Document GK8112XNGBZj5zp8ejQ6yeepx

----------------------------------------------------------------------------------------------------------------------------------------------------------------------- * Date Printed: 08-15-1996 Page 1 LA-MAR-KA, INC. MSDS MSDS for BROMOTHYMOL BLUE INDICATOR, METHANOLIC 1 -PRODUCT IDENTIFICATION PRODUCT NAME: COMMON NAMES: CHEMICAL FAMILY: FORMULA: FORMULA WT.: CAS NO.: NIOSH/RTECS NO.: PRODUCT USE: BROMTHYMOL BLUE INDICATOR, METHANOLIC BROMOTHYMOL BLUE INDICATOR, (0.04%) DYES AND INDICATORS N/A N/A 76-59-5 NA LABORATORY REAGENT CHEMTREC # (800) 424-9300 LA-MAR-KA, INC. 10272 SOUTH PERDUE STREET BATON ROUGE, LA. 70814 EFFECTIVE: 06/06/94 ISSUED: 06/06/94 REVIEWED 1-1-95 REVISION #03 PRECAUTIONARY LABELING LA-MAR-KA LABELING SYSTEM HEALTH - 3 SEVERE (POISON) FLAMMABILITY - 3 SEVERE (FLAMMABLE) . REACTIVITY - 1 SLIGHT CONTACT - 1 SLIGHT LABORATORY PROTECTIVE EQUIPMENT GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD; PROPER GLOVES; CLASS B EXTINGUISHER U.S. PRECAUTIONARY LABELING POISON DANGER FLAMMABLE. HARMFUL IF INHALED. CANNOT BE MADE NON-POISONOUS. MAY BE FATAL OR CAUSE BLINDNESS IF SWALLOWED. KEEP AWAY FROM HEAT, SPARKS, FLAME. DO NOT GET IN EYES, ON SKIN, ON CLOTHING. AVOID BREATHING VAPOR. KEEP IN TIGHTLY CLOSED CONTAINER. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. IN CASE OF FIRE, USE ALCOHOL FOAM, DRY CHEMICAL, CARBON DIOXIDE - WATER MAY BE INEFFECTIVE. FLUSH SPILL AREA WITH WATER SPRAY. PRECAUTIONARY LABELING (CONTINUED) INTERNATIONAL LABELING HIGHLY FLAMMABLE. TOXIC BY INHALATION AND IF SWALLOWED. KEEP OUT OF REACH OF CHILDREN. KEEP CONTAINER TIGHTLY CLOSED. KEEP AWAY FROM SOURCES OF IGNITION - NO SMOKING. AVOID CONTACT WITH SKIN. ( DO A 060688 CONFIDENTIAL H-------------------------------------------------------------------------------------------------------------------------------------------------------------------- + Date Printed: 08-15-1996 Page 2 LA-MAR-KA, INC. MSDS MSDS for BROMOTHYMOL BLUE INDICATOR, METHANOLIC 4. ------------------------------------------------------------------------------------------------------------------------------------------------------------------+ 1 -PRODUCT IDENTIFICATION (continued) LA-MAR-KA STORAGE COLOR CODE: RED (FLAMMABLE) 2 -COMPONENTS COMPONENT METHANOL BROMTHYMOL BLUE CAS NO. 67-56-1 76-59-5 WEIGHT % 90-100 >1 OSHA/PEL 200 PPM N/E ACGIH/TLV 200 PPM N/E 3 -PHYSICAL DATA BOILING POINT: 65 C (149 F) (AT 760 MM HG) VAPOR PRESSURE (MMHG): 96 (20 C) MELTING POINT: -98 C (-144 F) (AT 760 MM HG) VAPOR DENSITY (AIR=1): 1.11 SPECIFIC GRAVITY: 0.79 (H20=l) EVAPORATION RATE: 4.6 (BUTYL ACETATE = 1) _ ^LUBILITY(H2 0) : COMPLETE (100%) % VOLATILES BY VOLUME: 