Document GKZdRmDndO01dBaapJEwkzov

TM MATERIAL SAFETY DATA SHEET A DELAWARE LIMITED PARTNERSHIP - tSri ' f `A' drJ : i' PLASTICS BCP Management Inc. General Partner BOX 427, GEISMAR, LOUISIANA 70734 Emergency Telephone (614) 431-6600 (OPERATION ALERT) THE OSHA HAZARD COMMUNICATION STANDARD 29 CFR 1910*1200 REQUIRES THAT THE INFORMATION CONTAINED ON THESE SHEETS BE MADE AVAILABLE TO YOUR WORKERS* INSTRUCT YOUR WORKERS TO HANDLE THIS PRODUCT PROPERLY* FOR INDUSTRIAL USE ONLY VISTA POLYMERS CO INC ATTN: SAFETY DEPT NON-EMERGENCY TELEPHONE HIGHWAY 25 <304) 387-3101 ABERDEEN* MS 39730 description: PRODUCT type: application: SIGNAL WORD DANGER f VINYL CHLORIDE MONOMER VINYL CHLORIDE MONOMER USE IN MANUFACTURE OF POLYVINYL CHLORIDE CUR ISS 41* ft* ft 41 ft* 1-4 4 ft** h* ' IM *to ft # ftM *9* 4*4 #** *4** 49* ?4t4 44H ftW* *444 * P* *H< ** 49* **4 <ft** 4444 HH *4 ** *4t *** ill I *W->t 4-4 M4 f ft tot 4f t *4* ttlf ItR MN 44# +** * * fc- *<-4 4-4 fit 4*4 3 rt* M W* W RH 4*4 PAGE 1 20-MAY-89 1*1 tn * This material is a "health hazard* and/or a "physical hazard* as determined when reviewed according to the reouirements of the Occupational Safety and Health Administration 29 CFR Part 1910*1200 "Hazard Communication" Standard * or ; xu rv is; xs*1 mto m*. ** 4* ft 4w * *h #4' ** *4*1 * to* to 4* a 44 * * r 4 ** *4** 4*-* *4a 44f #44 14* t#i 4*4 *** 44*4 to*# 4 44 *4* 4 t** *< ***# 14# *# *#. 4 i W* f* *4* W** *4* * *4 *- me* a #4 ffi * 4to 4 M 4*4 4*4 4*4 44* #4* 4 f M ** l # * * * ** t ***#*- CHEMICAL HAZARD RATING HEALTH3<hidh> FIRE4<extreme) REACTIVITY**^ (slight) CHRONIC*** ssr sr -- xx us sx :&* sr ss at* a* r ^ ^ n: :r is* % is r: t" 4 I i* mat1 r 4ft 444- *9 ft 4444 ** *9* *4 P 4+ #4* 44? 4 44 *4 444 444* *9* t* * 44* 4*4* 49# *9- Ml 4*4 * 49# H* tto* Ml |mi #* * #*>#*- mme *4 4r mm* ft #4 am* * 4 - 9*- aw *#m 4* a 4*9- * * 4* *e4** *to* *4* 4 lto 4' t # # *91 fea> P4t 444# 4*4# ftto* tW *#i *4 29CFRI910* 1200 HAZARDOUS INGREDXENTS/REPORTED HEALTH EFFECTS CAS/REGISTRY NO* MATERIAL DESCRIPTION 4*4 m 44M #to H If The ingredients listed below have been associated with one or more of the listed immediate and/or delawed(*) health hazards* Risk of damage and effects depends upon duration and level of exposure* BEFORE USING OR HANDLING? READ AND UNDERSTAND THE MSDS. 75-01-4 *VINYL CHLORIDE CANCER HAZARD* Can cause cancer* This material has been listed bw NTP? IARC or OSHA as a human carcinogen Can cause liver damage* Can cause kidney damage* Can cause central nervous system depression* Signs and symptoms may include headache? dizziness? nausea? vomiting? unconsciousness and even death* ACBIH TLV1 5 PPM <10 MG/M3) TWA OSHA PEL! 1 PPM TWA? 5 PPM 15-MINUTE STEL NIOSH DOCUMENT NUMBER: 79-102 OTHER: OSHA PEL: CANCER-SUSPECT AGENT? 29CFR1910 * 1017 #rt *4 t #* to*** p* a m4 4 4 ?