Document J3p9VrQy5ojoqqQQegn0ew7RZ

PAGE 200-4 CAPTIVE USAGE T/D LIQUID PHASE EDC To TCE Mtq. & MC Mixes Perchlor Trlchlor Mfg. & Mixes Vinyl Chloride P/T-TETRA UNIT OHCEDC To Perchlor T richlor No. 2 EDC Plant P/T-TETRA UNIT PPG INr TRIES CHEMICAL DIVISION LAKE CHARLES, LOUISIANA 1974 JAM AVG. FEB. MAR. APR. WAV JUNE JULY AUG. SEP. OCT. NOV. DEC. 1975 AVG. 207.8 0.0 0.0 636.7 54.0 239.3 0.0 0.0 481.1 42.9 260.3 0.0 0.0 240.1 123.2 1 34,1 nn 0.0 132.8 306.4 112.1 115.1 0*0 0.0 0i0 0.0 365.8 546.1 231.7 53.9 122.3 0.0 0.0 798.4 125.8 0.0 0.0 721.3 0.0 3.6 144.6 134.9 0.0 0.0 0.0 0.0 772.8 787.6 0.0 0.0 '241.7 0.0 0.0 915.0 0.0 263.9 0.0 0.0 802.9 0.0 246.8 0.0 0.0 961.7 "TTTO 178.4 0.0 0.0 627.1 63.5 0.5 0.9 91.4 263.8 - 0.0 0,0 37.2 286.2 0.0 0.0 24.4 196.5 0.0 0.0 73.6 168.7 0*0 0*0 0.0 0.0 145.6 52.7 l4l. 5 241.1 1 0.0 0.0 164.8 119.9 0.0 0.0 201.4 113.0 0.0 0.0 137.6 227.2 0.0 0.0 187.5 206.1 0.0 0.0 282.8 133.2 0.0 0.0 193.4 171.2 0.0 0.0 242.9 206.9 0.0 0.0 145.3 184.3 CO 1 O f-y to* CO wi "" " f CONf IDE',NT I ftL: Subie ~t to prot^t tive i o: 14th Judic iai Hoi n-i] -------- r1 PAGE 201-4 EDC SHIPMENTS Mf JAN FEB CHfMICAl DIVISION UKE CHAR.ES, lOUSSIAMA LARORA-TORY PRO DUCT REPORT MAR APR MAY JUNE JULY AUG SEP OCT NOV DEC 1975 Avg. r*NS 1.2, Di chloroethylene ppm 1.1 DlCHLOROETHANE PPM IS 1.2 OlCHLOHOETMYLENE PPM iHLQROrORM PPM I TMYL EN E DlCHLORIDE % fn1IHLOROE THVLCNE 'ERCHLOROETMYLENE PPM PPM 1.1.2 Trichloroethanc ppm 08 4 (1 12. (1 0 0 17 17 8 14 12 : 16 19 18 7 17 25 10 2 8 1 1 33 67 69 47 39 ^5-------- 24 0 99 .'984 99.981 99.981 99.973 99i977 99.975 99.982 'SSTSSt 7 20 30 BS 70 67 63 "53-------- 10 16 . 3 T5--------- 12 4 0 -g---------- 27 31 1/ 51 26 25 41 "EE-------- 00 00 1 2 17 16 20 12 11 15 0 3 "5---------- l3 2 'J 0 0 * 21 32 17 30 99.98< 99.990 r99.995 99.983 99.990 99.982 112 44 2 33 2 49 00 00 0 5 0 24 18 92 74 39 :thylenc Cmlorobromibe ppm 7 6 24 6 2, 20 0 22 0 6 09 :thyl Chloride ppm 30 11 7 14 19 6 12 21 31 21 4 3 18 10 13 'OLOR (APHA) ''PPEAHMItt MID* TV -ATE* PPM PPM JON-VOLATILES total Iron pecific Gravity 60/'60F PPM ppm 7 CLEAR (1 48 8 CLEAR U 49 6 3LEAR 0.34 49 1 o7z3 1.562 <1 0.30 1.262 (1 3.24 1.260 8 Clear 0.59 38 t 3 3.26 L.261 7 CLEAR 1.02 47 8 CLEAR 0.78 20 7 CLEAR 0.93 48 6 CLEAR 0.90 37 69 CLEAR CLEAR 1.50 3.67 17 58 1 0.32 1.261 1 0.22 1.259 3f 6.31 1.262 3 0.24 1.263 0.42 1.259 U 0.47 1.259 9 CLEAR 1.00 28 5 CLEAR 1.00 22 8 CLEAR 1.00 32 7 CLEAR 1.10 37 1 0.52 1.262 13 0.30 1.263 13 0.40 1.263 4 0.33 1.561 0 If) O ----- E.i JSn u; - mupi HRNTf lL: 'lifripr 1 .In rot-pm: .ive O :der r-\ 1 JMi Inrl i r* pi 1 n i ;trict Cour t Mn . 91-11 5_ I PAGE 201-5 METHYLCHLOROFORM SHIPMENTS 1974 AVG. JAN. Type 314 Color Specific Gravity Distillation Ranqe Low Hiqh Moisture APHA 25/25 C C PPM (5 1 . TTR 73.9 75.2 32 - - Acidity Non-Volatile Residue Soluble Chlorides PPM asHCI (1 % (.0001 PPM (0.5 -- PPG lMfpSTL'IES chemical division LAKE CHA'U.F.S,LOUISIANA LABORATORY PRODUCT REPORT FEB. MAR. APR. MAT JUNE JULY --- - ----- - - im. - r - * -- -_ ---- -- - -- -- -- -- -- --- Type 343 Moisture Distillation Ranqe Low Hiqh Specific Gravity Color Acidity Non-Volatile Residue Soluble Chlorides PPM C 25/25 C APHA PPMasHCI % PPM 50 32 36 -- 77 6 (1 (1 Cl .0004 - "foJS - --- --- ------- AUG. SEP. ----------- OCT. -- 1-- - - NOV. DEC. 1975 AVG; --- - -- - -- -- - - - " 20 31 34 -- - -- 67 7 - -- 1 (1 (1 - -- --- .0004 - -" -- (0.5 L0 r- o Gj w C (INF T OF NTT AT. Su > jec?t to Prr tpntis e Orrli r of 1 th Ju ri i n i a nifitl icT Ct mrt To. 91 -1145 PAGE 201-6 Pf *.* C.KF.MICAL^F'ISION LAKE CHAfi ! r; s, LO Ul 5 fANA LABORATORY PRODUCT REPORT TRI-ETHANE SHIPMENTS m. JAN. FEB. MAR. APR. MAY JUNE JULY AUG. SEP. OCT. NOV. Tvne 324 Color Specific Gravity APHA 5 25/25 C 1.306 Distillation Range Low High Moisture C PPM 73.0 83.1 6d Acidity PPMasHCI 1 Soluble Chlorides Aluminum Scratch PPM APHA Non-Volatile Residue (0.5 24 .0002 Type 339 Color APHA 7 Specific Gravity 25/25 C 1.326 6 1.303 73.4 83.4 55 (1 (0.5._ 14 .0001 - 5 1.303 73.4 83.5 37 1 To73 . Od02 - Distillation Range Low High Moisture Acidity Non-Volattle Residue Soluble Chlorides C 73.2 82.4 PPM 62 PPM as HCI a % . 00U4 PPM (U. 5 _ -- - - " - 6 1.304 73.2 83.4 45 1 (0.5 16 .0002 - - - - 78 7 1.302 1 . TOT 1.303 73.1 83.4 4i (1 (0^5. 10 .0004 72.9 72.8 83.4 83.6 32 39 (1 Jo75 1 (0.5 24 17 (.0001 .0002 --- -- ------- - -- - - 6 1.305 44 55 1.304 1.305 mon 1.305 73.2 83.5 46 (1 (0.5 12 .0001 73.0 72.7 73.1 72.9 83.7 83.1 83.5 83.2 38 54 60 33 (1 (1 ~TT (1 (0.5 (0.5 (0.5 (0.5 - 19 20 20 .0005 .0001 (.0001 .0001 -- - --- _ -- - -- - - - "- - - - -- - -- - - -- --- - - -- -- - -- DEC. 6 1.304 73.3 82.2 46 1 (b.5 49 .0001 - - -- -- 1975 AVG. 6 1.304 73.1 83.3 44 (1 (0.5 20 .0002 - -- -- Cf) r~ i1 L CD --* CO ,p% w C TNFIDfi NT1AT.! Su >-ject to Fro tecti'. o nr/fr T " of I th Ju iiciai Disti act C( FUI L Jo. VJ -1145 PAGE 201-7 PPG i JSTRIPS * ;CHrMU.. . DIVISION LAKE CIIAI?1E5, LOUISIANA LAHORA TORY PRODUCT REPORT TRICHLOR SHIPMENTS JAN FEB MAR APR MAY JUNE JULY AUG SEP ivpeJ-j^ (Decreasing & So Lvent C radej Color Sncinc Gravity 20/BO C Distillation Range apha C 7. 7 1.461 1 . A(\Ct Lon water Content High Cloud Point C NONiVOLATILE % Acio Acceptance * as Naoh PH Aciiity/Alkalinity 86.1 86.2 87.7 87.9 (-10 (-20 .0008 .0001 "U7TT- 0.19 8.8 9.1 .ouiy .0024 78 - - 86.0 - 87.6 (-20 - - (-20 .0002 0.19 9.1 9.1 .0025 :0023 78 1.460 1.455 77 1.447 1.454 86.0 87.6 (-20 (.0001 0.18 9.2 .0022 86.1 86.0 87.8 87.5 (-10 (-10 .0002 .0003 0.19 0.19 9.2 9.2 .0024 .0020 86.0 87.8 (-10 .0002 0.19 9.2 .0017 66 1.460 1.460 86.0 88.0 (-20 .0009 0.19 9.1 .0018 86.1 87.5 (-10 .0001 0.20 9.2 .0021 OCT nov 96 1.460 1.460 86.1 86.2 87.3 87.6 (-10 (-10 .0002 .0003 0.19 0.19 9.2 9.2 .0024 .0019 DEC 1975 Avg . 87 1.461 1.458 86.1 87.6 (-20 .0001 0.19 9.3 .0013 86.1 87.6 (-10 .0002 0.19 9.2 .0021 , * TYPE 113 (Hieh Puritv Gr 'de) Color 20/20 CSpecific Gravity apha 6 Distillation Range C Lor water Content High Clouo Point Non-. Volatile C % (-10 .0004 6 66 77 67 4 (5 (-10 (-20 (-20 .0003 .0002 .0002 (-20 (-20 (-10 (-10 (-10 (-10 .0003 .0001 .0002 . 0002 .0002 .0002 54 (-10 (-10 .0002 .0002 66 (-20 (-10 .0002 .0002 qoiL "011 3439 CONF ! DRWPT Subiei rt to. ^rotpr1 T T C ol 14 th Judic Lai n l* sHrirE No. 91-11 _____ nt-l PAGE 201-8 . rf*a]fHr>T3iRiE5 CUtMIC M DIVISION IAKE CHARltS, IOUISIANA LABORATORY PRODUCT REPORT PERCHLOR SHIPMENTS TYPE 207 Cocos Specific gravity APHA 20/20 C Distillation Range C Low Water Content High Cloud Point C Non-volatile TH Vft,% Acid Acceptance % as naoh Copper Corrosion NAcidity ml of 0.01 NaOH Flask MG/30 CM2 Soxhlet MG/30 CM2 CM*MG/30Condenser Chlorides ppm m n to 8.3 JAN FEB MAR APR 11 8 11 11 (0 8.6 (0 8.5 (-10 (o , 8.4 8.4 MAY 9 (0 8.5 JUNE JULY AUG 12 8 7 :o 8.5 (0 8.6 (0 8.5 SEP 8 (0 8.4 OCT NOV OEC m 13 8 10 10 (0 (10 8.4 8.4 (0 8.4 (0 8.5 t TYPE 208 Color APHA . Specific Gravity 20/20 C Distillation Range C Low HI GH water Content Cloud Point C Non-volatile PH vt.% copper Corrosion Acidity ML of 0.01 N NaOH Flask MG/30 CM2 SOKHLET MG/30 CM2 Condenser MG/30 CM^ Chlorides ppm 10 9 1.625 1.625 120.8 121.7 (0 .0003 6.6 120.9 121.7 (0 .0004 6.6 2 1 7 8 6.09 2 1 6 8 0.09 8 - (-10 - 6.6 _ -- -- ooLi fVi 11 O341!4`T0V 9 1.623 121.0 121.9 (0 .0003 6.6 88 1.623 1.618 ` 10 1.614 121.0 121.9 (o .0004 6.5 121.1 121.1 122.0 121.9 (0 :o (.0001 .0003 6.6 6.6 77 1.615 _ 121.0 121.9 (0 .0008 6.9 - - (-10 6.9 7 1.623 121.0 121.8 (0 .0002 6.7 10 7 8 8* 1.625 1.625 1.624 1.622 121.3 121.0 121.8 121.9 (0 (0 .0007 (.0001 6.4 6.8 121.1 121.9 (0 .0004 6.6 121.1 121.9 (0 .0003 6.7 3 3 8 11 0.07 3 2. 6 8 0.07 2 2 5 12 (0.06 3 3 9 10 0.07 6 2 1 12 0.15 -3 2 12 3 -3 4 41 3 -7 12 6 6 7 -7 7 47 9 - 0.12 (0.04 (0.04 0.19 0.08 CON Pi JEnTTT jj i < lubjec : to l' i.otec L j v t: ^ 1 1 L. Iof 14 tli juftici a 1' -Dit| L riot &----------- PAGE 201-9 . ETHYL CHLORIDE SHIPMENTS M4 JAN ,PPG i JSTRIES 6|[(.^ICAL division LAKE CHARLES, LOUISIANA LADORATORY PRODUCT REPORT FEB MAR APR MAY JUNE JULY AUG SEP OCT NOV DEC COLOR MOISTURE specific Gravity APHA fPM 0/a C (5. 31 0.924 (5 18 0,927 6 (5 29 14 0.925 0.925 (5 22 0.924 6 42 0.925 (5 (5 8 -18 0.924 0.922 (5 44 0.923 (5 52 0.924 (5 5 19 19 0.923 0.924 (5 (5 20 25 0.924 0.924 Acidity as HCl non-volatile Residue wt. % wt. % (.0001 (.0001 (.0001 (.0001 .0002 .0003 (.0001 (.0001 .0001 (.0001 (.0001 (.0001 (.0001 (.0001 .0604 (.0001 (.0001 (.0001 (.0001 (.0001 (.0001 .0001 .0002 (.0001 (.0001 .0001 .0002 (.0001 Ethyl Cklgrioe Distillation Range Low High Wt. * C 99 .'9 7 99.97 99.98 99.98 99.98 99.99 99.99 99.99 99.975 99.98C 99.960 `"997970 99.98 99.98 -- 4 > fl 1 344 ^ ________11_________ 1 r%\ wiv je --*1 *11c1fl CONF 't t"o Judic Identj AL: Protec tive t LaToI strip* HoT 45 PAGE 201-10 VINYL CHLORIDE SHIPMENTS M* HC1 1974 JAM AVR. PPM 37 29 PPM (1 (0.1 rt ppm SULFUR j ACETYLtNt PPM PPM ALDEHYDES, as acetaldehyde ppm PtAOXIOEt. ASHjOt PPM (0.1 (0.1 (1 (1 (1 (1 71--------- (1 ti.oo 0.02 NON-V LATIL C RESIDUE ' - PPM 5 (1 PPG if^lSTRIB r VISION tAKE CHAKtES, IOIHSIANA LABORATORY PRODUCT REPORT FEB MAR APR MAY JUNE JULY AUG SEP 28 (0.1 40 0.1 (0.1 (1 (1 (1 (0.01 (0.1 (1 (1 (1 0.01 72 (0.1 fi2 47 (0.1 (0.1 19 (0.1 26 (0.1 34 (0.1 (0.1 (0.1 (i (1 tl (1 a-- (1 (0.01 (0.01 (0.1 (1 (1 (1 (0.01 (0.1 (0.1 (1 (1 U . (1 TI-------- (1 (0 :ur (0.01 (0.1 (1 (1 (1 (0.01 (1 1 fi 15 1 a (1 2 OCT NOV 43 0.1 54 .0.1 (0.1 [0.1 -- (1 (1 (1 d' (0.01 [0.01 4 (1 DEC 56 0.1 1975 AVG. ____ (0.1 ou____ (CLJ___ _U______ (1 (1 (1 (1 (0.01 (0.01 22 SwLt- y011 3V74*4T?4 ' p r Sii of 1 ~-------JQCt 'NT'-LDE fTlAT.t t o Prol ecti fcf* TJtltl iciaT Oistri rf --:-----ft 3. yi- U45 f*-- rfc -- PAGE 202-4 EOC PRODUCT #1 m PPM* JAN FEB PJ?G IN TRIPS CHCMtCM DIVISION IAKE CltARIES, LOUISIANA LArtONATORY OPERATIONS REPORT MAR APR MAY JUNE JULY Trans 1.2 DlCHLOROETHYLEHE 1 .1 DlCHLOROE THANE CPS .1.2 DlCHLOROtTHYLENE Chloroform Ethylene Dichlobioe 1.1.2 Trichloroethane i 15 1 53 (Wt. %) 99.979 21 1 15 4 14 99;996 0 - - - - - _ - - -= - - . - 8 15 16 9 99.983 23 - - - - - __ -- - - AUG -- >- SEP - t" " - OCT - - - - NOV - -- -- OEC 1975 Avg. -4 - 15 - 10 - 12 - 99.989 - 12 Ethylene Chlorosromioe Ethyl Chlortde UNIDENTIFIED 5 (1 19 5 30 --- --- -6 (1 -" ------ -- - - -- 3 " - -- 3 -- - --- -- 34 28 ' " _ - 22 --- - -- - --- 25 EE 0.07 0.06 - - 0.05 - -- - --- - 0.06 1CL 1.01 0.37 - - 0.85 - - _ -- - _- 0.62 * * ' ' SL 013443 ` 'Unless otherwise specified - t Sub Of J. 4 Offh r'n Ki ' ^ % " Xt iCvfl-"i i tUL n i .. UAL: out i Ve n-stT'j - -L 4 3' OrcJej cl 'Cot rt EOC PRODUCT #2 "W PPM* Avg. JAN FEO ppg in Strips tllLMIt M^^VIIION IAKE CMAIitlS, tOUtjIANA LAHORATORY OPERATIONS* REPORT MAR Apr MAY JUNE |JULY AUG SEP OCT NOV OEC 1975 Avg. ' Trans 1.2 DlCHiOftOCTHYLCNE ] 1.1 DtCHLOROETHANE 4 IS CIS .1.2 DlCHLOROETHYLENl CmOROfOBM Ethylene Di chloride 1.1.2 TRICHLOROETHANE / 12 (WT.%t 39'.978 ib * 3 15 11 10 99i993 1, 2 12 4 6 99.984 5 (1 ,tl 13 11 6 6, 38 6j 99.981 9.968 13 16 1 (1 13 17 22 7 49 99.991 99.938 4 19 (1 (1 6 2 (1 (1 1 16 8 36 21 7. 18 19 12 9 19 6 15 6 22 3~------ 72 139 15 15 37 99.931 99.992 99.981 99.964 99.986 99.993 99.975 11 . 3 5 20 32 8 11 CtHYltl.E CkLOROBROMIDE Ethyl Chloride Unidentified 5 2 (1 (1 2 21 (1 2 2 46 5 2 29 2 1 11 (1 4 33 9 (1 4 96 5 7 40 00 (1 (1 2 (1 2 "T 0 0 0 (1 ri?o 35 38 26 23 27 57 31 23 24 36 23 24 24 30 Ft 3.04 0.05 0.01 0.02 0.b2 0.18 - 0.21 0.06 0.06 0.02 0.03 0.08 0.07 Cl. 07 HCl L.05 0.70 0.82 1.16 1.20 2.56 1.74 0.77. 0.96 1.11 1.09 1.32 0.98 TTTO , * '; * *1 - SL 013444 * U. Unless otherwise specified .. * ..* * * * . M.'..' 1 * * **." ' **- * - 4 ^Allia St bled frfrTJ AT ot Ttectl **th ,ii 1u Li^ Mrs _n i Uist --U45 Orr r-ict r ^`iir t | EOC REACTOR #1 ElHYL[N[ BICHLORIDE Tb 1 Cl'lOMOr thylcnc PtBCiaOBOt IMYLtKt 1,1.J Tri naoROC thane U.TETRACHLOROE THANE S*7t TRAE.HLOOt THANE PtNTACHLOBOtTHANE 1974 JAN Avg. WT. % 98.86 99.26 0*02 0 00 0.41 0.44 00 0.22 p.44 00 Ethylene ChlobobbomioE Ethyl Chlobioe llNtDENTiritO 0 J5TTJ5 TT77S 0 0.03 0.07 FED PPG H^STKICS CtlCMICA^TOVIS'-OM LAKE CHARLES, LOUISIANA LABORATORY OPTRA!I DNS REPORT MAR APR MAY JUNE JULY AUG SEP 98.78 o 0.01 0.62 0 0.36 0 98.76 0 0 0.65 (0.01 0.22 (0.01 98.32 0 0 0,88 0; T5T53 olio 98.56 0 (0.01 0.43 0 0.15 [oTT7 98.13 0 0 1.10 O.oi 0.19 TTT2I 98.82 (0.01 0 0.74 0 0.18 (0.01 98.28 0 0 1.07 0 0.67 0.05 98.85 0 0 0.49 0 0.35 0 0 0.02 0.22 0 .. 0.02 0.33 0. 0*01 0.44 0 0.01 0.25 0 0.01 0.36 (0.01 0.02 0.22 0 0.03 0.14 0 0.05 0.24 OCT NOV DEC 1975 Avg . 98.90 98.96 0.03 (0.01 0.01 0.02 0.52 0.43 0 0.01 0.35 0.28 00 97.53 0 0 1.72 0 0.57 (o.oi 98.60 (0.01 (0.01 0.76 (0.01 0.33 0.(54 0 "0.05" 0.38 0.02 0.03 0.24 0.02 0.03 0.08 (0.01 0.03 0.25 H,0 Total Fe as FeCl3 Tabs SPECtnc Gravity PPM ft ft 6Oo-60F 1163 . 0751 fe. 00 i . ^yi) (161 0.33 3.35 1.276 (138 0.32 2.22 1.323 (222 0.51 4.54 1.286 (103 0*49 5.03 1.290 (202 0.42 4.22 1.290 (134 0.33 2.94 1.283 (100 0.25 4.01 1.292 178 0.40 3.54 1.276 (381 0.88 1.11 (219 0.50 6.92 1.299 (158 0.37 4.44 1.290 (162 0.373.88 1.292 (180 0.43 4.10 1.291 . * . _____ SL 013445 1 , " C JNPlbE MTIAL: Su iect T> Fro tectiv q urck r of 1 1. h J u i l e i a l L) istr i c t Cc. HIT------- iJo. yj -114 b SPG St'^TRKS EOC REACTOR #2 Etmylcnc Dichloridc Tfl1CHLOWOC tHYirnt PcRCHLOROCTHYECNt Tfill,t.2 IHIOROETHAMC U- Tt TRACHEOROtTtlANE . S-TtTRACHEOROETHANt PtnTACHIOBOC1HANC JR? WT. % 98.86 0..02 0. 0.37 0 0.26 0 JAM 99.33 0 0 0.38 0 0.40 0 FEB DIVISION IAKE CHAlitlS, IOUIS1ANA LABORATORY OPliRAT I ONS REPORT MAR APR MAY JUNE JULY AUG SEP 98.79 a o. oi 0.60 0 0.38 0 99.09 Q.. _ 0 0.60 (0.01 0.18 0 98.53 0, 01 0i81 0; 0U8 0.13 98.20 0 0 1.09 (0.01 0.21 o7T7 98.80 n 0 0.70 0 0.11 0.09 99.06 0.01 0 0.59 0 o:irTOJT" 98.10 0 0 1.02 0 0.66 0.02 98.98 0.03 0 0.51 0 0.22 P.01 OCT NOV DEC 1975 Avr. 98.64 or 0.01 0.58 99.01 0.01 0 0.44 0 0.01 0.33 "5753 {oTOT "0------------------------ 97.44 0 0 1.83 (0.01 0.49 98.66 (0.01 (0,01 0.76 (0.01 0.28 0.03 Ethylchc Cheorobromide Ethyl Chlorioc Uhi ocnti f icd 0 0.07 05 0 6.03 0.10 0 0.02 0.19 0 0.02 0.09 0 0.01 0.32 0 0.02 0.31 (0.01 0.01 0.25 (0.01 0.03 0.18 0 0.04 0.16 0 0.03 0.43 0 0.04 0.35 0.01 0.02 0.26 (0.01 0.03 0.17 (0.01 0.03 0.21 H?0 Total Ft as FcCl3 PPM * Tars % Specific Gravity 60.60F (153 0.36 4.47 1.287 (133 0.31 3.57 1.283 (138 0.32 3.47 1.331 (168 0.39 4.71 1.287 4 (141 0.34 4.88 1.289 (183 0.38 4.50 1.292 (124 0.36 3.79 1.288 (206 0.43 4.49 1.294 (144 0.35 2.26 1.274 (539 (231 (222 1.24 0.54 0.51 5.40 3.89 3.97 1.294 TTZScT 1.288 (195 0.45 2.88 1.280 (192 0.47 3.98 1.290 * . *_ " . n. 4 Cm sin I'iAL : r ,%u r i a 'll t Trot oct VI i i.m a 1 1 * i c t r iT a . 