Document GKQLQn9qOBVe2eYzXxGym2DEx

Ethyl *________________* > MATERIAL SAFETY DATA SHE-ET EMERGENCY PHONE (504) 344-7147 66.0.1 PRODUCT IDENTIFICATION TRADE NAME: SYNONYMS: MOTOR FUEL ANTIKNOCK COMPOUND Alkyl Lead Compound Antiknock Compound Lead Antiknock Compound PM Antiknock Dilutes TEL Aviation Antiknock TEL Motor Antiknock TML Antiknock Tetraethyl Lead Tetramethyl Lead MLA Antiknock CHEMICAL FAMILY: Organic lead, tetralkyl plunbanes. CHEMICAL FORMULA: <C2Hs>APb (TEL) <CHj)4Pb <TML>. MOLECULAR WEIGHT: 323.45 (TEL). CAS NAME: Non-specific. Mixture containing tetraalkyl lead such as tetraethyl and/or tetramethyl lead (TEL or TML) with one or more halogen compounds such as ethylene dibromide or ethylene dichloride and hydrocarbon solvents. CAS NO.: See "Hazardous Components" section. THIS MATERIAL COMPLIES WITH THE TOXIC SUBSTANCE CONTROL ACT (15 USC 2601-26291. 5ARDOPS COMPONENTS Tetraethyl Lead Tetramethyl lead Oiethyldimethyl Lead - in MLA only Ethyltrimethyl Lead - in MLA only Triethylmethyl Lead - in MLA only Ethylene Oichtoride Ethylene Oibromide Toluene Kerosene Xylene - In Dilute Solutions Only N-Heptane - In Oilute Solutions Only CAS NO. 78*00*2 75-74-1 1762-27-2 1762-26-1 1762-28-3 107-06-2 106-93-4 108-88-3 8008-20-6 1330-20-7 142-82*5 X 1-61 1-51 12-23 2-24 2-27 5-19 5-36 1-13 1-3 49-50 21 SAL 000009706 GSS16 CHEMICAL fi PHYSICAL PROPERTIES TRADE NAME KOTOR FUEL ANTIKNOCK COMPOUND APPEARANCE/OOOR: ODOR THRESHOLD; SOILING POINT: MELTING POINT: SPECIFIC GRAVITY <3 20'C): VAPOR PRESSURE urn Kg (3 2Q*C/68*F): VAPOR OENStTY: SOLUBILITY IN UATER: PERCENT VOLATILES: EVAPORATION RATE: Dyed red, orange or blue liquid with a sweet and/or musty odor. 1/3 of TLV. 93 K9*C 9 760 m Hg. (Calculated). 137 -30*C (TEL A TML) 0.9 - 1.7 5 - 41 4-7 (air 1.0). 0.002 wt X a 1*C (as lead alkyl). 99 wt. X a 20*C. 1.0 (water = 1.0). FIRE 6 EXPLOSION HAZARDS FLASH POINT (METHOD): AUTOIGNITION TEMPERATURE: AUTO DECOMPOSITION TEMPERATURE: EXTINGUISHING MEDIA: SPECIAL FIRE FIGHTING PROCEDURES: UNUSUAL FIRE ANO EXPLOSION HAZARDS: 13 - 108*C (TCC). (Closed cup flash points for MFAC are meaningless because of unpredictable trace amounts of low boilers present.) (TEL) 127'C. (TEL) 2E0*C. Ory chemical, water spray, chemical foam or carbon dioxide. Remote activation preferred. Evacuate personnel to a safe area. Keep personnel removed and upwind of fire. Wear self-contained breathing apparatus. Wear full-protective equipment (eye, body, respiratory). Use water spray. Cool tank/container with water spray. Mixtures may be flammable or combustible depending upon type of lead alkyl and/or diluents. Hazardous gases produced in fire are inorganic lead fuses; hydrogen halides. REACTIVITY DATA STABILITY: HAZARDOUS DECOMPOSITION: MATERIALS TO AVOID: HAZARDOUS POLYMERIZATION: Stable. Unstable with heat. Decomposes with heat. Decomposition temperature 100C - 1S0*C. Hazardous gases produced are inorganic lead fumes, hydrogen halides. Strong oxidizing agents, halogens and concentrated acids. Will not occur. SAL 000097,07 Page 2 TRADE NAME: HOTOR FUEL ANTIKNOCK COHPOUHP HEALTH HAZARDS This product contains skin irritants, ye irritants, and is untested for animal sensitization. ORGANIC LEAD COMPONENTS: Toxic effects expected in animals from short exposures by inhalation, ingestion, or skin contact would be largely attributable to the organic lead ingredients and would include central nervous system effects and liver effects. Tetraethyl lead does not have reproductive effects. Enbryotoxic effects are seen only at exposure levels at which significant maternal toxicity occur. Otherwise, no chronic toxicity information is available. Hwman health effects of overexposure by inhalation, ingestion, or skin or eye contact determined by the organic lead ingredients may initially include: subtle central nervous system effects such as insomnia or mood changes, progressing * with continued or higher exposure - to toxic psychosis with deliriua, convulsions or coma. Higher exposures may lead to: nonspecific discomfort, such as nausea, headache, or weakness; abnormal liver function as detected by laboratory tests; pulmonary edema; or fatality from gross over exposure by either neurologic effects or pulmonary edema. Skin permeation can occur in amounts capable of producing the effects of systemic toxicity. There are no reports of human sensitization. Individuals with preexisting diseases of the central nervous system may have increased susceptibility to the toxicity of excessive exposures. Ethyl recommends handling products containing organic lead compound as potential hunan develop* mental toxins, and states that the employment of women of chil{tearing potential in operations involving direct exposure to lead compounds should be avoided; however, contact with products containing trace quantities and exposure to airborne levels equivalent to normal ambient back ground levels are permitted. ETHYLENE 01BRQN1DE: Toxic effects described in animals from short exposures by inhalation, ingestion, or skin contact include liver and lung effects. Tests in some animals demonstrate carcinogenic activity. Tests in bacterial or maomalian cell cultures demonstrate mutagenic activity. Tests for reprodjctive toxicity in animals have been inconclusive, with positive results in seme studies, and negative results in others. Human health effects of overexposure by inhalation, ingestion, or skin or eye contact may include: non-specific discomfort, such as nausea, headache, or weakness; eye irritation with discomfort and tearing or blurring of vision; abnormal liver function with nausea or vomiting, reduced appetite, or abdominal pain or irritation of the upper respiratory passages. Skin permeation can occur in amounts capable of producing the effects of systemic toxicity. Epidemiologic studies do not demonstrate a significant risk of hunan cancer from exposure to this compound. Toxic effects described in arainals from short exposures by inhalation, ingestion or skin contact include liver, central nervous system, and kidney effects; temporary alteration of the heart's electrical activity with irregular pulse, palpitations or inadequate circulation; or possibly modest initial symptoms followed in hours by severe shortness of breath requiring prompt medical attention; and nonspecific effects such as weight loss and irritation. Tests in some animals demonstrate carcinogenic activity. Tests in bacterial or mammalian cell cultures demonstrate mutagenic activity. Animal testing indicates that this compound does not have evnbryotoxic, nor reproductive effects. Page 3 G S 3 16 TRADE NAME: MOTOR FUEL ANTIKNOCK COMPOUND HEALTH HAZARD8 - Continued ETHYLENE DICHLORIDE: Hunan health effects of overexposure by inhalation, ingestion, skin or eye contact may include: nose and throat irritation, anesthetic effects with headache and confusion, progressing with higher exposure to unconsciousness; nonspecific discomfort, such as nausea, headache, or weakness; abnormal liver or kidney function as detected by laboratory tests. Skin premeat ion can occur in amounts capable of producing the effects of systemic toxicity. There are no reports of hunan sensitization. Epidemiologic studies do not demonstrate significant risk of hunan cancer from exposure to this compound. Individuals with preexisting diseases of the liver may have increased susceptibility to the toxicity of excessive exposures. KEROSENE: Toxic effects described in animals from short exposures by inhalation, ingestion, or skin contact include lung and kidhey effects, and narcosis. No animal test reports are available to define carcinogenic, eabryotoxic, or reproductive hazards. Tests in bacterial or manmalian cell cultures demonstrate no mutagenic activity. Human health effects of overexposure by inhalation, ingestion, or skin or eye contact may initially include: nonspecific discomfort, such as nausea, headache, or weakness; abnormal kidney function as detected by laboratory tests; or temporary lung irritation effects with