Document J3ZNdzMZXLwaLLo187G5Kdyka

FILE NAME Owens Corning OC DATE 1935 DOC OC294 DOCUMENT DESCRIPTION Journal Article - Ruck Wool in Relation to Health AFTER THIS REPORT HAS SERVED YOUR PURPOSE AND IF YOU HAVE NO FURTHER NEED FOR IT PLEASE RETURN IT TO THhe Bureau OF MINES THE USE OF THIS MAILING LABEL TO DO SO WILL BE OFFICIAL BUSINESS AND NO POSTAGE STAMPS WILL BE REQUIRED UNITED STATES DEPARTMENT OF THE INTERIOR BUREAU OF MINES OFFICIAL BUSINESS RETURN PENALTY LABEL THIS LABEL MAY BE USED ONLY FOR RETURNING OFFICIAL PUBLICATIONS THE ADDRESS MUST NOT BE CHANGED PENALTY FOR PRIVATE USE TO AVOID PAYMENT OF POSTAGE 300 BUREAU OF MINES WASHINGTON D. C. 01 501 0758 Hopriated from THE JOURNAL OF INDi etnial liraISNE Vol 17 No , November 1935 ROCK WOOL IN RELATION TO HEALTH Lawrence T. FAIRHALL PH.D. STEWART H. WEBSTER PH.D. and GRANVILLE A. BENNETT M.D. From the Laboratory of Physiology Harvard School of Public Health and the Department of Pathology Harvard Medical School Boston Mass HE utilization of furnace slags T in the form of wool for insulation purposes has become so exten- sive that the former metallurgical by- product is now manufactured direct and marketed under various names such as rock wool mineral wool etc. insulating houses this material is blown into all spaces in the outer walls and a covering laid down in the attic so that the house is completely insulated Since individuals living within the houses are surrounded by such material it has been questioned whether the use of rock wool could be a problem of hygienic importance In- asmuch as this material enters into construction in such a manner that the ished product Although the latter is a relatively low silica glass stable insoluble and chemically inert a searching investigation was made of its chemical composition and of the pos- sibility of any vaporization of injurious substances The presence or absence of any poisonous element would to a large extent establish the material as either dangerous or innocuous completely it is true for assuming a very toxic combination of certain elc- ments this combination might escape detection in the search for the indi- vidual elements The practical test therefore was to determine the effect of the material upon animal life To this end the following experimental proce- occupants are separated from it by plastered walls which act as very effi- cient filters the only conceivable way in which it could cause injury assum- dure was adopted EXPERIMENTAL PROCEDURE Cats were selected as experimental ing harmful ingredients would be by means of vapor either direct or as a result of slow decomposition The animals since they are sufficiently sen > sitive to poisons can be housed conveniently and have tissues sufficiently following experiments were devised to large for extended chemical investiga- test this effect In this investigation all the raw materials entering into the manufac- ture were examined as well as the fin- * Received for publication October 15 1035 Our thanks are due the Manville investigation Company for the materials provided for this In addition to the raw ma- terials entering into the manufacture of the rock wool the finished products of three plants geographically distributed as follows were investigated Manville N. J. Alexan- dria Ind and Waukegan Ill 263 01 501 0759 261 THE JOURNAL JOURNAL OF INDUSTRIAL HYGIENT 17 no Hon Three types of procedure wete followed with the examals exammals One group cho was exposed to any futne or vapor that could be evolved evolved by passting ar over the rock wool at room tem priatur Another group 2 was ex- posed to air passed through the rock wool so heated that the air curient acquired a temperative varying bes tween 67 and 82 The third mafen diszont diszont of the rock wood from the vactions sources showed the follow- ing ments to be present and readily detectable chemically stheon cal- erum magnesium sodium iron aluJummum sulfur titanium michiganese and zine When large enough samples were used 10 gm or more an extreinely miniute amount of lead could be de- Si0 40 MgO K . N O MnO S. | HO Total