0 - 114 L U t d '> lf 1 EDC REACTOR 03 EtwYLENC DlCHLOSIOt Tni ciiLOHPt THYLEME i PEROaOROETMYLENE | . .2 Trti1 1 i.hloroethane U-TtTflACHLOROE THANE S-Tc trachloroethane Peril* OHIO not THAME WT. % 1974 JAN Avc. 97.94 0.05 (0.01 1.11 (0.01 0.44 Tovor 99.30 0 0 0.50 0 0.19 0 FEB PRO \\ 'm.STRIPS CHtMICM UlVIjIOM IAKC CilAHES, IOUI5IANA LABORATORY OPERATIONS REPORT MAR APR MAY JUNE JULY AUG 99.26 98.04 00 (0.01 (0.01 0.52 1.33 0 0.01 o.i4 0.58 COICJI 1)7oI 97.17 (0*01 0.01 li72 0.02 0.95 0.01 99.36 0 (0.01 0.42 0 0.12 (0.01 99.64 0 (0.01 0.19 0 0.07 (0.01 97.19 0.02 0.02 1.52 (0.01 1.13 0.01 99.34 0 0 0.28 0 0 0 SEP OCT 99.42 0 0 0.35 0 0*02 98.76 (0*01 0.02 0.87 0 0.13 (0.01 .{0.01 NOV DEC 1975 Avr.. 99.30 0 0 0.39 0.01 0.11 0 99.52 _Q_______________ (0.01 0.32 0 (0.01 0 98.86. (0.01 (0.01 0.62 (0.01 0.29 (0.01 Ethylene Chlororromide Ethyl Chloride Un 1 dent i tied 0 ff7<T5" 0.40 0 (0.01 (0.01 0 0.05 (0.01 0 (0.01 (0.01 0 (0,01 0.10 0 0.01 T5755 0 0.01 0.09 00 O.E52"' 0.02 0.07 0.16 0 0.16 6.03 00 0.o5~ 0.10 0.16 0.09 (0.01 0.06 0.06 (0.01 0.04 0.07 HjO FtTotal as FeClj Tars SPECirie Gravity PPM ft ft 60.60F (226 0.54 4.14 1.289 (198 0.43 1.67 1.271 (69 (147 0.26 0.39 0.56 1.07 1.302 1.266 (95 o;27 0.78 1.264 (83 0.19 , 1.17 1.265 (105 0.22 1.22 1.274 (109 0.28 1.20 1.280 (118 0.51 1.54 1.281 (84 0.19 1.23 1.262 (243 0.56 1.97 1.276 (229 0.53 1.64 1.271 (222 0.51 2.25 1.273 (144 0.36 1.36 1.274 * * * SL 013447 * C of *Ul CONFt ' to p I/I j! t udicj, Wo. s uct'C *1 ru ve Or W TlCt . PAGE 202-9 EOC STILL BOTTOMS #1 ETHYLENE Dl CHICHI 1 OE Tf 1 CMLOnOC thylene PeRCHLOROC THYLENE 1.1.2 ThICHLOROETHANE U-TETRACHLORETHANE S-TE TRACHLOROETHANE Pentachloboethane Ethylene Chlorobromide Ethyl Chloride Unidentified ' 1974 Avg. JAN W17. 71.35 (0:01 0.10 21.33 0.03 5.17 "0752 64.69 0 0.13 27.71 0.02 6.34 0.02 FEB -- - PPG INI PRIES CmfXCM DIVISION 1AKE CHAR TS, IOUISIANA LABORATORY OPERATIONS REPORT MAR APR MAY JUNE JULY _- 43.78 - - - -- 0.11 - - - 46.30 - - --0 - - - 8.63 - - -- 0.65 " iu& -- -- - 0.22 0 1.74 0.64 6 0738-- - - - 0.06 -- - -- - -" -- - - - 0757 -- - - SEP - _ " OCT - -- -- " -- 1975ov tJEC Avg. - " 54.24 - "0 - - 0.12 - - 37.01 - - 0.01 - - 7.49 - - 0.34 - - 0.35 -0 - - 0.43 HjO Fe HCL Specimc Gravity 60-60<>F tpm Frm PPM 34 55.16 7^4 1.331 34 44.83 435 1.308 - - - 20 -- _- 52.60 " - - 1720 " - - 1.373 -- - - - - -- -- -- _ -- - - 27 - 48.72 - 1078 - 1.341 SL 013446 fl * LUNr tDENTA ATT: strict CourtSnK-j^ -1 TlXf" P'rutec Live of 1 <3 f u ltd 1C L 1 DA C rder YT-Jti. 13 . PAGE 202-10 EOC STILL DOT TOMS #2 EtiiylehE OlCHLORlDC T<u tmosot ntvitNt FeRCHLOROETNYLENE 1.1.2 Trichlorocthahc U-TCTRUCHLORETHANC S-Te TOUCHEOBOETHANE Pentachloroethane ' 1974 Avg. W17. 32.35 0.27 0.43 54.70 0.17 9.56 0.05 JAN 10.39 0 0.81 72.38 0.45 14.97 0 FEB 3.96 0 1:36 76.71 0 16.30 0.13 pro (5IRIES ` CIlU'iC'ArmvidON IAKE CUAttlES, IOUISIAUA LABORATORY OPERATIONS REPORT MAR APR MAY JUNE JULY 24.03 0 0.64 46.90 0.41 10.24 0.28 17.62 0 '0.60 66.77 6.37 13.19 6.29 39.85 0 0.38 47.66 0.9a 9.10 0.27 31.26' 0 0.73 60.73 0 2.94 0.33 10.36 0 1.26 68.40 0.35 i8,34 0.35 AUG 15.59 0 0.60 69.31 0.11 12.88 0.25 SEP 23.63 0 0.57 67.58 0 6.0 0.49 OCT MOV OEC 1975 Avg. 15.71 0. 1.65 70.27 16.11 0.18 4.16 64.79 0 8.84 1.40 0 10.16 "o7T5 35.52 0.05 0.05 57.62 0.13 5.38 0.19 20.34 0.02 1.07 64.09 0.23 10.75 0.37 Ethyl Chloride L'HIOENliriED 0 2.17 0 0.75 0 1.29 0 1.28 * 0, 0 1.01 1.86 3 2.42 0 0.72 0 1.06 0 0.93 0 1.07 0 3.49 0 0.39 0 1.36 HjO ft HCt Sptctric Gravitt 60.60f PPM PPM ppm 59 41.64 1112 1.383 71 32.92 1TC 1.434 37 48.00 1242 1.452 4 35.10 1135 1.378 27 24.12 692 1.417 42 120.25 657 1.377 20 174.95 581 28.96 251 1.375 1.427 31 28.40 591 1.422 43 62.51 2397 1.401 43 30.88 1167 1.422 - 38.39 1396 1.412 18 17.28 670 1.380 34 53.48 932 1.408 % - SL 013449 * . row ^ 1 TTK'M'P i/\L; Subis ct tr> c iJud < 1 ^ 1 p ivy UTder t Com; No 97-7 4 5 PAGE 202-11 ___________________ '|TR 1 ETHANE* M4 JAN TCE REACTOR Ethyl Chloride WT.% {0.01 0 CIS '1.2 DlCHt.OROtTHVl.rHE (0.01 0 1.2 DlCHLOROE THANE TRI CHUIROETHVttHI 1.1.2 Tricmoroethane U-Tetrachloroethane S-Tetrachloroethane PtNTACHLOROETHANE 61.90. 0.02 33.11 1.99 2.31 o7T5 63.54 0 31.77 2.12 2.34 3.09 FEB PPG IhWSTRIES CHEMKAt Division IAKC Cl IARIES, lOUISIANA LABORATORY OPERATIONS REPORT MAR APR MAY JUNE JULY AUG SEP OCT NOV DEC 197T AVC. 0 0 0 . 0 0 0 (0.01 0 0 0 0 (0.01 00 0 0 o 0 0 (0.01 0 (0.01 0 , (0.01 60.89 0 33.99 2.27 2.61 0.11 71.14 0 26.24 1.28 1.29 0.03 76.19 0 22.04 0.69 0;73 0.02 74.35 0 23.38 0.81 0.99 CT.U2 73.35 0 24.32 0.86 1.05 0.04 73.95 0 24.09 "0775 0.99 0.02 70.11 0 27.10 1.12 1.42 0.05 65.07 60.08 52.39 0 0 (U ,01 30.90 34.36 39.99 1.72 TIT 3.37 2.05 2.78 4.11 0.10 0.17 0.20 54.64 0.01 37.64 2.84 3.45 0.15 66.31 0.00 29.65 1.69 1.98 0.08 * Ft PPM 16 i HEAVIES STILL REFLUX 16 67 4 13 15 10 22 5 39 15 10 1 Cis 1.2 Oichlorocthylihe (1.7 Oichloroethahe Trichloroethylchc 11.1.2 TriCHLOROtthane U-TETRACHLOROETHANE a 48 a3 * 95 35 L4 L99 Wt.% 99.92 >9.8& * 456 394 58 0 54 47 33 51 53 32 33 43 41 45 40 03 20 0 0 20 4 6 130 476 112 36 38 199 llfi 118 87 112 83 147 99.89 99.85 551 11 99.95 39.80 99.95 99.96 10 2 0 3 99.91 272 99.90 99.90 99.90 99.90 99.90 16S 216 435 265 194 * H,0 p PM ~ - - - - - -- -- Ft PPM U (1 (1 4.2 2 1 (1 a 2 (1 (1 -- (1 1 LIGHT STILL REFLUX PPM HjO (1 - -- - - -- - 11_______ FE 4 4 2 2 4 3 8 3 4 3 6 3 3 4 - ~ SL 013450 CON FI nPM'PT r . Jubiec t to rof or Of 14 th Judici pi 1 ni< No. 2JL-LU 5________ , aer tout t *PPM Pi?.G INlFRIES PAGE 202-12_____________________________________ CHEMICAL DIVISION IAKE CHARtCS, LOUISIANA LABORATORY OPERATIONS REPORT "TRI. ETHANE" 1974 avg. JAN FEB MAR APR MAY JUNE JULY AUG HFAV1ES STILL FEED 1.1,2 TnlCHLOROCIHANC l). Tr TRrMLORorTNNr S -Tt TRRCHLORQETHftNE PtNTACHlOROE THANE WT% 87.33 5,64 6.72 0.30 86.72 6.17 6.84 0-.24 86.72 90.64 6.21 4.39 6.86 4.82 0.16 0.11 93.54 2.99 3.41 0.06 93.58 3.00 3.78 0.06 91.98 3.d5 4.T1 0.24 92.45 3.32^ 4.12 0.08 91.22 4.53 5.30 0.22 SEP 90.38 T793 5.86 0.29 OCT NOV OEC 84.27 6.63 7.87 0.44 81.76 8.07 9.56 0.60 83.86 7.20 8.41 0.48 1975 Avg. 88.93 5.07 5.93 0.25 VDC REfLUX Wti' % vinylioehe Chloride tais. 1.2 Dichloroethylene CIS 1,2-Dlchloroethylene 99.40 99.30 0.33 0.38 0.02 0.17 99.29 99.28 0.42 0.42 0.23 0.14 99-40 99.25 0.43 0.57 0.07 0.08 99.15 99.09 99.11 0.46 0.44 0.46 0.33 0.41 0.36 98.98 0.43 0.47 98.97 99.08 0.40 0.43 0.47 0.42 99.03 0.43 0.48 99.16 0.44 0.31 ((AWE ppm 208 190 VDC PRODUCT HjO IlCTTvt PPM 38 "255 30 236 152 140 150 233 196 191 L69 . ' 22 13 22 21 38 43 21 184 156 1ST 291 285 255 L94 165 26 196 T55 161 T9 " ' 14 184 176 172 172 18 24 200 213 * ___ SL 013451 .'ONFID 3NT1AL * Pi !' j ec L to Pt: stecti ve Ore or of 4 t h J If] 1 cirl L Hist rict < our t No. Q ' - 1 J. 4 5 * PAGE 202-13 <g> **TRI .ETHANE" 1974 JAN Ave, MC REACTOR WT. % EtMYL CHIOMOC UINYLIPENC CHIPW1PE______________ TBAHS 1.2 *DICHLOAOE TKYtENE (0.01 4.19 0.90 fO.Ol S. T9 n.Ri CIS 1,2D1CH10H0ETHYIENE Mctmyl Chlohoeobm (0.01 0.15 94.62 93.82 FEB cMmic-ai Division IAKE OSAHi.ES, lOUSSIANA LADORATORY OPERATIONS RPPORT MAR APR MAY JUNE JULY AUG (0.01 4.43 1.46 (0.01 5.13 2.89 0.15 0.31 94.07 91.55' OiOl 8i 84 1.49 , 0;04 95.37 (0.01 11.94 5.41 0.04 S3.50 0.03 6.55 9.37 0.01 0.01 8.12 8.28 12.97 6.35 0.35 0.43 0.34 84.05 78.43 84.60 SEP (0.01 6.29 2.95 0.36 90.39 OCT NOV (0.01 0.03 4.92 4.81 3.57 1.25 0.35 0.28 91.03 93.21 DEC 1975 Avg. (0.01 4.97 1.78 0.01 6.63 4.19 0.38 0.26 92.83 88.90 TBICHLOAOETHYLENt 1 J ,2 *Tr fcklohoe thane U-TETAACHLOBOETHANE PEMTACHLOROETHANE UNA NOUN 0.01 5755 (0. U JL 0 0.01 0 0.02 0 0 (0.01 0. 0.03 0 0 0 0 0.02 0 0 0 <T" 0 03 ' 0.03 XT--------- 5 J. 0 0.02 OI 0 0.04 (0.01 0 0.01 0 0.03 0 0 0.01 00 0.06 0.08 P0 EJ----------- 0 0.01 0.01 TT------- 0.04 0 0.10 0.19 0.03 (5.51 5---------- 0 00 0 (0.01 (0.01 (0.01 0 0.06 . (0.01 0 (0.01 Ft PPM 755 581 305 349 386 496 561 973 1319 617 575 791 737 641 TOPPING ST Ml PRODUCT WT5 VINYL10EME CHLORIDE * 98 TRANS 1,2-D1CHLOBOE THYLENE 0.20 1 .1D 1CHEOROE THANE 0.05 CIS 1 ,2*01CHLOROCTHYLENE 0..02 METHYL CHLOROFOM* 99.59 1.I-DICHLOBOETHANE 0.04 Tb|CHLOBOE THYLENE (0.01 1.1,2 TA1CMLORCE THANE 0.07 175 0.21 0.11 0.11 99.46 0.03 0 0.08 ' 167 0.22 0.15 0.13" 99.43 0.03 0 0.07 , 200 0.19 0.15 0.10 99.56 0.01 0 0.03 1Q4 Oi 19 0*15 0.06 99.38 (0.01 0 0.02 116 0.02 0.19 0.06 99.70 (0.01 0 3.03 92 82 ` 0.06 0.13 0.07 0.02 0.18 0.24 99.61 99.45 0.01 0.01 00 5755-- 3.06 53 0.44 0.02 o72 99.11 0.03 0 0.10 82 0.38 0.04 0.29 99.11 0.04 0 0.09 "73------- 57 0.06 0.31 , 0.02 0.02 0.23, 0.25 | 99.49 99.23, 0.07 0.10 00 0.15 0.13 , 49 0.22 0.02 0.26 | 99.37! 0.04 0 0.06 ___i 104 i 0.201 0.08 0.18 99.41 0.03 0 0.07 ] CE RFTTTE1 i'j'lALs Sub ject o t*roi ectiV rrnrtte SL of 14 th Juc icial uistfc .ct Cu J1L 1 ----------- 1 7 91" 1143' i PAGE M .'iHE - TYPE 324 STABILIZATION VT. % Vinltidcnc Chloride BLM DTE .7 4 Avg i JAN O.-Ol 0.48 0.81 0.03 0.46 0.89 FE8 pro iWJSTRIES CHEMICAL DIVISION LAKE CHARLES, LOUISIANA LABORATORY OPERATIONS REPORT MAR APR MAY JUNE JULY 0.02 0.43 0.87 0.02 0.62 0.82 0.03 ~o75o 0.81 0.03 0.38 0.81 0.01 n. Tfl n. R9 0.01 0.36 O.R2 AUG 5EP -------- i ... 1 7, |B75 1 0.01 0.40 0.80 (0.01 0.34 0.81 (0.01 0.36 0.81 (0.01 0.35 0.81 (0.01 0.35 0.81 0.01 0.41 0.83 Methyl Chloroform DOL CIS 1,2-Oichloroethylene Trichloroethylene 1.Z-Dichloroethane IBL NRE NlTROETHANE NPL TLE 1,1,Z-TRICHLOROETHANE 93.83 1.01 0.01 (o.oi 0.02 0.32 2.09 o. 06 0.47 0.79 0.08 93.29 1.19 0.09 0.01 0 0.09 2.19 0.06 0.02 0.85 0.06 93.53 1.06 0.11 (0.01 (0.01 0.80 2.23 0 0.01 0.86 0710 93.34 1.08 0.12 (0.01 0 0754 2.19 0 0.01 0.90 0.05 93.55 94,79 1.09 1.09 0.05 0.05 (0.01 0 0 (0.01 0.84 0.83 2.ia 2.14 00 0.01 0.01 0.88 . 0.81 0.05 0.02 93.92 1.11 0.17 0 (0.01 0.84 2.14 0 0.01 0.86 0.06 93.42 1.13 0.24 0 (0.01 0.86 2.15 0 0.01 0.86 0.05 93.45 1.09 0.26 0 0.04 0.85 2.10 0 (0.01 0.83 0.10 92.93 1.10 0.26 0 0.08 6.55 2.09 0 (0.01 0.89 0.09 93.53 1.10 0.23 0 0.06 0.85 2.14" 0 0 6.54 0.14 93.22 93.15 1.10 1.14 o'.'2r 0.25 00 0.09 0.04 0.85 0.86 2.12 2.16 00 (0.01 (0.01 0.86 "o7s4 0.12 0.07 93.51 1.11 0.17 0 0.02 0.85 2.15 .0 (0.01 0.56 0.08 STABILIZING TANKS Moisture ppm pH HCl Acidity Non - volatile Residue ppm * Color Specific Gravity APha Avo. Dll TILLATIQN RANGE C Low Soluble Chlorides HIGH rfiA 52 6.9 1 . 0002 5 l. 30s 62 6.9 1 .0002 6 1.304 37 7.0 1 .0002 5 1.303 39 7.0 (1 .0003 8 1.303 35 30 7.0 . 6.8 (1 1 .0005 .0002 86 1.303 1.303 29 38 38 6.7 6.9 7.0 2 1 (1 (.0001 (.0001 .0002 67 5 1.304 1.306 1.304 51 6.7 4 .0004 5 1.304 "36------- 6.9 2 .0002 (5 1.305 36 24 7.0 7.0 2 (1 .0003 .0003 55 1.305 1.305 38 6.9 1 .0002 5 1.304 73.0 82.9 (0.5 73.4 83.3 (0.5 73.4 83.5 (0.5 73.1 83.2 (0.5 73.0 83.2 (0.5 72.7 82.7 (0.5 72.8 81.9 (0.5 72.7 80.8 (0.5 72.9 81.4 (0.5 73.0 83.1 (0.5 72.8 82.2 (0.5 72.9 82.6 (0.5 73.0 82.6 (0.5 73.0 82.5 (0.5 ci 013453 OL v 'w m m - ---------cc RFTUE! ITTAC: SITT5 ject E o Frol GCt 1 V : urde r _h Juc i c i a 1 Tmrrr -c't LO JxT ---------- cn 3T- ITT 5 PPG '.bsTRIES '' PAGE 202-15 ", ' CHIWCAl DIVISION lAKE Ci [ARIES, IOUISIANA LAnOHATORY OPERATIONS REPORT PER/TRI HEAVIES STILL BOTTOMS T1CHLOHOrTHrifHC 1, t,2Tnichlorqethahe PEBCHLOROtTHYLtNE U.TtTSAEHLOflOETHANE S.TETRACHIOROETHANE PenTACHLOROETHANE He kachloroethane % * * % * * % 197 1 JAN Avg. (0.01 0 0.03 0 H57ZT 15.51 4.40 4.06 29.52 30.77 25.05 32.57 j. bb 4731 FEB 0 0 27.28 3.78 20.94 31.15 4.60 MAR 0 0 11.86 4.72 39.03 29.67 T7I3 APR MAY JUNE JULY 0 0 22.12 4.79 30.64 27.53 3.96 (0.01 0 17.37 4.18 34.06 23.94 3.25 0 (0.01 00 12.00 18.60 4.91 3.67 43.88 31.75 20.08 25.35 2752-- 3.69 AUG 0.01 0 18. io 2.02 14.62 41.13 8.04 SEP OCT NOV 0 0 18.26 2.39 16.47 39.49 8.15 0 ,0 36; 85 3.22 17.81 24.08 4.40 0 0 12.42 4.37 35.30 27.3d T.T3 OEC 0 0 23.68 3.22 20.27 26.37 4.86 1975 Avg. (0.01 0 19.50 3.78 _ 27.96 29.06 4.54 Heavy Unknowns * 5.71 4.39 3.73 4.24 4.16 6.05 6.56 6.24 4.83 5.23 6.47 7.73 8.04 $.64 FeCl 1 Non-Volatile ppn 42 21 * 3.74 - 84 37 - 45 54 51 86 67 37 69 52 37 53 --- -- - - -- - - i , SL n01* 3o 41 bC 4A 1 4 ---------------- CONf identi AL: Sulrjfe :t to Jrotec Live ( rder 14 th Judic a 1 Di Strict Con r tNoT 91-11 15 PAGE 202-16 . PPG ^WSTRIES CHI MICAl DIVISION LAKE CHARLES, LOUISIANA LABORATORY OPERATIONS REPORT PERCHLOR STABILIZATION IYPE 208 WT. PEflCHLOROETHYLENE 1.1.DlCHLOftOBROMOETHYLENE 1. 2 -Dtcm.OROBROMOETHYLEKE 1, 1,2-Trichloroethane UiTETRUCHLOBOEthane EPE % 1974. JAN 99s 86 (0.01 0.01 0.03 0.04 0.05 99.86 (O.Ol (O.Ol 0.03 TT7TT5 0.05 FEB MAR 99.85 99.86 (0.01 0.01 0.02 0.06 (0.01 0.01 0.04 0.04 0.05 0.03 APR MAY JUNE JULY AUG SEP OCT NOV OEC .J375 '99.8C 99.86 (0.01 (0.01 0.01 (0.01 0.03 0.04 0.07 0.04 0.06 0.05 99.86 (0.01 0.01 0.03 0.04 0.05 99.87 (0.01 0.02 0.03 0.03 0.04 99.91 99.88 (0.01 (0.01 (0.01 (0.01 (0.01 (0.01 0.04 0.05 0.04 0.04 99.87 99.87 (0.01 (0.01 (0.01 (0.01 0.01 0.02 0.05 0.05 o. bs 0.06 99.86 99.86 (0.01 (0.01_ 0.02 (0.01 (0.01 0.02 0.06 0.05 0.05 0.05 TYPE 207 Pt BCHLOROtTHYLENE WT 1,1-DlEHLOflOBBOMOETHYLENC 1,2-Cichlorobromoetmyiene U,2-tTftfCm.OROE THANE U.Tetrachloroethane EPE % 99.80 (0.01 (0.01 0.02 0.04 0.05 99.80 0 0 0.03 0.06 0.05 . -- - -- - 99.78 0 0 0.03 0.05 0.05 99.79 99.81 90 00 0.03 0.04 0.05 0.04 0.05 0.04 99.84 0 0 0.02 0.04 0.04 99.81 0 0 0.02 0.03 0.06 99.84 0 0 (0.01 0.05 0.05 99.79 0 0 (0.01 0.06 0.06 99.80 99.79 00 00 0.03 (0.01 0.07 0.06 0.05 0.06 99.80 99.80 (0.01 0 00 0.01 0.02 0.06 0.05 0.06 0.05 SL 01345b Cf NFTDR jt r Ar. Snh Toof t n Pro pr-L i '/ = Orc{(3 c________ of 1 4 fh ,lnf i r- i p ! n i Rt- r i n fc Cn o - 9 1- .1 1 4 S PAGE 202-17 TRICHLOR STABILIZATION TTPE 132 WT.