Document J3O0an32bGmRLK2xo0rLywn1Z

MATERIAL SAFETY DATA SHEET PRODUCT transport-plus 7205 liquid NALCO Emergency Telephone Number Medical (708) 920-1510(24 hours) Cr S 5 2 3 SECTION 1 PRODUCT IDENTIFICATION on^ I'Sooln TRADE NAME: TRANSPORT-PLUS 7205 LIQUID DESCRIPTION: An aqueous solution of a polycarboxylic acid NFPA 704M/HMIS RATING 1/1 HEALTH 0/0 FLAMMABILITY 0/0 REACTIVITY 0=lnsignificant l=Slight 2=Moderate 3=High 4Extreme * * 0 OTHER * SECTION 2 HAZARDOUS INGREDIENTS Our hazard evaluation of the ingredient(s) under OSHA's Hazard Communication Rule, 29 CFR 1910.1200 has found none of the ingredient(s) hazardous. SECTION 3 PRECAUTIONARY LABEL INFORMATION ft * CAUTION: May cause irritation to skin and eyes. Avoid contact with skin, eyes and clothing. Do not take internally. Empty containers may contain residual product. Do not reuse container unless * properly reconditioned. * SECTION 4 FIRST AID INFORMATION EYES: SKIN: INGESTION: INHALATION: Flush with water for 15 minutes. Call a physician. Wash thoroughly with soap and rinse with water. Call a physician. Do not induce vomiting. Give water. Call a physician. Remove to fresh air. Treat symptoms. Call a physician. NOTE TO PHYSICIAN: No specific antidote is known. Based on the individual reactions of the patient, the physician's judgment should be used to control symptoms and clinical condition. CAUTION: If unconscious, having trouble breathing or in convulsions, do not induce vomiting or give water. * * * * * ft * * ft * * SECTION 5 HEALTH EFFECTS INFORMATION PRIMARY R0UTECS) OF EXPOSURE: Eye, Skin EYE CONTACT; SKIN CONTACT: May cause irritation with prolonged contact. May cause irritation with prolonged contact. SYMPTOMS OF EXPOSURE: A review of available data does not identify any symptoms from exposure. PAGE 1 OF 6 SAL 000009881 v'Al.CO CHEMICAL COMPANY ONE NALCO CEN'EP NAPERVILLE. ILLINOIS 60563-1199 y* NALCQ G S5 23 MATERIAL SAFETY DATA SHEET PRODUCT TRANSPORT-PLUS 7205 LIQUID Emergency Telephone Number Medical (708) 920-1510 (24 hours) SECTION 5 HEALTH EFFECTS INFORMATION ( CONTINUED ) AGGRAVATION OF EXISTING CONDITIONS: A review of available data does not identify any worsening of existing conditions. * SECTION 6 TOXICOLOGY INFORMATION TOXICITY STUDIES: No toxicity studies have been conducted on this product. * SECTION 7 PHYSICAL AND CHEMICAL PROPERTIES COLOR: Clear yellow DENSITY: SPECIFIC GRAVITY: pH (NEAT) = VISCOSITY: FREEZE POINT: BOILING POINT: FLASH POINT: FORM: Liquid 8.7 lbs/gal. 1.05 @ 73 Degrees F 9.9 7 cps @ 73 Degrees F 31 Degrees F 212 Degrees F @ 760 mm Hg Greater than 200 Degrees F (PMCC) ASTM D-1298 ASTM E-70 ASTM D-2983 ASTM D-1177 ASTM D-86 ASTM D-93 NOTE: These physical properties are typical values for this product. * ** * * * * SECTION 8 FIRE AND EXPLOSION INFORMATION FLASH POINT: Greater than 200 Degrees F (PMCC) ASTM D-93 EXTINGUISHING MEDIA: Not applicable * * SECTION 9 REACTIVITY INFORMATION INCOMPATIBILITY: None known SECTION 10 PERSONAL PROTECTION EQUIPMENT RESPIRATORY PROTECTION: Respiratory protection is not normally needed since the volatility and toxicity are low. For large spills, entry into large tanks, vessels or enclosed small spaces with inadequate ventilation, a pressure-demand, self-contained breathing apparatus is recommended. VENTILATION: General ventilation is recommended. PROTECTIVE EQUIPMENT: Use impermeable gloves and chemical splash goggles when attaching feeding equipment, doing maintenance or handling product. PAGE 2 OF 6 sAL 000009882 * * * * * * * * * * * * Nfl LCD CHEMICAL COMPANY OWE NALCO CENTER WAPEOVILLE. ILLINOIS 60563-1 1SS MATERIAL SAFETY DATA SHEET NALCO PRODUCT TRANSPORT-PLUS 7205 LIQUID Emergency Telephone Number Medical (708) 920-1510 (24 hours) S5 23 SECTION 10 PERSONAL PROTECTION EQUIPMENT ( CONTINUED ) If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse. * SECTION 11 SPILL AND DISPOSAL INFORMATION IN CASE OF TRANSPORTATION ACCIDENTS, CALL THE FOLLOWING 24-HOUR TELEPHONE NUMBER (708-920-1510) SPILL CONTROL AND RECOVERY: Small liquid spills: Contain with absorbent material, such as clay, soil or any commercially available absorbent. Shovel reclaimed liquid and absorbent into recovery or salvage drums for disposal. Refer to CERCLA in Section 14. Large liquid spills: Dike to prevent further movement and reclaim into recovery or salvage drums or tank truck for disposal. Refer to CERCLA in Section 14. DISPOSAL: If this product becomes a waste, it does not meet the criteria of a hazardous waste as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261, since it does not have the characteristics of Subpart C, nor is it listed under Subpart D. As a non-hazardous liquid waste, it should be solidified with stabilizing agents (such as sand, fly ash, or cement) so that no free liquid remains before disposal to an industrial waste landfill. A non-hazardous liquid waste can also be deep-well injected in accordance with local, state, and federal regulations. * * * * * * * * * * SECTION 12 ENVIRONMENTAL INFORMATION If released into the environment, see CERCLA in Section 14. SECTION 13 TRANSPORTATION INFORMATION * DOT PROPER SHIPPING NAME/HAZARD CODE - PRODUCT IS NOT REGULATED DURING 1TRANSPORTATION SECTION 14 REGULATORY INFORMATION The following regulations apply to this product. FEDERAL REGULATIONS: SAL 000009883 it . PAGE 3 OF 6 P'4 M.CO