Document GzdQ6Dq6r9pXmYNNxvkNZwj2Y
moro. STT=91-]
ICFIHBIEORNSD,DEVPIARRGTINNEINAT EI. SDPURUPAONNCTE D"STENFLEONX" OTE&UCCHRNoI.SC.ALTHC.
`COMPANYCONFIDENTIAL TECHNICAL REPORT
PERFLUGRO OCTANOIC ACID CONCENTRATION(CB) IN WASTE WATER
3c. wore
REPORT WRITTEN BY
F-- I
WORK SUPERVISED BY:
as ss1teer
PREVIOUS RELATED REPORTS: SAR 19-3SpAR 821 IR 92-1
rRodECT CODE
Eheim
PERIOD COVERED:
wero
NOTEBOOKS COVERED:
wa
snsTact TihnevactoearpanfyorsssmsmeotniauaCEGpef(luCceoemmoaostcayseaEtxeposu(C8r),e Gu&idseulrifnaec)entcfin pthpeb pTeotsiiotniscndof aissume insgep AhlLte Co8pser aodeecsr up Tiono FTtohntenJHabmeers Rivbersovpoeeutledntive CPSrGoduccoeuldaabeaveerxacgeeedcovnecledntrbaetidounrionfg p0er1iopdpsb ofTheextrceamley tliomveflhoews I sa one saver
000162
EISDP7R1O402053139
INTRODUCTION
TWoerfksl.on Adimsmpoenrissionpertetlumoardoe cinotaPnaccaktescabiuszga,suWVrfaactanWteshaidndgetdonto the dispereson to prevent aggolmeration of particles Amsonsum foubenrfdlucirnotshoetagnrcoautnedvaistercoammcoonulnyd WceasllhinCBg.tosThWiosrkscospound has best
wAanteerxasmticneaatsisonveorfepraenvailoyuzsedtetcohneivcaalluatsetudtiheesanayndpsoatmepnlteisalof vaste
Caonmamluynzietyvaesxtpeosvuartee.: sCrEeaMpsHilflo'rsCOl.aborTahetorryesuvlatssccoonutlradctoendlyto
aacdcdoeudnttofodrist5i0l%leodf
athteesCOvereSurfrroogmatSeI% setocov8e6r%ies Tohne
known bounce possibility
cGfonstehervatteistvebeaipnpgrosincherirsostobyasasumfeacttohratofalltoofisthereaClO. saTdsheup sa
the plants vaste vator system.
AJcameasverRaigveerTeflfolwon(51f0i4berX{pgrpodd)u,ctitohne CcBatecoanlooenagtrwaittihonthveoualdvebreage P0E.D1.0 ppEbx.treMmeaxliomvsflfoiwberiaprthoeducitvieorn ccoouulldd rraaiissee tthhee cloenvcelentforat0i.o1n5 nSEeedCoto4ndrtohpe brievleorw a1b0oG0veNHthepd.1 pgbThelimliotv flTohweforrivetrhefJlaozwervouRiidver poenriaodrsepeoaftaebxlterem1e0 yleoavrfclyocvlea(t1h0e10)riviesr,408thMeHprgopdductiDounriaofs Theeflcoonmpafniyb'esr mCaEyG offeed1 ptopbbe curtailed so as Bot to exosed the
PROGRAY OBJECTIVES
1 Tporocdeescse.zmine vhac happens to CB in the Tetlon spisnisg
2. Ecsatuasebdlisbhy tthhee esxitteen'ts. vaifsteanyw.atoefr commusity exposure to C6
RESULTS & CONCLUSIONS
1. Tbahleanacne.alysiTshefocrastC6tedosbselinoetvedalltoowbefor-S0d%oinageouarnataeccuraAtbeoutmass w55a%shofvattehre aCEnd1sthete cbeezlaiieovieadg StYo cexointdencsheesprioacetshse weixchkaustthe System and exits vith the effluent
2. ACconcneonrtmarlatiroinverposfsliovb.le$1i04tMhte gJpedm.esthReivseraxsihmomulCd8sor exceed
:
0.15 po.