% 19/' Avg. JAN ppg industries CHEW CAl DIVISION IAKC CIlACIES, IOUIS1ANA LABORATORY OPERATIONS REPORT FEB MAR APR MAY JUNE JULY L: AUG SEP OCT T57T NOV 1 DEC Avg. Carbon Tetrachloride EPN NPL TR1CM.OROE THYLENE PE RCHLOROE THYLENE 1.1.2-TRICHLOROETHANE (0.01 0.14 99.43 (O.Ol 0.02 (0.01 0.08 0.14 99.39 0 0.04 (0.01 (0.01 0.09 0.08 0.15 0.15 99.36 96.40 00 O.O3 (0.01 0.01 0.09 0.08 0.15 0.15 99.35 99.38 60 0.02 0.03 0.01 0.08 0.15 99.34 0 0.01 0.01 0.09 0.16 99.35 0 (0*Q1 0.01 0.09 0.15 99.41 13---------0.(32 0.01 0.07 0.15 99.40 0 (0.61 (O.Ol 0.09 0.17 99.34 0 0.03 0.01 0.09 0.16 99.36 0 0.02 (0.01 0.08 0.15 99.36 0 0.02 (0.01 0.08 0.15 99.37 0 0.02 Unidentified. Total NMP NRE DPE (0.01 0.029 0.06* 0.011 (0.01 0.028 0.06 0.009 (0.01 0.025 0.^5 0.009 (0.01 0.022 0.05 0.010 (0.01 (0.01 wo. 01 0.021 0.024 0.024 0.05 0.05 0.07 0.011 0.009 0.009 (0.01 0.024 0.06 0.011 (0.01 0.023 0.06 0.009 (0.01 0.023 0.06 0.011 (0.01 0.01 0.021 r0.022 0.06 0.07 0.014 0.010 (0.01 0.021 0.06 0.009 (0.01 0.023 0.06 0.010 TYPE 113 WT. % Carbon Tetrachloride Trichloroethylene PERCHLOROETHYLENE tv t .Z-Trichloroethahe UNIDENTIFIED. TOTAL * (0.01 (0.01 0 (0.01 (0.01 0.02 0.01 - 99.98 99.98 (0.01 (0.01 0.01 (0.01 99.98 99. 98 00 0.01 0.02 (0.01 0 0 (0.01 99.98 99.97 0 (0.01 0.01 0.02 99.50 0 0 -- - - 0 (0.01 0 - 0 (0.01 (0.01 (0.01 0 (0.01 99.98 0 0.01 99.99 0 (0.01 99.99 99.97 00 0.01 0.01 99.99 0 (0.01 99.94 0 (0.01 0 (0.01 0 0 (0.01 (0.01 -- SL O'3456 1 ( 'ONFID SNTlAr. ----------- Sn ^ ject to t'r< >tecti --w--r *tb Ju (Jicia, Dist ve I1rr| pr :int- No. "1145 ETHYL CHLORIDE C2H4 Feed % PRIMARY STRIPPER Bottoms PPM HC1 FeCl3 H2O J 1974 Avg. JAN FEB f'PG ir TRIES cntMicAi envision * IAKE CM VUES, IOUI5IANA LABORATORY 01'BRAT IONS REPORT MAR APR MAY JUNE JULY AUG SEP OCT NOV OEC 1975 AVq. 99.92 99.93 99.89 99.94 99.89 99.89 99.95 99.93 99.95 99.94 99.99 99.86 99.93 99.92 90.2 2.18 78 - 0.26 74 - 0.30 72 99.8 0.19 89 0.14 72 - 5.02 113 - 2.38 117 0.12 78 - 1.67 142 1.10 75 - 3.37 98 20.72 125 1.98 72 99.8 3.10 94 Still Overhead c2H5Ci HC1 H20 Wt. % PPM PPM 99.96 55 151 ci oi_ 013457 v , a N FI DE IT1AL: S u i; ject 0 Fro ect i. v ? Or fit; 1 ~oT TT tf> Jut 1 c j a i !)i s tr .ct Cc jz L r 0.. y I 114 5 VINYL CHLORIDE FELD TO UNIT * coc 99.98 VAPORIZING FURNACE PECO VIM V L 1 DEN E CHL RlOE 1.1' OICHtOnoCTHANC CHLOHOr RM WT, % (0.01 WT. \ 0.04WT.t u. 13 1.1- OICHIOROCTHANC OTMEl Hj' WT.% 99.68 WT( % 0.01 PPM 67 MC' wt.% 0.03 re PPM 0.37 c,a . (1 ABSORBER-STRIPPER COLUMNS QUENCH LIQUOR VINYL CHL RtOE VINYUDEME CKLOflIOC T. 7.04 wt.* 0.02 t- (.1 CIICHi.onoCTHVI.CNC wt.* 1 1* OlCHLOflOETH AN c CHL flOPRENC WT.% 0.05 WT.* 0.02 CHLOfl F RM yvr.% 0.04 1.1- OICHLOROCTHANC other* h4o HCI re WT.% W T.% PPM WT, * PPM 92.8(J o:o4 146 0.96 16.64 JAN FED ,!.ppg i^usmes CIU'MIC-^PlViyOM lAK[ Cl ASltS, lOimiAfU LABORATORY OPERATIONS REPORT (AAR Apn j MAY JUNE JULY AUG 99.99 99.99 99.98 99.96 99.99 99.87 99.97 99.98 SEP 99.97 # OCT NOV 99.96 99.99 DEC 99.99 .1975 AVG. 99.97 (o.oi (0.01 0.02 0.02 0.04 0.52 99.86 99^93 0.01 (0.01 .55 36 0.01 (0.01 0.62 0.30 1 (1 (0.01 0.02 TJ7ET5 (0.01 0.03 6.07 (0.01 0.03 0.03 yrrzr- 9737* WT75- 0.01 (0.01 ' TO 771' 24 (0.01 0.27 (1 39 7=; o.oi 0.01 0.30 1.15 (T---------- (1 (0.01 0.01 (0.01 (0.01 0.04 0.06 0.06 0.08 0.08 0.07 0.02 0.15 99.65 9377TT" 98.96 98.29 0.02 (0.01 <531 0.01 41 26 27 48 0.01 0.91 (1 0.04 1.13 (1 0.03 0.04 CT7T3 0.74 n-- 2 .0.01 0.11 U.3U 0.01 0.11 0.13 98.85 99.26 _T(20-.-0--1- 0.01 48 0.03 0.05 1.36 0.83 ~a-- U (0.01 0.10 0.09 99.46 (0.01 43 0.04 3.08 1 (0.01 0.06 0.09 99.35 (0.01 42 0.02 0.93 (1 164 8.17 209 3:73" - - * 214 U 2.36 269 - 5.80 147 - 4.07 82 -- 0.75 135 0.62 -- - - - - 174 - - -- -- 1572 - 5.09 * -l FURNACE FEED % CC1([ 0.05 (0.01 (0.01 0.02 0.03 0.01 n.m _ SL 013458 -- - -- -- 0.48 0.34 0.32 0.14 Of e..K 1 A4 tu JPIDEN QCt > Proti ** uuni L-Id 1 | ET7TFr~ active >18tri Order ;t Cou :t T 4 5----- ' PAGE 202-20 ; VINYL CHLORIDE ABSORBER-STRIPPER COLUMNS 1974 AVG. LEAN IL VtNV L CHLORIDE WTt* ----- tlNTUJEUt CH LORI PE______ WT.* 0.02 JAN FE0 fpg-irm^JSiKiLS CHtMC^Wl VISION IAKE CIIARIES, LOUISIANA LABORATORY OPERATIONS REPORT MAR APR MAY JUNE JULY AUG SEP OCT NOV DEC 1975 AVG. _ 1.1- DICHLOR ETHANE CHLOR PRENE WT,% 0.06 WT.S 0.04 . chlor ronM 1.2* dicmlopoethanc OTHERS H jO ,, MCI re . UPPER INTERCOOLER VIMYL CHL WIDE HjO NCI re WT.t WT.H W T,% PPM PPM PPM 0.04 99.75 0.03 53 9.14 0.56 * WT.S PPM RT.t PPM 1.70 197 1.49 16780 51 0.72 106 0.86 163 1.02 176 3.69 128 3.94 244 5.36 5.05 135 - 3.22 173 1.5,1 92 1.59 27 2.60 - - - 130 5.36 " 2.42 COWER INTERC OCER VINYL CHLOPIDC HjO HCI re -\ 1 WT, % PPM WT.% PPM 2.22 221 3.76 16.31 173 4.65 81 0.70 87 2.08 349 6.87 294 5.16 140 568 127 10.79 3.46 1.86 100 1.04 - - > 1 114 7.8 . - 203 - 3.74 X \ 1_ qi 013459 \ OL \ CONF DENT [ vL: 0 u b j s t t to rofcec :ive O rlpr Ui 1'4'th Judicj a 1 Di. strict Court JToT yi-11 5 ,-r PAGE 202-21 ' '- ^ PPG It^BSTRIES CM1MICAI OIVISIOM tAKC CHARllS, IOUISIANA LABORATORY OPERATIONS REPORT VINYL CHLORIDE _________ VC PRODUCT STILL 1974 JAN AVG rec o vinyl cmc mot VlNVUOENE CHLORIDE net 12.58 HT.t 0.05 l.- OICHS. nOETHANE WT.H 0.06 CHLOSOKHENE CHLOR r PM *T.i 0.04 ffT.t 3757 1.1- Dl chlowoetman s wt. 93.2$ other* HjO wt.% 0.02 PPM 61 H Cl PPM 6.73 t~z PPM 1.13 PR DUCTM HOMER (DAY TANKS) VtNVU CHLORIDE BUTADIENE METHYL CMLOfllOe ethyl chloride WT.% 99.989 99.995 PPM 6 2; PPM 28 27 ppm 23 19 FEB MAR 99.998 99.995 23 22 27o" 3 APR MAY JUNE JULY AUG SEP OCT NOV DEC 975 AVG * t 99.994 99.996 99.990 99.993 99.990 5 3 6 8 10 30 19 29 28 28 23 16 25 24 27 99.985 9 44 39 99.992 11 '36 28 W'< 99,993 7 26 26 99.993 7 29 30 99.993 6 29 22 OTHER! NjO PH HC1 Vinyl Acetylene 1,1 - Dichloroethane 1,2 - Dichloroethane PPM 0.2 PPM 42 PPM. 0.10 7.3 0.2 . PPM 5 PPM 1.2 PPM (1 0.2 20 0.02 7.3 (0.1 6 0 0 0 46 0.11 6.9 1.0 - 0.2 45 0.09 6.8 (1.0 3 - 0.3 34 0.14 6.7 (1.0 9 r Am 0.2 57 o7o5 7.1 (0.1 4 -- 0.3 39 0.07 7.7 (0.1 5 -- 0.5 0.1 32--------- 54 ' 0733-- 0.06 7.1 7.1 0.2 (0.1 7 10 -- -* (1 56 0.07 7.2 0.2 11 - - 0.5 0. 3 47 ' 62 0.36 0.08 6.9 7.3 "373 (0.1 ~1--------- 6 --- -- 0.2 59 0.18 7.4 * 0.2 . 5 - - 0.2 45 0.08 7.1 (0.1 7 - - *. ,' CONF TJPM'pt \ t . I SL 013460 Z . t5ubi<5{ to 14 th---------------T `Tudic. aJ '- i J __ {y 'TTor V.i No. 91-1 1 ex K Court ______________ ! i. ' PAGE 202-22.________ * PPG I. .' STRIES COMICAL DIVISION WKC CHARlfS, LOUISIANA LABORATORY OPERATIONS REPORT VINYL CHLORIDE JAN FEB MAR APR MAY JUNE JULY AUG rceo HEAVIES STILL VINVLIDCNC CHLORIDE RT.% 0.01 .. >. 02 1.1- DICHLOflOETHANC C- 1,** OlCHLOnOETHVLENE WT.1l Q.,07___ Q-05 WT, % fo.oi 0 . CHI ROP RM WT.* 0.22 0.09 11- OICMt. ROETHANE WT.% 93.. 2.1. 99-61 1.1.1- TRICMLOR ETHANE W T.X 0.13 0.07 OTHER* WT. 0.05 0.02 _Hz_______________________ PPM 69 NCI RT.1l 0.15 re PPM 4.01 51 0.01 2.01 c,a PPM (1 ; 3 BOTTOM* CHLOROFORM 1.1- DICHLOnOETH AN C __ trichloroethylene WT.X (0.01 **T.% BO'. 72 _Ht.% 3 0 90.01 0 . 0.01 0.02 0 d.64 99.82 0.10 0 54 (d.oi 2.75 1 0 92.48 0 0.01 0.03 0 .0.06 0.05 0.02 18 (0.01 2.34 2 0 88.26 0 *6.02 0.01 ' O'.103 0.02 (0.01 0.05 0.07 0.07 0.07 0.08 00 6.56" "6755 00 0 0.05 16765-- 6765 99.34" "95745" 99.32 99.22 99.02 0.06 0.08 33 0.06 0.09 0.13 TJ705-- 0 0.04 0731-- "44------- 32 0.16 0.10 46 0.02 0.01 0.01 0.03 0.04 3.07 6.00 3.82 4.13 5.00 2 (1 :i 71-------- (1 0 78.84 0 n 7Q_ n 0 n0 7ft 9ft 72.21 00 0 81.33 0 SEP OCT NOV 0.02 6.155 0.01 0.13 0.03 0.24 97.22 0.18 0.17 42 0.10 5.27 "4--------- 0 86.01 0 0.20 0.01 0.53 97.19 0.25 0726 29 0.05 5.59 1 0 56755 0* 0.19 0.01 0.27 97.88 0.16 0.32 45 0.07 5.21 a 0 81.30 0 DEC 1975 AVG. 0.01 0.01 0.22 0.01 0.18 97.82 0.27 0.47 21 0.04 4.04 (1 0.10 o. 0.14 98.81 0.13 0.13 37 0.03 4.10 1 0 69.70 0 0 81.78 0 1.1,1- TRICHLOROETHANE **T. LI. 52 OtHERI HC1 re WT.* 7.58 WT.X 0.03 PPM 80.34 ViASTF-DOPP KETTLE BOTTOMS 1.1- OICMt. R ETHANE %WT. RERCHLOROCTHVLEN E WT. % 1.1.1- TRICHLOROETHANE U^rCTRACHLOnOETHANE WT.% WT. % S-TETRACKLOROETHANE PEN TaCMLOROETHANE OTHER* WT. A WT,% hT.% TAR* NtflOUK PPM WT. * WT. 5.68 6.44 7.64 4.32 3.04 35.45 1.07 0.04 56.83 4.10 0.04 93.80 SL 013461 ** 6.07 20.13 0.11 58.63 6.98 13.71 0.06 41.00 9.01 12.54 V 12.73 12.54 0.02 0.02 41.00 37.50 3.81 9.86 3.03 24.10 1.21 1.70 0.04 44.82 7.15 5.82 9.20 12.88 0.03 0.03 31.60 44.60 14.04 * 17.01 0.05 54.25 7.62 9.94 0.04 51.71 CTJT FTTTETU TAL: STITT} scT fJ rrote UTl VO CTdPT j L 14 L t rrrnri (,,j 1 ;rr i 11 * T r i rt--i`rn Nt ~ y l - j TTD------ - . NaOH NajO MC-50 CAUSTIC DAY TANK COMPOSITE It As It X As It NCOt NaCI NajSOa XA. B. X A. B. X A. B. CaO Cu AI9O1 Pt Ha MgO Mn N( Si09 PPM A. B. PPM A. B. PPM A. B. PPM A. B. PPM A. 8. PPM A. 8. PPM A. B. PPM A. B. PPM A. B. 1974 JAN. Avg. 50.35 50.30 39.01 38.92 FEB. 50.03 38.90 PPG IKWSTRiES CHEMICAL DIVISION LAKE CHARLES,LOUISIANA LABORATORY OPERATIONS REPORT MAR. APR. MAY JUNE JULY AUG. 50.21 50.43 50.28 38.94 39.16 39.01 50.37 50.34 50.27 39.16 39.07 39.02 SEP. OCT. 50.20 50.25 38.97 38.65 NOV. DEC. 50.17 50.22 38.89 38.90 1975 Avg. 50.26 38.97 (0.01 0.002 0.(501 (0.01 (0.01 0.01 (0.01 (0.01 0.001 0.005 0.009 0.004 0.002 (0.001 (0.001 (0.001 (0.001 (0.001 (n.m 0.01 0.01 0.02 0.003 0.004 0.003 0.005 (0.001 (0.001 (0.001 (0.001 0.01 0.01 (0.01 (0.01 0.003 0.003 0.002 0.004 (0.001 (0.001 (0.001 (0.001 2.07 6.08 0.5 Ua 2 U. Ub 0.38 '0103 0.48 18 2.92 7o75 U.4 (J.TI3 0.46 0.03 0.54 0 1.43 0.10 0.5 0 0.03 0.50 0.04 0.60 ri" 1.41 0.06 (0.5 0 0.08 0.67 0.05 0.53 9 1.92 0.15 0.8 A.4 n.Od *0.56 0.06 0.67 , 15 1.54 0.09 (0.5 TO 0.04 0.32 0.05 0.52 20 1.40 0.14 1.4 0.2 0.03 0.21 0.04 0.84 12 1.82 1.40 0.09 0.09 2.5 1.9 TJ75----- 0.6 0.03 0.44 0.06 0.71 0.06 0.20 0.14. 71789 17 18 1752 T.T2" 1.67 0710" 0.14 0.10 T7S-- 1.4 (0.80 1.85 0.10 0.58 0.4 1.1 0.9 1.2 0.15 0.05 0.05 0.05 0.14 0.15 0.22 0.24 0.06 0.03 0.03 o7o3 0.58 "0732 0.57 0.57 TI------ T4------- ~Z3------ - 1.69 0.10 1.0 0.4 0.05 0.34 0.05 "0752 T4-------- ' <^t 013462 1 -----------1 ----- COM FIDBH'J IAIj; sub} *ct--tc "PTOtt Utl VM T Jud 1 uid 1 I istiii "fc Ik 91 "J 145----- CVjUI MERCURY CELLS Cell Feed Brine NaCI GPL NaCIOj GPL NaoSO^ GPL Insolubles PPM Turbidity JTU NHi PPM Fe PPM CaO MqO SI07 Mn Cu Cr Mo Al V PPM PPM PPM ppb PPB PPB PPB PPM PPB 1974 JAN. AVG. FEB. PPG IN0GTHIES CHEMICAL DIVISION LAKE CHARLES,LOUISIANA LABORATORY OPERATIONS REPORT MAR. APR. MAY JUNE JULY AUG. SEP. OCT. NOV. DEC. 1975 AVG. 298 2.63 1.84 (10 2.4 (0.1 0.08 14.1 0.84 26 4 21 1 (1 0.20 3 301 1.81 2.25 (10 3.2 (0.1 0.09 296 1.73 2.52 (10 3.3 (0.1 0.15 302 1.09 2.61 (10 2.5 (6.1 0.09 303 0.77 2.00 (10 3.5 (0.1 0.31 302 0.80 1.93 (10 4.2 (0.1 0.71 300 0.77 2.12 (10 3.1 (0.1 0.43 303 0.45 2. an (10 3.1 (0.1 0.40 14.5 0.95 38 3 17 (1 (1 0.07 (1 14.5 0.78 52 5 12 (1 (1 0.04 (1 13.2 12.1 0.81 1.25 38 35 24 68 71-------- (1 (1 0.02 (1 (1 0.01 2 10.5 0.86 32 5 6 2 (1 0.08 <2 14.9 0.85 32 12 9 1 1 0.09 1 12.R 0.58 26 6 13 1 (1 0.10 6 309 0.60 2.02 (10 1.7 (0.1 0.08 305 0.85 1.72 (10 1.5 (0.1 0.11 303 0.77 2.77 (10 2.1 (0.1 0.09 301 0.83 3.00 (10 1.3 (0.1 0.06 296 0.86 3.26 (10 1.6 (0.1 0.11 9.6 0.63 24 4 4 1 (1 0.10 11 13.4 0.59 30 6 5 (1 :i 0.20 (2 15.1 0.66 28 1--------"9--------71--------- 71 u;i2 10 11.4 0.54 31 3 9 1 (1 0.14 4 10.6 0.56 5 6 1 (1 0.13 (1 302 0.94 2.42 (10 2.6 (0.1 0.22 12.7 0.76 33 5 9 (1 (1 0.09 3 DeDleted Brine Fe PPM (.12 0.21 0.26 0.15 0.28 0.20 0.16 0.14 0.13 0.14 0.14 0.09 0.21 0.18 Ha PPM 15.0 13.0 11.8 9.7 11.7 14.1 9.7 9.7 9.9 11.7 11.6 12.4 23.4 12.4 01 Water To Head Tank PPM NaCI 13 8 10 9 10 10 10 6 3 4 3 22 6 Unfiltered MC-50 Hg PPM A.B. 3.2 Fe PPM A.B. 2.5 Ni PPM A.B. 0 Total Solids PPM A.B. 4 -- SL 013463 0.67 0.3 0 (10 1.07 0.4 10 3.80 0.4 - (10 3.24 0.6 -- 10 0.93 0.3 -- 15 . 3.50 0.4 - 16 2.50 0.6 5 2.60 0.4 - (10 (3752 0.8 (10 2.W 0.8 (10 4.80 1.1 - (10 4.50 0.9 -- 12 2.58 0.6 7 'ONFUJ ISN'T 1 AI Si '5 i 3 c t t o P r Jtecti ve ore of J 4 th J( id it: i ci J U i s t r i c t L| om L. ' No. y L-1145 PAGE 202-25 METALS IN MERCURY CELL FEED BRINE Test AA AA C SE AA SE AA T AA AA AA C AA SE AA NaCI Al Sb As Ba Be B Cd CaO Cr Co Cu Fe Pb MgO Mn GPL PPB PPB PPB PPM PPB PPM PPB PPM PPB PPB PPB PPM PPB PPM PPB AA He AA Mo AA Nl PPM PPB PPB C SIOz SE Sr PPM PPB AA AA(D) SE AA AA SE Sn Ti W V Zn Zr PPB PPB PPB PPB PPB PPM 1974 AVG. 299 41 JAN. 301 89 PPG IM0STRIES CHEMICAL DIVISION LAKE CHARLES,LCUISIANA LABORATORY OPERATIONS REPORT FEB. MAR. APR. MAY JUNE JULY 299 292 302 14 (3 ti 302 301 295 (4 56 115 AUG. SEP. 305 301 61 128 OCT. 301 14 NOV. 300 83 (30 (1 (2 (0.5 5 11.2 (3 7 25 0.04 12 0.6 2 16 (1 24 (1 9 (1 (0.5 (1 9.22 (1 1 19 0.03 1 U773 2 33.3 (1 20 (1 4 (1 (0.5 (1 12.20 U (1 13 0.05 4 2 40.8 (1 20 (1 i 3 (2 (0.5 l i 0.5 (1 1 12.20 (1 U 8 0.01 19 4( 4 p.08 2 0.60 6 0.76 ti--: 2 11.7 9.2 (1 1 19 21 Ho 7 2 (3 (0.5 (1 9.2 (1 5 7 0.08 (1 0.79 3 11.7 (1 41 ,U 3 (2 (0.5 (1 9.7 1 (1 7 0.39 4 0.70 9 12.5 (1 15 (1 (1 33 (15 (0.5 (1 (0.5 (1 13.7 1 2 10.9 1 71------- (1 TO------- 18 0.20 0.06 5 0.52 7 9.2 3 0.35 6 9.1 (1 (1 13 10 (1 (1 ti ;o.5 2 8.3 1 :i 8 0.04 5 0.47 4 12.5 1 11 (1 [1 (1 (2 (1 \2 (0.5 ;o.s 1 10 13.4 7.3 11 T-------- 1 "3--------- 11 0.05 0.02 34 0.09 0.58 1 12.5 1 8 1 11.7 1 33 22 34 (1.0 (1.0 38 (1.0 39 (1.0 40 (1.0 24 30 (1.0 (1.0 33 (1.0 28 (1.0 - (1.0 24 30 (1.0 :i.o (1.0 - - -- - - -- - - -- - (2 (1 (1 (1 d 34 36 36 37 23 - -- - - - -- - --- - --- (3 (2 (5 64 36 - - -- -- -- -- TI----------- 1 64 44 _-- - -- (2 571 - - - - (2 125 - DEC. 297 134 a*975 300 58 (1 (1 12 (0.5 1 9.0 1 (1 7 0.03 12 0.15 2 18.3 (1 7 (1 2 2 (0.5 i. "TUT? 2 1 10 0.09 4 0.52 3 16.0 (1 18 28 (1.0 - (2 158 32 (1.0 - -- (2 109 - t AA * Atomic Absorption C Colorimetric SE Spectrographtc Emission T Titration (D) - Test Being Developed SL 013464 __________ i__________ i__________ l - ran ? T DENT AI.: Kfih jt r*F Ln Prate :fc i ve rdf; r nf 14 I lid i :ia 1 D Lstric L Cour c No , 91-1 .45 OHC-EDC CONDENSED ORGANIC REACTOR NO. 1 Malhvl ChiorIda Vinvl Chlorido % Ethvl ChiorIda Vinyltdlna Chlorida 1.1-Dlchloroathvlana cis-T, 2-Dichloroathylant Chloroform EDC Carbontatrachlorida Trich loroethylana Chloral 1,1,2-.TrichloroGth^np Perch 1 oroa thv lena U-Tatrae h loroa thana S-TetracMoroothana Pe ntachtoroe thana Unknown* 1974 JAN. AVG. FEB. PPG IM0O5TRIF.5 CHEMICAL DIVISION LAKE CHARLES,LOUISIANA LABORATORY OPERATIONS REPORT MAR. APR. MAY JUNE JULY 0.05 1.07 1.45 ). 05 0.04 0.02 0.33 0.04 0.06 0.04 0.52 0.07 0.05 0.04 0.44 0.07 0.06 0.07 1.29 0.07 0.05 0.04 0.34 0.08 0.05 0.04 0.33 0.05 0.07 0.02 0.25 0.09 3.19 3.23 b. 63 94.93 0.74 0. 