TABLE Cursurya Composition or Vaisius Rock Wools 4 . Na Ce 11 28 37 10 33 98 20 0 28 13 0039 0039 01k 99 969 15:30 219Hi 219Hi 18 33 19 37 0 023 016 0 156 921 20 2393 67 11 952 19 0 028 0.051 17 100 812 7.65 0 30 16 0 025 0123 100 650 R mOeludes 0 110 and T10 B manufactured free 4 i | per cent 18 : Od content \ 15 partent 1.08 free e per tent 006 group 3 in addition to the same exposure given to 1 were further exposed for 1 hour daily to a dusty atmosphere of very finely ground rock wool All these groups received the exposure mis dicated for 2 months continuously At the end of this time the eats were chloroformed and their tissues removed removed for pathological investigation und chemical and spectrographie analysts Preliminary analysis of the raw tected of that order of magnitude one would expect to find in a natural rock and traces of arsenic often con- sidered questionable could barely be detected by the most refined elwinical means In order to minimize dust produe- tion in the process of manufacture the material is treated with mineral oil a small amount of which remates in the hed product The chemical com- Nav 1933 ROCK WOOL IN RELATION TO HEALTHE 2457 position of the various types of rock wool was determined and also the oil content These values are given in Table 1 If the rock wool is capable of giving off vapor or fime at room temperature it would be expected that this woukl be more abundantly evident by direct distillation Accordingly an glass apparatus was constructed consisting of a large distillation bulb joined to small glass receivers capable of being closed by means of stop cocks A manometer was connected in series in order to read the degree of vacuum attained Except where sealed all connections were made by means of ground glass joints A Hyvac pump could reduce the pressure to at least mm of mercury The material tested was the commercial oiled product powdered to facilitate loading into the apparatus The distillation bulb containing 10 12 gm of rock wool was heated by a bath of boiling water The receiver was was cooled to low tem- perature by means of a mixture of aleo- hol and carbon dioxide snow After half hour of distillation a very small amount of distillate 0.020.05 cc was collected and found to be simply water No oil distilled over Since under these extreme conditions no vapor other than a trace of water rould be evolved there is no probability that anything is likely to be evolved under ordinary conditions of commercial or domestic use 1. THE COLD VAPOR EXPERIMENTS EXPERIMENTS In order to determine further whether any vapor inimical to animal life could be evolved from rock wool at room temperature animals were made to depend solely upon air that had been in contact with rock wool To this end an apparatus was constructed which is shown in section in Fig 1. The metal cylinder was 4 ft high and 1 ft in diameter with spun ends and locked seams The orifices at top and bottom measured 13 inches in diameter A screen separated the F10 Cold vapor cylinder rock wool from the bottom so as to insure an even distribution of the air blown through the lower opening The cylinder held 20-25 pounds of rock wool depending upon the degree to which it was packed Air was blown through at a velocitoyf 3.3 to 4.5 cu ft minute The animals siniply lived in this atmosphere and were watched 01 501 0760 266 THE JOURNAL OF INDUSTRIAL HYGIENE 17 no 6 for weight changes or other effects of their environment At intervals of 3 weeks the rock wool was changed so that the animals were exposed to all three types The eight cats receiving this exposure were chloroformed at the end of the 2 months and their tissues rock wool when filled It was exter- nally beated electrically by means of winding of nichrome resistance wire Fig 2 Air was blown through at the rate of 9 cu ft per minute The air leaving the apparatus at u tem- perature of 67-82 was obviously too po a wa a | ab. ee eee = FIG Hot vapor cylinder a Nov, 1935 ROCK WOOL IN RELATION TO HEALTH 267 which the animals were kept was small and wholly dark except at such times as when cleaning feeding and