Document GzZqmrLdvxrDzJp6x4zg2611v

DownloadViewSend us a messageRandom document
ANALYTICAL REPORT STL STL Denver 4955 Yarrow Street Arvada, CO 80002 Tel: 303 736 0100 Fax: 303 431 7171 www.stl-inc.com PFOATFOS Analysis Lot#: D7D180342 Laura Vancho/Jane Hanszczyk NJ American Water 213 Carriage Lane Delran, NJ 08075 Severn Trent Laboratories, Inc ./STL Denver Gail DeRuzzo Project Manager May 4,2007 Severn Trent Laboratories, Inc. DEP2-SDWB-000334 Case Narrative D7D180342 The results included in this report have been renewed for compliance with the Laboratory Quality Manual. All results have been found to meet all requirements of NELAC and any exceptions are noted below. This report shall not be reproduced except in full, without the written approval of the laboratory or sponsor. Dilution factors and footnotes have been provided on each datasheet to assist in the interpretation of the results. Sample Arrival and Receipt The five water samples presented in this report was received at the STL Denver laboratory at a temperature of 4.6C on April 18, 2007. Standards Analytical standards were prepared using the acid form of the compound perfluorooctanoic acid (PFOA). PFOS is a commercial prepared and certified solution. A di-carbon-13 labeled perfluorooctanoic acid, [l,2-di-l3C] was introduced at the extraction step and was used as an internal standard for quantitation of PFOA and PFOS. Sample Extraction and Analysis The samples presented in this report were analyzed for the target analytes by STL Denver's SOP DENLC-0012. For water samples a 250 mL aliquot of each sample is acidified with 1 mL of 6N HC1 solution and it is extracted using solid phase extraction technique with methanol conditioned Cl 8 cartridges. Each sample is spiked with the internal standard, prior to extraction. After the sample is passed through the cartridge, the analytes are eluted with 4 mL of methanol. The final volume is brought to 5 mL using methanol and the extract is analyzed by LC/MS/MS. Method OC Samples The Method Blank is processed reagent water spiked with surrogate and prepared with each batch of 20 samples of the same matrix. The method blank: was non-detect at the reporting limit for the target analytes. Each batch is prepared with Laboratory Control Samples (LCS). The LCS recoveries for both levels were within established control limits. Due to limited sample volume, no matrix spikes were performed. Because the LCS data were in control, no corrective action was necessary. Analytical Comments The surrogate recovery for 13C4 PFOS was below the lower control limit in the low level LCS in QC batch 7114515. Because the LCS recoveries are in control and the control limits are default limits only, no corrective action was necessary. No other anomalies were noted. STL Denver 2 DEP2-SDWB-000335 EXECUTIVE SUMMARY - Detection Highlights D7D180342 PARAMETER REPORTING ANALYTICAL RESULT___ LIMIT_____ UNITS_____ METHOD BIRCH CREEK POE 04/17/07 08:25 001 PFOS PFOA C.0067 J C.062 0.010 0.015 ug/L ug/L DEN -LC-0012 DEN -LC-0012 BIRCH CREEK WELL 6 04/17/07 08:20 002 PFOS PFOA C .0072 J 0.061 0.010 0.015 ug/L ug/L DEN -LC-0012 DEN -LC-0012 BIRCH CREEK WELL 4 04/17/07 08:45 003 PFOS PFOA 0.0021 J 0.029 0.010 0.015 ug/L ug/L DEN -LC-0012 DEN -LC-0012 DRRWTP INLET 04/17/07 13:05 004 PFOS PFOA 0.0045 J 0.0094 J 0.010 0.015 ug/L ug/L DEN -LC-0012 DEN -LC-0012 DRRWTP PE 04/17/07 13:05 005 PFOS PFOA 0.0047 J 0.010 J 0.010 0.015 ug/L ug/L DEN -LC-0012 DEN -LC-0012 STL Denver 3 DEP2-SDWB-000336 METHODS SUMMARY D7D180342 ANALYTICAL PARAMETER__________________________________________ METHOD_______ LC/MS/MS, PFOA DEN -LC-00I2 References: DEN Severn Trent Laboratores, Denver, Facility Standard Operating Procedure. PREPARATION METHOD STL Denver DEP2-SDWB-000337 METHOD / ANALYST SUMMARY D7D18Q342 ANALYTICAL METHOD________________________ ANALYST________________________ DEN -LC-0012 Mark Dymerski References: DEN Severn Trent Laboratores, Denver, Facility Standard Operating Procedure. ANALYST ID_____ 004626 STL Denver DEP2-SDWB-000338 SAMPLE SUMMARY D7D180342 wo # SAMPLE# CLIENT SAMPLE ID JT6V0 001 BIRCH CREEK POE JT6V1 002 BIRCH CREEK WELL 6 JT6V2 003 BIRCH CREEK WELL 4 JT6V3 004 DRRWTP INLET JT6V4 005 DRRWTP PE HOTE(S) :_________________________________________________________________ The analytical results of the samples listed above are presented on the following pages. - All calculations are performed before rounding to avoid round-off errors in calculaied results. - Results noted as *ND" were not delected at or above the stated limit. This report must not be reproduced, except in full, without the written approval of the laboratory. - Results for the following parameters are never reported on a dry weight basis: color, corrosivity, density, flashpoint, ignitability, layers, odor, paint tiller test, pH, porosity pressure, reactivity, redox potential, specific gravity, spot tests, solids, solubility, temperature, viscosity, and weight. SAMPLED SAMP DATE TIME 04/17/07 08:25 04/17/07 08:20 04/17/07 08:45 04/17/07 13 :05 04/17/07 13 :05 STL Denver 6 DEP2-SDWB-000339 American Hater Company Client Sample ID: BIRCH CREEK POE HPLC Lot-Sample #... Date Sampled... Prep Date..... Prep Batch #... Dilution Factor D7D180342-00 04/17/07 08: 04/21/07 7114515 1 Work Order #... Date Received.. Analysis Date.. Analysis Time.. JT6V01AA 04/18/07 04/26/07 00:56 Method........ DEN -LC-0012 Matrix........ : WATER PARAMETER PFOS PFOA RESULT 0.0067 J 0.062 REPORTING LIMIT 0.010 0.015 UNITS_____ ug/L ug/L MDL 0.0020 0.0031 SURROGATE 13C4 PFOA 13C4 PFOS PERCENT RECOVERY 70 60 RECOVERY LIMITS (50 - 200) (50 - 200) MOTE(S) :_____________ I Estimated result. Result is less than RL. STL Denver DEP2-SDWB-000340 American Hater Company Client Sample I D : BIRCH CREEK HELL 6 HPLC Lot-Sample #... Date Sampled__ Prep Date..... Prep Batch #... Dilution Factor D7D180342-002 Work Order #...: JT6V11AA 04/17/07 08:20 Date Received..: 04/18/07 04/21/07 Analysis Date..: 04/26/07 7114515 Analysis Time..: 01:09 1 Method......... DEN -LC-0012 Matrix. PARAMETER pros PFOA RESULT 0.0072 J 0.061 REPORTING LIMIT 0.010 0.015 UNITS ug/L ug/L MDL 0.0020 0.0031 SURROGATE 13C4 PFOA 13C4 PFOS PERCENT RECOVERY 77 71 RECOVERY LIMITS (50 - 200) (50 - 200) HOTB(S) :_____________ J Estimated result. Result is less than RL. WATER STL Denver 8 DEP2-SDWB-000341 American Water Company Client Sample ID: BIRCH CREEK WELL 4 HPLC Lot-Sample #...: D7D180342-003 Work Order #...: JT6V21AA Date Sanpled...: 04/17/07 08:45 Date Received..: 04/18/07 Prep Date..... : 04/21/07 Analysis Date..: 04/26/07 Prep Batch #...: 7114515 Analysis Time..: 01:22 Dilution Factor: 1 Method......... DEN -LC-0012 Matrix. PARAMETER PFOS PFOA RESULT 0.0021 J 0.029 REPORTING LIMIT 0.010 0.015 UNITS ug/L ug/L MDL 0.0020 0.0031 SURROGATE 13C4 PFOA 13C4 PFOS PERCENT RECOVERY 77 69 RECOVERY LIMITS (50 - 200) (50 - 200) NOTE(S) :_____________ J Estimated result. Result is less than RL WATER STL Denver 9 DEP2-SDWB-000342 American Water Company Client Sample ID: DRRWTP INLET HPLC Lot-Sample #... : D7D180342 -004 Work Order #.. .: JT6V31AA Date Sampled... : 04/17/07 13:05 Date Received. .: 04/18/07 Prep Date..... : 04/21/07 Analysis Date. .: 04/26/07 Prep Batch #...: 7114515 Analysis Time. .: 01:35 Dilution Factor: 1 Method....... .: DEN -LC-0012 Matrix. PARAMETER PFOS PFQA RESULT 0.0045 J 0.0094 a REPORTING LIMIT 0.010 0.015 UNITS ug/L ug/L MDL 0.0020 0.0031 SURROGATE 13C4 PFOA 13C4 PFOS PERCENT RECOVERY 77 83 RECOVERY LIMITS (50 - 200) (50 - 200) NOTB(S) :_____________ J Estimated result. Result is less than RL. WATER STL Denver 10 DEP2-SDWB-000343 American Water Company Client Sample ID: DRRWTP PE HPIiC Lot-Sanale #. .. Date Sampled... Prep D a t e . ...... Prep Batch # __ Dilution Factor D7D180342-005 Work Order #... 04/17/07 13:05 Date Received.. 04/21/07 Analysis Date.. 7114515 Analysis Time.. 1 Method JT6V41AA 04/18/07 04/26/07 01:47 DEN -LC-0012 Matrix PARAMETER PFOS PFOA RESULT 0.0047 J 0.010 J REPORTING LIMIT 0.010 0.015 UNITS ug/L ug/L MDL 0.0020 0.0031 SURROGATE 13C4 PFOA 13C4 PFOS PERCENT RECOVERY 81 89 RECOVERY LIMITS (50 - 200) (50 - 200) MOTE(S) :_____________ J Estimated result. Result is less than RL. WATER STL Denver 11 DEP2-SDWB-000344 QC DATA ASSOCIATION SUMMARY D7D1B0342 Sample Preparation and Analysis Control Numbers SAMPLE# 001 002 003 004 005 MATRIX WATER WATER WATER WATER WATER ANALYTICAL METHOD DEN -LC-0012 DEN -LC-0012 DEN -LC-0012 DEN -LC-0012 DEN -LC-0012 LEACH BATCH # PREP BATCH # 7114515 7114515 7114515 7114515 7114515 STL Denver 12 DEP2-SDWB-000345 METHOD BLANK REPORT HPLC Client Lot #...: D7D180342 MB Lot-Sample #: R7D240000-515 Analysis Date..: 04/26/07 Dilution Factor: 1 Work Order #...: JVKEK1AA Prep Date,..... : 04/21/07 Prep Batch #...: 7114515 Matrix........ : WATER Analysis Time..: 00:17 PARAMETER PFOA PFOS RESULT ND ND REPORTING LIMIT UNITS 0.015 ug/L Q .010 ug/L METHOD DEN -LC-0012 DEN -LC-0012 SURROGATE 13C4 PFOA 13C4 PFOS PERCENT RECOVERY 68 63 RECOVERY LIMITS (50 - 200) (50 - 200) NOTB(S) :_______________________________________ Calculations are performed before rounding to avoid round-off errors in calculated results. STL Denver 13 DEP2-SDWB-000346 LABORATORY CONTROL SAMPLE EVALUATION REPORT HPLC Client Lot #... LCS Lot-Sanale# Prep Date..... Prep Batch #... Dilution Factor D7D180342 Work Order #. R7D240000-515 04/21/07 Analysis Date 7114515 Analysis Time 1 JVKEK1AC 04/26/07 00:30 Matrix PARAMETER PFOA pros PERCENT RECOVERY 120 90 RECOVERY LIMITS (70 - 130) (39 - 120) METHOD______ DEN -LC-0012 DEN -LC-0012 SURROGATE 13C4 PFOA 13C4 PFOS PERCENT RECOVERY 75 66 RECOVERY LIMITS (50 - 200) (50 - 200) NOTE(S) :_____________________________________ Calculations are performed before rounding to avoid round-off errors in calculated results. Bold print denotes control parameters WATER STL Denver 14 DEP2-SDWB-000347 LABORATORY CONTROL SAMPLE DATA REPORT HPLC Client Lot #...: D7D180342 Work Order #... LCS Lot-Sample#: R7D240000-515 Prep Date..... : 04/21/07 Analysis Date.. Prep Batch #...: 7114515 Analysis Time.. Dilution Factor: 1 JVKEK1AC 04/26/07 00:30 Matrix........ : WATER PARAMETER PFOA PFOS SURROGATE 13C4 PFOA 13C4 PFOS SPIKE AMOUNT 0.200 0.200 MEASURED AMOUNT 0.240 0.180 PERCENT RECOVERY 75 66 UNITS ug/L ug/L PERCENT RECOVERY 120 90 METHOD DEN -LC-0012 DEN -LC-0012 RECOVERY LIMITS (50 - 200) (50 - 200) NOTB(S) :_____________________________________ Calculations ate performed before rounding to avoid round-off errors in calculated results. Bold prim denotes control parameters STL Denver 15 DEP2-SDWB-000348 LABORATORY CONTROL SAMPLE EVALUATION REPORT HPLC Client Lot #...: D7D180342 Work Order #.. LCS Lot-Sample#: R7D240000-515 Prep Date..... : 04/21/07 Analysis Date. Prep Batch # __ : 7114515 Analysis Time. Dilution Factor: 1 : JVKEK1AD : 04/26/07 : 00:43 Matrix........ : WATER PARAMETER PFOA PFOS PERCENT RECOVERY 102 77 RECOVERY LIMITS (70 - 130) (39 - 120) METHOD______ DEN -LC-0012 DEN -LC-0012 SURROGATE 13C4 PFOA 13C4 PFOS PERCENT RECOVERY 56 47 * RECOVERY LIMITS (50 - 200) (50 - 200) NOTE(S) :_____________________________________ Calculations are performed before rounding to avoid round-off errors in calculated results. Bold print denotes control parameters * Surrogate recovery is outside stated control limits. STL Denver 16 DEP2-SDWB-000349 LABORATORY CONTROL SAMPLE DATA REPORT HPLC Client Lot #...: D7D180342 Work Order #.. LCS Lot-Sample#: R7D240000-515 Prep Date..... : 04/21/07 Analysis Date. Prep Batch #...: 7114515 Analysis Time. Dilution Factor: 1 JVKEK1AD 04/26/07 00:43 Matrix........ : WATER PARAMETER PFOA PFOS SPIKE AMOUNT 0.0200 0.0200 MEASURED AMOUNT 0.0205 0.0153 UNITS ug/L ug/L PERCENT RECOVERY 102 77 METHOD DEN -LC-0012 DEN -LC-0012 SURROGATE 13C4 PFOA 13C4 PFOS PERCENT RECOVERY 56 47 * RECOVERY LIMITS (50 - 200) (50 - 200) NOTE (S) :_____________________________________ Calculations are performed before rounding to avoid round-off errors in calculated results. Bold print denotes control parameters * Surrogate recovery is outside stated control limits. STL Denver 17 DEP2-SDWB-000350 Chain of Custody Record STL-4124 (0901) STLS E V F R N TRENT Severn Trent Laboratories, Inc. STL Denver 4955 Yarrow Street Arvada, CO 80002 IO CO o o o DEP2-SDWB-I LC/MS Supporting Documentation Sample Sequence, Chromatograms/Mass Spectra STL Lot ID: D I D 17 0 3 tM - Client: ktoMAat. tiladfA Method:_______ f F o A ( 'f-OS_________ ______ Associated Samples:_________ * ^ _______________________ Batch #(s):________ 1 H QrS l< ^____________________ I certify that, to the best o f my knowledge, the attachedpackage represents a complete and accurate copy o f the original data. Q foQ U *ttSignature/Date:_ 5 -4 -0 7 STL Denver 19 DEP2-SDWB-000352 LC/MS SEMIVOLATILE ORGANIC EXTRACTION LOG SHEETS DEP2-SDWB-000354 N RQC058 Severn Trent Laboratories, Inc. EXTRACTION BENCH WORKSHEET LEV LEV LEV LEV Y Y Blank Y Y weignts/volumes 7 7 Check 7 7 Spike & Surrogate Worksheet - MS/MSD 7 7 Vial contains correct volume 7 7 Labels, greenbars, worksheets computer batch: correct & all match Y Y Anomalies to Extraction Method Extractionist: 003601 Jaqueline Bonnett Concentrationistn OTF3601 Jaqueline Bonnett ************************ * ** QC BATCH: 7114515 ** ************************ Run Date: 4/24/07 Time: 4:27 Expanded Deliverable C_O_C__C_omIpD_le_t_e_d _ Bench Sheet Copied _ Package Submitted to Anal^ticalGroup Bench Sheet Copied per CO PREP DATE: 4/21/07 19:00 COMP DATE: 4/21/07 23:30 Reviewer/Date: BONNETJA / 4/24/07 BYTP AMT, T .r v r a MRRTTN# / TEST EXPR _DUE WORK ORDER FLGS EXT MTH MATRIX D7D180342-001 4/24/07 4/30/07 JT6V0-1-AA DR B7 H5 WATER COMMENTS: LC/MS/MS, PFOA SOLID PHASE EXTRACTION (NOMINAL) INIT/FIN PH"S SOLVENTS WT/VOL INIT RDJT ADJ2 EXTRACTION VOL~EXCHANGE 256mL 7.0 2.0 NA MEOH 5.00mL 4.0 SPIKE STANDARD/ VOL SURROGATE ID .0 1ML LCMS0039 04.24.07 D7D180342-002 4/24/07 4/30/07 JT6V1-1-AA DR B7 H5 WATER COMMENTS: 240mL 5.OOmL 7.0 2.0 NA MEOH 4.0 .0 1ML LCMS0039 04.24.07 D7D180342-003 4/24/07 4/30/07 TT6V2-1-AA DR B7 H5 WATER COMMENTS: 253mL 5.OOmL 7.0 2.0 NA MEOH 4.0 .0 1ML LCMS0039 04.24.07 D7D180342-004 4/24/07 4/30/07 JT6V3-1-AA DR B7 H5 WATER COMMENTS: 251mL 5.OOmL 7.0 2.0 NA MEOH 4.0 .0 1ML LCMS003 9 04.24.07 D7D180342-005 4/24/07 4/30/07 JT6V4-1-AA DR B7 H5 WATER COMMENTS: 244mL 5,OOmL 7.0 2.0 NA MEOH 4.0 .0 1ML LCMS0039 04.24.07 R7D240000-515 4/24/07 0/00/00 JVKEK-l-AAB COMMENTS: B7 H5 WATER 250mL 7.0 2.0 NA MEOH 5.OOmL 4.0 .0 1ML LCMS0039 04.24.07 R7D240000-515 4/24/07 0/00/00 JVKEK-1-ACC COMMENTS: B7 H5 WATER 250mL 7.0 2.0 NA MEOH 5.OOmL 4.0 .0 1 ML LCMS0028 04.18.07 1 LCMS0039 04 .24.07 W >t <D p p CD DEP2-SDWB-000355 (N CN RQC058 EXTR EXPR ANL LOT#,MSRUN#/ TEST DUE WORK ORDER FLGS R7D240000-515 4/24/07 0/00/00 JVKEK-l-ADC COMMENTS: Severn Trent Laboratories, Inc. EXTRACTION BENCH WORKSHEET *************'*******-**** ** * QC BATCH: 7114515 * ** *************'*+******** Run Date: 4/24/07 Time : 4:27 PREP DATE: 4/21/07 19:00 COMP DATE: 4/21/07 23:30 INIT/FIN PH"S SOLVENTS SPIKE STANDARD/ EXT MTH MATRIX WT/VOL INIT ADJT ADJ2 EXTRACTION VOL EXCHANGE VOL SURROGATE ID B7 H5 WATER 250ml. 7.0 2.0 NA MEOH 5.OOmL 4.0 .0 0.1 ML LCMS0028 04.18.01 1 LCMS0039 04.24.07 DEN-LC-0012 MEOH:C34E61 BAL:M27995 S/S:JCB-C W:KH H20:ELGA CART:0715906 SHARE-WITH 7114514 r _ RUSH c = CLP E = EPA 600 D = EXP.DEL) M = CLIENT REQ MS/MSD NUMBER OF WORK ORDERS IN BATCH: 8 Q) >fi (0 P P E-* W LC/MS SEMIVOLATILE STANDARD DATA STL Denver 23 DEP2-SDWB-000356 Quantify Calibration Report MassLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA. PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Method: C:\MassLynx\PFOA.PRO\MethDB\pF37d25.mdb 26 A pr 2007 07:49:52 Calibration: C:\MassLynx\Picric Acid.PRO\CurveDB\pf37d25.cdb 27 A pr 2007 10:20:34 Compound name: PFOA Coefficient of Determination: RA2 = 0.998734 Calibration curve: -0.00519466 * xA2 + 0.937722 * x + 0.00484394 Response type: Internal Std ( Ref 3 ), Area * ( IS Cone. / IS Area ) Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None Pa9 1 of 5 ^ m _________________ DEP2-SDWB-000357 Quantify Calibration Report MassLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA.PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Compound name: APFO Coefficient of Determination: RA2 = 0.998736 Calibration curve: -0.00479134 * xA2 + 0.900692 * x + 0.00509623 Response type: Internal Std ( Ref 3 ), Area * ( IS Cone. / IS Area ) Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None Analyst: Mark Dymerski DEP2-SDWB-000358 Page 2 of 5 i_n CM 1 1 1 111 [ U 11 p i 1 1 1 1 1 1 1 1 1111111 12.0 13.0 14.0 i i j i 11 i i r n r f i i t i |r i 1 1 ; 111 i | r n r y n- 15.0 16.0 17.0 18.0 U cu ' i >1111111111111 ri i C o n e 19.0 20.0 53 p p CO Quantify Calibration Report MassLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA.PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Compound name: PFOA 13C4 Response Factor. 1725.07 RRF SD: 132.825, % Relative SD: 7.69967 Response type: External Std, Area Curve type: RF Analyst: Mark Dymerski DEP2-SDWB-000359 Page 3 of 5 O) X ' I - r -v - i- l i . I i i i I l i ' I i T ' 1 I1 6.5 7.0 7.5 8.0 8.5 9.0 9.5 U 0) one Quantify Calibration Report MassLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA. PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Compound name: PFOS Coefficient of Determination: RA2 = 0.998746 Calibration curve: -0.0055757 * xA2 + 1.05667 * x + 0.00530869 Response type: Internal Std ( Ref 5 ), Area * ( IS Cone. / IS Area ) Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None Analyst: Mark Dymerski DEP2-SDWB-000360 Page 4 of 5 e'~ CN I " " I " Il I i i i i I I I I I I II i I I n i i I i I I I I I-I i i I i i I i |11 11.0 12.0 13.0 14.0 15.0 i i ~i 1 1 1 1 1 1 1 1 1 1 1 1 1 16.0 17.0 (L> TT-J-TT Tj I I I I I I I I TrTrTl one 18.0 19.0 20 Q Eh W Quantify Calibration Report MassLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA.PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Compound name: PFOS 13C4 Response Factor: 1137.47 RRF SD: 89.2906, % Relative SD: 7.8499 Response type: External Std, Area Curve type: RF Analyst: Mark Dymerski DEP2-SDWB-0I Page 5 of 5 00 OJ <co o o X X U 0) ~~Tn T T 1 l~r~r~^' iT 1 i--| abone $6.5 7.0 7.5 8.0 8.5 9.0 9.5 10 Q Eh CO DEP2-SDWB-000362 Quantify Sample Report MassLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA.PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Method: C:\MassLynx\PFOA.PRO\MethDB\pF37d25.mdb 26 Apr 2007 07:49:52 Calibration: C:\M assLynx\Picric Acid.PRO\CurveDB\pf37d25.cdb 