CHEMICAL COMPANY ONE NALCO CENTEP N'APERVILLE. ILLINOIS 60563-11 SS MATERIAL SAFETY DATA SHEET NALCO G S 5 23 PRODUCT TRANSPORT-PLUS 7205 LIQUID Emergency Telephone Number Medical (708) 920-1510 (24 hours) SECTION 14 REGULATORY INFORMATION ( CONTINUED ) OSHA HAZARD COMMUNICATION RULE, 29 CFR 1910.1200: Based on our hazard evaluation, this product is not hazardous. CERCLA/SUPERFUND, 40 CFR 117, 302: Notification of spills of this product is not required. SARA/SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE III) - SECTIONS 302, 311, 312 AND 313: SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355): This product does not contain ingredients listed in Appendix A and B as an Extremely Hazardous Substance. SECTIONS 311 and 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370): Our hazard evaluation has found that this product is not hazardous under 29 CFR 1910.1200. SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372): This product does not contain ingredients (at a level of 1% or greater) on the List of Toxic Chemicals. * W * * * * * * * * * * * it * TOXIC SUBSTANCES CONTROL ACT (TSCA): The chemical ingredients in this product are on the 8(b) Inventory List (40 CFR 710). FOOD AND DRUG ADMINISTRATION (FDA): Federal Food, Drug and Cosmetic Act: When use situations necessitate compliance with FDA regulations, this product is acceptable under 21 CFR 173.310 Boiler Water Additives. U. S. DEPARTMENT OF AGRICULTURE (USDA) : USDA Inspection and Grading Programs - Food Safety and Inspection Service: This product is authorized by USDA for use in federally inspected meat and poultry plants. Authorized use is under category G6. RESOURCE CONSERVATION AND RECOVERY ACT (RCRA) , 40 CFR 261 SUBPART C & D: Consult Section 11 for RCRA classification. FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15/ formerly Sec. 307, 40 CFR 116/formerly Sec. 311: None of the ingredients are specifically listed. * n it * * * * * * * * * * CLEAN AIR ACT, 40 CFR 60, SECTION 111, 40 CFR 61, SECTION 112: This product does not contain ingredients covered by the Clean Air Act. v PAGE 4 OF 6 N NALCO MATERIAL SAFETY DATA SHEET PRODUCT TRANSPORT-PLUS 7205 LIQUID Emergency Telephone Number Medical (708) 920-1510(24 hours) _ (f S 5 2 3 SECTION 14 REGULATORY INFORMATION CONTINUED ) STATE REGULATIONS: CALIFORNIA PROPOSITION 65: None of the chemicals on the current Proposition 65 list are known to be present in this product. MICHIGAN CRITICAL MATERIALS: This product does not contain ingredients listed on the Michigan Critical Materials Register. STATE RIGHT TO KNOW LAWS: The following ingredient(s) are disclosed for compliance with State Right To Know Laws: Sodium polymethyacrylate Water 25086-62-8 7732-18-5 * SECTION 15 A DDITIONAL INFORMATION None * SECTION 16 USER'S RESPONSIBILITY This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to ensure safe workplace operations. Please consult your local sales representative for any further information. SECTION 17 BIBLIOGRAPHY ANNUAL REPORT ON CARCINOGENS, U.S. Department of Health and Human Services, Public Health Service, PB 33-135855, 1983. CASARETT AND DOULL'S TOXICOLOGY, THE BASIC SCIENCE OF POISONS, Doull, J., Klaassen, C. D., and Admur, M. 0., eds., Macmillian Publishing Company, Inc., N. Y., 2nd edition, 1980. CHEMICAL HAZARDS OF THE WORKPLACE, Proctor, N. H.( and Hughes, J. P., eds., J. P. Lipincott Company, N.Y., 1981. PAGE 5 OF 6 SAL 000009885 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1153 MATERIAL SAFETY DATA SHEET NALCO G S 5 23 SECTION 17 BIBLIOGRAPHY PRODUCT TRANSPORT-PLUS 7205 LIQUID Emergency Telephone Number Medical (708) 920-1510 (24 hours) ( CONTINUED ) DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS, Sax, N. Irving, ed., Van Nostrand Reinhold Company, N.Y., 6th edition, 1984. IARC MONOGRAPHS ON THE EVALUATION OF THE CARCINOGENIC RISK OF CHEMICALS TO MAN, Geneva: World Health Organization, International Agency for Research on Cancer, 1972-1977. PATTY'S INDUSTRIAL HYGIENE AND TOXICOLOGY, Clayton, G. D., Clayton, F. E., eds., John Wiley and Sons, N. Y., 3rd edition, Vol. 2 A-C, 1981. REGISTRY OF TOXIC EFFECTS ON CHEMICAL SUBSTANCES, U.S. Department of Health and Human Services, Public Health Service, Center for Disease Control, National Institute for Occupational Safety and Health, 1983 supplement of 1981-1982 edition, Vol. 1-3, OH, 1984. Title 29 Code of Federal Regulations Part 1910, Subpart 2, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA). THRESHOLD LIMIT VALUES FOR CHEMICAL SUBSTANCES AND PHYSICAL AGENTS IN THE WORKROOM ENVIRONMENT WITH INTENDED CHANGES, American Conference of Governmental Industrial Hygienists, OH. Information on this MSDS has changed. The changes are indicated by asterisks on the right side of only the changed sections. This is an updated MSDS as required by OHSA's Hazard Communication Rule 29 CFR 1910.1200. PREPARED BY: Ricky A. Stackhouse PhD., Toxicologist DATE CHANGED: 10/17/90 DATE PRINTED: 11/22/90 PAGE 6 OF 6 sM_ 000009886 DATE: 12/12/00 INDEXi 1 1 9O34502B3 ACCT ! 169257-01 CAT NO) 1SQ9I MEncun* MERCURY * MERCURY** MATERIAL SAFETY DATA SHEET PAGE I I PO NBR: 316-0KI2O3-8 PEL FISHER SCIENTIFIC CHEMICAL DIVISION 1 REAOENT LANE FAin LAWN NJ 07410 (201) 796-7100 EMERGENCY NUMBERS (20!) 