000152
EISDP7R1O402053240
eee
3 Fe4rrToo1de2usldbieUotnpersma1yd3n00n1etheed 9ibo3v4ebresocutrhlatailtehde wCBhacnostcheenJtiaamcsioRnudeo.cs sot
secomesoutrons
1. No further casting for CO be dons at this sine
.
sates ssruation
Wwolpatent aoticn has basa taken ox ie anticipated ae a Femi of
suBLIchTION status
No publications ae plasasd.
serciaL sary pRscavTions
Noraxi SOBs cover ail of tabs vert
ENVIRGUENTAL CoRSTOERATIONS
StayToanbrTeearsktpiavciechsVvaesshsiaaagreeensooarkisn egtrfoevretsereacrooruad dealisg wich CB
000154
1s0e7r1o4c2o5s3ar
ae ToofbConitenets
Je--
.
2. orscussion
.
JR----
3
~
B. TEFLON* DISPERSIONS
a
c. pervious coven
.
J --------
s
[pe--
.
Rpe--
1. Wass BANE oF Co IH TEFL: SPEIIG
s
2. ASS BALANCE OF Co IN SPRUAICE WASTE WATER STSIDN 10
5. FRORGHED KASS BALANCE OF Go TX TRON: SPIRNG 11
C. FROROSED WASH BALAKCE AROIND WASTE WATER SYSTEN 2
5. sermon
Rr ep--
1auie
5. AMALITICAL DATA FOR LNG LASORATORY YO. 0152 35-30
000165
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I Tewosuanon
mTeafnluofnatctucroelloofidaTelfldoiaspecfeisboenr isTmhiexecdellwiuclhosevisccoonsteaizieadchiea the
Tvhiescorseegeniserarteegdeneosealtleudlosien atchtescaosag&ulmaattiroinx/sctiedbibnadthTeifalosnp:innpianrgiicles
~
=per1i1o0:idceolsTienftleorningdispSeurrsfiaocntsanttso parreeveunstedagignlotmheeramtainounfacotfurpeartoficles One of the sutactance used is F143. ammonium pertluore sciancace [
commonly referced to se C8)
2. prscussion
A.BARLIZR YSSUES
PInely19m7e3r.izatthiecn3MmCayompbeanytermaottoigteineidc.DuPoAnitzbotrhante cCu8stuseord viaapToerfleoene Perlotjectota(bReeptohrecesoSupccaeR o7f9-3t.heSeAxRpos8u2r-e1 & STeRver8a2l-11tewcekrseieatiritiated vo%afos csntoouatdtyaddecptheaecctkpeiodncgeinyatiaatalhaeeovxroprokdsiurrpeelsatcteocoaCnGitrabcsytavDwiuirPtoohamcmeTaeetafplloonTyheees hesdCi5isg xdipsepseerdsiotno sveirgeniftihecanotnlylevpeoltsentofialC8ar(Reeafs. t4h)at pTeersstosnnaetl Hcaasnkeblel LSaibGzsehcotweeddC3no etxrpaonrsufeer ofof peCsBsoftrsomfayasrdnisingtodrraybbFia:ra skieinmiarncdoal a(nRedf DuP5)oat'sC8HawasskelllaceL:abedeterained not to be teratogenic by
5. mM prsesesion
WToerfklson: CdBispwehricshionfeisthepraodmumcoendiuminsaaltbatofchpoeprefrinaotrisonsacttanWeaischinacgitdon Tisetluosne-d paasrtaicvleets.tingAagbeanttohtoofprdeivsepnetrsiaogngioimreriantiitcieallofy atbhoeut 7000 rIbas swhoifchC3conistaiandsded300t0o clhbes obfatcTheflionn:thesonpcroeecrhargeA sfaodtaisesofect4i0o8n0 dSteecpasn.tedAttcoerobtpaoilnyme6r0i%zastoiloindsis Wcaosmhpionlegcteodn. Wotrhkesdeisstpiemrastieosn tishat oStOhKerofSOthXegoCe8sivsitchentohveedcwointchentchreatdeedcadnitsepderasiuopnernitOen aandTefrlhoen: osnol+idedlebpaseirce.ionthebasCiOsconcentration vould be MSO pps. sad 500 pre
