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ONE-MILE RADIUS SURVEY AND C-8 SAMPLING REPORT WASHINGTON COUNTY, OHIO
(MARCH - JUNE 2002)
Date: August 2002
Project No.:DEWW7455 =
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`CORPORATE REMEDIATION GROUP An Alliance between
DuPont and URS Diamond
Barley Mill Plaza, Building 27 Wilmington, Delaware 19805
FONTAN ND CF!
000319
Oe.bieRadiusSurveyandC-8Samping Report
Table of Contents
TABLE OF CONTENTS
10 IRrOAUCHON. rrr rt ------------) 20 C8 AnaalndyAnsalyeticsal REPOTING ...corcurcrrccrrsrnrnrend 3.0 One-Mile Radius Survey SUMMAry OfRESUS... 4.0 Path FOWA cocoons 5.0 REFETONCES crass]
Table 1 Table2 Table3
Figure | Figue2
TABLES Summary of Ohio One-Mile Sampling Program (C-8 Sampling) OShuimomaOnrey-omfilCe-8RaAdniaulsytRiecsaildeRnetsiualltsSainmpGlrionugndwater and Surface Water RSaudmimuasrNyono-freCs-i8deAnntailayltiScaamlpRleisnuglts in Groundwater, Ohio One-mile
FIGURES Washington County, Ohio, One-mile Radius C- Results Two-mile Radius Survey and Sampling Areas
APPENDICES Appendix A One-mile Radius Well Survey Resulis--Washington County, Ohio
OF eporldoo.r 41d.331.02
--
000000332290 |
One.ie Radius Survey and C8 Samping Report
Introduction
1.0 INTRODUCTION
A multi-media consent order (Order No. GWR-2001-019) was entered into between the West Virginia Department of Environmental Protection (WVDEP), the West Virginia Department of Health and Human Resources--Bureau for Public Health (WVDHHRBPH) and DuPont on November 15, 2001 (Consent Order). The Consent Order identified a seriesofrequirements and tasks to be performed by the parties (WVDEP, WVDHHR-BPH, and DuPent) in order to determine whether there has been any impact on human health and the environment as a resultofreleases of ammonium perfluorooctanoate (C-8), CAS Number 3825-26-1, to the environment from DuPont operations at the Washington Works Facility and the associated landfills (Local, Letart, and Dry Run).
`The Consent Order established the C-8 Groundwater Investigation Steering Team (GIST) to oversee investigations and activities that will be conducted to assess the presence and extentof C-8 in drinking water, groundwater, and surface water at and around the Washington Works Facility and the Local, Letart, and Dry Run Landfills.
In addition, the Consent Order required sampling ofall surface or alluvial water intakes for public water supplies along the Ohio River in the area extending ten river miles downstream and one river mile upstream of the Washington Works Facility. The areas of investigation were to be expanded directionally,ifneeded, based on results obtained.
`The Little Hocking Water Association well field (Little Hocking) is located in Ohio on the north sideof the Ohio River immediately across from Washington Works facility. Little Hocking provides drinking water to residences and businesses in Washington County, Ohio. Groundwater sampling at the Little Hocking was first conducted in December 2001. In January 2002, upon receiving groundwater results which displayed C-8 concentrations up to 7.66 ug/L at Little Hocking, the Ohio Environmental Protection Agency (Ohio EPA) was asked to join the GIST as a non-voting member on West Virginia issues. In addition, a Memorandum of Understanding was negotiated between the Ohio EPA and DuPont that outlined investigation activities in Ohio. Based on the initial C- results obtained for Little Hocking groundwater, re-sampling was required by the GIST. Additional groundwater sampling in January and February of 2002 confirmed that C-8 had impacted the groundwater at Little Hocking. In February 2002 DuPont offered to conduct a distance-phased groundwater well and water-use survey within a one-mile radial distance from the Washington Works Facility, across the Ohio River in Washington County Ohio to evaluate the extentofthe impact from C-8. The Ohio EPA accepted the offer.