796-7100 CHEMTREC ASSISTANCE: (BOO) 424-9300 THIS INFORMATION IS BEIIEVEO TO BE ACCURATE ANO REPRESENTS THE BEST INFORMATION CURRENTLY AVAILABLE TO US. HOWEVER. WE MAKE NO WARRANTY OF MFRCHANTABILJTY OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, WITH RESPECT TO SUCH INFORMATION, ANO WE ASSUME NO LIABILITY RESULTING PROM ITS USE. USERS SHOULO MAKE THEIR OWN INVESTIGATIONS TO DETERMINE THE SUITABILITY OP THE INFORMATION FOR THEIR PARTICULAR PURPOSES. SUDSTANCE IDENTIFICATION SUBSTANCE I *MERCURY** CAS-NUMBER 7439-97-6 TRADE NAMES/SYNONYMSl COLLOIDAL MERCURY) METALLIC MERCURY) NCI-CB0399: QUICK SILVER) INORGANIC MERCURY) RCRA U1S1| NA 2809) HYORARQVRUM) ELEMENTAL MERCURY) M- 139) M-1401 M-141) UN 2809) HOI ACC 14020 CHEMICAL FAMILY) METAL MOLECULAR FORMULAl HO MOLECULAR WEIGHTs 200.59 CEF1CLA HATINOS (SCALE 0-3)I HEALTH'S FtRE-O REACTIVITY-O PERSISTENCE'S NrpA RATINGS (SCALE 0-4): HEALTH-3 FIRE-0 REACTIV1TY*0 COMPONENTS ANO CONTAMINANTS COMPONENT; MERCURY CAS# 7439-97-6 PERCENT: TOO OTHER CONTAMINANTS: NONE EXPOSURE LIMITS: MERCURY. ALL FORMS EXCEPT ALKYL (AS HO): 0.05 M0/M3 03HA TWA (VAPOR)I 0.1 M0/M3 OSHA CEILINQ (SKIN) 0,05 MG/M3 ACGIH TWA (VAPOR)) 0.10 M0/M3 ACGIH TWA (ARYL A O.OS MG/M3 NIOSH RECOMMENDEO 10 HOUR TWA INORGANIC)-(SKIN) SUBJECT TO SARA SECTION 313 ANNUAL TOXIC CHEMICAL RELEASE REPORTINO SUBJECT TO CALIFORNIA PROPOSITION 65 CANCER AND/OR REPRODUCTIVE TOXICITY WARNINO AND RELEASE REQUIREMENTS- (JULY I, 1990) MERCURY) 1 POUNO CERCLA SECTION 103 REPORTABLE QUANTITY PHYSICAL DATA DESCRIPTION: ODORLESS, SILVERY LIQIUD WITH A METALIC LUSTER. BOILING POINTi 674 F (35? C) MELTING POINT: -38 F (-39 C) SPECIFIC GRAVITY: 13.5939 VAPOR PRESSURE: 0.002 MMHQ 9 25 C SOLUBILITY IN WATER: INSOLUBLE VAPOR DENSITY) 7.0 SOLVENT SOLUBILITY: SOLUBLE IN BOILING SULFURIC ACIO, NITRIC ACID. LIPIDS) INSOLUBLE IN ALCOHOL, ETHER. HYDROCHLORIC ACID, HVOROGEN BROMIDE, HYOROQEN 100IDE VISCOSITY: 1.55 CPS 9 20 C FIRE AND EXPLOSION DATA FIRE AND EXPLOSION HAZARD) NEGLIGIBLE FIRE HAZARD WHEN EXPOSED TO HEAT OR FLAME. F I REF IOH TINO MEDIA: ORY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR REGULAR FOAM 0990 EMERGENCY RESPONSE OUIOEBOOK, DOT P 5600.5). 000009BB1 s M- CM CP (\l S8SS9 GS583 DATE i INDEX 1 12/12/90 1 1 90345028:* ACCTl 169207-01 CAT NO I 15091 I'ACit : 2 PO NBRl 319-BK1Z03-9 REL 744 TOR LARGER FIRES, USE WATER SPRAY, FOO OR REGULAR FOAM (1990 EMERGENCY RESPONSE OUIOEBOOK, DOT P 5900.S). FIREFIGHTING: MOVE CONTAINER FROM FIRE AREA IF YOU CAN OO IT WITHOUT RISK. APPLY COOLING WATER TO SIDES OF CONTAINERS THAT ARE EXPOSED TO FLAMES UNTIL WELL AFTER FIRE IS OUT. STAY AWAY FROM ENOS OF TANKS 11990 EMERGENCY RESPONSE OUIOEBOOK. DOT P 5900.S, OUJ0E PAGE 60). USC AGENTS SUITABLE FOR TYPE OF FIRE; USE WATER IN FLOODING AMOUNTS AS A FOO. AVDIO BREATHING CORROSIVE ANP POISONOUS VAPORS. KEEP UPWIND. TRANSPORTATION DATA DEPARTMENT OF TRANSPORTATION HAZARD CLASSIFICATION 49 CFR 172.1011 ORM-B DEPARTMENT OF TRANSPORTATION LABELING REQUIREMENTS 49 CFR 172.101 AND SUBPART El NONE DEPARTMENT OF TRANSPORTATION PACKAOINO REQUIREMENTS) 49 CFR 173.960 EXCEPTIONS! NONE TOXICITY MERCURY: TOXICITY OATAi 150 UO/M3/46 DAYS 1NHALATION-WOMAN TCLOl 44,300 UG/M3/9 HOURS INHALATION-MAN TCLOl 29 MG/M3/30 HOURS INHALATION-RABBIT LCLOl 129 MO/KO/S HOURS CONTINUOUSLY SKIN-MAN TOLOj MUTAGENIC DATA (RTECS)j REPRODUCTIVE EFFECTS DATA (RTECS>| TUMORIOENIC DATA 1RTECS). CARCINOGEN STATUS! NONE. LOCAL EFFECTS: IRRITANT- MUCOUS MEMBRANES. ACUTE TOXICITY LEVEL! INSUFFICIENT OATA. TAROET EFFECTS: SENSITIZER- PULMONARY, OERMALl NEUROTOXIN: NEPHROTOXIN; POISONING MAY ALSO AFFECT THE RESPIRATORY AND GASTROINTESTINAL SYSTEMS. AT INCREASEO RISK FROM EXPOSURE: PERSONS WITH CHRONIC RESPIRATORY DISEASE, NERVOUS SYSTEM OISOROERS AND NIONEY DISEASE. HEALTH EFFECTS AND FIRST AID INHALATION! MERCURYl IRRITANT/SENS ITJZER/NEUROTOXIN/NEPHROTOXIN. 29 MG/M3 IMMEDIATELY DANGEROUS TO LIFE OR HEALTH. ACUTE EXPOSURE- INHALATION OF HIGH LEVELS OF MERCURY VAPOR MAY CAUSE ALMOST IMMEDIATE DYSPNEA, COUGH, FEVER, NAUSEA, VOMITING, DIARRHEA, HEADACHE, STOMATITIS. SALIVATION, GINGIVITIS, A METALLIC TASTE, ANO CAR01AC ABNORMALITIES. RESPIRATORY IRRITATION MAY OCCUR WITH CHEST PAIN ANO TIGHTNESS. SYMPTOMS MAY RESOLVE OR MAY PROGRESS TO NECR0T1ZIN0 BRONCHIOLITIS, PNEUMONITIS, PULMONARY EDEMA, PNEUMOTHORAX, INTERSTITIAL FIBROSIS. AND DEATH. ACIDOSIS AND RENAL DAMAGE MAY ALSO OCCUR. ALLERGIC REACTIONS THAT MAY OCCUR IN PREVIOUSLY EXPOSEO PERSONS THCLUOE DERMATITIS, ENCEPHALITIS, AND DEATH. METAL FUME FEVER, AN INFLUENZA-LIKE ILLNESS, MAY OCCUR DUE TO THE INHALATION OF FRESHLY FORMED MCTAL OXIDE PARTICLES SIZEO BELOW 1.5 MICRONS ANO USUALLY BETWEEN 0.02-0.05 MICRONS. SYMPTOMS MAY BE DELAYED 4-12 HOURS ANO BEDIN WITH A SUDDEN ONSET OF THIRST, ANO A SWEET, METALLIC OR FOUL TASTE IN THE MOUTH. OTHER SYMPTOMS MAY iNCLUOE UPPER RESPIRATORY TRACT IRRITATION ACCOMPANIED BY COUGHING AND A ORVNESS OF THE MUCOUS MEMBRANES. LASSITUOE ANO A GENERALIZED FEELING OF MALAISE. FEVER, CHILLS. MUSCULAR PAIN, MILD TO SEVERE HEADACHE, NAUSEA, OCCASIONAL VOMITING, EXAQOERATEO MENTAL ACTIVITY, PROFUSE SWEATING. EXCESSIVE URINATION, DIARRHEA AND PROSTRATION MAY ALSO OCCUR. TOLERANCE TO FUMES DEVELOPS RAPIDLY, BUT IS QUICKLY L05T. ALL SYMPTOMS USUALLY SUBSIDE WITHIN 24-39 HOURS. CHRONIC EXPOSURE- INHALATION OF MERCURY VAPOR OVER A LONG PERIOD MAY CAUSE MERCURIAL ISM, WHICH IS CHARACTERIZED BY FINE TREMORS AND ERETHISM. TREMORS