aaThdmejmuosnTtieeufdmloveniatlhtdisetosoedariusmisoondbiyud(cmToxs3ai3ld1t1e.) vhuisIcendhthcfehoransgfoeiasZgeurlthaetsieCon3dguicaftcriioodmnbarcaethph ufsoerad, ipneTretflluoonr:o oficbtearnoispeinanciang. the C3 will covert to the aod
000166
EISDP7R1O402053543
2%
. PREVIOUS CONCERNS
PCehervoitoguhsbraensdelairacghofexyamainned eSmipnltoeyreesd pToetfelaotnislvareaxpohsaudre to CO nsainn-tdeertiencgtatbelmeperlaetvuerles iosf C3828 (CRef 4) The Tefloat fiber
~
iThtehbaoiTleifnlgonp'oinctoatoifngp,ervfhliuccthoarseotanemtcicexapcoisdedisto18B8igCh. Yaras
GCreemaptemceanttureosf dtihdesecoynatracien vdaescecs:iafbelcetivleeveilosEeofmovCBi.sg tThheerCsOs.l The
etsemepaerrcahtursehov(eTdabltehat1),th(Reef.CO r2)e.movaIlR vsacsans4 offuncottfiongasofftroimdethaend
RCheesteCd3 doycaarnchosxaymipalteesspirnotvoideCOdIthaendbapseicctlufoorrothweonochoyadclruisdieoranethsaees
not evaporate as it is heated up to 200 C (Ref. 4)
Tcheempdaartaatirfeoll1o0wsC tchreodKucaessetiacdou"rbulliengofofthtuhde"ratthea iEnxcrrreaapseinlgaticshe: phriesdicrteslattihoatnshailpl utphetoCBthies srieamtoevreidsgfrtoemmpcehreatfuirbeerof Teflon:
. EEESDNT DNYISORGNTALCONCERNS:
TChoentapmriensaettionssvir4saCzZe6s(tCaolnmusssietsyesmEexpevsiuthceCFGaisdoeaiivnietsh) grofsusd pvbatei:t ater bas been established by Maskell Labs
SParaopcleesss ovfereefftlaukeeanc tforoemstdiimfatfeeretnhte cspoontcsenitnratthieonTeoffloCnO' inspicshseing Tite's vaste stzesme. Sample locaticas are listed in Appendax 1
CtHhIeiNrHir1e1sulvtass caroentrinacAtpepdencdoixanaI.lyzeA tchoemplseatmeplerseportA sfruommmarCyHIof AHElLlLev1sforcon+tacionmepdletiea GAapspsendbiaxlanIcIe ThTehessaemapsluerecdesuciotnscednotrantoirons Cin6.(tFheigeff1l6u3en)t.streTahmesreoancley asecvceoruanltspofsosribalbeoutexp3l0a%naotfiotnhse, the CiBnicthiealmsoCa8llcyonsceeancttrea.tioint iiee 7e5n0caspepdm oinn 4thedryyarTae.fliotndeScaoimsp.osetsh.e ianviatpioarlateCs8 coronctehentcraetpioorntedislenovtelsliakceelyiabeceacucsoer olforindepTehnedelnotver canoanlcveenitscatdioocne abxy aWbeosuhtingitCoOCr Wpoprakcannd4 dSoirsupsearcseionhavseasissessuzTehde t3h8e Dioltlrecahcatngevittho ptehreflnuorcmtaoloccioacntoeinctsacoifdthiea Ttehfelobna:chsvpaiiacnhingshosvciicd bSaatche.redThienretheisyaaornreasonable vay to prove the idea of CO beds
00017
ES1PDR7O1040235464
Se
Pf(eoEvr7i3oth)se.swmiosrsTkiaenagacsCou3nrciedatTzhaetiporonenvivuonoususilndtweonrreckrddcotTnoecflbueadle1d0y6atrhpnaptsabhtoewaocCpoBoevmet VcToaherzkceiseidapcrweoirccsehisnsgthoofprouFvaeescriosnvteerricoTeshdisCOTeitsrlooiasnt ctyohaneclcnreavd"oitutilnideondpeotcorodmeMzsao-sskesagdiuocinzg exhaust sczens.