cough, discomfort, difficulty breathing, or shortness of breath. Higher exposures may lead to these effects: temporary nervous system depression with anesthetic effects such as dizziness, headache confusion, incoordination, and loss of consciousness; possibly modest initial synptons, followed in hours by severe shortness of breath, requiring prompt medical attention or fatality from gross overexposure. Skin premeation can occur in amounts capable of producing the effects of systemic toxicity. There are no reports of hunan sensitization. Individuals with preexisting diseases of the liver, or kidneys may have increased susceptibility to the toxicity of excessive exposures. TOLUENE: Toxic effects described in animats from exposure by inhalation, include neurologic depression, reversible liver changes, increased cardiac susceptibility to the arrythmogenic effects of adrenalin, and bone marrow effect. Animal testing indicates that this compound does not have carcinogenic, mutagenic, embryotoxic, nor reporductive effects. Human health effects of overexposure by inhalation, ingestion, or skin or eye contact may initially include: abnormal liver function as detected by laboratory tests; temporary nervous depression with anesthetic effects such as dizziness, headache, and confusion; irritation of the upper respiratory passages; and eye irritation with discomfort, tearing, or blurring of vision. Higher exposure may lead to these effects: non-specific discomfort, such as nausea, headache, or weakness; nervous system depression with anesthetic effects such as incoordination and toss of consciousness; abnormal kidney function as detected by laboratory tests; or fatality from gross overexposure. Significant skin premeation appears unlikely. There are no reports of hunan sensitization. Individuals with preexisting diseases of the central nervous system, cardiovascular system, liver, kidneys, or bone marrow may have increased susceptibility to the toxicity of of excessive exposures. (Toluene is an ingredient only in antiknock compounds containing tetramethy lead.) Page - SAL 000009709 TRADE NAME: MOTOR FUEL AMTICTOCK tOMPOtaa HEALTH HAZARDS - Continued XYLEME: Toxic effects described in animats from exposure by inhalation include liver and central nervous system effects. Tests in animals demonstrate no carcinogenic activity. Tests in bacterial and mammalian cell cultures demonstrate no mutagenic activity. Tests in animals demonstrate enferyotoxic activity. Tests in rats demonstrate increased nunbers of morphologically abnormal sperm at high dosage levels. Honan health effects of overexposure by inhalation, ingestion, or skin or eye contact may initially include: eye irritation with discomfort, tearing, or blurring of vision; nonspecific discomfort, such as nausea, headache, or weakness; and temporary nervous system depression with anaesthetic effects such as dizziness, headache, confusion, incoordination, and loss of conscious ness. Higher exposures may lead to fatality from gross overexposure. Evidence suggests that skin permeation can occur in amounts capable of producing the effects of systemic toxicity. There are no reports of hinan sensitization. Individuals with preexisting diseases of the central nervous system or liver may have increased susceptibility to the toxicity of excessive exposures. (Xylene and n-Heptane are used only as the diluents in dilute solutions of anitknock compound packaged in one liter cans.) n-HEPTANE: Kixnan health effects of overexposure by inhalation, ingestion or skin or eye contact may include: eye irritation with discomfort; skin irritation upon prolonged or repeated contact, respiratory tract irritation with narcosis in high concentrations. Toxic effects in animals occuring only with inhalation exposures are anesthetic effects, kidney, brain and central nervous system effects, respiratory effects and non-specific effects such as weight loss and irritation. ANIMAL DATA TETRAETHYL LEAD: TETRAMETHYL LEAD: Inhalation 1 hour LC 50: Skin absorption LD50: Oral LD50: 0.85 mg/1 in rats. 200 - 1S00 mg/kg in rabbits. 