1 2 3.36 L. 85 3.03 (0.01 0.34 0 0.12 O 0.88 94.61 1.32 7577)9 0.33 1.79 0.02 0.02 0.24 0 0.12 0.15 0.99 93.70 1.62 757(59 0.29 1.96 0.03 0.02 0.35 0 0.15 0.19 1.04 93.75 1.32 0.13 0.24 2.09 0.03 0.03 0 * 43 0 0.25 0.15 0.32 0.18 0.65 7)799 93.23 $4734 0.72 0.13 ,0.57 2.13 1.13 0.12 0.21 1.96 0.06 , 0.04 0.02 0 0.43 0.40 00 0.24 0.21 0.25 0.29 0.49 0.90 95.00 92.82 0.46 0.99 0.17 0.13 0.20 0.10 2.05 2.90 0.07 0.06 (0.01 0 0.63 1.17 00 (0.01 0 0.01 0 0 0.03 (0.01 0 AUG. SEP. OCT. NOV. DEC. m -- 0.10 . 0.04 0.03 0.04 0.05 0.06 0.08 0.10 0.08 0.05 0.41 0.90 0.74 0.82 0.58 -- 0.05 0.05 0.06 0.05 0.06 - 0.20 0717 0.22 0.18 0.18 - 0.12 7J7T7 0.23 0.14 0.20 - 0.70 0.80 0.80 0.71 0.81 - 95.08 94.69 94.33 95.32 94.26 - 1.14 0.78 1.17 0.80 i .04 " 0.12 0.07 0.09 0.07 0.11 0.35 0.41 0.32 0.31 0.30 1.47 1.59 1.66 1.32 1.90 - 0.05 o7o3 0.04 0.04 0.04 - 0.03 737751 o.bl 0.02 0.01 - 0.17 737T9 0.19 0.11 0.39 -0 0 0 00 - 0.02 (o.ol (0.01 (0.01 (0.01 SL 0w Ii3w4*RtO53 Unlan OtharwiM Indicated ( TjfTF'Tnr Si iviect to tr : 4 tb J id ci No. - i-p otd cr net L ourt OHC-EDC CONDENSED ORGANIC REACTOR NO. 2 Methyl Chlotida % Vinyl Chlo'irfo Elhyl Chlorirle Vfnylidint Cftlorld* 1974 AVG. JAM 0.04 0.06 0.43 0.05 Q.05 n.nfi 0.33 0.06 FEB. PPG Ks'tJPTRIES CHEMICAL DIVISION LAKE CHAF! LE 5, LOU I SIANA LADORAtORY OPERATIONS REPORT MAR. APR MAY JUNE JULY 0.04 0.07 0.60 0.08 0.07 0.06 0.61 0.07 Oi 07 0.05 0.90 0.08 0.06 0.03 0.03 0.05 0.21 0.31 _ 0.06 0.06 AUG. 0.04 0.06 0.37 0.08 SEP. - _ - 1. 1 Diehlorocthylcn# cis-1. 2-Dichtoroethylena Chloroform EDC Carbontelrachlorida Trichloroethytana Chloral 0.16 0.16 0.71 95.08 l.ol TTTTD <rm 1.*2 ' Trichloroethanp_______ 1.63 Pc rchloroothy 1 ana 0.02 U-Tetrachlorcethana 0.01 S-T ctracWorootl i an* 0.20 Pentachloroethana 0 0.12 0.12 0.98 94.61 1.49 0.08 0.23 1.62 0.03 0.02 0.15 0 0.11 0.12 1.10 93.47 2.17 0.08 0.26 1.68 0.03 0.02 0.17 u 0.15' 0.16 0.96 93.70 1.43 0.10 0.30 1.91 0.03 0.02 0.37 0 0.17 0il9 1*02 93.16 lt 63 0.14 0.20 2.00 0.06 0.0 3 0.32 0 - - -- .. - 0.29 0.39 0.49 95.78 0.47 0.16 0.38 2.65 0.06 0 0.97 0 0.20 0.14 1.08 93.92 1T57 0.18 0.17 1.58 0.07 0.05 0.19 0. 0.20 0.15 1.08 93.68 1.86 0.15 0.29 1.74 OT7T7 [7704----U.25 3 -- - -- - - - Unknowni to.01 0.02 0 0 0.01 -0 0 <0.01 - OCT. NOV. DEC. 1975 AVG. - 0.05 0.04 0.05 0.08 0.08 0.06 1.07 0.85 0.58 - 0.05 0.06 0.07 - 0.22 0.17 0.18 - 6.14 0.10 0.17 " 1)771 0.91 - 94.46 95.10 94.21 - 1.12 1.09 1.47 - 0.07 0.06 0.11 - 0.30 0.29 0.27 - 1.51 T.T6" 1.77 - 0.04 0.07 0.05 0.03 0.02 0.03 - 0.14 0.13 0.30 -0 0 0 - 0 'Toror {0.61 f SL 013466 * Unlais Otherwise Indicatad 0 COI iFIDEN* IaL: *lnh- pet t< i Prot' ictive UrTfeT -if 1 41 h Jud cial Jistri :t cmi N >. 91- TT5-- t , OHC-EDC CONDENSED ORGANIC REACTOR NO. 3 Methyl CMorlcf* X* Vinyl CMorido Ethyl eWorld* Virtylidin* eWorld* 1.1-Dlchtoroethvlen* cl*-1. 2-Dlchtoro*thvl*n* Chloroform EDC Carbontetrachlorid* Trichforoethyfan* Chloral t, t, 2-.TrichloroeEh;mr> Perchloroethyfen* U-Tetraehtoroe than* S-Te 1 rachl oro* than* Pentachloroathan* Unknown* 1974 JAN. AVG. 0.05 0.07 0.40 0.06 0.07 0.06 0.26 0.07 0.22 0.30 0.66 94.58 6.72 6.13 0.37 2.02 0T04 (0.01 0.37 0 0.21 0.32 0.94 93.32 1.21 0.08 0.32 2.51 0.04 (0.01 0.60 0 (0.01 0 FEB. - - - --1 -- -- - -- PPG IWUSTRiES CHEMICAL DIVI5IOM LAKE CHARLES,,LOUISIANA LABORATORY OPERATIONS REPORT MAR. APR. MAY JUNE JULY - 0.05 0.08 0.06 0.08 -- 0.05 0.05 0.03 0.04 -- 0.39 0.31 0.26 0.23 - 0.08 0.10 0.06 0.08 AUG. SEP. OCT. 0.08 0.08 0.33 0.09 0.08 0.04 0.25 0.07 0.05 0.09 0.36 0.04 NOV. 0.08 0.08 0.28 0.05 DEC. 1975 AVG. 0.07 0.10 0.20 0.05 0.07 0.06 0.29 0.07 - r 0.18 0.24 0.26 0724 0714 0.22 "0715 0.32 0.36 0.25 --- 0.26 (5734 0.31 0.30 o-- 0.23 0.24 0.37 0.49 0.32 -- 1.07 1.03 0.59 1.00 0.9/ 0.80 0.36 U. J5 6.36 0.74 - 92.48 92.04 93.68 92.98 92.9T 94.06 95.84 94.99 94.98 93.73 - J..82 1.33 0.54 1.24 1.42 0.79 0.23 0.20 0.12 0.89 - 0.l4~ 0.14 0.17 0.17 0.15 0.15 0.13 0.12 0.13 0.14 - .0.31 0.34 0.18 0.22 0.39 0.26 0.53 0.52 0.43 0.35 - 2.64 2.95 2.68 2.58 2.45 2.30 T3 2.04 2.15 2.39 -- 0.05 0.05 0.09 0.07 0.08 0.06 0.06 0.06 0.09 0.06 - 0.02 0.02 0 0.03 0.03 0.02 (0.01 0.01 6 0.01 - 0.48 0.98 1.07 0.73 0.47 0.68 0.19 0.54 0.54 0.63 - 00 0 0 0 00 0 0 0 - - 00 0.02 0.01 (0.01 (0.01 0 (0.01 (0.01 . * SL 013467 Unleu Otherwie* Indicated C(im F?i r Anri1 if\l of ih jr>r- h ( r, r>. o t e r.11: vu TTi< er ,4 th .1 Nr, 1 Di& t 1" 1 c : t_ Cl A ^ i'JL *i'l ( ourt PAGE 202-29 ppg mms'xnns CHEMICAL DIVISION LAKE CHARLES,LOUISIANA Ltl-X U^IV OHC-EDC DH STILL BOTTOM #1 Methyl Chloride X* Vinyl Chloride Ethyl Chloride___________________________ Vinylidine Chlorida 1974 aver. (0.01 (0.01 0.10 0.04 JAN. FEB. (0.01 (0.01 0.14 0.07 (0.01 (0.01 0.18 0.09 MAR. (0.01 (0.01 0.15 0.06 APR. (0.01 (0.01 0.26 0.07 MAY JUNE (0.01 (0.01 0.14 0.08 (0.01 (0.01 0.18 0.07 JULY -- _ _ 1,1 -Dichtoroethylene clt-1. 2-Diehloroetbvlene Chloroform -EOC Carbontetraehloriri* 0.18 0.24 1.2/ 94.80 0.84 Trichloroethylene 0.13 Chloral 0.13 1,1,2-Trichloroethanf;_________ 1.97 Perchloroethylene 0.03 U-Tetrachloroethan* (0.01 S-Tatrachloroethane 0.31 Pentachloroethan* 0 0.20 0.13 0.23 0.17 1.91 1.80 93.02' 93.11 1.62 n..i s fl-02 2.18 0.09 2.21 0.17 0 1.85 0.02 0.02 0.04 0.37 0.29 0 0' 0 0.16 1.52 94.22 1.36 0.13 0 1.91 0.02 0.02 0. 33 0 0.16 0.22 1.82 92.76 1.53 0.19 .0.02 2.39 0.04 0.02 0.53 0 0.18 0.28 1.59 92.77 1.08 0.18 0 2.67 0.04 (0.01 0.98 n 0.22 0.24 1.47 93.79 0.69 0.16 0.02 2.38 0.07 0.01 0.66 0 - - - - _ - Unknown* 0.03 0.02 (0.01 0 0.02 (0.01. (0.01 - Water Fa PPM 62 PPM 0 47 0 25' 19 00 ~3I------- 42 0O 34 0- AUG. SEP. OCT. NOV. DEC. 1975 avg. _ (0.01 (o.'or (0.01 (0.01 (0.01 (0.01 TOT (0.01 (0.01 (0.01 0.13 0.16 0.14 0.07 0.16 -- 0.05 0.05 0.04 0.04 0.06 - cr.zj 0.24 0.27 0.27 0.19 - 0.20 0.23 0.28 0.31 0.23 - 1.79 2.08 2.06 1.74 1.78 - 94.37 94.82 94.54 94.79 93.82 - 0.66 0.40 0.31 0.34 1.02 0.20 0.15 0.15 0.16 0.16 - 0.10 0 0.04 0.04 0.02 - 1.88 1.60 1.81 1.80 2.05 - 0.06 0.0$ 0.06 0.06 0.05 0.07. (0.01 (0.01 oToI 0.01 " 0.40 0,22 0.33 0.41 0.45 -- 0 0' 0 0 0 - 0 O.'Ol-' 0 (0.01 (0.01 34 31 23 22 31 -- 00 00 0 F bL 013466 *Unleo Otherwise Indicated Cti iMPthf U1*HTi ffltrrlj Sub iect t of 14 th tJlir n Prnl iri j| uistr ; h n. OIj U1 1 *icj i oravs; Coi rfc OHC-EDC DH STILL BOTTOM Methyl Chloride Vinyl Chloride Ethvl Chloride Vinylidine Chloride #2 %* 1974 aver. JAN. FEB. (0.01 (D.ai- fn.m to. or -- n rm 0.04 w. 0.03 "0704 - PPG INW5STRIES chemical DIVISION LAKE CHARLES,LOUISIANA LABORATORY OPERATIONS REPORT MAR. APR. MAY JUNE JULY (0.01 (0.01 0 0 (0.01 (0.01 0 0 0.05 0.04 0.02 0.04 _ 0.06 0.07 0.04 0.06 AUG. SEP. OCT. NOV. DEC. 1975 avg. (0.01 (0.01 (0.01 (n.m 0.07 n n^; 0.07 0.08 0 (0.01 0.01 0.02 (0.01 (0.01 0.05 0.03 (0.01 (0.01 0.03 0.03 (0.01 (0.01 0.04 0.05 1, 1-Dichloroethylene cis-l, 2-Dichloroethylene Chloroform EDC Carbontetrachloride Trichloroethylene Chloral 1.1, 2-Trichloroethane Perchloroethylene U-Tetrachloroethane S-T etrachloroethane Pe n tach 1 o roe th ane Unknown* 0.15 0.25 1.68 94.04 1.11 0.16 0.08 2.07 0.05 0.01 0.38 0 0.13 0.24 1.79 93.60 1.18 0.13 0.02 2.32 0.04 (0.01 0.48 0 - -- - - - (0.01 (0.01 - -- 0.13 0.17 0 0.20 0.19 0.17 0.13 0.21 0.19 0.15 - 0.21 0.29 0.27 0.27 0.24 0.19 0.20 0.27 0.29 0.25 -- 1.96 1.70 1.34 1.19 1.93 1.83 1.85 2.04 1.59 1.72 - 92.31 92.38 93.89 92.79 93.12 94.09 95.22 94.99 95.07 93.75 - .77 T733 0.63 1.25 1756 0.95 0.3? 0.40 0.32 0.95 - 0.19 0.18 0.20 0.21 0753-- 0.21 0.14 0.15 0.16 0.1& - _0 0.02 0.02 0.05 0.05 0.10 0 0.04 0.04 0.03 2.62 2.81 2.49 2.41 5753-- 1.98 1.72 1.80 1.77 2.22 _ 0.04 0.04 0.06 0.06 0707----- 0.05 0.05 0.06 0.06 0.05 0.02 0.01 0.23 0.05 T77CT3----- 0.02 (0.01 (0.01 0.01 0.03 _ 0.57 0.92 0.88 0.65 TJ73B------- 0.41 0.28 0.33 0.41 0.54 _ 00 00 o----------------- 0 0 00 0 - 0.01 (0.01 0 (0.01 0 0 (0.01 (0.01 0.01 to.or Water Fe PPM 57 57 PPM 0 0 - - 21 34 - 00 34 28 00 23 0 33 "54------------ 30 00 0 28 0 31 0 -- sl vl nndKQ u i o4uy 1 1 'Unleu Otherwise Indicated * <| Inly Of ] 4 ** b rr.iMFi >RMT f A 1.1 f- n P mt-pff t vp Or Tnr? i r* i n ! flic; fri rf Omy rd-t- Hn . 91-114 ri PAGE 202-30 ___ ___________LABORATORY OPERATIONS REPORT PPG IimiSTRIES ' CHEMICAL DIVISION LAKE CHARLES,LOUISIANA OHC-EDC LIGHTS STILL BOTTOMS (Productl Methyl Chlorido %* Vinyl Chlorido Ethvl Chlorido Vinylidino Chlorido trans-1, 2 Dichlarocthylens 1, 1-Dichlaroothylcns cis-1, 2-Dichloroothvlone Chloroform EDC Cnrbontctroch lorids Trirhloroothvlcno Chloral 1. 1, 2-' Tri r-hlornpHiano__________ Porchloroolhylono UTctrachloroethane S-Tetrachlcroothane Pentachloroethane 1974 aver. 0 0 (0.01 (0.01 0 0.03 0.03 0.05 98.05 0.26 0.25 0.04 1.54 0.07 0.03 0.3? 0.05" JAN. FEB. 00 00 00 00 o 0 00 0.02 0 0.01 0 79.88 96.34 00 0.06 0.20 0.17 0 16.27 3.00 0.25 0.02 0710-- 0.02 3.38 0.54 00 MAR. 0 0 0 0.02 0 0 0 0.02 7 96.69 0 0.06 (0.01 2.71 0.02 0.02 0.48 0 APR. WAY 00 00 00 00 00 00 0 (0.01 0.0.2 0 95.75 93.27 0,01 0 0.11 0.03 0.01 0.03 3.35 7712 0.04 0.03 0.71 0 0.09 0.02 1.64 0 JUNE JULY AUG. 0 n n 0 0 0 0 (0.01 99.05 0 0.17 0.10 0.79 0.09 0 0 0 0 0 (0.01 0 0 0 0 0.02 95.49 0.04 0.12 0.05 3.29 0.09 0.02 1.33 0 0 0 n (0.01 0 0 0 0.03 98.58 0 0.12 0.12 1.16 0.08 0.01 0.14 0 SEP. OCT. NOV. DEC. 0 0 0 0 0 0 0.02 0.10 98.34 0.16 0.12 0.03 1.38 0.07 0 0 0 0 0 0 0 0 0 0 ~57o7 98.41 ~U---------- 0.11 0 1.37 0.07 0 0 0 0 0 0 0 0 0 0.01 0.07. 99.13 (0.01 0.11 0.07 0.69 0.04 0 0.04 0 0 0 0.01 0.02 0 0.04 0.02 0U3S 98.57 0.02 0.12 0.02 1.01 0.07 0 0.06 0 1975 avq. 0 0 (0.01 (0.01 0 0 (0.01 0.03 95.79 0.01 0.11 0.05 3.34 0.08 0.02 0.69 0 Unknowns (0.01 0.04 0 0 0.01 (0.01 0.01 0.01 0.02 (0.01 (0.01 0.01 0.01 0.01 Water PPM 10 0 0 0 00 00 0 0 50 0 0 5 SL nlTA7fl 'Unlett Otherwise Indicated CUNF ID&NT1 AL: ---------- oi Subjte 14 -1 to Protec tive C rder Judic ial Di strict Court No. 91-11 i5 VINYLIDENE CHLORIDE MONOMER VDCM REACTOR CRUOE Acetylene Monochloroacetylene PPM PPM Oichloroacetytene PPM Vinylidene Chloride Wt.% trans-1,2 DichloroethylenePPM cis*l,2 Dichloroethylene PPM Trichloroethylene 1,2-Dichtoroethane PPM PPM Unknowns (Total) PPM Toluene PPM 1974 AVG. JAN. PPG [N0STf?IES CHEMICAL DIVISION LAKE CHARLES,LOUISIANA LABORATORY OPERATIONS REPORT FEB. MAR. APR. MAY JUNE JULY * .1 AUG. SEP. OCT. NOV. 1975~ DEC. AVG. STORAGE TANK Monochloroacetylene Dichloroacetylene PPM PPM Vinylidene Chloride Wt.% trans-1,2 DichloroethylenePPM cis-t ,2 Dichloroethylene PPM Trichloroethylene PPM 1,2-Dfchloroethane Unknowns (Total) PPM PPM Toluene PPM 29 81 99.79 1872 4 a 2 2. a 30 108 99.95 321 28 5 13 2 2 28 83 99.96 243 9 3 8 % 1 4 98 99.88 763 408 0 2 ~3---------75---------- 62 60 39 99.93 99.93 648 620 42 00 21 22 00 fl (1 2 36 45 43 99.96 99.97 99.90 369 205 911 23 32 00 2 .3 3 3 3 ~n-- "I---------- 00 0 1 64 99.86 983 82 0 5 4 0 3 72 99.81 1409 452 3 0 2 0 20 75 99.64 1626 1662 0 0 2 0 15 41 99.89 966 61 0 0 ... 1 0 9 64 99.89 755 229 1 3 2 0 H,0 Acidity, As HCI Color Peroxide, As H^Os HQMME Phenol Appearance PPM PPM APHA PPM PPM Wt.% 24 3 (5 _Q____ 198 0 CLEAR 17 17 a (1 (5 (5 (1 U 190 187 00 CLEAR CLEAR 14 1 (5 (1 188 0 CLEAR 15 19 a2 (5 (5 a (1 203 184 00 CLEAR CLEAR 17 18 (1 u (5 6 (1 a 188 198 00 CLEAR CLEAR 17 (1 (5 (1 211 0 CT.EAR 21 a (5 (i 198 0 CLEAR 15 (1 (5 a 192 0 CLEAR 19 (1 (5 (1 279 0 CLEAR 21 (1 6 (1 208 0 CLEAR 18 (1 (5 (1 202 0 CLEAR n11A7 1 - 11 ________1 CONI' t L: i ve O :der o SuFJec --tro--i 1'4 tli Judie NO * i ni 0 1 -- 11 O-.riet Cqui t WASTE RECOVERY UNIT Ethyl Chloride Wt. % Vinylidene Chloride t-1,2-Dichloroethvlene 1,1-Dichloroethane c-1,2-Dichloroethvlene Chloroform 1,2-Dichloroethane Carbon Tetrachloride Trichloroethylene 1,1,2-Trichloroethane Perchloroethvlene U-Tetrachloroethane S-Tetrachloroethane Pentachloroethane Hexachloroethane Pentachloro Butadiene Hexachloro Butadiene Unknowns off JAM AVG. 0.26 0.24 0.02 0.01 00 0.14 0.09 0.26 0.18 0.54 0.37 15.19 9.32 0.18 0.13 30.40 0.06 0.14 32.76 11.93 5.74 20.42 10.09 0.51 8.79 8-34 24.68 12.56 0.33 0.65 0.80 2.78 0.43 0.46 1.44 PPG li'T.wmsiES CHEMICAL DIVISION LAKE CHARLES,LOUISIANA LABORATORY OPERATIONS REPORT FEB. MAR. APR. MAY JUNE JULY AUG. 0.14 0.11 0.02 0.01 00 0.08 0.25 0.18 0.28 0.61 1.06 12.85 13.01 0.10 0.18 0.10 0.16 27.55 30.03 14.42 8.85 7_. 56 5.68 19.90 21.89 13.12 11.64 0.50 0.88 0.60 0.58 0.68 0.74 2.27 1.84 0.09 0.05 0i 14 Oi 30 0;47 0.76 6.76 0,37 0.41 24.79 12.19 7.06 26.39 13.57 1.02 0;63 0i83 1.38 0.27 0.29 (0.01 0.01 00 0.07 0.10 0.30 0.46 0.18 0.57 10.02 17.44 0.07 0.14 0.11 0.18 32.10 33.91 9.64 5.14 5.83 4.29 24.91 24.68 10.26 6.84 0.82 0.86 0.85 0.62 0.87 3.61 3.69 3.40 0.23 0.24 0.04 0.03 00 0.53 0.19 1.09 0.58 1.80 0.97 22.90 17.92 0.54 0.46 0.49 0.28 30.06 30.09 6716-- 6.05 3.51 9.36 20.31 17.04 6.36 11.06 0.41 1.00 0.45 0.29 0.51 0.57 4.22 3.26 SEP. OCT. NOV. DEC. 0.45 0.02 0 0.07 0.40 0.33 17.44 0.16 0.06 30.56 5.76 9.87 19.79 12.90 1.60 0.34 0.56 2.26 0.41 0.82 0.87 0.02 (0.01 0.02 000 0.06 0.08 0.16 0.26 0.34 0.63 0.40 0.42 0.79 15.66 0.19 0.08 30.83 14.80 19.45 0.30 0.24 0.02 0.06 31.74 32.54 15.03 8.06 9.87 6.62 7.50 5.56 17.34 21.90 17.97 7.69 7.96 5.73 0.59 0.52 0.33 0.44 0.52 0.64 0.60 0.66 0.82 3.36 3.58 3.72 1975 AVG. 0.35 0.02 0.01 0.17 0.43 0.69 14.80 0.23 0.17 30.58 9.16 6.84 21.40 9.97 0.74 0.53 0.66 2.87 Specific Gravity 1.475 1.488 1.493 1.480 1.524 1.476 1.445 1.418 1.438 1.463 1.470 1.454 1.441 1.466 opiL fUl 11 ToAh7/L __ \ . --(JUN1 > ltUEifrl Subje cx--t- XJ :--14fct! Jud-n pill 1 L* -J2jL=1 AT 1 rdor y f r i r* - Cnur : ____ PAGE 202-33 INCINERATOR J74 JAM WASTE GAS FEED C2H4 HCI EC VDC EDC Perchlor Trichlor Trans Cis Other Wt. % 9.15 15.43 19.94 21.56 n.83 0 1.81 0.90 1.97 2.75 0.16 0 1.26 0.01 1.93 0783 1.30 0152 0.13 0 PPG IHWTHIF.S CMErVCAL DIVISION LAKE CHARLES,LOUISIANA LABORATORY OPERATIONS REPORT FEB. MAR. APR. MAY JUNE JULY -_ --- * _- _ r -_ -- --, - -- - - --- A. -- - - -- - - - -- - - - - - -- --- -- - - -- -"- - - AUG. SEP. --- --- ----- --- No. 1 INCINERATOR HCl in Stack CI2 in Stack PPM 165 - - - - 189 91 44 "15------ 86 PPM 191 - - - 192 93 29 ~5T 68 HCl in Effluent GPL ~T57T~ T274 8.9 "375-- 5.0 4.2 3.6 8.4 10.2 6.5 Stack HCB Aqueous HCB PPM PPM * OCT. - " -- - 27 26 9.2 NOV. "ITT DEC. AVG. - 12.49 13.96 - 12.42 16.99 0;60 0.30 -- 1.44 1.17 - 0.96 1.86 - 0.13 0.06 - 0.79 0.40 - 1.06 0.96 - 0.81 0.66 -_ 0 25 28 64 29 43 66 9.9 11.7 7.9 No. 2 INCINERATOR HCl in Stack CI2 in Stack HCl in Effluent PPM PPM GPL 155 191 18.3 - - 4.8 Stack HCB Aqueous HCB PPM PPM STACK GAS ANALYSES CO NOX Orqanics PPM _CH4_____________________________ HCl Cl c 01347:1 _ -- 5.1 4.9 219 199 4.1 204 96 116 ) 300 28 141 52 104 112 28 3.6 4.9 1578 7.8 ~VT3 25 28 128 28 43 88 9.0 10.5 6.6 CONI `I DENT AL: St 1 h j p r' t to I'rotfi' :tive jrder O : 1 4T! Jiid i 1 i a 1. D .s t r Lc :u t"* u a 1 t No. g 1 _ 1 .