** #9* tto* i* 144 'M til * #4 4 ft > ft ft *4 44 # *4 * 4 * 44 4*4 *+A *4# + * to 4* 4ft ft ? 7* nr? *rf tr? *rj4 4 9* <* ft rf* 4*4 * m ft 4ft* *4 4 t*4 #4 * (* Itoft 4 4< #9* ftfftt -ftft* *** 44 4*44 444 4* ft '44* 444* 4**ft N ft* T ft <444 M4 READ NEXT PAGE DISCLAIMER --SEE REVERSE SIDE VAB.0001070663 TM MATERIAL SAFETY DATA SHEET A DELAWARE LIMITED PARTNERSHIP BORDEN CHEMICALS and PLASTICS Emergency Telephone (614) 431-6600 (OPERATION ALERT) BCP Management Inc. General Partner BOX 427, GEISMAR, LOUISIANA 70734 DESCRIPTION VINYL CHLORIDE HONOHER PRODUCT TYPEi VINYL CHLORIDE MONOMER application: USE XN MANUFACTURE OF POLYVINYL CHLORIDE CUR f *-*- . Ml- 4 * ** * * *4|v *** Wt #* H * t H tf-p-t M ' IP 4 ^ fWl M*1 ***1 tP1 1 W* * f * * rt N N P* 4 t i * 1 4 W f * 44 A H A fWi M* *<* *#" *P b f1 1st | H I 41 # B > *' 1 29CFR1910 * 1200 HAZARDOUS INGREBIENTS/REPQRTED HEALTH EFFECTS CAS/RE6ISTRY NO* MATERIAL DESCRIPTION A PAGE 2 20--MAY-89 I#* Mb M4 *< M* ** 4 m* * fr* *PP i 4 * . *v M* Mt M* Mb |b Mi W* *W fVi MM H * tit ti It* W * * Wt * t ** hh M *44 Ml M 4 *M i Mi Ml Mb MV1 *** Mf Wt f <* t * I M i* *4 I * *4 # V* |44 I M 4** MW* M* p* ' #b *4* I4> *' M1 * + *4* *t *4* Mb #* *M *4 +4 -* * #4* * * 4 * MM PHYSICAL DATA SOLUBILITY IN MATER -- SLIGHT SPECIFIC GRAVITY 25/25 C MELTING POINT VAPOR PRESSURE APPEARANCE BOILING POINTr 760 MM HG* ODOR VAPOR DENSITY <AIR=l>* 2SSZZZ23a:3S2Bt22SEi3i2m8S30S8ii2i32iiXSm ttrsris;ssr cvt*Trt;:r scrz:PL*n; 0 * 90S -256 DEG F AT 68 DEG F 3*39 ATM COLORLESS LKiUJD GAS 7*0 DEG F FAINTLY SWEET 2*15 I* Ml Mfl M* **! mi #i hm Mi 4*4 * Ml t *+ *M 9+T 4 * *i ** #* 4 M lt|f M V M *# t^i * 4* 4 * ! Mt* VM *41 *41 M* fl4 *#* M* M* * ** ** *4* t* frn 9* U *| tM ** ** tM* i*i *ai *** vat a *a mi t*v f 4i nt- i4- *t I H 4 If Ml a*v IMMEDIATE HEALTH HAZARD DATA SKIN ABSORPTION* No hazards known t.o Borden* INGESTION* May be harmful if swallowed* INHALATION: Harmful if inhaled* Can cause burns to nose* throat and lungs* Can cause central nervous system depression* SKIN: Causes burns* EYES: Causes burns* M4 MM rif aw4 * Me* 1*1 a Be il* 44* H7* VMM' **H4 I M* 4*4 **** *44 a*4 *4#e *4** *M<* 4*1 * *4 1*1 t*1 Ml 1*4 4*1 4t 4*i t v4 44 #f t *4 + *4 4 M aB f w t *4 V 41 4+ - IM 4** 4 t * 4 *t * * 44* 4*i 1*1 mm* Ml * *> M * fT* 4 # *? r4*41 * *4 i Ml *M* 4 Mi t 44 l 4* HANDLING PRECAUTIONS INHALATION: Do not breathe gas or mist* Use with adeeuate ventilation* SKIN* Do not get on skin* EYES: Do not set in eves* Handle in accordance with good industrial hygiene and safety practices* These practices include avoiding unnecessary exposure and removal of the material from eyes* skin and clothing* Wash thoroughly after handling* 4 M * Si * ** 4*4 * 4^ V*4l M* MB- 4*41 *4*4 41*4 4*4 **l #1** *** +**4 44** t*` ' #41 6* * * 4* - 