weighing were carried on Furthermore in spite of liberal rum of cooling wattheerorom was noted The animals remained healthy and normal throughout the experiment At the conclusion of the experiment they were chloroformed and their tissues examined as in the -35cm -35cm 46cm 9 35cm35cm -35cm L- HOLE FOR AIR SAMPLING es ANIMAL DUSTCABINET ELECTRIC HAMMER 30cm MOTOR DRIYEN INTERRUPTER KILOGRAMS |\i WEIGHT 24 5 6 7 99 10 11 12 13 14 15 16 17 EFFECT OF ENVIRONMENT UPON THE AVERAGE WEIGHT OF CATS DURING TWO MONTHS EXPOSURE Fia Weight changes during the experimental period removed for chemical and pathological examination II THE HOT VAPOR EXPERIMENTS The apparatus used for heating the rock wool was a metal cylinder 7 inches in diameter and 4 ft in length the air tubes at either end were 1 inch in diameter It held 10-12 pounds of hot to breathe and was therefore passed through a coil of copper tubing immersed in running water and was thereby brought down to a temperature slightly below outside room temperature The animals were confined to this atmosphere for 2 months successive lots of rock wool A B and C being used The space in Fia Dusting apparatus became unpleasantly warm and humid during especially warm days These animals were therefore subjected to rather severe conditions The slight weight loss indicated in the chart Fig 3 is therefore not surprising Beyond this however no other effect previous case for any significant changes III THE Dusting ExpenRIMENTS The eight animals exposed to the rock wool dust for 1 hour each day 5-6 days per week were incidently exposed 01 501 0761 6 208 THE JOURNAL OF INDUSTRIAL HYGIENE 17 no during the reminder of the time to the conditions ni group The cats were exposed in groups of four at a time in the appar dus shown in Fig 4 Compressed air freed from the slight moisture usually present by passing over calcium chloride was forced through the rock wool which had been repeatedly extracted with carbon tetrachloride and then finely ground in ball mill It was found to be rather difficult to produre dust with the com- COUPON The average particle size of the floating dust after allowing the coarser material to settle for a few minutes was 22 Impinger samples of a fixed volume 5 cu ft of air were taken during the dusting The distilled water suspensions thus ob- tained were evaporated to dryness in platimuum dishes and weighed The dust content in terms of milligrams per cubic meter is shown in the chart Fig 5 No attempt was made to 800 METER METER we METER CUBIC CUBIC CUBIC MILLIGRAMS MILGRAMS I aodMILGRAMS Hf MILIGRAMS Fa YJ 10 | = bd _ tf CW _ ~ f . 50 60 70 Fig Dust concentrations during the experimental period mercial type of oiled rurk wool no mat- ter how finely ground | Furthermore what dust was carried into the air remained in suspension a very short time only and quickly settled out The cal very effectively prevents dust formation When repeatedly X- tracted with carbon tetrachloriadned thoroughly died however a very satisfactory dust was produced which remained in suspension reasonably well Although finely ground the particle size vaned considerably of keep the dust at constant constant level on the contrary every effort was made to make the conditions extreme by running the dust content to high levels The animals were exposed to the vari- ous types of rock wool in turn af intervals of 3 weeks The sole purpose of the dusting experiment was to deter- mine whether the rock wool contained any poisonous substance that had escaped detection by other means Since as noteil later the only evidence obtained was of a negative character Nor, 1935 ROCK WOOL IN RELATION TO HEALTH 269 and because of the difficulty we ex- perienced in raising dust from it one may fairly assume that dustiness in commercial utilization of rock wool is distinctly a factor of no hygienic importance Throughout the experi- ment the animals remamed in excellent condition At the conclusion of the experiment their tissues were removed as in the other cases for further ex- amination DISCUSSION DISCUSSION Chemical investigation failed to disclose any single