Document JJ4Ra93Ddv7R5Ndag0YDaL8Me

MATERIAL SAFETY DATA sH EE T page: l DOW CHEMICAL IJ.S.A. MIDLAND MICHIGAN 40674 EMERGENCY PHONE: 5 17-636-4400 EFFECTIVE DATE! 12 MAR 85 DATE IRINTED: 13 MAR 85 PRODUCT CODE: 91575 PRODUCT NAME: VINYL CHLORIDE MONOMER i INGREDIENTS ATYPICAL VALUES-NCT SPECIFICATIONS) MSD: 066 a :X VINYL CHLORIDE, CASt 75-01-4 99.9 : SUBSTANCES LISTED IN THE INGREDIENT SECTION ARE THOSE IDENTIFIED AS BEING PRESENT AT A CONCENTRATION OF IX OR GREATER* OR 0.1X IF THE SUBSTANCE IS ON THE LIST OF POTENTIAL CARCINOGENS CITED IN OSHA HAZARO COMMUNICATION STANDARD. WHERE PROPRIETARY INGREDIENT SHOWS* THE IDENTITY OF THIS SUBSTANCE MAY BE MADE AVAILABLE AS PROVIDED IN 29 CFR 1910.1200(1). SECTION 1 PHYSICAL DATA BOILING POINT: -13.8C (+7.16F) : SOL. IN WATER: <C.1X VAP PRESS: 2524 MMHG * 336KPA S20C :.SP. GRAVITY: 0.9104 3 2C/20C, &8F VAP DENSITY (AIR=1>: 2.35 I X VOLATILE BY VCL: 100 APPEARANCE and odor: EXTREMELY FLAMMABLE* COLORLESS GAS OP LIQUID UNDER PRESSURE - FAINT, SWEET ODOR. SECTION 2 PIRE AND EXPLOSION HAZARD D A. T A FLASH POINT: -78 C (-1G8.4F) METHOD USED: CLEVELAND OPEN CUP : FLAMMABLE LIMITS : LFL: 3.6 VOL. % UFL: 33.0 VCL % EXTINGUISHING MEDIA: FOR CONTAINMENT OF FIRE AND PROTECTION OF SUP POUNDING EGUIPMENT ONLY. WATER FOG, FOAM, C02, DRY CHEMICAL. SPECIAL FIRE FIGHTING EQUIPMENT AND HAZARDS: WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS. VAPORS CpN FCY FLAMMAbLE MIXTURES WITH AIR AT ALL NORMAL AMBIENT TEMPEPAUTRES. ALL SOURCES OF POSSIBLE IGNITION SHOULD BE AVOIDED IN AREAS WHERE VINYL CHLORIDE VAPORS ARE PRESENT. AUTGIGNITICN TEMPERATURE 472C (8&2F). SECTION 7 REACTIVITY DATA STABILITY: AVOID EXPOSURE TO AIR, OXYGEN, SUNLIGHT, MOISTURE, Af.;;. ALL SOURCES OF HEAT OR IGNITION. AUTOIGN'ITES IN A I? AT 472C (*fc2F>. INCOMPATIBILITY: OXIDIZING MATERIAL, AND ALUMINUM OR ALUMINUM ALLOYS. (CONTINUED ON PAGE 2 ) (R) INDICATES A TRADEMARK OF THE DOW CHEMICAL COMPANY TDCC/BOGNER0095 material safety data sheet page: ? OOU CHEMICAL U.S.A. MIDLAND MICHIGAN A8fc7A EMERGENCY PHONE: 5 17-63g-aA 00 EFFECTIVE DATE: 12 MAR B5 DATE PRINTEO: 13 MAR 85 PRODUCT COOT : 91575 PRODUCT (CONT'D): VINYL CHLORIDE MONOMER MSP: OfefeA SECTION 3 REACTIVITY DATA (CONTINUED) HAZARDOUS DECOMPOSITION PRODUCTS: HYDROGEN CHLORIDE* CARBON MONOXIDE. HAZARDOUS POLYMERIZATION: MAY OCCUR. AVOID EXPOSURES TO OXYGEN (AIR), HEAT* SUNLIGHT, MOISTURE, AND FREE RADICAL INITIATORS OR OTHER CATALYTIC IMPURITIES. SECTION A SPILL, LEAK, AND DISPOSAL PROCEDURES ACTION TC TAKE FOR SPILLS: AMPLE VENTILATION, ALLOW AREA? 00 NOT ALLOW VINYL OF EXPLOSIVE HAZARD. REMOVE ALL SOURCES OF IGNITION; SUPPLY ONLY PROPERLY PROTECTED PERSONNEL INTO THE CHLORIDE TO ENTER THE SEWER SYSTEM BECAUSE DISPOSAL METHOD! INCINERATE IN EQUIPMENT WITH A HYDROCHLORIC ACIC SCRUBBER ACCORDING TO LOCAL, STATE, AND FEDERAL REGULATIONS. CONTACT THE DOW CHEMICAL COMPANY FOP ADDITIONAL HELP. SECTION 5 HEALTH HAZARD DATA EYE: IF LIQUID CONTACTS EYE, EVAPORATION MAY CAUSE FkSSTB I TO? YPE INJURY DUE TO RAPID COOLING. SKIN CONTACT: IF LIQUID CONTACTS SKIN, EVAPORATION MAY CAUSE FROST-BITE TYPE INJURY DUE TO RAPID CODLING. SKIN ABSORPTION: SKIN ABSORPTION IS UNLIKELY DUE TO PHYSICAL PROPERTIES. INGESTION: INGESTION IS UNLIKELY DUE TO PHYSICAL STATE. INHALATION: A