MAY AFFECT THE HANOS FIRST, BUT MAY ALSO BECOME EVIDENT IN THE FACE, ARMS, ANO LEGS. ERETHISM MAY BE MANIFESTED BY ABNORMAL SHYNESS, BLUSHING. SELF'CONSCIOUSNESS, DEPRESSION OR DESPONDENCY, RESENTMENT OF CRITICISM. IRRITABILITY OR EXCITABILITY, HEADACHE, FATIGUE, ANO INSOMNIA. IN SEVERE CASES. HALLUCINATIONS, LOSS OF MEMORY, AND MENTAL DETERIORATION MAY OCCUR. IN Hi_riA,_ I N> u<-V lML N I M tit iNlULnltU ill , ..u 111 fiv, 1A , ALtiuMiNUH ENZYMUIIIA. AND ANURIA. OTHER EFFECTS MAY INCLUDE SALIVATION, GINGIVITIS, STOMATITIS, LOOSCN1NO OF THE TEETH, BLUE LINES ON THE GUMS. DIARRHEA. WEIGHT LOSS, ANOREXIA, SPEECH AND SENSORY DISORDERS, UNSTEADY OAIT, CHRONIC PNEUMONITIS AND MILO ANEMIA. REPEATED EXPOSURE TO MEACURY AND ITS COMPOUNDS MAY RESULT IN SENSITIZATION. INTRAUTERINE EXPOSURE MAY RESULT IN TREMORS AND INVOLUNTARY MOVEMENTS IN THE INFANTS. MERCURY IS EXCRETED IN BREAST MILK. PATERNAL REPRODUCTIVE EFFECTS AND EFFECTS ON FERTILITY HAVE BEEN REPORTEO IN MALE RATS FOLLOWINO REPEATED INHALATION EXPOSURES. FIRST AID- REMOVE FROM EXPOSURE AREA TO FRESH AIR IMMEDIATELY. IF BREATHING HAS STOPPFD, GIVE ARTIFICIAL RESPIRATION. MAINTAIN AIRWAY ANO BLOOD PRESSURE ANO ADMINISTER OXYGEN IF AVAILABLE, KEEP AFFECTED PERSON WARM ANO AT REST. TREAT SYMPTOMATICALLY AND SUPPORTIVELV. ADMINISTRATION OF OXYOEN I 0000 98a. DINAOTEEK; i 12/12/90 1 t U034507B3 ACCTi 169257-01 CAT NOl I6091 PAGE : 3 PO NBRi 316-BK 1 201-6 REL 744 SHOULD lie I'ERFORMFO BV QIJAMFIEO PERSONNEL. 0E1 MEOICAL ATTENTION IMMEDIATELY . SKIN CONTACT! MERCURY SENS ITIZER/NEUHO T OXIN /NEP MOO TOXIN. ACUTE EXPOSURE- OtRECT CONTACT WITH LIQUIO MAY CAUSE IRRITATION AND REDNESS. SMALL AMOUNTS OT MERCURY MAY BE ABSORBEO THROUGH INTACT SKIN. ALLEROIC REACTIONS THAT MAY OCCUR IN PREVIOUSLY EXPOSEO PERSONS INCLUDE DERMATITIS, ENCEPHALITIS, AND DEATH. SUBCUTANEOUS INTRODUCTION, FROM HANDLING BROKEN THERMOMETERS, MAY RESULT IN LOCAL INFLAMMATION, GRANULOMATOUS SKIN REACTIONS, ANO SLIGHT SIGNS OF MERCURY POISONINO INCLUDING DIGESTIVE DISORDERS, METALLIC TASTE IN THE MOUTH, ANO NEUROPSYCMIC DISORDERS. CHRONIC EXPOSURE- PROLONGED OR REPEATEO EXPOSURE MAY RESULT IN DERMAL SENSITIZATION AND SYSTEMIC EFFECTS AS DETAILED IN CHRONIC INHALATION EXPOSURE. FIRST AIO- REMOVE CONTAMINATED CLOTHING ANO SHOES IMMEDIATELY. WASH AFFECTED AREA WITH SOAP OR MILD DETERGENT ANO LARGE AMOUNTS OF WATER UNTIL NO EVIDENCE OF CHEMICAL REMAINS (APPROXIMATELY 15-20 MINUTES>. OET MEDICAL ATTENTION IMMEDIATELY. EYE CONTACT! MERCURY I ACUTE EXPOSURE- OIRECT CONTACT WITH LIQUIO MAY CAUSE IRRITATION AND REDNESS. ANIMAL STU0IE3 INDICATE 0IFFU910N AND ABSORPTION OF MERCURY INTO THE TISSUES OF THE EYE MAY OCCUR. NO CLINICAL SIGNS OF CONJUNCTIVITIS OR INFLAMMATION OCCURRED. CHRONIC EXPOSURE- MERCUflY EXPOSURE FROM INHALATION, INGESTION, OR SKIN CONTACT MAY BE INDICATED BV MERCURIALENTIS, DISCOLORATION OF THE CRYSTALLINE LENS, ON SLIT LAMP EXAMINATION OF THE EYE. FIRST AID- WASH EYES IMMEDIATELY WITH LARGE AMOUNTS OF WATER OR NORMAL SALINE, OCCASIONALLY LIFTING UPPER AND LOWER LIDS, UNTIL NO EVIDENCE OF CHEMICAL REMAINS (APPROXIMATELY 15-20 MINUTES1. GET MEDICAL ATTENTION IMMEDIATELY. INGESTIONi MERCURYi NEUROTOXIN/NEPHROT OXIN. ACUTE EXPOSURE- MAY CAUSE BURNING OF THE MOUTH ANO THROAT, THIRST, NAUSEA ANO VOMITING. METALLIC MERCURY IS NOT USUALLY ABSORBEO SUFFICIENTLY FROM THE GASTROINTESTINAL TRACT TO INDUCE AN ACUTE TOXIC RESPONSE. RARELY, A LARGE SINGLE DOSE MAY RESULT IN SIGNS ANO SYMPTOMS OF CHRONIC INHALATION IF SUFFICIENT AMOUNTS OF MERCURY ARE RETAINCO IN THE BODY. CHRONIC EXPOSURE- REPEATED INGESTION OF SMALL AMOUNTS OF MERCURY MAY RESULT IN THE ABSORPTION OF SUFFICIENT AMOUNTS TO PRODUCE TOXIC EFFECTS AS OCTAILED IN CHRONIC INHALATION EXPOSURE. FIRST AID- REMOVE BY GASTRIC LAVAGE OR EMESIS. MAINTAIN BLOOD PRESSURE AND AIRWAY. GIVE OXYGEN IF RESPIRATION IS DEPRESSED. DO NOT PERFORM GASTRIC LAVAGE OR EMESIS IF VICTIM IS UNCONSCIOUS. GET MEDICAL ATTENTION IMMEDIATELY (DREISBACH. HANOBDOK OF POISONING, t1TH ED.I. ADMINISTRATION OF GASTRIC LAVAGE OR OXYGEN SHOULD BE PERFORMED BY QUALIFIED MEDICAL PERSONNEL. ANTIDOTE: THE FOLLOWING ANTIDOTE HAS BEEN RECOMMENOCO. HOWEVER, THE DECISION AS TO WHETHER THE SEVERITY OF POISONING REQUIRES ADMINISTRATION OF ANY ANTIDOTE ANO ACTUAL OOSE REOUIREO SHOULD BE MADE BV QUALIFIED MEOICAL PERSONNEL. MERCURY POISONING! GIVE OIMERCAPROL, 3 MO/KG (OR 0.3 ML/10 KOI EVERY 4 HOURS FOR THE FIRST 2 DAYS ANO THEN 2 MG/KG EVERY 12 HOURS FOR A TOTAL OF 10 DAYS IF NECESSARY. DIMERCAPROL IS AVAILABLE AS A 10X SOLUTION IN OIL FOR INTRAMUSCULAR ADMINISTRATION. HEMOOIALYSIS WILL SPEED THE REMOVAL OF THE MERCURY-DIMERCAPROL COMPLEX. PENICILLAMINE IS ALSO EFFECTIVE, OIVE UP TO 100 MG/KQ/DAY (MAXIMUM 1 GR/DAY) DIVIDEO INTO 4 DOSES FOR NO LONGER THAN 1 WEEK. IF A LONGER ADMINISTRATION PERIOD IS WARRANTED, DOSAGE SHOULD NOT EXCEEO 40 MG/KG/DAV. GIVE THE DRUO ORALLY HALF AN HOUR BEFORE MEALS. A CHELATING AGENT SHOULD BE BE C0NTINU6O UNTIL THE URINE-MERCURY LEVEL FALLS BELOW 50 UQ/24 HOURS {DREISBACH, HANDBOOK OF POISONING, I2TH ED.). ANTIDOTE SHOULO BE AOMINISTEREO BY QUALIFIED MEDICAL PERSONNEL. r REACTIVITY REACTIVITY! STABLE UNOER NORMAL TEMPERATURES ANO PRESSURES. INCOMPAT TB!LITIF5i MERCURY! ACETYLENE! FORMATION OF EXPLOSIVE COMPOUND. ACF.TYLINIC COMPOUNDS! FORMATION OF EXPLOSIVE COMPOUND. ALUMINUM: CORRODES. AMINES: MAY FORM EXPLOSIVE COMPOUNDS. AMMONIA MOISTURE! FORMS EXPLOSIVE COMPOUND. BORON 01IODPHOSPH1DEl IGNITES IN CONTACT WITH MERCURY VAPORS. BROMINE: VIOLENT REACTION. G85 83 000009889 SAL 88SS OATE! 12/.