4*m -Mm 44* 444 4 4 * M` H' *14 * * - *14* 4 44 44*4 4** * k V* 4*t 4* V M< 44 * 44* V4* 14 4** 1 M* i * H * V? 4*4 I 44 -4 H *44 I ft tt *4 *i 1*1 4N4 t#i 4W Mb l< Mt Mt Mi * *M* *** *4* *4 *** B I* *4* I* t | V* bM *- EMERGENCY AND FIRST AID PROCEDURES INGESTION! If accidently swallowed* dilute by drinking large Quantities of water* Immediately contact poison control center or hospital emergency room for any other additional treatment directions* INHALATION* If inhaled* remove to fresh air* If not breathing give artificial respiration* preferably mouth-to-mouth If breathing is difficult! give oxygen* Call a physician* SKIN CONTACT! Immediately flush skin with plenty of water* Remove contaminated clothing* Call a physician* Wash clothing before reuse* EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes* Eyelids should be held apart during irrigation to insure water contact with me* MV 4*44 *4* M n* 44*4 1*4 tftt tv* AM 4*4 *M* * 44* 14** * ** *1*1 *M4 4*4 4*fc p M1* Mb *M M f V4* -Mm*- M * MV 44 4 *B 441 |*f 44b 4#' 441 4* t*< 4*4 H*< f*t i4 #* 4^4 M< Ml l B*v t M* mm * 4m* 44^ V*l M * # f*t Ml *4* i 4*4* *M* fit 4M* |p* Mi MM MM *M4 Ml HH 4*M Mi Ml MM MM *M MM met* 4*4* MM *MW 4* * V* t H M* *** M M44 #M* Ml M* vw 4e - in Vr^i ****** t * ** I * x # * * b v# p- vp *** b *i V ** t* i * 4* V - W'4 *4 | M i H h* f P ** V P4 4m 4 *1 4Mt * *V 44*t 1 * * M%M* *44 * 4-t-V 4*1 *4B. - 1*4 **n Hb *4*4 *14 4 #+ V *4 * * * m * M DISCLAIMER --SEE REVERSE SIDE READ NE^J00PAG)64 TM MATERIAL SAFETY DATA SHEET * DELAWARE LIMITED PARTNERSHIP BORDEN CHEMICALS and PLASTICS Emergency Telephone (614) 431-6600 (OPERATION ALERT# BCP Management Inc. General Partner BOX 427, GEISMAR, LOUISIANA 70734 DESCRIPTION* PRODUCT TYPE* APPLICATION* VINYL CHLORIDE MONOMER VINYL CHLORIDE MONOMER USE IN MANUFACTURE OF POLYVINYL CHLORIDE tw im *** # t fi n* * ft tf t i f** tiff ft-** Hfi 44* 444* ft* tft* 41 * I |. fn 4 * *4' ** *< *+' ft--ft fat mm* mm* * **#" f H ft *tat *t*mtm4 ft PAGE 3 CUR ISS 20MAY-89 ft-ft ft t * i<* mm* 4f *#- fifT m* * ft-ft mm* *m mm* ** p* *1-1 -tft ++ * * ft 4 r | ft I-* fttit EMERGENCY AND FIRST AID PROCEDURES entire surface of ewes and lids* Call a physician* 4* * me * ft* 4* ft ' * h3? *^f -1* ir* i*? *3? *4 * *1 ff i 44 M *44 if i' .ftf f ft* * 4f p* 4 4 H +* ft M l* fti # f f tf tM * * *** 4ft4 PM1* 4 ft * i **e ei - m* * ft It* ft `44 i 4*4 *' MM ft** JJJJ ^m+ *** FIRE AND EXPLOSION HAZARD DATA EXTREMELY FLAMMABLE GAS* Keep vaeor away fro* heat* sparks? flame and other ignition sources including? hut not limited to? pilot lights? heaters? cigarettes? electric motors and static discharge* Vapor is heavier titan air and may settle in low places or travel outward to a source of ignition 4- f tm *+ *** and flashback* In case of fire? allow gas to burn if flow cannot be shut off immediately* Apply water from a safe distance to cool container and protect surrounding area* **m f 4 l *+* *p* ** a me *44 mm* 4 *4 4 m *4 ** +*** tmi n 1*4 ! * #*** *** -mm m i-mf m *4*44* 4ff 1 M H4 * 4* *# am 4 ft*4 -wm* mmm *mm BH W tH ** +mm '** ** +mm *4 I * 44 4** am * ** * *mm *?mm **+ *?