<5 AREA "B" DATA TOTAL YIELDS: Theoretical Actual 1974 AVG. JAN. FEB. PPG INDUSTRIES CHEMICAL DIVISION LAKE CHARLES,LOUISIANA a MAR. APR. MAY JUNE JULY Cl 90.7 C 92.0 Cl 83.4 C 89.7 91.6 92.1 89.5 92.2 91.0 92.0 90.4 91.8 92.4 92.8 88.3 92.0 91.1 91.8 .84.6 ,87.7 92.4 92.8 87.9 90.7 92.2 92.8 91.2 94.2 91.8 92.8 86.9 91.9 AUG. SEP. OCT. NOV. 91.0 92.1 91.1 94.4 89.3 91.2 85.4 89.4 89.9 9177".. 87.6 92.6 91.4 92.6 89.6 92.1 DEC. 1975 AVG. 90.1 91.7 R7.6 90.3 91.2 92.2 89.3 92.3 TOTAL CHLORINE TO: AREA "B" T/D 1132.1 1135.2 1009.f 829.5 874.1 918.4 776.2 891.3 873.9 713.3 947.1 1051.S 1056.1 923.1 PURCHASED ETHYLENE TO: AREA "B" T/D % PURITY 432.4 99.92 406.7 99.93 319.1 99.89 290.4 99.94 316.3 378.8 379.5 405.7 364.7 99.89 99.89 99.95 99.93 99.95 330.3 431.9 99.94 99.91 445.9 473.1 378.5 99.86 99.93 99.92 Cl 0 ^3*7* S'- _______ _______ C onftpi NT17TL Su ? ject to Prc tecti' e ord' :r of 1 Ith Ju dicia. Disti TcTO mrt jNo. 9. -1145 11 PAGE 209-1 . GENERAL DEPARTMENT MC Production MC Area Production "Trt-Ethane" Production "Trl-Ethane" Shipments T/D T/D T/O T/D Chlorine Consumed EDC Consumed C2H4 Consumed T/D T/D T/D 1974 AVG. 150.7 155.7 160.1 155.1 F'PG IN .TRIES CHEMICAL DIVISION LAKE CHAflLE5,LOUISIANA "TRI-ETHANE" DEPARTMENT OPERATIONS REPORT si 013475 JAN. FEB. MAR. APR. MAY JUNE JULY AUG. SEP. OCT. NOV. 198.0 202.5 209.3 277.3 217.6 222.1 229.5 145.9 103.4 105.6 111.0 131.8 73.Q 80.5 77.7 81.6 74.8 72.4 75.7 111.9 107.2 106.8 116.9 78.8 103.5 112.6 106.4 183.6 127.9 130.4 136.0 79.3 110.5 113.0 119.8 200.7 177.1 179.4 182.5 148.8 204.2 202.8 213.7 156.8 DEC. 209.5 217.5 227.6 207.7 1975 AVG. 142.2 145.5 150.5 150.4 159.9 180.5 189.6 98.2 87.9 84.6 93.2 93.9 118.2 106.7 192.2 204.0 188.0 136.4 207.8 239.3 260.3 134.3 112.0 115.2 122.3 125.8 144.6 134.9 241.7 264.0 246.8 178.4 YIELDS Ares Prod. + Trans. Credits Basis CI2 C Records Prod. Trans. Credits Basis Cl, TCE TO FER-TRI HCI to HCI Pross. C T/D T/D VDCtoVDCM T/D Tons Cl, /T TCE Tons EOC/T TCE Tons CaH4/T MC Tons N,/T MC Steam (140# Basis) Lbs./T MC Well Water M Gals/T MC Tons Cell Llquor/T MC Catalyst Lbs./T MC (FeCl3) TPPLbs./T MC HQMME Lbs./T VDC AIBN Lbs./TTCE "Tri-Ethane" Invent ry Tons Operating Time % 93.5 90.0 93.0 91.7 94.2 90.5 ----- 1----- 95.5 89.7 93.9 90^6 95.5 89.6 93.2 96.9 90.5 92.5 0 frn K" 1 ----------V tftftptf: VT i At,: b U i. ject ;o I't o fTTcFTv e~UT(tf L th Ju 1 i c L.t 1 ~DTsTT ITTf'CL TTTfe------ jo. yi -1145 98.0 95.0 97.6 95.8 93.3 92.1 90.5 90.1 92.6 88.3 94.6 91.2 91.6 88.1 69.4 29.6 26.0 0.580 (57752 91.7 90.3 68.6 3271 18.1 0.567 0.752 92.9 89.2 64.2 34.6 21.5 0.553 0.759 94.3 88.5 28.8 3m 20.6 0.559 0.764 89.1 85.7 18.4 17.5 27.0 0.618 0.788 97.0 91.2 26.9 19.3 28.7 0.548 0.746 93.5 90.8 20.7 15.9 17.6 0.565 0.741 91.7 96.8 87 .'1 93.7 14.5 17.5 15.9-- 25.8 19."3-- 29.3 0.575 0.585 0.771 0.715 96.3 94.4 22.3 21.0 21.7 0.575 0.727 92.6 89.8 53.8 92.4 90.4 80.0 43.6 43.8 43.9 25.6 0.608 0.582 0.765 0.753 90.3 85.9 51.2 40.3 21.9 0.597 0.784 93.2 89.7 38.9 27.6 24.6 0.578 0.755 0.084 1385 9.5 0.539 3.1 7.1 1.3 0.448 0.063 1239 8.3 0.468 2.3 3.9 - 0.638 0.010 1241 4.6 0.472 2.0 5.5 0.5 0.330 0.041 1240 6.7 0.616 0.6 9.1 0.6 0.477 Oi 036 1149 8*9 0.663 1.5 8.8 0.9 0.469 0.076 1310 10.2 0.642 2.6 18.4 0.9 0.240 0.019 1272 12.3 0.500 0.2 -6.8 0.5 0.292 0.018 1165 10.9 0.502 1.4 7.0 0.9 0.573 0.022 1242 11.1 0.526 1.9 3.7 0.6 0.303 0.018 1238 13.3 0.536 2.0 3.8 0.8 0.611 0.021 0.020 1251 1276 9.8 4.1 0.559 0.481 2.0 1.0 4.8 8.9 0.4 0.6 0.781 0.589 0.011 1220 3.3 0.455 2.1 8.1 0.5 0.912 0.030 1237 8.6 0.535 1.6 6.3 0.7 0.518 1672 94 1969 89 1977 100 3665 79 3537 83 2413 100 3554 1160 100 100 2906 100 473 67 1515 3209 "Too 87 3816 95 2516 92 PAGE 209-2 GENERAL DEPARTMENT MAN HOURS/T MC PRODUCED Production Maintenance Salaried Total Contract Malnt. Included In Above 1974 AVG. PPG .IN STP1ES CHEMICAL DIVISION LAKE CHARLES,LOUISIANA "TRI-ETHANE" DEPART ME NT OPERATIONS REPORT JAN. FEB. MAR. APR. MAY JUNE JULY AUG. SEP. OCT. 0.361 0.432 0.113 0.906 0.065 0.288 0.532 0.084 0.904 0.291 0.270 0.284 0.077 0.631 0.129 0.578 n.finq -O-l 54 1.541 0.213 0.680 0.271 0.218 1.169 0.070 0.755 0.224 1.266 0.000 0.518 0.1 31 0.165 0.814 0.002 0.475 0.124 0.151 0.750 0.000 0.441 0.137 0.125 0.703 0.000 0.489 0.935 0.149 1.573 0.285 0.331 0.035 0.099 0.465 0.033 NOV. DEC. 1975 AVG. 0.288 0.129 0.071 0.488 0.000 0.255 0.447 0.078 0.313 0.075 0.133 0.408 0.893 0.000 0.085 MAN HOURS/T "TRI-ETHANE" SHIPPED Bulk. Drum Salaried 0.036 0.826 0.007 0.029 1.045 0.007 0.066 2.317 0.013 - 0.041 0.034 1.820 1.734 0.0l5~ 0.017 0.045 0.037 1.427 1.093 0.020 0.010 0.063 1.448 0.014 0.035 0.897 0.006 0.039 1.393 0.010 0.037 0.897 0.008 0.040 0.042 0.787 1.349 0.008 0.012 , Z SL 013476 l I A l -- Sub lecL c > prut 2CC Orflr'T <1- CuU of 14 :h Jud N tcial lo. SH" 1 T1 TM C.---  MATERIAL BALANCE CARBON TONS Total Carbon in Feed Carbon in Production ' Carson loss in Process Acct. loss in Still Bottoms Mtsc. Acct. losses Unaccountable Carbon loss in Process Carbon Loading loss Total Carbon loss PPG STKJES CHFMIC AnilYlSION LAKE CM ARIES, LOUISIANA 1974 Avg. JAN . FEB MAR APR MAY JUNE JULY CONFIDENTIAL: Subject ho Protective Orcier `f 1*1 til* Judicial District Court AUG SEP OCT NOV OEC 1975 Avg, 1533.5 1800.7 1769.3 1010.7 817.4 867.3 1384.6 1611.4 1560.0 QFL7 c; -750.0 769.4 890.3 792.5 946.7 869.2 1087.8 1042.4 982.9 R7S _ 3 1819.1 1922.-3 1857.; 1314.3 1565.9 1579.-9 1680 3 1171.9 148.9 189.3 209.3 43.2 2.8 0.0 0.0 0.0 67.3 97.9 0.0 13.i 97.8 0.0 77.5 45.4 0.0 0.0 107.6 253.2 0.0 22.6 * 343.0 177.0 142.4 0.0 0.0 3.0 146.1 189.3 209.3 43.2 27.3 25.2 22.8 12.2 17577" 214.5 232.1 55.4 -67.3 84.8 97.8 40.4 -13.6 -2.4 107.7 84.3 95.4 77.5 45.4 50.4. 14.5 127:9" 59.9 107.6 230.6 343.0 177.0 13.7 12.8 -7.6 44.7 139.4 17.8 121.3 2bfc>. U 335.4 27177" 160.1 CHLORINE - TONS Total Chlorine in Feed Chlorine in Production Chlorine Loss in Process Acct. Loss in Still Bottoms Misc. Acer. Losses VDCLoss from Reaction Plus otncr Unaccountable Losses Chlorine Loading Loss Total Chlorine Loss 93577F 10910.1 10532.( 6028.5 6939.0 7941.2 7664.3 4533.8 , 2448.6 2968.9 2867.7 1494.7 1572 570 3.0 0.0 5045.6 5184.5 3442.( 3677.1 1603.C 1507.4 0.0 59.5 5425.2 3825.9 1599.3 0.0 5706.6 6874.1 4121.5 5040.7 1585.1 1833.4 0.0 3.0 6099.2 11327.3 L1795.4 11309.5 4245.3 7892.: 8497.3| 8427.3 1854.3 3434.9 3298.1 2882.2 0.0 118.2 0.0 Q.O 8019.8 5775.8 2244.0 14.8 . 2438.4 2968.-9 2867.7 1494.7 126.6 111.8 100.9 54.2 2575.2 3080.7 2968.6 1548.9 1603 .C 1447.9 1599.3 1585.1 1833.4 178.S -60.4 -10.4 223.1 54.1 1781.6 L447.0 1588.9 1808.3 L897.5 1854.1 3316.7 3298.1 2882.2 60 ; 7 56.6 -33.6 197.9 1914.8 3491,5 3264.5 3080.1 2229.2 78.6 2322.6 TCE REACTOR SYS1EM Temp. Bo i tom F Press. Top psig EDC AbSORUEH Temp. Chilled hcl uf feto Flo* gpm 208 49.4 25 L2.4 Temp. LIGHTS STILL Bottom VAPOR Feed Flor . SL 013477 F 290 F 203 gpm L06 _ 211 50.4 22 27.3 285 155 113 216 >0.9 24 L2.0 289 198 112 169 49.2 17 L2.0 284 L93 18 142 L88 46.9 46.3 T~-- L5 12.0 LO.O 279 277 188 .86 89 !0 160 45.9 23 10.0 201 48.0 22 10.0 214 48.4 29 2.5 280 283 281 191 193 L92 81 90 31 239 47.9 214 48.6 221 200 50.0 48.0 198 48.4 30 10.0 30 10.0 38 21 23 10.0 1Q.-Q ... -11,9-- - 284 285 287 284 198 196 198 195 283 194 91 110 113 109 98 __C~L_ PAGE 209-4______________ HEAVIES STILL Tim#. ft to Flow .'Bottom To# . 1974 JAN AV6. f 271 F 238 gpm 34.3 279 241 36.5 PPG !1 STRIES ' Cllft/ICAl DIVISION IAKE CtlAmS, IOUIS1ANA "TR I - ETHANE*' DEPARTMENT OPERATIONS REPORT FEB MAR APR MAY JUNE JULY AUG 277 238 37.5 272 239 23.5 272 240 17.1 270 240 15.8. 270 241 ' 17.2 267 239 18.4 260 232 22.6 SEP 262 233 T7TT OCT NOV 264 232 36 *0 269 234 39.4 DEC 275 247 37.0 1975 Avg. 270 238 27.3 VDC REACTOR SYSTEM Flow* (CE fteo gpm C.L. feed gpm 24.0 87.8 Bottom Column Press, Temp, Bottom Vapor psig. F f 22.5 226 m 28.7 29.0 19.3 103.9 107.5 82.6 20.8 222 131 19.8 221 130 20.3 225 133 16.1 56.6 13.8 47.6 16.2 54.6 17.7 238 124 18.8 20.7 159 249 T77----- 128 17.1 57.8 20.9 70.4 29`.6 62.1 28.0 25.2 22.2 22.2 106.1 100.0 101.4 79.2 20.9 246 129 20.7 20.1 2U------ 234 T73------ 126 21.0 ~rn 123 20.9 226 124 20.0 225 131 20.1 234 127 Mil RLACIOH SYSttM flo Temp. vdc Feed HCU Feed VDC Vap. Bottom Bottom gpm SCFM up Top F 18.7 637 136 94 87 23.7 848 153 94 84 21.8 813 148 101 84 12.9 465 137 94 89 10.2 343 131 96 90 8.2 240 133 97 91 11.2 382 133 97 90 11.5 403 135 97 89 13.2 488 131 95 86 16.7 645 131 94 85 20.0 717 133 87 85 24.1 888 132 99 85 21.8 802 135 99 91 16.3 586 136 96 87 flasher SYSTEM Temp. OF ' 185 Dopp Kettle Temn. F 176 STRIPPER SYSTEM Feed Flow Temp. Bottom gpm 29.4 uf 229 190 190- 42.1 234 Top Press. . psig 21.0 21.2 TOPPING STILL SYSItM Top Temp. op 167 L70 189 192 39.7 232 20.5 160 19(1 171 26.3 231 18.1 142 198 173 18.9 227 16.6 j 189 T 88 166 164 186 166 16.2 230 20.6 232 22.5 232 18.2 18.2 20.4 184 169 23.7 220 17.5 183 167 26.2 219 16.5 183 187 172 179 2.> 35.6 ~2l% 223 18.3 16.9 134 133 136 140 135 138 146 157 192 187 188 175 36.5 231 17.6 28.1 228 18.3 158 146 ` MC PRODUCT Flow gpm 18.6 23.5 22.1 8.6 5 i-7 5.0 12.0 13.5 15.6 20.8 23.0 28.3 28.4 17.2 = SL 013478 1 * of CONS'1! JEN 11A ubieci tOP /utec-t 14th .ludici rt--fcrirS --------- 1 HITS U-J-U : (r ve j; i nr rh rter Court 1 1 PAGE 210-1 oii> 3 Vrote^ v^' ^vC^ . to \ ^ \ns: PPG UWJSTRIES ;' CHEMICAL DIVISION SL 013479 HO- LAKE CHARLES, LOU I SIANA PERCHLORETHYLENE -- TRICHLORETHYLENE DEPARTMENT OPERAllum Htrutv. GENERAL DEPARTMENT Records Per Prod. < Shipments Inventory Records Tri Prod. T/D T/D Tons T/D __________ Shipments______ T/D * Inventory Tons Area Per Prod. T/D EDC T/T Cl, T/T 1974 JAN. AVG. 211.1 246.0 217.1 253.2 3510.5 3619.9 254.0 248.7 249.8 234.3 3620.3 4453.1 215.7 253.6 FEB. MAR. 262.1 182.7 127.2 173.3 6842.7 7135.5 265.4 218.9 239.7 219.6 5170.8 5147.5 265.9 i9i.d APR, 215.B 173.2 8413.1 248.1 265.0 4641.4 227.6 MAY JUNE JULY AUG. 164.9 90.0 246.6 202.1 104.9 248.0 129.5 7259.7 6814.0 3146.9 677 6. 8 227.7 137.4 112.8 103.1 103.8 135.6 168.1 118.8 8486.2 8542.7 6831.1 6345.3 163.3 86.2 133.0 246.5 SEP. OCT. NOV. DEC. 1975 AVG. 190.8 144.7 168.6 180.4 185.2_ 179.5 211.1 119.3 294.7 184.7 7114.6 5056.5 6537.8 2996.2 5976.1 102.7 129.3 166.7 202.0 180.2 183.5 126.1 179.2 242.3 184.7 3913 .S 4012.2 3638.1 3212.9 5366.3 203.6 146.1' 172.0 188.4 189.8 0.079 0.057 (T035" 0.000 . 0.000 0.000 0.000 0.083 0.073 0.060 0.076 0.083 0.052 0.043 NH, Lbs./T __Area Tri Prod.___________ T/D EDC T/T _______ S>2____________ T/T 7.8 4.8 7.7 7.3 3.3 9.0 6.9 6.3 6.2 258.2 245.2 240.2 238.5 256.4 228.4 132.6 114.6 108.5 0.050 0.036 0.022 0.000 0.000 0.000 0.000 0.052 0.046 2.7 5.6 4.4 5.6 5.8 103.fi 135.5 170.1 194.0 180.6" 0.037 0.043 0.052 0.033 0.027 NH3 Lbs./T Total Area Prod. O, T/T N, T/T Catalyst Lbs./T 400 # Stm.(actual) Lbs./T KWH/T Total Stillbottoms T/T 7.9 0.170 0.110 3.68 5010 79.2 0.305 4.8 0.186 0.128 3.76 4688 81.8 0.315 7.6 0.180 0.117 4.01 4191 81.6 0.316 7.2 0.177 0.146 3.53 500 2 94.5 0.386 3.5 0.173 0.128 4.7 4230 85.9 0.370 8.5 0.174 0.153 4.0 . 5023 97.9 0.340 6.5 0.187 0.253 1.4 8575 151.6 0.468 6.2 0.174 0.208 9.1 7334 125.9 0.337 6.0 0.153 0.213 2.0 4995 98.8 0.290 2.7 5.0 4.4 0.150 0.172 0.160 0.259 0.331 0.300 2.8 9.1 1.6 5986 '6152'" 5878 118.2 13I~.T 110.4 0.293 0.352 0.352 5.7 0.160 0.220 2.2 5026 92.7 0.302 5.7 0.170 0.205 4.3 5590 105.9 0.343 MAN HRS./T RECORDS PROD. Production Maintenance Salaried Total Contract Man Hrs. Included 0.235 0.404 0.062 0.701 0.015 0.222 0.478 0.060 0.760 0.042 0.210 0.500 0.059 0.769 0.022 0.253 0.642 0.066 0.961 0.030 0.269 0.647 0.064 0.980 0*000 0.327 0.796 0.073 1.196 0.061 0.584 1.029 0.141 1.754 0.130 0.489 1.281 0.120 1.890 0.3^6 0.359 0.702 0.080 1.141 0.164 0.438 0.915 0.096 1.449 0.153 0.438 0.368 0.537 0.884 O.lll 0.074 1.086 1.326 0.290 0.222 0.335 0.958 0.074 1.367 0.196 0.358 0.781 0.085 1.224 0.136 MAN HRS./T SHIPPED Bulk Drum Salaried TCE T/T TER AREA PROD. TCE T/T THI AREA PROD. 0.034 0.801 0.005 0.028 1.299 0.005 0.034 2.866 0.005 - 0.047 1.231 0*009 0.887 0.872 0.853 0.928 0.969 L.120 1.101 L.077 1.171 1.223 0.037 0.077 0.042 1.336 1.248 1.106 0.007 0.012 0.006 0.051 1.399 0.008 0.945 0.829 0.914 0.958 1.192 1.046 1.153 1.209 0.045 0.999 0.008 0.050 0.040 1.104 0.801 0.007 0.006 0.036 0.880 0.005 0.044 1.297 0.007 0.908 0.663 0.632 0.708 0.848 1 . 14fi 0.837 0. 798 0.894 1.071 PAGE 210-2 PPG IM'jTiTJSS chemicaAEC^Vt&lON LAKE CHARLES,LOUISIANA PERCH LOR ETHYLENE - TRICHLORETH *r LENE DEPARTMENT OPERATIONS REPORT 1974 YIELDS AVG. Area Production Basis + Trans. Cl2 86.3 C 87.1 Records Production Basis + Tram Cl2 85.3 c 85.8 JAN. 90.3 87.6 89.8 8772 FEB. 92.6 89.4 94.8 92.7 WAR. APR. 1 92.4 89.2 93.0 89.0 89.1 85.0 90.8 86.4 WAY JUNE JULY 91.1 89.6 91.0 87.3 88.5 93.2 91.3 87.4 91.5 89.9 90.9 91.9 AUG. SEP. 94.7 91.2 92.2 88 n 93.9 90.0 89.8 85.2 OCT. NOV. DEC. 92.9 93.4 91.4 90.5 92.5 89.1 91.4 92.3 92.4 89.5 89.2 . 89.4 JK? 92.1 89.5 91.4 88.7 - SL 013480 ________ 1 , ' row *1 PENT T AL: ---glfrP ) nr**< .rrt--h14*. f r\ Protfi ctive Order rial E istric t Coui t N'"1 . 91-] 145 MATERIAL BALANCE CARBON - IONS Total Carbon in Feld Carbon in Unstab. Product Process Loss by Dittehence PPOW3DU3TRIES CHEMICAL DIVISION LAKE CM ARIES, LOUISIANA PEIICHLORETHYLENE-TRI CHLORETt YLENE DEPARTMENT OPERATIONS REPORT 1974 JAN Avff. FEB MAR APR MAY JUNE JULY AUG SEP OCT NOV DEC 1975 A',"*.. 3622.3 3909.5 3445.8 3494.9 3758.3. 3225.5 1844.1 1814.8 2521`.0 3169.0 3425.1 3080.7 3TIR.3 3344.4 2814.9 1632.9 1fiQ?.T 2299.fi 453.3 484.4 365.1 37fi.fi 41 3 .9 410.6 211.2 122.7 221.5 2208.3 2145.2 2569.6 2864.5 2816.8 1957.1 1961.4 2325.5 2552.3 2517.0 251.1 183.8 244.0 312.2 299.8 Accountable Process Losses Reactor MlSCELLANEOUS Sub Total 433.3 20.0 453.3 464.4 20.0 484.4 345.1 20.0 365.1 356.6 20.0 376.6. 