27 Apr 2007 10:20:34 Name: pf37d2501, Date: 25-Apr-2007, Time: 17:10:00, ID: 923.79.1, Description: Blank PFOA MRM of 6 channels,ES412.7 >369 PFOA MRM of 6 channels.ES412.7 > 169.0 APFO PaSe 1 of 58 ^ cm ________________ MRM of 6 channels,ES412.7 > 369 PFOA 13C4 MRM of 6 channels,ES416.8 > 372 PFOS MRM of 6 channels,ES498.6 > 80 Analyst: Mark Dymerski (U > CL) Q E-i CO DEP2-SDWB-000363 Quantify Sample Report M assLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA.PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Name: pf37d2501, Date: 25-Apr-2007, Time: 17:10:00, ID: 923.79.1, Description: Blank PFOS MRM of 6 channels,ES498.6>98.9 PFOS 13C4 MRM o f 6 channels,ES- 502.6 > 80 PFOS 13C4 3.596e+004 8.49 1 12177.33 111111111I I I I j I I n j 'l I I I j'TTT'l ) I I I I | I I Ii'i1111111111 min 2.0 4.0 6.0 8.0 10.0 Page2 of 58 0 ^ ________________ Analyst: Mark Dymerski U <u (U p P Eh W Quantify Sample Report MassLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA.PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Name: pf37d2502, Date: 25-Apr-2007, Time: 17:22:52, ID: 923.79.2, Description: 0.2 pg/L PFOA MRM of 6 channels,ES412.7 > 369 PFOA 100-1 MRM o f 6 channels,ES- 412.7 > 169.0 PFOA PF0A 7.77 7.77 164.95 164.95 If 6.553e+002 APFO 10.28 11.40 APFO 100-, %- 0 - 1 1MT'| I M 111 11 ' 11111| 11 1111111; 1111I 1n 111111p i n I I 11111) 11 m i n 2.0 4.0 6.0 8.0 10.0 MRM of 6 channels,ES- APFO 7.77 164.95 APFO 7.77 164.95 412.7 > 169.0 6.553e+002 PFOA13C4 PFOS 415 375MRM of 6 channels,ES.Ri 10.28 11.40 o " 1' I' r, IIII T T T T JT I 2.0 4.0 min1111 I I i l I J I M I J I M I I m i I I m I 111 I 6.0 8.0 10.0 Analyst: Mark Dymerski PaQe 3 f 58 m ________________ MRM o f 6 channels,ES412.7 >369 MRM of 6 channels,ES498.6 > 80 U cu > <u p p Ui DEP2-SDWB-000364 DEP2-SDWB-000365 Q uantify Sample Report M assLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA.PRCApf37d252.qld Last Altered: Friday, April 27, 200710:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Name: pf37d2502, Date: 25-Apr-2007, Time: 17:22:52, ID: 923.79.2, Description: 0.2 pg/L PFOS PFOS 13C4 MRM of 6 channels,ES- 498.6>98.9 MRM of 6 channels,ES- 502.6 >80 Page 4 of 58 CN CO Analyst: Mark Dymerski Vi 0) 0) Q iJ Eh m DEP2-SDWB-000366 Quantify Sample Report M assLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA.PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Name: pf37d2503, Date: 25-Apr-2007, Time: 17:35:51, ID: 923.79.3, Description: 0.5 pg/L PFOA MRM of 6 channels,ES412.7 >369 PFOA MRM of 6 channels,ES412.7 > 169.0 APFO Page 5 of 58 M m ________________ MRM of 6 channels,ES412.7 > 369 APFO MRM of 6 channels,ES412.7 > 1GS.0 PFOA13C4 PFOS 372MRM of 6 channels,ES4i a. * MRM of 6 channels,ES498.6 > 80 Analyst: Mark Dymerski h 0) > <D P P Eh W Quantify Sample Report MassLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA. PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Name: pf37d2503, Date: 25-Apr-2007, Time: 17:35:51, ID: 923.79.3, Description: 0.5pg/L PFOS MRM of 6 channels,ES498.6>98.9 PROS 13C4 MRM of 6 channels,ES502.6 > 80 1 PFOA 2 APFO 3 PFOA13C4 4 PFOS 5 PFOS 13C4 7.82 826.403 bb 7.82 826.403 bb 7.80 19798.521 bb 8.38 611.677 bb 8.35 12746.258 bb 19798.521 19798.521 12746.258 3 0.417 3 0.417 0 19798.521 5 0.480 0 12746.258 0.441 0.459 11.477 0.450 11.206 88.2 68.2 114.8 90.0 112.1 Analyst: Mark Dymerski Page 6 of 58 ^ ro U <D > <U Q P H m DEP2-SDWB-000367 DEP2-SDWB-000368 Quantify Sample Report MassLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA. PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Name: pf37d2504, Date: 25-Apr-2007, Time: 17:48:49, ID: 923.79.4, Description: 1 pgfl- PFOA MRM of 6 channels,ES412.7 > 369 PFOA MRM of 6 channels,ES412,7 > 169.0 APFO Page 7 of 58 m MRM of 6 channels,ES412.7 > 369 APFO MRM of 6 channels,ES412.7 > 169.0 PFOA13C4 MRM of 6 channels,ES416.8 > 372 PFOS MRM of 6 channels,ES498 6 > 80 I Analyst: Mark Dymerski U <U > cu Q E-i CO Quantify Sample Report MassLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA.PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Name: pf37d2504, Date: 25-Apr-2007, Time: 17:48:49, ID: 923.79.4, Description: 1 pg/L PFOS MRM of 6 channels,ES- 498.6>98.9 PFOS 2.674e+003 8.35 I 862.15 PFOS 13C4 100-, MRM of 6 channels,ES- 502.6 > 80 PFOS 13C4 3.279e+004 8.35 1 11071.15 %- %- 4 i_ i|--------- ------ . lL| I " " '| .................. min 2.0 4.0 6.0 8.0 10.0 0 ` n i q ii 111 r n q 11n 1 11 1 1 | 11 1 1 11 1` 2.0 4.0 6.0 min 10.0 Analyst. Mark Dymerski Page 8 of 58 ^ n CU (U p p HCO DEP2-SDWB-000369 DEP2-SDWB-000370 Q uantify Sample Report MassLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA.PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27,2007 10:24:05 AM Mountain Daylight Time Name: pf37d2505, Date: 25-Apr-2007, Tim e: 18:01:46, ID: 923.79.5, Description: 2 pg/L PFOA MRM of 6 channels,ES412.7 >369 PFOA MRM of 6 channels,ES412.7 > 169.0 APFO PaQe 9 of 58 ^ m _______________ MRM of 6 channels,ES412.7 > 369 APFO MRM of 6 channels,ES412.7 > 169.0 PFOA 13C4 372MRM of 6 channels,ESA'tc n > PFOA13C4 7.74 17205.79 6.010e+004 PFOS %- 0 1111 j 11111 ii 111 m i'i 11 2.0 4.0 t r f rI l I | I IT I f 6.0 8.0 i i p 'n i y i m - min 10.0 Analyst: Mark Dymerski MRM of 6 channels.ES498.6 > 80 <0 i> d<U Q J H W Quantify Sample Report MassLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA.PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27,2007 10:24:05 AM Mountain Daylight Time Name: pf37d2505, Date: 25-Apr-2007, Time: 18:01:46, ID: 923.79.5, Description: 2 pg/L PFOS MRM of 6 channels,ES498.6>98.9 PFOS 13C4 MRM of 6 channels,ES502.6 > 80 Page 10 of 58 m ro _______________ Icso-. o DEP2-SDWB-I Analyst: Mark Dymerski (U > c (U o IH DEP2-SDWB-000372 Q uantify Sample Report MassLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA.PRO\pf37d252.qld Last Altered: Friday. April 27,2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Name: pf37d2506, Date: 25-Apr-2007, Time: 18:14:43, ID: 923.79.6, Description: 5 pg/L PFOA MRM of 6 channels,ES412.7 > 369 PFOA MRM o f 6 channels, ES412.7 > 169.0 APFO Page 11 of 58 cr\ ro MRM of 6 channels,ES412.7 369 APFO MRM of 6 channels,E S412.7 > 163.0 PFOA13C4 MRM of 6 channels,ES41 fl> 372 PFOS MRM of 6 channels,ES498.6 > 80 Analyst: Mark Dymerski U 0) 0) p P H CO Quantify Sample Report M assLynx4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA.PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Name: pf37d2506, Date: 25-Apr-2007, Time: 18:14:43, ID: 923.79.6, Description: 5 pg/L PFOS MRM of6 channels,ES498.6>98.9 PFOS 13C4 100-, MRM of6 channels,ES- 502.6> 80 PFOS 13C4 4.107e+004 8.33 12488.09 11111111111111111111111 2.0 4.0 6.0 L 8.0 10.0 Analyst: Mark Dymerski Page 12 of 58 0 ^ IH 0) > c aj P p cn DEP2-SDW B-000373 DEP2-SDWB-000374 Quantify Sample Report MassLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA.PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Name: pf37d2507, Date: 25-Apr-2007, Time: 18:27:39, ID: 923.79.7, Description: 10 pg/L PFOA 100-1 MRM of 6 channels,ES- 412.7 >369 PFOA 4.894e-i-004 7.74 1 14644.25 PFOA MRM of 6 channels,ES412.7 > 169.0 APFO 100-, %- %- Page 13 of 58 ^ MRM of 6 channels,ES- 412.7 >369 APFO 4.894e+004 7.74 I 14644.25 0 - 1111 p f r r p I i l 11 1111 1111 j 11 1 1 1......|W i I ) r n r ) r i T i | r riTjTii-i mm 2.0 4.0 6.0 8.0 10.0 APFO MRM of 6 channels,ES412.7 > 163.0 PFOA13C4 100-] %- " I .......111 i n ill 11iFm r l r rrh Ih h Imi min 2.0 4.0 6.0 8.0 10.0 MRM of 6 ch-4Ta4IneVn.Uael*"s.,EUIS4- PFOA13C4 5.752e+004 7.74 1 17237.65 PFOS MRM of 6 channels,ES- 498.6 > 80 PFOS 3.091e+004 8.33 1 10281.08 %- Analyst: Mark Dymerski 11rp Ti I r i j' 11 i | In i'p ri r| In q r r i i [ 111i |i u 2.0 4.0 6.0 8.0 10.0 111111111111111111111111111 2.0 4.0 6.0 Il{iIir;A 1111m -p111 min 8.0 10.0 ^i <u <L> P P E-i CO DEP2-SDWB-000375 Quantify Sample Report MassssLLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOAPRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Name: pf37d2507, Date: 25-Apr-2007, Time: 18:27:39, ID: 923.79.7, Description: 10pg/L PFOS PFOS 13C4 MRM of 6 channels,ES- 498.6>98.9 MRM of 6 channels,ES- 502.6 > 80 Page 14 of 58 O] Analyst: Mark Dymerski U<v > a <u Q Eh CO Quantify Sample Report M assLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA. PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27,2007 10:24:05 AM Mountain Daylight Time Name: pf37d2508, Date: 25-Apr-2007, Time: 18:40:36, ID: 923.79.8, Description: 20 pg/L PFOA MRM of 6 channels,ES- 412.7 > 369 PFOA 9.781e+004 7.71 29086.56 PFOA MRM of 6 channels,ES412.7 > 169.0 APFO %- 0-L r 11111 n ITri 1111111111111111 2.0 4.0 6.0 APFO 111111111 rri min 8.0 10.0 MRM of 6 channels,ES412.7 > iS. PFOA 13C4 100- MRM of 6 channels,ES- PFOA 13C4 7.71 17303.53 1 5.887e+004 PFOS 1 1 1 1 1 1 1 1 li 11T 1111 n 11 2.0 4.0 m -p n 6.0 11> 111 ; 11 n j n I"i I j 111 min 8.0 10.0 Analyst: Mark Dymerski Page 15 of 58 M ^ ______________ MRM of 6 channels.ES412.7 >369 MRM of 6 channels,ES4S8.6 > 80 U 0) a0) J Eh CO DEP2-SDWB-000376 Quantify Sample Report MassLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA. PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Name: pf37d2508, Date: 25-Apr-2007, Time: 18:40:36, ID: 923.79.8, Description: 20 pg/L PFOS MRM of 6 channels,ES498.6>98.9 PFOS13C4 MRM of 6 channels.ES502.6 > 80 1 PFOA 2 APFO 3 PFOA13C4 4 PFOS 5 PFOS 13C4 S i.v# Au hi . .K t.