Between March 20and June 6, 2002, DuPont, through Potesta Associates, Inc. (Potesta), conducted the one-mile radius groundwater well and water-use survey in Ohio. This document presents the results of the survey:
Q Section 2 provides information on C-8 analyses and analytical reporting.
Q Section 3 presents the resuolftthse one-mile radius survey and the C-8 results for
water 2002.
samples
collected
and
analyzed
between
March
20,
2002
and
June
30,
OWHiminrgeopn.orOoFc 1.31.02
000321 1
One: RadiusSurvey and C8 Samping Reppeort
Q Section 4 presents the path forward. Q Section 5 provides references.
iInnttrroodduuccttiioonn
O-Wni_reiopgion,rtOFdoJcu 31,02
000322
2
One-Mie Radius Survey and C8 Samping Regen
C-8 Analyses and Analytical Reporting
2.0 C-8 ANALYSES AND ANALYTICAL REPORTING
The Quality Assurance Project Plan (QAPP; DuPont, 2002) discusses the procedures and protocols developed to ensure that project information, data, and decisions derived from or based on data acquired during the groundwater investigation at Washington Works Facility and associated landfills are technically sound, usable, and properly documented. Specifically, Sections 5, 6, and 10 present sampling protocols, sample and document custody procedures, and intemal quality control checks that were followed during the field sampling activities associated with the groundwater well and water-use survey.
The QAPP also presents information on quality assurance, calibration procedures and ofrnetqhueenacnya,lyatniaclayltimceatlhpordocaenddurtehse,pdraetcaisrieodnucctriiotenr,iaveursiefidcaftoiront,heaCn-d8rerpeoprotritnign.g aIrneformation summarized below.
In October 2001 Exygen Research, Inc. (Exygen), located in State College, Pennsylvania, developed and tested a new analytical method that utilizes Liquid Cmhertohmoadt(oLgCr/apMhSy/TMaSn)dfeomr aMnaalsysziSnpgecCt-r8omientwrayte(rLCin/MNSo/vMeSm)b.erD2u0P0o1n.t Caudrorpetnetdlyt,hiEsxygen performs all C- water sample analyses for DuPont. aErxeyegveanluraetpeodrtfsorC-p8rerceissuilotns bfoyrctohmeplaarbionrgattohrey frieeplldicsaatmeoplfeeraecshulftiteoldtshaemcpoler.resTphoensdeinrgesults laboratory replicate result:
Q Ifboth results are less than the practical quantitation limit (PQL), the replicate
sample for that analyte is considered to have passed the precision criteria.
Q fone or both results are between one and five times the PQL, the replicate is
considered the PQL.
to
have
met
the
precision
criteria
if
the
two
results
differ
by
less
than
Q [fone result is less than the PQL and the other is not andif the two results differed by a value less than the PQL the replicate is said to have met the acceptance criteria
Q Finally, ifboth results are at least five times the PQL, the replicate is considered 1r0eshulatvseims eltestshtehacrnitoerrieaquifatlhteor2e0la%t.iveTpheercRePntDdiisfftehreeanbcseo(luRtPeD)vablueetowfetehnethe two difference oftwo measurements divided by their average.
`fiWehlednsatmheplpereacnidsitohnecrliatbeorriaatoourtylirenpeldicaabtoevreesaurletsmertep,oErtxeydg.enIfrcerpitoerrtisatfhoerapvreercaigseioonfatrhee Feixncaeleldy,edw,hEexnygoenen rreespuolrtts(ftrhoemhithgehesraomfptlhe/elasbaomrpalteorayndrepllaibcoartaetpoariyr)reipsliacbaoteveretshuletsP.QL and oConrepboerlaotwe,Etnhveirreosnumletntthaalt iDsaatbaobvaeseth(eCPEDQ)Lainsdreaproertreedp.ortCe-d8arsesFuClt-s14ar3eforreccoonrsdeidstienntchye with historical results.