factor of toxic importance From the raw materials including slag limestone sandstone and oil to the finished products including both oiled and treated rock wool nothing but | spectrographie traces of any elements of toxic signifi- cance could he found and these traces obviously are fixed in the form of sili- cates and are therefore most inert The small amount of oil left in the rock wool is also inert except that it has the valuable property of increasing the filtering action of the rock wool with respect to dust Not only is it difficult make a cloud of dust by blowing air through the ground up commercial rock wool but the rock wool of itself constitutes a filtering medium In order to test this runs were made both with the normal rock wool and with rock wool that had been heated for a mouth and largely dried out The velocity of the flow through the latter was three times that through the rock wool at rooth femperature The heated cylinder No. ) was operated 18 hours before testing the room teni- perature cylinder No. 2 was operated We are indebted to Mr Richard Page for the dust concentration measurements for 1 hour before testing The air flow through cylinder No. 1 was 9.9 cu ft per minute that through cylin- der No. 2 was 3 cu ft per minute The temperatures were as follows C. Compressed air Corridor air : Air leaving ) Air leaving Cyl 2 Experimental Room _ 32 71 vee 2. 27.5 . .. 33 Two samples of the compressed air one of the corridor air and one cach of the air leaving the cylinders were collected The dust concentration meusurements were made by the dark field method The results of the counts and the calculation of the con- centrations are as follows Sample I 2 3 4 5 Description Dual concentration bark peld particles per cubic foul Cylinder No .. 58,300,000 Compressed air . 41,600,000 Cylinder No. .. 18,300,000 Compressed air . 45,000,000 Corridor air . 28,000,000 That there is a slight increase in dustiness of air going through the heated cylinder is probably owing not only to the high velocitoyf the air but also to the fact that the filtering action was probably reduced by the oil having been largely dried out by the continu- ous heating during the preceding month There is a definite filtering action apparent in passing the air through the cylinder at room temperature at the lower velocity of 3.3 cu ft per minate That is there is a drop in number of dust particles from the mean value of 43,300,000 particles per eu ft in the compressed air to 18,300,000 partieles per cu ft on leaving the cylinder With respect to the effect of the rock 01 501 0762 Thi JOURNAL OF INDUSTRIAL HYGIENE 17 no 6 2 en ce --- ---- 1 ver TABLE TABLE 1 axertopsen FLOAT B a Weight Arsebut Arsebut 1 Mercurs | Jead Cald vapor 115 e a ve .. 2313 2313 100 80 60 1 223 . Mil | 15 29 Questionable Questionable Questionable Ver 98 10 Ivaney 4 15 | Nil = 19 Yer 29 20 40 9102791027 Liver Kade 19 17 OF Tuch Sidney 8910 26 10 Questiomobh- QuestiomobhNil NilQuestionable Questionable Nd Not Ni Ni Nil Nil Nil Nil y Nil Nil Nil Nil Nil Nil Nil Nil Nil Nil Nil Ni y Nil Nit NO 3 19 k 109 9 32 30 fang IN | | Nil = Liver 106 941 slicizumable Nil | | Judney 31 25 Nd Nil NB g 22 16:25 8 70l Lang 15.63 Nil Nit Nil || | fiver 72 Questionalde Nil Nil | Isidney 19 GIF Nil Nil Nil | NatNil 15 30 25 93 21 10 Jung 20 Nit | Inver 90 0 Questionable Jidney 23 ^ | Nil Nil Nil 2 21 21.55 6521 75 Lung 22 No Nil Nil Inver 83 Questionable || Kadney 23 10 Ni No 11 33 Na 2175 Lung Nal Na | | Laver 98.70 98.70 Questionable No Kahney 35.60 Nil | |: Nil Nil Nil Nil Nil Nik Nil Nit Nit Nil Nil = Hol vapor cats 3 89 34 15 20 Jung Liver kidney 2125 2125 Ni 86 Nil || 95 Kil b | 83872910 20 25 85 83872910 83872910 Lang 23 Ni LINE 83 No || hasnes 27 00 Nil 21 | D Ss SO 35 10 81 23 RO ee eee Dees Lang Liver Kidney 33 05 Nd 81 | Nil 22 00 Nil [| Nil ene Nil Nil || Ni Nil Nil Nil Nal Nal Nil Nil Nil Nil Nil Nil NNiill | NNaitl Nor 1933 ROCK WOOL IN RELATION TO HEALTH 271 _ ~ TABLE Continued Tor Tins fa eNaLTOEs Fy flea es BER Lung | Ilver | Kidney Weight uses Armente a Agr 10 | 5 Hot vapor Concluded Concluded xhams