100 (21 C) PH: N/A ODOR THRESHOLD (P.P.M.): N/A PHYSICAL STATE: LIQUID COEFFICIENT WATER/OIL DISTRIBUTION: N/A APPEARANCE & ODOR: CLEAR, ORANGE LIQUID. PUNGENT ODOR. 4 -FIRE AND EXPLOSION HAZARD DATA FLASH POINT (CLOSED CUP): 12 C (54 F) NFPA 704M RATING: 1-3-0 AUTOIGNITION TEMPERATURE: 463 C (867 F) FLAMMABLE LIMITS: UPPER - 36.0 % LOWER - 6.0 % FIRE EXTINGUISHING MEDIA USE ALCOHOL FOAM, DRY CHEMICAL OR CARBON DIOXIDE. (WATER MAY BE INEFFECTIVE.) ( OO A 060689 CONFIDENTIAL _l_- - - - - --- - - - - - - - - - - - - - - - - - - - - - - - - --- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - --- - - - - - - - - - - - - - -- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - -- --- - - - - - - --- - - - - - - -- -- -- -- --- - - - - - - - - - - - - - - - - - - - - - - f- Date Printed: 08-15-1996 Page 3 LA-MAR-KA, INC. MSDS MSDS for BROMOTHYMOL BLUE INDICATOR, METHANOLIC * ------------------------------------------------------------------------------------------------------------------------------------------------------------------ + 4 -FIRE AND EXPLOSION HAZARD DATA (continued) SPECIAL FIRE-FIGHTING PROCEDURES FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE. MOVE CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK. USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL. UNUSUAL FIRE & EXPLOSION HAZARDS VAPORS MAY FLOW ALONG SURFACES TO DISTANT IGNITION SOURCES AND FLASH BACK. CLOSED CONTAINERS EXPOSED TO HEAT MAY EXPLODE. CONTACT WITH STRONG OXIDIZERS MAY CAUSE FIRE. BURNS WITH A CLEAR, ALMOST INVISIBLE FLAME. TOXIC GASES PRODUCED CARBON MONOXIDE, CARBON DIOXIDE, FORMALDEHYDE EXPLOSION DATA-SENSITIVITY TO MECHANICAL IMPACT NONE IDENTIFIED. EXPLOSION DATA-SENSITIVITY TO STATIC DISCHARGE NONE IDENTIFIED. ^ -HEALTH HAZARD DATA ( THRESHOLD LIMIT VALUE (TLV/TWA): 260 MG/M3 (200 PPM) THE TLV LISTED DENOTES TLV (SKIN). SHORT-TERM EXPOSURE LIMIT (STEL): 310 MG/M3 (250 PPM) PERMISSIBLE EXPOSURE LIMIT (PEL): 260 MG/M3 (200 PPM) TOXICITY OF COMPONENTS ORAL RAT LD50 FOR METHANOL INTRAPERITONEAL RAT LD50 FOR METHANOL SUBCUTANEOUS MOUSE LD50 FOR METHANOL SKIN RABBIT LD50 FOR METHANOL CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: 5628 9540 9800 20 NO MG/KG MG/KG MG/KG G/KG CARCINOGENICITY NONE IDENTIFIED. REPRODUCTIVE EFFECTS NONE IDENTIFIED. EFFECTS OF OVEREXPOSURE INHALATION: IS HARMFUL AND MAY BE FATAL, HEADACHE, NAUSEA, VOMITING, DIZZINESS, NARCOSIS, RESPIRATORY FAILURE, LOW BLOOD D0 A 060690 confidential Date Printed: 08-15-1996 LA-MAR-KA, INC. MSDS MSDS for BROMOTHYMOL BLUE INDICATOR, METHANOLIC ( 5 -HEALTH HAZARD DATA (continued) Page 4 PRESSURE, CENTRAL NERVOUS SYSTEM DEPRESSION SKIN CONTACT: IRRITATION, PROLONGED CONTACT MAY