-'i 7.71 7.71 7.71 8.30 8.30 29086.564 29086.564 17303.525 19902.998 10445.627 bb bb bb bb bb 17303.525 17303.525 10445.627 3 16.810 3 16.81 U 0 17303.525 5 19.054 0 10445.627 20.176 21.004 10.031 20.175 9.183 100.9 100.9 100.3 100.9 91.8 Analyst: Mark Dymerski Page 16 of 58 _ <D > a<u cFoh DEP2-SDWB-000377 DEP2-SDWB-000378 Quantify Sample Report M assLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA.PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Name: pf37d2509, Date: 25-Apr-2007, Time: 18:53:34, ID: 923.79.1, Description: Blank PFOA MRM o f 6 channels,ES412.7 > 369 PFOA MRM o f 6 channels,ES412.7 > 169.0 APFO Pa9e 17 of 58 m ^ _______________________ MRM o f 6 channels,ES412.7 > 369 APFO MRM of 6 channels,ES412.7 > 169.0 PFOA13C4 100-, MRM of 6 channels,ES- 416.8 > 372 PFOA 13C4 4.960e+004 7.71 1 14757.61 PFOS 0 m 11MITfTT 2.0 1 1 1 111 1 1 1 11r I m i f h i 11 m 1 1 1 1 1 11 1 1111 m i min 4.0 6.0 8.0 10.0 Analyst: Mark Dymerski MRM of 6 channels,ES498.6 80 U 0) <D P p Eh U1 Quantify Sample Report M assLynx 4.1 PFOA Analysis Dataset: C:\MassLynxVPFOA.PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Name: pf37d2509, Date: 25-Apr-2007, Time: 18:53:34, ID: 923.79.1, Description: Blank PFOS PFOS 13C4 MRM of 6 channels,ES- 498.6>98.9 MRM of 6 channels.ES- 502.6 > 80 0 I " ' | " " f " 1H 11I 1I " " I 1" I " " I " M I " " I " " I " 1' I " 1 2.0 4.0 6.0 8.0 10.0 Analyst: Mark Dymerski Page 18 of 58 ^ ^ U <D > C 0) Q Eh CO DEP2-SDWB-000379 DEP2-SDWB-000380 Quantify Sample Report MassLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA. PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Name: pf37d2510, Date: 25-Apr-2007, Time: 19:06:31, ID: 923.79.10, Description: 2 pg/L ICV PFOA MRM of 6 channels,ES412.7 > 369 PFOA MRM of 6 channels,ES412.7 > 169.0 APFO Page 19 of 58 MRM of 6 channels,ES412.7 > 369 APFO MRM of 6 channels,ES412.7 > 169.0 PFOA13C4 100-, MRM of 6 channels,ES- 416.8 > 372 PFOA 13C4 5.125e+004 7.71 " j 14937.06 PFOS %- 0 1111n In 11 1111111111111,,,11m ,|^i11;11111111111111 min 2.0 4.0 6.0 8.0 10.0 Analyst: Mark Dymerski MRM of 6 channels,ES498.6 > 80 l-i (1) > <D Q j EH CO DEP2-SDWB-I Quantify Sample Report MassLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA.PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 200710:24:05 AM Mountain Daylight Time Name: pf37d2510, Date: 25-Apr-2007, Time: 19:06:31, ID: 923.79.10, Description: 2 pgfL ICV PFOS MRM of 6 channels,ES498.6>98.9 PFOS 13C4 100-1 MRM of 6 channels,ES- 502.6 > 80 PFOS 13C4 3.548e+004 8.33 1 11176.79 %- 0 11111111111111111111 n 2.0 4.0 "T11I6T1.0ri"iiIin8rt.0ni h li 111111TP111 10.0 min Page 20 of 58 oo ^ _______________ 00 CO o o o Analyst: Mark Dymerski <U > 0) Q E-i CO DEP2-SDWB-000382 Quantify Sample Report M assLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA.PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Name: pf37d2511, Date: 25-Apr-2007, Time: 19:19:27, ID: 923.79.3, Description: 0.5 pg/L RLV PFOA MRM of 6 channels,ES412.7 >369 PFOA MRM of 6 channels,ES412.7 > 169.0 APFO Page 21 of 58 ^ ____ MRM of 6 channels,ES412.7 > 369 APFO MRM of 6 channels,ES412.7 > 1C9.0 PFOA 13C4 MRM of 6 channels,ES416.8 > 37? PFOS MRM of 6 channels,ES498.6 > 80 Analyst: Mark Dymerski U <U <L> P P Eh W Quantify Sample Report MassLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA-PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Name: pf37d2511, Date: 25-Apr-2007, Time: 19:19:27, ID: 923.79.3, Description: 0.S pg/L RLV PFOS MRM of 6 channels,ES498.6>98.9 PFOS 13C4 MRM of 6 channels,ES502.6 > 80 PFOA ! APFO 3 PFOA 13C4 4 PFOS 5 PFOS 13C4 7.74 817.875 bb 7.74 817.875 bb 7.71 19625.471 bb 8.30 585.559 bb 8.30 12480.418 bb 19625.471 19625.471 12480.418 3 0.417 3 0.417 0 10625.471 5 0.469 0 12480.418 0.440 0.458 11.377 0.440 10.972 88.1 88.1 113.8 88.0 109.7 Analyst: Mark Dymerski Page 22 of 58 0 w Vi o > o Q Eh CO DEP2-SDWB-000383 DEP2-SDWB-000384 Quantify Sample Report MassLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA.PROVpf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Name: pf37d2533, Date: 26-Apr-2007, Time: 00:04:21, ID: 923.79.5, Description: 2 pgSL CCV PFOA MRM of 6 channels,ES412.7 > 369 PFOA MRM of 6 channels,ES412.7 > 169.0 APFO Page 23 of 58 m MRM of 6 channels,ES412.7 > 369 APFO MRM o f 6 channels,ES412.7 > 169.0 PFOA13C4 100-i MRM of 6 channels,ES- 416 B > 372 PFOA 13C4 5.586e+004 ]7.66 16745.74 PFOS %- i i i H i i i i }Tt r q n 1 1 1 1 1 r i | i i 11 pi 11 2.0 4.0 6.0 im i 11 it 11 in min a.o 10.0 Analyst: Mark Dymerski MRM of 6 channels,ES498.6 > 80 <D > <D P P Eh CO Quantify Sample Report MassLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA.PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Name: pf37d2533, Date: 26-Apr-2007, Time: 00:04:21, ID: 923.79.5, Description: 2 pg/L CCV PFOS MRM of 6 channels,ES498.6>98.9 PFOS 13C4 MRM of 6 channels,ES502.6 > 80 1 PFOA 2 APFO 3 PFOA 13C4 4 PFOS 5 PFOS13C4 7.66 7.66 7.66 8.27 8.24 3284.399 3284.399 16745.744 2141.343 10509.598 bb bb bb bb bb 16745.744 16745.744 10509.598 3 1.961 3 1.861 0 16745.744 5 2.038 0 10509.598 2.111 2.198 9.707 1.943 9.239 105.6 105.6 97.1 97.2 92.4 Analyst: Mark Dymerski Page 24 of 58 ^ m CU Ct (U Q .-3 Ui DEP2-SDWB-000385 DEP2-SDWB-000386 Quantify Sample Report MassLynx 4.1 PFOA Analysis : Dataset: C:\MassLynx\PFOA. PRO\pf37d252.qld ' Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Name: pf37d2542, Date: 26-Apr-2007, Time: 02:00:55, ID: 923.79.4, Description: 1 pg/L CCV PFOA MRM of 6 channels,ES412.7 > 369 PFOA MRM of 6 channels,ES412.7 > 169.0 APFO Page 41 of 58 M _________ MRM of 6 channels,ES412.7 > 369 APFO MRM of 6 channels,ES412.7 > 169.0 PFOA13C4 100-, MRM of 6 channels,ES- 416.8 > 372 PFOA 13C4 5.777e+004 7.63 1 17049.24 PFOS %- 0 m 1 1 1 1i i 1 11 2.0 rrjT T 4.0 r T ] 'r r 6.0 11111in 11m i min 10.0 Analyst: Mark Dymerski MRM o f 6 channels,ES- 496 6 > fiO aj > C <u P p Eh W Quantify Sample Report M assLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOAPRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Name: pf37d2542, Date: 26-Apr-2007, Time: 02:00:55, ID: 923.79.4, Description: 1 pg/L CCV PFOS MRM of 6 channels.ES498 6>98 9 PFOS 13C4 MRM of 6 channels,ES502.6 > 80 1 PFOA 2 APFO 3 PFOA 13C4 4 PFOS 5 PFOS 13C4 7.66 1643.499 bb 7.66 1643.499 bb 7.63 17049.244 bb 8.24 1058.437 bb 8.24 10097.919 bb 17049.244 17049.244 10097.919 3 0.964 3 0.964 0 17049.244 5 1.048 0 10097.919 1.029 1.0/1 9.883 0.992 8.877 102.9 102.9 98.8 99.2 88.8 Analyst Mark Dymerski Pa9 42 of 58 ^ m ________________ cu <D O Ecn-i DEP2-SDWB-000387 DEP2-SDWB-000388 Quantify Sample Report MassLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA.PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Name: pf37d2562, Date: 26-Apr-2007, Time: 06:19:56, ID: 923.79.1, Description: Blank PFOA MRM of 6 channels,ES412.7 >369 PFOA MRM of 6 channels,ES412.7 > 169.0 APFO Pa9e 43 of 58 ^ ^ __________ _______________ MRM of 6 channels,ES412.7 > 369 APFO MRM of 6 channels,ES412.7 > 169.0 PFOA13C4 MRM of 6 channels,ES416.8 > 377 PFOS MRM of 6 channels,ES498.6 > 80 Analyst: Mark Dymerski U <U 0) p p E-i CO DEP2-SDWB-000389 Q uantify Sample Report MassLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA.PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27,2007 10:24:05 AM Mountain Daylight Time Name: pf37d2562, Date: 26-Apr-2007, Time: 06:19:56, ID: 923.79.1, Description: Blank PFOS PFOS13C4 MRM of 6 channels,ES- 498.6>98.9 MRM of 6 channels,ES- 502.6 > 80 Pa9e 44 of 58 ^ m _______________ Analyst: Mark Dymerski (D > G a03 Eh 03 DEP2-SDWB-000390 Quantify Sample Report M assLynx4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA.PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Name: pf37d2563, Date: 26-Apr-2007, Time: 06:32:52, ID: 923.79.2, Description: 0.2 pg/L PFOA MRM of 6 channels,ES412.7 > 369 PFOA MRM of 6 channels,ES412.7 > 169.0 APFO Page 45 of 58 ^ m MRM of 6 channels,ES412.7 > 369 APFO MRM of 6 channels,ES412.7 > 169.0 PFOA 13C4 100-i PFOA 13C4 7.60 15384.20 MRM of 6 channels,ES418.8 > 372 4.738e+004 PFOS %- 0 r r n j n n 1111 m 11111| 2.0 4.0 6.0 111 j in |r n i min 10.0 Analyst: Mark Dymerski MRM of 6 channels,ES438.6 > 80 Q) > P(U Q U) DEP2-SDWB-I --------- Quantify Sample Report M assLynx 4.1 PFOA Analysis Dataset: C:\MassLynxVPFOA.PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Name: pf37d2563, Date: 26-Apr-2007, Time: 06:32:52, ID: 923.79.2, Description: 0.2 pg/L PFOS PFOS 13C4 MRM of 6 channels,ES- 498.6>98.9 MRM o f 6 channels,ES- 502.6 > 80 ,,3Page 46 of 58 m 0> CO o oo Analyst: Mark Dymerski <u <D P P Eh Ui DEP2-SDWB-000392 | Quantify Sample Report M assLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA.PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27,2007 10:24:05 AM Mountain Daylight Time Name: pf37d2564, Date: 26-Apr-2007, Time: 06:45:50, ID: 923.79.3, Description: 0.5 pg/L PFOA MRM of 6 channels,ES412.7 >369 PFOA MRM of 6 channels,ES412.7 > 169.0 APFO Pa9e f 58 cri 10 ______________________ MRM of 6 channels,ES412.7 > 369 APFO MRM of 6 channels,ES412.7 > 169.0 PFOA 13C4 100-1 PFOA13C4 7.60 18809.58 MRM of 6 channels,ES- 416.8 >372 5.861e+004 PFOS %- 0 *Ttn 1111111111 I Hm r( T11111 1 n I n 11 piL4111111 1 11111 1111 min 2.0 4.0 6.0 8.0 10.0 Analyst: Mark Dymerski MRM of 6 channels.ES498.6 > 80 U <D 50) p p E-i CO DEP2-SDWB-000393 Quantify Sample Report MassLynx 4.1 PFOA Analysis Dataset: C:\MassLynxVPFOA.PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Name: pf37d2564, Date: 26-Apr-2007, Time: 06:45:50, ID: 923.79.3, Description: 0.5 pg/L PFOS MRM of 6 channels,ES498.6>98.9 PFOS 13C4 MRM of 6 channels,ES- 502.6 > 80 PFOS 13C4 3.339e+004 8.21 1 11909.62 0 M I I | I I I I | I I I I |' ll\ 11aI I | I I M | M I I | I 11 r |T T rn'i 11i'i cttt min 2.0 4.0 6.0 8.0 10.0 Page 48 of 58 0 ________________ Analyst: Mark Dymerski <D (U Q Eh CO DEP2-SDWB-000394 Quantify Sample Report MassLynx 4.1 PFOA Analysis Dataset: C:\MassLynxVPFOA.PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Name: pf37d2565, Date: 26-Apr-2007, Time: 06:58:47, ID: 923.79.4, Description: 1 pg/L PFOA MRM of 6 channels,ES412.7 > 369 PFOA MRM of 6 channels,ES412.7 >169.0 APFO Page 49 of 58 H MRM of 6 channels,ES412.7 > 369 APFO MRM of 6 channels,ES412.7 > 169.0 PFOA13C4 PFOA13C4 7.60 16017.90 MRM of 6 channels,ES416.8 > 372 5.086e+004 PFOS %- 0 `ru i f i ) 1 1 1 1 n r ) r m - f n 111111;11111^' Tl p T i ) | I I 11 I 11 ri'ITTT min 2.0 4.0 6.0 8.0 10.0 Analyst: Mark Dymerski MRM of 6 channels,ES498.6 > 80 <L> > (U P P 03 Quantify Sample Report MassLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA.PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Name: pf37d2565, Date: 26-Apr-2007, Time: 06:58:47, ID: 923.79.4, Description: 1 pg/L PFOS MRM of 6 channels,ES498.6>98.9 PFOS13C4 100-1 MRM of 6 channels,ES- 502.6 > 80 PFOS 13C4 2.9000+004 8.19 1 10263.71 %- 0 ' 'I I I I I I I |T I |Tm fri 111n 11 1111 1 111 )/ 1Mn | i i 111111 n i7 n min 2.0 4.0 6.0 8,0 10.0 Analyst: Mark Dymerski Page 50 of 58 ^ <U <u Q CO DEP2-SDWB-000395 DEP2-SDWB-000396 Quantify Sample Report MassLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA.PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Name: pf37d2566, Date: 26-Apr-2007, Time: 07:11:43, ID: 923.79.5, Description: 2 pg/L PFOA MRM of 6 channels, ES412.7 > 369 PFOA MRM of 6 channels,ES412.7 > 169.0 APFO Page 51 of 58 m MRM of 6 channels,ES412.7 > 369 APFO MRM of 6 channels, ES412.7 > 169.0 PFOA 13C4 MRM of 6 channels,ES416.8 > 372 PFOS MRM of 6 channels,ES493.6 > 80 Analyst: Mark Dymerski Vi (U > tu Q E-i 05 DEP2-SDWB-000397 Quantify Sample Report MassLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOAPRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Name: pf37d2566, Date: 26-Apr-2007, Time: 07:11:43, ID: 923.79.5, Description: 2 pg/L PFOS MRM of 6 channels,ES498.6>98.9 PFOS13C4 MRM of 6 channels,ES502.6 > 80 Pa<3e 52 of 58 ^ ^ _________________ Analyst: Mark Dymerski (U (L> Q DEP2-SDWB-000398 Q uantify Sample Report MassLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA. PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Name: pf37d2567, Date: 26-Apr-2007, Time: 07:24:40, ID: 923.79.6, Description: 5 pg/L PFOA MRM of 6 channels,ES412.7 >369 PFOA MRM of 6 channels,ES412.7 >169.0 APFO Page 53 of 58 LD CD MRM of 6 channels,ES412.7 >369 APFO MRM of 6 channels,ES412.7 > 163.0 PFOA 13C4 100--1 MRM of 6 channels,ES- 410.8 > 372 PFOA 13C4 4.404e+004 7.57 1 14028.73 PFOS %- 0 Li i 11in i'| 11 2.0 trTiTi i | i i , |.|ii i l |l/ii^ r i i | i i i i |rm TnTr min 4.0 6.0 8.0 10.0 Analyst: Mark Dymerski MRM of 6 channels,ES498.6 > 80 u <u > a <u p p h CO DEP2-SDWB-000399 Quantify Sample Report MassLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA.PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Name: pf37d2567, Date: 26-Apr-2007, Time: 07:24:40, ID: 923.79.6, Description: 5 pg/L PFOS MRM of 6 channels,ES498.6>98.9 PFOS 13C4 MRM of 6 channels,ES502.6 > 80 Page 54 of 58 ^ ^ Analyst: Mark Dymerski a) > a> O Eh cn DEP2-SDWB-000400 Quantify Sample Report MassLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA. PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27,2007 10:24:05 AM Mountain Daylight Time Name: pf37d2568, Date: 26-Apr-2007, Time: 07:37:37, ID: 923.79.7, Description: 10 pgfl- PFOA MRM of 6 channels,ES412.7 > 369 PFOA MRM of 6 channels,ES412.7 > 169.0 APFO 100-1 Page 55 of 58 i> ^ ________________ MRM of 6 channels,ES- 412.7 > 369 APFO 4.262e+004 7.60 1 13801.67 APFO 100-1 %- MRM of 6 channels.ES- 412.7 > 169.0 APFO 2.261e+004 7.57 1 7099.32 PFOA 13C4 H m ~in rTTr m 11 n i r i i ri r i 1 1it 11 r11 f i n p r i 2.0 4.0 6.0 8.0 11PTlI min 10.0 PFOA 13C4 7.57 16152.24 MRM of 6 channels,ES416.8 > 372 5.2106+004 PFOS MRM of 6 channels,ES498.6 > 80 %- 11111111111111 i t | ' i 11111111"|i i r r 2.0 4.0 6.0 8.0 10.0 mm 0 11111'i'i 111111 n 11 n 1111 2.0 4.0 i i - p i i t [ T i r r p - l n 1 1 111 [ t i t 6.0 8.0 10.0 Analyst: Mark Dymerski i-i Q) > a aj p p Eh CO DEP2-SDWB-I Quantify Sample Report MassLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA-PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Name: pf37d2568, Date: 26-Apr-2007, Time: 07:37:37, ID: 923.79.7, Description: 10 pg/L PFOS MRM of 6 channels,ES498.6>98.9 PFOS13C4 MRM of 6 channels,ES502.6 > 80 Page 56 of 58 CLD0 O o o o Analyst: Mark Dymerski h tU > tu p P EH CO DEP2-SDWB-000402 Quantify Sample Report M assLynx4.1 PFOA Analysis Dataset: C:\MassLynxVPFOA.PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Name: pf37d2569, Date: 26-Apr-2007, Time: 07:50:34, ID: 923.79.8, Description: 20 pgfL PFOA MRM of 6 channels, ES412.7 > 369 PFOA 100-1 MRM of 6 channels,ES- 412.7 > 169.0 PFOA 4.604e+004 7.57 1 14897.13 APFO 100-. - %- Page 57 of 58 m ^ APFO 7.57 27882.56 MRM of 6 channels,ES412.7 > 369 8.768e+004 APFO 100- %- n i m i mm1 1 J l I I I ] I I I I J T T 1 I j l l l l h U + 1 1111111 11 1 2.0 4.0 6.0 8.0 10.0 0 'IT I I I II I I I IT I I I 2.0 4.0 APFO 7.57 ' 14897.13 MRM of 6 channels,ES412.7 > 169.0 4.604e+004 PFOA 13C4 100-i MRM of 6 channels,ES- 416.B > 372 PFO7A.5173C4- 5.325e+004 16680.89 PFOS 100-1 I I I I |l/ 1I I p i I I | I I I I | I MT | I I 6.0 8.0 10.0 MRM of 6 channels,ES4S8.6 > 80 PFOS 5.388e+004 8.16 18902.37 %- %- 0 ` m T| n n | 111111111 j u 111111111m |l Mif i 'ii 111 n i )1111 |i n i min 2.0 4.0 6.0 8.0 10.0 0 L 1111 11r q i 111111111 1mij i 111 111111ttiipVi111 111 1 1 1i n p 111 min 2.0 4.0 6.0 8.0 10.0 Analyst: Mark Dymerski 111j 11111111111111111i T f i - m 111 1111111111 iW'll I| nriViTr f|rn i1]1111111111111111111 min 2.0 4.0 6.0 8.0 10.0 l-l <U > <u Q J Eh CO Quantify Sample Report MassLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA.PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Name: pf37d2569, Date: 26-Apr-2007, Tim e: 07:50:34, ID: 923.79.8, Description: 20 pg/L PFOS MRM of 6 channels,ES498.6>98.9 PFOS13C4 100-, MRM of 6 channels,ES- 502.6 > 80 PFOS 13C4 2.847e+004 8.16 1 10014.32 %- 1 PFOA 2 APFO 3 PFOA13C4 4 PFOS 5 PFOS 13C4 0 1 1 n 1 1 m i |T rrT ) m r y i m j i n t |t t i t 2.0 4.0 6.0 1'lm 'l'ni min 10.0 7.57 27882.564 bb 7.57 27882.564 bb 7.57 16680.887 bb 8.16 18902.365 bb 8.16 10014.320 bb 16680.887 16680.887 10014.320 3 16.715 3 16.715 0 16680.887 5 18.875 0 10014.320 20.046 20.869 9.670 19.960 8.804 100.2 100.2 96.7 99.8 88.0 Analyst: Mark Dymerski Page 58 of 58 r- in <U > G Ql Q Echn DEP2-SDWB-000403 LC/MS SEMIVOLATILE SAMPLE DATA Sample List Report MassLynx 4.1 Sample List: C:\MassLynx\PFOA.PRO\SampleDB\pf37d25(2).SPL Last Modified: Friday, April 27,2007 10:20:08 Mountain Daylight Time Printed: Friday, April 27,2007 10:24:00 Mountain Daylight Time Page 1 of 2 Page Position (1,1) File Name Sample ID File Text Sample Type PFOA pg/L or kg APFO pg/L or kg Bottle 1 pf37d2501 923.79.1 Blank Blank 2 pf37d2502 923.79.2 0.2 pg/L Standard 3 pf37d2503 923.79.3 0.5 pg/L Standard 4 pf37d2504 923.79.4 1 pg/L Standard 5 pf37d2505 923.79.5 2 pg/L Standard 6 pf37d2506 923.79.6 5 pg/L Standard 7 pf37d2507 923.79.7 10 pg/L Standard 8 pf37d2508 923.79.8 20 pg/L Standard 9 pf37d2509 923.79.1 Blank Blank 10 pf37d2510 923.79.10 2 pg/L ICV QC 11 pf37d2511 923.79.3 0.5 pg/L RLV QC 12 pf37d2533 923.79.5 2 pg/L CCV QC 13 pf37d2534 JVKEK1AA R7D240000-515 MB Blank 14 pf37d2535 JVKEK1AC R7D240000-515 LCS QC 15 pf37d2536 JVKEK1AD R7D240000-515 LCS QC 16 pf37d2537 JT6V01AA D7D180342-001 Analyte 17 pf37d2538 JT6V11AA D7D180342-002 Analyte 18 pf37d2539 JT6V21AA D7D180342-003 Analyte 19 pf37d2540 JT6V31AA D7D180342-004 Analyte 20 pf37d2541 JT6V41AA D7D180342-005 Analyte 21 pf37d2542 923.79.4 1 pg/L CCV QC 22 pf37d2562 923.79.1 Blank Blank 23 pf37d2563 923.79.2 0.2 pg/L QC 24 pf37d2564 923.79.3 0.5 pg/L QC 25 pf37d2565 923.79.4 1 pg/L QC 26 pf37d2566 923.79.5 2 pg/L QC 27 pf37d2567 923.79.6 5 pg/L QC 28 pf37d2568 923.79.7 10 pg/L QC 29 pf37d2569 923.79.8 20 pg/L QC 0 0.2 0.5 1 2 5 10 20 0 2 0.5 2 0 10 1.0 0 0 0 0 0 1 0 0.2 0.5 1 2 5 10 20 0 0.208 0.520 1.041 2.082 5.205 10.411 20.821 0 2.082 0.520 2.082 0 10.411 1.0411 0 0 0 0 0 1.041 0 0.208 0.520 1.041 2.082 5.205 10.411 20.821 1:1,A 1:1,B 1:1,C 1:1,D 1:1,E 1:1,F 1:2,A 1:2,B 1:1,A 1:2,C 1:1,C 1:1,E 1:7,A 1:7,B 1:7,C 1:7,D 1:7,E 1:7,F 1:8,A 1:8,B 1:1,D 1:1,A 1:1,B 1:1,C 1:1,D 1:1,E 1:1,F 1:2,A 1:2,B STL Denver 72 D EP2-SD W B -000405 Sample List Report MassLynx 4.1 Sample List: C:\MassLynx\PFOA.PRO\SampleDB\pf37d25{2).SPL Last Modified: Friday, April 27,2007 10:20:08 Mountain Daylight