393.9 20.0' 413.9 390.6 191.2 20.0 20.0 410.6 211.2 102.7 20.0 122.7 201.5 20.0 221.5 231.1 20.0 251.1 m 163.8 20.0 183.8 224.0 20.0 244.0 292.2 20.0 312.2 279.8 20.0 299.8 Carbon Loading Loss Total Carbon Losses CHLORINE * TONS ^Total Chlorine in Feed Chlorinc in Unstab. Product Process Loss by Difference Accountable Process Losses ' Reactor MlSCELLANEOUS Sue Total Chlorinc Loading Loss Total Ciiloimne Loss SL 013481 30.9 -19.2 484.2 465.2 +23.8 38.8 47.0 388.9 415.4 460.9 . 37.1 -50.5 59.9 -11.7 447.7 160.7 182.6 209.8 72.6 37.5 30.0 -44.3 . 18.4____ 323,7 221.3 274.0 267.9 318.2 23101.-/ 24392. 21678 JO 21594.0 23468.5 19757.6 10864.1 L2413.E 16841.1 143C5.8 12827.i 15004.; 17002.3 17512.4 199RR.6 22033.2 20075.9 19961.0 21823.1 18008.0 9730.7 0.1294. E 15944.5 13244.1 11921.' 14012.9 15723.( 16147.8 3113.1 2359.3 1602.1 1633.0 L645.4 1749.6 1133.3 1119.0 896.6 .* 1061.7 905^5 991.3 1279.3 1364.6 -- , '3013.2 2259.3 1502.1 100.0 100.0 100.0 3113.2 2359.3 1602.1 , 1533.0 100.0 1633,0 1545.4 J.649.6 100.0 100.0 1645.4 1749.6 1033.3 100.0 1133.3 1019.q 796.6 100.0 100.0 1119.C 396.6 961.7 BOS. 5 100.0 100.0 1061.7 905.5 391.3 100.0 991.3 1179.3 1264.7 100.0 100.0 1279.3 1364.6 162.7 -57.2 +150.0 223.9 228.7 205.6 -272.5 329.2 -66.6 416.5 170.9 L53.1 -176.5 108.8 3275.9 2302.1 1752.1 1856.9 L874.1 1955.2 360.8 Z L448.2 330.0 1478.2 1076.4 L144.4 1102.8" 1473.4 COME X U L* [ a. Ti l * Sub je if t:cr c FTTtr -tJttcH-t -------t+Cr- : -i n 1J 1 -- } `Uric A'. Cou.r t CONFIDENTIAL: ubject to Protective Order 14th Judicial District Court No. 91-1145 FPG I JSTRIES CHEMICAL DIVISION 1AKE CHARLES. lOL'ISIANA SL PERCHLORETHYLENE-TRiCHLQRE"\IYLEME DEPARTMENT OPFfiM ipi'o ,'L 013482 REACTOR NO. 1 Ok Stream Time m * Hrs. 8201 JAN 714 FEB 620 MAR 690 APR 616 MAY 197 JUNE JULY 0. 0 AUG 0 SEP 0 OCT 0 NOV 0 Temp, Vaporizer Liquor Dortherm Out 374 502 357 465 391 -Mi___ 380 450 548 451 374 452 - -- - - - -. - --- - DEC 0 - - Avg. 2837 383 473 Sec. Cord. Disch Catalyst Charged Catalyst From Ctn tr i f i x plo* cm Orqanic SCFH CL2 Lbs* Lbs? 34 136392 136392 20.1 2626 28 6682 6682 16.4 646 34 10618 10618 17.8 770 38 10110 10110 15.2 0 32 20438 20438 18.3 0 32 2800 2800 22.2 0 13449 12760 12830 12086 13650 16630 0 0 0 0 0 - 0 0 0 0 0 - 0 0 0 0 0 -- - 33 0 15000 0 0 65648 0 15000 0 0 65648 0 0 0 0 18.0 0 0 0 0 283 000 0 13591 Per.Tri Ratio Per t Tri in crude 1.12 1.57 1.54 % 82.64 89.0 84,8 REACTOR NO. 2 Cm Stream Time Hrs.* 7855 Temp, Of vaporizer Liquor Dortherm Out 374 556 632 651 371 372 537 - 509 1.04 83.3 1 37 82.1 1.09 86.9 621 63.9 385 372 531 - 486 188 373 495 --- - -f - 686 685 339 364 521 470 628 360 464 - 0 <1 --- - - - - 1.32 - - 85.2 504 647 5841 360 358 365 476 503 499 Sec. Coho. Disch. Catalyst Charged Catalyst from CtNiRirt* Flow GPM SCfH Organic: CL;' lbs.* lbs.* IH " ' 28 130068 17881 130068 17881 16.6. 16.9 2903 1993 26 9393 9393 L6.2 323 27 19210 19210 16.9 0 29 15188 15188 19.3 o 32 1750 1750 18.3 9 1 2 16315 20689 20365 17864 20370 20000 35 40 3529 20786 3529 20786 15.4 17.5 1460 2930 31 3401 3401 r6.4_" 2515" - 0 0 0 0 1683C 18280 18250 0 - 15000 15000 0 0 82 6975 6975 16.1 2010 28 4730 4730 15.0 2200 36 117843 117843 16.8 1393 0 18220 17300 18817 - Per.Tri Ratio Per i trt M crude 1.1Q 1.06 1.30 1.07 r. 83.71 80.4 \ 84.1 80.5 L.23 35.9 < *Tot-a1s 1.35 0.91 1.14 84.1 31.8 2.56 88.3 - -- 1.26 1.40 1.33 -- 86.1 88.9 84.9 PAGE 210-5 CONFIDENTIAL: Subject to Protective ur tier District Court 14Of ttl .Judicia^ 1145 PPG US TRIES ' CKC.MCAl DIVISION WIAK.Et uCIiI/AwRlnfS,, itOuywiSImANmA SL N* 'PTRCnrofTETHYLENt.TRICItLORE IHYLENE DEPARTMENT OPERA t 1 013483 REACTOR NO. 3 Os Sl<t*u lint 7(U.F Vk*ORII(* tiouon Out 1974 JAN AVG. Hrs.* 8037 695 FEB 593 MAR 616 335 353 355 531 441 527 520 APR 651 360 482 MAY 627 374 463 JUNE 241 344 491 JULY 0 - AUG 9.6 353 459 SEP OCT NOV 640 576 629 347 "315------ 332 446 "358------ 524 DEC 709 354 546 1975 AVG. 6073 349 482 Stc. Coho, Disch. Catalyst CmaacCD [catalyst ro CfsrmfiK -1--*..^.... Qtaanicl SCFH Ctj 30 LOS, * 1160.68 lbs. * 11 finfiR 15.2 2646 21 7207 7207 11.8 1624 30 13418 13418 9:6 967 31 14310 14310 12.2 0 33 i588 9RRR 13.3 Oi 36 16604 16604 15.4 0 ot 16000 17678 15990 16536 19800 22800 *, 47 1085 1085 13.7 0 - 0 0 0 0 18090 0 27 10401 10401 9.8 0 37* 5250 5250 10.0 2970 42 12483 12483 9.9 2970 22 2075 2075 10.3 2090 27 9980 11.0 2210 32 1Q24Q1 in?jni 10.6 1069 15870 15030 15040 17500 18400 16061 . PtB-Ti Ratio P(R Tm IN CftUOt 1.08 % 85.5 REACTOR NO. 4 !0n Sm*u Tim Host 8268__ TtMP. OF Vapoai rc* Li ouon 1 DoTnrmi Out 354 531 1.06 1.31 83.0 88.1 672 629 320 374 439 . - 1.16 84.9 686 379 " 0.94 0.78 83.0 84.7 t 592 671 369 375 526 501 0.70 81.0 - 319 324 567 661 359 485 1.38 82.3 2.19 88.9 1.62 1.08 '87" 7 " 81.1 1.15 83.3 1.22 84.4 724 720 707 550 622____ IS22_ 358 376 355 351 358 358 447 450' T77------ 480 486 486 Stc. Como. Oisch. 51 Catalyst Chaagid Los.* 116068 Catalyst pom Cihtaitm . lbs.* 116068 Flob ctm SCrH Oraanic Cl 1 17.4 2400 21 *7^94 7994 20.6 1138 22 15168 15168 19.4 518 28 16760 16760 19.4 0 1 26 30 X02J38.. L3104 10988 L3104 19.8 L9.3 (3 0 42 2232 2232 13.6 3190 43 2132Q 21320 14.0 2210 27 4102 4102 13.1 2730 22 9800 9800 14.0 2240 33-------- 19______ 26 21i>fcJ3 4875 6480 21583 4875 6480 12.6 12.6 12.0 2560 2050 2140 28 134406 134406 15.9 1565 Or 15700 19208 19658 18324 18790 20950 14260 16100 17870 20860 18130 19120 20600 18656 '1 .l 't*Tl RATIO [jlN t TUI IN CAUOC 1.16 '0.79 1.15 . % 33.19 1181.6 85.4 *Total9 Lt 08 32.8 1.05 t>.93 34.2 0.82 1 - 4ft fcl.7 $5.1 0 Qe; 1.98 .82..7.. 90.8 1.70 1.18 89.5 85.8 1.19 86.9 1.36 85.3 t t c t Ij .CMCMlC/^Pr/l5IOtl IAKE CJtMdrr., tOUljlAf 1A PAGE 210-6PEBCIjLOnETMYLEflE-TRICilLOrtEllIYLENE DEPARTMENT OPERATIONS REPORT REACTOR NO. 5 a!74 JAN FED MAR APR MAY JUNE JULY AUG SEP OCT NOV OEC I Avf7'i ON STREAM TIME * HRS. . tcmp. r VAPomiER uquon OOWTHERM OUT 8220 333 517 608 378 488 669 "355 465 36ft 471 626 378 457 685 378 470 465 529 370 366 440 491 744 630 368 346 453 495 700 358 464 681 351 470 563 7530 348 366 513 AH__ SEC. COND. OISCH* CATALYST CHARGED catalyst FROM CENTRIFIX float cpm oraanic CFH CU * * LOS. * LOS. 49 * 45 120269 18406 120269 18406 17.4 20.8 266 J T233 8343 8343 20.4 980 47 26560 26560 24.2 0 i 4fe 11338 ll 338 21.1 6 58 14854 14854 21.1 0 58 2129 2129 21.2 0 59 28070 28070 18.5 2990 . 55 4452 4452 18.1 3220 48 10500 10500 16.5 3070 44 34 15284 2075 1^284 2075 23.2 20.9 3010 2630 30 4387 4387 18.0 2180 47 146398 146398 20.3 1614 Oa 13B50 18513 19140 17116 16930 20770 17470 17560 18430 16420 19890 18030 16300 18047 Por-Tri Ratio Per + Tri in Crurle 1.14 85.5 0.66 77.1 1.55 0.90 84.9 80.1 1.31 83.5 0.84 82.0 0.56 1.63 77.0 81.1 2.95 84.9 3.24 85.8 1.33 1.21 82.7 84.3 1.08. 84.6 1.44 82.3 * * i * ___ _ . _ . -- --1---------------- ^ SL 013484 1___________ __ Totals ` 4 . . r*n u'Ap -TL r\r'(Mi p x Jf Mft-TJj* l i; ,,S-Ub }F*rfr ft 1 r P* I. tL/ c sup. x ye rtf or of-ill pj cri -Cou L L __________ N< 1 t -- H& -- .-- -- -- -- of PAGE 210-7 CONFIDENTIAL: ubject t'o Protective Order 14th Judicial District Court Ho. 91-1145 PERCH LORET11Y LEME - rt'G i) si files chimicai revision IAKC CHARltS, lOlll MAMA TRICllLORETIlYEENE DEPARTMENT OPERATIONS SL REPORT 013485 REFRIGERATED BRINE Temp. F #1 Warm (in) #1 Cold (out)____ 1974 AVG. JAN #2 Warm (in) 5 -1 #2 Cold (out) -2 -5 F E0 MAR APR 02 -5 -2 1 -4 MAY JUNE JULY (-1 2 -5 -3 3 (0 AUG SEP OCT NOV r-3 -6 --------- 0 13--------- -4 4 -6 OEC -3 -5 1975 AVG___ (-1. -4 PER STILL #1 Feed Reflux Recycle Pot Temp Overhead Temp GPM GPH GPM oF Op 8.2 13.6 0.5 287 249 8.7 14.4 0.5 "279 241 10.0 13.7 0.6 ~Z7S 2jy 8.0 14.0 0.5 279 242"; PER STILL #2 Feed Reflux Recycle Pot Temp Overhead Temp TRI STILL #1 Feed Reflux Recycle Bottoms Pot Temp Overhead Temp TRI STILL #2 Feed 1 Reflux Recycle .Bottoms iPot Temo lr Ove rh e acUTemcL ! DH STILL #1 Temo. F 1 Pot Overhead i?ot Pressure GPM GPM GPM Op Op GPM GPM GPM GPM Op Op GPM GPM GPM GFM op of PSIG 18.7 19.0 4.1 294 253 15.8 58.0 3.5 15.1 229 166 26.3 92.3 5.7 20.7 235 158 183 146 1.64 20.4 17.6 4.6 291 251 20.5 17.9 4.9 293 248 15.6 53.8 2.5 15.1 226 164 14.1 58.9 1.2 14.9 231 158 27.4 93.0 4.5 21.3 233 160 24.9 93.. 2 4.3 18.1 233 159 185 188 155 158 U40____ 1 -50 15.8 17.2 3.5 293 249 12.0 53.8 1.1 14.4 226 144 21.5 93.3 3.4 16.4 234 151 L83 155 L^51, k.o It t 0.6 279 247 10.1 14.2 0.6 281 T33 * 18.5 17.0 4.7 293 251 15.9 19.0 3.0 282 248 5.8 15.2 0.3 280 241 7.4 15.0 0.6 280 239 13.2 20.8 2.5 272 247 20.5 24.1 4.7 275 245 5.7 14.1 0.04 225 6.1 12.5 0.0 277 240 18.3 28.8 0.4 276 245 18.7 25.5 0.2 275 246 5.4 12.1 0.0 272 230 -- - 23.5 29.3 3.1 277 247 22.2 28.8 2.3 278 250 7.8 15.6 1.2 287 245 7.6 14.0 0.5 279 239 21.2 27.1 2.0 276 249 19.1 22.8 3.0 281 248 13.7 49.8 2;3 15.1 226 148 13.3 53.6 1.8 15.8 228 155 9.3 46.7 1.4 13.6 227 148 _ - - ------ - - 7.0 9.5 11.8 - 52.9 58.5 53.5 1.3 1.7 1.7 11.1 13.2 14.2 228 230 228 -- 154 149 152 23.4 92; 8 3.8 19.9 237 149 21.4 88.8 3.1 19.8 233 143 21.5 96.9 2.6 20.6 234 145 21.8 101.9 2.4 20.4 234 151 19.6 101.2 1.9 19.1 234 163 21.5 102.4 1.0 20.6 235 156 21.9 102.2 2.6 20.6 236 148 21.0 103.4 3.5 18.6 238 146 19.7 100.9 3.3 18.3 236 143 22.1 97.5 3.0 19.5 235 151 182 182 154 165 1-43.- 179 146 185 151 .1,44, 1.25, . 185 162 1.17 - - - 191 201 186 - 134 134 151 - 1.50 1.54 1.42 \ PAGE 210-8 -Continued DH STILL #2 Temp. F. Pot ______________ _______________Overhead_________ Pot Pressure pstg 1974 AVG. 202 140 1.61 JAN 206 136 1.32 FED 208 136 1.42 PER-TRI STILL Feed GPM Reflux rpm Pat. .'Tamp*__________________ Qf Overhead TemD. F 75.8 63.6 293 192 77.2 67.4 292 192 78.7 60.6 ^290 190 --- -- - *-- _ MAR 202 132 1.41 62.0 54.6 284 187 rPG fi SIKieS chu'icai nivision iakc citAKics, louisiANA .JLLLUL_ APR MAY JUNE ' CONFIDENTIAL: ` Subject to* Protect i ve Order _ * of 14th Judicial District Court jIMT '.l/U.LUUL JULY AUG SEP OCT NOV DEC 1975 AVG. 201 131 1.35 197 1 33 1 .31 196 138 1 .35 221 1 52 n .74 225 157 0.82 220 15.3 1.24 212 141 1.28 208 134 1.27 210 134 1.30 209 140 1.23 71.3 60.5289 188 st 61.4 63.6 284 187 46.3 46.1 282 187 55.9 48.8 280 186 54.2 53.0 278 189 49.9 51.0 274 189 52.9 51.5 186 51.4 50.4 290 186 61.2 52.8 295 186 60.2 55.0 285 188' HEAVIES STILL Feed Reflux Temp F Top Pot- GPU GPM 33.4 318.6 259 314 NEUTRALIZATION & DRYING #1 PER NHi Product to Sta. PSTG 3.6 gpm 9.8 ______________ 82 PER________________ nh3 PSIG 5.2 Product to Sta. gpm 25.8 32.4 318.0 258 314 35.1 314.7 258 311 2.9 1.28 3.0 18.9 2.6 27.4 3.7 27.4 27.6 277.0 257 320 2.3 10.4 2.9 20.9 31.9 288.7 258 309 26.3 283.8 256 312 2*9 2.9 13.4 18.1 3*7 4.9 25.2 23.9 19.6 27.0 262.8 297.6 254 256 312 1.8 2.6 23.5 12.6 4.3 4.3 20.2 25.4 23.4 251.1 255 307 25.7 241.1 255 306 1.7 6.3 4.0 4.4 25.0 28.1 -TRIn3 Product to Stq. PSIG 2.4 GPM 29.6 2.4 29.3 2.4 23.6 2.3 17.9 2.3 27.7 2 .-4 24.7 -- 2.6 3.0 20.0 21.0 2.6 17.0 2.5 14.7 *, 29.4 250.7 252 295 22.5 245.9 254 311 28.1 238. n 253 297 27.4 272.5 256 309 ---- 2.5 3.3 32.9 26.5 4.2 43.4 4.0 26.2 2.7 17.7 3.7 25.8 2.4 2.6 16.4 15.1 2.3 15.2 2.5 20.2 SL 013486 GENERAL DEPARTMENT 62B - WET HC1 Wet HC1 Produced T/D 1974 AVG. 26.6 PPG IK TRIES CHl-MICAl DIVISION JAKE Ct'AKirS, IOUI5IANA HYDROGEN CHLORIDE DEPARTMENT OPERATIONS REPORT JAN FES WAR APR WAY JUNE JULY AUG 25.9 26.3 31.1 28.0 35.1 32.0 31.6 65.1 Uo Steam (Actual) Well Water HtSOj KWH/Ton T/T M lbs./T M Gals/T lbs./T 0.592 646 1.0 82.3 0.374 662 0.0 11.7 0.238 - 0.0 12.5 0.259 0.0 11.0 n ti n 0.0 ii.2 0.230 0.0 11.8 0.520 0.460 -- 0.0 0.0 11.3 11.4 0.051 - 0.0 11.0 MCI (as Muriatic Acid) Captive Use Shipped T/D 40.5 T/D 0.0 25.7 29.0 30.5 29.3 i 34.3 32.5 34.7 52.9 ACID Strong Weak Wt. % 31.34 31.12 31.33 30.37 Wt. % * 32.67 ,31.50 30.13 31.87 31.83 SEP OCT NOV DEC 1975 AVG. 29.1 26.5 34.3 32.7 J3.1 0.142 0.159 0.166 0.161 0.256 - - 662 0.0 0.0 11.2 11.7 0.0 0.0 11.5 11.8 0.0 11.5 30.1 31.0 32.7 35.1 33.2 29.93 30.60 - 30.78 31.10 OPERATING HOURS*___________ CQBEBBSSOBS #1________________ #2 ________________________ 113_________________ ________________________ M_________________________ ________________ 15 #6 12 #8 5421 6134 4518 506 1460 541 7509 423 666 327 652 673 STRIPPERS #1_________________ 555 0 0. 638 672 672 672 519 636 108 633 744 -- SL 013487 Totals , 595 588 7. 667 704 -J 689 715 39 734 735 637 744 108 175 665 566 720 743 60 525 660 227 734 732 74 744 96 648 435 744 603 344 210 392 504 744 0 672 720 72 284 744 684 584 416 160 674 744 684 580 0 136 ---------------fcri iiDini? ITT AT. -------Strt jeefc--1 "0--rtV o OrrlP r ot Is t t"l wUC -L -L. CJ A fli cTr i rt Cc urt f O ! -114 5 6548 6473 3636 8231 2617 5991 55 5 PAGE 211-2 PPG INuWTRIES CHEMICAL DIVISION LAKE CIIMtlES, LOUISIANA HYDROGEN CHLORIDE DD'ARIMENI OPERATIONS REPORT GENERAL DEPARTMENT 62D WETi HCL REER1GERATION UNIT Pressure PSIG Sue non D1SCMARGC SFAL TEMPERATURES Of Brine In Brine Our A urs 49?4 JAN FEB MAR APR MAY JUNE JULY AUG -21.4 8.8 30.1 -23.3 7.4 30.0 -24.5 -23.9 7.5 7.1 30.0 30.0 -24.0 6.1 30.0 -23.6 7.8 30.0 -23.1 9.7 30.0 -23.6 -23.3 9.2 10.8 30.0 30.0 28 36 14 16 15 IT-------- 21 10-------- 21 25 30 2 5 8 1----------- 15 I---------- 8 146 144 153 138 134 I5o 150 149 160 NO- t STRIPPER Flo*s SlRONG ACIO FEEO pry Srr m Lns/HR TtwrrnA JURE S Of Top Gas from Cooler 39.4 7425 227 40 SEP OCT NOV OEC av197! -23.6 8.7 30.0 -24.0 -24.1 7.9 4.9 29.0 30.0 -24.6 3.8 30.0 -23.8 7.6 30.0 18 20 15 20 145 149 22 18 21 17 147 133 19 13 145 NO- 2 STRIPPER fllS StR'jnr. Acin Feed Steam TEVPtRATUBES Top GPM Los /HR Of Gas from Cooler SL 013488 COfTF.1 DEN 11/ tij; O iubjec t TO I I'4 th J Uv4 L c j --ttov l u Lee1 . 1 VC U J 1 1j 1. A s t ri-ct JP^ir\ --1t-7e i C. . U 1-- I 11 r-t- \ma Hnmrs/TON hcl PlinoucrioN Mt tNTENAMCE 0.863 0.294 Salaried 0.283 TO TAL 1.440 0.000Contract Maint. IncHioeo in Aiiove 0.356 0.328 0.132 0.816 0.000 0.393 0.290 0.130 0.813 0.000 0.306 0.288 0.105 0.699 0.000 0;358 1% 469 0 * 125 1.952 1.197 0.269 0.484 0.092 0.846 0.000 Q .289 1 .41ft 0.110 1.815 0.000 0.323 0.544 0.108 0.975 0.000 0.152 0.354 0.050 0.556 0.000 0.323 0.563 0.115 1.001 0.000 0.394 0.455 0.134 0.983 0.000 0.298 0.279 0.312 0.674 0.641 0.625 0.084 0.099 0.107 1.056| '1.019 1.044 0.000 0.000 0.100 !