SINGLE BRIEp (MINUTES > INHALATION EXPOSURE TO EASILY ATTAINABLE CONCENTRATIONS MAY CAUSE SERIOUS ADVERSE EFFECTS. EVEN DEATH. SIGNS AND SYMPTOMS OF EXCESSIVE EXPOSURE AT CONCENTRATIONS OF 8,000 TO 10,000 PPM MAY BE ANESTHETIC OR NARCOTIC EFFECTS. SIGNS AND SYMPTOMS OF EXCESSIVE EXPOSURE MAY BE CENTRAL NERVOUS S^STrv EFFECTS. SYSTEMIC 5 OTHER EFFECTS: EXCESSIVE EXPOSURE MAY CAUSE LUNG, LIVE= AND KIDNEY EFFECTS. EXCESSIVE EXPOSURE HAS BEEN SHOWN TC CAUSE C - V . IN HUMANS AND IN LABORATORY ANIMALS. REPEATED EXCESSIVE EXPOSURE V * i CAUSE RAYNAUD'S PHENOMENON PSEUDOSCLE ROOEF.MA A NO AC ROOS TE CL YS I S I" HUMANS. has e EEN SHOWN to FE A MUTAGEN IN BACTERIA. HAS BEEN SHOW TO PRODUCE REVERSIBLE CHROMOSOMAL ABNORMALITIES IN HUMANS . VI Nvl iLU IS LISTED AS A CARCINOGEN BY THE NATIONAL TPXICOLC! .Y PROGS' ` , 'HE INTERNATIONAL AGENCY POP RESEARCH, AND OSHA. SECTION 6 FIRST TDCC/BOGNER0096 EYES: IRRIGATE IMMEDIATELY WITH WATER POP AT LEAST 5 MINUTES. skin: no adverse effects anticipate:1:' -;y this route of exppsluEXCEPT fOR FROSTBITE. MATEP I AL SAFE T r DATA SHEE T page: 3 DOW CHEMICAL U.S.A. MIDLAND MICHIGAN 48674 EMERGENCY PHONE l 5 17-636-4400 effective: date: i? mar pm date printed: is mar es PRODUCT <CONT*D: VINYL CHLORIDE MONOMER product code: 91575 MSOI 0664 SECTION 6 FIRST AID .'CONTINUED) ingestion: no adverse effects ANTIC fated by this route of exposure DUE TO PHYSICAL PROPERTIES. INHALATION: REMOVE TO fresh AIR. if NOT BR;- ' TWINS, MOUTH RESUSCITATION. IF BREATHING . S DIFFICULT G i A PHYSICIAN. i0U TH"T 0OXYGEN. CALL NOTE TO PHYSICIAN: NO SPECIFIC ANTIDOTE. SUPPORTIVE CARE. TREATMENT BASED CN JUDGMENT CF THE PHYSICIAN IN RESPONSE TO REACTIONS OF THE PATIENT. SECTION 7 SPECIAL HANDLING INFORMATION EXPOSURE GUIDELINES): ACGIH TLV IS 5 PPM FOR VINYL CHLORIDE. OSHA PEL IS 1 PPM FOR VINYL CHLORIDE WITH A 0.5 PPM ACTION LEVEL. VENTILATION: CONTROL AIRBORNE CONCENTRATIONS BELOW THE EXPOSURE GUIDELINE. USE ONLY WITH ADEQUATE VENTILATION. LOCAL EXHAUST VENTILATION MAY DE NECESSARY FOR SOME OPERATIONS. RESPIRATCRY PROTECTION: WHEN AIRBORNE EXPOSURE GUIDELINES AND/OR COMFORT LEVELS BE EXCEEDED. USE AN APPROVED POSIT IVE-PR E SSUK E SELF-CONTAINED BREATHING APPARATUS. PROTECTIVE CLOTHING: USE AN IMPERVIOUS FULL SLICKER SUIT WHEN THERE IS ANY POSSIBILITY OF SKIN CONTACT WITH LIQUID OR VAPORS IN EXCESS OF EXPOSURE GUIDELINES. EYE protection: use chemical ggggles. if VAPOR EXPOSURE CAUSES EYE IRRITATION, USE A FULL-FACE, SUPPLIE0-A I R RESPIRATOR. SECTION ft SPECIAL PRECAUTIONS AND ADDITIONAL INFORMATION PRECAUTIONS TC BE TAKEN IN HANDLING AND STORAGE: STORAGE SHOULD ~E IN AN ISOLATED, WELL-VENT ILA TEC AREA. PITS, DEPRESSIONS, AND BASEMENTS SHOULD PE AVOIDED. AVOID ALL SKIN AND EYE CONTACT. AVOID BREATHING VAPORS. VINYL CHLORIDE SHOULD A L W A v ; S 0 HANDLED WITH FULL RECOGNITION OF ITS VOLATILITY AND ITS FLAMMABILITY. KEEP THE `-'ATERIAL ENCLOSED A"C ELIMINATE ALL SOURCES CF IGNITION. ADDITIONAL INFORMATION: -EVISEO SECTIONS 1, 2, 3, 5, 6,' 7, AND INGREO I ENT G. 'TIE' DATE: 1-J A f. - 7 G LAST PAGE {R) INDICATES A TRADEMARK 0p THE DOW CHEMICAL COMPANY THE INFORMATION HEREIN IS GIVEN IN C-OOD FAITH, BUT NO WARRANTY, EXPRESSED CP. IMPLIED, IS MADE. FOR FUPTHER INFORMATION. CONSULT ThF 00 v chemical coTmDpCaCn/yBOGNER0097