* *mm <44 +** *# wh *m* *mm * 44 4 REACTIVITY DATA Normally stable? but maw become unstable at high temperatures or maw react with water* j --------- umx am. mm ma 44*f 4444 mm I *ftflft mim-t fm t Mil 4444 mam- 4*44 pw< Igf 4444 I4< i4* flff |f< 44< 44? fgi 44* * M 4144 Mf 4141 Mf Mf I Ml 444i 14 ' M? 444t 4m# ft m#t j 44 *g* jjjp J5J jjf Jgf 33 S3 S S3 S3 S3 S IS* S IS 3* S c JT* ** ?7. ITJ !* n *7 *h IB* * * In* >A w % 4+ ** rz* < *** ** #* * *** * *** 1*4 mm* *4* mi4* 4tf a-*t tmi <* *-*j 44? mm* <4i ittt 4*^ > <41 144 4i *14* 4*1 m^ *m *4 44 4-4 44 # 494 m-*ft 4*4 4 44 f t 4 4ft ft* # 4 44ft p ll tfi * 44 4* ft < ( CONTROL MEASURES If airborne contaminants are generated when the material is heated or handled? sufficient ventilation in volume and air flow patterns should be provided to keep air contaminant concentration levels below acceptable criteria* ENGINEERING CONTROLS* The following exposure control techniaues maw be used to effectively minimize employee exposure* local exhaust ventilation? enclosed system design? process isolation and remote control in combination with appropriate use of personal protective eeuipment and prudent work practices* These techniaues may not necessarily address ell issues pertaining to your operations* We? therefore? recommend that wou consult with experts of your choice to determine whether or not your programs are adeauate* SStStSStSX3!g223S&S!S?3SX3&SSmKS?Vt;t2?tSS? 1ST iff SS! SSi 15* Ml 44* #4tft *4*4 < 1* mm 1 *<** *h 4 44 r 44 4 *4 ft H 4t *** ***** M* * 4 #* * * mm* **: 4* 4 ** *h* * * ** 4 mm +4i* 1 4 ft 4 ft* mmt *m mi * mi mm* mm* mm*- mm* f*< pki **e *t *** 4*t 4*1 |*< *l * ft*> ftf I * *-i "ft *m m* pm* m *-* *ma 4*1 ft Mm **4 Iftft ft M ft tf 4*4 ftftl 444 *4* * * *p #*? arnm * tmt *** #<* 4m? *** ft * t ! * 4m mm t M t ** #' ** * m4 PERSONAL PROTECTION INFORMATION Wear full protective suit $ boots if contact is likely* Where air contaminants can exceed acceptable criteria? use NIOSH/MSHA approved respiratory protection eeuipment* Respirators should be selected based on the form and concentration of contaminants in air in accordance with OSHA 29 CFR 1910*134 or other applicable standards or guidelines* Use goggles and face shield if contact is likely* Wear impervious gloves as reeuired to prevent skin contact * #*4* Him mmmm * *< it* it* mmm mm* mrnmm ** mm** mm** tpt m* * Ml* mm* ft mi * *4* mm *** mm** * ***<- mm** * *** *** **? ** mn Mt *? im* ** *< *m? mm* mm* *( *- mm* 4m* f*? *? mm - 4*t t*i **+ *** mm * mm* mm* mm* * mm mm* **? #* * mm* *** *< I* *4* ** ftft* 1 44M *mmm imam to iv *m* *919 *11 ^am mm* <m* mm** <^* *mi* <pi ** iat mb* mb* Am* mm hh m pmmm mb* m* iw Aim ** tp'* mm* < * #-* -* * mm * mt *4 < ** +* l #> n u 4? mt* < ^ ft m * **+ 4* + * ?