------------ CONFIDENTIAL: Subject to Protective Order ^ PPG ll^fsiRIES of 14th Judicial District Court oumical division No. 91-1145 TAKE CHARIES, lOlll.MANA PAGE 212-1 ETHYL CHLORIDE DEPARTMENT OPERATIONS REPORT SL 013489 GENERAL DEPARTMENT Ethyl Chloride Production EC Arc* Production EC SHIPMENTS T^O T/D T/D 1974 JAN Avg 154.3 153.9 152.8 124.4 124.9 146.2 FES 135.9 135.3 127.3 MAR 11&aQ 116.4 118.5 APR 130.0 132.0 156.3 MAY JUNE 156.7 158.0 156.4 157.7 143.2 145.7 JULY lfin d 160.3 iGn ft AUG SEP OCT 153.1 152.2 175.4 134.8 162.4 134.2 163.1 145.3 152.3 NOV 164.6 164.0 171.9 OEC 163.1 164.0 173.6 JW5 146.6 146.7 150.0 HCL TO EC T/D 96.4 78.1 81.8 73.0 82.5 97.7 96.9 101.6 91.5 81.7 100.2 101.2 101.3 90.6 ECEthylene to Puri tv hcl EfricicNCr ' %V 71.4 57.4 61.6 51.9 61.2 73.7 75.0 99.92 99.93 99. R9 99.94 99.89 99.89 99.95 74". 4 99.93 68.2 60.7 75,6 99.95 99.94 99.91 74.7 99.86 76.2 67.6 99.93 99.92 % 90.7 91.2 94.1 90.7 91.0 91.2 92.5 89.8 95.3 93.5 92.5 92.8 92.9 92.3 CARPON Efficiency * 94.1 95.3 96.0 98.0 93.3 92.8 91.8 94.0 98.2 96.6 94.2 96.3 94.6 95.1 HCExcess l Excess HCl T/D 3.5 * 4.3 3.5 4.7 1.8 2.2 5.6 in 2.23 2.78 2.00 2.09 -0.58 4.79 -0.60 4.95 2.92 3.30 2.74 3.48 1.92 1.95 4.08 4.21 2.31 2.33 2.78 2.85 EC ECHCl to Tons/Ton Pnoo CjH,) to EC ECTons/Ton Nj to EC ECTons/Ton 3.626 3.464 3.064 0.625 0.459 0.106 0.604 0.454 0.053 0.627 tJL2L5_ 0.624 0.614 0.445 0.467 0.470 0.475 0.089 0.084 0.063 . 0.092 0.633 0.464 0.081 0.597 0.445 0.003 0.608 0.614 0.452 0.463 0.005 0.002 0.617 0.455 0.002 0.617 0.464 0.000 0.617 0.459 0.048 Tf Cl 3 Lns/Tow EC 'Steam Lds/ton EC Wf ll * TTR M ECGals/ Ton KV.i/ton EC 9.2 1311 1-696 36.2 8.8 1859 2.143 129.3 6.7 1818 1.979 127.3 8.5 2038 2.300 133.5 9.5 1716 1.842 115.9 7.4 8.4 1743 1772 1.299 1.289 lOSm 106.1 9.0 1.348 106.9 13.3 1756 1.495 110.9 16.6 1880 -- 111.9 10.2 1768 - 105.1 10.9 1734 - 103.4 8.4 1692 100.1 9.8 1792 1.712 113.0 MAN HOURS/TON EC PRonircTtriN 0.240 Ma intfhanc.e 0-215 Salaried Total . Contract Maine. Q.08R 0.543. 0.002Included in Arovf. 0.225 0.229 0.104 0.558 0.025 0.230 0.206 0.097 0.533 0.078 0.252 0.144 0.107 0.503 0.013 0.243 0.380 0.102 0.725 0.018 0.189 0.110 0.080 0.379 0.002 0.189 0.148 0.086 0.423 0.002 9.182 9.104 9.081 9.367 9.000 0.199 0.128 0.081 0.408 0.000 0.230 0.192 0.096 0.518 0.000 0.215 0.111 0.084 0.410 0.000 0,180 0.160 0.067 0.407 0.000 0.108 0.076 0.363 0.000 0.168 0.088 0.465 0.012 'an Hours/T IsC Shipped Bulk | Salaried 3.031 0.025 0.034 3.003 0.002 0.004 0.050 0.033 0.038 9.035 0.028 0.032 0.034 0.024 0.028 0.033 0.006 0.005 0.005 MSI. 0.003 0.004 0.004 2,*223.., 0.003 0.004 Page CONFIDENTIAL: Subject to Trotect i.v e Order rPG II STRIES 03 14th Judicial Distr let Court : CI!lO!'/J. DIVISION LAKE Cl ASUS, LOUISIANA 212-2 t?o. 91-114 5 ETHYL CHLORIDE DEF'AimtN T -OPERAT I ONS REPORT MATERIAL BALANCE 1974 Avg CHLORINE-- TONS Total Chlorine in Feed 2862.0 Cmloiuhe ih Production + Trans 2594.5 JAN FEB MAR APR MAY JUNE JULY 2353.8 2227.5 2201.4 2407.6 2946.2 2H27.T 3061.3 2147.9 2096.7 1997.3 ,2121*3 2686.4 2615.2 2747.R AUG SEP 2758.7 2382.4 262R.1 2228.7 OCT NOV OEC .1975 Avg 3021.f 2952.5 3054.7 2682.9 2?96.J 2740.7 2838.4 2476.2 Chlorine Loss in Process Bloadohn From heavies Still 267.5 14.1 205.9 130.8 204.1 216.3 259.8 212.1 313.5 19.8 14.2 14.4 14.5 21.3 15.7 17.2 130.6 153.7 19.4 16.1 225.4 211.8 216.3 206.7 16.9 37.0 44.7 20.9 * Chlorine Loading Loss Total Chlorine Loss '- J.3 270.8 8.5 -9.3 6.1 32.9 -5.2 214.4 121.5 210.2 249.2 254.6 -5.1 -2.2 207.1 311.3 16.2 ^6 ~ 11.9 -9.6 15.2 +4.2 146.8 144.1 237.3 202.2 231.5 210.9 CARBON -- TONS Total Carbon in Feed Crboh in Production + Trans. 1868.0 1523.3 1476.0 1377.3 1587.2 1955.3 1927.3 1976.3 1809.4 1559.9 1755.1 1451.1 1417.6 1350.2 1481.6 1815.6 176R.6 1858.1 1776.5 1506.6 2008.C 1919.7 2022.6 17C3..3 1890. S( 1849.C 1913.6 1673.3 Cardoh loss in process oloaooan From heavies Still .- 112.9 72.2 6.5 9.1 58.4 6.6 27.1 6.7 105.5 139.7 158.7 L18.2 32.9 6.7 9.9 7.3 7.9 9.0 53.3 7.5 117.1 70.7 109.0 88.6 7.8 17.1 20.6 9.7 l C "bin Loading Loss Total carroii Loss 2.0 5.8 114.9 78.0 -6.3 52.1 4.1 22.3 -3.5 -3.4 -1.5 11.0 31.2 127.8 136.2 155.3 L16.7 43.9 i-6.5 46.8 8.1 --6.6 10.3 +2.8 125.2 64.1 119.3 91.4 c, SL Q13490 u' i ' ......... 1 1 1 * PPG HTTOSIRIES Cl It i.MC Al DIVISION LAKE CMAIUCS, LOUISIANA ETHYL CHLORIDE DEPAR1MEN1 OPERATIONS REPORT REACTOR PRESSURE TEMPERATURE PSIG Op FLASHER Temperature Op Bottom Top PRIMARY STRIPPER Pressure psig Temp ERA TUBE Op Top 0OT TQM w JAN 111 95 127 123 FEB 88 121 158 164 162 135 135 136 84 82 82 111 108 110 148 147 149 MAR 94 123 163 135 83 107 150 APR 108 129 160 132 i 84 107 150 MAY 110 122 156 135 83 111 149 JUNE JULY 120 125 129 132 155 157 132 135 84 85 112 TCT 149 155 AUG 128 139 157 135 84 115 148 SEP 130 130 160 135 85 111 149 HEAVIES STILL to.Ff Rate GrM Rfelu* gpm Sttaw (actual) Lss/hb Temperature Top Op Bottom 41.6 19.6 3856 34.1 20.2 3703 35.3 21.1 3557 146 146 149 185 182 192 33.5 20.9 3525 36.9 20.0 3803 151 1.49 195 200 38.6 20.0 3586 149 192 39.5 20.3 3675 37.9 20.0 3556 147 148 194 195 38.2 20.9 3490 36.8 20.9 3631 148 148 192 187 SECONDARY STRIPPER PRESSURE psig Temperature of Top Bottom 73 152 153 73 139 151 73 150 150 73 74 150 151 150 152 74 74 74 150 150 150 150 150 74 74 150 150 150 150 OCT 126 135 NOV 120 129 157 159 136 133 85 85 114 111 148 149 39.0 18.0 3858 39.2 15.7 3497 149 143 166 164 74 74 150 151 T35----- 151 DEC 120 130 159 132 82 108 149 39.4 14.0 3672 140 154 72 149 150 1975 Avg 114 128 159 134 84 111 149 37.4 19.3 3629 147 184 74 149 150 - n(TAnl - -- Sub 3 yt--rrv L. r*nK PtnEN'i IAL: Prote ctive Order TueH rti Pi 1 I listri :t Cou Ft . 91 -J 145 PAGE 213-1 GENERAL DEPARTMENT VC Records Production VC Area Production VC Shipments T/O T/0 T/D 1974 AVG. 388.8 389.5 392.9 PPG IK TRIPS ghemicaUpi VISION LAKE CHARLES,LOUISIANA VINYL CHLORIDE DEPARTMENT OPERATIONS REPORT JAM FEB. WAR. APR. WAY JUNE JULY 294.4 143.8 297.2 146.2 134.4 147.5 189.6 226.2 189.1 226.5 272.3 253.6 336.5 337.3 279.3 4R1 .A 488.7 345.0 443.6 447.1 197.5 AUG. SEP. 473.3 472.0 372.7 466.9 473.0 198.1 OCT. NOV. DEC. 559.0 484.8 560.2 485.8 303.8 355.2 593.8 594.9 259.6 1975 AVG. 391.1 393.2 260.0 ___________ YIELDS________________ Area Prod. + Trans. Credits Basis Cl2 C Pe cords Prod. + Trans. Credits 99.0 98.5 Basts Cl3 98.6 C 97.9 HCI By-Prorluct Prod. HCI By-Prod. Utilized HC! By-Prod. Utilization T/D 227.4 T/D 223.2 % 98.3 Heavies Still Cottoms Prod. T/D 12.0 Dopp Kettle Waste Lbs./T VC 7.1 EDC Consumption EDC Consumption Cl2 Consumption T/D 636.7 T/T VC 1.64 Lbs./T VC 5.32 St-jaiTi Consumption Gas Consumption Weil Water Used Nitrogen Used Povmr Consumption Lbs./T MCE/T M Gals./T Lbs./T KWH/T 3778 5.12 1.96 88.1 71.1 98.9 99.6 98.7 99.0 98.5 99.4 98.4 [99.2 98.5 98.8 97.8 97.4 173.4 85.2 169.8 85.1 98.0 99.9 98.7 99.4 98.7 99.1 110.2 132.0 109.5 130.8 99.4 99.1 5.0 7.1 5.3 7.5 2.5 4.8 9.5 3.2 481.2 240.1 1.63 1.64 2.28 2.00 306.4 365.8 1.62 L. 62 0.36 D.35 5206 6.31 2.05 5.9 80.1 9320 8.35 3.62 173.5 177.4 7699 5.48 2.51 109.2 147.4 5792 4.47 2.31 113.3 151.1 98.9 99.1 99.3 98.7 98.7 99.1 98.0 97.8 96.8 96.5 98.9 97.6 98.5 97.3 99.0 98.8 98.7 98.4 98.8 98.4 98.9 98.5 97.3 98.3 98.1 98.0 96.2 95.3 ~55T8~ 97.5 98.3 97.1 98.9 98.6 98.4 97.9 196.6 196.6 100.0 1 284.9 280.7 98.5 5.7 16.5 6.5 5.4 260.6 260.6 100.0 , 7.8 7.0 275.1 276.5 100.5 275.7 286.1 103.8 9.2 7.6 13.0 5.9 326.5 283.1 326.2 283.1 100.0 346.8 346.6 99.9 229.2 229.3 99.9 16.5 13.4 7.2 5.3 9.4 4.7 9.2 6.7 546.1 786.4 1.62 1.63 2.47 3.65 721.2 772.8 1.6l 1.64 4.06' " 4.52 787.6 1.67 4.44 915.0 802.9 1.65 3.06 961.6 1.62 4.13 640.6 1.63 2.90 3634 3.25 1.48 33.1 107.6 2984 ' 2.72 1.08 25.8 65.7 3398 2.82 1.13 38.8 79.4 3093 2.56 1.24 14.2 74.7 3190 2.40 1.41 14.9 69.8 2714 2.17 1.04 3.0 63.5 3233 2.18 1.54 7.8 71.2 2556 1.86 1.01 6.2 54.3 4402 3.71 1.70 53.0 95.2 1 - SL 013492 rowf 1UKH1 - t 1 t 5u>) )& O r 1 At It E t (J Rcotei .lud U ial K ~'T'r Hu. ~TTT- r . PAGE 213-2 PPG IN.MTRIPS CH!TWiCALl5iVI3!OM LAKE CiIAELE 5, LOUISIANA VINYL CHLORIDE DEPARTMENT OPERATIONS REPORT GENERAL DEPARTMENT MAN HOURS/TON VC PROD. 974 AVG. Production 0.192 Maintenance 0.210 Salaried 0.049 Total 0.451 Contract ".an Hours include lt>.007 MAN HOURS/T VC SHIPPED euik Salaried 0.026 0.002 JAN. FEB. 0.209 0.399 6 ."17 8" 0.188 0.057 0.117 0.444 0.704 UTUOS" 0.014 0.038 0.042 0.004 0.004 WAR. APR. WAY 0.333 0.114 0.086 0.533 0.028 0.282 n nKt ' n ma 0.525 0.049 0.189 0.131 0.048 0.369 0.004 _ 0.023 0.030 -- 0.003 0.004 JUNE JULY 0.125 0.092 0.036 0.254 0.017 0.146 0.082 0.038 0.266 0.000 0.021 0.026 0.003 0.004 AUG. SEP. 0.136 0.064 0.034 0.234 0.000 0.140 0.076 0.036 0.252 0.000 0.018 0.034 0.002 0.004 OCT. NOV. DEC. 0.112 n.m 5 0.0.32 0.159 0.002 0.134 0.094 0.030 0.259 0.000 0.103 0.064 0.027 0.194 0.000 0.018 0.014 0.014 0.002 0.002 0.002 1975 AVG. 0.192 0.105 0.052 0.349 0.010 0.025 0.003 * 1 i cq NFIDEti TlAL: Sub iect t o Prot ectiv^ Ordei of 14 th Juc icial Distrj ct Coi irt o. 91- 1145 PAGE 213-3 PROCESS CONDITIONS VAPORIZING FURNACE t DC FEED TEMP. `UBNCE BRIDGEWALL TEMP. 1 t B VC .P5SE5 Jl (c 2 1974 Avq. JAN T *F PSI 314 _i.286-- 202 312 1223 206 cracking furnace feed temp. -f 403 400 PPG it' > TRIPS CHEA'ICAl DIVISU5M IAKE CltASlES, IOUISIAHA VIHYL CHLORiDE DEPARTMENT OPERATIONS REPORT FEB MAR APR WAY JUNE JULY AUG 301 1080 189 398 295 1100 270 1 ri7fi i 7q 404 398 291 1201 184 386 310 1 7f,d 1R1 309 1277 195 394 397 304 1267 190 394 SEP 302 12.&7 198 398 CRACKING FURNACE*] FURNACE BRIDGE WAUL TEMP. *F 1297 6t4 P AVG.. PASSES*!. *i. *S *4 PSI 137 1293 134 1213 114 1262 116 - 1247 117 1310 1293 129 134 1307 134 1319 138 OCT 271 1347 211 403 1314 144 NOV DEC 1975 Ava. 324 1252 199 317 196 301 1221 196 406 399 398 , 1287 1318 130 fL32 1288 129 vc. PASSOUTUET TEMP.. PASSES *1. *J. *3. fit *4 * F 889 873 857 CRACKING FURNACE #2 FURNACE BRIDGEWALL TEMP. 4 P AVG .PASSES*!. *1. * S 06 * 4 *F PSI 1253 130 1256 124 - .m..JASSDUTlrT TFMP PASSES *1. *. *J& #4 F 884 880 - 876 - 923 939 919 936 894 841 865 368 890 - 1256 1242 1282 1757-- 1280 1239 1284 1293 1306 1269 - 109 110 130 05 131 136 137 124 133 127 , - 910 911 923 899 925. 882 861 - 810 797 880 OUENCH TOWER TOP TEMP. TQ P P R ESS. *F PSIG 276 93 275 83 274 75 269 77 4 260 31 264 88 273 95 276 90 273 265 92 94 263 93 . 260 262 91 95 268 88 SL 013494 -- -- r _________ LLC M L- I Gut' j <=> F- f r> nf 1 !-tl .Thy- . 1 rP r A r W- L- -A. T l V A- T A 1146 1 PAGE 213-4 ______ , pro ii-^stries CULT.' CAt DIVISION LAKE C1IAHI.S, LOUISIANA VINYL CHLORIDE DEPARTMENT OPERATIONS REPORT PROCESS CONDITIONS JAN ADSOROLR COLUMN SEC. QUENCH CONO. GM TEED TEMP. BOTTOM LIQ TEMP. >7TP Ar TEMP. TP *Y *U TEMP. T R AY *JS TEMP. *F F *F F *F L1Q. FROM UPPER INTEBCOOLEfl TEMP. F uro FROM LOWER INTERCOOLER temp. *F LEAN OIL TO ABSORBER TEMP. F IF. AN OIL FLOW AVC. CPM ABSORBER top PRESSURE PSIG .STRIPPER COLUMN QUENCH LI Q. FEED TEMP, 30 T TOM LfQ. TEMP. *F *F STRIPPER TOP TEMP. BO T TOM RftCSS PRODUCT STILL COLUMN LIQUHJ FEED TEMP, BOTTOM LfQ. TEMP. *TB AY It TEMP. TOP TEMP. F PSIG *F *r F *F STILL TOP PRESSURE PSIG 160 128 74 58 24 46 ... (0 -25 172 79 131 216 126 94 223 321 242 108 85 147 124 63 54 29 38 -1 -27 140 76 121 222 124 88 228 317 240 105 79 FEB MAR 112 116 117 116 66 56 51 48 24 33 38 40 -3 -3 -25 -25 113 118 70 71 110 109 222 218 129 128 81 82 224 219 320 320 240 240 106 105 81 80 APR li8 lie 52 si 32 41 -2 -27 136 74 105 221 131 86 222 319 240 L05 31 MAY ' JUNE JULY AUG 145 159 124 129 75 86 55-------- 60 34-------- ~T5------ 165 132 73 55-------- 17 157 125 97 69 36 38 40 37 38 (-1 2 0 (1 -28 -27 ^25------ p26 152 168 T72------ 162 79 80 79--------- 77 118 215. 128 92 135 140 214 222 127 132 95 94 134 209 129 92 216 321 240 106 52--------- 213 326 241 108 86 220 207 326 328 240 240 10? 111 55--------- 89 SEP 134 119 79 57 19 35 0 -27 171 80 118 208 126 97 209 328 240 110 56 OCT NOV OEC 1975 Avg. 138 118 88 60 23 42 0 -29 174 77 117 204 125 94 204 327 240 109 87 132 118 69 56 20 39 -1 -25 182 77 111 213 128 91 208 330 240 107 82 138 119 90 64 20 41 0 -26 173 81 138 74 57 25' 32______ (-1 _ -26 155 77 112 119 211 215 130 128 96 91 206 331 240 107 81 * . 215 324 240 107 83 si 013495 I 1 * - g.th Id CO jerct t -h Jud l IF I DEM > prot icIaT Q . Si* F1 "T*v; get I VC Dlstri 11 Vj OrAp* e-t, Cm lEt_____ PPG INLhlE$ PAGE 213-5 CIlfMiCAL 01 vision LAKE CIIARICS, IOUI5IAHA VINYL CHLORIDE DEPARTMENT OPERATIONS REPORT PROCESS CONDITIONS 1974 Avq. HEAVIES STILL COLUMN LIQ rEED TEMP. BOTTOM LIQ, TEMP. TOO TEMP. TOO PPESSUPE REFRIGERATION r F r PSt G 176 238 200 1.32 PIPIT STAGE SUCTION TEMP. SECOND STAGE SUCTION TEMP. TMIRO stage suction temp. *F -33 *F -6 *F 45 P'OUPTH STAGE SUCTION PRESS. P 51 G compnejson <i. amps0 j.dov OrSCH ARGE PRESS DISCHARGE TEMP. P5IG *F 58 220 126 189 COMPRESSOR 2 ***MPS 9 2400V OUCH ARGE PRESS DISCHARGE TEMP. PSIC F 227 131 187 PRODUCT STORAGE DAY TANKS. AVG TEMP. AVG. PRESS. SPHERES* AVG, TEMP. AVG. PRESS *F PSl G F PStG 70 38 68 47 MISCELLANEOUS CI BY.product t distribution. T CMP, * F -22 JAN 145 234 199 1.11 -31 -4 41 58 220 125 181 232 132 190 55 30 56 46 -21 FEB MAR APR 143 215 192 1.49 142 216 1.46 150 219 191 1.&6 -28 -5 37 53 217 T5S 176 _ - - -30 -27 -4 40 51 720 T23 TBO----------- 38 52. 232 119 173 -- -- -- 54 58 27 30 55 58 47 30 64 . 37 65 48 -23 -22 -22 MAY JUNE JULY AUG SEP 162 226 195 2.24 168 231 199 2.48 171 "736 203 2.89 168 234 200 2.96 164 238 200 2.79 -29 -31 -29 -29 -1 -3 -4 -4 35 52 49 53 63 65 69 68 234 732---------- "730--------- 244 128 T3B---------- 136 142 173 184 179 181 221 245 241 245 T34--------- 141 140 146 T86------ T53" 187 192 75 77 80 81 46 50 49 50 75 80 81 81 55 54 57 53 -31 -4 45 63 246 129 181 245 134 187 1 76 46 78 50 -20 -- 2D -21 -19 -20 COOLING TOWER WATER T PLANT. TEMP. , F 87 82 81 80 83 86 91 92 93 91 - OCT NOV OEC T7F Avg. 167 239 203 2.80 159 239 201 2.70 167 248 202 2.60 159 232 198 2.28 -33 -1 57 60 257 129 182 249 134 '190 -25 +3 48 62 737---------- -23 +7 49 55 239 119 116 173 173 244 248 123 120 180 178 -26 -2 45' 60 234 127 241 134 187 71 40 n" 47 62 34 65 37 57 68 31 39 56 69 38 47 * -19 -18 -19 -20 ... 