grams| oF 05 ) 134 54 TGIF Lung 130 28 | Nil Liver 130 90 Nil Kidney 05 | Nil 5 | 29 30 88 29 73 = | Lung 2270 Nil Liver 85-55 85-55 Nil Kidney 28:00 } Ni | 88 05 || 22 29 70 25 Lung 20 Nil Liver 85 80 Ni Kidney 00 | Nit 17 | 22 25.00 22 Lung Liver Kidney 23 Nil || 68 60 Nil 23 | Nil 18 | 34 27.50 27.50 | 103 70 80 Lung 75 Nil || Liver 101 80 Nil Kidney 55 | Nil | Meteurs | Land Nil Nil Nil Nil Nil Nil Nil Nil Nil Nil Nil Nil Nil Nil Nil Nil Nil Nil Nil Nil Nil Nil Nil | Nil Nil Nil Nit Nil Nit Nil - 21 | 20 | 35 Dusting experiment 67 45 | Lung = 16 25 | Nil Liver 64 30 | Nil Kidney 40 | Nil 12 1.7 22 61 70 15.65 Lung 20 | Nil Liver 61 60 | Nil Kidney 14.45 | Nil 4 20 17.55 30 25 Lung 15 63 Nil { = || Liver 7670 7670 Nil Kidney 20 | Nil 8 [ 11 | 22 GO 16 70 Lung Liver Kidney 20 00 Nil | 57 35 Nil || 15 Nil 13 11 | 12.50 05 13 25 Lung 11.50 | Nil Liver 40 Nil || Kidney 11 65 Nil 1 5 35 35 Lung 90 {| Nil Liver 64.95 Nil || Kidney 21.10 Nil ee Nil Nit Nil Nil Nil Nil Nil Nil Nil Nil Nil Nil Nil Nil Nil Nil Nil Nil | Nil Nil Nil Ni Nil Nil Nil Nil Nil | Nil Nil Nil Nil Nil Nil Nil Nil Nik 01 501 0763 272 THE JOURNAL JOURNAL OF INDUSTRIAL HYGIENE 17 no 6 TABLE II Canlub I _ : WHY WHY on TIMEA TIMEA U8 RATA TESA rd | theme | | Lever ee awe Koken Wright and i Mercury end ~ ~ 13 Dusting experiment Concluded Concluded cae rama Lung Liver Kidney 172 172 ZZZ | 75 Nil || 05 ZZZ ZZZ 32 7 95 83 05 27 10 Lung 19 05 | Laver 85 Kidney 25 2 Ni Na Ni Nil Nil Nil Nil Nit Nil wool on animal life nothing whatever was evident that could be construed as injurions The animals either retained their weight or showed an increase in weight with the exception of slight traces of arsenic found were balanerd by the trace of arsenic in the nitric acid used in ashing MICROSCOPIC EXAMINATION OF TISSUES those subjected to air passed through heated rock wool and as has been noted above the slight average de- crease in weight particularly during the last 3 weeks is probably largely owing to the trying living conditions of temperature and Innuidity to which they subjected At the time they were chloroformed the animals looked healthy and macroscopic macroscopic inspection of their times on removal showed noth- ing unusual After chloroforming the cats their tissues were weighed at once before and Microscopic sections were prepared from the lungs kidneys and liver of each cat used in these experiments and from four normal control cats In the experimental animals the tissues were all fixed in Zenker's fluid embedded in paraffin and the sertions were stained with cosin and methylene blue Tis- sues from the control cats were fixed in Zenker's fluid and also in 10 per cent formaldehyde and paraffin sections sections were stained with methylene blue and hematoxylin and eosin after removal of pieces for microscopie examination and the remantler ana- lyzed chemically for arsenic mercury and lead chemicaly For this purpose the tissues were wet ashed by means of nitric acid in order to prevent any possible loss by volatilization of arsenic and mer- cury The data thus secured ure given in Table 2. It will be noted that the results are wholly negative No for- eigu metals of chemical significance were present in the tissues The very Cold Vapor Experiment Microscopic examination of the lungs liver and kidneys showed no constant changes from the normal The lungs from 5 of the 8 cats used in this experiment showed varying de- grees of congestion In the three uni- mals Nos 23 and 14 in which con- gestion was most marked there were also slight to moderate amounts of hemorrhage in the pulmonary alveoli Nov. 1935 ROCK WOOL IN RELATION TO HEALTH 273 The bronchi and bronchioles of all animals contained small amounts of a staining coagulum that had the histological appearance of mucus In three cats the larger bronchi contained considerably larger amounts of this material than was observed in sections from the control animals Slightly ex- cessive amounts of desquamated epi- thelium and cellular d^'bris were also present in both large and small bronchi specimens Occasional groups of mononuclear phagocytes