CAUSE DERMATITIS EYE CONTACT: IRRITATION, MAY CAUSE TEMPORARY CORNEAL DAMAGE SKIN ABSORPTION: NONE IDENTIFIED INGESTION: IS HARMFUL AND MAY BE FATAL, BLINDNESS, HEADACHE, NAUSEA, VOMITING, DIZZINESS, GASTROINTESTINAL IRRITATION, CENTRAL NERVOUS SYSTEM DEPRESSION, HEARING LOSS CHRONIC EFFECTS: KIDNEY DAMAGE, LIVER DAMAGE TARGET ORGANS EYES, SKIN, CENTRAL NERVOUS SYSTEM, GI TRACT, RESPIRATORY SYSTEM, LUNGS MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE EYE DISORDERS, SKIN DISORDERS, LIVER OR KIDNEY DISORDERS PRIMARY ROUTES OF ENTRY INHALATION, INGESTION, EYE CONTACT, SKIN CONTACT, ABSORPTION .ERGENCY AND FIRST AID PROCEDURES INGESTION: CALL A PHYSICIAN. IF SWALLOWED, IF CONSCIOUS, GIVE LARGE AMOUNTS OF WATER. INDUCE VOMITING. INHALATION: IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. SKIN CONTACT: IN CASE OF CONTACT, IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. WASH CLOTHING BEFORE RE-USE. EYE CONTACT: IN CASE OF EYE CONTACT, IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. SARA/TITLE III HAZARD CATEGORIES AND LISTS ACUTE: YES CHRONIC: YES FLAMMABILITY: YES PRESSURE: NO REACTIVITY: NO EXTREMELY HAZARDOUS SUBSTANCE: CERCLA HAZARDOUS SUBSTANCE: SARA 313 TOXIC CHEMICALS: GENERIC CLASS: TSCA INVENTORY: NO YES YES YES CONTAINS METHANOL (RQ = 5000 LBS CONTAINS METHANOL C05 ( DO A 06069 CONFIDENT I -------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- + Date Printed: 08-15-1996 Page 5 LA-MAR-KA, INC. MSDS MSDS for BROMOTHYMOL BLUE INDICATOR, METHANOLIC 6 -REACTIVITY DATA STABILITY: STABLE CONDITIONS TO AVOID: INCOMPATIBLES: DECOMPOSITION PRODUCTS HAZARDOUS POLYMERIZATION: WILL NOT OCCUR HEAT, FLAME, OTHER SOURCES OF IGNITION STRONG OXIDIZING AGENTS, STRONG ACIDS, ZINC, ALUMINUM, MAGNESIUM CARBON MONOXIDE, CARBON DIOXIDE, FORMALDEHYDE 7 -SPILL & DISPOSAL PROCEDURES STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING. SHUT OFF IGNITION SOURCES; NO FLARES, SMOKING OR FLAMES IN AREA. STOP LEAK IF YOU CAN DO SO WITHOUT RISK. USE WATER SPRAY TO REDUCE VAPORS. TAKE UP WITH SAND OR OTHER NON-COMBUSTIBLE ABSORBENT MATERIAL AND PLACE INTO CONTAINER FOR LATER DISPOSAL. FLUSH AREA WITH WATER. ^TSPOSAL PROCEDURE ( DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL ENVIRONMENTAL REGULATIONS. EPA HAZARDOUS WASTE NUMBER: U154 (TOXIC WASTE) 8 -INDUSTRIAL PROTECTIVE EQUIPMENT VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV REQUIREMENTS. RESPIRATORY PROTECTION: RESPIRATORY PROTECTION REQUIRED IF AIRBORNE CONCENTRATION EXCEEDS TLV. AT CONCENTRATIONS ABOVE 200 PPM, A SELF-CONTAINED BREATHING APPARATUS IS ADVISED. EYE/SKIN PROTECTION: SAFETY GOGGLES AND FACE SHIELD, UNIFORM, PROTECTIVE SUIT, RUBBER GLOVES ARE RECOMMENDED. 