29 mg/kg in rats Highly toxic by inhalation (4 hour LCSO 10 - 100 ppm; 0.08 0.6 mg/1). Moderately toxic by contact (LD50 200 - 5000 mg/kg). Highly toxic by ingestion (oral LD50 5 - 500 mg/kg). Inhalation 1 hour LD50: Skin absorption LD50: Oral 1050: greater than 8.9 mg/1. 6200 mg/kg in rabbits. 108 mg/kg in rats. Moderately toxic by inhalation (4 hour LD50 100 - 1000 ppm; 0.8 - 8 mg/1). Slightly toxic by contact (LD50 5000 - 10,000 mg/kg). Moderately toxic by ingestion (oral 1050 - 500 mg/kg). saL 000009710 Page 5 G S 31$ i TRADE NAME: MOTOR FUEL AWT1KNOCK COMPOUND ANIMAL DATA - Continued ETHYLENE 01 BROMIDE: Inhalation 2 hour AID: Skin absorption 1050: Oral 1050: 200 ppm in rats. 300 mg/kg in rabbits. 140 mg/kg in rats. Moderately toxic by inhalation (4 hour L050 100 - 1000 ppm; 0.08 - 8 mg/1). Moderately toxic by contact (LD5Q 200 - 5000 mg/kg). Moderately toxic by ingestion <Oral LD50 50 - 500 <ng/kg). ETHYLENE 01 CHLORIDE: Inhalation 4 hour LC50 : Skin absorption LD50: Oral LO50: 2100 ppm in rats. 2800 mg/kg in rabbits. 680 mg/kg in rats. Slightly toxic by inhalation <4 hour LD50 1000 * 5000 ppm; 8 * 50 mg/1). Moderately toxic by contact (L0S0 200 - 5000 mg/kg). Slightly toxic by ingestion (oral LDSO 500 5000 mg/kg). KEROSENE: Oral 1050: 20,400 mg/kg in guinea pigs. Very low toxicity by ingestion (oral L050 greater than 5000 mg/kg). XYLENE: inhalation 6 hour LC50: Skin absorption (.050: Oral AL0: 3907 ppm in mice. No information found. 4400 mg/kg in rats. Very low toxicity by inhalation (4 hour LC50 greater than 5,000; greater than 40/mb/1). Slightly toxic by ingestion (oral 1050 500 5000 mg/kg). CARCINOGENICITY The following ingredients are listed by IARC, NTP, or OSHA as carcinogens: 1 RAC NTP OSHA CHEMICAL: Ethylene Dichloride X Ethylene Dibromide XX X EXPOSURE LIMITS TETRAETHYL LEAO TETRAHETHYl LEAD ETHYLENE DIBROMIDE TUA,, (Ethvl) 0.1 ppm. ETHYLENE DICHLORIOE KEROSENE TOLUENE XYLENE n-HEPTANE TLV fACGIH) 0.1 mg/nr as Pb, skin. 0.15 mg/m^ as Pb, skin. PEL (OSHA) -0--.-0--7--5----m---g-/-m-3 , skin. 0.075 mg/m*, skin. A2, skin. 20 ppm TUAg. 10 ppm, 40 mg/**. 30 ppm Ceiling. 50 ppm TUAg. 100 ppm Ceiling. 200 ppm - 5 min. max. Not established. 100 ppm, 375 mg/ai*. STEL 150 ppm, 560 mg/m^. t 100 ppm, 435 mg/m , STEL 150 ppm, 655 mg/m^. 400 ppm, 1600 mg/m^ Not established. Not established. 100 ppm, 435 mg/m^. skin. 400 ppm, 1600 mg/m^. STEL 150 ppm, 2000 mg/m^ UEEL (AIHA) Not established. Not established. Not established. Not established. Not established. Not established Not established. SAL 000009711 Page 6 TRADE NAME: G S 3 16 MOTOR FUEL ANTIKNOCK COMPOUND SAFETY PRECAUTIONS Do not breathe vapor or mist. Do not get in eyes. Oo not get on skin. Do not get on clothing. Uash thoroughly after handling. Wash clothing after use. Discard shoes if contaminated. FIRST AID INHALATION: ETC CONTACT: SKIN CONTACT: INGESTION: If inhaled, remove to fresh air. If not breathing, give artificial respiration, preferably mouth-to-mouth. If breathing is difficult, give oxygen. Get medical attention. In case of contact, imnediately flush eyes with plenty of water for at least IS minutes. Get medical attention. In case of contact, immediately flush skin with kerosene and wash with plenty of soap and water for at least IS minutes while removing contaminated clothing and shoes. Uash clothing before reuse. Get medical attention. If swallowed, induce vomiting immediately by giving two glasses of water and sticking finger down throat. Never give anything by mouth to an unconscious person. Get medical attention. PROTECTIVE INFORMATION GENERALLY APPLICABLE CONTROL MEASURES AMO PROCEDURES: Use a totally enclosed system. Use only with adequate ventilation. Keep away from heat, sparks and flames. Keep container tightly closed. Do not mix with strong oxidizers, halogens, concentrated acids. Do not consume food, drink or tabacco in the areas where they may become contaminated with this material. Hove