.
otFinneo Works
Cpoo.wdesT"heTe"ffilaoen cecovesy of CB
fpohowadneerstb"heeens"ctteaisedtreidpeodwadndeatrsf"o19u0nedxChatuostsWoacmsothnaititragaedolinicttcsle
hLthEeaCHplreavvsiaoopnuodsraanttseeosdnclo<fu0fsitohtneheafbypoaiurstnnidnigensaetshwbeAeLsfEyitlbeartsiyossntpeiravaeiraogu1spresovdvaueperoesr.attihieton
FTpoaosttecenertdiuacCleocotfhouerghacoadmuvpceetratfsaiczreeu.bdboweavrtaearnbdelieotwhesp6r5faiyCn.eadl gZihanesthetexemaepuexsratautsgutarsehostoehden
sE"ahrroicceuxfldlleoyourstrecdrhuaocnoeedd.antoeIfacseoailelsnetsofubcobtnehdreitCgioooneisnvteencTethaaeellvyTeeifselarodne:artsbaiaisoeendmetnhfterom
CSeHvaer.BLthisacevoullodv lead 0 the conclusion that the asalpsis from
vCTearHtsasB0G1ci1ledcesitaoeonrmsiotnreerqdougiaoitxeesthfeoornBiacgmhharlevscsoinsscaemnp|tlreSaritreodgeSruer5sr0o1g0ar8teecdeoceefciorcvoeorniiheeirhe
GeSiaxezapculhseatsz.gesoomnfuerbobmseesahteefbyfelxbuSaepunrrtutsavcasesecsaabnnbdaelryozveeanddfccootmvshaCEvGReiNriLHsii8llepldpsbvaolasfbe.sCO. Thaend
vClaheses"sdduetetheancCtoi5o0tn%heofmoTshkseneoswssxcprleaasastoaeucdnitosbnyofaforLsaurrthgceeogaoltooevn-tmsaauctrgererorigaalteadcdeecedvevreys
eDCxehhcracosmmepstatsoigsatrsiaupnhaircoproptdehuaekctmsocsotuolpfyleodelliwikivecilhoysscaasclehasagteofadcie(lhuestoiraoucnbab-etfdaacctqaoeurtr of the
"Cahteeermscsoagmeplaersaieanpeafkren 8Th2e% "alysis being dow 20 eal
fsoutr8o6sace Thseessoovresriiessiliocny thofe
cshiesciiled
TTsehtteelzoelnottvsbsypsiloaatsifeoafgctopcrroonctofersasd2i8ctivTnhogeuldmbaetlteiireeifatlothgaoetnthCetrHheINthaeBcielmlajofosrCsrBteymu3iofcsthe
aEthirelnemaetatelhyariasrlcaocoeuraTsthee irf$0orchpep5eKvemeeoafspuotrrheetdiofncoocanolcfenmttahzetaerteiixeoilnti|onfgTChBetreooctrehretsrh.e35t%he
Y%"aoazshnWianesgvhaipnsogtretapotnessiWnocraeknsdthtceheecaoacviecdsoyndbeaprncoshceesisss.in100tO%haelryeecxybtoarlsaeacdte haomoTvdoaetssiSmhiofloargC8the
SFhcorxulbdberconvcahs lthoesesetzhuebaber028Thoef atsnoeunttotaflounadmouiant the exbases
0001s
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sae
Icfonodena,tcaotfidornaCoBf eSnHst#s2 sHausphperocsehsosulwdihhavNeawbewsaas4h50u0st5a3,3 hceai HPLeIr1c'esntmageeasuireedinamtohuestTaaogfe20of00Eepppabrtfssu5r2r%ogofatethaftecleeevreircs Tonhis deciiled vaer
.