-./90 INOEK: 11903450283 ACCT: 169257-01 CAT NOl 15091 PO NBR: 3 1 6-BK1203-8 REL 744 3 - JROMOPRUi't ht : EXPLOSION HAZARO, CALCIUM: AMAlOAM FORMATION 9 390 C 15 VIOLENT. CHLORINE: IGNITES 9 200-300 C. CHLORINE DIOXIOE: EXPLOOES. COPPER (AND ALLOYS>i MAY BE ATTACKED. ETHYLENE OXIOE + TRACES OF ACETYLENE: MAY FORM EXPLOSIVE ACETYLIOES. LITHIUM: AMALOAM FORMATION IS VIOLENTLY EXOTHERMIC AND MAY BE EXPLOSIVE. METHYL AZIDE: PRODUCES SHOCK SENSITIVE MIXTURE. METWYL.SILANE + OXYQENs PRODUCES SHOCK SENSITIVE MIXTURE. NITRIC ACID ALCOHOLS; F0F1MS FULMINATES CAPABLE OF OETONATION. OXALIC ACID: FORMS SHOCK SENSITIVE COMPOUNO. OXIOANTSl VIOLENT REACTION. PERWimvilC ACID! EXPLOSIVE REACTION. POTASSIUM: AMALOAM FORMATION IS VIGOROUSLY EXOTHERMIC AND MAY BE EXPLOSIVE. RUB10IUM: VIOLENT EXOTHERMIC REACTION. SILVER PERCHLORATE * 3-HEXYNEl EXPLODES. SILVER PERCHLORATE 2-PENTYHE1 EXPLODES. SODIUM: AMALOAM FORMATION IS VIOLENTLV EXOTHERMIC. SODIUM CARBIDE: VIGOROUS REACTION. SULFURIC ACID (HOT): REACTS. TETRACARBONYLNICKEL * OXYGEN! PRODUCES SHOCK SENSITIVE MIXTURE. DECOMPOSITION: THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE HIGHLY TOXIC VAPORS OF MERCURY AND MERCURY OXIDES. POLYMERIZATION: HAZARDOUS POLYMERIZATION HAS NOT BEEN REPORTEO TO OCCUR UNOER NORMAL TEMPERATURES ANO PRESSURES. STORAGE ANO DISPOSAL OBSERVE ALL FEOERAL, STATE AND LOCAL REGULATIONS WHEN STORING OR DISPOSING OF THIS SUBSTAHCE. FOR ASSISTANCE. CONTACT THE OISTRICT DIRECTOR OF THE ENVIRONMENTAL PROTECTION AOENCY. STORAOE** STORE AWAY FROM INCOMPATIBLE SUBSTANCES. DISPOSAL** DISPOSAL MUST BE IN ACCORDANCE WITH STANDARDS APPLICABLE TO OENERATORS OF HAZARDOUS WASTE, 40CFR 262. EPA HAZARDOUS WASTE NUMBER UfSI. MERCURY - REOULATORY LEVEL: 0.2 MO/L MATERIALS WHICH CONTAIN THE ABOVE SUBSTANCE AT OR ABOVE THE REGULATORY LEVEL MEET THE EPA CHARACTERISTIC OF TOXICITY. ANO MUST BE DISPOSED OP IN ACCORDANCE WITH 40 CFR PART 2S2. EPA HAZARDOUS WASTE NUMBER 0009. CONDITIONS TO AVOIO MAY BURN BUT OOES NOT IGNITE READILY. FLAMMABLE. POISONOUS GASES MAY ACCUMULATE IN TANKS ANO HOPPER CARS. MAY IONITE COMBUSTIBLES (WOOD. PAPER, OIL. ETC.). SPILL ANO LEAK PROCEDURES WATER SPILL: THE CALIFORNIA SAFE DRINKINO WATER ANO TOXIC ENFORCEMENT ACT OF 1988 (PROPOSITION 651 PROHIBITS CONTAMINATING ANY KNOWN SOURCE OF ORINKING WATER WITH SUBSTANCES KNOWN TO CAUSE CANCER AND/OR REPRODUCTIVE TOXICITY. OCCUPATIONAL SPILLl DO NOT TOUCH SPILLEO MATERIAL. STOP LEAK IF YOU CAN DO IT WITHOUT RISK. FOR SMALL SPILLS, TAKE UP WITH SAND OR OTHER ABSORBENT MATERIAL ANO PLACE INTO CONTAINERS FOR LATER DISPOSAL. A MERCURY SPILL KIT MAY ALSO BE USED FOR SMALL SPILLS IN THE WORKPLACE. FOR LARGER SPILLS, OIKE FAR AHEAD OF SPILL FOR LATER OISPOSAL. KEEP UNNECESSARY PEOPLE AWAY. ISOLATE HAZARO AREA ANO DENY ENTRY. ^ SUPERFUND AMENDMENTS ANO REAUTHOR IZATION ACT (SARA1' SECTION 304 REQUIRE. THAT A RELEASE EQUAL TO OR GREATER THAN THE REPORTABLE QUANTITY FOR THIS SUBSTANCE BE IMMEDIATELY REPORTEO TO THE LOCAL EMERGENCY PLANNINO COMMITTEE AND THE STATE EMERGENCY RESPONSE COMMISSION <40 CFR 355.40). IF THE RELEASE OF THIS SUBSTANCE IS REPORTABLE UNOER CERCLA SECTION 103, THE NATIONAL RESPONSE CENTER MUST BE NOTIFIED IMMEDIATELY AT (600) 424-8602 OR 42021 426-2*75 IN THE METROPOLITAN WASHINGTON. D.C. AREA (40 CFR 302.6). PROTECTIVE EQUIPMENT VENTILATION: PROVIOE LOCAL EXHAUST OR PROCESS ENCLOSURE VENTILATION TO MEET PUBLISHED I 000009B90 SAL I DATEi INDEX I 12/12/90 '1903490283 ACCTj 169257-01 CAT NO I 1 5091 PAGE! 5 PO NBA: 316-8K1203-8 PEL 744 EXPOSURE LIMITS. RESPIRATOR I THE POL LOWI NO UESPIRATOHS AND MAXIMUM USE CONCENTRATIONS ARE RECOMMENOAT1ON5 BY THE U.S. DEPARTMENT OP HEALTH AND HUMAN SERVICES, NIOSH POCKET GUIOE TO CHEMICAL HAZARDS; NIOSH CRITERIA DOCUMENTS OR BY THE U.S. DEPARTMENT OF LABOR, 29 CFR 1910 SUBPART Z. THE SPECIFIC RESPIRATOR SELECTED MUST BE BASEO ON CONTAMINATION LEVELS FOUND IN THE WORK PLACE, MUST NOT EXCEED THE WORKING LIMITS OF THE RESPIRATOR AND BE JOINTLY APPROVED BY THE NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY ANO HEALTH ANO THE MINE SAFETY AND HEALTH ADMINISTRATION <NIOSH-MSHA). MERCURY, ELEMENTAL 1 0.5 MQ/M3- ANY CHEMICAL CARTRIDGE RESPIRATOR WITH CARTRIDGES PROVIOINO PROTECTION AOAIHST MERCURY. ANY SUPPLIED-AIR RESPIRATOR. ANY SELF-CONTAINED BREATHING APPARATUS. 1.25 MO/M3- ANY SUPPL1EO-A1R RESPIRATOR OPERATED IN A CONTINUOUS FLOW MODE. ANY POWEREO AIR-PURIFYING RESPIRATOR WITH A CANISTER PROVIDING PROTECTION ADAINST MERCURY. 2.S MQ/M3- ANY SUPPLIED-AIR RESPIRATOR WITH A FULL FACEPIECE. ANY SELF-CONTAINED BREATHINQ APPARATUS WITH A FULL FACEPIECE. ANY SUPPLIEO-AIR RESPIRATOR WITH A TIGHT-FITTING FACEPIECE OPERATED IN A CONTINUOUS FLOW MODE. ANY CHEMICAL CARTRIDGE RE9PIRAT0R WITH A FULL FACEPIECE ANO CARTRIDGES PROVIDING PROTECTION AGAINST MERCURY. ANY AIR-PURIFYING FULL FACEPIECE RESPIRATOR (GAS MASK) WITH A CHIN-STYLE OR FRONT- OR BACK-MOUNTED CANISTER PROVIOINO PROTECTION AGAINST MERCURY. ANY POWERED AJR-PURIFYINO RESPIRATOR WITH A TIOHT-FITTINO FACEPIECE AND A CANISTER PROVIOINO PROTECTION AOAINST MERCURY. 