WOightoepno,riOcoFs 3a 3.02
~
--
000323 3
One Radius Survey and C8 Sampling Reort
C-8 Analyses and Analytical Reporting
An aliquotofeach field sample is also analyzed as a matrix spike (MS). Resultsof the MS analysis are used to assess accuracy. The MS recovery value must fall between 70 to 130%, unless the sample concentration is at least four times the amount spiked. The `maximum amount used to spike field samples is 500 ug/L. AllalbodraattaorpyacStkaangdeasrgdeOnpeerraatetdinbgyPErxocyegdeunreasre(rSeOvPi)ewaendd idna-thaouussaebifloirtyc,omuspilnigantcheecwhietchkltihset provided in the QAPP. Results of the in-house review indicate that data reported by. Exygen have been generated in compliance with the laboratory SOP, with few exceptions as noted in the individual review summaries. All data reported by Exygen have been judged usable for the purposes of the project. A subsetofthe data packages generated by Exygen (six data packages, representing 50 samples to date, including field blanks and duplicates) have been submitted to EqunavliirtoynamsesnutraalncSetarnedvairedws., ITnhce(qEuSaIl)itiynaVsaslulreayncFeorrgeev,iPeewnwnsayslvpaenrifao,rmfeordabnyiEnSdTepweintdhent guidance from the Region ITI Modifications to National Functional Guidelines for Organic Data Review [United States Environmental Protection Agency (USEPA), 1994]. Data were examined by ES] to determine the usabilityofthe analytical results and compliance relative to the QAPP and the laboratory SOPs. Results of the quality assurance review indicated that the qualityofthe data is acceptable and qualification of the data was not warranted. The quality assurance review is an ongoing process and future activities are discussed further in Section 4.
WiOnmiotgiwoen,mOeE waz
000324 7
One Radius Survey an C- Samping Repon
One-Mile Radius Survey Summary of
Results
3.0 ONE-MILE RADIUS SURVEY SUMMARY OF RESULTS
Table 1 summarizes results ofthe groundwater well and water-use survey conducted `within the Ohio one-mile radius. This table provides the summarized results of the
survey and presents the total numobfweatr er samples collected from wells, springs, and
wciastteerr.ns. It also indicates how many of these samples are from sources used for drinking
a`Tnadblsepr2ipnrgessleonctasttehdewaintahliyntitchael Orhesiuoltosnfeo-rmiwlaet.erFsoarmepalcehs scaolmlpelceteldisfterdo,mthweelslsa,mpcliseterns, identification, the sampling date, the C-8 concentration in ug/L, sample type, and `water-use comments are provided.
During the Ohio one-mile radius survey groundwater was sampled from a total of six wells at two industrial facilities. At Kraton Polymers, groundwater from four monitoring.
wells was sampled. At Price-Inland Industries groundwater was sampled from two
pmooinnittso.ring wells. Table 3 provides the C-8 results for these non-residential sampling
uses,Figure 1 shows the location of all samples included in Table 2 and Table 3. At each
sampling point shown in Figure 1, the sample identification and C-8 concentration are
noted.
(C) or
Sample identifications for
(S), respectively. All other
water samples from cisterns or springs are indicated by
sample identifications (without notation) indicate water
samples from wells. Sample identifications and C-8 concentrations colored blue indicate
drinking water sources. Sample identifications and C-8 concentrations colored black
indicate water samples that come from non-drinking water sources. Non-drinking water
uses include livestock watering, gardening and any other non-human consumption water
Appendix A provides the groundwater well and water-use survey results and includes
details such as the following:
9 Name
Q Address or physical description
Q Phone number
Q Date and time of water sample collection,ifcollected
Q Typeof sample
oO Wateruse
Q Sample identification
WOiHn-i1nrgeopno,nOtF.dJoucl. 31.02
000325 s
erie Rau Survey 3nd C- Samping Reset
Path Forward
4.0 PATH FORWARD
Based on apreliminary evaluationofthe results for the one-mile radius sampling, DuPont and the Ohio EPA mutually determined that expanding the survey area to a two-mile radius was needed. DuPont has agreed to extend the survey to a two-mile radius as
shown in Figure 2. All homes within the entire area within the two-mile radius, areas.