90 84 80 86 oqil un il Jtx4aobc r 'iNPl DR JT 1 AT,: On! n Pro - i v * Orde r f i - I 1 1 i i i i .t i K i s t r ict 'Cc urt. -1145 1 PAGE 216-1 GENERAL DEPARTMENT OHC-EDC Production T/O 1974 Avg. 358.5 JAN. 326.7 PPG l JS7PIPS * CHE 1ICAL DIVISION LAKE CHARLES, LOUISIANA OHC-EDC DEPARTMENT OPERATIONS REPORT FEB. MAR. APR. MAY JUNE JULY 224.0 232.6 278.3 286.6 298.1 308.3 AUG. 366.8 SEP. OCT. NOV. 1 Die. 399.2 412.8 355.7 447.2 197E Avg. 328.0 HCL to OHC-EDC HCL Consumed T/0 274.3 249.9 168.1 173.2 T/T EDC 0.763 0.764 0.750 0.744 210.5 0.756 220.2 225.9 233.4 0.768 0.757 0.757 27478 0.750 304.1 309.3 274.1 351.2 249.6 0.761 0.749 0.770 0.769 0.X8 Purchased C2H4 to OHC-EDC % CjHj Purity YIELD Clj Basis C?Ha Basis T/D % 105.3 96.4 62.4 64.0 99.92 99.93 99.89 99:94 96.6 93.6 96.3 92.5 TO72 9b. 9 99.0 97.7 77.0 99.89 97.4 97.2 81.3 84.8 88.6 99.89 99.95 99.93 96.8 96.6 98.9 97.7 99.0 96.5 101.9 99.95 99.3 99.6 114.1 118.4 101.9 99.94 99.91 99.86 98.1 98.0 98.6 96.6 97.8 97.6 132.0 93.6 99.93 99.92 96.9 *9778 9?. 0 97.1 Excess C2H4 Excess CjHj Excess C?Hj % 3.4 T/M 107.4 Lbs/T ED J.9.2 4.1 117.6 23.2 -1.7 -3.0 -30.4 -60.6 -9.7 -16.8 -2.4 -56.0 -13.4 0.3 0.0 0.1 0.4 9.9 2.2 1.4 -1.9 T77S-- -59.9 7.9 -10.6 0.7 24.2 4.0 1.0 38.2 6.0 1.1 32.9 6.2 2.0 80.8 11.4 1.7 11.2 -0.9 Oxygen to OHC-EDC Oxygen to OHC-EDC Excess O2 Excess Oj Excess O5 T/D 68.3 T/T EDC 0.190 % 13.7 T/M 245.8 Lbs/T ED <16.1 60.4 0.185 10.2 174.2 34.4 38.6 0.172 4.6 47.4 15.1 44.2 0.189 16.2 190.9 5170 55.2 0.198 19.6 271.2 65.0 57.5 0.200 19.0 284.1 63.9 61.8 62.9 0.207 0.204 24.7 22.8 367.9 362.2 81.8 757B 73.7 0.201 22.2 415.1 73.1 80.4 0.201 20.5 410.0 68.5 83.1 0.201 22.4 471.1 73.6 73.0 0.205 21.4 385.6 72.3 95.8 0.210 24.4 582.4 82.3 65.6 0.198 19.0 330.2 63.2 CRUDE EDCINVENTORY Tor Pcr-Tri Feed For EDC Still No. 2 Feed TONS TONS TONS ___ For Tetra Feed_______TONS Transferred to Per-Tri TONS Transferred to EDC Still No. 2 TONS Transferred to Tetra TONS 433.1 26.5 100.3 306.3 41.6 2786.1 8049.5 293.3 441.7 360.3 0.0 0.0 3.0 26.5 26.5 3.0 266.8 415.2 360.3 0.0 0.0 3.0 1154.0 682.5 2282.7 8872.5 5501.5 5228.9 MAN HOURS/TON EDC PRODUCED Production 0.167 Maintenance 0.218 Salaried 0.065 Total 0.450 Contract Man Hours Included 0.008 0.185 0.339 0.070 0.594 0.048 0.267 0.483 0.102 0.852 0.187 3.240 3.296 3.093 3.629 3.140 ,, Ql nntm 369.9 0.0 0.0 369.9 0.0 4367.1 4244.7 0.220 0.299 0.084 0.603 0.076 396.1 606.9 370.0 0.0 0.0 0.0 0.0 0.0 0.0 396.1 606.9 370.0 0.0 0.0 0.0 1634.2 4942.7 6243.0 7475.3 3746.2 3503.6 411.7 557.3 0.0 0.0 0.0 0.0 ^lTi7~ 557.3 404.5 557.4 0.0 0.0 155.0 167.4 74775" 390.0 0.0 0.0 0.0 0.0 4266.2 5624.3 8766.8 5803.1 7042.1 6181.S 4129.0 5135.5 480.2 0.0 169.1 311.1 0.0 7528.8 6412.5 437.5 0.0 45.4 392.1 0.0 4441.3 5622.8 0.204 0.254 0.076 0.534 0.000 0.175 0.247 0.079 0.501 0.021 0.176 0.189 0.074 0.439 0.000 0.158 0.213 0.059 0.430 0.000 ________ 0.154 0.288 0.056 0.498 0.112 0.134 0.064 0.058 0.256 0.012 0.161 0.193 0.054 0.408 0.023 0.123 0.144 0.048 0.315 0.021 0.183 0.251 0.071 0.505 0.053 romp TltPlWI At. . Snh jo fn Prrstpr fr i f rrlpr Utb Judicial Pi strict Court Of Subject to Protective 14th Judicial Distn Or^er ct Court Mo. 91-11*3 PAGE 216-2 ppg ind rniEs CHEMICAL DIVISION LAKE CHARLES,LOUISIANA V.UIUl'* GHC-SDC HCACTCR ff1 - 1974 JAN. AVG. FEB. MAR. APR. MAY JUNE J-n-StreaT. Time* Top Pressure Ccv.-therrr. Temp,(Frum) (Into) Hrs. pcig F F 6540 20 382 340 316 22 359 332 672 18 382 352 628 272 18 21 388 367 362 337 396 676 14 14 403 406 377 378 Leactor Temp. Catalvst Bottom F t 'dd die op Top up Vapor Space UK Rei'rig. Cond, Outlet UF FEZDS CpH/t scfh Oo SCFH HC1 SCFH 589 537 516 $19 51 38500 24900 87100 588 587 542 537 526 525 ,, 531 bidb 46 45 39300 34900 24300 22000. 94700 1 86500 588 542 526 526 46 34100 21500 85600 543 549 524 524 49 3900 2-4500 90900 583 540 540 527 45 29800 20200 74700 586 544 527 528 70 26800 19200 71900 RECYCLE AIiALYSIS( Vol, %) CCp CpHt02 Catalyst Charged % 33.6 % TFTo J6 2.4 Lbs, 7714 39.7 43.5 2.9^ 24320 41.9 42.1 2.7 - 44.6 37.3 2.8 12884 49.4 32.8 2.1 4000 51.2 33.2 2.9 2540 43.2 31.3 2.3 6920 JULY AUG. 24 84 TO------------ 16 - 382 - 352 570 588 531 533 521 524 519 528 74 44 25000 32500 16000 21100 67100 78800 24.7 39.8 2.0 0 47.4 40.2 3.1 11060 SL 013498 SEP. OCT. NOV. DEC. 628 720 23 22 364 373 332 345 472 744 19 19 388 390 360 364 595 539 506 525 48 42000 27900 97400 588 533 521 523 49 37200 25000 92200 588 536 526 527 47 34600 22800 84100 593 529 515 516 43 32100 21000 81400 45.8 41.0 3.5 872 42.1 35.3 2.7 16000 35.4 44.7 2.6 3200 40.9 39.1 2.9 4000 1975 AVG. 5632 18 382 354 583 538 523 525 50 33700 22100 83800 42.2 38.4 2.7 7800 REACTOR H2 On-Stream Time* Hrs, 6254 Top Pressure psic 17 Cowtherm Temp,(From) F 371 (Into) F 340 leactor Temp, Catalyst Bottom F 587 Middle F 529 .Top op 518 Vapor Space F 518 Refrig. Cond. Cutlet F 50 : '.oDS CpHL scfh 37500 02 SCFH 22200 HC1 SCFH 80700 iFCtfCLE ANALYSIS! Vol, %) CO? CpH/t % 37.6 > 47.5 02 % 2.6 Catalyst Charged Lbs, 9250 632 16 374 341 583 536 525 526 48 38035 22440 75170 35.8 45.1 2.0 13760 Tnt.t.U 524 14.7 394 367 583 534 524 526 46 35285 18920 74110 36.9 43.0 1.55 - 744 18.1 378 346 504 17; 5 372 336 589 539 527 529 45 37970 21250 82380 587 536 524 523 46' 37800 21700 75200 41.9 aq 1 2.27 5440 54;. 3 29.8 1.87 7000 44 11.3 387 404 0 - _ 597 552 541 542. 62. 30100 18100 62500 _ n n n 55.4 36.1 1.97 40000 _ 0 424 10 .-8 404 384 612 11.4 404 381 0 - - - 572 530 515 517 51 30500 16500 59100 582 531 512 509 50 30600 15900 63400 -- - - - - - - 39.7 46.1 39.3 39.6 2.41 2.48 14865 3840 - - 0 0 - - - - - 0 336 17.6 380 351 669 15.1 393 365 4489 14.7 387 364 595 547 528 532 46 39500 23100 80600 586 535 518 521 45 34600 21500 66900 586 538 524 525 49 34900 19900 71000 39.7 44.1 2.16 3200 33.7 45.5 1.63 4000 42.6 40.2 2.04 11513 PAGE 216-2A CHC-EDC REACTCR #3 197' JAN. AVG. On-Stream Time * Hrs. 5870 486 Top Pressure pcig 19.7 16.0 3cv:therrr. Trop.tFrora) F 391 393 (Into) F 371 375 Reactor Temp. Catalyst Bottom Kid lie Top Vapor Space Refrig. Cond. Outlet F 532 o* 524 UF 509 UF 503 F 53 544 533 527 519 47 PESOS CoHa SCFH 8200 78600 0-j HC1 SCFH 48400 41710 SCFH 16710C 153280 RECYCLE ANALYSIS(Vol. %) CC? % 47.2 59.2 CoHa 02 Catalyst Charged % % Lbs. 34.7 2.4 15978 28.6 2.5 19520 FEB. -- -- - - -- - - - ppg ihotItries CHEMICAL DIVISION LAKE CHARLES, LOUIS IANA X'. MAR. APR. MAY JUNE - 444 696 - 14.4 15.7 - 424 413 - 406 396 667 14.6 426 410 CONFIDENTIAL: Subject to Protective Order of 14th Judicial District Court No. 21-1145 JULY 744 17.7 403 383 AUG. SEP. OCT. 744 21.4 385 362 664 22.2 379 354 724 23.8 372 349 NOV. 556 22.0 388 374 PEC. 728 19.6 394 377 1975 AVG. 6453 18.7 398 379 538 542 534 531 531 530 529 538 546 536 534 528 535 532 532 527 519 528 535 530 5i5 526 518 519 520 522, 521 523 512 521 - 519 517 509 511 511 516 515 515 499 513 - 44 48 72 46 49 46 49 47 43 49 58200 73000 65100 76600 85200 89600 98100 88700 83700 80700 40S()0 47100 41800 49800 54600 53500 51100 50500 47400 47800 140700 154600 13780C 163200 177600 182500 188500 179100 163500 164100 s - _ 51 ^6 54.9 52.7 50.8 59.8 59.0 45.0 49.0 47.6 1 R - fi 20.1 18.6 22.4' 23.8 23.8 33.1 31.7 33.1 2.3 2.5 2.0 2.1 2.6 3.1 2.7 2.8 2.9 -- 38620 10000 10380 14865 9600 988 32680 5160 8120 53.0 25.4 2.6 14993 ' * -- .Ql H 1 *1 A n n -1 TntfOr-tt 1974 CKC-EDC PUMT DATA AVG. lefrigrrated Brine Temp. Warn F 46 Cold F-- 45 Chloral Treatment Feeds Organic (gpm 40.8 Cell Liquortgprc 5.2 Drying Still #1 Texp. Bottom F 174 Vapor Outlet F 155 Press, Bottom psig 2.3 JAR 51 49 34.9 5.9 184 163 1.9 FEB. 44 43 23.6 6.1 ~Ttt !!>/ 2.6 PPG IIWJSTftlES CHS!.. ICAL DIVISION LAKE CHAILES;LOUISIANA OXYHYirtuCiilCilIN.'lTILN CHTlATICilS MAR. APR. MAY JUNE JULY 44 42 42 41 23.4 32.2 6.0 5.9 184 189 158 159 2.6 2.9 42 66 41 66 33.8 6.0 33.8 6.0 185 185 165 167 2.8 2.3 41 39 35.9 5.9 - AUG. SEP. 44 42 43.3 9.6 41 39 45.3 9.5 --- 2.9 OCT. NOV. DEC. W 45 44 43 42 51.3 47.7 8.3 8.4 190 190 167 162 3.9 3.5 43 46 41 44 55.1 8.7 38.4 7.2 188 166 3.1 187 163 2.8 Drying Still #2 Temp. Bottom F Vapor Outlet F Press. Bottom PSIG 188 169 2.3 188 172 2.1 - - 186 187 189 188 188 193 192 190 189 - 167 169 172 172 172 - 173 173 174 172 - 1.4 1.9 2.3 2.1 2.3 2.9 3.0 2.8 2.8 2.4 Light Still Feed Reflux Temp. Bottom (GPH) (GPM) F Overhead F 18.7 23.1 207 177 17.2 20.7 186 173 27.4 21.4 181 153 28.9 20.7 206 183 .28.2__ 16.2 21-0 21.3 204 204 180 183 30.9 21.3 206 184 34.6 22.3 211 185 27.9 27.5 210 186 36.9 24.7 213 185 46.4 22.9 212 185 43.1 24.1 212 184 44.1 21.2 210 183 31.8 22.4 204 180 30# Steam Produced 45# STEAM PRODUCED Lbs. 1465 LBS. - Electric Power {KWH/T EDC) Well Water (M Gal/T EDC) Natural Gas (MCF/T EDC) Nitrogen (T/T EDC) Catalyst (Lb./T EDC) 86.8 0.117 0.000 0.098 3.31 2138 4042 106.5 0.256 0.000 0.130 2.63 2252 0 131.3 0.414 0.000 0.177 - 3265 0 144.8 0.055 0.000 0.180 2.54 1744 4224 115.8 0.011 0.000 0.148 1> 64 297 5406 2 4124 120.9 106.7 -- 0.000 0.003 0.105" 0.124 5.91 1.96 1 6456 115.1 0.502 0.000 0.111 3.11 1 7332 94.6 0.739 0.000 0.090 2.16 1 6316 82.5 0.684 0.000 0.094 - 09 6273 4012 84.6 102.9 0.742 0.937 0.000 0.000 0.100 0.121 3.80 1.08 347 6461 83.8 0.664. 0.000 0.090 1.14 838 4554 107.5 0.500 0.000 0.122 2.60 QO|L nU1(J*1 DrnUnu 1 of -- lubjec 14th Ct/ftr d a L: : lo ni Jodid ,1 ive Oi fli d trict --NO r gl-114 5 der CourEl GENERAL DEPARTMENT No. of Batches Highest Reactor Temp. Avq. Avg. Time of Reaction F 1974 AVG. PPG IN[j >.TR!ES GHEWICAt? 1VI3ION LAKE CHARLES,LOUISIANA VINVLIDENE CHLORIDE DEPARTMENT OPERATIONS REPORT JAM FEB. WAR. APR. WAY JUNE JULY AUG. SEP. OCT. NOV. DEC. 1975 Aim Reactor Feed_____________ GPM Still Pressure PSIG 17.9 Stilt Top Temp. F 111 Reboiier Steam Flow Reboiler Temp. #/Hr, 792 F 134 Bottoms to VDC Roto. % 30 17.4 15.3 106 106 595 363 124 125 20 -- 14.9 14.9 106 105 450 570 126 128 20 20 15.0 105 907 127 15.0 105 14.9 105 15.5 109 640 ~E6U----- 750 128 127 133 -- - 18.1 .113 840 138 16.3 16.4 111 107 908 893 139 137 -- 15.3 105 947 105 " 15.8 107 710 128 20 MAN HOURS/TON Production Maintenance Supervision Total Contract Man Hours/T inc. 0.582 0.236 0.784 0.718 0.508 0(368 0.337 0.526 0.497 0.341 0.446 0.226 0.394 0.436 0.465 0.146 0.018 0.006 0.007 0.109 0.159 0.013 0.000 0.000 0.000 0.031 0.066 0.046 Prod uc tion Shipped Tons/Day 26.0 Tons/Day 25.9 18.0 21.5 14.7 23.4 20.6 27.0 20.3 26.7 28.7 17.5 17.6 23.8 19.4 27.9 29.3 21.6 32.8 26.3 43.9 25.6 31.9 24.7 21.9 23.8 24.6 24.5 . HQt-LME #/Ton VnrM 1.5 0.3 1.5 1.5 1*4 1.5 1.5 TJ75----- 0.5 0.2 0.4 0.3 0.5 0.8 , sl n 1.1501 1 _ CON ?IDENT IAL: Subi< !Ct to Prote ::tive Order c 14 LI i Judii :ial D Lstric t Coui t No . 91-1 145 ________ PAGE 218-1 GENERAL DEPARTMENT Total Received from: T/D EDO TCE EC VC P/T CONOCO Puerto Rican Tank TOTAL FROM OHC Transferred to P/T T/D PPG .''CHET'ICAL DIVISION LAKE CHARLES, LOUISIANA "T97S AVG. WASTEJECQiiEE'L DEP&RJ RENT OPERATIONimS. REPORT JAN. FEB. MAR. APR. MAY JUNE JULY AUG. V 5.4 4.4 0.4 0.0 0.7 0.9 12.0 5.0 142.7 157.6 21.4 9.6 18.0 29.5 209.7 235.9 173.8 199.7 3.0 0.0 0.7 7.1 160.2 7.5 36.3 232.2 200.6 2.5 0.0 0.7 2.5 166.1 3.9 35.7 223.3 6.2 0.0 0.7 4.8 179.6 1.3 13.8 213.9 199.0 -189.4 7.0 1.6 5.8 0.0 0.0 0.0 1.0 .0.8 0.8 5.7 16.5 7.8 133.5 .102.4 83.5 17.1 17.1 15.8 1.5 18.9 47.2 183.2 172.5 161.9 2.3 4.5 1.0 161.0 146.6 144.2 5.4 0.0 0.9 9.2 103.2 14.7 10.7 154.5 3.4 125.9 SEP. 2.7 0.0 0.8 13.0 90.1 13.6 2.7 138.0 5.1 111.3 OCT. NOV. DEC. 4.2 4.5 0.8 16.5 99.2 21.3 4.9 163.6 1.1 145.6 10.6 0.0 1.8 13.5 4.7 0.0 2.1 9.5 120.7 115.8 21.7 22.0 11.7 33.6 193.3 202.2 3.1 4.8 160.4 173.3 m 4.8 0.4 1.0 9.2 12 6. Q 13.8 20.5 189.5 3.2 163.1 LOSS Tons 788.4 634.4 514.1 525.1 262.2 364.6 557.2 554.6 582.2 462.4 252.5 691.4 542.1 495.2 POT TEMPERATURES No. 1 Kettle No. 2 Kettle F 310 297 291 178 OVERHEAD TEMPERATURES F No. 1 Kettle No. 2 Kettle 288 297 275 286 YIELDS Cl 88.0 C 88.7 30.0 30.6 t 294 183 275 300 1 91.3 92.2 299 208 278 302 91.8 92.9 304 300 284 282 238 229 251 295 290 294 212 281 282 267 263 273 275 307 229 300 Ztt 298 295 95.9 95.0 93.0 92.9 88.2 8879-- 86.6 89.9 89.2 90.8 87.9 88.2 290 291 289 224 224 224 267 272 269 299 295 296 94.4 88.0 91.0 95.7 84.5 90.5 284 227 273 292 90.6 91.0 SOIL fUt 11J*1brnUo2 CON PI DENTIL L ! lub jec : to i1 rve--9i of 14th Fudici al"Dl.s Lt let Ro. 91-11 PAGE 219-1 SEE NOTE GENERAL DEPARTMENT VENT FLOWS No. 1 EDC No. 2 EDC P/T OHC M SCF/Dav pro w r CHi ;)CAL DIVISION LAKE CHArU.ES,LOUIS'ANA INCINERATOR OPERATIONS REPORT Ta/T, Proctive Ord?F of 14th Judicial District Court o- 91-1145 1974 AVG. 2 42.2 195.6 1294.9 312.5 JAN. FEB. MAR. APFt. 2.3 10.8 25.6 2.3 244.6 163.3 163.1 L5fi.fi 1209.5 1204.9 1066.4 1274 7 289.1 257.6 235.0 304.1. MAY 0.0 143.9 943.6 295.8 JUNE JULY 122.3 61.2 152.3 106.6 691.3 703.3 300.6 269.2 AUG. SEP. OCT. 61.6 151.3 752.3 270.7 109.3 154.7 742.5 250.7 83.5 171.1 703.2 285.7 NOV. 96.2 833.7 235.7 DEC. 1975 AVG* 80.6 54.6 148.4 166.2 1001.8 927.3 284.4 273.2 LIQUID FLOWS (cl) LBS./Day EDC Waste Recovery MC EC VC _ NO. 1 INCINERATOR Waste Gas M5CF/Day Natural Gas MSCF/Dav Lake Water GPM 338.9 248.2 516.6 1604. ( 1624.4 988.2 1187.4 1061.fi 766.3 866.9 -- 596*.Q- 738.1 740.5 473.6 246.1 236.0 443 385 363 396 470 432 395 821.7 739.5 213.6 144.5 466 489 1397.8 1607.1 688.0 1112 JL 215.4 m -8 144.9 351.0 405 452 475 431 Temperature Operating Hours* F 2426 - 2498 2470 590 602 2447 2462 717 704 2439 623 2480 2427 398 390 2449 397 2495 264 2510 363 2534 216 2494 2475 284 5548 HC1 in Aqueous Sol. Tons 1003 944 t605 310 350 36 7 193 ' 603 676 280 673 802 994 566 NO. 2 INCINERATOR Waste Gas tPCF/Day Natural Gas M5CF/Day Lake Water GPM 1856.1 1147.7 895.3 214.0 265.3 547.-p 395 451 957.6 1333.1 986.8 516.1 513.0 430.2 453 478 476 997.6 225.9 387.1 104.5 475 509 677.5 696.2 208.9 160.6 232.9 432.7 442 454 405 0.0 413.3 493 1188.( . 773.1 353.0 346.2 504 461 Temperature Operatinq Hours* F 2473 _ 2502 2394 281 362 2374 2456 708 713 2435 2443 2463 686 636 136 2398 2441 2520 293 377 668 2554 714 25.75 616 2463 6190 HC1 in Aqueous Sol. Tons 1574 339 209 399 123 345 250 63 326 377 723 798 985 436 SL 013503 NOTE EFFECTIVE 1-1-75 FLOW RATES FOR EACH INCINERATOR ARE B?GED ON INCINERATOR OPERATING TIME NOT MONTHLY AVERAGES. *Totals (*1 Estimated by ProcL