Tathhneevimzpoolsaatznetn'ctsoanlvsearitametpaicveteftlpiusoesnitG.otonaerTiihnaiesesvtthoiaumtladtailnalgbouottfhetdhpoeourbCleen3cisasidlts oufpCiHtK
117s aensured concentrations (Fig 3 6 4)
Dgiutvraeizrneaglgdea(cy1h9e3of7saCmt3oplvi1en9rg8e7)pderitislooodvtaz1fg1oe/r13ttohe&th1Jeu1m/e1Js4a/m5eR1siveaRrinvdeirsescSiITGmHaaecMedalopn2ag154term
Tshsitsinivtealdd0.a0k5epptbh.e CO concentiation in the Sues River a
TThhiessvzeaicladgedaisscmhuaardgepro1d4u55cti1obnofcatCe6 tfoorthTaefTlaomnes LRiinveerrs aisrc1stNlXyIb
TTThhheeissesceotruiilmmdantaepdddrCoBd5u.s3ctoinIocbsnenTCtaOztlaedcaiyofonrtoiTnetfhtleheenJtafoievfseirbReirwvsoesri1daas4de300proi0dbu/capeneyban
sstinited CB corcencacion of 015 Fob 1a the Fiver
TSdhifecinltgoive(hCfialsmoawspeiarAivaoedr10vo1suyelad4r08prsMoedpiuegcaretinagnmaceyscatlvieemreetcefedassCre3saetciimsneiesidncisbsysft7ai0ev:0e) it
TihnecreSaesxeestRheevec:onocfent1e.a20ticpepbtoand1.0S4arppibs pDruordiuncgtiotnheraltoevsflvoovrid
fPeereidodtso, bevhicouhrtasshioeudldShoap2p3e0n0 Below che C3 of 1 ppb
o1nbciedayeveofryTe1f0loyne:arsf.ibeprrodcuoctsitoany
cay
000164
E1sDe7r1oa02053846
See
"Feeeraxes
1 Forte. WA - SpaR 79-3
2. Fort. WA, Mokhtar, AM. - CD Noschly, Juse, 108:
3. Shelburne. SS. - BCD Monthly, December. 1981
~
4. Shelburae. S.5., Forte. NA. Mokhtar. AM. - SpAR 82-1
5. Burks PP. - TR 82-1
0002 70
SPRO00347 E1D714259
TABLE 1
TsHREEROFCwrTAT QEUTRACTARILITOYF CAFROMYRK (Ret. 2)
Initial C8 concentration on 9450 I & T yara - 600 poe
R08emainainYnagra
Time of Heat (minutes)
moc usc oc
10
sa wo
20
nu wo
3
nwo wo
"
a wm wo
NID Not detestable, 5 ppm
. Least Square Fic for prZooproosisesde lst Order Decarborylation
150 Anon
(exatpucer)
nse Aho oe -0.106 +10.C > (010610 0155)04= 2.16
(ccelaocsteiotnos. "r+u1l0e oCfrotuhguhslby" dfoorublteesapeersacttuiroenderpaeten)dency of kinetic
Exteesolation to 200 C
Boho "0.725
2107. A= 04 spe which te < 5 ppm ainizim detestable limit
Extrapolation to 325 C (Siacering) A = Ao eo-1084x 701 poh at = 0.0014 minutes - 0.1 seconds
000171
sPRO00348 EID714260
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HSS BALAKCE GF CO USTHD igh HILL TEST RESULTS
Pass eSPmRUsRNGE WANSOTVEERGAETRER1"3T,RE1R9T0R1ENT SYSToH
3
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000174
:
EmDrias65
FIGIRE 4 FROPOSED MASS BALAKCE AROUND WASTE UAER svsTEn
NOVEMBER 13, 1991
.
Frown seceas
TE ea vogm " PE |e
Aikogpm.
a3
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