"A", "B", and "C" will be surveyed. In area "B" all wells, springs, and cisterns will be
sampled, regardless of use (drinking water, non-drinking water, or unused). In addition,
all drinking water, non-drinking water, and unused wells, springs, and cisterns from residences located along Township Road 97 (located within area "C"), will be sampled.
However, in area "A" and "C" wells, springs, and cisterns will only be sampledifthey are used as drinking water sources; non-drinking water and unused sources will not be
sampled.
On May 17, 2002, surveying in the expanded two-mile radius began. Upon completion
ofthe surveying and water sampling and upon receiptof finalized results, a report
documenting the results will be generated and submitted to the GIST and the Ohio EPA.
Another path forward for the two-mile radius survey task is the quality assurance review.
As indicated in Section 2.0, independent quality assurance reviewofdata packages is an
ongoing activity. It is anticipated that data packages for the two-mile radius samples will
be submitted to the validator. Results of the ongoing quality assurance will be
summarized in a future report.
hme ane
Retain
000326
On. Radius Survey 3nd C-8 Samping Report
References
5.0 REFERENCES
DuPont. 2002. January 2002 Groundwater Investigation Quality Assurance Project Plan
for Washington Works Plant Washington, WV, January 2002. DuPont Corporate
Remediation Group and URS Diamond.
USEPA. 1994. Region III Modifications to National Functional Guidelines for Organic
Data Review.
ea 7
iden
000327
000323
TABLES
000329
Ses eri
RESIDENTIAL SAMPLING FOROHIO'"MILERADIUS "511.
abrof ames wet to contgetfor sve] 301} Number of homes surveyed] 150_| `Nuofmwelblsefournd through survey] __78__|
3. r sro c e nmens antanm=eee]s y | Numobfweelrls in survey sampl4e7d_]|
Number of springs sampled that are used for wroy]
CI A de
a
-
water
J
Table 2
Summary of C-8 Analytical Results in Groundwater and Surface Water Ohio One-mile Radius Residential Sampling
[-----MileSampleID[SampleDate]_C-8ugiL] Sample Type]
[OSKANITZKP| 3/21/2002] 0803]
Well
OS-RYANSP| |OS-WILCOXENWT|
3/21/2002]
391
3/2L 1/2002] BL
3/21/2002] 0.203]
3/21/2002]NQ(<0.050)
Well Well Well
WaterUse] DrinkingWater} DrinkingWater] Din ee Drinking Water} DrinkingWater}
[_OSPRICEFL| 3/22/2002] [OS-HORNBECKLK[ 4/1/2002
[OSMATHENYBL| IOS-MATHENYTL|
OSeDDYEE|
4/1/2002] 4/1/2002] 4/00
[OS-GERBERDA|_ 4/17/2002] [-- OS-GIVENSDL| 5/22/2002]
[_ OSSMITHPWI[ 3/20/2002] |OS-WICKHAMYD| 3/20/2002]
0802] 0237] 00805] 0.195]
64 0.102] 0416] 1.35] 0.0842]
Well DrinkingWater} Well Drinking Water]
Well Wel Well
Drinking Water] Drinking Water] Drinking Water]