28 MQ/M3- ANY SUPPLIEO-AIR RESPIRATOR WITH A HALF-MASK ANO OPERATEO IN A PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE. ESCAPE- ANY AIR-PURIFYINO FULL FACEPIECE RESPIRATOR (OAS MASK) WITH A CHIN-STYLE OR FRONT- OR BACK-MOUNTED CANISTER PROVIOINO PROTECTION AGAINST MERCURY. ANY APPROPRIATE ESCAPE-TYPE SELF-CONTAINED BREATHING APPARATUS. FOR FIREFIOHTINO AND OTHER IMMEDIATELY DANGEROUS TO LIFE OR HEALTH CONDITIONS > SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE. SUPPLIEO-AIR RESPIRATOR WITH FULL FACEPIECE ANO OPERATEO IN PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE IN COMBINATION WITH *N AUXILIARY SELF-CONTAINED BREATHINO APPARATUS OPERATED IN PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE. CLOTHINGI EMPLOYEE MUST WEAR APPROPRIATE PROTECTIVE (IMPERVIOUS) CLOTHING AND EQUIPMENT TO PREVENT ANY POSSIBILITY OF SKIN CONTACT WITH THIS SUBSTANCE. OLOVES: EMPLOYEE MUST WEAR APPROPRIATE PROTECTIVE GLOVES TO PREVENT CONTACT WITH THIS SUBSTANCE. EYE PROTECTION: EMPLOYEE MUST WEAR SPLASH-PROOF OR DUST-RESISTANT SAFETY GOGGLES AND A FACESHIELD TO PREVENT CONTACT WITH THIS SUBSTANCE. EMERGENCY WASH FAClLITIFSl WHERE THERE IS ANY POSSIBILITY THAT AN EMPLOYEE'S EYES AND/OR SKIN MAY BE EXPOSED TO THIS SUBSTANCE, THE EMPLOYER SHOULD PROVIDE AN EYE WASH FOUNTAIN AND QUICK DRENCH SHOWER WITHIN THE IMMEDIATE WORK AREA FOR EMERGENCY USE. AUTHORIZED - FISHER SCIENT IFIC, INC. CREATION DATEl 01/31/85 REVISION DATEi 10/10/90 - SAL 000009891 -------- -- --------------------- =ADD11 IONAt INFUHMRTTtJN- THIS INFORMATION IS BELIEVED TO BE ACCURATE AND REPRESENTS THE BEST INFORMATION CURRENTLY AVAILABLE TO US. HOWEVER, WE MAKE NO WARRANTY OF MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESS OR IMPLIEO, WITH RESPECT TO SUCH INFORMATION, AND WE ASSUME NO LIABILITY RESULTINO FROM ITS USE. USERS SHOULO MAKE THEIR OWN INVESTIGATIONS TO DETERMINE THE SUITABILITY OF THE INFORMATION FOR THEIR PARTICULAR PURPOSES. Crt Cn 00 CO MATERIAL SAFETY DATA SHEET NALCO PRODUCT NALCO 89RB068 CORROSION INHIBI Emergency Telephone dumber Medical (708) 920-1510 (24~tioura) GS681 SECTION 1 PRODUCT IDENTIFICATION z>v\on^ TRADE NAME: NALCO 89RB068 CORROSION INHIBI DESCRIPTION: An imidazoline in heavy aromatic naphtha 1' 46*0 ** NFPA 704M/HMIS RATING: 3/3 HEALTH 2/2 FLAMMABILITY 0/0 REACTIVITY O-Insignificant l=Slight 2=Moderate 3=High 4=Extreme 0 OTHER* * SECTION 2 HAZARDOUS INGREDIENTS Our hazard evalution has identified the following chemical ingredient(s) as hazardous. One or more is being claimed as a trade secret under OSHA's Hazard Communication Rule, 29 CFR 1910.1200. Consult Section 14 for the nature of the hazard(s). INGREDIENT(S) CAS # APPROX.% Heavy aromatic naphtha Proprietary imidazoline 64742-94-5 Proprietary SECTION 3 PRECAUTIONARY LABEL INFORMATION 40-70 40-70 WARNING: Causes burns to skin and eyes. Combustible. Do not get in eyes, on * skin, or on clothing. Wear goggles and face shield when handling. Avoid * prolonged or repeated breathing of vapor. Use with adequate ventilation. Do * not take internally. Keep away from heat and open flame. Keep container * closed when not in use. * Empty containers may contain residual product. Do not reuse container unless properly reconditioned. * * SECTION 4 FIRST AID INFORMATION EYES: SKIN: INGESTION: INHALATION: Immediately flush for at least 15 minutes while holding eyelids open. Call a physician at once. Immediately flush with water for at least 15 minutes. For a large splash, flood body under a shower. Call a physician at once. Do not induce vomiting. Give water. Call a physician. Remove to fresh air. Treat symptoms. Call a physician. NOTE TO PHYSICIAN: No specific antidote is known. Based on the individual reactions of the patient, the physician's judgment should be used to control symptoms and clinical condition. CAUTION: If unconscious, having trouble breathing or in convulsions, PAGE 1 OF 8 SAL 000009892 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINO'S 60563-1 198 MATERIAL SAFETY DATA SHEET |pRODUC^^alco"8^ NALCO GS6gl Emergency Telephone Number Medical (706) 920-1510 (24 hour*) SECTION 4 FIRST AID INFORMATION ( CONTINUED > do not induce vomiting or give water. NOTE TO PHYSICIAN: Probable mucosal damage may contraindicate the use of gastric lavage. Measures against circulatory shock, respiratory depression and convulsions may be needed. SECTION 5 HEALTH EFFECTS INFORMATION PRIMARY ROUTE{S) OF EXPOSURE: Eye, Skin, Inhalation EYE CONTACT: SKIN CONTACT: INGESTION: INHALATION: Corrosive to the eyes with possible permanent damage depending on the length of exposure and on the first aid action given. Corrosive to the skin possibly resulting in third degree burns, depending on the length of exposure and on the first aid action given. Can be harmful. Prolonged inhalation of vapor may be harmful. SYMPTOMS OF EXPOSURE: A review of available data does not identify any symptoms from exposure not previously mentioned. AGGRAVATION OF EXISTING CONDITIONS: A review of available data does not identify any worsening of existing conditions. SECTION 6 TOXICOLOGY INFORMATION ACUTE TOXICITY STUDIES: Acute toxicity studies have not been conducted on this product, but acute studies have been conducted on a similar product. The results are shown below. ACUTE ORAL TOXICITY (ALBINO RATS): LDS0 = 1,122 mg/kg 95% Confidence Limit =887 - 1,420 rag/kg ACUTE DERMAL TOXICITY (ALBINO RABBITS): LDS0 = Greater than 3,000 mg/kg PRIMARY SKIN IRRITATION