9 -STORAGE AND HANDLING PRECAUTIONS LA-MAR-KA STORAGE COLOR CODE: RED (FLAMMABLE) r? A 06069p C0N^TDENTTAi + -- ---- -- ----- -- LA-MAR-KA, INC. MSDS MSDS for BROMOTHYMO.L BLUE INDICATOR, -------------- Date Printed: METHANOLIC ------------ -- 08-15-1996 ----" -- -- + Page 6 9 -STORAGE AND HANDLING PRECAUTIONS (continued) STORAGE REQUIREMENTS KEEP CONTAINER TIGHTLY CLOSED. FLAMMABLE LIQUID STORAGE AREA. STORE IN A COOL, DRY, WELL-VENTILATED, SPECIAL PRECAUTIONS BOND AND GROUND CONTAINERS WHEN TRANSFERRING LIQUID. 10 -TRANSPORTATION DATA AND ADDITIONAL INFORMATION DOMESTIC (D.O.T.) UN 1230 N/A = NOT APPLICABLE OR NOT AVAILABLE N/E = NOT ESTABLISHED THE INFORMATION IN THIS MATERIAL SAFETY DATA SHEET MEETS THE REQUIREMENTS OF THE UNITED STATES OCCUPATIONAL SAFETY AND HEALTH ACT AND REGULATIONS PROMULGATED THEREUNDER (29 CFR 1910.1200 ET. SEQ.) AND THE CANADIAN WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM. THIS DOCUMENT IS INTENDED ONLY AS A ( IDE TO THE APPROPRIATE PRECAUTIONARY HANDLING OF THE MATERIAL BY A PERSON ..<AINED IN, OR SUPERVISED BY A PERSON TRAINED IN, CHEMICAL HANDLING. THE USER IS RESPONSIBLE FOR DETERMINING THE PRECAUTIONS AND DANGERS OF THIS CHEMICAL FOR HIS OR HER PARTICULAR APPLICATION. DEPENDING ON USAGE, PROTECTIVE CLOTHING INCLUDING EYE AND FACE GUARDS AND RESPIRATORS MUST BE USED TO AVOID CONTACT WITH MATERIAL OR BREATHING CHEMICAL VAPORS/FUMES. EXPOSURE TO THIS PRODUCT MAY HAVE SERIOUS ADVERSE HEALTH EFFECTS. THIS CHEMICAL MAY INTERACT WITH OTHER SUBSTANCES. SINCE THE POTENTIAL USES ARE SO VARIED, LA-MAR-KA CANNOT WARN OF ALL OF THE POTENTIAL DANGERS OF USE OR INTERACTION WITH OTHER CHEMICALS OR MATERIALS. LA-MAR-KA WARRANTS THAT THE CHEMICAL MEETS THE SPECIFICATIONS SET FORTH ON THE LABEL. LA-MAR-KA DISCLAIMS ANY OTHER WARRANTIES, EXPRESSED OR IMPLIED, WITH REGARD TO THE PRODUCT SUPPLIED HEREUNDER, ITS MERCHANTABILITY OR ITS FITNESS FOR A PARTICULAR PURPOSE. THE USER SHOULD RECOGNIZE THAT THIS PRODUCT CAN CAUSE SEVERE INJURY AND EVEN DEATH, ESPECIALLY IF IMPROPERLY HANDLED OR THE KNOWN DANGERS OF USE ARE NOT HEEDED. READ ALL PRECAUTIONARY INFORMATION. AS NEW DOCUMENTED GENERAL SAFETY INFORMATION BECOMES AVAILABLE, LA-MAR-KA WILL PERIODICALLY REVISE THIS MATERIAL SAFETY DATA SHEET. APPROVED BY LA-MAR-KA, INC. DO A 060693 CONFIDENTIAL +------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------ + Date Printed: 08-15-1996 Page 7 LA-MAR-KA, INC. MSDS a M--S--D-S----f-o---r---B--R--O-M---O-T--H--Y-M--O--L----B-L--U--E----IN---D--IC--A--T--O--R---,---M--E--T-H--A--N--O--L--IC------------------------------------------------------+ 10 -TRANSPORTATION DATA AND ADDITIONAL INFORMATION (continued) ( f DO A 060694 CONF rOFTNTTAL