*** *-** ft m 1 ft -ft*> * ft^r mm* t # Ml * M? *m * * <4 4+* ft m READ NEXT PAGE DISCLAIMER --SEE REVERSE SIDE VAB.0001070665 I:, I i *h- r' ** TW I MATERIAL SAFETY DATA SHEET A DELAWARE LIMITED PARTNERSHIP BORDEN CHEMICALS and PLASTICS BCP Management Inc. General Partner BOX 427, GEISMAR, LOUISIANA 70734 Emergency Telephone (614) 431-6600 (OPERATION ALERT) A description: product type: application: vinyl chloride mqnoher vinyl chloride monomer PACE A CUR ISS 20-MAY-89 use in manufacture of polyvinyl chloride * 44* tt 1*4 ti * t+ t*4 4 f i m* ftm* *m-* mm* *t** m ^ mm* * + mm* * *'1 + * m *** mm*, mm* mm *mm* mm* mm* *t +** mm* *** mmm m'* m*>r m t* *.+ mm * mm* m mm mm*. * +i m mm A mm m w* mm 4 M I t #* fc-4 i Ml * mm t4 M4 I * lb f *44 4 m* I ` mm* M* Ml >4^ *4- *41 *** | t' i * 4 m-*\ * * I 4 ! r I iH SPILL OR LEAK PROCEDURES Keep upwind of spills or leaks* is? 22 ss set sr sr sr ss sir s? sr is: ar sx :sr sa? is: ss; sr i n,' sc 32 ;& at * jr* rv rrr:r JT Ii ** * Ml M4 4V *l *4# Ml* M* *e+ *4 |+ tl m *H I ** *" # *-* * M 4 MM* ta fM * n *4* et 4 I4 I 4 * 4 fr 4 M< M *e *4* Mt m h * * I M * Mt * ** *4* * 4 1 fr fe* tI4t* Ml Mt ffti 4 * II I : WASTE DISPOSAL Dispose of according to local* state/provincial * and federal reauirements* Empty container: Maw contain explosive vapors* DO NOT cut* puncture or weld on or nearbw* mm* SSm 3Si SSm SL* Si* SSm S3* U* JiJf Sim * 1# t mm* m*m* mm* rn*m* mmrnm #e* it 4 * ** mm m * * +* in * * m * m* **t *m* m*m* *4 *+ I 4 M *>* M I l* Mt *4# pf t 14* M* IP + L* |l 4 | * Nt * m* * Ml Ml mm* Ml M* *41 *4 44 Iti * * h * I 41 >* 4m* * i ih m *41 fr t < Mt 4* *44 *14 STORAGE PRECAUTIONS Violent polymerization tu occur at elevated temperatures * Ml M1 4B4 Mi M* Ml 44* M* *4* 4*4 4 M* f tM ttl *4 - 1 * *-1 * **' it H| Ml * ft Ml 4 * * *T m Mt |MI *4' * * # 4 *'* * * *4 Ml' 4 tl ' la 4i i awh mm* av# amt mm* mm* *m* <ai mm* * * * * *4 -4 * fM 4m m *H 0M 4i f*t 4 t # 4 *4 MM DOT CLASSIFICATION Flammable Gas* m mm 35 ^5 aw * M ** *m Mi mmm aw Mi mi Mi Mr Mi Mi tf mm mi m> Mi mi m* if# mi M m* *ta* mn M* *4# 4r **i m *-< amt atit Mi fii* mi m M* mi Mi 14* *4* ir t4i Mi mi ** mi Mr mi * iff *mt v* ft* -4J *4P' SS 5ip 55 aw 3^ 4^ 44* 3 fim m m iot a m m 4na (iw aw am mm m mm mm m mm mm mm m av^ *4* *4 t * h 4 it *1* t * t w> im 11^ (4 mi tu mi* p ih t * * +* * mi p* trt ap-* t 4l tf> rmm* mm* mm mm' si **+1 m mm* mm* * it 1 * 600 PN-VCN PREVIOUS ISSUE:19-N0V-88 PRINT DATE: 12-Har-9J 02M2 PH CURRENT ISSUE:20-AY-89 THIS IS THE LAST PAGE DISCLAIMER --SEE REVERSE SIDE VAB.0001070666 TM MATERIAL SAFETY DATA SHEET A DELAWARE LIMITED PARTNERSHIP BORDEN CHEMICALS and PLASTICS BCP Management Inc. General Partner BOX 427, GEISMAR, LOUISIANA 70734 SARA TITLE III SECTION 313 AND AO CFR Part 372 TOXIC CHEMICAL NOTIFICATION SHEET Emergency Telephone (614) 431-6600 (OPERATION ALERT) A VINYL CHLORIDE MONOMER This product contains the following toxic chenicsKs) subject to the reporting reeuiregents of Section 313 of Title III of the Superfund Amendments 3nd Reauthorination Act of 1986* and Subpart C-Suprlier Notification Reouirement of AO CFR Part 372* CAS Registry Number Chemical Name 75-01-4 VINYL CHLORIDE (MONOMER) Pet* By Height * + 99*80 This Toxic Chemical Notification Sheet must not be detached from the Material Safety Data Sheet (MSDS)* Any copying and redistribution of the MSDS shall include copsing and redistribution of this notification sheet attached to copies of the MSDS subsequently redistributeti nlfW* *TT A1? > I 4M IH HM a mm mm am* *+* fW Vf * *+ i i m * n a * *mp g #4 s? pi *r? *r? *??pg * 4 ft* *a ^ p n> 4 a +-aa ii im am* i a* gT mS fti agn SS# mm mm *5* IS? 600 PM-VCM PRINT DATE * 12-Mr-91 02M2 PM DISCLAIMER --SEE REVERSE SIDE VAB.0001070667 f h 4 t '\ * * | V I - r * S 4 J. i X t 1 t *4 4i I I- rj J j k *.i t DISCLAIMER * i: ` SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR THE MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE OR CONCERNING THE ACCURACY OF ANY INFORMATION PROVIDED BY BORDEN CHEMICALS AND PLASTICS OPERATING LIMITED PARTNERSHIP, BCP MANAGEMENT, INC., except that the product shall conform to contracted specifications, and that the product does not infringe any valid United States patent. The information provided herein was believed by Borden Chemicals and Plastics Operating Limited Partnership, BCP Management, Incl to be accurate at the time of preparation or prepared from sources believed to be reliable, but it is the responsibility of the user to investigate and understand other pertinent sources of information, to comply with all laws and procedures applicable to the safe handling and use of product and to determine the suitability of the product for its intended use. Buyer's exclusive remedy shall be for damages and no claim of any kind, whether as to product delivered or for non-delivery of product, and whether based on contract, breach of warranty, negligence or otherwise shall be greater in amount than the purchase price of the quantity of product in respect of which damages are claimed. In no event shall Seller be liable for incidental or consequential damages, whether Buyer's claim is based on contract, breach of warranty, negligence or otherwise. t + tt: K * * i % * * * .< i kh \T I mr- r n v ii v \ i ) 1 ' i t V 1 "d A '*C* t i. v * VAB.0001070668