TEST (ALBINO RABBITS): SKIN IRRITATION INDEX DRAIZE RATING: 8.0/8.0 Extremely irritating (Corrosive) COMMENTS: Third degree burns were apparent on all application sites. PRIMARY EYE IRRITATION TEST (ALBINO RABBITS): EYE IRRITATION INDEX DRAIZE RATING: 110/110.0 Extremely irritating (Corrosive PAGE 2 OF 8 Sai 0009993 ____________ NALCO CHEMICAL. COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1136 MATERIAL SAFETY DATA SHEET NALCO PRODUCT NALCO 89RB068 CORROSION INHIBI Emergency Telephone Number Medical(708) 9201510(24 hours) 6S681 SECTION 6 TOXICOLOGY INFORMATION ( CONTINUED ) COMMENTS: Caused permanent damage to the cornea and iris. SECTION 7 PHYSICAL AND CHEMICAL PROPERTIES COLOR: Clear light amber FORM: Liquid SOLUBILITY IN WATER: Completely SPECIFIC GRAVITY: 0.92 @ 60 Degrees F VISCOSITY: 39 cst @ 60 Degrees F POUR POINT: Less than -30 Degrees F FLASH POINT: 152 Degrees F (PMCC) ODOR: Hydrocarbon ASTM D-445 ASTM D-97 ASTM D-93 NOTE: These physical properties are typical values for this product. SECTION 8 FIRE AND EXPLOSION INFORMATION FLASH POINT: 152 Degrees F (PMCC) ASTM D-93 EXTINGUISHING MEDIA: Based on the NFPA guide, use dry chemical, foam, carbon dioxide or other extinguishing agent suitable for Class B fires. Use water to cool containers exposed to fire. For large fires, use water spray or fog, thoroughly drenching the burning material. UNUSUAL FIRE AND EXPLOSION HAZARD: May evolve NOx under fire conditions. Containers exposed in a fire should be cooled with water to prevent vapor pressure buildup leading to a rupture. SECTION 9 REACTIVITY INFORMATION INCOMPATIBILITY: Avoid contact with strong oxidizers (eg. chlorine, peroxides, chromates, nitric acid, perchlorates, concentrated oxygen, permanganates) which can generate heat, fires, explosions and the release of toxic fumes. THERMAL DECOMPOSITION PRODUCTS: In the event of combustion CO, C0lr NOx may be formed. Do not breathe smoke or fumes. Wear suitable protective equipment. SECTION 10 PERSONAL PROTECTION EQUIPMENT RESPIRATORY PROTECTION: If it is possible to generate significant levels of vapors or mists, a NIOSH approved or equivalent respirator is recommended. For large spills, entry into large tanks, vessels or enclosed small spaces with* inadequate ventilation, a pressure-demand, self-contained breathing apparatus * is recommended. * PAGE 3 OF 8 ooooq sM- e- iftUCO CHEMICAL COMPANY ONE NALCO CENTEH NAPERVILLE. ILLINOIS 60563-1198 MATERIAL SAFETY DATA SHEET NALCO G S 6 81 PRODUCT NALCO 89RB068 CORROSION INHIB3 emergency Telephone Number Medical (708) 920-1510(24 hours) SECTION 10 PERSONAL PROTECTION EQUIPMENT ( CONTINUED ) VENTILATION: General ventilation is recommended. Additionally, local exhaust ** ventilation is recommended where vapors or mists may be released. PROTECTIVE EQUIPMENT: Wear gloves, boots, apron and a face shield with chemical splash goggles. A full slicker suit is recommended if gross exposure is possible. The availability of an eye wash fountain and safety shower is recommended. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse. SECTION 11 SPILL AND DISPOSAL INFORMATION * * * W * * * IN CASE OF TRANSPORTATION ACCIDENTS, CALL THE FOLLOWING 24-HOUR TELEPHONE NUMBER <708-920-1510) SPILL CONTROL AND RECOVERY: Small liquid spills: Contain with absorbent material, such as clay, soil or any commercially available absorbent. Shovel reclaimed liquid and absorbent into recovery or salvage drums for disposal. Refer to CERCLA in Section 14. * * * * * * * Large liquid spills: Dike to prevent further movement and reclaim into recovery* or salvage drums or tank truck for disposal. Refer to CERCLA in Section 14. * For large indoor spills, evacuate employees and ventilate area. Those responsible for control and recovery should wear the protective equipment specified in Section 10. * * * DISPOSAL: If this product becomes a waste, trace levels of benzene may cause the product to be classified as a hazardous waste under the Resource Conservation and Recovery Act (RCRA) 40CFR261. Hazardous Waste D018. Before disposal, the product should be analyzed for its benzene content, to determine if it meets the criteria of a hazardous waste under RCRA (Toxicity Characteristic Leaching Procedure {TCLP} Test). * * * * * * * As a hazardous liquid waste, it must be solidified with stabilizing agents (such as sand, fly ash, or cement) so that no free liquid remains before disposal to a licensed industrial waste landfill (Hazardous Waste Treatment, Storage and Disposal facility). A hazardous liquid waste can also be incinerated in accordance with local, state, and federal regulations. * * * * * PAGE 4 OF 8 SAL 000009995 NAUro CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 6D5B3-11SS MATERIAL SAFETY DATA SHEET NALCO PRODUCT NALCO 89RB068 CORROSION INHIBI Emergency Telephone Number Medical (70S) 920-1510(24 hours) gt r% /> W UD 1 SECTION 12 ENVIRONMENTAL INFORMATION If released into the environment, see CERCLA in Section 14. SECTION 13 TRANSPORTATION INFORMATION DOT PROPER SHIPPING NAME/HAZARD CODE - CORROSIVE LIQUID, N.O.S. CORROSIVE MATERIAL UN 1760 CONTAINS - ORGANIC AMINE COMPOUND SECTION 14 REGULATORY INFORMATION The following regulations apply to this product. FEDERAL REGULATIONS: OSHA HAZARD COMMUNICATION RULE, 29 CFR 1910.1200: Based on our hazard evaluation, the following ingredients