with vacuum. PERSONAL PROTECTIVE EQUIPMENT: Chemical goggles. H10SH approved organic vapor respirator. In emergency situation, NIOSH approved self contained breathing apparatus (SCBA). Protective footwear - Neoprene or PVC. Protective gloves * Neoprene or PVC. 0000971-2 SAL 0 Page 7 rTS3l6 TRADE NAME: MOTOR FUEL AHT1 KNOCK COMPOUND AOUATIC TOXICITY TETRAETHYL LEAD: Extremely toxic (96 hr LCSO less than 0.5 mg/1). The 96 hour LC50 in bluegill fish is 0.1S ppm. TETRAMETHYL LEAO: Highly toxic (96 hr LC50 0.5 - 1 mg/1). The 96 hour LCSO in fathead minnows is 19.3 ppm. ETHYLENE 0IBR0M10E: Hoderately toxic (96 hr LC50 1-50 mg/1). The 96 hour TLM in bluegill sunfish is 18 ppm. ETHYLENE D1CHLORIDE: Slightly toxic (96 hr LCSO 50-500 mg/1). The 96 hour LCSO in bluegill sunfish is 430 mg/1. TOLUENE: Hoderately toxic (96 hr LCSO 1-SO mg/1). The 96 hour LCSO in fathead minnows is 34-42 mg/1. XYLENE: Hoderately toxic (96 hr LC50 1-50 mg/1). The 96 hour LCSO in fathead minnows is 27-42 mg/1. DISPOSAL INFORMATION $P1LL/LEAJC/RELEASE: Superfund reportable discharge 10 lbs. for Tetraethyl lead. Review fire and explosion hazards and safety precautions before proceeding with clean up. Use appropriate personal protective equipment during clean tp. Evacuate personnel, thoroughly ventilate area, use self-contained breathing apparatus. Remove source of heat sparks, flame, impact, friction or electricity. Keep ipwjnd of leak * evacuate until gas has dispersed, if unable to extinguish fire, let burn until consumed. Dike spill. Prevent liquid from entering sewers, water ways or low area. Recover free liquid for reuse or reclamation. Soak up with sawdust, sand, oil, dry or other absorbent material. Neutralize small spills (less than 5 gal.) with 5X solution of Potassim Permanganate. WASTE DISPOSAL: Clearted-up material is a RCRA Hazardous Waste. Treatment, storage, transportation and disposal must be in accordance with Federal, State, and local regulations. Recover for reclamation. Recover nonusable free liquid and/or contaminated water, and dispose of in an approved and permitted biological treatment system or an approved and permitted deepwell. Remove nonusable solid material and/or contaminated soil, for disposal in an approved and permitted landfill. Do not flush to surface water or sanitary sewer system. Contaminated soil can be decontaminated thermally by heating in an approved incinerator or furnace. STORAGE CONDITIONS: Do not store with explosives, flaontable liquids or strong oxidizing agents. Store in well ventilated area. Keep container tightly closed. Oo not store or consume food, drink or tobacco in area where they may become contaminated with this material. Provide cooling water for fire. SAL 0000000000997^ 13 Page 8 TRADE NAME: 6 S 3 16 MOTOR FUEL ANTIKNOCK COMPOUND REVISED: 10/03/88 MSDS prepared by: Ethyl Corporation, Health and Environment Department FOR ADDITIONAL NON-EMERGENCY USDS INFORMATION, CONTACT: ETHYL CORPORATION HEALTH & ENVIRONMENT DEPARTMENT 451 FLORIDA STREET BATON ROUGE, LA 70801 <504> 388-7717 SUPERCEDES: 11/13/85 FOR ALL OTHER NON-EMERGENCY INFORMATION, CONTACT TOUR LOCAL ETHYL SALES REPRESENTATIVE. ___________________ THIS MATERIAL SAFETY DATA SHEET CONTAINS AT LEAST THE INFORMATION REQUIRED BY THE FEDERAL OSHA HAZARD COMMUNICATION RULE, COMM 29 CFR 1910.1200 <g) (2). o*1 0oO Page 9 TRADE NAME: GS316 TEL DILUTE GRAM BASIS ADDENDUM TO MSDS DATED: 3/07/89 MSDS ADDENDUM Regulatory Information SARA Title III, Section 313 This sheet has been prepared as a supplement to the Ethyl Corporation Material Safety Data Sheet. According to 40 CFR, Part 372, Subpart C, it must remain with the MSDS and all copies thereof. DO NOT DETACH! This product contains the following toxic chemicals subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 and of 40 CFR 372: COMPONENT______________ Ethylene dibromide Ethylene dichloride Xylene Tetraethyl lead CAS NUMBER 106-93--4 107-06-02 1330-20-7 78-00-2 PERCENTAGE <36.0 <19.0 <50.0 <62.0 2321E/16 000009715 SAL