Time Printed: Friday, April 27,2007 10:24:00 Mountain Daylight Time Page 2 of 2 Page Position (2,1) Extract mL Sample mL org Dilution Inject Volume MS Tune File Inlet File MS File 1.000000 1.000000 1.000000 1.000000 1.000000 1.000000 1.000000 1.000000 1.000000 1.000000 1.000000 1.000000 5.000000 5.000000 5.000000 5.000000 5.000000 5.000000 5.000000 5.000000 1.000000 1.000000 1.000000 1.000000 1.000000 1.000000 1.000000 1.000000 1.000000 0.000000 1.000000 1.000000 1.000000 1.000000 1.000000 1.000000 1.000000 1.000000 1.000000 1.000000 1.000000 250.000000 250.000000 250.000000 256.000000 240.000000 253.000000 251.000000 244.000000 1.000000 1.000000 1.000000 1.000000 1.000000 1.000000 1.000000 1.000000 1.000000 0.000000 20.000000 1.000000 20.000000 1.000000 20.000000 1.000000 20.000000 1.000000 20.000000 1.000000 20.000000 1.000000 20.000000 1.000000 20.000000 1.000000 20.000000 1.000000 20.000000 1.000000 20.000000 1.000000 20.000000 1.000000 20.000000 1.000000 20.000000 1.000000 20.000000 1.000000 20.000000 1.000000 20.000000 1.000000 20.000000 1.000000 20.000000 1.000000 20.000000 1.000000 20.000000 1.000000 20.000000 1.000000 20.000000 1.000000 20.000000 1.000000 20.000000 1.000000 20.000000 1.000000 20.000000 1.000000 20.000000 1.000000 20.000000 PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA S PFOA S PFOA S PFOA S PFOA S PFOA S PFOA S PFOA S PFOA S PFOA S PFOA S PFOA S PFOA S PFOA S PFOA S PFOA S PFOA S PFOA S PFOA S PFOA S PFOA S PFOA S PFOA S PFOA S PFOA S PFOA S PFOA S PFOA S PFOA S STL Denver 73 D EP2-SD W B -000406 Quantify Compound Summary Report MassLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA.PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Method: C:\MassLynx\PFOA.PRO\MethDB\pF37d25.mdb 26 Apr 2007 07:49:52 Calibration: C:\MassLynx\Picric Acid.PRO\CurveDB\pf37d25.cdb 27 Apr 200710:20:34 Compound name: PFOA Coefficient of Determination: RA2 = 0.998734 Calibration curve: -0.00519466 * xA2 + 0.937722 * x + 0.00484394 Response type: Internal Std ( Ref 3 ), Area * ( IS Cone. / IS Area ) Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None 1 pf37d2501 2 pf37d2502 3 pf37d2503 4 pf37d2504 5 pf37d2505 6 pf37d2506 7 pf37d2507 8 pf37d2508 9 pf37d2509 10 pf37d2510 11 pf37d2511 12 pf37d2533 13 pf37d2534 14 pf37d2535 15 pf37d2536 16 pf37d2537 17 pf37d2538 18 pf37d2539 19 pf37d2540 20 pf37d2541 21 pf37d2542 22 pf37d2562 23 pf37d2563 24 pf37d2564 25 pf37d2565 26 pf37d2566 27 pf37d2567 28 pf37d2568 Analyst: Mark Dymerski 923.79.1 923.79.2 923.79.3 923.79.4 923.79.5 923.79.6 923.79.7 923.79.8 923.79.1 923.79.10 923.79.3 923.79.5 JVKEK1AA JVKEK1AC JVKEK1AD JT6V01AA JT6V11AA JT6V21AA JT6V31AA JT6V41AA 923.79.4 923.79.1 923.79.2 923.79.3 923.79.4 923.79.5 923.79.6 923.79.7 Blank Blank 0.2 pg/L Standard 0.5 pg/L Standard 1 pg/L Standard 2 pg/L Standard 5 pg/L Standard 10 pg/L Standard 20 pg/L Standard Blank Blank 2 pg/L ICV QC 0.5 pg/L RLV QC 2 pg/L CCV QC R7D240000-515 MB Blank R7D240000-515 L... QC R7D240000-515 L... QC D7D180342-001 Analyte D7D180342-002 Analyte D7D180342-003 Analyte D7D180342-004 Analyte D7D180342-005 Analyte 1 pg/L CCV QC Blank Blank 0.2 pg/L QC 0.5 pg/L QC 1 pg/L QC 2 pg/L QC 5 pg/L QC 10 pg/L QC 0.200 0.500 1.000 2.000 5.000 10.000 20.000 7.96 22.626 7.88 331.817 7.82 826.403 7.77 1668.012 7.77 3309.523 7.74 7315.175 7.74 14644.253 7.71 29086.564 2.000 0.500 2.000 10.000 1.000 1.000 7.71 7.74 7.66 7.04 7.66 7.68 7.71 7.68 7.68 7.57 7.63 7.66 2869.092 817.875 3284.399 86.031 13534.138 924.474 3554.841 3610.696 1853.626 598.880 644.344 1643.499 0.200 0.500 1.000 2.000 5.000 10.000 7.66 342.897 7.57 833.425 7.57 1561.195 7.63 3019.240 7.60 6949.397 7.60 13801.671 DEP2-SDWB-000407 Page 1 of 1C r- bb 16399.908 3 0.014 0.0095 bb 2.012 NO 16512.135 3 0.201 0.2094 104.7 bb 1.761 NO 19798.521 3 0.417 0.4410 88.2 bb 1.825 NO 17327.461 3 0.963 1.0273 102.7 bb 1.913 NO 17205.789 3 1.923 2.0698 103.5 bb 1.907 NO 15369.824 3 4.759 5.2214 104.4 bb 1.828 NO 17237.646 3 8.496 9.5610 95.6 bb 1.857 NO 17303.525 3 16.810 20.1759 100.9 14757.614 3 bb 1.915 NO 14937.064 3 1.921 2.0669 103.3 bb 1.851 NO 19625.471 3 0.417 0.4403 88.1 bb 2.022 NO 16745.744 3 1.961 2.1111 105.6 bb 4.873 YES 11734.774 3 0.073 0.0015 bb 1.995 NO 12858.166 3 10.526 0.2404 120.2 bb 2.145 NO 9625.200 3 0.960 0.0205 102.5 bb 1.743 NO 12152.161 3 2.925 0.0619 bb 1.769 NO 13331.781 3 2.708 0.0611 bb 1.701 NO 13338.372 3 1.390 0.0294 bb 1.947 NO 13364.045 3 0.448 0.0094 bb 1.827 NO 13989.743 3 0.461 0.0100 bb 2.013 NO 17049.244 3 0.964 1.0287 102.9 14176.599 3 bb 1.937 NO 15384.203 3 0.223 0.2328 116.4 bb 2.058 NO 18809.576 3 0.443 0.4686 S&7 bb 1.856 NO 16017.895 3 0.975 1.0402 K k o bb 1.969 NO 16505.914 3 1.829 1.9669 98.3 bb 1.876 NO 14028.726 3 4.954 5.4416 1(8.8 bb 1.944 NO 16152.243 3 8.545 9.6197 $ 2 CA DEP2-SDWB-000408 Quantify Compound Summary Report M assLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA.PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Compound name: PFOA Page 2 of 10 m r~ Analyst: Mark Dymerski 0) > CL) Q CO Quantify Compound Summary Report MassLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA.PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Compound name: APFO Coefficient of Determination: RA2 = 0.998736 Calibration curve: -0.00479134 * xA2 + 0.900692 * x + 0.00509623 Response type: Internal Std ( Ref 3 ), Area * ( IS Cone. / IS Area ) Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None 1 pf37d2501 2 pf37d2502 3 pf37d2503 4 pf37d2504 5 pf37d2505 6 pf37d2506 7 pf37d2507 8 pf37d2508 S pf37d2509 10 pf37d2510 11 pf37d2511 12 pf37d2533 13 pf37d2S34 14 pf37d2535 15 pf37d2536 10 pf37d2537 17 pf37d2538 18 pf37d2539 19 pf37d2540 20 pf37d2541 21 pf37d2542 22 pf37d2562 23 pf37d2563 24 pf37d2564 25 pf37d2S65 26 pf37d2566 27 pf37d2567 28 pf37d2568 29 pf37d2569 923.79.1 923.79.2 923.79.3 923.79.4 923.79.5 923.79.6 923.79.7 923.79.8 923.79.1 923.79.10 923.79.3 923.79.5 JVKfcKIAA JVKEK1AC JVKEK1AD JT6V01AA JT6V11AA JT6V21AA JT6V31AA JT6V41AA 923.79.4 923.79.1 923.79.2 923.79.3 923.79.4 923.79.5 923.79.6 923.79.7 923.79.8 Blank Blank 0.2 pg/L Standard 0.5 pg/L Standard 1 pg/L 2 pg/L Standard Standard 5 pg/L Standard 10 pg/L Standard 20 pg/L Standard Blank Blank 2 pg/L ICV QC 0.5 pg/L RLV QC 2 pg/L C C V QC R7D240-5 5 MB Blank R7D 240000-515 L... Q C R7D 240000-515 L... Q C D7D180342-001 Analyte D7D180342-002 Analyte D 7D 180342-003 Analyte D 7D 180342-004 Analyte D7D180342-005 Analyte 1 pg/L C C V QC Blank Blank 0.2 pg/L QC 0.5 pg/L QC 1 pg/L QC 2 pg/L QC 5 pg/L QC 10 pg/L QC 20 pg/L QC 0.208 0.520 1.041 2.082 5.205 10 .4 11 20.821 7.96 7.88 7.82 7.77 7.77 7.74 7.74 7.71 2.082 0.520 2.082 10 .4 11 1.041 1.041 7.71 7.74 7.66 7.04 7.66 7.68 7.71 7.68 7.68 7.57 7.63 7.66 0.208 0.520 1.041 2.082 5.205 10 .4 11 20.821 7.66 7.57 7.57 7.63 7.60 7.60 7.57 Analyst: Mark Dymerski DEP2-SDWB-000409 Page 3 o f 10 CD r~- 22.626 331.817 826.403 1668.012 3309.523 7315.175 14644.253 29086.564 bb bb bb bb bb bb bb bb 2869.092 817.875 3284.399 68.031 13534.138 924.474 3554.841 3610.696 1853.626 598.880 644.344 1643.499 bb bb bb bb bb bb bb bb bb bb bb bb 342.897 833.425 1561.195 3019.240 6949.397 13801.671 27882.564 bb bb bb bb bb bb bb 2.012 1.761 1.825 1.913 1.907 1.828 1.857 NO NO NO NO NO NO NO 1.915 1.851 2.022 4.873 1.995 2.145 1.743 1.769 1.701 1.947 1.827 2.013 NO NO NO YES NO NO NO NO NO NO NO NO 1.937 2.058 1.856 1.969 1 876 1.944 1.872 NO NO NO NO NO NO NO 16399.908 16512.135 19798.521 17327.461 17205.789 15369.824 17237.646 17303.525 14757.614 14937.064 19625.471 16745.744 11734.774 12858.166 9625.200 12152.161 13331.781 13338.372 13364.045 13989.743 17049.244 14176.599 15384.203 18809.576 16017.895 16505.914 14028.726 16152.243 16680.887 3 0.014 3 0.201 3 0.417 3 0.963 3 1.923 3 4.759 3 8.496 3 16.810 3 3 1.921 3 0.417 3 1.961 3 0.073 3 10.526 3 0.960 3 2.925 3 2.708 3 1.390 3 0.448 3 0.461 3 0.964 3 3 0.223 3 0.443 3 0.975 3 1.829 3 4.954 3 8.545 3 16.715 0.0097 0.2177 0.4589 1.0692 2.1546 5.4357 9.9536 21.0042 104.7 88.2 102.7 103.5 104.4 95.6 100.9 2.1515 0.4581 2.1976 0.0015 0.2503 0.0213 0.0645 0.0636 0.0306 0.0098 0.0104 1.0707 103.3 88.1 105.6 120.2 102.5 102.9 0.2421 0.4875 1.0827 2.0475 5.6649 10.0147 20.8695 116.4 93.8 104.0 98.3 10^ 8 96LE 10<? ur Q co Q uantify Compound Summary Report MassLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA. PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Compound name: APFO Analyst: Mark Dymerski DEP2-SDWB-000410 Page 4 of 10 i> r~ cu > P aai E-f w Quantify Compound Summary Report MassLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA.PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Compound name: PFOA 13C4 Response Factor: 1725.07 RRF SD: 132.825, Relative SD: 7.69967 Response type: External Std, Area Curve type: RF 1 pf37d2501 2 pf37d2502 3 pf37d2503 4 pf37d2504 5 pf37d2505 6 pf37d2506 7 pf37d2507 8 pf37d2508 9 pf37d2509 10 pf37d2510 11 pf37d2511 12 pf37d2533 13 pt37d2534 14 pf37d2535 15 pf37d2536 16 pf37d2537 17 pf37d2538 18 pf37d2539 19 pf37d2540 20 pf37d2541 21 pf37d2542 22 pt37d2562 23 pf37d2563 24 pf37d2564 25 pf37d2565 26 pf37d2566 27 pf37d2567 28 pf37d2568 29 pf37d2569 923.79.1 923.79.2 923.79.3 923.79.4 923.79.5 923.79.6 923.79.7 923.79.8 923.79.1 923.79.10 923.79.3 923.79.5 JVKEK1AA JVKEK1AC JVKEK1AD