Document GmB2z8RMvaMNxqekEe92x9L1v

EMERGENCY HANDLING OF HAZARDOUS MATERIALS IN SURFACE TRANSPORTATION Edited by Patrick J. Student Bureau of Explosives Association of American Railroads 1920 L Street, N.W. Washington, D. C. 20036 MCD 000016910 EMERGENCY HANDLING OF HAZARDOUS MATERIALS IN SURFACE TRANSPORTATION Edited by Patrick J. Student Bureau of Explosives Association of American Railroads 1920 L Street, N.W. Washington, D.C. 20036 BUREAU OF EXPLOSIVES NEW 24-hour EMERGENCY PHONE 202*835-9500 Copyright Bureau of Explosives 1981 Thomas A. Phemister, Director MCD 000016911 NOTICE TO USERS The material in this book was prepared by the Bureau of Explosives staff in 1981 from sources and from experience deemed reliable and accurate. As with all information prepared for emergency response, especially emergency response involving hazardous materials, the printed word cannot substitute for the informed judgment of those responsible on the scene. Only they can accurately assess the scope of damage to equipment, hazardous lading lost and the potential for further harm in the immediate post-accident environment. It is vital to understand that each occurrence is different and each must be handled as the unique situation which it represents. Accordingly, while the Bureau of Explosives stands ready to offer the considerable help and expertise at its disposal, no claim can be made that the information in this book, or the advice rendered on scene by Bureau personnel, will always insure the complete safety of persons or property involved in an emergency arising out of the transportation of hazardous materials. With 75 years of experience in this business, the Bureau of Explosives would be suspicious of any person or organization making such a claim. Actions recommended or discussed in this book are aimed at handling an immediate emergency situation and may not detail all the potential hazards of the materials involved. This is especially true where several materials may have become mixed because of multiple leaks or container ruptures. Expert advice and assistance should be obtained and followed as quickly as possible. An excellent source of first response advice is CHEMTREC (800) 424-9300 (in the District of Columbia, call 483-7616). (in Alaska, Hawaii and Canada, call (202) 483-7616) The CHEMTREC communicators can often put those on scene at an emergency in touch with the shipper of the product(s). Thomas A. Phemister Director, Bureau of Explosives Washington, D.C. September 30, 1981 BASIC ORGANIZATION OF THIS BOOK Emergency Handling of Hazardous Materials in Surface Transportation is divided into two primary sections. The first section presents general information about hazardous materials incidents; it deals with general recommendations first and then with each DOT hazard class. Hazard class information is arranged in the order in which, historically, commodities of that class have been involved in accidents. Thus, flammable gases are discussed well before explosives because there have been more accidents involving them. The first section also defines or explains the various terms used in the specific commodity information. For instance, if the reader is advised to "wear self contained breathing apparatus'' or to "use water in flooding quantities as fog," these terms are explained toward the end of the first section under the heading "An explanation of terms used for emergency responders." The second section gives commodity specific emergency response information for each hazardous material regulated by the U.S. Department of Transportation and listed in Title 49 of the Code of Federal Regulations. For Environmental Protection Agency designated Hazardous Substances, this section also gives commodity specific emergency environmental damage mitigation information. At the back of this book are two cross reference indices. One shows the DOT-required 4-digit number and the product(s) and page(s) to which that number applies. For many commonly shipped materials, one DOT 4-digit number may apply to numerous commodities. The other cross reference index shows the 7-digit Standard Transportation Commodity Code number (the STCC number), the particular commodity to which that number applies and the page number on which information about that commodity appears. As additional information, the STCC cross reference index is preceded by an explanation of the 49-series format. 'VO/) Or.>00 16& 2-A EMERGENCY HANDLING OF HAZARDOUS MATERIALS IN SURFACE TRANSPORTATION INTRODUCTION When accidents or fires occur in connection with the trans portation of hazardous materials, the first priority is the prevention of fatalities and injuries to people. The prevention of unnecessary damage to property and of injury to livestock, wildlife and the environment is the second priority. To handle an incident in the safest manner, it is absolutely necessary to know the properties of the materials and of the shipping containers involved. Actual methods and procedures used may vary depending on local conditions. The material in this book should be reviewed before an incident occurs; and should, ideally, be part of training and pre planning exercises. RECOMMENDATIONS FOR RESPONSE (GENERAL RULES) It is entirely possible that the scene of an accident involving hazardous materials will represent such a high degree of hazard that the only safe course is to protect the perimeter and evacuate those who may become exposed to the dangers of violent rup tures of containers or of toxic fumes. These severe hazards may exist with or without the presence of fire, smoke or fumes. If an accident involving hazardous materials happens, IM MEDIATELY; 1. Notify local emergency response authorities and, if possi ble, the transportation carrier. 2. Make an initial survey of the scene, determining: * the location of threatened or potentially threatened people, * the presence of fire, smoke or fumes, ' the presence of hazardous materials, * the overall condition of the vehicles and con tainers, * wind direction and approximate speed; and * the condition of the terrain, including presence of water sources and supplies. 3. Rescue the injured, if possible. Wear the maximum de gree of protective equipment practicable. Plan an escape route before entering the immediate area. Do not expose personnel unnecessarily to smoke and fumes. 4. Identify the specific products, cars, trailers or containers involved. Identify also the "hazard class" of all products in volved. The train crew (or truck driver) will have shipping papers containing this information. In a rail yard or truck terminal, the papers are usually in the yard office or dispatch er's office. Placards applied to vehicles and/or labels on pack ages may help identify the presence or absence of hazardous materials, but the shipping papers are the best source of on-scene identification information. If the shipping papers and/or placards or labels are destroyed, the number on the rail car or motor vehicle can often be used to secure the name of the commodity being carried. Rail car numbers (or reporting marks) are a series of letters followed by a series of numbers, as in the following example; A5CX 12345. Many tank trucks use a similar numbering pattern. With this number, the carrier, or, in some cases, CHEMTREC (telephone number below) will be able to determine the contents of the vehicle. Using the second section of this book, identify and leam the dangerous characteristics of the hazardous materials in volved and the generally applicable emergency response in formation. (If the only available commodity information is the 4-digit number on a vehicle placard or a Standard Transporta tion Commodity Code (STCC) number on a shipping or move ment document, cross reference indices at the back of this book will help locate emergency response information. Plac ards on vehicles and labels on packages may also contain a single number at the bottom "point." This is a "hazard class" number assigned by the Intergovernmental Maritime Consul tive Organization (IMCO). A list of IMCO numbers and their general class assignments appears with the cross reference indices at the back of this book.) Use this information to plan evacuations, mitigation activities, personnel safety and ulti mate clean up. 5. Do not release any product(s) from containers or attempt to ignite or detonate either the products or the containers without expert advice and assistance. 6. If it is necessary to drag rail cars or other transport vehi cles as a part of accident clearing operations, it should only be done with the expert advice and assistance of persons trained in and familiar with such techniques. 7. An accident in a tunnel involving a release of hazardous materials creates a greater risk than one in an open area, because the vapors are not readily dissipated and because a fire may exhaust the air otherwise available for breathing. Damage to the tunnel structure, caused by the accident or during its aftermath, may also cause the tunnel to cave in. Conditions will vary greatly depending upon the drainage and ventilation of the tunnel, its length, the location of the accident and the response equipment available. In any event, close attention must be given to the risk of suffocation, and to the fire and explosion hazard in the tunnel. Self contained breathing apparatus should be used, be cause gas masks are equipped only with a filtering device and are not designed for service in areas with insufficient oxygen. Approach the wreckage from the windward end if possi ble. At least two persons should enter an area where vapors are concentrated, so that if one is overcome the other will be able to bring him/her out. Monitoring devices to detect explosive mixtures, toxic fumes and oxygen deficiency should be used as part of the initial survey of a tunnel accident. Continual (or frequent) monitoring for the presence of these dangerous conditions is also essential. 8. The shippers) should be contacted for additional infor mation on the product(s) involved. Additional emergency re sponse assistance is available from: CHEMTREC (800) 424-9300 In the District of Columbia, call 483-7616. In Alaska, Hawaii and Canada call (202) 483-7616. Puerto Rico and the Virgin Islands can use the "800" number. In many cases, the CHEMTREC communicator will be able to establish direct contact with the shipper(s) of the product(s) involved. The BUREAU OF EXPLOSIVES (202) 293-4048 (espe cially for hazardous materials involving railroads). An up-todate, free list of Bureau of Explosives' inspectors and their locations throughout the United States and Canada may be obtained by writing; The Bureau of Explosives Association of American Railroads 1920 L Street, N.W. Washington, D.C. 20036 MOD 000016913 4-A TABLE OF CONTENTS NOTICE TO USERS.............................................................................................................................................................. 2-A BASIC ORGANIZATION OF THIS BOOK....................................................................................................................... 2-A TABLE OF CONTENTS........................................................................................................................................................ 3-A INTRODUCTION....................................................................................................................................................................... 4-A RECOMMENDATIONS FOR RESPONSE (GENERAL RULES)................................................................................. 4-A RECOMMENDATIONS FOR RESPONSE (KEYED TO DOT HAZARD CLASSES)........................................ 5-A FLAMMABLE GASES..................................................................................................................................................... 5-A ASSESSMENT OF TANK DAMAGE................................................................................................................ 6-A FLAMMABLE LIQUIDS................................................................................................................................................... 6-A NONFLAMMABLE GASES............................................................................................................................................ 7-A CORROSIVE MATERIALS............................................................................................................................................ 8-A POISON B MATERIALS............................................................................................................................................... 8-A FLAMMABLE SOLIDS.................................................................................................................................................... 9-A OXIDIZERS........................................................................................................................................................................ 9-A ORGANIC PEROXIDES.............................................................................................................................................. 10-A POISON GASES........................................................................................................................................................... 10-A RADIOACTIVE MATERIALS...................................................................................................................................... 10-A EXPLOSIVES.................................................................................................................................................................. 12-A BLASTING AGENTS.................................................................................................................................................... 12-A IRRITATING MATERIALS.......................................................................................................................................... 13-A ETIOLOGIC AGENTS................................................................................................................................................. 13-A OTHER REGULATED MATERIALS (ORMs)....................................................................................................... 13-A AN EXPLANATION OF TERMS USED FOR EMERGENCY RESPONDERS................................................ 14-A INTERGOVERNMENTAL MARITIME CONSULTIVE ORGANIZATION (IMCO) HAZARD CLASS NUMBERS AND DESIGNATIONS............................................................................... 16-A COMMODITY SPECIFIC EMERGENCY RESPONSE AND ENVIRONMENTAL CONTAINMENT INFORMATION....................................................................................... 1 CROSS REFERENCE INDICES DOT INDENTIFICATION NUMBER/COMMODITY(IES)/PAGE(S) .................................................................. 545 DESCRIPTION OF STCC ORGANIZATION........................................................................................................... 566 STANDARD TRANSPORTATION COMMODITY CODE (STCC)/COMMODITY/PAGE............................. 567 AFTERWORD AND ACKNOWLEDGEMENTS................................................................................................................ 589 3-A K you have the following information when you call, help will be able to reach you much faster: 1. Your name, location and telephone number 2. Location of the incident 3. Carrier involved 4. Vehicle reporting marks (Car or truck numbers) 5. Placard/label applied 6. Name of commodity and shipper 7. Accessibility 8. Weather conditions 9. Local population information 10. Topographical features 11. Availability of water 9. Be aware that there are iegai requirements to report hazardous materials accidents to many agencies including the U.S, Department of Transportation--EPA/Coast Guard National Response Center. * All carriers must make immediate report to the DOT/ National Response Center at (800) 424-6802 (in the District of Columbia, call 426-2675) of any incident in which hazardous materials are responsible for death, serious injuries, property damage in excess of $50,000, or continuing danger to life and property. * All releases of hazardous material (and releases of radioactive materials or their involvement with fire) must be reported on Form F5800.1 to the DOT within 15 days of discovery. Releases of radioactive material are also subject to Nuclear Regulatory Commission and Depart ment of Energy reporting requirements. The telephone numbers (and regional offices of the DOE) are given in the section on radioactive materials which appears later in this portion of the book. * Rail carriers, in addition, should report all serious inci dents to the Bureau of Explosives, Phone (202) 2934048. The Bureau should receive a copy of all F5800.1 reports submitted to the DOT by rail carriers. RECOMMENDATIONS FOR RESPONSE (KEYED TO DOT HAZARD CLASSES) FLAMMABLE GASES GENERAL Flammable gases are often ignited immedi ately following a breach of their container. If not, the vapors can and often do flow until an ignition source--such as a highway flare or a hot exhaust manifold--is reached. When this happens, the entire cloud can catch fire almost at once. A gas leak that has ignited should not be extinguished unless the leakage can be stopped. Attempts to shut off the supply should be made only under streams of water to keep the metal cool. Let the gas burn if the valves cannot be closed. Tanks in intense fires, or exposed to flame impingement, especially if it is "torch-like,'' may rupture violently, producing a large fireball (up to 1800 feet across) and may hurl even large fragments nearly half a mile. Additional information about these materials will be found in the detailed commodity section which follows. This information should be consulted when assessing the danger of an accident situation involving these materials. IF ON FIRE If a flammable gas car is burning at the safety valve, manway cover, product valves or at a hole in the tank and the flames are not impinging on another car, there is relatively little risk of violent rupture of that tank from such a fire. Under such conditions, allowing the car to bum itself out has proven a safe course, even though the flames may bum for an extended time--perhaps several days. Allowing the nonburning vapors to spread may cause a sudden, violent, flash fire as noted earlier. Cars which are punctured and have burned out often have enough vapor left in them to create an explosive mixture in the tank. The tank must be purged when the fire goes out. One way to accomplish this is to flood the tank with water. VAPORS Flammable gas shipped in single unit tank cars is shipped as a liquified gas. This is important to know because these liquified gases will vaporize under normal condi tions and produce 200 to 600 volumes of vapor for each volume of liquid. The flammability range, a factor which varies for each material, is also an important factor. Some of these gas vapors are flammable in mixtures as lean as 2%: in other words, vapor diluted by 50 voiumes of air to 1 volume of vapor couid be flammable. Flammable vapors released from an opening in a tank car cannot be confined and wiki ignite upon contact with any spark, flame or other sufficient heat source and will bum with great rapidity, violence, and intensity back to the opening from which the vapor originated. After the flash of fire, the gas will bum above the surface of the liquid or at the point of discharge. If liquid or vapor is released from a tank car, all sources of ignition must be kept away from it or any area where the vapor concentration is at or above the Lower Explosive Limit (LEL). Explosimeters or other detectors are available to check for dangerous concentrations. If tank cars are breached or ruptured in a derailment, all people and power equipment should be kept at least 2500 feet away until the boundary of the LEL is known. Continual monitoring of the LEL boundary is required until the discharge is stopped and the vapors are known to have dispersed. Take these steps to avoid setting the vapors on fire: 1. Extinguish all fires, smoking materials and remove all other possible ignition sources from the vicinity. When lights are necessary, use only spark proof electric flashlights. Keep internal combustion engines well away from the vapor cloud. Do not allow trains to pass on adjoining tracks, or vehicular traffic to pass on adjacent roads as long as the LEL detectors show readings at or above the lower explosive limit. Use an LEL detector to determine the boundary of the lower explosive limits of a flammable vapor cloud. 2. Post guards and keep all spectators at least 2500 feet away. 3. Dig holes and trenches, or build earthen dikes in the path of the flowing liquid to reduce the liquid's surface area from which vapors can be given off. The vapor of flammable gas is usually heavier than air and tends to form a layer on the ground. These vapors will flow following the slope of the ground, and will settle in low places and places sheltered from the wind. Vapors wiil not drift or flow against the wind but may travel a considerable distance with wind. Dispersion of vapors will depend on the wind speed and direction. Vapor dispersion may be aided by using streams of water to break up the vapor at the point of leakage from the car. Water fog will tend to disperse vapors in still air. 4. Do not permit flammable gas to drain into sewers since vapor arising from it may ignite at some point far distant from the leak. Do not permit liquid to drain into water sources. Con taminated water may cause environmental harm. 5. Locate all leaks and stop them if possible. 5-A Mcd 000: '91, 6. Wrecking operations or transfer of contents of tank cars of flammable gas should not be attempted until all vapors in that vicinity are dispersed. Cutting torches must not be used on tank car tanks, either loaded or empty unless purged. 7. tf leaks are expected during the handling of wrecked cars or other vehicles, transfer their contents to another car or con tainer. Transfer of flammable gases should only be performed by trained personnel who are experienced in the necessary techniques. ASSESSMENT OF TANK DAMAGE Tank cars and other bulk containers involved in accidents may suffer severe damage without an immediate loss of their lading. This damage may look impressive, even awesome, and yet the car or other container may still have sufficient reserve strength to permit it to be carefully removed from the accident site, with its contents, for later transfer or unloading. The most treacherous damage that can occur to tanks and other containers is that caused by bending, denting, scoring or gouging without resultant leaks. Time, pressure and handling can result in a delayed rupture. If this happens, almost always there will be enough heat caused by the tearing of the metal to ignite the contents of the tank and cause the same kind of fireball described earlier. It must be noted that flammable gases are usually shipped in tank cars with external jackets. "Tank" damage refers to injuries suffered by the tank itself and not by the outer jacket. The pres ence of an outer jacket may be detected by observing the car to see if the ripped or tom outer covering reveals insulating material and, beneath that, another layer of metal. Resolve all doubts in the direction of safety and never attempt to cut or "jack" away the outer skin to search for an inner tank. The assessment of tank damage is not a casual matter and requires the presence of trained experts. The guidelines pre sented here are only intended to allow those first on the scene to make an initial appraisal for purposes of ordering a retreat until expert appraisal advice is available. The Bureau of Explosives, tank car builders and some major shippers of hazardous mate rials can assist in evaluating damage to tank cars and other bulk containers involved in accidents. Each dent, score or gouge must be examined. As adjacent cars or surrounding materials are removed, or as the tank itself is moved, the newly exposed surfaces must be examined as well. Dents in combination with scores, gouges or cracks and dents which cross a weld seam are the most dangerous and the tighter or smaller the radius or curve of the dent, the more danger ous it is. Dents in the cylindrical section of the tank, parallel to the long axis, are usually considered to be more dangerous than large dents in the head, but even large head dents are dangerous if they appear in conjunction with a gouge, score or crack. Small head dents (not exceeding 12" in diameter), especially with tight ly bent edges, should be considered marginal and may justify unloading in place, usually by transferring the material to another tank car or other container at the accident scene. Any crack in the base metal of a tank, especially if in com bination with a dent, score or gouge, justifies unloading the tank before it is moved (except as may be necessary to get the valves upright or at least accessible). Scores or gouges are especially dangerous if they are longi tudinal and approach 1/16 inch in depth. (The steel in some cars, and their pressure ratings in relation to the vapor pressure of the product they contain, may allow scores of greater than 1/16 inch without a fatal loss of residual strength, but these distinctions are not important from the point of view of initial emergency response decisions.) To repeat, the assessment of tank damage is a skill that requires training and the evaluation of not just the damage to the tank itself, but also such factors as outside air temperature, the product in the tank and its vapor pressure and the internal pres sure in the tank. In a questionable situation, the best course is to withdraw half a mile, send for expert help and keep the tank cool. "Keeping the tank cool" does not always mean flooding it with hose streams. In a non-fire situation, a spray or fog may be able to envelop the whole car and keep a film of water on it, allowing both evaporative cooling and cooling by conduction. The cooling effect of water applied to an insulated tank is question able. However, a tear in the jacket or the destruction of insulation by fire or physical causes may make an insulated tank operatively non-insulated in an emergency situation. When a fire, especially a "torching" fire, impinges on another tank, a heavy hose steam directed at the point of flame contact may prevent a dangerous heat and pressure build up in the non punctured tank. A "torching" fire occurs when a tank has been punctured and the flammable gas is burning out of the hole in a strongly projecting flame. With this kind of fire, unmanned monitor nozzles provide greater protection for firefighters than hand lines. Another situation where flooding with water may be in appropriate occurs when the water temperature is higher than the temperature of the product in the tank. This is often the case during the winter months. It must be remembered that a water attack is almost never the first thing that emergency responders should attempt. The General Rules stated earlier, especially those relating to making an initial survey and obtaining specific product identification and information, should be followed prior to laying, charging and using hose lines. FLAMMABLE LIQUIDS GENERAL Flammable liquids have a flash point below 100 F (37.8C). The flash point of a liquid is the temperature at which that liquid will give off enough vapor for ignition to occur. While the term "flash point" is often misunderstood, it is an important concept to understand because it is the vapor which bums, not the liquid. The possibility of ignition is greatest for liquids having low flash points. The lower the flash point, the greater the probability that either the temperature of the liquid or the temperature of the surrounding air will be higher than the flash point of the liquid. The higher these temperatures, the greater the amount of vapor formed and, thus, the greater the hazard. Quite frequently, when leakage occurs in the course of a derailment, ignition is caused instantly by friction sparks. If the vehicle(s) involved in the accident are carrying pack ages of flammable liquids (in other words, if they are not tank cars or tank trucks), one should assume that the packages are broken and that leakage which could cause a fire has occurred. The presence of vapors will generally be indicated by odors charac teristic of the chemical. If it is safe to do so, any vehicle containing packages of flammable liquids should be open for ventilation. The vehicle or packages marked with flammable liquid labels should be carefully removed to a safe place, away from ignition sources. When the leakage is continuous, ventila tion will probably not remove the danger. In this case, removal of ignition sources is imperative for the safety of responders. Flammable liquids spilled from broken packages should be well covered with chemically compatible dry absorbent material, including earth, sand or special sorbents. Flammable liquids with a low boiling point, such as ethylene oxide, carbon bisulfide and diethyl ether, may develop sufficient pressure inside a tank that the criteria for ASSESSMENT OF TANK DAMAGE, discussed earlier under flammable gases, will also be of use in evaluating an accident in which they are in volved. Additional information about these materials will be found in the detailed commodity section which follows. This information should be consulted when assessing the danger of an accident situation involving these materials. IF ON FIRE In addition to the general emergency re sponse recommendations given earlier, there are other actions or considerations which may reduce the hazard and aid in contain ing and extinguishing the fire: 1. Pull away any other cars or vehicles that are movable and not burning. 2. Dig holesorbuildearthendikes in the pathofthe burning liquid vapors to limit and contain the fire area and protect other cars or adjacent property. 3. Smotherfires around the car or other vehicle. Sand, dirt, foam and carbon dioxide are good agents. Water from a fog nozzle may smother the fire, but water is likely to float the liquid and may act to spread the fire. When vapors are burning at the safety valves, do not extin guish the flame unless re-ignition can be prevented. Putting out a fire at a safety valve may allow leakage from the valve to spread and ignite, causing a sudden violent flash fire. It is safer to let the vapor burn at the valves or point of leakage. The fire may be controlled to protect the surrounding area (both other transportation vehicles and surrounding property). Generally it is a good idea not to extinguish the fire at its source until all spilled material has either been burned or its re-ignition can be prevented. 4. Watch all tanks in the fire for evidence of bulging or the appearance of red-hot spots in the metal. Both are indications that the strength of the steel is being reduced by the heat to a point where it may not be able to hold the pressure in the tank maintained by the safety valves. If these signs are observed, keep all persons away from the tanks; if the metal fails, a stream of burning liquid or vapor may be projected many feet. 5. If sufficient water is available, use it as a fog to cool tanks affected by the heat of the fire. Remember that the run-off from the fog streams may spread the burning liquid. 6. As a general recommendation, do not puncture or rupture the shell of a transport vehicle involved in a fire because any opening made in a tank will liberate more flammable liquid and extend the fire. (There are circumstances in which it may be determined that a deliberate "holing" of the tank is necessary to reduce the time of the exposure or to permit other mitigating actions to take place more quickly. This determination, and its implementation, should only be made by experts. The Bureau of Explosives, tank builders and some major shippers of hazardous materials can assist in these decisions.) 7. The safety valves on tank cars are designed to limit the internal pressure to much less than the bursting pressure of the tank. In order to work, they must not be left open, broken off or buried. If the safety valves are obstructed, try to move the tank car in a position to let the valves function property. IF NOT ON FIRE When fire does not occur immediately in a wreck, the hazard of a leak of flammable liquid is generally considered to be greater than when fire is immediately present. The vapors of a flammable liquid will spread over a greater area (and often more rapidly) than the liquid. While the liquid will flow down hill, the vapors travel down wind and may engulf slight high spots that were "safe" only moments before. Vapors cannot be confined and will ignite upon contact with any spark or flame. Vapors will bum with great rapidity, violence, and intense heat back to the liquid surface from which they originated. After such a flash of fire, the vapor will bum above the surface of the liquid. When the material is not on fire: 1. Extinguish all sources of ignition in the vicinity. When lights are necessary, use only spark proof electric flashlights. Keep internal combustion engines out of the vapor cloud. Use an explosimeter or other detector to determine the boundary of the lower explosive limits (LEL) of a flammable vapor cloud. Keep people and power equipment at least 2500 feet away until the boundary of the LEL is known. Continual monitoring of the LEL boundary is necessary until the discharge is stopped and the vapors are known to have dispersed. 2. Post guards and keep all spectators over 2500 feet away. 3. Dig holes or trenches or build earthen dikes in the path of flowing liquid to contain the leak. This limits the amount of surface area from which vapors can come. 4. Cover the liquid with sand, dirt, or any other avaiiable mate rial which will blanket the surface and reduce the rate of evaporation. The vapor of gasoline and most other flam mable liquids is heavier than air and forms a layer along the ground which mixes with the air. This mixing action is in creased by wind. These vapors flow along the ground and settle in low places sheltered from the wind. They will not drift or flow against the wind but may travel a considerable dis tance with it. 5. Vapors can be dispersed by spraying with a water fog. The run off should be checked for flammable concentrations of the liquid. Do not permit the liquid to drain into sewers be cause vapors arising from the liquid may ignite at some point far distant from the leak and cause serious property damage or personnel injury. The contaminated water may cause environmental harm if allowed to mix with surface or ground water. 6. Attempt to dose tank valves and stop all leaks if possible. Wooden plugs are helpful and may be carried in the rail road's wreck train or as part of the equipment of a wreck clearing contractor. 7. Wrecking operations as well as the transfer of the contents of the vehicle should not be attempted until all vapors are dispersed. 6. Cutting torches must not be used on empty or loaded cars as tong as detectors show readings above the LEL. When cut ting torches are deemed safe to use, avoid contact with either products which have leaked or with ground saturated with such leakage. These materials can be ignited and will bum as do flammable liquids. 9. Many liquids that are regarded as safe under ordinary condi tions and transported as combustible or non-regulated mate rials should be treated as dangerous when handling a wreck. An empty or partially empty tank car, with or without plac ards, should be regarded as containing a vapor-air mixture which may ignite. 10. Fumes in any empty tank car can injure a person. An empty tank should not be entered without personnel protective equipment adequate for its internal atmosphere until it has been thoroughly cleaned and checked for residual vapors. 11. Move the least damaged cars to safety and avoid sudden shocks or jars that might produce sparks or friction. Do not move a damaged tank car that is leaking flammable liquid. If a tank car with only a small leak must be moved a short distance, it may be possible to attach a bucket under the leak to prevent the spread of the flammable liquid. 12. Do not allow trains to pass on adjoining tracks, or vehicular traffic to pass on adjoining roads, as long as the explosimeter shows reading at or above the lower explosive limit. NONFLAMMABLE GASES GENERAL Taken as a group, nonflammable gases are materials which do not (readily) bum and which have, in a con tainer, either an absolute pressure exceeding 40 pounds per square inch (psi) at 70F. or, regardless of the pressure at 70F., an absoute pressure exceeding 104 psi at 130F. The most common nonflammable gases in transportation are anhydrous ammonia and chlorine. Both of these commodities can be deadly. Whenever possible, the shipper should be called MCI) 000016917 7-A upon to assist in handling accidents in which these commodities are involved. The transfer of the contents of a car of non-flammable gas should only be done by persons familiar with the risks Involved and trained in the proper procedures and precautions. The criteria discussed in ASSESSMENT OF TANK DAM AGE which appeared above, in the section on flammable gases, are also applicable to most of the tanks used to transport non flammable gases. Additional information about these materials will be found In the detailed commodity section which follows. This information should be consulted when assessing the danger of an accident situation involving these materials. IF FIRE IS PRESENT If the wreckage is on fire, the heat of the fire will tend to vaporize any leakage and may carry the fumes skyward. If the car or container is not leaking, every effort should be made to extinguish the fire or to move the car or container away from the fire. The tanks of single-unit tank cars authorized for the transpor tation of nonflammable gases may or may not be insulated. They are equipped with safety valves which are designed to prevent the build up of excess internal pressure. Gas cylinders, with few exceptions, are provided with safety devices to prevent rupture in case they are exposed to fire. All unauthorized persons should be kept at least 1500 feet away in case the cylinder bursts due to flame or heat impingement. An explosion could throw pieces of the cylinder several hundred yards. IF FIRE IS NOT PRESENT If there is a leakage of liquid from any container of nonflammable gas. avoid contact with the liquid because it is likely to cause destruction of the skin tissues by freezing. Water spray should be used to knock down the vapors, but the run-off from the spray may have to be collected and/or neutralized to prevent further danger to persons, property and the environment. Because of the poisonous and irritating nature of most of these gases, all persons in the vicinity of a leak should be kept upwind. All persons in the path of irritating or poisonous fumes should be moved to a safe location. The leaking car or container should, if possible, be moved to a point where the escaping vapor will be carried by the wind away from occupied buildings or locations. It is difficult to stop compressed gas leaks, except where the gas escapes through an open valve. A leaking cylinder containing ammonia, chlorine, or sutfur dioxide should be moved to an isolated place. Cylinders of compressed gases that are not leak ing should be removed from the wreck. Avoid breaking any valves or striking the cylinders. CORROSIVE MATERIALS GENERAL Corrosive materials are liquids or solids that cause visible destruction or irreversible alterations in human skin tissue, or, in the case of a leakage from its packaging, a liquid that has a severe corrosion rate on steel. if corrosive materials come in contact with the body, water should be applied immediately and in large enough quantities to wash the material away. A general rule is to liberally wash the affected area for at least 15 minutes, if this action is taken quickly enough, it is possible to prevent or greatly reduce injury. Avoid breathing the vapors of corrosive materials. They can cause severe respiratory distress, the onset of which may be delayed by hours or even days. If the contents of a car of corrosive materials must be trans ferred, persons familiar with the dangers and techniques should perform the task. A good supply of water should be kept at hand in case of splashes or spills. Additional information about specific corrosive materials will be found in the detailed commodity section which follows. This information should be consulted when assessing the danger of an incident involving these materials. IF FIRE IS PRESENT The heat of a fire can accelerate the corrosive action of some of these materials. Some, but not all, corrosive materials are combustible or burnable. Specific fire response recommendations will be found in the detailed com modity section which follows. IF FIRE IS NOT PRESENT If the leak is small, a bucket can be used to prevent the leak from spreading. The bucket will have to be of a material not attacked by the corrosive involved. Larger spills will require the digging of holes or the building of earthen or sand dikes. Saturated soil may have to be neutralized or otherwise disposed of to prevent long term environmental harm. Factors to consider in the decision for containment are the soil characteristics and the location of water, if the soil is porous or near watersheds or water sources, additional measures-- such as lining the containment area and on site soil neutraliza tion--may be necessary. POISON B MATERIALS GENERAL These materials are liquids and solids (in cluding pastes and semisoiids), other than Class A Poisons or materials classed as "irritating," which are toxic to humans through ingestion (eating), inhalation or absorption. The vapors of some Ctass B poisons can be dangerous or offensive but to a lesser degree than the gases or liquids requiring the "Poison Gas" label or placard. Some of these poisons are flammable and expert advice from the shipper should be obtained if at all possible. If poisons come in contact with the body, immediately wash affected areas with water or soap and water. If they can be washed off quickly enough, injury may be prevented. Any person affected by the vapors should be removed from the area and placed on his/her back with head and back elevated. Call a physician immediately and tell the doctor the name of the poison involved. If clothing is saturated with poison, remove it to prevent further poisoning. Keep patient warm and quiet. If breathing has apparently ceased, start resuscitation immediately but remember that mouth-to-mouth artificial respiration may expose the rescuer to fumes inhaled by the victim. Personnel should be evacuated from the area known or suspected to be contaminated by the materials or their vapors. Whenever possible, monitoring equipment should be used to aid in determining and evaluating the contaminated area. Protective clothing should be worn by personnel dealing with the incident, and should be decontaminated after exposure. Vehicles which contained any poisonous materials must be thoroughly deemed after unloading or before going back into service. Additional information about these materials will be found in the detailed commodity section which follows. This information should be consulted when assessing the danger of an acddent situation involving these materials. IF FIRE IS PRESENT Fires may be fought using con ventional means, but all personnel in the area should have pro tective gear appropriate for the material(s) involved. Because the run-off may be contaminated, precautions should be taken to contain and reduce the area affected by the run-off. The methods usually available, such as digging holes or building earthen dikes, aFe often effective. However, any countermeasure should be evaluated to reduce not only the short term problem but also to reduce the potential post-accident cleanup costs and long term environmental degradation. IF FIRE IS NOT PRESENT If any container of these materials is leaking, no person should be allowed to enter the contaminated area without appropriate breathing apparatus and other protective equipment suitable for the material. If qualified persons are available, attempts to plug the leak or reduce the amount of leakage by use of wooden plugs may be made. Smaller containers, such as drums, can often be prevented from leaking by positioning the container so that the leak is above AfC'D OC>0169 18 8-A the level of the product. With tank cars or tank trucks, this may be possible if heavy equipment and operators trained in the neces sary techniques are available. Rolling tank cars or trucks is a specialized "art" and not every operator of heavy equipment has the necessary skill. The Bureau of Explosives can assist in eval uating the procedures to be used. Every precaution must be taken to keep leaking liquid from contacting the skin. At least two persons should work together. The second person should be available to help the first in case of an emergency. Digging holes or building earthen dikes to prevent any leak age from spreading is usually effective, but the effects of this action on post-accident cleanup and long-term environmental problems should be considered. Decontamination procedures will depend on the material involved. The agencies listed in the general recommendations section, earlier, may be able to pro vide help. If it is necessary to transfer the contents of any containers of these materials, persons skilled in those operations should per form the task. The shipper, nearest manufacturer or the Bureau of Explosives may be able to provide the necessary assistance. When handling or transferring these materials, appropriate pro tective equipment must be utilized. FLAMMABLE SOLIDS GENERAL There are only two major materials classed as flammable solids which are shipped in tank cars: phosphorus and sodium. Phosphorus will ignite with air at or above 86F. It is explo sive when mixed with oxidizing materials. Phosphorus tank cars in a derailment are likely to have a ruptured disc. Cars with a ruptured disc should be filled with water and the disc should be replaced. Phosphorus on the outside of the car should be scraped off (after it stops burning) and disposed of in an appropriate facility. Scraping may expose unbumed phosphorus which will bum H not kept under water. Protective clothing is required because phos phorus bums are very painful. Inhaling small amounts of phos phorus can be fatal. ' A leaking phosphorus car will burn until it crusts over. This fire should be fought with dirt or sand (preferably wet) and the phosphorus should be contained as near the car as possible. Once the fire is out, the car can be moved under water fog to clear the right of way. A dike should be built to prevent further fires. Spilled phos phorus can be temporarily buried under a mud cap until wrecking operations are completed. The residue from burned phosphorus is phosphorus pentoxide, a corrosive material which will dissolve In water to form phosphoric acid, another corrosive material. Final disposal of the car and the remaining product and residues will have to be coordinated with an appropriate environmental protec tion agency (usually Federal and/or state) and with the shipper or consignee. Sodium is a water reactive flammable solid. DO NOT USE WATER ON SODIUM. If a sodium car leaks, use dry soda ash, dry earth, salt, lime, powdered limestone, or any dry inert sub stance. DO NOT USE WATER, CARBON DIOXIDE, CARBON TETRACHLORIDE, FOAM, OR ANY OTHER LIQUID FIRE EX TINGUISHING AGENTS INCLUDING FREONS, because they will either cause a fire or will react violently with sodium. Burning sodium releases sodium oxide fumes which will react with water to produce sodium oxide fumes which will react with water to produce sodium hydroxide (caustic soda) which is injurious to eyes, skin, and mucous membranes. Other commonly shipped flammable solids include "strike anywhere" matches and charcoal. Naturally, they are not shipped in tank cars, although under certain conditions the DOT regulations permit charcoal to be shipped in bulk. Fire in shipments of "strike anywhere" matches is frequently caused by the ignition of the match heads in one or more of the inner cartons. If the outer box is not broken or opened, the fire is generally confined to these cartons, and after the head composi tion of the matches is consumed, the fire goes out. tf the outside box is not broken, and the smoke dies away after a few minutes, no further action is necessary, because the fire has already been extinguished from a lack of air, and nothing will be gained by opening the box. if the tire has gained some headway, the burn ing box or boxes should be removed, if possible, or water should be freely used. Boxes should not be broken open any more than necessary because this will only add more fuel and may add to the tire. When charcoal is on fire during transit, water should not be used if it is practicable to locate and remove the material on fire. This is because wet charcoal is much more liable to ignite spon taneously, and the tire cannot be stopped permanently except by the use of copious amounts of water. Fires in ground charcoal or in charcoal screenings are best handled by removing the burning packages, if fhis is not practical, water should be used sparingly to extinguish the visible fire, then remove all the charcoal and separate the wet from the dry mate rial. The wet charcoal must be destroyed. The dry charcoal should be stored under cover in a dry place, and held under observation for at least five days before further shipment, in order to reduce the chance of another ignition. Additional information about these materials will be found In the detailed commodity section which follows. This information should be consulted when assessing the danger of an accident situation involving these materials. OXIDIZERS GENERAL A few oxidizers are shipped in tank cars and most of them will cause fire in contact with combustible materials. Nitric acid, mixed acid, perchloric acid, or hydrogen peroxide are examples of oxidizers shipped in bulk quantities by rail. All of these may cause fire when brought into contact with combustible materials. In accidents involving chlorates, care is necessary to prevent ignition by friction or by contact with acids. When chlorates are mixed with organic matter, or even with dust, they form very flammable mixtures. Chlorates in contact with sulfuric acid are liable to cause fire or explosion. Solid oxidizers that are mixed with finely divided combustible material may bum with almost explosive violence. If it is necessary to transfer the contents of a car of these materials, persons familiar with the dangers and techniques should perform the task. Additional information about these materials will be found in the detailed commodity section which follows. This information should be consulted when assessing the danger of an accident situation involving these materials. IF FIRE IS PRESENT For liquid oxidizers, water should be used in sufficient quantity to extinguish the fire and to dilute and wash away the liquid. (Remember that the run-off may also be hazardous. Contaminated water should be contained for treat ment or disposal.) Whenever water contacts acids, splattering and slight explosions will occur; thus, a stream of water should be applied to the fire from a safe distance. (A good "safe distance" In this case is maximum distance that water from hose streams can be applied effectively.) The reddish fumes caused by fires of nitric acid or mixed acids are irritating and poisonous. Do not expose personnel to such fumes unless they are equipped with self contained breathing apparatus and full protective clothing--the fumes can cause skin damage. Wien solid oxidizers, such as sodium nitrate and other nitrates that ordinarily will not bum, are mixed with organic matter during the course of an accident or its cleanup, they will bum strongly if ignited. The heat of burning melts the nitrate which will then ignite any combustible material it touches. Melted nitrate holds a great deal of heat and when water is thrown on it, the sudden generation of steam will cause the melted nitrate to 9-A MOB 000016919 spatter and start a fresh fire. Whenever practical, fires in nitrate shipments should be smothered with earth or sand. Water should only be used when the fire is small. For the reasons stated above, the use of water on large fires of solid oxidizers is seldom effective. IF FIRE IS NOT PRESENT Position personnel upwind from the spill or leak. Because these materials can react with combustible materials, such as leaves and twigs, to cause fires, digging holes or the building of earthen dikes may not be effec tive. Containing the material in an area cleared of combustible material may help to reduce the hazard. ORGANIC PEROXIDES GENERAL These materials may be either liquids or solids. They support the burning of combustible materials. Under prolonged exposure to fire or heat, containers of these materials may explode. Liquid organic peroxides take some effort to ignite but once ignited, they burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination of organic peroxides with a wide variety of chemical substances can cause a violent chemical reaction, therefore, care must be taken during the response effort to consider material compatibility. Solid organic peroxides are more readily ignited and burn with increasing rapidity as the fire progresses. If mixed with finely divided combustible materials, explosive mixtures may be formed. Some organic peroxides are shipped under refrigeration. If the refrigeration fails, the product may decompose and give off sufficient heat to start a fire. The driver of a vehicle containing refrigerated organic peroxides is usually highly trained in the properties and handling of the material and has additional tech nical information on the material in the shipment. Additional information about these materials will be found in the detailed commodity section which follows. This information should be consulted when assessing the danger of an accident situation involving these materials. POISON GASES GENERAL The fumes from poison gases are deadly. Inhalation or contact with the vapors can be fatal and should be avoided. Often poison gas leakage is not noticeable because it cannot be seen or smelled. Use extreme care when handling any container of these gases. The shipper or the nearest manufactur er of the gas should be called for assistance in any incident involving leakage. Poison gases are transported in single unit tank cars, in cylinders and in multi-unit tank cars. The multi-unit tank car looks like a flat car with a series of cylinders carried on their sides, arranged so that the ends of the "cylinders" (actually DOT Speci fication 106 or 110 tanks) point towards the sides of the car. The "tanks" or multi-unit tank cars, which may also be transported on trucks or trailers, are detachable, are not insulated and, when used for the movement of poison gases, are not equipped with safety relief devices. Additional information about these materials will be found in the detailed commodity section which follows. This information should be consulted when assessing the danger of an accident situation involving these materials. IF FIRE IS PRESENT Because they are not equipped with safety devices, cylinders or multi-unit tanks are liable to burst or rupture when involved in a fire or when subjected to prolonged intense heat. Evacuate the area if the fire cannot be brought under immediate control to protect persons from cylinder frag ments and from fumes should an explosion or a rupture occur. If poison gas tanks are not leaking but are endangered by fire. every effort should be made to extinguish the fire around them or to move the tanks away from the fire. if the tanks are leaking, the fire may tend to vaporize the leakage and carry its fumes skyward. Do not rely on this to happen. In clearing a wreck involving these tanks, cutting torches should only be used with extreme caution and then only by persons well trained in their use and familiar with the dangers involved. IF FIRE IS NOT PRESENT II there is leakage of liquid or gas from a tank or cylinder containing poison gases, keep all persons out of any area where the vapors may accumulate. Detectors for the presence of these fumes are available, but are often so product specific that they may not be readily available. Personnel in the area should be limited to those absolutely essential to make a survey of the danger present. Immediate assistance should be secured from the shipper or consignee. No person should be allowed to enter the gas contaminated area without being equipped with a self-contained breathing apparatus and fully protective clothing. Persons using such apparatus must be qualified and experienced in its use. Cooling the tank with streams of water may be effective in reducing the internal pressure and rate of leakage. If it is possible to roll the tank so the point of leakage is at the top, the hazard may be reduced considerably. At least two persons should work together, with the second holding him/herself in position to be of assistance to the first in case of emergency. Any person affected by the gas should be removed from the contaminated area and placed on his/her back with head and back elevated. Call a physician immediately and tell the doctor the poison to which the victim has been exposed. If clothing is saturated with the gas, remove it to prevent skin irritation and bums. Keep the patient warm and quiet. If breathing has appar ently ceased, start resuscitation immediately, but remember that mouth-to-mouth artificial respiration may expose the rescuer to fumes inhaled by the victim. RADIOACTIVE MATERIALS GENERAL These materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful, where as films may be damaged by radiation of relatively low concentra tions. The long term exposure of humans to relatively low levels of radiation may also be hazardous over time, but this is not usually a relevant consideration at an accident site where exposures are likely to be brief. Additional information about these materials will be found in the detailed commodity section which follows. This information should be consulted when assessing the danger of an accident situation involving these materials. GENERAL INSTRUCTIONS: 1. Until the extent of the hazard can be determined, keep all persons the greatest practicable distance away. 2. Trains and vehicles may pass if they can do so without stop ping in the suspected area and without scattering spilled material. 3. Except tor Low Specific Activity materials, PERSONS NOT PROPERLY PROTECTED AGAINST RADIATION MUST NOT BE PERMITTED TO APPROACH THE VICINITY OF ANY PLACE WHERE RADIOACTIVE MATERIAL IS SUS PECTED TO HAVE BEEN SPILLED. Protection of personnel will vary, depending on circumstances and may consist solely of radiation monitoring. In cases where radioactive material has been scattered, anticontamination clothing and a means of shielding personnel from radiation may be necessary. 4. If material is involved in fire or spillage, avoid exposure to smoke fumes or dust. 10-A MCD 000016920 5. Take precautions to avoid further spreading of spilled materials. If radioactive material is submerged as a result of the acci dent, all persons must be kept as far away from the area as is practicable until qualified persons are available to direct the removal of the submerged material. 6. Assistance in handling and arranging for the disposal of radioactive materials can be obtained from the appropriate Department of Energy Regional Coordinating Office or from the 24 hour emergency number of the Nuclear Regulatory Commission. (See map and listing beiow.) DETAILED PROCEDURE If there is evidence of any damage to a shipping container, determine, with proper instru ments, whether the outside container has been broken open and whether material has been actually exposed or spilled. If the container is damaged, it is generally recommended to proceed as follows, depending on the type of package involved. FOR SMALL PACKAGES (Fiberboard or wooden boxes or steel or fiber drums weighing less than 200 pounds.): 1. Keep all persons at least 10 feet away if practicable and do not remain near exposed material unnecessarily. 2. If it is impractical to keep persons away, sandbag or cover the radioactive material with at least 4 inches of earth or sand, using a long-handled shovel. Remain near the material only as long as is necessary to accomplish the work. 3. Contact the DOE or NRC telephone number, below, for assist ance in arranging for the removal of the material and any necessary decontamination. FOR PACKAGES OF HEAVY STEEL OR METAL CON STRUCTION (weighing 200 pounds or more and lined or partially filled with lead, concrete, or paraffin.): 1. If there is any evidence that the container has been broken open or is seriously damaged, observe the recommendations in the GENERAL INSTRUCTIONS until assistance or further advice has been obtained from a competent authority. 2. Even though a container has not been opened or damaged, persons should not remain near container unnecessarily until it has been determined that no radiation hazard exists. LOW SPECIFIC ACTIVITY (LSA) materials, such as ura nium and thorium ores, waste paper or other contaminated scrap materials, are packed in ordinary containers such as bags, steel or fiber drums, or wooden orfiber boxes and may be in the form of powders, liquids or sludges. 1. Obtain assistance of qualified persons to handle spilled mate rials. Use the appropriate DOE or NRC telephone number listed below. 2. Avoid direct contact with spilled materials. 3. Protect persons from breathing any dust which may be around these materials. This can be accomplished by approaching from the upwind side or by breathing through respirators or handkerchiefs when other means are not available. 4. Prevent the spread of spilled material and keep it out of streams, reservoirs, or other bodies of water. FOR DEPARTMENT OF ENERGY--DEPARTMENT OF DEFENSE ESCORTED SHIPMENTS (sometimes shipped as explosive and radioactive material): 1. If guards are present and not incapacitated, follow their rec ommendations with regard to safety and mitigation of hazards until other assistance arrives. 2. If the guards are incapacitated and the shipment is involved in a fire which cannot be readily brought under control, keep all persons at least a mile away and observe the recommenda tions in the GENERAL INSTRUCTIONS. 3. If the guards are incapacitated and the shipment is not in volved in fire, it should not be moved until proper Instructions for its disposition are received from the shipper or the Depart ment of Energy. 4. in addition to the report to National Response Center required in the General Rules, immediately report the accident by telephone to the Albuquerque Operations Office of the De partment of Energy, Albuquerque, New Mexico, (505) 8444667. For assistance from the Department of Energy Regional Coordinating Office, nearest you please consult the map below and call the office in the region in which assistance is requested. For military shipments (Department of Energy--Department of Defense escorted shipments) contact the Albuquerque Opera tions Office of the Department of Energy at (505) 844-4667. For assistance from the Nuclear Regulatory Commission, call (301) 492-8111. This number can be reached on a 24-hour basis. DOE Regional Offices Brookhaven 1--(516) 345-2200 Oak Ridge 2--(615) 576-6833 or (615) 525-7865 Savannah River 3--(803) 824-6331, Ex. 3333 Albuquerque 4--(505) 844-4667 Chicago 5--(312) 972-5731 or (312) 972-4800 Idaho 6--(208) 526-1515 San Francisco 7--(415) 273-4237 Richland 8--(509) 942-7381 EXPLOSIVES GENERAL Explosives are' chemical compounds, mix tures, or devices, the primary or common purpose of which is to function by explosion. These materials are divided into 3classes: Class A explosives will detonate. Class B explosives function in general by rapid com bustion rather than detonation. A fire, once initiated in these materials, is virtually impossible to extinguish until the material has been consumed. Class C explosives may contain either Class A or B explosives, but in restricted quantities. Small arms ammunition, explosive rivets and common fireworks are examples of this class of explosives. If an accident involving these materials results in an explo sion, about the only thing that can be done is to care for any injured, and to prevent the spread of any fire which may have been caused by the explosion. When these materials are involved in accidents, it is essen tial to establish early contact with the Bureau of Explosives and the shipper. For shipments of explosives made by the Department of Defense that are found in distress, contact the telephone number provided on the government bill of lading for notification/assist ance. Additional information about these materials will be found in the detailed commodity section which follows. This information should be consulted when assessing the danger of an accident situation involving these materials. IF FIRE IS PRESENT If a fire has started near explo sives. every effort should be made to put out the fire, or to remove the explosives to a safer place. Some explosives detonate im mediately on ignition, others may burn for some time before exploding, and others may be completely consumed without any explosion. However, since burning explosives must be presumed to detonate easily, efforts to extinguish them are not recommend ed. Applying water to burning explosives may precipitate an explosion through the action of the steam that is generated. In all cases where explosives are involved in fires or serious accidents on the railroad, the Bureau of Explosives should be notified. The Bureau of Explosives' representative may be able to assist in determining whether the explosive involved may have contaminated the area. If so, necessary procedures for decon tamination may be organized. The recommended evacuation distances for explosives are: Class A explosives Class B explosives Class C explosives 1 mile 1/2 mile 1500 feet. IF FIRE IS NOT PRESENT If the accident does not cause the immediate ignition or detonation of the explosives, the first and most important precaution is to prevent fire. The area should be guarded to keep all unauthorized per sons away. Because of the potential hazard, it cannot be empha sized strongly enough that access to the accident site should be limited to only those experts necessary to make an initial assess ment. All other response personnel should remain beyond the recommended evacuation distances. Before beginning to clear a wreck containing explosives, remove all unbroken packages to a place of safety and gather any remaining explosive material rendered inert. Many explosives are readily set off by a direct blow or by the spark produced when two pieces of metal or a piece of metal and stone come together. In clearing a wreck, therefore, care must be taken not to start a fire with metal tools. With most explosives, a thorough wetting with water usually removes the danger of explosion from spark or impact but with the various kinds of dynamite, wetting does not make them safe from impacts. After clearing a wreck involving initiating explosives such as fulminates or azides, the ground should be kept wet until expert decontamination help has arrived and proper final cleanup proce dures can be carried out. If the wreck involves a vehicle containing chemical ammuni tion, every precaution must be taken to prevent fire and casual ties due to gas leakage. Only those persons necessary to clear the wreckage should be allowed in the vicinity of the wreck, and they should be cautioned to keep upwind. if a shipment of propellant explosives, Class B, is involved, it will bear "Explosives B" placards. All packages in the vehicle will be marked to indicate that they contain propellant explosives. Such explosives may be in the form of very fine grains or extreme ly large solid pieces weighing several tons. Class B Explosives are not liable to explode from impact or friction, although ignition of such explosives by friction is possible. Care must be exercised while handling broken or damaged packages. Every precaution must be taken to keep Class B Explosives away from sparks or flames since many of these explosives will bum rapidly or ex plode when ignited. Care must be exercised to avoid unneces sary inhalation of smoke since the products of combustion of a few kinds of propellant explosives may be poisonous. While handling packages of explosives and transferring them to and from vehicles, the greatest care must be taken, because shocks or falls can injure the containers. The shoes of the people handling the packages must be as free as possible from grit, and all possible precautions must be taken against fire. A broken box of high explosives that cannot be repackaged should be held until the arrival of an authorized person who can supervise the destruction of the condemned material. Since particles of explosive composition from damaged con tainers may be strewn on vehicle floors or freight, care should be exercised to avoid friction or sparks from shoes, tools, or other sources. Use of metal trucks, metal hammers or other metal tools should be avoided. Vehicle floors should be thoroughly swept, and washed with a plentiful supply of water. The wash water should be contained for proper disposal. Packages of leaking liquid explosives must be disposed of carefully. Leaking packages must: * be packed in other boxes large enough to permit enclosure, * be surrounded by at least 2 inches of dry, fine sawdust or dry and clean cotton waste; and * be stored in a safe place until arrival of an authorized person to supervise the destruction of the condemned materials. Whenever a vehicle carrying explosives has received rough treatment, inspection of the packages containing explosives must be made (without unnecessarily disturbing the lading) to see that they are properly loaded and secured and are in good condition. Leaking or broken packages must be carefully re moved to a safe place. Loose powder or other explosives must be swept up and carefully removed. If the floor is wet with nitroglycer in, the vehicle is unsafe to use. The shipper should be contacted and, if the accident occurs on a railroad, a representative of the Bureau of Explosives should be called immediately to supervise the thorough mopping and washing of the floor with a warm, saturated solution of concentrated lye or sodium carbonate. If necessary, the vehicle must be moved to an isolated area and the shipper should be notified. BLASTING AGENTS GENERAL Blasting agents are chemical compounds, mixtures, or devices, the primary or common purpose of which is to function by explosion. These materials are used (primarily) in the mining and agricultural industries for blasting. These mate rials cannot be detonated with an electric blasting cap and will not explode when subject to friction or impact. When the largest single package used for shipping is subject to fire, it will not MCI' 00001 692M 12-A explode, however, fires involving more than one package may explode. If an accident involving these materials results in an explo sion, about the only thing that can be done is to care for any injured, and to prevent the spread of any fire which may have been caused by the explosion. When these materials are involved in accidents, it is essen tial to establish early contact with the Bureau of Explosives and the shipper. For shipments of blasting agents made by the Department of Defense that are found in distress, contact the telephone num ber provided on the government bill of lading for notification/ assistance. Additional information about these materials will be found in the detailed commodity section which follows. This information should be consulted in assessing the danger of an accident situation involving these materials. IF FIRE IS PRESENT If a fire has started near blasting agents, every effort should be made to put out the fire, or to remove the blasting agents to a safer place. Some blasting agents may bum for some time before exploding, and others may be completely consumed without any explosion. However, since burning blasting agents must be presumed to explode easily, efforts to extinguish them are not recommended. Applying water to burning blasting agents may precipitate an explosion through the action of the steam that is generated. In all cases where blasting agents are involved in fires or serious accidents on the railroad, the Bureau of Explosives should be notified. The Bureau of Explosives' representative may be able to assist in determining whether the explosive involved may have contaminated the area. If so, necessary procedures for decontamination may be organized. The recommended evacuation distance for Blasting Agents is 2500 feet. IF FIRE IS NOT PRESENT If the accident does not cause the immediate ignition of the blasting agents, the first and most important precaution is to prevent fire. The area should be guarded to keep all unauthorized per sons away. Because of the potential hazard, it cannot be empha sized strongly enough that access to the accident site should be limited to only those experts necessary to make an initial assess ment. All other response personnel should remain beyond the recommended evacuation distances. Before beginning to clear a wreck containing blasting agents, remove all unbroken packages to a place of safety and gather any remaining blasting agents rendered inert. Many blast ing agents are readily ignited by a direct blow or by the spark produced when two pieces of metal or a piece of metal and stone come together. In clearing a wreck, therefore, care must betaken not to start a fire with metal tools. As with most explosives, a thorough wetting with water usually removes the danger or igni tion from spark or impact. Care must be exercised to avoid unnecessary inhalation of smoke since the products of combustion of a few kinds of blasting agents may be poisonous. While handling packages of blasting agents and transferring them to and from vehicles, the greatest care must be taken, because shocks or falls can injure the containers. The shoes of the people handling the packages must be as free as possible from grit, and all possible precautions must be taken against fire. A broken box of blasting agents that cannot be repackaged should be held until the arrival of an authorized person who can supervise the destruction of the condemned material. Since particles of blasting agents from damaged containers may be strewn on vehicle floors or freight, care should be exer cised to avoid friction or sparks from shoes, tools, or other sources. Use of metal trucks, metal hammers or other metal tools should be avoided. Vehicle floors should be thoroughly swept, and washed with a plentiful supply of water. The wash water should be contained for proper disposal. Packages of leaking liquid blasting agents must be disposed of carefully. Leaking packages must: --be packed in other boxes large enough to permit enclosure, --be surrounded by at least 2 inches of dry, fine saw dust or dry and clean cotton waste, and; --be stored In a safe place until arrival of an authorized person to supervise the destruction of the condemned materials. Whenever a vehicle carrying blasting agents has received rough treatment, inspection of the packages containing blasting agents must be made (without unnecessarily disturbing the lad ing) to see that they are properly loaded and secured and are in good condition. Leaking or broken packages must be carefully removed to a safe place. Loose material must be swept up and carefully removed. IRRITATING MATERIALS GENERAL Materials in this classification are such that a person will not remain in an area contaminated by them unless escape is impossible. Upon contact with fire or exposure to air, these liquid or solid materials give off intensely irritating fumes. Those which are shipped as liquids or gases might delay the clearance of wreckage If they leak, but otherwise they are not particularly hazardous. To move leaking or broken packages, they may be approached with safety from the windward side provided there is a breeze brisk enough to carry away the fumes and the broken or leaking package is not In a confined place. The use of self contained breathing apparatus and appropriate protective gear will reduce the chance of noxious contact. Additional information about these materials will be found in the detailed commodity section which follows. This information should be consulted when assessing the danger of an accident situation involving these materials. ETIOLOGIC AGENTS GENERAL An '`etiologic agent" means a viable microor ganism, or its toxin, which causes or may cause human disease. Whenever packages bearing the "Etiologic Agents" label are discovered leaking in transit, all unnecessary movement of the vehicle must cease and the vehicle must be isolated. Contact with the material must be avoided. Immediately notify the Director, Center for Disease Control. Atlanta, Georgia (404) 633-5313, for information on handling the incident. OTHER REGULATED MATERIALS (ORM) GENERAL These materials are regulated because they may pose an unreasonable risk to health and safety or property when transported, but they do not meet the definitions of the other hazard classes in the DOT hazardous materials regulations. Other Regulated Materials are subdivided as follows; ORM'A materials have an anesthetic, irritating, noxious, toxic or other similar property and, in the event of a leakage during transportation, they can cause extreme annoyance or discomfort to the passengers and crew of transport vehicles. ORM-B materials are those which could cause damage to a transport vehicle or vessel from leakage during transporta tion. Basically, the danger from these materials is their corro sivity to aluminum and the subsequent danger they could pose for aircraft. ORM-C materials are those which are unsuitable for trans port unless properly identified and prepared. All commod ities in this group are specifically named in the DOT reguia- 13-A MCD 000016923 tions and almost all of them are regulated only for transporta* tion by water. ORM`D materials are consumer commodities in packages like those found on store shelves. They present a minimal hazard during transportation because of the form, quantity or packaging in which they move. OflM-Ematerials are those not included in any other hazard classification but which are either Hazardous Wastes or Hazardous Substances as defined by the Environmental Protection Agency. Additional information about these materials will be found in the detailed commodity section which follows. This information should be consulted when assessing the danger of an accident situation involving these materials. AN EXPLANATION OF TERMS USED FOR EMERGENCY RESPONDERS The emergency response recommendations given for the hazardous materials in the second section of this book use speci fic terms with specific meanings. Virtually all of these terms are seif explanatory to trained emergency responders, but. as an aid to training and to avoid the danger of confusion, further informa tion about many of the terms is given below. The terms will be grouped and presented in the order in which they appear in section two. FIRE Responses: "Use water in flooding quantities asfog1'--Flooding quantities are amounts of water which will engulf the object against which they are directed. The water should be applied with a fog nozzle. "Solid streams of water may be ineffective"--Solid streams of water will not provide the cooling or vapor dispersing effect that a fog will. Water applied in a solid stream will sink through a pool of chemical and will have little or no effect. "Apply water from as far a distance as possible"--Water should be applied from as far away as the hose stream will reach. Unmanned monitor nozzles are a good option if the stream can be controlled to be effective. "Suitable" (as in "Use suitable dry powder" or "Extinguish fires using agent suitable for type of fire")--The properties of the burning material must be known and the proper agent em ployed to apply to it. At the very least, this requires that the product(s) involved in the fire be known. "Do not use water on material itself"--Trie material will react with water producing noxious products. The application of water will also promote vaporization of the material due to the heat of reaction with water. "Use water spray to absorb vapors"--Apply a water fog down wind of a leak, through the vapor cloud taking care to keep water out of the container and, if present, a pool of the product on the ground. "Do not apply water to point of leak in tank car or container"-- Water will react with the product to produce a material that will markedly increase the rate of corrosion or erosion about the hole. "Water spray or foam may be ineffective"--The size of the prob able fire or the reaction between the commodity and wateror foam is such that other extinguishing agents will give a better performance. "Low order explosive potential"--A "low order explosion" has been described as one that goes "wump" or "woosh" in stead of "bang." NON-FIRE Responses: "Use water spray to knock down vapors"--Direct a water fog or spray, rather than a solid stream downwind into the vapor cloud. "Use water spray to disperse vapors and dilute standing pools of liquid"--This is basically the same advice as given just above with the added consideration of the dilution of the spilled product. "Do not use water on material itself'--As noted above under the fire responses, water will have an adverse reaction with the material. "Do not apply water to the point of leak in tank car or container"-- Also as noted above in the fire response section, application of water to the point of leak will cause a reaction between the material and the water which will increase the size of the hole. PERSONNEL Responses: Several of the recommendations in this section use the term "protective," as in "protective gloves" and "protective clothing." Obtaining protection from a hazardous commodity requires at least knowing the name of the commodity and understanding its hazardous properties. Shippers and manufacturers of chemicals, suppliers of safety equipment, NIOSH (the National Institute of Occupational Safety and Health), OSHA (the Occupational Safe ty and Health Administration), NFPA (the National Fire Protection Association), CHEMTREC, the Bureau of Explosives and stan dard chemical reference works can provide guidance about the suitability of various types of protective equipment with specific chemicals. Explanations of other terms used in this portion include: "Wear full protective clothing"--Full protection from a hazardous material requires knowing what the material is and wearing suitable protective equipment which will not be penetrated, eaten away or destroyed. If called for on materials with large leaks, full "acid suit" type gear is required. In most cases where this recommendation is given, traditional fireman's turn out gear is NOT "full protective clothing." "Avoid bodily contact with the material"--This recommendation applies to commodities with a lower personnel hazard poten tial than those for which "futl protective clothing" is appli cable. It is not to be taken lightly and requires knowledge of the material and its dangers. As a practical matter, special ized gear other than fireman's turn out gear may be re quired. "Wear self contained breathing apparatus"--For many chem icals. pressure demand breathing apparatus is not adequate and a positive pressure system must be used to prevent fumes from entering the mask during inhalation. "Do not handle broken packages without protective equip ment"--While packages which are still tight do not pose a special danger, the material which may have escaped from a broken package does require suitable protective measures. "Wear seif contained breathing apparatus when fighting fires of this material"--The fumes given off by combustion of the material require respiratory protection. "If contact with the material anticipated, wear full protective clothing''--One can be near the commodity without suffering harm, but contact with it is dangerous. "Wear boots, protective gloves and gas tight goggles"--In addi tion to the precautions already noted, this material is harmful or very irritating to the eyes. EVACUATION Responses: These responses typically mention an evacuation radius. In all cases, these are minimum distances and do not take into account particular local situations or exposures. Where an evacuation distance is mentioned in relation to fire involving a container (for example: "If fire is prolonged and mate rial is confined in the container..."), it is based on the distances which fragments have been thrown from rupturing containers of the particular product. 14-A MCD 000016924 Where an evacuation distance is mentioned in relation to a leak without tire and the commodity is nonflammable (for exam ple, "if material leaking (not on fire) evacuate for a radius of 2500 feet."}, it is based on the noxious or toxic properties of the material and the minimum potential radius of a cloud of its fumes. In the case of a flammable material, it is based on the potential that a cloud of the material will ignite and bum rapidly back to the source of the leak. Where an evacuation distance is mentioned such as "If the material is on fire or involved in fire evacuate for a radius of 5000 feet," the effects of fire on the material can be so disastrous that no attempt should be made to fight the fire. Responses such as "If fire becomes uncontrollable--evacu ate ..mean that small fires involving the material may be fought but that large, uncontrollable fires either are impossible to extinguish or may result in a violent rupture of the container. If during the preparation of a training program using this book, additional questions arise about the selection or meaning of the recommended responses, additional help is available from the Bureau of Explosives by contacting: Patrick J. Student Manager--Operations Analysis Bureau of Explosives Association of American Railroads 1920 L Street, NW Washington, DC 20036 (202) 293-4048 MCB 000016925 15--A INTERGOVERNMENTAL MARITIME CONSULTIVE ORGANIZATION HAZARD CLASSES Class Number Class Name 1 Explosives 2 Gases 3 Flammable and Combustible Liquids 4 Flammable Solids 5 Oxidizers and Organic Peroxides 6 Poisons 7 Radioactive Materials 8 Corrosives The IMCO classifications are further divided, by adding decimal numbers following the basic classes, into divisions. For instance IMCO class 2 (gases) is divided: Class 2 Division 2.1 Division 2.2 Division 2.3 Gases Flammable gases Nonflammable gases Poison gases Mod 00q1 *926 16-A COMMODITY SPECIFIC EMERGENCY RESPONSE AND ENVIRONMENTAL CONTAINMENT INFORMATION BUREAU OF EXPLOSIVES Association of American Railroads 1920 L Street, Washington, D.C. 20036 Telephone: 202-293-4048 (This number may be reached at ail times) 0001U69 ACCUMULATOR, PRESSURIZED 4904825 NONFLAMMABLE GAS NA1956 Accumulators, pressurized are devices containing a nonflammable gas under pressure. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Personnel protection Avoid breathing vapors Wear protective gloves and goggles Do not handle broken packages without protective equipment ACETAL 490B103 FLAMMABLE LIQUID UN1088 Acetal is a clear colorless liquid with a pleasant odor. It has a flash point of -5 deg. F. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams ol water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol foam, caroon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container ts exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered ACETALDEHYDE 4907210 FLAMMABLE LIQUID UN1069 POLYMERIZABLE ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Acetaldehyde is a clear colorless liquid with a pungent choking odor. It is used to make other chemicals. It has a flash point of -36 deg. F. and a boiling point of 69 deg.f. It is flammable over a wide vapor-air concentration range. Its vapors are irritating to the mucous membranes and especially the eyes. It is easily oxidized by air to form unstable peroxides which may explode. If it becomes contaminated, it may either react with the contaminant or polymerize, both with the evolution of heat. It is lighter than water and soluble in water. Its vapors are heavier than air. It weighs 6.5 pounds per gallon. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use `alcohol" foam, carbon dioxide or dry chemical April 1981 If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation if fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash. cement powder, sawdust, or com mercial sorbents Neutralize with sodium bisulfate (nahso4) Environmental considerations--water spill Add sodium bisulfate If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors ACETALDEHYDE AMMONIA 4941103 ORM-A UNI 841 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Acetaldehyde ammonia is a white crystalline solid. It is used to make other chemicals, vulcanize rubber, and for other uses. It is soluble in water. It will burn though it may take some effort to ignite. It can cause illness by inhalation, skin absorption and-or ingestion. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a piastic sheet to prevent dissolving in ram or fire fighting water Environmental considerations--water spill Neutralize with dilute acid or removable strong acid If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates 1 MOD 000016928 ACETIC ACID (AQUEOUS SOLUTION) CORROSIVE MATERIAL, ACIDIC 4931401 UN2790 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Acetic acid (aqueous solution) is the solution of acetic acid in water having the odor of vinegar. It is corrosive to metals and tissue. It weighs 8.8 pounds per gallon. If material on fire or Involved in fire Use water in flooding quantities as fog Solid streams of water may De ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possiDle Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with caustic soda or soda ash Environmental considerations--water spill Add caustic soda Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked tor containment ACETIC ACID, GLACIAL 4931303 CORROSIVE MATERIAL, ACIDIC, COMBUSTIBLE UN2789 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-IOOO/454) Acetic acid, glacial is a clear colorless liquid with a strong odor of vinegar. It is used to make other chemicals, as a food additive, and in petroleum production. It is combustible and has a flash point of 104 deg. F. It is soluble in water with release of heat. It is corrosive to metals and tissue. It weighs 6.8 pounds per gallon. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash. or lime 2 Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with caustic soda or soda ash Environmental considerations--water spill Add caustic soda Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment ACETIC ANHYDRIDE 4931304 CORROSIVE MATERIAL, ACIDIC. COMBUSTIBLE UNI 71S ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000'454) Acetic anhydride is a clear colorless liquid with a strong Oder of vi negar. It is used to make fibers, plastics, pharmacueticals. dyes, and explosives. It is combustible and has a flash point of 129 deg. F. 11 is soluble in water and is readily decomposed by water to acetic acid with release of heat. It is corrosive to metals and tissue. It weighs 9.0 pounds per gallon. If material on fire or involved in fire Use water in flooding quantities as log Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the matenal Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body wiih copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand Dags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with caustic soda or soda ash Environmental considerations--water spill Add caustic soda Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment April 1981 Mn'D *00, $9p 9 ACETONE 4908105 FLAMMABLE LIQUID UN1090 Acetone is a clear, colorless liquid with a pleasant odor. It is used to make other chemicals, in paint and nail polish removers, as a solvent, and for other uses. It is quite volatile and has a flash point of 0 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use 'alcohol ' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on tire), downwind evacuation must be considered ACETONE CYANOHYDRIN 4921401 POISON B. COMBUSTIBLE UN1541 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10 4.54) Acetone cyanohydrin is a colorless liquid. It has a flash point of 165 deg. F. it slowly dissociates to acetone, a flammable liquid, and hydrogen cyanide, a flammable poisonous gas, under normal storage and trans portation conditions. The rate of dissociation is increased by contact with alkalis and/or heat. It is lethal by inhalation and less readily by skin absorption. It is lighter than water and soluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combus tion of this material, ft weighs 7.8 pounds per gallon. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Keep run-off water out of sewers and water sources If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 Evacuation If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Use natural Carriers or oil spill control booms to limit spill motion Use surface active agent (e g. detergent, soaps, alcohols) to com press and thicken spilled material If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ACETONE OIL 4908106 FLAMMABLE LIQUID UNI 091 Acetone oils are clear amber colored liquids. Their flash point is in the range of 50-100 deg. F. It is lighter than water ana is soluble in water. Its vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be slopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered ACETONITRILE FLAMMABLE LIQUID, POISONOUS 4907405 NA1648 Acetonitrile is a clear colorless liquid with an ethereal odor. It has a flash point of 42 deg. F. It is toxic by skin absorption. It is lighter than water and soluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol ' foam, carbon dioxide or dry chemical Continued on next page 3 MCD C00C16930 If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feel If material leaking (not on fire), downwind evacuation must he considered ACETYL BENZOYL PEROXIDE SOLUTION (NOT OVER 4919505 40% PEROXIDE) ORGANIC PEROXIDE UN2061 Acetyl benzoyl peroxide solution is a clear colorless liquid. The solution cannot be more than 40% acetyl benzoyl peroxide in a non-volatile solvent. The solution may take some effort to ignite but once ignited it burns with increasing rapidity. The dried material is quite easily ignited and burns with increasing rapidity. The dried material if contaminated with combustible material can form explosive mixtures. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol ' foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain (low as necessary Use water spray to knock-down vapors Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation II the material is on fire or involved in fire evacuate lor a radius of 2500 feet ACETYL BROMIDE 4931705 CORROSIVE MATERIAL, ACIDIC UN1716 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5O00 2270) Acetyl bromide is a colorless turning liquid with a pungent odor. It is decomposed by water to acetic and hydrobromic acids with release of heat. Its vapors are irritating to the eyes and mucous membranes. It is corrosive to metals and tissue. It weighs 13.9 pounds per gallon. If material on fire or involved in fire Use dry chemical or carbon dioxide Do not use water on material itself II large quantities of combustibles are involved, use water in Hooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface fiow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Adjust ph to neutral (ph-7) Use mechanical dredges or lilts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment ACETYL IODIDE 4931707 CORROSIVE MATERIAL, ACIDIC UNI 898 Acetyl iodide is a colorless, fuming liquid with a pungent odor. Its vapors are irritating to the eyes and mucous membranes. It is decom posed by water to acetic and hydriodic acids with release of heat. It is corrosive to metals and skin. If material on fire or Involved in fire Use dry chemical or carbon dioxide Do not use water on material itself II large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved In fire Keep sparks, (tames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime 4 April 1981 MOD 0GO01.693 i Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If matenal leaking {not on fire), downwind evacuation must be considered Environmental considerations--land spili Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash. cement powder, sawdust, or com mercial sorbents Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Apply `universal" gelling agent to immobilize spill Environmental considerations--water spili If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment ACETYL CYCLOHEXANESULPHONYL PEROXIDE, 4919103 (NOT MORE THAN 32% IN SOLUTION) ORGANIC PEROXIDE UN2083 Acetyl cyclohexanesulphonyl peroxide, (not more than 32% in solu tion) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and bums with increas ing rapidity as the fire progresses. It can form explosivemixtures with finely divided combustible materials, It supports the burning of combus tible materials. Under prolonged exposure to fire or heat containers of the material may explode. II material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved In fire Keep sparks, flames, and other sources oi ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear bools, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts ol water or soap and water April 1981 Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach tire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet ACETYL CYCLOHEXANESULPHONYL PEROXIDE, 4919104 (NOT MORE THAN 62%, WETTED WITH NOT LESS THAN 12% WATER) ORGANIC PEROXIDE UN20B2 Acetyl cyclohexanesulphonyl peroxide, (not more than 82%, welted with not less than 12% water) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and burns with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combustible materials. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or invotved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemcal Dangerously explosive If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled matenal before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on tire or involved in fire evacuate for a radius of 2500 feet ACETYL CHLORIDE 4907601 FLAMMABLE LIQUID, CORROSIVE UN1717 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Acetyl chloride is a colorless, fuming liquid with a pungent odor, it has a flash point of 40 deg. F. Its vapors are irritating to the eyes and mucous membranes. It is decomposed by water to acetic and hydrochloric acids with release of heat. It is corrosive to metals and tissue. Its vapors are heavier than air. It weighs 9.2 pounds per gallon. If material on fire or involved in fire Use dry chemical or carbon dioxide Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Continued on next page r:n not 0,0 5 ft material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing ACETYL PEROXIDE SOLUTION, (NOT OVER 25% 4919510 PEROXIDE) ORGANIC PEROXIDE UN2064 Acetyl peroxide, solution is a dear colorless liquid. The solution cannot contain more than 25% acetyl peroxide in a non-volatile solvent. The solution may take some effort to ignite but once ignited it burns with increasing rapidity. The dried material is quite easily ignited and burns with increasing rapidity. If contaminated with combustible material, the dried material can form explosive mixtures. Under prolonged exposure to heat or fire containers of the material may explode. If material on fire or Involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use `'alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Keep spilled material wet Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in lire evacuate for a radius of 2500 feet ACETYLENE 4905701 FLAMMABLE GAS UNI 001 Acetylene is a colorless gas with a faint garlic like odor. It is easily ignited and bums with a sooty flame. It may only be shipped in cylinders, and that only of one type that may be used for no other commodity. The gas is lighter than air but a flame can flash back to the source of a teak very easily. Under fire conditions, cylinders may violently rupture and rocket. 6 tf material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered ACID FISH SCRAP (FISH SCRAP (CONTAINING LESS 4917461 THAN 6% OR MORE THAN 12% MOISTURE)) FLAMMABLE SOLID NA1374 Acid fish scrap that is too dry is liable to spontaneous heating and ignition: or too wet is liable to decay, spontaneous heating and ignition. If material on fire or Involved in fire Flood with water If material not on fire and not involved in fire Keep sparks, flames, ana other sources of ignition away ACID, NEC, DRY, ORGANIC (CORROSIVE SOLID, 4931403 N.O.S.) CORROSIVE MATERIAL, ACIDIC UNI 759 Acid, nec, dry. organic is a solid material having the property of being corrosive to metals and/or tissue. If material on fire or involved In fire Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing ACIDS, CHEMICAL AND OTHER ARTICLES, MIXED 4950110 LOAD Consult the shipping papers for the exact contents of the car, con tainer, or trailer. April 1981 MOD 000016933 ACIDS, INORGANIC, NEC, DRY (CORROSIVE SOLID, 4930212 N.O.S.) CORROSIVE MATERIAL, ACIDIC UN1759 Acids, inorganic nec, dry are various solid materials that have the property of being corrosive to tissue. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding Quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible tt material not involved in fire Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves. anO goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing ACIDS, INORGANIC, NEC. LIQUID (ACIDS, LIQUID, 4930201 N.O.S.) CORROSIVE MATERIAL, ACIDIC NA1760 Acids, inorganic, nec. liquid are materials which have the property of being corrosive to metals and or tissue. They are generally heavier than water and soluble in water. They are generally noncombustible. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled matenal with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the matenal Wear full protective clothing Do not handie broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ACIDS, LIQUID, N.O.S. (ACIDS, NEC, LIQUID, 4931404 ORGANIC) CORROSIVE MATERIAL, ACIDIC NA1760 Acids, nec. liquid, organic are materials which have the property of being corrosive to metals and or tissue. If material on fire or involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use 'alcohol ' foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or lime April 1981 Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing ACROLEIN, INHIBITED 4906410 FLAMMABLE LIQUID, POISONOUS UN1092 POLYMERIZABLE ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Acrolein is a colorless to yellow colored volatile liquid with a pungent odor, it is used to make other chemicals, plastics, and as a herbicide. It has a flash point of less than 0. deg. F. It is initially irritating to the eyes and mucous membranes: prolonged exposure may lead to death. The material is subject to polymerization if its containers are subject to heat or if it becomes contaminated. It is soluble in water and it is lighter than water. The vapors are heavier than air. It weighs 7.0 pounds per gallon. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Coot alt affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 5000 feet If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Neutralize with sodium bisulfate (nahso4) Apply fluorocarbon-water foam to dimmish vapor and fire hazard Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Add sodium bisulfate If dissolved, apply activated carbon at ten times the spilled amount in region of IQppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Combustion products include corrosive or toxic vapors 7 Mnn J-9.34 ACRYLAMIDE SOLUTION (COMBUSTIBLE LIQUID. 4913187 N.O.S.) COMBUSTIBLE LIOUIO NA1993 Acrylamide solution is the colorless crystalline solid dissolved in a solvent. It is used for sewage and waste treatment, to make dyes, ad hesives, and for many other uses. The flash point of the material depends on the solvent used, but is between too and 199 deg. F. It is lighter than water and is soluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical H material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing ACRYLtC ACID CORROSIVE MATERIAL. ACIDIC, COMBUSTIBLE 4931405 UN2218 Acrylic acid is a colorless liquid, tt is combustible and it has a flash point of 130 deg. F. It is soluble in water. It is corrosive to metals and tissue. Prolonged exposure to fire or heat can cause the material to polymerize, if polymerization takes place in a container violent rupture may occur. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet ACRYLAMIDE SOLUTION (FLAMMABLE LIQUID, 4909183 N.O.S.) FLAMMABLE LIQUID UN1993 Acrylamide solution is the colorless crystalline solid dissolved in a solvent. It is used for sewage and waste treatment, to make dyes, ad hesives. and for many other uses. The flash point of the material depends on the solvent used, but is less than 100 deg. F. It is lighter than water and is soluble in water, its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing ACRYLONITRILE 4906420 FLAMMABLE LIQUID, POISONOUS UN1093 POLYMERIZABLE ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100'45.4) Acrylonitrile is a clear colorless liquid with a strong pungent odor II is used In insecticides and to make plastics, fibers and other chemicals. It has a flash point of 32 deg. F. It may polymerize if contaminated with strong bases or if the container is subject to heat as in fire conditions. Prolonged exposure to the vapors or skin contact may result in death It is lighter then water and is soluble In water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material. It weighs 6.7 pounds per gallon. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain (low as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing poofs of liquid Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 8 April 1981 tfCD 0O0016935 Evacuation If fire becomes uncontrollable or container ts exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--(and spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash. cement powder, sawdust, or com mercial sorbents Apply "universal" gelling agent to immobilize spill Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent <e.g. detergent, soaps, alcohols) to com press and thicken spilled material Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms Add calcium hypochlorite If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Combustion products include corrosive or toxic vapors ACTIVE PRIMARY AMYL ALCOHOL (ALCOHOL. 4913106 N.O.S.) COMBUSTIBLE LIQUID UNI 987 Active primary amyl alcohol is a clear colorless liquid. It has a flash point of 115 deg. F. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. It material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in Hooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soao and water ACTIVE SEC-AMYL ALCOHOL (ALCOHOL. N.O.S.) 4909106 FLAMMABLE LIQUID UN1987 Active sec-amyl alcohol is a clear colorless liquid. It has a flash point of 89 deg. F. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as tar a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical April 1981 If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keeo upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ACTUATING CARTRIDGE. EXPLOSIVE (FIRE 4903305 EXTINGUISHER OR VALVE) CLASS C EXPLOSIVE Actuating cartridge, explosive is a small metal or fiber housing con taining a small amount of explosive and is used to activate remotely controlled fire extinguishers and other apparatus. If material on fire or involved in fire Flood with water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation if fire becomes uncontrollable--evacuate for a radius of 1500 feet ADDITIVES. FUEL OIL. GASOLINE OR LUBRICATING 4910535 OIL, CONTAINING LESS THAN 50% BY WEIGHT PETROLEUM OIL (FLAMMABLE LIQUID. N.O.S.) FLAMMABLE LIQUID UNI 993 Additives, fuel oil. gasoline or lubricating oil are various colored liquids having a petroleum-like odor. Their Hash point is below 100 deg. F. They are lighter than water and insoluble in water. Their vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, (lames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do no! handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 9 MOD 000016936 ADDITIVES, FUEL OIL, GASOLINE OR LUBRICATING 491S535 OIL, CONTAINING LESS THAN 50% BY WEIGHT OF PETROLEUM (COMBUSTIBLE LIQUID. N.O.S.) COMBUSTIBLE LIQUID NA1993 Additives, fuel oil. gasoline or lubricating oil. are various colored liquids having a petroleum-like odor. They have a flash point between 100 and 200 deg. F. They are lighter than water and insoluble in water. Their vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ADHESIVE, N.O.S. 4910504 FLAMMABLE LIQUID NA1133 Adhesive, n.o.s. is the solution of various gums and resins in various solvents. The liquids are quite thick and range from a clear colorless to a black "tar". The flash point will depend on the solvent used, but it will be below 100 deg. F. The hazard of this material is flammability. If material on fire or involved in fire Do not extinguish fire unless flow can be slopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use `alcohol" foam, carbon dioxide or dry chemical If material not on tire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water AOHESIVE, N.O.S. 4915504 COMBUSTIBLE LIQUID NA1133 Adhesive, n.o.s. is the solution of various gums and resins in various solvents. The liquids are quite thick and range from a clear colorless to a black "tar". The flash point will depend on the solvent used, but it will be between 100 and 199 deg. F. The hazard of this material is combustibility. if material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of waier sources and sewers Buiid dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breaching vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ADIPIC ACID 4966110 ORM-E NA9077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000'2270) Adipic acid is a white crystalline solid. It is used to make plastics and foams and for other uses. It is insoluble in water. It will burn though it may take some effort to ignite. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, Names, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors or dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amouni in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates AFTER SHAVE LOTIONS (COMBUSTIBLE LIQUID. 4915424 N.O.S.) COMBUSTIBLE LIQUID NA1993 After shave lotions may contain significant amounts of alcohol. Their flash point is between 100 and 199 deg. F. They are lighter than water and soluble in water. Their vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical 10 Aphl 1981 MCD 000016937 If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water AFTER SHAVE LOTIONS (FLAMMABLE LIQUID, 4910424 N.O.S.) FLAMMABLE LIQUID UN1993 After shave lotions may contain significant amounts of alcohol. Their flash point is below 100 deg. F. They are lighter than water and soluble in water. Their vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water AIR CONDITIONING MACHINE, FLAMMABLE GAS (See REFRIG ERATING MACHINE, FLAMMABLE GAS 4905867) AIR CONDITIONING MACHINE, FLAMMABLE LIQUID (See REFRIG ERATING MACHINE, FLAMMABLE LIQUID 4910167) AIR CONDITIONING MACHINE, NONFLAMMABLE GAS (See RE FRIGERATING MACHINE, NONFLAMMABLE GAS 4904867) AIR, COMPRESSED 4904501 NONFLAMMABLE GAS UN1002 Air, compressed is ordinary air. compressed and shipped in cylinders under pressure. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible H material not involved In fire Keep sparks, flames, and other sources of ignition away Attempt to stop leak if without hazard Personnel protection Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution April 1981 AIRCRAFT ROCKET ENGINE (COMMERCIAL) 4917405 FLAMMABLE SOLID NA2791 Aircraft rocket engine (commercial) consists of a solid metal case containing a solid composite fuel--not classed as an explosive, and containing no explosive material or element. If material on fire or invotved In fire Flood with water Cool all affected containers with flooding quantities of water If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing fumes from burning material Evacuation If fire is prolonged and material is confined in the container--evac uate for a radius of 5000 feet If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet AIRCRAFT ROCKET ENGINE IGNITER (COMMERCIAL) 4917410 FLAMMABLE SOLID UN2792 Aircraft rocket engine igniter(commercial) are devices containing a small quantity of ignition material. They must be packaged in sealed metal containers. If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away ALCOHOL DISTILLATES, SYNTHETIC (ALCOHOL, 4915401 N.O.S.) COMBUSTIBLE LIQUID UNI 987 Alcohol distillates, synthetic are materials having a closed cup flash point between 100 and 199 deg. F. The hazard is combustibility. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as log Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ALCOHOL DISTILLATES. SYNTHETIC (ALCOHOL, 4910401 N.O.S.) FLAMMABLE LIQUID UN1987 Alcohol distillates, synthetic are materials having a closed cup flash point of less than 100 deg. F. The hazard is flammability. If material on fire or involved in fire Do not extinguish fire unless (low can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical Continued on next page 000016938 MOD 11 if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ALCOHOL IN BOND, FREE OF INTERNAL REVENUE TAX (ALCOHIC BEVERAGE) 4910102 FLAMMABLE LIQUID UN1170 Alcohol in bond is a clear colorless to amber colored liquid with a characteristic odor.lt has a flash point of less than 100 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless How can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ALCOHOL IN BOND. FREE OF INTERNAL REVENUE 4915102 TAX (ALCOHIC BEVERAGE) COMBUSTIBLE LIQUID UN1170 Alcohol in bond is a clear colorless to amber colored liquid with a characteristic odor. It has a flash ooint between 100 and 199 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid 12 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ALCOHOL OR SPIRITS. FRUIT, EXCEPT GRAPE, 4915104 NEUTRAL, IN BOND (ALCOHOLIC BEVERAGE) COMBUSTIBLE LIQUID UN1170 Alcohol or spirits, fruit, except grape, neutral is a clear colorless to variable colored liquid with a characteristic odor. It has a flash point of between 100 and 199 deg. F. It is lighter than water ana soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ALCOHOL OR SPIRITS, FRUIT,EXCEPT GRAPE. 4910104 NEUTRAL, IN BOND (ALCOHOLIC BEVERAGE) FLAMMABLE LIQUID UN1170 Alcohol or spirits, fruit, except grape, neutral is a clear colorless to variable colored liquid with a characteristic odor. It has a flash point of less than 100 deg. F. It is lighter than water and soluble m water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as tar a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water April 1981 mcd V00016939 ALCOHOL OR SPIRITS, GRAPE, NEUTRAL IN BOND 4910103 (ALCOHOLIC BEVERAGE) FLAMMABLE LIQUID UN1170 Alcohol or spirits, grape, neutral is a clear colorless to variable colored liquid with a characteristic odor. It has a flash point of less than 100 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ALCOHOL OR SPIRITS. GRAPE. NEUTRAL IN BOND (ALCOHOLIC BEVERAGE) 4915103 COMBUSTIBLE LIQUID UN1170 Alcohol or spirits, grape, neutral is a clear colorless to variable colored liquid with a characteristic odor. It has a Hash point between 100 and 199 deg. F. It is lighter than water and soluble in water, its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts ol water or soap and water ALCOHOL, CONTAMINATED, SUITABLE FOR ONLY 4910501 BLENDING OR REDISTILLING PURPOSES (ALCOHOL, N.O.S.) FLAMMABLE LIQUID UN1907 Alcohol, contaminated, suitable only for blending or redistilling pur poses is a clear colorless to dark colored liquid. It has a flash point of less than f 00 deg. F. it is lighter than water and generally is soluble in water. Its vapors are heavier than air. April 1981 If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain How as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ALCOHOL, CONTAMINATED. SUITABLE ONLY FOR 4915501 BLENDING OR REDISTILLING PURPOSES (ALCOHOL, N.O.S.) COMBUSTIBLE LIQUID NA1993 Alcohol, contaminated, suitable only for blending or redistilling pur poses is a clear colorless to dark colored liquid. It has a flash point between 100 and 199 deg. F. It is lighter than water and generally is soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ALCOHOL, N.O.S. 4913103 COMBUSTIBLE LIQUID UN1987 Alcohol, n.o.s. is the proper shipping name for the family of organic chemicals called "alcohols". Those classed as combustible liquid have a flash point between 100 and 199 deg. F. Most alcohols, n.o.s. are soluble in water. Their vapors are heavier than air. H material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Continued on next page 13 MCD 000016940 H material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without ha2ard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ALCOHOL,N.O.S. 4909105 FLAMMABLE LIQUID UN1987 Alcohol, n.o.s. is the proper shipping name for the family of organic chemicals called "alcohols". Their flash point is less than 100 deg. F. Most alcohols, n.o.s. are soluble in water. Their vapors are heavier than air. Their main hazard is flammability. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in Hooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ALCOHOLS, FATTY OR CYCLIC, ETHOXYLATED 4915108 (ALCOHOUN.O.S.) COMBUSTIBLE LIQUID NA1993 Alcohols, fatty or cyclic, ethoxylated are clear colorless liquids, their flash point is between 100 an 199 deg. F. They are lighter than water and are generally insoluble in water. Their vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If materiel not on fire and not Involved In fire Keep sparks, (lames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak H without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breaming vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ALCOHOLS, FATTY OR CYCLIC, ETHOXYLATED 4910111 (ALCOHOL,N.O.S.) FLAMMABLE LIQUID UNI 997 Alcohols, fatty or cyclic, ethoxylated are clear colorless liquids, their flash point is less than 100 deg. F. They are lighter than water and are generally insoluble in water. Their vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ALDOL (COMBUSTIBLE LIQUID, N.O.S.) 4913105 COMBUSTIBLE LIQUID NA1993 AkJol is a clear colorless to pale yellow syrupy liquid. It has a flash point of 150 deg. F. It is heavier than water and soluble in water. Its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use ''alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 14 April 1981 MCD 00lGQ41 ALDRIN 4921403 POISON B NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Aldrin is a brown to white crystalline solid. It is insoluble in water and is non-combustible. It is toxic by inhalation and skin absorption. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300 If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itseif does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing vapors or dusts Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spiii Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount m region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ALDRIN MIXTURE. DRY (WITH MORE THAN 65% 4921407 ALDRIN) POISON B NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Aldrin mixture, dry is a white to brown crystalline solid. Aldrin itself is non-combustible and insoluble in water. The other material in the mixture may or may not be combustible or water soluble. It is toxic by inhalation (dusts, etc) and by skin absorption. In case of damage to. or leaking from containers of this material contact the pesticide safety team net work. Telephone: 800-424-9300 If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use "alcohol'' foam, carbon dioxide or dry chemical If material not involved In fire Keep material out of water sources and sewers Personnel protection Avoid breathing vapors or dusts Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spiii Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water April 1981 Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trao material at bottom If dissolved, apply activated carbon at ten times the spiiled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ALDRIN MIXTURE, DRY, WITH 65% OR LESS ALDRIN 4941109 ORM-A NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/.454) Aldrin mixture, dry. is a white to brown colored solid. It is used as an insecticide. Aldrin. itself, is noncombustible and insoluble in water. The other material in the mixture may or maybe combustible or water soluble. It may cause sickness due to inhalation of dust or by skin absorption. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone- 600-424-9300. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ALDRIN MIXTURE. LIQUID (WITH MORE THAN 60% 4921406 ALDRIN) POISON B NA2762 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Aldrin mixture, liquid is a colorless to brown colored liquids. Aldrin itself is a non-combustible solid but the liquid mixture may be flammable combustible or non-combustible depending on the flammaoie property of the solvent. Its vapors are heavier than air. It is toxic by inhalation and skin absorption. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300 If material on fire or Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Continued on next page 15 MCD 000016942 If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e.g. detergent, soaps, alcohols) to com press and thicken spilled material Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ALDRIN MIXTURE. LIQUID. WITH 60% OR LESS 4941108 ALDRIN ORM-A NA2762 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1 0.454) Aldrin mixture, liquid is a colorless to brown colored liquid. It is used as an insecticide. Aldrin itself is a noncombustible solid, but the Iiauid may be combustible or noncombustible depending upon the flammable property of the liquid. Its vapors are heavier than air. It can cause sick ness due to inhalation of the vapors or by skin absorption. In case of damage to. or leaking from containers of this material contact the pes ticide network. Telephone- 800-424-9300. if material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e.g. detergent, soaps, alcohols) to com press and thicken spilled material Inject 'universal" gelling agent to solidify encircled spill and increase effectiveness of booms If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates 16 ALDRIN. CAST SOLID 4941107 ORM-A NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1 0.454) Aldrin. cast solid is a brown to white solid. It is used as an insecticide. If the large pieces are broken up or powdered, it is toxic by inhalation and skin absorption. It is insoluble in water and noncombustible. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone- 800-424-9300. If material involved in fire Extinguish fire using agent suitable for type of surrounding lire (Material itself does not burn or burns with difficulty.) If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ALKALINE CORROSIVE BATTERY FLUID 4935210 CORROSIVE MATERIAL, BASIC UN2797 Alkaline corrosive battery fluid consists of a water solution of potas sium hydroxide. It is corrosive to metals and tissue If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ft contact with the material anticipated, wear full protective clothing ALKALINE CORROSIVE BATTERY FLUID PACKED 4936565 WITH BATTERY CHARGER, RADIO CURRENT SUPPLY DEVICE OR ELECTRONIC EQUIPMENT AND ACTUATING DEVICES CORROSIVE MATERIAL, BASIC NA2797 Alkaline corrosive battery fluid packed with battery charger, radio cur rent supply device or electronic equipment and actuating devices consist of containers of alkaline corrosive battery fluid. Packed in the same outside shipping container with battery charger, radio current supply device or electronic equipment and actuating devices. The alkaline cor rosive battery fluid is soluble in water with evolution of heat. It is corrosive to metals and tissue April 1981 If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes lo contain flow as necessary Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any materiat which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing ALKALINE CORROSIVE BATTERY FLUID WITH 4935215 EMPTY STORAGE BATTERY CORROSIVE MATERIAL, BASIC UN2797 Alkaline corrosive battery fluid with empty storage battery is the stor age battery packed together with containers of the battery fluid. The fluid is a water solution of potassium hydroxide. It is corrosive to metals and tissue. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding Quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing ALKALINE CORROSIVE LIQUID, N.O.S, 4935220 CORROSIVE MATERIAL, BASIC NA1719 Alkaline corrosive liquid, n.o.s. are materials having the property of being corrosive to metals and-or tissue. Most of these materials are water soluble. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantifies as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing April 1981 ALKANESULFONIC ACID 4931408 CORROSIVE MATERIAL. ACIDIC UN2584 Alkanesulfonic acid is a mixture of methane, ethane, and propane sulfonic acids which is a colorless to amber colored liquid. It is soluble in water with release of heat. It is corrosive to metals and tissue. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with hooding quantities ot water Apply water from as far a distance as possible Use ' alcohol'' foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out ot water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of wafer or soap and water If contact with the material anticipated, wear full protective clothing ALL FREIGHT RATE SHIPMENTS, NEC (TOFC) 4950150 Consult the shipping papers for the exact contents of the car. con tainer. or trailer. ALLYL ALCOHOL 4907425 FLAMMABLE LIQUID, POISONOUS UN1098 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Ally! alcohol is a clear colorless liquid with a mustard-like odor. It has a flash point of 70 deg. F. It is toxic by inhalation and ingestion. It is lighter than water and soluble in water. Its vapors are heavier than air. It weighs 7.1 pounds per gallon. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use 'alcohol" foam, carbon dioxide or dry chemical tf material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak ii without hazard Use water spray to disperse vapors and dilute standing pools ot liquid Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Continued on next page 17 MOD 000016944 Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--`land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash, cement powder, sawdust, or com mercial sorbents Apply "universal" gelling agent to immobilize spilt Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors ALLYL BROMIDE 4907410 FLAMMABLE LIQUID, POISONOUS UN1099 Allyl bromide is a clear colorless to light yellow liquid with an irritating, unpleasant odor. It has a flash point ot 30 deg. F. It is an eye. skin, and respiratory irritant. Prolonged exposure of the skin to allyl bromide may result tn toxic amounts of the material being absorped. It is heavier than water and slightly soluble in water. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water In flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered ALLYL CHLORIDE 4907412 FLAMMABLE LIQUID, POISONOUS UN1100 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Allyl chloride is a clear colorless liquid with an unpleasant pungent odor. It has a flash point of *20 deg. F. Vapor is irritating to skin, eyes and mucous membranes. Prolonged exposure to the liquid or vapor can result in death by inhalation or skin absorption. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. It weighs 7.8 pounds per gallon. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the Oody with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash. cement powder, sawdust, or com mercial sorbents Apply "universal" gelling agent to immobilize spill Environmental considerations--water spiil Use natural barriers or oil spill control booms to limit spill motion Use surface active agent fe.g. detergent, soaps, alcohols) to com press and thicken spilled material Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Combustion products include corrosive or toxic vapors ALLYL CHLOROFORMATE (OR) ALLYL 4907607 CHLOROCARBONATE FLAMMABLE LIQUID, CORROSIVE UNI 722 Allyl chloroformate is a colorless liquid with a pungent odor. It has a flash point of 8B deg. F. It is corrosive to metals and tissue. It is de composed by water to give hydrochloric acid, a corrosive material.with evolution of heat. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use "alcohol" foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors 18 Mod ooonf'} - 69* April 1981 If material not on fire and not involved in fire Keep sparks, llamas, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without ha2ard Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective eauipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered ALLYL TRICHLOROSILANE 4934205 CORROSIVE MATERIAL, ACIDIC, FLAMMABLE UN1724 Ally! trichlorosilane is a colorless liquid with a pungent odor, it is flammable and has a Hash point of 95 deg. F. It is readily decomposed by moisture or water to hydrochloric acid with evolution of heat. It is corrosive to metals and tissue. If material on fire or involved in fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itseif Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing ALUMINUM ALKYL 4906011 FLAMMABLE LIQUID UN2845 Aluminum alkyl is a clear colorless liquid. II is used to make other chemicals. It ignites spontaneously on contact with air. It reacts violently with water and most chemicals. If material on tire or Involved in fire Do not extinguish lire unless (low can be stopped Do not use water Use graphite, soda ash or powdered sodium chloride April 1981 If material not on fire and not involved In fire Do not use water Keep sparks, flames, and other sources of ignition away Keep materia! out of water sources and sewers Keep material dry Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the matenal Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on tire), downwind evacuation must be considered ALUMINUM BROMIOE, ANHYDROUS, SOLID CORROSIVE MATERIAL, ACIDIC 4932301 UN1725 Aluminum bromide, anhydrous solid is a white to yellowish-red lumpy solid with a pungent odor. It reacts with water to form hydrobromic acid and aluminum hydroxide with release of heat. It is corrosive to metals and tissue. If material involved in fire Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors II material not involved in fire Keep material out of water sources and sewers Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing ALUMINUM CHLORIDE. DRY (CORROSIVE SOLID, 4932302 N.O.S.) CORROSIVE MATERIAL, ACIDIC UN1759 Aluminum chloride, dry is a white to grey powder with a pungent odor. It reacts with water to form hydrochloric acid and aluminum hydroxide with release of heat. It is corrosive to tissue. If material involved in fire Do not use water on material itself if large quantities of combustibles are involved, use water in flooding quantities as spray and log Use water spray to absorb vapors If material not involved In fire Keep material out of water sources and sewers Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Continued on next page 19 MCI) 0000169-46 Personnel protection Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective eauipment Wash away any material which may have contacted the body with copious amounts ot water or soap and water Wear sell-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Do not attempt to sweep up dry material Personnel protection Wear boots, protective gloves, and goggles Wash away any material which may have contacted the body with copious amounts of water or soap and water Avoid breathing Ousts ALUMINUM HYDRIDE 4916403 FLAMMABLE SOLID UN2463 WATER REACTIVE Aluminum hydride is a colorless to white solid. It reacts with water to form aluminum hydroxide and hydrogen, a flammable gas. The heat of this reaction may be sufficient to ignite the hydrogen. Prolonged ex posure of aluminum hydride to heat may result in its spontaneous de- compostion. It may react violently with oxidizers. If material on fire or involved in fire Do not use water Use graphite, soda ash or powdered sodium chloride If material not on fire and not involved in fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ALUMINUM LIQUID (OR PAINT) 4910101 FLAMMABLE LIQUID UN1263 Aluminum liquid or paint is a silvery colored liquid. II has a flash point of less than 100 deg. F. It is generally insoluble in water and its vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can De stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol1' foam, carbon diokide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ALUMINUM METALLIC POWOER (POWDER. NEC. 491670B ALUMINUM) FLAMMABLE SOLID UN1396 Aluminum, metallic powder is a light grey or silvery colored powdered metal. It is easily ignited and burns with an intense flame. If material on fire or involved in fire Do not use water Use suitable dry powder 20 ALUMINUM NITRATE 4918701 OXIDIZER UNI 438 Aluminum nitrate is a white crystalline solid, it is used m petroleum refining, in dyeing, in leather tanning, and for many other uses It absorbs moisture from the air and dissolves in it. The material is soluble in water. It is non combustible but it will accelerate the burning of combustible materials. If large quantities are involved or the combustible material is finely divided an explosion may result. Prolonged exposure of the ma terial to fire or heat may result in an explosion. Toxic oxiaes of nitrogen are produced in fires involving this material If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparKs. flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If lire becomes uncontrollable--evacuate for a radius of 2500 leet ALUMINUM PHOSPHATE SOLUTION 4932304 CORROSIVE MATERIAL. ACIDIC NA1760 Aluminum phosphate solution is the crystalline solid dissolved in phos phoric acid. Aluminum phosphate itself is insoluble in water U is cor rosive to metals and tissue. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as tog Solid streams of water may be ineffective Apply water from as far a distance as possible If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash. or hme Personnel protection Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing April 1981 ALUMINUM PHOSPHIDE 4916305 FLAMMABLE SOLID, POISONOUS UN1397 WATER REACTIVE Aluminum phosphide is a dark grey or dry yellow crystalline solid. It reacts with moisture to give phosphine, a flammable poisonous gas. Normally the phosphine will spontaneously ignite in contact with air. If there is an excess of water, this fire ot phosphine will not normally ignite surrounding combustible material. If material on fire or involved in fire Do not use water Use dry chemical or carbon dioxide If material not on fire and not involved in fire Do not use water Keep sparks, flames, and other sources ot ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing ALUMINUM SULFATE 4963303 ORM-E NA9078 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000 2270) Aluminum sulfate is a white crystalline solid. It is used in paper making, in fire-fighting foams, in sewage treatment and water purification, and for many other uses. It is soluble in water. It is non-combustible. II material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spilt Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ALUMINUM SULFATE SOLUTION 4944165 ORM-B NA1760 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000 2270) Aluminum sulfate solution is the white crystaline solid dissolved in water. It is used in paper making, in fire fighting foams, as a fire proofing agent, in sewage treatment and water purification, and for many other uses. It is non-combustible. It is corrosive to aluminum. It weighs 10.9 pounds per gallon. If material involved in fire Extinguish lire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) April 1981 If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon. holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash. cement powder, sawdust, or com mercial sorbents Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ALUMINUM SULPHATE FLUOSULPHATE MIXTURE, 4963304 FLUORINE CONTENT NOT TO EXCEED 25% (ALUMINUM SULFATE) ORM-E NA9076 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Aluminum sulphate fluosulphate mixture is a white solid. It is soluble in water. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not Involved in fire Keep material out ot water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts ot water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or tire lighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ALUMINUM SULPHATE, NOT MORE THAN 5% 4963305 ACTIVATED CARBON (ALUMINUM SULFATE) ORM-E NA9078 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Aluminum sulphate, not more than 5% activated carbon is a light grey solid. It is used to make ethane. Only the aluminum sulphate is soluble in water. It is non-combustible. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Materia! itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Continued on next page 21 XC.Z) &94Q Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ALUMINUM, METALLIC, POWDER (POWDERS, 4916707 ALUMINUM) FLAMMABLE SOLID UNI 396 Aluminum, metallic, powder is a light grey or silvery colored powdered metal. It is easily ignited and burns with an intense flame. If material on fire or involved in fire Do not use water Use suitable dry powder If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Do not attempt to sweep up dry material Personnel protection Wear boots, protective gloves, and goggles Wash away any material which may have contacted the body with copious amounts of water or soap and water Avoid breathing dusts 2-{2-AMINOETHOXY) ETHANOL 4935605 CORROSIVE MATERIAL, BASIC NA1760 2-(2-aminoethoxy) ethanol is colorless liquid with a faint fish like odor. It may burn though it may require some effort to ignite. It is soluble in water. It is corrosive to metals and tissue. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires invok ing this material If contact with the material anticipated, wear full protective clothing N-AMINOETHYL PIPERAZINE 4935610 CORROSIVE MATERIAL. BASIC, COMBUSTIBLE UN2B15 N-aminoethyl piperazine is a colorless liquid with a faint fish-like odor. It is combustible and has a flash point of 199 deg. F. It is soluble in water. It is corrosive to metals and tissue. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing AMiNOETHYLETHANOLAMINE (CORROSIVE LIQUID. 4935674 N.O.S.) CORROSIVE MATERIAL UN1760 Aminoethylethanolamine is a clear colorless liquid having an am monia-like odor. It is used to make other chemicals, it is corrosive to metals and tissue, it will burn though it may require some effort to ignite, it is lighter than water and soluble in water, its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water In flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing N-AMINOPROPYL MORPHOLINE 4935620 CORROSIVE MATERIAL, BASIC NA1760 N-aminopropyimorpholme is a colorless liquid with a faint fish-like odor. It may burn though it may require some effort to ignite. It is soluble in water, it is corrosive to metals and tissue. Toxic oxides of nitrogen are produced during combustion of this material. 22 "CO ooon *6.949 April 1961 if material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use alcohol'' foam, carbon dioxide or dry chemical if material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep matenai out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing BIS-(AMINOPROPYL) PIPERAZINE 4935625 CORROSIVE MATERIAL. BASIC NA1760 Bis-(aminopropyl) piperazine is a colorless liquid with a faint fish like odor. It solidifies at 59 deg. F. It may burn though it may require some effort to ignite. It is soluble in water. It is corrosive to metals and tissue. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing AMINOPROPYLDIETHANOL AMINE 493561S CORROSIVE MATERIAL, BASIC NA1760 Aminopropyldiethanol amine is a colorless liquid with a faint fishiike odor. It may bum though it may require some effort to ignite. It is soluble in water. It is corrosive to metals and tissue. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical April 1981 If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the matenai Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenai which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing AMMONIA SOLUTION (CONTAINING MORE THAN 44% 4904220 AMMONIA) NONFLAMMABLE GAS, CORROSIVE UN2073 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Ammonia solution is ammonia gas dissolved in water. It has the char acteristic ammonia odor. The solution is corrosive to metals and tissue. Although ammonia is lighter than air. the vapors from a leak will initially hug the ground. It weighs 7.3 pounds per gallon. If material Involved in fire Extinguish fire using agent suitable for type of surrounding tire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use water spray to absorb vapors If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and gas tight goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the Dody with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Evacuation If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with vinegar or other dilute acid Environmental considerations--water spill Neutralize with dilute acid or removable strong acid If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment 23 mod 00 Oq 2695o AMMONIACAL LIQUOR (COMPRESSED GAS. N.O.S.) 4904221 NONFLAMMABLE GAS. CORROSIVE UN19S6 Ammoniacal liquor is trie solution in water of various ammonium salts and ammonia gas. It has so much ammonia in it that there is pressure in excess of 40 psi at 70 deg. F. The solution is corrosive. Although ammonia is lighter than air. the vapors from a leak initially hug the ground. If material involved in fire Extinguish fire using agent suitable tor type ot surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use water spray to absorb vapors If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak it without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and gas tight goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the Dody with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Evacuation If material leaking (not on fire), downwind evacuation must be considered AMMONIUM ACETATE 4966708 ORM-E NA9079 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Ammonium acetate is a white crystalline solid. It is used in chemical analysis, in pharmaceuticals, in preserving foods, and for other uses. It is soluble in water. It is non-combustible. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the Dody with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in ram or fire fighting water Environmental considerations--water spill Neutralize with dilute acid or removable strong acid If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates AMMONIUM ARSENATE. SOLID 4923201 POISON B UN1546 Ammonium arsenate, solid is a white crystalline solid, it is soluble in water and toxic by ingestion. 24 If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material AMMONIUM BENZOATE 4966304 ORM-E NA9080 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-SOOO 2270) Ammonium benzoate is a white crystalline solid. It is used in medicine and as a food preservative. It is soluble in water. It is non-comOustible. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the Dody with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with dilute acid or removable strong acid If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates AMMONIUM BICARBONATE 4966308 ORM-E NA9081 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Ammonium bicarbonate is a white crystalline solid having the odor of ammonia. It is used to make other ammonium compounds, m food processing, and for other uses. It is soluble in water. It is non combustible. If material involved in fire Extinguish fire using agent suitable for type of surrounding tire (Material itself does not bum or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vaoors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 ooisysi Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with dilute acid or removable strong acid AMMONIUM BISULFITE SOLUTION 4932348 CORROSIVE MATERIAL NA2693 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Ammonium bisulfite solution is the white crystalline solid dissolved in water having an odor of burning sulfur. It is corrosive to metals and tissue. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material if contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Apply fluorocarbon-water foam to diminish vapor and fire hazard Environmental considerations--water spill Add calcium hypochlorite Neutralize with dilute acid or removable strong acid If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors AMMONIUM BISULFITE. SOLID 4944142 ORM-B NA2693 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Ammonium bisulfite, solid is a colorless crystalline solid. It is used m the manufacture of other chemicals. It is soluble in water. It is non combustible. It is corrosive to aluminum. If material involved in fire Extinguish fire using agent suitable tor type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in ram or fire fighting water Environmental considerations--water spill Add calcium hypochlorite Neutralize with dilute acid or removable strong acid Adjust ph to neutral (ph-7) AMMONIUM CARBAMATE 4941145 ORM-A NA9083 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Ammonium carbamate is a white crystaline solid. It is used as a fertilizer, it is soluble in water. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) If material not involved in fire Keep materiaf out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheer to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with dilute acid or removable strong acid Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment AMMONIUM CARBONATE 4941149 ORM-A NA90B4 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Ammonium carbonate is a colorless crystaline solid or a white powder with a strong odor of ammonia. It is used to make other ammonium compounds, in phapharmaceuticals. in food processing, and for many other uses. It is non-combustible. It is soluble in water. If material involved in fire Extinguish fire using agent suitable tor type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with dilute add or removable strong acid Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment 25 MCD 0000 6 S 2 AMMONIUM CHLORIDE 4966316 ORM-E NA9085 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Ammonium chloride is a white crystalline solid. It is used to make other ammonium compounds, as a soldering flux, as a fertilizer, and for many other uses. It is soluble in water. It is non-combustible. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with dilute acid or removable strong acid AMMONIUM CHROMATE 4963302 ORM-E NA9086 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Ammonium chromate is a yeilow crystalline solid. It is used in dyeing, photography, chemical analysis, and as a corrosion inhibitor, it is soluble in water. It is non-combustible. If material involved in fire Extinguish tire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Add sodium bisulfite Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Adjust ph to neutrai (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates if material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill vO Dig a pit. pond, lagoon, holding area to contain liquid or solid matenal SSCover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with dilute acid or removable strong acid If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates AMMONIUM DICHROMATE (AMMONIUM 4916701 BICHROMATE) FLAMMABLE SOLID. OXIDIZING UN1439 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Ammonium dichromate is a bright orange red crystalline solid. It is readily ignited and bums producing a voluminous green residue. If heated in a closed container, the container may rupture due to the decomposition of the material. It may also act as a strong oxidizing agent if mixed with or contaminated with combustible material. It is soluble in water. H material on fire or involved in fire Flood with water If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Add sodium bisulfite Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates AMMONIUM CITRATE, DIBASIC 4966320 ORM-E NA9087 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (HQ-5000/2270) Ammonium citrate is a white granular solid. It is used fn pharma ceuticals and in chemical analysis. It is soluble in water. It is non combustible. if material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) 26 AMMONIUM FLUOBORATE 4944125 ORM-8 NA9088 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Ammonium fluoborate is a white solid. It is used in metal plating and finishing. It is corrosive lo aluminum. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) If materia) not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary April 1981 MCI) 000016953 Personnel protection Keep upwind Wear boots, protective gioves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts oi water or soaD and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water AMMONIUM FLUORIDE 4944105 ORM-B UN2505 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Ammoumium fluoride is a white crystalline solid. It is used in chemical analysis, in brewing, and as a preservative for wood. It is soluble in water. It is non-combustible. It is corrosive to aluminum. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out ol water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any matenai which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Oigapit.pond.lagoon.holdingareatocontainfiqurdorsolidmaterial Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates AMMONIUM HYDROGEN FLUORIDE SOLUTION 4932307 CORROSIVE MATERIAL, ACIDIC UN2817 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Ammonium hydrogen fluoride solution is the white crystalline solid dissolved in water, ft is corrosive to metals and tissue. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible H material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled matenai with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodi)y contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenai which may have contacted the body with copious amounts of water or soap and water If contact with the matenai anticipated, wear lull protective clothing April 1961 Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment AMMONIUM HYDROGEN FLUORIDE, SOLID 4932303 CORROSIVE MATERIAL UN1727 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Ammonium hydrogen fluoride, solid is a white crystalline solid. It is used to sterilize food processing equipment, in chemical analysis, for electroplating and for many other uses. It is soluble in water. It is cor rosive to tissue. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Avoid breathing fumes from burning material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates AMMONIUM HYOROXIDE (CONTAINING LESS THAN 4940347 12% AMMONIA) ORM-A NA2672 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Ammonium hydroxide is a colorless to milky colored liquid with an odor of ammonia. It is used in cleaning compounds, to make other chemicals, and for many other uses, it is non-combustible and soluble in water with release of heat. It is corrosive to aluminum. It weighs 7.3 pounds per gallon. If material involved in fire Extinguish fire using agent suitable lor type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Apply water from as far a distance as possible Use water spray to absorb vapors Continued on next page MCD 0000.16954 27 If material not involved in fire Keep material out of water sources ana sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the Dooy with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with vinegar or other dilute acid Environmental considerations--water spill Neutralize with dilute acid or removable strong acid Environmental considerations--air spill Apply water spray or mist to knock down vapors AMMONIUM NITRATE (NO ORGANIC COATING) 4918311 OXIDIZER. THERMALLY UNSTABLE UN1942 Ammonium nitrate is a white crystalline solid. It is used to make fer tilizers and explosives, and as a nutrient in producing antibiotics and yeast. It is soluble in water. The materia) itself does not readily burn but will do so if contaminated by combustible material. It will accelerate the burning of combustible material. Toxic oxides of nitrogen are produced during combustion. If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources ot ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective eauipment Wash away any materiai which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Approach fire with caution Evacuation If fire becomes uncontrollable--evacuate for a radius of 5000 feet AMMONIUM HYDROXIDE (CONTAINING NOT LESS 4935280 THAN 12% BUT NOT MORE THAN 44% AMMONIA) CORROSIVE MATERIAL NA2672 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000,454) Ammonium hydroxide is a colorless to milky colored liquid with an odor of ammonia. it is used in cleaning compounds, to make other chemicals, and for many other uses. It is non-combustible and soluble m water with release of heat. It is corrosive to metals and tissue. It weighs 7.3 pounds per gallon. If material involved in fire Extinguish fire using agent suitable for type of surrounding lire (Materia! itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Apply water from as far a distance as possible Use water spray to absorb vapors If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand Dags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with vinegar or other dilute acid Environmental considerations--water spill Neutralize with dilute acid or removable strong acid Environmental considerations--air spill Apply water spray or mist to knock down vapors 28 AMMONIUM NITRATE (ORGANIC COATING) 4918312 OXIDIZER NA1942 THERMALLY UNSTABLE Ammonium nitrate (organic coating) is a white crystalline solid. The individual pieces of the material are coated with some substance in order to make the material more free flowing. It is soluble m water. The material itself will not burn but will readily do so if contaminated by combustible material, ft will accelerate the burning of combustible material. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities ot water Apply water from as far a distance as possible If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective eouipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this matenal Approach fire with caution Evacuation If fire becomes uncontrollable--evacuate for a radius of 5000 feet AMMONIUM NITRATE FERTILIZER (CONTAINING NO 4918310 MORE THAN 0.2% CARBON) OXIDIZER UN2067 THERMALLY UNSTABLE Ammonium nitrate fertilizer is a greyish white solid in the form of prills. It is soluble in water. The matenal itself does not readily burn but will readily do so it contaminated by combustible material. H will accelerate the burning of combustible matenal. Toxic oxides of nitrogen are pro duced during combustion of this material. It material on fire or Involved In fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible April 1981 MCD 000016955 If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Approach fire with caution Evacuation If fire becomes uncontrollable--evacuate for a radius of 5000 feet AMMONIUM NITRATE MIXED FERTILIZER OXIDIZER 4918705 UN2069 Ammonium nitrate mixed fertilizer is a variable colored granular solid. The material is soluble in water. It is noncombustible but it will accelerate the burning of combustible materials. If large quantities of the materia! are involved in the fire or the combustible material is finely divided an explosion may result. Prolonged exposure of the material to fire or heat may result in an explosion. Toxic oxides of nitrogen are produced in fires involving this material. If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Approach fire with caution Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet AMMONIUM NITRATE-CARBONATE MIXTURE 4918734 OXIDIZER UN2068 Ammonium nitrate-carbonate is a greyish white granular solid. It is the mixture of ammonium nitrafe and calcium carbonate, i.e. limestone. The ammonium nitrate is soluble in water: the calcium carbonate is not. The material itself is noncombustible, but it will accelerate the burning of combustible materials. Toxic oxides of nitrogen are produced in fires involving this material. If material on fire or involved in fire Flood with water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material April 1981 AMMONIUM NITRATE-FUEL OIL MIXTURE 4902910 (CONTAINING ONLY PRILLED AMMONIUM NITRATE AND FUEL OIL) BLASTING AGENT Ammonium nitrate-fuel oil mixture is a brownish-black granular solid. It is used for blasting rock and in some types of mining. It will accelerate the burning of combustible materials. The ammonium nitrate is soluble in water. If large quantities of this material are involved in a fire, it may explode. If material on fire or involved in fire Low order explosive potential Do not fight fires in a cargo of blasting agents Evacuate area and let bum If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep spilled material wet Wet spilled material before picking it up Do not attempt to sweep up dry material Personnel protection Avoid breathing dusts, and fumes from burning material Wear protective gloves and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet AMMONIUM NITRATE-PHOSPHATE 4918704 OXIDIZER UN2070 Ammonium nitrate-phosphate is a white granular solid, it is used as a fertilizer, it is soluble in water. It is noncombustibie but it will accelerate the burning of combustible materials. If large quantities of the material are involved in the fire or the combustible material is finely divided an explosion may result. Prolonged exposure of the material to fire or heat may result in an explosion. Toxic oxides of nitrogen are produced in fires involving this matenal. If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet 000C169SS MOD 29 AMMONIUM NITRATE, MAGNESIA AND PULP 4916703 MIXTURE (OXIDIZING MATERIAL, N.O.S OXIDIZER UN1479 Ammonium nitrate, magnesia and putp mixture is a white to light yellow granular solid. The material is soiuDle in water. It is non-comdustibie but it will accelerate the burning of combustible materials. If large Quantities of the material are involved in the tire or the combustible material is finely divided an explosion may result. Prolonged exposure of the ma terial to fire or heat may result in an explosion. Toxic oxides of nitrogen are produced in fires involving this material. It material on fire or involved in fire Flood with water Cool all affected containers with flooding Quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective eauipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet AMMONIUM NITRATE. SODIUM NITRATE MIXTURE 4918702 (OXIDIZING MATERIAL. N.O.S.) OXIOIZER UN1479 Ammonium nitrate, sodium nitrate mixture is a white to light greyish granular solid. The material is soluble in water. It is non-combustible but it will accelerate the burning of combustible materials. If large quantities of the matena! are involved in the fire or the combustible material is finely divided an explosion may result. Prolonged exposure of the ma terial to fire or heat may result in an explosion. Toxic oxides of nitrogen are produced in fires involving this material. If material on fire or Involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Approach fire with caution Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet AMMONIUM NITRATE. SOLUTION (CONTAINING NOT 4918774 LESS THAN 15% WATER) OXIOIZER UN2426 Ammonium nitrate solution is the white crystals dissolved in water. It is used to make fertilizers and explosives. Though the material itself is noncombustible it will accelerate the burning of combustible materials. Toxic oxides of nitrogen are produced in fires involving this material. If material on fire or involved In fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers 30 Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the oody with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet AMMONIUM OXALATE 4940350 ORM-A NA2449 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Ammonium oxalate is a colorless crystalline solid. It is used as a reagent in chemical analysis, for rust and scale removal, and for many other uses. It is soluble in water. It is non-combustible. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates AMMONIUM PERCHLORATE CLASS A EXPLOSIVE 4901550 Ammonium perchlorate is a white crystalline solid. It is used in making certain solid rocket propellants. It is smaller than 15 micron si2e or larger sized material that has been dried of its water of crystallization. The material itself does not readily burn, but will do so if contaminated by combustible material. Fires involving ammonium perchlorate an a com bustible material may result in an explosion. If material on fire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep spilled material wet Wet spilled material before picking it up Do not attempt to sweep up dry material Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning matenat Wear protective gloves and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet April 1981 AMMONIUM PERCHLORATE 4916320 OXIDIZER, THERMALLY UNSTABLE UN1442 Ammonium perchlorate is a white crystalline solid that is soluble in water. It is used to make rocket propellants, explosives and for other uses. Ammonium perchlorate that is smaller than 15 micron size or larger sized material that has been dried of its water of crystallization is classed as a class a explosive. The material itself does not readily burn, but will do so if contaminated by combustible material. Fires in volving ammonium perchlorate and combustible material may result in an explosion. Prolonged exposure of ammonium perchlorate and/or its containers to heat or fire may result in an explosion. If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 5000 feet AMMONIUM PERMANGANATE 4918322 OXIDIZER, THERMALLY UNSTABLE NA9190 Ammonium permanganate is a violet brown or dark purple crystalline solid. It is soluble in water. The material itself does not burn. It accel erates the burning of combustible materials. Contamination by some combustible materials may result in spontaneous ignition. Prolonged exposure of ammonium permanganate and or its containers to fire or heat may result in an explosion. If material on fire or Involved In fire Flood with water Cool alt affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet AMMONIUM PICRATE, WET (WITH 10% OR MORE 4917125 WATER) FLAMMABLE SOLID UN1310 Ammonium picrate. wet is a slurry or sludge of yellow crystals. Am monium picrate dry is a high explosive, dry it is easily ignited and burns vigorously. If large quantities are involved an explosion may result. The wet material will burn, though it may require some effort to ignite. Toxic oxides of nitrogen are produced during combustion. It material on fire or involved In fire Dangerously explosive Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible April 1981 If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Do not attempt to sweep up dry material Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 5000 feet AMMONIUM SILICOFLUORIDE 4944135 ORM-A UN2854 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Ammonium silicofluoride is a white crystaline solid. It is used as a disenfectant, in etching glass, metal casting, and electroplating. It is soluble in water. It is non-combustible. It is corrosive to aluminum. If material involved In fire Extinguish lire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water AMMONIUM SULFAMATE 4966732 ORM-E NA90B9 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Ammonium sulfamate is a white crystalline solid. It is used to flame proof fabrics and papers, in weed or brush killing products, and for other uses. It is soluble in water. It is non-combustible. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Add calcium hypochlorite Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates 31 oooo-^'9^ \AC^ AMMONIUM SULFIDE SOLUTION FLAMMABLE LIQUID UN2683 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Ammonium sulfide solution is the yellow crystalline material dissolved in a liquid, usually water. It has the odor of rotten eggs. Ammonium sulfide is slowly decomposed by moisture giving off hydrogen sulfide, a flammable gas. It weighs 9.0 pounds per gallon. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Add calcium hypochlorite Adjust ph to neutral (ph-7) Environmental considerations--air spill Apply water spray or mist to knock down vaoors Evolves flammadle hydrogen sulfide gas on contact with acids AMMONIUM SULFITE 4966332 ORM-E NA9090 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Ammonium sulfite is a colorless crystaline solid. It is used in the manufacture of other chemicals, in medicine, and photography. It is soluble in water. It is non-combustible. If material involved in fire Extinguish fire using agent suitable for type ol surrounding fire (Material itself does not bum or burns with difficulty.I If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or ousts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving m ram or fire fighting water Environmental considerations--water spill Add calcium hypochlorite Adjust ph to neutral (ph-7) Environmental considerations--air spill Evolves flammable hydrogen sulfide gas on contact with acids 32 AMMONIUM TARTRATE 4966336 ORM-E NA9091 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000 2270) Ammonium tartrate is a white crystalline solid. It is used to manufacture fabrics and in medicine. It is soluble in water. It is non-combustible. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material Itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with dilute acid or removable strong acid If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates AMMONIUM THIOCYANATE CRYSTALS (AMMONIUM 4966738 THIOCYANATE) ORM-E NA9092 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000 2270) Ammonium thiocyanate is a colorless crystalline solid. It is used m chemical analysis, in photography, as a fertilizer, and for many other uses. It is soluble in water. It is non-combustibte. If material involved in fire Extinguish fire using agent suitable for type ol surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with dilute acid or removable strong acid Add calcium hypochlorite Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates AMMONIUM THIOCYANATE LIQUOR (AMMONIUM 4966744 THIOCYANATE) ORM-E NA9092 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000 2270) Ammonium thiocyanate liquor is the colorless crystalline solid dis solved in water, it is used to make other chemicals, fertilizer, and for many other uses. It is non-combustible. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) April 1981 MCD 0000.16959 If material not involved in fire Keep materia) out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts o< water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand Dags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fiy ash or cement powder Environmental considerations--water spill Neutralize with dilute acid or removable strong acid Add calcium hypochlorite Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates AMMONIUM THIOSULFATE 4966750 ORM-E NA9093 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Ammonium thiosulfate is a white crystalline solid. It is used in pho tography. in chemical analysis, and for many other uses. It is soluble in water. It is non-combustible. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with dilute acid or removable strong acid If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates AMMONIUM THIOSULFATE SOLUTION (AMMONIUM 4966756 THIOSULFATE) ORM-E NA9093 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Ammonium thiosulfate solution is the white crystalline solid dissolved in water. It is used in photography and for many other uses. It is non combustible. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1961 Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Neutralize with dilute acid or removable strong acid If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates AMMUNITION FOR CANNON WITH EMPTY 4902110 PROJECTILE CLASS B EXPLOSIVE Ammunition tor cannon with empty projectile is fixed ammunition which is an assembled unit consisting of the cartridge case containing the propelling charge and primer with empty projectiles. Under prolonged exposure to fire or heat the material can explode. If material on fire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet AMMUNITION FOR CANNON WITH EXPLOSIVE 4901105 PROJECTILE CLASS A EXPLOSIVE Ammunition for cannon with explosive projectile is fixed ammunition which is an assembled unit consisting of a cartridge case containing the propelling charge and primer and explosive projectile containing a high explosive. It may be shipped either fuzed or unfuzed. The fuzed am munition may be sensitive to shock or mechanical impact. Under pro longed exposure to heat or tire it can explode. If material on fire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet AMMUNITION FOR CANNON WITH GAS PROJECTILE 4901110 CLASS A EXPLOSIVE Ammunition for cannon with gas projectile is fixed ammunition which is an assembled unit consisting of a cartridge case containing the pro pelling charge and primer, and a projectile containing a gas and a burster. It may be shipped either fuzed or unfuzed. The fuzed ammunition may be sensitive to shock or mechanical impact. Under prolonged exposure to fire or heat it can explode. Continued on next page 33 MOD 000016960 if material on fire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet AMMUNITION FOR CANNON WITH tLLUMINATINQ 4901115 PROJECTILE CLASS A EXPLOSIVE Ammunition for cannon with illuminating projectile is fixed ammunition which is an assembled unit consisting of a cartridge case containing the propelling charge and primer, and a projectile containing a pyrotechnic composition and burster. It may be either shipped fuzed or unfuzed. The fuzed ammunition may be sensitive to shock or mechanical impact. Under prolcnged exposure to fire or heat it can explode. If material on fire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and lumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet AMMUNITION FOR CANNON WITH INERT LOADED 4902120 PROJECTILE CLASS B EXPLOSIVE Ammunition for cannon with inert loaded projectile is fixed ammunition which is an assembled unit consisting of the cartridge case containing the propelling charge and primer with inert-loaded projectile. Under pro longed exposure to tire or heat the materia! can explode. If material on fire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet AMMUNITION FOR CANNON WITH SMOKE 4901125 PROJECTILE CLASS A EXPLOSIVE Ammunition for cannon with smoke projectile is fixed ammunition con sisting of a cartridge case containing a propelling charge and primer, and a projectile containing a smoke producing composition and a burster. It may either be shipped fuzed or unfuzed. The fuzed ammunition may be sensitive to shock or mechanical impact. Under prolonged exposure to heat or fire it can explode. If material on fire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting tires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet AMMUNITION FOR CANNON WITH INCENDIARY 4901120 PROJECTILE CLASS A EXPLOSIVE Ammunition for cannon with incendiary projectile is fixed ammunition consisting of acartridge case containing a propelling charge and a primer and a projectile containing a pyrotechnic composition and a burster. It may be shipped fuzed or unfuzed. The fuzed ammunition may be sen sitive to shock or mechanical impact. Under prolonged exposure to heat or fire it can explode. If material on fire or involved in fire Dangerously explosive Do not light fires in a cargo of explosives Evacuate area and let burn If material not on fire and not involved in fire Keep sparks. Dames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet 34 AMMUNITION FOR CANNON WITH SOLID 4902130 PROJECTILE CLASS B EXPLOSIVE Ammunition for cannon with solid projectile is fixed ammunition which is an assembled unit consisting of the cartridge case containing the propelling charge and primer with solid projectile. Under prolonged ex posure to fire or heat the material can explode. If material on fire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet April 1981 AMMUNITION FOR CANNON WITH TEAR GAS 4902127 PROJECTILE CLASS B EXPLOSIVE Ammunition for cannon with tear gas projectile is fixed ammunition which is an assembled unit consisting of a cartridge case containing the propelling charge and primer, and a projectile containing the tear gas and a burster. It may be shipped either fuzed or unfuzed. The fuzed ammunition may be sensitive to shock or mechanical impact. Under prolonged exposure to tire or heat it can explode ana release tear gas. If material on fire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and tumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved m fire evacuate for a radius of 2500 feet AMMUNITION FOR SMALL ARMS WITH EXPLOSIVE 4901130 PROJECTILE CLASS A EXPLOSIVE Ammunition for small arms with explosive projectile is fixed ammu nition of less than 20 mm which consists of a cartridge case containing a propelling charge and primer, and a projectile containing a high ex plosive. It may be shipped either fuzed or unfuzed. The fuzed ammunition may be sensitive to shock or mechanical impact. Under prolonged ex posure to lire it can explode. If material on fire or involved In fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet AMMUNITION FOR CANNON WITH TEAR GAS 4901127 PROJECTILE CLASS A EXPLOSIVE Ammunition for cannon with tear gas projectile is fixed ammunition which is an assembled unit consisting of a cartridge case containing tear gas and a burster. It may be shipped either fuzed or unfuzed. The fuzed ammunition may be sensitive to shock or mechanical impact. Under prolonged exposure to fire or heat it can explode and release tear gas. If material on fire or Involved in fire Dangerously explosive Do not tight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on tire or involved in fire evacuate for a radius of 5000 feet AMMUNITION FOR SMALL-ARMS WITH INCENDIARY 4901135 PROJECTILE CLASS A EXPLOSIVE Ammunition for small-arms with incendiary projectile is fixed ammu nition of less than 20mm consisting of a cartridge case containing a propelling charge and primer, and a projectile containing a pyrotechnic charge, tt may be either shipped fuzed or untuzed. The fuzed ammunition may be sensitive to shock or mechanical impact. Under prolonged ex posure to heat or fire it can explode. If material on fire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet AMMUNITION FOR CANNON WITHOUT PROJECTILE 4902140 CLASS B EXPLOSIVE Ammunition for cannon without projectile is fixed ammunition which is a unit consisting ot the cartridge case containing the propelling charge and primer without projectile. Under prolonged exposure to tire or heat the material can explode. If material on fire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet April 1961 AMMUNITION, CHEMICAL, EXPLOSIVE, WITH 4901167 IRRITANT CLASS A EXPLOSIVE Ammunition, chemical, explosive, with irritant may be any type of projectile, bomb, grenade, etc. It contains a material classified as an irritant and a burster. Under prolonged exposure to heat or fire it can explode. The irritant causes discomforting effects such as tearing of the eyes or a choking sensation of the respiratory system from inhalation or contact with small quantities. The irritant may or may not be combustible. If material on fire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Continued on next page MOD 000016962 35 Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet AMMUNITION. CHEMICAL. EXPLOSIVE. WITH POISON 4901165 A MATERIAL CLASS A EXPLOSIVE Ammunition, chemical, explosive, with poison a material may be any type of projectile bomb, grenade, etc. It contains a material classified as poison a and a burster. Under prolonged exposure to heat or tire it can explode. The poison a material may cause death by inhalation or skin absorption of very small Quantities. The poison a material may or may not be combustible. If material on fire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and iet burn If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet AMMUNITION. CHEMICAL, EXPLOSIVE, WITH POISON 4901166 B MATERIAL CLASS A EXPLOSIVE Ammunition, chemical, explosive, with poison b material may be any type of projectile, bomb, grenade, etc. It contains a material classified as poison b and a burster. Under prolonged exposure to heat or fire it can explode. The poison b matenal may cause death by inhalation, skin absorption, or ingestion of small quantities. The poison b material may not be combustible. If material on fire or involved In fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius ot 5000 feet AMYL ACETATE 4909111 FLAMMABLE LIQUID UN1104 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000'454) Amyl acetate is a clear colorless liquid having a banana like odor. The flash point may vary from 65 deg. F. to 95 deg. F. It is lighter than water and slightly soluble in water. The vapors are heavier than air. it weighs 7 2 pounds per gallon. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to aisperse vapors and dilute standing pools of liquid Personnel protection AOoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash. cement powder, sawdust, or com mercial sorbents Apply fluorocarbon-water foam to dimmish vapor and lire hazard Environmental considerations--water spill Use natural barriers or oil Spill control booms to limit spill molion Use surface active agent (e g. detergent, soaps, alcoholsi to com press and thicken spilled matenai Inject universal gelling agent to solidity encircled spill and increase effectiveness of booms If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors AMYL ACID PHOSPHATE 4933360 CORROSIVE MATERIAL UN2819 Amyl acid phosphate is a colorless liquid. It is used as a curing agent in paints and plastics and is used in the manufacture of synthetic fibers. It will burn though it may take some effort to ignite. It is heavier than water and is insoluble in water. It is corrosive to metals and tissue. Its vapors are heavier than air. If material on fire or Involved In fire Use dry chemical, carbon dioxide, or dry sand Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear lull protective clothing 36 April 1961 )000t696' MC'T> TERT-AMYL ALCOHOL (ALCOHOL, N.O.S.) 4909112 FLAMMABLE LIQUID UNI 987 Tert-amyl alcohol is a clear colorless liquid with a camphor like odor. It has a flash point of 67 deg. F. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. It material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water N-SEC-AMYL ALCOHOL (ALCOHOL, N.O.S.) 4909107 FLAMMABLE LIQUID UN1987 N-sec-amyl alcohol is a clear colorless liquid. U has a flash point of 94 deg. F. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water AMYL CHLORIDE 4909115 FLAMMABLE LIQUID UN1107 Amyl chloride is a clear, colorless liquid. The flash point may vary from 35 deg. F. to 54 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers April 1981 Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material AMYL FORMATE 4909310 FLAMMABLE LIQUID UN1109 Amyl formate is a clear colorless liquid with a plum like odor. It has a flash point of 79 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water AMYL MERCAPTAN 4909119 FLAMMABLE LIQUID UN1111 Amyl mercaptan is a clear, colorless to light yellow liquid with an offensive odor, It has a flash point of 65 deg. F. It is lighter than water and insoluble in water. Its vapors are lighter than water. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out oi water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material 37 MCD 000016964 AMYL NITRATE (COMBUSTIBLE LIQUIO, N.O.S.) COMBUSTIBLE LIQUID, OXIDY2ING 4913107 NA1993 Amyl nitrate is a clear colorless liquid with an ether-like odor, it is used as an additive lor diesel fuels. It has a flash point oil 18 deg. F. It will accelerate the burning of combustible materials. It weighs about the same as water and is insoluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material TERT-AMYL PEROXY-2-ETHYLHEXANOATE, (TECHNICALLY PURE) ORGANIC PEROXIDE 4919108 UN2898 Tert-amy! peroxy-2-ethylhexanoate. {technically pure) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burn ing of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use `'alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when lighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet AMYL NITRITE 4909121 FLAMMABLE LIQUID UN1113 Amyl nitrite is a clear colorless to yellowish liquid with an ethereal, fruity odor. It is used in medicine and to make other chemicals. It has a flash point of 50 deg. F. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenai which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material 38 AMYL PHENOL (CORROSIVE LIQUID, N.O.S.) 4935627 CORROSIVE MATERIAL, BASIC UN1760 Amyl phenol is a colorless to straw colored liquid. It is slightly soluble in water. It may burn though it may require some effort to ignite. It is corrosive to tissue. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting tires involv ing this material If contact with the material anticipated, wear full protective clothing April 1961 MOD 000016965 AMYL TRICHLOROSILANE 4934210 CORROSIVE MATERIAL. ACIDIC. COMBUSTIBLE UN1728 Amyl trichlorosilane is a colorless to yellow liquid with a pungent odor. It is comDustible and has a flash point of 145 deg. F. It is readily de composed by water to hydrochloric acid with evolution of heat. It is corrosive to metals and tissue. If material on fire or Involved in fire Use dry chemical, carbon dioxide, or dry sand Oo not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing AMYL6NE 4908108 FLAMMABLE LIQUID UN1108 Amylenes are clear colorless liquids with a petroleum-like odor. They are volatile liquids having flash points of below 0 deg. F. They are lighter than water and insoluble in water. Their vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct (lame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered AMYLAMINE 4909195 FLAMMABLE LIQUID UN1106 Amylamine is a clear colorless liquid with an ammonia-like odor. It is used as a corrosion inhibitor, solvent, flotation agent and in the manu facture of additional chemicals. It has a flash point of 30 deg. F. It is irritating to the eyes and respiratory system. It is lighter than water and soluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak it without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material if contact with the material anticipated, wear full protective clothing April 1981 ANHYDROUS AMMONIA 4904210 NONFLAMMABLE GAS, CORROSIVE UNI 005 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Anhydrous ammonia is a clear colorless gas with a characteristic odor. II is used as a fertilizer, as a refrigerant, and in the manufacture of other chemicals. Although it is classed as a nonflammable gas, it will bum within certain vapor concentration limits, and the fire hazard will increase in the presence of oil or other combustible materials. Its "combustibility" is definitely not a common problem in the event of leakage. It is shipped as a liquid under pressure. Contact with the liquid can cause frostbite. It is soluble in water forming a corrosive liquid. Although ammonia is lighter than air. the vapors from a leak initially hug the ground. It weighs 5.7 pounds per gallon. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use water spray to absorb vapors If material not involved in fire Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and gas tight goggies Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Evacuation If material leaking (not on fire), downwind evacuation must be considered Continued on next page 39 Men 00i 6966 Environmental considerations--land spill Dig a pit pond. Jagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with vinegar or other dilute acid Environmental considerations--water spill Neutralize with dilute acid or removable strong acid If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment ANILINE OIL. LIQUID 4921410 POISON B. COMBUSTIBLE UNI 547 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Aniline oil. liquid is a colorless to brown oily liquid with a characteristic odor. It is used to manufacture other chemicals, especially dyes, pho tographic chemicals, agricultural chemicals and others. It has a flash point of 158 deg. F. It can react with toluene dnsocyanate with the reaction leading to possible ignition. It is heavier than water and slightly soluble in water and its vapors are heavier than air. It is toxic by skin absorption and inhalation. Toxic oxides of nitrogen are produced during combustion of this material. It weighs 8.5 pounds per gallon. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Apply "universal ' gelling agent to immobilize spill Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates 40 Met) Environmental considerations--air spill Apply water spray or mist to knock down vapors Combustion products include corrosive or toxic vapors ANILINE OIL, LIQUID (ANILINE SLUDGE FOR 4921492 FURNACE USE) POISON B UNI 547 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000 454) Aniline sludge is a thick brown liquid with a characteristic odor it is combOstible though it may require some effort to ignite. It is very slightly soluble in water. It is toxic by inhalation and by skin absorotion. It weighs 8.5 pounds per gallon. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of waier Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped matenai with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors ANIMAL OR POULTRY DIP, NEC. LIQUID 4923905 (POISONOUS LIQUID, N O S.) POISON B NA2810 Animal or poultry dip. nec liquid is variable colored liquid, it is soluble in water and is toxic by ingestion. If material on fire or involved in fire Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Use loam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, fiames. and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary April 1981 Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water if contact with the material anticipated, wear full protective clothing ANIMAL OR POULTRY DIP, NEC, OTHER THAN 4923906 LIQUID (POISONOUS SOLID, N.O.S.) POISON B NA2611 Animal or poultry dip. nec. other than liquid is a variable colored solid. It is soluble in water. It is toxic by ingestion, and by inhalation of dusts. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.} Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved In fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when lighting fires involv ing this material If contact with the material anticipated, wear full protective clothing ANIMAL OR POULTRY FEED CHARCOAL, CRUSHED 4917386 OR GROUND, (FLAMMABLE SOLID, N.O.S.) FLAMMABLE SOLID UN1325 Animal or poultry feed charcoal, crushed or ground is a granular black solid. It is fairly easily ignited. The main hazard in transportation is that of spontaneous heating if the charcoal has not been properly cooled after manufacture or if it becomes wet. If material on fire or involved in fire Remove burning material from load if safe and practicable to do so Use dry chemical or carbon dioxide Use water only if flooding quantities are available If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material dry ANISOYL CHLORIDE 4931710 CORROSIVE MATERIAL, ACIDIC UN1729 Anisoyl chloride is an amber colored crystalline solid becoming a liquid at 72 deg. F. The liquid fumes in air. It is decomposed by water to give hydrochloric acid and insoluble anisic acid with release of heat. It is corrosive to metals and skin. If material on fire or involved in fire Use dry chemical or carbon dioxide Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible April 1981 If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing ANTI-FREEZE ALCOHOLS (ALCOHOL, N.O.S.) 4910402 FLAMMABLE LIQUID UN1987 Anti-freeze alcohols are materials containing a solvent having a closed cup flash point of less than 100 deg. F. The hazard is flammability. If material on fire or involved in fire Do not extinguish fire unless flow can be slopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ANTI-FREEZE ALCOHOLS (ALCOHOL, N.O.S,) 4915402 COMBUSTIBLE LIQUID UNI 987 Anti-freeze alcohols are materials containing a solvent having a closed cup hash point between 100 and 199 deg. F. They are generally lighter than water and soluble in water. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out ot water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Continued on next page 41 MOD 000016968 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ANTI-FREEZE COMPOUND, LIQUID 4910105 FLAMMABLE LIQUID NA1142 Anti-freeze compounds, liquid have flash points of less than 100 deg. F They are water soluble and their vapors are heavier than air. If material on fire or invoived in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use '`alcohol' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ANTI-FREEZE PREPARATION. LIQUID 4910106 FLAMMABLE LIQUID NA1142 Anti-freeze preparation, liquid have flash points of less than 100 deg. F. It is soluble in water. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol ' foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of wafer or soap and water ANTIFREEZE COMPOUND LIQUID 4915105 COMBUSTIBLE LIQUID NA1142 Anti-freeze compounds, liquid which are classed as combustible liquid have flash points between 100 and 199 deg. F. They are soluble in water and their vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be slopped Use water in flooding quantities as fog 42 Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ANTIFREEZE PREPARATION. LIQUID 4915106 COMBUSTIBLE LIQUID NA1142 Anti-freeze preparation, liquid which are classed as combustible liquid have flash points between 100 and 199 deg. F. It is soluble in water and its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water m flooding quantities as fog Solid streams of water may be ineffective Coot all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ANT1MINOUS CHLORIDE (See ANTIMONY TRICHLORIDE 4932316) ANTIMONY PENTACHLORIDE 4932310 CORROSIVE MATERIAL, ACIDIC UN1730 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Antimony pentachloride is a reddish-yellow fuming liquid with a pun gent odor, it is used to make other chemicals, and in chemical analysis. Its fumes are irritating to the eyes and mucous membranes. It is de composed by water to hydrochloric acid with release of heat. It solidifies at 37 deg. F. It is corrosive to metals and tissue. If material Involved in fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible April 1981 MOD 000016969 If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear sell-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liauid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Add caustic soda If dissolved, apply sodium sulfide solution to precipitate heavy metals Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Add soda ash Allow to aerate Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment ANTIMONY PENTACHLORIDE SOLUTION 4932312 CORROSIVE MATERIAL, ACIDIC UN1731 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Antimony pentachloride solution is a reddish-yellow solution of anti mony pentachioride in hydrochloric acid. It has a pungent odor and its fumes are irritating to the eyes and mucous membranes. It is decom posed by water into more hydrochloric acid with release of heat, it is corrosive to metals and tissue. If material involved in fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If materiel not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing April 1961 Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Add caustic soda If dissolved, apply sodium sulfide solution to precipitate heavy metals Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Add soda ash Allow to aerate Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment ANTIMONY PENTAFLUORIDE 4932005 CORROSIVE MATERIAL, ACIDIC. POISONOUS UN1732 Antimony pentafluoride is a colorless oily liauid. it is used to make other chemicals ana as a catalyst in the manufacture of other chemicals. It is decomposed by water to hydrofluoric acid and other materials with release of heat. Its fumes are irritating to the eyes and mucous mem branes. It is corrosive to metals and tissue. Hydrofluoric acid causes severe painful skin burns. The material may only be shipped in cylinders Prolonged exposure oi the cylinders to fire or heat may result in their violent rupturing and rocketing. If material involved in fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved In fire Keep material out of water sources and sewers Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing ANTIMONY POTASSIUM TARTRATE SOLID 4941114 ORM-A UN1551 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Antimony potassium tartrate solid is a colorless crystalme solid or a white powder. It is used in textile and leather processing and as an insectide. It is soluble in water. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Continued on next page 43 MCE 000016970 If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, bond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Add caustic soda If dissolved, apply sodium sulfide solution to precipitate heavy metals Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Adjust ph to neutral (ph-7) Allow to aerate ANTIMONY TRIBROMIDE. SOLID 4932319 CORROSIVE MATERIAL NA1549 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Antimony tribromide, solid is the yellow crystalline solid. It is used to make other antimony compounds, in chemical analysis, and in dyeing. It is decomposed by water giving an antimony oxide and hydrobromic acid. It is corrosive to tissue. If material involved in fire Use dry chemicai. carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with Hooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material if contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in ram or fire fighting water Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Add caustic soda If dissolved, apply sodium sulfide solution to precipitate heavy metals Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Add soda ash Allow to aerate 44 ANTIMONY TRIBROMIDE, SOLUTION 4932317 CORROSIVE MATERIAL ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Antimony tribromide, solution is the yellow crystalline solid dissolved in hydrobromic acid. It is used to make other antimony compounds, in chemicai analysis, and in dyeing. It is decomposed by water giving an antimony oxide and hydrobromic acid. It is corrosive to metals and tissue. If material Involved in fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding Quantities as spray and fog Use water spray to absorb vapors Coot all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Avoid breathing dusts Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Add caustic soda If dissolved, apply sodium sulfide solution to precipitate heavy metals Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Add soda ash Allow to aerate Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment ANTIMONY TRICHLORIDE SOLUTION 4932318 CORROSIVE MATERIAL. ACIDIC UN1733 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Antimony trichloride solution is a colorless liquid with a pungent odor. The solution is antimony trichloride dissolved in hydrochloric acid. The antimony trichloride is decomposed by water to hydrochloric acid and antimony oxychloride with release of heat, (the antimony oxychloride is soluble in hdyrochloric acid and insoluble in water). The solution is corrosive to metals and tissue. If material involved in fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible April 1981 MCD 000016971 If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Add caustic soda If dissolved, apply sodium sulfide solution to precipitate heavy metals Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Add soda ash Allow to aerate Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment ANTIMONY TRICHLORIDE. SOLID 4932316 CORROSIVE MATERIAL, ACIDIC UN1733 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000 454) Antimony trichloride, solid is a colorless crystalline mass. It is decom posed by water to hydrochloric acid and antimony oxychloride, -antimony oxychloride is soluble in hydrochloric acid but insoluble in water). It is corrosive to metals and tissue. If material involved in fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved In fire Keep material out of water sources and sewers Use water spray lo knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Add caustic soda If dissolved, apply sodium sulfide solution to precipitate heavy metals Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Add soda ash Allow to aerate Environmental considerations--air spili Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment ANTIMONY TRIFLUORIDE SOLUTION 4932305 CORROSIVE MATERIAL NA1549 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ.10Q0/454) Antimony trifluoride solution is the white to grey crystalline solid dis solved in water, it is used in ceramics and to make other chemicals. It is corrosive to metals and tissue. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacteO the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash. cement powder, sawdust, or com mercial sorbents Apply "universal" gelling agent to immobilize spill Environmental considerations--water spili Add caustic soda If dissolved, apply sodium sulfide solution to precipitate heavy metals Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmentai considerations--air spili Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment 45 MCI) 0000l697p ANTIMONY TRIFLUORIDE, SOLID 4932335 CORROSIVE MATERIAL NA1549 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Antimony trifluoride, solid is a white to grey crystalline solid. It is used in ceramics and to make other chemicals. It is corrosive to tissue. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled matenal with crushed limestone, soda ash. or lime Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving m rain or fire fighting water Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Add caustic soda if dissolved, apply sodium sulfide solution to precipitate heavy metals Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Add soda ash Allow to aerate Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment ANTIMONY TRIOXIDE (ANTIMONY OXIDE) 4966905 ORM-E NA9201 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Antimony trioxide is a white crystalline solid. It is used to fireproof fabrics, paper and plastics, as a paint pigment and for many other uses. It is insoluble in water. It is non-combustible. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Pereonnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spiil Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Add caustic soda If dissolved, apply sodium sulfide solution to precipitate heavy metals 46 Add soda ash Allow to aerate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates AQUA AMMONIA SOLUTION (CONTAINING 44% OR LESS AMMONIA) (See AMMONIUM HYDROXIDE 4935280) ARGON 4904502 NONFLAMMABLE GAS UN1006 Argon is a colorless odorless noncombustible gas. It is heavier than air and can asphyxiate by displacement of air. It may be shipped m cylinders or special tank cars. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved In fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment ARGON--OXYGEN GAS MIXTURE (COMPRESSED 4904410 GAS. N.O.S.) NONFLAMMABLE GAS UNI 956 Argon--oxygen gas mixture is a colorless odorless gas. Both argon and oxygen are noncombustible: however, oxygen can accelerate the burning of a fire. It may only be shipped in cylinders If material Involved In fire Extinguish fire using ageni suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep sparks, flames, and other sources of ignition away Attempt to stop leak if without hazard Personnel protection Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution ARGON PRESSURIZED LIQUID 4904503 NONFLAMMABLE GAS UNI 951 Argon pressurized liquid is a colorless noncombustible liquid. Contact with the liquid will cause frostbite. The gas is heavier than air and can asphyxiate by displacement of air. It may only be shipped in cylinders. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Cool all affected containers with flooding quantities of water Do not use water on material itself Apply water from as far a distance as possible If material not Involved in fire Attempt to stop leak if without hazard Do not use water on material itself Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment April 1981 MOD ~;000 1697 3 ARGON-CARBON DIOXIDE GAS MIXTURE 4904504 (COMPRESSED GAS, N.O.S.) NONFLAMMABLE GAS UN1956 Argon-carbon dioxide gas mixture is a colorless odorless gas. Both argon and carbon dioxide are noncombustible. The mixture can as phyxiate by the displacement of air. It may only be shipped in cylinders. If material Involved in fire Extinguish fire using agent suitable for type Of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment ARGON-HYDROGEN GAS MIXTURE (COMPRESSED 4905605 GAS. N.O.S.) FLAMMABLE GAS UN1954 Argon-hydrogen gas mixture is a colorless odorless gas. It is easily ignited. It may oniy pe shipped in cylinders. Argon is nonflammable and heavier than air: hydrogen is flammable and lighter than air. A flame may flash back to Ihe source of leak very easily. It may asphyxiate by the displacement of air. Under tire conditions cylinders may violently rupture and rocket. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Cool all affected containers with flooding quantities of water Apply water from as far a dislance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on tire), downwind evacuation must be considered ARGON-HYDROGEN GAS MIXTURE (COMPRESSED 4904505 GAS. N.O.S.) NONFLAMMABLE GAS UN1956 Argon-hydrogen gas mixture is a colorless odorless gas. Argon is noncombustible whereas hydrogen is a flammable gas. The mixture can separate with the hydrogen rising in the air. The mixture can asphyxiate by the displacement of air. It may only be shipped in cylinders. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment April 1981 ARGON-METHANE GAS MIXTURE (COMPRESSED 4905810 GAS. N.O.S.) FLAMMABLE GAS UN1954 Argon-methane gas mixture ts a colorless odorless gas. It is easily ignited and may only be shipped in cylinders. Argon is noncombustible and heavier than air. methane is flammable and lighter than air. A flame can flash back to the source of leak very easily. It may asphyxiate by the displacement o( air. Under fire conditions cylinders may violently rupture and rocket. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on ftrei. downwind evacuation must be considered ARGON-METHANE GAS MIXTURE (COMPRESSED 4904506 GAS. N.O.S.) NONFLAMMABLE GAS UN1956 Argon-methane gas mixture is an odorless colorless gas. Argon is noncombustible: methane is a flammable gas. Argon is heavier than air. Methane is lighter than air. The mixture can separate into its two com ponents. It can asphyxiate by the displacement of air. It may only be shipped in cylinders. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns wiih difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment ARGON-NITROGEN GAS MIXTURE (COMPRESSED 4904507 GAS, N.O.S.) NONFLAMMABLE GAS UN1956 Argon-nitrogen gas mixture is a colorless odorless gas. Both argon and nitrogen are noncombustible. The mixture can asphyxiate by the displacement of air. It may only be shipped in cylinders. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Attempt to stop leak if without hazard Continued on next page 47 CD oooq 16974 Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment AROMATIC CONCENTRATES. SUITABLE ONLY FOR 4915490 FURTHER PROCESSING (COMBUSTIBLE LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Aromatic concentrates suitable only tor further processing are ma terials having a closed cup flash point between 100 and 199 deg. F. The hazard of these materials is combustibility. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water AROMATIC CONCENTRATES. SUITABLE ONLY FOR 4910490 FURTHER PROCESSING (FLAMMABLE LIQUID, N.O.S.) FLAMMABLE LIQUID UN1993 Aromatic concentrates suitable only for further processing are ma terials having a dosed cup flash point of less than tOO deg. F. The hazard of these materials is flammability. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Peraonnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ARSENIC ACID SOLUTION (ARSENIC ACID OTHER 4923105 THAN FUSED) POISON B CORROSIVE UNI 554 Arsenic acid solution is a clear colorless liquid, it is soluble in water and non combustible. It is corrosive to metals and is toxic by ingestion. 48 If material involved in fire Extinguish fire using agent suitable lor type of surrounding fire (Material itself does not burn or burns with difficulty.! Use water in flooding quantities as tog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing ousts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting tires involv ing this material ARSENIC ACID, SOLID (ARSENIC ACID FUSED) 4923106 POISON B. CORROSIVE UNI 553 Arsenic acid, solid is a white crystalline solid. It is soluble in water and non combustible. It is corrosive to metals in the presence of moisture and is toxic by ingestion. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material ARSENIC BROMIDE. SOLID 4923202 POISON B UN1555 Arsenic bromide, solid is a yellowish white crystalline solid melting at 90 deg. F. It absorbs moisture from the air. It is decomposed by water to form arsenic acid and hydrobromic acid, a corrosive material. It is toxic by inhalation and ingestion. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Do not use water on material itself If large quantities of combustibles are involved, use water in flooding Quantities as spray and fog Use water spray to absorb vapors If material not involved in fire Keep material out of water sources and sewers Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime April 1961 MCI) O00016975 Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with (he material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material ARSENIC CHLORIDE, LIQUID 4923203 POISON B UNI 560 Arsenic chloride is a colorless to yellow oily fuming liquid, it is used to make other arsenic containing compounds. It is decomposed by water to give arsenic acid and hydrochloric acid, a corrosive material. It is irritating to the skin eyes and mucous membranes. It is toxic by inhalation and ingestion. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If material not involved in fire Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation I! material leaking (not on fire), downwind evacuation must be considered ARSENIC DISULFIDE (See ARSENIC SULFIDE 4923206) ARSENIC IODIDE, SOLID 4923205 POISON B NA1557 Arsenic iodide is an orange-red crystalline solid, it is used in medicine and in chemical analysis. It is decomposed by water to form arsenic acid and hydriodic acid, a corrosive material. It is toxic by ingestion. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If material not Involved in fire Use water spray to knock-down vapors Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material April 1981 Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material ARSENIC PENTOXIDE, SOLID 4923112 POISON B. CORROSIVE UN1559 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Arsenic pentoxide, solid is a white crystalline solid. It is soluble in water to form arsenic acid. It is corrosive to metals in the presence of moisture and is non combustible. It is toxic by ingestion. If material involved in fire Extinguish fire using agent suitable tor type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Add ferric chloride (fec!3) Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ARSENIC SULFIDE, SOLID 4923208 POISON B NA1557 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Arsenic sulfide is a yellow or red crystalline solid or powder. It is insoluble in water and it is combustible. It is toxic by inhalation (dust) and by ingestion. H material on fire or involved in fire Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical H material not on fira and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Continued on next page 00001.6976 HCt> 49 Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ARSENIC TRICHLORIDE 4923209 POISON B UN1560 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000 2270) Arsenic trichloride is a colorless to yellow oily fuming liquid. It is de composed by water to give arsenic acid and hydrochloric acid, a cor rosive material, ft is irritating to (he skin eyes and mucous membranes. It is toxic by inhalation and ingestion. If material involved in fire Extinguish lire using agent suitable for type of surrounding fire {Material itself does not burn or burns with difficulty.) Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material ith crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Adjust ph to neutral (ph-7) Add calcium hypochlorite Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Add ferric chloride (fecl3) Adjusi ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment ARSENIC TRIOXIDE. SOLID (ARSENIC. WHITE. SOLID 4923115 ARSENOUS ACID. SOLID) POISON B. CORROSIVE UN1S61 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Arsenic trioxide, solid is a white amorphous powder. It is slightly sol uble in water and is non combustible. It is corrosive to metals in the presence of moisture and is toxic by ingestion. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Add calcium hypochlorite Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Add ferric chloride (fecl3) Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ARSENIC TRISULFIDE 4923222 POISON B NA1557 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Arsenic trisulfide is a yellow crystalline solid. It is used as a pigment and for other uses, it is insoluble in water. It is noncombustible. If material on fire or involved in fire Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical N material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond. lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water 50 'V'z> 'On 0? <0 April 1981 Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to (rap material at bottom Adjust ph to neutral (ph-7) Add ferric chloride (fecl3) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ARSENIC WHITE. SOLID (See ARSENIC TRIOXIDE. SOLID 4923115) ARSENIC, CRUDE (POISONOUS SOLID, N.O.S.) 4923204 POISON B NA2811 Arsenic, crude, is a greyish metallic solid. It is insoluble in water. It is toxic by ingestion. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting (ires involv ing this material If contact with the material anticipated, wear full protective clothing ARSENIC. SOLID (ARSENIC METALLIC) 4923207 POISON B UN1556 Arsenic, solid is a greyish metallic solid turning black on the exposure to air. It is insoluble in water, it is toxic by ingestion. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use waier in flooding quantilies as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing ARSENICAL COMPOUND, N.O.S. (OR) ARSENICAL 4923210 MIXTURE, N.O.S. LIQUID POISON B UNI 556 Arsenical compound, n.o.s. or arsenical mixture, n.o.s.. liquid are liquid materials or solutions of solid materials containing arsenic. It is toxic by ingestion. April 1981 If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in Hooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Build dikes to contain tlow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the matenal Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ARSENICAL COMPOUND, N.O.S., SOLID, (OR) 4923211 ARSENICAL MIXTURE, N.O.S. SOLID POISON B UNI 557 Arsenical compound, n.o.s.. solid, (or) arsenical mixture, n.o.s. Solid are various colored solid materials containing arsenic. Material generally is not soluble in water. It is toxic by inhalation (dust) and by ingestion. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material ARSENICAL DIP. LIQUID (SHEEP DIP) 4923212 POISON B NA1557 Arsenical dip. liquid is a solution of an arsenic compound. It is soluble in water and is toxic by ingestion. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 00001.697ft MCD 51 ARSENICAL OUST 4923213 POISON B UNI 562 Arsenical dust is a greyish colored powder. It is insoluble in water. It is toxic by inhalation (dust) and by ingestion. If material Involved in fire Extinguish tire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material oul of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning matena! Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material ARSENICAL ORE, CRUDE (POISONOUS SOLID. 4923395 N.O.S.) POISONS NA2B11 Arsenical ore, crude is a variable colored solid., it is insoluble in water. It is toxic by ingestion. If material on fire or Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not Involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any materia! which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing ARSENICAL PESTICIDE. LIQUID, N.O.S. 4923301 (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC, LIQUID) POISON B UN2759 Arsenical pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The carrier may burn though it may regutre some effort to ignite. It is toxic by inhalation, skin absorption, and or ingestion. In case of damage to. or leaking from containers of this ma terial contact the pesticide safety team network. Telephone: 800-424- 9300. If material involved in fire Extinguish fire using agent suitable for type of surrounding tire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ARSENICAL PESTICIDE, LIQUID. N.O.S. 4923303 (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL. NEC) POISON B UN2759 Arsenical pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The carrier may burn though it may require some effort to ignite. It is toxic by inhalation, skin absorption, and or ingestion. In case of damage to. or leaking from containers of this ma terial contact the pesticide safety team network. Telephone: 800-424- 9300. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ARSENICAL PESTICIDE. LIQUID. N.O.S. 4910557 (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL, NEC) FLAMMABLE LIQUID UN2760 Arsenical pesticide is a liquid or solid dissolved m a liquid carrier. The carrier is water emulsifiable. The primary hazard of this material is the flammability of the carrier. It has a flash point below too deg. F. it can cause illness by inhalation, skin absorption and or ingestion, in case of damage to. or leaking from containers of this material contact the pes ticide safety team network. Telephone: 800-424-9300. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical if material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wear self-contained breathing apparatus when fighting fires involv ing this material 52 Mod April 1981 0000l ARSENICAL PESTICIDE. LIQUID. N.O.S. 4910558 (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC. LIQUID) FLAMMABLE LIQUID UN2760 Arsenical pesticide is a liquid or solid dissolved in a liquid carrier The carrier is water emulsifiable. The primary hazard ot this material is the flammability of the carrier. It has a flash point below 100 deg. F. It can cause illness by inhalation, skin absorption and or ingestion. In case of damage to. or leaking from containers of this material contact the pes ticide safety team network. Telephone; 800-424-9300. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol ' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wear self-contained breathing apparatus when lighting fires involv ing this material ARSENICAL PESTICIDE, SOLID, N.O.S. (COMPOUNDS 4923304 AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICUTURAL. NEC) POISON B UN27S9 Arsenical pesticide is a solid or a liquid absorbed on a dry carrier. It is a wettable powder. It is toxic by inhalation, skin absorption, and or ingestion. In case of damage to. or leaking from containers of this ma terial contact the pesticide safety team network. Telephone: 800-424- 9300. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as tog Use alcohol' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing ARSENICAL PESTICIDE. SOLID, N.O.S. (COMPOUNDS 4923302 AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC, OTHERTHAN LIQUID) POISON B UN27S9 Arsenical pesticide is a solid or a liquid absorbed on a dry carrier, tt is a wettable powder. It is toxic by inhalation, skin absorption, and or ingestion. In case of damage to. or leaking from containers of this ma terial contact the pesticide safety team network. Telephone; 800-424- 9300 April 1981 If material on fire or involved in fire Extinguish fire using agent suitable tor type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as log Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts Of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing ARSENOUS ACID, SOLID (See ARSENIC TRIOXIDE, SOLID 4923115) ARSENOUS AND MERCURIC IODIDE SOLUTION 4923215 POISON B NA2810 Arsenous and mercuric iodide solution is arsenous iodide and mercuric iodide dissolved in water and is red or yellow in color. It is toxic by ingestion. If material involved in fire Extinguish fire using agent suitable for lype of surrounding fire (Matenal itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ARSINE 4920135 POISON A, FLAMMABLE UN2188 Arsine is a colorless gas with a disagreeable garlic-like odor. It is flammable. The gas is heavier than air and a flame can (lash back to the source of leak very easily. It is toxic by inhalation. It may only be shipped in cylinders which may have to be overpacked in wooden or metal containers. Prolonged exposure of the cylinders to fire or heat may result in the cylinders violent rupturing and rocketing. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Continued on next page MCD 000016980 53 Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation if material leaking (not on fire), downwind evacuation must be considered ASPHALT ADDITIVE, ANTI-STRIPPING (CORROSIVE 4936543 LIQUIO, N.O.S.) CORROSIVE MATERIAL UN1760 Asphalt additive, anti-stripping is a various colored liquid. It is corrosive to metals and/or tissue, it may burn though it may require some effort to ignite. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itseif does not burn or burns with difficulty.) Use water in flooding quantities as fog Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing ASPHALT PAVEMENT SURFACE SEALER, ASPHALT. 4915302 COAL TAR OR PETROLEUM BASE (COMBUSTIBLE LIQUID. N.O.S.) COMBUSTIBLE LIQUID NA1993 Asphalt pavement surface sealer, asphalt, coal tar or petroleum base is a black liquid with a petroleum like odor. It has a Hash point between 100 and 199 deg. F. It Is generally heavier than water and is insoluble in water. Its vapors are heavier than air If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water 54 ASPHALT PAVEMENT SURFACE SEALER, ASPHALT. 4910302 COAL TAR OR PETROLEUM BASE (FLAMMABLE LIQUID, N.O.S.) FLAMMABLE LIQUID UN1993 Asphalt pavement surface sealer, asphalt, coal tar or petroleum base is a black liquid with a petroleum like odor, it has a flash point of less than 100 deg. F. It is generally heavier than water and is insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as log Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, ana goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ASPHALT TILE, PLASTICIZER (COMBUSTIBLE 4915408 LIQUID.N.O.S.) COMBUSTIBLE LIQUID NA1993 Asphalt tile, plasticizer is a material containing a solvent having a closed cup flash point between 100 and 199 deg. F. The hazard is combustibility. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical H material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ASPHALT TILE, PLASTICIZER (FLAMMABLE LIQUID. 4910408 N.O.S.) FLAMMABLE LIQUID UN 1993 Asphalt tile, plasticizer is a material containing a solvent having a closed cup flash point of less than 100 deg. F. The hazard is flammability. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical April 1981 MCI) 00001698I If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water ASPHALT, CUT BACK 4910220 FLAMMABLE LIQUID NA1999 Asphalt, cut back is a thick black liquid with a characteristic "tar" odor. It has a flash point of less than 100 deg. F. It is generally heavier than water and insoluble in water, its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out ot water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ASPHALT, CUT BACK (ASPHALT PETROLEUM. 4915320 LIQUID AND TALL OIL PITCH. MIXED COMBUSTIBLE LIQUID NA1999 Asphalt, cut back is a thick black liquid with a characteristic "tar" odor. It has a flash point between 100 and 199 deg. F. It is generally heavier than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 ASPHALTUM OR COAL TAR PAINT (PAINT) 4915252 COMBUSTIBLE LIQUID UNI 263 Asphaltum or coal tar paint may contain a combustible solvent. Its flash point is between 100 and 199 deg. F. The hazard is combustibility. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ASPHALTUM OR COAL TAR VARNISH (VARNISH) 4915253 COMBUSTIBLE LIQUID UN1263 Asphaltum or coal tar varnish may contain a combustible solvent. Its flash point is between 100 and 199 deg. F. The hazard is combustibility. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water AZINPHOS METHYL (OR) GUTHION (AGRICULTURAL 4921526 INSECTICIDES. NEC. LIQUID) POISON B NA2793 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-V0.454) Azinphos methyl is a brown waxy solid dissolved in a liquid carrier. It is used as a pesticide. II is a water emuisifiable liquid. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 600-424-9300. If material on (ire or involved in fire Do not extinguish lire unless How can be stopped Use water in flooding quantities as log Solid streams of water may be ineffective Cool ail affected containers with flooding quantities ot water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Continued on next page mod 00oqi696, 55 If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors AZINPHOS METHYL (OR) GUTHION (AGRICULTURAL 4921527 INSECTICIDES, NEC, OTHER THAN LIQUID) POISON B NA2763 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Azinphos methyl is a brown waxy solid. It is used as a pesticide. It is a wettable powder. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to. or leaking from containers of this ma terial contact the pesticide safety team network. Telephone; 800-424- 9300. If material on fire or involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as tog Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates 56 AZINPHOS METHYL (OR) GUTHION (INSECTICIDES, 492152B OTHER THAN AGRICULTURAL, NEC) POISON B NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Azinphos methyl is a brown waxy solid or the solid dissolved in a liquid carrier. It is used as a pesticide. It is toxic by inhalation, skin absorption, and/or ingestion. It is a wettable powder or water emulsifiable liquid. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors AZINPHOS METHYL MIXTURE, LIQUID (OR) GUTHION 4921529 MIXTURE, LIQUID (AGRICULTURAL INSECTICIDES, NEC, LIQUID) POISON B NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Azinphos methyl mixture, liquid is a brown waxy solid dissolved in a liquid carrier. It is used as a pesticide. It is a water emulsifiable liquid. It is toxic by inhalation, skin absorption, and/or ingestion, In case of damage to, or leaking from containers of this material contact the pes ticide safety team network. Telephone; 800-424-9300. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors April 1981 le983 Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spilt Apply water spray or mist to knock down vapors BAGS, SODIUM NITRATE EMPTY AND UNWASHED 4917301 FLAMMABLE SOLID UNI 359 Bags, sodium nitrate, empty and unwashed are burlap bags that have been used to ship sodium nitrate and are still contaminated by it. The bags are easily ignited and burn quite fiercely due to the oxidizing prop erties of sodium nitrate. The sodium nitrate is soluble in water. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Flood with water If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing fumes from burning material BARIUM AZIDE. WET (50% OR MORE WATER) 4917110 FLAMMABLE SOLID UN1571 Barium azide, wet is a slurry of white crystals. The dried material is a high explosive. Dry it is easily ignited and burns very vigorously, it is soluble m water. Toxic oxides of nitrogen are produced during combus tion of this material. If material on fire or involved in fire Dangerously explosive Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Do not attempt to sweep up dry material Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 5000 feet April 1981 BARIUM CHLORATE 4918708 OXIDIZER UN1445 Barium chlorate is a white crystalline solid, it is used in explosives and pyrotechnics, in dyeing textiles, and to make other chlorates. The ma terial is soluble in water. It forms a very flammable mixture with com bustible materials and this mixture may be explosive if the combustible material is very finely divided. The mixture can be ignited by friction. Contact with strong sulfuric acid can cause fires or explosions. When mixed with ammonium salts, spontaneous decomposition and ignition may result. Protonged exposure of the material to fire or heat can result in an explosion. If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Approach fire with caution Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet BARIUM CHLORATE, WET 4918605 OXIDIZER NA1445 Barium chlorate, wet is a water slurry or sludge of white crystals, it is used in explosives and pyrotechnics, in dyeing textiles, and to make other chlorates. The material is soluble in water. It forms a very flam mable mixture with combustible materials and this mixture may be ex plosive if the combustible material is very finely divided. The mixture can be ignited by friction. Contact with strong sulfuric acid can cause fires or explosions. When mixed with ammonium salts, spontaneous decom position and ignition may result. Prolonged exposure of the material to fire or heat can result in an explosion. If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Approach fire with caution Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet BARIUM CYANIDE, SOLID 4923410 POISON B UNI 565 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10/4.54) Barium cyanide, solid is a white crystalline solid. It is soluble in water and gradually decomposed by water and very rapidly decomposed by acids to give off hydrogen cyanide, a flammable poison gas. It is toxic by skin absorption through open wounds, by ingestion, and by inhalation of hydrogen cyanide from the decomposition of the materia!. Toxic oxides of nitrogen are produced in fires involving this matenal. Continued on next page 57 MOD 000016984 If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use foam, carbon dioxide or dry chemical Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If material not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Use water spray to knock-down vapors Do not use water on material itself Personnel protection Avoid breathing vapors or dusts Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain iiquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Add caustic soda Add calcium hypochlorite Add sodium sulfate (na2so4) Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates BARIUM HYDROXIDE MONOHYDRATE (CORROSIVE 4935238 SOLID, N.O.S.) CORROSIVE MATERIAL UN1760 Barium hydroxide monohydrate is a white powder. It is used in water purification, to make lubricating and oil additives, to make barium con taining chemicals and for many other uses. It is slightly soluble in water. It is corrosive to metals and tissue. Tissue. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Apply water from as far a distance as possible if material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water BARIUM NITRATE 4918709 OXIDIZER UNI 446 Barium nitrate is a white crystalline solid. The material is soluble in water. It is non-combustible but it will accelerate the burning of com bustible materials. If large quantities ol the material are involved in the fire or the combustible material is finely divided an explosion may result. Prolonged exposure of the matenal to tire or heat may result in an explosion. Toxic oxides of nitrogen are produced in fires involving this material. - 58 If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet BARIUM PERCHLORATE 4918710 OXIDIZER UN1447 Barium perchlorate is a white crystalline solid, it is used to make explosives. It is soluble in water. It is noncombustible but it will accelerate the burning of combustible materials. If large quantities of the material are involved in the tire or the combustible material is finely divided an explosion may result. Prolonged exposure of the matenal to tire or heat may result in an explosion. If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Approach fire with caution Evacuation if fire becomes uncontrollable--evacuate for a radius of 2500 feet BARIUM PERMANGANATE 4918711 OXIDIZER UN1448 Barium permanganate is a purplish colored crystalline solid, it is used as a disinfectant and to make other permanganates. It is soluble in water. The material itself is noncombustible but it will accelerate the burning of combustible material, if the combustible material is finely divided the mixture may be explosive. Contact with liquid combustible materials may result in spontaneous ignition. Contact with sulfuric acid may result in fires or explosions. If material on fire or Involved In fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers April 1961 Ooooi69b 5 MOD Personnel protection Avoid breathing dusts Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet BARIUM PEROXIDE 4918712 OXIDIZER UN1449 Barium peroxide is a greyish white granular solid. It is insoluble in water and is slowly decomposed by water. It is non-combustible but it will acceleraie the burning of combustible material, if the combustible material is finely divided the mixture may be explosive. Mixtures of combustible material and the peroxide can be ignited by friction or con tact with moisture. If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet BLASTING CHLORATE (CHLORATE, N.O.S.) 4918707 OXIDIZER UNI 461 Blasting chlorate is a crystalline solid. It is soluble in water. It forms a very flammable mixture with combustible materials and this mixture may be explosive if the combustible material is finely divided. The mixture can be ignited by friction. Contact with strong sulfuric acid can cause fires or explosions. When mixed with ammonium salts, spontaneous decomposition and ignition may result. Prolonged exposure to fire or heat can result in an explosion. If material on fire or Involved In fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If tire becomes uncontrollable--evacuate for a radius of 2500 feet April 1981 BATTERIES, ELECTRIC STORAGE. WET. WITH 4936502 AUTOMOBILE AUTO PARTS, ENGINE CORROSIVE MATERIAL NA2794 Batteries, electric storage, wet. with automobile auto parts engine consist of the wet electric storage battery and mechanic equipment in the same carload or trailer toad. There are two possible hazards tn transportation. First that the battery may be short circuited and resulting sparks may cause a fire. The second is that the battery may be turned over and the electrolyte spilled. The electrolyte is corrosive to metals and tissue. It is water soluble with evolution of heat. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing BATTERY BOX COMPOUNDS (COMBUSTIBLE LIQUID, 4915550 N.O.S.) COMBUSTIBLE LIQUID NA1993 Battery box compounds are various colored liquids. They have a flash point between 100 and 199 deg. F. They are generally heavier than water and insoluble in water. Their vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water BATTERY BOX COMPOUNDS (FLAMMABLE LIQUID, 4910550 N.O.S.) FLAMMABLE LIQUID UN1993 Battery box compounds are various colored liquids. They have a flash point of less than 100 deg. F. They are generally heavier than water and insoluble in water, their vapors are heavier than air. If material on fire or involved in fire Do not extinguish lire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use 'alcohol'' foam, carbon dioxide or dry chemical Continued on next page MOD 000016986 59 If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Oo not handle broken packages withoul protective eauipment Wash away any material which may have contacted the body with copious amounts of water or soap and water BATTERY CHARGER WITH ELECTROLYTE (ACID) 4936567 CORROSIVE MATERIAL, ACIDIC NA2794 Battery charger with electrolyte (acid) consists of a package containing a battery charger and container (s) of electrolyte (acid). The electrolyte is a sulfuric acid-water solution. It is a colorless odorless liquid and is soluble in water with evolution of heat. It is corrosive to metals and tissue. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use wafer in flooding quantities as fog Apply water from as far a distance as possible If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing BATTERY CHARGER WITH ELECTROLYTE 4936568 (ALKALINE BATTERY FLUID) CORROSIVE MATERIAL. BASIC NA2794 Battery charger with electrolyte (alkaline battery tluidl consists of a package containing a battery charger and container (s) of electrolyte (alkaline battery fluid). The electrolyte is water solution of potassium or sodium hydroxide. It is a colorless odorless liquid and is soluble in water with release of heal. It is corrosive to metals and tissue. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid bodily contact with the matenal Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing 60 MOD 000016987 BATTERY SETS FOR WET BATTERIES (CORROSIVE 4936503 SOLID, N.O.S.) CORROSIVE MATERIAL. BASIC UN17S9 Battery sets for wet batteries have containers of potassium or sodium hydroxide in the same package with other non-reguiated items. Potas sium or sodium hydroxide are white solids. They are soluble in water with release of heat. They are corrosive to metals ano tissue. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not Ourn or burns with difficulty.) Use water in flooding quantities as fog Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water BATTERY SETS IN BATTERY BOXES (CORROSIVE 4936504 SOLID, N.O.S.) CORROSIVE MATERIAL, BASIC UN1759 Battery sets in battery boxes have containers of potassium or sodium hydroxide in the same package with other non-regulated items. Potas sium and sodium hydroxide are white solids. They are soluble in water with release of heat. They are corrosive to metals and tissue. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Apply water from as far a distance as possible If material not involved In fire Keep material out of water sources and sewers Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Oo not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water BATTERY, ELECTRIC STORAGE, WET 4936558 CORROSIVE MATERIAL NA2794 Battery, electric storage, wet is the battery containing either electrolyte (acid) or alkaline corrosive battery fluid. The batteries are continuously evolving hydrogen, a flammable gas. The fluids are soluble m water with evolution of heat. They are corrosive to metals and tissue. If material involved In fire Extinguish lire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid bodily contact with the material Wear bools, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting tires involv ing this material If contact with the material anticipated, wear full protective clothing April 1981 BATTERY. ELECTRIC STORAGE, WET. WITH 4936557 CONTAINERS OF CORROSIVE BATTERY FLUID CORROSIVE MATERIAL NA2794 Battery, electric storage, wet. with containers of corrosive Cattery fluid consist of the batteries packed in the same outside shipping container with battery fluid. The fluid is usually sulfuric acid or sodium potassium hydroxide solutions. The fluid is soluble in water with evolution of heat. It is corrosive to metals and tissues. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting tires involv ing this material If contact with the material anticipated, wear full protective clothing BAY RUM (COMBUSTIBLE LIQUID. N.O.S.) 4915420 COMBUSTIBLE LIQUID NA1993 Bay rum is a clear colorless to variable colored liquid with a pleasant odor. It has a flash point between 100 and 199 deg. F. It is lighter than water and soluble in water. Its vapors are heavier ihan air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use 'alcohol ' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain How as necessary Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water BAY RUM (FLAMMABLE LIQUID, N.O.S.) 4910420 FLAMMABLE LIQUID UN1993 Bay rum is a clear colorless to variable colored liquid with a pleasant odor. It has a Hash point of less than 100 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Soiid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water trom as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers April 1981 Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water BELT DRESSING (COMBUSTIBLE LIQUID. N.O.S.) 4915416 COMBUSTIBLE LIQUID NA1993 Belt dressing is a material containing a solvent having a closed cup flash point between 100 and 199 deg. F. The hazard is combustibility. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as log Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" loam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water BELT DRESSING,(FLAMMABLE LIQUID, N.O.S.) 4910416 FLAMMABLE LIQUID UNI 993 Belt dressing is a material containing a solvent having a closed cud flash point of less than 100 deg. F. The hazard is flammability. If material on fire or involved in fire Do not extinguish fire unless flow can be slopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with Hooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical ff material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water BENZALDEHYDE 4913111 COMBUSTIBLE LIQUID NA1989 Benzaldehyde is a clear colorless to yellowish liquid with an almondlike odor. It has a flash point of 148 deg. F. It is heavier than water and insoluble in water. Its vapors are heavier than air. Continued on next page 61 mcd 001698q If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water BENZENE 4906110 FLAMMABLE LIQUID UN1114 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RG-1000/454) Benzene is a clear colorless liquid with a characteristic aromatic odor. It is used to make other chemicals, as a solvent, and as a gasoline additive. It has a flash point of 12 deg. F., and solidifies at 42 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. It weighs 7.3 pounds per gallon. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash. cement powder, sawdust, or com mercial sorbents Apply fluorocarbon-water foam to diminish vapor and fire hazard Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e.g. detergent, soaps, alcohols) to com press and thicken spilled material Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration 62 Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors BENZENE PHOSPHORUS DICHLORIDE 4931715 CORROSIVE MATERIAL. ACIDIC UN2798 Benzene phosphorus dichloride is a colorless fuming liquid. It is de composed by water to give hydrochloric acid with release of heat. It is corrosive to metals and tissue. If material on fire or involved in fire Use dry chemical or carbon dioxide Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing BENZENE PHOSPHORUS THIODICHLORIDE 4931720 CORROSIVE MATERIAL. ACIDIC UN2799 Benzene phosphorus thiodichloride is a colorless fuming liquid. It is decomposed by water to give hydrochloric acid with release of heat. It is corrosive to metals and tissue, tf material on fire or involved In fire Use dry chemical or carbon dioxide Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear lull protective clothing April 1981 MOD 000016989 BENZIDINE 4921503 POISON B UNI 885 Benzidine is a greyish yellow to greyish red crystalline solid. It is used to make other chemicals, and in chemical and biological analysis. It is soluble in hot water. It is toxic by ingestion, inhalation, and skin ab- sorbtion. Toxic oxides of nitrogen are produced during the combustion of this material. If material on fire or Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material BENZINE 4908112 FLAMMABLE LIQUID UN1115 Benzine is a clear colorless liquid with a petroleum-like odor. It has a flash point of less than 0 deg. F. It is lighter than water and insoluble in water. Us vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in tire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If tire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered BENZOIC ACID 4966340 ORM-E NA9094 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Benzoic acid is a white crystalline solid, it is used to make other chemicals, as a food preservative, and for other uses, it is slightly soluble in water. It will burn though it may take some effort to ignite. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog April 1981 Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors or dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill if dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates BENZOIC DERIVATIVE PESTICIDE, LIQUID. N.O.S 4910507 (COUMPOUNDS ANO PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL, NEC) FLAMMABLE LIQUID UN2770 Benzoic derivative pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The primary hazard of this material is the flammability of the carrier. It has a flash point below 100 deg. F. It can cause illness by inhalation, skin absorption and or inges tion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300. If material on fire or involved in fire Do not extinguish fire unless flow can be slopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool aii affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wear self-contained breathing apparatus when fighting fires involv ing this material BENZOIC DERIVATIVE PESTICIDE, LIQUID, N.O.S. 4921609 (COUMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC, LIQUID) POISON B UN2769 Benzoic derivative pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The carrier may burn though it may require some effort to ignite. It is toxic by inhalation, skin ab sorption. and/or ingestion. In case of damage to. or leaking from con tainers of this material contact the pesticide safety team network. Tele phone: 800-424-9300. Continued on next page MCD 000016990 63 If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain ftow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water BENZOIC DERIVATIVE PESTICIDE, LIQUID, N.O.S. 4910506 (COUMPOUNDS ANO PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC. LIQUID) FLAMMABLE LIQUID UN2770 Benzoic derivative pesticide is a liquid or solid dissolved in a liquid carrier. The liquid is water emulsifiable. The primary hazard of this ma terial is the flammability of the carrier. It has a flash point below 100 deg. F. it can cause illness by inhalation, skin absorption and or inges tion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain ftow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wear self-contained breathing apparatus when fighting fires involv ing this material BENZOIC DERIVATIVE PESTICIDE. SOLID. N.O.S. 4921611 (COMPOUNDS AND PREPARATION (AGRICULTURAL INSECTICIDES. NEC. OTHER THAN LIQUID) POISON B UN2769 Benzoic derivative pesticide is a solid or a liquid absorbed on a dry carrier. It is a wettable powder. It is toxic by inhalation, skin absorption. and'Or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800- 424-9300. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use `'alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective eauipment Wash away any material which may have contacted the body with copious amounts of water or soaD and water Wfear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full orotective clothing BENZOIC DERIVATIVE PESTICIDE. SOLID, N.O.S. 4921610 (COMPOUNDS AND PREPARATION (INSECTICIDES. NEC. OTHER THAN AGRICULTURAL) POISON B UN2769 Benzoic derivative pesticide is a solid or a liquid absorbed on a dry carrier. It is a wettable powder. It is toxic by inhalation, skin absorption, and or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safetv team network. Telephone: 800- 424-9300 If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use "alcohol ' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing BENZOIC DERIVITIVE PESTICIDE.LIQUID, N.O.S. 4921608 (COUMPOUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AGRICULTURAL, NEC) POISON B UN2769 Benzoic derivative pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The carrier may burn though it may require some effort to ignite. It is toxic by inhalation, skin ab sorption, and'or ingestion. In case of damage to. or leaking from con tainers of this material contact the pesticide safety team network. Tele phone: 800-424-9300. If material on fire or Involved In fire Do not extinguish fire unless ftow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical 64 April 1981 00 e.99l If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the matenal Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water BENZOL FORERUNNINGS. CRUDE, NOT BENZOL 4910204 (FLAMMABLE LIQUID, N.O.S.) FLAMMABLE LIQUID UN1993 Benzol forerunnings, crude, not benzol are clear colorless liquids with a petroleum like odor. They have a flash point of less than 100 deg. F. They are lighter than water and insoluble in water. Their vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water BENZONITRILE 4913134 COMBUSTIBLE LIQUID UN2224 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Benzonitrile is a clear colorless liquid having an almond-like odor. It is used as a specialty solvent, and to make other chemicals. It has a flash point of 161 deg. F. It is heavier than water and slightly soluble in water. It weighs 8.4 pounds per gallon. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid April 1981 Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the matenal Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with caustic soda or soda ash Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom Add caustic soda If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immoDilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Combustion products include corrosive or toxic vapors BENZOYL CHLORIDE 4931725 CORROSIVE MATERIAL, ACIDIC, COMBUSTIBLE UN1736 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Benzoyl chloride is a colorless fuming liquid having a pungent odor. It is used in medicine, and in the manufacture of other chemicals. It is combustible and has a flash point of 162 deg. F. Its fumes are irritating to the eyes and mucous membranes. It is decomposed by water to hydrochloric acid and water insoluble benzoic acid with release of heat. It is corrosive to metals and tissue. It weighs 10.2 pounds per gallon. If material on fire or involved in fire Use dry chemical or carbon dioxide Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Continued on next page 65 On1 eg9. Environmental considerations--land spiii Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (staked lime), crushed limestone, or sodium bicarbonate If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spilt Apply water spray or mist to knock down vapors BENZOYL PEROXIDE (BENZOYL PEROXIDE 4919115 CRYSTALS, GRANULES OR POWDERS. WET WITH NOT LESS THAN 30% WATER) ORGANIC PEROXIDE NA2085 Benzoyl peroxide is a white granular solid, tt is easily ignited and burns very rapidly. It strongly supports the burning of combustible ma terials. Contact with many materials may result in ignition Under pro longed exposure to fire or heat, containers of the peroxide can explode. As the peroxide dries out it becomes more susceptible to ignition and decomposition. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use ''alcohol'' foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material if contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet BENZOYL PEROXIDE (BENZOYL PEROXIDE.ORY OR 4919110 WET WITH LESS THAN 30% WATER) ORGANIC PEROXIDE NA2085 Benzoyl peroxide is a white granular solid. It is easily ignited and burns very rapidly. It strongly supports the burning of combustible ma terials. Contact with many materials may result in ignition. Under pro longed exposure to fire or heat containers of the peroxide can explode. As the peroxide dries out it becomes more susceptible to ignition and decomposition. 66 If material on fire or involved In fire Burns with explosive violence, if it becomes ignited, it cannot b< extinguished Use water in flooding quantities as fog Solid streams of water may De ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on tire or involved in fire evacuate for a radius of 2500 feet BENZOYL PEROXIDE. (MORE THAN 77% BUT LESS 4919118 THAN 95% WITH WATER) ORGANIC PEROXIDE UN2086 Benzoyl peroxide, (more than 77% but less than 95% with wateri is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and burns with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combustible materials, it supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. if material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on tire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet April 1981 TACt' 69^ BENZOYL PEROXIDE. (NOT LESS THAN 30% BUT 4919117 NOT MORE 52% WITH INERT SOLID) ORGANIC PEROXIDE UN2099 Benzoyl peroxide, (not less than 30% but not more 52% with inert solid) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and burns with increas ing rapidity as the tire progresses. It can form explosive mixtures with finely divided combustible materials. It supports the burning of combus tible materials. Under prolonged exposure to tire or heat containers of the material may explode, if material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled materia! wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation tf the material is on fire or involved in fire evacuate for a radius of 2500 feet BENZOYL PEROXIDE, (NOT MORE THAN 72% AS A 4919116 PASTE) ORGANIC PEROXIDE UN2087 Benzoyl peroxide, (not more than 72% as a paste) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and burns with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combus tible materials. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet BENZOYL PEROXIDE, (NOT MORE THAN 77% WITH 4919114 WATER) ORGANIC PEROXIDE UN2090 Benzoyl peroxide, (not more than 77% with water) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and burns with Increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combus tible materials. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "aicohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet BENZOYL PEROXIDE, (TECHNICALLY PURE OR) 4919113 BENZOYL PEROXIDE, (MORE THAN 52% WITH INERT SOLID) ORGANIC PEROXIDE UN2085 Benzoyl peroxide, (technically pure or) benzoyl peroxide, (more than 52% with inert solid) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and burns with increasing rapidity as the fire progresses. It can form explosive mixtures with fineiy divided combustible materials. It supports the burning of combustible materials. Under prolonged exposure to fire or heat con tainers of the material may explode, tf material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive Continued on next page MOD 000016994 67 If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on tire or involved in fire evacuate for a radius of 2500 feet BENZYL BROMIDE (BROMOTOLUENE, ALPHA) 4936010 CORROSIVE MATERIAL. POISONOUS UN1737 Benzyl bromide is a colorless liquid with an agreeable odor. It is toxic by inhalation and by skin absorption. It is slightly soluble m water and is heavier than water. It is corrosive to metals and tissue. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the matenal anticipated, wear full protective clothing BENZYL CHLORIDE 4936012 CORROSIVE MATERIAL, POISONOUS. COMBUSTIBLE UN1738 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Benzyl chloride is a colorless liquid with an irritating odor. It is toxic by inhalation and skin absorption. It is combustible and has a flash point of 153 deg. F. It is slightly soluble in water. It is corrosive to metals and tissue. It weighs 9.2 pounds per gallon. If material on fire or involved In fire Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical if material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Apply "'universal" gelling agent to immobilize spill Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom Remove trapped material with suction hoses If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment BENZYL CHLOROFORMATE 4933010 CORROSIVE MATERIAL. ACIDIC, POISONOUS UNI 739 Benzyl chloroformate is a colorless liquid with an acrid odor. It is decomposed by water to give hydrochloric acid with evolution of heat. Its vapors are irritating to eyes and mucous membranes. It is corrosive to metals and tissue. If material on fire or involved in fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing BERYLLIUM CHLORIDE 4923305 POISON B UN1566 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Beryllium chloride is a white to yellow crystalline mass. It absorbs water from the air and dissolves in it. it is toxic by ingestion. 68 April 1981 ttCD '>000 1 6&9f=> if material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet 10 prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates BERYLLIUM COMPOUND, N.O.S. 4923216 POISON B UN1566 Beryllium compounds, n.o.s. are generally white crystalline or pow dered material containing beryllium. They are generally soluble in water. They are toxic by inhalation and by ingestion. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Matenal itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep matenal out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material BERYLLIUM FLUORIDE 4923310 POISON B NA1566 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Beryllium fluoride is a colorless crystalline mass. It is soluble in water. It is toxic by ingestion. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not Involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind April 1981 Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates BERYLLIUM HYDROXIDE (BERYLLIUM COMPOUND, 4923315 N.O.S.) POISON B UN1566 Beryllium hydroxide is a white powder. It is insoluble in water. It is toxic by inhalation (dust, etc.) and by ingestion. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing BERYLLIUM NITRATE OXIDIZER 4918759 UN2464 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Beryllium nitrate is a white to pale yellow crystalline solid. It is used in chemical analysis. It is soluble in water. It is noncombustible, but it will accelerate the burning of combustible materials. If large quantities of the material are involved or the material is finely divided, an explosion may result. Prolonged exposure to lire or heat may result in an explosion. Toxic oxides of nitrogen are produced in fires involving this material. If material involved In fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved in fire Keep material out of water sources and sewers Personnel protection Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Continued on next page 69 mcd 00016qq6 Environmental considerations---water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates BERYLLIUM PHOSPHATE (BERYLLIUM COMPOUND. 4923325 N.O.S.) POISON B UNI566 Beryllium phosphate is a white crystalline powder. It is insoluble in water. It is toxic by inhalation (dust, etc.) and by ingestion. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective eauipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing BERYLLIUM SULFATE (BERYLLIUM COMPOUND. 4923330 N.O.S.) POISON B UNI566 Beryllium sulfate is a colorless crystalline solid. It is soluble in water. It is toxic by ingestion. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not Involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing BETA-PROPIOLACTONE (COMBUSTIBLE LIQUID, 4913110 N.O.S.) COMBUSTIBLE LIQUID NA1993 Beta-propiolactone is a clear colorless liquid with a pungent odor. II has a flash point of 167 deg. F. It is heavier than water and soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective 70 Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water BIPHENYL (DIPHENYL) (COMBUSTIBLE LIQUID. 4913108 N.O.S.) COMBUSTIBLE LIQUID NA1993 Biphenyl is a clear colorless liquid with a pleasant odor. It is used to manufacture other chemicals and as a fungicide. It has a flash point of 180 deg.f. and is insoluble in water. Its vapors are heavier than air If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water BIPYRIDILIUM PESTICIDE, LIQUID, N.O.S. 4910521 (COMPOUNDS ANO PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL. NEC) FLAMMABLE LIQUID UN27B2 Bipyridilium pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The primary hazard of this material is the flammability of the carrier, it has a flash point below 100 deg. F. It can cause illness by inhalation, skin absorption and or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors April 1981 mcd nooo >9 97 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective eauipment Wear self-contained breathing apparatus when fighting fires involv ing this material BIPYRIOILIUM PESTICIDE. LIQUID, N.O.S. 4910522 (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES. NEC, LIQUID) FLAMMABLE LIQUID UN2782 Bipyridilium pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The primary hazard of this material is the flammability of the carrier. It has a flash point below 100 deg. F. It can cause illness by inhalation, skin absorption and or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300 If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities ol water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out ol water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wear self-contained breathing apparatus when fighting fires involv ing this material BIPYRIOILIUM PESTICIDE. SOLID. N.O.S. 4921618 (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES. NEC, OTHER THAN LIQUID) POISON B UN2781 Bipyridilium pesticide is a solid or a liquid absorbed on a dry carrier. It is a wettabte powder. It is toxic by inhalation, skin absorption, and or ingestion. In case ot damage to. or leaking from containers of this ma terial contact the pesticide safety team network. Telephone: 800-424- 9300. It material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenai which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing April 1981 BIPYRIDILIUM PESTICIDE. SOLID. N.O.S. (COMPOUNDS AND PREPARATIONS) 4921617 (INSECTICIDES. OTHER THAN AGRICULTURAL, NEC) POISON B UN2781 Bipyridilium pesticide is a solid or a liquid absorbed on a dry earner. The carrier is water emulsifiable. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone: 800424-9300. tf material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as tog Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soao and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing BIPYRIDILIUM PESTICIDE,LIQUID, N.O.S. 4921616 (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC, LIQUID) POISON B UN2781 Bipyridilium pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The carrier may burn though it may require some effort to ignite. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800- 424-9300. tf material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use wafer in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 71 Mod 00001699a BIPYRIDILIUM PESTICIDE.LIQUID. N.O.S. 4921615 (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL, NEC) POISON B UN2781 Bipyridilium pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The carrier may burn though it may require some effort to ignite. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800- 424-9300. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool alt affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with (he material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water BLACK POWDER 4901710 CLASS A EXPLOSIVE Black powder is a black granular solid consisting of charcoal potas sium nitrate and sulfur. It is easily ignited and once ignited burns very rapidly. Under prolonged exposure to fire or heat containers of the ma terial can explode. If material on fire or Involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep spilled material wet Wet spilled material before picking it up Do not attempt to sweep up dry material Personnel protection Avoid breathing dusts, and fumes from burning material Wear protective gloves and safety glasses Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet BLACK POWDER IGNITER WITH EMPTY CARTRIDGE 4903110 BAG CLASS C EXPLOSIVE Black powder igniter with empty cartridge bag consists of empty car tridge bags with an igniter composed of black powder attached to it. If material on fire or involved in fire Dangerously explosive Flood with water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet BLASTING AGENT. N.O.S. 4902915 BLASTING AGENT Blasting agent. N.O.S. is the proper shipping name for those materials used for blasting that can not be detonated with an electric blasting cap. and will not explode when subject to friction, or impact: or when the largest single package is subject to fire. However if large quantities of this material are involved in a tire, it may explode. If material on fire or involved in fire Low order explosive potential Do not fight fires in a cargo of blasting agents Evacuate area and let burn If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep spilled material wet Wet spilled material before picking it up Do not attempt to sweep up dry material Personnel Protection Avoid breathing dusts, and fumes from burning material Wear protective gloves and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet BOILER COMPOUNDS, LIQUID 4936505 CORROSIVE MATERIAL NA1760 Boiler compounds, liquid are various colored liquids. They are water soluble and are corrosive to metals and/or tissue. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical Continued on next page 72 April 1981 WCD o J00169QQ If material not involved in fire Keep material out o< water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing BOND BREAKING COMPOUND, CONSISTING OF 4915144 NAPHTHA PETROLEUM RESINS AND VEGETABLE OIL (COMBUSTIBLE LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Bond breaking compound is a various colored liquid. It has a flash point between 100 and 200 deg. F. It is fighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water BOND BREAKING COMPOUND, CONSISTING OF 4910145 NAPHTHA, PETROLEUM RESINS AND VEGETABLE OILS (FLAMMABLE LIQUID. N.O.S.) FLAMMABLE LIQUID UNI 993 Bond breaking compound is a various colored liquid. It has a flash point of less than 100 deg. F. It is lighter then water and insoluble in water. Itsvapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary April 1981 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water BOOSTER (EXPLOSIVE) (COMMERCIAL) 4901310 CLASS A EXPLOSIVE Booster (explosive) consists of a casing containing a high explosive. It is used to intensify the explosion of a detonator If material on fire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on lire and not Involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation tf the material is on fire or involved in fire evacuate for a radius of 5000 feet BOOSTER. (EXPLOSIVE)(MILITARY) 4901215 CLASS A EXPLOSIVE Booster (explosive) consists of a casing containing a high explosive, tt is used to intensify the explosion of a detonator or detonating fuze. If the casing is metal the booster will explode under fire conditions. If the casing is nonmetallic the the booster may or may not explode under fire conditions. H material on fire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet BORDEAU ARSENITE, LIQUID 4923420 POISON 8 NA2759 Bordeau arsenite. liquid is arsenic and copper compounds. They are dark in color and are used as an insecticide. They are toxic by ingestion and inhalation. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved In fire Keep material out of water sources and sewers Continued on next page 73 I) 0OOi7 OQo Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the materia! Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing BORDEAUX ARSENITE, SOLID 4923415 POISON B NA2759 Bordeaux arsenite. solid is an arsenic and copper compound. It is a black crystalline solid, and is used as an insecticide. It is toxic by inges tion and by inhalation (dusts, etc). It is generally soluble in water. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources ano sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when lighting fires involv ing this material If contact with the material anticipated, wear full protective clothing BORON TRIBROMIDE 4932010 CORROSIVE MATERIAL, ACIDIC. POISONOUS UN2692 Boron tribromide is a colorless, fuming liquid with a pungent odor. Its fumes are irritating to the eyes and mucous membranes. It is decom posed by water to hydrobromic and bone acids with release of heat. It is corrosive to metals and tissue. If material Involved in fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing 74 Hen f BORON TRICHLORIDE CORROSIVE MATERIAL. POISONOUS. ACIDIC 4932011 UNI 741 Boron trichloride is a colorless fuming liquid with a pungeni odor. It is used as a catalyst in chemical manufacture, in soldering fluxes, and for many other uses, its fumes are irritating to the eyes and mucous membranes. It is decomposed by water to boric and hydrochloric acids with release of heat. It is corrosive to metals and tissue. II material involved in fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding 'quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broxen packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing BORON TRIFLUORIDE 4904110 NONFLAMMABLE GAS. POISONOUS UNI 008 Boron trifluoride is a colorless gas with a pungent odor. It is toxic by inhalation. It is soluble in water and slowly hydrolyzed by cold water to give hydrofluoric acid, a corrosive material. Its vapors are heavier than air. It may only be shipped m cylinders. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers wiih flooding quantities of water Apply water from as far a distance as possible Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and tog Use water spray to absorb vapors If material not involved in fire Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Do not use water on material itself Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on tire), downwind evacuation must be considered April 1981 ?0Qi BORON TRIFLUORIDE-ACETIC ACID COMPLEX 4930202 CORROSIVE MATERIAL. ACIDIC UN1742 Boron trifluoride-acetic acid complex is a colorless liquid with a pen etrating odor. It is soluble in water. It is corrosive to metals and tissue. If material on fire or involved in fire Do not use water on material itself Use ' alcohol' foam, carbon dioxide or dry chemical Cooi all affected containers with Hooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved in fire Keep material out ot water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash. or iime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing BOX TOE GUM 4910109 FLAMMABLE LIQUID UN2059 Box toe gum is the solution of a gum in a flammable solvent. It has a flash point of less than 100 deg. F. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical If material not on lire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers 8uild dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water BOX TOE GUM 4915109 COMBUSTIBLE LIQUID UN2060 Box toe gum is the solution of a gum in a flammable solvent. It has a flash point between 100 and 199 deg. F. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use ' alcohol' foam, carbon dioxide or dry chemical April 1981 If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water BRAKE OR SHOCK ABSORBER FLUID OR 4915543 HYDRAULIC SYSTEM FLUID OTHER THAN PETROLEUM (COMBUSTIBLE LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Brake or shock absorber fluid or hydraulic system fluid other than petroleum is a various colored liquid. It has a flash point of between 100 and 200 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool afl affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical ff material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep materia! out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keeo upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water BRANDY. ALCOHOLIC (ALCOHOLIC BEVERAGE) 4910107 FLAMMABLE LIQUID UN1170 Brandy, alcoholic is clear colorless to variable colored liquid with a charactetistic odor. It has a flash point of less than 100 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can Oe stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid MCD 000017002 Continued on next page 75 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water BRANDY, ALCOHOLIC (ALCOHOLIC BEVERAGE) 4915107 COMBUSTIBLE LIQUID UN1170 Brandy, alcoholic is clear colorless to variable colored liquid with a characteristic odor. It has a flash point between 100 and 199 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on tire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water BROMBENZYL CYANIDE. LIQUID (IRRITATING 4925210 AGENT, N.O.S.) IRRITATING MATERIAL NA1693 Brombenzyl cyanide is a pale yellow crystalline solid melting at 77 deg. F. to a brown oily liquid. The vapors are extremely irritating to the eyes and mucous membranes. Exposure to high concentrations may be fatal. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing BROMINE 493611C* CORROSIVE MATERIAL. POISONOUS, OXIDIZING UN1744 Bromine is a reddish brown fuming liquid with a pungent odor. Its vapors are irritating to the eyes and mucous membranes. It is toxic by inhalation. It is heavier than water and slightly soluble in water, it ac celerates the burning of combustible material. It is corrosive to metals and tissue. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as tog Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use water spray to absorb vapors If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire) evacuate for a radius of 2500 feet BROMINE PENTAFLUORIDE 4918505 OXIDIZER, CORROSIVE UN1745 Bromine pentafluoride is a colorless fuming liquid with a pungent odor, it is use to make other chemicals and in rockets, ft is decomposed by water to hydrofluoric acid and other materials with release of heat. Its vapors are irritating to the eyes and mucous membranes. It is corrosive to metals and tissue. It will accelerate the burning of combustible ma terial. It may only be shipped in cylinders without any safety relief device. If cylinders are involved in fire they may violently rupture and rocket. If material involved in fire Do not use water on material itself Use dry chemical or carbon dioxide Cool all affected containers with flooding quantities of water If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If material not involved in fire Do not use water on material itself Keep material out of water sources and sewers Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation if fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must br considered 76 MOD { :>0O017003 April 19B1 BROMINE TRIFLUORIDE 4918SD7 OXIDIZER, CORROSIVE UN1746 Bromine trifluoride is a colorless to yellow fuming liquid with a pungent odor. It solidifies at 48 deg. F. It is decomposed by water to hydrofluoric acid and other materials with release of heat. It is corrosive to metals and tissue. It will accelerate the burning of combustible material. It may only be shipped in cylinder without any safety relief device. If the cyl inders are involved in fire they may violently rupture and rocket. If material involved In fire Do not use water on material itself Use dry chemical or carbon dioxide Cool all affected containers with flooding quantities of water If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors tf material not involved in fire Do not use water on material itself Keep material out of water sources and sewers Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts ot water or soap and water Evacuation II tire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered BROMOACETIC ACID SOLUTION 4931411 CORROSIVE MATERIAL, ACIDIC UN1938 Bromoacetic acid solution is the colorless crystalline material dis solved in water. It is corrosive to metals and tissue. If material on fire or involved in fire Extinguish fire using agent suitable for lype of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with Hooding quantities of water Apply water from as far a distance as possible II material not on fire and not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when lighting fires involv ing this material If contact with the material anticipated, wear full protective clothing BROMOACETIC ACID, SOLID 4931410 CORROSIVE MATERIAL UN1938 Bromoacetic acid, solid is a colorless crystalline material. It absorbs moisture trom the air and forms a syrup. It is soluble in water. It is corrosive to metals and tissue. April 1961 If material on fire or involved in fire Use water in Hooding quantities as log Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing BROMOACETONE, LIQUID 4920101 POISON A, FLAMMABLE UN1569 Bromoacetone is a clear colorless litjuid turning violet in the absence of air and further decomoosing to a black resinous mass on long stand ing. In low concentrations it is very irritating to the eyes and in higher concentrations or prolonged exposure to low concentration it is toxic by inhalation. Contact with the liquid wilt cause very painful burns. The material may only be shipped in cylinders or bottles or cans packed in wooden boxes. The material will burn. Prolonged exposure of the cyl inders to heat or fire may result in the violent rupturing and rocketing ot the cylinders. If material on fire or involved in fire Do not extinguish lire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out ot water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear lull protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered BROMOBENZENE 4913112 COMBUSTIBLE LIQUID UN2514 Bromobenzene is a clear colorless liquid with a pleasant odor. It has a flash point of 124 deg. F. It is heavier than water and insoluble in water. Its vapors are heavier than air. Continued on next page MOD 000017004 77 If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of waier sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting tires involv ing this material BRUCINE, SOLID (DIMETHYL STRYCHNINE) 4921411 POISON B UNI 570 Brucine, solid is a white crystalline solid. It is very slightly soluble in water. It Is combustible though It may require some effort to ignite. It is toxic by inhalation (vapor, dust, etc.) If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding lire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide ar dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing vapors or dusts Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water BURSTER (EXPLOSIVE) 4901220 CLASS A EXPLOSIVE Burster (explosive) consists of a casing containing a high explosive. It is used to rupture a bomb or projectile to release the contents. Under fire conditions they wili explode If material on fire or involved in fire Dangerously explosive Do not tight fires in a cargo of explosives Evacuate area and let burn if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet BUTADIENE. INHIBITED (BUTADIENE FROM 4905705 ALCOHOL) FLAMMABLE GAS UN1010 Butadiene, inhibited is a colorless gas with an aromatic odor, if is used to make synthetic rubber and plastics, and to make other chemicals. It is shipped as a liquefied gas under its vaoor pressure. Contact with the liquid can cause frostbite, it must be shipped inhibited as it is liable to polymerization. If polymerization were to take place in a cylinder or tank car. the cylinder or tank car may violently rupture. It is easily ignited. Its vapor is heavier than air and a ftame can flash back to the source of leak very easily. It can asphyxiate by the displacement of air. Under fire conditions the cylinders or tank cars may violently rupture and rockel If material on fire or involved in fire Do not extinguish fire unless flow can be slopped Use water in flooding quantities as fog Cooi ali affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective ecuipment Approach fire with caution Evacuation if fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet Jf material leaking |not on fire), downwind evacuation must be Cbnsidered BURNT COTTON. NOT REPICKED (COTTON. NEC, IN 4917304 BALES COMPRESSED) FLAMMABLE SOLID NA1325 Burnt cotton, not repicked is cotton fibre that has been on fire and the burned portion has not been removed. The hazard is that once coiton has been on fire, the fire may persist in the interior of the bale for a long time. The regulations require that burnt cotton be held for ten days after the last evidence of fire, before if is offered for transportation. If material on fire or involved in fire Flood with water If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away 78 MOD 000017005 BUTADIENE, INHIBITED (BUTADIENE FROM 4905704 PETROLEUM) FLAMMABLE GAS UN1010 Butadiene, inhibited is a colorless gas with an aromatic odor. It is used to make synthetic rubber and plastics, and to make other chemicals. It is shipped as a liquefied gas under its vapor pressure. Contact with the liquid can cause frostbite. It must be shipped inhibited as Dutadiene is liable to polymerization. If polymerization occurs in a cylinder or tank car, the cylinder or tank car may violently rupture. It is easily ignited. Its vapors are heavier than air and a flame can flash back to the source of leak very easily. It can asphyxiate by the displacement of air. Under fire conditions the cylinders or tank cars may violently rupture and rocket. April 1981 If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If matenal leaking (not on fire), downwind evacuation must be considered If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach tire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered BUTADIENE. INHIBITED (BUTADIENE, IMPURE. FOR 4905703 FURTHER REFINING) FLAMMABLE GAS UN1010 Butadiene, inhibited is a colorless gas with an aromatic odor. It is shipped as a liquefied gas under its vapor pressure. Contact with the liquid can cause frostbite. It must be shipped inhibited as butadiene is liable to polymerization. If polymerization were to take place in a cylinder or tank car. the cylinder or tank car may violently rupture, it is easily ignited, its vapor is heavier than air and a flame can flash back to the source of leak very easily. It can asphyxiate by the displacement of air. Under fire conditions the cylinders or tank cars may violently rupture and rocket. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with Hooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2600 feet If material leaking (not on fire), downwind evacuation must be considered BUTANE (BUTANE. IMPURE. FOR FURTHER 4905702 REFINING) FLAMMABLE GAS UNI 075 Butane is a colorless gas with a faint petroleum like odor. It is shipped as a liquefied gas under its vapor pressure. Contact with the liquid can cause frostbite. It is easily ignited. Its vapors are heavier than air and a flame can flash back to the source of leak very easily. The leak can be either a liquid or vapor leak. Under fire conditions the cylinders or tank cars may violently rupture and rocket. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered BUTANE FLAMMABLE GAS 4905706 UN1075 Butane is a colorless gas with a faint petroleum like odor. It is used as a fuel, an aerosol propellant, in cigarette lighters, and to make other chemicals. For transportation it may be stenched. It is shipped as a liquefied gas under its vapor pressure. Contact with the liquid can cause frostbite. It is easily ignited. Its vapors are heavier than air and a flame can flash back to the source of leak very easily. The leak can be either a liquid or vapor leak. Under fire conditions the cylinders or tank cars may violently rupture and rocket. April 1981 2-BUTANOL (BUTYL ALCOHOL) 4909129 FLAMMABLE LIQUID NA1120 2-butanol is a clear, colorless liquid with a pleasant odor. It is used to make other chemicals and as a solvent. It has a flash point of 75 deg. F. It is lighter than water and soluble in water, its vapors are heavier than air. Continued on next peg* 79 MOD 000017008 If material on fire or involved in fire Do not extinguish tire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain How as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools ol liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of wafer or soap and water BUTENE GAS. LIQUEFIED (LIQUEFIED PETROLEUM 4905707 GAS) FLAMMABLE GAS UN1075 Butene gas, liquefied is colorless gas with a faint petroleum like odor. For transportation It may be stenched. It is shipped as a liquefied gas under its own vapor pressure. Contact with the fiQuid can cause frostbite. It is easily ignited, its vapor is heavier than air. and a flame can flash back to the source of the leak very easily. The leak can either be a liquid or vapor leak, it can asphyxiate by the displacement of air. Under fire conditions the cylinders or tank cars may violently rupture and rocket. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as tar a distance as possible if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking <noi on fire), downwind evacuation must be considered BUTYL ACETATE 4909128 FLAMMABLE LIQUID UN1123 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-SOOO/2270) Butyl acetate is a clear, colorless liquid with a fruity odor. It has a flash point in the range of 72 deg. F. to 88 deg. F. It is lighter than water and very slightly soluble in water, its vapors are heavier than air. It weighs 7.4 pounds per gallon. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts ot water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Apply fluorocarbon-water foam to diminish vapor and tire hazard Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent <e.g. detergent, soaps, alcohols) to com press and thicken spilled material Inject "universal'' gelling agent to solidify encircled spill and increase effectiveness of booms If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove .trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors N-BUTYL ACID PHOSPHATE 4933315 CORROSIVE MATERIAL. ACIDIC UN1718 N-butyl acid phosphate is a colorless liquid, tt is insoluble in water. It is corrosive to metals and tissue. If material on fire or involved in fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities ot water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing 80 Nr*7) Or, 'On On April 1981 BUTYL ACRYLATE (COMBUSTIBLE LIQUID, N.O.S.) 4912215 COMBUSTIBILE LIQUID NA1993 Butyl acrylate is a clear colorless liquid. It is used to make paints and plastics. It has a Hash point of 120 deg.l. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain How as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gioves. and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet N-BUTYL ALCOHOL (BUTYL ALCOHOL) 4909117 FLAMMABLE LIQUID NA1120 N-butyl alcohol is a clear colorless liquid. It is used to make other chemicals. It has a flash point of 95 deg. F. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use '`alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in Hooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as tar a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water BUTYL BROMIDE (NORMAL) 4909127 FLAMMABLE LIQUID UN1126 Butyl bromide (normal) is a clear colorless liquid. It has a flash point of 65 deg. F. It is heavier than water and insoluble in water. Its vapors are heavier than air. if material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cod all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain How as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material TERT-BUTYL ALCOHOL (BUTYL ALCOHOL) 4909130 FLAMMABLE LIQUID NA1120 Tert-butyl alcohol is a clear, colorless liquid with a camphor like odor. It has a flash point of 52 deg. F. and a melting point of 77 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. April 1981 BUTYL CHLORIDE 4908115 FLAMMABLE LIQUID UN1127 Butyl chloride is a clear colorless liquid. It has a flash point of 1 5 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. Continued on next page 81 OOr>Ol ?0$ M material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as tar a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak it without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered BUTYL ETHER 49091? FLAMMABLE LIQUID UN114. Butyl ether is a clear colorless with an ethereal odor. It has a flash point of 77 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water m flooding quantities as fog Solid streams of water may spread fire Cool all affected cotainers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire end not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water TERT-BUTYL CUMYL PEROXIDE. (TECHNICALLY 4919135 PURE OR) TERT-BUTYL CUMENE PEROXIDE, (TECHNICALLY PURE) ORGANIC PEROXIDE UN2091 Tert-butyl cumy! peroxide, (technically pure or) tert-butyl cumene per oxide. (technically pure) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning o* combustible materials. Un der prolonged exposure to fire or heat containers of the material may explode. If material on fire or Involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the materia! Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet 82 BUTYL FORMATE 4909126 FLAMMABLE LIQUID UN1128 Butyl formate is a clear colorless liquid. It has a flash point of 77 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. if material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical tf material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water TERT-BUTYL HYDROPEROXIDE. (MORE THAN 72% 4919136 BUT NOT MORE THAN 90% WITH WATER) ORGANIC PEROXIDE UN2094 Tert-butyl hydroperoxide, (more than 72% but not more than 90% with water) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is soluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible ma terials. spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of combustible materials. Under prolonged ex posure to fire or heat containers of the material may explode. April 1981 If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol'' foam, caroon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gioves. and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved m fire evacuate tor a radius of 2500 feet TERT-BUTYL HYDROPEROXIDE, (NOT MORE THAN 4919137 72% WITH WATER) ORGANIC PEROXIDE UN2093 Tert-butyi hydroperoxide, (not more than 72% with water) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is soluble in water. The liquid or solution may require some effort to ignite; but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burn ing of combustible materials Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet April 1981 TERT-BUTYL HYDROPEROXIDE. (NOT MORE THAN 4919138 80% IN DI-TERT-BUTYL PEROXIDE AND SOLVENT) ORGANIC PEROXIDE UN2092 Tert-butyl hydroperoxide, (not more than 80% in di-tert-butyl peroxide and solvent) is a colorless to pale yeliow liquid. It is used to manufacture paints, plastics, and rubber. It is soluble in water. The liquid or solution may require some effort to ignite; Out once ignited, it will Durn with increasing rapidity as the tire progresses. H spilled on comoustible ma terials. spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of combustible materials. Under prolonged ex posure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool alt affected containers with Hooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet N-BUTYL ISOCYANATE 4907415 FLAMMABLE LIQUID, POISONOUS UN2485 N-butyl isocyanate is a clear colorless liquid. It has a flash point of 70 deg. F- In low concentrations its vapors are irritating to the eyes and mucous membranes. In higher concentrations it is toxic by inhalation. It is lighter than water and insoluble in water. It is very slowly decom posed by water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use ''alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Continued on next page ^rT; >o0n 83 Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the matenal anticipated, wear full protective clothing Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any malarial which may have contacted the body with copious amounts of water or soap and water TERT-BUTYL ISOPROPYL BENZENE 4919590 HYDROPEROXIDE ORGANIC PEROXIDE NA2091 Tertiary butyl isopropyl benzene hydroperoxide is a white crystalline solid. It must be shipped as a solution in a non-volatile solvent of not more than 60% concentration. At times this may appear as a slurry or sludge of white crystals. The solution may take some effort to ignite but once ignited, it burns with increasing rapidity as the fire progresses. The dried material is more easily ignited. Contamination of the solution with many chemicals can cause a violent chemical reaction. The material supports the burning of combustible material. Under prolonged exposure to heat or tire containers of the material can explode. If material on fire or involved In fire Use water In flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use ''alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this matenal If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the matenal is on fire or involved in fire evacuate for a radius of 2500 feet BUTYL LACTATE (COMBUSTIBLE LIQUID, N.O.S.) 4913131 COMBUSTIBLE LIQUID NA1993 Butyl lactate is a clear colorless liquid with a mild odor. It is used as a solvent, and in the making of other chemicals. It has a flash point of 168 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. 84 BUTYL MERCAPTAN 4909133 FLAMMABLE LIQUID UN2347 Butyl mercaptan is a clear, colorless liquid with a strong skunk-like odor. It has a Hash point in the range of -15 deg. F. to 35 deg. F. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material TERT-BUTYL PEROXY-2-ETHYLHEXANOATE, (NOT 4919142 MORE THAN 30%) WITH 2,2-DI-{TERTBUTYLPEROXY) BUTANE. (NOT MORE THAN 35% WITH NOT LESS THAN 35% PHLEGMATIZER) ORGANIC PEROXIDE UN2886 Tert-butyl peroxy-2-ethylhexanoate, (not more than 30%) with 2.2-di- (tert-butylperoxy) butane, (not more than 35% with not less than 35% phlegmatizer) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and burns with increasing rapidity as the fire progresses, it can form explosive mixtures with finely divided combustible materials. It supports the burning of com bustible materials. Under prolonged exposure to fire or heat containers of the material may explode. The phlegmatizer is a material added to make the peroxide less reacitive. April 1961 HCX) 0000317011 If material on fire or involved In fire Use water in flooding Quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full profective clothing Approach fire with caution Evacuation If the material is on fire or involved m fire evacuate for a radius of 2500 feet TERT-BUTYL PEROXY-2-ETHYLHEXANOATE, (NOT 4919144 MORE THAN 50% WITH PHLEGMATIZER) ORGANIC PEROXIDE UN288B Ten-butyl peroxy-2-ethyihexanoate. (not more than 50% wiih phleg- matizer) is a colorless to pale yellow liauid. It is used to manufaclure paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort lo ignite: but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible ma terials. spontaneous ignition ot the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of combustible materials. Under prolonged ex posure to fire or heat containers of the material may explode The phieg- matizer is a material added to make the peroxide less reacitive. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantifies of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on lire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid brealhing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gioves. and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this matenal If contact with the material anticipated, wear full protective clothing Approach fire with caution April 1961 Evacuation If the matenal is on fire or involved in fire evacuate for a radius of 2500 feet TERT-BUTYL PEROXY-2-ETHYLHEXANOATE. 4919141 (TECHNICALLY PURE) ORGANIC PEROXIDE UN2143 Tert-butyl peroxy-2-ethylhexanoate. (technically pure) is a clear col orless liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of com bustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in Hooding quantities as fog Solid streams of waler may be ineffective Cool all affected containers with flooding quantifies of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled matenal wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the matenal is on fire or involved in fire evacuate for a radius of 2500 feet TERT-BUTYL PEROXY-2-ETHYLHEXANOATE, NOT 4919143 MORE 12%) WITH 2.2-DI-(TERT- BUTYLPEROXY)BUTANE. (NOT MORE THAN 14% WITH NOT LESS THAN 14% PHLEGMATIZER AND 60% INERT INORGANIC SOLID) ORGANIC PEROXIDE UN2887 Tert-butyl peroxy-2-ethylhexanoate. not more 12%) with 2.2-di-(tert- butylperoxy)butane. (not more than 14% with not less than 14% phleg- matizer and 60% inert inorganic solid) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite; but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the matenal may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of combustible materials. Un der prolonged exposure to fire or heat containers of the material may explode. The phlegmatizer is a material added to make the peroxide less reacitive. Continued on next pege r-icn OOQo 70 X 85 If material on fire or Involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use `'alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting tires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet 3-TERT-BUTYL PEROXY-3-PHENYLPHTHALIDE, 4919146 (TECHNICALLY PURE) ORGANIC PEROXIDE UN2S96 3-tert-butyl peroxy-3-phenylohthalide. (technically pure) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and burns with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combus tible materials. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the materia! may explode. If material on fire or involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on tire or involved in fire evacuate for a radius of 2500 feet TERT-BUTYL PEROXY-3.5.5-TRIMETHYLHEXANOATE 4919145 (OR) TERT-BUTYL PEROXYISONONANOATE. (TECHNICALLY PURE) ORGANIC PEROXIDE UN2104 Tert-butyl peroxy-3,5.5-trimethylhexanoate (or) ten-butyl peroxyiso- nonanoate. (technically pure) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and ruDber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of combustible materials Un der prolonged exposure to fire or heat containers of the material may explode. The phlegmatizer is a material added to make the peroxide less reacitive. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled matenal before picking it up Personnel protection Avoid breathing dusts, and fumes from burning matenal Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet TERT-BUTYL PEROXYACETATE, (NOT MORE THAN 4919147 52% IN SOLUTION) ORGANIC PEROXIDE UN2096 Tert-butyl peroxyacetate. (not more than 52% in solution) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burn ing of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up 86 April 1981 MCI> u u01701S Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the matenai anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet TERT-BUTYL PEROXYACETATE, (NOT MORE THAN 4919148 76% IN SOLUTION) ORGANIC PEROXIDE UN2095 Tert-butyl peroxyacetate. (not more than 76% in solution) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burn ing of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenai which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet TERT-BUTYL PEROXYBENZOATE (NOT MORE THAN 4919149 50% WITH INERT INORGANIC SOUD) ORGANIC PEROXIDE UN2690 Tert-butyl peroxybenzoate (not more than 50% with inert inorganic solid) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and burns with increas ing rapidity as the fire progresses, it can form explosive mixtures with finely divided combustible materials. It supports the burning of combus tible materials. Under prolonged exposure to fire or heat containers of the material may explode. April 1981 If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spiiled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when lighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet TERT-BUTYL PEROXYBENZOATE. (NOT MORE THAN 4919150 75% IN SOLUTION) ORGANIC PEROXIDE UN2098 Tert-butyl peroxybenzoate. (not more than 75% in solution) is a col orless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burn ing of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spiiled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on tire or involved in fire evacuate for a radius of 2500 feet MCI; (-00017014 87 TERT-BUTYL PEROXYBENZOATE. (TECHNICALLY 4919151 PURE OR) TERT-BUTYL PEROXYBENZOATE, (MORE THAN 75% IN SOLUTION) ORGANIC PEROXIDE UN2097 Tert-butyl peroxybenzoate. (technically pure or) tert-butyl peroxyben- zoate. (more than 75% in solution) is a colorless to pale yellow IiquiO. It is used to manufacture paints, plastics, and rubber. It is insoluble m water. The liquid or solution may require some effort to ignite: but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of combustible ma terials. Under prolonged exposure to fire or heat containers of the ma terial may explode. If material on fire or involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this matehal If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet TERT-BUTYL PEROXYCROTONATE, (NOT MORE 76% 4919152 IN SOLUTION) ORGANIC PEROXIDE UN2183 Tert-butyl peroxycrotonate. (not more 76% in solutioni is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burn ing of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or Involved in fire Use water in flooding quantities as log Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material 88 Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet N-BUTYL PEROXYDICARBONATE, (NOT MORE THAN 4919153 27% IN SOLUTION) ORGANIC PEROXIDE UN2170 N-butyl peroxydicarbonate. (not more than 27% in solution) is a col orless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burn ing of combustible materials. Under prolonged exposure to lire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear lull protective clothing Approach fire with caution Evacuation If the matehal is on fire or involved in fire evacuate for a radius of 2500 feet TERT-BUTYL PEROXYDIETHYLACETATE, 4919156 (TECHNICALLY PURE) ORGANIC PEROXIDE UN2144 Tert-butyl peroxydiethylacetate. (technically pure) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will bum with increasing rapidity as the lire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of com bustible materials. Under prolonged exposure to lire or heal containers of the material may explode. April 1981 MCuI COOo 1 ?Ol 5 ft material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled matenal wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet TERT-BUTYL PEROXYDIETHYLACETATE, (33% WITH) 4919155 TERT-BUTYL PEROXYBENZOATE, (33%, AND SOLVENT) ORGANIC PEROXIDE UN2551 Tert-butyl peroxydiethylacetate. (33% with) tert-butyl peroxybenzoate. (33%. and solvent) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: Out once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning ol combustible materials. Un der prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may.be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol ' foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear seif-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet April 1981 TERT-BUTYL PEROXYISOBUTYRATE, (MORE THAN 4919157 52% BUT NOT MORE THAN 77% IN SOLUTION) ORGANIC PEROXIDE UN2142 Tert-butyl peroxyisobutyrate, (more than 52% but not more than 77% in solution) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible ma terials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of combustible materials. Under prolonged ex posure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet TERT-BUTYL PEROXYISOBUTYRATE. (NOT MORE 4919158 THAN 52% IN SOLUTION) ORGANIC PEROXIDE UN2562 Tert-butyl peroxyisobutyrate. (not more than 52% in solution) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burn ing of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. H material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as tar a distance as possible Use "'alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Continued on next page 89 Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodtiy contact with the material Wear boots, protective gloves, and goggies Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation It the material is on fire or involved in fire evacuate for a radius of 2500 feet TERT-BUTYL PEROXYISOPROPYL CARBONATE. 4919159 (TECHNICALLY PURE) ORGANIC PEROXIDE UN2103 Tert-butyl peroxyisopropyl carbonate, (technically pure) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite; but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burn ing of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. if material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenai which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the matenai anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet TERT-BUTYL PEROXYMALEATE, (NOT MORE THAN 4919161 55% AS A PASTE) ORGANIC PEROXIDE UN2101 Tert-butyl peroxymaleate. (not more than 55% as a paste) is a white solid. It is used to manufacture paints.plastics. and rubber. It is insoluble in water. It is easily ignited and burns with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combus tible materials. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. 90 If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water . Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerousiys36explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenai out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenai which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in lire evacuate for a radius of 2500 feet TERT-BUTYL PEROXYMALEATE, (NOT MORE THAN 4919160 55% IN SOLUTION) ORGANIC PEROXIDE UN2100 Tert-butyl peroxymaleate. (not moie than 55% in solution) is a col orless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction, tt supports the burn ing of combustible matenals. Under prolonged exposure to fire or heat containers of the material may explode. ff material on fire or Involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep matenai out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggies Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet April 1981 Her, OOo v'017 TERT-BUTYL PEROXYMALEATE, (TECHNICALLY 4919162 PURE) ORGANIC PEROXIDE UN2099 Tert-butyl peroxymaleate. (technically pure) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and burns with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combustible materials. It supports the burning of combustible materials. Under prolonged ex posure to fire or heat containers of the material may explode. If material on fire or involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol' foam, cartoon dioxide or dry chemical Dangerously explosive If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting (ires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet TERT-BUTYL PEROXYNEODECANOATE. (NOT MORE 4919163 THAN 77% IN SOLUTION) ORGANIC PEROXIDE UN2177 Tert-butyl peroxyneodecanoate, (not more than 77% in solution) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite; but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burn ing of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, cartoon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Dp not handle broken packages without protective equipment April 1981 Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet TERT-BUTYL PEROXYNEODECANOATE, 4919164 (TECHNICALLY PURE) ORGANIC PEROXIDE UN2594 Tert-butyl peroxyneodecanoate. (technically pure) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite; but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of com bustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet TERT-BUTYL PEROXYPHTHALATE, (TECHNICALLY 4919165 PURE) ORGANIC PEROXIDE UN2105 Tert-butyl peroxyphthalate. (technically pure) is a white solid. It is used to manufacture paints, plastics, and rubber, it is insoluble in water. It is easily ignited and bums with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combustible materials. It supports the burning of combustible materials. Under prolonged ex posure to fire or heat containers of the matenal may explode. Continued on next page 91 M( '00017 0.1 8 If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use '`alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved In tire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet BUTYL PHENOL (CORROSIVE SOLID, N.O.S.) 4935629 CORROSIVE MATERIAL. BASIC UNI 75! Butyl phenol is a white crystalline solid, it is used to make other chemicals. It is insoluble in water, it may bum though it may require some effort to ignite. It is corrosive to metals and tissue, if material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers B.:,d dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing TERT-BUTYL PEROXYPIVALATE, (NOT MORE THAN 4919166 77% IN SOLUTION) ORGANIC PEROXIDE UN2110 Tert-butyl peroxypivalate. (not more than 77% in solution) is a col orless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite; but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burn ing of combustible materials. Under prolonged exposure to tire or heat containers of the material may explode. ft material on fire or Involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet 92 BUTYL PHOSPHORIC ACID (SEE ACIO BUTYL PHOSPHATE 4933315) N-BUTYL PHTHLATE 4962110 ORM-E NA9095 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) SUBSTANCE (RQ-100/45.4) N-butyl phthalate is a colorless oily liquid. It is used in paints and plastics and as a reaction media for chemical reactions, it is insoluble in water. It is combustible though it may take some effort to ignite. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources ot ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors or dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder April 1981 Men 00l70j.9 Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e.g. detergent, soaps, alcohols) to com press and thicken spilled material Inject "universal" gelling agent to solidity encircled spill and increase effectiveness of booms Remove trapped material with suction hoses If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors BUTYL TRICHLOROSILANE 4934215 CORROSIVE MATERIAL, ACIDIC, COMBUSTIBLE UN1747 Butyl tnchlorosilane Is a colorless liquid with a pungent odor, it is used to make various silicon containing compounds. It is combustible and has a flash point of 126 deg. F. It is readily decomposed by moisture or water to hydrochloric acid with evolution of heat. It is corrosive to metals and tissue. If material on fire or involved in fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itseii Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing N-BUTYL-4,4-DI-(TERT-BUTYLPEROXY)VALERATE, 4919133 (NOT MORE THAN 52% WITH INERT SOLID) ORGANIC PEROXIDE UN2141 N-butyl-4.4-di-(tert-butylperoxy)valerate, (not more than 52% with inert solid) is a white solid, it is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and burns with increas ing rapidity as the tire progresses. It can form explosive mixtures with finely divided combustible materials. It supports the burning of combus tible materials. Under prolonged exposure to fire or heat containers of the material may explode. April 1961 If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet N BUTYL-4,4-DI-(TERT-BUTYLPEROXY)VALERATE, 4919134 (TECHNICALLY PURE) ORGANIC PEROXIDE UN2140 N-butyl-4.4-di-(tert-butylperoxy|valerate. (technically pure) is a col orless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will burn with increasing rapidity as the fire progresses, if spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction, it supports the burn ing of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or Involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol'' foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet 000017020 MCD 93 BUTYLAMINE 4908120 FLAMMABLE LIQUID UN1125 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/4S4) Butylamine is a clear colorless liquid with an ammonia-like odor. It has a flash point of 10 deg. F. It is lighter than water and soluDle in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material. It weighs 6.2 pounds per gallon. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use `alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop teak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Evacuation If fire becomes uncontrollable or container is exposed to direct flama--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash. cement powder, sawdust, or com mercial sorbents Apply fluorocarbon-water foam to diminish vapor and fire hazard Neutralize with sodium bisulfate (nahso4) Environmental considerations--water epill Add sodium bisulfate If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked tor containment TERT-BUTYLAMINE (BUTYLAMINE) 4909134 FLAMMABLE LIQUID UN1125 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Tert-butylamine is a clear, colorless liquid with an ammonia like odor. It has a flash point of 70 deg. F. it is lighter than water and soluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material. It weighs 6.2 pounds per gallon. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash. cement powder, sawdust, or com mercial sorbents Apply fluorocarbon-water foam to diminish vapor and fire hazard Neutralize with sodium bisulfate <nahso4) Environmental considerations--water spill Add sodium bisuifate If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors BUTYLENE, IMPURE, FOR FURTHER REFINING 4905711 (UQUEFIEO PETROLEUM GAS) FLAMMABLE GAS UN1075 Butylene is a colorless gas with a faint petroleum like odor. It is shipped as a liquefied gas under its vapor pressure. Contact with the liquid can cause frostbite. It is easily ignited. Its vapor is heavier than air and a flame can flash back to the source of leak very easily. The leak can either be a liquid or vapor leak. It can asphyxiate by the displacement of air. Under fire conditions the cylinder or lank car may violently rupture and rocket. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved In fire Keep sparks, fiames. and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors 94 MCd oon 17Ar_ April 1981 Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered BUTYRALDEHYDE 4908119 FLAMMABLE LIQUID UN1129 Butyraldehyde is a clear liquid with a pungent odor. It has a flash point of 10 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical H material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered BUTYRIC ACID 4931414 CORROSIVE MATERIAL, ACIDIC, COMBUSTIBLE UN2820 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Butyric acid is a colorless liquid with an odor of rancid butter. It is combustible and has a flash point of 161 deg. F. It is soluble in water. It is corrosive to metals and tissue. It weighs 8.0 pounds per gallon. If material on fire or Involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors April 1981 K material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agncultural lime (slaked lime), crushed limestone, or sodium bicarbonate If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment BUTYRONfTRILE (FLAMMABLE LIQUID, N.O.S.) 4909241 FLAMMABLE LIQUID UNI 993 Butyronitrile is a clear colorless liquid. It is used in the manufacture of other chemicals. It has a flash point of 76 deg. F. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire end not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain Mow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing 95 MOD 000017022 CADMIUM ACETATE 4962303 ORM-E NA2570 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Cadmium acetate is a coloriess crystallite solid, tt is used in ceramics and in chemical analysis. It is soluble in water. It is non-combustibie. If material Involved In fire Extinguish fire using agent suitable for type ot surrounding tire (Material itself does not burn or burns with difficulty.) If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Add ferric chloride (fecl3) Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CADMIUM BROMIDE 4962305 ORM-E NA2570 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Cadmium bromide is a white to yellow crystalline solid. It is used in photography, printing, and lithogrphy. It is soluble in water. It is non combustible. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Add ferric chloride (fecl3) Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or (ire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Add ferric chloride (fecl3) Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CALCIUM ARSENATE AND SULPHUR, DRY (CALCIUM 4923218 ARSENATE) POISON B UN1573 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Calcium or lead, arsenate and sulfur, dry is a yellow white to yellow powder. It is insoluble in water. It is toxic by inhalation (dust) and by ingestion. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Add ferric chloride (fecl3) Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses ot pollutants and precipitates CADMIUM CHLORIDE 4962505 ORM-E NA2570 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Cadmium chloride is a white crystalline solid. Cadmium chloride is used in photography, in fabric printing, in chemical analysis, and in many other uses. It is soluble in water. It is non-combustible. CALCIUM ARSENATE, SOLID 4923217 POISON B UN1573 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Calcium arsenate solid is a white powder. It is very slightly soluble in water. It is toxic by inhalation (dust) and by ingestion. 96 April 1981 Hnr'l) O{n)00i 70p o J tt material involved in tire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical H material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts o) water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural iime (slaked lime), crushed limestone. or sodium bicarbonate Add ferric chloride (fecl3) Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CALCIUM BISULFITE SOLUTION (See CALCIUM HYDROGEN SULFITE SOLUTION 4932331) CALCIUM CARBIDE 4916408 FLAMMABLE SOLID UN1402 WATER REACTIVE ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RG-5000/2270) Calcium carbide exists as a greyish-black irregular lump solid. It is used to make acetylene and in steel manufacture, it reacts with water to form calcium hydroxide and acetylene, a flammable gas. The heat from this reaction may be sufficient to ignite the acetylene. If material on fire or involved in fire Do not use water Use graphite, soda ash. powdered sodium chloride, or suitable dry powder Carbon dioxide may be ineffective If material not on fire and not involved in fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or lire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate April 1981 CALCIUM CHLORATE 4918713 OXIDIZER UN1452 Calcium chlorate is a white crystalline solid, it is used in photography, in pyrotechnics, and as a herbicide. It is soluble in water. It forms a very flammable mixture with combustible materials and this mixture may be explosive if the combustible material is finely divided. The mixture can be ignited by friction. Contact with strong sulfuric acid can cause fires or explosions. When mixed with ammonium salts, spontaneous decom position and ignition may result. Prolonged exposure of the material to fire or heat can result in an explosion. If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation tf fire becomes uncontrollable--evacuate for a radius of 2500 feet CALCIUM CHLORITE 4918714 OXIDIZER UN14S3 Calcium chlorite is a white granular solid. It is decomposed by water to calcium hydroxide and chlorine dioxide, a nonflammable oxidizing gas. The material itself is non-combustible, but it will accelerate the burning of combustible materials. If the combustible material is finely divided, the mixture may be explosive. Prolonged exposure of the ma terial to fire or heat may result in an explosion and the rupturing of the containers. If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet CALCIUM CHROMATE 4963307 ORM-E NA9096 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000 454) Calcium chromate is a yellow powder. It is slightly soluble in water. It i inhlbtor. and for other uses, it is slightly soluble in water. It is non combustible. If material Involved in fire Extinguish tire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Continued on next page 97 00001^02 If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Add sodium bisulfite Neutralize with agricultural lime (slaked lime), crushed limestone'. or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CALCIUM CYANIDE. SOLID (OR) CALCIUM CYANIDE 4923223 MIXTURE. SOLID POISON B UN1575 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RG-10'4.54) Calcium cyanide, solid is a white crystalline powder or crystalline solid. It is slowly decomposed by water to give off hydrogen cyanide, a flam mable poison gas. Contact with acids will cause rapid evolution of hy drogen cyanide. It is toxic by skin absorption through open wounds, by ingestion, and by inhalation of hydrogen cyanide from the decomposition of the material. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use foam, carbon dioxide or dry chemical Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors if material not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Use water spray to knock-down vapors Do not use water on material itself Personnel protection Avoid breathing vapors or dusts Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in ram or fire fighting water Environmental considerations--water spill Add caustic soda Add calcium hypochlorite Adjust ph to neutral (ph-7) CALCIUM DODECYLBENZENESULFONATE 4963309 ORM-E NA9097 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000 454) Calcium dodecyibenzenesuitonate is a white to light yellow granular solid. It is used as a detergent. It is soluble in water. It is non-combustible. 98 If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty ) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with `copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or soiid material Cover solids with a plastic sheet to prevent dissolving in rain or fire lighting water Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CALCIUM HYDROGEN SULFITE SOLUTION (CALCIUM 4932331 BISULPHITE) CORROSIVE MATERIAL. ACIDIC NA2693 Calcium hydrogen sulfite solution is actually the solution of calcium sulfite and sulfur dioxide in water. It is a colorless to yellow liquid with an odor of sulfur dioxide. It is corrosive to metals. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire {Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of waler Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing CALCIUM HYPOCHLORITE MIXTURE (DRY, 4918715 CONTAINING MORE THAN 39 PERCENT AVAILABLE CHLORINE) OXIDIZER UN1748 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Calcium hypochlorite mixture is a white granular solid or tablets com pressed from the granules with an odor of chlorine, it is used in water purifica purification, as a swimming pool disinfectant, as a bleaching compound, and for many other uses. It is noncombustible but it will accelerate the burning of combustible materials. It is decomposed by water with evolution of chlorine gas and heat. Prolonged exposure to fire or heat may result in the vigorous decomposition of the material and the rupture of its container. Material containing less than 39 percent available chlorine will undergo reactions as described above though it may take longer to initiate and the resulting reactions may not be as vigorous. April 1981 MCD 000017025 If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective eguipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 5000 feet Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in ram or fire fighting water Environmental considerations--water spill Add sodium bisulfite Add soda ash Ad|ust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CALCIUM HYPOCHLORITE. HYDRATED (MINIMUM 4918795 5.5% BUT NOT MORE THAN 10% WATER, AND CONTAINING MORE THAN 39% AVAILABLE CHLORINE) OXIDIZER UN2880 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Calcium hypochlorite, hydrated is a white granular solid or tablets compressed from the granules having an odor of chlorine. It is used for water purification, disinfectant for swimming pools, for bleaching paper and textiles, and for many other uses. It is non-combustible, but it will accelerate the burning of combustible materials. It is decomposed by water with evolution of chlorine gas and heat. Prolonged exposure to fire or heat may result in the vigorous decomposition of the material and rupture of the container. Material containing less than 39% available chlorine will undergo reactions as described above though it amy take longed to initiate, and the resulting reactions may not be as vigorous. If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any materia! which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution April 1981 Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 5000 feet Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Add sodium bisulfite Add soda ash Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CALCIUM METAL 4916401 FLAMMABLE SOLID UN1401 WATER REACTIVE Calcium metal is a silvery, soft metal that oxidizes to greyish white on exposure to air. it is used in metallurgy. It is decomposed by water to form calcium hydroxide and hydrogen, a flammable gas. The heat of this reaction may be sufficient to ignite the hydrogen and possibly the calcium itself. If material on fire or Involved in fire Do not use water Do not use carbon dioxide Use graphite, soda ash. powdered sodium chloride, or suitable dry powder If material not on fire and not involved in fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Avoid breathing fumes from burning material CALCIUM NITRATE 4918716 OXIDIZER UN1454 Calcium nitrate is a white to light grey granular solid, it is used in fertilizers, explosives and pyrotechnics. It is soluble in water. It is non combustible but it will accelerate the burning of combustible materials. If large quantities are involved in the fire or the combustible material is finely divided an explosion may result. Prolonged exposure of the ma terial to fire or heat may result in an explosion. Toxic oxides of nitrogen are produced in fires involving this material. If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible if material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet 99 MCD 000017026 CALCIUM PERMANGANATE 4918718 OXIDIZER UN1456 Calcium permanganate is a purplish colored crystalline solid, it is used as a disinfectant and deodorizer, in water purification, and for many other uses. It is soluble in water. The material itself is noncombustible but it will accelerate the burning of combustible material; if the com bustible material is finely divided the mixture may be explosive. Contact with liquid combustible materials may result in spontaneous ignition. Contact with sulfuric acid may cause fires or explosions. If material on fire or involved In fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus wnen fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet CALCIUM PEROXIDE 4918717 OXIDIZER UN1457 Calcium peroxide is a greyish white granular material, it is used in baking, in medicine, in bleaching oils, and for amny other uses. It is insoluble in water and slowly decomposed by water. It is noncombustible but it will accelerate the burning ot combustible material; if the com bustible material is finely divided the mixture may be explosive. Mixtures of combustible material and the peroxide can be ignited by friction or contact with moisture. If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as tar a distance as possible If material not on fire end not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet CALCIUM PHOSPHIDE 4916310 FLAMMABLE SOLID, POISONOUS UN1360 WATER REACTIVE Calcium phosphide appears as red-brown crystals to grey granular lumps. It reacts with water to form calcium hydroxide and phosphine, a flammable poisonous gas. Phosphine will normally ignite sponta neously in contact with air. If there is an excess of water this tire of phosphine will not normally ignite surrounding combustible material. If material on fire or involved In fire Do not use water Use dry chemical or carbon dioxide If material not on fire and not involved in fire Do not use wafer Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting tires involv ing this material If contact with the material anticipated, wear full protective clothing CALCIUM RESINATE 4916703 FLAMMABLE SOLID UN1313 Calcium resinate is a greyish white to yellow amorphous powder. If it comes in contact with air, spontaneous heating may result. This heat may be sufficient to ignite the material itself or surrounding combustible material. It is insoluble in water. If material on fire or involved in fire Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical tf material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CALCIUM RESINATE, FUSED 4916704 FLAMMABLE SOLID UN1314 Calcium resinate, fused is in the form of greyish lumps made by fusing the powdered material. If it comes in contact with air, spontaneous heating may result. This heat may be sufficient to ignite the material itself or surrounding combustible material. It is insoluble in water. If material on fire or involved in fire Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CALCIUM-MANGANESE-SILICON ALLOYS. 4916767 (FLAMMABLE SOLID, N.O.S.) FLAMMABLE SOLID UN1325 Calcium-manganese-silicon alloys exist as grey lustrous crystalline lumps. It may react with water to give off hydrogen, a flammable gas. The heat of this reaction may be sufficient to ignite the hydrogen. 100 April 1961 Of:>017Q27 If material on fire or Involved In fire Do not use water Use graphite, soda ash. powdered sodium chloride, or suitable dry powder if material not on fire and not involved in fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Avoid breathing fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or lire fighting water Environmental considerations--water spill Add calcium hypochlorite Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Add ferric chloride (fecl3) Ad|ust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CALCIUM, METAL CRYSTALLINE 4916402 FLAMMABLE SOLID NA1401 WATER REACTIVE Calcium, metal, crystalline <s a greyish white granular metal, it is used in metallurgy. As it is finely divided it is more reactive with water than non-crystalline metallic calcium. It reacts with water to form hydrogen, a flammable gas. The heat of this reaction may be sufficient to ignite the hydrogen and also the calcium itself. If material on fire or involved in fire Do not use water Do not use carbon dioxide Use graphite, soda ash. powdered sodium chloride, or suitable dry powder If material not on fire and not involved in fire Do not use water Keep sparks, flames, and other sources ol ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Avoid breathing fumes from burning material CAMPHOR OIL 4913153 COMBUSTIBLE LIQUIO UN1130 Camphor oil is a colorless liquid with a characteristic odor. II has a flash point of 125 deg. F. It is insoluble in water and it is generally lighter than water. Its vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CALCIUMARSENITE. SOLID 4923219 POISON B NA1574 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Calcium arsemte. solid is a white powder. It is insoluble in water. It is toxic by inhalation (dust) and by ingestion. If material involved in fire Extinguish fire using agent suitable lor type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 CANNON PRIMERS CLASS C EXPLOSIVE 4903120 Cannon primer is a small device containing a small amount of a percussion sensitive explosive which ignites a large charge of defla grating explosive which in turn ignites the gun propellant. If material on fire or involved In fire Flood with water Apply water from as far a distance as possible tf material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet MCD 000017028 101 CAPRYLYL PEROXIDE SOLUTION 4919517 ORGANIC PEROXIDE NA2129 Caprylyl peroxide solution is a clear colorless to straw colored liquid with a sharp odor. The peroxide itself is a straw colored liquid. The solution may take some effort to ignite but once ignited it burns with increasing vigor as the fire progresses. It strongly supports the burning of combustible material. Containers of the solution, if exposed to fire or flame, may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors or dusts Keep uowind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet CAPTAN (AGRICULTURAL INSECTICIDES, NEC, 4961164 OTHER THAN LIQUID) ORM-E NA9099 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10/4.54) Captan is a white solid, it is used as a fungicide. It is a wettable powder. It can cause illness by inhalation, skin absorption and/or inges tion. In case of damage to. or leaking trom containers of this material contact the pesticide safety team network. Telephone: 800-424-9300. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CAPTAN (AGRICULTURAL INSECTICIDES, NEC, 4961167 LIQUID) ORM-E NA9099 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10/4.54) Captan is a white solid dissolved in a liquid carrier. It is used as a fungicide. It is a water emulsifiable liquid. It can cause illness by inhal ation. skin absorption and'Or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team net work. Telephone: 800-424-9300. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land apill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates 102 CAPTAN (INSECTICIDES, OTHER THAN 4961110 AGRICULTURAL, NEC) ORM-E NA9099 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10/4.54) Captan is a white solid or the solid dissolved in a liquid carrier. It is used as a fungicide. It is a wettable powder or water emulsifiable liquid. It can cause illness by inhalation, skin absorption and'or ingestion. In case of damage to. or leaking from containers ot this material contact the pesticide safety team network. Telephone; 800-424-9300. H material involved in fire Extinguish fire using agent suitable tor type of surrounding fire (Material itself does not bum or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Peraonnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates April 1981 tic: 29 CARBAMATE PESTICIDE, LIQUID. N.O.S. 4921625 (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC, LIQUID) POISON B UN2757 Carbamate pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emuisifiable. The carrier may burn though it may require some effort to ignite. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800- 424-9300. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CARBAMATE PESTICtOE. LIQUID, N.O.S. 4910528 (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC, LIQUID) FLAMMABLE LIQUID UN2758 Carbamate pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emuisifiable. The primary hazard of this material is the flammability of the carrier. It has a flash point below 100 deg. F. It can cause illness by inhalation, skin absorption and or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone. 800-424*9300. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as log Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wear self-contained breathing apparatus when lighting tires involv ing this material CARBAMATE PESTICIDE, LIQUID, N.O.S. 4910527 (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL, NEC) FLAMMABLE LIQUID UN2758 Carbamate pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emuisifiable. The primary hazard of this material is the flammability of the carrier. It has a flash point below 100 deg. F. It can cause illness by inhalation, skin absorption and'or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424*9300. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wear self-contained breathing apparatus when fighting fires involv ing this material April 1981 CARBAMATE PESTICIDE, LIQUID. N.O.S. 4921624 (COUMPOUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AGRICULTURAL, NEC) POISON B UN2757 Carbamate pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emuisifiable. The carrier may burn though it may require some effort to ignite. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone: 800* 424*9300. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be Ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 103 MCD 00001703Q CARBAMATE PESTICIDE. SOLID. N.O.S. 4921627 (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES. NEC. OTHER THAN LIQUID) POISON B UN2757 Carbamate pesticide is a solid or a liquid absorbed on a dry carrier. It is a wettable powder. It is toxic by inhalation, skin absorption. and'or ingestion. In case of damage to. or leaking from containers of this ma terial contact the pesticide safety team network. Telephone: 800-424- 9300. It material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, ana goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when lighting fires involv ing this material If contact with the material anticipated, wear full protective clothing CARBAMATE PESTICIDE. SOLID. N.O.S. 4921626 (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL. NEC) POISON B UN2757 Carbamate pesticide is a solid or a liquid absorbed on a dry carrier. It is a wettable powder. It is toxic by inhalation, skin absorption, and or ingestion. In case of damage to. or leaking from containers of this ma terial contact the pesticide safety team network. Telephone: 800-424- 9300. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing CARBARYL (AGRICULTURAL INSECTICIDES. NEC. 4941121 LIQUID) ORM-A NA2757 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Carbaryl is a white crystalline solid dissolved in a liquid carrier. It is used as a pesticide. It is a water emutsifiable liquid. It can cause illness by inhalation, skin absorption and'or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: BOO-424-9300. 104 a:cI; ',00J7rw, II material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash. cement powder, sawdust, or com mercial sorbents Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CARBARYL (AGRICULTURAL INSECTICIDES, NEC, 4941122 OTHER THAN LIQUID) ORM-A NA2757 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100 45.4) Carbaryl is a white cylstalline solid. It is used as a pesticide. It is a wettable powder. It can cause illness by inhalation, skin absorption and or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424- 9300. If material involved in fire Extinguish fire using agent suitable for type ot surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in ram or fire fighting water Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove-immobilized masses of pollutants and precipitates CARBARYL (INSECTICIDES, OTHER THAN 4941120 AGRICULTURAL, NEC) ORM-A NA2757 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Carbaryl is a white crystalline solid or the solid dissolved in a liquid carrier. It is used as a pesticide. It is a wettable powder or water emul- sifiable liquid. Ii can cause illness by inhalation, skin absorption and or ingestion. In case of damage to. or leaking from containers of this ma terial contact the pesticide safety team network. Telephone: 600-424- 9300. April 1981 If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) H material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CARBOFURAN 4921525 POISON B NA2757 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10 4.54) Carbofuran is a white solid or the solid dissolved in a liquid carrier. It is used as a pesticide. It is a wettable powder or water emulsitiabie liquid. It is toxic by inhalation, skin absorption, and or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800*424-9300. If material on fira or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak jf without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in ram or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of tOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates April 1981 CARBOFURAN MIXTURE. LIQUID (AGRICULTURAL 4921524 INSECTICIDES, NEC, LIQUID) POISON B NA2757 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10/4.54) Carbofuran mixture, liauid is a white solid dissolved in a liquid carrier. It is used as a pesticide. It is a water emulsitiabie liquid. It is toxic by inhalation, skin absorption, and or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or lire lighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of tOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CARBOLIC ACID OR PHENOL 4921220 POISON B. CORROSIVE, COMBUSTIBLE UN1671 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Carbolic acid or phenol is a colorless crystalline solid with a charac teristic odor. It is used to make plastics, adhesives, and other chemicals. It absorbs moisture from the air and liquefies. It is soluble in water and its vapor is heavier than air. It is also combustible. It is corrosive to the skin and lethal amounts can be absorbed through the skin. It weighs 8.9 pounds per gallon. If material on fire or Involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Continued on next page MCB 000017032 105 Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CARBOLIC ACID, LIQUID OR PHENOL, LIQUID, 4921210 (LIQUID TAR ACID CONTAINING OVER 50% BENZO-PHENOL) POISON B. CORROSIVE, COMBUSTIBLE NA2621 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Carbolic acid, liquid or phenol, liquid is a colorless liquid with a char acteristic odor. It is used to make plastics, adhesives, and other chem icals. It is also combustible. Its vapor is heavier than air and it is soluble in water, it is corrosive to the skin. Lethal quantities of the material can be absorbed through the skin. It weighs 8.9 pounds per gallon. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, ana other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates 106 CARBON BISULFIDE (OR) CARBON DISULFIDE 4908125 FLAMMABLE LIQUID UN1131 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Carbon bisulfide is a clear colorless to light yellow liquid with a strong disagreeable odor. It is used in the manufacture of rayon and cellophane, in the manufacture of flotation agents and as a solvent. It has a flash point of -22 deg. F. and is flammable over a wide vapor-air concentration range. The vapors are readily ignited: the heat of a common light bulb may be sufficient. It is heavier than water and insoluble in water. Its vapors are heavier than air. It weighs 10.5 pounds per gallon. It material on lire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Use dry chemical or carbon dioxide Do not use water Do not extinguish fire unless flow can be stopped If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Apply fluorocarbon-water foam to diminish vapor and tire hazard Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Combustion products include corrosive or toxic vapors CARBON BLACK OIL (COMBUSTIBLE LIQUID, N.O.S.) 4915323 COMBUSTIBLE LIQUID NA1993 Carbon black oil is a dark colored liquid with a petroleum-like odor. It has a flash point between 100 and 200 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical April 1961 MCD 0000.17033 If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CARBON BLACK OIL (FLAMMABLE LIQUID, N.O.S.) 4910323 FLAMMABLE LIQUID UN1993 Carbon black oil is a dark colored liquid with a petroleum like odor. It has a flash point of less than 100 deg. F. It is lighter than water and insoluble in water, its vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use loam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CARBON DIOXIDE--OXYGEN MIXTURE 4904420 NONFLAMMABLE GAS UN1014 Carbon dioxide--oxygen mixture is a colorless odorless gas. Both carbon dioxide and oxygen are noncombustiple: however, oxygen can accelerate the burning of a fire. It may only be shipped in cylinders. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved In fire Keep sparks, flames, and other sources of ignition away Attempt to stop leak if without hazard Personnel protection Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution CARBON DIOXIDE-AIR MIXTURE (COMPRESSED 4904510 GAS, N.O.S.) NONFLAMMABLE GAS UNI 956 Carbon dioxide-air mixture is a colorless odorless gas mixture. It is noncombustible. It may only be shipped in cylinders. April 1961 If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved In fire Attempt to stop leak if without hazard Personnel protection Wear protective gloves and goggles Do not handle broken packages without protective equipment CARBON DIOXIDE-ETHYLENE OXIDE GAS MIXTURE 4904511 (COMPRESSED GAS, N.O.S.) NONFLAMMABLE GAS UN19S6 Carbon dioxide-ethylene oxide mixture is a colorless gas with an ether like odor, it is used as a fumigant. Carbon dioxide is noncombustible. Ethylene oxide is flammable. The mixture can asphyxiate by displace ment of air. It may only be shipped in cylinders. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved In fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CARBON DIOXIDE-ETHYLENE OXIDE MIXTURE 4905820 (COMPRESSED GAS. N.O.S.) FLAMMABLE GAS UN1954 Carbon dioxide-ethylene oxide is a colorless gas with an ether like odor. It is easily ignrtable and may only be shipped in cylinders Carbon dioxide is noncombustible and ethylene oxide is flammable. Both are heavier than air. A flame can flash back to the source of leak very easily. It can asphyxiate by the displacement of air. Under fire conditions cyl inders may violently rupture and rocket. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered 107 MCD 000017034 CARBON DIOXIDE-NITROGEN GAS MIXTURE 4904512 (COMPRESSED GAS, N.O.S.) NONFLAMMABLE GAS UN1956 Carbon dioxide-nitrogen gas mixture is a colorless odorless gas. Both carbon dioxide and nitrogen are noncombustible. The mixture can as phyxiate by the displacement ol air. It may only be shipped in cylinders. If material involved in fire Extinguish tire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment CARBON DIOXIDE-NITROUS OXIDE MIXTURE 4904513 NONFLAMMABLE GAS UN1015 Carbon dioxide-nitrous oxide mixture is a colorless sweet tasting gas. Both carbon dioxide and nitrous oxide are noncombustible. The mixture can asphyxiate by the displacement of air. It may only be shipped in cylinders. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved in fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment CARBON DIOXIDE-PROPYLENE OXIDE GAS MIXTURE 4904514 (COMPRESSED GAS. N.O.S.) NONFLAMMABLE GAS UN1956 Carbon dioxide-propylene oxide gas mixture is a colorless gas with an ether like odor. Carbon dioxide is noncombustible. Propylene oxide is flammable. The mixture can separate with the flammable propylene oxide collecting in low areas. The mixture can asphyxiate by the dis placement of air. It may only be shipped in cylinders. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 108 CARBON DIOXIDE-PROPYLENE OXIDE MIXTURE 4905815 (COMPRESSED GAS, N.O.S.) FLAMMABLE GAS UN1954 Carbon dioxide propylene oxide mixture is a colorless odorless gas. It is easily ignited and may only be shipped in cylinders. Carbon dioxide is noncombustible and propylene oxide is flammable. Both are heavier than air. A flame can flash back to the source of leak very easily. It can asphyxiate by the displacement of air. Under fire conditions cylinders may violently rupture and rocket. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on tire), downwind evacuation must be considered CARBON DIOXIDE, LIQUEFIED 4904509 NONFLAMMABLE GAS UN2187 Carbon dioxide, liquefied is a colorless liquid. It is used as a refrigerant, in fire extinguishers, and in making carbonated beverages. It is non combustible. Contact with the liquid will cause frostbite. The gas is heavier than air and can asphyxiate by the displacement of air. II material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Malerial itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Do not use water on material itself Apply water from as far a distance as possible If matarial not involved in fire Attempt to stop leak if without hazard Do not use water on material itself Personnel protection Avoid breathing vapors Wear protective gloves and goggles Do not handle broken packages without protective equipment CARBON MONOXIDE 4905709 FLAMMABLE GAS UN1016 Carbon monoxide is a colorless, odorless gas. Prolonged exposure to carbon monoxide rich atmospheres may be fatal. It is easily ignited and may be shipped only in cylinders. It is just lighter than air and a flame can flash back lo the source of leak very easily. Under fire con ditions the cylinders may violently rupture and rocket. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible April 1981 MCD 000017085 If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knockdown vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered CARBON REMOVER, LIQUID 4910130 FLAMMABLE LIQUID UN1132 Carbon remover is a colorless liquid with a petroleum-like odor. It has a flash point of less than 100 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggtes Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CARBON TETRACHLORIOE 4940320 ORM-A UN1846 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Carbon tetrachloride is a clear colorless heavy liquid with a charac teristic odor. It is used as a solvent, in the manufacture of other chem icals. as an agricultural fumigant, and for many other uses. It is heavier than water and insoluble in water. It is non-combustible. It can cause illness by inhalation, skin absorption and or ingestion. It weighs 13.2 pounds per gallon, tt material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Apply "universal" gelling agent to immobilize spill Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom Remove trapped material with suction hoses If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment Thermal decomposition to phosgene can occur CARTRIDGE CASES. EMPTY, PRIMED 4903140 CLASS C EXPLOSIVE Cartridge cases, empty, primed consist of small arms cartridge cases, containing no propellant or projectile, with a smailarms primer attached to the base. If material on fire or involved in fire Flood with water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet CARTRIDGE, PRACTICE AMMUNITION 4903150 CLASS C EXPLOSIVE Cartridge, practice ammunition consists of a metal cartridge case, primed with a limited amount of propelling charge and a solid projectile or solid projectile with smoke spotting charge. If material on fire or involved In fire Flood with water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet CAUSTIC POTASH, DRY, SOLIO, FLAKE, BEAD, OR GRANULAR (See POTASSIUM HYDROXIDE, DRY, SOLID, FLAKE, BEAD, OR GRANULAR 4935225) CAUSTIC POTASH, LIQUID OR SOLUTION (See POTASSIUM HYDROXIDE, SOLUTION 4935230) MCP 000017036 109 CAUSTIC SODA AND CAUSTIC POTASH, MIXED, IN 4935244 SOLUTION {POTASSIUM HYDROXIDE, LIQUID, OR SOLUTION) CORROSIVE MATERIAL UN1814 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-1000/454) Caustic soda ana caustic potash, mixed, in solution is a white solid dissolved in water, it is used in chemical manufacturing, petroleum re fining. cleaning compounds, and for many other uses. It is corrosive to metals and tissue. It is non-combustible. It weighs 12.8 pounds per gallon. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing vapors or dusts Avoid bodily contact with the material Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Oike surface flow using sort. sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with vinegar or other dilute acid Environmental considerations--water spill Neutralize with dilute acid or removable strong acid Environmental considerations--air spill Apply water spray or mist to knock down vapors CAUSTIC SODA AND CAUSTIC POTASSIUM. MIXED, 4935245 IN SOLUTION (SODIUM HYDROXIDE LIQUID (OR) SOLUTION) CORROSIVE MATERIAL UN1624 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Caustic soda and caustic potassium, mixed, in solution is the white solid material dissolved in water. It is non-combustible. It dissolves in water with release of heat. It is corrosive to metals and tissue. It weighs 12.7 pounds per gallon. If material involved in fire Extinguish fire usmg agent suitabie for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land apffl Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with vinegar or other dilute acid Environmental conaiderations--water spill Neutralize with dilute acid or removable strong acid Environmental considerations--air spill Apply water spray or mist to knock down vapors CAUSTIC SODA SOLUTION SPENT (SODIUM 4935206 HYDROXIDE SOLUTION) CORROSIVE MATERIAL, BASIC UN1824 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Caustic soda solution, spent is a colorless to dark colored liquid. It is at least partially soluble in water with release of heat. It is corrosive to metals and tissue. It weighs 12.7 pounds per gallon. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Coot all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with vinegar or other dilute acid Environmental considerations--water spill Neutralize with dilute acid or removable strong acid Environmental considerations--air spill Apply water spray or mist to knock down vapors CAUSTIC SODA, DRY, SOLID, FLAKE, BEAD, OR GRANULAR (See SOOIUM HYDROXIDE, DRY, SOLID, FLAKE. BEAD, OR GRANULAR 4935235) CAUSTIC SODA, LIQUID OR SOLUTION (See SODIUM HYDROXIDE, SOLUTION 4935240) CELLULOSE FILM, NEC, PRINTED, (FLAMMABLE 4917397 SOLID, N.O.S.) FLAMMABLE SOUD UNI 325 Cellulose film. nec. printed is a flammable solid when made of nitro cellulose. It is then easily ignited and burns with great rapidity. Older film may deteriorate and be liable to spontaneous heating and ignition. Toxic oxides of nitrogen are produced during combustion. If material on fire or Involved in fire Flood with water If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away CEMENT OR CONCRETE WATER PROOFING 4915462 COMPOUNDS, LIQUID OR PASTE (COMBUSTIBLE LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Cement or concrete water proofing compounds, liquid or paste are materials containing a solvent having a closed cup flash point betweer 100 and 199 deg. F. The hazard of these materials is combustibility. It material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CEMENT OR CONCRETE WATER PROOFING 4910462 COMPOUNDS, LIQUID OR PASTE (FLAMMABLE LIQUID, N.O.S.) FLAMMABLE LIQUID UN1993 Cement or concrete water proofing compounds, liquid or paste are materials containing a solvent having a closed cup flash point of less than 100 deg. F. The hazard of these materials is flammability. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water CEMENT, ADHESIVE, N.O.S. COMBUSTIBLE LIQUID (See CEMENT, LIQUID, N.O.S.,COMBUSTIBLE UQUID 4915114) CEMENT, ADHESIVE, N.O.S., FLAMMABLE UQUID (See CEMENT, LIQUID, N.O.S., FLAMMABLE UQUID 4910114) CEMENT, CONTAINER LINOLEUM, TILE, OR 4910112 WALLBOARO, UQUID FLAMMABLE UQUID NA1133 Cement, container linoleum, tile, or wallboard. liquid are the solutions of various gums, resins etc. in different solvents. The liquids are generally quite thick and may range from clear colorless to black "tar." the flash point of the cement depends on the solvent used but it will be less than 100 deg. F. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water April 1981 Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CEMENT, CORK, INSULATION. LIQUID (CEMENT, 4910458 LIQUID, N.O.S.) FLAMMABLE LIQUID NA1133 Cement, cork, insulation, liquid is a solution of various gums and resins in various solvents. The liquids are generally quite thick and range from clear colorless to black "tar". The flash point depends on the sol vents used; but it will be below 100 deg. F. The hazard of these materials is flammability. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CEMENT, CORK. INSULATION, LIQUID (CEMENT, 49154S8 LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1133 Cement, cork, insulation, liquid is a solution of various gums and resins in various solvents. The liquids are generally quite thick and range from clear colorless to black tar. " the flash point depends on the solvents used but it will be between 100 and 199 deg. F. The hazard of these materials is combustibility. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use " alcohol" foam, carbon dioxide or dry chemical ft material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 111 MCD 000017038 CEMENT, LEATHER 4910110 FLAMMABLE LIQUID NA1133 Cement, leather is the solution of various gums and resins in various solvents. The liquids are generally Quite thick and may range from clear colorless to black tar . The flash point of the cement depends on the solvent used but it wifi be less than 100 deg. F. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use 'alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material wnich may have contacted the body with copious amounts of water or soap and water CEMENT. LIQUID. N.O.S. 4910114 FLAMMABLE LIQUIO NA1133 Cement, liquid, n.o.s. are solutions of various gums and resins in various solvents. The liquids are generally quite thick and may range from clear to black tar". The flash point of the cement depends on the solvent used but it will be less lhan 100 deg. F. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohof" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, ana other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CEMENT. LIQUID, N.O.S. 4915114 COMBUSTIBLE LIQUID NA1133 Cement, liquid, n.o.s. are solutions of various gums and resins in various solvents. The liquids are generally quite thick and may range from clear to black "tar". The flash point of the cement depends on the solvent used but ii will be between 100 and 199 deg. F. If material on fire or involved in fire Oo not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol'' foam, carbon dioxide or dry chemical 112 If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CEMENT. PYROXYLIN 4910116 FLAMMABLE LIQUID NA1133 Cement pyroxylin is pyroxylin plastic dissolved in a solvent. The flash point of the cement depends upon the solvent used but it will be less than 100 deg. F. The film deposited by the evaporation of the solvent is easily ignited and once ignited burns with great rapidity. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CEMENT, ROOFING. LIQUID 4910118 FLAMMABLE LIQUID NA1133 Cement, roofing, liquid is a solution of various gums and resins in various solvents. The liquids are quite thick and are generally black "tars". The flash point of the cement depends on the solvent used but it will be less than 100 deg. F. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on tire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain How as necessary Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Aprii 1981 MOD 000017039 CEMENT. RUBBER 4910120 FLAMMABLE LIQUID NA1133 Cement, rubber is a solution of various gums and resins in various solvents. The liquid is quite thick and is generally a milky white color. The flash point of the cement depends upon the solvent used but it will be less than 100 deg. F. If material on fire or involved In fire Do not extinguish lire unless flow can be stopped Use water in flooding quantities as (og Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CESIUM METAL 4916405 FLAMMABLE SOLID UN1407 WATER REACTIVE Cesium metal is a silver white metal readily tarnished greyish white by air. It is used tn electronics, as a catalyst in chemical processing, and for many other uses. It melts at 82 deg. F. It is violently decomposed by water giving cesium hydroxide and hydrogen, a flammable gas. The heat of this decomposition may be sufficient to ignite the hydrogen. If material on fire or involved in fire Do not use water Do not use carbon dioxide Use graphite, soda ash. powdered sodium chloride, or suitable dry powder If material not on fire and not involved in fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Do not attempt to sweep up dry material Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Avoid breathing fumes from burning material CHAMPAGNE (ALCOHOLIC BEVERAGE) 4910345 FLAMMABLE LIQUID UN1170 Champange is a variable colored bubbling liquid having the odor char acteristic of fermented liQuors. It has a flash point between 73 and 100 deg. F. It is soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, tiames. and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary April 1981 Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CHAMPAGNE (ALCOHOLIC BEVERAGE) 4915312 COMBUSTIBLE LIQUID UN1170 Champange is a variable colored bubbling liquid having the odor char acteristic of fermented liquors. It has a flash point between 100 and 199 deg. F. It is soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CHARCOAL BRIQUETTES (CHARCOAL BRIQUETTES 4917311 OR PELLETS. WITH PETROLEUM BINDER) FLAMMABLE SOLID NA1361 Charcoal briquettes are powdered or granular charcoal mixed with a tar or starch and water binder and pressed into regular lumps. The hazard is that of spontaneous heating if the charcoal briquettes are not properly cooled after manufacture. If material on fire or involved in fire Remove burning material from load if safe and practicable to do so Use dry chemical or carbon dioxide Use water only if flooding quantities are available If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material dry CHARCOAL BRIQUETTES (CHARCOAL BRIQUETTES 4917312 OR PELLETS, WITHOUT PETROLEUM BINDER) FLAMMABLE SOLID NA1361 Charcoal briquettes are powdered or granular charcoal mixed with a tar or starch and water binder and pressed into regular lumps. The hazard is that of spontaneous heating if the charcoal briquettes are not properly cooled after manufacture. Continued on next page 113 MCD 0000.17CM0 If material on fire or involved in fire Remove burning material from toad if safe and practicable to do so Use dry chemical or carbon dioxide Use water only if flooding quantities are available If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material dry CHARCOAL BRIQUETTES (CHARCOAL BRIQUETTES. COMPRESSED. SELF-IGNITING) 4917313 FLAMMABLE SOLID NA1361 Charcoal briquettes are powdered or granular charcoal mixed with a tar or starch and water binder and pressed into regular lumps. The hazard is that of spontaneous heating if the charcoal briquettes are not properly cooled after manufacture, if material on fire or involved In fire Remove burning material from load if safe and practicable to do so Use dry chemical or carbon dioxide Use water only if flooding quantities are available If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material dry CHARCOAL SCREENINGS, MADE FROM "PINON" 4917320 WOOD FLAMMABLE SOLID NA1361 Charcoal screenings, made from "pinon ' wood is a finely divided black solid. It is fairly easily ignited. The main hazard is that of spontaneous heating if the charcoal has not been properly cooled after manufacture. If material on fire or involved in fire Remove burning material from load if safe and practicable to do so Use dry chemical or carbon dioxide Use water only if flooding quantities are available If material not on fire and not involved in fire Keep material dry CHARCOAL, ACTIVATED 4917310 FLAMMABLE SOLID UN1362 Charcoal, activated is a black granular material that has been treated to improve its absorptive ability. The hazard is that of spontaneous heating if the charcoal is not properly cooled after manufacture. If material on fire or involved in fire Remove burning material from load if safe and practicable to do so Do not use carbon dioxide If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material dry CHARCOAL, CORN COB OR COTTONSEED OR RICE 4917394 HULL. NOT ACTIVATED (CHARCOAL, SHELL) FLAMMABLE SOLID UN1325 Charcoal, corn cob or cottonseed or rice hull, not activated is a black solid. The hazard in transportation is that of spontaneous heating if the material is not properly cooled after manufacture, or if it should become wet. If material on fire or involved in fire Remove burning material from load if safe and practicable to do so Use dry chemical or carbon dioxide Use water only if flooding quantities are available If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material dry 114 CHARCOAL. OTHER THAN ANIMAL OR WOOD, NEC. 4917395 NOT ACTIVATED. (FLAMMABLE SOLID, N.O.S.) FLAMMABLE SOLID UN1325 Charcoal, other than animal or wood. nec. not activated is a black solid. The hazard in transportation is that of spontaneous heating if the material is not properly cooled after manufacture or if it should become wet. If material on fire or involved in fire Remove burning material from load if safe and practicable to do so Use dry chemical or carbon dioxide Use water only if flooding quantities are available If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material dry CHARCOAL. SHELL 4917314 FLAMMABLE SOLID NA1361 Charcoal, shell is made from coconut shells, walnut shells, fruit pits, or other similar material. The hazard is that of spontaneous heating if the charcoal is not properly cooled after manufacture. If material on fire or involved in fire Remove burning material from load if safe and practicable to do so Use dry chemical or carbon dioxide Use water only if flooding quantities are available If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material dry CHARCOAL, WOOD SCREENINGS, OTHER THAN 4917322 "PINON" WOOD SCREENINGS FLAMMABLE SOLID NA1361 Charcoal, wood screenings, other than "pinon wood screenings is a finely divided black solid. It is fairly easily ignited. The main hazard is that of spontaneous heating it the charcoal has not been properly cooled after manufacture. If material on fire or involved in fire Remove burning material from load if safe and practicable to do so Use dry chemical or carbon dioxide Use water only if flooding quantities are available If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material dry CHARCOAL, WOOD. GROUND. CRUSHED, 4917316 GRANULATED. (OR) PULVERIZED FLAMMABLE SOLID NA1361 Charcoal, wood, ground, crushed, granulated, or pulverized is a finely divided black solid. It is fairly easily ignited. The mam hazard is that of spontaneous heating if the charcoal has not been properly cooled after manufacture. tf material on fire or involved In fire Remove burning material from load if safe and practicable to do so Use dry chemical or carbon dioxide Use water only if flooding quantities are available If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material dry CHARCOAL, WOOD, LUMP 491731B FLAMMABLE SOLID NA1361 Charcoal, wood, lump is large pieces of black material. The hazard in transportation is that of spontaneous heating if the charcoal has not been properly cooled after manufacture. April 1981 mod 0 7041 If material on fire or involved in fire Remove burning material from load if safe and practicable to do so Use dry chemical or carbon dioxide Use water only if flooding quantities are available If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material dry CHEMICAL AMMUNITION, NONEXPLOSIVE 4920925 (CONTAINING A POISON A MATERIAL) POISON A UN2016 Chemical ammuntition, nonexplosive (containing a poison a material) may be any type of projectile, bomb, granade. etc. containing a material classed as poison a. and does not contain any explosive components- the poison a material can cause death by inhalation or skin absorption. Of very small quantities. It may or may not be combustible. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation if material leaking (not on fire), downwind evacuation must be considered CHEMICAL AMMUNITION. NONEXPLOSIVE 4923915 (CONTAINING A POISON B MATERIAL) POISON B UN2016 Chemical ammunition, nonexplosive (containing a poison b material) may be any type of proiectile. bomb, grenade, etc. containing a material classed as a poison b. and does not contain any explosive components. The poison b material can cause death by inhalation, ingestion or skin absorption. The poison b material may or may not be combustible. If material on fire or involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing April 1981 CHEMICAL AMMUNITION, NONEXPLOSIVE (CONTAINING AN IRRITATING MATERIAL) 4925840 IRRITATING MATERIAL UN2017 Chemical ammunition, nonexplosive (containing an irritating material) may be any type of projectile, bomb, grenade, etc. containing a sub stance classed as an irritating material, and does not contain any ex plosive components. The irritating material gives off fumes that are ex tremely irritating to the eyes and mucous membrances when exposed to air or contact with fire. It may or may not be combustible. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CHEMICAL KIT 4936548 CORROSIVE MATERIAL NA1760 Chemical kit is a package containing limited quantities of various corrosive materials. They are generally non-combustible and soluble in water with release of heat. They are corrosive to metals and tissue. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as tog If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing CHEMICAL PLANT WASTE (COMBUSTIBLE LIQUID, 4915560 N.O.S.) COMBUSTIBLE LIQUID NA1993 Chemical plant waste, nec is a clear to variable colored liquid which may have a pleasant or unpleasant odor. It has a flash point of between 100 and 199 deg. F. It may be insoluble, partially soluble, or soluble in water. It may be heavier or lighter than water. Its vapors are heavier than air. Contact the shipper to determine the specific constituents and properties of this material. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Continued on next page 000017042 115 If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CHEMICAL PLANT WASTE, NEC (CORROSIVE 4936538 LIQUID, N.O.S.) CORROSIVE MATERIAL UN1760 Chemical plant waste, nec is a clear to variable colored iiauid. It is usually soluble in water. It may burn though it may require some effort to ignite. It is corrosive to metals and tissue. Contact the shipper to determine the specific constituents and properties of this material. (f material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of comDustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do rot handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing CHEMICAL PLANT WASTE, NEC (FLAMMABLE 4910560 LIQUID, N.O.S.) FLAMMABLE LIQUID UNI 993 Chemical plant waste, nec is a clear to variable colored liquid and may have a pleasant or unpleasant odor. It has a flash point of less than 100 deg. F. It may be insoluble, partially soluble, or soluble in water. It may be heavier or lighter than water. Its vapors are heavier than air. Contact the shipper to determine the specific constituents and properties of this material. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in Hooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers 116 CHEMICAL PLANT WASTE, NEC (POISONOUS 4923370 LIQUID, N.O.S.) POISON B NA2810 Chemical plant waste, nec is a variable colored liquid. It may or may not be water soluble. It may burn though it may require some effort to ignite. It is toxic by ingestion, inhalation (vapors, mist, etc.) or by skin absorption. Contact the shipper to determine the specific constituents and properties of this material. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol1' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered CHLORAL (CORROSIVE LIQUID, N.O.S.) 4935515 CORROSIVE MATERIAL UN1760 Chloral is a colorless oily liquid with a strong pungent odor. It is used to make chloral hydrate and ddt. It is heavier than water and is soluble in water. Us vapors are heavier than air. It is corrosive to tissue H material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.! Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use water spray to absorb vapors If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash. or lime April 1981 MOD 000017043 Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing CHLORATE AND BORATE MIXTURE 4918719 OXIDIZER UN1458 Chlorate and borate mixture is usually a white crystalline solid. It may only be partially soluble in water. It forms a very flammable mixture with combustible materials and this mixture may be explosive if the com bustible material is very finely divided. The mixture can be ignited by friction. Contact with strong sulfuric acid can cause fires or explosions. When mixed with ammonium salts, spontaneous decomposition and ignition may result. Prolonged exposure of the material to tire or heat can result in an explosion. If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possioie If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet CHLORATE AND MAGNESIUM CHLORIDE MIXTURE 4918720 OXIDIZER UN1459 Chlorate and magnesium chloride mixture is a white crystalline solid. It is soluble in water. It forms a very flammable mixture with combustible materials and this mixture may be explosive it the combustible material is very finely divided. The mixture can be ignited by friction. Contact with strong sulfuric acid can cause fires or explosions. When mixed with ammonium salts, spontaneous decomposition and ignition may result. Prolonged exposure of the material to fire or heat can result in an explosion. If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, ana other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet April 1981 CHLORATE OP POTASH (See POTASSIUM CHLORATE 4918722) CHLORATE OF SODA (See SODIUM CHLORATE 4918723) CHLORATE, N.O.S. 4918721 OXIDIZER UN1461 Chlorate, n.o.s. is a crystalline compound having the following prop erties. The material is soluble in water. It forms a very flammable mixture with combustible materials and this mixture may be explosive if the combustible material is finely divided. The mixture can be ignited by friction. Contact with strong sulfuric acid can cause fires or explosions. When mixed with ammonium salts, spontaneous decomposition and ignition may result. Prolonged exposure to fire or heat can result in an explosion. If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet CHLORATE, N.O.S., WET 4918610 OXIDIZER NA1461 Chlorate, n.o.s.. wet is a slurry or sludge of white crystalline com pounds compounos which have the following properties. The material is soluble in water. The material itself is noncombustible. but it can form a very flammable mixture with combustible materials, and this mixture may be explosive if the combustible material is very finely divided. The mixture can be ignited by friction. Contact with strong sulfuric acid can cause fires or explosions. When mixed with ammonium salts, sponta neous decomposition and ignition may result. Prolonged exposure of the material to heat or fire can result in an explosion. If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Approach fire with caution Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet 117 MCD 000017044 CHLOROANE. LIQUID 4909320 FLAMMABLE LIQUID NA2762 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1 0.454) Chlordane. liquid is the solution of chlordane. a clear colorless, odor less liquid in some solvent. It is used as an insecticide. It has a flash point of less than 100 deg. F. depending on the solvent and the con centration of chlordane: chlordane itself does not Durn. It is generally heavier than water and insoluble in water. Its vapors are heavier than air. It weighs 13.3 pounds per gallon. If material on fire or involved in fire Use water m flooding quantities as fog Do not extinguish fire unless flow can be stooped Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liauid with fly ash. cement powder, sawdust, or com mercial sorbents Apply universal gelling agent to immobilize spill Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Combustion products include corrosive or toxic vapors CHLORDANE, LIQUID 4913170 COMBUSTIBLE LIQUID NA2762 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1'0.454) Chlordane. liquid is the solution of chlordane. a clear colorless, odor less liquid in a solvent. It has a flash point between 100 and 199 deg. F. it is generally heavier than water and insoluble in water. Its vapors are heavier than air. It weighs 13.3 pounds per gallon. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors 118 Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective eauipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash. cement powder, sawdust, or com mercial sorbents Apply ' universal" gelling agent to immobilize spill Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Combustion products include corrosive or toxic vapors CHLORIC ACID 4918206 OXIDIZER. CORROSIVE NA2626 Chloric acid is a colorless liquid. It is used as a reagent in chemical analysis and to make other chemicals. It wiil accelerate the burning of combustible materials and can ignite most on contact. It is corrosive to metals and tissue, if material involved in fire Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet CHLORINATED LIME, LIQUID (CORROSIVE LIQUID, 4932332 N.O.S.) CORROSIVE MATERIAL, ACIDIC UN1760 Chlorinated lime, liquid is the water solution of calcium chloride and calcium hypochlorite. It has an odor of chlorine. It is corrosive to metals and to tissue. If material involved in fire Extinguish fire using agent suitable lor type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash. or lime April 1981 MCD ooo0170^5 Personnel protection Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing CHLORINATED PHENOL PETROLEUM SOLUTION 4921494 (POISONOUS LIQUID, N.O.S.) POISON B NA2810 Chlorinated phenol petroleum solution is a colorless to yellow liquid. It is insoluble in water and may or may not be combustible. It is toxic by inhalation and by skin absorption. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water CHLORINE 4904120 NONFLAMMABLE GAS. POISONOUS UN1017 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10/4.54) Chlorine is a greenish yellow gas with a pungent suffocating odor. It is used to purify water, bieach woodpulp. and to make other chemicals. It is toxic by inhalation. It is soluble in water. It reacts explosively or forms explosive compounds, with many common chemicals. It is nor mally shipped as a liquid in cylinders or tank cars. Contact with liquid should be avoided as it can cause frostbite. The liquid does readily vaporize to gas. The vapors are much heavier than air and tend to settle m low areas. It weighs 13.0 pounds per gallon. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use water spray to absorb vapors If material not Involved in fire Keep material out of water sources and sewers Attempt to stop leak if without hazard Do not apply water to point of leak in tank car or container Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus April 1981 Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire) evacuate for a radius of 2500 feet Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with caustic soda or soda ash Environmental considerations--water spill Add caustic soda If dissolved, apply activated carbon at ten times the spilled amount In region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment CHLORINE DIOXIDE HYDRATE. FROZEN 4918110 OXIDIZER. POISONOUS AND THERMALLY UNSTABLE NA9191 Chlorine dioxide hydrate, frozen is an orange colored solid, appearing as a block of ice. with a faint odor of chlorine, it is used to bleach wood pulp, fats and oils: in processing flour, and for water purification. It may only be shipped in the frozen state and then only by private or contract motor carrier. The melting point of the hydrate is around 30 deg. F. If it should thaw and further warm up. chlorine dioxide gas is given off. The gas is toxic by inhalation. The gas and liquid are violently decom posed by organic materials. The gas will decompose explosively at temperatures below the boiling point of water. If material on fire or involved in fire Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not on fire and not Involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing vapors Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet CHLORINE TRIFLUORIDE 4918210 OXIDIZER, POISONOUS, CORROSIVE UN1749 Chlorine trifluoride is a colorless gas or green liquid with a pungent odor. It becomes a gas at 53 deg. F. It reacts with water to form chlorine and hydrofluoric acid with release of heat. Contact with organic materials may result in spontaneous ignition. It may only be shipped in cylinders not equipped with safety relief devices. It is corrosive to metals and tissue. Prolonged exposure of the cylinders to fire can result in their violent rupturing and rocketing. Continued on next page lOA<S ,-ioooV 119 If material involved in fire Do not use water on material itself Use dry chemical or carbon dioxide Cool all affected containers with flooding quantities of water If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If material not involved in fire Keep material out of water sources and sewers Do not use water on material itself Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered 4'CHL0ROO*T0LUIDINE HYDROCHLORIDE 4921412 POISON B UNI579 4-chloro-o-toluidine hydrochloride is a white crystalline solid. It is sol uble in water. It is toxic by skin absorption and inhalation (dusti. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water m flooding quantities as fog Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing vapors or dusts Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material CHLOROACETIC ACID, SOLID 4931416 CORROSIVE MATERIAL, ACIDIC UN17S1 Chloroacetic acid, solid is a colorless to light-brown crystalline solid. It absorbs moisture from air and forms a syrup. It is soluble in water, it is corrosive to metals and tissue. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog ' Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep material out of water sources and sewers Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing CHLOROACETOPHENONE, GAS, LIQUID OR SOLID 4925220 IRRITATING MATERIAL UN1697 Chloroacetophenone is in the form of colorless to white crystals. The vapor of the material is very irritating to the eyes and mucous membranes. If material on fire or involved in fire Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing CHLOROACETYL CHLORIDE 4931210 CORROSIVE MATERIAL. ACIDIC. POISONOUS UN1752 Chloroacetyl chloride is a colorless to light yellow liquid with a pungent odor. It is decomposed by water to chloroacetic and hydrochloric acids. These and the material itself are corrosive to metals and tissue. If material involved in fire Use dry chemical or carbon dioxide Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Boild dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting tires involv ing this material If contact with the material anticipated, wear full protective clothing 120 MCI) 000017047 April 1981 CHLOROBENZOL (OR) CHLOROBENZENE 4909153 FLAMMABLE LIQUID UN1134 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100 45.4) Chlorobenzol is a clear colorless liquid with an almond-like odor. It has a flash point of 66 deg. F. It is heavier than water and slightly soluble in water. Its vapors are heavier than air. It weighs 9.2 pounds per gallon. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liauid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash. cement powder, sawdust, or com mercial sorbents Apply "universal'' gelling agent to immobilize spill Apply fluorocarbon-water foam to diminish vapor and fire hazard Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Combustion products include corrosive or toxic vapors P-CHLOROBENZOYL PEROXIDE 4919120 ORGANIC PEROXIDE UN2113 P-chlorobenzoyl peroxide is a white granular solid. It is easily ignited and burns very rapidly. If strongly supports the burning of combustible materials. It can form explosive mixtures with finely divided combustible materials. Under prolonged exposure to fire or heat containers of the material can explode. If material on fire or involved In fire Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up April 1981 Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soao and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticioated. wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet P-CHLOROBENZOYL PEROXIDE. (NOT MORE THAN 4919219 52% AS A PASTE) THAN 52% WITH INERT SOLID) ORGANIC PEROXIDE UN2114 3.3,6.6.9.9-hexamethyM ,2.4.5-tetraoxocyclononane. (not more than 52% solid. It is used to manufacture oaints. plastics, and rubber. It is plastics, and rubber. It is insoluble in water, it is easily ignited and as the fire progresses. It can form exoiosive mixtures with finely divided mixtures with finely divided combustible materials. It suooorts the burning under prolonged exposure to tire or heat containers of the material may containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with Hooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soao and water Wear self-contained breathing apparatus when fighting fires involv ing this material if contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved m fire evacuate for a radius of 2500 feet P-CHLOROBENZOYL PEROXIDE. (NOT MORE THAN 491921B 75% WITH WATER) ORGANIC PEROXIDE UN2113 P-chlorobenzoyl peroxide, (not more than 75% with water) is a white solid, it is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and burns with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combus tible materials. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. Continued on next page oooo^046 121 If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol' foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wei Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet CHLOROFORM (CHLOROFORM 4940310 (TRICHLORMETHANE), NEC, OTHER THAN TECHNICAL GRADE) ORM-A UN188B ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000 2270) Chloroform is a clear colorless heavy liquid with a characteristic odor. It is used as a solvent, to make other chemicals, as fumigant, and for other uses, ft is heavier than water and slightly soluble in water. It is nonflammable under most conditions, but it will burn under extreme fire conditions. It can cause illness by inhalation, skin absorption and/or ingestion. It weighs 12.3 pounds per gallon. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any matenal which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Apply "universal" gelling agent to immobilize spill Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom Remove trapped material with suction hoses If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Combustion products include corrosive or toxic vapors Thermal decomposition to phosgene can occur 122 CHLOROFORM (CHLOROFORM, NEC, TECHNICAL 4940311 GRADE (TRICHLOROMETHANE)) ORM-A UNI 888 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Chloroform is a clear colorless heavy liquid with a characteristic odor. It is used as a solvent, to make other chemicals, as fumigant, and for other uses. It is heavier than water and slightly soluble in water. It is nonflammable under most conditions, but it will burn under extreme fire conditions. It can cause illness by inhalation, skin absorption and/or ingestion. It weighs 12.3 pounds per gallon. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material Itself does not burn or burns with difficulty.) If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Apply ' universal' gelling agent to immobilize spill Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom Remove trapped material with suction hoses If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Combustion products include corrosive or toxic vapors Thermal decomposition to phosgene can occur CHLOROPENTANES (COMBUSTIBLE LIQUID, N.O.S.) 4913136 COMBUSTIBLE LIQUID NA1993 Chloropentanes are clear colorless to pale yellow liquids. They have a flash point between 100 and 199 deg. F. They are lighter than water and insoluble in water. Their vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material April 1981 MCD U00017049 CHLOROPENTANES (FLAMMABLE LIQUID. N.O.S.) 4909136 FLAMMABLE LIQUID UN1993 Chloropentanes are clear colorless to yellow liquids. Their flash point is in the range of 54 to 99 deg. F. They are lighter than water and insoluble in water. Their vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material CHLOROPHENYL TRICHLOROSILANE 4934220 CORROSIVE MATERIAL. ACIDIC UN1753 Chlorophenyl trichlorosllane is a colorless to pale yellow liquid with a pungent odor. The material will burn though it may take some effort to ignite. It is decomposed by moisture or water to hydrochloric acid with evolution of heat. It is corrosive to metals and tissue. If material on fire or involved in fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water m flooding Quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing 3-CHLOROPEROXYBENZOIC ACID. (NOT MORE THAN 4919223 86% WITH 3-CHLOROBENZOIC ACID) ORGANIC PEROXIDE UN2755 3-chloroperoxybenzoic acid, (not more than 86% with 3-chlorobenzoic acid) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and burns with increas ing rapidity as the fire progresses. It can form explosive mixtures with finely divided combustible materials, ft supports the burning of combus tible materials. Under prolonged exposure to tire or heat containers of the material may explode. If material on fire or Invoived in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use 'alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled matenal before picking it up Personnel protection Avoid breathing dusts, and iumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on lire or involved in fire evacuate tor a radius of 2500 feet April 1981 CHLOROPICRIN AND METHYL CHLORIDE MIXTURE 4920105 POISON A, FLAMMABLE UN1582 Chloropicrm and methyl chloride mixture is a colorless gas with an intense, penetrating odor. It is shipped as a liquefied gas under its vapor pressure. Methyl chloride is a flammable gas and chloropicrin is non combustible. The mixture can separate with the chloropicrin settling into low areas. Chloropicrin is very irritating to all body surfaces and is toxic by inhalation. It may only be shipped in cylinders and these may be overpacked in wooden boxes. Prolonged exposure to fire or heat may cause the cylinders to violently rupture and rocket. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol' foam, carbon dioxide or dry chemical H material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered 123 MCD 000017050 CHLOROPICRIN MIXTURE (CONTAINING NO 4921416 COMPRESSED GAS OR POISON A LIQUID) POISON B UN 1583 Chloropicrin mixture is a variable colored liquid usually colorless to yellow. Chloropicrin is non-combustible and the flammability of the mix ture will depend on the other component of the mixture. Chloropicrin vapors are heavier than air and it is toxic by inhalation, in case of damage to. or leaking from containers of this material contact the pesticide safety (earn network. Telephone: 000-424-9300 It material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as tog Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear lull protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contactea the body wilh copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered CHLOROPICRIN. ABSORBEO 4921415 POISON B NA1583 Chloropicrin. absorbed is a liquid chloropicrin absorbed on a dry ear ner. The strong odor of chloropicrin may or may not be present. The carrier usually is not soluble in water and is non-combustible. Chloro- pienn is slightly soluble in water and is nan-combustible. Vapors of chloropicrin are heavier than air and it is toxic by inhalation. In case o< damage to. or leaking from containers of this material contact the pes ticide safety team network. Telephone; 800-424-9300 If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.! Use water in Hooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing vapors or dusts Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the oody with copious amounts of water or soap and water If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered CHLOROPRENE. INHIBITED 4907223 FLAMMABLE LIQUID UNI 991 POLYMERIZABLE Chloroprene is a clear colorless liquid. It is used to make neoprene rubber. It has a flash point of -4 deg. F. If subject to heat it may poly merize. with evolution of additional heat. If the polymerization takes place in a container, the container is subject to possible rupture It is heavier than water and slightly soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as tar a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable or container is exposed to direct (lame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered CHLOROPICRIN, LIQUID POISON B 4921414 UN1560 Chloropicnn, liquid is a colorless to yellow liquid with a strong odor. It is slightly soluble in water and is non-combustible. Its vapors are heavier than air and it is toxic by inhalation. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300 124 2-CHLOROPHOPENE 4908128 FLAMMABLE LIQUID UN2456 2-chloropropene is a clear colorless volatile liquid. It has a flash point of -4 deg. f. and a boiling point of 73 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. April 1981 MOD 000017051 If material on fire or involved in fire Do no( extinguish tire unless flow can be stooped Use water in flooding Quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If tire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet It material leaking (not on tire), downwind evacuation must be considered CHLOROSULFONIC ACID 4930204 CORROSIVE MATERIAL, ACIDIC UN1754 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Chlorosullomc acid is a colorless to yellow colored turning liquid with a pungent odor. It is decomposed by water to give hydrochloric and sulfuric acids with release of heat. It is corrosive to metals and tissue. It weighs 14.7 pounds per gallon. If material involved in fire Do not use water on material itself Use water in flooding quantities as fog Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liauid or solid material Dike suriace flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Dilute slowly with water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment April 1981 CHLOROSUNFONIC ACID-SULFUR TRIOXIDE MIXTURE CORROSIVE MATERIAL. ACIDIC 4930205 UNI 754 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000 454) Chlorosulfonic acid-sulfur trioxide mixture is a colorless to yellow fum ing liquid with a pungent odor, it is decomposed by water into hydro chloric and sulfuric acid with release of heat. It is corrosive to meiais and skin. It weighs 14.7 pounds per gallon. If material involved in fire Do not use water on material itself Use water in flooding quantities as fog Coof all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the Dody with copious amounts of water or soap ana water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed oolyurethane. or foamed concrete Absorb bulk liouid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Dilute slowly with water Environmental considerations--water spill Neutralize with agricultural lime (slaked limei. crushed limestone, or sodium bicarbonate Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment CHLORPICRIN AND NONFLAMMABLE. 4920505 NONLIQUEFIED COMPRESSED GAS MIXTURE POISON A NA1955 Chlorpicrin and nonflammable, nonliquefied compressed gas is a col orless gas with an intense penetrating odor. It is toxic by inhalation (vapor) and ingestion. It may only be shipped in cylinders. Its vapors are heavier than air. Prolonged exposure of the cylinder to fire or heat may result in the violent rupturing and rocketing of the cylinder. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities ol water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Continued on next page 125 000017062 mob Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear fult protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at len times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CHLORPYRIFOS (AGRICULTURAL INSECTICIDES, 4941123 NEC, LIQUID) ORM-A NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Chlorpyrifos is a white crystalline solid dissolved in a liquid carrier. It is used as a herbicide, it is a water emuisifiable liquid. It can cause illness by inhalation, skin absorption and or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in lire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill It dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CHLORPYRIFOS (AGRICULTURAL INSECTICIDES, 4941124 NEC, OTHER THAN LIQUID) ORM-A NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Chlorpyrifos is a white crystalline solid. It is used as a herbicide. It is a wettable powder. It can cause illness by inhalation, skin absorption and/or ingestion, in case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone: 800- 424-9300. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in lire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water 126 CHLORPYRIFOS (INSECTICIDES. OTHER THAN 4941125 AGRICULTURAL. NEC) ORM-A NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Chlorpyrifos is a white crystalline solid or the solid dissolved in a liquid earlier. It is used as a herbicide. It is a wettable powder or water emul- Sifiable liquid. It can cause illness by Inhalation, skin absorption and or ingestion. In case of damage to. or leaking from containers of this ma terial contact the pesticide safety team network. Telephone: 800-424- 9300. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap materia) at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CHROME CHLORIDE SOLUTION (CHROMOUS 4963324 CHLORIDE) ORM-E NA9102 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Chrome chloride solution is the white crystalline solid dissolved in water. It is used to make other chemicats. It is non-combustible. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) H material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 MCI) 000017053 Environmental considerations--land spill Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Apply ' universal" gelling agent to immobilize spill Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CHROME CHLORIDE SOLUTION (CORROSIVE LIQUID, 4932338 N.O.S.) CORROSIVE MATERIAL, ACIDIC UN1760 Chrome chloride solution is the blue or green colored crystals dis solved in water. The solution is corrosive to metals. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CHROMIC ACETATE 4963312 ORM-E NA9101 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Chromic acetate is a greyish green to bluish green powder. It is used in tanning and in textile dyeing. It is soluble in water. It is non combustible. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spili Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CHROME SULPHATE SOLUTION (CHROMIC 4963319 SULFATE) ORM-E NA9100 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Chrome sulphate solution is the dark green to violet crystalline material dissolved in water. It is used in paints and inks, ceramics, and In textile dyeing, it is soluble in water. It is non-combustible. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in lire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash. cement powder, sawdust, or com mercial sorbents Apply universal" gelling agent to immobilize spill April 1981 CHROMIC ACID MIXTURE, DRY 4918511 OXIDIZER, CORROSIVE NA1463 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Chromic acid mixture, dry is the mixture of the dark purplish red solid and other solid chemicals. The chromic acid is soluble in water with release of heat. The other materials may or may not be soluble in water. The material itself is noncombustible but it will accelerate the burning of combustible materials. Its solution is corrosive to metals and tissue. If material on fire or involved in fire Flood with water Apply water from as far a distance as possible If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing dusts Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Approach fire with caution Continued on next page 127 7064 hQOV CV Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked time), crushed limestone, or sodium bicarbonate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CHROMIC ACID SOLUTION 4930206 CORROSIVE MATERIAL, ACIDIC UN1755 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Chromic acid solution is a dark red colored liquid. It is soluble in water. It is corrosive to metals and tissue. It can react with combustible materials and the heat of this reaction may be sufficient to result in the ignition of the combustible material. It weighs 13.9 pounds per gallon. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash, or time Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Adjust oh to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment CHROMIC ACID, SOLID 4918510 OXIDIZER. CORROSIVE NA1463 ENVIRONMENTALLY HAZARDOUS SU8STANCE (RQ-1000 454) Chromic acid is a dark purplish red solid, it is soluble in water to form a corrosive solution. The material itself is noncombustible but it will accelerate the burning of combustible materials. Sufficient heal may be generated from the reaction with combustible materials to ignite the mass. Prolonged exposure to fire or heat can cause containers of the material to explode. If material on fire or involved in fire Flood with water Apply water from as far a distance as possible 128 If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing dusts Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CHROMIC ANHYDRIDE (See CHROMIC ACID, SOLID 4918510) CHROMIC FLUORIDE SOLUTION 4932340 CORROSIVE MATERIAL, ACIDIC UNI 757 Chromic fluoride solution is the green crystalline solid dissolved in water. It is corrosive to metals and tissue. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Wear boots, protective gioves. and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Avoid breathing fumes from burning material If contact with the material anticipated, wear full protective clothing CHROMIC FLUORIDE, SOLID 4932339 CORROSIVE MATERIAL UN1756 Chromic fluoride, solid is a green crystalline solid. It is soluble in water. It is corrosive to tissue. It material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Neutralize spilled material with crushed limestone, soda ash. or lime April 1981 mod ooi7055 Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting tires involv ing this material If contact with the material anticipated, wear full protective clothing CHROMIC SULFATE 4963314 ORM-E NA9100 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Chromic sulfate is a dark green to violet solid. It is used in ceramics, as a pigment for paint, and in textile dyeing. It is soluble in water, il is non-combustible. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Materia! itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CHROMIC TRIOXIDE (See CHROMIC ACID, SOLID 4918510) CHROMIUM RESINATE (FLAMMABLE SOLID, N.O.S.) 4916765 FLAMMABLE SOLID UN1325 Chromium resinate is a green to violet amorphous powder. It may spontaneously heat in the presence of air or moisture. This heat may be sufficient to ignite surrounding combustible materials. If material on fire or involved In fire Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CHROMIUM SULPHATE, BASIC, DRY (CHROMIC 4963317 SULFATE) ORM-E NA9100 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Chromium sulphate, basic, dry is a green solid. It is used in leather tanning. It is soluble in water. It is non-combustible. April 1961 If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CHROMOUS CHLORIDE 4963322 ORM-E NA9102 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Chromous chloride is a white crystalline solid. It is used to make other chemicals and as an oxygen absorbent. It is soluble in water. It is non combustible. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in ram or tire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CHROMYL CHLORIDE (OR) CHROMIUM 4930203 OXYCHLORIDE CORROSIVE MATERIAL, ACIOIC UN1758 Chromyl chloride is a dark red colored fuming liquid with a pungent odor. It is decomposed by water to chromic acid, hydrochloric acid, and some chlorine with release of heat. If material involved In fire Extinguish fire using agent suitable tor type ot surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Continued on next page 129 MCI) 000017056 If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing CIGARETTE LIGHTER 4905726 FLAMMABLE GAS UN1057 Cigarette lighter consists of a small device charged with a flammable gas, usually butane and equipped with an ignition device. The lighters continually leak very small amounts ot gas and therefore may not be shipped in airtight containers. If material on fire or involved in fire Use water in flooding quantities as tog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing vapors Keep upwind Approach fire with caution CIGARETTE LIGHTER 4910425 FLAMMABLE LIQUID UN1226 Cigarette lighter is a small device containing a flammable liquid fuel m a reservoir with or without absorbent packing. The fuel has a flash point of less than 100 deg. F. it is lighter than water and insoluble in water. The vapors are heavier than air. II material on fire or involved in fire Do not extinguish tire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in tire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CIGARETTE LOADS 4903510 CLASS C EXPLOSIVE Cigarette load consist of wooden pegs to which are affixed a small amount of explosive composition. 130 If material on fire or Involved in fire Flood with water Apply water from as far a distance as possible if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet CLEANING COMPOUND, IRON OR STEEL, LIQUID 4936516 (COMPOUND, CLEANING, LIQUID) CORROSIVE MATERIAL NA1760 Cleaning compounds, iron or steel, nec. liquid are various colored liquids. They are water soluble and are corrosive to metals and/or tissue. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, ana goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing CLEANING COMPOUNDS, IRON OR STEEL, DRY 4936517 (CORROSIVE SOLID, N.O.S.) CORROSIVE MATERIAL UN1759 Cleaning compounds, iron or steel, dry are various colored solids. They are water soluble and are corrosive to metals and.or tissue. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water m flooding quantities as fog Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing COAL BRIQUETTE BINDER (COMBUSTIBLE LIQUID, 4915510 N.O.S.) COMBUSTIBLE LIQUID NA1993 Coal briquette binder is a dark colored liquid with a petroleum like odor. It has a flash point between 100 and 199 deg. F. It is generally heavier than water and insoluble in water. Its vapors are heavier than air. April 1961 MCD Oonv1i 7057 If material on tire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COAL BRIQUETTE BINDER (FLAMMABLE LIQUID, 4910510 N.O.S.) FLAMMABLE LIQUID UN1993 Coal briquette binder is a dark colored liquid with a petroleum like odor. It has a flash point of less than 100 deg. F. It is generally heavier than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COAL SPRAYING OIL, PETROLEUM (PETROLEUM 4910361 OIL, N.O.S.) FLAMMABLE LIQUID NA1270 Coal spraying oil. petroleum is a dark colored liquid with a charac teristic odor. It has a flash point of less than 100 deg. F. It is generally lighter than water and is insoluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on tire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors April 1981 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COAL SPRAYING OIL, PETROLEUM (PETROLEUM 4915361 OIL, N.O.S.) COMBUSTIBLE LIQUID NA1993 Coal spraying oil. petroleum is a dark colored liquid with a charac teristic odor. It has a flash point between 100 and 199 deg. F. It is generally lighter than water and is insoluble in water. Its vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COAL TAR DISTILLATE 4910133 FLAMMABLE LIQUID UN1136 Coal tar distillate is a clear colorless to dark brownish colored liquid with an aromatic odor, it has a flash point of less than 100 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical if material not on fire and not involved in fire Keep sparks, (tames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 131 MOD 000017058 COAL TAR DISTILLATE 4915133 COMBUSTIBLE LIQUID UN1137 Coal tar distillate ts a clear colorless to dark brownish colored liquid with an aromatic odor. It has a flash ooint between 100 and 199 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical if material not on tire and not involved in tire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COAL TAR DYE. LIQUID 4936510 CORROSIVE MATERIAL NA2B01 Coal tar dye. liquid are various colored liquids or solutions of solids. They are combustible though it may require some effort to ignite them. They are corrosive to metals and or tissue. It material on tire or involved in fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material tf contact with the material anticipated, wear full protective clothing COAL TAR FIBRE SATURANT LIQUID (FLAMMABLE 4910511 LIQUID, N.O.S.) FLAMMABLE LIQUID UN1993 Coal tar fiber saturant liquid is a dark colored liquid. It has a flash point of less than 100 deg. F. It is generally heavier than water and insoluble in water. Its vapors are heavier than air. If material on tire or involved in tire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Coo) all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical 132 If material not on tire and not involved in fire Keep sparks, flames, and Other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COAL TAR FIBRE SATURANT, LIQUID 4915511 (COMBUSTIBLE LIQUID, N.O.S.) COMBUSTIBLE LIQUIO NA1993 Coal tar fibre saturant. liquid is a dark colored liquid. It has a flash point between 100 and 199 deg. F It is generally heavier than water and insoluble in water. Its vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COAL TAR LIGHT OIL FLAMMABLE LIQUID 4910134 NA1136 Coal tar light oil is a clear colorless to dark brownish colored liquid with an aromatic odor. It has a flash point of less than 100 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 00 0b April 1961 COAL TAR LIGHT OIL 4915134 COMBUSTIBLE LIQUID NA1137 Coal tar fight oil is a clear colorless to dark brownish colored liquid with an aromatic odor. It has a flash point between 100 and 199 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical tf material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COAL TAR LIGHT OIL (CRUDE LIGHT OIL OF COAL 4910135 TAR) FLAMMABLE LIQUID NA1136 Coal tar light oil (crude light oil of coal tar) is a clear colorless to dark brownish colored liquid with an aromatic odor. It has a flash point ot less than 100 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stooped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vaoors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COAL TAR LIGHT OIL (CRUDE LIGHT OIL OF COAL 4915135 TAR) COMBUSTIBLE LIQUID NA1137 Coal tar light oil (crude light oil ot coal tar) is a clear colorless to dark brownish colored liquid with an aromatic odor. It has a flash point be tween 100 and 199 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water April 1981 Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts ot water or soap and water COAL TAR NAPHTHA 4910136 FLAMMABLE LIQUID NA2553 Coal tar naphtha is a clear colorless to dark brownish colored liquid with an aromatic odor. It has a flash point of less than 100 deg. F. It is lighter than water and insoluble m water, its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may spread tire Cool all affected containers with Hooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, tlames. and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COAL TAR NAPHTHA 4915136 COMBUSTIBLE LIQUID NA2553 Coal tar naphtha is a clear colorless to dark brownish colored liquid with an aromatic odor. It has a flash point between 100 and 199 deg. F. It is lighter than water and insoluble in water. It vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of Ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 133 CB OOQo 1?06o COAL TAR NAPHTHA (COAL TAR NAPHTHA, CRUDE) 910137 FLAMMABLE LIQUID NA2553 Coal tar naphtha, crude is a clear colorless to dark brownish colored liquid with an aromatic odor, tt has a flash point of less than 100 deg. F. it is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do net extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical It material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the Dody with copious amounts of water or soap and water COAL TAR NAPHTHA (COAL TAR NAPHTHA, CRUDE) 4915137 COMBUSTIBLE LIQUID NA2553 Coal tar naphtha, crude is a dear colorless to dark brownish colored liquid with an aromatic odor. It has a Hash point between 100 and 199 deg, F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken paexages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COAL TAR NAPHTHA AND LIGHT OIL OF COAL TAR, 4915512 CRUDE (COMBUSTIBLE LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Coal tar naphtha and light oil of coal tar, crude is a clear colorless to dark colored liquid with a petroleum like odor, it has a flash point between 100 and 199 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. if materia) on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical 134 If material not on fire and not Involved In fire Keep sparks, flames, ana other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COAL TAR NAPHTHA AND LIGHT OIL OF COAL TAR. 4910512 CRUDE (FLAMMABLE LIQUID, N.O.S.) FLAMMABLE LIQUID UN1993 Coal tar naphtha and light oil of coal tar. crude is a clear colorless to dark colored liquid with a petroleum like odor. It has a flash point of less than 100 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COAL TAR OIL 4910138 FLAMMABLE LIQUID NA1136 Coal tar oil is a clear colorless to dark brownish colored liquid with an aromatic odor, it has a flash point of less than 100 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as log Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water MCI) OQq l7oe>i April 1981 COAL TAR OIL 4915138 COMBUSTIBLE LIQUID NA1137 Coal tar oil is a clear colorless to dark brownish colored liquid with an aromatic odor. It has a Hash point between 100 and 199 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, fiames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COAL TAR OIL (COAL TAR OIL, CRUDE, NEC) 4910139 FLAMMABLE LIQUID NA1136 Coal tar oil, crude, nec is a clear colorless to dark brownish colored liquid with an aromatic odor. It has a flash point of less than 100 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COAL TAR OIL (COAL TAR OIL, CRUDE. NEC) 4915139 COMBUSTIBLE LIQUID NA1137 Coal tar, oil. crude, nec is a clear colorless to dark brownish colored liquid with an aromatic odor. It has a flash point between 100 and 199 deg. F. It is lighter than water and insoluble m water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use (oam, carbon dioxide or dry chemical April 1981 If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COAL TAR OIL, CRUDE, NEC (CORROSIVE LIQUID. 4931412 N.O.S.) CORROSIVE MATERIAL, ACIDIC UN1760 Coal tar oil. crude, nec, is a dark colored liquid with a creosote odor. It is combustible though it may take some effort to ignite. It is lighter than water and is partially soluble in water. It is corrosive to tissue. If material on fire or involved In fire Use water in Hooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use `'alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing COAL TAR OIL. CRUOE, NEC (CORROSIVE SOLID. 4931413 N.O.S.) CORROSIVE MATERIAL. ACIDIC UN1759 Coal tar oil, crude, nec, is a dark colored solid with a creosote odor. It is combustible. It is heavier than water and is partially soluble in water. It is corrosive to tissue. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear tull protective clothing 135 MOD 000017062 COAL TREATING COMPOUNDS, OTHER THAN 4915330 PETROLEUM, NEC, LIQUID (COMBUSTIBLE LIQUID) COMBUSTIBLE LIQUIO NA1993 Coal treating compounds, other than petroleum, nee. liquid are vari able colored liquids. They have a flash point between 100 and 199 deg. F. They are generally Insoluble in water and heavier than water. Their vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COAL TREATING COMPOUNDS, OTHER THAN 4910330 PETROLEUM. NEC, LIQUID (FLAMMABLE LIQUID. N.O.S.) FLAMMABLE LIQUID UN1993 Coal treating compounds, other than petroleum, nec. liquid are vari able colored liquids. They have a flash point of less than 100 deg. F. They are generally insoluble in water and heavier than water. Their vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities ol water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts ol water or soap and water COAL, GROUND BITUMINOUS, SEA COAL, COAL 4917307 FACINGS. ETC. FLAMMABLE SOLID NA1361 Coal, ground bituminous is powdered coal. It must be stored for six days after grinding, else it must be shipped in tight metal containers or cars. If not stored it is liable to spontaneous heating and ignition. If material on fire or involved in fire Use dry chemical or carbon dioxide Use water only if flooding quantities are available If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material dry 136 COATING SOLUTION 4910142 FLAMMABLE LIQUID UN1139 Coating solution is a solution of various gums and resins in various solvents. The liquids are generally quite thick and may range from clear colorless to black "tar ". The flash point depends on the solvent used but it will be less than 100 deg. F. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use 'alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COBALT RESINATE, PRECIPITATED 4916705 FLAMMABLE SOLID UN1318 Cobalt resinate. precipitated is a reddish brown powder, it is used a drier in paints. If it comes in contact with air. spontaneous heating may result. This heat may be sufficient to ignite the material itself or sur rounding combustible material. It is insoluble in water. If material on fire or involved in fire Use water in flooding quantities as tog Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COBALTOUS BROMIDE 4963710 ORM-E NA9103 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RCM000/454) Cobaltous bromide is a red violet crystalline solid. It is used as a catalyst in the production of other chemicals, it is soluble in water. It is non-combustible. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Peraonnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water April 1981 MOD 000017063 Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium Dicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates COBALTOUS FORMATE 4963327 ORM-E NA9104 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000454) Cobaltous formate is a red crystalline solid. It is used to make caiaiysts for use in chemical manufacture. It is soluble in water, (t >s non combustible. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving m ram or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates COBALTOUS SULFAMATE 4963329 ORM-E NA9105 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000 454) Cobaltous sulfamate is a. It is used for electroplating metals. It is soluble in water. It is non-combustible. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Matenal itself does not burn or burns with difficulty.) If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in ram or fire fighting water Environmental considerations--water spill Add calcium hypochlorite Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates April 1981 COCCULUS. SOLID 4921418 POISON B UNI 564 Cocculus. solid is a dried fruit. It is toxic by ingestion If material on fire or Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing COCOA BEAN SHELLS. (FLAMMABLE SOLID. N.O.S.) 4917387 FLAMMABLE SOLID UN1325 Cocoa bean shells are in the form of brown leaves or flakes'. If the shells are not cooled after processing, or dried too much, or appre ciable oil is left behind in processing, they are liable to spontaneous heat ing and ignition. If material on fire or involved in fire Flood with water If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away COLLiDIENE (COMBUSTIBLE LIQUID, N.O.S.) 4913173 COMBUSTIBLE LIQUID NAI993 Collidiene is a clear colorless liquid. It is used to make other chemicals. It has a flash point of 135 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing QOO 0&4 137 COLLODION 4910144 FLAMMABLE LIQUID NA2059 Collodion is a solution of nitrocellulose tn a mixture of ether and ethyl alcohol. Its flash point may vary but it is well below 100 deg. F. The film deposited by the evaporation of the solvent is easily ignited and once ignited burns with great rapidity. If the fire is confined, and large quantities of material are involved, an explosion may result. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material COMBUSTIBLE LIQUID, N.O.S. COMBUSTIBLE LIQUID 4915165 NA1993 Combustible liquid, n.o.s. is the proper shipping name for those ma terials having a closed cup flash point between tOO and 199 deg. F. and not specifically mentioned in the hazardous materials regulations. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water trom as tar a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Peraonnei protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing COMBINATION FUZE 4903205 CLASS C EXPLOSIVE Combination fuze is a device used for detonating the bursting charge of a projectile. It has both a percussion mechanism and a time delay mechanism. If material on fire or involved in fire Flood with water Apply water from as far a distance as possible If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet COMMON FIREWORKS 4903520 CLASS C EXPLOSIVE Common fireworks are fireworks devices suitable for use by the public and designed primarily to produce visible effects by combustion. Some small devices designed to produce audible effects are also included in this description. If material on fire or involved in fire Flood with water Apply water from as far a distance as possible If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet COMBINATION PRIMER 4903210 CLASS C EXPLOSIVE Combination pnmer is a device employing both a percussion element and an electrical element either of which can be used to make the device function. If material on fire or involved in fire Flood with water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet COMPOUND, CLEANING, LIQUID 4936515 CORROSIVE MATERIAL NA1760 Compound, cleaning, liquid is a variable colored liquid. The compound is generally water soluble. It is corrosive to metals and/or tissue. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary 138 April 1981 mcd 00o170r, jO Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing COMPOUND, CLEANING. LIQUID 4910147 FLAMMABLE LIQUID NA1993 Compound, cleaning, liquid is a variable colored liquid with a petro- leumlike odor. Its has a flash point of less than 100 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on tire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COMPOUND, CLEANING, LIQUID 4915147 COMBUSTIBLE LIQUID NA1993 Compound, cleaning, liquid is a variable colored liquid with a petro leum like odor. It has a flash point between 100 and 199 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 COMPOUND, CLEANING. LIQUID (CONTAINING 4930209 HYDROCHLORIC (MURIATIC) ACID) CORROSIVE MATERIAL, ACIDIC NA1769 Compound, cleaning, liquid (containing hydrochloric (muriatic) acid) are various colored liquids with a pungent odor. It is soluble in water with release of some heat. It is corrosive to metals and/or tissue. If material on tire or Involved in fire Do not use water on material itself Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing COMPOUND, CLEANING, LIQUID (CONTAINING 4930210 HYDROFLUORIC ACID) CORROSIVE MATERIAL, ACIDIC NA1790 Compound, cleaning, liquid (containing hydrofluoric acid) are various colored liquids with a pungent odor. They are soluble in water with the release of some heat. They are corrosive to metals and. or tissue. Skin contact with fumes or small quantities of material for short periods of time can cause severe painful burns. If material on fire or involved in fire Do not use water on material itself Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use loam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible H material not on fire and not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear lull protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COMPOUND, CLEANING. LIQUID (CONTAINING 4936520 PHOSPHORIC OR ACETIC ACIDS) CORROSIVE MATERIAL, ACIDIC NA1760 Compound, cleaning, liquid (containing phosphoric or acetic acids) are various colored liquids, generally odorless if containing phosphoric acid and having a vinegar tike odor, if containing acetic acid. They are soluble in water with evolution of heat. They are corrosive to metals and tissue. Continued on next page 139 MCI) 000017066 If material involved in fire Extinguish tire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Apply water from as far a distance as possible If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing COMPOUND, CLEANING. LIQUID (CONTAINING 4936521 SOOIUM OR POTASSIUM HYDROXIDE) CORROSIVE MATERIAL, BASIC NA1760 Compound, cleaning, liquid (containing sodium or potassium hydrox ide) are various colorea liquids. They are soluble in water with evolution of heat. They are corrosive to metals and tissue. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing COMPOUND, ENAMEL 4910150 FLAMMABLE LIQUID NA1263 Compound, enamel is a variable colored "paint" like iiauid. It has a flash point of less than 100 deg. F. It is usually lighter than water and is insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 140 Hen Ooor0j l7(>87 COMPOUND, LACQUER. PAINT OR VARNISH 4936535 REMOVING LIQUID CORROSIVE MATERIAL, BASIC, COMBUSTIBLE NA1760 Compounds, lacquer, paint or varnish removing liquid are various colored materials. They are corrosive to metals and or tissue. If material on fire or involved in fire Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use 'alcohol" foam, carbon dioxide or dry chemical It material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing COMPOUND, LACQUER. PAINT. OR VARNISH. 4915153 REMOVING, REDUCING OR THINNING COMBUSTIBLE LIQUID NA1142 Compound, lacquer, paint, or varnish, removing, reducing or thinninc are generally clear colorless liquids. Their flash point is between 100 and 199 deg. F. Most of these compounds are lighter than water and insoluble in water. Their vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire uniess flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources ana sewers Build dikes to contain tiow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COMPOUND. LACQUER. PAINT, OR VARNISH. 4910153 REMOVING, REDUCING OR THINNING, FLAMMABLE LIQUID NA1142 Compound, lacquer, paint, or varnish, removing, reducing or thinning are generally clear colorless liquids. Their flash point is less than 100 deg. F. Most of these compounds are lighter than water and insoluble in water. Their vapors are heavier than air. April 1961 If material on fire or Involved in fire Do not extinguish tire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COMPOUND, POLISHING, LIQUID 4910155 FLAMMABLE LIQUID NA1142 Compound, polishing, liquid is usually a variable colored liquid con taining an undissolved solid. It -has a flash point of less than too deg. F. It is lighter than water and generally insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COMPOUND, TREE (OR) WEED KILLING. LIQUID 4936532 CORROSIVE MATERIAL NA1760 Compound, tree (or) weed killing, liquid is a variable colored liquid. It may either be a solution of solid material in a liquid or a simple liquid or mixture of liquids. It may be combustible though requiring some effort to ignite. It is usually soluble in water. It is corrosive to metals and or tissue. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as log Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary April 1961 Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing COMPOUND, TREE OR WEED KILLING. LIQUID 4910157 FLAMMABLE LIQUID NA1993 Compound, tree or weed killing, liquid is a variable colored liquid It has a flash point of less than 100 deg. F. most of these materials are lighter than water. Its vapors are heavier than air. If material on lire or involved in fire Do not extinguish fire unless flow can be stooped Use water in flooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in tire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COMPOUND. TREE OR WEED KILLING. LIQUID 4915157 COMBUSTIBLE LIQUID NA1993 Compound, tree or weed killing, liquid is a variable colored liquid. It has a flash point between 100 and 199 deg. F. Most of these materials are lighter than water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing 141 ooooi^68 COMPOUND, TREE OR WEED KILLINGS, SOLID 4918405 OXIDIZER NA1479 Compound, tree or weed killing, solid are various solid materials. They may or may not burn, but if mixed with combustible materials they will accelerate their burning. Prolonged exposure of these materials and or their containers to fire or heat may result in an explosion. If material on fire or involved In fire Rood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Approach lire with caution Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet COMPOUND, VULCANIZING, LIQUID 4910162 FLAMMABLE LIQUID NA1142 Compound, vulcanizing, liquid is a variable colored liquid. It has a Mash point of less than 100 deg. F. The hazard of this material is flammability. If material on fire or involved in fire Do not extinguish tire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol- foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain fiow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COMPOUND, VULCANIZING, LIQUID 4936534 CORROSIVE MATERIAL NA1760 Compound, vulcanizing, liquid are various colored materials. They are corrosive to metals and/or tissue. If material on fire or Involved in fire Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol - foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material 142 Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing COMPOUNDS CAULKING OR GLAZING 4915450 (COMBUSTIBLE LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Compounds caulking or glazing are materials containing a solvent having a closed cup flash point between 100 and 199 deg. F. The hazard of these materials is combustibility. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in Hooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COMPOUNDS CAULKING OR GLAZING (FLAMMABLE 4910450 LIQUID, N.O.S.) FLAMMABLE LIQUID UN1993 Compounds caulking or glazing are materials containing a solvent having a closed cup flash point of less than 100 deg. F. The hazard of these materials is flammability. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams ot water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COMPOUNDS GAS PURIFYING (FLAMMABLE SOLID, 4917396 N.O.S.) FLAMMABLE SOLID UN1325 Compounds gas purifying are various colored solid materials having the property of being readily ignited by external sparks or flame am when so ignited burns vigorously and persistently April 1961 MOD 000017069 If material on fire or involved In fire Flood with water If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Build dikes to contain flow as necessary Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Avoid breathing dusts, and fumes from burning material COMPOUNDS METAL PURIFYING, NEC (POISONOUS 4923390 SOLID, N.O.S.) POISON B NA2811 Compounds metal purifying are various colored solid materials. They may or may not be water soluble. They are toxic by ingestion, inhalation (dusts), or by skin absorption. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing COMPOUNDS. CASE CARBURIZING OR HARDENING. 4923391 NEC (POISONOUS SOLID, N.O.S.) POISON B NA2811 Compounds, case .carburizing or hardening, nec are various colored solids frequently containing some cyanide. The material is toxic by inges tion. Cyanides are decomposed by acids giving off hydrogen cyanide a flammable poison gas. Cyanides are also toxic by skin absorption through open wounds and by inhalation ot the hydrogen cyanide from decomposition. If material Involved In fire Extinguish fire using agent suitable for type ot surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting tires involv ing this material If contact with the material anticipated, wear full protective clothing April 1981 COMPOUNDS, CASE HARDENING OR CARBURIZING. CHARCOAL, COAL, OR COKE BASE (POISONOUS SOLID, N.O.S.) 4923392 POISON B NA2811 Compounds, case hardening or carburizing, charcoal, coal or coke base are black solids frequently containing some cyanide. The material is toxic by ingestion. Cyanides are decomposed by acids giving off hydrogen cyanide a flammable poison gas. Cyanides are also toxic by skin absorption through open wounds, and by inhalation of hydrogen cyanide from the decomposition of the material. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical if material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when lighting fires involv ing this material If contact with the material anticipated, wear full protective clothing COMPOUNDS, HECTOGRAPH (COMBUSTIBLE 4915470 LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Compounds, hectograph are materials containing a solvent having a closed cup flash point between 100 and 199 deg. F. The hazard of these materials is combustibility. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COMPOUNDS, HECTOGRAPH (FLAMMABLE LIQUIO, 4910470 N.O.S.) FLAMMABLE LIQUIO UN1993 Compounds, hectograph are materials containing a solvent having a closed cup flash point of less than 100 deg. F. The hazard df these materials is flammability. Continued on next page KCD OOQ 1?07q 143 If material on fire or involved In fire Do not extinguish tire unless flow can be stopped Use water in flooding Quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts ot water or soap and water COMPOUNDS. IRON OR STEEL RUST PREVENTING. 4915184 OTHER THAN PETROLEUM, NEC (RUST PREVENTIVE COATING) COMBUSTIBLE LIQUID NA1142 Compounds, iron or steel rust preventing other than petroleum, nec are thick variable colored liquids having an odor of paint. They have a flash point between 100 and 199 deg. F. They are insoluble in water and are heavier than water. Their vapors are heavier than air. if material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COMPOUNDS. LEATHER FINISHING. NEC 4915472 (COMBUSTIBLE LIQUID. N.O.S.) COMBUSTIBLE LIQUID NA1993 Compounds, leather finishing, nec is a material containing a solvent having a closed cup flash point between 100 and 199 deg. F. The hazard of this material is combustibility. If material on fire or involved In fire Do not extinguish fire unless How can be stopped Use water in flooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors 144 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material COMPOUNDS. LEATHER FINISHING, NEC 4910472 (FLAMMABLE LIQUID, N.O.S.) FLAMMABLE LIQUID UN1993 Compounds, leather finishing, nec is a material containing a solvent having a closed cup flash point of less than 100 deg. F. The hazard of this material is flammablility. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COMPOUNDS. PETROLEUM TREATING. CRUDE. NEC 4936563 (ACID. LIQUID, N.O.S.) CORROSIVE MATERIAL UN1760 Compounds, petroleum treating, crude, nec are various colored liq uids. They are corrosive to metals and tissue. They may burn though it may require some effort to ignite. If material on fire or involved in fire Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material if contact with the material anticipated, wear full protective clothing April 1981 mod 00l707j COMPOUNDS, PETROLEUM TREATING, CRUDE, NEC 4910349 (FLAMMABLE LIQUID. N.O.S.) FLAMMABLE LIQUID UNI 993 Compounds, petroleum treating, crude, nec are various colored liq uids. They have a flash point of less than 100 deg. F. They are generally lighter than water and soluble in water. Their vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use '`alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COMPOUNDS. RUST PREVENTING (OR) COMPOUND 4936530 RUST REMOVING CORROSIVE MATERIAL NA1760 Compounds rust preventing or compound rust removing are various colored liquids. They are soluble tn water with evolution of heat. They are corrosive to metals and tissue. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing COMPOUNDS. STONE STENCIL. IN SHEET FORM 4936571 (CORROSIVE SOLID. N.O.S.) CORROSIVE MATERIAL UN1759 Compounds, stone stencil in sheet form are various materials im pregnated in paper or cloth. These compounds have the property of being corrosive to tissue. They may or may not be water soluble. The sheets may be combustible. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog April 1981 If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COMPOUNDS, TREE OR WEED KILLING. LIQUIO 4921419 POISON B NA2810 Compound, tree or weed killing, liquid are various materials or solu tions that have the property of being toxic by ingestion, inhalation or skin absorption. If material on fire or involved in fire Do not extinguish tire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not involved in tire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COMPOUNDS, WALL OR WALL PAPER CLEANING 4910414 (COMPOUND, CLEANING, LIQUID) FLAMMABLE LIQUID NA1993 Compounds, wall or wall paper cleaning contain a flammable liquid. The flash point is less than 100 deg. F. The hazard is flammability. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages Wfthout protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 145 MCI) 00001707 COMPOUNDS. WALL OR WALL PAPER CLEANING 4915414 (COMPOUND. CLEANING, LIQUID) COMBUSTIBLE LIQUID NA1993 Compounds, wall or wall paper cleaning contain a combustible liquid. The Hash point is between 100 and 199 deg. F. The hazard is combustibility. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use 'alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COMPOUNDS, WATER SYSTEM RUST OR SCALE 4936546 PREVENTING. DRY (CORROSIVE SOLID. N.O.S.) CORROSIVE MATERIAL UN1759 Compounds, water system rust or scale preventing, dry are various colored solid materials. They are water soluble. They are corrosive to tissue. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing COMPRESSED GAS, N.O.S. 4905710 FLAMMABLE GAS UN1954 Compressed gases, n.o.s. are materials which are shipped in con tainers under pressure. They may be mixtures of flammable and non flammable gases. With the mixture having flammable properties. The gas is easily ignited. The mixture may separate with the flammable gas settling in low areas, or the nonflammable gas settling in low areas, it may only be shipped in cylinders A flame may flash back to the source of leak very easily. Under fire conditions the cylinders may violently rupture and rocket. If the cylinder is an aerosol it will violently rupture under fire conditions. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Coot all affected containers with flooding quantities of water Apply water from as far a distance as possible 146 If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered COMPRESSED GAS. N.O.S. 4904515 NONFLAMMABLE GAS UN1956 Compressed gases, n.o.s. are materials which are shipped in con tainers under pressure. They may be mixtures consisting of a nonflamm able gas(es) and a flammable gaslesi with the mixture having nonflamm able properties. The mixture may separate with the flammable gas settling in low areas, or the nonflammable gassettling into low areas. It may asphyxiate by the displacement ot air. It may only be shipDed in cylinders. If the cylinder is an aerosol container, it can rupture and rocket under fire conditions. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Do not use water on material itself Use water spray to absorb vapors If material not involved in fire Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered COPPER ACETATE (VERDIGRIS) (CUPRIC ACETATE) 4962310 ORM.E NA9106 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10045.4) Copper acetate is a blueish greenish crystalline solid. It is used as an insecticide, in the preparation ot other chemicals, as a fungicide, and mildew preventive. It is soluble in water. It is non-combustible. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary MOD 00017073 April 1981 Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates COPPER ACETOARSENITE, SOLIO 4923220 POISON B UN15B5 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Copper acetoarsenite, solid is an emerald-green powder. It is insoluble in water. It is toxic by inhalation (dust) and by ingestion. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material tf contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates COPPER ARSENITE, SOUD 4923221 POISON B UN1586 Copper arsenite. solid is a light green powder. It is insoluble in water. It is toxic by ingestion. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind April 1981 Avoid bodily contact with the matenal Wear boots, protective gloves, and goggles Oo not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear lull protective clothing COPPER BASED PESTICIDE. LIQUID, N.O.S. 4923331 (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL. NEC) POISON B UN2775 Copper based pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The carrier may burn though it may require some effort to ignite. It is toxic by inhalation, skin absorption, and'or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800- 424-9300. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the matenal Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COPPER BASED PESTICIDE. LIQUID, N.O.S. 4923332 (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES. NEC, LIQUID) POISON B UN2775 Copper based pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The carrier may burn though it may require some effort to ignite. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone: 800- 424-9300. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Pereonnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water MCD 000017074 147 COPPER BASED PESTICIDE. LIQUID, N.O.S. 4910506 (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES. NEC, LIQUID) FLAMMABLE LIQUID UN2776 Copper based pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The primary hazard of this material is the flammability of the carrier. It has a flash point below 100 deg. F. It can cause illness by inhalation, skin absorption and or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300. It material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use 'alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wear self-contained breathing apparatus when fighting fires involv ing this material COPPER BASED PESTICIDE. SOLID, N.O.S. 492333 (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES. NEC. OTHER THAN LIQUID) POISON B UN2775 Copper based pesticide is a solid or a liquid absorbed on a dry carrier. It is a wettable powder. It is toxic by inhalation, skin absorption, and or ingestion. In case of damage to. or ieaking from containers of this ma terial contact the pesticide safety team network. Telephone: 800-424- 9300. If material on fire or Involved in fire Extinguish lire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soao and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing COPPER BASED PESTICIDE. LIQUID, N.O.S. 4910505 (COMPOUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AGRICULTURAL. NEC) FLAMMABLE LIQUID UN2776 Copper based pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The primary hazard of this material is the flammability of the earner. It has a flash point below 100 deg. F. It can cause illness by inhalation, skin absorption and or ingestion, in case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with Hooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, caroon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wear self-contained breathing apparatus when fighting fires involv ing this material COPPER BASED PESTICIDE, SOLID, N.O.S. 4923333 (COMPOUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AGRICULTURAL. NEC) POISON B UN2775 Copper based pesticide is a solid or a liquid absorbed on a dry carrier, it is a wettable powder. It is toxic by inhalation, skin absorption, and or ingestion, in case of damage to. or leaking from containers of this ma terial contact the pesticide safety team network. Telephone: 800-424- 9300. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical H material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear lull protective clothing COPPER CHLORIDE 4944173 ORM-B UN2802 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10 4.54) Copper chloride is a yellowish brown powder or a green crystalline it is useto manufacture other chemicals, in dyeing, in printing, in fun gicides. as a wood preservative, and for many other uses. It is soluble in water. It is non-combustible. It is corrosive to aluminum. 148 April 1981 MCD 00 0017o 7s If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not Durn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates COPPER CYANIDE 4923418 POISON B UN1587 Copper cyanide is a green powder. It is insoluble in water. II is de composed by acids to give off hydrogen cyanide, a flammable ooison gas. It is toxic by skin absorption through open wounds, by ingestion, and by inhalation of hydrogen cyanide from decomposition of the ma terial. Toxic oxides of nitrogen are produced in fires involving this material. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use foam, carbon dioxide or dry chemical Do not use water on material itself If large quantities of combustibles are involved, use watenn Hooding quantities as spray and fog Use water spray to absorb vapors If material not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Use water spray to knock-down vapors Do not use water on material itself Personnel protection Avoid breathing vapors or dusts Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full prolective clothing COPPER NAPHTHANATE PETROLEUM SOLUTION. 4910516 NOT MORE THAN 8% COPPER NAPHTHANATE (FLAMMABLE LIQUID. N.O.S.) FLAMMABLE LIQUID UN1993 Copper naphthanate petroleum solution is a green colored liquid with a petroleum like odor. It has a flash point of less than 100 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire uniess flow can be stooped Use water in flooding quantities as fog Solid streams of water may spread fire April 1981 Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use ' alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COPPER NAPHTHANATE SOLUTION. NOT MORE 4915516 THAN 8% COPPER NAPHTHANATE (COMBUSTIBLE LIQUID. N.O.S.) COMBUSTIBLE LIQUID NA1993 Copper naphthanate solution is a green colored liquid with a petroleum like odor. It has a flash point between 100 and 199 deg. F. it is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire uniess flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of waier Apply water from as far a distance as possible Use "alcohol' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COPPER NITRATE SOLUTION (CUPRIC NITRATE) 4918745 OXIDIZER NA1479 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100 45.4) Copper nitrate solution is a blue crystalline solid dissolved in water. It is used in medicine, as an insecticide, in chemical analysis, in making light sensitive papers, and for many other uses. It is noncombustibie. but it wiil accelerate the burning of combustible materials. If large quan tities of the material are involved or the material is finely divided, an explosion may result. Prolonged exposure to fire or heat may result in an explosion. Toxic oxides of nitrogen are produced in fires involving this material. If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Continued on nextpege 149 Mod 0000i?0?6 Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain hauid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime'i. crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates COPPER RESINATE. (FLAMMABLE SOLID, N.O.S,) 4916762 FLAMMABLE SOLID UNI 325 Copper resinate is a green amorphous powder. It may spontaneously heat in the presence of air and moisture. This heat may be sufficient to ignite nearby combustible material. It is insoluble in water. If material on fire or involved in fire Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COPPER SULFATE AND LIME COMBINED, DRY 4961317 (CUPRIC SULFATE) ORM-E NA9109 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-10/4.S4) Pentachlorophenol is a white powder or crystalline solid or. fused in copper sulfate is blue and lime is white. It is used as an agricultural soil is slightly soluble in water. It is non-combustible. Is non-combustible. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates 150 COPPER SULPHATE AND SULPHUR (CUPRIC 496131 ' SULFATE) ORM-E NA9109 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10 4.54) Copper sulphate and sulphur is a solid; copper sulfate is blue and suiter is yellow. It is used as an agricultural fungicide. The copper sulfate is soluble in water sulphur is not soluble in water. It is non-combustible. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itseif does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in ram or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CORDEAU DETONANT FUSE 4903341 CLASS C EXPLOSIVE Cordeau detonant fuse is a fuse containing a core of pentaerythrite tetranitrate or cyclotrimethylene-tnnitramine not exceeding 400 grains per linear foot, overspun with tapes, yarns, plastics, or waterproofing compounds. If material on fire or involved in fire Dangerously explosive Flood with water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet CORES OR CORE ASSEMBLIES OR FUEL BLANKET 4926445 ASSEMBLIES, NUCLEAR REACTOR. NOT IRRADIATED, WITH NON-IRRADIATED FUEL, (RADIOACTIVE MATERIAL, N.O.S.) RADIOACTIVE MATERIAL NA9181 Cores or core assemblies or fuel blanket assemblies, nuclear reactor, not irradiated, with non-irradiated fuel, are sealed metal tubes or tube assemblies containing the fuel. Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful, whereas film may be damaged by radiation from relatively low concentrations. April 1981 OO0 7? If material on fire or involved in fire Contact the local, state, or department of energy radiological re sponse team Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Coof all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Contact the iocai. state, or department of energy radiological re sponse team Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Keep upwind Avoid breathing fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation Keep unnecessary people out of incident area until area declared safe by radiological response team If material on fire or Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing CORROSIVE LIQUID, N.O.S. 4936540 CORROSIVE MATERIAL UN1760 Corrosive liquid, n.o.s. is a liquid that can cause visible destruction or irreversible alterations in human skin tissue at the site of contact, or in the case of leakage from its packaging a liquid that has a severe corrosion rate on steel. It may be combustible though it may require some effort to ignite. It may or may not be water soluble. If material on fire or Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out o< water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing CORROSIVE LIQUID. POISONOUS, N.O.S. 4936015 CORROSIVE MATERIAL,POISONOUS UN2922 Corrosive liquid, poisonous, n.o.s. Is a liquid that can cause visible destruction or irreversible alterations in human skin tissue at the site of contact, or in the case of leakage from its packaging a liquid that has a severe corrosion rate on steel, is is also toxic by ingestion, inhalation, or by skin absorption. It may be combustible though it may require some effort to ignite. It may or may not be water soluble. April 1981 CORROSIVE SOLID, N.O.S. 4936545 CORROSIVE MATERIAL UN1759 Corrosive solid, n.o.s. is a variable colored material that can cause visible destruction or irreversible alteration in human skin tissue at the site of contact. It may be combustible though requiring some effort to ignite, it may or may not be water soluble. If material on fire or involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing COSMETICS, N.O.S. 4917377 FLAMMABLE SOLID NA132S Cosmetics, n.o.s. is the proper shipping name of any solid material, other than one classed as an explosive, or specifically listed by name in the list of hazardous materials which is liable under conditions incident to transportation to cause fires through friction, absorption of moisture, spontaneous chemical changes as a result of retained heat from the manufacturing or processing of the solid, or which can be readily ignited by external sparks or flame and when so ignited bums vigorously and per sistenlly. Try to ascertain the exact name of the material. H material on fire or Involved in fire Extinguish fire using agent suitable for type of fire Continued on next page 151 HOD 00i707e If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Build dikes to contain flow as necessary Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COSMETICS, N.O.S. 4918411 OXtOtZER NA1479 Cosmetics, n.o.s. are various materials which have the property of accelerating the burning of combustible material. These materials may not bum by themselves. Prolonged exposure of these materials and or their containers to fire or heat may result in an explosion. These materials may only be shipped in containers of 55 gallon capacity or less. If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Approach fire with caution Evacuation If fire becomes uncontrollable--evacuate tor a radius of 1500 feet COSMETICS. N.O.S. 4910192 FLAMMABLE LIQUIO NA1993 Cosmetics, n.o.s. is the proper shipping name for those materials having a closed cup Hash point ol less than 100 deg. F. and not spe cifically mentioned in the hazardous materials regulations. The hazard is flammability. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 152 COSMETICS, N.O.S. 4915192 COMBUSTIBLE LIQUID NA1993 Cosmetics, n.o.s. is the proper shipping name for those materials having a closed cup flash point between 100 and 199 deg. F. and not specifically mentioned in the hazardous materials regulations. The haz ard is combustibility. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ali affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water COSMETICS, N.O.S., LIQUID CORROSIVE MATERIAL 4936551 NA1760 Cosmetics, n.o.s.. liquid is the proper shipping name for various col ored liquids having the property of being corrosive to steel or tissue. It may either be a simple liquid material or a solid material dissolved in a solvent. It may be combustible though requiring some effort to ignite. They may or may not be water soluble. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing COSMETICS, N.O.S., SOLID 4936552 CORROSIVE MATERIAL NA1759 Cosmetics, n.o.s.. solid is the proper shipping name for various colored solids having the property of being corrosive to tissue. They may or may not be water soluble. April 1981 MOD 000017079 If material on fire or involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing COTTON WASTE. OILY (WITH MORE THAN 5% 4917415 ANIMAL OR VEGETABLE OIL) FLAMMABLE SOLID UN1364 Cotton waste, oily is material contaminated, coated or impregnated with animal or vegetable oil. It is liable to spontaneous heating and ignition. If material on fire or involved In fire Flood with water if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away COUMAPHOS 4921505 POISON B NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10/4.54) Coumaphos is white to light brown crystalline solid. It is combustible and is insoluble in water. It is toxic by ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300 If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Environmental considerations--isnd spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates April 1981 COUMAPHOS MIXTURE. LIQUID (AGRICULTURAL 4921506 INSECTIDES, NEC, LIQUID) POISON B NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10 4.54) Coumaphos mixture, liquid is the white to light brown crystalline solid dissolved in a liquid carrier, it is combustible and is insoluble in water, it is toxic by ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300 If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting tires involv ing this material Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CREOSOTE. COAL TAR 4915363 COMBUSTIBLE LIQUID NA1993 Creosote, coal tar is a yellowish to dark green colored liquid with a characteristic odor. It is used as a wood preservative and as a disin fectant. It has a flash point in the range of 120 to 180 deg. F. It is heavier than water and insoluble in water, its vapors are heavier than air. If material on fire or involved in fire Do not extinguish tire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing 153 MCD 000017080 CRESOL 4931417 CORROSIVE MATERIAL. ACIDIC. COMBUSTIBLE UN2076 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000'454) Cresylic acid is a colorless to yellow liquid with a tar-like odor. It is combustible and has a flash point of 170 deg. F. It is insoluble in water. It is corrosive to tissue. It weighs 8.7 pounds per gallon. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash. cement powder, sawdust, or com mercial sorbents Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dreoges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment CROTONALDEHYDE 4909137 FLAMMABLE LIQUID UN1143 POLYMERIZABLE ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Crotonaldehyde is a clear, colorless to straw colored liquid with a penetrating pungent odor. It has a flash point of 55 deg. F. If sublet to heat it may polymerize. If polymerization takes place in a container the container may violently rupture. It is lighter than water and slightly soluble in water, its vapors are heavier than air. It weighs 7.1 pounds per gallon. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in Hooding quantities as tog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid 154 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any materia) which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, loamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Apply fluorocarbon-water foam to diminish vapor and fire hazard Add sodium bisulfite (nahso3) Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e.g. detergent, soaps, alcohols) to com press and thicken spilled material Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors CROTONIC ACID 4931418 CORROSIVE MATERIAL, ACIDIC. COMBUSTIBLE UN2823 Crotomc acid is a white crystalline solid. It is combustible and has a flash point of 190 deg. F. It is soluble in water. It is corrosive to metals and tissue. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical 11 material not on fire and not involved In lire Keep material out of water sources and sewers Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing CROTONYLENE FLAMMABLE LIQUID 4909138 UN1144 Crotonylene is a clear colorless liquid with a petroleum like odor. It has a flash point of less than -4 deg. F. and a boiling point of 61 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. ft material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors April 1981 MCD 000017081 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CRUDE NITROGEN FERTILIZER SOLUTION (MORE 4904240 THAN 25.3 PSIG) NONFLAMMABLE GAS, CORROSIVE NA1043 Crude nitrogen fenilizer solution is the aqueous solution of nitrogen fertilizer charged with ammonia gas having an absolute pressure ex ceeding 40 psi at 70 deg. F. in the container, the solution is corrosive. Although ammonia is lighter than air. the vapors from a leak initially hug the ground. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use water spray to absorb vapors If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and gas tight goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Evacuation if material leaking (not on fire), downwind evacuation must be considered CRUDE OIL. PETROLEUM 4910165 FLAMMABLE LIQUID UN1267 Crude oil. petroleum is dark viscous liquid. It has a flash point of less than 100 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water tn flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 CRUDE OIL, PETROLEUM 4915165 COMBUSTIBLE LIQUID UN1267 Crude oil. petroleum is a dark viscous liquid. It has a flash point between 100 and 199 deg. F- It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective eouipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CUMENE (COMBUSTIBLE LIQUID. N.O.S.) 4913125 COMBUSTIBLE LIQUID NA1993 Cumene is a clear colorless liquid with an aromatic odor. It has a flash point of 111 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish tire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CUMENE HYDROPEROXIDE 4919525 ORGANIC PEROXIDE UN2116 Cumene hydroperoxide is a colorless to pale yellow colored liquid. It must be shipped as a solution not exceeding 96% m a non-volatile solvent. The solution may take some effort to ignite but once ignited it bums with increasing vigor as the fire progresses, it strongly supports the burning of combustible material. Containers of the solution if exposed to fire or flame may explode. Solutions of 90% peroxide in a non-volatile solvent may be shipped in tank cars. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical Continued on next page 155 MCI) OOf`0 1 ?f)po If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep materia) out of water sources and sewers Build dikes to contain ftow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear seif-contained breathing apparatus when fighting fires involv ing this material It contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CUPRIC NITRATE 4918744 OXIDIZER NA1479 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Cupric nitrate is a blue crystalline solid. It is used in medicine, as an insecticide, in chemical analysis, in making light sensitive papers, and for many other uses. It is soluble in water. It is noncombustible, but it will accelerate the burning ot combustible materials. If large quantities of the material are involved or the material is finely divided, an explosion may result. Prolonged exposure to fire or heat may result in an explosion. Toxic oxides of nitrogen are produced in fires involving this material. If material on fire or involved in fire Flood with water Coot all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material. Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CUPRIC OXALATE 4962610 ORM-E NA2449 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RG-100/45.4) Cupric oxalate is a bluish white powder. It is used as a catalyst in the manufacture of other chemicals. It is insoluble in water. It is non combustible. 156 CUPRIC SULFATE 4961316 ORM-E NA9109 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10 4.54) Cupric sulfate is a blue crystalline solid. It is used in agriculiure. as a fertilizer, pesticide, or feed aditive. to make other copper compounds, as a wood preservative, and for many other uses. It is soluble in wafer. It is non-combustible. If material involved in fire Extinguish tire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liQuid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CUPRIC SULFATE, AMMONIATED 4962313 ORM-E NA9110 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Cupric sulfate, ammomated is a dark blue crystalline solid with a faint odor of ammonia. It is used as a pesticide, to print fabrics, and to make other copper compounds. It decomposes on exposure to air giving off ammonia. It is soluble in water, it is non-combusttble. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary April 1981 MOD 000017083 Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in ram or fire fighting water Environmental considerations--water spill Adjust ph to neutral (ph-7) Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CUPRIC TARTRATE 4962614 ORM-E NA9111 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Cupric tartrate is a green to blue powder. It is used for electroplating metals. It is insoluble in water. It is non-combustible. If material involved in fire Extinguish fire using agent suitable for type of surrounding lire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of IQppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CUPRIETHYLENE-DIAMiNE SOLUTION CORROSIVE MATERIAL, BASIC 4935630 UN1761 Cupriethylene-diamine solution is a purple colored liquid with an am monia like odor, it is soluble in water, it is corrosive to metals and tissue. Toxic oxides ol nitrogen are produced during combustion of this material. If material on fire or involved in fire Do not extinguish tire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of waler may be ineffective Use `alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary April 1981 Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the matenal Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body wilh copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing CUTCH, CATECHU. OR JAPONICA EXTRACTS. 4915432 LIQUID (COMBUSTIBLE LIQUID. N.O.S.) COMBUSTIBLE LIQUID NA1993 Cutch. catechu, or japonica extracts, liquid are materials containing a solvent having a closed cup flash point between 100 and 199 deg. F. The hazard of these materials is combustibility. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool atl affected containers with flooding quantities of water Apply water from as far a distance as possible Use ' alcohol ' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CUTCH. CATECHU. OR JAPONICA EXTRACTS. 4910432 LIQUID (FLAMMABLE LIQUID. N.O.S.) FLAMMABLE LIQUID UN1993 Cutch, catechu, or japonica extracts, liquid are materials containing a solvent having a closed cup flash point of less than 100 deg. F. The hazard of these materials is flammability. If material on fire or involved in fire Do not extinguish tire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 157 toon OonJO 17 ?<>08<! CYANIDE OR CYANIDE MIXTURE, DRY 4923224 POISON B UNI 588 Cyanide or cyanide mixtures, dry are generaily white crystalline or powdered material. They are slowly decomposed Oy water and very rapidly decomposed Py acids to give off hydrogen cyanide, a flammable poison gas. It is toxic by skin absorption through open wounds, by ingestion, and inhalation of the hydrogen cyanide from the decompo sition of the material. Toxic oxides of nitrogen are produced in fires involving this material. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use foam, carbon dioxide or dry chemical Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If material not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Use water spray to knock-down vapors Do not use water on material itself Personnel protection Avoid breathing vapors or dusts Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective eauipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing CYANOGEN BROMIDE 4923229 POISON B UN1889 Cyanogen bromide is a colorless to white crystalline solid with a pen etrating odor, it is used in gold extraction, to make other chemicals, and as a fumigant. It is slightly soluble in water. It is gradually decomposed by water and very rapidly by acids to give off hydrogen bromide, a flammable poison gas. Contamination with many materials can cause rapid decomposition of the material. It is toxic by inhalation of its vapors or by the hydrogen cyanide from decomposition or by ingestion. Toxic oxides of nitrogen are produced in fire involving this material. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If material not involved in fire Keep material out of water sources and sewers Use water spray to knock-down vapors Do not use water on material itself Personnel protection Avoid breathing vapors or dusts Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CYANIDE SOLUTION. N.O.S. 4923230 POISON B UN1935 Cyanide solution, n.o.s. is the white crystalline material dissolved in water with a stabilizer having the faint odor of bitter almonds. It is slowly decomposed by water and very repidly by acids to give off hydrogen cyanide, a flammable poison gas. It is toxic by skin absorption, by inges tion. and inhalation of the hydrogen cyanide from the decomposition of the material. If material on fire or Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Matenal itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Use foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 158 CYANOGEN CHLORIOE (CONTAINING LESS THAN 0.9% WATER) 4920506 POISON A UNI 589 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10/4.54) Cyanogen chloride is a colorless liquid boiling at 60 deg. F. with a strong odor. In very low concentrations it is irritating to the eyes and mucous membranes white in higher concentrations it is toxic by inhal ation. Its vapor is heavier than air. It may only be shipped in cylinder. Prolonged exposure of the cylinder to fire or heat may cause violently rupturing and rocketing. It weighs 10.0 pounds per gallon. If material Involved in fire Extinguish fire using agent suitable for lype of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical If material not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 MCI) U00170B5 Evacuation If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit, pond, iagoon. holding area to contain liquid or solid material Dike surface flow using soii. sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Add caustic soda Add calcium hypochlorite Adjust ph to neutral (ph-7) Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment CYANOGEN GAS 4920115 POISON A, FLAMMABLE UN1026 Cyanogen gas is a colorless gas with an odor of almonds, it is used to make other chemicals, as a fumigant, and as a rocket propellant. It is shipped as a liquefied gas under its vapor pressure, its vapor is heavier than air and a flame can travel back to the source of leak very easily. Material is soluble in water and slowly decomposed by water to oxalic acid, a non regulated material, and ammonia. Material may be only shipped in cylinders and these may have to be overpacked in wooden boxes. Prolonged exposure to fire or heat may cause violent rupturing and rocketing of the cylinders, if material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water Irom as far a distance as possible Solid streams of water may be ineffective Use alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered CYCLOHEXANE 4908132 FLAMMABLE LIQUIO UN1145 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Cyclohexane is a clear colorless liquid with a petroleum-like odor. It is used to make nylon, as a solvent, paint remover, and to make other chemicals. It has a flash point of -4 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. It weighs 6.5 pounds per gallon. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire April 1981 Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use toam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of igniuon away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash. cement powder, sawdust, or com mercial sorbents Apply "universal" gelling agent to immobilize spill Apply fluorocarbon-water foam to diminish vapor and fire hazard Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e.g. detergent, soaps, alcohols) to com press and thicken spilled material Inject 'universal" gelling agent to solidify encircled spill and increase effectiveness of booms Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors CYCLOHEXANONE (COMBUSTIBLE LIQUID. N.O.S.) 4913179 COMBUSTIBLE LIQUID NA1993 Cyclohexanone is a colorless to pale yellow liquid with a pleasant odor. It is used to make nylon, as a chemical reaction medium, and as a solvent. It is lighter than water and is slightly soluble in water. It has a flash point of 111 deg. F. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 159 MCI) 000017086 CYCLOHEXANONE PEROXIDE (IN SOLUTION WITH 4919527 NOT MORE THAN 9% BY WEIGHT ACTIVE OXYGEN) ORGANIC PEROXIDE UN2116 Cyclohexanone peroxide, (in solution with not more than 9% by weight active oxygen) is a colorless to pale yellow liquid. It is used to manu facture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite; but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamina tion with many chemical substances can cause a violent chemical re action. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or Involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet CYCLOHEXANONE PEROXIDE AND BIS(1- 4919537 HYDROXYCYCLOHEXYL) PEROXIDE MIXTURE ORGANIC PEROXIDE UN2119 Cyclohexanone peroxide and bis(l-hydroxycyclohexyl) peroxide mix ture is a colorless solution of a white crystalline solid in a non-volatile solvent. The solution may take some effort to ignite but once ignited it burns with increasing vigor as the fire progresses. The dried material is easier to ignite. It strongly supports the burning of combustible ma terial. The dried material can form explosive mixtures with finely divided combustible materials. Under prolonged exposure to heat or fire con tainers of the material can explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use 'alcohol' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment 160 Wash away any materiai which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the materiai is on fire or involved in fire evacuate for a radius of 2500 feet CYCLOHEXANONE PEROXIDE AND Dl-(1- 4919125 HYDROXYCYCLOHEXYL) PEROXIDE MIXTURE ORGANIC PEROXIDE UN2896 Cyclohexanone peroxide and di-(l-hydroxycyclohexyl) peroxide mix ture is a white solid or colorless to white liquid or paste. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of combustible materials. Un der prolonged exposure to fire or heat, containers of the materials may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet CYCLOHEXANONE PEROXIDE, (AS A PASTE WITH 4919528 NOT MORE THAN 9% BY WEIGHT ACTIVE OXYGEN) ORGANIC PEROXIDE UN2896 Cyclohexanone peroxide, (as a paste with not more than 9% by weight active oxygen) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and burns with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combustible materials. It supports the burning of com bustible materials. Under prolonged exposure to tire or heat containers of the material may explode. H material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all aftected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive April 1981 OOCOl'708'7 MOD If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the matenal anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet CYCLOHEXANONE PEROXIDE, (NOT OVER 50% 4919530 PEROXIDE) ORGANIC PEROXIDE UN2896 Cyclohexanone peroxide is a colorless solution of a white crystalline solid. The solution may take some effort to ignite but once ignited it burns with increasing vigor as the fire progresses. It strongly supports the burning of combustible material. The dried material is easily ignited. The dried material can form explosive mixtures with combustible ma terials. Under prolonged exposure to fire or heat containers of the ma terial may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use ' alcohol' foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gioves. and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the matenal anticipated, wear fun protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet CYCLOHEXANONE PEROXIDE. (50 TO 85% 4919535 PEROXIDE) ORGANIC PEROXIDE UN2119 Cyclohexanone peroxide is a colorless solution of a white crystalline solid. The solution may take some effort to ignite but once ignited it burns with increasing vigor as the fire progresses. It strongly supports the burning of combustible material. The dried material is easily ignited. The dried material can form explosive mixtures with combustible ma terials. If exposed to fire or heal for prolonged periods Of time, container of the solution may explode. April 1981 H material on fire or involved in fire Use water in flooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet CYCLOHEXENYL TRICHLOROSILANE 4934217 CORROSIVE MATERIAL. ACIDIC, COMBUSTIBLE UNI 762 Cyclohexenyl trichlorosilane Is a colorless liquid with a pungent odor, it is used to make various silicon containing compounds, it is combustible and has a flash point of 200 deg. F. It is readily decomposed by moisture or water to hydrochloric acid with evolution of heat. It is corrosive to metals and tissue. If material on fire or involved in fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spiiled matenal with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water if contact with the material anticipated, wear full protective clothing CYCLOHEXYL TRICHLOROSILANE 4934218 CORROSIVE MATERIAL, ACIDIC UN1763 Cydohexyl trichlorosilane is a colorless to pale yellow liquid with a pungent odor, it is combustible and has a flash point of 185 deg. F. it is readily decomposed by moisture or water to hydrochloric acid with evolution of heat. It is corrosive to metals and tissue. Continued on next page MCI) g000l7088 161 If malarial on fira or involved in fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself if large quantities of comoustibles are involved, use water m flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on matenal itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken pacxages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing CYCLOHEXYLAMINE 4909139 FLAMMABLE LIQUID UN2357 Cyclohexylamine is a clear colorless to yellow liquid with an ammonia like odor. It has a flash point of 90 deg. F. It is irritating to the eyes and respiratory system. Skin contact may result in Purns. It is lighter than water and soluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use ' alcohol " foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material CYCLOPENTANE 4908135 FLAMMABLE LIQUID UN1146 Cyciopentane is a clear colorless liquid with a petroleum-like odor. It has a flash point of -35 deg. F. it is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread tire Cool all affected containers with flooding quantities of water 162 Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered CYCLOPENTANE. METHYL 4908137 FLAMMABLE LIQUID UN2298 Cyciopentane, methyl is a clear colorless liquid with a petroleum-like odor. It has a flash point of -17 deg. F It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered CYCLOPROPANE 4905713 FLAMMABLE GAS UN1027 Cyclopropane is a colorless gas with a petroleum like odor. It is shipped as a liquid under its own vapor pressure. It is easily ignited and may only be shipped in cylinders. It is heavier than air and a flame can ' flash back to the source of leak very easily. Contact with the liquid may cause frostbite. It can asphyxiate by the displacement of air. Under fire conditions the cylinders may violently rupture and rocket. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible April 1981 MCD 000017089 If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Use water spray to knock-down vapors Keep material dry Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation if fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on tirei. downwind evacuation must be considered If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear tull protective clothing DDT (OR) DICHLORODIPHENYLTRICHLOROETHANE 4941129 ORM-A NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.4S4) Ddt is a colorless to white crystalline solid. It is used as a pesticide. It is a wettable powder or water emulsifiable liquid. It can cause illness by inhalation, skin absorption and or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.} If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates DE-INKING COMPOUNDS USED IN RECYCLING 4935278 PAPER (CORROSIVE LIQUID. N.O.S.) CORROSIVE MATERIAL UN1760 De-inking compounds are various colored liquids. They may or may not be soluble in water. They may burn though it may take some effort to ignite. They are corrosive to metals and tissue. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use ``alcohol'' foam, carbon dioxide or dry chemical April 1981 DECABORANE 4916610 FLAMMABLE SOLID, POISONOUS UN1B68 Decaborane is a colorless to white crystalline material with a persistent disagreeable odor. It is readily ignited and once ignited burns with a green flame. It may spontaneously ignite on exposure to air. It is toxic by skin absorption. It is slightly soluble in cold water and is slowly hy drolyzed by hot water to give off hydrogen, a flammable gas. It forms shock sensitive compounds when dissolved in oxygenated or haiogen- ated solvents. If material on fire or involved in fire Use water in flooding quantities as fog Use dry chemical or carbon dioxide If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Avoid breathing dusts Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water DECAHYORONAPHTHALENE 4913167 COMBUSTIBLE LIQUID UN1147 Decahydronaphthalene is a clear colorless liquid with an aromatic odor. It has a flash point of 134 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water MCr> 000017090 DECANOYL PEROXIDE, (TECHNICALLY PURE) 4919128 ORGANIC PEROXIDE UN2120 Decanoyl peroxide, (technically pure) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and burns with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combustible materials. It supports the burning of combustible materials. Under prolonged ex posure to fire or heal containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet DECYL ALCOHOL. OTHER THAN PERFUMERY 4913121 GRADE (ALCOHOL. N.O.S.) COMBUSTIBLE LIQUID UNI 987 Decyl alcohol is a dear colorless liquid with a sweet fat-like odor. It has a flash point of 180 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water DEFOAMING COMPOUND, NEC, LIQUID 4915208 (COMBUSTIBLE LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Defoaming compound, nec. liquid is a variable colored liquid. It has a flash point between 100 and 199 deg. F. It is generally lighter than water and soluble in water, its vapors are heavier than air. 164 If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water DEFOAMING COMPOUND, NEC. LIQUID (FLAMMABLE 4910208 LIQUID. N.O.S.) FLAMMABLE LIQUID UN1993 Defoaming compound, nec. liquid is a variable colored liquid. It has a flash point of less than 100 deg. F. It is generally lighter than water and soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water DEGUMMING COMPOUNDS, FABRIC OR FIBER 4915466 (COMBUSTIBLE LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Degumming compounds, fabric or fiber are materials containing a solvent having a flash point between 100 and 199 deg. F. The hazard of these matenals is combustibility. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors April 1961 MCI) 000017091 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water DEGUMMING COMPOUNDS. FABRIC OR FIBER 4910466 (FLAMMABLE LIQUID, N.O.S.) FLAMMABLE LIQUID UN1993 Degumming compounds, fabric or fiber are materials containing a solvent having a flash point of below 100 deg. F. The hazard of these materials is flammability. If material on lire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be Ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water DELAY ELECTRIC IGNITER 4903435 CLASS C EXPLOSIVE Delay electric igniter consists of small metal, fiberboard or paste board tubes containing a wire bridge in contact with a small quantity of an ignition compound in contact to a short piece of igniter cord. If material on fire or involved in fire Flood with water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet DENATURED ALCOHOL 4909141 FLAMMABLE LIQUID NA1966 Denatured alcohol is a clear, colorless liquid with a characteristic odor. It is used as a fuel, solvent, antifreeze, and to make other chemicals. It has a flash point of 58-60 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical April 1981 It material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water DENATURED ALCOHOL SOLVENT, (ALCOHOL, 4909142 N.O.S.) FLAMMABLE LIQUID UN1987 Denatured alcohol is a clear, colorless liquid with a characteristic odor. It has a flash point of 58-60 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams o< water may be ineffective Cooi all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water DENATURED ALCOHOL, SOLIDIFIED (ALCOHOL, 4910403 N.O.S.) FLAMMABLE LIQUID UN1987 Denatured alcohol, solidified is a sterno-iike gel. The alcohol can separate out. The hazard is flammability. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 165 MOD 000017092 DENATURING ALCOHOL, NEC (ALCOHOL. N.O.S.) 4909143 FLAMMABLE LIQUID UN1987 Denaturing alcohol is a clear colorless liquid. It has a flash point of 100 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of waier Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water DENATURING ALCOHOL. NEC (ALCOHOL. N.O.S.) 4913133 COMBUSTIBLE LIQUID UNI 987 Denaturing alcohol, nec is a clear colorless liquid. It has a Hash point between 100 and 199 deg. F. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water DETERGENT INTERMEDIATES, OTHER THAN CYCLIC 4915371 OR PETROLEUM (COMBUSTIBLE LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Detergent intermediates, other than cyclic or petroleum are clear col orless liquid. They have a flash point between 100 and 199 deg. F. They are generally lighter than water and soluble in water. Their vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical 166 If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water DETERGENT INTERMEDIATES. OTHER THAN CYCLIC 4910371 OR PETROLEUM (FLAMMABLE LIQUID, N.O.S.) FLAMMABLE LIQUID UNI 993 Detergent intermediate, other than cyclic or petroleum are clear col orless liquid. They have a flash point of less than 100 deg. F. They are generally lighter than water and soluble in water. Their vapors are heav ier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water DETONATING FUZE 4901205 CLASS A EXPLOSIVE Detonating fuze is a device consisting of a detonator and may contain several ounces of high explosives encased in a heavy steel envelope. Under fire conditions they will explode. If material on fire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate tor a radius of 5000 feet DETONATING FUZE, CLASS C EXPLOSIVE 4903215 CLASS C EXPLOSIVE Detonating fuze, class c explosive is a device containing a limited amount of explosive and is used to detonate the bursting charge of projectiles, bombs, mines, torpedoes, or grenades, or to transmit a det onation between two or more explosive devices. April 1981 MCI) 1 70.9.3 If material on fire or involved in fire Flood with water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breaming apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet DETONATING FUZE, RADIOACTIVE 4901210 CLASS A EXPLOSIVE Detonating fuze, radioactive is a device consisting of a detonator and may contain several ounces of high explosives and a small amount of a radioactive component encased in a steel envelope. Under fire con ditions they will explode. If material on fire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not involved in fire Keep sparKs. flames, ana other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on tire or involved in fire evacuate for a radius of 5000 feet DETONATING PRIMER (CAPS. BLASTING OR 4901260 ELECTRIC BLASTING, EXPLOSIVE) CLASS A EXPLOSIVE Detonating primer is a device consisting of a metal or plastic envelope containing a detonator and an additional charge of high explosives. Under fire conditions these devices will explode. If material on fire or involved in fire Dangerously explosive Do not fight tires in a cargo of explosives Evacuate area and let burn If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this matenal Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet DETONATING PRIMER (CAPS. BLASTING OR 4901365 ELECTRIC BLASTING, EXPLOSIVE) CLASS C EXPLOSIVE Detonating primer is a device consisting of a metal or plastic envelope containing a detonator and an additional charge of high explosives. Under fire conditions these devices will explode. If material on fire or involved In fire Dangerously explosive Flood with water Apply water from as far a distance as possible April 1961 If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Pereonnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning matenal Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet DETONATORS (CAPS, BLASTING OR ELECTRIC 4901330 BLASTING, EXPLOSIVE) CLASS C EXPLOSIVE Detonators are small tubes, usually made of an alloy of either copper or aluminum closed at one end and loaded with one or more charges of initiating or priming explosives. Under fire conditions they will explode. If material on fire or Involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet DETONATORS (CAPS, BLASTING OR ELECTRIC 4903360 BLASTING. EXPLOSIVE) CLASS C EXPLOSIVE Detonators are small tubes, usually made of an alloy of either copper or aluminum closed at one end and loaded with one or more charges of initiating or priming explosives. Under fire conditions they will explode. If material on fire or Involved in fire Dangerously explosive Flood with water Apply water from as far a distance as possible If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet DI(2-ETHYLHEXYL) PHOSPHORIC ACID 4931422 CORROSIVE MATERIAL, ACIDIC NA1902 Di(2*ethylhexyl) phosphoric acid is a colorless liquid. It is insoluble in water. It is corrosive to metals and tissue. If material on fire or involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Appty water from as far a distance as possible Use water spray to absorb vapors Continued on next page MCI) 00Ol7094 167 If material not on fire and not involved in fire Keep material out of water sources anO sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective eauipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing 1,1-DI-(TERT-BUTYLPEROXY)-3,3,5-TRIMETHYL 4919296 CYCLOHEXANE, (TECHNICALLY PURE) ORGANIC PEROXIDE UN2145 l.1-di-(tert-buty!peroxy)-3.3.5-trimethyl cyclohexane, (technically purel is a colorless to pate yellow liquid. It is used to manufacture paints. Plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite; but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spon taneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, ana goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet 1,1-DI-(TERT-BUTYLPEROXY)-3.3,5-TRIMETHYL 4919297 CYCLOHEXANE, (NOT MORE THAN 57% IN SOLUTION) ORGANIC PEROXIDE UN2146 1.1-di-(teri-butylperoxy)-3,3.5-trimethyl cyclohexane, (not more than 57% in solution) is a coloress to pale yellow liquid. It is used to manu facture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamina tion with many chemical substances can cause a violent chemical re action. It supports the burning of combustible materials. Under prolonged exposure to tire or heat containers of the material may explode. 168 If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or mvolved in fire evacuate for a radius of 2500 feet 1.1-DMTERT-BUTYLPEROXY)-3.3,5-TRIMETHYL 4919298 CYCLOHEXANE, (NOT MORE THAN 56% WITH INERT SOLID) ORGANIC PEROXIDE UN2147 1.1-di-(tert-butylperoxy)-3.3.5-tnmethyl cyclohexane, (not more than 58% with inert solid) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and burns with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combustible materials. It supports the burning of combustible materials. Under prolonged exposure to fire or heat con tainers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as tog Solid streams of water may be ineffective Cooi all affected containers with flooding quantities ol water Apply water from as far a distance as possible Use 'alcohol'' foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the materia! Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting tires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved m fire evacuate for a radius o'. 2500 feet April 1961 Met) . ,J0Oox ?os5 2,2-DI-(TERT*8UTYLPEROXY)BUTANE. (NOT MORE THAN 55% IN SOLUTION) 4919210 ORGANIC PEROXIDE UN2111 2.2-di-(tert-butylperoxy)butane. (not more than 55% in solution) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burn ing of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with Hooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate tor a radius of 2500 feet 1,1-Dl-(TERT-BUTYLPEROXY)CYCLOHEXANE. (NOT 4919229 MORE THAN 40% WITH INERT INORGANIC SOLID, WITH NOT LESS THAN 13% PHLEGMATIZER) ORGANIC PEROXIDE UN2S85 1.l-di-(tert-butylperoxyicyclohexane. (not more than 40% with inert inorganic solid, with not less than 13% phtegmalizer) is a wmte solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and burns with increasing rapidity as the fire progresses, it can form explosive mixtures with finely divided combus tible materials. It supports the burning ot combustible materials. Under prolonged exposure to fire or heat containers ot the material may ex plode. The phlegmatlzer is a material added to make the peroxide less reacitive. If material on fire or involved in fire Use water in flooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water . Apply water from as far a distance as possible Use 'alcohol foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles April 1981 Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on tire or involved in fire evacuate for a radius of 2500 feet 1,1-DI-(TERT-BUTYLPEROXY)CYCLOHEXANE, (NOT 4919230 MORE THAN 50% WITH PHLEGMITIZER) ORGANIC PEROXIDE UN2897 1.1-di-(tert-butylperoxy)cyclohexane. (not more than 50% with phleg- matizer) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible ma terials. spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of combustible materials. Under prolonged ex posure to fire or heat containers of the material may explode. The phieg- matizer is a material added to make the peroxide less reacitive If materia) on fire or involved in fire Use water in flooding quantities as fog Solid streams 0* water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol' foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources o< ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet 1,1-DI-(TERT-BUTYLPEROXY)CYCLOHEXANE, (NOT 4919227 MORE THAN 77% IN SOLUTION) ORGANIC PEROXIDE UN2180 1.1-di-(tert-butylperoxy)cyclohexane. (not more than 77% in solution) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spon taneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. 0^96 OOO VICD Continued on next page 169 If material on fire or involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use 'alcohol'' foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on tire or involved in fire evacuate for a radius of 2500 feet 1,2-DI-(TERT-BUTYLPEROXY)CYCLOHEXANE, (NOT 4919228 MORE THAN 77% IN SOLUTION) ORGANIC PEROXIDE UN2181 1.2-di-(tert-butylperoxy)cyclohexane. (not more than 77% in solution) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble m water. The liquid or solution may require some effort to ignite; but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spon taneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. if material on fire or involved in fire Use water in flooding quantities as fog Solid streams of wafer may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet 170 1,1-DI-(TERT-BUTYLPEROXY)CYCLOHEXANE. 4919226 (TECHNICALLY PURE) ORGANIC PEROXIDE UN2179 l.l-di-(tert-butylperoxy)cyclohexane. (technically pure) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite; but once ignited, it will burn with increasing rapidity as the fire progresses. If spiiled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burn ing of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or Involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet DI-<TERT-BUTYLPEROXY)PHTHALATE. (NOT MORE 4919288 THAN 55% AS A PASTE) ORGANIC PEROXIDE UN2108 Di-(tert-butylperoxy)phthalate. (not more than 55% as a paste) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and burns with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combustible materials. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. if material on fire or involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up On>Oo April 1981 Personnel protection Avoid breathing dusts, and fumes from Cuming material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet DKTERT-BUTYLPEROXY)PHTHALATE. (NOT MORE 49192B7 THAN 55% IN SOLUTION) ORGANIC PEROXIDE UN2107 Di-(tert-butylperoxy)phthalate. (not more than 55% in solution) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber, tt is insoluble in water. The liquid or solution may require some effort to ignite; but once ignited, it will bum with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction It supports the burn ing of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes trom burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts ot water or soap and water Wear self-contained breathing apparatus when fighting tires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet OHTERT'BUTYLPEROXY)PHTHALATE, 4919286 (TECHNICALLY PURE) ORGANIC PEROXIDE UN2106 Di-(tert-butylperoxy)phthalate, (technically pure) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and bums with increasing rapidity as the fire pro gresses. It can form explosive mixtures with finely divided combustible materials. It supports the burning of combustible materials. Under pro longed exposure to fire or heat containers of the material may explode. April 1981 If material on fire or involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet 2,2-DI*(TERT-BUTYLPEROXY)PROPANE, (NOT MORE 4919291 THAN 40% WITH INERT INORGANIC SOLID WITH NOT LESS THAN 13% PHLEGMATIZER) ORGANIC PEROXIDE UN2884 2.2-di-(tert-butylperoxy)propane, (not more than 40% with inert inor ganic solid with not less than 13% phlegmatizer) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and bums with increasing rapidity as the fire pro gresses. It can form explosive mixtures with finely divided combustible materials. It supports the burning of combustible materials. Under pro longed exposure to fire or heat containers of the material may explode. The phlegmatizer is a material added to make the peroxide less reacitive. If material on fire or involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on tire or involved in fire evacuate for a radius of 2500 feet MCD 000017098 171 2,2-DI-(TERT-BUTYLPEROXY)PROPANE, (NOT MORE 4919290 THAN 50% WITH PHLEGMATIZER) ORGANIC PEROXIDE UN2B63 2.2-di-(tert-butylperoxy)propane. (not more than 50% with phlegma- tizer) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will bum with increasing rapidity as the fire progresses. If spilled on combustible materials, spon taneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. The phlegmatizer is a material added to make the peroxide less reacitive. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spiiled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the materia! Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet DI-41-HYDROXYCYCLOHEXYL) PEROXIDE, 4919279 (TECHNICALLY PURE) ORGANIC PEROXIDE UN2148 Di-(l-hydroxycyclohexyl) peroxide, (technically pure) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and burns with increasing rapidity as the fire progresses, it can form explosive mixtures with finely divided combus tible materials. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet DM2-ETHYLHEXYL) PEROXYDICARBONATE. (NOT 49192B1 MORE THAN 67% IN SOLUTION) ORGANIC PEROXIDE UN2123 Di-(2-ethylhexyl) peroxydicarbonate. (not more than 67% in solution) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite; but once ignited, it will burn with increasing rapidity as the fire progresses. If spiiled on combustible materials, spon taneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaciion. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of Ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spiiled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate lor a radius of 2500 feet DI-(2-ETHYLHEXYL) PEROXYDICARBONATE. 4919280 (TECHNICALLY PURE) ORGANIC PEROXIDE UN2122 Di-(2-ethylhexyi) peroxydicarbonate. (technically pure) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite; but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burn ing of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cooi all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical Dangerously explosive 172 MOD 000017099 April 1981 If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear seH-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet DM2-METHYLBENZOYL) PEROXIDE, (NOT MORE 4919282 THAN 85% WITH WATER) ORGANIC PEROXIDE UN2593 Di-(2-methylbenzoyl| peroxide, (not more than 85% with water) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and burns wilh increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combustible materials, tt supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate tor a radius of 2500 feet April 1981 1,3-DI-(2-TERT-BUTYLPEfiOXYISOPROPYL) BENZENE 4919207 ANO 1t4-DI-(2-TERT- BUTYLPEROXYISOPROPYL) BENZENE MIXTURE. (TECHNICALLY PURE OR MORE THAN 40% WITH INERT SOLID) UN2112 ORGANIC PEROXIDE 1,3-di-(2-tert-butylperoxyisopropyl) benzene and 1.4-di-(2-tert-butyi- peroxyisopropyl) benzene mixture, (technically pure or more than 40% with inert solid) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and burns with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combustible materials, it supports the burning of com bustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water tn flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use ``alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear seif-contained breathing apparatus when fighting fires involv ing this material If contaci with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet 1,3-DI-{2*TERT-BUTYLPEROXYISOPROPYL) 4919206 BENZENE. (TECHNICALLY PURE OR MORE THAN 40% WITH INERT SOLID) ORGANIC PEROXIDE UN2112 1.3-di-(2-tert-butyiperoxyisopropyl) benzene, (technically pure or more than 40% with inert solid) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and burns with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combustible materials. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Continued on next page 173 7 ]o0 Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting tires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet 1,4-OI-(2-TERT-BUTYLPEROXYISOPROPYL) 4919208 BENZENE. (TECHNICALLY PURE OR MORE THAN 40% WITH INERT SOLID) ORGANIC PEROXIDE UN2112 1.4-di-(2-tert-butyfoeroxyisopropyl) benzene, (technically pure or more than 40% with inert solid) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and burns with increasing rapidity as the fire progresses. I! can form explosive mixtures with finely divided combustible materials. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled materia) wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet DI-(3,5,5-TRIMETHYL-1.2-DIOXOLANYL-3) PEROXIDE, 4919263 (NOT MORE THAN 50% AS A PASTE, WITH PHLEGMATIZER) ORGANIC PEROXIDE UN2597 Di-(3.5.5-trimethyl-t.2-dioxolanyl-3) peroxide, (not more than 50% as a paste, with phlegmatizer) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and burns with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combustible materials. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. The phlegmatizer is a material added to make the peroxide less reacitive. 174 If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use 'alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled materiel before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting tires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet Dt-(4-TERT- 4919284 BUTYLCYCLOHEXYL)PEROXYDICARBONATE, (NOT MORE THAN 42%, STABLE DISPERSION, IN WATER) ORGANIC PEROXIDE UN2894 Di-(4-lert-butyfcyclohexyl)peroxydicarbonate. (not more than 42%. stable dispersion, in water) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. The liquid or solution may require some effort to ignite: but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spon taneous ignition of the matenal may occur. Contamination with many chemical substances can cause a violent chemicai reaction. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the materia) may exp)ode. ff material on fire or involved in fire Use water in flooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet April 1981 00l7 lOX DM4-TERT- 4919285 BUTYLCYCLOHEXYL)PEROXYOICARBONATE, (TECHNICALLY PURE) ORGANIC PEROXIDE UN2154 Di-(4-tert-bytylcyclohexyl)peroxydicarbonate. (technically pure) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and burns with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combustible materials. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet 2,2-DH4,4-DI-TERT-BUTYLPEROXYCYCLOHEXYL) 4919292 PROPANE. (NOT MORE THAN 42% WITH INERT SOLID) ORGANIC PEROXIDE UN2168 2.2-di-(4,4-di-tert-bulylperoxycyclohexyl) propane, (not more than 42% with inert solid) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and burns with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combustible materials, it supports the burning of combustible materials. Under prolonged exposure to fire or heat con tainers of the material may explode. If material on fire or involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spiiied material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the matehal anticipated, wear full protective clothing Approach fire with caution Evacuation if the material is on tire or involved in fire evacuate for a radius of 2500 feet DI-N-PROPYL PEROXYDICARBONATE, (TECHNICALLY PURE) 4919294 ORGANIC PEROXIDE UN2176 Di-n-propyl peroxydicarbonate. (technically pure) is a white solid. It is used to manufacture paints, plastics, and rubber. It is slightly soluble in water. It is easily ignited and burns with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combus tible materials. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled matenal before picking it up Personnel protection Avoid breathing dusts, and fumes from burning matenal Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet DI-N-PROPYLAMINE (FLAMMABLE LIQUID, N.O.S.) 4909157 FLAMMABLE LIQUID UNI 993 Di-n-propylamine is a clear colorless liquid with an ammonia-like odor. It has a flash point of 30 deg. F. ft is lighter than water and soluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Appty water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Continued on next page 175 MOD 000017102 Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing DI-SEC-BUTYL PEROXYDICARBONATE, (NOT MORE 4919214 THAN 52% IN SOLUTION) ORGANIC PEROXIDE UN2151 Di-sec-butyl peroxydicarbonate, (not more than 52% in solution) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will burn with increasing rapidity as the tire progresses. If spilled on combustible matenais. spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burn ing of combustible matenais. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of Ignition away Keep material out of water sources and sewers Keep spilled material wet Wei spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet DI-SEC-BUTYL PEROXYDICARBONATE. 4919215 (TECHNICALLY PURE) ORGANIC PEROXIDE UN2150 Di-sec-butyl peroxydicarbonate. (technically pure) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of com bustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water 176 Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and ether sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet DI-TERT-BUTYL PEROXIDE. (TECHNICALLY PURE) 4919213 ORGANIC PEROXIDE UN2102 Di-tert-butyl peroxide, (technically pure) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of combustible ma terials. Under prolonged exposure to fire or heat containers of the ma terial may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet DlACETONE ALCOHOL 4909149 FLAMMABLE LIQUID UN114B Diacetone alcohol is a clear colorless liquid with a pleasant odor. It has a flash point of less than 100 deg. F. It is lighter than water and is soluble in water. Its vapors are heavier than air. April 1981 a/Q) If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water DIACETONE ALCOHOL PEROXIDE, (NOT MORE THAN 4919234 57% IN SOLUTION WITH NOT MORE THAN 9% HYDROGEN PEROXIDE, NOT LESS THAN 26% DIACETONE ALCOHOL AND NOT LESS THAN 9% WATER; TOTAL ACTIVE OXYGEN CONTENT NOT MORE THAN 9%) ORGANIC PEROXIDE UN2163 Diacetone alcohol peroxide, (not more than 57% in solution with not more than 9% hydrogen peroxide, not less than 26% diacetone alcohol and not less than 9% water: total active oxygen content not more than 9%) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. The liquid or solution may require some effort to ignite; but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of com bustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as log Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach tire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet April 1981 DIACETYL 4909144 FLAMMABLE LIQUID UN2346 Diacetyl is a clear colorless liquid with a strong chlorine like odor. It has a flash point of 80 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water DIAZINON (AGRICULTURAL INSECTICIDES, NEC. LIQUID) 4941141 ORM-A NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Diazinon is a colorless to white liquid. It is used as a pesticide. It is a water emuisifiable liquid. It can cause illness by inhalation, skin ab sorption and/or ingestion. In case of damage to. or leaking from con tainers of this material contact the pesticide safety team network. Tele phone: 800-424-9300. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates 0000171-04 MOD 177 DIAZINON (AGRICULTURAL INSECTICIDES, NEC. 4941142 OTHER THAN LIQUID) ORM-A NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Dia2inon is a colorless to white liquid absorOed on a dry carrier. It is used as a pesticide. It is a wettable powder. It can cause illness by inhalation, skin absorption and or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 600-424-9300. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or tire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates If dissolved, apply activated carbon at ten times ttie spilled amount in region of lOppm or greater concentration DIAZINON (INSECTICIDES, OTHER THAN 4941140 AGRICULTURAL, NEC) ORM-A NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Diazinon is a colorless to white liquid or the liquid absorbed on a dry carrier. It is used as a pesticide. It Is a wettable powder or water emul- sifiable liquid. It can cause Illness by inhalation, skin absorption and or ingestion. In case of damage to. or leaking from containers of this ma terial contact the pesticide safety team network. Telephone: 800-424- 9300. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in ram or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration 178 DIBENZYL PEROXYDICARBONATE, (NOT MORE 4919235 THAN 87% WITH WATER) ORGANIC PEROXIDE UN2149 Dibenzyl peroxydicarbonate, (not more than 87% with water) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water, it is easily ignited and burns with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combus tible materials. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water In flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Appiy water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages wilhout protective equipment Wash away any material which may have contacteQ the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in tire evacuate for a radius of 2500 feet DIBORANE 4905420 FLAMMABLE GAS, POISONOUS UN1911 Diborane is a colorless gas with an offensive odor. It is used in elec tronics. it is toxic by inhalation. Diborane is decomposed by water giving off hydrogen, another flammable gas and boric acid non-regulated ma terial. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Approach fire with caution Evacuation tf fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered April 1981 GQq DIBORANE MIXTURES 4905425 FLAMMABLE GAS, POISONOUS UN1911 Diborane mixtures is a colorless gas with an offensive odor. It is used in electronics. Diborane is decomposed by water giving off hydrogen, another flammable gas. and boric acid, a non-regulated material. Their vapors are heavier than than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use water spray to absorb vapors If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct ^ flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered 1,2-DIBROMOETHANE (See ETHYLENE DIBROMIDE 4940335) Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates DICAMBA (AGRICULTURAL INSECTICIDES, NEC. 4963337 OTHER THAN LIQUID) ORM-E NA2769 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-IOOO/454) Dicamba is a white solid or the solid dissolve in a liquid carrier. It is used as a herbicide. It is a wettable powder. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 000-424-9300. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid materiai Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates DICAMBA (AGRICULTURAL INSECTICIDES, NEC, 4963334 LIQUID) ORM-E NA2769 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Dicamba is a white solid dissolved in a liquid earner. H is used as a herbicide. It is a water emutsifiable liquid. It can cause illness by inhal ation. skin absorption and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team net work. Telephone; 800-424-9300. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder April 1981 DICAMBA (INSECTICIDES, OTHER THAN 4963332 AGRICULTURAL, NEC) ORM-E NA2769 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-IOOO/454) Dicamba is a white solid or the solid dissolved in a liquid carrier. It is used as a herbicide. It is a wettable powder or water emutsifiable liquid. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300. H material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid materiai Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill If dissolved, appiy activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates WCD Oqq 1 ?1oe 179 DICETYL PEROXYDICARBONATE, (NOT MORE THAN 4919237 42%, STABLE DISPERSION. IN WATER) ORGANIC PEROXIDE UN2895 Dicetyl peroxydicarbonate, (not more than 42%. stable dispersion, in water) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. The liquid or solution may require some effort to ignite: but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burn ing of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matehal out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet DICETYL PEROXYDICARBONATE. (TECHNICALLY 4919238 PURE) ORGANIC PEROXIDE UN2164 Dicetyl peroxydicarbonate. (technically pure) is a white solid. It is used to manufacture paints, plastics, and rubber, it is insoluble in water. It is easily ignited and burns with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combustible materials. It supports the burning of combustible materials. Under prolonged ex posure to fire or heal containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as lar a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive It materia) not on tire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 180 Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet DICHLOBENIL (AGRICULTURAL INSECTICIDES, NEC, 4963609 LIQUID) ORM-E NA2769 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Dichlobenil is a white solid dissolved in a liquid carrier. It is used as a herbicide. It is a water emulsifiabie liquid. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates DICHLOBENIL (AGRICULTURAL INSECTICIDES, NEC. 4963814 OTHER THAN LIQUID) ORM-E NA2769 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Dichlobenil is a white solid. It is used as a herbicide. It is a wettable powder. It can cause illness by inhalation, skin absorption and or inges tion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water April 1981 Ouoo 17.i 07 Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates DICHLOBENIL (INSECTICIDES. OTHER THAN 4963805 AGRICULTURAL. NEC) ORM-E NA2769 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000 454) Oichlobenil is a white solid or the solid dissolved in a liquid carrier. It is used as a herbicide. It is a wettable powder or water emulsifiable liquid. It can cause illness by inhalation, skin absorption and or ingestion. In case of damage to. or leaking from containers ot this material contact the pesticide safety team network. Telephone; 800-424-9300. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts ot water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain iiquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates D1CHLONE (AGRICULTURAL INSECTICIDES. NEC, 4960617 LIQUID) ORM-E NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-10.454) Dichlone is a yellow crystalline solid dissolved in a liquid earner. It is used as a fungicide. It is a water emulsifiable Iiquid. It can cause illness by inhalation, skin absorption and or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface (low using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder April 1981 DICHLONE (AGRICULTURAL INSECTICIDES. NEC, 4960616 OTHER THAN LIQUID) ORM-E NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-1/0.454) Dichlone is a yellow crystalline solid. It is used as a fungicide. It is a wettable powder. It can cause illness by inhalation, skin absorption and or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424- 9300. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in ram or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates DICHLONE (INSECTICIDES, OTHER THAN 4960618 AGRICULTURAL, NEC) ORM-E NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Dichlone is a yellow crystalline solid or the solid dissolved in a liquid carrier. It is used as a fungicide. It is a wettable powder or water emul sifiable liquid. It can cause illness by inhalation, skin absorption material contact the pesticide safety team network. Telephone; 800-424-9300. tf material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Contlnuad on next page 181 MOD 000017108 Environmental considerations--land spill Oig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or tire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottpm If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates DICHLOROACET1C ACID 4931420 CORROSIVE MATERIAL ACIDIC UN1764 Dichloroacetic acid is a colorless crystalline solid melting at 49 deg. F. It is soluble in water. It is corrosive to metals and tissue. H material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted (he body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing DICHLOROACETYL CHLORIDE 4931735 CORROSIVE MATERIAL, ACIDIC. COMBUSTIBLE UN1765 Dichloroacetyl chloride is a colorless, fuming liquid with a pungent odor. It is combustible and has a flash point of 151 deg. F. Its vapors are irritating to the eyes and mucous membranes. II is decomposed by water to dichloroacetic acid and hydrochloric acid, corrosive materials, with release of heat. It Is corrosive to metals and tissue, if material on fire or involved in fire Use dry chemical or carbon dioxide Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Coot all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing 182 DICHLOROANILINE (POISONOUS SOLID, N.O.S.) 4921515 POISON B NA2811 Dichloroaniline is an amber to brownish colored crystalline solid. It is used in the manufacture of dyes and pesticides. It is insolube in water and is combustible. It is toxic by skin absorption and by inhalation (dust, etc.). Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Use dry chemical or carbon dioxide Cool all affected containers with flooding quantities of water Use water in flooding quantities as fog If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this matenal DICHLOROBENZENE, ORTHO, LIQUID 4941127 ORM-A UNI 591 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Dichlorobenzene, ortho, liquid is dear colorless liquid with a pleasant odor. It is used to make other chemicals, solvent, fumigant and insec ticide. and for many other uses, tt is combustible and has a flash point of 150 deg. F. it is heavier than water and is soluble in water If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Apply "universal" gelling agent to immobilize spill Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates DICHLOROBENZENE, PARA, SOLID 4941128 ORM-A UN1592 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Dichlorobenzene, para, solid is a white crystalline volatile solid having the odor of moth balls. It is used as a moth repellent, to make other chemicals, as a fumigant, and for many other uses. It is heavier than water and insoluble in water. It will burn though it may take some effort to ignite. MCD 000017109 April 1981 If material involved in fire Extinguish fire using agent suitable for- type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or (ire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates 2,4-DICHLOROBENZOYL PEROXIDE, (NOT MORE 4919243 THAN 52% AS A PASTE) ORGANIC PEROXIDE UN2136 2.4-dichlorobenzoyl peroxide, (not more than 52% as a paste) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and burns with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combustible materials. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation if the material is on fire or involved in fire evacuate for a radius of 2500 feet April 1981 2,4-DICHLOROBENZOYL PEROXIDE. (NOT MORE 4919244 THAN 52% IN SOLUTION) ORGANIC PEROXIDE UN2139 2,4-dichlorobenzoyl peroxide, (not more than 52% in solution) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burn ing of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the matenai Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet 2,4-DICHLOROBENZOYL PEROXIDE. (NOT MORE 4919242 THAN 75% WITH WATER) ORGANIC PEROXIDE UN2137 2,4-dichlorobenzoyl peroxide, (not more than 75% with water) is a white solid. It is used to manufacture paints, plastics, and rubber. It is easily ignited and bums with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combustible materials. It supports the burning of combustible materials. Under prolonged ex posure to fire or heat containers of the material may explode. If material on fire or involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Continued on next page 1B3 KCJj OOor: 0l?I JQ Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing DICHLOROBUTENE 4907605 FLAMMABLE LIQUID, CORROSIVE NA2924 Dichlorobutene is a clear colorless to straw colored liquid. It has a flash point of 80 deg. F. It is corrosive to metals and tissue. It is heavier than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless tlow can be stopped Use water in flooding quantities as fog Solid streams of water may Oe ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered DICHLOROBUTENE 4936312 CORROSIVE MATERIAL NA2924 Dichlorobutene is a clear colorless liquid. It is used to make other chemicals. It will burn though it may require some effort to ignite. It is corrosive to tissue. It is heavier than water and insoluble in water. It vapors are heavier than air. H material on fire or involved In fire Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as tar a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors 184 DtCHLORODIFLUOROMETHANE 4904516 NONFLAMMABLE GAS UN1028 Dichlorodifluoromethane is a colorless gas having a faint ethereal odor. It is shipped as a liquid under its own vapor pressure. It is non combustible. It is heavier than air and can cause asohyxiation by the displacement of air. Contact with the liquid can cause frostbite. Toxic gases can be produced in fires involving this material. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as tar a distance as possible if material not involved in fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment DICHLORODIFLUOROMETHANE AND 4904534 DIFLUOROETHANE MIXTURE (CONSTANT BOILING MIXTURE) NONFLAMMABLE GAS UN2602 Dichlorodifluoromethane and difluoroethane mixture is a colorless gas having a faint ethereal odor. It is shipped as a liquefied gas under its own vapor pressure. Dichlorodifluoromethane is noncombustible: di fluoroethane is a flammable gas. The vapor of dichlorodifluoromethane is heavier than that of difluoroethane and both are heavier than air. They can asphyxiate by the displacement of air. Contact with the liquid can cause frostbite. Toxic gases can be produced in fires involving this material. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible H material not involved in fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment April 1981 MCB 000017111 DICHLORODIFLUOROMETHANE- 4904519 DICHLOROTETRAFLUOROETHANE MIXTURE NONFLAMMABLE GAS NA1956 Dichlorodifluoromethane-dichlorotetrafluoroethane mixture is a col orless gas having a faint ethereal odor. It is shipped liquefied as a gas under its own vapor pressure. Both dichlorodifluoromethane and dich- lorotetrafluoroethane are noncombustible. The two gases are heavier than air and can asphyxiate by the displacement of air in a closed space. Contact with the liquid can cause frostbite. Toxic gases can be produced in fires involving this material. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved In fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment DICHLORODIFLUOROMETHANE- 4904525 TRICHLOROMONOFLUOROMETHANE- MONOCHLORODIFLUORO- METHANE MIXTURE NONFLAMMABLE GAS NA1956 Dichlorodifluoromethane-trichloromonofluoromethane-monochlorodi- iluoromethane mixture is a colorless gas. It is shipped as a liquefied gas under its own vapor pressure. Its odor varies from none to faintly ethereal or carbon tetrachloride like odor. All three gases are noncombustible. They can asphyxiate by the displacement of air. Contact with the liquid can cause frostbite If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment DICHLORODIFLUOROMETHANE- 4904522 MONOCHLORODIFLUOROMETHANE MIXTURE NONFLAMMABLE GAS NA1956 Dichlorodifluoromethane-monochlorodifluoromethane mixture is a col orless gas: odorless to a faint chloroform like odor. It is shipped as a liquefied gas under its own vapor pressure. Both gases are noncom bustible. They can asphyxiate by the displacement of air in a closed space. Contact with the liquid can cause frostbite. If material involved in fire Extinguish fire using agent suitable for type of surrounding lire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities ol water Apply water from as far a distance as possible If material not involved in fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment DICHLORODIFLUOROMETHANE- 4904528 TRICHLOROTRIFLUOROETHANE MIXTURE NONFLAMMABLE GAS NA1956 Dichlorodifluoromethane-trichlorotrifluoroethane mixture is a colorless odorless gas. It is shipped as a liquefied gas under its own vapor pres sure. Both gases are noncombustible, it can asphyxiate by the displace ment of air. Contact with the liquid can cause frostbite. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment DICHLORODIFLUOROMETHANE- 4904531 MONOCHLOROTRIFLUOROMETHANE MIXTURE NONFLAMMABLE GAS NA1956 Dichlorodifluoromethane-monochlorotrifluoromethane mixture is a colorless gas with no odor to a faint ethereal-carbon tetrachloride odor. It is shipped as a liquefied gas under its own vapor pressure. Both gases are noncombustible. They can asphyxiate by the displacement of air. Contact with the liquid can cause frostbite. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment April 1981 D1CHLOROETHYL ETHER (POISONOUS 4921550 LIQUID,N.O.S.) POISON B NA2810 Dichloroethyl ether is a clear colorless liquid with a chloroform-like odor. It is used in cleaning compounds, in paints, in textile finishing, and as a general solvent. It is combustible and has a flash point of 131 deg. F. It is heavier than water and is insoluble in water. It is toxic by inhalation and skin absorption. If material on fire or involved In fire Do not extinguish tire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Continued on next page MCI) 000017112 185 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective eguipment Wash away any materiai which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material DICHLOROETHYLENE 4909145 FLAMMABLE LIQUID UN1150 Dichloroethylene is a clear colorless liquid with an ether-like odor. It has a flash point of 36-39 deg. F. It is heavier than water and tnsoluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparxs. flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any materiai which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material DICHLOROlSOCYANUHIC ACID (OXIDIZING 4918724 MATERIAL. N.O.S.) OXIDIZER UN1479 Dichloroisocyanuric acid is a white crystalline solid with an odor of chlorine, it is used as a dry bleach m household cleaning compounds and in swimming pool disinfectants. The material itself is noncombustible but if contaminated with combustible material ignition can result. It will accelerate the burning of combustible materials. Contact with ammonium compounds or hydrated salts can cause a very vigorous chemical re action. May vigorously react with small quantities of water releasing chlorine gas. Prolonged exposure of the material to fire or heat may result in its violent decomposition and rupturing of the container. It material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Peraonnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If lire becomes uncontrollable--evacuate for a radius of 2500 feet 186 DICHLOHOISOPROPYL ETHER 4936315 CORROSIVE MATERIAL. COMBUSTIBLE UN249C Dichloroisopropyl ether is a colorless liquid. It is combustible and has a flash point of 185 deg. F. It is heavier than water and insoluble in water. It is corrosive to metals and tissue. If material on fire or involved in fire Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol ' foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing DICHLOROPENTANE 4909147 FLAMMABLE LIQUID UN1152 Dichloropentane is a clear colorless to yellow liquid. It has a flash point of 90 deg. F. It is lighter than water and Is insoluble in water. Its vapors are heavier than air. if material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread tire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material 2,4-DiCHLOROPHENOXYACEHC ACID 4941126 ORM-A NA276S ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) 2.4-dichlorophenoxyacelic acid is a white to yellow crystalline solid it is used as a weed killer and defoliant. If is slightly soluble in wafer. It is non-combustible. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) April 1981 MClj 0r; >0q17113 If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped matenal with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates 2,4-DICHLOROPHENOXYACETIC ACID ESTER 4962130 ORM-E NA2765 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) 2.4-dichlorophenoxyacetic acid ester is a white solid. It is used as a herbicide and defoliant. It is slightly soluble in water. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn br burns with difficulty.) If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates DICHLOROPHENYL TRICHLOROSILANE 4934225 CORROSIVE MATERIAL. ACIDIC UN1766 Dichlorophenyl trichlorosilane is a straw colored liquid with a pungent odor. Material will burn though it may require some effort to ignite It is decomposed by moisture or water to hydrochloric acid with evolution of heat, it is corrosive to metals and tissue. If material on fire or involved in fire Use dry chemical, carbon dioxide, or dry sand Do not use water on matenal itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible April 1981 If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to Knock-down vapors Do not use water on matenal itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing DICHLOROPROPANE (See PROPYLENE DICHLORIDE 4909269) DiCHLOROPROPENE 4909255 FLAMMABLE LIQUID UN2047 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Dichloropropene is a clear colorless liquid. It is used to make other chemicals and as soil fumigant. It has a flash point of 95 deg. F. It is heavier than water and insoluble in water. Its vapors are heavier than air. It weighs 10.2 pounds per gallon. If material on fire or involved in fire Use water in flooding quantities as fog Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash. cement powder, sawdust, or com mercial sorbents Apply fluorocarbon-water foam to diminish vapor and tire hazard Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Combustion products include corrosive or toxic vapors Thermal decomposition to phosgene can occur 187 Mf'Ti A f\f\r\ i <- - * OICHLOROPROPENE AND PROPYLENE DICHLORIOE 4907640 MIXTURE FLAMMABLE LIQUID. CORROSIVE NA2047 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000 2270) Oichloropropene and propylene dichloride mixture is a colorless liauid with a chloroform like odor. It is flammable and has a flash point below 100 deg. F. It is heavier than water and insoluble in water. It is corrosive to metals and tissue, it weighs 9.9 pounds per gallon. If material on fire or involved in fire Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use 'alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash. cement powder, sawdust, or com mercial sorbents Apply fluorocarbon-water foam to diminish vapor and fire hazard Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses o< pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Combustion products include corrosive or toxic vapors Thermal decomposition to phosgene can occur 2.2-DICHLOROPROPIONIC ACID 4931455 CORROSIVE MATERIAL NA1760 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000 2270) 2.2*dichloropropionic acid is a colorless liquid. It is used as a herbicide. It is soluble in water. It is corrosive to metals and tissue. It weighs 11.6 pounds per gallon. If material on fire or involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use water spray to absorb vapors If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash. or lime 188 Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water if contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash. cement powder, sawdust, or com mercial sorbents Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors DICHLORVOS (AGRICULTURAL INSECTICIDES. NEC, 4921534 LIQUID) POISON B NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10 4.54) Dichlorvos is a colorless to amber liquid. It is used as a pesticide. It is a water emulsifiable liquid. It is toxic by inhalation, skin absorption, and or ingestion. In case of damage to. or leaking from containers o< this material contact the pesticide safety team network. Telephone: 60C 424-9300. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors -O 0. April 1981 DICHLORVOS (AGRICULTURAL INSECTICIDES, NEC. 4921S3S OTHER THAN LIQUtD) POISON B NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10'4.54) Dichforvos is a colorless to amber liquid absorbed on a dry carrier. It is used as a pesticide. It is a wettable powder. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. If material on fire or Involved in fire Extinguish tire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in Hooding quantities as fog Use "alcohol" foam, caroon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving m ram or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates DICHLORVOS (INSECTICIDES. OTHER THAN 4921536 AGRICULTURAL, NEC) POISON B NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10 4.54) Dichlorvos is a colorless to amber liquid or the liquid absorbed on a dry carrier. It is used as a pesticide. It is a wettable powder or water emulsifiable liquid. It is toxic by inhalation, skin absorption, and or inges tion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing April 1981 Do not handle broken packages without protective equipment Wash away any material which may have contacted the DoOy with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors DICHLORVOS MIXTURE. DRY (AGRICULTURAL 4921537 INSECTICIDES, NEC, OTHER THAN LIQUID) POISON B NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10 4.54) Dichlorvos mixture, dry is a colorless to amber liquid absorbed on a dry earner. It is used as a pesticide. It is a wetable powder It is toxic by inhalation, skin absorption, and or ingestion In case of damage to. or leaking trom containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty i Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in ram or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barners to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates OICUMYL PEROXIDE (50% PEROXIDE) 4919545 ORGANIC PEROXIDE NA2121 Dicumyl peroxide (50% peroxide) is a colorless to straw colored liquid, it may take some effort to ignite but once ignited it burns with increasing vigor as the fire progresses, it strongly supports (he burning of com bustible materials. If the containers of the peroxide are exposed to fire or heat for prolonged periods, they may explode Continued on next page MCD OOOOl? H6 189 If material on fire or involved in fire Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Keep spilled material wet Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet DICYCLOHEXYL PEROXYDICARBONATE, (NOT MORE 4919248 THAN 91% WITH WATER) ORGANIC PEROXIDE UN21S3 Dicyclohexyl peroxydlcarbonate. (not more than 91% with water) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and burns with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combustible materials. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or Involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use ' alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet DICUMYL PEROXIDE. DRY 4919540 ORGANIC PEROXIDE UN2121 Dicumyl peroxide, dry is a buff colored crystalline or lumpy solid. Ii is easily ignited and once ignited it burns with increasing vigor as the fire progresses. It strongly supports (he burning of combustible material. If the containers of the peroxide are exposed to lire or heat for prolonged periods, they may explode. If material on tire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in lire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Personnel protection Avoid breathing vapors or dusts Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective eguipment Wash away any matehal which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet DICYCLOHEXYL PEROXYDICARBONATE, 4919247 (TECHNICALLY PURE) ORGANIC PEROXIDE UN2152 Dicyclohexyl peroxydicarbonate, (technically pure) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and burns with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combus tible materials. It supports the burning of combustible matenals. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or Involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If malarial not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up 190 NCI) 000l7ll? April 1981 Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet DIELDRIN (AGRICULTURAL INSECTICIDES, NEC, 4941134 LIQUID) ORM-A NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Dieldrin is a light tan solid dissolved in a liquid carrier. It is used as a pesticide. It is a water emulsifiable liquid. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion if dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration * Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates DIELDRIN (AGRICULTURAL INSECTICIDES, NEC, 4941135 OTHER THAN LIQUID) ORM-A NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-1/0.454) Dieldrin is a light tan solid. It is used as a pesticide. It is a wettable powder. It can cause illness by inhalation, skin absorption and-or inges tion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 600-424-9300. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) H material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of toppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates DIELDRIN (INSECTICIDES, OTHER THAN 4941133 AGRICULTURAL, NEC) ORM-A NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Dieldrin is a light tan solid or the solid dissolved in a liquid carrier. It is used as a pesticide. It is a wettable powder or water emulsifiable liquid. It can cause illness by inhalation, skin absorption and or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300, If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) if material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates DIESEL FUEL (See FUEL OIL 4915113) DIETHYL BENZENE (COMBUSTIBLE LIQUID, N.O.S.) 4913135 COMBUSTIBLE LIQUID NA1993 Dietheylbenzene is a clear colorless liquid with an aromatic odor. It has a flash point of 140 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical Continued on next page 191 mod 000017118 If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water DIETHYL OICHLOROSiLANE 4907609 FLAMMABLE LIQUID, CORROSIVE UN1767 Diethyl dichiorosilane is a colorless liquid with a pungent odor. It has a flash point of 77 deg. F. It is readily decomposed by water to hydro chloric acid with evolution of heat. It is corrosive to metals and tissue. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use "alcohol" foam, carbon dioxide or dry chemical Do not use water on material itself Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on tire), downwind evacuation must be considered DIETHYL PEROXYDICARBONATE, (NOT MORE THAN 4919251 27% >N SOLUTION) ORGANIC PEROXIDE UN2175 Diethyl peroxydicarbonate, (not more than 27% in solution) is a col orless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber, it is insoluble in water. The liquid or solution may require some effort to ignite; but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous Ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burn ing of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet DIETHYL KETONE 4909150 FLAMMABLE LIQUID UN1156 Diethyl ketone is a clear colorless liquid with an acetone-like odor. It has a flash point of 55 deg. F. It is lighter than water and slightly soluble m water, its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers DIETHYL SULFATE (CORROSIVE LIQUID, N.O.S.) 4933320 CORROSIVE MATERIAL, ACIDIC UN1760 Diethyl sulfate is a clear colorless liquid with a peppermint odor. If will bum though it may require some effort to ignite. It is heavier than water and is slowly decomposed by water to ethyl alcohol, a flammable liquid, and ethyl sulfate. It is corrosive to metals and tissue. If material on fire or involved in fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible 192 April 1981 mcd 00l7il9 If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing DIETHYLAMINE 4907815 FLAMMABLE LIQUID, CORROSIVE, BASIC UN1154 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Diethylamine is a clear colorless liquid with an ammonia like odor. It has a flash point of -15 deg. F. It is a respiratory irritant and is corrosive to the eyes and skin. It is lighter than water and soluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion ot this material. It weighs 5.9 pounds per gallon. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable or container is exposed fo direct flame--evacuate tor a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash. cement powder, sawdust, or com mercial sorbents Neutralize with sodium bisutfate (nahso4) Environmental considerations--water spill Add sodium bisulfate If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration April 1981 Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment DIETHYLAMINOETHANOL (COMBUSTIBLE LIQUID. 4913186 N.O.S.) COMBUSTIBLE LIQUID NA1993 Diethylaminoethanol is a clear colorless liquid, it is used to make other chemicals, it has a flash point of 140 deg. F. It is lighter than water and is soluble in water, its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material. If material Involved in fire Use water in flooding quantities as fog Solid streams ot water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible For scattered burning fusees, smother in dirt If material not on fire and not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Keep upwind Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material if contact with the material anticipated, wear full protective clothing DIETHYLENETRIAMINE (CORROSIVE LIQUID, N.O.S.) 4935631 CORROSIVE MATERIAL, BASIC UN1760 Diethylenetriamine is a yellow colored liquid with an ammonia-like odor. It is used as a solvent for plastics and dyes and in chemical synthesis. It is lighter than water and soluble in water. It will burn though it may take some effort to ignite, t is corrosive to metals and tissue. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing 000017120 MOD 193 DIETHYLHYDROXYLAMINE (COMBUSTIBLE LIQUID. 4913185 N.O.S.) COMBUSTIBLE LIQUID NA1993 Diethylhydroxylamine is a clear colorless liquid. It is used in photog raphy and as a corrosion inhibitor. It has a (lash point of 113 deg. F. it is lighter than water and is soluble in water, its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Soiid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material' not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing DIFLUOROMONOCHLOROETHANE 4905719 FLAMMABLE GAS UN2517 Difluoromonochloroethane is a colorless gas shipped as a liquefied gas under its vapor pressure. Contact with the liquid can cause frostbite. It is easily ignited. Its vapor is heavier than air and a flame can travel back to the source of leak very easily. The leak can either be a liquid or vapor leak. It can asphyxiate by the displacement of air. Under fire conditions the cylinders or tank cars may violently rupture or rocket. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Wear self-contained breathing apparatus when fighting fires involv ing this material Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered 1,1-DIFLUORO*1-CHLOROETHANE (See DIFLUOROMONOCHLOROETHANE 4904552) DIFLUOROETHANE 4905716 FLAMMABLE GAS UNI 030 Difluoroethane is colorless, odorless gas shipped as a liquefied gas under its vapor pressure. Contact with the liquid can cause frostbite. It is easily ignited. Its vapors are heavier than air and a flame can travel back to the source of leak very easily. This leak can be either a liquid or vapor leak. It can asphyxiate by the displacement of air. Under fire conditions the cylinders or tank cars may violently rupture and rocket. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak If without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Wear self-contained breathing apparatus when fighting fires involv ing this material Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered DIFLUOROPHOSPHORIC ACID. ANYDROUS 4930214 CORROSIVE MATERIAL. ACIDIC UN1768 Difluorophosphoric acid is a colorless fuming liquid. It is soluble in water. It is corrosive to metals and tissue If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Coot all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing 2,2-DIHYDROPEROXY PROPANE. (NOT MORE THAN 4919253 25% WITH INERT ORGANIC SOLID) ORGANIC PEROXIDE UN2178 2,2-dihydroperoxy propane, (not more than 25% with inert organic solid) is a white solid. It is used to manufacture paints, plastics, and rubber. It is slightly soluble in water. It is easily ignited and bums with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combustible materials. It supports the burning of com bustible materials. Under prolonged exposure to fire or heat containers of the material may explode. 194 MCD 000017121 April 1981 If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, caroon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenai which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the matenai anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet DIHYDROPYRAN 4908240 FLAMMABLE LIQUID UN2376 Dihydropyran is a clear colorless liquid with an ethereal odor. It has a flash point of 0 deg. F. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenai which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If matenai leaking (not on fire), downwind evacuation must be considered DIISOBUTYL KETONE 4913140 COMBUSTIBLE LIQUID UN1157 Diisobutyl kefone is a clear colorless liquid. It has a flash point of 140 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog April 1981 Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, caroon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water DIISOBUTYLAMINE (FLAMMABLE LIQUID, N.O.S.) 4909177 FLAMMABLE LIQUID UN1993 Diisobutylamine is a clear colorless liquid with a fish like odor. It has a flash point of 85 deg. F. Jt is lighter than water and insoluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop teak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material DIIS08UTYLCARBIN0L (COMBUSTIBLE LIQUID, 4913119 N.O.S.) COMBUSTIBLE LIQUID UN1967 Diisobutylcarbinol is a colorless liquid. It has a flash point of 162 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Continued on next page 195 MCD 000017122 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet DIISOBUTYLENE (FLAMMABLE LIQUID, N.O.S.) 4909209 FLAMMABLE LIQUID UN1993 Diisobutylene is a clear colorless liquid with a petroleum-like odor is used in the manufacture of other chemicals. It has a flash point of 10 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities ot water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water DIISOBUTYRYL PEROXIDE, (NOT MORE THAN 52% IN 4919255 SOLUTION) ORGANIC PEROXIDE UN2182 Oiisobutyryl peroxide, (not more than 52% in solution) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burn ing of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or Involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 196 DIISOOCTYL ACID PHOSPHATE 4933325 CORROSIVE MATERIAL, ACIDIC. COMBUSTIBLE UN1902 Diisooctyl acid phosphate is a colorless liquid, it will bum though it may require some effort to ignite, it is corrosive to metals and tissue If material on fire or Involved in fire Use dry chemical, carbon dioxide, or dry sand Cool ali affected containers with flooding quantities of water Apply water from as far a distance as possible Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled matenal with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing DIISOPROPYL ETHER 4908195 FLAMMABLE LIQUID UN1159 Diisopropyl ether is a clear colorless liquid with an ethereal odor, it has a flash point ot -18 deg. F. On prolonged standing in contact with air peroxides may form which may explode spontaneously or if heated. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 mcd 0017123 Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered DIISOPROPYLAMINE 4909148 FLAMMABLE LIQUID UN1158 Diisopropyiamine is a clear colorless liQuid with an ammonia-like odor, it is used to make other chemicals. It has a flash point of 30 deg. F. It is lighter than water and is soluble in water, its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing DIISOPROPYLBENZENE HYDROPEROXIDE SOLUTION 4919130 (NOT OVER 60% PEROXIDE) ORGANIC PEROXIDE UN2171 Diisopropylbenzene hydroperoxide is a colorless to pale yellow liquid. It must be shipped in a non-volatile solvent not exceeding 60% con centration. It may take some effort to ignite but once ignited it burns with increasing vigor as the fire progresses. It strongly supports the burning of combustible materials. Under prolonged exposure to heat or fire con tainers of material can explode. Chemical substances can cause a vi olent chemical reaction, it supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spitied material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles April 1961 Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet DIISOTRIOECYL PEROXYDICARBONATE, 4919257 (TECHNICALLY PURE) ORGANIC PEROXIDE UN2889 Diisotridecyl peroxydicarbonate. (technically pure) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of com bustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet DIMETHYL CARBONATE 4909154 FLAMMABLE LIQUID UN1161 Dimethyl carbonate is a clear, colorless liquid with a pleasant odor. It is used to make other chemicals and as a special purpose solvent. It has a flash point of 66 deg. F. It is heavier than water and slightly soluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Continued on next page 197 MCD 000017124 If material not on fire and not involved in fire Keep sparks, flames, and Other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation tf fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered DIMETHYL CHLOROTHIOPHOSPHATE 4933319 CORROSIVE MATERIAL, POISONOUS NA2922 Dimethyl chlorothiophosphate is a colorless to light amber liquid. It is used to make other chemicals, as a corrosion inhibitor, as a fuel and lubricant additive, and for may other uses. It is slightly soluble in water. It is corrosive to metals and tissue. It is toxic by inhalation, skin ab sorption. and/or ingestion. If material Involved in fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved In fire Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material' If contact with the material anticipated, wear full protective clothing DIMETHYL ETHER 490S725 FLAMMABLE GAS UNI 033 Dimethyl ether is a colorless gas with a faint ethereal odor. It is shipped as a liquefied gas under its vapor pressure. Contact with the liquid can cause frostbite, ft is easily ignited. Its vapors are heavier than air and a flame can flash back to the source of leak very easily. The leak can either be liquid or vapor leak. It can asphyxiate by the displacement of air, Under fire conditions the cylinder or tank car may violently rupture. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors DIMETHYL HYDRAZINE, UNSYMMETRICAL 4906210 FLAMMABLE LIQUID, POISONOUS, CORROSIVE UN1163 THERMALLY UNSTABLE Unsymmetrical dimethylhydrazine is a clear colorless liquid with an ammonia like odor. It is used as a rocket propellant, to make other chemicals, and for many other uses. It has a flash point of 0. deg. F. It is flammable over a wide range of vapor-air concentrations. It may ignite spontaneously in contact with oxidizers. The vapors are toxic and attack the eyes and respiratory system. The liquid is corrosive to the skin. It is lighter than water and soluble in water. The vapors are heavier than air. Prolonged exposure of containers of the material to fire or heat may result in their violent rupturing and rocketing due to the decom position of the material. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material put of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 5000 feet If material leaking (not on fire), downwind evacuation must be considered DIMETHYL PHOSPHOROCHLORIDOTHIOATE (See DIMETHLYL CHLOROTHIOPHOSPHATE 4933319) DIMETHYL SULFATE 4933322 CORROSIVE MATERIAL, ACIDIC, COMBUSTIBLE UNI 595 Dimethyl sulfate is a colorless oily liquid, odorless to a faint onlonlike odor. It is a combustible liquid and has a flash point of 182 deg. F. It is slightly soluble in water and decomposed by water to give suifuric acid with evolution of heat. It is corrosive to metals and tissue. 198 000 April 1961 If material on fire or involved In fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire end not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing DIMETHYL SULFIDE 4908151 FLAMMABLE LIQUID UN1164 Dimethyl sulfide is a clear colorless to straw colored liquid with a disagreeable odor. It has a Hash point of less than 0. deg. F. It Is lighter than water and slightly soluble in water. Its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water In flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical tl material not on fire and not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak If without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered April 1981 2,5-DIMETHYL-2,5-Dl-(BENZOYLPEROXY) HEXANE, 4919260 (NOT MORE THAN 82% WITH INERT SOLID) ORGANIC PEROXIDE UN2173 2,5-dimethyl-2,5-di-(benzoylperoxy) hexane, (not more than 62% with inert solid) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water, it is easily ignited and burns with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combustiblemateriats. It supports the burning of com bustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use ` alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet 2,5-DIMETHYL*2,5-DI-(BENZOYLPEROXY) HEXANE, 4919259 (TECHNICALLY PURE) ORGANIC PEROXIDE UN2172 2.5-dimethyl-2.5-di-(benzoylperoxy) hexane, (technically pure) is a white solid. It is used to manufacture paints, plastics, and rubber, It is insoluble in water. It Is easily ignited and burns with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combustible materials. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. H materia) on tire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not Involved in fire Keep sparks, tlames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Continued on next page 199 HOD OOOO 1.7126 Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet 2,5-DIMETHYL2,5*DI*(TERT-BUTYLPEROXY) HEXANE, 4919263 (NOT MORE THAN 52% WITH INERT SOLIO) ORGANIC PEROXIDE UN2156 2.5-dimethyl-2,5-di-(tert-butylperoxy) hexane, (not more than 52% with inert solid) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and burns with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combustible materials. It supports the burning of com bustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Appiy water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive if materiai not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material if contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet 2,5-DIMETHYL-2,5-DI-(TERT-BUTYLPEROXY) HEXANE, 4919262 (TECHNICALLY PURE) ORGANIC PEROXIDE UN2155 2,5-dimethyl-2,5-di-(tert-butylperoxy) hexane, (technically pure) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite; but once ignited, it will bum with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burn ing of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled materiai wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting tires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet 2,5-DIMETHYL-2,5*Dl-(TERT-BUTYLPEROXY)HEXYNE- 4919265 3, (NOT MORE THAN 52% WITH INERT SOLID) ORGANIC PEROXIDE UN2159 2,5-dimethyl-2.5-di-(!eri-butyiperoxy)hexyne-3, (not more than 52% with inert solid) is a white solid. It is used to manufacture paints, plastics, and rubber, it is insoluble in water, it is easily ignited and burns with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combustible materials. It supports the burning of com bustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as log Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep materiai out of water sources and sewers Keep spilled material wet Wet spilled materiai before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any materiai which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the materiai is on fire or involved in fire evacuate for a radius of 2500 feet 200 April 1981 MOD 0000171.27 2,5-DIMETHYL-2,5-DI-(TERT-BUTYLPEROXY)HEXYNE- 4919264 3, (TECHNICALLY PURE) ORGANIC PEROXIDE UN2158 2,5-dimethyl-2,5-di-(tert-butylperoxy)hexyne-3. (technically pure) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burn ing of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or Involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Appiy water from as far a distance as possible Use `'alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting tires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet 2.5-DIMETHYL-2.5-DH2-ETHYLHEXANOYLPEROXY) 4919258 HEXANE, (TECHNICALLY PURE) ORGANIC PEROXIDE UN2157 2.5-dimethyl-2,5-di-(2-ethylhexanoylpefOxy) hexane, (technically pure) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spon taneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet 2,5-DIMETHYL-2,5-DIHYDROPEROXY HEXANE, (NOT 4919261 MORE THAN 82% WITH WATER) ORGANIC PEROXIDE UN2174 2,5-dimethyl-2.5-dihydroperoxy hexane, (not more than 82% with water) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and burns with increas ing rapidity as the fire progresses. It can form explosive mixtures with finely divded combustible materials. It supports the burning of combus tible materials. Under prolonged exposure to fire or heat containers of the material may explode. if material on fire or involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use ' alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet DIMETHYLAMINE, ANHYDROUS 4905510 FLAMMABLE GAS, CORROSIVE UN1032 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Dimethylamine anhydrous is a colorless gas with a fish-like odor at low concentrations changing to ammonia-like odor at higher concentra tions. It is used to make other chemicals, as a solvent, as a solvent, and for many other uses. It is shipped as liquefied gas under its vapor pressure. Contact with the liquid can cause frostbite or chemical type bums. The gas itself is corrosive and it is soluble in water to form flammable corrosive solutions. It is easily ignited. Its vapor is heavier than air and a flame can flash back to the source of leak very easily. It can asphyxiate by the displacement of air. Under fire conditions the cylinders or tank cars may rupture and rocket. Toxic oxides of nitrogen are produced during combustion of this material. It weighs 5.5 pounds per gallon. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Continued on next page MCD 000017128 201 If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet if material leaking (not on fire), downwind evacuation must be considered Environmental considerations---land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash, cement powder, sawdust, or com mercial sorbents Neutralize with sodium bisulfate (nahso4) Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e.g. detergent, soaps, alcohols) to com press and thicken spilled material Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Add sodium bisuifate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment DIMETHYLAMINE, AQUEOUS SOLUTION 4907820 FLAMMABLE LIQUID, CORROSIVE, BASIC UN1160 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Dimethylamine. aqueous solution is the solution of dimethylamine, a gas, in water and has an odor ranging from a fish-iike to ammonia-like as the vapor concentration increases. A 25% solution has a flash point of 54 deg. F. It is corrosive to the skin and eyes. The solution is lighter than water and soluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material. It weighs 7.3 pounds per gallon. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on tire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash. cement powder, sawdust, or com mercial sorbents Apply "universal1' gelling agent to immobilize spill Neutralize with sodium bisulfate (nahso4) Environmental considerations--water spill Add sodium bisulfate If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment DIMETHYLAMINIOETHYL METHACRYLATE 4912218 (COMBUSTIBLE LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 POLYMERIZABLE Dimethylaminioethyl methacrylate is a clear colorless liquid. It is used to make plastics, in textiles, and for many other uses, its vapors are irritating to eyes and mucous membranes. It has a flash point of 165 deg. F. It is lighter than water and is insoluble in water, its vapor are heavier than air. If it becomes contaminated or is subject to heat, it may polymerize, if this polymerization takes place inside a container, the container may violently rupture, toxic oxides of nitrogen are produced during combustion of this material, if material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water DIMETHYLAMINOETHANOL (COMBUSTIBLE LIQUID, 4913184 N.O.S.) COMBUSTIBLE LIQUID NA1993 Dimethylaminoethanol is a clear colorless liquid having a fish-like odor. It is used to make other chemicals. If has a flash point of 105 deg. F. It is lighter than water and is soluble in water, its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion ol this material. 202 ArC&i 'On J0 9 April 1981 If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing 2.3- DIMETHYLBUTANE 4906275 FLAMMABLE LIQUID UN2457 2, 3-dimethylbutane is a clear colorless liquid with a petroleum odor. It has a flash point of -20 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, (lames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop ieak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet if material leaking (not on fire), downwind evacuation must be considered 1.4- DIMETHYLCYCLOHEXANE 4909156 FLAMMABLE LIQUID UH2263 1,4-dimethytcyclohexane is a clear, colorless liquid with a petroleum like odor. It has a flash point of 51 to 61 deg. F. It is lighter than water and is insoluble in water. Its vapors are heavier than air. tf material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers April 1981 Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water DIMETHYLDICHLOROSILANE 4907610 FLAMMABLE LIQUID, CORROSIVE, ACIDIC UN1162 Dimethyldichlorosilane is a colorless fuming liquid with a pungent odor. It has a flash point of 16 deg. F. Vapor and liquid can cause bums. It is heavier than water and is decomposed by water to form hydrochloric acid, a corrosive material. Its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use "alcohol" foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered DIMETHYLETHYLAMINE (FLAMMABLE LIQUID, 4907825 N.O.S.) FLAMMABLE LIQUID UNI 993 Dimethylethyiamine is a clear colorless liquid with a strong odor that can vary from ammonia to fish-like. It is used in the manufacture of other chemicals. It has a flash point of 10 deg.f. Its vapors are irritating to the eyes and mucous membranes. It is lighter than water and soluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors Continued on next page MCD 000017130 203 If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable or container is exposed to direct flame---evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered DIMETHYLHEXANE DIHYDROPEROXIDE, (WITH 18% 4919140 OR MORE WATER) ORGANIC PEROXIDE UN2174 Dimethylhexane dihydroperoxide solution is a slurry or sludge of white crystals. Wet. the material requires some effort to ignite, but once ignited it burns very rapidly. Dry. the material is very easily ignited. In either condition it strongly supports the burning of combustible materials. Under prolonged exposure to heat or fire containers of the material can explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled matenaf wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material It contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet DIMYRISTYL PEROXYDICARBONATE, (NOT MORE 4919270 THAN 22%, STABLE DISPERSION, IN WATER) ORGANIC PEROXIDE UN2892 Dimyristyl peroxydicarbonate. (not more than 22%. stable dispersion, in water) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. The liquid or solution may require some effort to ignite: but once ignited, it will burnwith increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction, it supports the burn ing of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. 204 If material on fire or Involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Appiy water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the matenal Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet DIMYRISTYL PEROXYDICARBONATE, (TECHNICALLY 4919269 PURE) ORGANIC PEROXIDE UN2595 Dimyristyl peroxydicarbonate. (technically pure) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and burns with increasing rapidity as the fire pro gresses. it can form explosive mixtures with finely divided combustible materials. It supports the burning of combustible materials. Under pro longed exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet MCD 00001713 April 1981 DINITROBENZENE, SOLID OR DINITROBENZOL. 4921421 SOLID POISON B UN1597 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000454) Dinitrobenzene, solid is a white or yellow crystalline solid. It is slightly soluble in water. It is toxic by skin absorption and by inhalation (dust.etc). It is combustible. Prolonged exposure of the material to fire or heat may result in the spontaneous decomposition ol the material with a resultant explosion. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or Involved in fire Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use '`alcohol'1 foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear sell-contained breathing apparatus when fighting fires involv ing this material Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fiqhting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates DINITROBENZOL, SOLUTION 4921422 POISON B UNI 597 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RG-1000/454) Dinitrobenzol. solution is the colorless or yellow solution of dinitro benzene in a suitable solvent. The flammability of the solution depends on the nature of the solvent. The material itself is combustible. It is toxic by skin absorption and inhalation. Prolonged exposure to tire or heat may result in spontaneous decomposition with a resultant explosion. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol' foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment April 1981 Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash, cement powder, sawdust, or com mercial sorbents Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e.g. detergent, soaps, alcohols) to com press and thicken spilled material Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates DINITROCHLOROBENZOL, SOUD OR 4921424 DINITROCHLOROBENZENE POISON B UNI 577 Dinitrochlorobenzol. solid is a colorless to yellow crystalline solid with an almond like odor, it is insoluble in water. It is combustible though it may require some effort to ignite. It is toxic by skin absorplion or in halation (dust, etc.). Prolonged exposure to fire or heat may result in spontaneous decomposition with a resultant explosion. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or Involved in fire Use water in flooding quantities as fog Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing DINITROPHENOL (FLAMMABLE SOLID, POISONOUS, 4916626 N.O.S.) FLAMMABLE SOUD,POISONOUS UNI 992 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Dinrtrophenol is a yellow crystalline solid, shipped water wet with at least 15 % water. It is used to make dyes, as a lumber preservative, and to make explosives. When not water wet it is a high explosive. Dry, the material is easily ignited and it will burn very vigorously. The wet material can bum though it may require some effort to ignite. It is slightly soluble in water. Toxic oxides of nitrogen are produced in fires involving this material. If material on fire or Involved In fire Dangerously explosive Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Continued on next page 205 Mod 000017I32 tf material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Do not attempt to sweep up dry material Personnel protection Wear boots, protective gioves. and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable--evacuate for a radius of 5000 feet Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates DINITROPHENOL SOLUTION 4921425 POISON B UNI 599 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Dinitrophenol solution is a yellow colored liquid of the yellow crystalline material dissolved in a suitable solvent. The material itself is very slightly soluble in water. The flammability of the solution depends on the nature of the solvent. Dinitrophenol itself is combustible though it may require some effort to ignite. It is toxic by skin absorption and inhalation. Pro longed exposure to fire or heat may result in the spontaneous decom position and heating with a resultant explosion. Toxic oxides ot nitrogen are produced during combustion of this material. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig apit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e g. detergent, soaps, alcohols) to com press and thicken spilled material Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates DINITROTOLUENE, LIQUID 4963120 ORM-E UN1600 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Dinitrotoluene, liquid is a yellow colored liquid, it is used to make dyes, explosives, and other chemicals, it is insoluble in water, it is combustible though it may take some effort to ignite. Toxic oxides of nitrogen are produced during combustion of this material. It weighs 10.6 pounds per gallon. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors or dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Apply "universal" gelling agent to immobilize spill Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spiii motion Use surface active agent (e.g. detergent, soaps, alcohols) to com press and thicken spilled material Inject "universal'' gelling agent to solidify encircled spill and increase effectiveness of booms Remove trapped material with suction hoses If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates DINITROTOLUENE, SOLID 4963115 ORM-E UN1600 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Dinitrotoluene is a yellow crystalline solid. It is used to make dyes, explosives, and other chemicals. It is insoluble in water. It is combustible though it may take some effort to ignite. Toxic oxides of nitrogen are produced during the combustion of this material. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use foam, carbon dioxide or dry chemical 206 April 1981 MCD "oi7133 K material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors or dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom Remove trapped material with suction hoses If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates DIOXANE 4909155 FLAMMABLE LIQUID UN1165 Dioxane is a ciear colorless liquid with a faint ethereal odor. It has a flash point of 55 deg. F. It is slightly heavier than water and is soluble in water. Its vapors are heavier than air. If malarial on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water DIOXOLANE 4909158 FLAMMABLE LIQUID UN1166 Dioxolane is a clear colorless liquid. It has a flash point of 35 deg. F. It is lighter than water and is soluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical tf material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers April 1981 Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water DIPHENYL DiCHLOROSILANE 4934235 CORROSIVE MATERIAL, ACIDIC UN1769 Diphenyl dichlorosilane is a colorless liquid with a pungent odor. Ma terial will burn though it may require some eftort to ignite. It is decom posed by water to hydrochloric acid with evolution of heat. It is corrosive to metals and tissue. If material on fire or involved In fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing DIPHENYL METHYL BROMIDE, SOLID 4936220 CORROSIVE MATERIAL UN1770 Diphenyl methyl bromide, solid is a white crystalline solid. It is insoluble in cold water and is decomposed by hot water producing hydrobromic acid, a corrosive material. It is corrosive to tissue. H material on fire or involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible ft material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing 207 MCD 000017134 DIPHENYL METHYL BROMIDE, SOLUTION 4936225 CORROSIVE MATERIAL UN1770 Diphenyl methyl bromide, solution is the white crystalline solid dis solved in some solvent. The combustibility of the solution depends on the solvent used. Diphenyl methyl bromide is insoluble in cold water and is decomposed by hot water producing hydrobromic acid, a corrosive material. The solution is corrosive to metals and tissue. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing DJPHENYLAMINECHLOROARSINE 4925230 IRRITATING MATERIAL UN169B Diphenylaminechloroarsine is in Ihe form of yellow crystals. The va pors of this material are very irritating to the eyes and mucous mem branes and are also nauseating. If material on fire or Involved in fire Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantifies of water Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing DIPHENYLCHLORARSINE (IRRITATING AGENT, 925240 N.O.S.) IRRITATING MATERIAL NA1693 Diphenylchloroarsine is in the form of colorless crystals if pure oth erwise a brown oily liquid. The vapors of the material are extremely irritating to the eyes and mucous membranes, if material on fire or involved in fire Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water Use water spray to absorb vapors 208 If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Evacuation If material leaking (not on fire), downwind evacuation must be considered DIQUAT (AGRICULTURAL INSECTICIDES, NEC, 4963342 LIQUID) ORM'E NA2781 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Oiquat is a yellow crystalline sollid dissolved in a liquid carrier, tt is used as a herbicide. It is a water emulsifiable liquid. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates DIQUAT (AGRICULTURAL INSECTICIDES, NEC, 4963344 OTHER THAN LIQUID) ORM'E NA2781 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Diquat is a yellow crystalline solid. It is used as a herbicide. It is a wettable powder. It can cause illness by inhalation, skin absorption and/ or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424- 9300. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary April 1981 MCD 000017135 Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates DIQUAT (INSECTICIDES. OTHER THAN 4963339 AGRICULTURAL, NEC) ORM-E NA2781 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Diquat is a yellow crystalline solid or me solid dissolved in a liquid carrier. It is used as a herbicide. It is a wettabie powder or water emul- sifiable liquid. It can cause illness by inhalation, skin absorption and/or ingestion, in case of damage to, or leaking from containers of this ma terial contact the pesticide safety team network. Telephone: 800-424- 9300. H material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates DISINFECTANT, LIQUID 4923910 POISON B UN1601 Disinfectant, liquid is a variable colored liquid. It is generally soluble in water. It is toxic by ingestion, inhalation (vapors, mists, etc.), or by skin absorption. H material on fire or involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material April 1981 Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing DISINFECTANT, LIQUID 4936561 CORROSIVE MATERIAL UN1903 Disinfectant, liquid is a variable colored liquid. It is generally soluble in water. It may be combustible though it may require some effort to ignite, it may be toxic by ingestion, inhalation (vapors, mists, etc.) or by skin absorption. It is corrosive to metals and/or tissue. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing DISINFECTANT, LIQUID, N.O.S. 4915115 COMBUSTIBLE LIQUID NA1993 Disinfectant, liauid. n.o.s. is a variable colored liquid. It has a flash point between 100 and 199 deg. F. Although the material is not classed as a poison b. breathing of the vapors or skin contact with the liquid should be avoided. It is lighter than water and soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as log Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical H material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gioves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing y.36 00 209 DISINFECTANT, SOLID 4923911 POISON B UNI 601 Disinfectant, solid is a variable colored solid. It is generally soluble in water, it is toxic by ingestion, inhalation (dusts), or by skin absorption. If material on fire or Involved in fire Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing DISPERSANT GASES, NEC (COMPRESSED GAS, 4904536 N.O.S.) NONFLAMMABLE GAS UN1956 Dispersant gases, nec are materials which are shipped in containers under pressure. They may be mixtures consisting of nonflammable gas(es) (and flammable gas(es)) with the mixture being nonflammable. The mixture may separate with the flammable gas setting into low areas, or the nonflammable gas setting into low areas. It may asphyxiate by the displacement of air. It may only be shipped in cylinders. Toxic gases can be produced in fires involving this material. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Coot all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment DISPERSANT GASES, NEC, FLAMMABLE 4905727 (COMPRESSED GAS, N.O.S.) FLAMMABLE GAS UN1954 Dispersant gases are colorless gases shipped as liquefied gases un der its vapor pressure. Contact with the liquid can cause frostbite, it is easily ignited. Its vapors are heavier than air and a flame can flash back to the source of leak very easily. This leak may either be a liquid or vapor leak. It can asphyxiate by the displacement of air. Under fire conditions the cylinder or tank car may violently rupture and rocket. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered DISULFOTON (AGRICULTURAL INSECTICIDES, NEC, 4921511 LIQUID) POISON B NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Disutfoton is a pale yellow liquid, it is used as a pesticide. It is a water emulsifiable liquid. It is toxic by inhalation, skin absorption, and/or inges tion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 600-424-9300. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors DISULFOTON (AGRICULTURAL INSECTICIDES, NEC. 4921512 OTHER THAN LIQUID) POISON B NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Disulfoton is a pale yellow liquid absorbed on a dry carrier. It is used as a pesticide. It is a wettable powder. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. 210 April 1981 MCI) 000017137 If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use '`alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates DISULFOTON (INSECTICIDES. OTHER THAN 4921513 AGRICULTURAL, NEC) POISON B NA27B3 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Disulfoton is a pale yellow liquid or the liquid absorbed on a dry carrier. It is used as a pesticide. It is a wettable powder or water emulsifiable liquid. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder April 1981 Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates DISULFOTON MIXTURE, DRY (AGRICULTURAL 4921508 INSECTICIDES, NEC, OTHER THAN LIQUID) POISON B NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Disulfoton mixture, dry is the pale yellow liquid absorbed on a dry carrier. It is used as a pesticide. It is a wetable powder. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates DISULFOTON MIXTURE, LIQUID (AGRICULTURAL 4921509 INSECTICIDES, NEC, LIQUID) POISON B NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Disulfoton mixture, liquid is a pale yellow liquid, it is used as a pes ticide. It is a water emulsifiable liquid. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Continued on next page MCB 000017138 211 If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of fOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors DITHIOCARBAMATE PESTICIDE. LIQUID, N.O.S. 4921631 (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL, NEC) POISON B UN2771 Dithiocarbamate pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The carrier may bum though it may require some effort to ignite. It is toxic by inhalation, skin ab sorption, and/or ingestion. In case of damage to. or leaking from con tainers of this material contact the pesticide safety team network. Tele phone: 800-424-9300. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water DITHIOCARBAMATE PESTICIDE, LIQUID, N.O.S. 4921632 (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC, LIQUID) POISON B UN2771 Dithiocarbamate pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The carrier may bum though it may require some effort to ignite. It is toxic by inhalation, skin ab sorption. and/or ingestion. In case of damage to. or leaking from con tainers of this material contact the pesticide safety team network. Tele phone: 800-424-9300. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as tar a distance as possible Use `'alcohol" foam, carbon dioxide or dry chemical If material not on firs and not involved in fire Keep sparks, (lames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 212 DITHIOCARBAMATE PESTICIDE. LIQUID, N.O.S. (COMPOUNDS AND PREPARATIONS) 4910532 (AGRICULTURAL INSECTICIDES, NEC. LIQUID) FLAMMABLE LIQUID UN2772 Dithiocarbamate pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The primary hazard of this material Is the flammability of the carrier. It has a flash point below 100 deg. F. It can cause illness by inhalation, skin absorption and/or inges tion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggies Do not handle broken packages without protective equipment Wear self-contained breathing apparatus when fighting fires involv ing this material MOD 000017139 April 1981 DITHIOCARBAMATE PESTICIDE. LIQUID, N.O.S. 4910531 (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL, NEC) FLAMMABLE LIQUID UN2772 Dithiocarbamate pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The primary hazard of this material is the flammability of the carrier, It has a flash point below 100 deg. F. It can cause illness by inhalation, skin absorption and/or inges tion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wear self-contained breathing apparatus when fighting fires involv ing this material OITHfOCARBAMATE PESTICIDE, SOLID. N.O.S. 4921633 (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL. NEC) POISON B UN2771 Dithiocarbamate pesticide is a solid or a iiquid absorbed on a dry carrier, it is a wettable powder. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800- 424-9300. If material on fire or involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as tog Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing DITHIOCARBAMATE PESTICIDE, SOLID. N.O.S. (COMPOUNDS AND PREPARATIONS) 4921634 (AGRICULTURAL INSECTICIDES, NEC, OTHER THAN LIQUID) POISON B UN2771 Dithiocarbamate pesticide is a solid or a liquid absorbed on a dry carrier. It is a wettable powder. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800* 424-9300. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting (ires involv ing this material If contact with the material anticipated, wear full protective clothing April 1981 OIURON (AGRICULTURAL INSECTICIDES, NEC, 4962620 LIQUID) ORM-E NA2767 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Diuron is a white crystalline solid dissolved in a liquid carrier. It is used as a herbicide. It is a water emulsifiable liquid. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain How as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates MCD 000017140 213 DIURON (AGRICULTURAL INSECTICIDES, NEC, 4962621 OTHER THAN LIQUID) ORM-E NA2767 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/4S.4) Diuron is a white crystalline solid. It is used as a herbicide. It is a wettable powder. It can cause illness by inhalation, skin absorption and/ or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424- 9300. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill If dissolved, apply activated carbon at ten times the so'Ned amount in region of 10ppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates DIURON (INSECTICIDES, OTHER THAN 4962622 AGRICULTURAL, NEC) ORM-E NA2767 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1 DO/45.4) Diuron is a white crystalline solid or the solid dissolved in a liquid carrier. It is used as a herbicide. It is a wettable powder or water emul- sifiabte liquid. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to. or leaking from containers of this ma terial contact the pesticide safety team network. Telephone: 800-424- 9300. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any materia! which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water apill If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical H material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered DODECYL TR1CHLOROSILANE 4934240 CORROSIVE MATERIAL, ACIOIC UN1771 Dodecyl trichlorosilane is a colorless to yellow liquid with a pungent odor. Material will burn though it may take some effort to ignite. It is decomposed by moisture or water to hydrochloric acid with evolution of heat. It is corrosive to metals and tissue. If material on fire or Involved In fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing DIVINYL ETHER 4908165 FLAMMABLE UQUID UN1167 Divinyl ether is a clear colorless liquid. It has a flash point of less than -22 deg. F. it Is lighter than water and insoluble in water. Its vapors are heavier than air. 214 DODECYLBENZENESULFONIC ACID 4931426 CORROSIVE MATERIAL NA2S84 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Dodecylbenzenesulfonic acid is a colorless liquid, it is used to make detergents. It is soluble in water. It is corrosive to metals and tissue. April 1981 W<2> 00 *?U1 If material on fire or Involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the matenal anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates DRUGS OR MEDICINES. N.O.S. 4917376 FLAMMABLE SOUD NA1325 Drugs or medicines, n.o.s. is the proper shipping name of any solid material, other than one classed as an explosive, or specifically listed by name in the list of hazardous materials which is liable under conditions incident to transportation to cause fires through friction, absorption of moisture, spontaneous chemical changes as a result of retained heat from the manufacturing or processing of the solid, or which can be readily ignited by external sparks or flame and when so ignited burns vigorously and persistently. Try to ascertain the exact name of the material. If materiel on fire or involved in fire Extinguish fire using agent suitable for type of fire If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Build dikes to contain flow as necessary Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water DRUGS OR MEDICINES. N.O.S. 4916410 OXIDIZER NA1479 Drugs or medicines, n.o.s. are various materials which have the prop erty of accelerating the burning of combustible material. These materials may not bum by themselves. Prolonged exposure of these materials and/or their containers to fire or heat may result in an explosion. These materials may only be shipped in containers of 55 gallon capacity or less. April 1981 If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equtpment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Approach fire with caution Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet DRUGS OR MEDICINES, N.O.S. (LIQUID) 4921427 POISON B NA2810 Drugs or medicines, n.o.s. (liquid) are liquid or solution of solids ma terials which have the property of being toxic by ingestion, inhalation, or skin absorption. The liquid or solution may or may not burn depending on the nature of the material and/or the solvent of the solution. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered DRUGS OR MEDICINES, N.O.S. (SOUD) 4921496 POISON B NA2811 Drugs or medicines, n.o.s. (solid) are pure materials or mixtures of two or more solids or liquids absorbed on a dry carrier. It has the property of being toxic by ingestion, inhalation (vapor dust, etc) or skin absorption. If material on fire or involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Continued on next page 000017142 MOD 215 Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective eauipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing DRUGS, N.O.S. 4915191 COMBUSTIBLE LIQUID NA1993 Drugs, n.o.s. are those drugs with the property of having a flash point between tOO and 199 deg. F. They are generally lighter than water and soluble in water. Their vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing DRUGS, N.O.S. 4910191 FLAMMABLE LIQUID NA1993 Drugs, n.o.s. are those drugs with the property of having a flash point of less than 100 deg. F. They are generally lighter than water and soluble in water. Their vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material oul of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 216 DRUGS, N.O.S., LIQUID 4936581 CORROSIVE MATERIAL NA1760 Drugs, n.o.s.. liquid is the proper shipping name for various liquids having the property of being corrosive to steel or tissue. It may either be a simple liquid material or a solid material dissolved in a solvent, it may be combustible though requiring some effort to ignite. They may or may not be water soluble. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing DRUGS, N.O.S., SOLID 4936582 CORROSIVE MATERIAL NA1759 Drugs, n.o.s., solid is the proper shipping name for various colored solids having the property of being corrosive to tissue. They may or may not be water soluble. If material on fire or involved In fire Extinguish fire using agenl suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing DRY CLEANER, LIQUID, OR LIQUID CLEANSER 4910146 (COMPOUND, CLEANING, UQUID) FLAMMABLE LIQUID NA1993 Dry cleaner, liquid, or liquid cleanser is a variable colored liquid with a petroleum like odor. II has a flash point of less than 100 deg. F. It is lighter than water and generally insoluble in water, its vapors are heavier than air. April 1981 mconiHZ.,1 II material on fire or involved in fire Da not extinguish fire unless flow can be stooped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water DRY CLEANER, LIQUID, OR LIQUID CLEANSER 4915146 (COMPOUND, CLEANING, LIQUID) COMBUSTIBLE LIQUID NA1993 Dry cleaner, liquid, or liquid cleanser is a variable colored liquid with a petroleum like odor. It has a flash point between 100 and 199 deg. F. It is lighter than water and generally insoluble in water. Its vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "'alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water DYE INTERMEDIATE, LIQUID 4936555 CORROSIVE MATERIAL UN2801 Dye intermediate, liquid is a variable colored material. It may be com bustible though requiring some effort to ignite. It is corrosive to metals and/or tissue, it may or may not be water soluble. If material on fire or Involved in fire Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain (low as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles April 1981 Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the materiat anticipated, wear full protective clothing ELECTRIC SQUIB 4903440 CLASS C EXPLOSIVE Electric squib consists of a small tube or block containing a small amount of an ignition compound in contact with a bridge wire. The device may or may not have long lead wires attached to it. If material on fire or involved in fire Flood with water Apply water from as far a distance as possible H material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feel ELECTRIC WIRE SATURATING OR FINISHING COMPOUND, ASPHALT OR PITCH BASE 4915468 (COMBUSTIBLE LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Electric wire saturating or finishing compound asphalt or pitch base is a material containing a solvent having a closed cup flash point between 100 and 199 deg. F. The hazard of this material is combustibility. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any materiat which may have contacted the body with copious amounts of water or soap and water ELECTRIC WIRE SATURATING OR FINISHING 4910468 COMPOUND, ASPHALT OR PITCH BASE (FLAMMABLE LIQUID, N.O.S.) FLAMMABLE LIQUID UNI 993 Electric wire saturating or finishing compound asphalt or pitch base is a material containing a solvent having a closed cup flash point of less than 100 deg. F. The hazard of this material is flammability. Continued on next page 217 MCD 000017143 If material on fire or involved In fire Do not extinguish tire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ELECTRIC WIRE SATURATING OR FINISHING 4915418 COMPOUND, PARAFFINE BASE (COMBUSTIBLE LIQUID, N.O.S.) COMBUSTIBLE LiQUIO NA1993 Electric wire saturating or finishing compound is a matenai containing a solvent having a closed cup flash point between 100 and 199 deg. F. The hazard is combustibility. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in tlooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ELECTROLYTE (ACID) BATTERY, FLUID 4930216 CORROSIVE MATERIAL. ACIDIC UN2796 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Electrolyte (acid), battery fluid is a sulfuric acid-water solution. It is a clear colorless odorless liquid. It is soluble in water with release of heat. It is corrosive to metals and to tissue. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment ELECTRIC WIRE SATURATING OR FINISHING COMPOUNO, PARAFFINE BASE (FLAMMABLE 4910418 LIQUID, N.O.S.) FLAMMABLE LIQUID UN1993 Electric wire saturating or finish compound is a material containing a solvent having a closed cup flash point of less than 100 deg. F. The hazard is flammability. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical It material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors 218 ELECTROLYTE (ACID) PACKEO WITH BATTERY 4936564 CHARGER, RADIO CURRENT SUPPLY DEVICE OR ELECTRONIC EQUIPMENT AND ACTUATING DEVICE) CORROSIVE MATERIAL, ACIDIC NA2797 Electrolyte (acid) packed with battery charger, radio current supply device or electronic equipment and actuating devices consist of con tainers of electrolyte (acid) packed in the same outside shipping con tainer with battery charger, radio current supply device or electronic equipment and actuating devices. The electrolyte (acid) is soluble in water with evolution of heat. It is corrosive to metals and tissue. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Apply water from as far a distance as possible If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash, or time April 1981 MOD 000017144 Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing ELECTROLYTE (ACID) PACKED WITH DRY STORAGE 4930217 BATTERY CORROSIVE MATERIAL NA2797 Electrolyte (acid) packed with dry storage battery is the dry (empty) storage battery and the electrolyte (acid) in a container packaged to gether in the same outside container. The electrolyte (acid) is a sulfuric acid-water solution. It is a clear colorless liquid. It is soluble in water with release of heat. It is corrosive to metals and tissue. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodify contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing EMBEDDING CEMENT, NEC (CEMENT, LIQUID, N.O.S.) 4910448 FLAMMABLE LIQUID NA1133 Embedding cement nec is a solution of various gums or resins in various solvents. The liquids are generally quite thick and may range from clear colorless to black "tars". The flash point of the cement de pends on the solvents used but it will be less than 100 deg. F. The hazard is flammability. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 EMBEDDING CEMENT, NEC (CEMENT. LIQUID, N.O.S.) 4915448 COMBUSTIBLE LIQUID NA1133 Embedding cement nec is a solution of various gums or resins in various solvents. The liquids are generally quite thick and may range from clear colorless to black "tars." the flash point of the cement depends on the solvents used but it will be between 100 and 199 deg. F. The hazard is combustibility. if material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, names, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ENAMEL (ENAMEL OTHER THAN WATCH DIAL) 4910176 FLAMMABLE LIQUID UN1263 Enamel or watch dial may contain a flammable solvent. Its flash point is 100 deg. F. or lower. The hazard is that of flammablility. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ENAMEL (ENAMEL OTHER THAN WATCH DIAL) 4915176 COMBUSTIBLE LIQUID UN1263 Enamel is a variable colored liquid which may contain a combustible solvent. Its flash point is between 100 and 199 deg. F. The hazard is that of combustibility. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Continued on next page MCD 000017145 219 If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ENAMEL WHITENING COMPOUNDS (COMBUSTIBLE 4915177 QUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Enamel whitening compounds are clear colorless to white liquids. They have a flash point between 100 and 199 deg. F.They are generally lighter than water and insoluble in water. Their vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Sotid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ENDOSULFAN (AGRICULTURAL INSECTICIDES, NEC, 4921516 LIQUID) POISON B NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Endosulfan is a white solid dissolved in a liquid carrier, it is used as a pesticide. It is a water emulsifiable liquid. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical It material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear lull protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill If dissolved, appty activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors ENAMEL WHITENING COMPOUNDS (FLAMMABLE 4910177 LIQUID, N.O.S.) FLAMMABLE LIQUID UN1993 Enamel whitening compounds are clear colorless to white liquids. They have a flash point of less than 100 deg. F. They are generally lighter than water and insoluble in water. Their vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be slopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ali affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical tl material not on lire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 220 ENDOSULFAN (AGRICULTURAL INSECTICIDES, NEC, 4921517 OTHER THAN LIQUID) POISON B NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Endosulfan is a white solid it is used as a pesticide, fungicide, or herbicide. It is a wettabie powder. It is toxic by inhalation, skin containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. H material on fire or Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers April 1981 MCD 00017146 Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, appiy activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ENDOSULFAN (INSECTICIDES. OTHER THAN 4921518 AGRICULTURAL, NEC) POISON B NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-1/0.454) Endosulfan is a white solid or the solid dissolved in a liquid carrier. It is used as a pesticide, fungicide, or herbicide. It is a wettable powder or water emuisifiable liquid. It is toxic by inhalation, skin absorption, and/ or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424- 9300. If material on fire or involved In fire Do not extinguish lire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors April 1981 ENDOSULFAN MIXTURE, LIQUID (AGRICULTURAL 4921519 INSECTICIDES, NEC, LIQUID) POISON B NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Endosulfan mixture, liquid is the white soiid dissolved in a liquid carrier. It is used as a pesticide. It is a water emuisifiable liquid. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors ENDRIN (AGRICULTURAL INSECTICIDES, NEC. 4921521 LIQUID) POISON B NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Endrin is a white solid dissolved in a liquid carrier. It is used as a pesticide. It is a water emuisifiable liquid. It is loxic by inhalation, skin absorption, and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical ff material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Continued on next page 221 00001714-7 MCI) Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid matenal Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of tOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors ENDRIN (AGRICULTURAL INSECTICIDES, NEC. 4921522 OTHER THAN LIQUID) POISON B NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Endrin is a white solid. It is used as a pesticide. It is wettable powder. It is toxic by inhalation, skin absorption, and/or ingestion, in case of damage to. or leaking from containers of this material contact the pes ticide safety team network. Telephone; 800-424-9300. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Peraonnei protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear seif-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates 222 ENDRIN (INSECTICIDES, OTHER THAN 4921523 AGRICULTURAL, NEC) POISON B NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Endrin is a white solid or the solid dissolved in a liquid carrier. It is used as a pesticide. It is a wettable powder or water emuisifiabie liquid. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to, or leaking from containers of this matenal contact the pes ticide safety team network. Telephone: 800-424-9300. It material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the matenal Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors ENDRIN MIXTURE, LIQUID (AGRICULTURAL 4921520 INSECTICIDE, NEC, LIQUID) POISON B NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Endrin mixture, liquid is a white solid dissolved in a liquid carrier. It is used as a pesticide, it is a water emuisifiabie liquid. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. If material on firs or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool alt affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical H material not on firs and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors April 1981 MCD 000017148 Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors ENGINE STARTING FLUID 4905728 FLAMMABLE GAS UN1960 Engine starting fluid is a flammable liquid in a container mixed with a flammable or nonflammable compressed gas as a propellant, it is easily ignited and may only be shipped in cylinders. It is heavier than air and a flame can flash back to the source of leak very easily. Under fire conditions the cylinders may violently rupture and rocket. If the cylinders are aerosols they will violently rupture and rocket under fire conditions. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing vapors Keep upwind Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet EPICHLOROHYDRIN 4907420 FLAMMABLE LIQUID, POISONOUS UN2023 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Epichlorohydrin is a clear, colorless liquid with an irritating chloroform like odor, it is used to make plastics, and as a solvent. It has a flash point of 87 deg. F. if contaminated, the material is subject to polymer ization with evolution of heat. If the polymerization takes place inside a container, the container is subject to rupture. It is irritating to the skin and respiratory system and is toxic by ingestion. It is heavier than water and soluble in water. Its vapors are heavier than air, It weighs 9.8 pounds per gallon. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical April 1981 If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash, cement powder, sawdust, or com mercial sorbents Apply "universal" gelling agent to immobilize spill Apply fluorocarbon-water foam to diminish vapor and fire hazard Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Combustion products include corrosive or toxic vapors Thermal decomposition to phosgene can occur ERADICATOR, PAINT OR GREASE, LIQUID 4910178 FLAMMABLE LIQUID UN1850 Eradicator, paint or grease, liquid is variable colored liquid generally having a petroleum odor. It has a flash point of less than 100 deg. F. It is generally lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fira and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 223 mod ooooi f 149 ETCHING ACID, LIQUIO, N.O.S. 4930005 CORROSIVE MATERIALS, ACIDIC, POISONOUS NA1790 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Etching acid, liquid, n.o.s. is a colorless to pale yellow liquid composed of nitric acid, hydrofluoric acid, water and possibly acetic acid. It is soluble in water with release of heat. It is corrosive to metals and tissue. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment ETHER (DIETHYL ETHER, ANESTHESIA GRADE) 4908157 FLAMMABLE LIQUID UN115i Ethyl ether is a clear colorless liquid with a characteristic anesthetic odor, it is used as an anesthetic, as a solvent, and to make other chem icals. It has a flash point of -49 deg. F. It is lighter than water and insoluble in water, its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of wafer or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered ETHANE 4905731 FLAMMABLE GAS UN1035 Ethane is a colorless odorless gas. It is easily ignited and may only be shipped in cylinders. It is heavier than air but a flame can easily flash back to the source of the leak very easily, it can asphyxiate by the displacement of air. Under fire conditions the cylinders may violently rupture and rocket. It material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water tn flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved In fire Keep sparks, flames, and other sources oi ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach tire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet ETHER (DIETHYL ETHER, OTHER THAN ANESTHESIA 4908156 GRADE) FLAMMABLE LIQUID UN1155 Ether is a clear colorless liquid with a characteristic anesthetic odor. It has a flash point of -49 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matehal which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on tire), downwind evacuation must be considered 224 MCD 000017150 April 1981 ETHION (AGRICULTURAL INSECTICIDES, NEC, 4921565 LIQUID) POISON B NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10/4.54) Ethion is a colorless liquid. It is used as a pesticide. It is awater emulsifiable liquid. It is toxic by inhalation, skin absorption, and-or inges tion. in case of damage to. or leaking from containers of this matenal contact the pesticide safety team network. Telephone; 800-424-9300. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors ETHION (AGRICULTURAL INSECTICIDES, NEC, 4921566 OTHER THAN LIQUID) POISON B NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10/4.54) Ethion is a colorless liquid absorbed on a dry carrier. It is used as a pesticide. It is a wettable powder. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800- 424-9300. If material on fire or Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material April 1981 Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ETHION (INSECTICIDES, OTHER THAN 4921567 AGRICULTURAL, NEC) POISON B NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10/4.54) Ethion is a colorless liquid or the liquid absorbed on a dry carrier. It is used as a pesticide. It is a wettable powder or water emulsifiable liquid. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors 225 MOD 000017151 ETHION MIXTURE, DRY (AGRICULTURAL 4921568 INSECTICIDES, NEC. OTHER THAN DRY LIQUID) POISON B NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10/4.54) Ethion mixture, dry is a colorless liquid absorbed on a dry carrier, it is used as a pesticide. It is a wetabie powder. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical if material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Iflcontact with the material anticipated, wear tulf protective clothing Environmental considerations--land spiii Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount 1 in region of lOppm or greater concentration U|se mechanical dredges or lifts to remove immobilized masses of , pollutants and precipitates ETHYL ACRYLATE, INHIBITED 4907215 FLAMMABLE LIQUID POLYMERIZABLE UN1917 Ethyl acrylate is a clear colorless liquid with an acrid odor. It is used to make paints and plastics. It has a flash point of 60 deg. F. If the material is subjected to heat for prolonged periods or becomes contam inated it is subject to polymerization with evolution of heat. If the poly merization takes place inside a container the container may violently rupture. The material is lighter than water and slightly soluble in water. The vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered ETHYL ACETATE 4909160 FLAMMABLE LIQUID UN1173 Ethyl acetate is a clear colorless liquid with a fruity odor. It has a flash point of 24 deg. F. it is lighter than water and slightly soluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical if material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any materia! which may have contacted the body with copious amounts of water or soap and water 226 ETHYL ALCOHOL (COLOGNE SPIRITS) 4909159 FLAMMABLE LIQUID NA1170 Ethyl alcohol is a clear colorless liquid with a characteristic odor. It has a flash point of 62 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 MCI) 000017152 ETHYL ALCOHOL, ANHYDROUS, DENATURED IN 4909110 PART WITH GASOLINE, GASOLINE CONTENT NOT TO EXCEED 5 PERCENT (ALCOHOL, N.O.S.) FLAMMBLE LIQUID UN1987 Ethyl alcohol, anhydrous, denatured in part with gasoline is a colorless liquid with a characteristic alcohol odor. It is used for blending with gasoline to make gasohoi. It has a flash point of 58-60 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use `'alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ETHYL ALDEHYDE (See ACETALDEHYDE 4907210) ETHYL BENZENE 4909163 FLAMMABLE LIQUID UN1175 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Ethyl benzene is a clear colorless liquid with an aromatic odor. It is used as a solvent and to make other chemicals. It has a flash point of 59 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. It weighs 7.2 pounds per gallon. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash, cement powder, sawdust, or com mercial sorbents April 1981 Apply "universal" gelling agent to immobilize spill Apply fluorocarbon-water foam to diminish vapor and fire hazard Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e.g. detergent, soaps, alcohols) to com press and thicken spilled material Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms If dissolved, apply activated carbon at ten times tne spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors ETHYL BORATE 4909161 FLAMMABLE LIQUID UN1176 Ethyl borate is a clear colorless liquid. It has a flash point of 52 deg. F. It is lighter than water and is decomposed by water giving ethyl alcohol, another flammable liquid. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ETHYL BUTYL ACETATE 4913113 COMBUSTIBLE LIQUID UN1177 Ethyl butyl acetate is a clear colorless liquid. It has a flash point of 130 deg. F. It is heavier than water and insoluble in water, its vapors are heavier than air. H material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 227 MOD 000017153 ETHYL BUTYL ETHER 4909164 FLAMMABLE LIQUID UN1179 Ethyl butyl ether is a clear, colorless liquid with an ethereal odor. It has a flash point of 40 deg. F. It is lighter than water and is slightly soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ETHYL BUTYRALDEHYDE 4909168 FLAMMABLE LIQUID UN1178 Ethyl butyraldehyde is a clear, colorless liquid. It has a flash point of 70 deg. F. It is lighter than water and is insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish tire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-oown vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ETHYL BUTYRATE 4909132 FLAMMABLE LIQUID UN11B0 Ethyl butyrate is a clear colorless liquid with a pineapple-like odor. It has a flash point of 78 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical 228 If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ETHYL CHLOROACETATE 4913114 COMBUSTIBLE LIQUID UN1181 Ethyl chloroacetate is a clear colorless liquid with a pungent odor, it has a flash point of 100 deg. F. It is heavier than water and insoluble in water. Its vapors are heavier than air. If material on fire or invoived in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material ETHYL CHLOROFORMATE 4907617 FLAMMABLE LIQUID, CORROSIVE UN1162 Ethyl chloroformate is a colorless liquid with a pungent odor, it has a flash point of 66 deg. F. Its vapor is irritating to the eyes and mucous membranes. It is corrosive to metais and tissue. It is decomposed by water to give hydrochloric acid.a corrosive material.with evolution of heat. Its vapors are heavier than air. If material on fire or invoived In fire Do not extinguish fire unless flow can be stopped Use "alcohol" foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 MCD 000017154 Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered ETHYL CHLOROTHIOFORMATE 4933327 CORROSIVE MATERIAL UN2B26 Ethyl chlorothioformate is an amber colored liquid with a pungent penetrating odor. It is combustible and has a flash point of 125 deg. F. The vapors are irritating to the eyes and respiratory system. It is corrosive to metals and tissue. It is heavier than water and reacts with water forming hydrochloric acid, another corrosive material, with evolution of heat. Its vapors are heavier than air. If material on fire or involved In fire Use "alcohol" foam, carbon dioxide or dry chemical Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ETHYL CROTONATE 4909162 FLAMMABLE LIQUID UN1862 Ethyl crotonate is a clear colorless liquid with a pungent odor. It has a flash point of 36 deg. F. It is lighter than water and is insoluble in water. Its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1961 ETHYL DICHLOROSILANE 4907615 FLAMMABLE LIQUID, CORROSIVE, ACIDIC UN1163 Ethyldichlorosilane is a colorless fuming liquid with a pungent odor. It has a flash point of 30 deg. F. Vapor and liquid can cause burns. It is heavier than water and is decomposed by water to form hydrochloric acid, a corrosive material. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use "alcohol" foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks, flames, and other sources of Ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective ciothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered ETHYL FORMATE 4908167 FLAMMABLE LIQUID UN1190 Ethyl formate is a clear colorless liquid with a pleasant odor. It has a flash point of -4 deg. F. It is lighter than water and soluble in water. It is slowly decomposed by water to formic acid, a corrosive material and ethyl alcohol, another flammable liquid. Its vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use "alcohol" foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Do not use water on material itself If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Do not use water on material itself Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Continued on next page ,0OO\T^b MCE 0 229 Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must t>e considered ETHYL HEXALDEHYDE 4913164 COMBUSTIBLE LIQUID UN1191 Ethyl hexaldehyde is a clear colorless liquid with a mild odor. It has a flash point of 125 deg. F. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. if material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered ETHYL LACTATE 4913165 COMBUSTIBLE LIQUID UN1192 Ethyl lactate is a clear colorless liquid with a mild odor. It has a flash point of 115 deg. F. It is heavier than water and soluble In water. Its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep spades, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ETHYL MERCAPTAN 4908169 FLAMMABLE LIQUID UN2363 Ethyl mercaptan is a clear colorless liquid with an overpowering garlic like odor. It has a flash point of -55 deg. F. and a boiling point of 97 deg. F. It is lighter than water and very slightly soluble in water. Its vapors are heavier than air. 230 ETHYL METHYL ETHER 4908171 FLAMMABLE LIQUiO UNI 039 Ethyl methyl ether is a clear colorless liquid with a medicinal like odor. It has a flash point of -35 deg. F. and a boiling point of 52 deg. F. Upon prolonged standing, or exposure to sunlight or oxygen; peroxides may form which may explode spontaneously or when heated. It is lighter than water and soluble in water, Its vapors are heavier than air. tf material on fire or involved in fire Do not extinguish lire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered April 1961 MCI) 000037156 ETHYL NITRATE 4907010 FLAMMABLE LIQUID NA1993 THERMALLY UNSTABLE Ethyl nitrate is a clear, colorless liquid with a pleasant odor. It has flash point of 50 deg. F. Prolonged exposure of the material to heat may result in the spontaneous decomposition ot the material and this de composition may reach explosive violence. Prolonged exposure of the containers of the material to fire or heat may result in the violent rupturing of the containers due to the decomposition of the material. It is heavier than water and insoluble in water. Its vapors are heavier than air, Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered ETHYL NITRITE 4907020 FLAMMABLE LIQUID UN1194 THERMALLY UNSTABLE Ethyl nitrite is a clear colorless to yellow liquid- It has a flash point of- 31 deg. f, and a boiling point of 63. deg. F. It is flammable over a wide range of vapor-air concentrations. The vapors may ignite spontaneously at 194 deg. f, and its decomposition may reach explosive violence. It is decomposed by heat and light. Prolonged exposure to heat or fire by the containers of the material may result in their violently rupturing due to the decomposition of the material. It is lighter than water and insoluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material, tf material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material April 1981 Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered ETHYL PHENYL DICHLOROSILANE 4934245 CORROSIVE MATERIAL, ACIDIC UN2435 Ethyl phenyl dichforosilane is a colorless liquid with a pungent odor. It is decomposed by water to hydrochloric acid with evolution of heat. It is corrosive to metals and tissue. If material on fire or Involved in fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water In flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on tire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Buiid dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing ETHYL PHOSPHONOTHIOIC DICHLORIDE, 4933355 ANHYDROUS CORROSIVE MATERIAL NA1760 Ethyl phosphonothioic dichloride, anhydrous is a clear colorless liquid with a pungent odor. It will bum though it may require some effort to ignite. It is heavier than water and reacts with water forming hydrochloric acid, a corrosive material, with release of heat. It is corrosive to metals and tissue. If material on fire or Involved in fire Use "alcohol" foam, carbon dioxide or dry chemical Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes lo contain flow as necessary Attempt to stop leak If without hazard Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime Continued on next page 231 MCtj Orv'>01 '15? Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ETHYL PHOSPHONOUS DICHLORIDE, ANHYDROUS 4933332 CORROSIVE MATERIAL, ACIDIC NA2845 PYROFORIC Ethyl phosphonous dichloride, anhydrous is a colorless liquid with a pungent odor. It is pyroforic and will spontaneously ignite on contact with moist air or water. It is heavier than water and besides igniting on contact with water hydrochloric acid, a corrosive material, is produced. It is corrosive to metals and tissue. If material on fire or involved in fire Use "alcohol'1 foam, carbon dioxide or dry chemical Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Appiy water from as far a distance as possible if material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ETHYL PHOSPHORODICHLORIDATE 4933333 CORROSIVE MATERIAL, ACIDIC NA1760 Ehtyl phosphorodichloridate is a clear colorless liquid with a pungent odor. It reacts with water giving hydrochloric and phosphoric acids, which are also corrosive materials. It is corrosive to metals and tissue. If material on fire or involved in fire Use "alcohol" foam, carbon dioxide or dry chemical Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ETHYL PROPIONATE 4909170 FLAMMABLE LIQUID UN1195 Ethyl propionate is a clear colorless liquid with a pineapple like odor. It has a flash point of 54 deg. F. It is lighter than water and is insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak it without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ETHYL SILICATE 4913166 COMBUSTIBLE LIQUID UN1292 Ethyl silicate is a clear colorless liquid with a faint odor. It has a flash point of 125 deg. F. It is lighter than water and reacts with water forming a silicone adhesive, a milky white mass. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'1 foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ETHYL-N-BUTYLAMINE (FLAMMABLE LIQUIO, N.O.S.) 4909173 FLAMMABLE LIQUID UN1993 Ethyl-n-butylamine is a clear colorless liquid with a fish like odor. It has a flash point of 65 deg. F. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material. 232 April 1961 MCIi n'-'000l7i58 If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing ETHYL-N-CYCLOHEXYLAMINE (FLAMMABLE LIQUID, 4909165 N.O.S.) FLAMMABLE LIQUIO UN1993 Ethyl-n-cyclohexylamine is a clear colorless liquid with an ammonia like odor. It has a flash point of 66 deg. F. It is lighter than water and is slightly soluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Appty water from as far a distance as possible Use `'alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing April 1981 ETHYL-3-3,DI-(TERT-BUTYLPEROXY)BUTYRATE. 4919275 (TECHNICALLY PURE) ORGANIC PEROXIOE UN2184 Ethyl-3-3,di-(tert-butylperoxy)butyrate, (technically pure) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber, it is insoluble in water. The liquid or solution may require some effort to ignite; but once ignited, it will burn with increasing rapidity as the fire progresses, if spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burn ing of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire end not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material v.+iich may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet ETHYL-3,3-DMTERT-BUTYLPEROXY)BUTYRATE, 4919273 (NOT MORE THAN 50% WITH INERT INORGANIC SOLID) ORGANIC PEROXIDE UN2598 Ethyl-3,3-di-(tert-butylperoxy)butyrate. (not more than 50% with inert inorganic solid) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water, it is easily ignited and burns with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combustible materials. It supports the burning of com bustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as tar a distance as possible Use "ataohoT foam, carbon dioxide or dry chemical Dangerously explosive H material not on fira and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Continued on next page 233 MCB 000017159 Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear sell-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation if the material is on fire or involved in fire evacuate for a radius of 2500 feet ETHYL-3,3-DI-(TERT-BUTYLPEROXY)BUTYRATE, 4919274 (NOT MORE THAN 77% IN SOLUTION) ORGANIC PEROXIDE UN2185 Ethyl-3,3-di-(tert-butytperoxy)butyrate, (not more than 77% in solution) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite; but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spon taneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or Involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet ETHYLCHLORIDE 4908162 FLAMMABLE LIQUID UN1037 Ethyl chloride is a clear colorless liquid with a pungent odor, it has a flash point of -58 deg. F. and a boiling point of 54 deg. F. It is lighter than water and insoluble in water, its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless (low can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical 234 'VcD %'OnU j6q If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on tire), downwind evacuation must be considered ETHYLENE 4905734 FLAMMABLE GAS UN1962 Ethylene is a colorless gas with a sweet odor and taste. It is easily ignited. The gas is lighter than air Out a flame can flash back to the source of the leak very easily. Under fire conditions cylinder of the gas may violently rupture and rocket. It material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered ETHYLENE CHLOROHYDRIN 4921420 POISON B, COMBUSTIBLE UN1135 Ethylene chlorohydrin is a colorless liquid with an ether-like odor. It is soluble in water and is also a combustible liquid. Its vapors are heavier than air and it is toxic by inhalation and skin absorption, if material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool alt affected containers with flooding quantities of water Apply water from as far a distance as possible Use 'alcohol'' foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid April 1981 Personnel protection Avoid breathing vapors Keep upwind Wear sell-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered ETHYLENE DIBROMiDE (OR) 1,2-DIBROMOETHANE 4940335 ORM-A UNI 605 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Ethylene dibromide is a clear colorless liquid with a sweetish odor. It Is used as a solvent, as a grain fumigant, in the manufacture of other chemicals, and for many other uses. It is heavier than water and slightly soluble in water. It is non-combustible. It can cause illness by inhalation, skin absorption and/or ingestion. It weighs 18.1 pounds per gallon. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Apply "universal" gelling agent to immobilize spill Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ETHYLENE DICHLORIDE 4909166 FLAMMABLE LIQUID UN1164 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Ethylene dichioride is a dear colorless liquid with a chloroform-like odor, it has a flash point of 56 deg. F. It is heavier than water and insoluble in water. Its vapors are heavier than air. It weighs 10.4 pounds per gallon. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical April 1981 If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash, cement powder, sawdust, or com mercial sorbents Apply "universal" gelling agent to immobilize spill Apply fluorocarbon-water foam to diminish vapor and fire hazard Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Thermal decomposition to phosgene can occur ETHYLENE GLYCOL DIETHYL ETHER 4913115 COMBUSTIBLE LIQUID UN1153 Ethylene glycol diethyl ether is a clear colorless liquid with a faint ether-like odor. It has a flash point of 100 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ETHYLENE GLYCOL MONOETHYL ETHER 4913116 COMBUSTIBLE LIQUID UN1171 Ethylene glycol monoethyl ether is a clear colorless liquid. It has a flash point of 120 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. Continued on next page MCD 000017161 235 ff material on fire or involved in fire Do not extinguish fire unless fiow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ETHYLENE GLYCOL MONOETHYL ETHER ACETATE 4913117 COMBUSTIBLE LIQUID UN1172 Ethylene glycol monoethyl ether acetate is a clear colorless liquid with a pleasant odor. It has a flash point of 120 deg. F. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ETHYLENE GLYCOL MONOMETHYL ETHER 4913162 COMBUSTIBLE LIQUID UN11B8 Ethylene glycol monomethyl ether is a clear colorless liquid with a pleasant odor. It has a flash point of 110 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid 236 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ETHYLENE GLYCOL MONOMETHYL ETHER ACETATE 4913163 COMBUSTIBLE LIQUID UN1189 Ethylene glycol monomethyi ether acetate is a clear colorless liquid with a pleasant odor. It has a flash point of 135 deg. F. It is heavier than water and soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ETHYLENE IMINE, INHIBITED 4906220 FLAMMABLE LIQUID. POISONOUS UN1185 THERMALLY UNSTABLE Ethylene imine is a clear, colorless liquid with an ammonia-like odor. It has a flash point of 12 deg. F. It is flammable over a wide range of vapor-air concentrations. The vapors are initially irritating to the skin, eyes. nose, and throat. Prolonged exposure may result in death due to inhalation, skin absorption, or ingestion. It is lighter than water and soluble in water. The vapors are heavier than air. Prolonged exposure of containers of the material to fire or heat may result in its polymerization and a violent rupturing of the container. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid April 1981 ooooi7162 Her Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Adjust ph to neutral (ph-7) Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CUPRIC TARTRATE 4962614 ORM-E NA9111 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Cupric tartrate is a green to blue powder. It is used for electroplating metals. It is insoluble in water. It is non-combustible. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of waler sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates CUPRIETHYLENE-DIAMINE SOLUTION 4935630 CORROSIVE MATERIAL BASIC UN1761 Cupriethylene-diamine solution is a purple colored liquid with an am monia like odor, it is soluble in water, it is corrosive to metals and tissue. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary April 1981 Personnel protection Avoid breatning vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing CUTCH, CATECHU, OR JAPONICA EXTRACTS, 4915432 LIQUID (COMBUSTIBLE LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Cutch, catechu, or japonica extracts, liquid are materials containing a solvent having a dosed cup flash point between 100 and 199 deg. F. The hazard of these materials is combustibility If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water CUTCH, CATECHU. OR JAPONICA EXTRACTS, 4910432 LIQUID (FLAMMABLE LIQUID, N.O.S.) FLAMMABLE LIQUID UN1993 Cutch. catechu, or japonica extracts, liquid are materials containing a solvent having a closed cup flash point of less than 100 deg. F. The hazard of these materials is flammability. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water MCD 000017163 157 tf material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with sodium bisulfate (nahso4) Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e.g. detergent, soaps, alcohols) to com press and thicken spilled material Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms Add sodium bisulfate If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment ETHYLENEDIAMINETETRAACETIC ACID (OR) EDTA 4966910 ORM-E NA9117 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000'2270) Ethylenediaminetetraacetic acid is colorless crystalline solid. It is used m chemical analysis, to make detergents and cleaning compounds, and for many other uses, it is slightly soluble in water, It is non-combustible. tf material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land apUl Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Add caustic soda Adjust ph to neutral (ph-7) Use mechanical dredges or lifts lo remove immobilized masses of pollutants and precipitates 238 ETHYLHEXYLACRYLATE (COMBUSTIBLE LIQUID, 4912220 N.O.S.) COMBUSTIBLE LIQUID NA1993 Ethylhexylacrylate is a clear colorless liquid with a pleasant odor. It is used in making of paints and plastics. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet ETHYLTRICHLOROSILANE 4907620 FLAMMABLE LIQUID. CORROSIVE ACIDIC UN1196 Ethyltrichlorositane is a colorless fuming liquid with a pungent odor. It has a flash point of 57 deg. F. Vapor and liquid can cause burns. It is heavier than water and is decomposed by water to form hydrochloric acid, a corrosive material. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use "alcohol" foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Do not .use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered April 1981 OOO01 ETIOLOGIC AGENT, N.O.S. (OR) INFECTIOUS 4S25999 SUBSTANCE. HUMAN, N.O.S. ETIOLOGIC AGENT NA2614 Etiologic agent or infectious substance, human is a viable microo- ganism or its toxin which causes or may cause human disease. In case of damage to. or leaking of the package contact- Director, center for disease control Atlanta, georgia its toxin which causes or may cause human disease. In case of damage to, or leaking of the package contact- corrosive material. Its vapors are heavier than air. EXPLOSIVE AUTO ALARM 4903420 CLASS C EXPLOSIVE Explosive auto alarm is a tubular device containing a smalt amount of explosive composition and igniting compound which is ignited by an electric spark. If material on fire or involved In fire Dangerously explosive Flood with water Apply water from as far a distance as possible If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation <f tire becomes uncontrollable--evacuate for a radius of 1500 feet EXPLOSIVE BOMB 4901230 CLASS A EXPLOSIVE Explosive bomb is a metal or other type of container filled with a high explosive. It may be shipped either fuzed or unfuzed. The fuzed bomb may be sensitive to shock or mechanical impact. Under prolonged ex posure to heat or fire it can explode. If material on fire or involved In fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet EXPLOSIVE CABLE CUTTER 4903310 CLASS C EXPLOSIVE Explosive cable cutter is a device containing an explosive charge used to propel a knife-edged component into an anvil. If material on fire or involved in fire Flood with water Apply water from as far a distance as possible If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away April 19B1. Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet EXPLOSIVE MINE 4901235 CLASS A EXPLOSIVE Explosive mine is a metal or composition container filled with a high explosive. It may be shipped either fuzed or unfuzed. The fuzed mine may be sensitive to shock or mechanical impact. Under prolonged ex posure to heat or fire it can explode. If material on fire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet EXPLOSIVE POWER DEVICE, CLASS B 4902570 CLASS B EXPLOSIVE Explosive power device, class b is a device designed to drive a gen erator or mechanical apparatus by means of a propellant explosive, class b. The device has a housing containing the propellant explosive and an electric igniter or squib. The explosive power device class b differs from an explosive power device, class c by the amount of the propellant explosive. If material on fire or Involved In fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet EXPLOSIVE POWER DEVICE, CLASS C 4903480 CLASS C EXPLOSIVES Explosive power device, class c is a device designed to drive a gen erator or mechanical apparatus by means of a propellant explosive class b, The device has a housing containing the propellant explosive and an electric igniter or squib. The explosive power device, class c differs from an explosive power device, class b by the amount of propellant explosive or the power of the propellant explosive. If material on fire or Involved In fire Flood with water Apply water from as far a distance as possible Continued on next page 239 OnOOl 7 -r 65 If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet EXPLOSIVE PROJECTILE 4901240 CLASS A EXPLOSIVE Explosive projectile is a shell, projectile, warhead, or rocket head loaded with explosives or bursting charges with or without other mate rials. It may be shipped either fu2ed or unfuzed. The fuzed projectile may be sensitive to shock or mechanical impact. Under prolonged ex posure to heat or fire it can explode. If material on fire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation if the material is on fire or involved in fire evacuate for a radius of 5000 feet EXPLOSIVE RELEASE DEVICE 4903315 CLASS C EXPLOSIVE Explosive release device consists of a rod or link fitted with a means for mechanical attachment to other apparatus or equipment and con taining a small electrically initiated explosive charge which will break the rod or link upon functioning. If material on fire or involved in fire Flood with water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames; and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet EXPLOSIVE RIVET 4903425 CLASS C EXPLOSIVE Explosive rivet is an ordinary rivet having a cavity in the end opposite to the rivet head. The cavity is filled with an explosive composition. It functions on application of heat or impact by expanding, If material on fire or Involved in fire Dangerously explosive Flood with water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away 240 EXPLOSIVE TORPEDO 4901245 CLASS A EXPLOSIVE Explosive topedo is a metal device containing a propulsion device and a quantity of high explosives. It may be shipped either fuzed or unfuzed. It may be sensitive to shock or mechanical impact. Under prolonged exposure to heat or fire it can explode. If material on fire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet EXTRACT, LIQUID, FLAVORING 4910181 FLAMMABLE LIQUID UN1197 Extract, liquid, flavoring is generally an alcoholic extract of various vegetable products used for flavoring food. It has a flash point ol less than 100 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless How can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggies Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water EXTRACTS, CHESTNUT OR QUEBRACHO, LIQUID 4915430 (COMBUSTIBLE LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Extracts, chestnut or quebracho, liquid are materials containing a solvent having a closed cup flash point between 100 and 199 deg. F. The hazard is combustibility. April 1981 MCI 0Q0 I 3- 6Q If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water EXTRACTS, CHESTNUT OR QUEBRACHO, LIQUID 4910430 (FLAMMABLE LIQUIDS, N.O.S.) FLAMMABLE LIQUID UN1993 Extracts, chestnut or quebracho, liquid are materials containing a solvent having a closed cup flash point of less than 100 deg, F. The hazard is flammability. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, llames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water EXTRACTS. FUSTIC OR LOGWOOD, LIQUID OR 4915434 PASTE (COMBUSTIBLE LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Extracts, fustic or logwood liquid or paste are materials containing a solvent having a closed cup flash point between 100 and 199 deg. F. The hazard of these materials is combustibility. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in Hooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical tf material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors April 1981 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water EXTRACTS, FUSTIC OR LOGWOOD, LIQUID OR 4910434 PASTE (FLAMMABLE LIQUID, N.O.S.) FLAMMABLE LIQUID UN1993 Extracts, fustic or log wood liquid or paste are materials containing a solvent having a closed cup Hash point of less than 100 deg. F. The hazard of these materials is flammability. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, llames. and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water EXTRACTS, HYPERNfC LIQUID OR PASTE 491543B (COMBUSTIBLE LIQUID, N.O.S.) COMBUSTIBLE UOUID NA1993 Extracts, hypemic. liquid or paste are materials containing a solvent having a closed cup flash point between 100 and 199 deg. F.The hazard of these materials is combustibility. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as log Solid streams of water may be ineffective Cool all affected containers with Hooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical tf material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water MOD 000017167 241 EXTRACTS, HYPERNIC LIQUID OR PASTE 4910438 (FLAMMABLE LIQUID, N.O.S.) FLAMMABLE LIQUID UN1993 Extracts, hypernic. liquid or paste are materials containing a solvent having a closed cup Hash point of less than 100 deg. F, The hazard of these materials is flammability. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep material out of water sources and sewers Keep sparks, flames, and other sources of ignition away Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water EXTRACTS, TANNING, NEC LIQUID OR PASTE 4915440 (COMBUSTIBLE LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Extracts, tanning, nec liquid or paste are materials containing a solvent having a closed cup flash point between 100 and 199 deg. F. The hazard ot these materials is combustibility. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water EXTRACTS, TANNING, NEC LIQUID OR 4910440 PASTE(FLAMMABLE LIQUID, N.O.S.) FLAMMABLE LIQUID UN1993 Extracts, tanning, nec liquid or paste are materials containing a solvent having a closed cup flash point of less than 100 deg. F. The hazard of these materials is flammability. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical 242 >! material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water FATTY ALCOHOLS, ALIPHATIC OR CYCLIC, 4935223 CYANOETHYLATED AND HYDROGENATED, AND DERIVATIVES THEREOF SUCH AS SALTS DIAMINES, OXYALKYLATES AND QUANTERNARY AMMONIUM COMPOUNDS (ALKALINE CORROSIVE LIQUID, N.O.S.) CORROSIVE MATERIAL, BASIC NA1719 Fatty alcohols, aliphatic or cyclic, cyanoethylated or hydrogenated and derivatives thereof such as salts, diamines, oxyalkylates and quaternary ammonium compounds are colorless to milky or amber colored liquid. They will burn though they may require some effort to ignite. They are lighter than water and may or may not be soluble in water. They are corrosive to metals and/or tissue. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical tf material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing FATTY ALCOHOLS, ANIMAL FAT OR ANIMAL. FISH, 4915546 PETROLEUM, SEA-ANIMAL OR VEGETABLE OILS, NEC, WHEN BLENDED WITH EACH OTHER, LIQUID (ALCOHOL, N.O.S.) COMBUSTIBLE LIQUID UNI 987 Fatty alcohols are clear colorless to light colored liquids. They have a flash point between 100 and 200 deg. F. They are lighter than water and insoluble in water. Their vapors are heavier than air, If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors April 1981 MOD 000017168 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water FEEDING TANKAGE, NEC (FLAMMABLE SOLID, 4917412 N.O.S.) FLAMMABLE SOUD NA1325 Feeding tankage, nec is various scrap food products. If it has not been properly cooled or is too dry it is liable to spontaneous heating and ignition. If material on fire or involved In fire Flood with water If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away FELT, WASTE, WET (See WASTE WOOL, WET 4917372) FERRIC AMMONIUM CITRATE 4963349 ORM-E NA9118 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Ferric ammonium citrate is a yellowish brown to red solid with a faint odor of ammonia. It is used in medicine, In making blueprints, and as a feed additive. It is soluble in water. It is non-combustible. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates FERRIC AMMONIUM OXALATE 4963352 ORM-E NA9119 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Ferric ammonium oxalate is a green crystalline solid. It is used In making blueprints. It is soluble in water. It is non-combustible. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary April 1981 Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates FERRIC ARSENATE, SOUD 4923231 POISON B UNI 606 Ferric arsenate, solid is a green or brown powder. It is insoluble in water. It is toxic by ingestion. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing FERRIC ARSENITE, SOLID 4923232 POISON B UNI 607 Ferric arsenite is a yellow-brown powder. It is insoluble in water. It is toxic by ingestion. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as tog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing 243 MCI) 000017169 FERRIC CHLORIDE SOLID ORM-B 4944138 UNI 773 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Ferric chloride is an orange to brown black solid. It is used to treat sewage, industrial waste, to purity water, as an etching agent for en graving circuit boards, and in the manufacture of other chemicals. It is soluble in water. It is non-combustible. It is corrosive to aluminum. K material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Peraonnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates FERRIC CHLORIDE SOLUTION (IRON CHLORIDE 4932343 (IRON MURIATE). OTHER THAN CRUDE, LIQUID) CORROSIVE MATERIAL UN2582 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Ferric chloride solution is the water solution of the yellow orange crystalline solid having a faint hydrochloric acid odor, it is corrosive to metals and tissue. It weighs 12.6 pounds per gallon. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Oike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fty ash, cement powder, sawdust, or com mercial sorbents Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate 244 Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Adjust ph to neutral (ph-7) Environmental considerations--air spill Apply water spray or mist to knock down vapors FERRIC CHLORIDE SOLUTION (IRON CHLORIDE, 4932342 CRUDE, LIQUID NOT LESS THAN 50% WATER) CORROSIVE MATERIAL UN2582 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Ferric chloride solution is the water solution of the yellow orange crystalline solid having a faint hydrochloric acid odor. It is corrosive to metals and tissue. It weighs 12.6 pounds per gallon. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb butk liquid with fly ash, cement powder, sawdust, or com mercial sorbents Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Adjust ph to neutral (ph-7) Environmental considerations--air spill Apply water spray or mist to knock down vapors FERRIC FLUORIDE 4962626 ORM-E NA9120 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Ferric fluoride is a green crystalline solid. It is used in ceramics. It is soluble in water. It is non-combustible. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water April 19B1 00x7 ?0 Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid orsolid material Cover solids with a plastic sheet to prevent dissolving in rain or lire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Add soda ash Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates FERRIC NITRATE 4918725 OXIDIZER UN1466 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Ferric nitrate is a violet crystalline solid. It is used for dyeing and tanning, in chemical analysis, and in medicine. It is soluble in water. It is non-combustible but it will accelerate the burning of combustible ma terials. if large quantities are involved in the fire or the combustible material is finely divided an explosion may result. Prolonged exposure of the material to fire or heat may result in an explosion. Toxic oxides of nitrogen are produced in fires involving this material. If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible ff material not on lire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet Environmental considerations--land spill Dig apit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pottutants and precipitates FERRIC SULPHATE SOLUTION (FERRIC SULFATE) 4963827 ORM-E NA9121 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Ferric sulphate solution is the yellow crystalline solid dissolved in water. It is used in water purification, as a disenfectant, in textile proc essing, and for many other uses. It is non-combustibie. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash. cement powder, sawdust, or com mercial sorbents Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates FERROUS AMMONIUM SULFATE 4963354 ORM-E NA9122 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Ferrous ammonium sulfate is a light green crystalline solid. It is used in medicine, in chemical analysis, and in metallurgy. It is soluble in water. It is non-combustible. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in ram or tire fighting water Environmental considerations--water spill Allow to aerate Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates FERROUS AMMONIUM SULPHATE, FERTILIZER 4963357 GRADE (IRON AMMONIUM SULPHATE) (FERROUS AMONIUM SULFATE) ORM-E NA9122 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Ferrous ammonium sulphate, fertilizer grade is a light green crystalline solid. It is used as an ingredient to mixed fertilizers or as a soil additive by itself. It is soluble in water. It is non-combustible. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Continued on next page 245 00001^171 HOD Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in ram or fire fighting water Environmental considerations--water spill Allow to aerate Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Adjust pt] to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates FERROUS ARSENATE, SOLID 4923233 POISON B UN1608 Ferrous arsenate, solid is a green powder. It is insoluble in water. It is toxic by ingestion. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when lighting fires involv ing this material If contact with the material anticipated, wear full protective clothing FERROUS CHLORIDE, SOLID 4941131 ORM-A NA1759 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Ferrous chloride is a greenish white crystalline solid. It is used in sewage treatment, in dyeing of fabrics, and for many other uses. It is soluble in water. It is non-combustible. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Adjust ph to neutral (ph-7) Allow to aerate Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates 246 FERROUS CHLORIDE, SOLUTION 4932329 CORROSIVE MATERIAL NA1760 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Ferrous chloride, solution is the greenish-white crystalline solid dis solved in water. It is used in dyeing, in medicine, and sewage treatment. It is corrosive to metals and tissue. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash. cement powder, sawdust, or com mercial sorbents Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Adjust ph to neutral (ph-7) Environmental considerations--air spill Apply water spray or mist to knock down vapors FERROUS SULFATE 4963832 ORM-E NA9125 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Ferrous sulfate is a greenish to yellow brown crystalline solid. It is used used to make other iron compounds, in water and sewage treat ment, as a fertilizer, feed additive, and for many other uses, tt is slightly soluble in water. It is non-combustible. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) tf material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water April 1981 MOD 000017172 Environmental considerations--water spill Adjust ph to neutral (ph-7) Allow to aerate Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates FERROUS SULPHATE, LESS THAN 40% WATER 4963836 (FERROUS SULFATE) ORM-E NA9125 ENVIRONMENTALLY HAZAROOUS SUBSTANCE (RQ-1000/454) Ferrous sulphate, less than 40% water is a greenish to yellowish brown crystalline solid. It is used for sewage and water treatment, as a fertilizer, feed additive, and for many other uses. It is slightly soluble in water. It is non-combustible. It weighs 15.0 pounds per gallon. II material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Oig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash, cement powder, sawdust, or com mercial sorbents Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Adjust ph to neutral (ph-7) Allow to aerate Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates FERROUS SULPHATE, NOT LESS THAN 40% WATER 4963641 (FERROUS SULFATE) ORM-E NA9125 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Ferrous sulphate, not less than 40% water is either a greenish to yellow brown crystalline or a dark green to brown liquid. It is used for water or sewage treatment, as a fertilizer ingredient, and for other uses. It is non-combustible. It weighs 15.0 pounds per gallon. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash. cement powder, sawdust, or com mercial sorbents Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Adjust ph to neutral (ph-7) Allow to aerate Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates FERTILIZER AMMONIATING SOLUTION (CONTAINING 4904250 FREE AMMONIA) NONFLAMMABLE GAS, CORROSIVE UN1043 Fertilizer ammoniating solution is the solution of ammonium com pounds charged with ammonia gas and having a absolute pressure exceeding 40 psi at 70 deg. F. in the container. It has the characteristic odor of ammonia. The solution may be corrosive. Although ammonia is lighter than air, the vapors initially tend to hug the ground. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use water spray to absorb vapors If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and gas tight goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap ana water If contact with the material anticipated, wear full protective clothing Evacuation If material leaking (not on fire), downwind evacuation must be considered FERTILIZER SOLUTION, CONSISTING OF WATER, 493S272 FREE AMMONIA AND SULPHUR, TOTAL AMMONIA CONTENT NOT TO EXCEED 30 PERCENT BY WEIGHT (CORROSIVE LIQUID, N.O.S.) CORROSIVE MATERIAL UN1760 Fertilizer solution, consisting of water, free ammonia and sulphur, total ammonia content not to exceed 30 percent by weight is a colorless to yellow colored liquid having the odor characteristic of ammonia. It is corrosive to metals and tissue, its vapors are heavier than air. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as tog Apply water from as far a distance as possible Use water spray to absorb vapors Continued on next pago MOD 000017173 247 If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing FILM (NITROCELLULOSE) (CELLULOSE FILM SCRAP 4917383 OR WASTE) FLAMMABLE SOUD NA1324 Film (nitrocellulose) is a photographic film made from nitrocellulose. It is easily ignited and burns with great rapidity. Older film may deteriorate and be liable to spontaneous heating and ignition. Toxic oxides of ni trogen are produced during combustion. If material on fire or involved in fire Flood with water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Wear self-contained breathing apparatus when fighting fires involv ing this material Approach fire with caution FERTILIZING COMPOUNDS. NEC DRY (OXIDIZING 4918920 MATERIAL. N.O.S.) OXIDIZER UN1479 Fertilizing compounds, nee, dry are various materials which have the property ot accelerating the burning of combustible material. These materials may not bum by themselves. Prolonged exposure to fire or heat by these materials and/or their containers may result in an explo sion. These materials may only be packaged in containers of 55-gallon capacity or smaller. If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear sell-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate tor a radius ot 2500 feet FIBERS OR FABRIC, CONTAINING NOT MORE THAN 4917327 5% ANIMAL OR VEGETABLE OIL. FLAMMABLE SOUD NA1373 Fibers or fabric, containing not more than 5% animal or vegetable oil are materials that have been contaminated, impregnated or coated with animal or vegetable oil. It is liable to spontaneous heating and ignition. tf material on fire or involved In fire Flood with water If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away FILM (NITROCELLULOSE) (MOVING PICTURE FILM 4917340 SCRAP) FLAMMABLE SOUD NA1324 Film (nitrocellulose) is a photographic film made of nitrocellulose. It is easily ignited and burns with great rapidity. Older film may deteriorate and be liable to spontaneous heating and ignition. Toxic oxides of ni trogen are produced during combustion. If material on fire or involved in fire Flood with water Apply water from as far a distance as possible If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Wear self-contained breathing apparatus when fighting fires involv ing this material Approach fire with caution FILM (NITROCELLULOSE) (MOVING PICTURE FILM, 4917337 EXPOSED, NEC) FLAMMABLE SOLID NA1324 Film (nitrocellulose) is a photographic film made of nitrocellulose. It is easily ignited and burns with great rapidity. Older film may deteriorate and be liable to spontaneous heating and ignition. Toxic oxides of ni trogen are produced during combustion. If material on fire or involved in fire Flood with water Apply water from as far a distance as possible If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Wear self-contained breathing apparatus when fighting fires involv ing this material Approach fire with caution FIBERS. BURNT 4917325 FLAMMABLE SOLID NA1372 Burnt fiber is fiber that has been on fire and the burned parts have not been removed. The hazard is that once the fiber has been on fire the fire may persist for a long time in the interior of the bale or bag. If material on fire or Involved in fire Flood with water If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away 248 FILM (NITROCELLULOSE) (PHOTOGRAPHIC FILM, 4917382 NEC, UNEXPOSED) FLAMMABLE SOUD NA1324 Film (nitrocellulose) is a photographic film made from nitrocellulose. It is easily ignited and bums with great rapidity. Older film may deteriorate and be liable to spontaneous heating and ignition. Toxic oxides of ni trogen are produced during combustion, tf material on fire or Involved in fire Flood with water Apply water from as far a distance as possible April 1961 MCD 000017174 If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Wear self-contained breathing apparatus when lighting fires involv ing this material Approach fire with caution FIRE EXTINGUISHER 4904820 NONFLAMMABLE GAS UN1044 Fire extinguisher is a device containing a nonflammable gas under pressure. It has a mechanism to spray the contained gas or expel a liquid, through some type of nozzle. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Wear protective gloves and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water FIRE EXTINGUISHER CHARGES CONTAINING 4930219 SULFURIC ACID CORROSIVE MATERIAL ACIDIC UN1774 Fire extinguisher charges consist of two chemicals packed in the same outside container. One is sodium bicarbonate, white water soluble solid that is non hazardous. The other is sulfuric acid, in limited quantities, a colorless odorless liquid. Sulfuric acid is soluble in water with release of heat. It is corrosive to metals and tissue. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective ciothing FIRECRACKERS OR TORPEDOES (COMMON 4903525 FIREWORKS) CLASS C EXPLOSIVE Firecrackers or torpedoes are tubular devices, made of paper with external dimensions not exceeding 1 1/2 inches in length and 1/4 inch in diameter. They are filled with a pyrotechnic composition not exceeding two grains in weight designed to produce an audible effect. If material on fire or involved in fire Flood with water Apply water from as far a distance as possible If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet FISH MEAL CONTAINING LESS THEN 6% OR MORE 4917326 THAN 12% WATER (FISH MEAL, GROUND, PULVERIZED OR SCREENED) FLAMMABLE SOLID NA1374 Fish meal that is too dry is liable to spontaneous heating and ignition. Fish meal that is too wet is liable to decay, spontaneous heating and ignition. It must be shipped in air tight metal containers. If material on fire or Involved In fire Flood with water If material not on fire end not Involved in fire Keep sparks, flames, and other sources of ignition away FIRE PROOFING COMPOUNDS, LIQUID, NEC 4936536 (CORROSIVE LIQUID, N.O.S.) CORROSIVE MATERIAL UN1760 Fireproofing compounds, liquid, nec are various colored materials. They are corrosive to metals and/or tissue. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itsetf does not bum or bums with difficulty.) Use water in flooding quantities as fog Apply water from as far a distance as possible April 1981 FISH OIL RESIDUUM, DEHYDRATED (GARBAGE 4917460 TANKAGE (CONTAINING LESS THAN 8% MOISTURE) FLAMMABLE SOLID NA1325 Fish oil residuum, dehydrated is liable to spontaneous heating and ignition if not properly cooled after manufacture or is too dry. If material on fire or involved In fire Flood with water 249 0000 FISH SCRAP CONTAINING LESS THAN 6% OR MORE 4917329 THAN 12% WATER (FISH SCRAP, GROUND, PULVERIZED OR SCREENED) FLAMMABLE SOUO NA1374 Fish scrap that is too dry is liable to spontaneous heating and ignition. Fish scrap that is too wet is liable to decay, spontaneous heating and ignition. It must be shipped in airtight metal containers. II material on fire or involved in fire Flood with water If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away FISH SCRAP CONTAINING LESS THAN 6% OR MORE 4917330 THAN 12% WATER (FISH SCRAP, NEC, DRY NOT GROUND, PULVERIZED NOR SCREENED) FLAMMABLE SOLID NA1374 Fish scrap that is too dry is liable to spontaneous heating and ignition. Fish scrap that is too wet is liable to decay, spontaneous heating and ignition. It must be shipped in airtight metal containers. If material on fire or Involved in fire Flood with water If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away FISH SCRAP OR FISH MEAL CONTAINING LESS 4917331 THAN 6% OR MORE THAN 12% WATER (FISH TANKAGE, NEC, DRY, NOT GROUND, PULVERIZED, OR SCREENED) FLAMMABLE SOLID NA1374 Fish scrap or fish meal that is too dry is liable to spontaneous heating and ignition. Fish scrap or fish meal that is too wet is liable to decay, spontaneous heating and ignition. It must be shipped in airtight metal containers. If material on fire or involved In fire Flood with water If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away FISH SCRAP, NEC, GREEN (FISH SCRAP 4917462 (CONTAINING LESS THAN 6% OR MORE THAN 12% MOISTURE)) FLAMMABLE SOLID NA1374 Fish scrap, nec. green that is too dry is liable to spontaneous heating and ignition; or too wet is liable to decay, spontaneous heating and ignition. If material on fire or involved in fire Flood with water If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away FLAME COLORING COMPOUNDS (OXIDIZING 4916905 MATERIALS, N.O.S.) OXIDIZER UN1479 Flame coloring compounds are various materials which have the prop erty of accelerating the burning of combustible material. These materials may not burn by themselves. Prolonged exposure to fire or heat by these ma terials and/or their containers may result In an explosion. These materials may only be found in containers of 55-gallon capacity or smaller. If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible 250 If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet FLAME RETARDANT COMPOUND, LIQUID 4936570 CORROSIVE MATERIAL NA1760 Flame retardant compound liquid is a variable colored material having the property of being corrosive to metals and/or tissue. It may or may not be water soluble. If material Involved in fire Extinguish fire using agent suitablo for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing FLAMMABLE GAS, N.O.S. (See COMPRESSEO GAS, N.O.S., FLAMMABLE GAS 4905710) FLAMMABLE LIQUID, CORROSIVE, N.O.S. 4907629 FLAMMABLE LIQUID, CORROSIVE UN2924 Flammable liquid, corrosive, n.o.s. is the proper shipping name for those liquids having a closed cup flash piont of less than 100 deg. F., being corrosive to steel and/or tissue, and not being specifically men tioned in the hazardous materials regulations. Try to ascertain the exact name of the material from the shipping papers. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use "alcohol" foam, carbon dioxide or dry chemical Cool all affected containers with Hooding quantities of water Apply water from as far a distance as possible Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime April 1981 MCD 000017176 Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water FLAMMABLE LIQUID, N.O.S. 4910185 FLAMMABLE LIQUID UN1993 Flammable liquid, n.o.s. is the proper shipping name for those ma terials having a closed cup flash point of less than 100 deg. F. and not specifically mentioned in the hazardous materials regulations. H material on fire or involved in fire Oo not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water FLAMMABLE LIQUID, POISONOUS. N.O.S. 4907422 FLAMMABLE LIQUID UNI 992 Flammable liquid, poisonous, n.o.s. is the proper shipping name for those liquids having a closed cup flash point of less than 100 deg. F., being toxic by ingestion, inhalation, or skin absorption, and not specif ically mentioned in the hazardous materials regulations. Try to ascertain the exact name of this material from the shipping papers. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear setf-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing April 1981 Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered FLAMMABLE SOLID, CORROSIVE, N.O.S. 4916755 FLAMMABLE SOLID UN2925 Flammable solid, corrosive, n.o.s. is the proper shipping name of any solid material other than one classed as an explosive which is liable under conditions incident to transportation to cause fires through friction, absorption of moisture, spontaneous chemical changes as a result of retained heat from the manufacturing or processing of the material, or which can be easily ignited by external sparks or flame and when so ignited burns vigorously and persistently. Also, the material is corrosive to metals and/or tissue. Try to ascertain the exact name of the material from the shipping papers. If material on fire or involved In fire Extinguish fire using agent suitable for type of fire If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing FLAMMABLE SOUD, N.O.S. 4917332 FLAMMABLE SOLID UN1325 Flammable solid, n.o.s. is the proper shipping name of any solid ma terial other than one classed as an explosive, or specifically listed by name in the list of hazardous materials which is liable under conditions incident to transportation to cause fires through friction, absorption of moisture, spontaneous chemical changes as a result of retained heat from the manufacturing or processing of the solid, or which can be readily ignited by external sparks or flame and when so ignited burns vigorously and persistently. Try to ascertain the exact name of the material. If materiel on fire or Involved In fire Extinguish fire using agent suitable for type of fire If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Build dikes to contain flow as necessary Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water FLAMMABLE SOLID, POISONOUS, N.O.S. 4916615 FLAMMABLE SOLID, POISONOUS UN2926 Flammable solid, poisonous, n.o.s. is the proper shipping name of any solid material other than one classed as an explosive which is liable under conditions incident to transportation to cause fires through friction, absorption of moisture, spontaneous chemical changes as a result of retained heat from the manufacturing or processing of the material, or which can be easily ignited by external sparks or flame and when so ignited burns vigorously and persistently. Also, the material is toxic by ingestion, inhalation, or skin absorption. Try to ascertain the exact name of the material from the shipping papers. Continued on next page MOD 000017.177 251 If material on fire or involved in fire Extinguish fire using agent suitable for type of fire If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Build dikes to contain flow as necessary Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water tt material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray fo knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water FLARES, HIGHWAY SAFETY, SOLIDIFIED FUEL, 4917445 OTHER THAN EXPLOSIVES OR FIREWORKS. (FLAMMABLE SOLID, N.O.S.) FLAMMABLE SOLID UN1325 Flares, highway safety, solidified fuel are pasteboard or fiber tubes containing a solid fuel that bum with an intense red, green, or yellow (lame. Once ignited they can bum under water. If material on fire or involved In fire If fire is massive, back off, protect surroundings, and let bum For scattered burning fusees, smother in dirt If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing fumes from burning material FLEXIBLE LINEAR SHAPED CHARGE. METAL CLAD 4903320 CLASS C EXPLOSIVE Flexible linear shaped charge, metai clad consists of a core containing not more than 15 grains of high explosive composition per foot and not exceeding 26 feet in length or containing not more than 2 1/2 grains ol high explosive composition per fool covered with metal. It may be cov ered with tapes, yams, plastics or waterproofing compounds. If material on Fire or Involved In fire Dangerously explosive Flood with water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation if fire becomes uncontrollable---evacuate for a radius of 1500 feet FLOOR COVERING UNDER LAYMENT COMPOUNDS, 4910456 NEC (FLAMMABLE LIQUID, N.O.S.) FLAMMABLE LIQUID UN1993 Floor covering underlayment compounds, nec are various colored thick liquids. They have a flash point of less than 100 deg. F. They are generally heavier than water and insoluble in water. The vapors are heavier than air. If material on tire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical 252 FLOOR COVERING UNDERLAYMENT COMPOUNDS, 4915456 NEC (COMBUSTIBLE LIQUIDS, N.O.S COMBUSTIBLE LIQUID NA1993 Floor covering underlayment compounds, nec are various colored thick liquids. They have a flash point between 100 and 199 deg. F. They are generally heavier than water and insoluble in water. Their vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water FLOOR POUSH OR WAX (POLISH, WOOD, LIQUID) 4910271 FLAMMABLE LIQUID NA1142 Floor polish or wax is a clear colorless to milky white or cream colored thick liquid. It has a flash point of less than 100 deg. F. It is generally heavier than water and insoluble in water, its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 MOD FLOOR POLISH OR WAX (POLISH, WOOD, LIQUID) 4915271 COMBUSTIBLE LIQUID NA1142 Floor polish or wax is a clear colorless to milky white or cream colored thick liquid. It hasaflash point between 100 and 199 deg. F. It is generally heavier than water and insoluble in water, its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use `'alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water FLOUR BLEACHING COMPOUNDS, NEC (OXIDIZING 491B910 MATERIAL, N.O.S.) OXIDIZER UN1479 Flour bleaching compounds, nec are various materials which have the property of accelerating the burning of combustible material. These materials may not burn by themselves. Prolonged exposure to fire or heat by these materials and/or their containers may result in an explo sion. These materials may be only packaged in containers of 55-gallon capacity or smaller. If material on fire or Involved In fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved in fire Keep sparks, (lames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet FLUOBORIC ACID 4930222 CORROSIVE MATERIAL. ACIDIC UN1775 Fluoboric acid is a colorless odorless liquid. It is soluble in water with release of heat. It is corrosive to metals and tissue. If material Involved in fire Extinguish fire using agent suitable tor type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as log Cool ait affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind April 1981 Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing FLUORIC ACID (See HYDROFLUORIC ACID SOLUTION 4930022) FLUORINE 4904030 NONFLAMMABLE GAS, OXIDIZING, POISONOUS, UN1045 CORROSIVE Fluorine is a pale yellow gas with a pungent odor. It is toxic by in halation. Contact with skin in lower than lethal concentration causes bums. It reacts with water to form hydrofluoric acid and oxygen. It is corrosive to most common matenals. It reacts with most combustible materials to the point that ignition often occurs. It must be shipped in cylinders, not equipped with a safety relief device and in quantities not exceeding 6 pounds of gas per cylinder. Under fire conditions the cyl inders are subject to violent rupturing and rocketing. If material involved in fire Do not extinguish fire unless flow can be stopped Extinguish tire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Do not use water on material itself Use water spray to absorb vapors If material not Involved in fire Keep sparks, flames, and other sources of ignition away Attempt to stop leak if without hazard Use water spray to knock-down vapors Do not use water on material itself Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered FLUOROETHANE GASES, NONFLAMMABLE 4904536 (COMPRESSED GAS, N.O.S.) NONFLAMMABLE GAS UN1956 Fluoroethane gases are colorless odorless gases. They are noncom bustible. They can cause asphyxiation by the displacement of air. It may only be shipped in cylinders. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved in fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment rtCD OGOOl'7 179 253 FLUOROPHOSPHORIC ACID, ANHYDROUS (See MONOFLUOROPHOSPHORIC ACID, ANHYDROUS 4930240) FLUOROSILICIC ACID (See HYDROFLUOROSILICIC ACID 4930226) FLUOSULFONIC ACID (OR) FLUOROSULFONIC ACID 4930010 CORROSIVE MATERIAL, ACIDIC, POISONOUS UNI 777 Fluosulfonic acid is an odorless fuming liquid. It is soluble in water and is decomposed by water to hydrofluoric acid and sulfuric acid with release of heat. It is corrosive to metals and to tissue. The fumes and very short contact with small quantities of the acid can cause severe painful burns. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material FOOT WARMER OR HOT BOTTLE CHARGES, 4915476 CHEMICAL (COMBUSTIBLE LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Foot warmer or hot bottle charges, chemical are materials containing a solvent having a closed cup flash point between 100 and 199 deg. F. The hazard of these materials is combustibility. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use 'alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water FOOT WARMER OR HOT BOTTLE CHARGES, 4910476 CHEMICAL (FLAMMABLE LIQUID, N.O.S.) FLAMMABLE LIQUID UNI 993 Foot warmer or hot bottle charges, chemical are materials containing a solvent having a closed cup flash point of less than 100 deg. F. The hazard of these materials is flammability. 254 If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water FORMALDEHYDE (OR) FORMALIN SOLUTION (IN 4940341 CONTAINERS OF 110 GALLONS OR LESS) (FORMALDEHYDE, LIQUID) OfiM-A UN1198 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Formaldehyde is the colorless solution of formaldehyde gas in water. It is used to make plastics, other chemicals and fertilizers, as a pre servative, as a corrosion inhibitor, and for many other uses. It is com bustible and has a flash point varying from 122 to 185 deg. F. The gas readily vaporizes from the solution and is flammable over a wide vapor- air concentration range. It is heavier than water and is soluble in water. Its vapors are heavier than air. It weighs 9.4 pounds per gallon. If material on fire or involved in fire Do not extinguish lire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors or dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fty ash or cement powder Apply ''universal" gelling agent to immobilize spill Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e.g. detergent, soaps, alcohols) to com press and thicken spilled material Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors April 1981 MCD 000017180 FORMALDEHYDE (OR) FORMALIN SOLUTION (IN 4940342 CONTAINERS OF 110 GALLONS OR LESS) (FORMALDEHYDE, PASTE) ORM-A UN1196 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Formaldehyde is the colorless solution of formaldehyde gas in water. It is used to make plastics, other chemicals and fertilizers, as a pre servative, as a corrosion inhibitor, and tor many other uses. It is com bustible and has a flash point varying from 122 to 165 deg. F. The gas readily vaporizes from the solution and is flammable over a wide vapor- air concentration range. It is heavier than water and is soluble in water. Its vapors are heavier than air. It weighs 9.4 pounds per gallon. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use ''alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of Ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors or dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Apply "universal" gelling agent to immobilize spill Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e.g. detergent, soaps, alcohols) to com press and thicken spilled material Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors FORMALDEHYDE. LIQUID (FORMALDEHYDE OR 4913144 FORMALIN SOLUTION) COMBUSTIBLE LIQUID UN1198 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Formaldehyde liquid is the colorless solution of formaldehyde gas in water. It is used to make plastics, other chemicals, and fertilizers, as a preservative, as a corrosion inhibitor, and for many other uses. It has a flash point varying from 122 to 185 deg. F. The gas readily vaporizes from solution and is flammable over a wide vapor air concentration range. The liquid is heavier than water and soluble in water. Its vapors are heavier than air. it weighs 9.4 pounds per gallon. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical April 1981 If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Add sodium bisulfite (nahso3) Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e.g. detergent, soaps, alcohols) to com press and thicken spilled material Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms Add sodium bisulfite If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Combustion products include corrosive or toxic vapors FORMALDEHYDE, PASTE (FORMALDEHYDE OR 4913145 FORMALIN SOLUTION) COMBUSTIBLE LIQUID UN1198 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Formaldehyde, paste is the thick mixture of paraformaldehyde the polymer of formaldehyde, formaldehyde and water having an irritating odor. Formaldehyde, itself, is a gas which readily vaporizes from the paste and is flammable over a wide vapor air concentration range. The paste has a flash point range of 122 to 165 deg. F. It is heavier than water and soluble in water, Its vapors are heavier than air. It weighs 9.4 pounds per gallon, If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical H material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Continued on next page 255 MCD ^00017 isl Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Add sodium bisulfite (nahso3) Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e.g. detergent, soaps, alcohols) to com press and thicken spilled material Inject "universal'' gelling agent to solidify encircled spill and increase effectiveness of booms Add sodium bisulfite If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Combustion products include corrosive or toxic vapors FORMIC ACID 4931320 CORROSIVE MATERIAL, ACIDIC, COMBUSTIBLE UN1779 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Formic acid is a colorless liquid with a pungent odor. It is combustible over a wide range of vapor air mixtures and has a (lash point of 156 deg. F. It is soluble in water with release of heat. It is corrosive to metals and tissue. It weighs 10.2 pounds per gallon. If material on fire or Involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment 256 FORMIC ACID SOLUTION 4931431 CORROSIVE MATERIAL, ACIDIC UNI 779 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Formic acid solution is the liquid material dissolved in water, tt has a pungent odor. It is corrosive to metals and tissue. It weighs 10.2 pounds per gallon. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with, agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment FREIGHT FORWARDER TRAFFIC 4950130 Consult the shipping papers for the exact contents of the car. con tainer, or trailer. FUELOIL 4915113 COMBUSTIBLE LIQUIO NA1993 Fuel oil is a straw yellow to dark colored liquid with a petroleum like odor. It has a flash point between 100 and 199 deg. F. It is lighter than water and insoluble in water, tls vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread tire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors April 1981 MC 0 (!OOij 17 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water FUEL OIL TREATING COMPOUNDS (CORROSIVE 4936537 LIQUID, N.O.S.) CORROSIVE MATERIAL UNI 760 Fuel oil treating compounds are various colored liquids. They are corrosive to metals and tissue. They may burn though it may require some effort to ignite. If material on fire or involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible tf material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing FUEL OIL, DIESEL (See FUEL OIL 4915113) FUEL OIL, NO, 1,2,4, OR 5 4915112 COMBUSTIBLE LIQUID NA1993 Fuel oil, no. 1,2, 4, or 5 are straw yellow to dark colored liquids with a petroleum like odor. They have a flash point between 100 and 199 deg. F. They are lighter than water and insoluble in water. Their vapors are heavier than air. tf material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical tf material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts ol water or soap and water April 1981 FUEL, AVIATION, TURBINE ENGINE 4909215 FLAMMABLE LIQUID UN1863 Fuel, aviation, turbine engine is a clear colorless to variable colored liquid with a petroleum like odor. It has a flash point In the range of -10 deg. f to 100 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water FUEL, AVIATION, TURBINE, ENGINE 4915167 COMBUSTIBLE LIQUID UN1863 Fuel, aviation, turbine, engine is a clear colorless to variable colored liquid with a faint petroleum like odor. It has a flash point of between 100 and 199 deg. F. ft is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water FUMARIC ACID 4966352 ORM-E NA9126 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Fumade add is a colorless crystalline solid. It is used to make paints and plastics, in food processing and preservation, and for other uses. It is slightly soluble in water, ft is combustible though it may take some effort to ignite. Continued on next page 257 MOD 000017183 If material on fire or involved In fire Do not extinuish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use ''alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors or dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig apit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Adjust ph to neutral (ph*7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates FUNGICIDES, AGRICULTURAL, NEC, LIQUID 4915196 (COMBUSTIBLE LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Fungicides, agricultural, nec, liquid, are various colored liquids. They consist of either a mixture of liquid materials or a solid dissolved in some solvent. They are generally lighter than water and are soluble in water. Prolonged exposure to the vapors or contact with liquid may result in poisoning by inhalation or skin absorption. Their flash point is between 100 and 200 deg. F. Their vapors are heavier than air. In case of damage to or leakage from containers of this material, contact the pesticide safety team network. Telephone 800-424-9300. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical II material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material FUMARYL CHLORIDE 4931740 CORROSIVE MATERIAL, ACIDIC, COMBUSTIBLE UN1780 Fumaryl chloride is a straw colored fuming liquid with a pungent odor. It is combustible ana has a flash point of 165 deg. F. Its fumes are irritating to the eyes and mucous membranes, it is decomposed by water to hydrochloric acid, a corrosive material, and water insoluble fumaric acid with release of heat. It is corrosive to metals and tissue. If material on fire or Involved In fire Use dry chemical or carbon dioxide Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing 258 FUNGICIDES, AGRICULTURAL, NEC, LIQUID 4910198 (FLAMMABLE LIQUID, N.O.S.) FLAMMABLE LIQUID UN1993 Fungicides, agricultural, nec, liquid are various colored liquids. They consist of either a mixture of liquid materials or a solid dissolved in some solvent. They are generally lighter than water and are soluble in water. Prolonged exposure to the vapors or contact with the liquid may result in poisoning by inhalation or skin absorption. Their flash point is below 100 deg. F. Their vapors are heavier than air. In case of damage to or leakage from containers of this material, contact the pesticide safety team network. Telephone 800-424-9300. If material on fira or Involved in fire Do not extinguish fire unless flow can be stopped Use water in tlooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Oni0ina4 April 1981 FUNGICIDES, AGRICULTURAL, NEC, LIQUID 4921454 (POISONOUS LIQUID, N.O.S.) POISON B NA2810 Fungicides, agricultural, nec, liquid, are various colored liquids. They consist of either a mixture of liquid materials or a solid dissolved in some solvent. They are generally lighter than water and are soluble in water. They are toxic by ingestion, skin absorption and inhalation, in case of damage to or leaking from containers of this material, contact the pes ticide safety team network. Telephone 800-424-9300. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical if materiel not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water FUNGICIDES, AGRICULTURAL, NEC, OTHER THAN 4921456 LIQUID (POISONOUS SOLID, N.O.S.) POISON B NA2S11 Fungicides, agricultural, nec. other than liquid, are either a mixture of dry materials or a liquid adsorbed on some solid carrier. They are toxic by ingestion, inhalation (dust, etc) or skin absorption. In case of damage to or leaking from containers of this material, contact the pesticide safety team network. Telephone 800-424-9300. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Use "alcohol1' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing FURAN 4909175 FLAMMABLE LIQUID UN2389 Furan is a clear colorless liquid, it has a flash point of less than 32 deg. F. ft is lighter than water and insoluble in water. Its vapors are heavier than air. April 1981 ff material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water FURFURAL 4913146 COMBUSTIBLE LIQUID UN1199 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Furfural is a clear colorless liquid turning reddish brown on exposure to light and air having a penetrating odor of almonds. It has a flash point of 140 deg. F. it is heavier than water and is soluble in water. Its vapors are heavier than air. It weighs 9.7 pounds per gallon. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply wafer from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Add sodium bisulfite (nahso3) Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Combustion products include corrosive or toxic vapors 259 Hr*t) Orj'Or FURFURYL ALCOHOL (ALCOHOL, N.O.S.) 4913124 CUMBUSTIBLE LIQUID UN1987 Furturyl alcohol is a clear colorless liquid (uming brown to dark red on exposure to light. It has a flash point of 167 deg. F. It reacts vigorously with most adds forming a black solid. It is heavier than water and soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Peraonnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water FUSE IGNITER 4903445 CLASS C EXPLOSIVE Fuse igniters are small cylindrical pasteboard or metal tubes contain ing an igniting composition in one end with the other end open to permit it to be placed on safety fuse. If material on fire or involved In fire Flood with water Apply water from as far a distance as possible If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet FUSE, SAFETY 4903323 CLASS C EXPLOSIVE. Safety fuse consists of a core of fine grained black powder encased in a fabric covering of yam. tape, and a waterproofing compound. Under fire conditions it will only burn and not explode. If material on fire or involved in fire Flood with water Apply water from as far a distance as possible If material not on fire and not involved in lire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material FUSEE (RAILWAY AND HIGHWAY) 4917333 FLAMMABLE SOLID NA1325 Fusees (railway and highway) are pasteboard or fiber tubes containing a pyrotechnic composition that burns with an intense red, green or yellow flame. Once ignited the fusee may burn under water. If material on fire or involved in fire If fire is massive, back off, protect surroundings, and let burn For scattered burning fusees, smother in dirt if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Peraonnel protection Avoid breathing fumes from burning material FUSEE (TRUCK FLARES, STEEL, 24 GAUGE OR 4917366 THICKER) FLAMMABLE SOLID NA1325 Fusees (truck flares, steel, 24 gauge or thicker) are metal devices containing a pyrotechnic composition. These devices are easily ignited and bum with an intense flame. If material on fire or involved in fire If fire is massive, back off. protect surroundings, and lei burn For scattered burning fusees, smother in dirt ff material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing fumes from burning material FUSE LIGHTER CLASS C EXPLOSIVE 4903450 Fuse lighters are small cylindrical pasteboard or metal tubes contain ing an igniting composition in one end with the other end open to permit it to be placed on safety fuse. If material on fire or involved In fire Flood with water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach tire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet 260 FUSEL OIL 4915169 C0M8USTIBLE LIQUID UNI 201 Fusel oil is a clear colorless liquid with a mild odor. It has a flash point of 123 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. If materiel on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid April 1981 mod 00001 7186 UNUSED NUMBERS Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water GALENA ORE, CRUDE (LEAD SULFIDE) 4966994 ORM-E NA2291 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Galena ore. crude is stone with grey crystalline solid. It is used as the source mineral for lead. It is insoluble in water. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Bulk! dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates GAMBIER EXTRACTS, LIQUID (FLAMMABLE LIQUID, 4910436 N.O.S.) FLAMMABLE UQUID UN1993 Gambier extracts, liquid are materials containing a solvent having a closed cup flash point of less than 100 deg. F. The hazard of these materials is flammability. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water GARBAGE TANKAGE (CONTAINING LESS THAN 8% 4917346 MOISTURE) FLAMMABLE SOLID NA1325 Garbage tankage is dried waste food products. If It has not been properly cooled or is too dry, it is liable to spontaneous heating and ignition. If material on fire or Involved in fire Flood with water If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away GAMB1ER EXTRACTS, LIQUID (COMBUSTIBLE 4916436 LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Gambier extracts, liquid are materials containing a solvent having a closed cup flash point between 100 and 199 deg. F. The hazard of these materials is combustibility. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 GARBAGE TANKAGE (CONTAINING LESS THAN 8% 4917364 WATER) FLAMMABLE SOLID NA132S Garbage tankage is dried waste food products. If it has not been properly cooled or is too dry. it is liable to spontaneous heating and ignition. If material on fire or Involved in fire Flood with water If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away GAS DRIPS, HYDROCARBON 4915188 COMBUSTIBLE UQUID UN1864 Gas drips, hydrocarbon are clear colorless to variable colored liquids. Their flash point is between 100 and 199 deg. F. They are lighter than water and insoluble in water. Their vapors are heavier than air. H material on fire or involved in fire Do not extinguish tire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical Continued on next page 261 000017168 MOP If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water GAS DRIPS, HYDROCARBON 4910168 FLAMMABLE LIQUID UN1864 Gas drips, hydrocarbon are clear colorless to variable colored liquids. Their flash point is below 100 deg. F. and is generally much lower. They are lighter than water and insoluble in water. Their vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water GAS IDENTIFICATION SET 4920510 POISON A NA9035 Gas identification set is a collection of small quantities of poisonous liquids and gases, poison a and possibly irritating materials and chlorine. It is used to familiarize people with the smell of the various materials. The outside container must be either a wooden box or a specially con structed flanged steel cylinder. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Cool ail affected containers with flooding quantities of water Use "alcohol'1 foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 262 MCD 0000171H9 GAS IDENTIFICATION SET 4925635 IRRITATING MATERIAL NA9035 Gas identification set is a collection of small containers of irritating materials absorbed on an inert material. It is used to familiarize people with the smell of the various materials. The outside container must be either a wooden box or a specially constructed flanged steel cylinder. If material on fire or involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool ail affected containers with flooding quantities oi water Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources ot ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water GAS MIXTURE, NEC. COMPRESSED, OTHER THAN 4904560 POISON (COMPRESSED GAS, N.O.S.) NONFLAMMABLE GAS UN1956 Gas mixtures, nec are two or more gases shipped in the same con tainer under pressure. The mixture may consist of both nonflammable and flammable gases with the mixture having nonflammable properties. The mixture can separate after leaking with either the flammable or nonflammable gas settling in low areas. It may asphyxiate by the dis placement of air. It may only be shipped in cylinders. If the cylinder is an aerosol container, it can rupture and rocket under fire conditions. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Do not use water on material itself Use water spray to absorb vapors If material not Involved In fire Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water GAS ODORANTS, NOT COMPRESSED GAS 4915474 (COMBUSTIBLE LIQUIO, N.O.S.) COMBUSTIBLE LIQUID NA1993 Gas odorants, not compressed gas are materials containing a solvent having a closed cup flash point between 100 and 199 deg. F.The hazard of these materials is combustibility. H material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical April 1981 If material not on fire and not involved In fire Keep sparks, (lames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water GAS ODORANTS, NOT COMPRESSED GAS 4910474 (FLAMMABLE LIQUID, N.O.S.) FLAMMABLE LIQUID UN1993 Gas odorants, not compressed gas are materials containing a solvent having a closed cup flash point of less than 100 deg. F. The hazard of these materials is flammability. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Coot ait affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water GASOHOL 4907827 FLAMMABLE LIQUID NA1257 Gasohol is a blend o( gasoline and ethyl alcohol having an odor more of alcohol than gasoline. It is used as a motor fuel. It has a (lash point of less than 0 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. It material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered GASOLINE 4908178 FLAMMABLE LIQUID UNI 203 Gasoline is a clear colorless to amber colored volatile liquid with a petroleum like odor. It has a flash point of less than 0 deg. F. It is lighter than water and insoluble in water. The vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may spread lire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered GASOLINE (GASOLINE NATURAL (CASING HEAD)) 4908176 FLAMMABLE LIQUID UN1203 Gasoline is a clear colorless to amber colored volatile liquid with a petroleum like odor. It has a flash point of less than 0 deg. F. It is lighter than water and insoluble in water. The vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If matenal leaking (not on fire), downwind evacuation must be considered 263 MCI) )00i7j 90 GASOLINE (GASOLINE, BLENDED) 4908177 FLAMMABLE LIQUID UN1203 Gasoline is a clear colorless to amber colored volatile liquid with a petroleum like odor. It has a flash point of less than 0 deg. F. it is lighter than water and insoluble in water. The vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered GASOUNE PRESERVATIVE, NEC, LIQUID (COMBUSTIBLE LIQUID, N.O.S.) 4915478 COMBUSTIBLE LIQUID NA1993 Gasoline preservative nec, liquid is a material containing a solvent having a closed cup flash point between 100 and 199 deg. F. The hazard of this material is combustiblity. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water GASOLINE PRESERVATIVE, NEC, LIQUID 4910478 (FLAMMABLE LIQUID, N.O.S.) FLAMMABLE LIQUID UN1993 Gasoline preservative nec, liquid is a material containing a solvent having a closed cup flash point of less than 100 deg. F. The hazard of this material is flammability. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective 264 Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water GERANIOL'NEROL MIXTURE (COMBUSTIBLE LIQUID, 4913182 N.O.S.) COMBUSTIBLE LIQUID NA1993 Geraniol-nerol mixture is a colorless to pale yellow liquid having a pleasant flowery odor, it is used in perfumery and as a flavoring. It has a flash point of 176 deg. F. it is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, ana goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water GERMANE 4920120 POISON A UN2192 Germane is a colorless gas with a pungent odor, it is used in making electronics. It is flammable. The gas is heavier than air and a flame can flash back to the source of leak very easily. It is toxic by inhalation. It may only be shipped in cylinders which may have to be overpacked in wooden or metal containers. Prolonged exposure of the cylinders to fire or heat may result in the cylinders violent rupturing and rocketing. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Coot ail affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use ` alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors April 1961 MCD 0000171 ci i Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Oo not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation if material leaking (not on fire), downwind evacuation must be considered GLUE CATALYST, NEC (COMBUSTIBLE LIQUID, 49154S4 N.O.S.) COMBUSTIBLE LIQUID NA1993 Glue catalyst, nec is a material containing a solvent having a closed cup flash point between 100 and 199 deg. F. The hazard of this material is combustibility. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water GLUE CATALYST, NEC (FLAMMABLE LIQUID, N.O.S.) 4910454 FLAMMABLE LIQUID UN1993 Glue catalyst, nec is a material containing a solvent having a closed cup flash point of less than 100 deg. F. The hazard of this material is flammability. If material on fire or involved In fire Oo not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 GLYCERINE, CRUDE, (SPENT LYE), CONCENTRATED 4936541 (CORROSIVE LIQUID, N.O.S.) CORROSIVE MATERIAL, BASIC UN1760 Glycerine, crude, (spent lye), concentrated is a colorless to brown colored liquid. It is soluble in water. It is combustible though it may require some effort to ignite. The residual sodium hydroxide (lye) is what cause this material to be corrosive to metals and/or tissue. If material on fire or involved in fire Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing GLYCOL ETHERS (COMBUSTIBLE LIQUID, N.O.S.) 4913194 COMBUSTIBLE LIQUID NA1993 Glycol ethers are clear colorless liquids, with odors varying from none to mildly pleasant. They are used as a solvent for paints and plastics, and as a reaction medium for chemical synthesis. They have flash points between 100 and 200 deg. F. They are lighter than water and are soluble in water. Their vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water GRENADE, EMPTY, PRIMED 4903245 CLASS C EXPLOSIVE Grenade, empty, primed is a grenade shell devoid of any bursting charge but which has the primer installed, if material on fire or involved in fire Flood with water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Continued on next page 265 MCD 000017192 Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet GRENADE, HAND, EXPLOSIVE 4901250 CLASS A EXPLOSIVE Hand grenade is a small metal device filled with explosives with or without other material such as toxic gas or tear gas. smoke or incendiary charge and a burster. Under fire conditions they will explode, fragmenting in the process. tf material on fire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet GUANIDINE NITRATE 491B415 OXIDIZER, THERMALLY UNSTABLE UN1467 Guanidine nitrate is a white crystalline solid that is soluble in water. It takes some effort to ignite but once ignited it will burn with increasing vigor as the fire progresses. If contaminated with combustible materials it will accelerate their burning. Prolonged exposure of guanidine nitrate and/or its containers to fire or heat may result in an explosion. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breaming apparatus when fighting fires involv ing this material Approach fire with caution Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet HAFNIUM METAL, DRY 4916711 FLAMMABLE SOLID UN2545 Hafnium metal, dry. is a greyish metallic colored powder. Dust from dry powder may be ignited by static electricity. The dry powder reacts with moisture to produce hydrogen, a flammable gas. The heat from this reaction may be sufficient to ignite the hydrogen. It does not appreciably react with large quantities of water. If material on fire or Involved in fire Use suitable dry powder Use dry chemical or carbon dioxide Use water only if flooding quantities are available 266 n,Ov- n-9'3 If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water HAFNIUM, METAL, WET 4916712 FLAMMABLE SOLID UN1326 Hafnium metal, wet is a greyish metallic colored sludge. Dust from dry powder may be ignited by static electricity. The dry powder reacts with moisture to produce hydrogen, a flammable gas. The heat from this reaction may be sufficient to ignite the hydrogen. It does not appreciably react with large quantities of water. If material on fire or involved in fire Use suitable dry powder Use dry chemical or carbon dioxide Use water only if flooding quantities are available If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water HAIR, WET 4917435 FLAMMABLE SOLID NA1372 Hair, wet is hair wet with water. It is liable to spontaneous heating and ignition. If material on fire or involved in fire Flood with water If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away HAND SIGNAL DEVICE 4903610- CLASS C EXPLOSIVE Hand signal devices are a metal, cardboard or plastic tube containing a pyrotechnic composition which produces either a flare or smoke upon functioning. tf material on fire or involved in fire Flood with water Apply water from as far a distance as possible If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet April 1981 HAZARDOUS SUBSTANCE, LIQUID (OR) SOLID, NO.S. 4960132 ORM-E NA91B8 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Hazardous substance, liquid (or) solid, n.o.s. Specifically named in the hazardous materials regulations that has been determined to be hazardous to the environment if released. Consult the shipping papers tor the exact contents of the car, trailer, or container. HAZARDOUS WASTE, LIQUID (OR) SOLID, N.O.S. 4960131 ORM-E NA9189 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Hazardous waste, liquid (or) solid, n.o.s. Specifically named in the hazardous materials regulations that is being shipped to an epa des ignated disposal facility. Consult the shipping papers for the exact contents of the car. trailer, or container. HELIUM--ARGON GAS MIXTURE (COMPRESSED 4904542 GAS, N.O.S.) NONFLAMMABLE GAS UN1956 Helium--argon gas mixture is a colorless odorless gas. Both helium and argon are noncombustible. Helium is lighter than air and argon is heavier than air. It can cause asphyxiation by the displacement of air. It may only be shipped in cylinders. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible It material not Involved in fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment HEATER FOR REFRIGERATOR CAR, LIQUID FUEL 4910195 TYPE FLAMMABLE LIQUID NA1993 Heater for refrigerator car. liquid fuel types are mechanical devices for heating refrigerator cars. They may only be shipped containing fuel if shipped in carload or truckload quantities. The hazard is flammability which will depend upon the specific fuel. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water HELIUM 4904540 NONFLAMMABLE GAS UN1046 Helium is a colorless odorless gas. It is lighter than air and is noncombustible. It material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved In fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment April 1981 HELIUM--OXYGEN MIXTURE 4904430 NONFLAMMABLE GAS NA1960 Helium-oxygen mixture is a colorless odorless gas. Both helium and oxygen are noncombustible: however, oxygen will accelerate the com bustion of a fire. It may only be shipped in cylinders. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool alt affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved in fire Keep sparks, flames, and other sources of ignition away Attempt to stop leak if without hazard Personnel protection Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution HELIUM-BUTANE GAS MIXTURE (COMPRESSED GAS, 4904543 N.O.S.) NONFLAMMABLE GAS UNI 956 Helium-butane gas mixture is a colorless odorless gas. While helium is non-combustible and butane is flammable, the mixture is nonflamm able. The mixture can separate with the butane settling into low areas. It may only be shipped in cylinders, If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment 267 HELIUM-BUTANE GAS, MIXTURE (COMPRESSED 4905840 GAS, N.O.S.) FLAMMABLE GAS UN1954 Helium butane gas mixture is a colorless gas with a faint odor of petroleum. It is easily ignited and may only be shipped in cylinders. Helium is lighter than air and noncombustibie, butane is flammable and heavier than air. A flame may flash back to the source of leak very easily. Under fire conditions cylinders may violently rupture and rocket. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on tire), downwind evacuation must be considered HELIUM-CARBON DIOXIDE-NITROGEN MIXTURE 4904547 (COMPRESSED GAS, N.O.S.) NONFLAMMABLE GAS UN1956 Helium-carbon dioxide-nitrogen is a colorless, odorless gas. Helium, carbon dioxide, and nitrogen are each noncombustible. It can asphyxiate by the displacement of air. It may only be shipped in cylinders. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved In fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment HEUUM-ISOBUTANE GAS MIXTURE (COMPRESSED 4905842 GAS, N.O.S.) FLAMMABLE GAS UN1954 Helium-isobutane gas mixture is a colorless gas with a faint petroleum like odor. It is easily ignited and may only be shipped in cylinders. Helium is lighter than air and noncombustible, isobutane is heavier than air and flammable. A flame may flash back to the source of leak very easily. Under fire conditions cylinders may violently rupture and rocket. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors 268 Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered HEUUM-ISOBUTANE GAS MIXTURE (COMPRESSED 4904544 GAS, N.O.S.) NONFLAMMABLE GAS UNI 956 Helium-isobutane gas mixture is a colorless odorless gas. While he lium is noncombustible and isobutane is flammable. The mixture is non flammable. The mixture can separate with the isobutane settling into low areas. It may only be shipped in cylinders. ft material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Appiy water from as far a distance as possible If material not Involved In fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment HELIUM-NITROGEN MIXTURE (COMPRESSED GAS, 4904545 N.O.S.) NONFLAMMABLE GAS UN1956 Helium-nitrogen mixture is colorless odorless gas. Both helium and nitrogen are noncombustibie. It may only be shipped in cylinders. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible H material not Involved in fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment HEPTACHLOR 4960630 ORM-E NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Heptachlor is a white to light tan waxy looking solid. It is used as an insectide. It is non-combustible. It is insoluble in water. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone- 800-424-9300. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums witti difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If large quantities of combustibles are involved, use water in flooding quantities as spray and fog April 1981 MCI) 000017^95 H material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breaming vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors HEPTANE 4909190 FLAMMABLE LIQUID UNI 206 Heptane is a clear colorless liquid with a petroleum-like odor. It has a flash point of 25 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical tf material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water HEXACHLOROCYCLOPEHTAOIENE 4933015 CORROSIVE MATERIAL, POISONOUS UN2646 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Hexachlorocyclopentadiene a pale yellow liquid with a pungent odor. It is noncombustible and solidifies at 50 deg. F. It is insoluble in water. It is toxic by skin absorption and inhalation, it is corrosive to tissue. It weighs 14.3 pounds per gallon. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water spray to absorb vapors If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary April 1961 HEXADECYL TRICHLOROSILANE 4934250 CORROSIVE MATERIAL, ACIDIC UN1781 Hexadecyl trichlorosilane is a colorless to yellow liquid with a pungent odor. Material will bum though it may require some effort to ignite. It is decomposed by moisture or water to hydrochloric acid with evolution of heat. It is corrosive to metals and tissue, tf material on fire or involved in fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing HEXADIENE 4908184 FLAMMABLE LIQUID UN2458 hexadiene is a dear, colorless liquid with a petroleum like odor. It has a flash point of less than 0 deg. F. ft is lighter than water and insoluble in water. Its vapors are heavier than air. Continued on next page HCP GODOVA 269 If material on fire or involved in fire Oo not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without ha2ard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered HEXAETHYL TETRAPHOSPHATE MIXTURE, DRY 4921423 (CONTAINQ NOT MORE THAN 2% HEXAETHYL TETRAPHOSPHATE) POISON B NA2783 Hexaethyl tetraphosphate mixture, dry is a liquid absorbed on a dry carrier. Hexaethyl tetraphosphate itself is soluble in water and is difficult to burn. It is toxic by skin absorption and inhalation (dust, etc.). In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 600-424-9300 If material on fire or Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing If material on fire or Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing HEXAETHYL TETRAPHOSPHATE MIXTURE, LIQUID 4921432 (CONTAINING MORE THAN 25% HEXAETHYL TETRAPHOSPHATE) POISON B NA2783 Hexaethyl tetraphosphate mixture, liquid is the yellow liquid dissolved in a solvent. The mixture is soluble in water. The combustibility of the mixture will depend on the solvent used. It is toxic by inhalation and by skin absorption. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424- 9300 tf material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear seif-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered HEXAETHYL TETRAPHOSPHATE MIXTURE, DRY 4921431 (CONTAINING MORE THAN 2% HEXAETHYL TETRAPHOSPHATE) POISON B NA2783 Hexaethyl tetraphosphate mixture, dry is a liquid absorbed on a dry carrier. Hexaethyl tetraphosphate itself is soluble In water and is difficult to burn. It is toxic by skin absorption and inhalation (dust. etc.). In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300 270 HEXAETHYL TETRAPHOSPHATE MIXTURE, LIQUIO 4921441 (CONTAINING NOT MORE THAN 25% HEXAETHYL TETRAPHOSPHATE) POISON B NA2783 Hexaethyl tetraphosphate mixture, liquid is the yellow liquid dissolved in a solvent. The mixture is soluble in water. The combustibility of the mixture will depend on the solvent used. It is toxic by inhalation and by skin absorption. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424 9300 MCD 000017197 April 1981 ft material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Matehal itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Use foam, carbon dioxide or dry chemical It material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation if material leaking (not on fire), downwind evacuation must be considered If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as tog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered HEXAETHYL TETRAPHOSPHATE, LIQUID 4921430 POISON B UNI 611 Hexaethyl tetraphospdate. liquid is a yellow liquid. It is soluble in water and difficult to burn, it is toxic by skin absorption and inhalation. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300 If material on fire or Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered HEXAETHYLTETRAPHOSPHATE AND COMPRESSED 4920515 GAS MIXTURE POISON A UN1612 Hexaethyltetraphosphate and compressed gas mixture is a liquid material charged with a gas. Hexaethyltetraphosphate is a yellow liquid and is lethal by skin absorption and inhalation. The material may only be shipped in cylinders, and these must be over packed in either a wooden box or a fiberboard box. Prolonged exposure of the cylinders to fire or heat may result in the violent rupturing and rocketing of the cylinders. In case of damage to, or leaking from containers of this ma terial contact the pesticide safety team network. Telephone; 800-424- 9300 HEXAFLUOROPHOSPHORIC ACID 4930015 CORROSIVE MATERIAL, ACIDIC, POISONOUS UN1782 Hexafiuorophosphoric acid is a colorless fuming liquid. It is soluble in water with release of heat. It is corrosive to metals and tissue. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing HEXAFLUOROPROPYLENE 4904546 NONFLAMMABLE GAS UNI 858 Hexafiuoropropylene is an odorless, colorless gas. It is noncombus tible. It can asphyxiate by the displacement of air. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment April 1981 271 MCI) 000017198 HEXAFLUOROPROPYLENE OXIDE 4904548 NONFLAMMABLE GAS NA1956 Hexafluoropropyiene oxide is a colorless odorless gas. it is shipped as a liquefied gas under its vapor pressure. Contact with the liquid can cause frostbite. Its vapors are heavier than air. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment HEXALDEHYDE 4909185 FLAMMABLE LIQUID UN1207 Hexaldehyde is a clear colorless liquid with a pungent odor. It has a flash point of 90 deg. F. It is lighter than water and is insoluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'1 foam, carbon dioxide or dry chemical tl material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 3,3,6,6,9,9-HEXAMETHYL-l .2,4,5- 4919277 TETRAOXOCYCLONONANE, (TECNHICALLY PURE) ORGANIC PEROXIDE UN2165 3,3,6,6,9,9-hexamethyl-i,2,4,5-tetraoxocyclononane, (tecnhically pure) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and burns with increasing rapidity as the fire progresses. It can form explosive mixtures with finely divided combustible materials, it supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or Involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive H material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up 272 Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet 3,3,6,6,9.9-HEXAMETHYL-1,2t4,5- 4919169 TETRAOXOCYCLONONANE, (NOT MORE THAN 52% WITH INERT SOLID) ORGANIC PEROXIDE UN2166 3.3,6,6.9,9-hexamethyl-1,2,4.5-tetraoxocyclononane, (not more than 52% with inert solid) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spon taneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. tf material on lire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet 3,3,6,6,9,9-HEXAMETHYL-1,2,4,5- 4919168 TETRAOXOCYCLONONANE, (NOT MORE THAN 52% IN SOLUTION) ORGANIC PEROXIDE UN2167 3,3.6,6,9,9-hexamethyl-1,2,4,5-tetraoxocyclononane, (not more than 52% in solution) is a colorless to pale yellow liquid. It is used to man ufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamina tion with many chemical substances can cause a violent chemical re action. It supports the burning of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. April 1981 MOD O00O1 7199 If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gioves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet HEXAMETHYLENE DIAMINE SOLUTION 4935645 CORROSIVE MATERIAL, BASIC UNI 763 Hexamethylene diamine solution is a clear colorless liquid. It is used to make nylon. It will burn though it may require some effort to ignite. It is soluble in water. It is corrosive to metals and tissue. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gioves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with die material anticipated, wear full protective clothing HEXAMETHYLENE DIAMINE, SOLID 4935640 CORROSIVE MATERIAL, BASIC UN2280 Hexamethylene diamine, solid is a colorless crystalline solid. It is soluble in water. It is corrosive to metals and tissue. Toxic oxides of nitrogen are produced during combustion of this material. H material on fire or involved in fire Use water in flooding quantities as fog Cod all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical April 1981 If material not on fire and not Involved in fire Keep Sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing HEXAMETHYLENE IMINE CORROSIVE MATERIAL, BASIC, FLAMMABLE, 4935650 UN2493 POISONOUS Hexamethylene imine is a colorless liquid with an ammonia like odor. It is flammable and has a flash point of 65 deg. F. It is toxic by ingestion. It is soluble in water. It is corrosive to metals and tissue. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical H material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing HEXANE 4908183 FLAMMABLE LIQUID UN1208 Hexane is a clear colorless liquid with a petroleum like odor. It is used as a solvent, paint thinner, and chemical reaction medium. It has a flash point of -9 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak it without hazard Use water spray to knock-down vapors Continued on next page 273 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered HEXANOIC ACIO 4931434 CORROSIVE MATERIAL, ACIDIC NA1760 Hexanoic acid is a colorless to light yellow liquid with an odor of limburger cheese. It will bum though it may take some effort to ignite. It is slightly soluble in water. It is corrosive to metals and tissue. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any materiai which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing HEXYL ALCOHOL, OTHER THAN PERFUMERY 4913126 GRADE (ALCOHOL. N.O.S.) COMBUSTIBLE LIQUID UN1987 Hexyl alcohol is a clear colorless liquid. It has a Mash point of 149 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. H material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 274 HEXYL TRICHLOROSILANE 4934255 CORROSIVE MATERIAL, ACIDIC UN1784 Hexyl trichlorosiiane is a colorless liquid with a pungent odor. It is decomposed by moist air or water to hydrochloric acid with evolution of heat. It is corrosive to metals and tissue. If material on fire or involved In fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing HIGH EXPLOSIVE 4901502 CLASS A EXPLOSIVE High explosive is the proper shipping name for those solid materials having the property of detonating when initiated by a commercial number 8 electric blasting cap. It is a variable colored solid. It does not function by burning. Most high explosives will burn once ignited by a flame and many will bum quietly if the quantity is small or the material is thinly spread over a large area. If large quantities are involved in the fire, or if the material is confined, or is packaged for shipment, the material can explode en masse without warning. If material on fire or Involved In fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum If material not on fire and not involved in fire Keep sparks, flames, and other sources of Ignition away Keep spilled material wet Wet spilled material before picking it up Do not attempt to sweep up dry material Personnel protection Avoid breathing dusts, and fumes from burning material Wear protective gloves and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet April 1961 MCI) OOQo 17201 HIGH EXPLOSIVE (NITROCELLULOSE, DRY) CLASS A EXPLOSIVE 4901S20 Nitrocellulose, dry is a white fibrous to amorphous powder, or a com pressed block or stick. It can be detonated with a commercial number 8 electric blasting cap. It will bum once ignited with a flame and will continue to bum vigorously if the quantity is small or the material is thinly spread over a large area. If large quantities are involved in the fire, or if the material is confined, or is packaged for shipment, the material can explode en masse without warning. If material on fire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and iet burn If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep spilled material wet Wet spilled material before picking it up Do not attempt to sweep up dry material Personnel protection Avoid breathing dusts, and fumes from burning material Wear protective gloves and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when tighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet HIGH EXPLOSIVE (NITROSTARCH, DRY) 4901530 CLASS A EXPLOSIVE ' Nitrostarch. dry is a white solid. It can be detonated with a commercial number 8 electric blasting cap. It will bum once ignited with a flame and will continue to burn vigorously if the quantity is small or the material is thinty spread over a large area. If large quantities are involved in the fire, or if the material is confined, or is packaged for shipment, the material can explode en masse without warning. If material on fire or involved in fire Dangerously explosive Do not tight fires in a cargo of explosives Evacuate area and let bum If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep spilled material wet Wet spilled material before picking it up Do not attempt to sweep up dry material Personnel protection Avoid breathing dusts, and fumes from burning material Wear protective gloves and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet HIGH EXPLOSIVE (PICRIC ACID, DRY) 4901510 CLASS A EXPLOSIVE Picric acid is a yellow crystalline solid. It can be detonated with a commercial number 6 electric blasting cap. It will burn once ignited by a flame and will continue to burn quietly if the quantity is small or the material is thinly spread over a large area. If large quantities are involved in the fire, or if the material is confined, or is packaged for shipment, the material can explode en masse without warning. April 1981 If material on fire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep spilled material wet Wet spilled material before picking it up Do not attempt to sweep up dry material Personnel protection Avoid breathing dusts, and fumes from burning material Wear protective gloves and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet HIGH EXPLOSIVE (TRINITROTOLUOL, DRY) 4901540 CLASS EXPLOSIVE Trinitrotoluol, dry is a yellow crystalline soiid. It can be detonated with a commercial number 8 electric blasting cap, It will burn once ignited by a flame and will continue to burn quietly if the quantity is small or the material is thinly spread over a large area. If large quantities are involved, or the material is confined, or is packaged for shipment, the material can explode en masse without warning. If material on fire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep spilled material wet Wet spilled material before picking it up Do not attempt to sweep up dry material Personnel protection Avoid breathing dusts, and fumes from burning material Wear protective gloves and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet HIGH EXPLOSIVE, LIQUID 4901504 CLASS A EXPLOSIVE High explosive, liquid is the proper shipping name for those liquid materials having the property of detonating when initiated by a number 8 electric blasting cap. They are various colored liquids and slurries. They do not function by burning. They are sensitive to shock or impact. Most high explosives, liquid will bum once ignited by a flame and many will bum quietly if the quantity is small or the material is thinly spread over a large area. If large quantities are involved in the fire, or if the material is confined, or is packaged for shipment, the material can ex plode en masse without warning. If material on fire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum Continued on next page 275 00O017202 If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep spilled material wet Wet spilled material before picking it up Do not attempt to sweep up dry material Personnel protection Avoid breathing dusts, and fumes from burning material Wear protective gloves and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet HYDRAZINE, ANHYDROUS 4906225 FLAMMABLE LIQUID, POISONOUS, CORROSIVE UN2029 THERMALLY UNSTABLE Hydrazine, anhydrous is a colorless, fuming oily liquid with an am monia like odor. It has a flash point of 99 deg. F. It can ignite sponta neously on contact with oxidizers, and may ignite spontaneously on contact with porous materials such as earth, wood, and cloth. It is toxic by inhalation and by skin absorption. It is corrosive to tissue. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use ` alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered HYDRAZINE, AQUEOUS SOLUTION 4935030 CORROSIVE MATERIAL, BASIC, POISONOUS UN2030 Hydrazine, aqueous solution is a colorless liquid with an ammonia like odor. It is combustible though K may require some effort to ignite. Contact with oxidizing materials may result in spontaneous ignition. It is toxic by inhalation and by skin absorption. It is corrosive to tissue. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water 276 Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohor foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet HYDRIODIC ACID 4930226 CORROSIVE MATERIAL UN1787 Hydriodic acid is a colorless to yellow liquid with a pungent odor. Its fumes are irritating to the eyes and mucous membranes. It is soluble in water with release of heat. It is corrosive to metals and to tissue. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog . Coo) all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing HYDR08ROMIC ACID (MORE THAN 49% STRENGTH) 4930227 CORROSIVE MATERIAL, ACIDIC UN1766 Hydrobromic acid is a colorless to yellow liquid with a pungent odor. Its fumes are irritating to the eyes and mucous membranes. It is soluble in water with release of heat. It is corrosive to metals and tissue. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or time April 1981 Mor* (JOG o; Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts ot water or soap and water If contact with the material anticipated, wear full protective clothing Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered HYDROBROMIC ACID, ANHYDROUS (See HYDROGEN BROMIDE 4904260) HYDROBROMIC ACID, NOT MORE THAN 49% 4930232 STRENGTH CORROSIVE MATERIAL UN17B8 Hydrobromic acid is a colorless to yellow liquid with a pungent odor. Its fumes are irritating to the eyes and mucous membranes. It is soluble in water with release of heat. It is corrosive to metals and tissue. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out ot water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing HYDROCARBON GAS, LIQUEFIED 4905749 FLAMMABLE GAS UN1965 Hydrocarbon gas. liquefied is a colorless gas with a faint petroleum like odor shipped as a liquefied gas under its vapor pressure. For trans port ation it may be stenched. Contact with the liquid can cause frostbite. It is easily ignited. Its vapor is heavier than air and a flame can flash back to source of leak very easily. The leak can be either a liquid or vapor leak. It can asphyxiate by the displacement of air. Under fire conditions the cylinders or tank cars may violently rupture and rocket. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind April 1981 HYDROCARBON GAS, NONUQUEFIED 4905779 FLAMMABLE GAS UN1964 Hydrocarbon gas, nonliquefied is a colorless gas with a faint petroleum like odor. It is easily ignited and may only be shipped in cylinders. A flame may flash back to the source of leak very easily. Under fire con ditions the cylinders may violently rupture and rocket. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Keep upwind Wear self-contained breathing apparatus Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered HYDROCARBON GAS, NONLIQUEFIED (COAL GAS) 4905708 FLAMMABLE GAS UNI 964 Coal gas is a colorless gas. It has a faint petroleum odor unless there are impurities to give it the characteristic odor of the impurity; commonly hydrogen sulfide, rotten eggs; or benzene, aromatic. It is easily ignited and may only be shipped in cylinders. A flame may flash back to the source of leak very easily. Under fire conditions the cylinders may vi olently rupture and rocket. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out ot water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on tire), downwind evacuation must be considered 277 Mr.T) 0i(>Oi ! 7 2;04 HYDROCHLORIC ACID 493022B CORROSIVE MATERIAL, ACIDIC UN1789 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Hydrochloric acid is a colorless to yellow liquid with a pungent odor. It is used for cleaning masonary and metals, manufacturing chemicals, in petroleum production, and for many other uses. Its fumes are irritating to the eyes and mucous membranes. It is soluble in water with release of heat. It is corrosive to metals and tissue. It weighs to. 1 pounds per gallon. It material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment HYDROCHLORIC ACID (MURIATIC ACID, SPENT) 4930231 CORROSIVE MATERIAL UN1789 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Muriatic acid, spent is a dark colored liquid with a pungent odor. Its fumes are irritating to the eyes and mucous membranes. It is soluble In water with release of heat, it is corrosive to metals and tissue. It weighs 10.1 pounds per gallon. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material Itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment 278 Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment HYDROCHLORIC ACID MIXTURE 4930229 CORROSIVE MATERIAL, ACIDIC NA1789 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Hydrochloric add mixtures are colorless to yellow liquids. Its fumes are irritating to the eyes and mucous membranes. It is soluble in water with release of heat. It is corrosive to metals and tissue. It weighs 10.1 pounds per gallon. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away arty material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone,* or sodium bicarbonate Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment HYDROCHLORIC ACID SOLUTION, INHIBITED 4930230 CORROSIVE MATERIAL, ACIDIC NA1789 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Hydrochloric acid solution, inhibited is a colorless to yellow liquid. Its fumes are irritating to the eyes and mucous membranes. It is soluble in water with release of heat. It contains some material which cuts its rate of corrosivity to metals compared to the uninhibited acid. It is cor rosive to metals and tissue. It weighs 10.1 pounds per gallon. Man '>0O j 7 20$ April 1981 ff material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved in fire Keep matehal out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled matehal with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gioves. and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the matehal anticipated, wear fult protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment HYDROCHLORIC ACID, ANHYDROUS (See HYDROGEN CHLORIDE 4904270) HYDROCYANIC ACID, LIQUEFIED 4920125 POISON A, FLAMMABLE NA1051 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-10/4.54) Hydrocyanic acid, liquefied is a colorless gas with a taint aromatic odor. It is shipped as a liquefied gas under its vapor pressure and it must be stabilized to avoid polymerization. It is easily ignited. The vapor is just lighter than air but a flame can travel back to the source of leak very easily. It can polymerize from contact with alkali. Lethal amounts may be absorbed through the skin, as well as by inhalation. It may be shipped in cylinders or tank cars. Prolonged exposure to fire or heat may cause the cylinder or tank car to violently rupture and rocket. It weighs 5.7 pounds per gallon. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In firt Keep sparks, flames, and other sources of ignition away Keep matehal out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire) evacuate for a radius of 2500 feet Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment HYDROCYANIC ACID. SOLUTION 4920130 POISON A, FLAMMABLE UN1613 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-10/4.54) Hydrocyanic acid, solution is hydrocyanic acid, a gas dissolved in water. It is a clear colorless liquid with a faint aromatic odor. It is flam mable though the lower concentrations may require some effort to ignite. The vapor is lighter than air, but a flame can flash back to the source of the leak very easily. Lethal amounts may be absorbed through the skin as well as by inhalation. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol'1 foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire) evacuate for a radius of 2500 feet Continued on next page April 1981 279 Hinr, Oqi * 7^0q Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment HYDROCYANIC ACID, SOLUTION, LESS THAN 5% 4921417 HYDROCYANIC ACID POISON B UN1613 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10/4.54) Hydrocyanic acid solution is water containing up to 5% dissolved hydrocyanic acid with the faint odor of almonds. It is toxic by inhalation and skin absorption. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment HYDROFLUORIC ACID SOLUTION 4930022 CORROSIVE MATERIAL, ACIDIC, POISONOUS UN1790 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Hydrofluoric acid solution is a colorless fuming liquid with a pungent odor. It is soluble in water with release of heat. It is corrosive to metals and tissue. The fumes and very short contact with small quantities of the liquid can cause severe painful bums. It weighs 9.6 pounds per gallon. 280 MCD UOOO17207 If material involved in fire Extinguish fire using agent suitable lor type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as tog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved In fire Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Add soda ash Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment HYDROFLUORIC ACID, ANHYDROUS (OR) 4930024 HYDROGEN FLUORIDE CORROSIVE MATERIAL, ACIDIC, POISONOUS UN1052 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Hydrofluoric acid, anhydrous is a colorless fuming liquid boiling at 67 deg. F. It is used as a catalyst and raw material in chemical manufacture. It is shipped as a liquid or liquefied gas under its vapor pressure. It is soluble in water with release of heat, it is corrosive to metals and tissue. The fumes and very short contact with small quantities of the liquid can cause severe painful bums. It weighs 6.2 pounds per gallon. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with Hooding quantities of water Apply water from as far a distance as possible If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or lime April 1981 Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire) evacuate for a radius of 2500 feet Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Add soda ash Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked lor containment HYDROFLUORIC AND SULFURIC ACID MIXTURES 4930020 CORROSIVE MATERIAL, ACIDIC, POISONOUS UNI 766 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Hydrofluoric and sulfuric acid, mixture is a dear colorless liquid with a pungent odor. It is soluble in water with release of heat, it is corrosive to metals and tissue. The fumes and very short contact with small quan tities of the acid can cause severe, painful bums. It weighs 15.3 pounds per gallon. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate April 1981 Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment HYDROFLUOSIUCIC, ACID 4930026 CORROSIVE MATERIAL, ACIOIC, POISONOUS NA1778 Hydrofluosilicic acid is a colorless fuming liquid with a penetrating pungent odor, it is used in water fluoridation, in hardening cement and ceramics, as a wood preservative, and for many other uses, it is soluble in water with release of heat. It is corrosive to metals and tissue. The fumes and very short contact with small quantities of the liquid can cause severe painful burns. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing HYDROGEN 4905746 FLAMMABLE GAS UN1049 Hydrogen is a colorless, odorless gas. It is easily ignited. It is lighter than air, but a flame can flash back to the source of the leak very easily. It is flammable over a wide range of vapor air concentrations. It may be shipped in cylinders and special tank cars. Under fire conditions the cylinders may violently rupture and rocket. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep matenai out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered O00:-7209 mod 281 HYDROGEN BROMIDE 4904260 NONFLAMMABLE GAS, CORROSIVE UN1048 Hydrogen bromide is a colorless gas with a pungent irritating odor. It is used to make other chemicals and as a catalyst in the manufacture of chemicals. The gas is corrosive. It dissolves in water to form hy- drobromic acid, a corrosive material. The vapor is heavier than air. It may only be shipped in cylinders. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with tlooding quantities of water Apply water from as far a distance as possible Use water spray to absorb vapors If material not involved in fire Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or lime Do not use water on material itself Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered HYDROGEN CHLORIDE 4904270 NONFLAMMABLE GAS, CORROSIVE UN1050 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (HQ-5000/2270) Hydrogen chloride is a colorless gas with a pungent odor. The gas is corrosive to metals and tissue and irritating to the eyes and respiratory system. It dissolves in water to form hydrochloric acid, a corrosive ma terial. The vapor is heavier than air. It weighs 9.9 pounds per gallon. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use water spray to absorb vapors If material not involved In fire Keep material out of water sources and sewers Attempt to stop ieak if without hazard Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or lime Do not use water on material itself Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment HYDROGEN IODIDE SOLUTION (See HYDRIOOIC ACID 4930226) HYDROGEN PEROXIDE SOLUTION (OVER 52% 4918335 PEROXIDE) OXIDIZER, CORROSIVE, THERMALLY UNSTABLE UN2015 Hydrogen peroxide solution is a colorless liquid dissolved in water. It is used to bleach textiles and wood pulp, in chemical manufacturing and food processing, and in water purification. Its vapors are irritating to the eyes and mucous membranes. The material can violently decom pose on contact with most common metals and their compounds Con tact with combustible material can result in spontaneous ignition. It is corrosive to tissue. Under exposure to fire or heat containers of the material can violently rupture due to decomposition of the material. If material involved in fire Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear respiratory protection if material is misting Wear boots, protective gloves, and goggles Avoid bodily contact with the material If contact with the material anticipated, wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet HYDROGEN PEROXIDE SOLUTION (40% TO 52% 4918776 PEROXIDE) OXIDIZER, CORROSIVE UN2014 Hydrogen peroxide solution is the colorless liquid dissolved in water. Its vapors are irritating to the eyes and mucous membranes. It is cor rosive to tissue. The material can violently decompose on metals and their compounds. Contact with combustible material can result in spon taneous ignition. Under exposure to fire or heat containers of the material can violently rupture due to the decomposition of the material. If material Involved In fire Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear respiratory protection if material is misting Wear boots, protective gloves, and goggles Avoid bodily contact with the material If contact with the material anticipated, wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If matenal leaking (not on fire), downwind evacuation must be considered HYDROGEN SULFATE (See SULFURIC ACID 4930040) HYDROGEN PEROXIDE SOLUTION (8% TO 40% 4918775 PEROXIDE) OXIDIZER, CORROSIVE UN2014 Hydrogen peroxide solution is the colorless liquid dissolved in water. Its vapors are irritating to the eyes and mucous membranes. The ma terial. especially the higher concentrations, can violently decompose in contact with most common metals and their compounds. Contact with combustible materials can result in spontaneous ignition. Under pro longed exposure to fire or heat containers of the material may violently rupture due to decomposition of the material. If material Involved in fire Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear respiratory protection if material is misting Wear boots, protective gloves, and goggles Avoid bodily contact with the material If contact with the material anticipated, wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water HYDROGEN SELENIDE 4905415 FLAMMABLE GAS, POISONOUS UN2202 Hydrogen selenide is a colorless gas with an offensive odor. It is soluble in water. It is irritating to the eyes and mucous membranes. It is heavier than air. It may only be shipped in cylinders. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors HYDROGEN SULFIDE 4905410 FLAMMABLE GAS, POISONOUS UNI 053 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Hydrogen sulfide is a colorless gas having the odor of rotten eggs. It is shipped as a liquefied gas under its own vapor pressure. One's sense of smell becomes rapidly fatigued in atmospheres containing hydrogen sulfide and hence cannot be counted on to warn of the con tinued presence of the gas. Contact with the liquid can cause frostbite. The gas is heavier than air and a flame can flash back to the source of leak very easily. Under fire conditions cylinders and tank cars may vi olently rupture and rocket. It is soluble in water. It weighs 8.3 pounds per gallon. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire) evacuate for a radius of 2500 feet Environmental considerations--land spit! Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment HYDROGEN, LIQUEFIED 4905745 FLAMMABLE GAS UN1966 Hydrogen, liquefied is hydrogen gas which has been compressed and condensed as a liquid at very low temperatures, boiling point -442 deg. F. It is a colorless liquid and may be shipped only in special very heavily insulated cylinders and tank cars. Contact with the liquid will cause frostbite. Hydrogen gas at normal temperatures is lighter than air but until vapors from the liquid warms up it will be heavier than air. It is very easily ignited and a flame will flash back to the source of the leak very easily. The leak could either be a liquid or vapor leak, -the tank car or cylinder is required to vent the vapor as it is normally given off). Under fire conditions the tank car or cylinder may violently rupture and rocket. If material on Are or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Oo not use water on material itself If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep materia! out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Do not use water on material itself Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water HYDROXY ALDEHYDE WASTES (FLAMMABLE 4910488 LIQUID, N.O.S.) FLAMMABLE LIQUID UN1993 Hydroxy aldehyde wastes is a material containing a solvent having a closed cup flash point of less than 100 deg. F. The hazard of this material is flammability. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water HYDROSILICOFLUORIC ACID (See HYDROFLUOROSIUCIC ACID 4930026) HYDROXY ALDEHYDE WASTES (COMBUSTIBLE 4915486 LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Hydroxy aldehyde wastes is a material containing a solvent having a closed cup flash point between 100 and 199 deg. F. The hazard of this material is combustibility. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be Ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind 284 HYDROXYETHYLACRYLATE (CORROSIVE 4935675 LIQUID,N.O.S.) CORROSIVE MATERIAL UNI 760 Hydroxyethylacrylate is a clear colorless liquid. It is used to make plastics. It is corrosive to tissue. It is also combustible and has a flash point of 120 deg. F. If the material is subject to heat or becomes con taminated, it is liable to polymerize with release of heat. If the poly merization takes place inside a container, the container is subject to voilent rupture. It is lighter than water and is slightly soluble in water. Its vapors are heavier than air. If material on fire or involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing April 1981 HYDROXYPROPYL ACRYLATE (CORROSIVE LIQUID, 4935510 N.O.S.) CORROSIVE MATERIAL, POISONOUS UN1760 POLYMERIZABLE Hydroxypropyl acrylate is a clear colorless liquid. It is used to make plastics. It is toxic by inhalation and skin absorption, and is corrosive to tissue. It is also combustible and has a Hash point of 136 deg. F. If the material is subject to heat or becomes contaminated, it is liable to po- lymerize with release of heat. If the polymerization takes place inside a container, the container is subject to violent rupture. It is lighter than water and is slightly soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use `alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts oi water or soap and water If contact with the material anticipated, wear full protective clothing HYPOCHLORITE SOLUTION (CONTAINING MORE 4936335 THAN 7% AVAILABLE CHLORINE BY WEIGHT) CORROSIVE MATERIAL UN1791 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-100/45.4) Hypochlorite solutions are colorless to light yellow liquids having a chlorine like odor. They consist of a hypochlorite compound dissolved in water. They are corrosive to metals and tissue. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting (ires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate April 1961 Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors HYPOCHLORITE SOLUTION CONTAINING NOT MORE 4944145 THAN 7% AVAILABLE CHLORINE (BY WEIGHT) ORM-A NA1791 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Hypochlorite solution containing not more than 7% available chlorine (by weight) is the white crystalline solid dissolved in water having a faint odor of chlorine, it is used as a bleach for textiles and paper pulp, for water purification, to make other chemicals, and for many other uses. It is corrosive to aluminum. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors IGNITER 4903465 CLASS C EXPLOSIVE Igniter consists of a fiberboard, plastic, paper, or metal tube containing a small quantity of igniting compound which is ignited by the action of a primer, pull wire or scratch composition. If material on fire or involved in fire Flood with water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material 285 MCI) 000017212 IGNITER CORD 4903455 CLASS C EXPLOSIVE Igniter cord consists of textile yams and/or a wire uniformly covered with a combustible chemical mixture, with or without additional textile or wire counterings waterproofing or finishing coatings which, when ig nited burns externally at various rates according to design. H material on fire or involved In fire Flood with water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material IGNITER FUSE-METAL CLAD 4903460 CLASS C EXPLOSIVE Igniter fuse-metal clad is an explosive igniter composition encased in a metal tube. If material on fire or involved in fire Flood with water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet IGNITER, JET THRUST (JATO) 4901360 CLASS A EXPLOSIVE Igniter, jet thrust (jato) is a device consisting of an electrically or remotely controlled ignition element and a charge of deflagrating type explosive. They are used to ignite the propelling charge of jet thrust units. If material on fire or involved In fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet IGNITER, JET THRUST (JATO) 4902540 CLASS B EXPLOSIVE Igniter, jet thrust (jato) are devices consisting of an electrically or remotely controlled ignition element and a charge of deflagrating type explosive. They are used to ignite the propelling charge of jet thrust units. If material on fire or involved In fire Dangerously explosive Do not tight fires in a cargo of explosives Evacuate area and let bum 286 If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Peraonnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet IGNITER, ROCKET MOTOR 4902550 CLASS S EXPLOSIVE Igniters, rocket motor are devices consisting of electrically or remotely controlled ignition elements and a deflagrating type of explosive. They are used to ignite the propulsion charge of rocket motors. If material on fire or Involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear seif-contained breathing apparatus when fighting tires involv ing this material Evacuation If the material is on fire or involved in fire evacuate tor a radius of 2500 feet IGNITER, ROCKET MOTOR 4901362 CLASS A EXPLOSIVE Igniter, rocket motor is a device consisting of an electrically or remotely controlled ignition element and a deflagrating type of explosive. They are used to ignite the propelling charge of rocket motors. H material on fire or Involved In fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Peraonnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet IMINOBISPROPYLAMINE 4935658 CORROSIVE MATERIAL, BASIC, COMBUSTIBLE UN2269 Immobispropyiamine is a colorless liquid, with an ammonia-like odor. It is combustible and has a flash point of 175 deg. F. It is soluble in water. It is corrosive to metals and tissue. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use '`alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary April 1981 MCI) 000017213 Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing INITIATING EXPLOSIVE (DIAZODINITROPHENOL) 4901430 CLASS A EXPLOSIVE Diazodinitrophenol is a yellow crystalline solid that darkens on ex posure to sunlight. It must be shipped wet with at least 40% water or water and denatured alcohol mixture, if it should dry out it can explode due to shock, heat, flame or friction. Upon prolonged exposure to fire or heat containers of the wet material will explode. H material on fire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum ff material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep spilled material wet Wet spilled material before picking it up Do not attempt to sweep up dry material Personnel protection Avoid breathing dusts, and fumes from burning material Wear protective gloves and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet INITIATING EXPLOSIVE (FULMINATE OF MERCURY, 4901420 WET) CLASS A EXPLOSIVE Fulminate of mercury, wet is shipped as a slurry or wet mass of white crystals, it must be shipped wet with at least 25% water or water-ethyl alcohol mixture. If it should dry out. it can explode due to shock, heat flame, or friction. Upon prolonged exposure to fire or heat containers of the wet material will explode. H material on fire or Involved In fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum If materiel not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep spilled material wet Wet spilled material before picking it up Do not attempt to sweep up dry material Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation if the material is on fire or involved in fire evacuate for a radius of 5000 feet INITIATING EXPLOSIVE (GUANYL NITROSAMINO 4901435 GUANYLIDENE HYDRAZINE) CLASS A EXPLOSIVE Guanyl nitrosamino guanyiidene hydrazine is a colorless to pale yeilow fluffy crystalline solid. It must be shipped wet with at least 30% water or water and denatured ethyl alcohol mixture. Dry it will detonate due to shock, heat, flame, or friction. Containers of the wet material can explode on prolonged exposure to fire or heat. If material on fire or Involved In fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep spilled material wet Wet spilled material before picking it up Do not attempt to sweep up dry material Personnel protection Avoid breathing dusts, and fumes from burning material Wear protective gloves and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet INITIATING EXPLOSIVE (LEAD AZIDE, DEXTRINATED 4901440 TYPE ONLY) CLASS A EXPLOSIVE Lead azide is shipped as a wet slurry or mass of colorless crystals. It must be shipped wet with at least 20% water or water and denatured ethyl alcohol mixture. If it should dry out, it may explode or detonate due to shock, heat, flame or friction, under prolonged exposure to fire or heat containers of the wet material will explode. If material on fire or Involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and iet bum If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep spilled material wet Wet spilled material before picking it up Do not attempt to sweep up dry material Personnel protection Avoid breathing dusts, and fumes from burning material Wear protective gloves and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet INITIATING EXPLOSIVE (LEAD 4901445 MONONITRORESORCINATE) CLASS A EXPLOSIVE Lead mononitroresorcinate is shipped as a slurry or wet mass of reddish-brown crystals. It must be shipped wet with at least 40% water or water and denatured alcohol mixture. If it should dry out, it can explode due to shock, heat, flame, or friction. Upon prolonged exposure to fire or heat containers of the wet material will explode. Continued on next page April 1961 MOD 000017214 287 tf material on fire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep spilled material wet Wet spilled material before picking it up Do not attempt to sweep up dry material Personnel protection Avoid breathing dusts, and fumes from burning material Wear protective gloves and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts ot water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation It the material is on fire or involved in fire evacuate for a radius of 5000 feet INITIATING EXPLOSIVE (LEAD STYPHNATE)(LEAD 4901450 TRINITRORESORCINATE) CLASS A EXPLOSIVE Lead styphnate is shipped as slurry or wet mass of orange-yellow crystals. It must be shipped wet with at least 20% water or water and denatured ethyl alcohol mixture. If it should dry out. it can explode due to shock, heat, flame or friction. Upon prolonged exposure to fire or heat containers of the wet material will explode. If material on fire or Involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep spilled material wet Wet spilled material before picking it up Oo not attempt to sweep up dry material Peraonnel protection Avoid breathing dusts, and fumes from burning material Wear protective gloves and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet INITIATING EXPLOSIVE (NITROSOGUANIDINE) 4901460 CLASS A EXPLOSIVE Nitrosoguanidine is shipped as a slurry or wet mass of pale yellow crystals. It must be shipped wet with at least 10% water. If it should dry out it can explode due to shock, heat, flame, or friction. Upon prolonged exposure to fire or heat containers of the wet material will explode. If material on fire or Involved in fire Dangerously explosive Do not tight tires in a cargo of explosives Evacuate area and let bum II material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep spilled material wet Wet spilled material before picking it up Do not attempt to sweep up dry material Personnel protection Avoid breathing dusts, and fumes from burning material Wear protective gloves and goggles Do not handle broken packages without protective equipment 286 Wash away any material which may have contacted the body witt copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires Involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet INITIATING EXPLOSIVE (PENTAERYTHRITE 4901465 TETRANITRATE) CLASS A EXPLOSIVE Pentaerythrite tetranitrate is shipped as a slurry or wet mass of white crystals. It must be shipped wet with at least 40% water or water and denatured alcohol mixture. If it should dry out, it can explode due to shock, heat, flame or friction. Upon prolonged exposure to fire or heat containers of the wet material will explode. If material on fire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep spilled material wet Wet spilled material before picking it up Do not attempt to sweep up dry material Personnel protection Avoid breathing dusts, and fumes from burning material Wear protective gloves and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet INITIATING EXPLOSIVE (TETRAZENE) (GUANYL 4901470 NITROSOAMINO GUANYL TETRAZENE CLASS A EXPLOSIVE Tetrazene is shipped as a slurry or wet mass of light yellow fluffy solid. It must be shipped wet with at least 30% water or water and denatured alcohol mixture, if it should dry out it can explode due to shock heat, flame, or friction. Upon prolonged exposure to tire or heat containers of the wet material will explode. If material on fire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep spilled material wet Wet spilled material before picking it up Do not attempt to sweep up dry material Peraonnel protection Avoid breathing dusts, and fumes from burning material Wear protective gloves and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in (ire evacuate for a radius of 5000 feet April 1981 MOD O00017215 INITIATING EXPLOSIVES (NITRO MANNITE) 4901455 CLASS A EXPLOSIVE Nitro mannite is shipped as a slurry or wet mass of colorless crystals. It must be shipped wet with at least 40% water or water and denatured alcohol mixture. If it should dry out. it can explode due to shock, heat, flame, or friction. Upon prolonged exposure to fire or heat containers of the wet material will explode. If material on fire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep spilied material wet Wet spilled material before picking it up Do not attempt to sweep up dry material Personnel protection Avoid breathing dusts, and fumes from burning material Wear protective gloves and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet INK (INK MATERIALS, NEC) 4915206 COMBUSTIBLE LIQUID NA1993 Ink materials, nec may contain a flammable solvent. Its flash point is between 100 and 199 deg. F. The hazard is combustibility. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water INK (INK, PRINTING, NEC) 4910205 FLAMMABLE LIQUID UN1210 Ink, printing, nec is various colored liquids or fluid pastes. It has a flash point of less than 100 deg. F. It is generally lighter than water and insoluble in water. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical April 1981 If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water INK MATERIALS, NEC (FLAMMABLE LIQUID, N.O.S.) 4910206 FLAMMABLE LIQUID UN1993 Ink materials, nec may contain a flammable solvent. Its flash point is less man 100 deg. F. The hazard is flammability. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water INK, PRINTING, NEC (INK) 4915205 COMBUSTIBLE LIQUID UN2867 Ink, printing, nec is various colored liquids, fluids, or pastes. It has a flashpoint between 100 and 199 deg. F. It is generally lighter than water and insoluble in water. Its vapors are heavier than air. ft material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 289 MCD 000017216 INSECTICIDE ADHESIVES. LIQUID (ADHESIVE, N.O.S.) 4915S02 COMBUSTIBLE LIQUID NA1133 Insecticide adhesives, liquid are the solutions of various gums and resins in various solvents. The liquids are generally quite thick and range from a clear colorless to a black "tar". The flash point depends on the solvent used, but it will be between 100 and 199 deg. F. The hazard of this material is combustibility. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water INSECTICIDE ADHESIVES, LIQUID (ADHESIVES, 4910S02 N.O.S.) FLAMMABLE LIQUID NA1133 Insecticide adhesives, liquid are the solutions of various gums and resins in various solvents. The liquids are generally quite thick and range from a clear colorless to a black "tar". The flash point depends on the solvent used. But it will be below 100 deg. F. The hazard of this material is flammability. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water INSECTICIDE ADHESIVES, SPREAOERS OR 4936594 STICKERS, LIQUID (CORROSIVE LIQUID, N.O.S.) CORROSIVE MATERIAL UN1760 insecticide adhesives, spreaders or stickers, liquid are various colored liquids having the property of being corrosive to metals and/or tissue. It may be combustible though requiring some effort to ignite. It may or may not be water soluble. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical 290 If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing INSECTICIDE, DRY, N.O.S. (AGRICULTURAL 4921435 INSECTICIDES OR FUNGICIDES, NEC, OTHER THAN LIQUID) POISON B NA2588 insecticide, dry is a material which have the property of being toxic by ingestion, inhalation or skin absorption. Contact the pesticide safety team network. Telephone; 800-424-9300 If material on fire or Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing INSECTICIDE, DRY, N.O.S. (INSECTICIDES. INSECT 4921434 OR ANIMAL REPELLENTS OR VERMIN EXTERMINATORS, NEC, OTHER THAN AGRICULTURAL) POISON B NA25BB Insecticide, dry, n.o.s. is a material which have the property of being toxic by ingestion, inhalation or skin absorption. H material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material April 1981 MOD '7017217 INSECTICIDE. LIQUEFIED GAS 4904830 NONFLAMMABLE GAS NA1968 Insecticide, liquefied gas are nonflammable formulations using a liq uefied nonflammable gas as a propellant to disperse the material. While the material doesn't meet dot poison definitions prolonged breathing of the fumes should be avoided. It may only be shipped in cylinders or aerosol containers. Exposure of the aerosol containers to fire or heat can result in their rupturing and rocketing. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Cooi all affected containers with flooding quantities of water Apply water from as far a distance as possible Use water spray to absorb vapors If material not involved in fire Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water INSECTICIDE, LIQUID, N.O.S. 4910210 FLAMMABLE LIQUID NA1993 Insecticide, liquid is the proper shipping name for those materials having closed cup flash point of less than 100 deg. F. and not specifically mentionned in the hazardous materials regulations. Prolonged exposure to the vapors or contact with the liquid may result in death through inhalation or stun absorption, though the main hazard is flammability. ft material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material INSECTICIDE, LIQUID, N.O.S. 4915210 COMBUSTIBLE LIQUID NA1993 Insecticide, liquid is the proper shipping name for those materials having a closed cup flash point between 100 and 199 deg. F. and not specifically mentioned in the hazardous materials regulations. Prolonged exposure to the vapors or contact with the liquid may result in death through inhalation or skin absorption, though the main hazard is combustibility. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog April 1981 Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water INSECTICIDE. LIQUID, N.O.S. (AGRICULTURAL 4921436 INSECTICIDES OR FUNGICIDES, NEC, LIQUID) POISON B NA2902 Insecticide, liquid, n.o.s. is a liquid material which has the property of being toxic by ingestion, inhalation, or skin absorption, (n case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300 (f material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in tire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water INSECTICIDE, LIQUID, N.O.S. (INSECTICIDES OR 4910197 FUNGICIDES, AGRICULTURAL, NEC, LIQUID) FLAMMABLE LIQUID NA1993 Insecticide liquid, n.o.s. is the proper name for those materials having a closed cup flash point of less than 100 deg. F. and not specifically mentioned in the hazardous materials regulations. Although the main hazard is flammability, prolonged exposure to the vapors or contact with the liquid may result in death thruogh inhalation or skin absorption, in case of damage to or leaking from containers of this material, contact the pesticide safety team network. Telephone 800-424-9300. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of wafer may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Continued on next page 291 VoD If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material INSECTICIDE, LIQUID. N.O.S. (INSECTICIDES OR 4915197 FUNGICIDES, AGRICULTURAL, NEC, LIQUID) COMBUSTIBLE LIQUID NA1993 Insecticide liquid n.o.s-, is the proper shipping name for those ma terials having a closed cup flash point between 100 and 200 deg.f and not specifically mentioned in the hazardous materials regulations. Pro longed exposure to the vapors or contact with the liquid may result in illness or death through inhalation or skin absorption though the main hazard is combustibility. In case of damage to or leakage from containers of this material, contact the pesticide safety team network. Telephone 800-424-9300. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material INSECTICIDE, LIQUIEFIED GAS, CONTAINING POISON 4920550 A MATERIAL OR POISON B MATERIAL POISON A NA1967 Insecticide, liquefied gas, containing poison a material or poison b material are formulations using a liquefied gas as a propellant to disperse the poison a or b material. It may only be shipped in cylinders which may have to be overpacked in wooden or metal containers. Prolonged exposure of the cylinders to fire or heat may result in the violent rupturing and rocketing of the cylinders. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300 If material involved in fire Do not extinguish fire unless flow can be stopped Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use `alcohol" foam, carbon dioxide or dry chemical 292 If material not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered INSTANTANEOUS FUSE 4903470 CLASS C EXPLOSIVE Instantaneous fuse is cotton yarn impregnated with a finely-powdered deflagrating composition. It is overspun with tape and yam. and is used to ignite multiple lengths of safety fuse from a common point. If material on fire or involved in fire Flood with water Apply water from as far a distance as possible If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material IODINE MONOCHLORIDE 4932345 CORROSIVE MATERIAL UNI 792 Iodine monochloride is a reddish brown oily liquid becoming a solid at 81 deg. F. It has a pungent odor. It is decomposed by water into iodine, iodic acid and hydrochloric acid with release of heat. It is corrosive to metals and tissue. If material involved in fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Coot alf affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing April 1981 MOD oOOOi'7 9 IODINE PENTAFLUORIDE OXIDIZER, POISONOUS, CORROSIVE 4918215 UN2495 Iodine pentafiuoride is a colorless fuming liquid. It is decomposed by water to iodine and hydrofluoric acid. Contact with organic materials may result in spontaneous ignition. It is corrosive to metals and tissue. It may only be shipped in cylinders not equipped with safety relief de vices. Prolonged exposure of the cylinder to fire may result in their violent rupturing and rocketing, if material involved In fire Do not use water on material itself Use dry chemical or carbon dioxide Cool all affected containers with flooding quantities of water If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors if material not involved in fire Keep material out of water sources and sewers Do not use water on material itself Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet if material leaking (not on fire), downwind evacuation must be considered IRON CHLORIDE, SOLID (See FERRIC CHLORIDE, SOLID 4944138) IRON SESQUICHLORIDE, SOLIO (See FERRIC CHLORIDE, SOUD 4944138) IRON SULPHATE (FERRIC), DRV, CRUDE (FERRIC 4963823 SULFATE) ORM-E NA9121 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-1000/454) Iron sulphate (ferric), dry, crude is a yellow crystalline to greyish white powder. It is used in water purification, as a soil conditioner, and for many other uses. It is slightly soluble in water. It is non-combustible. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) tf material not Involved In fire Keep material out ol water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates IRON MASS OR SPONGE (NOT PROPERLY OXIDIZED) 4916717 FLAMMABLE SOLID NA1383 Iron mass or sponge (not properly oxidized) is finely divided iron oxide on a wood shavings base. If the iron is not completely oxidized the iron sponge is liable to spontaneous heating as the remaining iron is oxidized. The heat from the oxidation may be sufficient to ignite the material. Iron sponge is fairly easily ignited by sparks or heat from external sources. If material on fire or involved in fire Flood with water If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles IRON MASS, (OR) SPONGE, SPENT (IRON SPONGE, 4916718 SPENT, OR SPENT OXIDE) FLAMMABLE SOLID UNI 376 Iron mass (or) sponge, spent is iron sponge saturated with sulfur from gas purification. It is quite liable to spontaneous heating. This heat may be sufficient to ignite the iron mass. It is also fairly easily ignited by sparks or heat from external sources. If material on fire or involved in fire Flood with water If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles April 1981 IRON SULPHATE (FERRIC), DRY, OTHER THAN 4963816 CRUDE (FERRIC SULFATE) ORM-E NA9121 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Ferric sulphate is a yellow crystalline or greyish white powder. It is used in water purification, as a soil conditioner, as a disenfectant, and for many other uses. It is soluble in water. It is non-combustible. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) H material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land apiil Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates 293 MCD 0000 1 '220 IRON, POWDERED, NEC (FLAMMABLE SOLID, N.O.S.) 4916769 FLAMMABLE SOLID UNI 325 iron, powdered, nec is a grey lustrous powder, it is used in powder metallurgy, and as a catalyst in chemical manufacture. It may react with water to give off hydrogen, a flammable gas. The heat from this reaction may be sufficient to ignite the hydrogen. If material on fire or involved in fire Use water only if flooding Quantities are available Use graphite, soda ash. powdered sodium chloride, or suitable dry powder If material not on fire and not involved in fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles IRRITATING AGENT. N.O.S. 4925630 IRRITATING MATERIAL NA1693 Irritating agent, n.o.s. is the proper shipping name for those materials not specifically mentioned in the regulations having the property of giving fumes that are extremely irritating to the eyes and mucous membranes when exposed to air, or contact with fire. Try to ascertain the exact material. If material on fire or Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water if contact with the material anticipated, wear full protective clothing ISO HEPTYL ALCOHOL (ALCOHOL, N.O.S.) 4913122 COMBUSTIBLE LIQUID UN1987 Iso heptyl alcohol is a clear colorless liquid with a pleasant odor. It is used to make other chemicals, as a solvent, and in cosmetic for mulations. It has a flash point of 106 deg. F. It is liqhter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use 'alcohol'1 foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors 294 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ISOAMYL ALCOHOL (ALCOHOL, N.O.S.) 4913127 COMBUSTIBLE LIQUID UN19B7 Isoamyl alcohoi is a clear colorless liquid with a disagreeable odor. It has a flash point of 114 deg. F. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire end not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ISOBUTANE 4905747 FLAMMABLE GAS UNI 075 Isobutane is a colorless gas with a faint petroleum like odor. It is shipped as a liquefied gas under its vapor pressure. Contact with the liquid can cause frostbite. It is easily ignited. Its vapor is heavier than air and a flame can flash back to the source of leak very easily. The leak can either be a liquid or vapor leak. It can asphyxiate by the dis placement of air. Under fire conditions the cylinders or tank car may violently rupture and rocket. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation if fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered April 1961 mod 000 V' ISOBUTANE (ISOBUTANE FOR FURTHER REFINERY 4905750 PROCESSING) FLAMMABLE GAS UN1075 Isobutane is a colorless gas with a faint petroleum like odor. It is used as an aerosol propellant, to make other chemicals, and for many other uses it is shipped as a liquefied gas under its vapor pressure. Contact with the liquid can cause frostbite. It is easily ignited. Its vapors are heavier than air and a flame can flash back to the source of leak very easily. The leak can be either a liquid or vapor leak. It can asphyxiate by the displacement of air. Under fire conditions the cylinders or tank cars may rupture and rocket, if material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered ISOBUTYL ACETATE 4909207 FLAMMABLE LIQUID UNI 213 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Isobutyl acetate is a clear colorless liquid with a fruity odor. It has a flash point of 64 deg.f. It is lighter than water and insoluble in water. Its vapors are heavier than air. It weighs 7.2 pounds per gallon. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical tf material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Apply fluorocarbon-water foam to diminish vapor and fire hazard Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e.g. detergent, soaps, alcohols) to com press and thicken spilled material April 1981 Mor, ( Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors ISOBUTYL ALCOHOL (BUTYL ALCOHOL) 4909131 FLAMMABLE LIQUID NA1120 Isobutyl alcohol is a clear colorless liquid. It has a flash point of 82 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. tf material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ISOBUTYLACRYLATE (FLAMMABLE LIQUID, N.O.S.) 4907263 FLAMMABLE LIQUID UN1993 POLYMERIZABLE Isobutyl acrylate is a clear colorless liquid with an acrid odor. It has a flash point of 86 deg. F. The vapors are irritating to the eyes and respiratory system, If the material is subjected to heat for prolonged periods or becomes contaminated, it is subject to polymerization, if the polymerization takes place inside a container, the container may violently rupture. The material is lighter than water and slightly soluble in water. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do rot handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered 295 ?2.2r> ISOBUTYLAMINE 4908166 FLAMMABLE LIQUID UN1214 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Isobutylamine is a clear colorless liquid with a fish tike odor. It has a flash point of 15 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material. It weighs 6.1 pounds per gallon. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash, cement powder, sawdust, or com mercial sorbents Apply fluorocarbon-water foam to diminish vapor and fire hazard Neutralize with sodium bisulfate (nahso4) Environmental considerations--water spill Add sodium bisulfate If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible tf material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered ISOBUTYRALDEHYDE (FLAMMABLE LIQUID, N.O.S.) 4906185 FLAMMABLE LIQUID UN1993 isobutyraldehyde is a clear colorless liquid having a pungent odor. It is used to make other chemicals, it has a flash point of -40 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray lo knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered ISOBUTYLENE 4905748 FLAMMABLE GAS UN1075 Isobutylene is a colorless gas with a faint petroleum like odor. For transportation it may be stenched. It is shipped as a liquefied gas under its vapor pressure. Contact with the liquid can cause frostbite. It is easily ignited. Its vapors are heavier than air and a flame can flash back to the source of leak very easily. The leak can either be in liquid or vapor leak, it can asphyxiate by the displacement of air. Under fire conditions the cylinder or tank car may violently rupture and rocket. 296 ISOBUTYRIC ACID 4931438 CORROSIVE MATERIAL, ACIDIC, COMBUSTIBLE UN2529 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Isobutyric acid is a colorless liquid with a light odor of rancid butter. It is combustible and has a flash point of 132 deg. F. It is soluble in water. It is corrosive to metals and tissue. It weighs 7.9 pounds per gallon. April 1981 2 ?223 If malarial on fire or Involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment ISOBUTYRIC ANHYDRIDE 4931439 CORROSIVE MATERIAL, ACIDIC, COMBUSTIBLE UN2530 Isobutyric anhydride is a colorless liquid. It is combustible and has a flash point of 139 deg. F. It is decomposed by water to isobutyric acid, which is water soluble with release of heat. It is corrosive to metals and skin. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing April 1981 ISOBUTYRONITRILE (FLAMMABLE LIQUID, N.O.S.) 4909208 FLAMMABLE LIQUID UN1993 Isobutyronitrile is a clear colorless liquid. It has a flash point of 47 deg. F. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing ISONONANYL PEROXIDE, (TECHNICALLY PURE)(OR) 4919174 ISONONANYL PEROXIDE. (IN SOLUTION) ORGANIC PEROXIDE UN212B Isononanyl peroxide, (technically pure or) isononanyl peroxide, (in solution) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite: but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible ma terials. spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of combustible materials. Under prolonged ex posure to fire or heat containers of the material may explode. If material on fire or Involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet 297 00017224 mod oc ISOOCTANE 4908188 FLAMMABLE LIQUID UNI 262 isooctane is a clear colorless liquid having a petroleum like odor. It has a flash point of 10 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. if material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered ISOOCTENE 4908189 FLAMMABLE LIQUID UN1216 Isooctene is a clear colorless liquid having a petroleum-like odor. It has a flash point of less than 20 deg. F. It is lighter than water and insoluble in water. Its vapors are lighter than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet if material leaking (not on fire), downwind evacuation must be considered 298 ISOOCTYL ALCOHOL, OTHER THAN PERFUMERY 4913128 GRADE (ALCOHOL, N.O.S.) COMBUSTIBLE LIQUID UN1987 Isooctyl alcohol, other than perfumery grade, is a clear colorless liquid with a faint pleasant odor. It is used as a solvent, in the making of cutting and lubricating oils, in hydraulic fluids, and in the production of other chemicals. It has a flash point of ISO deg.f. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ISOOCTYL ALCOHOL, PERFUMERY GRADE 4913129 (ALCOHOL, N.O.S.) COMBUSTIBLE LIQUID UNI 987 Isooctyl alcohol, perfumery grade is a clear colorless liquid with a faint pleasant odor. It is used as an ingredient of cosmetics. It has flash point of ISO deg.f. It is lighter than water and in soluble in water. Its vapors are heavier than air If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Soiid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ISOPENTANE 1908192 FLAMMABLE LIQUID UN1265 Isopentane is a clear colorless liquid having a petroleum like odor. It has a flash point of -70 deg. F. a boiling point of 82 deg. F. It is lighter than water and insoluble in water, its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Soiid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical April 1981 MOD i.)00017 22d ff material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet if material leaking (not on fire), downwind evacuation must be considered ISOPENTANOIC ACID 4931440 CORROSIVE MATERIAL NA1760 Isopentanoic acid is a colorless liquid with a penetrating odor. It is slightly soluble in water. It is corrosive to metals and to tissue, if material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use `'alcohol'' foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled matenal with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing ISOPRENE 4907230 FLAMMABLE LIQUID UN1218 POLYMERIZABLE ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Isoprene is a clear colorless liquid with a petroleum-like odor. It has a flash point of -65 deg. F. and a boiling point of 93 deg. F. If it becomes contaminated or is subjected to heat, isoprene may polymerize. If the polymerization take place in a container, the container is subject to violent rupture. It is lighter than water and insoluble in water. Its vapors are heavier than air. It weighs 5.7 pounds per gallon. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical April 1981 If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain iiquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash. cement powder, sawdust, or com mercial sorbents Apply "universal" gelling agent to immobilize spill Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e.g. detergent, soaps, alcohols) to com press and thicken spilled matenal Inject "universal'' gelling agent to solidify encircled spill and increase effectiveness of booms Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors ISOPROPANOL 4909205 FLAMMABLE LIQUID UN1219 Isopropanol is a clear colorless iiquid with a medicinal odor. It it used to make other chemicals, as a solvent, in pharmaceuticals (rubbing alcohol), and for many other uses. It has a flash point of 53 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. H material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical H material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 299 MOD ISOPROPANOL AND METHANOL MIXTURE 4909206 (ALCOHOL, N.O.S.) FLAMMABLE LIQUID UN1987 Isopropanol and methanol mixture is a clear colorless liquid. It has a flash point of 52-55 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ISOPROPANOLAMINE 4965359 DODECYLBENZENESULFONATE ORM-E NA9127 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Isopropanolamine dodecylbenzenesulfonate is a while to light yellow granular solid. It is used as a detergent. It is soluble in water. It will bum though it may require some effort to ignite, tf material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill tf dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates ISOPROPY NITRATE 4907035 FLAMMABLE LIQUID UN1222 THERMALLY UNSTABLE Isopropyl nitrate is a clear colorless liquid with a pleasant odor, it has a flash point between 32 and 73 deg. F. Prolonged exposure of the material to heat may result in the spontaneous decomposition of the material and this decomposition may reach explosive violence. Pro* longed exposure of the containers of the material to fire or heat may result in the violent rupturing of the containers due to the decomposition of the material. It is heavier than water and insoluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during com bustion of this material. 300 Mr <' f If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered ISOPROPYL ACETATE 4909210 FLAMMABLE LIOUIO UN1220 Isopropyl acetate is a clear colorless liquid. U has a flash point of 40 deg. F. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. tf material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water ISOPROPYL ACID PHOSPHATE, SOLID CORROSIVE MATERIAL, ACIDIC 4933335 UN1793 Isopropyl acid phosphate is a white crystalline solid. It is corrosive to metals and tissue. If material on fire or involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible ff material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Neutralize spilled material with crushed limestone, soda ash, or iim< April 1981 Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when lighting fires involv ing this material If contact with the material anticipated, wear full protective clothing ISOPROPYL MERCAPTAN 4908205 FLAMMABLE LIQUID UN2703 Isopropyl mercaptan is a colorless liquid having a very strong disa greeable odor. It has a flash point of-30 deg. F. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered ISOPROPYL PERCARBONATE, STABILIZED 4919550 ORGANIC PEROXIDE NA2134 Isopropyl percarbonate is a white granular solid. It must be shipped in refrigerated containers by private or contract motor carriage. It is insoluble in water. Spontaneous decomposition at room temperature releases flammable and corrosive products. It will accelerate the burning of combustible materials. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet ISOPROPYL PERCARBONATE, UNSTABILIZED 4919551 ORGANIC PEROXIDE NA2133 Isopropyl percarbonate, unstabilized is a white crystalline or granular solid. It must be shipped in refrigerated containers by private or contract motor carriage. It is insoluble in water. Spontaneous decomposition at room temperature releases flammable and corrosive products. It will accelerate the burning of combustible materials. If material on fire or Involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet ISOPROPYL PEROXYDICARBONATE, (NOT MORE 4919176 THAN 52% IN SOLUTION) ORGANIC PEROXIDE UN2134 Isopropyl peroxydicarbonate. (not more than 52% in solution) is a colorless to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite; but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burn ing of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in Hooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive Continued on next page April 1981 301 ooooV'f' >9.6 If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet ISOPROPYL PEROXYDICARBONATE, (TECHNICALLY 4919175 PURE) ORGANIC PEROXIDE UN2133 Isopropyl peroxydicarbonate, (technically pure) is a white solid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. It is easily ignited and burns with increasing rapidity as the fire pro gresses. It can form explosive mixtures with finely divided combustible materials. It supports the burning of combustible materials. Under pro longed exposure to fire or heat containers of the material may explode. If material on fire or Involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is or fire or involved in fire evacuate for a radius of 2500 feet ISOPROPYLAMINE 4908194 FLAMMABLE LIQUIDS UN1221 Isopropylamine is a clear colorless liquid with an ammonia-like odor. It is used as a solvent and to make other chemicals. It has a flash point of -35 deg. F. and a boiling point of 90 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during the combustion of the material. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective 302 Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of wafer sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered ISOPROPYLTOLUENE (COMBUSTIBLE LIQUID, 4913147 N.O.S.) COMBUSTIBLE LIQUID NA1993 Isopropyltoluene is a clear colorless liquid with an aromatic odor, It has a flash point of 117 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Coot all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water JET THRUST UNIT (JATO) 4902510 CLASS B EXPLOSIVE Jet thrust unit (jato) is a metal cylinder containing a mixture of chem icals capable of burning rapidly. They are used to furnish auxiliary thrust in the launching of aircraft, missiles etc. The usual (jato) units contain solid propellant although units based on liquid propellants are also used. Under prolonged exposure to heat or fire these units may explode. If material on fire or Involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away April 1981 Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate tor a radius of 2500 feet JET THRUST UNIT (JATO) 4901340 CLASS A EXPLOSIVE Jet thrust unit (jato) consists of a metal cylinder containing propellant explosive capable of burning rapidly and producing considerable pres sure. These units are designed to be ignited by an electric igniter. II material on fire or involved In fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let bum If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet KELTHANE (AGRICULTURAL INSECTICIDES, NEC, 4966940 OTHER THAN LIQUID) ORM-E NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Kelthane is a white crystalline solid, it is used as a pesticide. It is a wettable powder. It can cause illness by inhalation, skin absorption and/ or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424- 9300. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or soiid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates KELTHANE (AGRICULTURAL INSECTICIDES, NEC, 4966930 LIQUID) ORM-E NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Kelthane is a white crystalline solid dissolved in a liquid carrier. It is used as a pesticide. The carrier is water emulsifiable. it can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates April 1981 KELTHANE (INSECTICIDES, OTHER THAN 4966920 AGRICULTURAL, NEC) ORM-E NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Kelthane is a white crystalline solid or the solid dissolved on a liquid carrier. It is used as a pesticide. It is a wettable powder or water emul sifiable liquid. It can cause illness by inhalation, skin absorption and/or ingestion, in case of damage to. or leaking from containers of this ma terial contact the pesticide safety team network. Telephone; 600-424- 9300. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or soiid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates tintj Or 303 -JQ KEPONE 4960140 ORM-E NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.4S4) Kepone is a white solid. It is used as a pesticide. It is a wettable powder or water emulsifiable liquid. It can cause iilness by inhalation, skin absorption and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300. If material involved in fire Extinguish fire using agent suitable for type Of surrounding fire (Material itself does not bum or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants ana precipitates KEROSENE 4915171 COMBUSTIBLE LIQUID UN1223 Kerosene is a clear colorless to light amber liquid with a petroleum odor. It has a flash point of 100 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water KITS, PNEUMATIC TIRE CLEANING, AUTO 4910484 (FLAMMABLE LIQUID, N.O.S.) FLAMMABLE LIQUID UN1993 Kits, pneumatic tire cleaning, auto is a material containing a solvent having a closed cup flash point of less than 100 deg. F. The hazard of this material is flammability. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, fiames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water LACQUER BASE DRY 4917323 FLAMMABLE SOLID NA2557 Lacquer base dry is the solid material used in making lacquers (paint). Because the material contains nirocellulose. it is very flammable and easily ignited. Toxic oxides of nitrogen are produced during combustion. If material on fire or involved in fire Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Wear self-contained breathing apparatus when fighting fires involv ing this material KITS, PNEUMATIC TIRE CLEANING, AUTO 4915484 (COMBUSTIBLE LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Kits, pneumatic tire cleaning, auto is a material containing a solvent having a closed cup flash point between 100 and 199 deg. F. The hazard of this material is combustibility. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water 304 LACQUER BASE OR LACQUER CHIPS, PLASTIC 4910217 (WET WITH ALCOHOL OR SOLVENT) FLAMMABLE LIQUID NA1263 Lacquer base or lacquer chips, plastic contain a flammable solvent. Its flash point is 100 deg. F. or lower. The hazard is flammability. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical April 1981 MOD oucorv23i It material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water LACQUER CHIPS, DRY 4917324 FLAMMABLE SOLID NA2S57 Lacquer chips, dry is the solid material used in making lacquers (paint). Because the material contains nitrocellulose it is very flammable and easily ignited. Toxic oxides of nitrogen are produced during combustion. If material on fire or involved in fire Use water in flooding quantities as fog Use `'alcohol" foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water If material not on tire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Wear self-contained breathing apparatus when fighting fires involv ing this material LACQUER THINNING COMPOUNDS, USED 4910486 (COMPOUND, LACQUER. THINNING) FLAMMABLE LIQUID NA1142 Lacquer thinning compounds used are generally clear colorless liq uids. The flash point is below 100 deg. F. Most of these compounds are lighter than water and only partially soluble in water, Their vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water LACQUER THINNING COMPOUNDS, USED 4915486 (COMPOUND. LACQUER, THINNING) COMBUSTIBLE LIQUID NA1142 Lacquer thinning compounds used are generally clear colorless liq uids. The flash point is between 100 and 199 deg. F. Most of these compounds are lighter than water and only partially soluble in water. Their vapors are heavier than air. April 1981 If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water LACTIC ACID (HYDROXYPROPIONiC ACID) (ACID, 4931757 LIQUID, N.O.S.) CORROSIVE MATERIAL, ACIDIC, COMBUSTIBLE NA1760 Lactic acid is a colorless to yellow syrupy liquid and is odorless. It is used to make cultured dairy products, as a food preservative, and to make chemicals. It is soluble in water, it is corrosive to metals and tissue. If material on fire or Involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors Vapor knockdown water is corrosive or toxic and should be diked for containment Mf'T. OOOO 7 305 LAUHOYL PEROXIDE 4919560 ORGANIC PEROXIDE ON2124 Lauroyl peroxide is a coarse white powder. It is shipped either dry or 30 percent water wet. Dry, the material is easily ignited and burns with increasing rapidity as the fire progresses, though not as vigorously as some other peroxides, Dry or wet it supports the burning of combustible materials. Under prolonged exposure to heat or fire containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing vapors or dusts Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material if contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet LAUROYL PEROXIDE, {NOT MORE THAN 4919167 42%,STABLE DISPERSION, IN WATER) ORGANIC PEROXIDE UN2893 Lauroyl peroxide, (not more than 42%.stable dispersion, in water) is a colorless to pale yellow liquid, it is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite; but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burn ing of combustible materials. Under prolonged exposure to fire or heat containers of the material may explode. if material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet LEAD ACETATE 4966640 ORM-E UN1616 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Lead acetate is a white crystalline solid. It is used to make other lead compounds, in chemical analysis, as an insecticide, and for many other uses. It is soluble in water. It is non-combustible. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates LEAD ARSENATE AND SULPHUR, DRY (LEAD 4923318 ARSENATE, SOLID) POISON B UNI 617 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Lead arsenate and sulphur, dry is a yellow white to yellow powder. It is insoluble in water. It is toxic by inhalation and ingestion. Lead arsenate and sulphur, dry (lead arsenate, solid) na2020 If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Use loam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in ram or fire fighting water 306 MOD of >0017233 April 1981 Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Add ferric chloride (fecl3) Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates LEAD ARSENATE, SOLID 492323S POISON B UN1617 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Lead arsenate, solid is a white powder. It is insoluble in water. It is toxic by skin absorption, inhalation (dust) and by ingestion. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved In fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and gaggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Add ferric chloride (fec!3) Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates LEAD ARSENATE. SOLID (LEAD ARSENATE, PASTE) 4923234 POISON B UN1617 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Lead arsenate, paste is the white powder mixed with water to form a thick slurry. It is insoluble in water. The dried material is toxic by skin absorption, inhalation (powder) and by ingestion. If material Involved in fire Extinguish fire using agent suitable tor type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical tf material not Involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing April 1981 Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Add ferric chloride <fecl3) Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates LEAD ARSENITE, SOLIO 4923236 POISON B UN1618 Lead arsenite. solid is a white powder. It is insoluble in water. It is toxic by inhalation (dust) and by ingestion. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not Involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing LEAD BAGHOUSE FLUE DUST (FLUE DUST, 4923361 POISONOUS) POISON B NA2811 Lead baghouse flue dust is a greyish black powder. It is insoluble in water. It is toxic by inhalation (dust, etc.) and by ingestion. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as tog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing LEAD CHLORIDE 4944130 ORM-B NA2291 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Lead chloride is a white crystaline solid. It is used to make other lead compounds and in analytical chemistry. It is insoluble in cold water and is soluble in hot water. It is non-combustible. It is corrosive to aluminum. Continued on next page Men OQr) 1 7p c 307 If material involved in fire Extinguish tire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spilt Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates LEAD CYANIDE 4923447 POISON B UNI 620 Lead cyanide is a white to yellowish powder, it is slightly soluble in water and is gradually decomposed by water and very rapidly decom posed by acids to give off hydrogen cyanide, a flammable poison gas. it is toxic by skin absorption through open wounds, by ingestion, and by inhalation of dusts or hydrogen cyanide decomposition of the matenal. Toxic oxides of nitrogen are produced in fires involving this material, If material involved in fire Extinguish fire using agent suitable for type of surrounding lire (Material itself does not bum or burns with difficulty.) Use foam, carbon dioxide or dry chemical Do not use water on material itself if large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If material not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Use water spray to knock-down vapors Keep material dry Personnel protection Avoid breathing vapors or dusts Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing LEAD FLUE DUST (FLUE DUST, POISONOUS) 4923360 POISON B NA2811 Lead flue dust is a greyish black powder. It is insoluble in water, it is toxic by inhalation (dust, etc.) and by ingestion. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved In fire Keep material out of water sources and sewers 308 Personnel protection Avoid breathing dusts, and fumes from burning materia) Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggtes Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing LEAD FLUOBORATE 4944133 ORM-B NA2291 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Lead fluoborate is a colorless crystalline solid. It is used in matel plating and finishing. It is corrosive to aluminum. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use foam, carbon dioxide or dry chemical Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates LEAD FLUORIDE 4944140 ORM-B NA2811 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Lead fluoride is a white crystalline solid. It is used in electronics and to make optical glasses. It Is insoluble in water. It is non-combustible. It is corrosive to aluminum. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water MCD 00017235 April 1981 Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates LEAD IODIDE 4966950 ORM-E NA2B11 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Lead iodide is a yellow crystalline solid. It is used in printing and photography, to seed clouds and other uses. It is insoluble in water. It is non-combustible. It material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates LEAD NITRATE 4918726 OXIDIZER UNI 469 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-1000/454) Lead nitrate is a white crystalline solid. The material is soluble in water. It is non-combustibie but it will accelerate the burning of com bustible materials. If large quantities of the material are involved in the fire an explosion may result. Prolonged exposure of the material to lire or heat may result in an explosion. Toxic oxides of nitrogen are produced in fires involving this material. If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material April 1981 Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates LEAD PEROXIDE. GROUND, DRY (LEAD PEROXIDE 4918779 OXIDIZER UNI 872 Lead peroxide, ground, dry is a brown granular or powdered material. It is insoluble in water. It is non-combustible but it will accelerate the burning of combustible material. If material involved in fire Flood with water If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water LEAD PEROXIDE, PASTE (LEAD PEROXIDE) 4918780 OXIDIZER UNI 872 Lead peroxide, paste is a brown dough-like material. The usual liquid in the paste is water or acetic acid, it is insoluble in water. Lead peroxide itself is non combustible but it will accelerate the burning of combustible materials. If material involved in fire Flood with water If material not involved in fire Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water LEAD STEARATE 4966960 ORM-E NA2811 ENVIRONMENTALLY HAZARDOUS SU8STANCE (RQ-5000/2270) Lead stearate is a white powder. It is used as a corrosion inhibitor, as a dryer for paints, and for many other uses. It is slightly soluble in water. It will burn though it may take some effort to ignite. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggtes Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Continued on next pege Her, o 1 7,, 309 Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or lire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates LEAD SULFATE, SOLID (CONTAINING MORE THAN 4930237 3% FREE ACID) CORROSIVE MATERIAL, ACIDIC UN1794 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Lead sulfate, solid (containing more than 3% free acid is a white wet looking solid. The lead sulfate itself is insoluble in water. The suifuhc acid is soluble in water. The material is corrosive to metals and tissue. It material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash, cement powder, sawdust, or com mercial sorbents Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors LEAD SULFIDE 4966987 OHM-E NA2291 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Lead sulfide is a silvery metalic crystalline soiid or black powder, it is used to make ceramics, in the electronic industry, and for other uses. It is insoluble in water. It is non-combustible. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) If material not Involved In fire Keep material out of water sources and sewers Build dikes lo contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates LEAD SULPHATE, CRUDE (LEAD SULFATE) 4966970 ORM-E UN1794 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Lead sulphate, crude is a white to grey crystalline solid. Refined it is used to make storage batteries, and as in certain paints as a pigment. It is slightly soluble in water. It is non-combustible. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates LEAD SULPHATE, REFINED (LEAD SULFATE) 4966980 ORM-E UN1794 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Lead sulphate, refined is a white crystalline solid. It is used to make storage batteries and as a pigment in specialized paints. It is slightly soluble in water. It is non-combustible. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear bools, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates LEAD THIOCYANATE 4966356 ORM-E NA2291 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Lead thiocyanate is a white to yellow crystalline solid. It is used to make explosives, safety matches, and in dyeing. It is slightly soluble in water. It is non-combustible. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--(and spiff Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water split Neutralize with agricultural lime (slaked lime), crushed limestone, or sodium bicarbonate If dissolved, apply activated carbon at ten times the spilled amount in region of tOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates LEATHER BLEACH FLAMMABLE LIQUID 4910222 NA1142 Leather bleach is a commercial preparation which may contain a flammable solvent which has a flash point of less than 100 deg. F. The hazard is flammability. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 mc: r,000l7' LEATHER BLEACH 4915222 COMBUSTIBLE LIQUID NA1142 Leather bleach is a commercial preparation which may contain a solvent having a flash point between 100 and 199 deg. F. The hazard is combustibility. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use ``alcohol'' foam, carbon dioxide or dry chemical ff material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water LEATHER DRESSING 4910223 FLAMMABLE LIQUID NA1142 Leather dressing is a commercial preparation which may contain a flammable solvent. In this case the hazard is the flammability of the solvent. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water LEATHER DRESSING 4915223 COMBUSTIBLE LIQUID NA1142 Leather dressing is a commercial preparation which may contain a solvent having a flash point between 100 and 199 deg. F. The hazard Is combustibility. ff material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Continued on next page 311 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water LEWISITE (POISONOUS LIQUID, N.O.S.) 4920517 POISON A NA9035 Lewisite is a colorless liquid with a geranium-like oddr, It is colorless when pure but impurities will have the color ranging from brown to violet. It is toxic by inhalation and skin absorption. Contact with the skin will also cause severe burns. At concentrations below that at which one can detect the material by smelt, it is irritating to the eyes and mucous membranes. It is slowly decomposed by water. It may only be shipped in cylinders. Prolonged exposure of the cylinders to fire or heat may result in the violent rupturing and rocketing of the cylinders. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water irom as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical If material not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered LIGHTER FLUID 4910125 FLAMMABLE LIQUID UN1226 Lighter fluid is a clear colorless liquid with a petroleum like odor. It has a flash point of less than 100 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 312 LIGNITE ASH, URANIUM BEARING (RAOIOACTIVE 4926438 MATERIAL. LOW SPECIFIC ACTIVITY. (OR). LSA, N.O.S.) RADIOACTIVE MATERIAL UN2912 Lignite ash, uranium bearing, is a greyish to light tan colored solid. Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful, whereas film may be damaged by radiation from relatively low concentrations. If material Involved in fire Contact the local, state, or department of energy radiological re sponse team Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Contact the local, state, or department of energy radiological re sponse team Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Keep upwind Avoid breathing fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water LIME SALTS, NEC (CORROSIVE SOLID, N.O.S.) 4935255 CORROSIVE MATERIAL. BASIC UN1759 Lime salts, nec are various calcium containing compounds having the property of being corrosive to either metals and or tissue If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water LINDANE (AGRICULTURAL INSECTICIDES, NEC, 4941151 LIQUID) ORM-A NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RCM/0.454) Lindane is a white to yellow liquid dissolved in a liquid carrier. It is used as a pesticide. It is a water emulsifiable liquid. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary April 1981 MCD 000017 Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Use natural barners or oil spill control booms to limit spill motion If dissolved, apply activated carbon at ten limes the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates LINDANE (AGRICULTURAL INSECTICIDES, NEC, 4941152 OTHER THAN LIQUID) ORM-A NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Lindane is a white to yellow solid. It is used as a pesticide, it is a wettable powder. It can cause illness by inhalation, skin absorption and/ or ingestion, in case of damage to. or leaking from containers of this matenal contact the pesticide safety team network. Telephone; 800-424- 9300. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) If material not involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom Remove trapped matenal with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration LINOANE (INSECTICIDES, OTHER THAN 4941150 AGRICULTURAL, NEC) ORM-A NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Lindane is a white to yellow solid or the solid dissolved in a liquid carrier. It is used as a pesticide. It is a wettable powder or water emul- sifiable liquid, it can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to, or leaking from containers of this ma terial contact the pesticide safety team network. Telephone; 800-424- 9300. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) April 1981 If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration LIQUEFIED NONFLAMMABLE GASES (CHARGED 4904840 WITH NITROGEN. CARBON DIOXIDE, OR AIR) NONFLAMMABLE GAS NA1058 Liquefied nonflammable gases are liquids other than those classified as flammable, corrosive or poisonous which are charged with nitrogen, carbon dioxide, or air for the purpose of expelling the liquid from the container. In the case of aerosols the violent rupture and rocketing of the container is possible if the container is exposed to fire or heat. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved in fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear protective gloves and goggles Do not handle broken packages without protective equipment LIQUEFIED PETROLEUM GAS 4905752 FLAMMABLE GAS UN1075 Liquefied petroleum gas is a colorless gas with a faint petroleum like odor shipped as a liquid under its vapor pressure. For transportation it may be stencried. Contact with the liquid can cause frostbite. It is easily ignited. Its vapor is heavier than air and a flame can flash back to the source of leak very easily. This leak may be either a liquid or vapor leak. It can asphyxiate by the displacement of air. Under lire conditions the cylinders can rupture and rocket. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Coot all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Continued on next page MCD 00017240 313 Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Oo not handle broken packages without protective equipment Approach fire with caution Evacuation W fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered LIQUEFIED PETROLEUM GAS (PINTSCH GAS) 4905780 FLAMMABLE GAS UN1075 Pintsch gas is a colorless gas with a petroleum-like odor. It is shipped as a liquefied gas under its vapor pressure. For transportation it may be stenched. Contact with the liquid can cause frostbite. It is easily ignited. Its vapor is heavier than air and a flame can flash back to the source of leak very easily. This leak can be either a liquid or vapor leak. It can asphyxiate by the displacement of air. Under fire conditions the cylinders or tank cars may violently rupture and rocket. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in Hooding quantities as tog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on tire), downwind evacuation must be considered LIQUORS, ALCOHOLIC, NEC (ALCOHOLIC 4910225 BEVERAGE) FLAMMABLE LIQUID UN1170 Alcoholic liquors are beverages containing alcohol. They have suffi cient alcohol in them for the flash point to be below 100 deg. F. They are about the same density as water and soluble in water. The alcohol vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid 314 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gioves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water LIQUORS, ALCOHOLIC, NEC (ALCOHOLIC 4915225 BEVERAGE) COMBUSTIBLE LIQUID UN1170 Alcoholic liquors are beverages containing alcohol. They have suffi cient alcohol in them tor the flash point to be between 100 and 199 deg. F. They are about the same density as water and soluble in water. The alcohol vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts ol water or soap and water LITHIUM ACETYLIDE-ETHYLENE DIAMINE COMPLEX 4916415 FLAMMABLE SOLIO NA2813 WATER REACTIVE Lithium acetylide-ethylene diamine complex is a crystalline solid. It can absorb moisture from the air and spontaneously heat and ignite. It reacts with water to form lithium hydroxide, a corrosive material, and acetylene, a flammable gas. The heat of this reaction may be sufficient to ignite the acetylene. If material on fire or involved In fire Do not use water Use graphite, soda ash, powdered sodium chloride, or suitable dry powder If material not on fire and not Involved In fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Wear boots, protective gloves, and goggles Oo not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Approach fire with caution Wear self-contained breathing apparatus when fighting fires involv ing this material MOD 000017241 April 1981 LITHIUM ALUMINUM HYDRIDE 4916420 FLAMMABLE SOLID UN1410 WATER REACTIVE Lithium aluminum hydride is a light greyish white powder, it is used to make other chemicals, as a polymerization catalyst, as a hydrogen source, and as a propellant. If spread out over a large flat combustible surface friction may be sufficient to cause ignition. It reacts with water to form lithium hydroxide, a corrosive material, aluminum hydroxide and hydrogen, a flammable gas. The heat of this reaction may be sufficient to ignite the hydrogen. The lithium and aluminum hydroxides are cor rosive. It may react violently with heat or oxidizing materials. If material on fire or Involved In fire Do not use water Use graphite, soda ash. powdered sodium chloride, or suitable dry powder H material not on fire and not involved In fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Do not attempt to sweep up dry material Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water LITHIUM ALUMINUM HYDRIDE, ETHEREAL 4908215 FLAMMABLE LIQUID UNI 411 Lithium aluminum hydride, ethereal is the solution of lithium aluminum hydride in an ether solvent, it is used to make other chemicals, and as a catalyst in making plastics. It has a flash point of less than 20 deg. F. It reacts with water giving off hydrogen, a flammable gas. The heat of this reaction may be sufficient to ignite the hydrogen. It can react violently if in contact with oxidizers. If the solvent evaporates the solid remaining is a white powder. If subject to very light friction, a fire is very likely to result. The solvent vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Do not use water Use "alcohol" foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Do not use water Do not attempt to sweep up dry material Personnel protection Avoid breathing fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered April 1981 *<5> , '>0.Oo2? LITHIUM AMIDE, POWDERED 4916722 FLAMMABLE SOLID UNI 412 Lithium amide is a white to greyish crystalline solid with an ammonia like odor, it is used to make other chemicals. It reacts with water to form lithium hydroxide a corrosive material, and ammonia, a nonflammable gas. (he heat from this decomposition may be sufficient to ignite sur rounding combustible materials. If material on fire or involved in fire Do not use water Use graphite, soda ash or powdered sodium chloride If material not on fire and not involved in fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing LITHIUM BOROHYDRIDE 4916421 FLAMMABLE SOLID UN1413 WATER REACTIVE Lithium borohydride is a white to greyish crystalline powder. If is de composed by water to form lithium hydroxide, a corrosive material, and hydrogen, a flammable gas. The heat of this reaction may be sufficient to ignite the hydrogen. The material itself is easily ignited and burns vigorously once ignited. If material on fire or Involved In fire Do not use water Use graphite, soda ash, powdered sodium chloride, or suitable dry powder If material not on fire and not involved in fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Do not attempt to sweep up dry material Personnel protection Avoid breathing dusts, and fumes from burning matenal Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water LITHIUM CHROMATE 4963720 ORM-E NA9134 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Lithium chromate is a yellow crystalline solid. It is used as a corrosion inhibtor and in the manufacture of other chemicals. It is soluble in water. It is non-combustible. tf material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Continued on next page 315 Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, tagoon. holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with agricultural lime (slaked lime), crushed limestone. or sodium bicarbonate Add soda ash Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates LITHIUM FERRO SILICON 4916422 FLAMMABLE SOLID UN2830 WATER REACTIVE Lithium ferro silicon is in the form of crystalline metallic lumps or powder. It reacts with water to form lithium hydroxide, a corrosive ma terial and hydrogen, a flammable gas. The heat of the reaction may be sufficient to ignite the hydrogen. If material on fire or involved in fire Do not use water Do not use carbon dioxide Use suitable dry powder Use dry chemical or carbon dioxide If material not on fire and not Involved In fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water LITHIUM HYDRIDE 4916424 FLAMMABLE SOLID UN1414 WATER REACTIVE Lithium hydride is a greyish white granular powder. It reacts with water to form lithium hydroxide, a corrosive material, and hydrogen, a flam mable gas. The heat of this reaction may be sufficient to ignite the hydrogen. It may react violently with heat or oxidizing materials. If material on fire or involved in fire Do not use water Do not use dry chemical or carbon dioxide Use graphite, soda ash or powdered sodium chloride If material not on fire and not Involved in fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 316 LITHIUM HYDRIDE IN FUSED SOLID FORM 4916425 FLAMMABLE SOLID UN2805 WATER REACTIVE Lithium hydride in fused solid form exists as greyish white lumps, it is used to make other chemicals, as a hydrogen source, and for other uses. It reacts with water to form lithium hydroxide, a corrosive material and hydrogen a flammable gas. The heat from this decomposition may be sufficient to ignite the hydrogen, it may react violently with heat or oxidizing materials. If material on fire or involved in fire Do not use water Do not use dry chemical or carbon dioxide Use graphite, soda ash or powdered sodium chloride If material not on fire and not involved in fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water LITHIUM HYPOCHLORITE COMPOUND. DRY 4918727 CONTAINING MORE THAN 39 PERCENT AVAILABLE CHLORINE OXIDIZER UN1471 Lithium hypochlorite compound, dry is a white granular solid or tab lets compressed from the granules with an odor of chlorine, it is used as a dry bleach. It is noncombustible but it will accelerate the burning of combustible material. It is decomposed by water with the evolution of chlorine gas and heat. Prolonged exposure of the material to fire or heat may result in the vigorous decomposition of the material and the rupture of its container. Material containing less than 39 percent available chlorine will undergo reactions described above though it may take longer to initiate and the resulting reactions may not be as vigorous, tf material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet LITHIUM METAL 4916428 FLAMMABLE SOLID UN1415 WATER REACTIVE Lithium metal is a soft silvery metal though normally greyish white due to oxide formation. It reacts with water to form lithium hydroxide a cor rosive material, and hydrogen a flammable gas. The heat of this reaction may be sufficient to ignite the hydrogen. If lithium metal is heated to its melting point, spontaneous ignition is likely. 000017243 April 1981 If material on fire or involved in fire Do not use water Do not use carDon dioxide Use graphite, soda ash. powdered sodium chloride, or suitable dry powder If material not on fire and not involved In fire Do not use water Keep sparks. Ilames. and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water LITHIUM METAL. IN CARTRIDGES 4916429 FLAMMABLE SOLID UN1415 WATER REACTIVE Lithium metal in cartridges is a very limited quantity of the soft silvery metal sealed in a copper tube overpacked in a wooden box. Lithium reacts with water to form lithium hydroxide, a corrosive material and hydrogen a flammable gas. The heat of this reaction may be sufficient to ignite the hydrogen. If material on fire or involved in fire Do not use water Do not use carbon dioxide Use graphite, soda ash. powdered sodium chloride, or suitable dry powder If material not on fire and not involved in fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water LITHIUM NITRIDE . 4916432 FLAMMABLE SOLID UN2606 WATER REACTIVE Lithium nitride is a reddish brown powder, it is used in metallurgy, and to make other chemicals. It is easily ignited and burns slowly with intense heat. Moisture intensifies the fire. It reacts with water to form lithium hydroxide, a corrosive material and ammonia, a nonflammable gas. The heat of the reaction may be sufficient to ignite nearby combustible ma terials or the material itself. If material on fire or involved In fire Do not use water Do not use dry chemical or carbon dioxide Use graphite, soda ash or powdered sodium chloride If material not on fire and not involved In fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 LITHIUM PEROXIDE 4918520 OXIDIZER. CORROSIVE UN1472 Lithium peroxide is a white to light yellow granular solid. It is soluble in water. Contaminants can cause the solution to decompose to a lithium hydroxide solution which is corrosive. The matenal itself ic nn-com- bustible but it accelerates the burning of combustible material, rolonged exposure of the material and/or its containers to fire or heat may result in a vigorous chemical reaction and the resulting rupture of the containers. If material on fire or involved In fire Use suitable dry powder If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective ciothing Approach fire with caution Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet LITHIUM SILICON 4916431 FLAMMABLE SOLID UN1417 WATER REACTIVE Lithium silicon is a black, lustrous powder to lump material with a sharp irritating odor. It reacts with water to form lithium hydroxide a corrosive material and hydrogen, a flammable gas. The heat of this reaction may be sufficient to ignite Ihe hydrogen. If material on fire or involved in fire Do not use water Do not use carbon dioxide Use graphite, soda ash. powdered sodium chloride, or suitable dry powder If material not on fire and not Involved in fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water LONDON PURPLE, SOLID 4923237 POISON B UNY621 London purple, solid consists of a mixture of arsenic trioxide, aniline, lime and ferrous oxide. It is insoluble In water. It is toxic by inhalation (dust, etc.) and by Ingestion. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, Ilames. and other sources of ignition away Keep material out of water sources and sewers Continued on next page 317 OOOO V792.44 \\C& Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing LOW EXPLOSIVE 4901705 CLASS A EXPLOSIVE Low explosive is a solid material which can be made to burn very vigorously by means of a spark or flame. Upon prolonged exposure to fire containers of the material can explode, if material on fire or involved in fire Dangerously explosive Do not fight fires in a cargo of explosives Evacuate area and let burn If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep spilled material wet Wet spilled material before picking it up Do not attempt to sweep up dry material Personnel protection Avoid breathing dusts, and fumes from burning material Wear protective gloves and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when lighting fires involv ing this material Evacuation If the material is on fire or involved in fire evacuate for a radius of 5000 feet LUBRICATING OIL, NEC (COMBUSTIBLE LIQUID, 4915229 N.O.S.) COMBUSTIBLE LIQUID NA1993 Lubricating oil, nec, is a variable colored liquid with a petroleum-like odor. It has a flash point between 100 and 200 deg. F. it is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemicai If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain Dow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 318 LUBRICATING SYSTEM SIGHT FEED FLUID 4915228 (COMBUSTIBLE LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Lubricating system sight feed fluid is a variable colored liquid with a petroleum-like odor. It has a flash point between 100 and 200 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water LUTIDENE (FLAMMABLE LIQUID,N.O.S.) 4909181 FLAMMABLE LIQUID UN1993 Lutidene is a colorless liquid having a peppermint odor. If is used to make other chemicals, if has a flash point of 92 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool alt affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear futl protective clothing LYE, CONCENTRATED, NEC (SODIUM HYDROXIDE, 4935262 DRY, SOLID, FLAKE, BEAD OR GRANULAR) CORROSIVE MATERIAL, BASIC UN1823 ENVIRONMENTALLY HAZAROOUS SUBSTANCE (RQ-1000/454) Lye, concentrated, nec is a white solid. It is soluble in water with release of heat. It absorbs moisture from the air and dissolves in it. It is corrosive to metals and tissue. Oq oo '*5 April 1981 If material involved in fire Extinguish fire using agent suiiable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Apply water from as far a distance as possible If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Neutralize with dilute acid or removable strong acid MAGNESIUM ALUMINUM PHOSPHIDE 4916440 FLAMMABLE SOLID UN1419 WATER REACTIVE Magnesium aluminum phosphide is a crystalline or a grey lump solid. It reacts with water to form magnesium and aluminum hydroxides and phosphine a flammable poisonous gas. Phosphine will normally ignite spontaneously in contact with air. If material on fire or involved in fire Do not use water Use dry chemical or carbon dioxide If material not on fire and not Involved in fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material MAGNESIUM ARSENATE, SOLID 4923238 POISON B UN1622 Magnesium arsenate, solid is a white powder. It is insoluble in water. It is toxic by inhalation (dust, etc.) and by ingestion. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing April 1961 & MAGNESIUM NITRATE 491S728 OXIDIZER UN1474 Magnesium nitrate is a white crystalline solid, it is used in pyrotechnics, it absorbs moisture from the air and dissolves in it. The material is soluble in water. It is noncombustible but it will accelerate the burning of com bustible materials. If large quantities of the material are involved in the fire or the combustible material is finely divided an explosion may result. Prolonged exposure of the material to fire or heat may result in an explosion. Toxic oxides of nitrogen are produced in fires involving this material. If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet MAGNESIUM PERCHLORATE 4918729 OXIDIZER UNI 475 Magnesium perchlorate is a white crystalline solid, it is used as a drying agent and as an oxidizing agent. It strongly absorbs water from air and dissolves in it. The material is soluble in water. It is noncom bustible but it will accelerate the burning of combustible materials. If large quantities of the material are involved in the fire or the combustible material is finely divided an explosion may result. Prolonged exposure of the material to fire or heat may result in an explosion. If material on fire or involved In fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggies Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet MAGNESIUM PEROXIDE, SOLID 4918730 OXIDIZER UN1476 Magnesium peroxide is a white powder, it is used in medicine, and as a bleaching agent. It is insoluble in water and slowly decomposed by water. It is noncombustible but it will accelerate the burning of com bustible material, if the combustible material is finely divided the mixture may be explosive. Mixtures of combustible material and the peroxide can be ignited by friction or contact with moisture. If material on fire or Involved In fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Continued on next page 319 ft material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet MAGNESIUM SCRAP (BORINGS, CLIPPINGS, 4916436 SHAVINGS, SHEET, TURNINGS, OR SCALPINGS) FLAMMABLE SOLID NA1669 WATER REACTIVE Magnesium scrap is a silvery colored metal. The more finely divided forms react with water to liberate hydrogen, a flammable gas. though not as vigorously as lithium or sodium. The thinner pieces are easily ignited and burn with an intense white flame. if material on fire or involved jn fire Do not use water Use graphite, soda ash. powdered sodium chloride, or suitable dry powder If material not on fire and not Involved in fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Wear boots, protective gloves, and goggles MAGNESIUM, METAL (POWDERED, PELLETS, 4916435 TURNINGS OR RIBBONS) FLAMMABLE SOLID UN1669 WATER REACTIVE Magnesium, metal (powdered, pellets, turnings, or ribbons) is a light silvery colored metal. The more finely divided material reacts with water to liberate hydrogen, a flammable gas, though this reaction is not as vigorous as that of sodium or lithium with water. In finely divided forms it is easily ignited and burns with an intense white flame. If material on fire or involved in fire Do not use water Use graphite, soda ash, powdered sodium chloride, or suitable dry powder If material not on fire and not Involved in fire Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Do not attempt to sweep up dry material Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of wafer or soap and water 320 MALATHION 494115? ORM-A NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10/4.54) Malathion is a yellow liquid. It is used as an insecticide. It is com bustible though it may take some effort to ignite. It is slightly soluble in water. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone: 800-424-9300. It weighs 10.3 pounds per gallon. If material involved in fire Extinguish fire using agent suitable tor type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spiff Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with liy ash or cement powder Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates MALEIC ACID 4941155 ORM-A NA2215 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Maleic acid is a colorless crystaline solid having a faint odor. It is used to make other chemicals and for dyeing and finishing naturally occurring fibers. It is combustible though it may take some effort to ignite. It is soluble in water. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use ` alcohol'' foam, carbon dioxide or dry chemical It material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors or dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or lire fighting water Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and prec MCn 000017247 April 1981 MALEIC ANHYDRIDE 4941161 ORM-A UN2215 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Maleic anhydride is a colorless crystaline solid. It is used to make paints and plastics and other chemicals. It is combustible though it may lake some effort to ignite. It is slowly decomposed by water to give maleic acid, another orm-a. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors or dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates MANGANESE RESINATE, (FLAMMABLE SOLID, 4916766 N.O.S.) FLAMMABLE SOLID UN1325 Manganese resinate ranges from a dark brown-black solid mass to a light tan powder. It may spontaneously heat in the presence of air or moisture. This heat may be sufficient to ignite surrounding combustible materials. It is insoluble in water. If material on fire or involved In fire Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water MATCHES. SAFETY (BOOK, CARD OR STRIKE ON 4917356 BOX) FLAMMABLE SOLID UN1944 Matches, safety are strips of cardboard held together as an assembly, or wooden sticks having their ends dipped with a pyrotechnic mixture and requiring a specially treated surface for striking to cause ignition. If material on fire or Involved in fire Flood with water If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing fumes from burning material April 1981 MATCHES, STRIKE ANYWHERE 4917336 FLAMMABLE SOLID UN1331 Matches, strike anywhere are wooden sticks with an end coated with a pyrotechnic composition that may be ignited by friction with almost any dry surface. Fires occurring in packages of these matches caused by internal friction between the matches or impact are usually contained in the package if it is not broken. If the matches have gotten wet and dried out they are more readily ignited. If material on fire or Involved in fire Flood with water If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Avoid breathing fumes from burning material MEDICINES, N.O.S. 4917378 FLAMMABLE SOLID NA1325 Medicines, n.o.s. is the proper shipping name of any solid material, other than one classed as an explosive, or specifically listed by name in the list of hazardous materials which is liable under conditions incident to transportation to cause fires through friction, absorption of moisture, spontaneous chemical changes as a result of retained heat from the manufacturing or processing of the solid, or which can be readily ignited by external sparks or flame and when so ignited burns vigorously and persistently. Try to ascertain the exact name of the material. If material on fire or involved in fire Extinguish fire using agent suitable for type of fire If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Build dikes to contain flow as necessary Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water MEDICINES, N.O.S. 4918412 OXIDIZER NA1479 Medicines, n.o.s. are various materials which have the property of accelerating the burning of combustible material. These materials may not burn by themselves. Prolonged exposure of these materials and/or their containers to fire or heat may result in an explosion. These materials may only be shipped in containers of 55 gallon capacity or less. If material on fire or Involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Approach fire with caution Evacuation If fire becomes uncontrollable--evacuate for a radius of 1500 feet 321 MCT) 0000 17248 MEDICINES, N.O.S. 4910193 FLAMMABLE LIQUID NA1993 Medicines, n.o.s. are those medicines with the property of having a flash point of less than 100 deg. F. They are generally lighter than water and soluble in water. Their vapors are heavier than air If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water MEDICINES. N.O.S. 4915193 COMBUSTIBLE LIQUID UN1851 Medicines, n.o.s. are those medicines with the property of having a flash point between 100 and 199 deg. F. They are generally lighter than water and soluble in water. Their vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing MEDICINES, N.O.S. (LIQUID) 4921426 POISON B NA2610 Medicines, n.o.s. (liquid) are liquids or a solid dissolved in a liquid having the property of being toxic by ingestion, inhalation, or skin ab sorption. The liquid or solution may or may not bum depending on the nature of the material and/or the solvent of the solution. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective 322 Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered MEDICINES, N.O.S. (SOLID) 4921491 POISON B NA2811 Medicines, n.o.s. (solid) are pure materials or mixtures of two or more solids or a liquid absorbed on a dry carrier. It has the property of being toxic by ingestion, inhalation (vapor dust, etc) or skin absorption, if material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing MEDICINES, N.O.S.. LIQUID 4936583 CORROSIVE MATERIAL UN1851 Medicines, n.o.s., liquid is the proper shipping name for various liquids having the property of being corrosive to steel or tissue. It may either be a simple liquid material or a solid dissolved in a solvent. It may be combustible though requiring some effort to ignite. They may or may not be water soluble. If material on fire or Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary MOD 000017249 April 1961 Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing MEDICINES, N.O.S., SOLID 4936S84 CORROSIVE MATERIAL UN1851 Medicines, n.o.s., solid is the proper shipping name for various colored solids having the property of being corrosive to tissue. They may or may not be water soluble. If material on fire or Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing MEMTETRAHYDROPHTHALIC ANHYDRIDE CORROSIVE MATERIAL 4931441 NA1760 Memtetrahydrophthalic anhydride is a colorless to tight yellow liquid. It is used to make plastics. It is soluble in water and decomposed by water to tetrahydrophthalic acid, which is also water soluble, with release of heat. It is corrosive to skin. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use '`alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled matenal with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing April 1981 MCI) 0000 l y. .50 MERCAPTAN MIXTURE, ALIPHATIC COMBUSTIBLE LIQUID 4913120 NA1228 Mercaptan mixture, aliphatic is a clear colorless to light yellow liquid with a very offensive odor. It has a flash point between 100 and 199 deg. F. It is lighter than water and very slightly soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear seif-contained breathing apparatus when fighting fires involv ing this material MERCAPTAN MIXTURE, ALIPHATIC 4909220 FLAMMABLE LIQUID NA122B Mercaptan mixture, aliphatic is a clear colorless to light yellow liquid with a very offensive odor. It has a flash point of less than 100 deg.f. It is lighter than water and very slightly soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop ieak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear bools, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material MERCAPTODIMETHUR 4962145 ORM-E NA2757 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Mercaptodimethur is a white crystalline powder. It is used as a pes ticide. It is a wettable powder or water emulsifiable liquid. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. Continued on next page 323 If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates MERCURIC ACETATE 4923241 POISON B UNI629 Mercuric acetate is a white crystalline solid with a vinegar like odor. It is soluble in water and is decomposed by water to form a white insoluble precipitate, it is toxic by inhalation (dust, etc.) and by ingestion. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical H material not involved in fire Keep materia) out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing MERCURIC BENZOATE, SOLID 4923243 POISON B UNI 631 Mercuric benzoate, solid is a white crystalline solid. It is slightly soluble in water. It is toxic by inhalation (dust, etc.) and by ingestion. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not Involved In fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing 324 MERCURIC BROMIDE. SOLID 4923244 POISON B UN1634 Mercuric bromide, solid is a white crystalline solid. It is very slightly soluble in water, tt is toxic by inhalation (dust, etc.) and by ingestion. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Materia) itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved In fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this matenal If contact with the material anticipated, wear full protective clothing MERCURIC CHLORIDE 4923245 POISON B UNI 624 Mercuric chloride is a white crystalline solid. It is soluble in water. It is corrosive to the mucous membranes. It is toxic by inhalation (dust etc.) and ingestion. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not Involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing MERCURIC CHLORIDE (MERCURIC CHLORIDE AND 4923271 CHARCOAL CATALYST, SPENT) POISON B UNI 624 Mercuric chloride and charcoal catalyst, spent is mercuric chloride deposited on a charcoal carrier base. The mercuric chloride is soluble in water, ft is corrosive to the mucous membranes. It is toxic by ingestion, and inhalation (dusts, etc). If material on fire or involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not on fire and not invotved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers April 1981 MOD 000017251 Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing MERCURIC CYANIDE, SOLID 4923246 POISON B UNI 636 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Mercuric cyanide solid is a white crystalline solid. It is slightly soluble in water. It is gradually decomposed by water and rapidly decomposed by acids to give off hydrogen cyanide, a flammable poison gas. It is toxic by inhalation (dust, and the hydrogen cyanide from decomposition) and by ingestion. Toxic oxides of nitrogen are produced in fires involving this material. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved In fire Keep material out of water sources and sewers Personnel protection Avoid breathing vapors or dusts Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in ram or fire fighting water Environmental considerations--water spill Add caustic soda If dissolved, apply sodium sulfide solution to precipitate heavy metals Add calcium hypochlorite If dissolved, apply activated carbon at ten times the spilled amount in region of tOppm or greater concentration Adjust ph to neutral (ph-7) Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates MERCURIC IODIDE, SOLID POISON B 4923247 UN1638 Mercuric iodide, solid is a red crystalline solid. It is very slightly soluble in water. It is toxic by inhalation (dusts, etc) and by ingestion. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not Involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind April 1981 MOD 000017252 Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing MERCURIC IODIDE, SOLUTION 4923249 POISON B UNI 638 Mercuric iodide, solution is a red liquid, it is slightly soluble in water. It is toxic by ingestion. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sawers Personnel protection Avoid breathing vapors or dusts Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing MERCURIC NITRATE 4918769 OXIDIZER UN162S ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10/4.54) Mercuric nitrate is a white crystalline solid. It is used to make other chemicals and in medicine. It is soluble in water. It is non-combustible, but it will accelerate the burning of combustible materials. If large quan tities are involved in a fire or the combustible materia) is finely divided, an explosion may result. Prolonged exposure to fire or heat may result in an explosion. Toxic oxides of nitrogen are produced in tires involving this material. If material on fire or Involved In fire Flood with water Cool alt affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Continued on next pege 325 Environmental considerations--water spill Add caustic soda If dissolved, apply sodium sulfide solution to precipitate heavy metals If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Allow to aerate MERCURIC OLEATE, SOLID 4923250 POISON B UNI640 Mercuric oleate, solid is a yellowish-brown grease-iike solid. It is in soluble in water. It is toxic by ingestion. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved In fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing MERCURIC OXIDE, SOLID 4923251 POISON B UNI 641 Mercuric oxide, solid is a red-orange powder. It is insoluble in water. It is toxic by inhalation (dust etc.) and by ingestion. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved In fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing MERCURIC OXYCYANIDE, SOLID (DESENSITIZED) 4923253 POISON B UN1642 Mercuric oxycyanide, solid is a white crystalline solid, it is used in medicine. It is soluble in water. It can explode on prolonged exposure to fire or heat. It decomposes on contact with acid to give off hydrogen cyanide, a flammable poison gas. It is toxic by inhalation (dust and hydrogen cyanide from decomposition) and by ingestion. 326 If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing MERCURIC SALICYLATE, SOLID 4923255 POISON B UN1644 Mercunc salicylate, solid is a white powder with a yellow or pink tint. It is insoluble in water. It is toxic by inhalation (dust, etc.) and by ingestion. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not Involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing MERCURIC SUBSULFATE, SOLID 4923256 POISON B NA2025 Mercuric subsuifate, solid is a lemon yellow powder or a yellow scaley material. It is insoluble in water. It is toxic by inhalation (dust, etc.) and by ingestion. If material involved in fire Extinguish fire using agent suitable lor type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing MCI) OQqq 1 725s April 1981 MERCURIC SULFATE, SOLID 4923257 POISON B UNI 645 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10/4.54) Mercuric sulfate, solid is a white crystalline powder, it is used in med icine, for gold and silver extraction, and to make other mercury com* pounds. It is decomposed by water to yellow mercuric subsulfate and free sulfuric acid, a corrosive material. It is toxic by inhalation (dust) and by ingestion. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit. pond, lagoon, hoiding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Add caustic soda If dissolved, apply sodium sulfide solution to precipitate heavy metals If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Allow to aerate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--water spill Add caustic soda If dissolved, apply sodium sulfide solution to precipitate heavy metals If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Allow to aerate Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates MERCURIC-AMMONIUM CHLORIDE, SOLID 4923242 POISON B UN1630 Mercuric-ammonium chloride is a white crystalline solid. It is soluble in water. It is corrosive to the mucous membranes. It is toxic by inhalation (dust, etc.) and by ingestion. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not Involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing MERCURIC SULFO CYANATE, SOLID (OR) MERCURIC 4923258 THIOCYANATE POISON B UN1646 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10/4.54) Mercuric sulfo cyanate is a white crystalline powder. It is very slightly soluble in water. When heated or burned it expands to many times in volume. It is toxic by inhalation (dust) and by ingestion. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved In Are Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water April 1981 MCD 000017254 MERCURIC-POTASSIUM CYANIDE, SOLID 4923254 POISON B UNI626 Mercuric--potassium cyanide solid is a colorless crystalline solid. It is soluble in water. It is rapidly decomposed by acids to give off hydrogen cyanide, a flammable poison gas. It is toxic by inhalation (dust, and the hydrogen cyanide from decomposition) and by ingestion. Toxic oxides of nitrogen are produced in fires involving this material, ff material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use foam, carbon dioxide or dry chemical Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If material not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Do not use water on material itself Personnel protection Avoid breathing vapors or dusts Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing 327 MERCURIC-POTASSIUM IODIDE, SOLID POISON B 4923272 UN1643 Mecuric-potassium iodide, solid is a yellow crystalline solid. It absorbs water from the air and dissolves in it. It is soluble in water. It is toxic by ingestion. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not Involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing MERCUROL OR MERCURY NUCLEATE, SOLID 4923259 POISON B UN1639 Mercurol is a brown powder containing a mercury compound. It is soluble in water. It is toxic by inhalation (vapor, dust, etc) and by skin absorption. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water In flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep materia! out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing MERCUROUS ACETATE, SOLID 4923266 POISON B UNI 629 Mercurous acetate, solid is a white crystalline solid with a vinegar like odor. It is soluble in water and is decomposed to white insoluble pre cipitate. it is toxic by ingestion and by inhalation (dusts, etc). If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment 328 Wash away any material which may have contacted the body with copious amounts of water or soao and water Wear self-contained breathing apparatus when fighting tires involv ing this material If contact with the material anticipated, wear full protective clothing MERCUROUS BROMIDE, SOLID 4923260 POISON B UN1634 Mercurous bromide, solid is a white powder darkening on exposure to light. It is insoluble in water. It is toxic by inhalation (dust, etc) and by ingestion. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep materia! out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing MERCUROUS GLUCONATE, SOLID 4923261 POISON B UN1637 Mercurous gluconate, soiid is a white powder. It is slightly soluble in water. It is toxic by inhalation (dust, etc.) and by ingestion. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing MERCUROUS IODIDE, SOLID 4923262 POISON B UNI 638 Mercurous iodide, solid is a light yellow powder. It is insoluble in water. It is toxic by inhalation (dust, etc.) and by ingestion. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers April 1981 MOD 000017255 Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing MERCUROUS NITRATE, SOLID 4918752 OXIDIZER. POISONOUS UN1627 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-10/4.54) Mercurous nitrate, solid is a colorless crystalline material with a faint odor of nitric acid, it is used in medicine and in chemical analysis. It darkens on exposure to light, it is slightly soluble in water and decom poses to a white insoluble precipitate. It will accelerate the burning of combustible material. It is toxic by ingestion or inhalation of dusts, toxic oxides of nitrogen are produced in fires involving this material. If material on fire or involved in fire Flood with water Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Approach fire with caution Evacuation if fire becomes uncontrollable--evacuate for a radius of 1500 feet Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or tire fighting water Environmental considerations--water spill Add caustic soda If dissolved, apply sodium sulfide solution to precipitate heavy metals Allow to aerate If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Use mechanical dredges or lifts to remove immabilized masses of pollutants and precipitates MERCUROUS OXIDE, BLACK, SOLID 4923264 POISON B UN1641 Mercurous oxide, black, solid is a black powder. It is decomposed by light to free mercury and mercuric oxide. It is insoluble in water. It is toxic by inhalation (dust, etc) and by ingestion. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical if material not involved in fire Keep material out of water sources and sewers April 1981 MERCUROUS SULFATE, SOLID 4923265 POISON B UNI628 Mercurous sulfate, solid is a white to yellow crystalline powder. It is insoluble in water. It is toxic by inhalation (dust, etc) and by ingestion. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not Involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing MERCURY BASED PESTICIDE, LIQUID, N.O.S. 4921651 (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL, NEC) POISON B UN2777 Mercury based pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The carrier may bum though it may take some effort to ignite. It is toxic by inhalation, skin absorption, and' or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424- 9300. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 329 MCD 000017256 MERCURY BASED PESTICIDE, LIQUID, N.O.S. 4921652 (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC, LIQUID) POISON B UN2777 Mercury based pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The carrier may bum though it may take some effort to ignite. It is toxic by inhalation, skin absorption, and/ or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-4249300. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water MERCURY BASED PESTICIDE, LIQUID, N.O.S. 4910537 (COMPOUNDS AND PREPARATIONS) (INSECTICIDES, OTHER THAN AGRICULTURAL, NEC) FLAMMABLE LIQUID UN2778 Mercury based pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The primary hazard of this material is the flammability of the carrier. It has a flash point below 100 deg. F. it can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wear self-contained breathing apparatus when fighting fires involv ing this material MERCURY BASED PESTICIDE. LIQUID, N.O.S. 4910538 (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC, LIQUID) FLAMMABLE LIQUID UN2778 Mercury based pesticide is a liquid or solid dissolved in a liquid carrier. The carrier is water emulsifiable. The primary hazard of this material is the flammability of the carrier. It has a flash point below 100 deg. F. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. H material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wear self-contained breathing apparatus when fighting fires involv ing this material 330 MERCURY BASED PESTICIDE, SOLID, N.O.S. 4921653 (COMPOUNDS AND PREPARATIONS) (INSECTICIDES. OTHER THAN AGRICULTURAL, NEC) POISON B UN2777 Mercury based pesticide is a solid or a liquid absorbed on a dry carrier. It is a wettable powder. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to. or leaking from containers of this ma terial contact the pesticide safety team network. Telephone; 800-424- 9300. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as tog Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the materia! Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this matenal If contact with the material anticipated, wear full protective clothing April 1981 MCI) 000017257 MERCURY BASED PESTICIDE, SOLID, N.O.S. 4921654 (COMPOUNDS AND PREPARATIONS) (AGRICULTURAL INSECTICIDES, NEC, OTHER THAN LIQUID) POISON B UN2777 Mercury based pesticide is a solid or a liquid absorbed on a dry carrier. It is a wettable powder. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to. or leaking from containers of this ma terial contact the pesticide safety team network. Telephone; 800-424- 9300. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing MERCURY COMPOUND, SOLID, N.O.S. 4923269 POISON B UN2025 Mercury compound, solid, n.o.s. is a various colored crystalline ma terial containing mercury. It may or may not be water soluble. It is toxic by inhalation (dust) or by ingestion. If material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Oo not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing MESITYL OXIDE 4909223 FLAMMABLE LIQUID UN1229 Mesityl oxide is a colorless, oily liquid with a pungent honey-like odor. It is used in paint removers, as a solvent for plastics, and as an insect repellent. It has a flash point of 87 deg. F. It is lighter than water and is slightly soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical April 1981 MOD 000017258 If material not on fire and not Involved in lire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water METAL ALKYL, SOLUTION, N.O.S. 4906030 FLAMMABLE LIQUID NA919S PYROFORIC Metal alkyl, solution, n.o.s. is a material whose principal property is that of igniting spontaneously in contact with moist air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Do not use water Use graphite, soda ash or powdered sodium chloride If material not on fire and not involved in fire Do not use water Keep sparks, flames, and Other sources of ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered METAL ALLOY BILLETS. BLOOMS, INGOTS, PIGS, 492648B SPONGE OR SHOT, NEC, NOT IRRADIATED NOR REQUIRING PROTECTIVE SHIELDING (RADIOACTIVE MATERIAL, N.O.S.) RADIOACTIVE MATERIAL UN2912 Metal alloy billets, blooms, ingots, pigs, sponge or shot are greyish to silvery colored materials. Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful, whereas film may be damaged by radiation from relatively low concentrations. If material on fire or Involved In fire Contact the local, state, or department of energy radiological re sponse team Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Use graphite, soda ash, powdered sodium chloride, or suitable dry powder Continued on next page 331 If material not on fire and not involved in fire Contact the local, state, or department of energy radiological re sponse team Do not use water Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep material dry Do not attempt to sweep up dry material Personnel protection Keep upwind Avoid breathing dusts, and fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation Keep unnecessary people out of incident area until area declared safe by radiological response team METAL OR METAL ALLOY BILLETS, BLOOMS, 4926489 INGOTS, PIGS, SPONGE. OR SHOT, NOT IRRIDATED NOR REQUIRING PROTECTIVE SHIELDING {RADIOACTIVE MATERIAL. LOW SPECIFIC ACTIVITY OR LSA, N.O.S.) RADIOACTIVE MATERIAL UN2912 Metal or metal alloy billets, blooms, ingots, pigs, sponge, or shot is greyish to silvery colored material. Radioactive materials emit certain rays that may be hazardous. These rays can be detected only by instruments. Exposure of humans to intense radiation may be harmful whereas films may be damaged by radiation from relatively low concentrations. If material on fire or involved in fire Contact the local, state, or department of energy radiological re sponse team Extinguish fire using agent suitable for type of surrounding fire (Matenal itself does not burn or burns with difficulty.) Use graphite, soda ash. powdered sodium chloride, or suitable dry powder If material not on fire and not involved in fire Contact the local, state, or department of energy radiological re sponse team Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Keep upwind Avoid breathing dusts, and fumes from burning material Wear full protective clothing Wear self-contained breathing apparatus Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation Keep unnecessary people out of incident area until area declared safe by radiological response team METHACRYLIC ACID, GLACIAL (CORROSIVE LIQUID, 4931402 N.O.S.) CORROSIVE MATERIAL, ACIDIC, COMBUSTIBLE UN1760 Methacrylic acid, glacial is a clear colorless liquid having a pungent odor. It is used to make plastics, ft is corrosive to metals and tissue, it is also combustible and has a flash point of 154 deg. f. and a melting point of 61 deg. F. If the material becomes contaminated or is subject to heat, it may polymerize, if the polymerization takes place inside a container, the container may violently rupture. It is lighter than water and is soluble in water, its vapors are heavier than air. 332 If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Neutralize spilled matenal with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet METHALLYL CHLORIDE (FLAMMABLE LIQUID, 4908223 N.O.S.) FLAMMABLE LIQUID UN1993 Methallyl chloride is a colorless to straw colored liquid with a sharp penetrating odor. It has a flash point of 11 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding Quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Build dikes lo contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggtes Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable or container is exposed to direct dame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered Mod 00017259 April 1981 METHANE 4905755 FLAMMABLE GAS UN1971 Methane is a colorless odorless gas. It is easily ignited. It may only be shipped in cylinders. The gas is lighter than air but a flame may flash back to the source of a leak very easily. Under fire conditions the cyl inders may violently rupture and rocket. If material on fire or involved in fire Oo not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If materia) leaking (not on tire), downwind evacuation must be considered METHANOL (METHYL ALCOHOL, COLUMBIAN 4909230 SPIRITS) FLAMMABLE LIQUID UNI 230 Methanol is a clear colorless liquid. It is used to make other chemicals, to remove water from automotive and aviation fuels, as an antifreeze, and as a solvent for various paints and plastics. It has a flash point of 52 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. if material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical It materia) not on fire and rot involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any matehal which may have contacted the body with copious amounts of water or soap and water METHANOL. CONTAMINATED. VALUE ONLY FOR REFINING (ALCOHOL, N.O.S.) 4909237 -LAMMABIE LIQUID UN1987 Methanol, contaminated is a clear colorless to variable colored liquid. It has a flash point of 52 deg. F. which may vary depending on contam ination. It is lighter than water and may not be completely water soluble, methanol itself is water soluble.) its vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use '`alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water METHANOL. SOLIDIFIED (ALCOHOL, N.O.S.) 4910404 FLAMMABLE LIQUID UN1967 Methanol, solidified is a sterno-like gel. The alcohol can separate out. The hazard is flammability. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance ?s possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water METHYL CHLOROCARBONATE (see METHYL CHLOROFORMATE 4907429) METHYLETHANOLAMINE (COMBUSTIBLE LIQUID, 4913183 N.O.S.) COMBUSTIBLE LIQUID NA1933 Methylethanolamine is a dear colorless liquid, it is used to make other chemicals. It has a flash point of 165 deg. F. It is lighter than water and is soluble in water, its vapors are heavier than air. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical Continued on next page April 1981 MCD 000017260 333 If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwtnd Avoid bodily contact with the material METHOXYCHLOR (AGRICULTURAL INSECTICIDES, 4960646 NEC, LIQUID) ORM-E NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Methoxychlor is a white crystalline solid dissolved in a liquid carrier. It is used as a pesticide, it is a water emulsifiable liquid. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800*424-9300. tf material Involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) If material not Involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid materiai Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates METHOXYCHLOR (INSECTICIDES, OTHER THAN 4960648 AGRICULTURAL, NEC) ORM-E NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Methoxychlor is a white crystalline solid or the solid dissolved in a liquid carrier. It is used as a pesticide. It is a wettabie powder or water emulsifiable liquid. It can cause illness by inhalation, skin absorption and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800- 424-9300. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom if dissolved, appiy activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates METHOXYCHLOR (AGRICULTURAL INSECTICIDES. 4960647 NEC. OTHER THAN LIQUID) ORM-E NA2761 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Methoxychlor is a while crystalline solid. It is used as a pesticide. It is a wettabie powder. It can cause iilness by inhalation, skin absorption and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800- 424-9300. H material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) If material not Involved In fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Keep upwind Wear boots, protective gloves, and goggles Avoid breathing vapors or dusts Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water METHYL ACETATE 4908220 FLAMMABLE LIQUID UN1231 Methyl acetate is a clear colorless liquid with a fragrant odor. It has a flash point of 14 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water 334 Mcd 00Z7r>, April 1981 Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered METHYL ACETOACETATE (COMBUSTIBLE LIQUID, 4913150 N.O.S.) COMBUSTIBLE UQUID NA1993 Methyl acetoacetate is a clear colorless liquid. It has a flash point of 158 deg. F. It is heavier than water and slightly soluble in water, its vapors are heavier than air. tf materiel on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water METHYL ACETONE 4909238 FLAMMABLE UQUID UNI 232 Methyl acetone is a clear colorless liquid composed of acetone, methyl acetate and methanol. It has a flash point of less than 52 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. tf material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water METHYL AMYL ACETATE 4909235 FLAMMABLE UQUID UN1233 Methyl amyl acetate is a clear colorless liquid, it has a flash point of 95 deg. F. It is lighter than water and is insoluble in water. Its vapors are heavier than air. April 19B1 Men If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical 11 material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water METHYL AMYL KETONE 4913132 COMBUSTIBLE UQUID UN1110 Methyl amyl ketone is a clear colorless liquid. It has a flash point of 126 deg. F. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use ` alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water METHYL BROMIDE AND ETHYLENE DIBROMIOE 4921438 MIXTURE, LIQUID POISON B UN1647 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Methyl bromide and ethylene dibromide mixture, liquid is the mixture of two liquids having a chloroform like odor, Neither material is com bustible. Both are very slightly soluble in water. The mixture is toxic by inhalation and skin absorption. It weighs 18.0 pounds per gallon. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Continued on next page 335 Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Oo not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors METHYL BROMIDE AND MORE THAN 2% 4921437 CHLOROPICRIN MIXTURE, LIQUID POISON B NA1581 Methyl bromide and more than 2% chloropicrin mixture, liquid is a mixture of two liquids. Neither is combustible or water soluble. They are toxic by inhalation. Prolonged or repeated skin contact can cause severe bums and possible absorption of toxic quantities of the material. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered METHYL BROMIDE AND NONFLAMMABLE 4921439 NONLIQUEFIED COMPRESSED GAS MIXTURE, LIQUID POISON B NA1955 Methyl bromide and nonflammable nonliquefied compressed gas mix ture, liquid is a liquid charged with a gas. It is non-combustible and has a chloroform-like odor. It is very slightly soluble in water. It is toxic by inhalation. 336 If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool ali affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical II material not on fire and not involved in lire Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered METHYL BROMIDE. LIQUID (INCLUDING UP TO 2% 4921440 CHLOROPICRIN) POISON B UN1062 Methyl bromide is colorless liquid with a chloroform-like odor. Under most circumstances it is non-combustible. It is very slightly soluble in water. It is toxic by inhalation. Prolonged or repeated skin contact can cause severe burns and possible absorption of toxic quantities of the material. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Use foam, carbon dioxide or dry chemical If material not involved in fire Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear futl protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered METHYL BUTENE 4909225 FLAMMABLE LIQUID UN2460 Methyl butene is a clear colorless liquid with a petroleum like odor. It has a flash point of less than 20 deg. F. ft is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may spread fire Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical April 1981 MOD U0001726M If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water METHYL BUTYL KETONE (FLAMMABLE LIQUID, 4909242 N.O.S.) FLAMMABLE LIQUID UN1993 Methyl butyl ketone is a clear colorless liquid. It has a flash point of 95 deg. F. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of Ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, pfotective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water METHYL BUTYRATE 4909226 FLAMMABLE LIQUID UN1237 Methyl butyrate is a clear colorless liquid. It has a flash point of 37 deg. F. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 METHYL CHLORIDE 4905761 FLAMMABLE GAS UN1063 Methyl chloride is a colorless gas with a faint sweet odor, it is used to make other chemicals and as a herbicide. It is shipped as a liquefied gas under its vapor pressure. Contact with the liquid can cause frostbite. It is easily ignited. Its vapors are heavier than air, and a flame can flash back to the source of leak very easily. The leak can be either a liquid or vapor leak. It can asphyxiate by the displacement of air. Under tire conditions the cylinder or tank car may violently rupture and rocket. If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on tire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered METHYL CHLORIDE-METHYLENE CHLORIDE 4905764 MIXTURE FLAMMABLE GAS UN1912 Methyl chloride-methylene chloride is a colorless gas with a faint sweet odor. It is shipped as a liquefied gas under its vapor pressure. Contact with the liquid can cause frostbite. It is easily ignited. Its vapors are heavier than air and a flame can flash back to the source of leak very easily. It can asphyxiate by the displacement of air. Under fire conditions (he cylinders or lank cars may violently rupture or rocket. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered 337 MCI) O00ni7264 METHYL CHLOROFORMATE 4907429 FLAMMABLE LIQUID, CORROSIVE UN1238 Methyl chloroformate is a colorless liquid with a pungent odor. It has a flash point of 54 deg. F. It is slightly soluble in water and decomposed by water to hydrochloric acid with evolution of heat. It is corrosive to metals and tissue, its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use "alcohol'' foam, carbon dioxide or dry chemical Coot all affected containers with flooding quantities of water Apply water from as far a distance as possible Do not use water on material Itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or iime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1 500 feet If material leaking (not on fire), downwind evacuation must be considered METHYL DICHLOROACETATE 4933350 CORROSIVE MATERIAL, ACIDIC, COMBUSTIBLE UN2299 Methyl dichloroacetate is a colorless liquid with an ethereal odor. It is used to make other chemicals. It is combustible and has a flash point of 176 deg. F. It is decomposed by water to dichloroacetic acid, a cor rosive material with evolution of heat. It is corrosive to metals and tissue. If material on fire or involved in fire Use dry chemical, carbon dioxide, or dry sand Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool alt affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing 338 METHYL ETHYL KETONE (ETHYL METHYL KETONE) 4909243 FLAMMABLE LIQUID UN1193 Methyl ethyl ketone is a clear colorless liquid with an acetone-like odor, ft is used as a solvent for paints, plastics, and adhesives, ft has a flash point of 21 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol'' foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water METHYL ETHYL KETONE PEROXIDE, (IN SOLUTION 4919178 WITH NOT MORE THAN 9% BY WEIGHT ACTIVE OXYGEN) ORGANIC PEROXIDE UN2550 Methyl ethyl ketone peroxide, (in solution with not more than 9% by weight active oxygen) is a coloress to pale yellow liquid. It is used to manufacture paints, plastics, and rubber. It is insoluble in water. The liquid or solution may require some effort to ignite; but once ignited, it will burn with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of combustible materials. Un der prolonged exposure to fire or heat containers of the material may explode. H material on fire or involved In fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet MCD 000017265 April 1981 METHYL ETHYL PYRIDINE 4935660 CORROSIVE MATERIAL, BASIC, COMBUSTIBLE UN2300 Methyl ethyl pyridine is a colorless liquid with a sharp penetrating odor. It is combustible and has a flash point of 165 deg. F. It is slightly soluble in water. It is corrosive to metals and tissue. Toxic oxides of nitrogen are produced during combustion of this material. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Solid streams of water may be ineffective Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the matenal anticipated, wear full protective clothing METHYL FORMATE 4908225 FLAMMABLE LIQUID UN1243 Methyl formate is a dear coioriess liquid with an agreeable odor. It has a flash point of -27 deg. F. It is lighter than water and reacts with water to give formic acid, a corrosive material and methyl alcohol, an other flammable liquid. Both of these materials are soluble in water. Its vapors are heavier than air. H material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use "alcohol" foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Do not use water on matenal itself If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Peraonnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any matenal which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered April 1981 METHYL HYDRAZINE 4906230 FLAMMABLE LIQUID, POISONOUS, CORROSIVE UN1244 THERMALLY UNSTABLE Methyl hydrazine is a colorless liquid with an ammonia-iike odor, it is used to make other chemicals, as a solvent, and as a rocket propellant. It has a flash point of 17 deg. F. It is flammable over a wide range of vapor air concentrations. It may ignite spontaneously in contact with porous materials such as earth, wood, cloth, etc., and with oxidizing materials. It is toxic and the vapors attack the eyes and respiratory system. It is also corrosive to the skin, it is lighter than water and slightly soluble in water. The vapors are heavier than air. Prolonged exposure of the containers of the material to fire or heat may result in the spon taneous decomposition of the material and violent rupture of the con tainer. Toxic oxides of nitrogen are produced during combustion of this matenal. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical ff material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective cfothlng Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 5000 feet If material leaking (not on fire), downwind evacuation must be considered METHYL ISOBUTYL CARBINOL (COMBUSTIBLE 4913143 LIQUID, N.O.S.) COMBUSTIBLE LIQUID UN1987 Methyl isobutyl carbinol is a dear colorless liquid. It has a flash point of 120 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not cm fire and not involved in fire Keep sparks, ffames. and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to disperse vapors and dilute standing pools of liquid Continued on next page 339 MCD 000017266 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water METHYL ISOBUTYL KETONE (FLAMMABLE LIQUID, 4909245 N.O.S.) FLAMMABLE LIQUID UN1993 Methyl isobutyl ketone is a clear colorless liquid with a pleasant odor. It has a flash point of 73 deg. F. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carton dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water METHYL ISOBUTYL KETONE PEROXIDE, (IN 4919180 SOLUTION WITH NOT MORE THAN 9% BY WEIGHT ACTIVE OXYGEN) ORGANIC PEROXIDE UN2126 Methyl isobuty! ketone peroxide, (in solution with not more than 9% by weight active oxygen) is a colorless to pale yellow liquid, ft is used to manufacture paints, plastics, and rubber. It is slightly soluble in water. The liquid or solution may require some effort to ignite; but once ignited, it will bum with increasing rapidity as the fire progresses. If spilled on combustible materials, spontaneous ignition of the material may occur. Contamination with many chemical substances can cause a violent chemical reaction. It supports the burning of combustible materials. Un der prolonged exposure to fire or heat containers of the material may explode. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Dangerously explosive If material not on fira and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Keep spilled material wet Wet spilled material before picking it up Personnel protection Avoid breathing dusts, and fumes from burning material Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment 340 Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If the material is on fire or involved in fire evacuate for a radius of 2500 feet METHYL ISOPROPENYL KETONE. INHIBITED 4907240 FLAMMABLE LIQUID UN1246 POLYMERIZATION Methyl isopropenyl ketone is a clear colorless liquid. It has a flash point of 52 deg. F. if contaminated or subjected to heat it may polymerize if methyl isopropenyl ketone is confined in a container when polymeri zation takes place the container may violently rupture. It is heavier than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered METHYL MAGNESIUM BROMIDE IN ETHYL ETHER 4908230 FLAMMA8LE LIQUID UN1928 This is the solution of methyl magnesium bromide in ethyl ether. Ethyl ether has a flash point of -49 deg. F. The solution reacts with water to give methane, a flammable gas. The heat of this reaction may be suf ficient to ignite the methane. The vapors of ethyl ether are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use "alcohol" foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Do not use water on material itself If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Do not use water on material itself April 1981 MCD 0000.17267 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered METHYL MERCAPTAN 4905520 FLAMMABLE GAS, CORROSIVE UN1064 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-100/45.4) Methyl mercaptan is a colorless gas with a very strong disagreeable odor of rotten cabbage. It is shipped as a liquefied gas under its vapor pressure. Contact with the liquid can cause frostbite or chemical type burn. It is slightly soluble in water, it is easily ignited, tts vapor is heavier than air and a flame can flash back to the source of leak very easily. It can asphyxiate by the displacement of air. Under fire conditions the cylinders or tank cars may violently rupture and rocket. It weighs 7.3 pounds per gallon. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit. pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors April 1981 METHYL METHACRYLATE MONOMER, INHIBITED 4907250 FLAMMABLE LIQUID UNI 247 POLYMERIZABLE ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-5000/2270) Methyl methacrylate monomer is a clear colorless liquid. It is used to make plastics. It has a flash point of 50 deg. F. The vapors are irritating to the eyes and respiratory system. If contaminated or subjected to heat, it may polymerize. If the polymerization takes place in a container, the container is subject to violent rupture. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. It weighs 7.8 pounds per gallon. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on tire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash. cement powder, sawdust, or com mercial sorbents Apply "universal'' gelling agent to immobilize spill Apply fluorocarbon-water foam to diminish vapor and fire hazard Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e.g. detergent, soaps, alcohols) to com press and thicken spilled material Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors METHYL METHOXY PENTANONE (COMBUSTIBLE 4913138 LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Methyl methoxy pentanone is a clear colorless liquid. It is used as a solvent. It has a flash point of 141 deg. F. it is liqhter than water and insoluble in water. Its vapors are heavier than air. Continued on next page 341 MOD 000017266 If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water METHYL NORBORNENE DICARBOXYLIC ANHYDRIDE (See MEMTETRAHYDRO PHTHALIC ANHYDRIDE 4931441) METHYL PARATHION MIXTURE, DRY 4921443 POISON B NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Methyl parathion mixture, dry is the liquid material absorbed on a dry carrier. Methyl parathion is very slightly soluble in water. Methyl para thion is a combustible liquid but the combustibility depends on the nature of the carrier and quantity of methyl parathion. It is toxic by skin ab sorption and inhalation (vapor, dust, etc.) in case of damage to, or leaking from containers of this material contact the pesticide safety team net work. Telephone; 800-424-9300 If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Use foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid materia! Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remve immobilized masses of pollutants and precipitates 342 METHYL PARATHION MIXTURE, LIQUID (CONTAINING 4921444 25% OR LESS METHYL PARATHION) POISON B NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Methyl parathion mixture, liquid is the solution of methyl parathion and a liquid or solid dissolved in it. Methyl parathion is slightly soluble in water and is itself a combustible liquid. The combustibility of the mixture depends upon the nature of the other material dissolved in the solution. It is toxic by inhalation and by skin absorption. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300 If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire end not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop ieak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered Environmental considerations---land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e.g. detergent, soaps, alcohols) to com press and thicken spilled material Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors METHYL PARATHION MIXTURE, LIQUID (CONTAINING 4921447 OVER 25% METHYL PARATHION) POISON B NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Methyl parathion mixture, liquid is the solution of methyl parathion and a liquid or solid dissolved in it. Methyl parathion is slightly soluble in water and is itself a combustible liquid. The combustibility of the mixture depends upon the nature of the other material dissolved in the solution. It is toxic by inhalation and by skin absorption. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 600-424-9300 April 1981 oo 0 l7ss9 If material on fire or involved In fire Do not extinguish tire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep materia! out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e.g. detergent, soaps, alcohols) to com press and thicken spilled material Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spltl Apply water spray or mist to knock down vapors Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered METHYL PENTANE 4906191 FLAMMABLE LIQUID UN2462 Methyl pentane is a clear colorless liquid with a petroleum like odor. It has a flash point of >10 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered METHYL PENTADIENE 4908173 FLAMMABLE LIQUID UN2461 Methyl pentadiene is a clear colorless liquid with a petroleum like odor. It has a flash point of -30 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. If materiel on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1981 METHYL PHOSPHONOTHIOIC DICHLORIDE, 4933336 ANHYDROUS CORROSIVE MATERIAL, POISONOUS NA1760 Methyl phosphonothioic dichloride, anhydrous is a colorless liquid with a pungent odor. It is noncombustible. It is toxic by inhalation. It is heavier than water and reacts with water to give hydrochloric acid.a corrosive material, with release of heat. It is corrosive to metals and tissue. If material on fire or Involved In fire Use "alcohol" foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime Continued on next page 343 MGD OOOO!7270 Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water METHYL PHOSPHONOUS DICHLORIDE 4933337 CORROSIVE MATERIAL NA2845 PYROFORIC Methyl phosphonous dichloride is a colorless liquid with a pungent odor. It is pyroforic and will spontaneously ignite on contact with moist air or water. It is heavier than water and besides igniting on contact with water hydrochloric acid, a corrosive material, is produced. It is corrosive to metals and tissue. If material on fire or involved in fire Use 'alcohol'' foam, carbon dioxide or dry chemical Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Do not use water on material itself Neutralize spiiled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water METHYL PROPIONATE 4909240 FLAMMABLE LIQUID UN124S Methyl propionate is a clear colorless liquid, it is used as a flavoring and as a solvent. It has a flash point of 28 deg. F. It is lighter than water and is slightly soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish lire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors 344 Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water METHYL PROPYL KETONE 4909216 FLAMMABLE LIQUID UN1249 Methyl propyl ketone is a dear colorless liquid with an odor of fingernail polish. It has a flash point of 45 deg. F. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Ff material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water METHYL SULFATE (See DIMETHYL SULFATE 4933322) METHYL SULFIDE (See DIMETHYL SULFIDE 4908122) METHYL VINYL KETONE, INHIBITED 4907260 FLAMMABLE LIQUID UN1251 POLYMERIZABLE Methyl vinyl ketone is a clear colorless liquid. It has a (lash point of 20 deg. F. If contaminated or subjected to heat it may polymerize. If the polymerization takes place in a container, the container may violently rupture. It is lighter than water and soluble in water, Its vapors are heavier than air. Its vapors are heavier than air. ff material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical H material not on fire and not involved in lire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain (low as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water April 1961 mod 0017271 Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered N-METHYL-N'-NITRO-N-NITROSOGUANIDINE 4916723 FLAMMABLE SOLID NA1325 N-methyl-n'-nitro-nitrosoguanidine If material on fire or involved in fire Flood with water If material not on fire and not involved in fire Keep sparks, flames, and other sources oi ignition away Keep material out of water sources and sewers Keep material dry Personnel protection Wear boots, protective gloves, and goggles Oo not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material METHYLACETYLENE-PROPADIENE, STABILIZED 4905758 FLAMMABLE GAS UN1060 Methylacetylene-propadiene stabilized is a colorless gas with an acetylene like odor. It is shipped as a liquefied gas under its vapor pressure. Contact with the liquid can cause frostbite. It is easily ignited. Its vapors are heavier than air and a flame can flash back to the source of leak very easily. This leak may be either a liquid or a vapor leak. It can asphyxiate by the displacement of air. Under fire conditions the cylinders or tank cars may violently rupture and rocket. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment Approach fire with caution Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered METHYLACRYLATE, INHIBITED 4907245 FLAMMABLE LIQUID UN1919 POLYMERIZABLE Methyl acrylate is a clear colorless liquid with an acrid odor. It has a flash point of 27 deg. F. The vapors are irritating to the eyes and res piratory system, if the material is subjected to heat for prolonged periods or becomes contaminated, it is subject to polymerization with evolution of heat. If (he polymerization takes place inside a container, the container may violently rupture. The material is lighter than water and is slightly soluble in water. Its vapors are heavier than air. April 1981 If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 2500 feet If material leaking (not on fire), downwind evacuation must be considered METHYLAL 4908222 FLAMMABLE LIQUID UN1234 Methylal is a clear colorless liquid with a chloroform-tike odor. It has a flash point of 0 deg. F. It is lighter than water and soluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered METHYLCHLOROMETHYL ETHER, ANHYDROUS 4907430 FLAMMABLE LIQUID, POISONOUS UN1239 Methylchtoromethyl ether is a clear colorless liquid. It has a flash point of -4 deg. F. It is irritating to the eyes and respiratory system. Prolonged exposure to its vapors may result in death. It is heavier than water and is decomposed by water to form hydrochloric acid, a corrosive material, its vapors are heavier than air. Continued on next page 345 MCI) 000017272 If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to disperse vapors and dilute standing pools of liquid Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodiiy contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered METHYLCYCLOHEXANE 4909330 FLAMMABLE LIQUID UN2296 Methyl cyclohexane is a clear colorless liquid with a petroleum like odor. It has a flash point of 25 deg. F. It is tighter than water and insoluble in water. Its vapors are heavier than air. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical H material not on fira and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water METHYLDICHLOROARSINE 4920520 POISON A NA1556 Methyldichloroarsine is a colorless liquid with a strong burning odor. In low concentrations it is very irritating to the respiratory system and in higher concentrations or prolonged exposure to low concentrations it is toxic by inhalation. Contact with the liquid will cause very painful bums. The material may only be shipped in cylinders and these must be overpacked in wooden boxes. Prolonged exposure to fire or heat may cause the cylinders to violently rupture and rocket 346 If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or bums with difficulty.) Use water in flooding quantities as fog Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do rot handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered METHYLDICHLOROSILANE 4907625 FLAMMABLE UQU10, CORROSIVE, ACIDIC UN1242 Methyldichlorosilane is a colorless fuming liquid with a pungent odor. It has a flash point of -26 deg. F. Vapor and liquid can cause burns. It is heavier than water and is decomposed by water to form hydrochloric acid, a corrosive material. Its vapors are heavier than air. If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use "alcohol" foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors ft material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered METHYLFURAN 4906210 FLAMMABLE LIQUID UN2301 Methylfuran is a dear colorless liquid with an ether like odor. It has a flash point of -22 deg. F. It is lighter than water and insoluble in water. Its vapors are heavier than air. April 1961 MOD 000017273 If material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may spread fire Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 leet If material leaking (not on fire), downwind evacuation must be considered METHYLMETHACRYLATE MONOMER, UNINHIBITED FLAMMABLE LIQUID 4907255 NA1247 POLYMERIZABLE ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-S000/2270) Methyl methacrylate monomer, uninhibited is a clear colorless liquid. It is used to make plastics. It has a flash point of 50 deg. F. The vapors are irritating to the eyes and respiratory system. Containers of the ma terial must be shipped under refrigeration, or the chilled material may be shipped in heavily insulated containers. If the material becomes con taminated or the chilled material warms up, it may polymerize. If the polymerization takes place inside a container, the container is subject to violent rupture. It is lighter than water and slightly soluble in water. Its vapors are heavier than air. It weighs 7.8 pounds per gallon. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may spread fire Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep matenal out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear boots, protective gioves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or soiid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete April 1961 Absorb bulk liquid with fly ash. cement powder, sawdust, or com mercial sorbents Apply "universal" gelling agent to immobilize spill Apply fluorocarbon-water foam to diminish vapor and fire hazard Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e.g. detergent, soaps, alcohols) to com press and thicken spilled material Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms If dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors METHYLTRICHLOROSILANE 4907630 FLAMMABLE LIQUID, CORROSIVE, ACIOIC UNI250 Methyltrichlorosilane is a colorless fuming liquid with a pungent odor. It has a flash point of 8 deg. F. Vapor and liquid can cause bums. It is heavier than water and is decomposed by water to form hydrochloric acid, a corrosive material, its vapors are heavier than air. if material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use "alcohol" foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered METHYL PARATHION, LIQUID 4921442 POISON B, COMBUSTIBLE NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-100/45.4) Methyl parathion, liquid is a clear colorless liquid, it is used as a pesticide. It is slightly soluble in water and it is a combustible liquid. It is toxic by inhalation and skin absorption. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300 it weighs 11.3 pounds per gallon. Continued on next page 347 MCD O00017274 If material on fire or Involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use foam, carbon dioxide or dry chemical If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If material leaking (not on fire), downwind evacuation must be considered Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fiy ash or cement powder Environmental considerations--water spill Use natural barriers or oil spill control booms to limit spill motion Use surface active agent (e.g. detergent, soaps, alcohols) to com press and thicken spilled material Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms if dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Remove trapped material with suction hoses Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors MEVINPHOS (AGRICULTURAL INSECTICIDES, NEC, 4921531 LIQUID) POISON B NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RO-1/0.454) Mevinphos is a yellow to orange liquid. It is used as a pesticide. It is a water emuisifiable liquid. It is toxic by inhalation, skin absorption, and/ or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424- 9300. If material on fire or involved in fire Do rot extinguish fire unless flow can be stopped Use water in flooding quantities as tog Solid streams of water may be ineffective Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohof foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind 348 Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid orsoiid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spiii if dissolved, apply activated carbon at ten times the spilled amount in region of 10ppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors MEVINPHOS (AGRICULTURAL INSECTICIDES, NEC, 4921532 OTHER THAN LIQUID) POISON B NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Mevinphos is a yellow to orange liquid absorbed on a dry carrier. It is used as a pesticide. It is a wettable powder. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to. or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical N material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spiii Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates MEVINPHOS (INSECTICIDES, OTHER THAN 4921533 AGRICULTURAL, NEC) POISON B NA27B3 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Mevinphos is a yellow to orange liquid or the liquid absorbed on a dry carrier. It is used as a pesticide, it is a wettable powder or water emul- sifiable liquid. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. April 1981 MCD 000017275 If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use 'alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak it without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors MEVINPHOS MIXTURE, DRY (AGRICULTURAL 4921538 INSECTICIDES. NEC, OTHER THAN LIQUID) POISON B NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Mevinphos mixture, dry is a yellow to orange liquid absorbed on a dry carrier. It is used as a pesticide. It is a wettable powder. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. If material on fire or involved in fire Extinguish tire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carton dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water April 1981 MOD 0000.17276 Environmental considerations--water apill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates MEVINPHOS MIXTURE, LIQUID (AGRICULTURAL 4921539 1NSECTC1DES, NEC, LIQUID) POISON B NA2783 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1/0.454) Mevinphos mixture, liquid is a yellow to orange liquid. It is used as a pesticide. It is a water emulstfiable liquid. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. If material on fire or involved in fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors MEXACARBATE (AGRICULTURAL INSECTICIDES. 4921541 NEC, LIQUID) POISON B NA2757 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Mexacarbate is a white solid dissolved in a liquid carrier. It is used as a pesticide. It is awater emulsifiabte liquid. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 800-424-9300. If material on fire or Involved In fire Do not extinguish fire unless flow can be stopped Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Continued on next page 349 if material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Attempt to stop leak if without hazard Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amcunts of water or soap and water Environmental considerations--land spit) Digapit, pond lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors MEXACARBATE (AGRICULTURAL INSECTICIDES, 4921542 NEC, OTHER THAN LIQUID) POISON B NA2757 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Mexacarbate is a white solid. It is used as a pesticide, ft is a wettable powder. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone; 600-424-9300. If material on fire or involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this materia! if contact with the material anticipated, wear full protective clothing Environmental considerations--iand spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water Environmental considerations--water splii Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom If dissolved, apply activated carbon at tan times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates 350 MEXACARBATE (INSECTICIDES, OTHER THAN 4921540 AGRICULTURAL, NEC) POISON B NA2757 ENVIRONMENTALLY HAZARDOUS SUBSTANCE (RQ-1000/454) Mexacarbate is a white solid or the solid dissolved in a liquid carrier. It is used as a pesticide. It is a wettable powder or water emulsitiable liquid. It is toxic by inhalation, skin absorption, and/or ingestion. In case of damage to, or leaking from containers of this material contact the pesticide safety team network. Telephone'. 800-424-9300. If material on fire or involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical If material not on fire and not Involved in fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Avoid breathing dusts, and fumes from burning material Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Environmental considerations--land spill Dig a pit, pond, lagoon, holding area to contain liquid or solid material Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete Absorb bulk liquid with fly ash or cement powder Environmental considerations--water spill If dissolved, apply activated carbon at ten times the spilled amount in region of lOppm or greater concentration Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates Environmental considerations--air spill Apply water spray or mist to knock down vapors MILD DETONATING FUSE, METAL CLAD 4903355 CLASS C EXPLOSIVE Mild detonating fuse, metal clad consists of a core containing not more than 15 grains of high explosive composition per foot and not exceeding 26 feet in length or containing not more than 2 l /2 grains of high explosive composition per foot covered with metal. It may or may not be covered with tapes, yams, plastics or waterproofing compounds. Under fire con ditions they will explode. If material on fire or involved In fire Dangerously explosive Flood with water Apply water from as far a distance as possible If material not on fira and not Involved in fire Keep sparks, flames, and other sources of ignition away Personnel protection Approach fire with caution Avoid breathing dusts, and fumes from burning material Wear self-contained breathing apparatus when fighting fires involv ing this material Evacuation If fire becomes uncontrollable--evacuate lor a radius of 1500 feet April 1981 'tf1 oOOO' MINE RESCUE EQUIPMENT CONTAINING CARBON 4904645 DIOXIDE NONFLAMMABLE GAS NA1956 Mine rescue equipment containing carbon dioxide consists of various apparatus and a cylinder of carbon dioxide. Carbon dioxide is nonflamm able and is heavier than air. It can asphyxiate by the displacement of air. If material Involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not Involved In fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Wear protective gloves and goggles Do not handle broken packages without protective equipment Attempt to stop leak if without hazard Use water spray to knock-down vapors Do not use water on material itself Neutralize spilled material with crushed limestone, soda ash. or lime Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear full protective clothing Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Evacuation If fire becomes uncontrollable or container is exposed to direct flame--evacuate for a radius of 1500 feet If material leaking (not on fire), downwind evacuation must be considered MINING REAGENT, LIQUID (CONTAINING 20% OR 4931442 MORE CRESYLIC ACID) CORROSIVE MATERIAL. ACIDIC NA2022 Mining reagent, liquid (containing 20% or more cresylic acid) is a variable colored liquid with a phenol-tike odor. It is insoluble in water. It is corrosive to tissue. If material on fire or Involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing MIXEO CHLOROSILANES (FLAMMABLE LIQUID, 4907636 CORROSIVE, N.O.S.) FLAMMABLE LIQUID. CORROSIVE UN2924 Mixed chlorosilanes are a clear colorless liquid having a pungent odor, it has a flash point of less than 100 deg. F. Both the liquid and vapor are corrosive. It is decomposed by water to give hydrochloric acid. Its vapors are heavier than air. H material on fire or involved In fire Do not extinguish fire unless flow can be stopped Use ``alcohol'' foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Do not use water on material itself If large quantities of combustibles are involved, use water in flooding quantities as spray and fog Use water spray to absorb vapors H material not on fire and not Involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary April 1961 ,00 ^ 8 0< MIXEO LOAD OF GROCERIES AND GROCERS 4950160 SUPPLIES Consult shipping paper for exact contents of the car. container or trailer MONO-(TRICHLORO) TETRA-(MONOPOTASSIUM 4918420 DICHLORO) PENTA-S-TRIAZINETRIONE (DRY CONTAINING MORE THAN 39% AVAILABLE CHLORINE) OXIDIZER NA2468 Mono*(trichloro)tetra-(monopotassium dichioro) penta-s-triazinetrione is a white crystalline solid with an odor of chlorine, it is used as a dry bleach in household cleaning compounds and swimming pool disinfec tants. The material itself is noncombustible but if contaminated with combustible material ignition can result. It will also accelerate the burning of combustible material. Contact with ammonium compounds or hy drated salts can cause a very vigorous chemical reaction. May vigorously react with small Quantities of water releasing chlorine gas. Prolonged exposure of the material to fire or heat may result in the vigorous de composition of the matenaf and the rupturing of its containers. Material containing less than 39% available chlorine will undergo reactions as described above though it may take longer to initiate and the resulting reaction may not be as vigorous. If material on fire or involved In fire Flood with water Cool ail affected containers with flooding quantities of water Apply water from as far a distance as possible If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Personnel protection Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water Wear self-contained breathing apparatus when fighting fires involv ing this material If contact with the material anticipated, wear full protective clothing Approach fire with caution Evacuation If fire becomes uncontrollable--evacuate for a radius of 2500 feet 351 MONO-TERT-BUTYL-META-CRESOL (COMBUSTIBLE 4913172 LIQUID, N.O.S.) COMBUSTIBLE LIQUID NA1993 Mono-tert-butyl-meta-cresol is a clear colorless liquid. It is used as a disinfectant, to make rubber, as a lubricating oil additive, and for many other uses. It has a flash point of 116 deg. f. and a melting point of 74 deg. F. It is lighter than water and insoluble in water. If material on fire or involved in fire Use water in flooding quantities as fog Solid streams of water may be ineffective Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use "alcohol" foam, carbon dioxide or dry chemical Use water spray to absorb vapors If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water MONOBROMOTRIFLUOROMETHANE 4904549 NONFLAMMABLE GAS UN1009 Monobromotrlfluoromethane is a colorless, odorless gas. It is shipped as a liquefied gas under its own vapor pressure. It is noncombustibie. It can asphyxiate by the displacement of air. Contact with the liquid can cause frostbite. If material involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not bum or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible If material not involved In fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment MONOCHLOROACETIC ACID, LIQUID 4931444 CORROSIVE MATERIAL, ACIDIC UN1750 Monochloroacetic acid, liquid is a colorless solution of the white crys talline solid. It is corrosive to metals and tissue. If material on fire or involved In fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or bums with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible Use water spray to absorb vapors If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Build dikes to contain flow as necessary Neutralize spilled material with crushed limestone, soda ash, or lime Personnel protection Avoid breathing vapors Keep upwind Avoid bodily contact with the material 352 Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing MONOCHLOROACETONE, STABILIZED OR INHIBITED 4925250 IRRITATING MATERIAL UN1695 Monochloroacetone. stabilized or inhibited is a colorless liquid with the pungent odor characteristic of hydrochloric acid. Its vapors are ex tremely irritating to the eyes and mucous membranes. If material on fire or involved in fire Use water in flooding quantities as fog Use "alcohol" foam, carbon dioxide or dry chemical Cool all affected containers with flooding quantities oi water Use water spray to absorb vapors If material not on fire and not involved In fire Keep sparks, flames, and other sources of ignition away Keep material out of water sources and sewers Use water spray to knock-down vapors Personnel protection Avoid breathing vapors Keep upwind Wear self-contained breathing apparatus Avoid bodily contact with the material Wear boots, protective gloves, and goggles Do not handle broken packages without protective equipment Wash away any material which may have contacted the body with copious amounts of water or soap and water If contact with the material anticipated, wear full protective clothing Evacuation If material leaking (not on fire), downwind evacuation must be considered MONOCHLORODIFLUOROMETHANE 4904552 NONFLAMMABLE GAS UN1018 Monochlorodifluoromethane is a colorless gas with an ethereal odor. It is shipped as a liquefied gas under its own vapor pressure. It is noncombustible, ft can asphyxiate by the displacement of air. Contact with the liquid can cause frostbite. Toxic gases can be produced in fires involving this material. If material involved in fire Extinguish fire using agent suitable for type of surrounding fire (Material itself does not burn or burns with difficulty.) Cool all affected containers with flooding quantities of water Apply water from as far a distance as possible if material not involved in fire Attempt to stop leak if without hazard Personnel protection Avoid breathing vapors Keep upwind Wear protective gloves and goggles Do not handle broken packages without protective equipment MONOCHLOROETHYLENE (See VINYL CHLORIOE, MONOMER 4905792) MONOCHLOROPENTAFLUOROETHANE 4904555 NONFLAMMABLE GAS UN1020 Monochloropentafluoroethane is a colorless odorless gas with an ether like odor. It is shipped as a liquefied gas under its own vapor pressure. It is noncombustible. It can asphyxiate by the displacement of air. Contact with the liquid can cause frostbite. 7.n9 .A' April 1981