Well DrinkingWater] Well DrinkingWater] Well Non-drinkingWater} Well] Non-drinkingWater]
[--__O 4/1S 5/200P 2] I3E 8]RCWeE ll NoL n-drinR king W| ater|
[OSFUCHSSL| 5/22/2002] 0955]
Well Non-drinkingWater}
[ OSSICKLESTS| _ 4/9/2002] 12.4]
Well
Unused)
[OSLEFEBVRESAI 4/2002]
tao]
Well
Unused]
[ OS-RIPPETOK[ 4/16/2002] 449]
Well
Unused)
[OSW4/A 8/200T 2] S1O 72 NM WellP1Un| used)
|OS-PARSONSDOH| 4/23/2002] 2.00
Well
Unused]
[--_OS_- /1/C 2002O ] L0.L 104 INWS ellRL2 Unu| sed]
[OS-D5/A 1/200U 2] G16H 8] ER WeT ll YD Unu| sed]
[___O 5/1/20S 02] M 007C 61] GE WellETUn| used]
[OSWINDLANDB| 5/2/2002] [OSHUMESD|_s/a002 [OS-SHETLERF| 5/3/2002]
115] 23s] 0.461]
Well Well Wel
Unused) Unused] Unused]
[ |___o_ S_ WIOLS 5L/6/I- 200A2F MR S11G.A 6375]]]N sS iWWeI eellrllC zC o0M UUnnauuI ss]eedd)]
rtr2002
Torz
000331 OHA T20H-1s
Table 2 `Summary of C-8 Analytical Results in Groundwater and Surface Water
Ohio One-mile Radius Residential Sampling
IOscTAHPR4 siea02] |OS-STAHLPRa2| 5/15/2002]
6%] 636]
Well Well
Unused Unused]
[else seen [osareauon) smopnosl
5/24/2002]
Os 4.22) to
Well
Unies)
Well Unused)
Well
Unead
Unused|
[OSSTAHLPR2|_ 4/8/2002] 572
Spring| Non-drinkingWater}
[OS-S4/9T /200E 2] P8H .88] AN SprinM a| NoL n-drin2 king W| ater]
[ OS-RAUCHSPGI| 4/11/2002] 358] Spring| Non-drinkingWater]
[__OS4/- 11/2R 002] AU 44C ] HSS prinP g]NonG -drink3 ing W| ater] [--_OS 4/1R 1/200A 2] U4.C 97] HS SpriP ng|NoG n-drin4 king W| ater [OS-RAUCHSPGS| _4/11/2002] 576] Spring] Non-drinkingWater}
[OS-WATSONMPS| 4/18/2002] | OSSWERRINGENW| 4/22/2002]
236] 655]
Spring| Non-drinkingWater} Spring]Non-drinkingWater
[ OscasTOBI| 7/2002] 381
Spring|Non-drinkingWater]
[_os- _e/7c /200a 2] s4t 3]oB Sprii ng| No- n-drin2 kingW| ater}
|OS-CASTOB2(dup)| 6/7/2002]
296]
Spring| Non-drinkingWater
[ oOscastoBs| _em/z002] 583] Spring| Non-drinkingWater}
[OS-STEPHANML 4/9/2002]
541] Cistern|Non-drinkingWater}
[OS-WATSONMP4| 4/18/2002
7.33] Cistem| Non-drinkingWater}
[_OS-4S /0/2T 002 EP 252H ] APN OOLM INonL drinkS ingW] ater]
* Drinking Water (highlighted in bold blue) indicates human consumption. Non-drinking
Water uses include livestock watering, gardening and any other non-human
cNoDns=umNpottiDoentewcatteedr autseosr.above the limit of detection (LOD). The listed LOD NisQap=pNrootxiQmuaatnetiainabdlvea.riDeestebcytiendsattruamecnotncaenntdroavtieorntiambeo.ve the LOD and below the limit of quantiication (LOQ).
312002
2012
000332
OH1 T20H-1.xs
-
OSKRAT MW11(dup)| ~~ 4/30/2002
3.48] Monitoring Well
| osericeiwwe arsvoce
49] MonitoringWell
000334
FIGURES
000335
APPENDICES
000336
000337
APPENDIX A ONE-MILE RADIUS WELL SURVEY RESULTS--
WASHINGTON COUNTY, OHIO
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