in this product are hazardous and the reasons are shown below. Heavy aromatic naphtha - Combustible, skin irritant Proprietary imidazoline - Corrosive to eyes/skin Heavy aromatic naphtha = 100 ppm TLV Manufacturer's recommendation CERCLA/SUPERFUND, 40 CFR 117, 302: Notification of spills of this product is not required. SARA/SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE III) - SECTIONS 302, 311, 312 AND 313: SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355): This product does not contain ingredients listed in Appendix A and B as an Extremely Hazardous Substance. SECTIONS 311 and 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370): Our hazard evaluation has found this product to be hazardous. The product should be reported under the following EPA hazard categories: XX Immediate (acute)health hazard -- Delayed (chronic) health hazard XX Fire hazard -- Sudden release of pressure hazard -- Reactive hazard * * * * * * * * * * * PAGE 5 OF SAL 000009B96 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE, ILLINOIS 60563-1108 MATERIAL SAFETY DATA SHEET NALCO G S 6 81 PRODUCT NALCO 89RB068 CORROSION INHIB] Emergency Telephone Number Medical {708} 920-1510 {24 hours) SECTION 14 REGULATORY INFORMATION ( CONTINUED ) SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372): This product does not contain ingredients (at a level of 1% or greater) on the List of Toxic Chemicals. TOXIC SUBSTANCES CONTROL ACT (TSCA): The chemical ingredients in this product are on the 8(b) Inventory List (40 CFR 710). RESOURCE CONSERVATION AND RECOVERY ACT (RCRA), 40 CFR 261 SUBPART C & D: Consult Section 11 for RCRA classification. FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15/ formerly Sec. 307, 40 CFR 116/formerly Sec. 311: None of the ingredients are specifically listed. CLEAN AIR ACT, 40 CFR 60, SECTION 111, 40 CFR 61, SECTION 112: This product does not contain ingredients covered by the Clean Air Act. STATE REGULATIONS: * * * * * * * * * * * CALIFORNIA PROPOSITION 65: None of the chemicals on the current Proposition 65 list are known to be present in this product. MICHIGAN CRITICAL MATERIALS: This product does not contain ingredients listed on the Michigan Critical Materials Register. STATE RIGHT TO KNOW LAWS: This product does not contain ingredients listed by State Right To Know Laws. * * * * * INTERNATIONAL REGULATIONS: This is a WHMIS controlled product under The House of Commons of Canada Bill C-70. The product contains the following substance(s), from the Ingredient Disclosure List or has been evaluated based on its toxicological properties, to contain the following hazardous ingredient(s): Chemical Name CAS # % Concentration Range Heavy aromatic naphtha Proprietary imidazoline 64742-94-5 Proprietary 40-70 40-70 PAGE 6 OF 8 SAL 000009897 NALCO CHEMICAL COMPANY ONE NALCO CENTER * NAPERVILLE. ILLINOIS GOSB3-1198 MATERIAL SAFETY DATA SHEET NALCO PRODUCT NALCO 89RB068 CORROSION INHIBI Emergency Telephone Number Medical (708) 920-1510(24 hours) SECTION 15 ADDITIONAL INFORMATION None SECTION 16 USER'S RESPONSIBILITY This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to ensure safe workplace operations. Please consult your local sales representative for any further information. SECTION 17 BIBLIOGRAPHY ANNUAL REPORT ON CARCINOGENS, U.S. Department of Health and Human Services, Public Health Service, PB 33-135855, 1983. CASARETT AND DOULL'S TOXICOLOGY, THE BASIC SCIENCE OF POISONS, Doull, J.r Klaassen, C. D., and Admur, M. 0., eds., Macmillian Publishing Company, Inc., N. Y., 2nd edition, 1980. CHEMICAL HAZARDS OF THE WORKPLACE, Proctor, N. H., and Hughes, J. P., eds., J. P. Lipincott Company, N.Y., 1981, DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS, Sax, N. Irving, ed. , Van Nostrand Reinhold Company, N.Y., 6th edition, 1984. IARC MONOGRAPHS ON THE EVALUATION OF THE CARCINOGENIC RISK OF CHEMICALS TO MAN, Geneva: World Health Organization, International Agency for Research on Cancer, 1972-1977. PATTY'S INDUSTRIAL HYGIENE AND TOXICOLOGY, Clayton, G. D., Clayton, F. E., eds., John Wiley and Sons, N. Y., 3rd edition, Vol. 2 A-C, 1981. REGISTRY OF TOXIC EFFECTS ON CHEMICAL SUBSTANCES, U.S. Department of Health and Human Services, Public Health Service, Center for Disease Control, National Institute for Occupational Safety and Health, 1983 supplement of 1981-1982 edition, Vol. 1-3, OH, 1984. Title 29 Code of Federal Regulations Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA). THRESHOLD LIMIT VALUES FOR CHEMICAL SUBSTANCES AND PHYSICAL AGENTS IN THE PAGE 7 OF 8 SAL 000009893 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 6D553-1198 MATERIAL SAFETY DATA SHEET NALCO 6 S6si PRODUCT NALCO 89RB068 CORROSION INHIB] Emergency Telephone Number Medical (708) 920-1510 (24 hours) SECTION 17 BIBLIOGRAPHY ( CONTINUED ) WORKROOM ENVIRONMENT WITH INTENDED CHANGES, American Conference Of Governmental Industrial Hygienists, OH. Information on this MSDS has changed. The changes are indicated by asterisks on the right side of only the changed sections. This is an updated MSDS as required by OHSA's Hazard Communication Rule 29 CFR 1910.1200. PREPARED BY: Ricky A. Stackhouse PhD., Toxicologist DATE CHANGED: 10/23/90 DATE PRINTED: 11/22/90 S*L 00009399 PAGE 8 OF 8 II samm NALCO CHEMICAL COMPANY ON'E NALCO CENTER NAPERVILLE. ILLINOIS 605B3-1195