were observed in the smaller bronchi and bronchioles of all animals Although many of these cells contained very fine dark brown or black dust particles it was only in two animals that rare refractile particles of silicate could be detected Slight emphysema was ob- served in most animals and in three of the eight cats there were small amounts of peribronchial inflammatory cell in- filtration These abnormalities were also observed in the control animals Sections of the kidneys and livers lungs from two cats showed slight traces of connective tissue increase in scattered areas The most extensive of these lesions was located in the periphery of the lung beneath a moderately thickened pleura The entire area was infiltrated with mod- erate numbers of lymphocytes niononuclear leucocytes and occasional poly- morphonuclear leucocytes In the re- maining areas there were no signs of active inflammation No particles of silicate were detected in any of these areas or in the surrounding lung tissue and there was no evidence of associated foreign body reaction These areas were interpreted as healed or healing inflammatory lesions prob- ably initiated by pulmonary infection Occasional bronchioles contained small groups of mononuclear phagocytes which contained small amounts of dark brown or black pigment Silicate particles however were observed in only one animal In this instance a rare particle was found after pro- showed no abnormalities that were not observed in the control cats longed search Sections from the kidneys showed Hot Vapor Experiment no significant abnormality Sections from the livers revealed Sections of the lungs of these ani- mals were practically identical in histological appearance to those in Group I. Excessive mucus desquamated epi- thelium and cellular d^'bris were ob- served in the large and small bronchi of no lesions except in Cat 5. In this animal there was a moderate amount of chronic periportal inflammation throughout the organ The liver cells however were well preserved and there was no evidence of bile stasis two cats The lungs of two animals showed recent hemorrhage into pul- Dusting Experiment monary alveoli In sections from one The most significant difference in of these animals and in sections from the lungs of this group of cats as two other cats there was also fresh compared with those already de- blood within large and small bronchi indicating that a terminal aspiration of blood was the probable method of spread to the alveolar spaces The scribed was the presence of large numbers of refractile particles of silicate in the small bronchi bronchioles and alveolar ducts of all animals ac+me 01 501 0764 274 THE JOURNAL OF INDUSTRIAL HYGIENE 17 no 6 Smaller amounts of this particulate SUMMARY OF MICROSCOPICAL matter were observed in the alveolar EXAMINATION spaces and interstitial tissues Re- gardless of its location much of this foreign material was contained in phagocytic cells Many of the small bronchial passages were filled with clumps of macrophages cach contain- ing large numbers of varying sized particles of silicate in addition to the fine durk pigment observed in + cats from the other experimental groups With the exception of the presence of numerous particles of silicate the lungs of five of the eight cats showed no abnormalities not present in the previous groups of animals In the three remaining cats there were vary- No pathological change that could be attributed to the experimental environment was observed in the liver and kidneys of any animal The renal epithelium of the proximal con- voluted tubules of 11 cats five from Group I four from Group II and two from Group III showed slight to moderate degrees of vacuolization Because 2 of the 4 control cats showed equal or greater amounts of vacuoliza- tion and because there were no accom- panying signs of retrograde changes in the tubules and no glomerular lesions this finding was not considered ing numbers of small circumscribed lesions that consisted for the most part of dense accumulations of large oval and elongated mononuclear cells lymphocytes cosinophiles and