Albert Fries Bill Spence Maurice Janneck, Chairman H. Joe Thayer STAFF: Robert N. Gulick Executive Director Ronald J. Becht Northern Area Representative Frank J, Dave Southern Area Representative Stuart Oreek Froject Manager Russ Hepler Photography Roy Schramm Art Work k'm&g? 667. COMMON TEXTURES USED IN CALIFORNIA SKIP TROWEL KNOCKDOWN SPLATTER FOG ORANGE PEEL FOG AND SPLATTER ROLLER TEXTURE CEILING TEXTURE (HEAVY FINISH) 66*7 3 : '7- .'.:srr;=R* INTRODUCTION^ -This brochure hasT^h~pjp&c*3^ the users of gypsunvdrvwal! sv&emsbythe1&R^ INDUSTRY most common The DRYWALL INDUSTRY T^|^Nto-mlip^^g^= sires to. expose Urchit^s;*Spel5ifi^S6^n^|i^^^^Ji4?l^ teams, and huH^r^.to-th^ that -.they 'ciih <x>mmumcit^ desired ^x^rg**finishfjfor ^INAnD^eUxSteTnsOiveYs/uTr^Ry USTTSUNK^J^^I^l^eB^--^^sS^H'"S"1_SV>sS_*i 7dons';pfSh^'Msieg?x&r#^&@llMre1&^3u^g|||^ ^envision'for your ~we would,s"uggsf : :v>id ;doc^m5i^7^aJ^]^figdp^3^Mde|l5ji -: specxfications'of'She'l^iurf 7; ' 'Whether vou's^i^bneS^fe youlspecify ;anotS^;(ybU;Ayinjaxi^^i}l^b]^tC|ne|^rj?^|g;; ^a; r^\-- V; '.'Texture Snishes^adtthe^0ucBto^g5T^^^?'MlStl board. The proper joint' treatniehtl^>'^*^s^^i^lthsuru=&T^p *^iyfimshih*g-t6u^l?Cbihpa^^7^t*^i^g^c^herj^^p ,' bbmWoh 'iibobk /the'size ^contractor in- the;idbli:area'6trthaf^ r:X *;- * * '~i*-4' ; ~ -'."*.-'^T i- ,\-^=Tvi-vr you'solve.yowprobl^^-jgs SKIP TROWEL Skip Trowel texture is the basic rough texture for walls that is hand applied in a one-coat operation. The material used is joint cement or & manufactured texture with sand added to produce the rough effect The tex ture shown is a common pattern produced. Variations for special effects can be achieved by changing the amount of texture applied and varying the depth of the pattern. lCm3e> RR7T I I KNOCK DOWN Knock Down is the basic rough texture that is applied with special spray equipment. The material used is a manufactured spray texture. After spray application the texture is knocked down with a clean wide knife to pro duce the desired effect. Variations on this basic result can be achieved with the spray equipment, the amount of materia] applied, and the hand finishing treatment. SPLATTER Spray gun applied, the material is a manufactured product produced to achieve this texture. The pattern shown in the photo can vary in sire and coverage. The specifier should indicate size and depth of the pattern, (i.e., %). Approximately fifty per cent of the wall area is covered, and this is an acceptable degree of coverage. 6R7 PRIOR TO TEXTURE AFTER TEXTURE FOG A fine sprayed-on texture. After the texture is applied, the joint work will still be moderately apparent, how ever, this will not affect the finish painted wall. This texture is a manufactured product designed to achieve a light stipple finish. 6B7R ORANGE PEEL (Light) ' A W*. ORANGE PEEL. This texture is spray gun applied, with special nozzle and pressure settings to achieve the results shown. Ad ditional depth can be achieved. Specifier should indi cate a light, medium, or heavy texture finish. Samples should be submitted for approval. ORANGE PEEL (Heavy) RP7/ llflllfc .&r$m?:^ ^Res&lx'-- r,;: - ' *"455T*i&"AJ*A*;' . 'r';'I, ':sai^^tei;; ?wX.-"A " fp s|S PRIOR TO TEXTURE AFTER TEXTC/SE FOG AND SPLATTER As the name indicates, this texture is a combination of Fog and Splatter. The entire surface of the wall is covered with material The ultimate effect, after the walls have been painted, is a richer deeper appearance than the Splatter texture. i6n00 6fir*fl riAv/.Wi'P'V ROLLER TEXTURE This texture is applied with a hand roller. The results which are achieved by this method of application gives the viewer the effect of complete coverage of the gyp sum wallboard surface. The degree of texture and coverage are dependent on the amount of material applied and the type of roller used. 6RS CEILING TEXTURE (HEAVY FINISH) This texture is used for gypsum wallboard ceilings and is usually specified for residential living and sleep ing areas. Another widespread use is on concrete ceil ings of hotels, motels, and commercial structures. Formulated for ceiling application exclusively, it does not require any additional surface coating. The highlow pattern will vary from one manufacturer's material to another. When a particular pattern is desired, the contractor should be required to supply samples. ADDITIONAL TOUCH UP PLUS SANDING In addition to texture finishes shown in this brochure there are two types of surface preparations which will achieve a smooth wall surface. One is achieved with additional touch up and sanding prior to the applica tion of a proper sealer suitable for additional coatings or wall coverings. This type of finish can also be ob tained with the application of an additional coat of joint cement over the entire surface of the gypsum wallboard. 1Imfre 6fic? SURFACE PREPARATION: All wallboard Joints and nail head or screw depressions should be prepared in order to create the proper foundation for the desired texture prior to application. Concrete surfaces should be cured and be free from dirt, grease, dust, and water soluble materials and any exposed metal properly primed. Projections and offsets must be removed and voids filled flush in order to pro duce the desired results over these concrete surfaces. Preparation of the concrete surfaces shall be prescribed in the scope of work, APPLICATION: Most manufacturers require a limit in the range of air temperature prior to and during ap plication of textures. There are also some time limita tions that mustbe achieved-underslow drying conditions, RESULTS: There are degrees, depths, and surface coverage (all variables) of most of the textures de scribed in this brochure. We believe that your best Interests and those of your clients will be achieved when there is a mutual understanding of the texture you -desire M4th-thote-iho^vili.beresp<>nrible-for-heprepfir- ation and application and you are urged to require that samples be furnished for approval. This may not be necessary in situations where there is an ongoing rela tionship between purchaser and producer. VLlhM