JT6V01AA JT6V11AA JT6V21AA JT6V31AA JT6V41AA 923.79.4 923.79.1 923.79.2 923.79.3 923.79.4 923.79.5 923.79.6 923.79.7 923.79.8 Blank Blank 0.2 pg/L Standard 0.5 pg/L Standard 1 pg/L Standard 2pg/L Standard 5 pg/L Standard 10 pg/L Standard 20 pg/L Standard Blank Blank 2 pg/L ICV QC 0.5 pg/L RLV QC 2 pg/L CCV QC R7D240000-515 MB Blank R7D240000-515 L... QC R7D240000-515 L... QC D7D180342-001 Analyte D7D180342-002 Analyte D7D180342-003 Analyte D7D180342-004 Analyte D7D180342-005 Analyte 1 pg/L CCV QC Blank Blank 0.2 pg/L QC 0.5 pg/L QC 1 pg/L QC 2 pg/L QC 5 pg/L QC 10 pg/L QC 20 pg/L QC 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 7.94 7.82 7.80 7.77 7.74 7.74 7.74 7.71 7.71 7.71 7.71 7.66 7.68 7.66 7.71 7.68 7.68 7.68 7.60 7.63 7.63 7.66 7.60 7.60 7.60 7.60 7.57 7.57 7.57 Analyst: Mark Dymerski 16399.908 16512.135 19798.521 17327.461 17205.789 15369.824 17237.646 17303.525 14757.614 14937.064 19625.471 16745.744 11734.774 12858.166 9625.200 12152.161 13331.781 13338.372 13364.045 13989.743 17049.244 14176.599 15384.203 18809.576 16017.895 16505.914 14028.726 16152.243 16680.887 bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb Page 5 of 10 CO r- o o o 0 16399.908 0 16512.135 0 19798.521 0 17327.461 0 17205.789 0 15369.824 0 17237.646 0 17303.525 0 14757.614 0 14937.064 0 19625.471 0 16745.744 0 11734.774 0 12858.166 0 9625.200 0 12152.161 0 13331.781 0 13338.372 0 13364.045 0 13989.743 0 17049.244 0 14176.599 0 15384.203 0 18809.576 0 16017.895 0 16505.914 0 14028.726 0 16152.243 0 16680.887 9.5068 9.5719 11.4769 10.0445 9.9740 8.9097 9.9924 10.0306 8.5548 8.6588 11.3766 9.7073 6.8025 7.4537 5.5796 7.0444 7.7283 7.7321 7.7470 8.1097 9.8832 8.2180 8.9180 10.9037 9.2854 9.5683 8.1323 9.3632 9.6697 95.1 95.7 114.8 100.4 99.7 89.1 99.9 100.3 85.5 86.6 113.8 97.1 68.0 74.5 55.8 70.4 77.3 77.3 77.5 81.1 98.8 82.2 89.2 109.0 92.9 95.7 8^3 9M 9&7 nr Q EChO DEP2-SDWB-I Quantify Compound Summary Report MassLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA. PRO\pf37d252.qld Last Altered: Friday. April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Compound name: PFOA 13C4 Analyst: Mark Dymerski DEP2-SDWB-000412 Page 6 of 10 Ol r~ t <u >tcu O E-i ui Q uantify Com pound Summary Report MassLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA.PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Com pound name: PFOS Coefficient of Determination: RA2 = 0.998746 Calibration curve: -0.0055757 * xA2 + 1.05667 * x + 0.00530869 Response type: Internal Std ( Ref 5 ), Area * ( IS Cone. / IS Area ) Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None 1 pf37d2501 2 pf37d2502 3 pf37d2503 4 pf37d2504 5 pf37d2505 6 pf37d2506 7 pf37d2507 8 pf37d2508 9 pf37d2509 10 pf37d2510 11 pf37d2511 12 pf37d2533 13 pf37d2534 14 pf37d2535 15 pf37d2536 16 pf37d2537 17 pf37d2538 18 pf37d2539 19 pf37d2540 20 pf37d2541 21 pf37d2542 22 pf37d2562 23 pf37d2563 24 pf37d2564 25 pf37d2565 26 pf37d2566 27 pf37d2567 28 pf37d2568 29 pf37d2569 923.79.1 923.79.2 923.79.3 923.79.4 923.79.5 923.79.6 923.79.7 923.79.8 923.79.1 923.79.10 923.79.3 923.79.5 JVKEK1AA JVKEK1AC JVKEK1AD JT6V01AA JT6V11AA JT6V21AA JT6V31AA JT6V41AA 923.79.4 923.79.1 923.79.2 923.79.3 923.79.4 923.79.5 923.79.6 923.79.7 923.79.8 Blank Blank 0.2 pg/L Standard 0.5 pg/L Standard 1 pg/L Standard 2pg/L Standard 5 pg/L Standard 10 pg/L Standard 20 pg/L Standard Blank Blank 2 pg/L ICV QC 0.5 pg/L RLV QC 2 pg/L CCV QC R7D240000-515 MB Blank R7D240000-515 L... QC R7D240000-515 L... QC D7D180342-001 Analyte D7D180342-002 Analyte D7D180342-003 Analyte D7D180342-004 Analyte D7D180342-005 Analyte 1 pg/L CCV QC Blank Blank 0.2 pg/L QC 0.5 pg/L QC 1 pg/L QC 2 pg/L 5 pg/L QC QC 10 pg/L 20 pg/L QC QC 0.200 0.500 1.000 2.000 5.000 10.000 20.000 7.54 8.44 8.38 8.35 8.35 8.33 8.33 8.30 2.000 0.500 2.000 8.33 8.30 8.27 10.000 1.000 1.000 8.27 8.30 8.30 8.21 8.21 8.24 8.24 8.24 0.200 0.500 1.000 2.000 5.000 10.000 20.000 8.21 8.21 8.19 8.19 8.21 8.19 8.16 Analyst: Mark Dymerski D EP 2-SD W B -000413 Page 7 o f 1C o CD 12.368 242.454 611.677 1208.480 2412.917 6743.988 10281.079 19902.998 bb bb bb bb bb bb bb bb 2484.865 585.559 2141.343 bb bb bb 6855.432 436.819 250.550 300.915 90.375 226.873 249.530 1058.437 bb bb bb bb bb bb bb bb 263.105 632.047 1002.100 2061.491 5358.097 9472.549 18902.365 bb bb bb bb bb bb bb I 1 9 HB n 12177.335 5 1.466 NO 10850.116 5 1.295 NO 12746.258 5 1.402 NO 11071.146 5 1.445 NO 11300.640 5 1.408 NO 12488.086 5 1.415 NO 10721.331 5 1.367 NO 10445.627 5 9890.509 5 1.353 NO 11176.792 5 1.393 NO 12480.418 5 1.392 NO 10509.598 5 7151.678 5 1.378 NO 7557.958 5 1.278 NO 5380.769 5 1.494 NO 6783.595 5 2.257 YES 8099.259 5 1.764 YES 7806.280 5 1.566 NO 9393.114 5 1.965 YES 10133.093 5 1.513 NO 10097.919 5 10643.887 5 1.604 NO 10021.992 5 1.630 NO 11909.618 5 1.362 NO 10263.706 5 1.373 NO 10157.976 5 1.370 NO 9934.720 5 1.381 NO 9984.450 5 1.373 NO 10014.320 5 B -- 0.010 0.0046 0.223 0.2067 0.480 0.4502 1.092 1.0336 2.135 2.0376 5.400 5.2512 9.589 9.5514 19.054 20.1746 2.223 0.469 2.038 2.1227 0.4400 1.9431 9.070 0.812 0.369 0.372 0.116 0.242 0.246 1.048 0.1801 0.0153 0.0067 0.0072 0.0021 0.0045 0.0047 0.9921 0.263 0.531 0.976 2.029 5.393 9.487 18.875 0.2437 0.4985 0.9235 1.9353 5.2441 9.4441 19.9602 103.3 90.0 103.4 101.9 105.0 95.5 100.9 106.1 88.0 97.2 90.1 76.6 99.2 121.9 99.7 92.3 96.8 104.9 H 99.4 j- 8 P P H Ui Quantify Compound Summary Report M assLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA.PROVpf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Compound name: PFOS Analyst: Mark Dymerski DEP2-SDWB-000414 Page 8 of 10 r--I CO fi CD f>i <U Q fif E-i 0} Q uantify Compound Summary Report M assLynx 4.1 PFOA Analysis Dataset: C:\MassLynxVPFOA.PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Com pound name: PFOS 13C4 Response Factor: 1137.47 RRF SD: 89.2906, Relative SD: 7.8499 Response type: External Std, Area Curve type: RF 1 pf37d2501 2 pf37d2502 3 pf37d2503 4 pf37d2504 5 pf37d2505 6 pf37d2506 7 pf37d2507 8 pf37d2508 9 pf37d2509 10 pf37d2510 11 pf37d2511 12 pf37d2533 13 pf37d2534 14 pf37d2535 15 pf37d2536 16 pf37d2537 17 pf37d2538 18 pf37d2539 19 pf37d2540 20 pf37d2541 21 pf37d2542 22 pf37d2562 23 pf37d2563 24 pf37d2564 25 pf37d2565 26 pf37d2566 27 pf37d2567 28 pf37d2568 29 pf37d2569 923.79.1 923.79.2 923.79.3 923.79.4 923.79.5 923.79.6 923.79.7 923.79.8 923.79.1 923.79.10 923.79.3 923.79.5 JVKLK1AA JVKEK1AC JVKEK1AD JT6V01AA JT6V11AA JT6V21AA JT6V31AA JT6V41AA 923.79.4 923.79.1 923.79.2 923.79.3 923.79.4 923.79.5 923.79.6 923.79.7 923.79.8 Blank Blank 0.2 pg/L Standard 0.5 pg/L Standard 1 pg/L Standard 2 pg/L Standard 5 pg/L Standard 10 pg/L Standard 20 pg/L Standard Blank Blank 2 pg/L ICV QC 0.5 pg/L RLV QC 2 pg/L CCV QC K7D2400-515 MB Blank R7D240000-515 L... QC R7D240000-515 L... QC D7D180342-001 Analyte D7D180342-002 Analyte D7D180342-003 Analyte D7D180342-0O4 Analyte D7D180342-005 Analyte 1 pg/L CCV QC Blank Blank 0.2 pg/L QC 0.5 pg/L QC 1 pg/L QC 2 pg/L QC 5 pg/L QC 10 pg/L QC 20 pg/L QC 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 8.49 B.38 8.35 8.35 8.33 8.33 8.33 8.30 8.33 8.33 8.30 8.24 8.24 8.24 8.30 8.27 8.27 8.24 8.19 8.24 8.24 8.24 8.21 8.21 8.19 8.19 8.21 8.16 8.16 Analyst: Mark Dymerski 12177.335 10850.116 12746.258 11071.146 11300.640 12488.086 10721.331 10445.627 9890.509 11176.792 12480.418 10509.598 7151.678 7557.958 5380.769 6763.595 8099.259 7806.280 9393.114 10133.093 10097.919 10643.887 10021.992 11909.618 10263.706 10157.976 9934.720 9984.450 10014.320 bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb bb Page 9 of 10 CN 00 0 12177.335 0 10850.116 0 12746.258 0 11071.146 0 11300.640 0 12488.066 0 10721.331 0 10445.627 0 9890.509 0 11176.792 0 12480.418 0 10509.598 0 7151.678 0 7557.958 0 5380.769 0 6783.595 0 8099.259 0 7806.280 0 9393.114 0 10133.093 0 10097.919 0 10643.887 0 10021.992 0 11909.618 0 10263.706 0 10157.976 0 9934.720 0 9984.450 0 10014.320 10.7056 9.5388 11.2058 9.7331 9.9349 10.9788 9.4256 9.1832 8.6951 9.8260 10.9720 9.2394 6.2873 6.6445 4.7305 5.9637 7.1204 6.8628 8.2579 8.9084 8.8775 9.3575 8.8107 10.4702 9.0232 8.9303 8.7340 8.7777 8.8040 107.1 95.4 112.1 97.3 99.3 109.8 94.3 91.8 87.0 98.3 109.7 92.4 62.9 66.4 47.3 59.6 71.2 68.6 82.6 89.1 88.8 93.6 88.1 104.7 90.2 89.3 87.3 8&8 a io <L) p p Eh cn D EP2-SD W B -000415 Quantify Compound Summary Report M assLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA.PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Com pound name: PFOS 13C4 Analyst: Mark Dymerski DEP2-SDWB-000416 Page 10 of 10 m 03 <u > <D Q Echo DEP2-SDWB-000417 Quantify Sample Report MassLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA. PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Name: pf37d2534, Date: 26-Apr-2007, Time: 00:17:18, ID: JVKEK1AA, Description: R7D240000-515 MB PFOA MRM of 6 channels,ES412.7 >369 PFOA MRM o f 6 channels.ES412.7 > 169.0 APFO Page 25 of 58 co MRM o f 6 channels,ES412.7 > 369 APFO MRM of 6 channels ,ES412.7 > 169.0 PFOA13C4 100-. MRM of 6 channels,ES416 8 > 372 PFOA 13C4 3.927e+004 7.68 I 11734.77 PFOS MRM of 6 channels.ES498.6 > 80 Analyst: Mark Dymerski 11 1 11'| n 11 ; r i 11 ; 1111 1i'i 2.0 4.0 6.0 111 1 1 11] n 1 1p i 8.0 10.0 1 1j 111 n n I f f m r min 0) 0) Q p Eh CO Quantify Sample Report MassLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA. PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time / Name: pf37d2534, Date: 26-Apr-2007, Time: 00:17:18, ID: JVKEK1AA, Description: R7D240000-515 MB PFOS PFOS 13C4 MRM of 6 channels,ES- MRM of 6 channels,ES502.6 > 80 7.04 7.04 7.68 86.031 86.031 11734.774 bb bb bb 8.24 7151.678 bb 11734.774 11734.774 7151.678 3 0.073 3 0.073 0 11734.774 5f 0 7151.678 0.001 0.002 6.802 68.0 6.287 62.9 Analyst: Mark Dymerski Page 26 of 58 in oo cu > (<hU Q J H CO DEP2-SDWB-000418 DEP2-SDWB-000419 Quantify Sample Report MassLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA.PRO\pf37d252.qld Last Altered: Friday, April 27,2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Name: pf37d2535, Date: 26-Apr-2007, Time: 00:30:17, ID: JVKEK1AC, Description: R7D240000-515 LCS PFOA MRM of 6 channels,ES412.7 > 369 PFOA MRM o f 6 channels,ES412.7 > 169.0 APFO Page 27 of 58 ^ co MRM of 6 channels,ES412.7> 369 APFO MRM of 6 channels,ES412.7 > 169.0 PFOA13C4 MRM of 6 channels,ES416.8 > 372 PFOS MRM of 6 channels,ES498.Q> 80 Analyst: Mark Dymerski <U > Ithu Q iJ Eh CO DEP2-SDWB-000420 Quantify Sample Report MassLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA.PRCApf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27,2007 10:24:05 AM Mountain Daylight Time / Name: pf37d2535, Date: 26-Apr-2007, Time: 00:30:17, ID: JVKEK1AC, Description: R7D240000-515 LCS PFOS MRM of 6 channels,ES498.6>98.9 PFOS13C4 MRM of 6 channels,ES502.6 > 80 Pa9e 28 of 58 ^ _____________ Analyst: MarkDymerski U <U > <D Q E-i CO DEP2-SDWB-I Quantify Sample Report MassLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA.PRO\pf37d252.qld Last Altered: Friday. April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Name: pf37d2536, Date: 26-Apr-2007, Time: 00:43:12, ID: JVKEK1AD, Description: R7D240000-515 LCS PFOA MRM of 6 channels,ES412.7 >369 PFOA MRM of 6 channels,ES412.7 > 169.0 APFO Page 29 of 58 00 00 C'OdSI' o o MRM of 6 channels,ES412.7 >369 APFO MRM of 6 channels,ES412.7 > 169.0 PFOA13C4 100-, MRM of 6 channels,ES- 416.0 > 372 PFOA 13C4 3.186e+004 7.71 1 9625.20 PFOS %- u n p i n pm I I I ] I I I -r p r il f In i In h min 2.0 4.0 6.0 8.0 10.0 Analyst: Mark Dymerski MRM of 6 channels,ES438.6 > 80 U (U > ci 0) p p P C6 DEP2-SDWB-000422 Quantify Sample Report MassLynx4.1 PFOA Analysis Dataset: C:\MassLynxVPFOA.PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time y Name: pf37d2536, Date: 26-Apr-2007, Time: 00:43:12, ID: JVKEK1AD, Description: R7D240000-515 LCS PFOS MRM of 6 channels,ES498.6>98.9 PFOS 13C4 -,100 MRM of 6 channels,ES- 502.6 > 80 PFOS13C4 1.590e+004 8.30 1 5380.77 %- 10 ^ 11l'|TI"l i r* i i 'r|` 111 |IITTj ,, i i11T|n il| iiii 1ii \11 rprrr min 2.0 4.0 6.0 8.0 10.0 Page 30 of 58 co Analyst: Mark Dymerski S-i <u > d a<u cEn-i DEP2-SDWB-000423 Quantify Sample Report MassLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA.PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27,2007 10:24:05 AM Mountain Daylight Time Name: pf37d2537, Date: 26-Apr-2007, Time: 00:56:10, ID: JT6V01AA, Description: D7D180342-001 PFOA MRM of 6 channels,ES412.7 > 369 PFOA MRM o f 6 channels,ES412.7 > 169.0 APFO Page 31 o f 58 0 m ________________ MRM o f 6 channels,ES412.7 > 369 APFO MRM of 6 channels,ES412.7 ^ 169.0 PFOA13C4 100-, MRM of 6 channels,ES- 4 1 6 .8 '3 7 2 PFOA13C4 3.953e+004 7.68 1 12152.16 PFOS %- 0 h m p 11n 11rT|i ,Trp n 11P , 1 1 1n >v|M i 111 1M111 n 1 1111 min 2.0 4.0 6.0 8.0 10.0 Analyst: Mark Dymerski MRM of 6 channels,ES498.6 > 80 (D > CD P P 0H} DEP2-SDWB-000424 Quantify Sample Report M assLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA.PROVpf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Name: pf37d2537, Date: 26-Apr-2007, Time: 00:56:10, ID: JT6V01AA, Description: D7D180342-001 PFOS MRM o f 6 channels,ES498.6>98.9 PFOS 13C4 MRM of 6 channels,ES502.6 > 80 Page 32 of 58 ^ Analyst: Mark Dymerski <u <u p p Eh 0} DEP2-SDWB-000425 Quantify Sample Report M assLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA.PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Name: pf37d2538, Date: 26-Apr-2007, Time: 01:09:07, ID: JT6V11AA, Description: D7D180342-002 PFOA MRM of 6 channels,ES412.7 > 369 PFOA MRM o f 6 channels,ES412.7 > 169.0 APFO Pa9e 33 o f 58 cn 171 _______________ MRM of 6 channels,ES412.7 >369 APFO MRM of 6 channels,ES412.7 > 169.0 PFOA 13C4 MRM of 6 channels,ES416.8 > 372 PFOS MRM of 6 channels,ES498.6 > 80 Analyst: Mark Dymerski V-4 (D > a o p p Eh CO Quantify Sample Report M assLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA.PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time S Name: pf37d2538, Date: 26-Apr-2007, Time: 01:09:07, ID: JT6V11AA, Description: D7D180342-002 PFOS MRM of 6 channels,ES498.6>98.9 PFOS13C4 MRM o f 6 channels,ES502.6 > 80 1 PFOA 2 APFO 3 PFO A13C4 4 PFOS 5 PFO S13C4 7.68 7.68 7.68 8.21 8.27 3610.696 3610.696 1 3 3 3 1.7 8 1 300.915 8099.259 bb bb bb bb bb 13 3 3 1.7 8 1 1 3 3 3 1.7 8 1 8099.259 3 2.708 3 2.708 0 13331.781 5 0.372 0 8099.259 0.061 0 .0 6 4 ^ 7.728 0.007 7.120 ^ 77.3 71.2 Analyst: Mark Dymerski Page 34 of 58 m CP> u (D > C 0) Q H CO DEP2-SDWB-000426 DEP2-SDWB-000427 Quantify Sample Report M assLynx4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA.PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Name: pf37d2539, Date: 26-Apr-2007, Time: 01:22:03, ID: JT6V21AA, Description: D7D180342-003 PFOA MRM of 6 channels,ES412.7 > 369 PFOA MRM of 6 channels,ES412.7 > 169.0 APFO Page 35 of 58 ^ <n MRM of 6 channels,ES412.7 > 369 APFO MRM of 6 ch8nnels.ES412.7 > 169.0 PFOA13C4 MRM of 6 channels,ES416.S > 372 PFOS MRM of 6 channels,ES498.6 > 80 Analyst: Mark Dymerski h <U > n a) P J E-i CO Quantify Sample Report M assLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA.PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Name: pf37d2539, Date: 26-Apr-2007, Time: 01:22:03, ID: JT6V21AA, Description: D7D180342-003 PFOS MRM of 6 channels,ES498.6>98.9 PFOS 13C4 MRM of 6 channels,ES502.6 > 80 1 PFOA 2 APFO 3 PFOA 13C4 4 PFOS 5 PFOS 13C4 7.68 1853.626 bb 7.68 1853.626 bb 7.68 13338.372 bb 8.21 90.375 bb 8.24 7806.280 bb 13338.372 13338.372 7806.280 3 1.390 0.029y 3 1.390 0.031 0 13338.372 7.732 ' 77.3 5 0.116 0.002 0 7806.280 6.863 68.6 -------------- Analyst: Mark Dymerski Page 36 of 58 m CD CD Q Eco-i DEP2-SDWB-000428 DEP2-SDWB-000429 Quantify Sample Report Mass Lynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA. PRO\pf37d252.qld Last Altered: Friday, April 27,2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Name: pf37d2540, Date: 26-Apr-2007, Time: 01:35:00, ID: JT5V31AA, Description: D7D180342-004 PFOA MRM of 6 channels,ES412.7 >369 PFOA MRM of 6 channels,ES412.7 > 169.0 APFO Page 37 of 58 KO o\ MRM of 6 channels,ES412.7 > 369 APFO MRM of 6 channels.ES412.7 > 169.0 PFOA13C4 MRM of 6 channels,ES416.6 > 372 PFOS MRM of 6 channels,ES496.6 - 80 Analyst: MarkDymerski d 0) > d (D p p E-* U1 Quantify Sample Report M assLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA.PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time / Name: pf37d2540, Date: 26-Apr-2007, Time: 01:35:00, ID: JT6V31AA, Description: D7D180342-004 PFOS MRM of 6 channels,ES498.6>98.9 PFOS 13C4 MRM o f 6 channels,ES502.6 > 80 ipi.. t I 1 PFOA ' 2 APFO 3 PFOA13C4 4 PFOS 5 PFOS 13C4 7.57 7.57 7.60 8.24 8.19 598.880 598.880 13364.045 226.873 9393.114 bb bb bb bb bb 13364.045 13364.045 9393.114 3 0.448 3 0.448 0 13364.045 5 0.242 0 9393.114 0.009 ^ 0.010 7.747 * 0.004 8.258 j 77.5 82.6 Analyst: Mark Dymerski Page 38 of 58 i> CA <U > cu Q U1 DEP2-SDWB-000430 DEP2-SDWB-I _______________________________________________________________________________________ Quantify Sample Report MassLynx4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA.PRO\pf37d252.qld Last Altered: Friday, April 27, 2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time Name: pf37d2541, Date: 26-Apr-2007, Time: 01:47:57, ID: JT6V41AA, Description: D7D180342-005 PFOA MRM of 6 channels,ES412.7 > 369 PFOA MRM of 6 channels,ES412.7 > 169.0 APFO Page 39 of 58 oo m CO o o o MRM of 6 channels.ES412.7 > 369 APFO MRM of 6 channels,ES412.7 > 169.0 PFOA 13C4 MRM of 6 channels,ES416.8 >3/2 PFOS MRM of 6 channels,ES498.6 > 80 Analyst: Mark Dymerski <D > <D P p CO Quantify Sample Report M assLynx 4.1 PFOA Analysis Dataset: C:\MassLynx\PFOA.PRO\pf37d252.qld Last Altered: Friday, April 27,2007 10:20:34 AM Mountain Daylight Time Printed: Friday, April 27, 2007 10:24:05 AM Mountain Daylight Time / Name: pf37d2541, Date: 26-Apr-2007, Time: 01:47:57, ID: JT6V41AA, Description: D7D180342-005 PFOS MRM of 6 channels,ES- PFOS 498.6>98.9 PFOS 13C4 100- MRM of 6 channels,ES- 502.6 > 80 PFOS 13C4_ 2.973e+004 1 03M&3.09 1 %- 1 PFOA 2 APFO 3 PFOA13C4 4 PFOS 5 PFOS 13C4 I | 1 1 1 I | I 11 11 I 11 I |T I 1 1 1 I I 11 1 1 I 11 p I I T fl T n 1! 11 I I [ T I- r p T 2.0 4.0 6.0 8.0 10.0 7.63 7.63 7.63 8.24 8.24 644.344 644.344 13989.743 249.530 10133.093 bb bb bb bb bb 13989.743 13989.743 10133.093 3 0.461 3 0.461 0 13989.743 5 0.246 0 10133.093 0 .0 1 0 ^ 0.010 8.110 * 0.005 ^ 8.908 , 81.1 89.1 Analyst: Mark Dymerski Page 40 of 58 ^ cu > c (U Q Eh CO DEP2-SDWB-000432
Contact UsLoginSign Up
CUNY - The Graduate CenterColumbia University Mailman School of Public Health - Sociomedical Sciences