scat tered polymorphonuclear leucocytes The alveolar walls at the periphery of some of these lesions were moderately thickened and infiltrated with mono- nuclear and polynuclear inflammatory cells Siliente particles could be found readily in the majority of these lesions Four of the cats showed a recent and probably terminal extravasation of blood into the bronchi and pulmonary alveoli Excessive mucous secretion and an increased desquamation of bronchial epithelium were observed in two cats These abnormalities how- important Examination of the lungs from cats in Groups I and II revealed no constant changes that were considered significant The slight to moderate excess secretion of mucus in the bronchi and bronchioles and the increased epithelial desquamation which were observed in few cats were not accom- panied by any evidence of inflamma- tion of the bronchial walls or peri- bronchial tissue Hemorrhage into the lungs was ob- served in a few cats from all experi- mental groups and in one of the four normal control cats The microscopic appearances clearly indicated that this extravasation of blood had oc- curred as a terminal event probably ever did not differ from those ob- served in the other experimental groups Histological examination of the kidneys and livers showed no noteworthy abnormality during chloroformization Examination of the lungs of cats which had been subjected to the ex- cessive dusting described earlier in the paper revealed that large amounts of silicate particles had been inhaled Nov. 1955 ROCK WOOL IN RELATION TO HEALTH 275 and retained in the smaller air passages and lung tissues In 3 of the 8 cats from this group there were varying numbers of small cellular lesions in which silicate particles could be de- tected Except for the presence of silicate particles the remaining 5 cats revealed no abnormalities that were not present in animals from the other experimental groups The absence of spread inflammatory changes in the lungs of all of these animals where silicate particles were in in- timate contact with the tissues sug- gests that no highly irritating sub- stance was present SPECTROGRAPHIC EXAMINATION In addition to the chemical analyses an aliquot portion of the ash of each tissue was examined spectrographically by means of a Hilger quartz spectrograph with the following results Arsenic most sensitive line for arsenic is 2319.8 It can be seen only very faintly if at all in any of the tissues Mercury apparently is not present in any tissue Loud The typical lead line is extremely faint in all cases with the exception of cat kidney No. 5. In this case other lead lines can be found readily to confirm the first line The other tissues of this eat show a very faint no lead line The lead in the kidney of this cut is doubtless due to some previous expositre otherwise some other of the 23 cats subjected to similar conditions would have exhibited similar effects Thallium is absent Cadmium is very faintly pres- ent in most cases No certain indi- cation of Antimony is given owing to the presence of iron and traces of silicon The above metals representing those commonly met with to which may be ascribed any toxic significance are so faintly marked in general that they may be considered of quite negligible importance Indeed there is no reason to consider them of hygienic significance since these metals when present in the original rock wool are present in spectrographic traces only and furthermore are in the form of silicates and are therefore inert SUMMARY The chemical data thus obtained entirely deny the existence of any hygienic hazard in connection with contact with commercial rock wool of the type investigated The histological examination of the lungs liver and kidneys revealed no constant or significant pathological changes In the dusted cats there was evidence of inhalation of considerable quantities of silicate and the accompanying changes in the lungs were those which one might expect such foreign matter to produce 01 501 0765 plehee. Tye tzhe t pe nee aPeane) TFs, RE NOKS ma *: asad HAZRDS OF COMPETIVw rane we PRODUCTS